diff --git a/PL9fwy3NUQKwY9jl8xw-bWkVZkWcGGyspd/1ElgyngArXQ_postprocess.srt b/PL9fwy3NUQKwY9jl8xw-bWkVZkWcGGyspd/1ElgyngArXQ_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..7aae2c5eff8f8369436a5c05813d486300120690
--- /dev/null
+++ b/PL9fwy3NUQKwY9jl8xw-bWkVZkWcGGyspd/1ElgyngArXQ_postprocess.srt
@@ -0,0 +1,4344 @@
+1
+00:00:02,190 --> 00:00:06,830
+السلام عليكم ورحمة الله وبركاته طالبات العزيزات
+
+2
+00:00:06,830 --> 00:00:10,610
+المحاضرة الماضية كانت بعنوان blood component أي
+
+3
+00:00:10,610 --> 00:00:17,250
+يعني مكونات الدم حكينا عن مكونات الدم و أجزاءه و
+
+4
+00:00:17,250 --> 00:00:21,410
+حكينا عن خلايا الدم الفارث ما بين ال plasma و ال
+
+5
+00:00:21,410 --> 00:00:25,650
+serum ال anticoagulants مضادات التخطر اللي .. اللي
+
+6
+00:00:25,650 --> 00:00:30,010
+تم استخدامها يعني most common فيمختبرات ال
+
+7
+00:00:30,010 --> 00:00:34,750
+hematology و ان شاء الله اليوم محاضرتنا بعنوان
+
+8
+00:00:34,750 --> 00:00:38,650
+blood collection كيف انا اسحب عينة الدم او احصل
+
+9
+00:00:38,650 --> 00:00:43,670
+على عينة الدم من المريض blood collection المحاضرة
+
+10
+00:00:43,670 --> 00:00:48,710
+طويلة نوعا ما يعني انا دي 49 slide فلذلك ممكن انا
+
+11
+00:00:48,710 --> 00:00:54,170
+اجزقها ال part one and part two طيب طب خلينا نشوف
+
+12
+00:00:54,170 --> 00:01:00,120
+اش ما يتعلق بال blood collectionفي البداية راح
+
+13
+00:01:00,120 --> 00:01:04,940
+نحكي عن contact with patient التواصل مع المريض the
+
+14
+00:01:04,940 --> 00:01:09,980
+patient in hospital is anxious, fearful, ill
+
+15
+00:01:09,980 --> 00:01:12,860
+health and he is physically uncomfortable as a
+
+16
+00:01:12,860 --> 00:01:16,220
+result of his disease or injury he is also
+
+17
+00:01:16,220 --> 00:01:19,900
+separated from his family هلأ ال patient عادة
+
+18
+00:01:19,900 --> 00:01:24,500
+بيكون متوتر, anxious, fearful, خايف, ill health،
+
+19
+00:01:24,500 --> 00:01:30,240
+صحته مش مساعدة، مريضو أيضا هو غير مرتاح نتيجة مرضه
+
+20
+00:01:30,240 --> 00:01:37,100
+أو نتيجة يعني الإصابة أو الشكوى الصحية اللي هو عم
+
+21
+00:01:37,100 --> 00:01:41,720
+بيشك منها هلأ طبيعي أنه يكون كمان حتى مش بس عنده
+
+22
+00:01:41,720 --> 00:01:46,640
+تعب physical يعني تعب واضح ظاهر على جسدهممكن يكون
+
+23
+00:01:46,640 --> 00:01:51,200
+حتى كمان نفسيته تعبانة لإنه عنده قلق عنده توتر بما
+
+24
+00:01:51,200 --> 00:01:57,040
+يتعلق بصحته هل هذا العلة او المرض اللي هو مصابتي
+
+25
+00:01:57,040 --> 00:02:01,320
+هل هيودي بحياته او لأ he .. he is also separated
+
+26
+00:02:01,320 --> 00:02:06,700
+from his family هو ايضا اذا كان مريض مقيم في ال ..
+
+27
+00:02:06,880 --> 00:02:11,300
+المستشفى يعني موجود على أحد أسرة أقسام المستشفى
+
+28
+00:02:11,300 --> 00:02:16,940
+فبالتالي هو بيكون بعيد عن أسرته فهذا أيضا بيأثر
+
+29
+00:02:16,940 --> 00:02:20,600
+على نفسيته فبالتالي ال medical technologist must
+
+30
+00:02:20,600 --> 00:02:24,600
+show the patient at all time the kindness and
+
+31
+00:02:24,600 --> 00:02:28,020
+understanding that can mean some .. mean so much
+
+32
+00:02:28,190 --> 00:02:33,190
+هلأ يعني ال .. الشخص احنا كأخصائي تحاليل طبية انا
+
+33
+00:02:33,190 --> 00:02:39,430
+لازم اظهر تعاطفي و اظهر .. اظهر لطفي و ايضا تفهمي
+
+34
+00:02:39,430 --> 00:02:43,770
+لوضع المريض اللي هذا يعني راح يكون بيعني له الكثير
+
+35
+00:02:44,830 --> 00:02:49,430
+طيب بالنسبة لو كان المريض هذا عبارة عن a child
+
+36
+00:02:49,430 --> 00:02:53,750
+ممكن تكون تجربة تسحب عينة من a child عبارة عن
+
+37
+00:02:53,750 --> 00:02:58,150
+terrible experience بالنسبة لإله يعني تجربة سيئة
+
+38
+00:02:58,150 --> 00:03:04,050
+أو تجربة مخيفة جدا مريعة لإله و ممكن تكون
+
+39
+00:03:04,050 --> 00:03:06,990
+remembered and feared for that child for many
+
+40
+00:03:06,990 --> 00:03:11,230
+years يعني انها تظلها عالقة بذاكرته و تخوفه لسنوات
+
+41
+00:03:11,230 --> 00:03:17,490
+عديدةليش؟ لأنه ممكن تكون هذه التجربة، تجربة صح
+
+42
+00:03:17,490 --> 00:03:21,730
+بالعينة أو الحصول على العينة كانت سيئة أو مؤلمة أو
+
+43
+00:03:21,730 --> 00:03:25,190
+ما كانت بالاحتواء اللي يجب أو ينبغي أن تكون عليه
+
+44
+00:03:25,190 --> 00:03:29,460
+gain the child trust before the proceedingwith
+
+45
+00:03:29,460 --> 00:03:35,800
+blood collection لازم انه نكسب او نكسب ثقة الطفل
+
+46
+00:03:35,800 --> 00:03:40,260
+قبل لنبدأ بعملية سحب الدم the child should be
+
+47
+00:03:40,260 --> 00:03:43,720
+informed of what is going to happen if the child
+
+48
+00:03:43,720 --> 00:03:47,060
+is told that the puncture will not hurt the child
+
+49
+00:03:47,060 --> 00:03:49,760
+trust will be lost because this statement is
+
+50
+00:03:49,760 --> 00:03:54,360
+generally is not true هلأ احنا طبعا لازم نخبر
+
+51
+00:03:54,360 --> 00:04:02,340
+الطفل انهإيش إحنا راح نسوي يعني مثلا بالتعامل مع
+
+52
+00:04:02,340 --> 00:04:07,960
+الطفل يعني بيكون kindly أنا راح أفوت الإبرة و أسحب
+
+53
+00:04:07,960 --> 00:04:14,380
+منك عينة دم طبعا ما لازم أحكيله انه هذه الاشي مش
+
+54
+00:04:14,380 --> 00:04:18,220
+مؤلم لإن هو فعليا راح يتألم وبتالي هيك أنا راح
+
+55
+00:04:18,220 --> 00:04:22,100
+أخسر ثقته و راح أكون عنده terrible experience
+
+56
+00:04:22,100 --> 00:04:26,540
+يتذكرها و يخاف منها لسنوات تمام؟فبالتالي لازم انا
+
+57
+00:04:26,540 --> 00:04:29,020
+مثلا أحكيله بالتفصيل انا إيش بدي أعمل يعني أنا بدي
+
+58
+00:04:29,020 --> 00:04:31,620
+أسحب .. بدي .. بدي أنخزك شويه صغيرة و بدي أسحب منك
+
+59
+00:04:31,620 --> 00:04:36,160
+عينة دم عشان نعملك الفحص و نتطمن عليك بس أنت قوي
+
+60
+00:04:36,160 --> 00:04:40,040
+مش راح تتألم كتير هي التوجع شويه صغيرة أنخزها
+
+61
+00:04:40,040 --> 00:04:45,040
+صغيرة و أنت يعني كتير قوي و أنت راح تتحمل و أنت
+
+62
+00:04:45,040 --> 00:04:50,580
+أسد و .. من هذا الكلام رفعا لمعنوياته و نحاول أنه
+
+63
+00:04:50,580 --> 00:04:55,140
+احنا نكسب ثقتهطبعا بالنسبة لأ ال pheloptomy ال
+
+64
+00:04:55,140 --> 00:04:58,120
+procedure خلينا نشوف إيش معناة كلمة pheloptomy
+
+65
+00:04:58,120 --> 00:05:03,360
+phelop .. phelop لحالها معناها artery او معناها
+
+66
+00:05:03,360 --> 00:05:07,680
+vein .. vein sorry معناها vein وريد تمام و to me
+
+67
+00:05:07,680 --> 00:05:13,020
+معناها يعني to remove أو to isolate تمام يعني أن
+
+68
+00:05:13,020 --> 00:05:21,150
+أنا أعزل أو أستقصل أو أزيل تماممن الوريد تمام جزء
+
+69
+00:05:21,150 --> 00:05:24,790
+منه ايش هو الجزء اللي انا بده اشيله من الوريد ال
+
+70
+00:05:24,790 --> 00:05:30,490
+blood تمام اذا في look to me يعني عملية سحب عينة
+
+71
+00:05:30,490 --> 00:05:36,520
+دم من الوريد هاي معناها تمامطيب و نفس المعنى أيضًا
+
+72
+00:05:36,520 --> 00:05:41,360
+vein puncture إن أنا أسحب عينة من الوريد أيضًا
+
+73
+00:05:41,360 --> 00:05:44,820
+معناها vein puncture خلّيني أنا أشوف إيش مكتوب هنا
+
+74
+00:05:44,820 --> 00:05:48,720
+blood specimens عينات الدم are commonly obtained
+
+75
+00:05:48,720 --> 00:05:53,060
+from patients vein puncture under some
+
+76
+00:05:53,060 --> 00:05:56,640
+circumstances a skin puncture will be used for
+
+77
+00:05:56,640 --> 00:06:00,920
+this purposeهلأ أحيانا في بعض الحالات ممكن أنا
+
+78
+00:06:00,920 --> 00:06:04,600
+أعمل skin puncture لحتى أحصل على عينة الدم يعني
+
+79
+00:06:04,600 --> 00:06:08,160
+عينة الدم غالبا commonly obtained commonly
+
+80
+00:06:08,160 --> 00:06:13,580
+obtained يعني غالبا تعزل من الوريد أو يعني يحصل
+
+81
+00:06:13,580 --> 00:06:18,710
+عليها من الوريد، نحصل عليها من الوريدتمام؟ ولكن في
+
+82
+00:06:18,710 --> 00:06:22,750
+بعض الحالات أنا ممكن أحصل على عينة الدم من إحداث
+
+83
+00:06:22,750 --> 00:06:27,350
+.. يعني نخز في الاسكان كلمة puncture أكيد مرت
+
+84
+00:06:27,350 --> 00:06:31,210
+معاكم أنه مثلا puncture عجل السيارة، puncture عجل
+
+85
+00:06:31,210 --> 00:06:35,570
+الدراجة، تمام؟ إيش يعني؟ يعني صار في ثقوب، تمام؟
+
+86
+00:06:35,570 --> 00:06:38,870
+فلما أنا أحكي vain puncture يعني إحداث ثقوب في
+
+87
+00:06:38,870 --> 00:06:43,700
+الوريد للخروج أو لحصول على عينة الدماحداث ثقب في
+
+88
+00:06:43,700 --> 00:06:47,900
+ال skin لخروج أو الحصول على عينة دم، اذا puncture
+
+89
+00:06:47,900 --> 00:06:51,820
+يعني ثقب، تمام؟ اذا van puncture يعني حصول على
+
+90
+00:06:51,820 --> 00:06:57,550
+عينة دم من الوريدتمام؟ و skin puncture حصولة على
+
+91
+00:06:57,550 --> 00:07:01,610
+عينة دم من ال skin تمام؟ أكيد يعني ممكن مرتوا
+
+92
+00:07:01,610 --> 00:07:06,170
+بتجربة أن تروحوا على العيادات خصوصا عيادات الرعاية
+
+93
+00:07:06,170 --> 00:07:10,090
+الأولية مثل عيادات الواكالة و أنه لما بيدهم يسحبوا
+
+94
+00:07:10,090 --> 00:07:15,910
+منكوا معينة ينخذوا الإصبع تمام؟ و من خلال أداة
+
+95
+00:07:15,910 --> 00:07:21,340
+شفرةخاصة للنخز و الحصول على عينة دم من خلال ال
+
+96
+00:07:21,340 --> 00:07:25,300
+skin من خلال يعني انه انا ما .. ما .. ما استعملت
+
+97
+00:07:25,300 --> 00:07:29,940
+ابره و مادخلت جوا بريد تمام؟ هاي معناه ال skin
+
+98
+00:07:29,940 --> 00:07:35,700
+punctureبغض النظر عن طريقة سحب العينة irrespective
+
+99
+00:07:35,700 --> 00:07:40,420
+of the method use
+
+100
+00:07:40,420 --> 00:07:44,820
+certain techniques are common to all polyptomy
+
+101
+00:07:44,820 --> 00:07:48,440
+procedures هلأ أنا لازم في عدة خطوات بدي أحضرها
+
+102
+00:07:48,440 --> 00:07:55,680
+بدي أمر فيها بدي أتأكد منها أو أسويهاقبل لأحصل على
+
+103
+00:07:55,680 --> 00:07:59,860
+عينة الدم هذه أول إشي بدي أعمل ا check the request
+
+104
+00:07:59,860 --> 00:08:04,540
+form بدي أتأكد من ال request form اللي جاي مع
+
+105
+00:08:04,540 --> 00:08:13,680
+العينة هلأ في طبعا المختبرات المستشفة بتكون عجارة
+
+106
+00:08:13,680 --> 00:08:17,860
+عن عدة أقسام قسم ال hematology قسم ال chemistry ال
+
+107
+00:08:17,860 --> 00:08:22,220
+microbiology ال routine القسم ال ..الـ serology
+
+108
+00:08:22,220 --> 00:08:26,640
+المناعة فبالتالي عدة أقسام وبيكون في عندي غرفة
+
+109
+00:08:26,640 --> 00:08:31,640
+منفصلة عنهم اللي هي غرفة سحب العينات بنسميها ال
+
+110
+00:08:31,640 --> 00:08:34,340
+sample collection room تمام؟ هي ممكن تكون أيضا
+
+111
+00:08:34,340 --> 00:08:38,200
+كمان يعني مش شرط تكون موجودة متصلة مع المختبر ممكن
+
+112
+00:08:38,200 --> 00:08:41,600
+تكون يعني المختبر يكون على الطابق التاني غرفة سحب
+
+113
+00:08:41,600 --> 00:08:44,940
+العينات تكون على الطابق الأول زي مثلا ما هو موجود
+
+114
+00:08:44,940 --> 00:08:47,200
+بمستشفى الأوروبي تمام؟
+
+115
+00:08:49,050 --> 00:08:54,830
+فغرفة سحب العينات هذه بيصلها ال request form إيش
+
+116
+00:08:54,830 --> 00:08:58,450
+يعني ال request form؟ يعني طلب سحب العينة أو طلب
+
+117
+00:08:58,450 --> 00:09:06,290
+الفحصتمام و بيكون طبعا .. بيكون كتبه الطبيب في ..
+
+118
+00:09:06,290 --> 00:09:12,610
+في form خاص نموذج خاص لعينات و الحصات بيشيك عليها
+
+119
+00:09:12,610 --> 00:09:16,130
+الدكتور مثلا انا بدي عين .. بدي تعملي CBC او urine
+
+120
+00:09:16,130 --> 00:09:19,710
+test او urine analysis او stool analysis حسب ايش
+
+121
+00:09:19,710 --> 00:09:24,290
+نوع الفحص اللي مطلوب فب .. هذا الطلب الفحص اللي
+
+122
+00:09:24,290 --> 00:09:30,350
+بيجي اللي بيسمي request form بيجي مع المريضفأنا ب
+
+123
+00:09:30,350 --> 00:09:34,110
+.. باطلع عليه فبكون عارفة بناء أنا على ما عرفتي
+
+124
+00:09:34,110 --> 00:09:38,450
+وعلمي اللي درسته بكون عارفة إيش نوع العينة اللي
+
+125
+00:09:38,450 --> 00:09:44,670
+يجب أن نحصل عليها من المريض فبالتالي بصحب العينة
+
+126
+00:09:44,670 --> 00:09:47,790
+إذا .. إذا بده عينة دم بصحب عينة دم إذا بده عينة
+
+127
+00:09:47,790 --> 00:09:51,510
+urine بخليه هو يجمع عينة urine و بعطي تعليمات حول
+
+128
+00:09:51,510 --> 00:09:54,770
+الجامعة عين تستول و يجمع عين تستول و بعطي تعليمات
+
+129
+00:09:54,770 --> 00:09:58,730
+حول الجامعةفيعني احنا ذكرنا قبل هيك انه في عينات
+
+130
+00:09:58,730 --> 00:10:01,430
+انا بجمعها بنفسي، في عينات انا بعطي تعليمات للمريض
+
+131
+00:10:01,430 --> 00:10:05,810
+كيف يجمعها و فيها تعليمات انا بعطي معلومات للمريض
+
+132
+00:10:05,810 --> 00:10:09,370
+انه كيف يحضر حاله للفحص مثلا يصوم او ياكل اشي معين
+
+133
+00:10:09,370 --> 00:10:12,350
+او يفطر على اشي معين او يمتنع عن اكل اشياء معينة
+
+134
+00:10:12,350 --> 00:10:16,460
+حسبتمام؟ فبالتالي ال request form إذا هو الطلب
+
+135
+00:10:16,460 --> 00:10:20,280
+اللي بيكتبه المريض أو بيكون هو نموذج، معادل بس على
+
+136
+00:10:20,280 --> 00:10:24,940
+الدكتور يعمل test، يحط صح جنب الفحص اللي هو بدويا
+
+137
+00:10:24,940 --> 00:10:30,390
+نجري للمريض، تمام؟الخطوة تانية اذا انا بدي اشيك
+
+138
+00:10:30,390 --> 00:10:33,630
+على هذا ال request form بدي اتأكد ان هو معبق بشكل
+
+139
+00:10:33,630 --> 00:10:37,130
+صحيح او لأ من قبل الطبيب the correct patient
+
+140
+00:10:37,130 --> 00:10:42,290
+identification بدي ا .. اتعرف على المريض بشكل صحيح
+
+141
+00:10:42,290 --> 00:10:45,570
+اتأكد انه هذا هو المريض اللي انا بدي اجمع منه
+
+142
+00:10:45,570 --> 00:10:52,950
+العين او لأيعني ماروحش أجمع عينة من مريض آخر ويكون
+
+143
+00:10:52,950 --> 00:10:57,450
+يعني مثلا هيك بكون أنا عاملك mix ما بين النموذج
+
+144
+00:10:57,450 --> 00:11:00,570
+يعني يكون النموذج من مريض و العينة من مريض آخر
+
+145
+00:11:00,570 --> 00:11:05,010
+فبالتالي النتائج بتكونش معبرة تمام؟ بيصير في خلط و
+
+146
+00:11:05,010 --> 00:11:09,590
+خربطة في ما بين ال requestات form و ما بين العينات
+
+147
+00:11:10,270 --> 00:11:13,730
+the correct specimen identification أنا بدي أعرف
+
+148
+00:11:13,730 --> 00:11:18,550
+أيش نوع العينة اللي بدي أستخدمها زي ما انتوا شفتوا
+
+149
+00:11:18,550 --> 00:11:23,090
+لو مثلا لو بدي أسحب عينة دم مثلا بدي أعرف أنا في
+
+150
+00:11:23,090 --> 00:11:27,330
+أي تيوب بدي أحطها المحاضرة الماضية احنا تحدثنا عن
+
+151
+00:11:27,330 --> 00:11:32,020
+عدة أنواع من التيوبات كل تيوب فيها additiveفيها
+
+152
+00:11:32,020 --> 00:11:37,340
+إضافة فيها anticoagulant مختلف عن الأخرى فبالتاني
+
+153
+00:11:37,340 --> 00:11:40,840
+أنا بده اميز فيه فحوصات بتنعمل على heparin فيه
+
+154
+00:11:40,840 --> 00:11:44,900
+فحوصات بتنعمل على citrate شرط لازم يكون citrate في
+
+155
+00:11:44,900 --> 00:11:48,880
+العينة فيه فحوصات على edita فحسب إيش نوع ال
+
+156
+00:11:48,880 --> 00:11:52,400
+anticoagulant الموجود أو ال additive الموجود فيه
+
+157
+00:11:52,400 --> 00:11:56,300
+فحوصات لأ لازم العينة تتجلط و أنا أفصل serum فلازم
+
+158
+00:11:56,300 --> 00:11:59,340
+أحطها في planet tube أو التيوبات اللي فيها clot
+
+159
+00:11:59,340 --> 00:12:03,680
+activatorفهذه كلها طبعا انا بدي اميزها بدي اعرف
+
+160
+00:12:03,680 --> 00:12:08,460
+انا ايش نوع العينة المطلوب عشان احصل على ايش
+
+161
+00:12:08,460 --> 00:12:11,600
+correct specimen identification انا عرفت على نوع
+
+162
+00:12:11,600 --> 00:12:18,710
+العينة الصحيح اللي انا بدي احصل عليه تمام؟فلازم
+
+163
+00:12:18,710 --> 00:12:24,150
+أيضا أعمل إجراءات تضمن ال safety تضمن الأمان
+
+164
+00:12:24,150 --> 00:12:28,710
+والسلامة و ال infection control و الحد من انتقال
+
+165
+00:12:28,710 --> 00:12:32,350
+العدوى لمين؟ أنا حكيت بدي أحافظ .. أحافظ على
+
+166
+00:12:32,350 --> 00:12:37,010
+سلامتي أولا و سلامة ال patientو سلامة ال
+
+167
+00:12:37,010 --> 00:12:40,650
+colleagues, الزملاء اللي بيشتغلوا بالمختبر، تمام؟
+
+168
+00:12:40,650 --> 00:12:46,690
+و أيضا بدي بعد هيك أبدأ أحضر مكان ال puncture
+
+169
+00:12:46,690 --> 00:12:50,530
+المكان اللي أنا بدي أسحب منه عينة دم سواء كان vein
+
+170
+00:12:50,530 --> 00:12:55,050
+أو سواء كان skin فبدي أحضره علشان أبدأ في سحب
+
+171
+00:12:55,050 --> 00:12:59,540
+العينةتمام؟ إذا هذه الخطوات بغض النظر عن عملية
+
+172
+00:12:59,540 --> 00:13:06,300
+السحب ذات نفسها أنا لازم أقوم فيها في كل مرة بسحب
+
+173
+00:13:06,300 --> 00:13:11,220
+فيها عينا من مريض، تمام؟ طيب، انشوف
+
+174
+00:13:13,800 --> 00:13:17,740
+إيش يعني .. نشوف هلأ ال slides الجاية راح تحكي عن
+
+175
+00:13:17,740 --> 00:13:22,720
+كل واحدة بالدور إيش هما؟ تمام؟ تفاصيل أكتر نحكي عن
+
+176
+00:13:22,720 --> 00:13:27,060
+ال request form هلأ ال request form هو عبارة عن
+
+177
+00:13:27,060 --> 00:13:30,700
+نموذج ممكن يكون اسمه request form أو requisition
+
+178
+00:13:30,700 --> 00:13:35,160
+form نفس المعنى طلب، نموذج طلب، لفحص، نموذج طلب
+
+179
+00:13:35,160 --> 00:13:41,310
+إجراء فحص، هك اسمهطبعا لازم كل عينة تأتي للمختبر
+
+180
+00:13:41,310 --> 00:13:45,310
+من غرفة جمع العينات لازم يكون معها ال request
+
+181
+00:13:45,310 --> 00:13:49,490
+الخاص فيها، هلأ صارت ال requestات يا بنات تيجي
+
+182
+00:13:49,490 --> 00:13:52,890
+إلكتروني لإنه صار في عندي حاجة اسمها lab
+
+183
+00:13:52,890 --> 00:13:57,760
+informaticsبس زمان كان في ورقي بس المهم بغض النظر
+
+184
+00:13:57,760 --> 00:14:01,520
+كان النظام المعمول به بالمستشفى ورقي أو إلكتروني
+
+185
+00:14:01,520 --> 00:14:05,680
+لازم يكون كل عينة بتنشغل في المختبر يكون فيه ال
+
+186
+00:14:05,680 --> 00:14:08,920
+Hercules يعني مجرد ما أنا أستلم العينة إذا أنا
+
+187
+00:14:08,920 --> 00:14:12,160
+بشتغل إلكتروني بدي أروح أحدث البرنامج و أشوف هل
+
+188
+00:14:12,160 --> 00:14:16,630
+وصلني طلب لهذه العينة أو لاطبعا؟ طيب العينة ..
+
+189
+00:14:16,630 --> 00:14:21,190
+الطلب هذا the requisition form must contain the
+
+190
+00:14:21,190 --> 00:14:23,770
+proper information in order to process the
+
+191
+00:14:23,770 --> 00:14:28,430
+specimen لازم يكون موجود فيه المعلومات الكافية و
+
+192
+00:14:28,430 --> 00:14:32,750
+الجيدة لحت .. لحتى أنا أشتغل على العينة طبعا؟
+
+193
+00:14:32,750 --> 00:14:38,710
+معلومات دقيقة بتتعلق بالمريد و العينة و كل إشي ب
+
+194
+00:14:38,710 --> 00:14:43,590
+.. متعلق يعني في عملية السحب لحتى أنا أقدر أشتغل
+
+195
+00:14:43,590 --> 00:14:47,630
+الفحصتمام؟ و .. او احكم هل العينها دي صالحة لإجراء
+
+196
+00:14:47,630 --> 00:14:51,390
+الفحص او لأ The essential element of requisition
+
+197
+00:14:51,390 --> 00:14:57,390
+form are العناصر المكونة لطلب الفحص هو اول حاجة ال
+
+198
+00:14:57,390 --> 00:15:01,410
+patient surname, first name and middle initial
+
+199
+00:15:01,410 --> 00:15:09,170
+لازم يكون موجود فيالطلب اسم ال .. اسم المريض كاملا
+
+200
+00:15:09,170 --> 00:15:13,790
+ال surname اسم العائلة و ال first name اسم .. اسمه
+
+201
+00:15:13,790 --> 00:15:18,810
+الأولى يعني مثلا أنا نور أبوتايم تمام؟ لازم يكون
+
+202
+00:15:18,810 --> 00:15:22,510
+أبوتايم نور و اذا .. و ال middle initial يعني حرف
+
+203
+00:15:22,510 --> 00:15:27,780
+ال I من اسم الوالد إبراهيمتمام؟ هذا ال .. ال .. ال
+
+204
+00:15:27,780 --> 00:15:31,480
+band الأول معناه انه لازم يكون في عندي الاسم
+
+205
+00:15:31,480 --> 00:15:35,040
+العائلة و الاسم الأول و ال middle initial الحرف
+
+206
+00:15:35,040 --> 00:15:39,540
+الأول من اسم الوالد patient ID number طبعا احنا
+
+207
+00:15:39,540 --> 00:15:44,880
+نعرف بالمستشفى عن طريق numbers احنا عبارة عن رقم
+
+208
+00:15:44,880 --> 00:15:50,920
+.. رقم ملفي هو رقمي الطبيلازم هذا .. طبعا هذا اللي
+
+209
+00:15:50,920 --> 00:15:54,580
+أنا من خلاله بيتعرفوا عليا في المستشفى من خلال
+
+210
+00:15:54,580 --> 00:16:01,520
+طبعا الفحص بيجي مرفق برقمي الخاص الأدوية بتصرف
+
+211
+00:16:01,520 --> 00:16:05,760
+تبعا لرقمي الخاص صور الأشعة حسب رقمي التمريد
+
+212
+00:16:05,760 --> 00:16:09,500
+الفحوصات الفيزيائية العلاج الطبيعي كل شيء بيكون
+
+213
+00:16:09,500 --> 00:16:13,020
+طبعا بيتعرفوا عليا من خلال الرقمي الخاص فيا
+
+214
+00:16:14,040 --> 00:16:18,400
+patient's date of birth and sex لازم يكون في عندى
+
+215
+00:16:18,400 --> 00:16:23,100
+تاريخ الميلاد طبعا و لازم يكون ال gender معروف
+
+216
+00:16:23,100 --> 00:16:28,060
+male or female لازم يكون مضوّن بعدين ال
+
+217
+00:16:28,060 --> 00:16:33,540
+requisition physicianscomplete name تمام؟ و أيضا
+
+218
+00:16:33,540 --> 00:16:40,040
+اللي لازم يكون الاسم الكامل للطبيب اللي طلب هذا
+
+219
+00:16:40,040 --> 00:16:44,360
+الفحص أو طلب الصح بالعينة indicating the test
+
+220
+00:16:44,360 --> 00:16:48,560
+requested و أيضا لازم يكون الطبيب هذا معلم على
+
+221
+00:16:48,560 --> 00:16:52,780
+الفحوصات اللي احنا بدنا نشتغلها source of specimen
+
+222
+00:16:53,920 --> 00:16:57,580
+طبعا this information must be given when
+
+223
+00:16:57,580 --> 00:17:01,180
+requesting microbiology, cytology, fluid analysis
+
+224
+00:17:01,180 --> 00:17:05,480
+or other testing where analysis is reporting and
+
+225
+00:17:05,480 --> 00:17:11,880
+is site specific هلأ أحيانا بيكون الطبيبمعينلي ال
+
+226
+00:17:11,880 --> 00:17:15,460
+source of specimen يعني أسحبيلي عينة من المكان
+
+227
+00:17:15,460 --> 00:17:19,080
+الفلاني أنا بدي خصوصا إذا كان بديها لل
+
+228
+00:17:19,080 --> 00:17:22,880
+microbiology إذا أحنا بنعمل مزرعة أو إذا كان بدنا
+
+229
+00:17:22,880 --> 00:17:27,020
+ندرس الخلايا نشوف هل في خلايا سرطانية يعني عفوا أو
+
+230
+00:17:27,020 --> 00:17:35,720
+لأ بدي أشوف فحوصات ال سواق الجسم بده مثلا فحص من
+
+231
+00:17:35,720 --> 00:17:43,790
+جزء من الجلد ملتهبو .. الطبيب شاكت إنه في عدوى
+
+232
+00:17:43,790 --> 00:17:48,010
+فطرية .. فطريات على الجلد فأنا لازم من هذه المكان
+
+233
+00:17:48,010 --> 00:17:52,490
+أخد مسحة من ال .. ال .. فما .. فما بنفع يجي ..
+
+234
+00:17:52,490 --> 00:17:58,770
+يعني ما بنفع يسيب ليها يعني عايمة مش معروفةلازم
+
+235
+00:17:58,770 --> 00:18:03,150
+انا يحددلي انه من المكان الفلاني مثلا من الإيد
+
+236
+00:18:03,150 --> 00:18:10,650
+اليمنى فوق الرسغ مثلا موجود في منطقة infection
+
+237
+00:18:10,650 --> 00:18:13,710
+منها انا بدي سحب عينة عشان اشوف ايش نوع ال
+
+238
+00:18:13,710 --> 00:18:17,030
+infection مثلا فطريات ولا بكتيريا او whatever
+
+239
+00:18:17,030 --> 00:18:21,750
+فبالتالي لما يكون المكان ال site specific لازم انا
+
+240
+00:18:21,750 --> 00:18:27,080
+اسحب من مكان معين لازم هذاالطبيب يحددلي source of
+
+241
+00:18:27,080 --> 00:18:31,200
+specimen مصدر العينة date and time of collection
+
+242
+00:18:31,200 --> 00:18:38,920
+أيضا التاريخ ووقت سحب العينة لازم يكون يعني مكتوب
+
+243
+00:18:38,920 --> 00:18:44,370
+و ال initial of the optomist برضه كمان لازمالاسم
+
+244
+00:18:44,370 --> 00:18:48,730
+الأول من الشخص اللي سحب العينة يكون موجود أو مدكر
+
+245
+00:18:48,730 --> 00:18:53,610
+يعني في معلومات بعديها الطبيب يعني اسم المريض و ال
+
+246
+00:18:53,610 --> 00:18:57,390
+ID number ال date of birth ال gender ال
+
+247
+00:18:57,390 --> 00:19:00,450
+requisition physician complete name و ال
+
+248
+00:19:00,450 --> 00:19:02,990
+indicating test و ال source of specimen هدول
+
+249
+00:19:02,990 --> 00:19:07,850
+بعبيهم الطبيباحنا بعد ما أنا أاخد ال request من
+
+250
+00:19:07,850 --> 00:19:12,670
+المريض و أصحبله العينة لازم أسجل الوقت و التاريخ
+
+251
+00:19:12,670 --> 00:19:17,830
+لصحب العينة و أيضا الاسم الأول من اسمي، نور، تمام؟
+
+252
+00:19:17,830 --> 00:19:22,330
+فهكذا بكتب على ال request form، تمام؟ اذا جزء يعبق
+
+253
+00:19:22,330 --> 00:19:26,510
+من خلال أو يملق من خلال الطبيب و جزء يملق من خلال
+
+254
+00:19:26,510 --> 00:19:30,230
+ال .. ال philoptomist أو اللي هو أخصائي المختبرات
+
+255
+00:19:30,230 --> 00:19:35,610
+اللي بيجمع العينة، تمام؟طيب patient identification
+
+256
+00:19:35,610 --> 00:19:40,990
+أثناء وصول ال request تمام؟ و أنا بدي أسحب العينة
+
+257
+00:19:40,990 --> 00:19:44,470
+من المريض لازم أعمل حاجة اسمها patient
+
+258
+00:19:44,470 --> 00:19:49,210
+identification أنا بدي أميز أن هو مريض أو أي مريض
+
+259
+00:19:49,210 --> 00:19:53,090
+أنا بدي أسحب منه العينة تمام؟ف is it critical for
+
+260
+00:19:53,090 --> 00:19:56,570
+hospital patient that is accomplished by checking
+
+261
+00:19:56,570 --> 00:20:02,030
+the identification wristband؟ إذا الشخص مقيم على
+
+262
+00:20:02,030 --> 00:20:05,790
+.. في المستشفى أو يعني عنده بيات في المستشفى هو
+
+263
+00:20:05,790 --> 00:20:10,270
+hospital patient، تمام؟ أو أحيانا بسميها in
+
+264
+00:20:10,270 --> 00:20:15,270
+patient، بحط كلمة in، تمام؟بحط كلمة in هنا بيصير
+
+265
+00:20:15,270 --> 00:20:21,050
+inpatient طبعا إذا كان كالشخص .. المريض inpatient
+
+266
+00:20:21,050 --> 00:20:25,330
+يعني patient مريض داخل المستشفى أو hospital
+
+267
+00:20:25,330 --> 00:20:29,990
+patient طبعا إذا كان هذا الطبيب في داخل المستشفى
+
+268
+00:20:29,990 --> 00:20:33,810
+على أحد الأسرة فأنا أو إذا كان خصوصا فاقد الوعي
+
+269
+00:20:33,810 --> 00:20:39,030
+يعني أو مغيب بيكون في بإيده حاجة اسمها wristband
+
+270
+00:20:39,030 --> 00:20:44,680
+طبعايعني اللي على الرسخ على الكوع يعني لأ مش الكوع
+
+271
+00:20:44,680 --> 00:20:51,700
+الرسخ عند إيده هنا بيكون في اسورة هو لابسها و فيها
+
+272
+00:20:51,700 --> 00:20:58,780
+معلوماته الخاصة اسمه و رقمه و ال .. مثلا يعني أي
+
+273
+00:20:58,780 --> 00:21:02,260
+معلومات مهمة بتتعلق بالمريد النام و ال hospital
+
+274
+00:21:02,260 --> 00:21:05,820
+نفس ال .. الاسورة اللي بتكون في إيدي المولود أول
+
+275
+00:21:05,820 --> 00:21:10,470
+ما بينولد بن .. بنكتب اسم فلان اذن فلانةو ال .. ال
+
+276
+00:21:10,470 --> 00:21:15,830
+number تبعه و تاريخ الولادة و مثلا وزنه هدى
+
+277
+00:21:15,830 --> 00:21:18,690
+معلومات بتتعلق فى المريض او بتتعلق فى الباب اللى
+
+278
+00:21:18,690 --> 00:21:22,510
+انولد تمام؟ فأيضا نفس الاشي المريض اللى بيكون على
+
+279
+00:21:22,510 --> 00:21:25,170
+أسرة المستشفى بيكون في عنده .. المفروض يكون في
+
+280
+00:21:25,170 --> 00:21:30,200
+عنده wrist band يعنى قسورة فى إيدهو مكتوب فيها على
+
+281
+00:21:30,200 --> 00:21:33,480
+الأقل النام و ال hospital و بعض المعلومات المتعلقة
+
+282
+00:21:33,480 --> 00:21:37,400
+فيه فانا لما باجي بدي أسحب من عينة من مريض خصوصا
+
+283
+00:21:37,400 --> 00:21:41,040
+لو كان فاقد للواعي او مغيب بدي ا check عليها
+
+284
+00:21:41,040 --> 00:21:44,800
+الاسورة و أشوف المعلومات اللي هو اللي عليها مطابقة
+
+285
+00:21:44,800 --> 00:21:46,920
+لل request عشان أعرف ان هو هذا المريض اللي بدي
+
+286
+00:21:46,920 --> 00:21:51,720
+أسحب منه او لاطبعا إذا كان in patient صاحي بقوله
+
+287
+00:21:51,720 --> 00:21:55,520
+بدي أتكلم معه بدي أحكيله أنت فلان إيش إسمك؟ طب إيش
+
+288
+00:21:55,520 --> 00:22:01,980
+رقمك؟ طب إيش إسمك بالكامل؟ جدش عمرك؟ عم بدي أسأله
+
+289
+00:22:01,980 --> 00:22:05,280
+بعض الأسئلة أكرر بعض الأسئلة اللي موجودة في ال
+
+290
+00:22:05,280 --> 00:22:09,060
+request عشان أتأكد إن هو هذا الشخص اللي موجود ..
+
+291
+00:22:09,060 --> 00:22:12,120
+اللي ممنشن إله أو اللي مشارقله في ال request بدي
+
+292
+00:22:12,120 --> 00:22:17,930
+أسحب منه عينة أو لأ طبعا؟ طيبإذا كان المريض عبارة
+
+293
+00:22:17,930 --> 00:22:21,650
+عن outpatient، إيش يعني outpatient؟ يعني هو مريض
+
+294
+00:22:21,650 --> 00:22:27,810
+خارج المستشفى، إذا إجا .. إجا لحتى يزور المستشفى،
+
+295
+00:22:27,810 --> 00:22:32,560
+يعني إجا على العيادات الخارجية للمستشفىتمام؟ و بده
+
+296
+00:22:32,560 --> 00:22:38,040
+يتعالج و يطلبوله فحص مثلا معين فساعتها أنا بدي
+
+297
+00:22:38,040 --> 00:22:42,880
+أتعامل مع المريض هذا بدي أعمل .. بدي أسأله ask the
+
+298
+00:22:42,880 --> 00:22:47,260
+patient for his or her full name بدي أسأله عن اسمه
+
+299
+00:22:47,260 --> 00:22:51,940
+بالكامل عن بعض المعلومات المتعلقة to be verified
+
+300
+00:22:51,940 --> 00:22:59,590
+عشان أتأكدإنه هذا هو الشخص المعني بال request form
+
+301
+00:22:59,590 --> 00:23:04,070
+أو هو الشخص اللي .. اللي لازم أنا أسحب منه عينة و
+
+302
+00:23:04,070 --> 00:23:08,630
+هذا ال request إله أو لأ، تمام؟ إذا نوعي المرضى
+
+303
+00:23:08,630 --> 00:23:12,470
+نعين، إما بيكون inpatient أو outpatient، تمام؟ ال
+
+304
+00:23:12,470 --> 00:23:17,630
+inpatient ممكن يكون فاقد للوعي، نايم على الأسرة،
+
+305
+00:23:17,630 --> 00:23:21,370
+لا يمكن التواصل معاه، verbal communication، مش
+
+306
+00:23:21,370 --> 00:23:25,830
+عارفة أتكلم معاهفبدي أشيك على wristband إذا كان هو
+
+307
+00:23:25,830 --> 00:23:30,110
+صاحي فبسأله أما ال out patient طالما هو خارج
+
+308
+00:23:30,110 --> 00:23:32,410
+المستشفى و إيجي على العيادات الخارجية إذا ان هو
+
+309
+00:23:32,410 --> 00:23:39,150
+إيجي واعي معناها بدي أسأله اسمه بالكامل بعض
+
+310
+00:23:39,150 --> 00:23:42,870
+المعلومات اللي موجودة في ال request و عشان يأكدلي
+
+311
+00:23:42,870 --> 00:23:47,570
+أن هذا ال request له زي تاريخ ميلادهمكان سكنه، أي
+
+312
+00:23:47,570 --> 00:23:51,250
+إشي بتعلق فيه داخل ال request بسأله عنه عشان أشوف
+
+313
+00:23:51,250 --> 00:23:54,330
+إجابته صحيحة أو لأ، هو هذا الشخص اللي .. اللي طلب
+
+314
+00:23:54,330 --> 00:23:59,290
+إله أو لأ، تمام؟ طيب، هذا .. إذن هذا بالنسبة لل
+
+315
+00:23:59,290 --> 00:24:02,150
+patient identification بالنسبة لل specimen
+
+316
+00:24:02,150 --> 00:24:06,390
+identification، لو العينة أجتني من غرفة الساحب على
+
+317
+00:24:06,390 --> 00:24:11,310
+المختبرات، تمام؟فمعناها العينة لازم تكون إشمالها
+
+318
+00:24:11,310 --> 00:24:16,370
+.. سيريلها labelled معلمة أو صار .. عملنا لها
+
+319
+00:24:16,370 --> 00:24:21,510
+label كتبنا عليها معلومات مهمة لحتى ما يتم فقدانها
+
+320
+00:24:21,510 --> 00:24:26,710
+أو ضياع عنها أو خربطتها أو يعني أنها يتم استبدالها
+
+321
+00:24:26,710 --> 00:24:32,040
+بعينات أخرىعملية ال labeling مهمة جدا يا بنات
+
+322
+00:24:32,040 --> 00:24:36,240
+فلازم انا اعمل labeling بشو ب ال patients surname
+
+323
+00:24:36,240 --> 00:24:40,120
+first and middle يعني نفس الاسم بنفس الطريقة
+
+324
+00:24:40,120 --> 00:24:43,140
+الكتابة اللي موجودة في ال request بكتبها على
+
+325
+00:24:43,140 --> 00:24:50,880
+العينة ايضا ال ID number الرقم المعرف للمريض سواق
+
+326
+00:24:50,880 --> 00:24:56,390
+كان رقم هويته او رقم الطبأو رقم ملفه حسب يعني
+
+327
+00:24:56,390 --> 00:25:00,170
+المستشفى إيش نظامها في تعريف المرضى، في ناس في
+
+328
+00:25:00,170 --> 00:25:03,350
+مستشفيات بتعرف المرضى من خلال رقم هويتهم، في لأ
+
+329
+00:25:03,350 --> 00:25:08,810
+بتعطيهم رقم هي هذا رقم الطبي أو رقم ملفه، تمام؟
+
+330
+00:25:08,810 --> 00:25:11,970
+date, time and initial of the phileptomist لازم
+
+331
+00:25:11,970 --> 00:25:15,050
+أيضا الجزئية اللي بدي أعبيها أنا ع ال request اللي
+
+332
+00:25:15,050 --> 00:25:19,250
+هي تاريخ ووقت سحب العينة و ال initial تبعي اسم
+
+333
+00:25:19,250 --> 00:25:23,520
+الأول لازم أيضا أكتبها على العينةعلشان لو في أي
+
+334
+00:25:23,520 --> 00:25:27,920
+مشا .. مشاكل يرجعولي، تمام؟ أي خربطة أو أي مشاكل
+
+335
+00:25:27,920 --> 00:25:31,840
+يرجعولي مثلا ب .. بيتعلق بسحب العينة علشان أنا
+
+336
+00:25:31,840 --> 00:25:34,840
+أفيدهم طيب
+
+337
+00:25:37,770 --> 00:25:42,370
+Safety and infection control أيضا لازم .. لازم
+
+338
+00:25:42,370 --> 00:25:47,910
+أراعي ال .. ال .. الأمان والسلامة و أيضا أحب
+
+339
+00:25:47,910 --> 00:25:52,490
+انتقال العدوى في .. أثناء سحب العينة تمام؟ أثناء
+
+340
+00:25:52,490 --> 00:25:57,610
+الحصول على العينةفبالتالي لازم طبعا انا لما بدأ
+
+341
+00:25:57,610 --> 00:26:01,450
+اتواصل مع ال .. ال .. ال sick patient و عيناتهم
+
+342
+00:26:01,450 --> 00:26:05,450
+طبعا انا بسحب عينة دم يا بناة عينة دم يعني انا
+
+343
+00:26:05,450 --> 00:26:09,010
+معرضة لمثلا انه لا سمح الله، لا سمح الله، اذا
+
+344
+00:26:09,010 --> 00:26:14,550
+المريض مثلا مصاب ب hepatitis، ب virus ال AIDSبأي
+
+345
+00:26:14,550 --> 00:26:18,990
+فيروس خطير ممكن ينتقل لإلي عبر الدم، تمام؟ إذا لو
+
+346
+00:26:18,990 --> 00:26:23,150
+مثلا أنا ما اتبعت القواعد السلامة و الأمان، إذا
+
+347
+00:26:23,150 --> 00:26:26,550
+جرح صغير موجود في إيدي أثناء عملية سحب الدم،
+
+348
+00:26:26,550 --> 00:26:31,350
+معناها أنا هيك أذيت نفسي، تمام؟ فبالتالي عشان هيك
+
+349
+00:26:31,350 --> 00:26:35,210
+أنا براعي بتعامل مع إنه أنا بصحى بعينة الدم إن
+
+350
+00:26:35,210 --> 00:26:39,880
+إنها هي عينة معديةو بكون لابسة ال gloves ال .. ال
+
+351
+00:26:39,880 --> 00:26:45,440
+guanti التضية و بستخدم الكحول للتعقيم و بحافظ على
+
+352
+00:26:45,440 --> 00:26:50,240
+نضافة المكان لحتى ما أنقل لنفسي العدوى، تمام؟
+
+353
+00:26:50,240 --> 00:26:55,060
+الاشي مش مخيف و ما ان .. يعني انا مش بصدد ان
+
+354
+00:26:55,060 --> 00:27:00,050
+اعمللكم تهويل لإلهلأ هين الحمد لله قلنا سنوات في
+
+355
+00:27:00,050 --> 00:27:04,050
+المجال و الحمد لله يعني محافظين على أنفسنا و سهل
+
+356
+00:27:04,050 --> 00:27:07,370
+جدا انتوا تتبعوا الخطوات للسلامة و الأمان و
+
+357
+00:27:07,370 --> 00:27:11,430
+تتحافظوا على أنفسكم ولكن يعني زي ما احنا مابدنا
+
+358
+00:27:11,430 --> 00:27:16,450
+نهور الأمر برضه كمان مابدنا نستصغر الأمور و نستهين
+
+359
+00:27:16,450 --> 00:27:20,610
+فيها فبالتالي نقضي أنفسنايعني فقط عليكم اتباع
+
+360
+00:27:20,610 --> 00:27:25,190
+الخطوات المهمة و اللي بتتعلق بالسلامة و الأمان و
+
+361
+00:27:25,190 --> 00:27:28,330
+الحد من انتشار العدوى و هيك انتوا بتكونوا في ال ..
+
+362
+00:27:28,330 --> 00:27:31,650
+الدائرة الخضراء او في ال .. في ال safe line ان شاء
+
+363
+00:27:31,650 --> 00:27:38,800
+اللهطبعا انا إيش بلزمني؟ بلزمني انه to protect
+
+364
+00:27:38,800 --> 00:27:42,620
+myself to protect the other ال colleagues و ال
+
+365
+00:27:42,620 --> 00:27:50,460
+visitors يعني بدي أحمي زملائي زواري المختبر العمال
+
+366
+00:27:50,460 --> 00:27:55,520
+النظافة المراسلين كل حد بيورد على المختبر أيضا بدي
+
+367
+00:27:55,520 --> 00:27:59,320
+أحميه تمام؟ يعني بدي أحمي البيئة المحيطة فيا و
+
+368
+00:27:59,320 --> 00:28:03,580
+أنظفها و أحاول ان انا يكون بيئتي ..فنضيفة سليمة
+
+369
+00:28:03,580 --> 00:28:07,740
+آمنة لحتى أنه ما أؤذي غيري و أيضا to protect the
+
+370
+00:28:07,740 --> 00:28:10,320
+patient، بدي أحمل patient that نفسه، يعني ما أكون
+
+371
+00:28:10,320 --> 00:28:13,500
+أنا عم بنقل عدوة من مريض إلى آخر و من آخر إلى آخر
+
+372
+00:28:13,500 --> 00:28:18,920
+و هكذاhow to protect yourself كيف بديك تحمي نفسك؟
+
+373
+00:28:18,920 --> 00:28:22,800
+حكينا الإشي إحنا مش بصدد التهويل لكن أيضا ما بدنا
+
+374
+00:28:22,800 --> 00:28:26,760
+نستهين في الأمور فقط علينا اتباع الخطوات المهمة و
+
+375
+00:28:26,760 --> 00:28:32,040
+التعليمات المهمة لحتى نحمي أنفسنا wear gloves and
+
+376
+00:28:32,040 --> 00:28:35,460
+lab coat or change gloves after each patient or
+
+377
+00:28:35,460 --> 00:28:39,710
+when contaminatedأول حاجة بدي أرتدي ال gloves اللي
+
+378
+00:28:39,710 --> 00:28:44,330
+هي لجوانتي الطبية و ال lab coat تبعي و يفضل إن أنا
+
+379
+00:28:44,330 --> 00:28:47,930
+أغير ال gloves بين كل مريض و الآخر يعني كل ما أقع
+
+380
+00:28:47,930 --> 00:28:50,570
+بالمريد يعني أنا سحبت عينة من مريض أجي المريض اللي
+
+381
+00:28:50,570 --> 00:28:54,830
+بعده يفضل إن أنا أشلح ال gloves أتخلص منها و ألبس
+
+382
+00:28:54,830 --> 00:28:59,550
+gloves جديدة طبعا إذا تلوثت أيضا لازم أنا أتخلص
+
+383
+00:28:59,550 --> 00:29:04,710
+منهاwash hands frequently لازم انا اغسل ايدي ب ..
+
+384
+00:29:04,710 --> 00:29:08,990
+ب .. بكثرة يعني انا مثلا بين مريض و اخر او بين ..
+
+385
+00:29:08,990 --> 00:29:13,330
+بين .. بين فت .. من فترة الى اخره يفضل ان انا اغسل
+
+386
+00:29:13,330 --> 00:29:16,250
+ايدي اغسل ايدي اول ما افوت المختبر و قبل ما اخرج
+
+387
+00:29:16,250 --> 00:29:20,430
+من المختبر او اغادر المختبر بين كل فترة و تانية
+
+388
+00:29:20,430 --> 00:29:23,350
+مثلا بين كل مريضين تلاتة اربعة انا ب .. بفضل ان
+
+389
+00:29:23,350 --> 00:29:27,520
+انا اروح اغسل ايدي و ارجعتمام؟ على أساس أنه هيك
+
+390
+00:29:27,520 --> 00:29:31,980
+أنا بكون عم بحمي حالي تمام؟ عم بحمي حالي dispose
+
+391
+00:29:31,980 --> 00:29:35,780
+of items in appropriate container يعني أنه أنا لما
+
+392
+00:29:35,780 --> 00:29:40,960
+بدي أتخلص من أدوات السحب تمام؟ dispose items يعني
+
+393
+00:29:40,960 --> 00:29:44,520
+أتخلص من الأدوات و الأجزاء و المكونات اللي .. و
+
+394
+00:29:44,520 --> 00:29:47,620
+الأدوات اللي بشتغل فيها in appropriate container
+
+395
+00:29:47,620 --> 00:29:52,260
+يعني مثلا اللي بدي أنحط في سلةالسلة العادية لازم
+
+396
+00:29:52,260 --> 00:29:55,120
+أنا أطلفه في السلة العادية اللي بده ينحط في السلة
+
+397
+00:29:55,120 --> 00:29:58,840
+اللي محطوط عليها إشارة ال biohazard اللي لازم تفوت
+
+398
+00:29:58,840 --> 00:30:02,740
+على جهازي ال autoclave التعقيم بحطه و بطلفه فيها
+
+399
+00:30:02,740 --> 00:30:07,300
+الأدوات ال sharp و الحاد ده و الإبر و الشوفر
+
+400
+00:30:07,300 --> 00:30:12,620
+بستخدم .. لازم أطلفها في ال sharp boxطبعا؟ فكل إشي
+
+401
+00:30:12,620 --> 00:30:16,640
+لازم أنا أتخلص منه في ال container المخصص لإله
+
+402
+00:30:16,640 --> 00:30:22,500
+لحتى أحمي نفسي إذا .. إذا أنا إجيت مثلا رميت مثلا
+
+403
+00:30:22,500 --> 00:30:27,980
+الشفرة أو الإبرة على ال .. ال bench تبعي فممكن
+
+404
+00:30:27,980 --> 00:30:33,040
+يعني بحركة عشوائية أو أنا مش منتبهة أكون جرحت نفسي
+
+405
+00:30:33,040 --> 00:30:36,160
+طبعا؟ و هذه ال .. ال needle يعني ممكن الإبرة تكون
+
+406
+00:30:36,160 --> 00:30:41,970
+ملوثةفلازم أنا أتخلص منها في ال container المناسب
+
+407
+00:30:41,970 --> 00:30:46,370
+لإلها dispose of needles immediately upon removal
+
+408
+00:30:46,370 --> 00:30:51,010
+from patient vein ال needle اللي هي الإبرة تمام
+
+409
+00:30:51,010 --> 00:30:56,630
+لازم أنا أتخلص منها على طول مجرد ما أنا أطلعها من
+
+410
+00:30:56,630 --> 00:31:01,250
+وريد المريض تمام لإنها صارت ملوثة بدمه و أنا ما
+
+411
+00:31:01,250 --> 00:31:05,030
+بعرف هو دمه يعني نظيف أو غير نظيف لازم أنا أتعامل
+
+412
+00:31:05,030 --> 00:31:09,670
+معاه على إن هو معديكل الأحوال حتى لو أنا كنت عارفة
+
+413
+00:31:09,670 --> 00:31:12,950
+أنه هذا المريض سليم، يعني لو كان هذا المريض بيخصني
+
+414
+00:31:12,950 --> 00:31:16,750
+وعارف أنه سليم ومافيش عنده فيروسات ومافيش عنده أش
+
+415
+00:31:16,750 --> 00:31:22,090
+.. يعني organism .. يعني ميكروبات معضية في دمه،
+
+416
+00:31:22,090 --> 00:31:25,750
+أنا بدي أتعامل مع دمه أن هو معضي، حتى لو أنا ضمن
+
+417
+00:31:25,750 --> 00:31:31,550
+أنه نظيف، تمام؟طيب فأول ما بتطلع ال needle و بتخلص
+
+418
+00:31:31,550 --> 00:31:37,430
+منها لإنها بتكون تلوثت بدمه طبعا في عندي قاعدة راح
+
+419
+00:31:37,430 --> 00:31:41,430
+تتكرر كتير في المختبرات و بتيجي فيها جمل الصح و
+
+420
+00:31:41,430 --> 00:31:47,530
+الغلط don't bend, break or recap or ..طبعا
+
+421
+00:31:47,530 --> 00:31:50,890
+recapped needles to avoid accident needle puncture
+
+422
+00:31:50,890 --> 00:31:54,890
+or splashing of content طبعا أنا مش لازم الإبرة
+
+423
+00:31:54,890 --> 00:31:58,990
+اللي أنا بتطلعها من وريض المريض مش لازم أتنيها
+
+424
+00:31:58,990 --> 00:32:04,690
+أكسرها أو أجرب أحاول أرجع أغطيها مرة تانية علشان
+
+425
+00:32:04,690 --> 00:32:10,550
+ما .. يعني أتجنب إنها هي تنخزني تمام؟ ليش؟ لإن هي
+
+426
+00:32:10,550 --> 00:32:14,030
+ممكن تكون ملوثة بدم المريض وإحنا حكينا إن دم
+
+427
+00:32:14,030 --> 00:32:17,000
+المريض ممكن يكون فيه فيروسات أو أي أنيany
+
+428
+00:32:17,000 --> 00:32:22,240
+infectious microorganism أي مايكروب معدي فإذا أنا
+
+429
+00:32:22,240 --> 00:32:25,260
+نخزف نفسي فيها معناها أنا حقنت هذا ال microbe اللي
+
+430
+00:32:25,260 --> 00:32:30,060
+موجود في دم المريض في جسمي يعني أنا اتسببت بالعدوى
+
+431
+00:32:30,060 --> 00:32:36,460
+لنفسي فإذا never ever never ever never ever bend,
+
+432
+00:32:36,620 --> 00:32:43,190
+break, recap, needle تمام؟ممنوع أحاول أتنيها،
+
+433
+00:32:43,190 --> 00:32:48,730
+أكسرها أو أرجع أغطيها مرة تانية، تمام؟ على طول
+
+434
+00:32:48,730 --> 00:32:53,790
+بفكها من عن ال syringe و بتخلص منها في ال sharp
+
+435
+00:32:53,790 --> 00:32:58,970
+box زي ما هيclean up any blood spill with a
+
+436
+00:32:58,970 --> 00:33:04,470
+disinfectant such as freshly made 10% bleach هلأ
+
+437
+00:33:04,470 --> 00:33:09,750
+طبعا إذا يعني نكب قطرات من الدم على ال bench أو
+
+438
+00:33:09,750 --> 00:33:13,670
+على الأرض أو على أي مكان على أي سطح داخل المختبر
+
+439
+00:33:13,670 --> 00:33:21,310
+لازم أنا أنظفه ب ..ب disinfectant بمعقم تمام و هذا
+
+440
+00:33:21,310 --> 00:33:24,950
+ال disinfectant يعني ممكن يكون كحول ممكن يكون عشرة
+
+441
+00:33:24,950 --> 00:33:28,290
+في المية منظف يعني عشرة في المية مثلا chlorine
+
+442
+00:33:28,290 --> 00:33:31,950
+عشرة في المية iod عشرة في المية ditol عشرة في
+
+443
+00:33:31,950 --> 00:33:35,170
+المية سابون أي محلول سابوني أو منظف موجود داخل
+
+444
+00:33:35,170 --> 00:33:37,670
+المختبر تمام احنا بنستخدم عشرة في المية chlorine
+
+445
+00:33:37,670 --> 00:33:42,710
+فهي يعني و أحيانا بنستخدم .. و بنستخدم الكحول و
+
+446
+00:33:42,710 --> 00:33:45,450
+بنستخدم ال ditol أيضا في عملية ال disinfection
+
+447
+00:33:45,450 --> 00:33:50,930
+اللي هي التعقيمطيب if you stick yourself with
+
+448
+00:33:50,930 --> 00:33:54,750
+contaminated needle إذا إن صار لسمح الله و نخست
+
+449
+00:33:54,750 --> 00:33:58,910
+نفسك ب contaminated needle بإبرة ملوثة إيش بدنا
+
+450
+00:33:58,910 --> 00:34:04,570
+نعمل؟ أول حاجة remove your gloves تمام؟ لازم أنا
+
+451
+00:34:04,570 --> 00:34:09,210
+أرفع ال gloves يعني أشلح ال gloves و أتخلص منهم
+
+452
+00:34:09,210 --> 00:34:15,880
+بالسلة تمام؟بعد هيك بدي أعمل sequencing لل
+
+453
+00:34:15,880 --> 00:34:19,840
+puncture site to promote bleeding، بدي أعصر منطقة
+
+454
+00:34:19,840 --> 00:34:24,860
+ال puncture، يعني بدي أضغط عليها لحتى أحفظ أنه
+
+455
+00:34:24,860 --> 00:34:28,300
+يصير في عندى bleeding، بعد هيك بدي .. يعني هيك
+
+456
+00:34:28,300 --> 00:34:33,150
+بيكون الدم هو عم بيطلعتمام و عم بيسيرله bleeding و
+
+457
+00:34:33,150 --> 00:34:38,110
+بتلع من الجارح اللي أنا نخست نفسي فيه هيك بيكون عم
+
+458
+00:34:38,110 --> 00:34:41,990
+بيعمل wash لمكان الجارح يعني في احتمال كبير انه ال
+
+459
+00:34:41,990 --> 00:34:47,670
+microbe اللي فيها تطلع wash the area well with
+
+460
+00:34:47,670 --> 00:34:53,500
+soup and waterبدي أغسل المكان بالمية و الصابون و
+
+461
+00:34:53,500 --> 00:35:00,420
+بدي أسجل اسم المريض و ال ID number عشان أتبع معاه
+
+462
+00:35:00,420 --> 00:35:05,960
+أشوف هذا المريض إيش عنده و إيش راح يصير معايا في
+
+463
+00:35:05,960 --> 00:35:10,720
+المستقبل من ماذا يحمللي المستقبل من مفاجأات متعلقة
+
+464
+00:35:10,720 --> 00:35:14,780
+بهذا المريض و ال .. ال .. النخزة اللي أنا نخزت
+
+465
+00:35:14,780 --> 00:35:22,120
+فيها نفسي من ال needle الملوثة بدعمهمprotect the
+
+466
+00:35:22,120 --> 00:35:27,840
+patient كيف أنا بدي أحمي المريض تمام place blood
+
+467
+00:35:27,840 --> 00:35:35,400
+collection equipment away from patient sorry place
+
+468
+00:35:35,400 --> 00:35:39,280
+blood collection equipment away from patients
+
+469
+00:35:39,280 --> 00:35:43,300
+especially children and psychiatric patients لازم
+
+470
+00:35:43,300 --> 00:35:48,160
+أنا أبعد قدوات سحب الدم عن المريض خصوصا لو كان هذا
+
+471
+00:35:48,160 --> 00:35:52,120
+المريض طفل أو مريض نفسييعني أدوات حادة أنا بستعمل
+
+472
+00:35:52,120 --> 00:35:57,500
+chauffeur بستعمل needles إبر فممكن يكون هذا المريض
+
+473
+00:35:57,500 --> 00:36:00,840
+يعني إذا كان مثلا مريض نفسي psychiatric فبالتالي
+
+474
+00:36:00,840 --> 00:36:04,320
+ممكن يأذي نفسه إذا كان طفل ممكن يلعب فيها من باب
+
+475
+00:36:04,320 --> 00:36:08,260
+الفضول و أيضا يأذي نفسه فبالتالي أنا بدي أبعد هذه
+
+476
+00:36:08,260 --> 00:36:12,620
+الأدوات عن المريضpractice hygiene for the patient
+
+477
+00:36:12,620 --> 00:36:18,380
+protection، بدي أعقم المكان، السطح، أي مكان بيلامس
+
+478
+00:36:18,380 --> 00:36:23,320
+المريض أو بيحط عليه إيدي، لازم أنا أكون معقمة، بدي
+
+479
+00:36:23,320 --> 00:36:27,380
+ألبس gloves و أبدلهم مثل ما حكينا بين كل مريض و
+
+480
+00:36:27,380 --> 00:36:31,180
+الآخر، change them between each patientand wash
+
+481
+00:36:31,180 --> 00:36:36,300
+your hand frequently و أغسل إيديا ب .. باستمرار من
+
+482
+00:36:36,300 --> 00:36:39,460
+فترة لإلى أخرى علشان أيضا كمان أحمي نفسي و أحمي
+
+483
+00:36:39,460 --> 00:36:43,420
+المريض always wear a clean lab coat or gown يعني
+
+484
+00:36:43,420 --> 00:36:48,460
+أنا بدي ألبس على طول ال lab coat طبيعي يكون انظيف
+
+485
+00:36:48,460 --> 00:36:54,380
+ما يكون ملوثو بعد هيك ببدأ بعملية preparation of
+
+486
+00:36:54,380 --> 00:36:59,360
+the puncture site كيف انا اسحب او احضر مكان السحب
+
+487
+00:36:59,360 --> 00:37:05,300
+سواء كان vein puncture او skin puncture بدي اعقم
+
+488
+00:37:05,300 --> 00:37:11,920
+المكان باستخدام 70% isopropanol طبعا 70%
+
+489
+00:37:11,920 --> 00:37:16,860
+isopropanol يا بنات او تمام مش شرط يعني 70%
+
+490
+00:37:16,860 --> 00:37:23,920
+isopropanolممكن يكون 70% isopropanol or ethanol،
+
+491
+00:37:23,920 --> 00:37:29,000
+طبعا؟ يعني 70% isopropanol أو 70% ethanol نفس
+
+492
+00:37:29,000 --> 00:37:31,800
+الاشي، طبعا؟ نفس الاشي
+
+493
+00:37:34,230 --> 00:37:41,910
+تمام اذا انا بعقم المكان بامسحه ب 70% ethanol و
+
+494
+00:37:41,910 --> 00:37:48,510
+طبعا بعد ما انا اعقم لازم المنطقة اللي عقمتها
+
+495
+00:37:48,510 --> 00:37:53,030
+اتركها جافة يعني اترك مجال لل .. للكحول يتبخر او
+
+496
+00:37:53,030 --> 00:37:59,010
+اني امسح .. ارجع امسح المنطقة ب sterile gauze يعني
+
+497
+00:37:59,010 --> 00:38:05,220
+بشاش او بقطن معقمو يجاف لحتى أنشف المكان أجففه
+
+498
+00:38:05,220 --> 00:38:13,720
+عشان يكون هيك صار انظيف معقم و بالتالي جاهز لسحب
+
+499
+00:38:13,720 --> 00:38:19,620
+العينة بمجرد يا بنات أنه أنا أكون عقمت المكان سواء
+
+500
+00:38:19,620 --> 00:38:26,760
+كان منطقة الوريد أو ال ..ال skin، الإصبع، يعني
+
+501
+00:38:26,760 --> 00:38:29,800
+سواء من الوريد، يعني من منطقة ال .. ال .. اللي هي
+
+502
+00:38:29,800 --> 00:38:34,840
+عندى المفصل، الكوع أو من منطقة ال .. ال .. الأصابع
+
+503
+00:38:34,840 --> 00:38:40,200
+فبمجرد ما أعاقمها ممنوع ألمسها مرة تانية بإيدي
+
+504
+00:38:40,200 --> 00:38:45,060
+لإنه هيك أنا بكون عم بلوسها مرة تانية، احنا في
+
+505
+00:38:45,060 --> 00:38:49,420
+ميكروبات بتكون موجودة على جسمنا و هاي الميكروبات
+
+506
+00:38:49,420 --> 00:38:53,490
+ممكن تكون .. ماتكونش ممرضة على ال skin تبعناطبعا،
+
+507
+00:38:53,490 --> 00:38:57,250
+لكن إذا فاتت للدم، إذا أنا لوثت فيها منطق السحب
+
+508
+00:38:57,250 --> 00:39:00,790
+الدم و فاتت للدم، ممكن تصير ممرضة في داخل الدم،
+
+509
+00:39:00,790 --> 00:39:04,730
+طبعا، فبالتالي لازم .. عشان هيك أنا عم بعقم منطقة
+
+510
+00:39:04,730 --> 00:39:06,550
+ال skin قبل السحب
+
+511
+00:39:12,960 --> 00:39:18,080
+طيب نيجي لأ ال .. ال micro sample technique micro
+
+512
+00:39:18,080 --> 00:39:21,400
+sample يا بنات يعني أنه أنا بدي أحصل على عينة
+
+513
+00:39:21,400 --> 00:39:27,260
+صغيرة الحجم يعني أنا بدي أسحب عينة من ال skin طبعا
+
+514
+00:39:27,260 --> 00:39:31,340
+is .. refers to blood collection by skin puncture
+
+515
+00:39:31,340 --> 00:39:36,240
+يعني أنا بدي أسحب عين الدم من خلالال skin puncture
+
+516
+00:39:36,240 --> 00:39:40,720
+طبعا من خلال أن أنا أحصل أعمل نخزة في ال skin في
+
+517
+00:39:40,720 --> 00:39:43,960
+الإصبع يعني مثلا أو في كعب الرجل عند المريض عند
+
+518
+00:39:43,960 --> 00:39:47,400
+الأطفال حسب وين المكان المهم في ال skin مش في
+
+519
+00:39:47,400 --> 00:39:52,140
+منطقة وريدand is frequently used in the following
+
+520
+00:39:52,140 --> 00:39:56,800
+types of patients طبعا يا بنات هذه العينة وهذا هذا
+
+521
+00:39:56,800 --> 00:40:01,800
+موضوع سؤال امتحان يعني انا امتى او من مين او ايش
+
+522
+00:40:01,800 --> 00:40:06,700
+مين هم المرضى اللي انا بضطر اسحب منهم micro sample
+
+523
+00:40:06,700 --> 00:40:10,820
+technique او بضطر اسحب منهم عينة من خلال skin
+
+524
+00:40:10,820 --> 00:40:14,440
+puncture يعني مابقدر اسحبلهم vein puncture بسحبلهم
+
+525
+00:40:14,440 --> 00:40:18,740
+skin puncture اول اشي الأطفال ال infant حديثي
+
+526
+00:40:18,740 --> 00:40:24,120
+الولادةأقل من 6 شهور أطفال يعني مولودين موليد أقل
+
+527
+00:40:24,120 --> 00:40:28,180
+من 6 شهور في العمر طبعا ماعندهمش large blood
+
+528
+00:40:28,180 --> 00:40:33,180
+supply ماعندهمش كمية دم كبيرة في جسمهم لإن حجمهم
+
+529
+00:40:33,180 --> 00:40:38,940
+صغير احنا حكينا حجم الدم يعني بيتراوح حسب الكتلة
+
+530
+00:40:38,940 --> 00:40:42,580
+تبع الجسم طب إذا هو طفل صغير معناها حجم الدم عنده
+
+531
+00:40:42,580 --> 00:40:50,040
+أيضا صغيرتمام؟ و ال .. بالتالي بيكون خطر عليه إن
+
+532
+00:40:50,040 --> 00:40:54,660
+أنا أسحب عينة من الوريد، تمام؟ فبضطر أنا أسحبله من
+
+533
+00:40:54,660 --> 00:40:58,260
+ال skin، هذا الطفل إما بنخزه من كعب رجله أو من
+
+534
+00:40:58,260 --> 00:41:03,150
+الإصبع، تمام؟in younger children في الأطفال الأكبر
+
+535
+00:41:03,150 --> 00:41:09,530
+شوي بالعمر و لكن الفحص المطلوب لإلهم محتاج small
+
+536
+00:41:09,530 --> 00:41:14,170
+amount of blood يعني هم صح أطفال أكبر و عندهم
+
+537
+00:41:14,170 --> 00:41:19,230
+blood supply أكبر ولكن أنا محتاجة أصلا للفحص small
+
+538
+00:41:19,230 --> 00:41:23,410
+amount of blood طمام طالما أنا محتاجة small amount
+
+539
+00:41:23,410 --> 00:41:27,730
+of blood ف ال skin puncture هي الخيار تبعي بعمل
+
+540
+00:41:27,730 --> 00:41:32,650
+أسحابلهم من خلال ال skin punctureأو when adult has
+
+541
+00:41:32,650 --> 00:41:37,770
+poor vein لما يكون شخص adult ده لغى كبير يعني عنده
+
+542
+00:41:37,770 --> 00:41:43,310
+أوريدة و عنده كمية دم كافية ولكن ال .. الوريد مش
+
+543
+00:41:43,310 --> 00:41:47,310
+انا .. مش عم .. مش عم بستطيع أو مش عم بقدر انه انا
+
+544
+00:41:47,310 --> 00:41:53,500
+أسحبله عينة من الوريد، تمام؟إيه؟ ليش؟ مثلا ممكن
+
+545
+00:41:53,500 --> 00:41:57,660
+يكون منطقة الوريد صارلها burned يعني انحرقت، عنده
+
+546
+00:41:57,660 --> 00:42:02,120
+حروق يعني في جسمه كلها أو في مغطية حجم كبير من
+
+547
+00:42:02,120 --> 00:42:06,720
+جسمه فبالتالي ده يعني صعب أصل للوريد فبالتالي صعب
+
+548
+00:42:06,720 --> 00:42:11,600
+أن أنا أسحب له عينة من الوريد الناس اللي بتاخد
+
+549
+00:42:11,600 --> 00:42:17,240
+chemotherapy لمرضى ال cancer اللي بيتعالجه بال
+
+550
+00:42:17,240 --> 00:42:24,270
+chemotherapy، بالكماويفبالتالي هدول بيصير عندهم
+
+551
+00:42:24,270 --> 00:42:27,770
+ضعف في الأوردة الأوردة تبعتهم بتصير رفيعة و دقيقة
+
+552
+00:42:27,770 --> 00:42:33,390
+جدا فبالتالي صعب ان انا يعني ا .. ا .. احصل عليها
+
+553
+00:42:33,390 --> 00:42:38,250
+او ادور عليها و صعب ان انا افوت فيها إبرة فبالتالي
+
+554
+00:42:38,250 --> 00:42:41,770
+باخدلهم من ال skin puncture كمان
+
+555
+00:42:51,200 --> 00:42:55,440
+تمام؟ إيش الحاجات اللي .. اللي بتلزمني أو الأدوات
+
+556
+00:42:55,440 --> 00:42:58,260
+اللي بتلزمني علشان أنا أصحب عينة من ال skin
+
+557
+00:42:58,260 --> 00:43:02,420
+puncture؟ أول حاجة بلزمني يعني زي ال reagents و ال
+
+558
+00:43:02,420 --> 00:43:05,920
+equipment أول إشي بلزمني سبعين في المية حكينا
+
+559
+00:43:05,920 --> 00:43:09,980
+isopropyl alcohol يعني isopropanol أو سبعين في
+
+560
+00:43:09,980 --> 00:43:15,250
+المية ethanol the same تمام؟الملزمني sterile goes
+
+561
+00:43:15,250 --> 00:43:21,470
+bad يعني قطن أو شاش معقّم و حتى أحطه على مكان
+
+562
+00:43:21,470 --> 00:43:27,270
+السحب العينى يعني بعد ما أخلص سحب و أزيل ال needle
+
+563
+00:43:27,270 --> 00:43:35,880
+بدي أحطه مكانهابلزمني أيضًا مثلًا ال .. يعني
+
+564
+00:43:35,880 --> 00:43:39,980
+blasters عشان أحطها للمريض أيضًا على مكان السحب
+
+565
+00:43:39,980 --> 00:43:44,340
+gloves و هذه ال gloves أنا في .. عندي تلت أنواع من
+
+566
+00:43:44,340 --> 00:43:48,360
+ال gloves إما مصنوعة من ال latex و هي الأكثر شيوعا
+
+567
+00:43:48,360 --> 00:43:52,540
+أو مصنوعة من ال nitril أو ال vinyl راح نحكي عنهم
+
+568
+00:43:52,540 --> 00:43:56,160
+في ال slide الجاي و نشوف إيش الفرق ما بينهم تمام؟
+
+569
+00:43:57,210 --> 00:44:00,910
+warm to protect the patient and philiptomist طبعا
+
+570
+00:44:00,910 --> 00:44:04,970
+ال gloves بتحمي المريض و بتحمي ال .. ال .. ال
+
+571
+00:44:04,970 --> 00:44:09,070
+أخصائي المختبرات sterile disposable blood Lancet
+
+572
+00:44:09,070 --> 00:44:14,070
+طبعا أنا بالزمني ال .. في ال .. سحب ال skin
+
+573
+00:44:14,070 --> 00:44:16,330
+puncture أو في سحب عينة من ال skin puncture
+
+574
+00:44:16,330 --> 00:44:20,780
+بالزمني ال .. ال Lancet طبعاإيش هي ال lancet اللي
+
+575
+00:44:20,780 --> 00:44:26,160
+هي شفرة مصممة يعني مدببة الطرف مصممة لإحدى ثقوب أو
+
+576
+00:44:26,160 --> 00:44:32,680
+نخز في ال skin لحتى نحصل على عينة دم طبعا latex اي
+
+577
+00:44:32,680 --> 00:44:36,040
+gloves ايش ال latex gloves طبعا مصنوعة من ال
+
+578
+00:44:36,040 --> 00:44:40,260
+rubber طبعا و بتستخدم إما في المجال الطبي أو
+
+579
+00:44:40,260 --> 00:44:43,900
+المجال الصناعي ولكن عندي مشكلة إنها ممكن تسبب
+
+580
+00:44:43,900 --> 00:44:47,840
+حساسية طبعا و هي الأكثر شيوعا طبعا أكتر استخداما
+
+581
+00:44:48,450 --> 00:44:51,910
+اللي هي ال gloves اللي لونها أبيض، تمام؟ ال
+
+582
+00:44:51,910 --> 00:44:55,910
+nitrale gloves طبعا مافيش فيها latex، يعني مافيش
+
+583
+00:44:55,910 --> 00:44:58,930
+فيها powder، ال latex يعني فيها powder يا بنات،
+
+584
+00:44:58,930 --> 00:45:02,510
+تمام؟ مصنعة من المطاط و فيها powder من الداخل، ال
+
+585
+00:45:02,510 --> 00:45:05,630
+.. طبعا ال .. ال nitrale gloves مافيش فيها powder،
+
+586
+00:45:05,630 --> 00:45:10,300
+تمام؟مصنعة من ال .. ال .. ال synthetic rubber يعني
+
+587
+00:45:10,300 --> 00:45:13,660
+ال .. المطاط الصناعي مش المطاط الطبيعي، هذه مطاط
+
+588
+00:45:13,660 --> 00:45:20,160
+طبيعي، تمام؟ و فبالتالي هي مابتسببش حساسية، تمام؟
+
+589
+00:45:20,160 --> 00:45:25,740
+و هي puncture resistant يعني مقاومة لإنه يصير ثقب
+
+590
+00:45:25,740 --> 00:45:30,820
+فيهايعني لو ال needle بدها تنخزها عشان انا .. يعني
+
+591
+00:45:30,820 --> 00:45:35,700
+لو صار في accident و بدي أنخز نفسي اذا انا يعني
+
+592
+00:45:35,700 --> 00:45:40,340
+لابسة night rally gloves بيصعب انه يصير في .. ان
+
+593
+00:45:40,340 --> 00:45:44,200
+انا أنخز نفسي medical grade يعني هي مفضلة في
+
+594
+00:45:44,200 --> 00:45:48,140
+المجال الطب يستخدموها في العمليات لونها أزرق و هي
+
+595
+00:45:48,140 --> 00:45:52,670
+بتعطيني درجة حماية أكبر ال vanilla glovesلسه
+
+596
+00:45:52,670 --> 00:45:56,670
+durable يعني لسه protection لسه expensive يعني ما
+
+597
+00:45:56,670 --> 00:46:02,910
+بتتحملش كتير بتعطيني حماية أقل و هي بالتالي أرخصة
+
+598
+00:46:02,910 --> 00:46:07,550
+الثمن مش expensive تمام؟ هذا بالنسبة لأنواع ال
+
+599
+00:46:07,550 --> 00:46:10,530
+gloves تمام؟
+
+600
+00:46:12,170 --> 00:46:19,210
+ال procedure تجربة ال .. ال .. ال skin puncture
+
+601
+00:46:19,210 --> 00:46:24,470
+أول حاجة approach the patient in friendly calm
+
+602
+00:46:24,470 --> 00:46:28,170
+manner provide for their comfort as much as
+
+603
+00:46:28,170 --> 00:46:31,810
+possible and gain the patients cooperation أول
+
+604
+00:46:31,810 --> 00:46:36,130
+حاجة تعاملي مع المريض بشكل friendly و دود و هادق
+
+605
+00:46:36,130 --> 00:46:39,250
+طبعا ما تكوني aggressive معاه ما تكوني عنيفة أو
+
+606
+00:46:39,250 --> 00:46:44,930
+يعني معصبة أو اتوتريةتمام؟ و بدي أكون مريحة لإله
+
+607
+00:46:44,930 --> 00:46:48,530
+إن ان شاء الله ماريح تتقلم كتير و يعني هي نخزة
+
+608
+00:46:48,530 --> 00:46:53,990
+بسيطة و أحاول أريحه يعني لو هو متوتر أخلي يعني هيك
+
+609
+00:46:53,990 --> 00:46:58,870
+ياخد نفس عميق يحاول يرتاح أمسك إيده أعمللها
+
+610
+00:46:58,870 --> 00:47:01,670
+rubbing يعني أفرك إيده أحاول أدفله إيده إذا إيده
+
+611
+00:47:01,670 --> 00:47:07,640
+باردة فبالتالي هيك أنا بكون عم بريحه نفسياand gain
+
+612
+00:47:07,640 --> 00:47:10,580
+the patient cooperation وبالتالي هيك بكون ايضا
+
+613
+00:47:10,580 --> 00:47:14,720
+بخلي الطبيب المريض يكون متعاون معاه اكتر identify
+
+614
+00:47:14,720 --> 00:47:18,060
+the patient correctly بدي اتعرف على المريض بشكل
+
+615
+00:47:18,060 --> 00:47:23,690
+صحيح تمامبدي اسأله انت فلان لفلاني ايش اسمك
+
+616
+00:47:23,690 --> 00:47:29,830
+بالكامل؟ كام عمرك؟ معاك اثبات؟ وين ما .. وين معاك
+
+617
+00:47:29,830 --> 00:47:35,010
+ال kart تبعك؟ اشوف رقمك تطبي؟ انت يعني من ايش
+
+618
+00:47:35,010 --> 00:47:39,390
+بتشكي؟ كذا يعني اسأله كام سؤال احاول اتأكد انه هذا
+
+619
+00:47:39,390 --> 00:47:44,410
+المريض هو يعني المريض الصح لل request الصح عشان
+
+620
+00:47:44,410 --> 00:47:48,820
+احصل على العين الصح تمام؟properly fill out
+
+621
+00:47:48,820 --> 00:47:53,040
+appropriate requisition form طبعا بدي أعبي الجزئية
+
+622
+00:47:53,040 --> 00:47:59,860
+الخاصة فيا من ال request form اللي هي يعنيال ..
+
+623
+00:47:59,860 --> 00:48:04,560
+يعني اللي هي عبارة عن ال time و ال date of sample
+
+624
+00:48:04,560 --> 00:48:08,300
+collection و ال initial طبعا verify the patient
+
+625
+00:48:08,300 --> 00:48:13,280
+condition طبعا إذا كان الفحص محتاج شروط معينة مثلا
+
+626
+00:48:13,280 --> 00:48:18,380
+إنه يكون المريض صايم أو يعني dietary restriction
+
+627
+00:48:18,380 --> 00:48:22,540
+ممتنع عن أكل معينة أو متناول أكل معينة أو ممتنع عن
+
+628
+00:48:22,540 --> 00:48:27,000
+أدوية معينة أو متناول أدوية معينةتوقيت الفحص مثلا
+
+629
+00:48:27,000 --> 00:48:32,000
+في فحصات لازم أعملها في الصبح يعني الصباح المبكر
+
+630
+00:48:32,000 --> 00:48:35,060
+في تمارين .. في فحصات بعملها بعد تمارين رياضية في
+
+631
+00:48:35,060 --> 00:48:39,980
+فحصات بعملها في المساء حسب يعني ال .. ال .. ال
+
+632
+00:48:39,980 --> 00:48:43,480
+time و الظروف المناسبة للفحص بدي أتأكد صايم كام
+
+633
+00:48:43,480 --> 00:48:49,140
+ساعة صومتطيب أكلت كذا إيش الدوة اللي بتاخده ..
+
+634
+00:48:49,140 --> 00:48:53,180
+بتاخد أدوية معينة؟ بدي أسأله على أساس إن أنا أتأكد
+
+635
+00:48:53,180 --> 00:49:00,440
+إن هو مستوى في شروط إجراء الفحص، تمام؟ و طبعا ال
+
+636
+00:49:00,440 --> 00:49:04,940
+medical treatment are all of concern and should be
+
+637
+00:49:04,940 --> 00:49:08,540
+noted on the lab requisition طبعا أي إيش بياخده هو
+
+638
+00:49:08,540 --> 00:49:12,940
+الشخص لازم يكون .. يعني ممنشن إله في ال lab
+
+639
+00:49:12,940 --> 00:49:16,690
+requestposition the patient طبعا بدي اجلس المريض
+
+640
+00:49:16,690 --> 00:49:20,730
+في مكان على كرسي طبعا هذا الكرسي مايكون عالي او
+
+641
+00:49:20,730 --> 00:49:26,430
+مايكونش له دهر مثلا انه هيك بيكون المريض اذا كان
+
+642
+00:49:26,430 --> 00:49:29,610
+الكرسي عالي او مالوش دهر او كذا ممكن يكون المريض
+
+643
+00:49:29,610 --> 00:49:32,650
+دور دلال اذا أغمى عليها على طول بيجي على الأرض
+
+644
+00:49:32,650 --> 00:49:37,120
+وواجهته بتكون محرزةفلأ يعني اللي لازم أنا أجلسه
+
+645
+00:49:37,120 --> 00:49:43,080
+على كرسي و .. أو أخليه يستلقي على سرير و لازم
+
+646
+00:49:43,080 --> 00:49:47,440
+الكرسي هذا إذا كان .. مايكونش عالي و مايكونش ال ..
+
+647
+00:49:47,440 --> 00:49:52,440
+يعني و يكون إيله دهر و أسان و إيله أيدي بحيث أنه ي
+
+648
+00:49:52,440 --> 00:49:56,540
+.. يمسك المريض منيح في حال لو فقده عينه يعني في
+
+649
+00:49:56,540 --> 00:50:01,100
+مرضى بيخافوا، بيتوتروا، في يعني ممكن تصل لدرجة
+
+650
+00:50:01,100 --> 00:50:07,390
+الإغماء من ساحب عين دمlocation of the puncture
+
+651
+00:50:07,390 --> 00:50:12,250
+site طبعا the best location of finger stick ..
+
+652
+00:50:12,250 --> 00:50:16,830
+finger stick أو ال .. يعني
+
+653
+00:50:16,830 --> 00:50:19,730
+ال .. أو ال finger puncture هي نفسها يعني أنا باخد
+
+654
+00:50:19,730 --> 00:50:24,170
+عينة من الإصبع لازم يكونوا يا بنات هو الإصبع
+
+655
+00:50:24,170 --> 00:50:30,260
+التالت و الرابع مين هم التالت و الرابع؟يعني ال ..
+
+656
+00:50:30,260 --> 00:50:35,400
+ال .. ال .. الإصبع الأوسط و اللي .. و اللي بعده،
+
+657
+00:50:35,400 --> 00:50:39,660
+تمام؟ هذا معناها التالت والرابع، يعني الابهام رقم
+
+658
+00:50:39,660 --> 00:50:44,420
+واحد، السبابة رقم اتنين، الأوسط رقم تلاتة، الخنصر
+
+659
+00:50:44,420 --> 00:50:47,500
+اللي هو رقم أربع، اذا هو الأوسط و الخنصر، اللي هو
+
+660
+00:50:47,500 --> 00:50:50,740
+الخنصر لأ، تمام؟ طب ليش أنا اخترت هدول التلات
+
+661
+00:50:50,740 --> 00:50:56,260
+أصابع؟ في عندهم soft tissueكافي بحيث إن أنا لو ..
+
+662
+00:50:56,260 --> 00:51:01,340
+لو نخزت ما بقلمهم و ما بوصل للعظم، طبعا، لو جينا
+
+663
+00:51:01,340 --> 00:51:05,820
+للإبهام، الإبهام بتحسي إصبع مسطح، انفلطح فبالتالي
+
+664
+00:51:05,820 --> 00:51:09,280
+كمية ال soft tissue في منطقة ال .. في المنطقة
+
+665
+00:51:09,280 --> 00:51:14,080
+العلوية فيه جليلة، طبعا، فإذا أنا نخزت ممكن أوصل
+
+666
+00:51:14,080 --> 00:51:19,260
+للعظمفبالتالي بكون أذية العظم طبعا السبابة أنتوا
+
+667
+00:51:19,260 --> 00:51:22,320
+بتعرفوا إحنا بنمسك الجنم باستخدام الإبهام والسبابة
+
+668
+00:51:22,320 --> 00:51:26,980
+والسبابة تبعنا غالبا يعني بيكون rigid أو ناشف شوية
+
+669
+00:51:26,980 --> 00:51:33,080
+طبعا فبرضه كمان ببتعد عنه وفال .. ال .. ال ..
+
+670
+00:51:33,080 --> 00:51:36,320
+الإصبع رقم تلاتة واربعة هما اللي هي فيهم طراوة
+
+671
+00:51:36,320 --> 00:51:39,840
+وفيهم ال soft tissue يعني كفيل بإن أنا أعمل نخزة
+
+672
+00:51:39,840 --> 00:51:44,900
+بعيدة عن العظمالأصبع الصغير هذا الحزين ال .. ال ..
+
+673
+00:51:44,900 --> 00:51:49,180
+ال .. البنصر طبعا صعب إن أنا أعمله نخز لإنه ه ..
+
+674
+00:51:49,180 --> 00:51:55,660
+هأقضيه، تمام؟ هذا بالنسبة للأصابع، التالت والرابع
+
+675
+00:51:55,660 --> 00:51:59,460
+ويفضل إن أنا أستخدم يا بنات ال non-dominant hand
+
+676
+00:51:59,800 --> 00:52:04,140
+تمام؟ يفضل إن أنا أستخدم ال non-dominant hand إيش
+
+677
+00:52:04,140 --> 00:52:07,060
+يعني ال non-dominant hand؟ يعني هو إذا بكتب بال ..
+
+678
+00:52:07,060 --> 00:52:12,180
+بالإيد اليمنى بسحبله من اليسرة إذا هو أعثر بكتب
+
+679
+00:52:12,180 --> 00:52:16,180
+بالإيد اليسرة بسحبله من اليمنى و هكذا don't use
+
+680
+00:52:16,180 --> 00:52:20,180
+the tip of the finger or center of finger تمام؟
+
+681
+00:52:20,180 --> 00:52:26,640
+يمنع أنا استخدام ال .. ال .. رأس الإصبع يعني أو
+
+682
+00:52:26,640 --> 00:52:29,890
+المركز طبعه تمام؟avoid
+
+683
+00:52:32,940 --> 00:52:37,960
+the side of the finger كمان على الجوانب تمام يعني
+
+684
+00:52:37,960 --> 00:52:42,160
+مابس .. مابس بعمل نخزة على الجوانب لإنه هيك أنا
+
+685
+00:52:42,160 --> 00:52:46,120
+بكون .. يعني جربت من منطقة الأضافر و صعب هذه
+
+686
+00:52:46,120 --> 00:52:49,760
+المنطقة أن أنا أعمل لها نخز تمام؟ و أيضا في .. على
+
+687
+00:52:49,760 --> 00:52:53,700
+الجوانب في لسه تشوفها تكون مؤلمة تمام؟ يعني في
+
+688
+00:52:53,700 --> 00:52:58,580
+كمان أيضا تجمع للأعصاب على الجوانب فهذه بتأدي إلى
+
+689
+00:52:58,580 --> 00:53:04,330
+إنه يكون الاشي مؤلمتمام ال .. ال second اللي هو ال
+
+690
+00:53:04,330 --> 00:53:09,390
+.. ال index الأصبع السبابة رقم اتنين هو thicker هو
+
+691
+00:53:09,390 --> 00:53:14,150
+سميك يعني جلده سميك نفسه فصعب أن أنا أعمله نخزا و
+
+692
+00:53:14,150 --> 00:53:20,330
+أصل يعني لعمق معين و أحصل على كمية الدم الكافيةو
+
+693
+00:53:20,330 --> 00:53:23,630
+ال fifth finger الأصبع الصغير الحزين حكينا أنه
+
+694
+00:53:23,630 --> 00:53:28,750
+عنده less soft to show فبالتالي يعني ممكن أنا أصل
+
+695
+00:53:28,750 --> 00:53:33,150
+العظم بسهولة و أنا عم بنخذه فبالتالي أسببله ألم أو
+
+696
+00:53:33,150 --> 00:53:37,030
+damage للبون avoid puncturing a finger which that
+
+697
+00:53:37,030 --> 00:53:39,950
+is cold or cyanotic, swollen, scarred or covered
+
+698
+00:53:39,950 --> 00:53:43,980
+with rashيعني الإصبع اللي شك الإيد لو كانت باردة
+
+699
+00:53:43,980 --> 00:53:47,860
+أو مزرقة ما .. ما .. ما بنخزها لإنه طبعا هي باردة
+
+700
+00:53:47,860 --> 00:53:50,980
+أو مزرقة يا إما من الخوف يا إما من التوتر أو من ..
+
+701
+00:53:50,980 --> 00:53:55,220
+من حالة مرضية عنده يعني مادامها باردة و مزرقة يعني
+
+702
+00:53:55,220 --> 00:53:58,660
+مافيش blood supply كافي فبالتالي يعني أنا لو نخزته
+
+703
+00:53:58,660 --> 00:54:01,600
+مش راح أحصل على كمية دم كافي يعني بس عم بكون بقلم
+
+704
+00:54:01,600 --> 00:54:05,610
+المريض وخلاصswollen ال .. إذا كان هو .. يعني إصبع
+
+705
+00:54:05,610 --> 00:54:09,730
+منتفخ و أنا أجي أنخزه يعني أنا هيك عم بسببله مشكلة
+
+706
+00:54:09,730 --> 00:54:14,050
+إضافية إذا كان فيها scar أو .. أو .. أو عنده rash
+
+707
+00:54:14,050 --> 00:54:22,230
+rash يعني .. يعني ال .. ال .. ال .. الاشي يعني هو
+
+708
+00:54:22,230 --> 00:54:30,750
+الأحمر اللي موجود يعني ال ..ال .. يعني مش عارفة
+
+709
+00:54:30,750 --> 00:54:36,970
+أترجمها بالعربي الصراحة هي ال rush يعني ال .. إذا
+
+710
+00:54:36,970 --> 00:54:40,810
+كان أحيانا بيكون في حساسية و بيكون في إحمرار مع
+
+711
+00:54:40,810 --> 00:54:46,930
+حبوب صغيرة و أشياء هذه بيسميها rush، تمام؟ فيفضل
+
+712
+00:54:46,930 --> 00:54:51,450
+إن أنا ما أستخدمها، تمام؟ إذا كان الإيد فيها rush
+
+713
+00:54:51,450 --> 00:54:55,690
+ما أستخدمها، تمام؟ يعني .. يعني دللت على وجود
+
+714
+00:54:55,690 --> 00:54:58,070
+حساسية أو infection أو التهابات معينة
+
+715
+00:55:01,400 --> 00:55:06,360
+طبعا إذا أنا بدي أسحب عينة من ال heel of the foot،
+
+716
+00:55:06,360 --> 00:55:10,120
+من كعب الرجل، طبعا حاكينا الأطفال ممكن أسحبلهم من
+
+717
+00:55:10,120 --> 00:55:10,860
+كعب الرجل
+
+718
+00:55:14,500 --> 00:55:17,900
+when obtaining blood from infant less than one
+
+719
+00:55:17,900 --> 00:55:22,000
+year إذا كان الطفل أقل من سنة يفضل إن أنا أخدله
+
+720
+00:55:22,000 --> 00:55:25,760
+العينة من كعب رجله، تمام؟ the site chosen should
+
+721
+00:55:25,760 --> 00:55:30,820
+be on the inside medial or outside plantar of the
+
+722
+00:55:30,820 --> 00:55:36,960
+foot يعني هاي .. هاي الرجل، تمام؟ رجل المريض،
+
+723
+00:55:36,960 --> 00:55:42,270
+خليني أكبر ال slideهي هذه رجل المريض تمام؟ هذا ال
+
+724
+00:55:42,270 --> 00:55:47,170
+plantar surface يعني المنطقة الطرفية من القدم
+
+725
+00:55:47,170 --> 00:55:50,730
+بسميها ال plantar surface و هذا ال medial المنطقة
+
+726
+00:55:50,730 --> 00:55:54,750
+الوسطى يعني المحادية للرجل التانية يعني المنطقة
+
+727
+00:55:54,750 --> 00:55:59,030
+الداخلية من الرجل بسميها ال plant .. ال medial
+
+728
+00:55:59,030 --> 00:56:05,000
+surface تمام؟ لو أنا بدي أرسم خطimaginary line
+
+729
+00:56:05,000 --> 00:56:13,500
+تمام خط وهمي ب .. برسمه طبعا من منتصف الأصبع
+
+730
+00:56:13,500 --> 00:56:20,840
+الكبير تمام إلى كعب الرجل و أيضا خط أخر من ال ..
+
+731
+00:56:21,740 --> 00:56:26,080
+المسافة ما بين الإصبع الرابع و الخامس اللي هي هذه
+
+732
+00:56:26,080 --> 00:56:32,700
+المسافة و أيضا برسم خط يتقاطع في ال .. ال .. كعب
+
+733
+00:56:32,700 --> 00:56:37,380
+الرجل تمام؟ أي منطقة في كعب الرجل خارج رأس المتلت
+
+734
+00:56:37,380 --> 00:56:41,940
+بسميها هي المنطقة اللي يعني ممكن أنا أسحب منها عين
+
+735
+00:56:41,940 --> 00:56:48,240
+الدمإذا أول ما بمسك رجل الطفل لأقل من سنة برسم خط
+
+736
+00:56:48,240 --> 00:56:54,900
+وهمي بنظري يمتد من نصف الإصبع الكبير إلى إياش إلى
+
+737
+00:56:54,900 --> 00:56:59,400
+من نصف الإصبع الكبير إلى كعب الرجل ومن أو ال line
+
+738
+00:56:59,400 --> 00:57:04,240
+from between the fourth and the fifth two وخط أيضا
+
+739
+00:57:04,240 --> 00:57:07,780
+من المسافة ما بين الإصبع الرابع والخامس إلى كعب
+
+740
+00:57:07,780 --> 00:57:10,380
+الرجل تمام؟
+
+741
+00:57:11,190 --> 00:57:13,910
+المنطقة هذه اللي في كعب الرجل اللي في رأس المتلات
+
+742
+00:57:13,910 --> 00:57:17,150
+بستثنيها، اذا اي منطقة خارج كأراس المتلات هي
+
+743
+00:57:17,150 --> 00:57:21,370
+المنطقة اللي acceptable for puncture، اذا the area
+
+744
+00:57:21,370 --> 00:57:24,910
+outside of these two lines، المنطقة اللي خارج
+
+745
+00:57:24,910 --> 00:57:31,530
+تقاطع الرأس الخاتين هدولة، يعني خارج رأس المتلات،
+
+746
+00:57:31,530 --> 00:57:35,730
+هذه المنطقة هي acceptable for the puncture، تمام
+
+747
+00:57:36,910 --> 00:57:41,410
+طيب، هلأ ال .. ال puncture دبث، عنق ال puncture،
+
+748
+00:57:41,410 --> 00:57:48,780
+تمام؟يعني أنا بدي .. جدش بدي أفوت عمق في ال .. ال
+
+749
+00:57:48,780 --> 00:57:53,080
+skin اللي أنا عم بنخزه للمريض for finger .. for
+
+750
+00:57:53,080 --> 00:57:59,400
+finger stick لو أنا ماخدة العينة من الإصبع تمام
+
+751
+00:57:59,400 --> 00:58:04,400
+not deeper than 3.1 millimeter يعني ممنوع أفوت
+
+752
+00:58:04,400 --> 00:58:09,730
+أكتر من 3.1 millimeter تمام؟طيب ال distance
+
+753
+00:58:09,730 --> 00:58:14,350
+between the skin surface and bone دايما المسافة ما
+
+754
+00:58:14,350 --> 00:58:18,630
+بين ال .. ال .. ال skin surface ما بين الجلد و
+
+755
+00:58:18,630 --> 00:58:25,730
+العظم بتتراوح ما بين 3.1 ل 10.9 millimeter تمام؟
+
+756
+00:58:25,730 --> 00:58:29,970
+اذا انا لازم ما اصل 3.1 لإن انا ممكن هيك اكون وصلت
+
+757
+00:58:29,970 --> 00:58:34,730
+للعظم لازم اكون وصلت جابل ال 3.1 يعني انا اكون
+
+758
+00:58:34,730 --> 00:58:41,610
+ماكونش فوتت أعمق من 3.1تمام؟ طيب بالنسبة لأ
+
+759
+00:58:41,610 --> 00:58:48,250
+الأطفال اللي يعني عمرهم ست شهور الطفل هذا المسافة
+
+760
+00:58:48,250 --> 00:58:52,950
+ما بين ال skin و العضل ده تروح ما بين واحد و نص
+
+761
+00:58:53,840 --> 00:58:58,220
+millimeter ل اتنين واربعة millimeter تمام فبالتالي
+
+762
+00:58:58,220 --> 00:59:02,800
+يفضل ايش عشان هيك ال finger ما بستخدمه لهدول
+
+763
+00:59:02,800 --> 00:59:06,680
+الأطفال بفضل ان انا استخدملهم heel puncture تمام
+
+764
+00:59:06,680 --> 00:59:11,390
+بستخدملهم او بعمللهم heel punctureتمام اذا بالنسبة
+
+765
+00:59:11,390 --> 00:59:14,450
+ل finger stick عند الناس ال adult او الناس اللى
+
+766
+00:59:14,450 --> 00:59:19,070
+مسموحلى انا اخد منهم من الاصبع مش لازم اتجاوز ال 3
+
+767
+00:59:19,070 --> 00:59:24,430
+.1 mm عمق النخزة علشان لإن المسافة ما بين ال skin
+
+768
+00:59:24,430 --> 00:59:28,920
+و العظم تتراوح ما بين 3.1لعشرة point تسعة
+
+769
+00:59:28,920 --> 00:59:33,840
+millimeter عند الناس طبعا يعني انا مدام مش لازم
+
+770
+00:59:33,840 --> 00:59:36,600
+اصل عمق تلاتة point واحد لإنه في خاطر اكون وصلت
+
+771
+00:59:36,600 --> 00:59:39,940
+العظام لازم اكون وصلت .. العمق يكون قبل التلاتة
+
+772
+00:59:39,940 --> 00:59:46,960
+point واحد تمام؟for heel puncture عمق ال puncture
+
+773
+00:59:46,960 --> 00:59:53,340
+تمام في أي وقت لازم مايكونش اكتر من 2.4 يعني في ال
+
+774
+00:59:53,340 --> 00:59:57,240
+general في الشكل .. بالشكل العام مش لازم يكون اعمق
+
+775
+00:59:57,240 --> 01:00:02,820
+من 2.4 millimeter عشان ا .. يعني اتجنب ان انا اعمل
+
+776
+01:00:02,820 --> 01:00:06,540
+damage لل bonebecause the blood supply for the
+
+777
+01:00:06,540 --> 01:00:10,580
+infant's heel is located between one point يعني
+
+778
+01:00:10,580 --> 01:00:14,440
+الدم موجود يعني الأوعية الدموية الشعيرات الدموية
+
+779
+01:00:14,440 --> 01:00:20,360
+موجودة على بعد من point تلاتة خمسة إلى واحد وستة
+
+780
+01:00:20,360 --> 01:00:24,980
+point millimeter واحد point ستة millimeter تمام
+
+781
+01:00:24,980 --> 01:00:29,360
+تحت ال skin فلازم الضربة تبعتي ما تكونش أعمق من
+
+782
+01:00:29,360 --> 01:00:32,870
+واحد point ستةيعني تكون في .. في العمق ما بين
+
+783
+01:00:32,870 --> 01:00:37,150
+point تلاتة خمسة لواحد point ستة يعني في العمق
+
+784
+01:00:37,150 --> 01:00:40,050
+اللي موجودة فيه الأوعيات الدموية أنا مش لازم أصل
+
+785
+01:00:40,050 --> 01:00:43,490
+أعمق لإنه هيك أكون .. بكون عم بقلم المريض ممكن
+
+786
+01:00:43,490 --> 01:00:48,050
+أوصل للعظم ممكن أوصل لل nerve تبعته فبالتالي أقلمه
+
+787
+01:00:48,050 --> 01:00:53,840
+و .. أو أسببله damage يعني فعال فاضييعني أنا بس
+
+788
+01:00:53,840 --> 01:00:57,640
+محتاجة ضربة قوية عميقة enough .. enough deep تمام
+
+789
+01:00:57,640 --> 01:01:02,880
+بحيث انه يعني يتمكني ان انا أسحب عين الدم تبعتيطيب
+
+790
+01:01:02,880 --> 01:01:05,620
+performance of skin puncture مجرد ما أنا عملت
+
+791
+01:01:05,620 --> 01:01:09,040
+التحضيرات هذه و عرفت من وان بدي أسحب العينة تمام؟
+
+792
+01:01:09,040 --> 01:01:12,040
+هلأ بدي أعمل ال .. ال .. ال performance of skin
+
+793
+01:01:12,040 --> 01:01:15,380
+puncture the puncture site should be .. shouldn't
+
+794
+01:01:15,380 --> 01:01:18,520
+be cold طبعا مش لازم يكون بارد ولا cyanotic ولا
+
+795
+01:01:18,520 --> 01:01:25,220
+swollen ولا فيه rash ال .. عليه يعني احمرار أو
+
+796
+01:01:25,220 --> 01:01:32,020
+حساسية أو انتفاخ أو أي إشي تمام؟must be warmed
+
+797
+01:01:32,020 --> 01:01:36,460
+either by rubbing the side, hanging the hand or
+
+798
+01:01:36,460 --> 01:01:43,000
+applying hot gauze in venture side هلأ شوفوا معايا
+
+799
+01:01:43,000 --> 01:01:47,340
+طبعا مش لازم المكان يكون بارد وإذا كان بارد أنا
+
+800
+01:01:47,340 --> 01:01:50,000
+لازم أدفيه إما من خلال إن أنا أمسك إيده و أفركها
+
+801
+01:01:50,000 --> 01:01:54,060
+بين إيديا أو أخلي أعملها hanging hand إيش يعني
+
+802
+01:01:54,060 --> 01:01:58,430
+hanging hand؟طبعا، هلأ انت جالسة على كرسي المكتب،
+
+803
+01:01:58,430 --> 01:02:02,470
+إيدك على مستواكي، لو جربت تنزلي إيدك لتحت .. لتحت،
+
+804
+01:02:02,470 --> 01:02:06,710
+يعني باتجاه .. يعني بحيث أنه أصابعك تكون مشيرة إلى
+
+805
+01:02:06,710 --> 01:02:10,030
+الأسفل، إلى الأرض، طبعا، هتلاحظ إنه الأوعية
+
+806
+01:02:10,030 --> 01:02:13,810
+الدموية تبعتك اللي في إيدك، طلعي على الشراين اللي
+
+807
+01:02:13,810 --> 01:02:18,090
+في إيدك، طبعا، هتلاحظ إنها هي برزتارفع إيدك مرة
+
+808
+01:02:18,090 --> 01:02:23,510
+تانية، بتلاحظ أنه اختفى البروز هذا، تمام؟ فارجع
+
+809
+01:02:23,510 --> 01:02:27,490
+نزليها مرة تانية، معناه إذا أنت نزلت إيدك أدنى من
+
+810
+01:02:27,490 --> 01:02:31,130
+مستواكي، معناه أنت سمحت للدم أنه يتضفق في إيلها،
+
+811
+01:02:31,130 --> 01:02:35,670
+على طول بتدفع، تمام؟ أو من خلال أن أنا أاخد شاش
+
+812
+01:02:35,670 --> 01:02:41,350
+دافي أو شاش ساخن و يعني hot goes و أحطه على مكان
+
+813
+01:02:41,350 --> 01:02:46,650
+ال puncture عشان أدفيهطيب use a sterile lancet إذا
+
+814
+01:02:46,650 --> 01:02:49,950
+الشفرة أو الأداة اللى أنا بستخدم فيها بسحب فيها من
+
+815
+01:02:49,950 --> 01:02:54,470
+ال skin puncture باسمها Lancet تمام؟ إيش اسمها؟
+
+816
+01:02:54,470 --> 01:03:00,650
+Lancet make طبعا لازم أنا أعمل puncture دربة أو
+
+817
+01:03:00,650 --> 01:03:05,090
+ثقب من خلال .. من خلال إيش؟ لازم إيه لها صفات هاي
+
+818
+01:03:05,090 --> 01:03:08,890
+الدربة اللى أنا بقدر أعملها؟ تكون strong قوية و
+
+819
+01:03:08,890 --> 01:03:13,190
+fast and deep skin punctureإذا لازم تكون strong و
+
+820
+01:03:13,190 --> 01:03:17,550
+fast و deep مابنفع أنا أكون هيك يعني عم .. عم بحرك
+
+821
+01:03:17,550 --> 01:03:22,530
+إيدي ببطء و .. عشان أجي أنخذ المريض أو إنه يكون ..
+
+822
+01:03:22,530 --> 01:03:25,930
+تكون يدوب خفيفة الضربة لأ يعني انا بكون ممكن ..
+
+823
+01:03:25,930 --> 01:03:29,250
+إذا خفيفة يعني معناها أنا بس خدشت ال skin مافوتش
+
+824
+01:03:29,250 --> 01:03:34,390
+deep enough تمام؟فبالتالي لازم strong, fast, deep
+
+825
+01:03:34,390 --> 01:03:39,370
+تمام؟ و أيضا لازم تكون من خصائصها إنها تكون
+
+826
+01:03:39,370 --> 01:03:43,770
+اشمالها يا بنات perpendicular to the ridges of the
+
+827
+01:03:43,770 --> 01:03:49,030
+fingerprint و عمودية على خطوط البصمة لحظة طلع على
+
+828
+01:03:49,030 --> 01:03:55,560
+أصابعك مخططين بشكل دائري تمام؟ لازم ال ..الضربة
+
+829
+01:03:55,560 --> 01:04:02,100
+تبعتي تكون عمودية على خطوط البصمة وإن شاء الله بس
+
+830
+01:04:02,100 --> 01:04:06,100
+نرجع المختبر ونجرب ال skin puncture راح أورجيكم
+
+831
+01:04:06,100 --> 01:04:11,420
+إيش معنى كلمة عمودية على خطوط البصمة، تمام؟ طيبهذا
+
+832
+01:04:11,420 --> 01:04:15,040
+.. ده أنا .. طبعا ليش أنا بديها عمودية؟ لإنه لو
+
+833
+01:04:15,040 --> 01:04:18,760
+أنا عملت ال .. ال .. الجرح أو ال .. ال .. الثقوب
+
+834
+01:04:18,760 --> 01:04:22,660
+أو ال skin puncture موازي لخطوط البصمة راح يسيل
+
+835
+01:04:22,660 --> 01:04:26,400
+الدم يسيل ويمشي مع خطوط البصمة تمام؟ يمشي مع
+
+836
+01:04:26,400 --> 01:04:30,980
+الخطوط بتلاقي الدم صار سايح فبالتالي ما بيتجمع
+
+837
+01:04:30,980 --> 01:04:35,060
+كقطرات و صعب أنا أجمعهم تمام؟ انا بدي .. لازم يكون
+
+838
+01:04:35,060 --> 01:04:38,800
+الدم عمودي .. ال .. الضربة تكون عمودية على ال ..
+
+839
+01:04:38,800 --> 01:04:44,170
+ال .. ال ..خطوط البصمة فبالتالي هذا بيمكن انه انا
+
+840
+01:04:44,170 --> 01:04:49,930
+.. بيمكنني من انه لما انا يعني يطلع الدم بيطلع على
+
+841
+01:04:49,930 --> 01:04:54,050
+هائت قطارات و يسهل اجمعه داخل الإنبوبة، تمام؟ لكن
+
+842
+01:04:54,050 --> 01:04:58,110
+لو ساح مع خطوط البصمة أو في الفرشات هذه اللي ..
+
+843
+01:04:58,110 --> 01:05:02,610
+اللي موجودة بين الخطوط صعب ان انا اجمعه، هذا معنى
+
+844
+01:05:02,610 --> 01:05:06,950
+انه يكون perpendicular، تمام؟عشان الدم ال drop of
+
+845
+01:05:06,950 --> 01:05:12,050
+blood قطرة الدم ما تروحش run down ما تسيحش أو ما
+
+846
+01:05:12,050 --> 01:05:19,520
+تمشيش مع ال ridges مع خطوط البصمة تمامwipe away
+
+847
+01:05:19,520 --> 01:05:24,940
+the first drop of blood ايوة اول قطرة دم بتطلع بعد
+
+848
+01:05:24,940 --> 01:05:29,560
+ال puncture بدي اتخلص منها which tend to contain
+
+849
+01:05:29,560 --> 01:05:32,500
+excessive tissue fluid طبعا يا بنات انا بما اني
+
+850
+01:05:32,500 --> 01:05:35,740
+انا عملت نخزة في ال skin يعني انا عملت cell damage
+
+851
+01:05:35,740 --> 01:05:39,520
+دمرت خلايا الخلايا دي فيها cytoplasm في حوالها
+
+852
+01:05:39,520 --> 01:05:42,720
+سوائل في extra cellular fluid حوالها اذا ان هي
+
+853
+01:05:42,720 --> 01:05:47,430
+فيها داخلها سائل و مخاطب سائلفالدم هذا اللي بيطلع
+
+854
+01:05:47,430 --> 01:05:52,150
+في أول قطرة بيكون يحتوي على ال tissue fluid السائل
+
+855
+01:05:52,150 --> 01:05:55,290
+اللي موجود هذا داخل الانسجار داخل الخلايا أو محيط
+
+856
+01:05:55,290 --> 01:06:01,090
+فيها يعني بيكون هذا الدم إشمال و مخفف و لا يعبر عن
+
+857
+01:06:01,090 --> 01:06:06,410
+الدم اللي بيجر في الأوردة تبعتنا فبالتالي أنا لازم
+
+858
+01:06:06,410 --> 01:06:10,350
+أتخلص منه عشانك بعملها wipe away بمسحها أول قطر
+
+859
+01:06:10,350 --> 01:06:15,310
+الدم بتطلعبعدين collect drops of blood into the
+
+860
+01:06:15,310 --> 01:06:18,950
+collection device by gently massaging the finger
+
+861
+01:06:18,950 --> 01:06:25,670
+يعني بستخدم طبعا بيكون في عندي قنابيب مخصصة لجمع
+
+862
+01:06:25,670 --> 01:06:33,620
+الدم من ال skin من الإصبع سواء أو من الكعبو طبعا
+
+863
+01:06:33,620 --> 01:06:40,160
+يا بنات يعني كيف دي أحكيلكم إياها؟ يعني مثلا بصير
+
+864
+01:06:40,160 --> 01:06:44,020
+أنا أعمل مساج خفيف، باجي من بداية الإصبع، من عند
+
+865
+01:06:44,020 --> 01:06:47,720
+.. يعني من أول الإصبع، من عند إيدي، تمام؟ بعمل
+
+866
+01:06:47,720 --> 01:06:52,320
+مساج خفيف خفيف و لما بقصل مكان ال puncture، بضغط
+
+867
+01:06:52,320 --> 01:06:57,270
+ضغطةتمام؟ ففي هذه الحالة أنا بكون عم بعمل gentle
+
+868
+01:06:57,270 --> 01:07:02,710
+massaging عشان أحفظ ال .. ال .. يعني سريان الدم و
+
+869
+01:07:02,710 --> 01:07:06,930
+أنه يطلع معايا دم كافي، إذا عصرت كتير يا بنات الدم
+
+870
+01:07:06,930 --> 01:07:10,530
+هيتجلط و هيسكر الجرح و مش هاخد الدم الكافي، مش
+
+871
+01:07:10,530 --> 01:07:14,980
+لازم ..أنا أعصر الدم، أنا بسيب .. بسيب إيد المريض
+
+872
+01:07:14,980 --> 01:07:19,500
+يعني ب .. و ما ب .. بضغط عليها و مجرد إنه أنا بس
+
+873
+01:07:19,500 --> 01:07:23,780
+من بداية أصبعه بصير أعمل مساج خفيف يعني يده بكون
+
+874
+01:07:23,780 --> 01:07:28,160
+أنا عم بلامس أصبعه و مجرد ما أصل مكان الجرح بكون ب
+
+875
+01:07:28,160 --> 01:07:33,060
+.. بضغط ضغطة بطلع الدم، تمام؟ هذا معناه ال .. ال
+
+876
+01:07:33,060 --> 01:07:37,130
+.. ال gentle massagingavoid excessive pressure
+
+877
+01:07:37,130 --> 01:07:43,070
+ممنوع انا اضغط بالحامي ليش؟ اول سبب حكيتلكم انه
+
+878
+01:07:43,070 --> 01:07:47,390
+ممكن يتوقف الدم تاني سبب ممكن انه انا هيك بكون عم
+
+879
+01:07:47,390 --> 01:07:51,290
+بعصر الخلايا اللي انا عملتلها damage و يصير في
+
+880
+01:07:51,290 --> 01:07:54,370
+عندي squeeze لل tissue fluid يعني يطلع ال tissue
+
+881
+01:07:54,370 --> 01:07:59,630
+fluid يساقل الخلايا او عصارة الخلايا تطلع مع الدم
+
+882
+01:07:59,630 --> 01:08:05,230
+و هيك انا بكون باخد دم مخفف تمام؟طيب بعد ما بسحب
+
+883
+01:08:05,230 --> 01:08:09,470
+الكمية الكافية have the patient hold a small gauze
+
+884
+01:08:09,470 --> 01:08:12,710
+bed over the puncture site for a couple of minutes
+
+885
+01:08:12,710 --> 01:08:18,130
+to stop the bleeding يعني بخلي المريض أنه يحط قطعة
+
+886
+01:08:18,130 --> 01:08:22,210
+من القطن أو الشاشة على أصبعه و يضغط عليها لحتى
+
+887
+01:08:22,210 --> 01:08:26,050
+يتوقف النزيف و بتخلص من الأدوات اللي هي ال
+
+888
+01:08:26,050 --> 01:08:28,550
+contaminated material و ال supplies القطن اللي أنا
+
+889
+01:08:28,550 --> 01:08:32,280
+قمت فيه و القطن اللي مسحت فيه أول قطرةال .. ال
+
+890
+01:08:32,280 --> 01:08:35,600
+Lancet اللي استخدمتها لإحداث ال .. ال نخزة أو
+
+891
+01:08:35,600 --> 01:08:40,780
+الثقوب و هذه كلها الأدوات بتخلص منها properly في
+
+892
+01:08:40,780 --> 01:08:44,720
+ال container الخاص فيها مثلا ال Lancet عبارة عن
+
+893
+01:08:44,720 --> 01:08:48,660
+أداة حادة بستخدم .. باطلفها في ال sharp box القطن
+
+894
+01:08:48,660 --> 01:08:51,880
+ملوث بالدم إذا بحطه في السلة الموجود .. م .. م ..
+
+895
+01:08:51,880 --> 01:08:55,760
+محطوط عليها علامة biohazard القطن المش ملوث بالدم
+
+896
+01:08:55,760 --> 01:09:00,060
+بستخ .. باطلفه في السلة العادية تمام؟الورقة
+
+897
+01:09:00,060 --> 01:09:04,020
+المغلفة لا ال Lancet بتلفها بالورقة العادية بالسلة
+
+898
+01:09:04,020 --> 01:09:09,140
+العادية فبالتالي اذا كل اشي لازم اتخلص منه بال
+
+899
+01:09:09,140 --> 01:09:14,020
+container المناسب ليله بالوعاء المناسب ليله label
+
+900
+01:09:14,020 --> 01:09:18,680
+all appropriated tubes at the patient bedside طبعا
+
+901
+01:09:18,680 --> 01:09:22,680
+لازم انا العينة تبعتي اعمللها labeling وانا
+
+902
+01:09:22,680 --> 01:09:27,750
+نستاتني جنب المريضمش يعني انه خلاص يلا اروح و
+
+903
+01:09:27,750 --> 01:09:30,270
+هاتوا اللي بعده و بعدين بعمل laboring، ما انا
+
+904
+01:09:30,270 --> 01:09:34,930
+بنسأ، تمام؟ او ممكن اخربط، فلأ ما اعتمد على
+
+905
+01:09:34,930 --> 01:09:40,470
+ذاكرتي، افضل ذاكرة هي الذاكرة المكتوبة، تمام؟و
+
+906
+01:09:40,470 --> 01:09:45,070
+أكتب مباشرة المعلومات أعمل labeling للعينة
+
+907
+01:09:45,070 --> 01:09:51,170
+بالمعلومات اللازمة يعني الاسم اسمه الأول و عائلته
+
+908
+01:09:51,170 --> 01:09:55,230
+و ال initial of middle name التاريخ الميلاد ال
+
+909
+01:09:55,230 --> 01:09:59,490
+gender ال .. طبعا مثلا مهم يا بنات كمان أعمل
+
+910
+01:09:59,490 --> 01:10:05,820
+labeling لل genderطبعا مثلا في شخص اسمه ضياء طبعا
+
+911
+01:10:05,820 --> 01:10:09,660
+أنا مش عارفة هو ضياء بنت ولا ولد، تمام؟ لازم يكون
+
+912
+01:10:09,660 --> 01:10:13,580
+يعني يميز ان هو male أو female خصوصا مع الأسماء
+
+913
+01:10:13,580 --> 01:10:17,280
+اللي تصلح لإنه يكون ل male أو female زي ضياء، نور،
+
+914
+01:10:17,280 --> 01:10:21,760
+إسلام زي أشياء .. الأشياء هاد .. الأسماء هادى، مهم
+
+915
+01:10:21,760 --> 01:10:25,100
+إن أنا يعني أو مع كل الأسماء مهم إن أنا أميز ال
+
+916
+01:10:25,100 --> 01:10:28,720
+gender of patientdelivers specimen promptly to the
+
+917
+01:10:28,720 --> 01:10:33,900
+laboratory فورا لازم انا اسلم العينة للمختبر
+
+918
+01:10:33,900 --> 01:10:38,920
+لاجراء الفحوصات اللازمة اذا بحدد الاصبع المراد
+
+919
+01:10:38,920 --> 01:10:43,560
+اجراء skin puncture لاقله تمام لازم يكون التالت او
+
+920
+01:10:43,560 --> 01:10:47,100
+الرابع هي الاول الابهام السبابة التاني هي هنا
+
+921
+01:10:47,100 --> 01:10:51,880
+التالت الوسطىو هي الرابع و الاخير الخامس طبعا هو
+
+922
+01:10:51,880 --> 01:10:57,040
+الوسطى و الخنصر هم اللي باستخدمهم او يعني هو
+
+923
+01:10:57,040 --> 01:11:00,560
+التالت و الرابع يعني رقم تلاتة الوسطى و اللي بعده
+
+924
+01:11:00,560 --> 01:11:05,700
+هدول اللي مناسبين طبعا بحضر الأدوات تبعتي بفتح ال
+
+925
+01:11:05,700 --> 01:11:10,680
+Lancetطبعا و بعقمها يا بنات بعقم المكان بالكحول
+
+926
+01:11:10,680 --> 01:11:13,520
+بفتح ال Lancet تبعتي ال Lancet زي ما انتوا شايفين
+
+927
+01:11:13,520 --> 01:11:18,100
+شفرة مدبّبة الطرف طبعا إلها طرف مدبّب فأنا بفو ..
+
+928
+01:11:18,100 --> 01:11:22,740
+بعمل ضربة بحيث إن هاي الضربة تكون strong, fast,
+
+929
+01:11:23,420 --> 01:11:26,700
+deep and perpendicular الأربع خواص طبيعتها اللي
+
+930
+01:11:26,700 --> 01:11:32,090
+بتيجي أسألكم عليها بالامتحانتمام بعدين بصحى بتخلص
+
+931
+01:11:32,090 --> 01:11:35,450
+من أول قطر الدم بعدين ببدأ من هنا من عند بداية
+
+932
+01:11:35,450 --> 01:11:40,090
+الإصبع بعمل gentle massage المساج خفيف جدا و لما
+
+933
+01:11:40,090 --> 01:11:44,310
+أصل لمنطقة النخزة بضغط ضغطة تمام مجرد ما أضغط ضغطة
+
+934
+01:11:44,310 --> 01:11:48,910
+.. ضغطة تمام بيبدأ تطلع عندي تتشكل قطرة دائرية
+
+935
+01:11:48,910 --> 01:11:53,790
+بجمعها في ال tube المخصص لجمع العينات و بعد هيك
+
+936
+01:11:53,790 --> 01:11:57,270
+ايش بس برسل ال .. بعمل labeling للعينة مباشرة و
+
+937
+01:11:57,270 --> 01:12:01,650
+برسلها للمختبربعطي المريض قطنة او شاشة او قطعة
+
+938
+01:12:01,650 --> 01:12:06,010
+معقمة ان هو يضغط على المكان الجرح لحين التوقف
+
+939
+01:12:06,010 --> 01:12:09,090
+النظيف تمام؟ انت شايفين القطرة كيف .. القطرة كيف
+
+940
+01:12:09,090 --> 01:12:13,290
+اتكون دائرية لإن انا فوتت عمودية على ال ridges
+
+941
+01:12:13,290 --> 01:12:18,490
+تمام؟ و هحكيلكم اش يعني عمودية في داخل المختبر ان
+
+942
+01:12:18,490 --> 01:12:21,670
+شاء الله تمام
+
+943
+01:12:24,170 --> 01:12:29,030
+طيب خلينا بس ال .. ال .. ناخد المناقشة أو الجزء
+
+944
+01:12:29,030 --> 01:12:34,730
+المتعلق بال .. السحب
+
+945
+01:12:34,730 --> 01:12:39,210
+.. العينة الدم من ال skin طبعا يا بنات العينة ال
+
+946
+01:12:39,210 --> 01:12:42,190
+skin puncture أو الدم اللي جاى من ال skin puncture
+
+947
+01:12:42,190 --> 01:12:47,290
+هو مش دم وريدي ولا شرياني هو عبارة عن mix مندم
+
+948
+01:12:47,290 --> 01:12:51,190
+شرياني ووريدي
+
+949
+01:12:51,190 --> 01:12:55,130
+ومن capillary tubes، تمام؟ ويعني حتى كمان من
+
+950
+01:12:55,130 --> 01:12:59,890
+الشعيرات الدموية فبالتالي التركيز داخل هذا الدم
+
+951
+01:12:59,890 --> 01:13:03,590
+بتكون مختلفة مثلا تركيز ال .. ال .. ال analytes أو
+
+952
+01:13:03,590 --> 01:13:07,830
+المواد المرادقية أو ال .. ال .. ال .. الأشياء
+
+953
+01:13:07,830 --> 01:13:11,150
+المرادقياسها سواء كانت أنا بدأ أقيس بروتينات،
+
+954
+01:13:11,150 --> 01:13:15,060
+هرموناتglucose، دهون، أي إشي بدي أقيصه في .. في
+
+955
+01:13:15,060 --> 01:13:19,300
+العينة هذه تمام دي أجري له فحص لازم .. بيكون مختلف
+
+956
+01:13:19,300 --> 01:13:24,380
+طبعا تركيزه داخلها عن تركيزه في الوريد لإنه هذا
+
+957
+01:13:24,380 --> 01:13:28,120
+عبارة عن mixture، مزيج من الدم الوريدي والشرياني
+
+958
+01:13:28,120 --> 01:13:34,500
+وحتى الشعيرات الدموية فبالتالي لذلك لازم أنا أ
+
+959
+01:13:34,500 --> 01:13:41,470
+mention أكتب في ال ..ال report في النتيجة في
+
+960
+01:13:41,470 --> 01:13:46,030
+التقرير اللي بيطلع من المختبر النتيجة احكي انه هذه
+
+961
+01:13:46,030 --> 01:13:52,930
+النتيجة اللي فحص أجري على عينة was obtained from
+
+962
+01:13:52,930 --> 01:13:57,890
+skin puncture تمام؟ اذا تركيز مختلفة بتكون و ال
+
+963
+01:13:57,890 --> 01:14:01,860
+differbetween skin puncture blood and arterial or
+
+964
+01:14:01,860 --> 01:14:05,960
+venous يعني بتركيز مختلفة في هذا الدم اللي جامل ال
+
+965
+01:14:05,960 --> 01:14:09,260
+skin puncture عن التركيز اللي موجودة في الدم
+
+966
+01:14:09,260 --> 01:14:16,120
+الوليدي او الشرياني فبالتاليلازم انه طبعا في .. في
+
+967
+01:14:16,120 --> 01:14:20,340
+ال test report في التقرير should indicate يعني
+
+968
+01:14:20,340 --> 01:14:25,680
+أشير إلى أنه العينة الدم هذه حصلنا عليها من skin
+
+969
+01:14:25,680 --> 01:14:29,060
+puncture عشان الدكتور لما يقيم وضع المريض ياخد
+
+970
+01:14:29,060 --> 01:14:32,520
+بعين الاعتبار أنه العينة هي skin puncture يعني
+
+971
+01:14:32,520 --> 01:14:36,380
+التركيز مختلفة شويةexcessive massaging لو انا بدي
+
+972
+01:14:36,380 --> 01:14:40,640
+اعمل ال massage القوي ايش حكيناه اول حاجة بكون عم
+
+973
+01:14:40,640 --> 01:14:44,020
+بعمل squeeze تعصير ل ال finger او ال foot او اللي
+
+974
+01:14:44,020 --> 01:14:48,080
+هو المكان ل skin puncture فبالتالي بكون بطلع عصارة
+
+975
+01:14:48,080 --> 01:14:51,820
+الخلايا وبالتالي بخفف الدم بيصير عندى diluted
+
+976
+01:14:51,820 --> 01:14:58,050
+bloodأو أحيانا ممكن يسبب تجلط للدم سريع وبالتالي
+
+977
+01:14:58,050 --> 01:15:01,250
+توقف خروج الدم يعني انا مابحصل على ال volume
+
+978
+01:15:01,250 --> 01:15:05,910
+المناسب يا بحصل على الدم مخفف فبالتالي مش لازم انا
+
+979
+01:15:05,910 --> 01:15:09,570
+اعمل excessive massaging لأ gentle massaging
+
+980
+01:15:09,570 --> 01:15:17,870
+وبالتالي انه يعني بيكون هيك مناسب لاستمرارية ضمن
+
+981
+01:15:17,870 --> 01:15:22,130
+استمرارية انه خروج الدم وانه انا بحصل على دم مش
+
+982
+01:15:22,460 --> 01:15:26,380
+المخافة Since deep puncture is not any more
+
+983
+01:15:26,380 --> 01:15:30,400
+painful than superficial puncture it's best to go
+
+984
+01:15:30,400 --> 01:15:34,000
+deep enough the first time thereby avoid
+
+985
+01:15:34,000 --> 01:15:37,560
+puncturing the patient a second time يعني ال deep
+
+986
+01:15:37,560 --> 01:15:41,560
+puncture بتكونش مقليمة زي ال superficial فبالتالي
+
+987
+01:15:41,560 --> 01:15:45,980
+أنا لازم أجوجلبي و أعمل puncture أعمل ضربة قوية و
+
+988
+01:15:45,980 --> 01:15:51,120
+تكون عميقة enoughتمام؟ عشان اتجنب ان انا انخذ
+
+989
+01:15:51,120 --> 01:15:53,700
+المريض مرة تانية لو طلعت superficial بدي ارجع
+
+990
+01:15:53,700 --> 01:15:57,160
+انخذه مرة تانية وهذا non-ethical مش أخلاقي ان انا
+
+991
+01:15:57,160 --> 01:16:01,290
+اضل اجرب المريض يعني انا بكون عم بقلمهexcess
+
+992
+01:16:01,290 --> 01:16:07,110
+crying إذا كان المريض هذا متوتر و يعني ببكي إذا
+
+993
+01:16:07,110 --> 01:16:12,170
+كان خصوصا طفل هذا راح يأثر على نتائج المختبر يعني
+
+994
+01:16:12,170 --> 01:16:15,170
+مثلا ممكن يرفع ال white pieces نتيجة ال stress
+
+995
+01:16:15,170 --> 01:16:18,050
+يعني ممكن ال white blood cell count يكون يصير له
+
+996
+01:16:18,050 --> 01:16:23,830
+increase falsely increase فيعني يزيد و هو زيادة
+
+997
+01:16:23,830 --> 01:16:28,780
+خاطئة يعني إنه بس نتيجة التوترفبالتالي أنا الأفضل
+
+998
+01:16:28,780 --> 01:16:32,940
+أنه هذا المريض أستنى عليه نص ساعة على ساعة بعد ما
+
+999
+01:16:32,940 --> 01:16:37,720
+يخلص يعني موجة البكاء اللي هو فيها أحاول أهدي
+
+1000
+01:16:37,720 --> 01:16:40,140
+أستنى عليه من نص ساعة على ساعة و بعدين أسحب له
+
+1001
+01:16:40,140 --> 01:16:45,240
+العينة طبعا ال thumb وال .. وال .. ال .. يعني
+
+1002
+01:16:45,240 --> 01:16:49,410
+الإصبع الكبيرال .. الإبهام و الإصبع الكبير بالرجل
+
+1003
+01:16:49,410 --> 01:16:53,150
+و ال ear loop اللي هي حلمة ال .. ال .. الأذن أو
+
+1004
+01:16:53,150 --> 01:16:56,910
+يعني طرف .. طرف الأذن مكان ما بنحط ال .. ال ..
+
+1005
+01:16:56,910 --> 01:17:01,230
+الحلق يعني هذا طبعا صعب يا بنات نعمله skin
+
+1006
+01:17:01,230 --> 01:17:05,070
+puncture ممنوع يعني مابستخدمله ما .. يعني مابعمله
+
+1007
+01:17:05,070 --> 01:17:09,050
+skin puncture و ماباخد منه عين الدم يفضل أني مااخد
+
+1008
+01:17:09,050 --> 01:17:12,370
+منه من هذا المكان Misidentification of the patient
+
+1009
+01:17:13,540 --> 01:17:17,080
+إذا أنا ما اتعرفت على المريض بشكل صحيح معناها راح
+
+1010
+01:17:17,080 --> 01:17:22,120
+يصير في عندى طبعا سلسلة من ال error series of
+
+1011
+01:17:22,120 --> 01:17:26,040
+error ما اتعرفت على ال .. ال .. ال مريض بشكل صحيح
+
+1012
+01:17:26,040 --> 01:17:29,500
+إذا أنا سحبت العين الخطأ من المريض الخطأ و حصلت
+
+1013
+01:17:29,500 --> 01:17:33,780
+على نتائج خطأ للمريض فبالتالي ما ده معناه تشخيص
+
+1014
+01:17:33,780 --> 01:17:38,160
+خاطئ إذا علاج خاطئ إذا هذا سل .. كسلسل من ال error
+
+1015
+01:17:38,160 --> 01:17:43,510
+series of error تمام؟طيب هو ممكن يكون وقعها
+
+1016
+01:17:43,510 --> 01:17:48,490
+disastrous او implication of the patient يعني ..
+
+1017
+01:17:48,490 --> 01:17:54,890
+يعني تأثيرها او وقعها caressي على المريض beta
+
+1018
+01:17:54,890 --> 01:17:59,330
+-diene .. beta-diene او iodine طبعا shouldn't be
+
+1019
+01:17:59,330 --> 01:18:02,110
+used routinely to clean the pleptomy area يعني انا
+
+1020
+01:18:02,110 --> 01:18:11,210
+مش لازم اعقم المكان ب .. ب iodine بحلول iodineطبعا
+
+1021
+01:18:11,210 --> 01:18:15,970
+ليش؟ لإنه طبق ال .. ال contamination ب .. يعني ..
+
+1022
+01:18:15,970 --> 01:18:20,410
+ب .. يعني إنه ييجي beta-diene أو iodine على مكان
+
+1023
+01:18:20,410 --> 01:18:26,190
+ال skin puncture ممكن طبعا يلوث العينة يعني لما
+
+1024
+01:18:26,190 --> 01:18:28,950
+أجي أنا أصحب العينة أصحب العينة و فيها بقايا هذا
+
+1025
+01:18:28,950 --> 01:18:33,380
+ال iodine فبالتالي يسببلي some errortest result
+
+1026
+01:18:33,380 --> 01:18:36,780
+يعني مثلا ارتفاع في ال potassium ارتفاع في ال uric
+
+1027
+01:18:36,780 --> 01:18:39,600
+acid ارتفاع في ال phosphorus result مثلا اجي احكم
+
+1028
+01:18:39,600 --> 01:18:42,700
+على المريض مثلا والله عنده uric acid عالي يعني
+
+1029
+01:18:42,700 --> 01:18:46,260
+مثلا عنده مشكلة في مشاكل في وظائف الكدن و وظائف
+
+1030
+01:18:46,260 --> 01:18:50,240
+الكلة ابدأ اوجه المريض ان هو مثلا ممكن يكون عنده
+
+1031
+01:18:50,240 --> 01:18:54,040
+مشاكل في الكلة او kidney failure او كذامصيبة تمام؟
+
+1032
+01:18:54,040 --> 01:18:58,560
+نتيجة خلط بسيط في جمع العينة ممكن يعني ي .. اوجه
+
+1033
+01:18:58,560 --> 01:19:01,700
+المريض او يعني ان انا يصير في تشخيص خاطئ للمريض
+
+1034
+01:19:01,700 --> 01:19:05,880
+وبالتالي يعني اعرضه لإن هو يتعرض لأدوية او علاجات
+
+1035
+01:19:05,880 --> 01:19:10,040
+ممكن تكون خاطرة عليه skin must be dried لازم انه
+
+1036
+01:19:10,040 --> 01:19:13,220
+انا لما اجي اسحب من العينة .. اسحب عينة من المكان
+
+1037
+01:19:15,150 --> 01:19:18,910
+سواء كان ال .. ال .. الإصبع أو ال heel لازم يكون
+
+1038
+01:19:18,910 --> 01:19:23,110
+جاف تماما، يعني بقايا الكحول اتبخرت أو إن أنا إذا
+
+1039
+01:19:23,110 --> 01:19:26,950
+كان استخدمت .. يعني أنا أقامت بكحول كتير أستخدم ال
+
+1040
+01:19:26,950 --> 01:19:31,750
+.. ال .. جوز، يعني شاش أو قطن معقم حتى أمسح بقايا
+
+1041
+01:19:31,750 --> 01:19:36,110
+هذا الكحولليش؟ لإنه مجرد يا بنات ما أنا أجى أنخذه
+
+1042
+01:19:36,110 --> 01:19:40,130
+يطلع الدم .. يطلع الدم .. التقاء الدم مع الكحول
+
+1043
+01:19:40,130 --> 01:19:44,790
+هيصير في عندي hemolysis of blood، هيتكسر الدم بفعل
+
+1044
+01:19:44,790 --> 01:19:48,460
+التقاء أو ال mixing تبعه مع الكحولهيصير فيه
+
+1045
+01:19:48,460 --> 01:19:54,920
+homolysis يعني تكسر للدم، تمام؟ هذا طبعا خطأ يعني،
+
+1046
+01:19:54,920 --> 01:19:58,780
+فإذا أنا حصلت على دم متكسر، خلايا الدم متكسرت
+
+1047
+01:19:58,780 --> 01:20:01,520
+فبالتالي أنا مش راح أقدر أعدها، في حصات كتير مش
+
+1048
+01:20:01,520 --> 01:20:06,490
+راح أقدر أجريها على ال homolized blood، تمام؟طيب
+
+1049
+01:20:06,490 --> 01:20:12,330
+لو أنا خلّيت .. طبعا استخدمت كحولي كتير و خلّيته
+
+1050
+01:20:12,330 --> 01:20:15,670
+فترة .. استنيت عليه فترة لما يجف .. إيش معا .. إيش
+
+1051
+01:20:15,670 --> 01:20:21,750
+رح يصير؟ طبعا يا بنات الكحول لما بيتبخر و بيتطير
+
+1052
+01:20:21,750 --> 01:20:26,470
+بيصير معاه .. يعني بيسحب معاه سائل، ماء، بيسحب
+
+1053
+01:20:26,470 --> 01:20:29,730
+معاه ماء، يعني انت ..حاليا حط الكحول على إيديك و
+
+1054
+01:20:29,730 --> 01:20:33,770
+السبيل يتبخر، بتحسي ببرودة، البرودة هذه ناتجي
+
+1055
+01:20:33,770 --> 01:20:36,710
+نتيجة تبخر الماء اللي موجود في خلايانا أو بين
+
+1056
+01:20:36,710 --> 01:20:41,470
+الخلايا و بعديها بتحسي بجفاف للبشرة، تمام؟ طيب،
+
+1057
+01:20:41,470 --> 01:20:46,210
+إذا أنا حطيت كحول كتير على مكان السحب و إستنيت
+
+1058
+01:20:46,210 --> 01:20:50,930
+لبين ميط طايرمعناها هيتبخر الماء من الموجود ما بين
+
+1059
+01:20:50,930 --> 01:20:54,990
+الخلايا أو الموجود في .. حتى ممكن يكون موجود في ال
+
+1060
+01:20:54,990 --> 01:20:57,670
+capillary في الأوعية الدموية الضيقة أو الصغيرة
+
+1061
+01:20:57,670 --> 01:21:01,870
+اللي موجودة في المكان فبالتالي راح يتركز الدم راح
+
+1062
+01:21:01,870 --> 01:21:04,390
+يصير في عندي حاجة اسمها hemoconcentration طالما
+
+1063
+01:21:04,390 --> 01:21:10,310
+أنه صار في عندي فقدلأس .. ل .. ل .. للماء و الدم
+
+1064
+01:21:10,310 --> 01:21:14,850
+أصلا مكوناته ماء مش احنا حكينا لبلازمة 90% منها
+
+1065
+01:21:14,850 --> 01:21:19,050
+ماء تمام و الخلايا معلقة فيها لذا المدام صار فيه
+
+1066
+01:21:19,050 --> 01:21:22,970
+تبخر معناه فقدار للماء لذا التركيز للدم لذا في
+
+1067
+01:21:22,970 --> 01:21:25,770
+عندي حاجة اسمها hemoconcentration إذا بدي أفحص
+
+1068
+01:21:25,770 --> 01:21:28,930
+مكونات الدم كلشي هلاجيه عالي ال vitaminات ال
+
+1069
+01:21:28,930 --> 01:21:32,230
+enzymes ال proteinات ال .. ال waste ال hormoneات
+
+1070
+01:21:32,230 --> 01:21:35,640
+كلشي عاليفبالتالي هنا بيكون بقى أنا ببدأ أحكم على
+
+1071
+01:21:35,640 --> 01:21:38,540
+المريض أن هو عنده مشاكل و هو لأ يعني المشكلة مني
+
+1072
+01:21:38,540 --> 01:21:43,900
+أنا أثناء السحب فلازم أنتبه لهذه النقطة و يعني
+
+1073
+01:21:43,900 --> 01:21:47,900
+خطوات و تعليمات اللي احنا بنحكيها يعني السحب يا
+
+1074
+01:21:47,900 --> 01:21:54,800
+بنات عبارة عن يعني لحظي في مجرد يعني دقيقة دقيقتين
+
+1075
+01:21:54,800 --> 01:21:59,770
+بتكون انت خلاص يعني خلصتي عملية السحبلكن التعليمات
+
+1076
+01:21:59,770 --> 01:22:04,470
+اللي أثناء السحب و ما قبل السحب و ما بعد السحب هي
+
+1077
+01:22:04,470 --> 01:22:08,190
+اللي مهمة عشان أنا أحصل على ال proper sample،
+
+1078
+01:22:08,190 --> 01:22:15,210
+العينة المثلة، تمام؟ طيبرح أتوقف لهنا بالتسجيل
+
+1079
+01:22:15,210 --> 01:22:18,330
+لعند ال van puncture و ان شاء الله رح أسجل ال van
+
+1080
+01:22:18,330 --> 01:22:23,850
+puncture بتسجيل جديد يعني سحب العينة من وريد علشان
+
+1081
+01:22:23,850 --> 01:22:29,770
+يكون الحجم التسجيل مناسب و أيضا يعني بإمكانكم انكم
+
+1082
+01:22:29,770 --> 01:22:32,470
+انتوا تتعاملوا معاه يعني انا مايكونش في عندنا
+
+1083
+01:22:32,470 --> 01:22:35,110
+مشاكل في رفعه على ال drive او على يوتيوب او
+
+1084
+01:22:35,110 --> 01:22:39,120
+whateverيعطيكم العافية، اقراكم ان شاء الله في ال
+
+1085
+01:22:39,120 --> 01:22:44,460
+part two of blood collection اللي بيتحدث عن ال van
+
+1086
+01:22:44,460 --> 01:22:44,980
+puncture
+
diff --git a/PL9fwy3NUQKwY9jl8xw-bWkVZkWcGGyspd/C6AH0Ptcsrk_raw.json b/PL9fwy3NUQKwY9jl8xw-bWkVZkWcGGyspd/C6AH0Ptcsrk_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..ac01db428d90b99624f32e238df0887bff07fdcc
--- /dev/null
+++ b/PL9fwy3NUQKwY9jl8xw-bWkVZkWcGGyspd/C6AH0Ptcsrk_raw.json
@@ -0,0 +1 @@
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"no_speech_prob": 0.00033020973205566406, "words": [{"start": 5.48, "end": 5.96, "word": "السلام", "probability": 0.9207356770833334}, {"start": 5.96, "end": 6.34, "word": " عليكم", "probability": 0.9375}, {"start": 6.34, "end": 6.7, "word": " ورحمة", "probability": 0.9505615234375}, {"start": 6.7, "end": 6.88, "word": " الله", "probability": 0.96826171875}, {"start": 6.88, "end": 7.58, "word": " وبركاته", "probability": 0.98798828125}, {"start": 7.58, "end": 8.86, "word": " نستكمل", "probability": 0.9156494140625}, {"start": 8.86, "end": 9.0, "word": " مع", "probability": 0.916015625}, {"start": 9.0, "end": 9.32, "word": " بعض", "probability": 0.99267578125}, {"start": 9.32, "end": 9.46, "word": " ان", "probability": 0.55615234375}, {"start": 9.46, "end": 9.58, "word": " شاء", "probability": 0.98876953125}, {"start": 9.58, "end": 9.76, "word": " الله", "probability": 0.9443359375}, {"start": 9.76, "end": 10.18, "word": " الجزء", "probability": 0.82763671875}, {"start": 10.18, "end": 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32674, "start": 302.6, "end": 326.74, "text": "alcohol wipes طبعا لازم يكون في عندي قطن مغموس بالالكهول 70% ايزوبربانول او 70% ايثانول gauze sponge طبعا لازم يكون في عندي قطن مثلا او شاش ادهيسف باندش حكاية لازم يكون في عندي لاسق تمام بلاستر و لازم يكون في عندي gloves", "tokens": [304, 7210, 41228, 23032, 3555, 3615, 995, 5296, 31377, 2304, 7251, 30544, 8978, 18871, 16254, 12174, 9566, 1863, 3714, 17082, 2304, 41779, 20666, 6027, 4117, 3224, 12610, 5285, 4, 1975, 1829, 11622, 2407, 26890, 3555, 7649, 12610, 1975, 2407, 5285, 4, 1975, 1829, 12984, 7649, 12610, 5959, 84, 1381, 23134, 23032, 3555, 3615, 995, 5296, 31377, 2304, 7251, 30544, 8978, 18871, 16254, 12174, 9566, 1863, 50113, 15040, 1975, 2407, 13412, 33599, 1975, 3215, 3224, 1829, 3794, 5172, 4724, 7649, 3215, 8592, 11331, 4117, 995, 10632, 5296, 31377, 2304, 7251, 30544, 8978, 18871, 16254, 20193, 3794, 4587, 46811, 10943, 4724, 15040, 14851, 2288, 4032, 5296, 31377, 2304, 7251, 30544, 8978, 18871, 16254, 14976], "avg_logprob": 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رفيع", "probability": 0.9171549479166666}, {"start": 383.1, "end": 383.72, "word": " The", "probability": 0.211669921875}, {"start": 383.72, "end": 384.08, "word": " most", "probability": 0.916015625}, {"start": 384.08, "end": 384.46, "word": " commonly", "probability": 0.8544921875}, {"start": 384.46, "end": 384.88, "word": " used", "probability": 0.9130859375}, {"start": 384.88, "end": 385.4, "word": " needle", "probability": 0.9013671875}, {"start": 385.4, "end": 385.96, "word": " طبعا", "probability": 0.968994140625}, {"start": 385.96, "end": 386.78, "word": " ال", "probability": 0.90673828125}, {"start": 386.78, "end": 387.18, "word": " needle", "probability": 0.9951171875}, {"start": 387.18, "end": 388.7, "word": " يعبر", "probability": 0.6783447265625}, {"start": 388.7, "end": 389.0, "word": " عن", "probability": 0.99462890625}, {"start": 389.0, "end": 389.72, "word": " قطرها", "probability": 0.9166259765625}, {"start": 389.72, "end": 389.96, "word": " أو", "probability": 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ب number اسمه gauge number، تمام؟ gauge number و أيضا كمان طبعا بيعبر أيضا على .. عن طولها، يعني كمان ال gauge number فهلأ ال .. زي ما انتوا شايفين ال gauge number عشرين، واحد و عشرين، اتنين و عشرين، تمام؟ هدولة ال most commonly used", "tokens": [21292, 3615, 26890, 4724, 1230, 24525, 2304, 3224, 17924, 1230, 12399, 46811, 10943, 22807, 17924, 1230, 4032, 36632, 11242, 995, 9122, 2304, 7649, 23032, 3555, 3615, 995, 4724, 40228, 26890, 36632, 11242, 995, 15844, 4386, 18871, 23032, 12610, 11296, 12399, 37495, 22653, 9122, 2304, 7649, 2423, 17924, 1230, 6156, 3224, 1211, 10721, 2423, 4386, 30767, 1829, 19446, 16472, 2655, 14407, 13412, 995, 33911, 9957, 2423, 17924, 1230, 6225, 46309, 9957, 12399, 36764, 24401, 4032, 6225, 46309, 9957, 12399, 1975, 2655, 1863, 9957, 4032, 6225, 46309, 9957, 12399, 46811, 10943, 22807, 8032, 3215, 12610, 3660, 2423, 881, 12719, 1143], "avg_logprob": -0.15261994678564747, "compression_ratio": 1.81, "no_speech_prob": 5.364418029785156e-07, "words": 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"word": " فهلأ", "probability": 0.8995361328125}, {"start": 411.11, "end": 412.05, "word": " ال", "probability": 0.78466796875}, {"start": 412.05, "end": 412.25, "word": " ..", "probability": 0.9853515625}, {"start": 412.25, "end": 412.63, "word": " زي", "probability": 0.967529296875}, {"start": 412.63, "end": 412.71, "word": " ما", "probability": 0.970703125}, {"start": 412.71, "end": 412.89, "word": " انتوا", "probability": 0.7926432291666666}, {"start": 412.89, "end": 413.37, "word": " شايفين", "probability": 0.992431640625}, {"start": 413.37, "end": 413.93, "word": " ال", "probability": 0.78125}, {"start": 413.93, "end": 414.15, "word": " gauge", "probability": 0.9677734375}, {"start": 414.15, "end": 414.53, "word": " number", "probability": 0.97021484375}, {"start": 414.53, "end": 415.57, "word": " عشرين،", "probability": 0.87158203125}, {"start": 415.57, "end": 415.79, "word": " واحد", "probability": 0.91552734375}, {"start": 415.79, "end": 415.87, "word": " و", "probability": 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\ No newline at end of file
diff --git a/PL9fwy3NUQKwY9jl8xw-bWkVZkWcGGyspd/DG-2O71i3Fw_raw.srt b/PL9fwy3NUQKwY9jl8xw-bWkVZkWcGGyspd/DG-2O71i3Fw_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..113043c13bed0fc9916e1b970a05a5b9f9b89279
--- /dev/null
+++ b/PL9fwy3NUQKwY9jl8xw-bWkVZkWcGGyspd/DG-2O71i3Fw_raw.srt
@@ -0,0 +1,3016 @@
+1
+00:00:09,950 --> 00:00:13,210
+السلام عليكم ورحمة الله وبركاته طالبات العزيزات
+
+2
+00:00:13,210 --> 00:00:17,230
+اليوم ان شاء الله راح نشرح محاضرة بعنوان white
+
+3
+00:00:17,230 --> 00:00:21,530
+blood cell count في نهاية هذه المحاضرة راح نكون
+
+4
+00:00:21,530 --> 00:00:26,370
+بنعرف كيف احنا بنعد خلايا الدم البيضاء بطريقة
+
+5
+00:00:26,370 --> 00:00:31,670
+manual بطريقة يدوية وكيف بنحصل على عدد خلايا الدم
+
+6
+00:00:31,670 --> 00:00:35,230
+البيضاء as a total اذا white blood cell count
+
+7
+00:00:35,230 --> 00:00:40,330
+معناها عد خلايا الدم البيضاءفي البداية خلونا نحكي
+
+8
+00:00:40,330 --> 00:00:44,090
+كتقديم بسيط عن ال white blood cells و ال
+
+9
+00:00:44,090 --> 00:00:48,110
+characteristic لإلها، خصائص هذه الخلايا بيحكيلي
+
+10
+00:00:48,110 --> 00:00:53,530
+whenever a germ or infection enter the body the
+
+11
+00:00:53,530 --> 00:00:57,450
+white blood cell have a variety of ways by which
+
+12
+00:00:57,450 --> 00:01:03,950
+they can attack إذا كان في عندي germ، جراثيم أو
+
+13
+00:01:03,950 --> 00:01:09,850
+عدوى مسبب لعدوى أو حتى أجسام غريبةدخلت إلى جسم
+
+14
+00:01:09,850 --> 00:01:14,610
+الإنسان، تمام؟ فال white blood cells عندها variety
+
+15
+00:01:14,610 --> 00:01:19,690
+of ways، أطرق متنوعة لتهاجم بها هذا الجسم الغريب
+
+16
+00:01:19,690 --> 00:01:24,230
+أو هذا الكائن الغريب اللي غزى جسم الإنسان أو دخل
+
+17
+00:01:24,230 --> 00:01:29,790
+إليهSome will produce protective antibodies، بعض
+
+18
+00:01:29,790 --> 00:01:33,750
+هذه الخلايا، بعض أنواع من ال white species ممكن
+
+19
+00:01:33,750 --> 00:01:39,750
+إنها تنتج antibodies تمام؟ أجسام مضادة لحتى تحارث
+
+20
+00:01:39,750 --> 00:01:44,050
+فيها هذه الكائنات الغريبة أو الأجسام الغريبةthat
+
+21
+00:01:44,050 --> 00:01:47,910
+will overpower the germ تتغلب فيها من خلال ال
+
+22
+00:01:47,910 --> 00:01:53,010
+antibodies تتغلب على الكائنات الدقيقة أو
+
+23
+00:01:53,010 --> 00:01:57,350
+الميكروبات أو الأجسام الغريبة اللي غزت الجسم أو
+
+24
+00:01:57,350 --> 00:02:02,050
+دخلت إلى الجسمother will surround and devour the
+
+25
+00:02:02,050 --> 00:02:07,110
+bacteria أنواع أخرى من هذه الخلايا ممكن أن تحيط
+
+26
+00:02:07,110 --> 00:02:13,890
+بالكائنات الدقيقة و تغزوها أو يعني تلتهمها أو
+
+27
+00:02:13,890 --> 00:02:20,130
+تقتلها تمام؟ the white blood cellhave a rather
+
+28
+00:02:20,130 --> 00:02:28,270
+short life cycle بنظر إلى ال RBCs حكينا إنه فترة
+
+29
+00:02:28,270 --> 00:02:33,290
+حياتها 120 يوم تمام ال white blood cell بالمقارنة
+
+30
+00:02:33,290 --> 00:02:37,610
+عندها short life cycleحياتها أو فترة حياتها قصيرة
+
+31
+00:02:37,610 --> 00:02:42,050
+من few days ل few weeks من أيام قليلة إلى أسابيع
+
+32
+00:02:42,050 --> 00:02:47,770
+قليلة، تمام؟ إذا ال RBC بتعيش مائة و عشرين يوم ال
+
+33
+00:02:47,770 --> 00:02:52,030
+white BC من few days ل few weeks البلاتلت بتعيش
+
+34
+00:02:52,030 --> 00:02:57,940
+عشر أيام تقريبافإذا كل خلية إلها life span أو life
+
+35
+00:02:57,940 --> 00:03:03,000
+cycle يعني فترة حياة هي بتعيش فيها فال white
+
+36
+00:03:03,000 --> 00:03:06,080
+species بتعتبر فترة حياتها قصيرة يعني لإنها
+
+37
+00:03:06,080 --> 00:03:12,760
+باستمرار بتقابل مثلا خلايا متوفة يعني dead cells
+
+38
+00:03:12,760 --> 00:03:20,430
+أجسام غريبة كائنات غريبة بقايا T-Shirtيعني waste
+
+39
+00:03:20,430 --> 00:03:24,330
+أحيانا كل هاي الشغلات بتكون بتخلصنا منها داخل جسم
+
+40
+00:03:24,330 --> 00:03:30,410
+الإنسان ف .. لذلك هي فترة حياتها قصيرة نوع عامة
+
+41
+00:03:30,410 --> 00:03:34,650
+several different and diverse types of leukocyte
+
+42
+00:03:34,650 --> 00:03:40,530
+exist احنا ذكرنا في محاضرة ال blood component أنه
+
+43
+00:03:40,530 --> 00:03:46,490
+أنا في عندي أنواع من خلايا الدم البيضاءحكينا إنه
+
+44
+00:03:46,490 --> 00:03:52,930
+في عندي خلايا بسميها محببة تمام granulocyte وماذا
+
+45
+00:03:52,930 --> 00:03:57,610
+يعني محببة أو granulocyte؟ هي الخلايا اللي يوجد في
+
+46
+00:03:57,610 --> 00:04:02,270
+الcytoplasm تبعها حبيبات تمام؟ هاي الحبيبات طبعا
+
+47
+00:04:02,270 --> 00:04:06,830
+بيكون فيها انزيمات هاضمة وانزيمات قاتلة و السلاح
+
+48
+00:04:06,830 --> 00:04:14,270
+تبعها هذا ال store مخزن السلاح لخلايا الدم المحببة
+
+49
+00:04:14,270 --> 00:04:20,590
+تمام؟في عندي خلايا غير محببة، تمام؟ و هاي الخلايا
+
+50
+00:04:20,590 --> 00:04:24,270
+غير المحببة اللي احنا بنسميها A-granulocyte و
+
+51
+00:04:24,270 --> 00:04:28,950
+حكينا إضافة ال A في بداية الكلمة للنفي، تمام؟ A
+
+52
+00:04:28,950 --> 00:04:33,330
+-granulocyte يعني لا تحتوي على حبيبات و حكينا إنها
+
+53
+00:04:33,330 --> 00:04:37,200
+هي ال monocyte و ال lymphocyteهلأ رح نذكرهم و
+
+54
+00:04:37,200 --> 00:04:41,460
+نستعرضهم مع بعض مرة تانية ولكن خلونا بس نكمل
+
+55
+00:04:41,460 --> 00:04:45,180
+بحكيلي انه هذه الخلايا صح أنا في عندى different
+
+56
+00:04:45,180 --> 00:04:49,260
+and diverse types of leukocytes صح هي متنوعة و
+
+57
+00:04:49,260 --> 00:04:57,530
+عديدة تمام ولكن they are all كلهمproduced and
+
+58
+00:04:57,530 --> 00:05:03,110
+derived تم إنتاجهم أو يعني مشتقين من multi-potent
+
+59
+00:05:03,110 --> 00:05:06,890
+stem cell من نفس الخلية الأم اللي بنسميها
+
+60
+00:05:06,890 --> 00:05:11,450
+hematobiotic stem cell موجودة في البومارو طيب نذكر
+
+61
+00:05:11,450 --> 00:05:15,890
+مع بعض أو نستعرض مع بعض هذه الصورة اللي بتوضح
+
+62
+00:05:15,890 --> 00:05:22,770
+خلايا الدم كلها بشكل كامل وهي من وين جاية او من
+
+63
+00:05:22,770 --> 00:05:26,870
+وين تم اشتقاقهافي عندي احنا طبعا احنا حكينا انه
+
+64
+00:05:26,870 --> 00:05:30,830
+يتم تصنيع خلايا الدم في ال bone marrow في نخاع
+
+65
+00:05:30,830 --> 00:05:36,810
+العضم بيكون في عندي hematobiotic stem cell نجرب
+
+66
+00:05:36,810 --> 00:05:42,460
+نكبر الصورةHematobiotic Stem Cell اللي هي عبارة عن
+
+67
+00:05:42,460 --> 00:05:45,980
+Multipotential Stem Cell خلية جدعية ممكن تعطيني
+
+68
+00:05:45,980 --> 00:05:50,920
+عدد معين من الخلايا يعني ممكن إنها تتميز إلى عدد
+
+69
+00:05:50,920 --> 00:05:57,820
+معين من الخلايا فهي بصراحة لما بتنقسم تعطيني two
+
+70
+00:05:57,820 --> 00:06:04,080
+mother cells خليتين أم واحدة اسمها Myeloidmyeloid
+
+71
+00:06:04,080 --> 00:06:08,120
+progenitor cells myeloid تمام و الخلية الأم
+
+72
+00:06:08,120 --> 00:06:13,140
+التانية اسمها lymphoid طيب ال .. الخلية ال .. ال
+
+73
+00:06:13,140 --> 00:06:17,860
+myeloid هاي لما بدها تنقسم و تتميز ايضا في عندها
+
+74
+00:06:17,860 --> 00:06:22,280
+بعض خصائص الاستمثال فهي بتنقسم و تتميز لمين؟ ل
+
+75
+00:06:22,280 --> 00:06:28,280
+Xenophilو Bezophil و Neutrophil اللى هى الخلايا
+
+76
+00:06:28,280 --> 00:06:32,460
+الى granulocyte المحددة ممكن تعطينى ايضا monocyte
+
+77
+00:06:32,460 --> 00:06:35,960
+و تعطينى erythrocyte اللى هى ال RBCs و Blatulate
+
+78
+00:06:35,960 --> 00:06:38,980
+هدول كلهم مشتقين من نفس الخلية الأم اللى هى
+
+79
+00:06:38,980 --> 00:06:43,600
+الmyeloidطبعا ال lymphoid ايش هتعطيني؟ ال lymphoid
+
+80
+00:06:43,600 --> 00:06:48,620
+بتعطيني ال T cells lymphocyte و B cell lymphocyte
+
+81
+00:06:48,620 --> 00:06:52,920
+و natural killer lymphocyte و dendritic cell يعني
+
+82
+00:06:52,920 --> 00:06:56,080
+فى النهاية هى بتعطينى lymphocyte لحالها بأنواعها
+
+83
+00:06:56,080 --> 00:06:59,860
+طبعا lymphoid lymphocyte myeloid بتعطينى ال
+
+84
+00:06:59,860 --> 00:07:02,960
+granulocyte اللى هم ال xenophil, bezophil و
+
+85
+00:07:02,960 --> 00:07:07,780
+neutrophil بالاضافة ل RBCs و monocyte و black lead
+
+86
+00:07:07,780 --> 00:07:13,160
+طبعاطيب، بغض النظر احنا اليوم عنوان محاضرتنا اللي
+
+87
+00:07:13,160 --> 00:07:16,100
+هو ال white pieces count يعني أنا معنية في مين؟
+
+88
+00:07:16,100 --> 00:07:18,980
+معنية في ال granulocyte اللي هم ال xenophil و
+
+89
+00:07:18,980 --> 00:07:23,600
+bezophil و neutrophil و معنية في ال agranulocyte
+
+90
+00:07:23,600 --> 00:07:29,330
+اللي هي monocyte و lymphocyte، تمام؟طيب حكينا إن
+
+91
+00:07:29,330 --> 00:07:34,630
+هم مشتقين من مين؟ من خلية واحدة بالاصل اللي هي ال
+
+92
+00:07:34,630 --> 00:07:38,070
+hematobiotic stem cell حكينا بنسميها multi
+
+93
+00:07:38,070 --> 00:07:40,450
+potential stem cell إيش يعني multi potential؟ يعني
+
+94
+00:07:40,450 --> 00:07:43,790
+خلايا .. خلية جدعية يمكنها أن تتميز وتعطيني عدد
+
+95
+00:07:43,790 --> 00:07:54,070
+معين من الخلايا تمام؟
+
+96
+00:07:58,070 --> 00:08:01,330
+leukocytes are found throughout the body موجودة في
+
+97
+00:08:01,330 --> 00:08:04,850
+جسم الإنسان موجودة في ال blood في ال lymphatic
+
+98
+00:08:04,850 --> 00:08:09,690
+system في .. موجودة أحيانا في ال tissues يعني في
+
+99
+00:08:09,690 --> 00:08:13,970
+في الكبد خلايا lymph .. white species خاصة فيه
+
+100
+00:08:13,970 --> 00:08:18,250
+يعني to haggle أي كائن ممكن يخزق الكبد في في ال
+
+101
+00:08:18,250 --> 00:08:22,730
+spleen في في ال intestine يعني وين الأعضاء اللي
+
+102
+00:08:22,730 --> 00:08:26,990
+موجودة ممكن أن تتعرض إلى infectionموجود فيها خلايا
+
+103
+00:08:26,990 --> 00:08:30,970
+مثبتة من الـ leukocyte بالإضافة إلى إنه أيضًا كمان
+
+104
+00:08:30,970 --> 00:08:35,010
+الـ leukocyte ليه ال white disease يعني ممكن تكون
+
+105
+00:08:35,010 --> 00:08:39,110
+بتوجد بال circulation في الدم في مسار الدم في
+
+106
+00:08:39,110 --> 00:08:42,390
+الدورة الدموية و أيضًا في ال lymphatic system
+
+107
+00:08:43,370 --> 00:08:48,550
+بالجهاز اللينفاوي the name white blood cell من وين
+
+108
+00:08:48,550 --> 00:08:51,690
+اجا؟ ليش صميناها احنا white blood cell؟ هل فعلا هي
+
+109
+00:08:51,690 --> 00:08:56,670
+اسمها او لونها white لحتى صميناها white؟ بحكيلي
+
+110
+00:08:56,670 --> 00:09:02,530
+فعليا تم اشتقاق الاسم هذا لانه from the fact that
+
+111
+00:09:02,530 --> 00:09:05,930
+after centrifugation of a blood sample the white
+
+112
+00:09:05,930 --> 00:09:09,700
+blood cell are found in the puffy coatتم اشتقاق
+
+113
+00:09:09,700 --> 00:09:12,700
+اسم ال white blood cell لإنه لما احنا بنعمل
+
+114
+00:09:12,700 --> 00:09:16,680
+centrifugation نفس العين الدم على ال centrifuge ال
+
+115
+00:09:16,680 --> 00:09:19,240
+white blood cell بتكون موجودة في طبقة ال buffy
+
+116
+00:09:19,240 --> 00:09:24,460
+coat اللي هي أصلا لونها أبيض فعليا ال white blood
+
+117
+00:09:24,460 --> 00:09:29,020
+cell هي خلايا colorless مش ملونة تمام؟ ولكن نظرا
+
+118
+00:09:29,020 --> 00:09:33,240
+لإنه هي موجودة في منطقة ال buffy coat اللي تتاخذ
+
+119
+00:09:33,240 --> 00:09:41,000
+اللون الأبيض تمام؟فبنسميها احنا white blood cellو
+
+120
+00:09:41,000 --> 00:09:46,500
+.. احنا هذا .. هنا بيشرحلي انه لما احنا بنفصل عينة
+
+121
+00:09:46,500 --> 00:09:50,300
+الدم على ال centrifuge بيكون في عندي ال buffy coat
+
+122
+00:09:50,300 --> 00:09:53,500
+اللي هو عبارة عن thin layer of the nucleated cell
+
+123
+00:09:53,500 --> 00:09:57,780
+تمام؟ موجود between the sedimented red blood cell
+
+124
+00:09:57,780 --> 00:10:01,400
+وبتوين البلازمة موجود بين ال RBCs و البلازمة وهذا
+
+125
+00:10:01,400 --> 00:10:06,060
+ممكن يجيني تعريف في الأسئلة ماذا .. يعني انه لما
+
+126
+00:10:06,060 --> 00:10:09,380
+أجي أحكيلك the thin layer of the nucleated cell
+
+127
+00:10:10,010 --> 00:10:14,370
+that found between the RBCs layer and the plasma
+
+128
+00:10:14,370 --> 00:10:18,150
+layer اللي بتحكيلي هي ال buffet code وممكن أسألك
+
+129
+00:10:18,150 --> 00:10:20,610
+ماذا يحتوي ال buffet code اللي بتحكيلي يحتوي على
+
+130
+00:10:20,610 --> 00:10:26,410
+white pieces وplatelet طبعا طيبال .. ال white bc's
+
+131
+00:10:26,410 --> 00:10:30,410
+لها اسم تاني اللي هي lycosides ماذا تعني
+
+132
+00:10:30,410 --> 00:10:34,870
+lycosides؟ lycosides هي كلمة يونانية، تمام؟ و
+
+133
+00:10:34,870 --> 00:10:39,990
+معناها ال white cells lyco white معناها و site
+
+134
+00:10:39,990 --> 00:10:44,650
+يعني cells زي فكرة ال rbc's بنسميها erythrocyte و
+
+135
+00:10:44,650 --> 00:10:48,430
+أيضا هي كلمة يونانية ال erythro معناها red و ال
+
+136
+00:10:48,430 --> 00:10:54,740
+site معناها cell، تمام؟طيب مبدأ اعد خلايا الدم
+
+137
+00:10:54,740 --> 00:10:58,320
+البيضاء كيف احنا بنعد خلايا الدم البيضاء؟ في
+
+138
+00:10:58,320 --> 00:11:03,040
+البداية في عندي free-flowing capillary او ممكن
+
+139
+00:11:03,040 --> 00:11:06,040
+استخدم well-mixed anticoagulated venous blood
+
+140
+00:11:08,000 --> 00:11:11,740
+بستخدم يعني باخد حجم معين من الدم و يكون في عندي
+
+141
+00:11:11,740 --> 00:11:15,640
+محلول daily you want انا بخلطه مع هذا الدم بحيث
+
+142
+00:11:15,640 --> 00:11:21,040
+انه هذا المحلول يخلصني من ال RBCs و يحفظلي ال YBCs
+
+143
+00:11:21,040 --> 00:11:25,820
+علشان انا اتمكن من عدهاباستخدام شريحة معينة مخصصة
+
+144
+00:11:25,820 --> 00:11:30,720
+للعد انا بحط السائل او المحلول اللي انا حضرته اللي
+
+145
+00:11:30,720 --> 00:11:34,700
+هو عبارة عن الدم ال diligent بحطه على هذه الشريحة
+
+146
+00:11:34,700 --> 00:11:39,760
+و ببدأ اعد على ال microscope تمام؟ هذه هي الفكرة
+
+147
+00:11:39,760 --> 00:11:43,560
+ببساطة خلينا نتعمق فيها اكتر و نشوف ايش تفاصيلها
+
+148
+00:11:43,560 --> 00:11:47,890
+العلميةfree-flowing capillary or well-mixed
+
+149
+00:11:47,890 --> 00:11:51,730
+anticoagulated venous blood is added to a specific
+
+150
+00:11:51,730 --> 00:11:56,390
+volume of the diluent in the thermopiped طبعا احنا
+
+151
+00:11:56,390 --> 00:12:00,970
+ممكن انا استخدم عينة من الوريد تمام و احطها في
+
+152
+00:12:00,970 --> 00:12:05,110
+tube إدتة يعني عليها anticoagulant تمام و تصير هذه
+
+153
+00:12:05,110 --> 00:12:08,930
+العينة اسمها well-mixed anticoagulated venous
+
+154
+00:12:08,930 --> 00:12:09,370
+blood
+
+155
+00:12:14,850 --> 00:12:17,990
+فى tube editor لإنه احنا لما بنسحب عين تدام فى ال
+
+156
+00:12:17,990 --> 00:12:22,370
+editor انا بحكيلكم اعمله good mixing تمام بنعمل
+
+157
+00:12:22,370 --> 00:12:29,290
+good mixing و بعد هيك طبعا انا حكينا انه هذا ال
+
+158
+00:12:29,290 --> 00:12:34,130
+blood ممكن انا استخدمه عشان اعمله dilution مع
+
+159
+00:12:34,130 --> 00:12:38,610
+diluentطيب في نوع اخر او مصدر اخر للعينة تبعتي
+
+160
+00:12:38,610 --> 00:12:42,590
+ممكن يكون هو عبارة عن free flowing capillary يعني
+
+161
+00:12:42,590 --> 00:12:46,490
+من ال skin puncture تمام من ال .. من الاصبع و
+
+162
+00:12:46,490 --> 00:12:49,930
+مباشرة اعبي capillary طب ال capillary هذه اش
+
+163
+00:12:49,930 --> 00:12:54,670
+خصائصها؟ الخصائصها اسمها؟هي Thoma Bibet خلينا
+
+164
+00:12:54,670 --> 00:12:58,710
+نستعرض مع بعض صورة لهاي ال Bibet اللي هو ال .. ال
+
+165
+00:12:58,710 --> 00:13:03,510
+.. ال capillary اللي إحنا بنستخدمها و نشوف إيش هي
+
+166
+00:13:03,510 --> 00:13:07,470
+خصائصها، هي مش capillary بمعنى capillary زي ال
+
+167
+00:13:07,470 --> 00:13:11,750
+capillary tubes اللي إنتوا شفتوهملكن هي من الداخل
+
+168
+00:13:11,750 --> 00:13:18,010
+تمام مصممة على إنه المحلول يتم تعبئته فيها
+
+169
+00:13:18,010 --> 00:13:21,890
+بالخاصية الشعرية يعني هي من الداخل رفيعة كتير ولو
+
+170
+00:13:21,890 --> 00:13:25,810
+انها ممكن تكون سميكة من برا تمام؟ لكن من جوا رفيعة
+
+171
+00:13:25,810 --> 00:13:31,010
+كتيرتمام؟ في عندي طبعا واحدة بتكون مخصصة لعد ال
+
+172
+00:13:31,010 --> 00:13:35,510
+RPCs وواحدة مخصصة لعد ال white PCs احنا اليوم راح
+
+173
+00:13:35,510 --> 00:13:39,950
+نذكر اللي احنا بصدد نتعرف عليها اللي هي ال white
+
+174
+00:13:39,950 --> 00:13:44,070
+PCs ثومة بايبت لما نشرح ال RPCs count راح نتطرق ل
+
+175
+00:13:44,070 --> 00:13:49,740
+ال RPCs by bitطيب زي ما انتوا شايفين عبارة عن
+
+176
+00:13:49,740 --> 00:13:54,060
+ثومابايبت مكونة من هنا اسمها capillary stem stem
+
+177
+00:13:54,060 --> 00:14:00,360
+تمام؟ capillary stem و هذا ال capillary stem درج
+
+178
+00:14:00,360 --> 00:14:07,460
+لنص و واحد تمام؟ طيب في عندى هنا bulb مستودع او
+
+179
+00:14:07,460 --> 00:14:12,280
+انتفاخ تمام؟ مستودع او انتفاخ بسميه bulb هي هنا
+
+180
+00:14:12,280 --> 00:14:18,170
+capillary stemستم فيه من جوا يعني مصمم ان هو
+
+181
+00:14:18,170 --> 00:14:23,050
+المحلول يتم تعبقته فيه بالخاصية الشعرية تمام؟ لإنه
+
+182
+00:14:23,050 --> 00:14:30,910
+رفيع كتير و المدرج تمام؟ و في عندي أيضا مستودع هذا
+
+183
+00:14:30,910 --> 00:14:36,710
+المستودع بسميه bulb تمام؟ و هو عبارة عن انتفاخ في
+
+184
+00:14:36,710 --> 00:14:41,150
+داخله فيه قطعة القطعة هاي معدنية كرة معدنية بسميها
+
+185
+00:14:41,150 --> 00:14:48,870
+bead تمام؟ بسميها beadو أخر تدريج لأ ال .. ال ..
+
+186
+00:14:48,870 --> 00:14:55,090
+capillary طبعا بيكون عند 11 تمام؟ يعني نص و واحد
+
+187
+00:14:55,090 --> 00:14:58,870
+تمام؟ هذا ال .. ال .. هنا volume كبير بيكون موجود
+
+188
+00:14:58,870 --> 00:15:03,530
+فيه تمام؟ يعني تقريبا ال .. ال .. العشرة كلهم
+
+189
+00:15:03,530 --> 00:15:07,070
+موجودين هنا و على نهاية ال bulb بيكون في تدريج ..
+
+190
+00:15:07,070 --> 00:15:11,890
+رقم 11 تمام؟ بيكون في رقم 11هنا هاي الأشياء
+
+191
+00:15:11,890 --> 00:15:17,590
+التفاصيل .. هلأ راحت لزمني بشرح ال .. طريقة تعبئة
+
+192
+00:15:17,590 --> 00:15:23,170
+ال capillary و طريقة الحصول على الحسابات فإذا هذا
+
+193
+00:15:23,170 --> 00:15:28,450
+هو شكل ال white pieces بايبت تمام؟ أو ال white
+
+194
+00:15:28,450 --> 00:15:33,090
+pieces thermopiped خلونا نرجع لمحاضرتنا إذا حكينا
+
+195
+00:15:33,090 --> 00:15:37,270
+طبعا أنا حكينا ممكن هادي ال capillary أنه مباشرة
+
+196
+00:15:38,680 --> 00:15:42,780
+تمتع بيئتها لحد النص اللى عند علامة النص بال blood
+
+197
+00:15:42,780 --> 00:15:47,600
+تمام؟ او ممكن من ال skin puncture طبعا او ممكن من
+
+198
+00:15:47,600 --> 00:15:51,900
+ال tube ادتها انا سحبت منه .. سحبت يعني دم وريدي
+
+199
+00:15:51,900 --> 00:15:56,460
+وفضيته في tube ادتها وعملت ال will mixing تمام؟
+
+200
+00:15:56,460 --> 00:15:56,800
+طيب
+
+201
+00:16:02,850 --> 00:16:07,710
+the diluent أنا بستخدم diluent lies erythrocyte
+
+202
+00:16:07,710 --> 00:16:11,350
+بيكسرلي ال erythrocyte علشان ال erythrocyte عددها
+
+203
+00:16:11,350 --> 00:16:14,770
+كتير كبير بالملايين تمام لكن عدد ال white pieces
+
+204
+00:16:14,770 --> 00:16:19,570
+بالآلاف فإذا أنا لازم أكسر هاي ال erythrocyte عشان
+
+205
+00:16:19,570 --> 00:16:23,410
+ما تعملي noise و ما تأثر على القراءة أنا بدي بس ال
+
+206
+00:16:23,410 --> 00:16:26,070
+leucocyte اللي ماتكون موجودة علشان أعرف أقرأها
+
+207
+00:16:26,340 --> 00:16:30,060
+تمام؟ فوجود ال erythrocyte لإنه عددها كبير ممكن
+
+208
+00:16:30,060 --> 00:16:34,840
+يعيق عملية القراءة فإذا لازم أستخدم محلول من خواصه
+
+209
+00:16:34,840 --> 00:16:39,520
+إنه بيكسرلي ال erythrocyte من خواصه إنه بيكسر ال
+
+210
+00:16:39,520 --> 00:16:46,810
+erythrocyte تمام؟the diluted blood is added to the
+
+211
+00:16:46,810 --> 00:16:51,830
+hematocytometer chamber هذا الدم المخفف أنا بضيفه
+
+212
+00:16:51,830 --> 00:16:55,090
+على حاجة اسمها hematocytometer chamber اللي هي
+
+213
+00:16:55,090 --> 00:17:01,290
+حكينا شريحة مخصصة للعد إلها خواص أو مميزات إنه
+
+214
+00:17:01,290 --> 00:17:08,260
+يعني هي تستخدم فقط لعد الخلاياطيب إذا العينة تبعتي
+
+215
+00:17:08,260 --> 00:17:11,680
+إيش هتكون إما edata anticoagulated venous blood
+
+216
+00:17:11,680 --> 00:17:16,980
+يعني دم وريدي موجود في تيوب edata أو حتى ممكن تكون
+
+217
+00:17:16,980 --> 00:17:21,540
+من ال skin puncture ولكن ال edata anticoagulated
+
+218
+00:17:21,540 --> 00:17:27,050
+blood طبعايعني سواء كان هو أو كان من ال capillary
+
+219
+00:17:27,050 --> 00:17:31,590
+يعني من ال .. ال venous فهم يعني تقريبا أفضل أنواع
+
+220
+00:17:31,590 --> 00:17:35,230
+يعني أستخدم إيديتا أفضل نوع anticoagulant ممكن
+
+221
+00:17:35,230 --> 00:17:39,810
+يكون موجود أو حتى من ال .. ال skin puncture مباشرة
+
+222
+00:17:39,810 --> 00:17:46,560
+إلى ال thermopipedطيب، إيش الأدوات و ال .. ال
+
+223
+00:17:46,560 --> 00:17:50,380
+reagents اللي ممكن أنا أستخدمها؟ طبعا إحنا حكينا
+
+224
+00:17:50,380 --> 00:17:54,000
+إنه أنا لازم عينة الدم أخففها، بدي أستخدم diluting
+
+225
+00:17:54,000 --> 00:17:58,180
+fluid طبعا ال diluting fluid هذا في عندي أنواع منه
+
+226
+00:17:58,340 --> 00:18:01,560
+ممكن استخدم ascetic acid بتركيز 2% volume to
+
+227
+00:18:01,560 --> 00:18:07,020
+volume وطبعا احنا أخدنا محاضرة ال dilution وشرحنا
+
+228
+00:18:07,020 --> 00:18:13,100
+كيف انا بحضر تركيز volume to volume 2% مثلا او 3%
+
+229
+00:18:13,100 --> 00:18:18,020
+حسب و هذا ممكن تسأله عنه فبترجعوا لمحاضرة ال
+
+230
+00:18:18,020 --> 00:18:21,520
+dilution و بتعرفوا كيف احنا بنحضر volume to volume
+
+231
+00:18:21,520 --> 00:18:27,440
+wet to wet او wet to volume تمام؟طيب، diluting
+
+232
+00:18:27,440 --> 00:18:32,600
+fluid ممكن يكون Acetic acid 2% volume to volume أو
+
+233
+00:18:32,600 --> 00:18:37,760
+HCl 1% volume to volume أو حتى ممكن يكون عندي نوع
+
+234
+00:18:37,760 --> 00:18:41,400
+تالت اللي هو الأكثر شيوعا واستخداما هو ال terg
+
+235
+00:18:41,400 --> 00:18:45,480
+solution و هو المحلول اللي احنا راح نستخدمه، تمام؟
+
+236
+00:18:45,480 --> 00:18:50,100
+في المختبر، مما مكون .. مكون من glacial acetic
+
+237
+00:18:50,100 --> 00:18:56,010
+acid، تمام؟و crystal violet صبغة اسمها crystal
+
+238
+00:18:56,010 --> 00:18:59,550
+violet و distilled water هلأ ال glacial acetic
+
+239
+00:18:59,550 --> 00:19:04,110
+acid حمض تمام وظيفته انه يكسرلي الخلايا بمساعدة
+
+240
+00:19:04,110 --> 00:19:08,530
+ايضا الصبغة كمان بتساعد على انها تخرب ال membrane
+
+241
+00:19:08,530 --> 00:19:14,580
+للخلايا فبسهول تكسرهال .. لcrystal violet راح
+
+242
+00:19:14,580 --> 00:19:18,100
+تصبغلي أنوية .. بما أنها صابغة راح تصبغ أنوية ال
+
+243
+00:19:18,100 --> 00:19:23,720
+white pieces فإذن أنا بإمكاني إن أنا أشوف الخلايا
+
+244
+00:19:23,720 --> 00:19:27,900
+.. تمام .. أنويتها من الداخل أو الخلايا من الداخل
+
+245
+00:19:27,900 --> 00:19:31,480
+مخدة اللون الأزرق اللي هو نوع اللون لcrystal
+
+246
+00:19:31,480 --> 00:19:36,940
+violet فإذن بإمكاني يعني أعدها بسهولة ب .. من خلال
+
+247
+00:19:36,940 --> 00:19:43,990
+إنه أنا أعرف إنها هي مخدة اللون تمام؟ طيبالأدوات
+
+248
+00:19:43,990 --> 00:19:49,690
+اللى بدي اياها محتاجة diluting fluid وحكينا راح
+
+249
+00:19:49,690 --> 00:19:55,730
+نستخدم في المختبر TERC ومحتاجة thoma white pipet
+
+250
+00:19:55,730 --> 00:20:01,830
+اللى هى المدرجة نص لواحد لحداشر حكينا ال RBC's
+
+251
+00:20:01,830 --> 00:20:05,570
+النوع بتاعى بتكون تدريجة نص واحد مية واحد وال bulb
+
+252
+00:20:05,570 --> 00:20:08,650
+تبعها كبير اكبر من ال white pieces زى ما انتوا
+
+253
+00:20:08,650 --> 00:20:11,750
+شايفين كنتوا فى الصورة هناال .. ال .. ال white
+
+254
+00:20:11,750 --> 00:20:16,510
+pieces ال .. الحجم تبعها أكبر، تمام؟ فهي عشان هيك
+
+255
+00:20:16,510 --> 00:20:22,110
+نهاية التدريج تبعها ل 101 و .. لإن عددها أكبر بكون
+
+256
+00:20:22,110 --> 00:20:26,430
+محتاجة أنه تتخفف أكتر عشان هيك ال .. ال .. التدريج
+
+257
+00:20:26,430 --> 00:20:32,160
+أكبر هناالتفاصيل هاي رح ناخدها في ال RBCs count
+
+258
+00:20:32,160 --> 00:20:37,280
+lecture ولكن احنا حاليا رح نحكي فقط عن ال
+
+259
+00:20:37,280 --> 00:20:41,080
+thermopipet اللي هي خاصة بعد ال white pieces حكينا
+
+260
+00:20:41,080 --> 00:20:45,940
+تدريجها نص و واحد و لعند 11 تمام محتاجة هذه ال
+
+261
+00:20:45,940 --> 00:20:49,700
+thermopipet محتاجة ال hematocytometer chamber اللي
+
+262
+00:20:49,700 --> 00:20:53,580
+هي الشريحة المخصصة للعدمحتاجة cover slip اللي هي
+
+263
+00:20:53,580 --> 00:20:56,340
+القطعة الزجاجية اللي أنا بحطها على الشريحة علشان
+
+264
+00:20:56,340 --> 00:21:01,440
+تغطيلي العينة و بإمكاني بعد هيك أنه أستخدم .. يعني
+
+265
+00:21:01,440 --> 00:21:05,220
+أحطها على ال microscope و أعد بلزمني microscope،
+
+266
+00:21:05,220 --> 00:21:10,260
+بلزمني wipe شاش أو جوز أو قطن، بلزمني برضه كمان
+
+267
+00:21:10,260 --> 00:21:15,120
+قطع أو .. قطن مغموسة بالكحول اللي هي alcohol pads
+
+268
+00:21:17,120 --> 00:21:19,960
+تمام، إذا إيش الأدوات اللي بتلزمني؟ حكينا
+
+269
+00:21:19,960 --> 00:21:24,540
+thomapipet، بيكون في عندي أيضا متصلة ب rubber، هذا
+
+270
+00:21:24,540 --> 00:21:28,160
+ال rubber بيكون يا بنات معقّم ونظيف ومتصل بقطعة
+
+271
+00:21:28,160 --> 00:21:33,480
+عشان احنا أحيانا بنستخدم الفم في سحب المحلولو أيضا
+
+272
+00:21:33,480 --> 00:21:37,660
+في عندي هنا hematocytometer chamber اللي هو عبارة
+
+273
+00:21:37,660 --> 00:21:43,120
+عن شريحة مخصصة للعدد شايفين انه مش زي الشرائح
+
+274
+00:21:43,120 --> 00:21:46,620
+العادية الزجاجية العادية البسيطة هي شريحة مصممة
+
+275
+00:21:46,620 --> 00:21:51,300
+بطريقة معينة تمكنني من عدد الخلايا و حساب العدد
+
+276
+00:21:51,300 --> 00:21:56,480
+بطريقة accurate تمام؟ فإذا هذه هي الإدوات اللي
+
+277
+00:21:56,480 --> 00:22:00,800
+بتلزمنيطبعا اللي هي metacitometer ال chamber بيكون
+
+278
+00:22:00,800 --> 00:22:05,720
+موجود في plastic container خاص فيه عشان احنا نحافظ
+
+279
+00:22:05,720 --> 00:22:09,220
+عليه ما ينكسر لإنه بنرجع بنستخدمه مش زي الشريحة
+
+280
+00:22:09,220 --> 00:22:13,640
+العادية استخدمته حطيت عليه مسحة دم مثلا بعد ما
+
+281
+00:22:13,640 --> 00:22:18,230
+أخلص بكبها لأفي عندي هذا يعني أنا بعقمه و برجع
+
+282
+00:22:18,230 --> 00:22:23,230
+بستخدمه لأكتر من عينة لإنه يعني هو غالي الثمن و
+
+283
+00:22:23,230 --> 00:22:28,090
+مابنفع احنا نتلفه و لازم نحافظ عليه من الكثر فإذا
+
+284
+00:22:28,090 --> 00:22:31,560
+هو بيكون موجود في plastic containerالـ
+
+285
+00:22:31,560 --> 00:22:35,920
+hematocytometer تفاصيل أكثر عن هذا الـ chamber الـ
+
+286
+00:22:35,920 --> 00:22:39,100
+hematocytometer counting chamber is used for cell
+
+287
+00:22:39,100 --> 00:22:42,960
+counting هو عبارة عن .. احنا بنسمي hematocytometer
+
+288
+00:22:42,960 --> 00:22:47,380
+chamber .. chamber ولكن هو عبارة عن شريحة مخصصة
+
+289
+00:22:47,380 --> 00:22:51,500
+لعد الخلايا مثل ما ذكرنا it's constructed so that
+
+290
+00:22:51,500 --> 00:22:54,220
+the distance between the bottom of the cover slip
+
+291
+00:22:54,220 --> 00:22:57,840
+and the surface of the counting area point one
+
+292
+00:22:57,840 --> 00:23:02,300
+millimeterهو عبارة عن مصمم بطريقة معينة بحيث ان لو
+
+293
+00:23:02,300 --> 00:23:05,620
+حطيت عليه cover slip اللي هو الغطاء الزجاجي اللي
+
+294
+00:23:05,620 --> 00:23:09,500
+انا بحط عليه تمام المسافة هتكون ما بين ال cover
+
+295
+00:23:09,500 --> 00:23:13,860
+slip و ال chamber هتكون مسافة point واحد
+
+296
+00:23:13,860 --> 00:23:18,320
+millimeterتمام؟ اللي هي يعني ال .. ال .. المنطقة
+
+297
+00:23:18,320 --> 00:23:21,860
+أو المسافة اللي أنا بعبي فيها العينة ارتفاع العينة
+
+298
+00:23:21,860 --> 00:23:25,800
+هيكون point واحد millimeter لإنها هتكون موجودة في
+
+299
+00:23:25,800 --> 00:23:29,880
+ال .. المنطقة مابين ال chamber و ال cover slab the
+
+300
+00:23:29,880 --> 00:23:33,300
+surface of that chamber contain two square ruled
+
+301
+00:23:33,300 --> 00:23:38,240
+areas separated by at shape mode خليني أشوفزي ما
+
+302
+00:23:38,240 --> 00:23:42,880
+انتوا شايفين هذا هو ال chamber تمام؟ زي عامل شكل
+
+303
+00:23:42,880 --> 00:23:47,580
+الأتشاب وين احنا بنعد؟ في عندي هنا مربع و هنا مربع
+
+304
+00:23:47,580 --> 00:23:52,540
+و بكونوا مسطرين ه .. تسطيرة معينة هورجيكم إياها
+
+305
+00:23:52,540 --> 00:23:56,660
+بالعين المجردة أول ما نرجع على المختبر على شأع
+
+306
+00:23:56,660 --> 00:24:01,960
+أساس أنه تشوفوها منيحطبعا لو أنا جيت حطيت cover
+
+307
+00:24:01,960 --> 00:24:06,400
+slip قطعة زجاجية cover على هذا ال chamber طبعا أنا
+
+308
+00:24:06,400 --> 00:24:10,780
+بحط ال cover slip بعدين بعب العينة طيب فإذا لو أنا
+
+309
+00:24:10,780 --> 00:24:14,140
+حطيت ال cover slip راح يكون في عندي مسافة فاصلة
+
+310
+00:24:14,140 --> 00:24:17,540
+هنا بين ال .. بين ال chamber و ال cover slip هذه
+
+311
+00:24:17,540 --> 00:24:20,820
+المسافة الفاصلة ارتفاعها واحد من عشرة millimeter
+
+312
+00:24:20,820 --> 00:24:25,960
+هنا تكمن العينة او يعني هنا انا بتم .. ب .. بعمل
+
+313
+00:24:25,960 --> 00:24:30,170
+تعبي على العينةبعبي العينة في هذه المنطقة طبعا
+
+314
+00:24:30,170 --> 00:24:33,510
+لازم انا لما اعبي العينة تكون العينة فقط على
+
+315
+00:24:33,510 --> 00:24:37,630
+المربع يعني حوافها جاي على حواف المربع بالظبط
+
+316
+00:24:37,630 --> 00:24:42,210
+مابنفع ان العينة تكون خارج عن حواف المربع زي هذا
+
+317
+00:24:42,210 --> 00:24:46,070
+الشكل او حتى فيها air bubble فيها فقعات يعني
+
+318
+00:24:46,070 --> 00:24:51,350
+فراغات لإن هذا هيأثر على الحسابات طبعتي فهيكون في
+
+319
+00:24:51,350 --> 00:24:55,710
+عندي خطأ error اذا لازم انا اعبيها بشكل ان مايكون
+
+320
+00:24:55,710 --> 00:25:02,000
+فيهافراغات إنها ما تطف على الجوانب لازم تكون فقط
+
+321
+00:25:02,000 --> 00:25:06,340
+على حواف المربع اللي مخصص للعدد هذا المربع و هذا
+
+322
+00:25:06,340 --> 00:25:12,860
+تمام و تكون يعني حجمها مناسب و كميتها مناسبة تمام
+
+323
+00:25:12,860 --> 00:25:17,760
+و ما تكون طبعا يعني إنها هيك عاملة زي التفاف دائرة
+
+324
+00:25:17,760 --> 00:25:20,960
+إنه يعني الحجم ناقص لأ لازم تكون well-fit يعني
+
+325
+00:25:20,960 --> 00:25:25,720
+تماما مخدة شكل المربع اللي هي جالسة فيهه .. هنا ..
+
+326
+00:25:25,720 --> 00:25:29,080
+هذا شكل ايه؟ او يعني التعليمات اللي خاصة بالتعبئة
+
+327
+00:25:29,080 --> 00:25:34,200
+طبعا احنا بنعد .. ممكن نعد في مربع واحد في واحد
+
+328
+00:25:34,200 --> 00:25:37,760
+منهم و ممكن اعد في المربعين و في نهاية القراءة
+
+329
+00:25:37,760 --> 00:25:41,140
+اقسمها على اتنين اخد ال average لإلها اقسمها على
+
+330
+00:25:41,140 --> 00:25:44,660
+اتنين تمام؟ طيب
+
+331
+00:25:47,820 --> 00:25:51,640
+إيش ال .. التجربة طبعتي؟ أول حاجة سواء كان أنا
+
+332
+00:25:51,640 --> 00:25:55,040
+بستخدم معايا ال blood من skin puncture يعني من
+
+333
+00:25:55,040 --> 00:26:00,040
+الإصبع أو من edita tube يعني سحبت .. سحبت من وريد
+
+334
+00:26:00,040 --> 00:26:03,640
+وقع ملقته في ال .. في edita tube عملت mixing منيح
+
+335
+00:26:03,640 --> 00:26:08,730
+مع ال editaسواء كانت العينة skin puncture أو vein
+
+336
+00:26:08,730 --> 00:26:14,210
+puncture أنا لازم أملأ ال .. ال .. ال .. ال .. ال
+
+337
+00:26:14,210 --> 00:26:14,490
+.. ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال ..
+
+338
+00:26:14,490 --> 00:26:15,030
+ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال
+
+339
+00:26:15,030 --> 00:26:15,590
+.. ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال ..
+
+340
+00:26:15,590 --> 00:26:16,330
+ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال
+
+341
+00:26:16,330 --> 00:26:16,330
+.. ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال ..
+
+342
+00:26:16,330 --> 00:26:16,870
+ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال
+
+343
+00:26:16,870 --> 00:26:19,630
+.. ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال ..
+
+344
+00:26:19,630 --> 00:26:19,690
+ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال
+
+345
+00:26:19,690 --> 00:26:19,690
+.. ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال ..
+
+346
+00:26:19,690 --> 00:26:19,690
+ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال
+
+347
+00:26:19,690 --> 00:26:21,850
+.. ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال ..
+
+348
+00:26:21,850 --> 00:26:26,170
+ال .. ال .. ال ..الـ Cabillary أو الـ Thaumabibet
+
+349
+00:26:26,170 --> 00:26:29,890
+بالـ blood طبعا إذا أنا حطيتها في تيوب هتتبهدل من
+
+350
+00:26:29,890 --> 00:26:35,610
+برا فلازم أنا أمسحها ب wipe تمام عشان أنظفها أشيلي
+
+351
+00:26:35,610 --> 00:26:40,390
+ال excess من ال blood اللي موجودة على السطحة أو
+
+352
+00:26:40,390 --> 00:26:43,550
+عليها من برا تمام لإن هذا هيأثر على ال dilution
+
+353
+00:26:43,800 --> 00:26:47,460
+طمام؟ اذا اول حاجة املا ايه ال .. ال .. ال thoma
+
+354
+00:26:47,460 --> 00:26:52,320
+pipet لعند علابة النص بال blood بعدين امسحي wipe
+
+355
+00:26:52,320 --> 00:26:55,020
+the outside of the capillary بنمسحي ال capillary
+
+356
+00:26:55,020 --> 00:26:57,920
+من برا علشان ال excess blood اللي موجودة عليها من
+
+357
+00:26:57,920 --> 00:27:02,640
+برا ممكن يأثر على ال dilution طمام؟ ليش؟ لإن انا
+
+358
+00:27:02,640 --> 00:27:05,960
+هاي ال capillary بعد ما املأها بال blood بدي احطها
+
+359
+00:27:05,960 --> 00:27:10,820
+بشكل عمودي في tube و هذا ال tube موجود فيه diluent
+
+360
+00:27:10,820 --> 00:27:16,080
+طمام؟و .. و أصحى بال diligent ام لأ ال .. ال
+
+361
+00:27:16,080 --> 00:27:20,080
+capillary بال diligent لعند العلامة 11 تمام؟ لعند
+
+362
+00:27:20,080 --> 00:27:26,410
+العلامة 11 طيب اش اللي راح يصير بالظبط؟خلّينا نرجع
+
+363
+00:27:26,410 --> 00:27:30,110
+لشكل الكابلري عشان نشرح عليها أنا ملاقت لعند
+
+364
+00:27:30,110 --> 00:27:33,970
+العلامة هنا نص blood مسحتها و نظفتها من برا عشان
+
+365
+00:27:33,970 --> 00:27:37,030
+ال excess blood ممكن يؤثر على ال dilution بعد هيك
+
+366
+00:27:37,030 --> 00:27:40,870
+باخد الكابلري هادي بشكل عمودي بفوت في محلول تمام
+
+367
+00:27:40,870 --> 00:27:45,050
+المحلول هذا عبارة عن diluent تمام it's a solution
+
+368
+00:27:45,050 --> 00:27:51,490
+حكيناال .. رح أسحب او يعني رح ا .. ال .. ال ..
+
+369
+00:27:51,490 --> 00:27:56,450
+أكمل ل .. في .. تعبقت الثومة بايبت، بدلي one لعندي
+
+370
+00:27:56,450 --> 00:28:01,890
+العلامة 11، تمام؟طيب، أش اللي راح يصير؟ ال blood
+
+371
+00:28:01,890 --> 00:28:06,330
+هنا لما ييجي عب التارك ال blood هيطلع .. كله
+
+372
+00:28:06,330 --> 00:28:10,910
+هيستقر وين؟ هيستقر في منطقة المستودع، يعني هنا ال
+
+373
+00:28:10,910 --> 00:28:15,210
+blood هيكون موجود، تمام؟ و هنا هيصير فقط موجود
+
+374
+00:28:15,210 --> 00:28:20,370
+تارك و هنا موجود أيضا بقايا ال blood مع ال ..
+
+375
+00:28:20,370 --> 00:28:27,320
+التاركطيب بعد ما أملأ لحد العلامة 11 بجيب قطنة و
+
+376
+00:28:27,320 --> 00:28:32,540
+بفضّي محتويات ال stem هنا اللي هي إيش صارت موجود
+
+377
+00:28:32,540 --> 00:28:36,940
+فيها؟ موجود فيها فقط تارك، تمام؟ فقط موجود فيها
+
+378
+00:28:36,940 --> 00:28:40,420
+تارك solution اللي هو ال daily one لإن الدم خلاص
+
+379
+00:28:40,420 --> 00:28:48,330
+صعد إلى منطقة المستودعطيب إذا بعد ملق ال capillary
+
+380
+00:28:48,330 --> 00:28:57,410
+لحد العلامة 11 طبعا لازم أسكرها هيك بعد ما أطلعها
+
+381
+00:28:57,410 --> 00:29:01,170
+من ال daily want بسكرها بالسبابة لإن أي فتحة فيها
+
+382
+00:29:01,170 --> 00:29:05,390
+ممكن يرجع يكب المحلول منها طبعا لازم أعملها مغلقة
+
+383
+00:29:05,390 --> 00:29:11,450
+و بعد هيك بروح على قطنة على قطعة قطن بفضي محتويات
+
+384
+00:29:11,450 --> 00:29:16,670
+الاستمال هي الواحدة هذه طبعايعني بفضّي تقريبا تلت
+
+385
+00:29:16,670 --> 00:29:21,490
+قطرات أو أربع قطرات اللي هم محتويات الستم و بعد
+
+386
+00:29:21,490 --> 00:29:26,770
+هيك بروح بمسح ال .. ال hematocytometer و بنضفه
+
+387
+00:29:26,770 --> 00:29:33,930
+بقالكحول بعد بقطعة قطنية أو قمع .. يعني جوز شاش
+
+388
+00:29:33,930 --> 00:29:39,630
+مبلل بيه الكحولبنطفه بحط عليه cover slip و
+
+389
+00:29:39,630 --> 00:29:44,310
+باستخدام ال by bit من عن الطرف هنا من عند حواف أو
+
+390
+00:29:44,310 --> 00:29:49,510
+حافة ال cover slip بسير افرغ محلول بحيث انه يملأ
+
+391
+00:29:49,510 --> 00:29:56,630
+المربع و يعبيه بشكل حكينا متناسق انه ما يطف من عن
+
+392
+00:29:56,630 --> 00:29:59,930
+الجوانب مايكون excess فيه عندي و مايكون فيه فراغات
+
+393
+00:29:59,930 --> 00:30:04,790
+او حتى airdrops اللي هي يعني فقعة هوا
+
+394
+00:30:07,660 --> 00:30:12,480
+مجرد ما أنا .. ما لاقت ال chamber بروح بحطه على ال
+
+395
+00:30:12,480 --> 00:30:17,320
+microscope أول إشي على عشرة، تمام؟ ممكن أجيب ال
+
+396
+00:30:17,320 --> 00:30:20,680
+field على أربعة، بعدين أروح أحط على عشرة علشان
+
+397
+00:30:20,680 --> 00:30:24,640
+أعد، تمام؟ و بعد أنا على العدسة رقم عشرة، تمام؟
+
+398
+00:30:24,640 --> 00:30:28,260
+إذا لازم أجيب ال field على أربعةطيب لإنه إحنا
+
+399
+00:30:28,260 --> 00:30:30,820
+حاكينا .. اتعلمنا إنه أنا بجيب ال field أول إشي
+
+400
+00:30:30,820 --> 00:30:36,100
+على عدسة تكبيرها صغير بعدين بكبر على العدسة اللي
+
+401
+00:30:36,100 --> 00:30:39,120
+أنا مراد استخدامها أو العدسة اللي تكبيرها أكبر
+
+402
+00:30:39,120 --> 00:30:45,640
+شويةبب .. طبعا كيف ال .. ال .. شكل ال .. ال field
+
+403
+00:30:45,640 --> 00:30:50,860
+اللي هجيبه؟ هشوفه بهذا الشكل، إشي مسطر، تمام؟ طيب،
+
+404
+00:30:50,860 --> 00:30:54,500
+إحنا حكينا إنه ال .. ال .. ال chamber إله تستيرة
+
+405
+00:30:54,500 --> 00:30:59,640
+معينة، تمام؟ و التستيرة هذه أنا هورجيكم إياها على
+
+406
+00:30:59,640 --> 00:31:03,600
+ال .. يعني هتشوفوها بالعين المجردة، ولكن إحنا ما
+
+407
+00:31:03,600 --> 00:31:07,260
+راح نشوف تفاصيلها، تفاصيل هذه التستيرة راح تكون
+
+408
+00:31:07,260 --> 00:31:11,720
+واضحة أكتر على ال microscopeال .. التصطيرة بهذا
+
+409
+00:31:11,720 --> 00:31:17,940
+الشكل أنا في عندى يعني خطوط مضغوطة تمام؟ خطوط
+
+410
+00:31:17,940 --> 00:31:23,780
+مضغوطة بهذا الشكل تمام؟ متقاطعة وفي على الحواف
+
+411
+00:31:23,780 --> 00:31:27,660
+مربعات تمام؟ أربع مربعات في المنطقة الوحدة يا بنات
+
+412
+00:31:27,660 --> 00:31:30,820
+يعني أنا لو جيت على ال chamber من هنا في المنطقة
+
+413
+00:31:30,820 --> 00:31:35,240
+الوحدةتمام؟ هنا موجود نفس التصطيرة اللي في ال
+
+414
+00:31:35,240 --> 00:31:38,400
+slide السابق اللي .. اللي كان .. من شوية كنا فيها
+
+415
+00:31:38,400 --> 00:31:42,300
+و هنا أيضا موجود نفس التصطيرة حكينا أنا بعين ممكن
+
+416
+00:31:42,300 --> 00:31:45,080
+أقعد هنا لحال أو أقعد هنا لحال أو ممكن أقعد في
+
+417
+00:31:45,080 --> 00:31:49,600
+الجهتين و أقسم على اتنين تمام؟
+
+418
+00:31:51,820 --> 00:32:01,160
+طيب إذا حكينا إنه هيك التستيرة مضغوط يعني زي ال ..
+
+419
+00:32:01,160 --> 00:32:06,200
+ال cross هيك المضغوط تمام؟ و يعني .. مش يعني مضغوط
+
+420
+00:32:06,200 --> 00:32:10,100
+يعني ال .. الستور أو الخطوط جنب بعضها متلاسقة يعني
+
+421
+00:32:10,100 --> 00:32:14,590
+مافي مسافات، شايفين؟ جنب بعضهاو هنا أيضا مضغوط
+
+422
+00:32:14,590 --> 00:32:18,910
+فهذا التقاطع المضغوط على أطرافه موجود عندي أربع
+
+423
+00:32:18,910 --> 00:32:22,950
+مربعات الأربع مربعات هذه هي اللي بنعد فيها ال
+
+424
+00:32:22,950 --> 00:32:25,590
+white pieces شايفين علامة ال W هذه يعنيها هذه
+
+425
+00:32:25,590 --> 00:32:29,570
+مخصصة لل white pieces لعد ال white pieces تمام ال
+
+426
+00:32:29,570 --> 00:32:34,790
+R هذه مخصصة لعد ال RPCs راح نشوف تفاصيلها في
+
+427
+00:32:34,790 --> 00:32:41,540
+محاضرة ال RPCs count تمام؟هذه المربعات عبارة عن
+
+428
+00:32:41,540 --> 00:32:46,040
+ستاشر مربع أربعة في أربعة تمام؟ هي اللي أنا بعد
+
+429
+00:32:46,040 --> 00:32:49,860
+فيها طيب حوافها من هنا بتكون مستطيلات على الأطراف
+
+430
+00:32:49,860 --> 00:32:52,400
+هنا مستطيلات يعني هو مش جايب ليها موضح ليها بس
+
+431
+00:32:52,400 --> 00:32:58,600
+أنتوا بتشوفوها في ال .. تحت ال microscope في عندي
+
+432
+00:32:58,600 --> 00:33:06,890
+مستطيلات هنا تمام؟طيب فإذا أنا بعد في هذه المربعات
+
+433
+00:33:06,890 --> 00:33:12,190
+الأربعة، تمام؟ في جهة واحدة ممكن أعد أيضا كمان
+
+434
+00:33:12,190 --> 00:33:17,090
+أربعة في الجهة التانية من ال at shed من ال .. ال
+
+435
+00:33:17,090 --> 00:33:22,310
+chamberو يكون أنا هيك عديت في 8 مربعات أربعة فوق
+
+436
+00:33:22,310 --> 00:33:26,130
+أربعة تحت فبقسم على اتنين لإنه في النهاية أنا بدي
+
+437
+00:33:26,130 --> 00:33:30,130
+قراة لأربع مربعات أطبق فيها في القانون سواء عديت
+
+438
+00:33:30,130 --> 00:33:33,530
+في أربعة من جهة واحدة أو عديت في تمانية و قسمت على
+
+439
+00:33:33,530 --> 00:33:37,610
+اتنين مش مهم المهم أنا يعني بدي في النهاية مجموع
+
+440
+00:33:37,610 --> 00:33:43,890
+القراة يكون لأربع مربعات طيبإذا زي ما أنتوا شايفين
+
+441
+00:33:43,890 --> 00:33:49,830
+المنطقة المضغوطة هذه بتفيدني علشان أعرف أنا في أين
+
+442
+00:33:49,830 --> 00:33:53,870
+في أي مربع تمام؟ يعني انت مثلا لو كانت ال .. ال ..
+
+443
+00:33:53,870 --> 00:33:57,710
+طبعا هي بنت ال field بيكون بس مسلط على منطقة معينة
+
+444
+00:33:57,710 --> 00:34:01,090
+زي هيك فانت لو عرفت .. لو شوفت المضغوط من هذه
+
+445
+00:34:01,090 --> 00:34:04,950
+الجهة و من هذه الجهة مضغوط فانت معناها موجودة في
+
+446
+00:34:04,950 --> 00:34:08,490
+المربع الأول في المربع التاني لما تكون المضغوط
+
+447
+00:34:08,490 --> 00:34:12,650
+بهذا الشكلو في المربع التالت لما تكون .. يكون
+
+448
+00:34:12,650 --> 00:34:15,470
+المضغوط بهذا الشكل و في المربع الرابع لما يكون
+
+449
+00:34:15,470 --> 00:34:19,570
+بهذا الشكل تمام؟ فإذا إنت when كدك تعرفي حالك في
+
+450
+00:34:19,570 --> 00:34:23,230
+أي مربع مثلا كنت هنا في أي مربع في .. مثلا كنت هنا
+
+451
+00:34:23,230 --> 00:34:27,210
+و شفتي إنه مضغوط على الجانب من هنا و من .. من تحت
+
+452
+00:34:27,210 --> 00:34:30,510
+فمعناها بدك تتخيل الرسمة كلها و تعرفي حالك إنك إنت
+
+453
+00:34:30,510 --> 00:34:34,230
+في المربع التاني لو مثلا لإنه طبعا هو ما بعرضلك كل
+
+454
+00:34:34,230 --> 00:34:38,430
+الرسمة هذه ال field ال field بيكون مركز على ال 16
+
+455
+00:34:38,430 --> 00:34:42,470
+مربع اللي هناتمام؟ و جايبلك .. بس عرضلك جزء من
+
+456
+00:34:42,470 --> 00:34:46,490
+المضغوط اللي محيط في ال 16 مربع اللي انت بتقرأ
+
+457
+00:34:46,490 --> 00:34:54,130
+فيهم تمام؟ ف .. وين اتجاه المضغوط بتتخيلي انت في
+
+458
+00:34:54,130 --> 00:34:59,230
+مخيلتك كيف الرسمة او الشكل بشكل مكبر و بتعرفي حالك
+
+459
+00:34:59,230 --> 00:35:02,390
+انت وين بالظبط ف .. و بتعرفي حالك من وين .. وين
+
+460
+00:35:02,390 --> 00:35:05,330
+بدك تتنقلي يعني انت مثلا في المربع الأول شوفت
+
+461
+00:35:05,330 --> 00:35:08,970
+المضغوط هنا و هنا معناها انت في المربع الأولوين
+
+462
+00:35:08,970 --> 00:35:12,310
+بدك تنتقلي؟ بدك تنتقلي للتاني فمعناها مثلا بدك
+
+463
+00:35:12,310 --> 00:35:17,130
+تتحركي بهذا الاتجاه في ال field طبعا او بدك تنزلي
+
+464
+00:35:17,130 --> 00:35:21,310
+هيك عشان تروحي على التالت فإذا بيساعدك وين ..
+
+465
+00:35:21,310 --> 00:35:26,970
+تحددي وين انت موجودة و كيف بدك تنتقلي لأي مربع و
+
+466
+00:35:26,970 --> 00:35:32,610
+كيف الاتجاه تبع حركتكتمام؟ هذه التفاصيل كلها راح
+
+467
+00:35:32,610 --> 00:35:37,430
+نشتغلها خطوة بخطوة مع بعض فيعني اذا في اشي مبهم او
+
+468
+00:35:37,430 --> 00:35:42,070
+اشي تساؤلات كيف احنا بنعمل هاي الشغلة حاولوا انه
+
+469
+00:35:42,070 --> 00:35:48,090
+يعني تكونوا relaxed و ما .. يعني ما تستغربوا او
+
+470
+00:35:48,090 --> 00:35:51,550
+تخافوا لإنه الاشي راح يكون ع التطبيق ان شاء الله
+
+471
+00:35:52,450 --> 00:35:56,310
+مابحكيش ان هو هيكون سهل جدا ممكن يكون في صعوبة
+
+472
+00:35:56,310 --> 00:35:59,510
+ولكن يمكن تجاوزها و راح تتعلموا و تكون ان شاء الله
+
+473
+00:35:59,510 --> 00:36:05,830
+متمكنين و شطرين طيب احنا بس في النهاية بدي اذكر
+
+474
+00:36:05,830 --> 00:36:08,550
+انه انا لما بتحرك بهذا الاتجاه يعني انا بتحرك
+
+475
+00:36:08,550 --> 00:36:12,790
+لليسار في الشريحة بكون بتحرك لليمين على ال chamber
+
+476
+00:36:12,790 --> 00:36:16,030
+لإن الحركة بتكون معاكوسة و مقلوبة ايضا الصورة
+
+477
+00:36:16,030 --> 00:36:20,230
+بتكون معاكوسة و مقلوبةتمام طيب إيش اللي أنا بده
+
+478
+00:36:20,230 --> 00:36:24,330
+أعده في ال 16 مربع هدول؟ بده أعد النقاط السودة هاي
+
+479
+00:36:24,330 --> 00:36:29,010
+طب كيف أنا أعرف هذه النقطة السودة؟ خلية ولا دبرس و
+
+480
+00:36:29,010 --> 00:36:36,030
+غبار أو مثلا أشياء موسخة الشريحة ممكن تكون يعني
+
+481
+00:36:36,030 --> 00:36:40,020
+إشي مش خلايا كيف أنا بده أعرفه؟زاكرين تركيب ال
+
+482
+00:36:40,020 --> 00:36:43,300
+microscope لما حكينا انه ال course adjustment عشان
+
+483
+00:36:43,300 --> 00:36:46,020
+اجيب ال field عشان اقرب المسافة ما بين ال stage و
+
+484
+00:36:46,020 --> 00:36:49,900
+العدسات و ال fine adjustment علشان اشوف ال details
+
+485
+00:36:49,900 --> 00:36:54,660
+التفاصيل تمام فانا بلعب بال fine adjustment إذا
+
+486
+00:36:54,660 --> 00:36:58,540
+ظهرت إلي في داخل الخلية هذه في داخل النقطة السودة
+
+487
+00:36:58,540 --> 00:37:02,320
+لون أزرق تمام أو حتى أخضر يعني هو ممكن يكون على
+
+488
+00:37:02,320 --> 00:37:05,600
+اخضرار لأ بسبب إضاءة ال microscope بس هو فعليا
+
+489
+00:37:05,600 --> 00:37:11,390
+الصبغة لونها أزرق تمامفإذا ظهر عندى لون فى الداخل
+
+490
+00:37:11,390 --> 00:37:14,610
+معناه عادي خليها ماخدة لون مصبوغة بالصبغة اللى
+
+491
+00:37:14,610 --> 00:37:18,030
+موجودة فى مكونات ال Turk solution فى مكونات ال
+
+492
+00:37:18,030 --> 00:37:24,580
+diligent اللى أنا استخدمتهاطيب الحساب او الحسابات
+
+493
+00:37:24,580 --> 00:37:30,300
+اللى احنا بدنا نجريها لحتى نجيب التراكيز او العدد
+
+494
+00:37:30,300 --> 00:37:32,820
+الخلايا ال white pieces count ال total white
+
+495
+00:37:32,820 --> 00:37:36,960
+pieces count طبعا انا عندي عمق العينة طبعتي اللى
+
+496
+00:37:36,960 --> 00:37:40,920
+هى المسافة اللى انا عبقت فيها او ملقت فيها العينة
+
+497
+00:37:40,920 --> 00:37:45,280
+كانت 1 من 10 ملي متر اللى هى المسافة الفاصلة ما
+
+498
+00:37:45,280 --> 00:37:50,840
+بين ال chamber و cover slipتمام؟ طيب ال .. ال
+
+499
+00:37:50,840 --> 00:37:54,500
+dilution اللي أنا بستخدمه أنا بعمل dilution واحد
+
+500
+00:37:54,500 --> 00:37:59,900
+لعشرين من أين أجا .. من أين أتى هذا الواحد لعشرين؟
+
+501
+00:37:59,900 --> 00:38:05,310
+خلينا نرجع لل Thaumabioticو نستفكر مع بعض احنا ايش
+
+502
+00:38:05,310 --> 00:38:10,830
+ذكرنا بخصوص ال Tom and pie أنا ملقت الدم لعند نص
+
+503
+00:38:10,830 --> 00:38:19,530
+تمام و بعد هيك كملت بال daily one لعند 11 يعني
+
+504
+00:38:19,530 --> 00:38:26,590
+كمان في عندي نرجع هنا نعمل
+
+505
+00:38:29,870 --> 00:38:35,010
+بنحط notes كان في عندي blood خدنا نكتب هنا بس ال
+
+506
+00:38:35,010 --> 00:38:45,050
+blood إلى diluent تمام؟ كان في عندي ال blood حطيت
+
+507
+00:38:45,050 --> 00:38:58,330
+أنا نص تمام؟ و ال .. ال diluent كان 11 تمام؟ طيبفي
+
+508
+00:38:58,330 --> 00:39:02,170
+عندى محتويات ال stem انا حكيت فضيتها اللى كانت
+
+509
+00:39:02,170 --> 00:39:05,510
+daily want لحاله، تمام؟ ذاكرين .. ذاكرين لما
+
+510
+00:39:05,510 --> 00:39:10,230
+حكيتلكم ال blood بيطلع ع المستودع و ال .. ال stem
+
+511
+00:39:10,230 --> 00:39:15,230
+اللى هى من صفر لواق من .. لعند الواحد هذه بتصير
+
+512
+00:39:15,230 --> 00:39:20,590
+daily want كامل او daily want صافىترك لحاله تمام و
+
+513
+00:39:20,590 --> 00:39:24,530
+أنا بفضّي محتويات هذا ال stem على قطعة قطن اللي هي
+
+514
+00:39:24,530 --> 00:39:28,230
+التلت أو أربع قطرات اللي أنا بتخلص منهم فأصبح أنا
+
+515
+00:39:28,230 --> 00:39:31,850
+خلصت .. اتخلصت من محتويات ال stem اللي هي عبارة عن
+
+516
+00:39:31,850 --> 00:39:41,210
+واحد يعني صار عندي ال dilution نص إلى .. إلى
+
+517
+00:39:41,210 --> 00:39:46,270
+عشرة اللي هي الواحد اللي خلصت منه
+
+518
+00:39:49,070 --> 00:39:53,110
+تمام؟ اتخلصت منه الواحد طب ليش انا عملت اصلا عبيته
+
+519
+00:39:53,110 --> 00:39:57,810
+لعند ال 11؟ لأ لإنه انا معنية انه يعني بهذه ال ..
+
+520
+00:39:57,810 --> 00:40:00,950
+ال .. الكمية من ال daily want انا بكون فوتت الدم
+
+521
+00:40:00,950 --> 00:40:06,160
+للمستودع يعني أمنته موجود في المستودعتمام؟ طيب
+
+522
+00:40:06,160 --> 00:40:09,560
+فإذا و بعد هيك بقايا ال stem اللي هي فيها daily
+
+523
+00:40:09,560 --> 00:40:13,880
+one لحالي اللي هي أصلا كلها حجمها واحد بتخلص منه
+
+524
+00:40:13,880 --> 00:40:18,420
+على قطعة قطن فبصير عندي في النهاية أنا ماخدة نص ل
+
+525
+00:40:18,420 --> 00:40:24,800
+11 في واحد اتخلصت منه يعني نص ل 10 يعني واحد تمام
+
+526
+00:40:24,800 --> 00:40:25,440
+إلى
+
+527
+00:40:31,120 --> 00:40:34,940
+عشرين تمام؟ take ال delayotion طبيعي واحد إلى
+
+528
+00:40:34,940 --> 00:40:40,980
+عشرين تمام جديد بالذكر احكيلكم انه هذه ال .. ال
+
+529
+00:40:40,980 --> 00:40:47,140
+bead اللي هنا بعد ما انا اوصل الدم للمستودع هذه ال
+
+530
+00:40:47,140 --> 00:40:50,860
+bead لو انا عملت mixing رجيت ال .. ال by bit طبعا
+
+531
+00:40:50,860 --> 00:40:55,140
+سكرتها ب ..بأصابعي سكرت فوها من هنا و من هنا و
+
+532
+00:40:55,140 --> 00:40:59,700
+عملت mixing تمام هذه البيض راح تتحرك و هي تخلط
+
+533
+00:40:59,700 --> 00:41:04,280
+الدم مع ال diligent و راح تساعد على تكسير خلايا ال
+
+534
+00:41:04,280 --> 00:41:07,860
+RBCs و تنصبغ ال white BCs بالصبغة اللي موجودة في
+
+535
+00:41:07,860 --> 00:41:12,740
+المحلول علشان في النهاية انا احصل على محلول متجانس
+
+536
+00:41:12,740 --> 00:41:19,890
+أملؤه داخل ال chamberطيب أنا عديت في مربعات المربع
+
+537
+00:41:19,890 --> 00:41:24,990
+كل واحد منه كان ستة .. يعني مقسم إلى ستاشر مربع
+
+538
+00:41:24,990 --> 00:41:29,430
+صغير هنا المربعات هذه أنا عديت أربع مربعات كل واحد
+
+539
+00:41:29,430 --> 00:41:33,190
+فيهم ستاشر مربع صغير طب هذا المربع الكبير اللي فيه
+
+540
+00:41:33,190 --> 00:41:37,170
+ستاش ايش أبعاده عبارة عن واحد millimeter في واحد
+
+541
+00:41:37,170 --> 00:41:41,910
+millimeter أبعاده؟تمام؟ يعني طيب فإذا لو أنا بدي
+
+542
+00:41:41,910 --> 00:41:46,210
+أجي أخد حجم المربع الواحد عبارة عن .. طب الحجم هو
+
+543
+00:41:46,210 --> 00:41:49,750
+عبارة عن إيش؟ تلت أبعاد طول في عرض في ارتفاع طيب
+
+544
+00:41:49,750 --> 00:41:53,770
+واحد millimeter طول و عرض واحد millimeter طول طب
+
+545
+00:41:53,770 --> 00:41:58,270
+ارتفاعه جداش كان؟ كان هو اللي هو المسافة أو البعد
+
+546
+00:41:58,270 --> 00:42:04,210
+ما بين ال chamber و ال slide ال cover slip اللي
+
+547
+00:42:04,210 --> 00:42:11,620
+محطوط تمام؟ فإذا ..حجم المربع هيكون واحد من عشرة
+
+548
+00:42:11,620 --> 00:42:17,720
+ملي متر مكعب وبما إن السوائل تاخد حجم القناع اللي
+
+549
+00:42:17,720 --> 00:42:23,260
+بتوضع فيه، تمام؟ إذا حجم السائل اللي أنا قرأته في
+
+550
+00:42:23,260 --> 00:42:28,060
+المربع هذا هو حجم المربع الطول في العرض في
+
+551
+00:42:28,060 --> 00:42:31,540
+الارتفاع في كام مسافة كام ما بين ال chamber هذا و
+
+552
+00:42:31,540 --> 00:42:37,960
+ال cover slip تمام؟طيب، أنا عديت في أربع مربعات،
+
+553
+00:42:37,960 --> 00:42:41,000
+يعني خلّينا نحسب إنه أنا عديت في منطقة واحدة من
+
+554
+00:42:41,000 --> 00:42:45,100
+الأتشاب، في أربع مربعات، هيهم، تمام؟ المنطقة
+
+555
+00:42:45,100 --> 00:42:51,520
+الواحدة من الأتشاب بتكون هيك مسطرة، تمام؟
+
+556
+00:42:51,520 --> 00:42:55,580
+هي الأتشاب، المنطقة الواحدة بتكون هيك مسطرة، زي ما
+
+557
+00:42:55,580 --> 00:43:01,920
+شفنا، و هنا كمان موجود أيضًا تسطيرة أخرىطيب أنا
+
+558
+00:43:01,920 --> 00:43:05,520
+عديت فيه أربع مربعات معناها الحجم اللي حسبته
+
+559
+00:43:05,520 --> 00:43:10,140
+للمربع الواحد بضربه فيه أربعة ففي عندي الحجم لأربع
+
+560
+00:43:10,140 --> 00:43:13,660
+مربعات هو عبارة عن أربعة في الواحد من عشرة
+
+561
+00:43:13,660 --> 00:43:18,380
+millimeter مكعب و هيعطيني فاصلة أربعة من عشرة أو
+
+562
+00:43:18,380 --> 00:43:22,860
+point أربعة millimeter مكعب ال millimeter مكعب هو
+
+563
+00:43:22,860 --> 00:43:25,540
+نفس ال microliter طيب
+
+564
+00:43:31,840 --> 00:43:36,740
+نفترض إنه أنا عدت في أربع مربعات خمسين خلية تمام؟
+
+565
+00:43:36,740 --> 00:43:39,540
+في الأربع مربعات كان مجموع العدد خمسين نفترض
+
+566
+00:43:39,540 --> 00:43:46,020
+افتراض طيب الخمسين كانوا موجودين في حجم فاصلة من
+
+567
+00:43:46,020 --> 00:43:51,560
+أربعة من عشرة يعني ملي متر مكعب طب كام بيكون موجود
+
+568
+00:43:51,560 --> 00:43:57,330
+في الواحد ملي متر مكعب؟ لإنه في النهاية أناوحدة
+
+569
+00:43:57,330 --> 00:44:03,470
+قياس الخلايا اللي هي عبارة عن سل أو اللي هي الوحدة
+
+570
+00:44:03,470 --> 00:44:10,030
+لعد الخلايا سل per micrometer مكعب، تمام؟ per
+
+571
+00:44:10,030 --> 00:44:11,230
+micrometer مكعب
+
+572
+00:44:16,630 --> 00:44:20,150
+مش موجود القص هنا مش عارفة من وين اجيبه ما علينا
+
+573
+00:44:20,150 --> 00:44:24,050
+متر م .. ملي متر مكعب او ممكن تكون اللي هي عبارة
+
+574
+00:44:24,050 --> 00:44:31,690
+عن سل بير microliter تمام بير microliter طيب انا
+
+575
+00:44:31,690 --> 00:44:34,930
+في ال microliter الواحد كام بيكون موجود في ال
+
+576
+00:44:34,930 --> 00:44:38,350
+millimeter مكعب الواحد كام بيكون موجود خلايا هذا
+
+577
+00:44:38,350 --> 00:44:44,660
+اللي بلزمني ففي النهاية انا بعمل زي ضرب تبادليو
+
+578
+00:44:44,660 --> 00:44:49,460
+بطلع عندي الخمسين في واحد على أربعة من عشرة طبعا
+
+579
+00:44:49,460 --> 00:44:53,760
+ال volume correction هو الواحد لأربعة من عشرة
+
+580
+00:44:53,760 --> 00:44:57,100
+فدايما بضربه في ال and في العدد الخلايا اللي بيطلع
+
+581
+00:44:57,100 --> 00:45:01,020
+معايا طبعا و هيك طبعا بضربه كمان أيضا في ال
+
+582
+00:45:01,020 --> 00:45:06,800
+dilution factor في ال dilution factor طبعا و
+
+583
+00:45:06,800 --> 00:45:18,360
+بالنهاية بحصل على ال total طبعا ofWhite PCsتمام؟
+
+584
+00:45:18,360 --> 00:45:22,880
+إذا في النهاية أنا بالزمني أكون عارفة أبعاد المربع
+
+585
+00:45:22,880 --> 00:45:28,020
+عشان أجيب الحجم و .. و أجيب .. و الحجم بالزمني
+
+586
+00:45:28,020 --> 00:45:33,400
+عشان أنا في النهاية بدي بدل ما أحسب أدد الخلايا في
+
+587
+00:45:33,400 --> 00:45:38,360
+point أربعة ملي متر مكعب بدي أحسبه في واحد ملي متر
+
+588
+00:45:38,360 --> 00:45:42,900
+مكعب تمام؟ فب .. ب .. بعمل يعني .. بدرب العدد في
+
+589
+00:45:42,900 --> 00:45:48,270
+مقلوب هذا ال volume تمام؟فهيك بكون جبت ال volume
+
+590
+00:45:48,270 --> 00:45:52,290
+correction طب دلت العينة مخففة فعندي فانا بدي
+
+591
+00:45:52,290 --> 00:45:57,670
+العينة ك .. ك .. ك .. أصل مجدش فيها عدد خلايا فبدي
+
+592
+00:45:57,670 --> 00:46:00,830
+أضرب في ال dilution factor و احنا عرفنا لما دايما
+
+593
+00:46:00,830 --> 00:46:04,430
+لما بدي أجيب الأصل ال original بدرب في ال dilution
+
+594
+00:46:04,430 --> 00:46:09,590
+factorفإذا ال total of white pieces count هيكون هو
+
+595
+00:46:09,590 --> 00:46:12,910
+عدد الخلايا اللي أنا عدتها في كام مربع؟ في أربع
+
+596
+00:46:12,910 --> 00:46:17,090
+مربعات عشان هيك لو أنا جبت يعني يا بعد في جهة
+
+597
+00:46:17,090 --> 00:46:20,790
+واحدة يا إما بعد في الجهتين و بقسم على اتنين لإن
+
+598
+00:46:20,790 --> 00:46:24,050
+لو عدت في الجهتين هيكون في عندي تمان قراءات فأنا
+
+599
+00:46:24,050 --> 00:46:28,330
+بدي لأ أنا بدي فقط أربع قراءات مجموع أربع قراءات
+
+600
+00:46:28,330 --> 00:46:33,800
+تمام؟ مجموع الخلايا في أربع مربعات فقط لا غيرو
+
+601
+00:46:33,800 --> 00:46:36,560
+بدربه في ال volume correction و ايضا في ال
+
+602
+00:46:36,560 --> 00:46:40,120
+dilution factor طبعا هذه التفاصيل ان شاء الله ممكن
+
+603
+00:46:40,120 --> 00:46:48,380
+نوضحها اكتر في المعمل و ننتقل الى ال discussion او
+
+604
+00:46:48,380 --> 00:46:53,500
+الجزئية اللى بتتعلق بصرد .. صرد مصادر ال error و
+
+605
+00:46:53,500 --> 00:46:56,820
+كيف احنا نحلها لو كان في عند الشخص عنده
+
+606
+00:46:56,820 --> 00:47:02,800
+leukocytosis اش يعني leukocytosis؟ يعني زيادة high
+
+607
+00:47:03,520 --> 00:47:08,640
+أو elevated leukocyte count عدد كبير او ارتفاع
+
+608
+00:47:08,640 --> 00:47:13,060
+كبير في عدد خلايا الدم البيضاء معناه اش بده اعمل؟
+
+609
+00:47:13,060 --> 00:47:16,220
+بده اعمل dilution اكبر بدل ما اعمل dilution واحد
+
+610
+00:47:16,220 --> 00:47:20,160
+لعشرين بعمل واحد لمية dilution خارجي في ال tube مش
+
+611
+00:47:20,160 --> 00:47:22,860
+شرط استخدم الثومابايبت لأنها مش هتوفرلي هذا ال
+
+612
+00:47:22,860 --> 00:47:26,380
+dilution طيب
+
+613
+00:47:26,380 --> 00:47:29,760
+لو كان الشخص عنده
+
+614
+00:47:33,780 --> 00:47:39,120
+ليكو سايتو بينيا
+
+615
+00:47:40,620 --> 00:47:45,840
+leukocytopenia اللي هي يعني low like leukocyte
+
+616
+00:47:45,840 --> 00:47:49,920
+count تمام او reduced leukocyte count يعني عدد
+
+617
+00:47:49,920 --> 00:47:55,080
+قليل من ال ال white pieces تمام يعني اقل مثلا من
+
+618
+00:47:55,080 --> 00:48:01,060
+3000 خلية per millimeter فبالتالي انا بدي اقلل ال
+
+619
+00:48:01,060 --> 00:48:03,940
+dilution هنا لو انا عملت dilution 1 ل 20 و هو اصلا
+
+620
+00:48:03,940 --> 00:48:07,560
+عنده نقص في خلايا الدم البيضاء معناه مش هشوف خلايا
+
+621
+00:48:07,560 --> 00:48:11,720
+لإن انا مخففاهافبدى اقلل ال dilution بعمل dilution
+
+622
+00:48:11,720 --> 00:48:17,840
+واحد لعشرة بيكون كافي ممكن انه يعني مثلا بعبي الدم
+
+623
+00:48:17,840 --> 00:48:24,400
+لعندي الواحد و بكمل لالإحداش تمام؟ بتخلص من واحد
+
+624
+00:48:24,400 --> 00:48:28,700
+من خلال القطارات فبيصير ال dilution واحد لعشرة او
+
+625
+00:48:28,700 --> 00:48:33,180
+ممكن اعمله ك dilution خارجي في طيوب و هنعلمكم كيف
+
+626
+00:48:33,180 --> 00:48:34,880
+بنعمل dilution خارجي في طيوب
+
+627
+00:48:39,440 --> 00:48:43,600
+طيب لو كان .. لو أنا كنت عاملة مسحة دم ل .. للمريض
+
+628
+00:48:43,600 --> 00:48:49,260
+و لاجيت عنده في ال blood smear in nucleated RBCs
+
+629
+00:48:49,260 --> 00:48:53,700
+هاي ال nucleated RBCs ممكن ما تتكسر بفعل ال terg
+
+630
+00:48:53,700 --> 00:48:56,600
+solution و تظل موجودة و لما قاعد .. قاعد .. قاعدها
+
+631
+00:48:56,600 --> 00:49:02,420
+على أساس إنها white BCs تمام؟ و .. يعني تعملي
+
+632
+00:49:02,420 --> 00:49:07,050
+errorتزودلي ال .. ال count ال total count طبعا
+
+633
+00:49:07,050 --> 00:49:10,610
+فأنا لازم ساعتها هنا لو لمحت في ال blood smear في
+
+634
+00:49:10,610 --> 00:49:14,430
+ال .. في الفيلم في مسحة الدم خلايا nucleated وكنت
+
+635
+00:49:14,430 --> 00:49:17,790
+عاملة في نفس الوقت white pieces count لازم أروح
+
+636
+00:49:17,790 --> 00:49:21,250
+أطبق قانون اسمه corrected white pieces count طبعا
+
+637
+00:49:21,250 --> 00:49:26,330
+لإن أنا بكون ساعتها أكيد عديت خلايا RPCs على أساس
+
+638
+00:49:26,330 --> 00:49:29,990
+إنها white piecesإيش هي الـ Nucleated RBCs؟ الـ
+
+639
+00:49:29,990 --> 00:49:34,490
+Nucleated RBCs هي عبارة عن خلايا RBCs غير نادجة،
+
+640
+00:49:34,490 --> 00:49:38,570
+تمام؟ الخلايا النادجة هي اللي بتفقد النواة تبعتها،
+
+641
+00:49:38,570 --> 00:49:42,490
+لطالما موجودة النواة معناها هي خلايا غير نادجة
+
+642
+00:49:42,490 --> 00:49:46,270
+طلعت ع ال circulation بفعل ضغط على البون مارو مثلا
+
+643
+00:49:46,270 --> 00:49:50,330
+في نزيف أو أنيميا أو مشكلة معينة أن ال RBCs مش
+
+644
+00:49:50,330 --> 00:49:53,810
+كافية بس بيصير البون مارو يطلع ال RBCs وهي غير
+
+645
+00:49:53,810 --> 00:49:58,310
+نادجةعلى الدم عشان تحلي المشكلة اللي برا تحلي هي
+
+646
+00:49:58,310 --> 00:50:04,530
+مشكلة ال high box تمام حكينا انه هاي ال RBCs ال
+
+647
+00:50:04,530 --> 00:50:09,150
+nucleated RBCs resist lysis ما .. ما بتتكسر بفعل
+
+648
+00:50:09,150 --> 00:50:12,410
+ال diluent فانا لو لمحتها في ال blood film طبعا
+
+649
+00:50:12,410 --> 00:50:15,690
+انا مابشوفها على ال .. ال chamber ممكن اشوفها في
+
+650
+00:50:15,690 --> 00:50:21,710
+مسحة الدمإذا لمحتها في مسحة الدم معناها وكنت عاملة
+
+651
+00:50:21,710 --> 00:50:24,790
+في نفس الوقت white pieces count معناها في عندي خلل
+
+652
+00:50:24,790 --> 00:50:27,890
+أو في عندي زيادة في ال white pieces count سببه هذه
+
+653
+00:50:27,890 --> 00:50:30,750
+ال nucleated RBCs اللي انعدت على أساس أنها white
+
+654
+00:50:30,750 --> 00:50:34,230
+pieces فلازم أطبق هذا القانون اللي هو عبارة عن
+
+655
+00:50:34,230 --> 00:50:37,030
+خلايا ال white pieces اللي .. اللي أنا عديتها
+
+656
+00:50:37,030 --> 00:50:42,450
+وكانت يعني فيها زيادة فيها .. هي uncorrect ضرب 100
+
+657
+00:50:42,960 --> 00:50:48,320
+و على 100 زائد اللي هي ال nucleated RBCs اللي
+
+658
+00:50:48,320 --> 00:50:52,920
+موجودة في .. يعني عدد ال nucleated RBCs اللي
+
+659
+00:50:52,920 --> 00:50:56,780
+موجودة في مسحة الدم تمام؟ و أنا بعمل differential
+
+660
+00:50:56,780 --> 00:51:01,920
+لما أجي أعد خلايا white bases على ال blood smear
+
+661
+00:51:01,920 --> 00:51:06,500
+بشوف .. يعني ب .. بعد ال nucleated RBCs و بستخدمها
+
+662
+00:51:06,500 --> 00:51:10,280
+في تطبيق هذا القانونإيش يعني مسحة الدم و كيف أنا
+
+663
+00:51:10,280 --> 00:51:13,300
+بشوف ال nucleated RBCs و إيش يعني أصلا white
+
+664
+00:51:13,300 --> 00:51:16,840
+pieces differential هذا راح ناخده في معمل blood
+
+665
+00:51:16,840 --> 00:51:21,440
+film أو blood smear تمام؟ هتضح .. هتضح إلكم الصورة
+
+666
+00:51:21,440 --> 00:51:30,970
+أكترطيب sources of error حكينا إن الخلل ممكن يكون
+
+667
+00:51:30,970 --> 00:51:36,770
+موجود فيه سببه failure to have required blood
+
+668
+00:51:36,770 --> 00:51:40,600
+volume يعني أنا ما ملقت الدم للنصفي حال .. في
+
+669
+00:51:40,600 --> 00:51:45,020
+الحالات الطبيعية ماملقته للواحد في حالات انه مثلا
+
+670
+00:51:45,020 --> 00:51:50,260
+عنده leukocytopenia ماعملت dilution كويس في حالات
+
+671
+00:51:50,260 --> 00:51:54,720
+ال leukocytosis مااخدتش الحجم الدم اللازم فإذا انا
+
+672
+00:51:54,720 --> 00:52:01,760
+مااخدتش كمية دم معبرة تمام فبالتالي الفحص التابعي
+
+673
+00:52:01,760 --> 00:52:04,940
+أيضا مش راح يكون معبر و النتائج انتباهتي مش راح
+
+674
+00:52:04,940 --> 00:52:08,610
+تكون دقيقةfailure to mix well إذا أنا ماعملت
+
+675
+00:52:08,610 --> 00:52:14,070
+mixing منيح لل blood مع ال .. ال daily one معناها
+
+676
+00:52:14,070 --> 00:52:18,210
+أنا برضه كمان هنا ممكن أاخد concentrated أو أخد
+
+677
+00:52:18,210 --> 00:52:24,430
+مثلا دم مش مكسرة فيه ال RBCs فبالتالي اتعيق عملية
+
+678
+00:52:24,430 --> 00:52:29,660
+القراءةfailure to discard the first four drops لو
+
+679
+00:52:29,660 --> 00:52:33,560
+أنا ما اتخلصت من الأربع قطرات أو الثلاث قطرات اللي
+
+680
+00:52:33,560 --> 00:52:40,380
+بيكونوا موجودين في أول الجزء من الثومة بعيبة اللي
+
+681
+00:52:40,380 --> 00:52:45,060
+هو الstemمعناها انه انا لما اهجأ املأ ال chamber
+
+682
+00:52:45,060 --> 00:52:50,000
+هاملأه فيهم هدول القطارات يعني هاملأه بترك
+
+683
+00:52:50,000 --> 00:52:53,320
+solution لحال مش راح يكون في عندي عينة كافية على
+
+684
+00:52:53,320 --> 00:52:56,140
+ال chamber فبالتالي هيكون ال white pieces count
+
+685
+00:52:56,140 --> 00:53:01,430
+قليل نتيجة ان انا محطتش عينة كفايةfailure to .. و
+
+686
+00:53:01,430 --> 00:53:04,850
+ايضا كمان ال delution تبعي هيكون فيه خلال failure
+
+687
+00:53:04,850 --> 00:53:07,710
+to barely charge the counting chamber لو انا
+
+688
+00:53:07,710 --> 00:53:11,910
+مملقتش ال chamber بطريقة صحيحة ايضا كمان راح يكون
+
+689
+00:53:11,910 --> 00:53:15,730
+في عندي خلال لإن زي ما انتوا شايفين الحسابات تبعتي
+
+690
+00:53:15,730 --> 00:53:19,930
+بلزمني الحجم اللي كان .. الحجم ال blood اللي هو
+
+691
+00:53:19,930 --> 00:53:25,790
+حجم المربعات اللي كان يملقها ال blood تمام؟ و
+
+692
+00:53:25,790 --> 00:53:30,070
+علشان احصل على volume correctionوبلزمني أيضًا
+
+693
+00:53:30,070 --> 00:53:33,510
+delusion factor عشان أحصل على اللي .. اللي هو
+
+694
+00:53:33,510 --> 00:53:39,240
+الصيغة كاملةfailure to preparely chart the
+
+695
+00:53:39,240 --> 00:53:41,960
+counting chamber إذا أنا ما ملاقت ال chamber بشكل
+
+696
+00:53:41,960 --> 00:53:46,060
+منيح معناها القانون اللي أنا بتبقه خطأ و مش معبر
+
+697
+00:53:46,060 --> 00:53:50,380
+فبالتالي نتائجي فيها خطأ أيضا كمان في عندي مشاكل
+
+698
+00:53:50,380 --> 00:53:55,060
+تانية ل ال error أقل يعني شيوعا ولكن ممكن تكون
+
+699
+00:53:55,060 --> 00:53:58,760
+موجودة ال by بتكون فيها مشكلة مثلا أو ال chamber
+
+700
+00:53:58,760 --> 00:54:04,070
+في مشكلة يكون inaccurateتستيرته خطأ، أبعاده،
+
+701
+00:54:04,070 --> 00:54:09,070
+البيبط فيها مشكلة، انكسرات، سبددات أو إشي، moist
+
+702
+00:54:09,070 --> 00:54:12,850
+or unclean بيبط إذا كانت ال .. البيبط من جوا فيها
+
+703
+00:54:12,850 --> 00:54:17,390
+مبللة أو فيها سائل أو مش نظيفة، أيضا كمان هذا ..
+
+704
+00:54:17,390 --> 00:54:22,070
+يعني إشي راح يشغل حيز و بالتالي راح يأثر على الحجم
+
+705
+00:54:22,070 --> 00:54:25,470
+و يأثر على ال dilution تبعيexcessive pressure in
+
+706
+00:54:25,470 --> 00:54:29,690
+finger لو أنا أخدت عينة من ال .. ال finger من ال
+
+707
+00:54:29,690 --> 00:54:33,490
+skin puncture وعملت pressure يعني ضغط جامد فمعناها
+
+708
+00:54:33,490 --> 00:54:37,170
+أنا بكون عم بطلع عصارة خلاياتي شجوس فبالتالي ال
+
+709
+00:54:37,170 --> 00:54:40,470
+blood هيكون diluted فبالتالي مش هيكون أيضا معبر
+
+710
+00:54:41,390 --> 00:54:46,050
+هحصل على reduced او low white basis count too
+
+711
+00:54:46,050 --> 00:54:48,930
+little or too much diluting fluid لو انا حطيت
+
+712
+00:54:48,930 --> 00:54:52,870
+diluting fluid بكميات كبيرة او بكميات قليلة هدها
+
+713
+00:54:52,870 --> 00:54:56,930
+يأثر على ال dilution slowness in manipulation وهي
+
+714
+00:54:56,930 --> 00:55:04,190
+نقطة مهمة انه نسرع او انه نكون هيك يعنيكيف دي
+
+715
+00:55:04,190 --> 00:55:09,650
+أحكيها ناشطين يعني انه مش بطق في الخطوات و روح
+
+716
+00:55:09,650 --> 00:55:13,470
+نفارطة لأ لإنه فعليا مثلا لو انت بدك تاخدي عينة من
+
+717
+00:55:13,470 --> 00:55:16,510
+ال skin puncture عشان تعبي فيها ثمابيبت لو انت ما
+
+718
+00:55:16,510 --> 00:55:20,330
+أسرعتي و حطيه و على طول ملقتي ال blood للنص و وراه
+
+719
+00:55:20,330 --> 00:55:24,030
+على طول مباشرة حطيت daily one الدم رح يتجلط لإن
+
+720
+00:55:24,030 --> 00:55:27,570
+انت عم تاخديه مباشرة من ال skin puncture يعني
+
+721
+00:55:27,570 --> 00:55:31,590
+مافيش anticoagulant في الموضوع فممكن يتجلط و يسدد
+
+722
+00:55:31,590 --> 00:55:35,600
+ال themabibetلو كان في ال .. في ال thermo pipet
+
+723
+00:55:35,600 --> 00:55:38,760
+air bubbles برضه كمان معناها في مشكلة فلذلك لازم
+
+724
+00:55:38,760 --> 00:55:43,440
+انا اتحكم بنفسي منيح و انا عم باخد ال volumes و
+
+725
+00:55:43,440 --> 00:55:49,580
+ايضا كمان لما افوت ال pipet مثلا في solution
+
+726
+00:55:49,580 --> 00:55:53,380
+افوتها بشكل عمودي يعني في trickات ريحت تعلموها
+
+727
+00:55:53,380 --> 00:55:59,100
+بالشغل العملي كيف انت تمنعي حدوث ال air bubbles او
+
+728
+00:55:59,100 --> 00:56:02,750
+يعني ظهور ال air bubbles في الشغلو برضه كمان ال
+
+729
+00:56:02,750 --> 00:56:05,590
+air bubble في ال counting chamber هتأثر على الحجم
+
+730
+00:56:05,590 --> 00:56:10,930
+اللي أنا عم بعده فبالتالي ممكن تعطيني error إذا
+
+731
+00:56:10,930 --> 00:56:14,750
+كان ال .. ال .. ال chamber مش نظيف مثلا أو في
+
+732
+00:56:14,750 --> 00:56:20,110
+المحلول تبعي مش نظيف مثلا في yeast أو fungi أو فطر
+
+733
+00:56:20,110 --> 00:56:23,900
+معين عفنفي المحلول أو حتى كمان ممكن يكون على ال
+
+734
+00:56:23,900 --> 00:56:28,520
+chamber ما .. عليه غبار أو ما مسح كويس فبالتالي
+
+735
+00:56:28,520 --> 00:56:33,740
+هذا هيأثر لإن هتعيق عملية العد هذه الغبار و ال ..
+
+736
+00:56:33,740 --> 00:56:39,840
+ال contaminationPresence of many nucleated red
+
+737
+00:56:39,840 --> 00:56:43,280
+cells causing a high white cell count إذا كان في
+
+738
+00:56:43,280 --> 00:56:48,580
+عندي عديد من الخلايا ال .. ال red cell نيوكلياتد
+
+739
+00:56:48,580 --> 00:56:52,920
+تمام معناه هذا هيعطيني error فلذلك أو إذا كان أنا
+
+740
+00:56:52,920 --> 00:56:57,360
+بشتغل white bc count مع blood film مع بعض و لمحت
+
+741
+00:56:57,360 --> 00:57:01,820
+في ال blood film نيوكلياتد red cell على طول لازم
+
+742
+00:57:01,820 --> 00:57:05,700
+أروح أطبق قانون ال corrected white bc count
+
+743
+00:57:07,130 --> 00:57:10,110
+mistakes in counting or calculation إذا كان أنا
+
+744
+00:57:10,110 --> 00:57:14,950
+طبقت القانون غلط مثلا يعني هنا حطيت ال and تكون
+
+745
+00:57:14,950 --> 00:57:20,010
+اللي هي مجموع عدد الخلايا في ال 8 مربعات مثلا أو
+
+746
+00:57:20,010 --> 00:57:23,710
+في 3 مربعات غلط إذا أنا عديت في 8 يعني عديت في
+
+747
+00:57:23,710 --> 00:57:30,730
+الجهتين فوق و تحت لازم أقسم ع 2 لازم هذا يكون ال
+
+748
+00:57:30,730 --> 00:57:33,870
+number of cells هو مجموع الخلايا في الأربع مربعات
+
+749
+00:57:33,870 --> 00:57:34,730
+تمام؟
+
+750
+00:57:39,680 --> 00:57:43,900
+أو حتى في الحسابات يعني مثلا ما جبت ال correction
+
+751
+00:57:43,900 --> 00:57:50,920
+volume أو ال volume correction صح ما جبت ال
+
+752
+00:57:50,920 --> 00:57:57,000
+dilution factor بشكل صح دي برضه كمان رح يأثر بهيك
+
+753
+00:57:57,000 --> 00:58:00,460
+بنكون وصلنا لنهاية محاضرتنا لليوم أتمنى أنها تكون
+
+754
+00:58:00,460 --> 00:58:04,180
+واضحة ومش صعبة عليكم يعطيكم ألف عافية
+
diff --git a/PL9fwy3NUQKwY9jl8xw-bWkVZkWcGGyspd/Eut_8KsMs84_raw.srt b/PL9fwy3NUQKwY9jl8xw-bWkVZkWcGGyspd/Eut_8KsMs84_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..427c3084cd164781db92fb42f33a2cd840b7665f
--- /dev/null
+++ b/PL9fwy3NUQKwY9jl8xw-bWkVZkWcGGyspd/Eut_8KsMs84_raw.srt
@@ -0,0 +1,3484 @@
+1
+00:00:04,860 --> 00:00:08,240
+السلام عليكم ورحمة الله وبركاته طالبات العزيزيات
+
+2
+00:00:08,240 --> 00:00:10,600
+اليوم ان شاء الله راح نشرح محاضرة بعنوان
+
+3
+00:00:10,600 --> 00:00:14,780
+microscope راح نتعرف على ال microscope أجزاءه
+
+4
+00:00:14,780 --> 00:00:20,080
+وظائف هذه الأجزاء وأيضا أنواع ال microscope طريقة
+
+5
+00:00:20,080 --> 00:00:25,120
+استخدام ال microscope وطريقة العناية به ومبدأ عمل
+
+6
+00:00:25,120 --> 00:00:29,470
+ال microscopeففي البداية ال microscope هو عبارة عن
+
+7
+00:00:29,470 --> 00:00:34,470
+is an important device that enable us to visualize
+
+8
+00:00:34,470 --> 00:00:39,430
+minute objects هو عبارة عن أداء مهمة important
+
+9
+00:00:39,430 --> 00:00:46,550
+device that enable us تمكننا من رؤية أو إيضاح ال
+
+10
+00:00:46,550 --> 00:00:51,630
+minute objects الأجزاء أو المكونات أو العناصر
+
+11
+00:00:51,630 --> 00:00:55,490
+الدقيقة جدا في العينة سواء كانت هذه العناصر
+
+12
+00:00:55,490 --> 00:01:01,730
+animateحية أو in animate غير حية وهي ال objects
+
+13
+00:01:01,730 --> 00:01:07,190
+طبعا لا نتمكن من رؤيتها بالعين المجردة لذلك نستعين
+
+14
+00:01:07,190 --> 00:01:10,470
+بال microscope نراها تحت ال microscope that you
+
+15
+00:01:10,470 --> 00:01:14,730
+can't be seen by our naked eye لذلك لا يمكن رؤيتها
+
+16
+00:01:14,730 --> 00:01:19,510
+بالعين المجردةنراها تحت ال microscope إذا هو
+
+17
+00:01:19,510 --> 00:01:22,770
+الأداة اللي بتمكننا من رؤية ال minor objects سواء
+
+18
+00:01:22,770 --> 00:01:25,530
+كانت هذه ال objects حية أو غير حية سواء كانت
+
+19
+00:01:25,530 --> 00:01:29,510
+المكونات أو العناصر أو الأجزاء المراد إيضاحها حية
+
+20
+00:01:29,510 --> 00:01:34,410
+أو غير حية بداية هذا هو ال microscope مما يتكون ال
+
+21
+00:01:34,410 --> 00:01:39,410
+microscope أول إشي يتكون من ocular lenses تمام؟
+
+22
+00:01:39,410 --> 00:01:43,050
+ocular lenses أو eyepiece نفس المعنى سواء حكينا
+
+23
+00:01:43,050 --> 00:01:50,110
+eyepiece أوocular lenses نفس المعنى طيب و أيضا
+
+24
+00:01:50,110 --> 00:01:56,170
+مكون من ال tube و هذه ال tube هي اللي بتنقل الصورة
+
+25
+00:01:56,170 --> 00:01:59,990
+طبعا اللي بتاخدها العدسات الشيئية و بتوديها على
+
+26
+00:01:59,990 --> 00:02:06,730
+العدسات العينية عشان يتم تكبيرها تمام؟ و المكون من
+
+27
+00:02:06,730 --> 00:02:15,470
+ذراع arm هذا c arm طيب مكون أيضا من base قاعدةمكون
+
+28
+00:02:15,470 --> 00:02:19,310
+من course adjustment العجل هذا الكبير اسمه course
+
+29
+00:02:19,310 --> 00:02:22,950
+adjustment و العجل الصغير fine adjustment طبعا
+
+30
+00:02:22,950 --> 00:02:26,090
+موجودين هايهم course adjustment و fine adjustment
+
+31
+00:02:26,090 --> 00:02:32,190
+طيب مكون من light source و iris diaphragm و
+
+32
+00:02:32,190 --> 00:02:35,910
+condenser و هذه stage هذه المنصة أو الطاولة اللي
+
+33
+00:02:35,910 --> 00:02:40,470
+بنحط عليها العينة العينة يتم تثبيتها من خلال ملاقت
+
+34
+00:02:40,470 --> 00:02:46,600
+بنسميها clips أو stage clipsتمام؟ هذه الـ
+
+35
+00:02:46,600 --> 00:02:49,180
+objective lenses اللي هي العدسات الشيئية اللي ..
+
+36
+00:02:49,180 --> 00:02:52,600
+اللي هي بتكبر الشيء المراد فحصه اللي .. اللي ..
+
+37
+00:02:52,600 --> 00:02:57,860
+اللي بنكون حاطينه في شريحة على ال stage هنا تمام؟
+
+38
+00:02:57,860 --> 00:03:02,080
+فإذا هذه هي مكونات ال .. ال microscope راح نتحدث
+
+39
+00:03:02,080 --> 00:03:06,220
+عنها بالتفصيل بداية خلونا لما بنحكي عن ال major
+
+40
+00:03:06,220 --> 00:03:08,940
+parts of microscope الأجزاء الأساسية في ال
+
+41
+00:03:08,940 --> 00:03:13,360
+microscope نقسمهم إلى أجزاءأول إشي خلونا نحكي عن
+
+42
+00:03:13,360 --> 00:03:16,720
+الهيكل ال framework of microscope الشكل الخارجي لل
+
+43
+00:03:16,720 --> 00:03:21,280
+microscope مما يتكون .. يتكون من تلت قطع أو تلت
+
+44
+00:03:21,280 --> 00:03:26,000
+مناطق تمام؟ الشكل الخارجي لل microscope أول إشي ال
+
+45
+00:03:26,000 --> 00:03:30,480
+arm هادي اللي انتوا شايفينها هاي ال arm هي اللي
+
+46
+00:03:30,480 --> 00:03:36,370
+بتوصل ال .. ال .. ال ..الجسم ال microscope ببعضه
+
+47
+00:03:36,370 --> 00:03:42,550
+إذا هي اللي بتعمل attachment أو يصال أو ربط ما بين
+
+48
+00:03:42,550 --> 00:03:49,500
+اللي هو العدسات و ال stage و القاعدة، تمام؟فإذا هي
+
+49
+00:03:49,500 --> 00:03:53,380
+الجزء الأساسي في أو اللي هي عماد ال microscope
+
+50
+00:03:53,380 --> 00:03:58,260
+اللي عليها يتم إيصال الأجزاء كلها ببعضها البعض ال
+
+51
+00:03:58,260 --> 00:04:02,580
+stage هو عبارة عن ال table الطاولة هاي أو المنصة
+
+52
+00:04:02,580 --> 00:04:05,960
+هاي اللي عليها إحنا بنحط ال slide و ال slide بيكون
+
+53
+00:04:05,960 --> 00:04:10,320
+عليها الشريحة أو هي ال slide هي الشريحة اللي بيكون
+
+54
+00:04:10,320 --> 00:04:15,780
+عليها العينة المراد فحصهاFoot or base القدم أو
+
+55
+00:04:15,780 --> 00:04:20,120
+القاعدة هي القاعدة المستطيلة high اللي الجهاز كله
+
+56
+00:04:20,120 --> 00:04:23,760
+rest عليها يرتاح عليها و يجلس عليها و يستند عليها
+
+57
+00:04:23,760 --> 00:04:28,280
+طبعا فإذا لو أنا بدي أقسمه بقسمه إلى تلت مناطق
+
+58
+00:04:29,690 --> 00:04:33,790
+تمام؟ و ال .. ال stage و ال base هذا هو الهيكل
+
+59
+00:04:33,790 --> 00:04:36,670
+الخارجي لل microscope the frame out work أو اللي
+
+60
+00:04:36,670 --> 00:04:41,590
+هي the framework of the microscope طيب نشوف الجهاز
+
+61
+00:04:41,590 --> 00:04:46,670
+او ال .. ال .. ال .. ال system التاني من تركيب ال
+
+62
+00:04:46,670 --> 00:04:50,810
+microscope اللي هو ال focusing system نظام التوضيح
+
+63
+00:04:50,810 --> 00:04:53,830
+في ال microscope احنا حكينا ان ال microscope بيوضح
+
+64
+00:04:53,830 --> 00:04:58,150
+بيكبر بيمكني من رؤية الأجزاء اللي هي لا ترى بالعين
+
+65
+00:04:58,150 --> 00:05:03,300
+المجردةطيب أكيد عنده نظام توضيح ونظام تكبير خاص
+
+66
+00:05:03,300 --> 00:05:08,200
+بعرض الصور بدقة متناهية إذا ال .. ال focusing
+
+67
+00:05:08,200 --> 00:05:12,720
+system هو نظام ال .. ال .. ال .. التوضيح أو
+
+68
+00:05:12,720 --> 00:05:17,810
+التركيز في ال microscopeو هذا النظام يتكون من
+
+69
+00:05:17,810 --> 00:05:23,910
+عجلين تمام two knobs هدول ال two knobs بنسميهم
+
+70
+00:05:23,910 --> 00:05:29,030
+لكبير بنسمي course focusing adjustment و لصغير
+
+71
+00:05:29,030 --> 00:05:33,200
+fine focusing adjustmentللاختصار بنحكي course
+
+72
+00:05:33,200 --> 00:05:38,800
+adjustment و fine adjustment تمام؟ إذا مكون من two
+
+73
+00:05:38,800 --> 00:05:43,600
+knobs هدول هيهم pair of knobs و الكبير course
+
+74
+00:05:43,600 --> 00:05:47,300
+adjustment و الصغير fine adjustment طيب ما هو
+
+75
+00:05:47,300 --> 00:05:49,780
+وظيفة ال course adjustment و ال fine adjustment؟
+
+76
+00:05:49,780 --> 00:05:54,350
+شوفوا معاياال course adjustment خلّيني أرجع على ال
+
+77
+00:05:54,350 --> 00:05:58,870
+microscope هنا ال course هايهم هدول العجلين أو
+
+78
+00:05:58,870 --> 00:06:02,610
+القضيبين هدول بنسميهم course adjustment الكبير و
+
+79
+00:06:02,610 --> 00:06:07,890
+الصغير fine adjustment طيب إيش وظيفة ال course
+
+80
+00:06:07,890 --> 00:06:10,910
+adjustment؟ شوفوا معايا أنا لما أحط الشريحة هنا
+
+81
+00:06:10,910 --> 00:06:15,810
+اللي عليها العينةمحتاجة أقرب المسافة ما بين
+
+82
+00:06:15,810 --> 00:06:19,770
+العدسات الشيئية التي ترى الشيء تمام أو تكبر الشيء
+
+83
+00:06:19,770 --> 00:06:23,930
+المراد فحصه وما بين الطاولة أو المنصة أو ال stage
+
+84
+00:06:23,930 --> 00:06:28,310
+اللي موجود عليه هذه العينة تمام؟ محتاجة أن المسافة
+
+85
+00:06:28,310 --> 00:06:33,790
+تكون قريبة عشان يتم تكبير ال .. ال .. ال ..العنصر
+
+86
+00:06:33,790 --> 00:06:40,430
+و أيضا يتم عرضه بإيضاح، يتم عرضه بإيضاح طيب، إذا
+
+87
+00:06:40,430 --> 00:06:45,090
+لابد من أنه يا إما العدسات الشيئية تقترب من ال
+
+88
+00:06:45,090 --> 00:06:50,130
+stage أو ال stage يقترب من العدسات الشيئية، تمام؟
+
+89
+00:06:51,210 --> 00:06:56,270
+فبتحريك هذا ال knobs اللي هو ال .. ال .. ال course
+
+90
+00:06:56,270 --> 00:07:01,330
+adjustment تمام؟ بتحريك هذا ال knob يتم إما تقريب
+
+91
+00:07:01,330 --> 00:07:04,850
+العدسات الشيئية من ال stage أو تقريب ال stage من
+
+92
+00:07:04,850 --> 00:07:07,880
+العدسات الشيئيةتمام هتشوفوا في مايكروسكوبات
+
+93
+00:07:07,880 --> 00:07:11,780
+العدسات الشيئية هي اللي بتتحرك وفي مايكروسكوبات لأ
+
+94
+00:07:11,780 --> 00:07:14,220
+ال stage اللي بتتحرك انتوا هتشتغلوا تقريبا معظم
+
+95
+00:07:14,220 --> 00:07:17,440
+مايكروسكوبات اللي عندنا بالقسم هو ال stage هو اللي
+
+96
+00:07:17,440 --> 00:07:23,080
+بيتحرك بيصعد بالقرب من العدسات الشيئيةتقترب
+
+97
+00:07:23,080 --> 00:07:26,940
+العدسات الشيئية من الشريحة اللى موجودة عليها
+
+98
+00:07:26,940 --> 00:07:31,620
+العينة المراد فحصها وبالتالي وبالتالي بتكون
+
+99
+00:07:31,620 --> 00:07:36,220
+العدسات الشيئية قريبة من ال objects تمام to be
+
+100
+00:07:36,220 --> 00:07:40,120
+visualized اللى احنا بدنا نوضحه فبتلتقط الى صورة
+
+101
+00:07:40,120 --> 00:07:44,940
+مكبرة وهذه الصورة المكبرة تنتقل عبر ال tube او
+
+102
+00:07:44,940 --> 00:07:50,550
+القناع اللى هنا الى العدساتال .. العينية يتم
+
+103
+00:07:50,550 --> 00:07:55,210
+تكبيره مرة أخرى وإذا احنا بناخد ال .. الصورة
+
+104
+00:07:55,210 --> 00:07:58,950
+النهائية بتكون مكبرة مرتين مرة بقوة تكبير العدسات
+
+105
+00:07:58,950 --> 00:08:02,710
+الشيئية أو العدسة الشيئية المستخدمة و .. اللي هي
+
+106
+00:08:02,710 --> 00:08:06,470
+بتكون صورة أولية و الصورة الأولية هدي تنتقل إلى
+
+107
+00:08:06,470 --> 00:08:10,990
+العدسات العينية ويتم تكبيرها مرة أخرى باستخدام
+
+108
+00:08:10,990 --> 00:08:17,430
+العدسات العينية تمام؟فبالتالي إذا لحتى الآن إحنا
+
+109
+00:08:17,430 --> 00:08:20,810
+بنعرف إنه ال course adjustment هو اللي مسؤول عن
+
+110
+00:08:20,810 --> 00:08:25,410
+تقريب ال stage من العدسات الشيئية أو تقريب العدسات
+
+111
+00:08:25,410 --> 00:08:29,050
+الشيئية من ال stage ليتم التقاط الصورة الأولية،
+
+112
+00:08:29,050 --> 00:08:32,730
+إنه يعني العدسات الشيئية تكبرلي ال .. ال .. ال
+
+113
+00:08:32,730 --> 00:08:37,730
+objects تمام؟ أو ال .. اللي هي محتويات العينةطيب
+
+114
+00:08:37,730 --> 00:08:42,970
+ال fine adjustment هاي طب .. لإش وظيفته؟ كل خلية
+
+115
+00:08:42,970 --> 00:08:48,630
+.. كل كائن حي .. كل molecule .. كل مكون object
+
+116
+00:08:48,630 --> 00:08:53,550
+عنصر بإحنا بنتحصه بيكون إله أبعاد هو ما بيكون مصمم
+
+117
+00:08:53,550 --> 00:08:56,110
+يعني هيك نايم على ال slide و ما .. لأ بيكون إله
+
+118
+00:08:56,110 --> 00:09:02,190
+طولة عرض ارتفاع تمام؟ فال .. ال .. ال fine
+
+119
+00:09:02,190 --> 00:09:06,760
+adjustment .. ال fine adjustment تمام؟هو عبارة عن
+
+120
+00:09:06,760 --> 00:09:11,960
+العجل اللي بيتحكم أيضا ب .. بقرب العدسات الشيئية
+
+121
+00:09:11,960 --> 00:09:16,660
+من ال .. ال .. ال object ولكن كيف بيتم .. يعني أو
+
+122
+00:09:16,660 --> 00:09:24,750
+كيف بيتم تحكمه؟هو بيتحكم بعمق الصورة يتحكم بعمق
+
+123
+00:09:24,750 --> 00:09:28,150
+الصورة يعني ممكن يعرضلي تفاصيل مثلا هنا أقل أجبت
+
+124
+00:09:28,150 --> 00:09:32,070
+خلية بدي أشوفها خلية animal cell خلية حيوانية
+
+125
+00:09:32,070 --> 00:09:36,730
+تمام؟ هاي الخلية الحيوانية في في .. هي مش .. يعني
+
+126
+00:09:36,730 --> 00:09:41,850
+إيه؟ هي إلها أبعاد وإلها طول عرض ارتفاع تمام؟ طيب
+
+127
+00:09:41,850 --> 00:09:45,030
+و هاي الخلية في داخلها في عندي مثلا endoplasmic
+
+128
+00:09:45,030 --> 00:09:48,860
+reticulum شبكة endoplasmiaفيها geology apparatus،
+
+129
+00:09:48,860 --> 00:09:52,420
+جهاز geology، فيها نواة، فيها ريبوزومات، فيها
+
+130
+00:09:52,420 --> 00:09:56,760
+سيتوبلازم، تمام؟ هلأ، لو أنا أشوفها أول مرة، لما
+
+131
+00:09:56,760 --> 00:10:00,680
+أحطها على ال slide، و أقرب باستخدام ال course
+
+132
+00:10:00,680 --> 00:10:04,380
+adjustment، أقرب ال .. الاستاج من العدسة الشيئية،
+
+133
+00:10:04,380 --> 00:10:08,700
+و أشوفها، ممكن ما أشوف كل تفاصيل الصورة، يعني ممكن
+
+134
+00:10:08,700 --> 00:10:12,600
+بس تظهرلي ال membrane تبع الخلية، و تظهرلي النواة
+
+135
+00:10:12,600 --> 00:10:19,110
+فقط، لا غيرتمام؟ تظهر لي نواة الخلية فقط طيب لو
+
+136
+00:10:19,110 --> 00:10:22,670
+أنا بدي أشوف تفاصيل أكتر و هي مش موجودة .. يعني
+
+137
+00:10:22,670 --> 00:10:25,070
+هذه التفاصيل ممكن يكون جولجي مش موجودة على نفس
+
+138
+00:10:25,070 --> 00:10:29,350
+العمق تبع ال .. ال .. النوا ف .. او ال endoplasmic
+
+139
+00:10:29,350 --> 00:10:33,490
+reticulum مثلا مش موجودة على عمق جولجي تمام؟ لإنه
+
+140
+00:10:33,490 --> 00:10:38,160
+احنا حكينا الخلية إلها أبعادف ال .. ال fine
+
+141
+00:10:38,160 --> 00:10:43,320
+adjustment هو اللي بيتحكم بعمق الصورة يعني ممكن
+
+142
+00:10:43,320 --> 00:10:46,640
+إذا كان أنا الصورة الأولية كان فقط مبين فيها
+
+143
+00:10:46,640 --> 00:10:51,140
+membrane و نواة ال fine adjustment لما أحركه تمام
+
+144
+00:10:51,140 --> 00:10:56,110
+لما ألعبتيممكن يبينلي جولجي يختفي جولجي يتبين
+
+145
+00:10:56,110 --> 00:10:59,670
+endoplasmic reticulum إذا هو بيبحث على أبعاد أو
+
+146
+00:10:59,670 --> 00:11:04,310
+على أعماق مختلفة من الصورة ذات نفسها، تمام؟ ليش؟
+
+147
+00:11:04,310 --> 00:11:08,230
+لإن مكونات ال object المراد فحصه أحيانا بتكون
+
+148
+00:11:08,230 --> 00:11:11,290
+الشكلها على نفس المسافة لإن ال object هذا إله
+
+149
+00:11:11,290 --> 00:11:15,970
+أبعاد، تمام؟ إله أبعادفإذا ال fine adjustment
+
+150
+00:11:15,970 --> 00:11:20,910
+بيورجيني ال details تمام بيورجيني ال details هذا
+
+151
+00:11:20,910 --> 00:11:25,430
+ال fine adjustment بستخدمه خصوصا لو كنت أنا بفحص
+
+152
+00:11:25,430 --> 00:11:30,970
+العينة على ال high power objective lens علىال ..
+
+153
+00:11:30,970 --> 00:11:36,770
+العدسات الشيئية اللي قوة تكبيرها كبيرة نوع عامة
+
+154
+00:11:36,770 --> 00:11:41,710
+طيب، Condenser Adjustment فيه عندي أيضا نب قديب أو
+
+155
+00:11:41,710 --> 00:11:46,110
+عجل هنا هذا بسميه Condenser Adjustment إيش وظيفة
+
+156
+00:11:46,110 --> 00:11:49,790
+ال Condenser Adjustment؟ هو بيتحكم ه .. this moves
+
+157
+00:11:49,790 --> 00:11:53,850
+the condenser up or down بيحرك ال condenser إلى
+
+158
+00:11:53,850 --> 00:11:58,490
+أعلى و إلى أسفل، تمام؟ بيحرك إلى أعلى و إلى أسفل
+
+159
+00:11:59,380 --> 00:12:03,900
+فإذا خلّينا بس نرجع نشوف كيف بيتحرك هذا هو ال
+
+160
+00:12:03,900 --> 00:12:06,920
+condenser اللي هنا اللي هنا بنسميه condenser تحت
+
+161
+00:12:06,920 --> 00:12:10,580
+ال stage مباشرة وهي هذه عدسته اللي مبينة من فتحة
+
+162
+00:12:10,580 --> 00:12:15,560
+ال stage طيب إيش وظيفة ال condenser؟ هو بياخد
+
+163
+00:12:15,560 --> 00:12:18,000
+الضوء من ال light source هنا في عندي light source
+
+164
+00:12:18,000 --> 00:12:22,220
+في عندي لمبة بتعطيني ضوءبيستلم الضوء و من اسمه
+
+165
+00:12:22,220 --> 00:12:25,400
+condenser يكثف الضوء يجمعه علشان اللي جه الضوء
+
+166
+00:12:25,400 --> 00:12:29,400
+قادر يخترق العينة و يصل الى العدسة الشيئية فهنا
+
+167
+00:12:29,400 --> 00:12:34,980
+بيتم وصول صورة واضحة جدا الى العدسة الشيئية تمام؟
+
+168
+00:12:35,610 --> 00:12:42,390
+لإن الضوء تم تكثيفه واختراقه في ال .. في العينة
+
+169
+00:12:42,390 --> 00:12:47,050
+هلأ إحنا مثلا إيش مبدأ الرؤية طبعتنا؟ الأشياء ..
+
+170
+00:12:47,050 --> 00:12:50,510
+الضوء يسقط على الأشياء ينعكس إلى .. إلى عيوننا
+
+171
+00:12:50,510 --> 00:12:55,310
+فنرى الأشياء، صح؟ بدليل إنه بالعتمة إحنا ما بنشوف
+
+172
+00:12:55,990 --> 00:13:00,230
+لأنه مافيش ضوء يسقط على الأشياء وينعكس على عيوننا
+
+173
+00:13:00,230 --> 00:13:04,390
+فبالتالي ما .. ما بنشوف يعني بتكون الأشياء يعني
+
+174
+00:13:04,390 --> 00:13:13,450
+غير مرئية طبعا طيب فبالتالي اللي لازم أنه يكون في
+
+175
+00:13:13,450 --> 00:13:16,990
+عندي تجميع للضوء لحتى يسقط أو يخترق العين على اللي
+
+176
+00:13:16,990 --> 00:13:21,730
+يتم رؤية حتى العدسة الشيئية هي يمكنها رؤيتها طبعا
+
+177
+00:13:21,730 --> 00:13:28,870
+و تكبيرها وصورة أولية منهاطيب ال .. ال knob هذا
+
+178
+00:13:28,870 --> 00:13:31,590
+القضيب اللى عالجنب هنا من هنا اللى بنسميه
+
+179
+00:13:31,590 --> 00:13:38,390
+condenser adjustment هو بيتحكم ببعد او تحريك هذا
+
+180
+00:13:38,390 --> 00:13:42,930
+ال condenser up او down بنزله لتحت فبيبعد هذا ال
+
+181
+00:13:42,930 --> 00:13:47,070
+condenser عن ال stage فبصير كمية ضوء قليلة تخترق
+
+182
+00:13:47,070 --> 00:13:51,270
+العينة هذا يتناسب مع العدسات اللى قوة تكبيرها
+
+183
+00:13:51,270 --> 00:13:57,190
+قليلةو ممكن إن أنا أقربه من العدسة أحركه للأعلى
+
+184
+00:13:57,190 --> 00:14:01,230
+فيقترب أكتر من العينة فيصير يجمع لي كمية ضوء أكبر
+
+185
+00:14:01,230 --> 00:14:04,370
+لتختارق العينة وهذا يتناسب مع العدسات اللي قوة
+
+186
+00:14:04,370 --> 00:14:08,630
+تكبيرها كبيرة تمام؟ لإن مع العدسات اللي قوة
+
+187
+00:14:08,630 --> 00:14:13,090
+تكبيرها كبيرة احنا محتاجين كمية ضوء أكبر عشان
+
+188
+00:14:13,090 --> 00:14:19,180
+العدسة تتمكن من التقاط صورة مكبرة واضحةتمام؟ و مع
+
+189
+00:14:19,180 --> 00:14:24,060
+العدسات اللي قوة تكبيرها صغيرة محتاجين كمية ضوء
+
+190
+00:14:24,060 --> 00:14:27,100
+أقل تمام؟ للإضاءة
+
+191
+00:14:29,530 --> 00:14:33,230
+طيب، إذا صيرنا بنعرف إيش يعني course adjustment،
+
+192
+00:14:33,230 --> 00:14:37,970
+إيش يعني fine adjustment، وإيش معنى ال condenser
+
+193
+00:14:37,970 --> 00:14:43,470
+adjustment طيب، في مكون آخر أيضا يتحكم بكمية الضوء
+
+194
+00:14:43,470 --> 00:14:47,410
+اللي مارة للعينة، اللي هو عبارة عن ال iris
+
+195
+00:14:47,410 --> 00:14:52,110
+diaphragm، تمام؟ ال iris diaphragmخلينا نشوف إيش
+
+196
+00:14:52,110 --> 00:14:55,810
+هو ال iris diaphragm؟ ال iris diaphragm هو عبارة
+
+197
+00:14:55,810 --> 00:14:59,450
+عن اللسان المعدني هذا اللي مطرود هذا اللسان
+
+198
+00:14:59,450 --> 00:15:02,750
+المعدني هذا هو عبارة عن ال iris diaphragm اللي
+
+199
+00:15:02,750 --> 00:15:05,850
+أنتوا شايفينه طب هذا إيش وظيفته؟ شوفوا معايا
+
+200
+00:15:06,520 --> 00:15:10,340
+الcondenser موجود تحته القرص diaphragm، diaphragm
+
+201
+00:15:10,340 --> 00:15:16,220
+يعني حجاب أو يعني إشي .. يعني غطاء حاجز، هذا معناه
+
+202
+00:15:16,220 --> 00:15:21,780
+diaphragm طيب هذا ال .. ال .. القرص تبعه، القرص
+
+203
+00:15:21,780 --> 00:15:27,640
+diaphragm بيتحرك يمين و يسار و مع حركته بيسكر
+
+204
+00:15:27,640 --> 00:15:33,610
+الحجاب و بي .. و بيفتحطبعا إذا أغلق الحجاب إذا
+
+205
+00:15:33,610 --> 00:15:37,150
+كمية الضوء اللى واصل على الcondenser هتكون قليلة
+
+206
+00:15:37,150 --> 00:15:41,450
+فبالتالي كمية الضوء اللى تخترق العينة قليلة و هذا
+
+207
+00:15:41,450 --> 00:15:47,430
+حكينا أشماله أيضا يناسب من .. يناسب العدسات اللى
+
+208
+00:15:47,430 --> 00:15:54,270
+قوة تكبيرها قليلةوإذا تم فتح هذا القرص إذا الحجاب
+
+209
+00:15:54,270 --> 00:15:57,610
+مفتوح إذا كمية الضوء اللي بتعبر إلى الcondenser
+
+210
+00:15:57,610 --> 00:16:02,590
+كتيرة وكمية الضوء اللي يخترق العينة كبيرة فهذا
+
+211
+00:16:02,590 --> 00:16:08,260
+يناسب لعدسات اللي قوة تكبيرها كبيرةتمام؟ إذا في
+
+212
+00:16:08,260 --> 00:16:12,520
+عندي نوعين من التحكم في كمية الضوء اللي مارة
+
+213
+00:16:12,520 --> 00:16:18,960
+للعينة أول طريقة التحكم اللي هي عبارة عن ال .. ال
+
+214
+00:16:18,960 --> 00:16:23,120
+.. الـ Condenser Adjustment وطريقة التحكم الثانية
+
+215
+00:16:23,120 --> 00:16:27,180
+هي القرص الأكثر شيوعا واستخداما هي القرص يعني أنه
+
+216
+00:16:27,180 --> 00:16:30,680
+احنا بنستخدمها أكثر من أنه احنا نرفع وننزل
+
+217
+00:16:30,680 --> 00:16:34,150
+Condenserولكن يمكن استخدام أيضًا ال .. ال .. ال ..
+
+218
+00:16:34,150 --> 00:16:38,350
+الـ Condenser Adjustment Knob علشان نتحكم بكمية
+
+219
+00:16:38,350 --> 00:16:42,690
+الضوء اللي مارة إلى ال .. تخترق العينة وتمر إلى
+
+220
+00:16:42,690 --> 00:16:49,630
+العدسات الشيية تمام؟فهذا هو ال .. ال .. طريقة
+
+221
+00:16:49,630 --> 00:16:54,310
+التحكم course condenser adjustment وعندي كمان اللي
+
+222
+00:16:54,310 --> 00:16:56,830
+هو ال earth diaphragm هاي هنا بيحكيلي the
+
+223
+00:16:56,830 --> 00:17:00,950
+principal purpose of the condenser is to condense
+
+224
+00:17:00,950 --> 00:17:04,690
+the light وظيفته ال condenser انه يكسر في الضوء
+
+225
+00:17:04,690 --> 00:17:07,870
+اللي .. و .. اللي يخترق العينة و اللي احنا
+
+226
+00:17:07,870 --> 00:17:12,430
+محتاجينه لاش لل visualization للاضاح و ال .. و ال
+
+227
+00:17:12,430 --> 00:17:18,260
+.. و التكبير و انه التقاط صورة واضحةطيب، حكينا
+
+228
+00:17:18,260 --> 00:17:22,920
+لحتى الآن عن ال frame، الهيكل للميكروسكوب، حكينا
+
+229
+00:17:22,920 --> 00:17:27,600
+عن جهاز التركيز أو نظام التركيز اللي هو عبارة عن
+
+230
+00:17:27,600 --> 00:17:31,580
+course adjustment, fine adjustment, condenser
+
+231
+00:17:31,580 --> 00:17:38,590
+adjustment و ال iris diaphragmو أيضًا راح نحكي عن
+
+232
+00:17:38,590 --> 00:17:41,770
+نظام التكبير، طبعًا؟ خلّيني أحكينا عن نظام
+
+233
+00:17:41,770 --> 00:17:46,230
+التركيز، هنحكي عن نظام التكبير، طبعًا؟ ما هي
+
+234
+00:17:46,230 --> 00:17:50,730
+الأدوات اللي مسؤولة عن تكبير ال object في ال
+
+235
+00:17:50,730 --> 00:17:56,150
+microscope؟ هي ال objective lenses، طبعًا؟ و ال
+
+236
+00:17:56,150 --> 00:17:59,130
+ocular lenses، إذا العدسات اللي موجودة في ال
+
+237
+00:17:59,130 --> 00:18:04,480
+microscope هي اللي مسؤولة عن التكبيرفي عندى عدسات
+
+238
+00:18:04,480 --> 00:18:09,000
+objective lenses تمام ومن اسمها objective ليش
+
+239
+00:18:09,000 --> 00:18:12,120
+تسمينها objective لإنها قريبة من ال object المراد
+
+240
+00:18:12,120 --> 00:18:17,700
+فحصه تمام قريبة من ال object المراد فحصه لذلك تسمى
+
+241
+00:18:17,700 --> 00:18:23,760
+objectiveطيب هذه العدسات أربعة، كل عدسة إلها قوة
+
+242
+00:18:23,760 --> 00:18:29,160
+تكبير مختلفة، هي أنا عندي 4x يعني ال .. ال object
+
+243
+00:18:29,160 --> 00:18:34,760
+بيكون مكبر أربع مرات، تمام؟ ال .. في .. في الصورة
+
+244
+00:18:34,760 --> 00:18:38,100
+الأولية اللي يتم التقاطها
+
+245
+00:18:39,060 --> 00:18:44,300
+تمام؟ هنا ال object بيتم تكبيره 10x يعني عشر مرات
+
+246
+00:18:44,300 --> 00:18:49,180
+في الصورة الأولية، هنا عندي 40x وهنا 100x تمام؟
+
+247
+00:18:49,180 --> 00:18:54,300
+لما أحكيلك low power objective تمام؟ يعني قوة
+
+248
+00:18:54,300 --> 00:18:56,980
+تكبير قليلة من ال objective معناها بدك تستخدم
+
+249
+00:18:56,980 --> 00:19:01,210
+العدسة أربعة أو عشرةلمّا أحكيلك high power
+
+250
+00:19:01,210 --> 00:19:05,130
+objective يعني بدك تستخدم العدسة أربعين، لما
+
+251
+00:19:05,130 --> 00:19:09,190
+أحكيلك oil immersion objective يعني العدسة مية،
+
+252
+00:19:09,190 --> 00:19:13,670
+تمام؟ إذا إما بحبنعرفهم بقوة التكبير تبعتهم أو
+
+253
+00:19:13,670 --> 00:19:18,370
+بpower تبعهم، هذه low power, high power, oil
+
+254
+00:19:18,370 --> 00:19:18,850
+immersion
+
+255
+00:19:21,980 --> 00:19:27,360
+طيب إذا و العدسات العينية هي ال upper optical
+
+256
+00:19:27,360 --> 00:19:30,260
+component اللي هي الجزء اللي .. اللي إحنا بنشوف
+
+257
+00:19:30,260 --> 00:19:35,520
+فيه و بيكون موجود في أعلى ال microscope و طبعا
+
+258
+00:19:35,520 --> 00:19:39,960
+وظيفة حكينا إنه العدسات الشيئية بتلتقط صورة أولية
+
+259
+00:19:39,960 --> 00:19:46,880
+مكبرة إما 4X أو 10X أو 40X أو 100Xتمام؟ هذه الصورة
+
+260
+00:19:46,880 --> 00:19:54,070
+الأولية تمام بتنتقل عبر ال tube إلى ال .. ال ..الـ
+
+261
+00:19:54,070 --> 00:19:58,190
+ocular lenses فهي ال ocular lenses وظيفتها انها
+
+262
+00:19:58,190 --> 00:20:03,030
+magnify the primary image بتكبر الصورة الأولية مرة
+
+263
+00:20:03,030 --> 00:20:06,810
+أخرى تمام؟ و هذه العدسات موجودة ممكن يكون قوة
+
+264
+00:20:06,810 --> 00:20:13,290
+تكبيرها 4x, 6x, 7x او 10 او حتى 15 او 20x تمام؟
+
+265
+00:20:13,290 --> 00:20:16,630
+فإذا إلها قوات تكبير مختلفة ال more common use
+
+266
+00:20:16,630 --> 00:20:20,150
+اللي انتوا هتستخدموه مايكروسكوبات ال ocular lenses
+
+267
+00:20:20,150 --> 00:20:26,760
+تبعتها 10xتمام؟ ف .. اذا ان هي بتكبر الصورة
+
+268
+00:20:26,760 --> 00:20:31,840
+المبدئية او الاولية اللى وصلتها من ال objective فى
+
+269
+00:20:31,840 --> 00:20:41,160
+عندى microscope و ال .. طبعا ال .. بنوعين حسب عدد
+
+270
+00:20:41,160 --> 00:20:44,800
+ال eyepiece اللى موجود فيه فى عندى ال microscope
+
+271
+00:20:44,800 --> 00:20:48,960
+اللى بيكون فيه one ocular lenses او one eyepiece
+
+272
+00:20:49,460 --> 00:20:57,700
+بنسمي mono-ocular طبعا إذا كان في عدستين عينية two
+
+273
+00:20:57,700 --> 00:21:02,880
+او اوكيولار lenses بنسمي bi-ocular طبعا إذا ال
+
+274
+00:21:02,880 --> 00:21:06,340
+microscope بنسمي bi-ocular او mono-ocular حسب عدد
+
+275
+00:21:06,340 --> 00:21:10,600
+العدسات العينية اللي موجودة فيه جدير بتذكر انه
+
+276
+00:21:10,600 --> 00:21:14,360
+احكي eyepiece او احكي اوكيولار lenses نفس المعنى
+
+277
+00:21:16,460 --> 00:21:21,920
+طيب حكينا عن جهاز أو نظام التكبير نحكي عن نظام ال
+
+278
+00:21:21,920 --> 00:21:26,500
+illumination الإضاءة و التحكم بالإضاءة أيضا ال
+
+279
+00:21:26,500 --> 00:21:32,720
+condenser و ال iris من ال .. يتبعوا للنظام التوضيح
+
+280
+00:21:32,720 --> 00:21:36,650
+و الإضاءة تمام؟اللي هو احنا حكينا الـ Condenser
+
+281
+00:21:36,650 --> 00:21:40,330
+وظيفته انه بي .. بيجمع الضوء اللي واصله من ال
+
+282
+00:21:40,330 --> 00:21:43,550
+light source تمام؟ و بيخليه يختارق العينة اللي
+
+283
+00:21:43,550 --> 00:21:47,190
+يمكن رؤية الصورة الأولية بوسط ال objective lens
+
+284
+00:21:47,190 --> 00:21:52,070
+تمام؟و ده هي ال .. the condenser عدسة ال condenser
+
+285
+00:21:52,070 --> 00:21:55,710
+هاي اللي بتكون .. حكينا بتكون مبينة من فتحة ال ..
+
+286
+00:21:55,710 --> 00:21:59,150
+ال .. ال stage بتكون تستلم الضوء من وين؟ من ال
+
+287
+00:21:59,150 --> 00:22:02,850
+light source و بتمرره خلال العينة و إلى ال
+
+288
+00:22:02,850 --> 00:22:05,890
+objective هذا ال earth ده في الرقم شايفينه بيكون
+
+289
+00:22:05,890 --> 00:22:07,230
+موجود تحت ال condenser
+
+290
+00:22:12,640 --> 00:22:19,000
+طبعا مع حركة القرص هذا زي حجاب بيسكر و بيفتح، طبعا
+
+291
+00:22:19,000 --> 00:22:22,720
+بيسكر و بيفتح، اذا بتحكم بكمية الضوء اللي مارة من
+
+292
+00:22:22,720 --> 00:22:26,140
+ال light source إلى الcondenserهين زي ما انتوا
+
+293
+00:22:26,140 --> 00:22:29,460
+شايفين هي هذا القرص مفتوح على الآخر، هذا مغلق
+
+294
+00:22:29,460 --> 00:22:33,580
+شوية، هذا مغلق أكتر، فإذا حسب حركة ال .. ال ..
+
+295
+00:22:33,580 --> 00:22:37,480
+القرص diaphragm هذا بي .. بي .. بيسكرلي ال
+
+296
+00:22:37,480 --> 00:22:42,130
+diaphragm أو بيفتحهمتمام؟ إذا the iris is
+
+297
+00:22:42,130 --> 00:22:46,230
+mechanical device mounted underneath the condenser
+
+298
+00:22:46,230 --> 00:22:50,930
+موجودة تحت الcondenser and controls the amount of
+
+299
+00:22:50,930 --> 00:22:55,470
+light بتتحكم بكمية الضوء اللي فايت على الcondenser
+
+300
+00:22:55,470 --> 00:22:58,730
+من وين؟ من ال light source تمام؟ من ال light
+
+301
+00:22:58,730 --> 00:23:03,710
+source يوجد أيضا أحيانا بيكون mirror وين بتكون ال
+
+302
+00:23:03,710 --> 00:23:08,020
+mirror هادي؟نرجع لصورة ال microscope بيكون هنا
+
+303
+00:23:08,020 --> 00:23:12,040
+أحيانا فوق ال light source بيكون فيه مراية ليش؟
+
+304
+00:23:12,040 --> 00:23:15,180
+المراية هذه وظيفتها أنها تاخد الضوء اللي جاي من ال
+
+305
+00:23:15,180 --> 00:23:21,000
+light source و تعكسه لحتى يتم انعكاسه إلى ال
+
+306
+00:23:21,000 --> 00:23:25,020
+condenser تمام؟ لينعكس إلى ال condenser بس يعني
+
+307
+00:23:25,020 --> 00:23:32,720
+لتعزيز كفاءة استخدام الضوء فقط لا غير أحيانا في ..
+
+308
+00:23:34,540 --> 00:23:37,880
+مايكروسكوبات ما بتعمل على .. يعني مافيها لمبة
+
+309
+00:23:37,880 --> 00:23:41,100
+بتعمل على ضوء النهار أو ضوء المنطقة المحيطة فيها
+
+310
+00:23:41,100 --> 00:23:44,720
+فلازم يكون في عندي عدسة جامع على الضوء و .. لحتى
+
+311
+00:23:44,720 --> 00:23:47,360
+تجمع الضوء اللي موجود في المنطقة اللي موجود فيها
+
+312
+00:23:47,360 --> 00:23:51,880
+المايكروسكوب و توجهه باتجاه الـ Condenserتمام؟
+
+313
+00:23:51,880 --> 00:23:57,120
+فإذا هذه فائدة الـ mirror الـ mirror بتكون تحت الـ
+
+314
+00:23:57,120 --> 00:24:02,260
+condenser و تحت القرص أيضا و فوق ال light source
+
+315
+00:24:02,260 --> 00:24:06,440
+مباشرة و إيش وظيفتها reflect the beam of light
+
+316
+00:24:06,440 --> 00:24:10,560
+تعكس اللي هو الضوء إلى .. باتجاه ال condenser into
+
+317
+00:24:10,560 --> 00:24:16,580
+the condenserماشي و سواء كان هذا الضوء جاي من ال
+
+318
+00:24:16,580 --> 00:24:19,520
+daylight أو من ال electrical light من الضوء
+
+319
+00:24:19,520 --> 00:24:21,860
+الكهربائي أو اللمبة اللي موجودة في ال microscope
+
+320
+00:24:23,750 --> 00:24:28,950
+طيب إذا مصادر الإضاءة daylight اللي هو يعني ضوء
+
+321
+00:24:28,950 --> 00:24:34,330
+المحيط بالجهاز يعني إن أكتفي بالضوء للنهار مثلا و
+
+322
+00:24:34,330 --> 00:24:40,110
+هذا ممكن يكون sufficient يعني كافي في بعض الأشياء
+
+323
+00:24:40,110 --> 00:24:44,750
+ولكن أحيانا بيكون غير كافي إذا أنا بدأ أستخدم قوة
+
+324
+00:24:44,750 --> 00:24:47,650
+تكبير كبيرة زي ال oil immersion اللي هي ال 100x
+
+325
+00:24:47,950 --> 00:24:52,430
+حكينا إنه مع القوة التكبير القليلة، تمام؟ ال
+
+326
+00:24:52,430 --> 00:24:56,070
+objective lenses ما بتكون محتاجة ضوء كتير، لكن مع
+
+327
+00:24:56,070 --> 00:24:59,630
+ال .. ال .. القوة التكبير العالية، ال objective
+
+328
+00:24:59,630 --> 00:25:05,190
+بتكون محتاجة كمية ضوء أكبر، تمام؟ بتكون محتاجة
+
+329
+00:25:05,190 --> 00:25:12,510
+كمية ضوء أكبر ال electric light، تمام؟اللي هو ال
+
+330
+00:25:12,510 --> 00:25:16,830
+.. ال .. ال مصدر الضوء اللمبة بتكون tungsten lamp
+
+331
+00:25:16,830 --> 00:25:20,810
+تمام؟ بتكون tungsten lamp أحيانا ممكن تكون طبعا
+
+332
+00:25:20,810 --> 00:25:25,230
+tungsten lamp أو quartz halogen lamp حسب يعني نوع
+
+333
+00:25:25,230 --> 00:25:28,850
+ال microscope و حسب نوع الإضاءة .. النوع الإضاءة
+
+334
+00:25:28,850 --> 00:25:34,050
+اللي موجودة أو اللي إحنا محتاجينها طبعا في ال
+
+335
+00:25:34,050 --> 00:25:39,590
+microscopeطيب فلاتر أحيانا بيكون أيضا موجود في ال
+
+336
+00:25:39,590 --> 00:25:43,990
+.. ال .. ال .. ال illumination system فلاتر
+
+337
+00:25:47,230 --> 00:25:50,630
+طيب الفيلتر هذا عبارة عن إيش؟ هو عبارة عن قطعة
+
+338
+00:25:50,630 --> 00:25:55,790
+زجاجية ملونة تمام؟ وإيش وظيفته؟ بيقلل شدة الضوء
+
+339
+00:25:55,790 --> 00:25:58,970
+اللي مع ال rubber دو كمان بيكون موجود الفيلتر
+
+340
+00:25:58,970 --> 00:26:04,910
+موجود يعني الممكن أحطه هنا هو بيه طبعا هو اللي
+
+341
+00:26:04,910 --> 00:26:09,530
+بتحكي يعني ممكن أنا أركبه أو أشيله تمام؟ يعني أنا
+
+342
+00:26:09,530 --> 00:26:13,110
+بتحكم بإن هو موجود أو غير موجود بس هو بيجي مع ال
+
+343
+00:26:13,110 --> 00:26:17,370
+microscope فلاتر ضوئيةتمام قطعة زجاجية ملونة بتكون
+
+344
+00:26:17,370 --> 00:26:22,170
+موجودة على ال .. ال light source أنا بحطها على ال
+
+345
+00:26:22,170 --> 00:26:25,250
+light source هنا عشان تتحكم بكمية الضوء اللي
+
+346
+00:26:25,250 --> 00:26:29,650
+موجودة ولعل هذه الفكرة طرحناها في محاضرة ال
+
+347
+00:26:29,650 --> 00:26:34,510
+calorie meter وذكرنا انهلو كان في عندي لمبة و أنا
+
+348
+00:26:34,510 --> 00:26:39,850
+حطيت زجاج ملون هذا الزجاج .. الزجاج راح يحجب كمية
+
+349
+00:26:39,850 --> 00:26:46,010
+من الضوء و يمرر ما تبقى، تمام؟ إذا هو بيتحكم بكمية
+
+350
+00:26:46,010 --> 00:26:48,830
+الضوء اللي موجودة أو اللي .. اللي تعبر إلى
+
+351
+00:26:48,830 --> 00:26:52,850
+الcondenser و من ثم إلى ال objectiveطيب ممكن كمان
+
+352
+00:26:52,850 --> 00:26:56,270
+أحيانا في بعض الأجزاء خصوصا الأجزاء اللي غير
+
+353
+00:26:56,270 --> 00:27:02,310
+مسبوغة ممكن يزيد الإيضاح increase resolution تمام؟
+
+354
+00:27:02,310 --> 00:27:06,370
+لإنه في بعض الأشياء اللي احنا بنكون محتاجين نشوفها
+
+355
+00:27:06,530 --> 00:27:12,830
+بتكون هي معتمة، تمام؟ فمش محتاجة ضو كتير يخليها
+
+356
+00:27:12,830 --> 00:27:17,890
+فاتحة و غير مرئية طيب و أيضا كمان وظيفة ال filter
+
+357
+00:27:17,890 --> 00:27:21,190
+انه protect the eye from injury، هلأ احنا مع
+
+358
+00:27:21,190 --> 00:27:28,650
+الاستخدامالمطول لـ Microscope بيتم .. بيصير يعني
+
+359
+00:27:28,650 --> 00:27:32,030
+لمعة الضوء في عينا مؤضية فممكن نستخدم ال filter
+
+360
+00:27:32,030 --> 00:27:35,050
+عشان نحد من كمية الضوء اللي يعني بيخبط في عينا
+
+361
+00:27:35,050 --> 00:27:40,770
+فبالتالي او انه يعني نحافظ على سلامة العين او نكون
+
+362
+00:27:40,770 --> 00:27:45,930
+مرتاحين اكثر و احنا بنشتغل طيب، هيك بنكون عرضنا
+
+363
+00:27:45,930 --> 00:27:53,240
+مكونات ال .. ال .. ال microscopeسردناها كصرد أولي
+
+364
+00:27:53,240 --> 00:27:57,740
+و بعد هيك حكينا إنها مكون من أجزاء الجزء الأول هو
+
+365
+00:27:57,740 --> 00:28:03,260
+الهيكل تلت .. تلت مناطق منطقة ال arm و ال stage و
+
+366
+00:28:03,260 --> 00:28:07,820
+منطقة ال base الجزء الثاني هو منطق اللي هو ال
+
+367
+00:28:07,820 --> 00:28:10,900
+focusing system اللي هو عبارة عن ال course و ال
+
+368
+00:28:10,900 --> 00:28:14,220
+fine adjustment و أيضا ال condenser adjustment و
+
+369
+00:28:14,220 --> 00:28:18,000
+ممكن ييجي معهم القرص حكينا بعدين عن ال elimination
+
+370
+00:28:18,000 --> 00:28:23,560
+system اللي هوالإضاءة ال light source و أيضًا كمان
+
+371
+00:28:23,560 --> 00:28:27,400
+ال condenser و القرص ممكن يكونوا جزء من ال light
+
+372
+00:28:27,400 --> 00:28:32,040
+source او من ال illumination system و ال filter و
+
+373
+00:28:32,040 --> 00:28:36,360
+ال mirror حكينا عن ال magnification system نظام
+
+374
+00:28:36,360 --> 00:28:40,740
+التكبير اللي هو يشمل ال objective lenses و ال
+
+375
+00:28:40,740 --> 00:28:46,070
+ocular lensesطبعا حتى كمان شدة الضوء يا بنات ممكن
+
+376
+00:28:46,070 --> 00:28:50,830
+انا اتحكم فيها من هنا في عندي عجل بيزود الضوء ل ..
+
+377
+00:28:50,830 --> 00:28:56,110
+الضوء اللامبا نفسها بيزود .. بيزودها و بيقلل طبعا
+
+378
+00:28:56,110 --> 00:29:00,610
+و في .. في كبسة أيضا هنا موجودة بتفتح و بتسكر
+
+379
+00:29:00,610 --> 00:29:10,190
+الضوء طيب هذا بالنسبة لال ..مكونات خلينا نشوف مبدأ
+
+380
+00:29:10,190 --> 00:29:13,770
+عمل ال oil immersion ليش احنا بنحكي عن العدسة اللي
+
+381
+00:29:13,770 --> 00:29:22,010
+قوة تكبيرها 100X تمام؟ ليش بنسميها oil immersion؟
+
+382
+00:29:22,010 --> 00:29:26,670
+تمام طيب قبل ان نحكي عن ال oil immersion خلينا
+
+383
+00:29:26,670 --> 00:29:31,100
+نحكي عن ال microscope بشكل عام ايش مبدأ عمله؟ال ..
+
+384
+00:29:31,100 --> 00:29:35,940
+ال microscope بشكل عام هو magnifying instrument،
+
+385
+00:29:35,940 --> 00:29:42,500
+هو عبارة عن جهاز تكبير، تمام؟ و الصورة اللي بتصل
+
+386
+00:29:42,500 --> 00:29:46,400
+ال .. ال .. طبعا ال .. ال .. لأ ال objective
+
+387
+00:29:46,400 --> 00:29:51,320
+lenses بتكون هي عبارة عن ال primary، تمام؟ image
+
+388
+00:29:52,800 --> 00:29:56,920
+بأول حاجة الضوء بيخترق ال object اللى موجودة على
+
+389
+00:29:56,920 --> 00:30:00,760
+ال stage تمام وبيصل الى ال objective ف ال
+
+390
+00:30:00,760 --> 00:30:05,040
+objective هتجمع الضوء هذا و تلتقط صورة الصورة هاي
+
+391
+00:30:05,040 --> 00:30:09,420
+عبارة عن ال primary image مكبرة بقوة تكبير ال
+
+392
+00:30:09,420 --> 00:30:15,300
+objectiveتمام؟ هذه الصورة راح تنتقل إلى عدسة أخرى
+
+393
+00:30:15,300 --> 00:30:18,020
+اللي هي near the eye بالقرب من العين عشان هيك
+
+394
+00:30:18,020 --> 00:30:22,220
+بنسميها ocular lenses أو eyepiece و هذه العدسة
+
+395
+00:30:22,220 --> 00:30:27,140
+العينية راح تكبر ال primary image مرة ثانية تمام؟
+
+396
+00:30:27,140 --> 00:30:32,100
+إذا أنا ممكن أعرف ال total magnification التكبير
+
+397
+00:30:32,100 --> 00:30:37,100
+الكل للميكروسكوب أو للصورة اللي أنا عم بشوفها هو
+
+398
+00:30:37,100 --> 00:30:41,160
+عبارة عن حاصل تكبير ال objective lens ضربحاصل
+
+399
+00:30:41,160 --> 00:30:45,500
+تكبير ال .. ال .. ال ocular lens أو ال Ibs يعني
+
+400
+00:30:45,500 --> 00:30:49,200
+مثلا لو كنت أنا مستخدمة ب .. بشوف خلايا بكتيرية
+
+401
+00:30:49,200 --> 00:30:54,770
+على العدسة عشرة X objective تمام؟وعندي ال IBS
+
+402
+00:30:54,770 --> 00:30:58,750
+حكيتلكم ال most common انها تكون عشرة في قوة تكبير
+
+403
+00:30:58,750 --> 00:31:02,590
+أخرى ولكن احنا عندنا اللي بنستخدمهم عشرة طيب طيب
+
+404
+00:31:02,590 --> 00:31:07,590
+العدسة الشيئية التقطت صورة مكبرة عشر مرات عشرة X
+
+405
+00:31:07,590 --> 00:31:11,970
+ونقلتها إلى ال IBS فكبرتها أيضا عشر مرات اذا
+
+406
+00:31:11,970 --> 00:31:17,290
+التكبير ال total هو عبارة عن عشرة في عشرة ميت X
+
+407
+00:31:17,290 --> 00:31:22,560
+بتكون مكبرة ميتAX 100 مرة تمام هذا ال total
+
+408
+00:31:22,560 --> 00:31:26,020
+magnification طيب لو أنا كنت مستخدمة ال 40X اللي
+
+409
+00:31:26,020 --> 00:31:31,710
+هي ال high power lensفالصورة الأولية هتتكبر 40x
+
+410
+00:31:31,710 --> 00:31:36,050
+ويتنتقل إلى ال Ibs فهتكبرها عشر مرات كمان فالتكبير
+
+411
+00:31:36,050 --> 00:31:40,450
+الكل هيكون 400 تمام؟ في ال oil immersion أو ال
+
+412
+00:31:40,450 --> 00:31:46,130
+100x هتكون الصورة الأولية مكبرة 100 مرة ويتنتقل
+
+413
+00:31:46,130 --> 00:31:50,330
+إلى ال Ibs فتكبرها عشر مرات كمان فبصير في عندي
+
+414
+00:31:50,330 --> 00:32:00,110
+التكبير الكل ألف x تمام؟ ألف xطيب إذا الـ total
+
+415
+00:32:00,110 --> 00:32:04,730
+magnification هو عبارة عن ال .. ال magnification
+
+416
+00:32:04,730 --> 00:32:09,250
+of .. of objective تكبير العدسة الشيئية multiplied
+
+417
+00:32:09,250 --> 00:32:14,230
+مضروب ب that of the eyepiece بتكبير العدسة ال
+
+418
+00:32:14,230 --> 00:32:19,740
+eyepiece وهذا بنسميه ال total magnification طيبطيب
+
+419
+00:32:19,740 --> 00:32:24,840
+ال numerical aperture مصطلح لازم نذكره قبل نشرح
+
+420
+00:32:24,840 --> 00:32:31,920
+مبدأ عمل العدسة ال oil immersion يعني هاي الشغلات
+
+421
+00:32:31,920 --> 00:32:36,350
+لازم نذكرها قبل تمام the numerical apertureال
+
+422
+00:32:36,350 --> 00:32:40,510
+numerical aperture هو عبارة عن the amount أو
+
+423
+00:32:40,510 --> 00:32:45,770
+amount of light entering the objective from the
+
+424
+00:32:45,770 --> 00:32:50,410
+microscopic field كمية الضوء اللي بتصل إلى العدسة
+
+425
+00:32:50,410 --> 00:32:55,790
+الشيئية بنسميها numerical aperture طب ماذا يتحكم
+
+426
+00:32:55,790 --> 00:33:00,290
+بكمية الضوء اللي مار إلى العدسة الشيئية؟ حكينا ال
+
+427
+00:33:00,290 --> 00:33:05,360
+condenserوالارس ده فراجم وجود mirror أو لأ وجود
+
+428
+00:33:05,360 --> 00:33:09,180
+filter أو لأ شدة الضوء أصلا في ال light source قرب
+
+429
+00:33:09,180 --> 00:33:13,060
+الcondenser و بعضه عن ال .. ال .. ال stage كل هذه
+
+430
+00:33:13,060 --> 00:33:17,060
+عوامل تؤثر في كمية الضوء اللي مار إلى العدسة
+
+431
+00:33:17,060 --> 00:33:21,860
+الشيئية تمام؟ طيب لو أنا بدي أجي أحسبه بقانون
+
+432
+00:33:21,860 --> 00:33:27,070
+بينحسب PRفي sign لم يو، إيش sign لم يو هذه؟ تشوفوا
+
+433
+00:33:27,070 --> 00:33:34,170
+معايا R هو ال refractive index of glassاللي هو
+
+434
+00:33:34,170 --> 00:33:37,810
+يعني معامل انكسار الزجاج لإنه العدسة هي زجاج يعني
+
+435
+00:33:37,810 --> 00:33:42,110
+الضوء أصلا بيطلع من لمبة زجاجية و بيفوت على
+
+436
+00:33:42,110 --> 00:33:45,930
+الcondenser و عدسته زجاجية بيخترق ال slide اللي هي
+
+437
+00:33:45,930 --> 00:33:50,850
+عدسة زجاجية او اللي هي شريحة زجاجية sorry و بيروح
+
+438
+00:33:50,850 --> 00:33:53,710
+على ال objective أيضا ال objective اللي الضوء بيمر
+
+439
+00:33:53,710 --> 00:33:56,590
+من خلالها هي عدسة زجاجية إذا لازم أنا أستخدم ال
+
+440
+00:33:56,590 --> 00:34:00,830
+refractive index of glass تمام؟طيب الـmu هي عبارة
+
+441
+00:34:00,830 --> 00:34:04,410
+عن إيش الـmu هذه؟ هي الزاوية اللي يصنعها الشعاع
+
+442
+00:34:04,410 --> 00:34:09,010
+اللي يمر بمركز أو منتصف العدسة مع الشعاع اللي يمر
+
+443
+00:34:09,010 --> 00:34:13,930
+بحافة العدسة أو بطرف العدسة، طبعا؟ الشعاع يمر
+
+444
+00:34:13,930 --> 00:34:17,770
+بمركز، تخيلوا أرسموه بشكل وهمي و الشعاع اللي يمر
+
+445
+00:34:17,770 --> 00:34:22,330
+بحافة العدسة، هذه الزاوية بنسميها الـmu أو هذه
+
+446
+00:34:22,330 --> 00:34:25,450
+الـmu، واحدة منهم، طبعا؟ فهذه
+
+447
+00:34:27,650 --> 00:34:32,750
+الزاوية assign لميو يستخدم في حساب ال numerical
+
+448
+00:34:32,750 --> 00:34:36,290
+aperture طيب بيحكيلي هنا ال numerical aperture
+
+449
+00:34:37,410 --> 00:34:41,510
+depend on the radius of the lens تمام؟ هذا ال
+
+450
+00:34:41,510 --> 00:34:48,370
+numerical aperture يعتمد على القطر العدسة اه والله
+
+451
+00:34:48,370 --> 00:34:55,010
+كل ما زاد قطر العدسة تمام؟ شايفين؟ كل ما زاد قطر
+
+452
+00:34:55,010 --> 00:35:02,520
+العدسة معناها انه ال .. ال ..الزاوية ال new ها دي
+
+453
+00:35:02,520 --> 00:35:06,940
+أكبر تمام و محتاجة ضوء أكتر هي دي شايفين كمية
+
+454
+00:35:06,940 --> 00:35:10,020
+الضوء اللي فاتة أكتر فبالتالي ال numerical
+
+455
+00:35:10,020 --> 00:35:14,280
+aperture يعتبد على قطر العدسة هي هنا مثلا مثلا
+
+456
+00:35:14,280 --> 00:35:19,840
+شايفين numerical aperture 95% كمية الضوء كبيرة
+
+457
+00:35:19,840 --> 00:35:24,700
+هنقل numerical aperture قلت كمية الضوء فقلت و قلت
+
+458
+00:35:24,700 --> 00:35:27,640
+أكتر فأكترنتيجة ان ال numerical aperture قليلة،
+
+459
+00:35:27,640 --> 00:35:30,480
+اذا هو بيعبرلي عن ايش كمية الضوء اللى بده تروح على
+
+460
+00:35:30,480 --> 00:35:36,080
+ال objective lens، على العدسة الشيئية، تمام؟ اذا و
+
+461
+00:35:36,080 --> 00:35:39,240
+بنحسبه بالR، refractive index of glass، حكينا لإن
+
+462
+00:35:39,240 --> 00:35:42,780
+العدسة مصنوعة من ال glass، و ايضا ال mu اللى هى ال
+
+463
+00:35:42,780 --> 00:35:47,220
+angle، الزاوية اللى مصنوعة made by، مصنوعة من Ray،
+
+464
+00:35:47,220 --> 00:35:53,690
+شعاريمر بي الحافة العدسة the edge of lens والتاني
+
+465
+00:35:53,690 --> 00:35:59,110
+يمر بي the center of the lens مركز العدسة تمام
+
+466
+00:35:59,110 --> 00:36:06,230
+resolving power قوة الإضاح تمام؟ وطيب جدير بالذكر
+
+467
+00:36:06,230 --> 00:36:10,970
+او يعني حتى اذكر احنا حكينا معلومة مهمة انه
+
+468
+00:36:10,970 --> 00:36:19,030
+العدسات اللي قوة تكبيرهاكبيرة تمام محتاجة ان ضوء
+
+469
+00:36:19,030 --> 00:36:23,130
+اكثر فمحتاجة ان انا مثلا افتح القرص عشان اتمكن انه
+
+470
+00:36:23,130 --> 00:36:29,250
+ان الضوء يصل ال condenser اكثر اما العدسات اللي
+
+471
+00:36:29,250 --> 00:36:34,930
+قوة تكبيرها قليلة زي ال low power lens تمام هى
+
+472
+00:36:34,930 --> 00:36:40,510
+بتكون مش محتاجة ضوء كتير فبالتالي ممكن انا اسكر
+
+473
+00:36:40,510 --> 00:36:43,910
+القرص عشان كمية الضوء اللي نافظة العدسة تكون قليلة
+
+474
+00:36:47,590 --> 00:36:53,950
+resolving power اللي هي قوة التكبير، تمام؟ هي يعني
+
+475
+00:36:53,950 --> 00:36:56,430
+التوظيف لل magnification، بنعبر عن ال
+
+476
+00:36:56,430 --> 00:37:00,070
+magnification باستخدام ال resolving power، بنعبر
+
+477
+00:37:00,070 --> 00:37:01,770
+عن التكبير بقوة الإضاءة
+
+478
+00:37:04,950 --> 00:37:09,230
+يُعرف هذا ال resolving power بإن هو the ability of
+
+479
+00:37:09,230 --> 00:37:12,750
+microscope قدرة الميكروسكوب at the specific
+
+480
+00:37:12,750 --> 00:37:17,210
+magnification على قوة تكبير معينة to distinguish
+
+481
+00:37:17,210 --> 00:37:22,590
+أنه يميز two separate objects situated close to
+
+482
+00:37:22,590 --> 00:37:26,410
+one another أنه يميز ما بين نقطتين أو two objects
+
+483
+00:37:26,410 --> 00:37:29,850
+أو منصرين موجودين في الشريحة أو في العينة المراد
+
+484
+00:37:29,850 --> 00:37:34,150
+فحصها ويكونوا قراب من بعضهم البعضفكل ما كانت
+
+485
+00:37:34,150 --> 00:37:37,070
+المسافة ما بين هدول ال two objects هدول النقطتين
+
+486
+00:37:37,070 --> 00:37:41,310
+أو العنصرين كل ما كانت المسافة ما بينهم قليلة the
+
+487
+00:37:41,310 --> 00:37:46,790
+smaller the distance تمام؟ the smaller the
+
+488
+00:37:46,790 --> 00:37:50,850
+distance هيكون انه ال .. ال .. ال .. ال .. كل ما
+
+489
+00:37:50,850 --> 00:37:55,530
+كانت المسافة ما بينهم صغيرة وتمكن ال microscope من
+
+490
+00:37:55,530 --> 00:37:59,930
+إيضاحهم وتكبيرهم إذا والله هذا ال microscope عنده
+
+491
+00:37:59,930 --> 00:38:05,310
+greater resolution power تمام؟عنده قوة إيضاح أكبر
+
+492
+00:38:05,310 --> 00:38:12,770
+طالما أن هو بيفصللي يعني تفاصيل وبيوضحلي يعني نقاط
+
+493
+00:38:12,770 --> 00:38:16,750
+أو عناصر أو أشياء قريبة جدا من بعضهم البعض المسافة
+
+494
+00:38:16,750 --> 00:38:20,470
+ما بينهم قليلة جدا كانت المسافة ما بينهم قليلة
+
+495
+00:38:20,470 --> 00:38:25,830
+كتير و هو تمكن من إيضاحهم إذا هو عنده greater
+
+496
+00:38:25,830 --> 00:38:31,070
+resolution power تمام؟طيب ال minimum ال distance
+
+497
+00:38:31,070 --> 00:38:34,850
+المسافة ما بين ال two objects ممكن حسابها بهذا
+
+498
+00:38:34,850 --> 00:38:41,640
+القانون تمام؟ و ال .. ال .. هنا عملية ربطThe
+
+499
+00:38:41,640 --> 00:38:45,300
+larger numerical aperture اش يعني larger numerical
+
+500
+00:38:45,300 --> 00:38:48,200
+aperture؟ يعني كمية الضوء فايتة للعدسة الشيئية
+
+501
+00:38:48,200 --> 00:38:53,320
+كبيرة وحكينا انه العدسة الشيئية اللي قوة تكبيرها
+
+502
+00:38:53,320 --> 00:38:57,060
+كبيرة، اللي magnification تبعها كبير هي اللي بدها
+
+503
+00:38:57,060 --> 00:39:02,670
+larger NA تمام؟ بدها larger numerical apertureطيب
+
+504
+00:39:02,670 --> 00:39:08,710
+فمعناها هيكون هذا ال .. ال .. ال .. ال numerical
+
+505
+00:39:08,710 --> 00:39:11,230
+aperture وهذه العدسة اللي .. اللي قوة تكبيرها
+
+506
+00:39:11,230 --> 00:39:16,530
+كبيرة بيوضحلي smaller distance between objects
+
+507
+00:39:16,530 --> 00:39:21,410
+هيوضحلي مسافات .. يعني يفصللي ال objects أو النقات
+
+508
+00:39:21,410 --> 00:39:27,030
+اللي ما بينهم مسافات قليلة جدا، تمام؟ إذا هو عنده
+
+509
+00:39:27,030 --> 00:39:32,030
+efficientأو greater resolution power تمام؟ بيزيد
+
+510
+00:39:32,030 --> 00:39:35,430
+ال numerical aperture بيزيد كمية الضوء اللي فايتة
+
+511
+00:39:35,430 --> 00:39:39,410
+للعدسة الشيئية إذا العدسة الشيئية نفسها هتكون قوة
+
+512
+00:39:39,410 --> 00:39:43,130
+تكبيرها كبيرة عشان هي .. هي اللي بتحتاج ضوء أكبر
+
+513
+00:39:43,130 --> 00:39:48,510
+إذا قوة توضيح هتكون أكبر و هيوضحلي ال objects اللي
+
+514
+00:39:48,510 --> 00:39:51,450
+بينهم مسافات أصغر تمام؟
+
+515
+00:39:54,070 --> 00:39:57,530
+working principle of an oil immersion مبدأ عمل ال
+
+516
+00:39:57,530 --> 00:40:02,550
+oil immersion كيف احنا العدسة ال ال ال 100x او ال
+
+517
+00:40:02,550 --> 00:40:08,010
+oil immersion lens كيف بتشتغل شوفوا معايا نرجع ل
+
+518
+00:40:08,010 --> 00:40:14,570
+ال microscope و نتخيل مع بعض مصار الدوء مصار الدوء
+
+519
+00:40:16,490 --> 00:40:21,930
+طيب الضوء ينتقل من ال light source ممكن يمر بمرقاء
+
+520
+00:40:21,930 --> 00:40:27,590
+او ب filter و بعدين بالقرص بيتحكم بكمية وجوده او
+
+521
+00:40:27,590 --> 00:40:31,670
+كميته اللي فايتة ل ال condenser و ال condenser
+
+522
+00:40:31,670 --> 00:40:37,010
+بيجمعه و بيخليه يعني يفوت في العدسة الشريقية اللي
+
+523
+00:40:37,010 --> 00:40:42,220
+هي 100X او ال oil immersionو احنا متفقين انه مبين
+
+524
+00:40:42,220 --> 00:40:47,280
+ان ال oil immersion هي اكبر عدسة او اكبر قوة تكبير
+
+525
+00:40:47,280 --> 00:40:50,320
+في ال microscope، في ال light microscope، هذا
+
+526
+00:40:50,320 --> 00:40:54,660
+تمام؟ ال microscope الضوءي اللي احنا بنشرحه، تمام؟
+
+527
+00:40:54,660 --> 00:41:01,050
+فمعناها انها محتاجة اكبر كمية ضوءطيب الضوء يمر
+
+528
+00:41:01,050 --> 00:41:06,750
+بأوساط مختلفة glass اللامبة، هواء ال glass ال ..
+
+529
+00:41:06,750 --> 00:41:07,970
+ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال
+
+530
+00:41:07,970 --> 00:41:08,250
+.. ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال ..
+
+531
+00:41:08,250 --> 00:41:11,670
+ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال
+
+532
+00:41:11,670 --> 00:41:12,430
+.. ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال ..
+
+533
+00:41:12,430 --> 00:41:12,450
+ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال
+
+534
+00:41:12,450 --> 00:41:12,970
+.. ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال ..
+
+535
+00:41:12,970 --> 00:41:13,030
+ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال
+
+536
+00:41:13,030 --> 00:41:13,750
+.. ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال ..
+
+537
+00:41:13,750 --> 00:41:13,750
+ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال
+
+538
+00:41:13,750 --> 00:41:14,830
+.. ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال ..
+
+539
+00:41:14,830 --> 00:41:14,850
+ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال
+
+540
+00:41:14,850 --> 00:41:19,150
+.. ال ..
+
+541
+00:41:19,150 --> 00:41:23,430
+ال .. ال .. ال
+
+542
+00:41:29,750 --> 00:41:35,750
+للعدسة مية مش كتيرة كما ينبغي تمام؟ مش كتيرة كما
+
+543
+00:41:35,750 --> 00:41:39,810
+ينبغي ليش؟ لإن جزء من هذا الضوء يتشتت نتيجة
+
+544
+00:41:39,810 --> 00:41:45,850
+انتقاله في أوصات مختلفة وانكساراته تمام؟ طيب، طب
+
+545
+00:41:45,850 --> 00:41:49,370
+إيش هم نعمل علشان إحنا نحافظ على كمية الضوء هذه
+
+546
+00:41:49,370 --> 00:41:52,990
+إنها كلها تفوت للعدسة الشيئية أو مايتم تشتت هذا
+
+547
+00:41:52,990 --> 00:41:58,430
+الضوء؟ شوفوا معايا إيش بنساوي نرجع بس لل slide
+
+548
+00:42:01,070 --> 00:42:07,110
+هي هنا الضوء بيمر من زجاج إلى هواء إلى زجاج مرة ..
+
+549
+00:42:07,110 --> 00:42:11,350
+إلى هواء مرة أخرى إلى زجاج فإيش؟ بيحكينا إن هو
+
+550
+00:42:11,350 --> 00:42:16,390
+بيتشتت تمام؟ طيب لكن لو أنا حطيت على الشريحة تبعتي
+
+551
+00:42:16,390 --> 00:42:23,080
+هذه هي الشريحة لو حطيت عليها قطرة زيتoil غمرتها بـ
+
+552
+00:42:23,080 --> 00:42:27,180
+oil فصارت oil و طبعا شغالتي المسافة اللي ما بين ..
+
+553
+00:42:27,180 --> 00:42:30,220
+المسافة اللي ما بين العدسة ال 100x يا بنات و ال
+
+554
+00:42:30,220 --> 00:42:34,860
+slide بتكون كتير قليلة طبعا فإذا شغالتي المساحة أو
+
+555
+00:42:34,860 --> 00:42:38,640
+المسافة ما بينهم بقطرة oil فساعتها العدسة هذه
+
+556
+00:42:38,640 --> 00:42:42,140
+بتكون عدسة مغمورة بالزيت عشان هيك احنا بنحكي عنها
+
+557
+00:42:42,140 --> 00:42:46,420
+اما 100x او بنحكي عنها ال oil emerging العدسة اللي
+
+558
+00:42:46,420 --> 00:42:52,360
+تغمر بالزيت طبعا طيبإيش اللي هيصير بهذه الوضع؟ لو
+
+559
+00:42:52,360 --> 00:42:59,480
+أنا حطيت oil immersion فمعناها إنه ال .. ال .. ال
+
+560
+00:42:59,480 --> 00:43:03,860
+.. الزيت هذا اللي أنا حطيته إليه نفس معامل انكسار
+
+561
+00:43:03,860 --> 00:43:09,470
+الزجاج فبيصير الضوء بيمر منالـ light source بيروح
+
+562
+00:43:09,470 --> 00:43:13,770
+على الزجاج اللي هو زجاج الـ condenser بعدين زجاج
+
+563
+00:43:13,770 --> 00:43:17,890
+الشريحة بعدين بيمر في المنطقة هذه اللي هي مغمورة
+
+564
+00:43:17,890 --> 00:43:21,410
+بال oil اللي يلو نفس معامل انكسار الزجاج يعني إزاي
+
+565
+00:43:21,410 --> 00:43:26,250
+كأنه الضوء ماشي بزجاج أصلا تمام وينتقل إلى العدسة
+
+566
+00:43:26,250 --> 00:43:30,610
+الشيئية اللي هي أيضا مصنوعة من الزجاج إذا أصبح
+
+567
+00:43:30,610 --> 00:43:34,630
+إحنا هيك وحدنا مصاري الضوء أو لا كأنه وحدنا اللي
+
+568
+00:43:34,630 --> 00:43:38,330
+باستخدامالزيت اللي يقيله نفس معامل انكسار الزجاج
+
+569
+00:43:38,330 --> 00:43:42,230
+فزي كأنه الضوء بيمور بنفس المسار من زجاج
+
+570
+00:43:42,230 --> 00:43:46,210
+الcondenser إلى ال slide إلى ال oil إلى زجاج
+
+571
+00:43:46,210 --> 00:43:52,510
+العدسة الشيء يعنيو هيك بنكون احنا بطل في تشتت
+
+572
+00:43:52,510 --> 00:43:56,890
+للضوء لمينا الضوء جمعناه كله لحتى يفوت في العدسة
+
+573
+00:43:56,890 --> 00:44:01,310
+الشيئية ليش؟ لأنه احنا مستخدم قوة تكبير كبيرة عدسة
+
+574
+00:44:01,310 --> 00:44:06,570
+100X فمحتاجين كمية الضوء أكبر محتاجين ان ال NA ال
+
+575
+00:44:06,570 --> 00:44:10,950
+numerical aperture يكون أعلى تمام؟ و مش محتاجة ولا
+
+576
+00:44:10,950 --> 00:44:15,600
+نت في الضوء يتشتت تمام؟ مابدي أي ضوء يتشتتفهي هي
+
+577
+00:44:15,600 --> 00:44:18,900
+فكرة ال oil immersion، الضوء يتشبط نتيجة مروره
+
+578
+00:44:18,900 --> 00:44:23,640
+بمسارات مختلفة، مع وجود ال oil، الضوء رح ينحجب و
+
+579
+00:44:23,640 --> 00:44:30,220
+رح يظل كأنه زي كأنه ماشي بمسار واحد، فبالتالي كله
+
+580
+00:44:30,220 --> 00:44:33,600
+هيفوت في ال .. ال objective و هيك هيكون في عندي
+
+581
+00:44:33,600 --> 00:44:38,480
+قوة إيضاح أفضل و تكبير أفضلنشوف الكلام اللي مكتوب
+
+582
+00:44:38,480 --> 00:44:42,300
+هنا هو نفسه اللي شرحنا و in a beam of light لما
+
+583
+00:44:42,300 --> 00:44:47,080
+تكون عندى حزمة ضوء passes from air into glass it
+
+584
+00:44:47,080 --> 00:44:50,860
+is bend تمام لما بتنتقل من الهواء اللى موجود تحت
+
+585
+00:44:50,860 --> 00:44:54,220
+الcondenser لل glass اللى فى الcondenser بتنكسر
+
+586
+00:44:54,580 --> 00:44:58,320
+طبعا and when it passed back from glass to air و
+
+587
+00:44:58,320 --> 00:45:01,560
+لما ايضا كمان هذا الضوء ينتقل من ال glass تبع
+
+588
+00:45:01,560 --> 00:45:08,060
+الcondenser و الهواء المسافة اللي ما بين الشريحة و
+
+589
+00:45:08,060 --> 00:45:14,300
+العدسة ايضا كمان بينكسر مرة تانية فبالتالي لما
+
+590
+00:45:14,300 --> 00:45:19,310
+بيرجع لمصاره بيكون تشتت جزء منهلما بيرجع على مسار
+
+591
+00:45:19,310 --> 00:45:23,570
+أو بيمشي في مساره باتجاه العدسة الشيئية بيكون احنا
+
+592
+00:45:23,570 --> 00:45:27,510
+فقدنا جزء من هذا الضوء نتيجة انكساراته ينكسر ويرجع
+
+593
+00:45:27,510 --> 00:45:32,230
+ينعكس، ينكسر ويرجع ينعكس، اذا .. اذا اتشتتتمام؟
+
+594
+00:45:32,230 --> 00:45:37,490
+طيب فهذا هيأثر على ال oil immersion objective ليش؟
+
+595
+00:45:37,490 --> 00:45:40,510
+لإنه هيأثر على ال numerical aperture كمية الضوء
+
+596
+00:45:40,510 --> 00:45:44,110
+اللى فايت على ال objective وإحنا متفقين وكررنا
+
+597
+00:45:44,110 --> 00:45:48,270
+مرارا وتكرارا إنه والله كل ما استخدمنا قوة تكبير
+
+598
+00:45:48,270 --> 00:45:52,510
+كبيرة معناها بدي أنقى كبير بدي كمية ضوء أعلى تصل
+
+599
+00:45:52,510 --> 00:45:57,390
+أو أكبر تصل ل ال objective lensتمام؟ فإذا أيضا
+
+600
+00:45:57,390 --> 00:46:00,770
+هيأثر على ال resolving power على قوة الإيضاح لهذه
+
+601
+00:46:00,770 --> 00:46:06,030
+العدسة فبالتالي المفروض أنه أنا أمنع انكسار الضوء
+
+602
+00:46:06,030 --> 00:46:14,420
+هذا من خلال أن أنا أحل الهواء اللي موجودالهواء
+
+603
+00:46:14,420 --> 00:46:21,280
+اللي موجود بين العينة و العدسة أشغله ب .. بقطرة
+
+604
+00:46:21,280 --> 00:46:27,140
+زيت، تمام؟ هذا الزيت .. هذا الزيت إله the same
+
+605
+00:46:27,140 --> 00:46:30,600
+optical properties of a glass، إله نفس الخصائص
+
+606
+00:46:30,600 --> 00:46:36,280
+الضوئية أو الخصائص للزجاج، يعني إله نفس معامل
+
+607
+00:46:36,280 --> 00:46:42,980
+انكسارالضوء في الزجاج فإذا لما الضوء بيطلع من
+
+608
+00:46:42,980 --> 00:46:48,000
+الcondenser بيمور بال slide و بعدين بيمور بالزيت
+
+609
+00:46:48,000 --> 00:46:50,960
+نفس معامل انكسار الزجاج ده يعني ذلك إنه ينتقل من
+
+610
+00:46:50,960 --> 00:46:54,820
+زجاج إلى زجاج إلى ما يشبه الزجاج اللي هو ال oil و
+
+611
+00:46:54,820 --> 00:47:01,530
+من ثم إلىال oil emerging العدسة اللي هي أيضا زجاج
+
+612
+00:47:01,530 --> 00:47:06,670
+اذا انا هيك وحدت مصار الضوء منعت تشتته لميته كله
+
+613
+00:47:06,670 --> 00:47:11,770
+وجمعته عشان يخترق العدسة الشيئية لإنها محتاجة NA
+
+614
+00:47:11,770 --> 00:47:15,870
+أكبر لإن قوة تكبيرها عالية حكينا هي أعلى شمية X في
+
+615
+00:47:15,870 --> 00:47:20,290
+ال microscope في ال light microscopeتمام؟ اذا انا
+
+616
+00:47:20,290 --> 00:47:25,530
+هيك اش بعمل collecting ل ال light تمام؟ بجمع الضوء
+
+617
+00:47:25,530 --> 00:47:30,650
+و بخليه يختارق العينة اذا ال oil فائدة ال oil
+
+618
+00:47:30,650 --> 00:47:34,590
+بيعطيني better resolution تمام؟ و brighter image
+
+619
+00:47:34,590 --> 00:47:41,430
+وضوء يعني صورة مضيئة اكثر و واضحة اكثروحكينا ليش
+
+620
+00:47:41,430 --> 00:47:45,670
+بسمي العدسة oil immersion لإن المسافة ما بين ال
+
+621
+00:47:45,670 --> 00:47:49,410
+slide و العدسة بتكون قليلة فلما أحط قطرة الزيت
+
+622
+00:47:49,410 --> 00:47:53,670
+العدسة تنغمر في قطرة الزيت هذه فبتصبح المسافة
+
+623
+00:47:53,670 --> 00:47:58,850
+مشغولة من هنا بالزيت فلإنها بتنغمر بالزيت بنسميها
+
+624
+00:47:58,850 --> 00:48:02,450
+oil immersion طيب
+
+625
+00:48:04,410 --> 00:48:10,830
+types of microscopy تمام؟ أنواع الميكروسكوبات في
+
+626
+00:48:10,830 --> 00:48:13,710
+عندي أنواع للميكروسكوبات مش كلها واحد احنا اللي
+
+627
+00:48:13,710 --> 00:48:16,730
+شرحناه هو ال light microscope هو الميكروسكوب
+
+628
+00:48:16,730 --> 00:48:21,730
+الضوءي لكن في عندي أنواع أخرى من الميكروسكوب زي ال
+
+629
+00:48:21,730 --> 00:48:26,010
+ultraviolet microscopeالـ Ultraviolet Microscopy
+
+630
+00:48:26,010 --> 00:48:29,810
+أو Ultraviolet Microscope هو بيستخدم ال light
+
+631
+00:48:29,810 --> 00:48:37,750
+source عنده UV Ultraviolet ضوء فوق بنفسجي أشعة فوق
+
+632
+00:48:37,750 --> 00:48:46,230
+بنفسجية و طبعا قوة التوضيح بيوضح المسافة
+
+633
+00:48:46,230 --> 00:48:49,490
+ما بين ال two objects ممكن تكون point one
+
+634
+00:48:49,490 --> 00:48:54,590
+micrometerيعني قوة توضيح عالية، تمام؟ احنا إيش
+
+635
+00:48:54,590 --> 00:48:57,730
+عرفنا ال resolution؟ حكينا هي قوة التوضيح ما بين
+
+636
+00:48:57,730 --> 00:49:04,350
+two objects أو نقطتين، يعني two points في الصورة
+
+637
+00:49:04,350 --> 00:49:07,670
+أو في العيلة المراد فحصها، ال distance ما بينهم
+
+638
+00:49:07,670 --> 00:49:12,530
+كتير قليلة، تمام؟ هو بوضح لحد distance point one
+
+639
+00:49:12,530 --> 00:49:20,010
+micrometer، طيببغض النظر عن ان ال UV light is
+
+640
+00:49:20,010 --> 00:49:23,350
+invisible احنا انا مابشوف الأشعة فوق البنفسجية
+
+641
+00:49:23,350 --> 00:49:26,330
+يعني صعب ان اشوف ال .. يعني أنظر على العدسات
+
+642
+00:49:26,330 --> 00:49:30,810
+العينية واشوف صورة، تمام؟ فالصورة هاي اللي
+
+643
+00:49:30,810 --> 00:49:34,330
+بيلتقطها المايكروسكوب باستخدام ال ultraviolet
+
+644
+00:49:34,330 --> 00:49:40,920
+مايكروسكوبيهو راح ينقلها إلى photographic plate أو
+
+645
+00:49:40,920 --> 00:49:46,800
+fluorescent screen إلى أشعة أو صورة يعني شاشة
+
+646
+00:49:46,800 --> 00:49:52,540
+فلورنسية فتبدو الصورة مضيقة على هذه الشاشة وممكن
+
+647
+00:49:52,540 --> 00:49:57,290
+رؤيتهاطمام؟ إذا أنا ما بتمكن من رؤية الصورة على
+
+648
+00:49:57,290 --> 00:50:01,910
+العدسات العينية للمايكروسكوب لإنه أنا أصلا مابشوفش
+
+649
+00:50:01,910 --> 00:50:06,370
+العدسات .. الأشعة فوق البنفسجية مابشوفش مصدر ضوء
+
+650
+00:50:06,370 --> 00:50:10,170
+بإنتي تعالي تطلعي في .. في .. في مكان معتم إنتي مش
+
+651
+00:50:10,170 --> 00:50:14,030
+شايفة فيه ضوء فمش هتشوفي صورة لازم تنقل الصورة إلى
+
+652
+00:50:14,030 --> 00:50:19,450
+microscope إلى .. إلى photographic plate إلى ..
+
+653
+00:50:19,450 --> 00:50:24,580
+يعني ..جهاز مخصص لنقل الصور أو شاشة فلورنسية أو
+
+654
+00:50:24,580 --> 00:50:29,300
+جهاز computer لحتى أشوفها و العدسات بتكون مصنوعة
+
+655
+00:50:29,300 --> 00:50:35,120
+من liquids كمانلأ علشان هي أفضل إشي حكينا لل UV
+
+656
+00:50:35,120 --> 00:50:39,420
+light تمام؟ هي أفضل إشي لـ UV light طيب
+
+657
+00:50:39,420 --> 00:50:43,380
+fluorescence ميكروسكوبي نوع من أنواع الميكروسكوبات
+
+658
+00:50:43,380 --> 00:50:49,080
+اللي أيضا بيستخدم ال UV light ولكن هنا العينة
+
+659
+00:50:49,080 --> 00:50:53,040
+تبعتي بتكون مصبوغة بصبغة بنسميها fluorescence dye
+
+660
+00:50:53,040 --> 00:50:57,160
+هذه ال fluorescence dye هي عبارة عن صبغات أول ما
+
+661
+00:50:57,160 --> 00:51:02,020
+بي .. يعني صبغةأول ما بيضروا فيها ال .. ال .. أشعة
+
+662
+00:51:02,020 --> 00:51:06,320
+ال UV light بتتأين و بيصير ت .. بيصير لامعة، بيصير
+
+663
+00:51:06,320 --> 00:51:10,780
+تعطي إشعاع فلورنزي، تمام؟ فبشوف الصورة مشعة بهذا
+
+664
+00:51:10,780 --> 00:51:14,620
+الشكل تحت ال microscope، تمام؟ يعني نفس فكرة ال
+
+665
+00:51:14,620 --> 00:51:18,000
+ultraviolet، بس اللهم بدل ما أنقل الصورة على
+
+666
+00:51:18,000 --> 00:51:21,460
+fluorescent screen أو photographic plate أو
+
+667
+00:51:21,460 --> 00:51:27,680
+computer systemالعدسة نفسها .. العينة نفسها بتكون
+
+668
+00:51:27,680 --> 00:51:31,720
+مصبوغة ب fluorescent dye و بشوفها لامعة تحت ال
+
+669
+00:51:31,720 --> 00:51:35,160
+microscope تمام؟ هذا فكرة ال fluorescent
+
+670
+00:51:35,160 --> 00:51:39,790
+microscope طيب ال dark field microscopeال dark
+
+671
+00:51:39,790 --> 00:51:43,470
+field microscope هو عبارة عن microscope بيعطيني
+
+672
+00:51:43,470 --> 00:51:49,330
+black background اللي هو خلفية معتمة للصورة أو
+
+673
+00:51:49,330 --> 00:51:53,930
+للعينة و فقط البكتيريا أو الخلية أو العنصر المراد
+
+674
+00:51:53,930 --> 00:51:58,760
+رؤيته هو اللي بيكون مضيقتمام ال suspended bacteria
+
+675
+00:51:58,760 --> 00:52:01,740
+أو ال element العنصر اللي مراد رؤيته هو اللي بيكون
+
+676
+00:52:01,740 --> 00:52:08,100
+bright لامع و مضيق تمام كيف بيتم تصوير بهذا ال ..
+
+677
+00:52:08,100 --> 00:52:12,480
+بهذه القالية ال .. ال microscope هذا عنده special
+
+678
+00:52:12,480 --> 00:52:17,260
+condenser هذا الcondenser بيجمع الضوء تمام و فقط
+
+679
+00:52:17,260 --> 00:52:20,840
+بيخليه يخترق مين؟ بيخليه يخترق ال object اللي على
+
+680
+00:52:20,840 --> 00:52:25,360
+ال .. على العدسة على ال slide تمام بيخترق ال .. ال
+
+681
+00:52:25,360 --> 00:52:29,250
+.. ال .. ال ..فقط اللي هو ال bacteria أو ال
+
+682
+00:52:29,250 --> 00:52:33,810
+element المراد رؤيته على ال slide وينتقل الضوء منه
+
+683
+00:52:33,810 --> 00:52:37,570
+إلى العدسة الشيئية، أي شيء آخر، في حوالين هذا ال
+
+684
+00:52:37,570 --> 00:52:42,110
+.. ال element يتبدد فاحنا بنشوف كل إشي معتم إلا
+
+685
+00:52:42,110 --> 00:52:47,360
+الخلية أو العنصر المراد رؤيته بيكون مضيع، تمام؟ف
+
+686
+00:52:47,360 --> 00:52:50,560
+.. وعندي نوعة رابع اللي هو ال face contrast
+
+687
+00:52:50,560 --> 00:52:54,600
+مايكروسكوبي ال face contrast مايكروسكوبي هو طبعا
+
+688
+00:52:54,600 --> 00:52:58,460
+احنا في الأنواع السابق ذكرها احنا بنشوف الخلايا و
+
+689
+00:52:58,460 --> 00:53:03,700
+البكتيريا و الفطريات و الطفاليات اي خلايا سواء
+
+690
+00:53:03,700 --> 00:53:08,160
+كانت طبعا يعني animal cells or plant cells او حتى
+
+691
+00:53:08,160 --> 00:53:16,320
+كمان اللي بروكاريوت تمام؟بنشوفها و هي ميتة الخلايا
+
+692
+00:53:16,320 --> 00:53:20,960
+يعني لابد من قتلها و نجففها و نصبغها should be
+
+693
+00:53:20,960 --> 00:53:25,760
+killed dried and stained و نصبغها عشان نتمكن من
+
+694
+00:53:25,760 --> 00:53:28,540
+رؤيتها لكن هذا ال microscope اللي هو ال face
+
+695
+00:53:28,540 --> 00:53:33,520
+contrast مايكروسكوبي بيورجيني
+
+696
+00:53:33,520 --> 00:53:37,970
+الخلايا visualize the living bacteria andcells
+
+697
+00:53:37,970 --> 00:53:42,070
+تمام بيورجيني الخلايا و هي حية كيف والله انه انا
+
+698
+00:53:42,070 --> 00:53:46,450
+في عندى معامل معامل انكسار مختلف لمرور الضوء اثناء
+
+699
+00:53:46,450 --> 00:53:55,390
+خلال كائن حي وأثناء مرور الضوء في كائن أو خلية
+
+700
+00:53:55,390 --> 00:54:00,130
+ميتة، تمام؟ فهذا ال .. ال .. ال microscope يوظف
+
+701
+00:54:00,130 --> 00:54:04,650
+هذا الفرق في المعامل الانكسار للضوء، تمام؟ إذا
+
+702
+00:54:04,650 --> 00:54:07,890
+المعامل الانكسار للضوء يختلف أثناء مروره في خلية
+
+703
+00:54:07,890 --> 00:54:12,580
+حيةعن مروره في خلية ميتة هذا ال microscope enhance
+
+704
+00:54:12,580 --> 00:54:16,820
+بيعزز أو بيستخدم ال slight difference هذا الفرق ما
+
+705
+00:54:16,820 --> 00:54:19,760
+بين ال .. ال .. ال .. هذا الفرق في ال refractive
+
+706
+00:54:19,760 --> 00:54:24,120
+index في معامل الانكسار ما بين مروره في خلايا حية
+
+707
+00:54:24,120 --> 00:54:27,840
+و ما بين مروره في الوسط أو الخلايا الميتة المحيطة
+
+708
+00:54:27,840 --> 00:54:34,560
+فيها فبالتالي بيوضحلي ال .. الخلايا الحيةالكترون
+
+709
+00:54:34,560 --> 00:54:38,580
+مايكروسكوبي طبعا هو تقريبا افضل مايكروسكوب و اعلى
+
+710
+00:54:38,580 --> 00:54:43,540
+قوة تكبير لمايكروسكوب بتقريبا بيعطيني قوة تكبير
+
+711
+00:54:43,540 --> 00:54:50,120
+1500x او 2000x وفي قوة عند خمسين الف اكس تمام
+
+712
+00:54:50,120 --> 00:54:51,300
+بيكون كبير
+
+713
+00:54:54,250 --> 00:54:59,850
+الإلكترون مايكروسكوبي فيه منه نوعين طبعا فيه ال
+
+714
+00:54:59,850 --> 00:55:02,850
+transmission electron microscope بيعطيني صورة
+
+715
+00:55:02,850 --> 00:55:06,490
+ثنائية الأبعادو في scanning electron microscope
+
+716
+00:55:06,490 --> 00:55:14,650
+اللي هو ثلاثي الأبعاد، تمام؟ فهو عنده يعني .. ب ..
+
+717
+00:55:14,650 --> 00:55:16,990
+ب .. احنا .. احنا بنفضل نستخدمه عن ال light
+
+718
+00:55:16,990 --> 00:55:20,210
+microscope ليش؟ لإن ال light microscope يعني مقنعة
+
+719
+00:55:20,210 --> 00:55:24,550
+فيه عنده decreased efficiency و resolving power،
+
+720
+00:55:24,550 --> 00:55:28,390
+تمام؟ لكن هو .. هذا عنده high degree of resolving
+
+721
+00:55:28,390 --> 00:55:33,900
+power، ال electron microscopyطيب routine use of
+
+722
+00:55:33,900 --> 00:55:37,400
+microscope هاي ال .. النقاط أنا راح أذكرها بشكل
+
+723
+00:55:37,400 --> 00:55:42,300
+سرد سريع ولكن راح أشرحها بالتفصيل داخل المختبر على
+
+724
+00:55:42,300 --> 00:55:46,500
+المختبر .. على ال .. ال microscope ده نفسه تمام؟ ف
+
+725
+00:55:46,500 --> 00:55:50,260
+.. لحتى يكون أسهل و أوضحأول إشي أنا لما بدي أجي
+
+726
+00:55:50,260 --> 00:55:53,280
+أستخدم ال microscope لازم أتأكد إن هو موجود على
+
+727
+00:55:53,280 --> 00:55:56,560
+farm bench على bench ثابت مافيش .. ال bench هذا مش
+
+728
+00:55:56,560 --> 00:56:00,660
+موجود جنب جهاز طلاجة أو centrifuge أو إشي بيعملي
+
+729
+00:56:00,660 --> 00:56:05,300
+اهتزازات لإن هذا هيأثر على وضوح الصورة تمام؟و make
+
+730
+00:56:05,300 --> 00:56:08,140
+sure that is not exposed to direct sunlight انه
+
+731
+00:56:08,140 --> 00:56:13,200
+هذا الجهاز مش لازم يتعرض لأشعة الشمس مباشرة لإنه
+
+732
+00:56:13,200 --> 00:56:20,380
+ممكن يطلف، يصدق، يخرب و أيضا ال user المستخدم
+
+733
+00:56:20,380 --> 00:56:24,680
+لmicroscope لازم يجلس على ارتفاع مناسب من ال
+
+734
+00:56:24,680 --> 00:56:28,260
+microscope should be seated at the correct height
+
+735
+00:56:28,260 --> 00:56:35,650
+يعني على ارتفاع مناسب من ال microscopeselect the
+
+736
+00:56:35,650 --> 00:56:40,310
+appropriate source of light لازم نختار مصدر الضوء
+
+737
+00:56:40,310 --> 00:56:45,950
+سواء كان لمبة أو daylight و بشغل الجهاز بالكهربا
+
+738
+00:56:45,950 --> 00:56:48,870
+بضوي الضوء من عند الكابسا اللي حكيتلكم عنها بتحكم
+
+739
+00:56:48,870 --> 00:56:54,260
+بشدة الإضاءة من أيضا المكان الليأشرتلكم إليه في
+
+740
+00:56:54,260 --> 00:57:00,260
+أول ال slides و طبعا بحط العينة تبعتي على ال stage
+
+741
+00:57:00,260 --> 00:57:05,620
+بثبتها بال clips و طبعا بتأكد إن ال slide من تحت
+
+742
+00:57:05,620 --> 00:57:10,500
+طبعا تكون ناشفة لإن أي بقايا صبغ عليها أوسائل راح
+
+743
+00:57:10,500 --> 00:57:15,460
+يأثر على وضوح الصورة فبمسحها قبل ما أحطها على ال
+
+744
+00:57:15,460 --> 00:57:20,040
+slide على ال stage select the objective to be used
+
+745
+00:57:22,490 --> 00:57:28,510
+بختار العدسة الشيئية المراد استخدامها وهنا يفضل يا
+
+746
+00:57:28,510 --> 00:57:32,410
+بنات إذا أنا بدي أستخدم قوة تكبير كبيرة يفضل إن
+
+747
+00:57:32,410 --> 00:57:36,010
+أنا أبدأ بقوة تكبير صغيرة بعدين أنتقل لكبيرة it's
+
+748
+00:57:36,010 --> 00:57:38,490
+better to begin examination with low power with
+
+749
+00:57:38,490 --> 00:57:43,850
+A10X مثلاتمام؟ و طبعا ليش .. ليش أنا ب .. ببدأ في
+
+750
+00:57:43,850 --> 00:57:46,510
+العشرة X؟ عشان أ .. أظبط ال .. ال .. ال
+
+751
+00:57:46,510 --> 00:57:51,930
+illumination، الإضاءة، أجيب ال field، أجيب الصورة،
+
+752
+00:57:51,930 --> 00:57:57,450
+تمام؟ أتأكد إن كل ال .. الأمور تمام، بعدين أنتقل
+
+753
+00:57:57,450 --> 00:58:00,410
+لل high power field، اللي هي أربعين X أو حتى oil
+
+754
+00:58:00,410 --> 00:58:05,520
+immersion، ممكن أنتقل لإلهاطبعا كيف أنا بجيب ال
+
+755
+00:58:05,520 --> 00:58:09,940
+field? bring the objective as close as possible to
+
+756
+00:58:09,940 --> 00:58:15,780
+the slide preparation يعني أنا بقرب المسافة ما بين
+
+757
+00:58:15,780 --> 00:58:20,160
+ال stage اللي عليها ال slide و ما بين ال objective
+
+758
+00:58:20,160 --> 00:58:25,100
+lenses كيف؟ بحرك ال course adjustmentمجرد ما اجيب
+
+759
+00:58:25,100 --> 00:58:29,720
+course adjustment ممكن انا اتحكم بكمية الضوء اللي
+
+760
+00:58:29,720 --> 00:58:34,540
+مارة من خلال ان انا اعمل adjustment لل light و ..
+
+761
+00:58:34,540 --> 00:58:40,630
+و .. لل condenserممكن أفتح القرص أو أسكره حسب كمية
+
+762
+00:58:40,630 --> 00:58:43,130
+الضوء اللي بضيقها و حسب نوع العدسة اللي أنا
+
+763
+00:58:43,130 --> 00:58:47,330
+بستخدمها و طبعا حكينا على ال low power القرص يفضل
+
+764
+00:58:47,330 --> 00:58:50,990
+أنه يكون مغلق و بفتحه على ال high power و ال oil
+
+765
+00:58:50,990 --> 00:58:55,490
+immersion طيب و طبعا هنا هاي بيحكيلي the wider the
+
+766
+00:58:55,490 --> 00:59:00,670
+condenser aperture كلما زاؤ وسعت فتحة ال aperture
+
+767
+00:59:00,670 --> 00:59:04,990
+فتحة الحجاباللي .. اللي تحت ال condenser طبعا
+
+768
+00:59:04,990 --> 00:59:09,110
+معناها كمية ضوء أكبر هتفوت ل ال condenser معناها
+
+769
+00:59:09,110 --> 00:59:13,650
+الصورة إيش هتكون brighter مضيقة أكتر ولامعة أكتر
+
+770
+00:59:13,650 --> 00:59:18,610
+طبعا و أحيانا .. أحيانا بتكون ال details قليلة
+
+771
+00:59:18,610 --> 00:59:23,250
+اللي بنشوفها في هاي الشغلة إلا إذا كنت بستخدميعني
+
+772
+00:59:23,250 --> 00:59:27,890
+عدسة كبيرة فلأ يعني ال wider condenser هيعطيني
+
+773
+00:59:27,890 --> 00:59:33,830
+brighter و برضه كمان أوضح فعشان هيك لازم أن أنا
+
+774
+00:59:33,830 --> 00:59:37,830
+أسكره في العدسات اللي قوة تكبيرها قليلة لإن ممكن
+
+775
+00:59:37,830 --> 00:59:40,590
+تكون ال details مش واضحة كتير يعني أنا بس شايفها
+
+776
+00:59:40,590 --> 00:59:44,650
+صورة لامعة فقط لا غير تمام؟ إذا في هذه دولة
+
+777
+00:59:44,650 --> 00:59:48,350
+النقطتين ينطبقوا على العدسة 10xإنه كل ما كان
+
+778
+00:59:48,350 --> 00:59:50,830
+الـcondenser فاتح أكتر، يعني ضوء أكتر، يعني
+
+779
+00:59:50,830 --> 00:59:53,870
+الـdetails مابشوفهاش كتير، بتكون الصورة بس لامعة
+
+780
+00:59:53,870 --> 00:59:57,750
+على الفاضي، تمام؟ فإذا كان الـsmaller aperture،
+
+781
+00:59:57,750 --> 01:00:02,150
+يعني great will be contrast، يعني في تباين في
+
+782
+01:00:02,150 --> 01:00:06,530
+الصورة، فبتكون واضحة أكتر، هذا ينطبق على 10X، لكن
+
+783
+01:00:06,530 --> 01:00:11,150
+على العدسات اللي قوة تكبيرها أعلى، العكس، يعني أنا
+
+784
+01:00:11,150 --> 01:00:13,850
+محتاجة wider condenser ومحتاجة ضوء أكتر
+
+785
+01:00:16,710 --> 01:00:20,330
+تمام؟ العادة الصورة كيف أنا بشوفها؟ بشوفها upside
+
+786
+01:00:20,330 --> 01:00:26,450
+down مقلوبة و معكوسة كمان upside down and in
+
+787
+01:00:26,450 --> 01:00:29,110
+opposite direction يعني اللي تحت فوق و اللي فوق
+
+788
+01:00:29,110 --> 01:00:33,710
+تحت و على المعكوسة
+
+789
+01:00:33,710 --> 01:00:40,510
+يعني اليمين يسار و اليسار يمين عشان هيك في مكان
+
+790
+01:00:40,510 --> 01:00:43,510
+لتحريك الشريحة
+
+791
+01:00:44,850 --> 01:00:52,430
+على ال stage هنا هنا
+
+792
+01:00:52,430 --> 01:00:58,290
+هادول .. هادول الإتنينبيحركولي الشريحة، طبعا؟
+
+793
+01:00:58,290 --> 01:01:04,130
+فواحد بيحركها لفوق وتحت وواحد بيحركها يمين يسار،
+
+794
+01:01:04,130 --> 01:01:09,410
+طبعا؟ فلما أنا بكون بروح يمين على .. لما بحرك
+
+795
+01:01:09,410 --> 01:01:13,210
+الشريحة
+
+796
+01:01:13,210 --> 01:01:17,350
+إلى اليمين على ال stage معناه أنا بكون بروح لليسار
+
+797
+01:01:17,350 --> 01:01:23,290
+في الصورةو لما بحرك ال .. ال .. هدول يعني بحرك ال
+
+798
+01:01:23,290 --> 01:01:26,890
+.. ال slide إلى اليسار على ال stage معناها أنا
+
+799
+01:01:26,890 --> 01:01:30,010
+بروح لليمين في الصورة لإن الصورة معكوسة و نفس
+
+800
+01:01:30,010 --> 01:01:33,490
+الاشي لو أنا كنت بطلع لفوق على ال .. في ال .. في
+
+801
+01:01:33,490 --> 01:01:37,450
+ال slide تمام معناها أنا بكون بنزل لتحت في الصورة
+
+802
+01:01:37,450 --> 01:01:41,420
+و لما بنزل لتحت في ال slide بكون بطلعلفوق في
+
+803
+01:01:41,420 --> 01:01:44,700
+الصورة لإن الصورة بتكون upside-down إذا الإتجار
+
+804
+01:01:44,700 --> 01:01:47,380
+بتكون معكوسة على ال microscope وهذه شغل .. شغل
+
+805
+01:01:47,380 --> 01:01:51,820
+لازم ينتبهلها كتير منيح و هنتعلمها مع الممارسة
+
+806
+01:02:00,350 --> 01:02:05,210
+تمام بعد هيك ممكن أصل ل .. يعني أغير على 40x بعد
+
+807
+01:02:05,210 --> 01:02:10,090
+ما جبت الصورة باستخدام ال 10x و أبدأ أفحص ال .. ال
+
+808
+01:02:10,090 --> 01:02:15,370
+.. العينة تبعتي و ممكن انا إذا محتاجة oil
+
+809
+01:02:15,370 --> 01:02:22,170
+immersion أو 100x lenses فبحط قطرة زيت على الشريحة
+
+810
+01:02:22,170 --> 01:02:28,870
+تبعتي علشان أتمكن من شو ..رؤية الأجزاء والصورة
+
+811
+01:02:28,870 --> 01:02:32,670
+موضحة أكتر هي عندي طبعا ال oil immersion هنستخدمها
+
+812
+01:02:32,670 --> 01:02:36,190
+لما تعملوا ال blood smear مسحة الدم وهتستخدموها في
+
+813
+01:02:36,190 --> 01:02:40,630
+مختبرات ال microbiology لما تستخدموا ال asbestos
+
+814
+01:02:40,630 --> 01:02:46,010
+تاني اللي هي صبغة لسباغة البكتيريا وكل ما بتكون
+
+815
+01:02:46,010 --> 01:02:49,730
+تصبغوا بكتيريا أو خلايا راح تستخدموا ال oil
+
+816
+01:02:49,730 --> 01:02:54,880
+immersionطيب care, cleaning and repair of the
+
+817
+01:02:54,880 --> 01:02:57,640
+microscope كيف أنا أقعدتني في ال microscope؟ أول
+
+818
+01:02:57,640 --> 01:03:03,140
+إشي ال microscope طبعا يعني معرب للتلف فلازم أنا
+
+819
+01:03:03,140 --> 01:03:07,020
+أراعي أو يكون في عندي اعتبارات تراعى أثناء
+
+820
+01:03:07,020 --> 01:03:10,910
+استخدامهأول إشي بدي أمسكه بإيديا تنتين ممنوع أمسكه
+
+821
+01:03:10,910 --> 01:03:14,690
+بإيد واحدة لإنه ممكن يعني إذا واجع خلاص خيرب يتكسر
+
+822
+01:03:14,690 --> 01:03:18,310
+و not in use إذا أنا ما استخدمته فمعناها إن أنا
+
+823
+01:03:18,310 --> 01:03:22,750
+لازم أحمي أول إشي من الغبرة من الرطوبة من ال
+
+824
+01:03:22,750 --> 01:03:29,370
+sunlight فيعنيإله بيكون sack إله حقيبة بلاستيكية
+
+825
+01:03:29,370 --> 01:03:33,390
+أو بكات أو cover بيغطيه فلازم أكون مغطية أكون
+
+826
+01:03:33,390 --> 01:03:37,630
+فاصلة من الكهربا مش لازم يضل مشبوك بالكهربا و لازم
+
+827
+01:03:37,630 --> 01:03:44,420
+يكون طبعا ..إذا كان أنا .. إذا بدي أخليه في مكان
+
+828
+01:03:44,420 --> 01:03:48,680
+الشغل جاهز يعني لأي وقت بستخدمه فيه بس على الأقل
+
+829
+01:03:48,680 --> 01:03:53,020
+يعني أغطيه بال cover تبعه تمام؟ في ال humidity
+
+830
+01:03:53,020 --> 01:03:56,960
+climate في المناطق اللي الجو تبعها رطب ممكن إنه
+
+831
+01:03:56,960 --> 01:03:59,880
+يصدق هذا ال microscope نتيجة تكوين قطرات ندى عليه
+
+832
+01:03:59,880 --> 01:04:04,420
+وهذا فبيصدق فيفضل إنه ال cover تبعه اللي هو ال
+
+833
+01:04:04,420 --> 01:04:08,160
+plastic bag تبعته اللي هو الكيس أو الحقيبة اللي
+
+834
+01:04:08,160 --> 01:04:14,850
+بتغطيهفإنه تكون عليها silica gel مادة silica gel
+
+835
+01:04:14,850 --> 01:04:18,970
+وهي مادة drying agent عامل مجفف يمتص الرطوبة عشان
+
+836
+01:04:18,970 --> 01:04:25,030
+العدسات ما تخرب وما ينمو عليها فطر والهيكل المعدني
+
+837
+01:04:25,030 --> 01:04:26,470
+للميكروسكوب لا يصدق
+
+838
+01:04:29,100 --> 01:04:33,220
+طبعا اكيد at the end of each day في نهاية كل يوم
+
+839
+01:04:33,220 --> 01:04:37,840
+لازم انا انظف العدسات هاي تمام؟ انظف ال stage من
+
+840
+01:04:37,840 --> 01:04:42,040
+بقايا الزيت و الشرايح انظف ال objective lenses و
+
+841
+01:04:42,040 --> 01:04:45,000
+ال eye lenses و الcondenser طبعا كيف انا .. طبعا
+
+842
+01:04:45,000 --> 01:04:47,720
+الcondenser يا بنات ممكن تتجمع عليه غبار عدسته
+
+843
+01:04:47,720 --> 01:04:52,980
+فمهم جدا انك انتي تمسحيه قبل استخدامهو طبعا كيف
+
+844
+01:04:52,980 --> 01:04:57,260
+بنظفهم؟ بنظفهم بمادة مخصصة لها اللي هي للزايلين و
+
+845
+01:04:57,260 --> 01:05:01,080
+يفضل إن أنا ما أستخدم الكحول إذا .. إلا إذا مش
+
+846
+01:05:01,080 --> 01:05:04,380
+متوفر زايلين يعني فيفضل إن أنا أبعد عن الكحول لإن
+
+847
+01:05:04,380 --> 01:05:08,560
+الكحول بسرع تلف العدساتrepair of the microscope
+
+848
+01:05:08,560 --> 01:05:13,680
+بيحكيلي انه لو تعرض ال .. ال .. ال .. ال
+
+849
+01:05:13,680 --> 01:05:18,240
+microscope لتلف تمام صارله damaged اما optically
+
+850
+01:05:18,240 --> 01:05:21,180
+يعني نظام العدسات فيه خربط او mechanically انكسر
+
+851
+01:05:22,490 --> 01:05:26,650
+خرب ف it's better to send it or .. or the damaged
+
+852
+01:05:26,650 --> 01:05:30,310
+part to reliable scientific instrument repairer or
+
+853
+01:05:30,310 --> 01:05:33,890
+the .. to the manufacturer يعني إما ب .. ب .. يعني
+
+854
+01:05:33,890 --> 01:05:39,130
+بارسله لمهندس صيانة للأجهزة الطبية أو للجهة
+
+855
+01:05:39,130 --> 01:05:43,330
+المصنعة له لحتى هي لإن هي بتكون أكتر حد فاهم تصنيع
+
+856
+01:05:43,330 --> 01:05:49,770
+هذا الجهاز و .. فبتكون أفضل حد ممكن يصلحه تمام؟ و
+
+857
+01:05:49,770 --> 01:05:56,940
+..يعني إذا كان التلف إشي بسيط ممكن أنتي ت .. يعني
+
+858
+01:05:56,940 --> 01:06:00,200
+ال .. يعني كان simple measures يعني أشياء بسيطة
+
+859
+01:06:00,200 --> 01:06:05,240
+جدا أنتي ممكن تعمليها فعادي يعني ممكن أنتي تقومي
+
+860
+01:06:05,240 --> 01:06:09,730
+بالعملية هاييعني damage كبير optically or
+
+861
+01:06:09,730 --> 01:06:12,870
+mechanically لأ ودي إما المهندس صيانة أو الشركة
+
+862
+01:06:12,870 --> 01:06:17,370
+المصنعة هيك بنكون أوصلنا لنهاية محاضرتنا لليوم
+
+863
+01:06:17,370 --> 01:06:20,010
+يعطيكم العافية اتمنى تكونوا استفدتوا ان شاء الله
+
+864
+01:06:20,010 --> 01:06:25,520
+المعمل .. المعمل ال microscopeرح نعمل
+
+865
+01:06:25,520 --> 01:06:30,340
+demonstration في بداية المعمل نشوف كيف احنا مع بعض
+
+866
+01:06:30,340 --> 01:06:33,940
+كيف ن .. نش .. نشبك ال microscope كيف بحضره للشغل
+
+867
+01:06:33,940 --> 01:06:38,260
+و كيف انا بجيب ال field و كيف بستخدمه و رح نتعرف
+
+868
+01:06:38,260 --> 01:06:41,720
+عن الأدوات أجزاء ال .. ال microscope عن قرب و كل
+
+869
+01:06:41,720 --> 01:06:45,640
+واحدة اش وظيفتها يعني إعادة بسيطة للمحاضرة أو
+
+870
+01:06:45,640 --> 01:06:52,140
+إفراء للمحاضرة على أرض الواقع يعطيكم العافية و
+
+871
+01:06:52,140 --> 01:06:53,320
+موفقين بإذن الله
+
diff --git a/PL9fwy3NUQKwY9jl8xw-bWkVZkWcGGyspd/FgXeSCpsx3M_postprocess.srt b/PL9fwy3NUQKwY9jl8xw-bWkVZkWcGGyspd/FgXeSCpsx3M_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..a5a0b9d2b121c5f69e625416e8abcd9c99e9c6b3
--- /dev/null
+++ b/PL9fwy3NUQKwY9jl8xw-bWkVZkWcGGyspd/FgXeSCpsx3M_postprocess.srt
@@ -0,0 +1,1912 @@
+1
+00:00:06,410 --> 00:00:10,510
+السلام عليكم و رحمة الله و بركاته طالبات العزيزات،
+
+2
+00:00:10,510 --> 00:00:14,410
+إذا ان شاء الله اليوم راح نبلش محاضرة جديدة بعنوان
+
+3
+00:00:14,410 --> 00:00:18,990
+centrifuges، أي أجهزة الطارد المركزي أو جهاز
+
+4
+00:00:18,990 --> 00:00:25,310
+الطارد المركزي، تمام؟ طيببس بداية خلونا نحكي عن
+
+5
+00:00:25,310 --> 00:00:30,350
+محاضرة ل blood component تمام؟ لما حكينا إنه عينة
+
+6
+00:00:30,350 --> 00:00:34,690
+الدم إذا أنا فصلتها باستخدام جهاز ال centrifuge
+
+7
+00:00:34,690 --> 00:00:39,270
+باستخدام جهاز الطارد المركزيال .. ال RBCs خلايا
+
+8
+00:00:39,270 --> 00:00:42,210
+ثقيلة الوزن راح تكون موجودة في ال sediment في
+
+9
+00:00:42,210 --> 00:00:47,610
+القاع تمام at the bottom و يليها طبق من ال .. ال
+
+10
+00:00:47,610 --> 00:00:51,290
+.. ال buffy coat اللي بتحتوي على ال white BCs و ال
+
+11
+00:00:51,290 --> 00:00:55,510
+blatelet خلايا الدم البيضاء و الصفائح الدموية و
+
+12
+00:00:55,510 --> 00:00:59,350
+راح يكون بعد هيك البلازمة اللي هى أخفقش في الوزن و
+
+13
+00:00:59,350 --> 00:01:04,910
+تكون at the top تمام ال RBCs راح تحتل نسبة خمسة و
+
+14
+00:01:04,910 --> 00:01:09,710
+..و أربعين في المية و ال .. و ال buffy coat أقل من
+
+15
+00:01:09,710 --> 00:01:15,010
+واحد في المية و ال .. ال .. ال plasma خمسة و خمسين
+
+16
+00:01:15,010 --> 00:01:21,450
+في المية تمام؟ طبعا في مراجع يعني ممكن تكون يذكروا
+
+17
+00:01:21,450 --> 00:01:25,450
+أن ال RBC بتحتل نسبة أربع و أربعين في المية و ال
+
+18
+00:01:25,450 --> 00:01:29,070
+buffy coat واحد في المية و ال .. ال plasma خمسة و
+
+19
+00:01:29,070 --> 00:01:33,400
+خمسين في المية يعني مجموحهم مية بالميةهلأ لو كانت
+
+20
+00:01:33,400 --> 00:01:36,420
+.. لو احنا .. لو انا حكيتلك ال RBC's خمسة و أربعين
+
+21
+00:01:36,420 --> 00:01:38,820
+في المية أو أربع و أربعين في المية مافيش خلاف
+
+22
+00:01:38,820 --> 00:01:43,060
+طبعا؟ لو كنت .. لو حكيت أنه ال RBC's خمسة و خمسين
+
+23
+00:01:43,060 --> 00:01:46,980
+في المية بكون بعتبر أنه ال .. ال .. ال buffy coat
+
+24
+00:01:46,980 --> 00:01:50,600
+negligable يعني مهمل أما إذا حكيتلك أنه أربع و
+
+25
+00:01:50,600 --> 00:01:52,920
+أربعين في المية بكون معتبرة أن ال buffy coat واحد
+
+26
+00:01:52,920 --> 00:01:57,710
+في المية طبعا؟ طيبالفكرة أنه باستخدام جهاز الطرد
+
+27
+00:01:57,710 --> 00:02:02,250
+المركزي بيتم فصل الأجزاء ل blood أو عينة الدم إلى
+
+28
+00:02:02,250 --> 00:02:07,130
+طبقة من الخلايا الثقيلة موجودة في القاع يليها طبقة
+
+29
+00:02:07,130 --> 00:02:11,830
+أخف وزنا موجودة اللي هي buffy coat و ثم الطبقة
+
+30
+00:02:11,830 --> 00:02:15,670
+الأخف على الإطلاق أو أخف واحدة فيهم هتكون موجودة
+
+31
+00:02:15,670 --> 00:02:21,670
+at the topإذاً هذا ما بفعل ال centrifuge يحدث بفعل
+
+32
+00:02:21,670 --> 00:02:25,850
+ال centrifuge باستخدام جهاز الطرد المركزي أو جهاز
+
+33
+00:02:25,850 --> 00:02:30,150
+ال fossil اللي احنا بنستخدمه بالمختبرات centrifuge
+
+34
+00:02:30,150 --> 00:02:34,990
+شو يعني centrifuge؟ هو عبارة عن equipment it's
+
+35
+00:02:34,990 --> 00:02:38,870
+equipment that is used to separate solid matter
+
+36
+00:02:38,870 --> 00:02:42,450
+from liquid suspension by mean of centrifugal
+
+37
+00:02:42,450 --> 00:02:46,790
+forcesأنا بفصل الأجزاء الصلبة أو الأجزاء الثقيلة
+
+38
+00:02:46,790 --> 00:02:51,770
+المعلقة داخل سائل بفعل أو بتأثير أو بأثر ال
+
+39
+00:02:51,770 --> 00:02:56,190
+centrifugal forces تمام؟ نفس الفكرة بالنسبة لل
+
+40
+00:02:56,190 --> 00:02:59,750
+blood ال blood هو عبارة عن خلايا عن أجزاء صلبة
+
+41
+00:02:59,750 --> 00:03:03,950
+خلايا صلبة تمام؟ معلقة في ال plasma اللي هي السائل
+
+42
+00:03:03,950 --> 00:03:08,680
+تمام؟ إذا solid matter هو الخلاياfrom يعني أنا بدي
+
+43
+00:03:08,680 --> 00:03:12,880
+أفصلها from liquid suspension من السائل اللي ..
+
+44
+00:03:12,880 --> 00:03:16,100
+اللي .. اللي معلقة فيه اللي هو عبارة عن ال plasma
+
+45
+00:03:16,100 --> 00:03:20,420
+بتأثير ال centrifugal forces ال sediment أو ال
+
+46
+00:03:20,420 --> 00:03:27,250
+solid matter ممكن يكون خلايا ممكن يكون بكتيرياcast
+
+47
+00:03:27,250 --> 00:03:32,690
+رواسب ممكن يكون parasite توفيليات وبيكون معلق
+
+48
+00:03:32,690 --> 00:03:37,510
+suspended in a fluid معلق فيه سائل لما انا بأثر
+
+49
+00:03:37,510 --> 00:03:42,570
+عليه بقوة ال centrifugal forces بقوة الطرد المركزي
+
+50
+00:03:42,570 --> 00:03:47,610
+انا ساعتها بفصله بحيث ان هذا ال sediment بيترسب
+
+51
+00:03:47,610 --> 00:03:52,490
+هذا ال ..ال solid matter بيترسب في قاعل tube و
+
+52
+00:03:52,490 --> 00:03:57,070
+السائل بيكون موجود على السطح، بينتقل إلى السطح،
+
+53
+00:03:57,070 --> 00:04:01,710
+تمام؟ هذه centrifugal forces هي عبارة عن force
+
+54
+00:04:01,710 --> 00:04:07,850
+greater than of the gravity، هي أضعاف قوة الجاذبية
+
+55
+00:04:07,850 --> 00:04:11,560
+الأرضية، هي قوة الطارد المركزيthe suspended
+
+56
+00:04:11,560 --> 00:04:17,540
+material المواد المعلقة في سائل are deposited in
+
+57
+00:04:17,540 --> 00:04:21,940
+the order of their weight بتترثبت بمعالجة وزنها
+
+58
+00:04:21,940 --> 00:04:27,440
+الأثقل على الإطلاق يكون في القاع و الأخف فيهم أخف
+
+59
+00:04:27,440 --> 00:04:32,540
+إشي بيكون موجود at the top تمام؟ و احنا حكينا مش
+
+60
+00:04:32,540 --> 00:04:38,260
+whyإنه في حالة مثلا عينة blood ال RBCs بتكون
+
+61
+00:04:38,260 --> 00:04:44,080
+موجودة at the bottom لإنها أثقل إشي يليها أخف وزنا
+
+62
+00:04:44,080 --> 00:04:47,920
+منها طبقة ال white BCs و البليلت و يليها الطبقة
+
+63
+00:04:47,920 --> 00:04:51,240
+الأخف إشي على الإطلاق اللي هي البلازمة في العينة
+
+64
+00:04:51,240 --> 00:04:55,580
+دي فبالتالي بتكون هي موجودة على ال top تمام أو على
+
+65
+00:04:55,580 --> 00:04:59,400
+ال surface على السطح تمام إذا the suspended
+
+66
+00:04:59,400 --> 00:05:03,680
+material الأجزاء المعلقة أو الجزيئات المعلقةبترتب
+
+67
+00:05:03,680 --> 00:05:08,060
+حسب وزنها أفقل إشي في القاع و أخف إشي at the top
+
+68
+00:05:08,060 --> 00:05:12,760
+طبعا there are many types of centrifuges فى عندى
+
+69
+00:05:12,760 --> 00:05:17,060
+أكتر من نوع من ال centrifuges و لكن كلها تقريبا
+
+70
+00:05:17,060 --> 00:05:22,160
+لها نفس مبدأ العمل طبعا و هى بتستخدم أو توظف ال
+
+71
+00:05:22,160 --> 00:05:25,720
+centrifugal forces اللى هى قوة الطرد المركزى فى
+
+72
+00:05:25,720 --> 00:05:29,180
+فصل الجزيعة طب خلونا نشوف مع بعض شو يعني
+
+73
+00:05:29,180 --> 00:05:34,610
+centrifugal forces و كيف هى الأجهزةتطبق مبدأ الـ
+
+74
+00:05:34,610 --> 00:05:39,150
+centrifugal forces لحتى تفصل المواد طيب تمام when
+
+75
+00:05:39,150 --> 00:05:43,570
+a body is rotated in a circular movement at speed
+
+76
+00:05:43,570 --> 00:05:48,130
+centrifugal force is created that drive the body
+
+77
+00:05:48,130 --> 00:05:51,390
+away from the center of the circular movement
+
+78
+00:05:51,390 --> 00:05:58,260
+تمام؟ هلأ لما بيكون في جسم body تمام؟بيتحرك حركة
+
+79
+00:05:58,260 --> 00:06:02,600
+دائرية circular movement at speed بسرعة معينة
+
+80
+00:06:02,600 --> 00:06:08,080
+هيكون بيأثر على هذا الجسم قوة اسمها centrifugal
+
+81
+00:06:08,080 --> 00:06:12,620
+force طبعا؟ بت .. هذا .. بت .. بت .. بت .. يعني
+
+82
+00:06:12,620 --> 00:06:17,580
+القوة هذه لها نزع بعيد عن المركز يعني بت .. بت ..
+
+83
+00:06:17,580 --> 00:06:23,400
+بتحرك هذا الجسم انه يروح بعيد عن المركزطبعا؟ إيش
+
+84
+00:06:23,400 --> 00:06:28,080
+يعني؟ هل في في الطبيعة أو في حوالنا إشي يحاول
+
+85
+00:06:28,080 --> 00:06:32,580
+يوضحلنا معنى الكلام هذا؟ أه فيه أكيد كلنا روحنا
+
+86
+00:06:32,580 --> 00:06:37,320
+على مدينة الملاهي و كلنا لعبنا بلعبة السلاسل طبعا؟
+
+87
+00:06:37,320 --> 00:06:43,820
+لعبة السلاسل هي عبارة عن إيش؟ هي عبارة عن زي عمود
+
+88
+00:06:43,820 --> 00:06:51,570
+أو ..محور مركزي تمام؟ و هذا المحور المركزي مرتبط
+
+89
+00:06:51,570 --> 00:06:56,550
+فيه عدة كراسي، هذا الكراسي هي ال body تمام؟ هي ال
+
+90
+00:06:56,550 --> 00:07:01,990
+body تمام؟ لما بت .. بنشغل لعبة ال .. السلاسلو ال
+
+91
+00:07:01,990 --> 00:07:06,670
+body هذا بيبدأ يتحرك ب circular movement، بيبدأ
+
+92
+00:07:06,670 --> 00:07:10,690
+يصير في حركة دائرية وسرعة لهذه الكراسي، ساعتها إيش
+
+93
+00:07:10,690 --> 00:07:14,290
+بيصير؟ بنلاحظ إن هي الكراسي هذه بعدت عن المركز،
+
+94
+00:07:14,290 --> 00:07:17,550
+صح؟ بتصير بعيدة، بتصير طايرة في الهواء، تمام؟
+
+95
+00:07:17,550 --> 00:07:22,420
+نتيجة بعضها عن المركز، ما الذي أبعدها عن المركز؟هي
+
+96
+00:07:22,420 --> 00:07:26,700
+ال centrifugal forces القوة اللي طردتها من المركز،
+
+97
+00:07:26,700 --> 00:07:34,240
+قوة طرد المركزي، تمام؟ نفس الاشي بيحدث في الجهاز
+
+98
+00:07:34,240 --> 00:07:38,360
+ال centrifuge أنا بحط ال body اللي هي الأنابيب،
+
+99
+00:07:38,360 --> 00:07:43,880
+أنابيب العيناتو بتتحرك بحركة دائرية مع سرعة
+
+100
+00:07:43,880 --> 00:07:47,620
+فبالتالي هذه الأنابيب إيش مالها؟ بتفرد، بتصير
+
+101
+00:07:47,620 --> 00:07:51,960
+بعيدة، بتصير بعيدة عن المركز، منتشرة، تمام؟
+
+102
+00:07:51,960 --> 00:07:59,370
+فبالتالي بيفصل محتوها بحيث إنه إيش؟الأسقل إشي
+
+103
+00:07:59,370 --> 00:08:03,310
+بيكون .. بيروح على .. بيروح أبعد ما يمكن عن المركز
+
+104
+00:08:03,310 --> 00:08:07,630
+و أخاف إشي بيكون أقرب ما يمكن من المركز إش معنى
+
+105
+00:08:07,630 --> 00:08:13,510
+هذا الكلام؟ يعني أبعد إشي عن المركز هو أسقل جزء في
+
+106
+00:08:13,510 --> 00:08:17,070
+العينة، يعني بيكون at the bottom of a tube، في
+
+107
+00:08:17,070 --> 00:08:23,970
+قاعلة tubeطبعا، ولكن الجزء اللي بيكون خفيف، light،
+
+108
+00:08:23,970 --> 00:08:29,750
+وزنه خفيف، بيكون قريب من المركز، يعني بيكون at the
+
+109
+00:08:29,750 --> 00:08:33,890
+top of التيوب، على سطح التيوب أو في السطح العلوي
+
+110
+00:08:33,890 --> 00:08:38,960
+من التيوبطبعا هاي فكرة عمل ال .. ال centrifuge وهي
+
+111
+00:08:38,960 --> 00:08:43,460
+معناه كلمة centrifugal forces قوة بتطرد ال objects
+
+112
+00:08:43,460 --> 00:08:48,920
+بتطرد ال body بعيدا عن المركز أثناء دورانه بحركة
+
+113
+00:08:48,920 --> 00:08:53,930
+دائرية على سرعة معينة، طبعا؟the greater the
+
+114
+00:08:53,930 --> 00:08:57,890
+outward pull due to rotation that is centrifugal
+
+115
+00:08:57,890 --> 00:09:01,730
+force, the more rapid and effective is the
+
+116
+00:09:01,730 --> 00:09:06,090
+sedimentation طبعا كل مكان فيه سحب أو بعد أو طرد
+
+117
+00:09:06,090 --> 00:09:10,830
+بعيد عن المركز، طبعا؟ معناه بيكون في عندي أكثر
+
+118
+00:09:10,830 --> 00:09:16,210
+سرعة و أكثر فعالية للفصل، لل sedimentation، لترسيب
+
+119
+00:09:16,210 --> 00:09:21,930
+الأجزاء الثقيلة، طبعا؟ طيبas a result فبالتالي
+
+120
+00:09:21,930 --> 00:09:27,370
+وينتج عن ذلك heavier elements are thrown to the
+
+121
+00:09:27,370 --> 00:09:32,470
+bottom of the tube الأجزاء السقيلة بتكون أبعد ما
+
+122
+00:09:32,470 --> 00:09:36,930
+يمكن عن المركز يعني بتكون في the bottom of ال tube
+
+123
+00:09:36,930 --> 00:09:40,290
+في قاعل ال tube لإن قاعل ال tube هو بيكون أبعد جزء
+
+124
+00:09:40,290 --> 00:09:44,830
+عن المركز تمام? followed by lighter particle و
+
+125
+00:09:44,830 --> 00:09:49,530
+بعدها بيليها الأجزاء الخفيفة اللي بتكونat the top
+
+126
+00:09:49,530 --> 00:09:52,670
+of the tube يعني بتكون قريبة نوعا ما من المركز
+
+127
+00:09:52,670 --> 00:09:57,750
+علشان نفهم الكلام اللي حكيناه خلونا نشوف صورة ال
+
+128
+00:09:57,750 --> 00:10:01,830
+centrifuge و نعرف كيف بيشتغل هاي ال centrifuge و
+
+129
+00:10:01,830 --> 00:10:05,370
+موجود فينا فرض موجود حطينا فيه أنبيض هذا ال
+
+130
+00:10:05,370 --> 00:10:10,630
+centrifuge و شغلناه صار يتحرك حركة دائرية على سرعة
+
+131
+00:10:10,630 --> 00:10:14,260
+معينةراح يأثر على القوة طارد مركزي، إيش يعني؟ يعني
+
+132
+00:10:14,260 --> 00:10:17,920
+الأنابيب هذه إيش معلها؟ راح تبعد عن المركز، إيش
+
+133
+00:10:17,920 --> 00:10:20,620
+يعني راح تبعد عن المركز؟ يعني البطم تبعها راح يبعد
+
+134
+00:10:20,620 --> 00:10:25,800
+عن المركز، راح تتحرك بعيد عن المركز، وهذه الأنابيب
+
+135
+00:10:25,800 --> 00:10:29,940
+إذا البطم تبعها بيكون بعيد عن المركز، طبعا؟ طيب
+
+136
+00:10:30,900 --> 00:10:34,240
+تبعًا لـ centrifugal force as a result
+
+137
+00:11:00,990 --> 00:11:06,270
+تمام؟ هى معناه انه انا افصل عينة باستخدام ال
+
+138
+00:11:06,270 --> 00:11:09,550
+centrifuge و تطبيق ال centrifugal forces اللى هى
+
+139
+00:11:09,550 --> 00:11:15,710
+قوة الطرد المركزى، تمام؟ طيب centrifugal forces
+
+140
+00:11:15,710 --> 00:11:19,870
+increase with the speed of rotation that is
+
+141
+00:11:19,870 --> 00:11:23,290
+revolution of the rotor per minute and the radius
+
+142
+00:11:23,290 --> 00:11:28,560
+of rotation هلأ قوة الطرد المركزى ب ..تزيد كل ما
+
+143
+00:11:28,560 --> 00:11:32,820
+زادت السرعة و السرعة بنعبر عنها revolution per
+
+144
+00:11:32,820 --> 00:11:36,240
+minute أو round per minute، كام دقيقة .. كام لفة
+
+145
+00:11:36,240 --> 00:11:41,660
+بيلف الجهاز بالدقيقة الواحدة هي سرعته، تمام؟ و
+
+146
+00:11:41,660 --> 00:11:46,060
+أيضا قطر الجهاز لإنه إحنا كل ما كان قطره كبير يعني
+
+147
+00:11:46,060 --> 00:11:51,340
+فيه هيكون إيش؟ هيكون .. هيصير طرد بعيد عن المركز،
+
+148
+00:11:51,340 --> 00:11:55,920
+تمام؟و هيكون بتاع ليه قوة الطرد المركزي أكتر، لذا
+
+149
+00:11:55,920 --> 00:12:04,840
+قوة الطرد المركزي بتتأثر يا بنات ب ..بال .. السرعة
+
+150
+00:12:04,840 --> 00:12:11,360
+.. سرعة الجهاز و أيضا بالقطر، قطر الجهاز، تمام؟
+
+151
+00:12:11,360 --> 00:12:17,640
+هذا إذا بتتأثر بسرعة الجهاز و بقطر الجهاز، تمام؟
+
+152
+00:12:17,640 --> 00:12:24,660
+إذا هذا بالنسبة لمين لال ..الcentrifugal forces
+
+153
+00:12:24,660 --> 00:12:30,500
+the actual sedimentation achieved at a given speed
+
+154
+00:12:30,500 --> 00:12:34,120
+depends therefore on the radius of centrifusion
+
+155
+00:12:34,120 --> 00:12:40,360
+هلأ لو أنا بدي أثبت السرعة a given speed يعني سرعة
+
+156
+00:12:40,360 --> 00:12:44,560
+معينة معناها ال sedimentation هيعتمد على مين؟
+
+157
+00:12:44,560 --> 00:12:47,840
+هيعتمد على ال radius على القطريعني ال centrifugal
+
+158
+00:12:47,840 --> 00:12:51,180
+forces طالما هي بتعتمد على السرعة و ال radius إذا
+
+159
+00:12:51,180 --> 00:12:55,160
+السرعة ثابتة معناها بتعتمد على ال radius طبعا؟ طيب
+
+160
+00:12:55,160 --> 00:13:00,020
+إذا يعني إشي واضح و منطقي most techniques
+
+161
+00:13:00,020 --> 00:13:03,460
+requiring centrifugation will usually specify that
+
+162
+00:13:03,460 --> 00:13:07,080
+require a relative centrifugal force expressed in
+
+163
+00:13:07,080 --> 00:13:12,810
+gravityهلأ معظم التقنيات و التجارب و الفحوصات اللي
+
+164
+00:13:12,810 --> 00:13:17,370
+إحنا بنستخدمها لابد إنه نمر بمرحلة فصل للعينة عشان
+
+165
+00:13:17,370 --> 00:13:21,370
+نحصل على مثلا plasma نحصل على serum إذا كان أنا
+
+166
+00:13:21,370 --> 00:13:25,550
+بستخدم blood أو نحصل على sediment إذا أنا بستخدم
+
+167
+00:13:25,550 --> 00:13:30,490
+عينة urine أو stool أو whatever تمام؟ لازم أنا قبل
+
+168
+00:13:30,490 --> 00:13:34,550
+ما أجري الفحص أستخدم إيش؟ أستخدم ال ..
+
+169
+00:13:37,540 --> 00:13:41,440
+يعني قبل لأجر الفحص أستخدم الcentrifugal حتى أفصل
+
+170
+00:13:41,440 --> 00:13:48,140
+العينة تبعتي طبعا طيب التجربة تبعتي بيكون مانشنلي
+
+171
+00:13:48,140 --> 00:13:52,640
+او محددلي انه افصلي على سرعة كذا او باستخدام
+
+172
+00:13:52,640 --> 00:13:57,660
+relative centrifugal forces قيمتها كذا طبعاو دايما
+
+173
+00:13:57,660 --> 00:14:00,660
+بيعبّر عن ال relative centrifugal forces على إنها
+
+174
+00:14:00,660 --> 00:14:05,560
+هي بدلالة ال G احنا حاكينا هي أضعف أضعف ل gravity،
+
+175
+00:14:05,560 --> 00:14:08,520
+لذا هيعبّر عنها بدلالة ال gravity، زي هنا مثال
+
+176
+00:14:08,520 --> 00:14:13,880
+بيحكي 2000 X gravity، يعني إن ال relative
+
+177
+00:14:13,880 --> 00:14:18,620
+centrifugal forcesهي تقريبا ألفين ضعف أو ألفين مرة
+
+178
+00:14:18,620 --> 00:14:23,340
+جد ل gravity طبعا ألفين ضعف ل gravity قوة الجاذبية
+
+179
+00:14:23,340 --> 00:14:28,320
+طبعا وهي هنا بنعبر عنها بقانون عبارة عن حاصل ضرب
+
+180
+00:14:28,320 --> 00:14:33,640
+ثابت واحد point واحد اتنين في عشرة أسالب خمسة في
+
+181
+00:14:33,640 --> 00:14:37,550
+الار في ال round per minute استربيةطبعا ال round
+
+182
+00:14:37,550 --> 00:14:39,790
+per minute او ال revolution per minute اللي هي
+
+183
+00:14:39,790 --> 00:14:42,650
+السرعة حكينا ان ال relative centrifuge forces
+
+184
+00:14:42,650 --> 00:14:46,630
+هتتعد تعتمد على ال R اللي هو ال radius و تعتمد على
+
+185
+00:14:46,630 --> 00:14:52,660
+السرعة ال speedتمام؟ هذا الكلام هو بس شرح
+
+186
+00:14:52,660 --> 00:14:56,360
+للاختصارات إيش يعني RCF؟ centrifugal forces أو
+
+187
+00:14:56,360 --> 00:15:00,320
+relative centrifugal forces قوة الطرد المركزي ال R
+
+188
+00:15:00,320 --> 00:15:03,840
+هو ال radius و ال round per minute أو ال
+
+189
+00:15:03,840 --> 00:15:06,740
+revolution per minute اللي هي السرعة و ال G
+
+190
+00:15:06,740 --> 00:15:11,000
+gravitational force طبعاً ده الوحدة اللي بنقيس
+
+191
+00:15:11,000 --> 00:15:16,700
+فيها إذا هذا الرقم بطلعلي مثلا لو أنا حسبت عوضت
+
+192
+00:15:16,700 --> 00:15:23,750
+بقيمة ال Rقطر الجهاز وسرعته وطلع عندي قيمة، هذه
+
+193
+00:15:23,750 --> 00:15:27,730
+القيمة عبارة هي عن .. مثلا طلعت خمس تلاف، هي خمس
+
+194
+00:15:27,730 --> 00:15:32,690
+تلاف G بكتب، يعني خمس تلاف مرة ضعف ال gravity اللي
+
+195
+00:15:32,690 --> 00:15:39,270
+هو الجاذبية الأرضية، تمام؟طيب نشوف إيش هي مكونات
+
+196
+00:15:39,270 --> 00:15:44,610
+هذا الجهاز لو أنا جيت أشوف إيش مكونات الجهاز يعني
+
+197
+00:15:44,610 --> 00:15:48,610
+مكوّن من ال central shaft المكوين الأول central
+
+198
+00:15:48,610 --> 00:15:53,310
+shaft، تمام؟ ال central shaft هو عبارة عن المحور
+
+199
+00:15:53,310 --> 00:16:00,280
+المركزي اللي موجود في منتصف الجهاز، تمام؟ و ..هو
+
+200
+00:16:00,280 --> 00:16:03,440
+اللي مسؤول عن الدوران هو اللي بيلف و بيدور طبعا
+
+201
+00:16:03,440 --> 00:16:09,960
+اذا هو the part that rotates الجزء اللذي يدور طبعا
+
+202
+00:16:09,960 --> 00:16:13,860
+لما بيصير فيه عملية spinning او centrifugation او
+
+203
+00:16:13,860 --> 00:16:17,380
+sedimentation او fossil separation طبعا هذه كلها
+
+204
+00:16:17,380 --> 00:16:20,540
+مصطلحات نفس الاشي لما اقول انا عملت spinning
+
+205
+00:16:20,540 --> 00:16:24,940
+للعينة اعملت centrifugation اعملت sedimentation
+
+206
+00:16:25,180 --> 00:16:28,680
+عملت separation نفس المعنى يعني أنا عملت فصلتها
+
+207
+00:16:28,680 --> 00:16:33,440
+باستخدام جهاز ال centrifuge طبعا طيب إذا هو الجزء
+
+208
+00:16:33,440 --> 00:16:40,800
+اللي بي rotate بيلف طبعا طيبال .. ال head هي ال ..
+
+209
+00:16:40,800 --> 00:16:45,400
+الرأس يعني هذه الحلقة الدائرية اللي موجودة في ..
+
+210
+00:16:45,400 --> 00:16:50,600
+يعني at the top of centrifuge موجودة في .. يعني
+
+211
+00:16:50,600 --> 00:16:54,680
+على .. أعلى ال centrifuge، هاي الحلقة الدائرية،
+
+212
+00:16:54,680 --> 00:16:57,600
+تمام؟ زي ما تشتركي ان هذا ال course الدائري بسميه
+
+213
+00:16:57,600 --> 00:17:01,360
+headتمام؟ هذا الhead عبارة عن فتحات و الفتحات ها
+
+214
+00:17:01,360 --> 00:17:06,140
+دي موجود فيها buckets موجود فيها مش أنبيب يعني هي
+
+215
+00:17:06,140 --> 00:17:10,880
+.. يعني مصممة ع شكل الإنبوب و أنا ما بحط فيها
+
+216
+00:17:10,880 --> 00:17:15,000
+العينة مباشرة لأ أنا بحط داخلها ال tube و داخل ال
+
+217
+00:17:15,000 --> 00:17:19,600
+tube بيكون فيه العينة تمام؟ اذا موجود فيها ال
+
+218
+00:17:19,600 --> 00:17:25,790
+buckets اللي يعني اللي بتستقبل العينة تمام؟إذا الـ
+
+219
+00:17:25,790 --> 00:17:30,010
+head هي عبارة عن it's a part that hold the bucket
+
+220
+00:17:30,010 --> 00:17:35,450
+إذا هو الجزء اللي بيحمل أو بيثبت ال buckets، اللي
+
+221
+00:17:35,450 --> 00:17:42,650
+هي مكان وضع العينة، تمام؟وهو اللي بيوصل القنابيب
+
+222
+00:17:42,650 --> 00:17:46,050
+حلقة وصل القنابيب مع ال central shaft يعني
+
+223
+00:17:46,050 --> 00:17:50,030
+القنابيب إذا حطت وموجودة على ال head خلاص طالما
+
+224
+00:17:50,030 --> 00:17:53,630
+أنه لف ال .. ال .. ال central shaft إذا صار يدور
+
+225
+00:17:53,630 --> 00:17:57,650
+معناها القنابيب صارت تدور معاه، تمام؟ طيب الجزء
+
+226
+00:17:57,650 --> 00:18:00,470
+التالت اللي هي ال buckets أو ال tubes حكينا إنها
+
+227
+00:18:00,470 --> 00:18:06,050
+هذه قنابيب مصممة أو buckets مصممة لتستقبل قنابيب
+
+228
+00:18:06,050 --> 00:18:10,770
+العينة إذا إن هي عبارة عن a portion جزء تمام؟that
+
+229
+00:18:10,770 --> 00:18:15,010
+hold test tubes بتثبت أنا بيه بالفحص أو أنا بيه
+
+230
+00:18:15,010 --> 00:18:18,030
+باللي أنا بشتغل فيها اللي فيها عينتي to beast band
+
+231
+00:18:18,030 --> 00:18:22,130
+طبعا الجهاز ال centrifuge يا بنات بيكون طبعا هذا
+
+232
+00:18:22,130 --> 00:18:26,650
+الجزء أنا ما بشوفه ده يعني ما بيكون مرئي هنا يعني
+
+233
+00:18:26,650 --> 00:18:32,190
+زي يعملي زي كأنه نازعالجزء الأمامي من الجهاز عشان
+
+234
+00:18:32,190 --> 00:18:37,290
+يشوفها يعني هذه رسمة توضيحية لمحتويات الجهاز ولكن
+
+235
+00:18:37,290 --> 00:18:40,370
+انا لما بشوف .. بس بشوف ال .. ال .. يعني انا لما
+
+236
+00:18:40,370 --> 00:18:43,490
+بدي ألقي نظرة بلقي نظرة علوية على الجهاز من هنا
+
+237
+00:18:43,490 --> 00:18:48,970
+تمام من الفتحة تبعته بشوف بس ال head و ال .. ال
+
+238
+00:18:48,970 --> 00:18:52,150
+buckets تمام؟ مابشوفش ال shaft ال central shaft
+
+239
+00:18:52,150 --> 00:18:59,950
+مابشوفهتمام؟ إذا هذه هي مكونات الجهاز طيب نيجي
+
+240
+00:18:59,950 --> 00:19:03,650
+لأنواع ال .. ال centrifuge classification of
+
+241
+00:19:03,650 --> 00:19:07,730
+centrifuge تصنيف ال centrifuge أو أنواعه طبعا حسب
+
+242
+00:19:07,730 --> 00:19:12,810
+على .. على ماذا يدار هذا الجهاز أو كيف يتم إدارة
+
+243
+00:19:12,810 --> 00:19:18,190
+أو تشغيل هذا الجهاز يتصنف ال centrifuges ل hand
+
+244
+00:19:18,190 --> 00:19:22,980
+centrifuges و electrical centrifugesمن اسمها hand
+
+245
+00:19:22,980 --> 00:19:27,720
+centrifuges إذا .. إذا تدار باستخدام .. إيش؟
+
+246
+00:19:27,720 --> 00:19:31,780
+باستخدام اليد أما ال .. ال electrical centrifuges
+
+247
+00:19:31,780 --> 00:19:35,980
+تدار باستخدام الكهربا طبعا؟ طيب خلينا نشوف إيش
+
+248
+00:19:35,980 --> 00:19:40,080
+يعني hand centrifugesزي ما انتوا شايفين هي عبارة
+
+249
+00:19:40,080 --> 00:19:44,300
+عن old fashion of centrifuge يعني ال centrifuge
+
+250
+00:19:44,300 --> 00:19:51,060
+هيك موديل قديم، دقة قديمة، تمام؟ ويعني ال .. ال ..
+
+251
+00:19:51,060 --> 00:19:54,780
+ال .. موديل القديم من ال centrifuge ب .. ب .. بيتم
+
+252
+00:19:54,780 --> 00:19:57,980
+تشغيله باستخدام ال hand يعني باليدوي، تمام؟ انا
+
+253
+00:19:57,980 --> 00:20:03,290
+بحرك ال .. اليد هادي و بيصير يدورطمام؟ هى زى ما
+
+254
+00:20:03,290 --> 00:20:06,370
+انتوا شايفين الـ central shaft و head هى الدائرة
+
+255
+00:20:06,370 --> 00:20:09,970
+اللى عاملة زى ال cross و ال buckets هى هى طبعا
+
+256
+00:20:09,970 --> 00:20:14,150
+هادى انا بحط فيها القنابيب تبعتي طيب اذا بيتم
+
+257
+00:20:14,150 --> 00:20:17,490
+تشغيله اما بال hand او بال water pressure يعني
+
+258
+00:20:17,490 --> 00:20:20,950
+ممكن ضغط ماء يأثر على اليد هادى و تصير يحركها
+
+259
+00:20:20,950 --> 00:20:25,570
+فاتلف و يلف معاها الجهاز و يتم الفصلطبعا بما ان
+
+260
+00:20:25,570 --> 00:20:28,610
+old fashion معناها بيستخدم في ال small
+
+261
+00:20:28,610 --> 00:20:34,170
+laboratories كان يستخدم قديما بيستخدم ممكن في ال
+
+262
+00:20:34,170 --> 00:20:37,870
+routine purposes اش يعني routine purposes؟ لما
+
+263
+00:20:37,870 --> 00:20:44,510
+احكي routine test او routine lab work يعني urine
+
+264
+00:20:44,510 --> 00:20:50,250
+and stool analysis طبعا؟ اذا بيستخدم هذا النوع من
+
+265
+00:20:51,010 --> 00:20:55,410
+ال .. ال .. ال centrifuges في ال routine work يعني
+
+266
+00:20:55,410 --> 00:20:58,810
+في ال urinary sediment عشان أحضر ال urinary
+
+267
+00:20:58,810 --> 00:21:02,210
+sediment أفصل عينة ال urine عشان أعمل
+
+268
+00:21:02,210 --> 00:21:05,110
+concentration لل parasites اللي موجود في ال stool
+
+269
+00:21:05,110 --> 00:21:08,730
+تمام؟ إذا عينات ال urine هو ال stool اللي بيستخدم
+
+270
+00:21:08,730 --> 00:21:15,030
+it is not advisable not advisable مش يعني غير موصف
+
+271
+00:21:15,030 --> 00:21:19,340
+أو غير .. لا ينصحبإنه هذا الجهاز يستخدم عشان أفصل
+
+272
+00:21:19,340 --> 00:21:25,260
+عينة دم فيه، ليش؟ لإنه أنا بستخدم يدوي وحركة يدي
+
+273
+00:21:25,260 --> 00:21:28,820
+مش منتظمة، إذا ال relative centrifugal forces
+
+274
+00:21:28,820 --> 00:21:33,220
+هتكون irregular طالما إنه كانت القوة irregular
+
+275
+00:21:33,220 --> 00:21:37,660
+معناها عملية الفصل غير منتظمة، يعني ممكن ال RBCs و
+
+276
+00:21:37,660 --> 00:21:41,860
+هي عم تنفصل و هي عم بتتجه باتجاه ال sediment تتكسر
+
+277
+00:21:42,510 --> 00:21:45,690
+بالتالي ال serum أو ال plasma اللي أنا بدي أخدها
+
+278
+00:21:45,690 --> 00:21:50,810
+بدل ما يكون لونها لون أصفر و قشي strong color و
+
+279
+00:21:50,810 --> 00:21:56,570
+تكون clear ممكن تتحول لونها للون الأحمر نتيجة تكسر
+
+280
+00:21:56,570 --> 00:22:02,350
+ال RBCs و أيضا خروج محتويات ال RBCs على ال serum
+
+281
+00:22:02,350 --> 00:22:06,710
+أو على ال plasma ممكن يؤثر على عدة فحوصات و تصبح
+
+282
+00:22:06,710 --> 00:22:11,870
+العينة غير صالحة لإجراء الفحوصاتتمام؟ فبالتالي إذا
+
+283
+00:22:11,870 --> 00:22:16,110
+لا ينصح بيه لفصل عينة قدام خلينا نشوف إيش يعني
+
+284
+00:22:16,110 --> 00:22:20,450
+electrical centrifuges electrical centrifuges هي
+
+285
+00:22:20,450 --> 00:22:23,610
+عبارة عن ال centrifuges that are operated by
+
+286
+00:22:23,610 --> 00:22:27,890
+electrical power تمام؟ بيتم إدارتها باستخدام
+
+287
+00:22:27,890 --> 00:22:33,070
+الكهرباء and produce high centrifugal force ب ..
+
+288
+00:22:33,070 --> 00:22:41,000
+يعني ..بتنتج يعني قوة طارد مركزي عالية جدا و
+
+289
+00:22:41,000 --> 00:22:44,860
+بتستخدم في ال most medical laboratories و بتستخدم
+
+290
+00:22:44,860 --> 00:22:49,200
+ايضا لفصل عينات الدم يعني بتعطيني انه يعني فصل
+
+291
+00:22:49,200 --> 00:22:55,570
+دقيق و فصل يعني جيدتمام؟ هذا بالنسبة ليه .. how it
+
+292
+00:22:55,570 --> 00:22:59,870
+operated كيف أنا ممكن أشغّل الجهاز by hand or by
+
+293
+00:22:59,870 --> 00:23:04,590
+electric .. electric أو electricity تمام؟ طيب، هلأ
+
+294
+00:23:04,590 --> 00:23:10,470
+بالنسبة لحجم ال centrifuge، في عندي أنواع منهفي
+
+295
+00:23:10,470 --> 00:23:14,310
+micro centrifuge يعني بيستخدم أنا بيب صغيرة أو
+
+296
+00:23:14,310 --> 00:23:18,490
+بسميه zero centrifuge هذا يا بنات بيفصل بينستخدمه
+
+297
+00:23:18,490 --> 00:23:22,750
+for spinning لفصل small tubes يعني انا العينات
+
+298
+00:23:22,750 --> 00:23:25,410
+تبعتي بتكون موجودة في ال small tubes زي ال
+
+299
+00:23:25,410 --> 00:23:28,570
+centrifuges اللي بتكون موجودة في ال blood bank
+
+300
+00:23:28,570 --> 00:23:32,990
+laboratories في مختبرات اللي هو بنوك الدم طبعا
+
+301
+00:23:32,990 --> 00:23:39,100
+خلينا نشوف إيش يعني ال .. ال ..ال small tubes هلأ
+
+302
+00:23:39,100 --> 00:23:42,520
+في عندي tube بسميها ebendrof tube هي صغيرة كتير
+
+303
+00:23:42,520 --> 00:23:45,480
+يعني انها بتاخد بس واحد صندي واحد امقال او واحد و
+
+304
+00:23:45,480 --> 00:23:49,940
+نص امقال تمام هي زي ما انتوا شايفين هنا هي مدرجة و
+
+305
+00:23:49,940 --> 00:23:55,040
+بتاخد يعني واحد امقال او واحد و نص امقال فصغيرة
+
+306
+00:23:55,040 --> 00:23:59,220
+كتير محتوها صغير العينة تبعت اللي هتكون فيها small
+
+307
+00:23:59,220 --> 00:24:04,250
+amountفبالتالي هي small tubes فالجهاز تبعي ال
+
+308
+00:24:04,250 --> 00:24:08,530
+centrifuge بسمي اللي بيفصل او بيستقبل هاي القنابيب
+
+309
+00:24:08,530 --> 00:24:12,110
+و بفصلها بسمي micro centrifuge او sericentrifuge
+
+310
+00:24:12,110 --> 00:24:14,310
+معناها هذا ال micro centrifuge او ال
+
+311
+00:24:14,310 --> 00:24:17,190
+sericentrifuge ال bucket تبعته هتكون صغيرة مصممة
+
+312
+00:24:17,190 --> 00:24:23,040
+على جد عشان ال .. ال .. ال ependrofetubeتمام؟ طيب
+
+313
+00:24:23,040 --> 00:24:27,660
+ال .. بالنسبة ل ال medium-sized centrifuge حجم
+
+314
+00:24:27,660 --> 00:24:31,000
+متوسط يعني بنستخدمه لفصل عينات ال urine ممكن
+
+315
+00:24:31,000 --> 00:24:35,420
+لعينات ال blood بيستخدم medium-sized tubes بيفصل
+
+316
+00:24:35,420 --> 00:24:38,080
+medium-sized tubes اللي هي بنسميها centrifuge
+
+317
+00:24:38,080 --> 00:24:43,120
+tubes اللي أنا بتبعته بسميها centrifuge tubesزي
+
+318
+00:24:43,120 --> 00:24:47,900
+كيف شكلها ممكن يكون هيك شكلها مثلا هذه ممكن أسميها
+
+319
+00:24:47,900 --> 00:24:52,200
+هي falcon tube ويلها غطاية هي اسمها falcon tube
+
+320
+00:24:52,200 --> 00:24:56,740
+تمام ويلها غطاية و لكن هي centrifuge tube نحطها في
+
+321
+00:24:56,740 --> 00:25:00,240
+ال centrifuge و بتفصل تمام و لكن مش هي الأكتر
+
+322
+00:25:00,240 --> 00:25:03,720
+شيوعا في عندي نوع من القنابيب أكتر شيوعا زيها بس
+
+323
+00:25:03,720 --> 00:25:08,020
+مايله غطاية هلأ بورجيكميا هي تمام
+
+324
+00:25:12,270 --> 00:25:18,370
+وينو كان موجود من شوي هنا هاي .. هذا بسميه
+
+325
+00:25:18,370 --> 00:25:22,470
+centrifuge tube تمام؟ و بنستخدم .. و هنستخدمه كتير
+
+326
+00:25:22,470 --> 00:25:28,850
+في المختبرات طبعتنا medium size تمام؟ طيب لكن ال
+
+327
+00:25:28,850 --> 00:25:33,110
+.. ال .. ال large centrifuges ال .. ال centrifuges
+
+328
+00:25:33,110 --> 00:25:36,290
+الكبيرة بتاخد أنابيب كتير كبيرة يا بنات يعني هاي
+
+329
+00:25:36,290 --> 00:25:42,940
+مثلا ممكن زي هاي الأنابيبشايفين هنا الحجم تبعها
+
+330
+00:25:42,940 --> 00:25:50,280
+بيصل لخمسين أمقال يعني، تمام؟ هذا هو الحجم اللي
+
+331
+00:25:50,280 --> 00:25:54,640
+أنا بيبلي كبيرة، ممكن يعني بياخد لخمسين أمقال،
+
+332
+00:25:54,640 --> 00:25:59,500
+ممكن فلسكات، تيوبات حجمها كبير، فبالتالي هذه
+
+333
+00:25:59,500 --> 00:26:03,080
+بسميها إيش؟ Large Centrifugesنستخدمها في ال
+
+334
+00:26:03,080 --> 00:26:07,640
+bacteriology أو أحيانا كمان في ال cytology في ال
+
+335
+00:26:07,640 --> 00:26:15,420
+.. ال .. لعبات الخلايا و ال .. يعني علم الخلايا و
+
+336
+00:26:15,420 --> 00:26:18,900
+العلم ال micro part لو أنا مثلا عاملة enrichment
+
+337
+00:26:18,900 --> 00:26:22,800
+عاملة cultivation .. culture لبكتيريا، زراعة
+
+338
+00:26:22,800 --> 00:26:27,340
+بكتيريا بكميةبكميات يعني في .. في أنابيب كبيرة و
+
+339
+00:26:27,340 --> 00:26:30,160
+هلأ بدي أفصل ال .. أنا ال bacteria بحيث أني
+
+340
+00:26:30,160 --> 00:26:33,320
+أرسّبها و أستخدمها، أعمل عليها تطبيقات، بستخدم ال
+
+341
+00:26:33,320 --> 00:26:38,000
+dark centrifuge، تمام؟ طيب، هذا بالنسبة لمين؟ لـ
+
+342
+00:26:38,000 --> 00:26:43,160
+ال .. ال أنواع ال centrifuges حسب حجمها، تمام؟أي
+
+343
+00:26:43,160 --> 00:26:48,160
+جهاز أنا بدي أستخدمه طبعا لازم في عندي تعليمات كيف
+
+344
+00:26:48,160 --> 00:26:51,960
+أنا أستخدمه و كيف أنا أعتني بهذا الجهاز و أحافظ
+
+345
+00:26:51,960 --> 00:26:55,760
+عليه أول إشي reading of the manufacturer
+
+346
+00:26:55,760 --> 00:27:00,520
+instruction لما أنا أقرأ تعليمات الجهة المصنع لهذا
+
+347
+00:27:00,520 --> 00:27:05,280
+الجهاز الكتيب اللي بيجي مع الجهاز ساعتها أنا عرفت
+
+348
+00:27:05,280 --> 00:27:09,500
+كيف أستخدمه كيف أحافظ عليه كيف انا يعني المحاذير
+
+349
+00:27:09,500 --> 00:27:14,640
+اللي بتكون يعني مرفقة مع هذاالجهاز طبعا؟ طيب و
+
+350
+00:27:14,640 --> 00:27:21,560
+أيضا لازم كجهاز centrifuge انا اعمله placing على
+
+351
+00:27:21,560 --> 00:27:25,140
+firm level bench ايش يعني؟ يعني احطه على bench
+
+352
+00:27:25,140 --> 00:27:29,320
+ثابت غير .. يعني مش .. غير قبل الاهتزاز او الحركة
+
+353
+00:27:29,320 --> 00:27:35,760
+او انه ممكن الجهاز ييجع منه طبعا؟و أيضا لإنه يا
+
+354
+00:27:35,760 --> 00:27:41,300
+بنات لما إحنا بنشغل هذا الجهاز بيعطيني ذدابات أو
+
+355
+00:27:41,300 --> 00:27:46,320
+vibrations اهتزازات لو ماكانش على بنش ثابت و
+
+356
+00:27:46,320 --> 00:27:51,420
+الجهاز موجود يعني ثابت على ال .. ال bench فممكن
+
+357
+00:27:51,420 --> 00:27:56,160
+إنه يتحرك و يجعل تمام؟ و أيضا لازم أنا أبعده عن ال
+
+358
+00:27:56,160 --> 00:28:01,890
+sunlight عن ضوء الشمسيخرب و بحطه داخل ال bench
+
+359
+00:28:01,890 --> 00:28:05,630
+يعني مش على طرف ال bench لإنه مع الاهتزازات ممكن
+
+360
+00:28:05,630 --> 00:28:09,930
+أنه يقع الجهاز always closing the centrifuge
+
+361
+00:28:09,930 --> 00:28:15,010
+before turning it on ده طبعا لازم أن أنا أسكر
+
+362
+00:28:15,010 --> 00:28:18,990
+غطايت ال centrifuge لما بدي أشغل ال centrifuge
+
+363
+00:28:18,990 --> 00:28:24,220
+لازم أنا أسكر ال cover طبعه بعدين أشغلهليش؟ لإنه
+
+364
+00:28:24,220 --> 00:28:27,880
+لو أنا شغلته هو فاتح ممكن تطاير الأنابيب أو يطاير
+
+365
+00:28:27,880 --> 00:28:32,820
+محتوياها أو ينكب نتيجة فعل ال .. يعني ال rotation،
+
+366
+00:28:32,820 --> 00:28:37,900
+تمام؟ فبالتالي خطأ إن أنا أشغله هو فاتح لازم أسكر
+
+367
+00:28:37,900 --> 00:28:43,480
+الجهاز قبل لأشغله Always balancing the tubes that
+
+368
+00:28:43,480 --> 00:28:47,890
+are being centrifugedهلأ طبعا لازم انا اعمل
+
+369
+00:28:47,890 --> 00:28:52,270
+balance لليوبيات على مرجوحة ال .. ال .. السلاسل
+
+370
+00:28:52,270 --> 00:28:55,590
+لما بيشوا بي .. بيجلسوا الناس اللي جاية تلعب
+
+371
+00:28:55,590 --> 00:29:00,850
+بيجلسوهم كل اتنين مقابل بعضهم و بيكونوا طبعا نفس
+
+372
+00:29:00,850 --> 00:29:04,610
+الحجم أو نفس الوزن، يعني نفس الكتلة، تمام؟ يفضل،
+
+373
+00:29:04,610 --> 00:29:09,000
+يرعى، هيكطبعا فنفس الفكرة في جهاز ال centrifuge
+
+374
+00:29:09,000 --> 00:29:13,640
+لما انا بدي احط القنابيب داخل ال centrifuge لازم
+
+375
+00:29:13,640 --> 00:29:17,440
+احطها balance اش يعني كل tube مقابلها tube نفس
+
+376
+00:29:17,440 --> 00:29:21,800
+الشكل و نفس الحجم و نفس المحتوى طبعا بحطهم مقابل
+
+377
+00:29:21,800 --> 00:29:25,770
+بعضهم البعضطب إذا أنا ماعملت balancing راح يصير
+
+378
+00:29:25,770 --> 00:29:29,950
+فيه اهتزازات للجهاز ممكن يقع ممكن تتكسر الأنابيب
+
+379
+00:29:29,950 --> 00:29:35,110
+في الداخل أو ينكب محتوها، تمام؟ وبيعطي صوت يعني
+
+380
+00:29:35,110 --> 00:29:38,830
+إزعاج، بيبطل يستوعب الجهاز، نتيجة أنه مافيش
+
+381
+00:29:38,830 --> 00:29:44,890
+balance، تمام؟ فإذا جزئية ال balance أو نقطة ال
+
+382
+00:29:44,890 --> 00:29:48,630
+balance مهمة جدا يا بناتال tubes should also be
+
+383
+00:29:48,630 --> 00:29:51,230
+the same size and should contain the same amount
+
+384
+00:29:51,230 --> 00:29:53,610
+الأنابيب اللي أنا بدي أحطها بالمقابل بعضها البعض
+
+385
+00:29:53,610 --> 00:29:58,770
+لازم تكون نفس الحجم ومحتوها أيضا نفس الكمية طب أنا
+
+386
+00:29:58,770 --> 00:30:05,030
+عندي انبوب واحدة فيها 5 cm أو 5 أمقال من ال blood
+
+387
+00:30:05,030 --> 00:30:08,790
+طب أنا كيف بدي أفصلها كيف بدي أعمل لها balance؟
+
+388
+00:30:08,790 --> 00:30:12,590
+مالهاش balance أحطها لحالها؟ لأ يستحق أحطها لحالها
+
+389
+00:30:12,950 --> 00:30:17,830
+لازم أحط tube .. أجيب tube نفس الشكل و نفس الحجم و
+
+390
+00:30:17,830 --> 00:30:23,150
+أحط فيها خمسة أمقال water تمام? distilled water أو
+
+391
+00:30:23,150 --> 00:30:27,290
+water .. tap water تمام؟ و أحطهم مقابل بعضهم البعض
+
+392
+00:30:27,290 --> 00:30:33,150
+في الجهاز نهائيا الجهاز ما بيستوعب ولا بيشتغل إذا
+
+393
+00:30:33,150 --> 00:30:37,450
+ما .. انا ماحطيت balanceتمام؟ إذا ما حطيتله إشي
+
+394
+00:30:37,450 --> 00:30:41,770
+usingه يعني كل عينة مقابلها عينة أو كل tube
+
+395
+00:30:41,770 --> 00:30:45,730
+مقابلها tube نفس الشكل، نفس الحجم، نفس المحتوى أو
+
+396
+00:30:45,730 --> 00:30:50,660
+نفس الكمية من المحتوى، تمام؟ إذا أنا ما ..يعني
+
+397
+00:30:50,660 --> 00:30:54,000
+مابدى أحط balance الجهاز بتنح بيبقى بيصير ما
+
+398
+00:30:54,000 --> 00:30:57,620
+بيشتغل بيكسر القنابيب و بيكب القنابيب و بطلع صوت
+
+399
+00:30:57,620 --> 00:31:00,460
+كتير كبير عالي و بيصير فيه اهتزازات و vibration
+
+400
+00:31:00,460 --> 00:31:05,540
+يعني الجهاز بطل يستوعب عن جد تمام never open the
+
+401
+00:31:05,540 --> 00:31:09,240
+centrifuge while it is spinning never try to slow
+
+402
+00:31:09,240 --> 00:31:13,800
+it down with your hand طبعا ممنوع منعا باتا انه
+
+403
+00:31:13,800 --> 00:31:18,500
+احاول اوقف الجهاز أثناء دورانه او يعني او احاول
+
+404
+00:31:18,500 --> 00:31:23,890
+ابطق بإيديأول إشي ممنوع أفتح الجهاز أثناء دورانه
+
+405
+00:31:23,890 --> 00:31:27,170
+لإنه ممكن تطير الأنابيب و .. أو يكبل محتوى .. أو
+
+406
+00:31:27,170 --> 00:31:31,370
+يطير محتواها، تمام؟ هاي شغلة، نتيجة السرعة
+
+407
+00:31:31,370 --> 00:31:36,990
+العالية، لو إنتي على .. على لعبة سلاسل و إن فتح
+
+408
+00:31:36,990 --> 00:31:41,070
+الكرسي، بطل فيه أمان للكرسي، بتطير الشخص اللي
+
+409
+00:31:41,070 --> 00:31:44,690
+بيرعب على الكرسي، يعني جارس على اللعبة، تمام؟ نفس
+
+410
+00:31:44,690 --> 00:31:50,880
+الفكرة هناإذا أنا فتحت ال .. ال cover تبع الجهاز
+
+411
+00:31:50,880 --> 00:31:56,910
+بتطير الأنابيب أو محتوهاتمام؟ ممنوع لما ال ..
+
+412
+00:31:56,910 --> 00:32:01,870
+الجهاز بيتوقف عن الدوران أو بتخلص مدة دورانه لحاله
+
+413
+00:32:01,870 --> 00:32:06,890
+بيصير يبطء تدريجي لإلى أن يقف تمام؟ ممنوع أنا
+
+414
+00:32:06,890 --> 00:32:12,530
+أحاول أ .. أسرع او أباطئ حركته بإيدي، أسرع إيقافه
+
+415
+00:32:12,530 --> 00:32:16,690
+أو أبطئ حركته بإيدي، أعمله slow down بإيدي، بyour
+
+416
+00:32:16,690 --> 00:32:22,350
+handممنوع؟ ليش؟ طيب خلينا نشوف هنا هي عين الدم
+
+417
+00:32:22,350 --> 00:32:25,210
+انفصلت باستخدام جهاز ال centrifuge أفضل اشي ال
+
+418
+00:32:25,210 --> 00:32:28,090
+RBCs نزلت لتحت في ال bottom بعدها ال buffy coat
+
+419
+00:32:28,090 --> 00:32:34,050
+بعدها ال plasma طبعا لو أنا جيت أثناء الجهاز هو عم
+
+420
+00:32:34,050 --> 00:32:39,950
+بيوقف أو بيبطق سرعته لحتى يقف بعد ما خلص فصل طبعا
+
+421
+00:32:39,950 --> 00:32:43,010
+بعد ما صار الشكل اللي منضوب بهذا الشكل يعني خلص
+
+422
+00:32:43,010 --> 00:32:48,710
+فصل طبعالو أنا جيت حطيت إيدي عشان أسرع إيقافه، جزء
+
+423
+00:32:48,710 --> 00:32:52,350
+من ال red blood cell اللي هي ال sediment اللي في
+
+424
+00:32:52,350 --> 00:32:56,570
+القاع بيندفع باتجاه ال .. ال .. الطب، باتجاه ال
+
+425
+00:32:56,570 --> 00:33:00,450
+surface، تمام؟ يعني بتختلط الأنبوبة مرة تانية،
+
+426
+00:33:00,450 --> 00:33:04,530
+أصبح ساعتها ال sedimentationال separation ال
+
+427
+00:33:04,530 --> 00:33:09,470
+centrifugation ال spinning اشماله not efficient مش
+
+428
+00:33:09,470 --> 00:33:13,730
+فعال مش كويس انا مافصلتش كويس لإنه انا بال .. يعني
+
+429
+00:33:13,730 --> 00:33:22,230
+بالاخر يعني .. فصلت العينة بالاخر انا جيت خربتها
+
+430
+00:33:22,230 --> 00:33:25,710
+بنفسي لما حطيت إيدي على الجهاز عشان أسرع إيقافه
+
+431
+00:33:25,710 --> 00:33:27,270
+طبعا؟ طيب
+
+432
+00:33:29,630 --> 00:33:34,370
+إذا بستناله لحتى يتوقف بنفسه ما بوقفه بإيدي أو
+
+433
+00:33:34,370 --> 00:33:38,350
+بحاول أبطق سرعته بإيدي لو في حال .. لو في حال أنا
+
+434
+00:33:38,350 --> 00:33:42,810
+مثلا انسيت أن أنا أعمل balance انسيت أضيف tube أو
+
+435
+00:33:42,810 --> 00:33:46,980
+أحط بعض القنابيب يعنيحطت جزء منهم و ماحطت الجزء
+
+436
+00:33:46,980 --> 00:33:50,560
+التاني فممكن في عندي حاجة اسمها break في الجهاز
+
+437
+00:33:50,560 --> 00:33:54,760
+بيوقفوا بسرعة بحيث أن أنا أفتح الجهاز و أحط
+
+438
+00:33:54,760 --> 00:33:59,920
+قنابيبي يعني القنابيب اللي بدي أحطهم و بعدين أرجع
+
+439
+00:33:59,920 --> 00:34:05,820
+أسكر الجهاز و يرجع الجهاز ي .. يعمل around أو
+
+440
+00:34:05,820 --> 00:34:11,380
+centrifugal forces أو ..rotation مرة تانية، طبعا،
+
+441
+00:34:11,380 --> 00:34:14,300
+إذا ال break أنا مابستخدمه إلا إذا في حالة طارقة،
+
+442
+00:34:14,300 --> 00:34:17,880
+أنا بدي وقفه بحق .. بدي أوقف الجهاز في حالة طارقة،
+
+443
+00:34:17,880 --> 00:34:21,680
+طبعا، ولكن أنا إذا بدي أشتغل، بدي أفصل منيح، يفضل
+
+444
+00:34:21,680 --> 00:34:25,080
+إن أنا أستنى على الجهاز لحتى يتباطأ سرعته تدريجيا
+
+445
+00:34:25,080 --> 00:34:30,440
+ويقف لحالهطبعا في timer في الجهاز انا بحدد السرعة
+
+446
+00:34:30,440 --> 00:34:35,040
+اللي بدياها هاي هنا و بحدد ال timer يعني كام وقت
+
+447
+00:34:35,040 --> 00:34:38,200
+الفصل five minutes بعد الجهاز عن five minutes بس
+
+448
+00:34:38,200 --> 00:34:44,460
+يخلصه بيبدأ .. بي .. بيعطيني run هذا الجرس تبعه
+
+449
+00:34:44,460 --> 00:34:47,760
+بيعطيني run انه خلاص توقف الفصل و توقف الجهاز و
+
+450
+00:34:47,760 --> 00:34:53,580
+خلصت المدة فبتبدأ تتباطأ حركته الى ان يقف لحاله
+
+451
+00:34:53,580 --> 00:34:58,850
+طبعا؟هذا بالنسبة لجهاز ال centrifuge ان شاء الله
+
+452
+00:34:58,850 --> 00:35:03,290
+كتطبيق على جهاز ال centrifuge راح ناخد فحص اسمه
+
+453
+00:35:03,290 --> 00:35:07,830
+hematocrit تمام؟ او نسبة ال RBC's نسبة .. نسبة
+
+454
+00:35:07,830 --> 00:35:11,270
+المئوية ل ال RBC's من ايش؟ من ال whole blood
+
+455
+00:35:11,270 --> 00:35:15,750
+volume يعني جدش بتحتل ال RBC's من ال whole volume
+
+456
+00:35:15,750 --> 00:35:19,730
+ده اعتبر ان العينة ال blood كلها 100% و اشوف ال
+
+457
+00:35:19,730 --> 00:35:24,170
+RBC's كام في المية من هذه العينةتمام؟ احنا أخدنا
+
+458
+00:35:24,170 --> 00:35:28,150
+إنه هي theoretical 45% بنشوف عند .. في ال .. في
+
+459
+00:35:28,150 --> 00:35:31,890
+البناء أدمين كام بتكون نسبتها أو يعني كام ال range
+
+460
+00:35:31,890 --> 00:35:38,060
+طبعهاتمام هذا ال .. التطبيق العملي رح يكون يعني
+
+461
+00:35:38,060 --> 00:35:42,100
+أنا راح أسحب عين الدم راح أحطها في tube طبعا ال ..
+
+462
+00:35:42,100 --> 00:35:46,060
+ال .. ال .. هذا شرح عشان ي .. يقربلي الفكرة ولكن
+
+463
+00:35:46,060 --> 00:35:49,820
+أنه أنا بدي أحطها في tube خاصة في الفحص ال
+
+464
+00:35:49,820 --> 00:35:53,500
+hematocrite و بعدين بحطها في جهاز centrifuge أصلا
+
+465
+00:35:53,500 --> 00:35:57,870
+أيضا خاص في ..فحص الـ hematocrit بسميه hematocrit
+
+466
+00:35:57,870 --> 00:36:02,350
+centrifuge و بفصل بعدين بقيس على باستخدام meter
+
+467
+00:36:02,350 --> 00:36:08,410
+باستخدام مقياس مخصص لل hematocrit بشوف نسبة ال ..
+
+468
+00:36:08,410 --> 00:36:12,230
+ال .. ال RBC's كام في المية من اللي هو المية في
+
+469
+00:36:12,230 --> 00:36:17,160
+المية العينة كلهاتمام؟ هذا هو اللي راح يكون عنوان
+
+470
+00:36:17,160 --> 00:36:21,080
+محاضرتنا العملية اللي هي math of creative تمام؟
+
+471
+00:36:21,080 --> 00:36:26,040
+طيب إذا وصلنا لنهاية محاضرتنا اليوم أتمنى تكونوا
+
+472
+00:36:26,040 --> 00:36:29,540
+استفدتوا يكون الأشي بسيط بالنسبالي لكم أي سؤال ما
+
+473
+00:36:29,540 --> 00:36:32,580
+تترددوا تسألوني إما ب group ال whatsapp أو ان شاء
+
+474
+00:36:32,580 --> 00:36:38,000
+الله بال discussion الإسبوعي اللي احنا موعدنا كل
+
+475
+00:36:38,000 --> 00:36:42,600
+ثابت الساعة تماني على google meet و بتمنى لكم
+
+476
+00:36:42,600 --> 00:36:48,230
+التوفيقان شاء الله موعدنا يوم السبت الجاي على ال
+
+477
+00:36:48,230 --> 00:36:54,690
+google meet لحتى نتناقش بمحتوى المحلرة يعطيكم
+
+478
+00:36:54,690 --> 00:36:55,210
+العافية
+
diff --git a/PL9fwy3NUQKwY9jl8xw-bWkVZkWcGGyspd/OkcVPozKdZ4_postprocess.srt b/PL9fwy3NUQKwY9jl8xw-bWkVZkWcGGyspd/OkcVPozKdZ4_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..ef8b293bdc3be9f516e220733d8802ecf9506f4a
--- /dev/null
+++ b/PL9fwy3NUQKwY9jl8xw-bWkVZkWcGGyspd/OkcVPozKdZ4_postprocess.srt
@@ -0,0 +1,1728 @@
+1
+00:00:05,970 --> 00:00:09,190
+السلام عليكم ورحمة الله وبركاته طالبات العزيزات
+
+2
+00:00:09,190 --> 00:00:12,670
+اليوم ان شاء الله راح ناخد مع بعض محاضرة بعنوان
+
+3
+00:00:12,670 --> 00:00:17,550
+glucose test تمام؟ فحص السكر او فحص السكر في الدم
+
+4
+00:00:17,550 --> 00:00:22,900
+او ل glucose testفي البداية blood glucose is the
+
+5
+00:00:22,900 --> 00:00:26,140
+main sugar that the body made from the food in the
+
+6
+00:00:26,140 --> 00:00:31,440
+diet فعليا احنا بنتناوأ الأغذية، هذه الأغذية ممكن
+
+7
+00:00:31,440 --> 00:00:36,280
+تكون سكريات، ممكن تكون carbohydrate معقدة، نشويات
+
+8
+00:00:36,280 --> 00:00:42,220
+مثلا وما شابه، ممكن تكون بروتينات أو دهونلابد من
+
+9
+00:00:42,220 --> 00:00:46,760
+تحويل هذه المواد الغذائية إلى سكر في الدم، تمام؟ و
+
+10
+00:00:46,760 --> 00:00:51,200
+هذا السكر هو ال glucose، تمام؟ لازم يكون glucose
+
+11
+00:00:51,200 --> 00:00:56,400
+لحتى الخلايا تستطيع انها تاخد هذا ال glucose و
+
+12
+00:00:56,400 --> 00:01:00,940
+تصنع منه طاقة، اذا ال blood glucose هو .. يعني
+
+13
+00:01:00,940 --> 00:01:05,370
+السكر الرئيسي اللي احنا بنشوفه في ال ..في الدم أو
+
+14
+00:01:05,370 --> 00:01:10,310
+في الجسم نظرا لإن هو النوع السكري الوحيد اللي ممكن
+
+15
+00:01:10,310 --> 00:01:15,710
+تعرف الخلايا تتعامل معاه تاخدوا تدخلوا اليها عبر
+
+16
+00:01:15,710 --> 00:01:21,430
+مستقبل على سطحها و تصنع من خلاله الطاقة تمام؟
+
+17
+00:01:21,430 --> 00:01:26,600
+produce energyglucose is a simple sugar هو عبارة
+
+18
+00:01:26,600 --> 00:01:30,900
+عن سكر بسيط، monosaccharide، سكر أحادي، the body
+
+19
+00:01:30,900 --> 00:01:35,480
+produce it from protein, fat and in largest part
+
+20
+00:01:35,480 --> 00:01:41,040
+carbohydrate الجسم بيصنعه بشكل أساسي أو بشكل كتير
+
+21
+00:01:41,040 --> 00:01:44,620
+كبير من ال carbohydrate إلى أنوقات أيضا يتم تصنيعه
+
+22
+00:01:44,620 --> 00:01:48,820
+من البروتينات و الدهون مثل ما ذكرنا سابقا
+
+23
+00:01:49,380 --> 00:01:52,820
+الجليجلوكوز is carried through the blood stream to
+
+24
+00:01:52,820 --> 00:01:55,820
+provide energy to all cells in the body اذا ايش
+
+25
+00:01:55,820 --> 00:02:00,260
+وظيفة الجليجلوكوز او ايش اهمته ان هو ينقل عبارة دم
+
+26
+00:02:00,260 --> 00:02:05,040
+الى الخلايا الخلايا بتعمله uptake بتاخده و بتصنع
+
+27
+00:02:05,040 --> 00:02:08,600
+من خلاله الطاقة من خلال عمليات ال glycolysis و
+
+28
+00:02:08,600 --> 00:02:12,460
+creep cycle و ال energy production metabolism اللي
+
+29
+00:02:12,460 --> 00:02:18,420
+انتوا تعلمتوها في ال biochemengusted glucose ال ..
+
+30
+00:02:18,420 --> 00:02:22,820
+ال .. ال glucose اللي يتم تناولوه عبر الفم،
+
+31
+00:02:22,820 --> 00:02:26,740
+engusted glucose is absorbed directly into the
+
+32
+00:02:26,740 --> 00:02:29,780
+blood from the intestine and result in rapid
+
+33
+00:02:29,780 --> 00:02:33,200
+increase in blood glucose. هلأ إذا احنا تناولنا
+
+34
+00:02:33,200 --> 00:02:38,050
+glucose تمامهذا ال glucose يتم امتصاصه مباشرة من
+
+35
+00:02:38,050 --> 00:02:41,710
+ال intestine و على طول بيفوت الدم مابيحتاجش عملية
+
+36
+00:02:41,710 --> 00:02:45,230
+تحويل مش زي السكريات المعقدة أو السكريات اللي هي
+
+37
+00:02:45,230 --> 00:02:48,150
+بنسميها مثلا disaccharide أو polysaccharide أو
+
+38
+00:02:48,150 --> 00:02:52,430
+starch أو whatever فهدول لأ لازم يمروا بمراحل
+
+39
+00:02:52,430 --> 00:02:57,810
+تكسير وتحويل علشان يتحولوا لglucose بعدين يعني يتم
+
+40
+00:02:57,810 --> 00:03:01,920
+نقلهم عبر الدم إلى الخلايالكن اذا احنا عملنا
+
+41
+00:03:01,920 --> 00:03:06,940
+ingested glucose يعني تناولنا glucose pure فهذا
+
+42
+00:03:06,940 --> 00:03:10,260
+على طول يتم امتصاصه من ال intestine بيفوت الدم و
+
+43
+00:03:10,260 --> 00:03:14,640
+بتنقله الى الخلايا الخلايا طبعا يا اما تستخدمه
+
+44
+00:03:14,640 --> 00:03:19,800
+كمصدر للطاقة اذا هي محتاجة طاقة او راح اتخزنهفإذا
+
+45
+00:03:19,800 --> 00:03:22,720
+ال cells can't use glucose without the help of
+
+46
+00:03:22,720 --> 00:03:26,800
+insulin طبعا بعد إحنا ما نتناول ال glucose و يتم
+
+47
+00:03:26,800 --> 00:03:31,480
+امتصاصه من ال intestine تمام و يفوت على الدم هذا
+
+48
+00:03:31,480 --> 00:03:36,500
+رح يؤدي إلى أو ينتج عنه rapid increase in blood
+
+49
+00:03:36,500 --> 00:03:42,600
+glucose هذا رح يزود أو يعلي تركيز ال glucose في
+
+50
+00:03:42,600 --> 00:03:46,570
+الدمcells can't use glucose without the help of
+
+51
+00:03:46,570 --> 00:03:51,610
+insulin طبعا الخلايا ما بتستطيع انها تصنع او انه
+
+52
+00:03:51,610 --> 00:03:56,650
+تستخدم ال glucose او تصنع منه طاقة بدون مساعدة ال
+
+53
+00:03:56,650 --> 00:04:00,250
+insulin اذا ال insulin هو المفتاح اللي بيفتح بوابة
+
+54
+00:04:00,250 --> 00:04:04,130
+ال glucose و بيخلي الخلايا مثلا اتمرر ال glucose
+
+55
+00:04:04,130 --> 00:04:09,030
+الى داخلها وبالتالي يمكن بعد هيك تصنيع منه طاقة
+
+56
+00:04:09,030 --> 00:04:13,630
+اذا كنا محتاجين energy او تخزينهالجلوكوز إيه له
+
+57
+00:04:13,630 --> 00:04:17,330
+اسم آخر اللي هو dextrose، تمام؟ إيه له اسم آخر؟
+
+58
+00:04:17,330 --> 00:04:23,770
+Dextrose، في عندي عدة فحوصات احنا ب .. ممكن نجريها
+
+59
+00:04:23,770 --> 00:04:28,630
+على عينة المريض و هي مرتبطة بشكل ما بال blood
+
+60
+00:04:28,630 --> 00:04:33,860
+glucose testهي عدة أشكال لتقييم موضع السكر في الدم
+
+61
+00:04:33,860 --> 00:04:38,740
+من هذه الفحصات ال homoglobin A1C الفحص الأول
+
+62
+00:04:38,740 --> 00:04:42,240
+homoglobin A1C هلأ ال .. ال .. ال .. احنا كلنا
+
+63
+00:04:42,240 --> 00:04:45,520
+عارفين انه ال glucose بيفوت على الخلايا إحدى
+
+64
+00:04:45,520 --> 00:04:49,040
+الخلايا اللي بيفوت عليها ال glucose هي ال RBCs
+
+65
+00:04:49,040 --> 00:04:53,910
+خلايا الدم الحمرعفهناك جزء منه بيرتبط مع ال
+
+66
+00:04:53,910 --> 00:04:57,450
+homoglobin و بنسمي ال homoglobin المرتبط مع ال
+
+67
+00:04:57,450 --> 00:05:04,090
+glucose-glycated homoglobin أو homoglobin A1C طبعا
+
+68
+00:05:04,090 --> 00:05:09,210
+إذا كان في عندي زيادة في نسبة السكر في الدم هذا رح
+
+69
+00:05:09,210 --> 00:05:15,470
+يؤدي إلى زيادة في ارتباط السكر مع ال homoglobin A1
+
+70
+00:05:15,470 --> 00:05:19,130
+.. ال homoglobin اللي موجود في ال RBCs فبالتالي رح
+
+71
+00:05:19,130 --> 00:05:24,880
+يؤدي إلى زيادةفي تركيز ال homoglobin A1C ونظرا
+
+72
+00:05:24,880 --> 00:05:31,960
+لإنه ال RBCs يعني ال average لحياتها معدل حياتها
+
+73
+00:05:31,960 --> 00:05:37,320
+او معدل ال life span تبعتها 120 يوم اذا انا ب .. ب
+
+74
+00:05:37,320 --> 00:05:43,100
+.. يعني بنسبة بقياس نسبة homoglobin A1C بإمكاني
+
+75
+00:05:43,100 --> 00:05:47,800
+اني انا اطلع على وضع السكر في الجسم خلال مثلا
+
+76
+00:05:47,800 --> 00:05:52,050
+التلات شهور اللي ماضين ك average timeتمام؟ إذا
+
+77
+00:05:52,050 --> 00:05:56,570
+نرتب أفكارنا شوية إحنا متفقين إنه ال glucose بيكون
+
+78
+00:05:56,570 --> 00:06:02,030
+موجود في ال blood يسري في ال blood ممكن إنه يفوت
+
+79
+00:06:02,030 --> 00:06:06,210
+على الخلايا تاخد الخلايا تصنع منه طاقة أحد الخلايا
+
+80
+00:06:06,210 --> 00:06:09,730
+اللي ممكن يدخل ال glucose لإلها هي ال RBCs حالها
+
+81
+00:06:09,730 --> 00:06:14,890
+حال أي خلية في الجسمولكن جزء من ال glucose هذا
+
+82
+00:06:14,890 --> 00:06:18,830
+بيروح بيرتبط مع ال homoglobin اللي موجود في ال ..
+
+83
+00:06:18,830 --> 00:06:23,250
+ال RBCs فبي .. بينتجلي حاجة اسمها glycated
+
+84
+00:06:23,250 --> 00:06:27,690
+homoglobin أو homoglobin A1C هلأ هذا ال homoglobin
+
+85
+00:06:27,690 --> 00:06:31,870
+A1C كل ما زاد السكر في الدم كل ما زاد دخول السكر
+
+86
+00:06:31,870 --> 00:06:35,970
+على الخلايا كل ما زاد دخوله على ال RBCs كل ما زاد
+
+87
+00:06:35,970 --> 00:06:39,650
+ارتباطه بال homoglobin إذا زاد .. هيزيد تركيزي ال
+
+88
+00:06:39,650 --> 00:06:45,840
+homoglobin A1Cتمام؟ و لإنه عمر خلية ال RBCs 120
+
+89
+00:06:45,840 --> 00:06:50,620
+يوم يعني هم 4 شهور بس أنا ك average ممكن أنا لو
+
+90
+00:06:50,620 --> 00:06:54,700
+جست ال homoglobin A1C في أي لحظة أكون يعني عندي
+
+91
+00:06:54,700 --> 00:07:00,240
+نظرة أو عندي تخمين كيف كان وضع السكر في الجسم خلال
+
+92
+00:07:00,240 --> 00:07:04,000
+التلت شهور الماضية خلينا نحكي مش الأربع شهور تمام؟
+
+93
+00:07:04,000 --> 00:07:10,620
+ك average period يعني كمدة هيك تقريبية تمام؟والله
+
+94
+00:07:10,620 --> 00:07:14,980
+إذا كان ال homoglobin A1C عالي تمام معناها إنه كان
+
+95
+00:07:14,980 --> 00:07:18,460
+في سكر كتير عالي في الجسم عشان هيك هو ارتبط مع ال
+
+96
+00:07:18,460 --> 00:07:21,120
+homoglobin بشكل كتير كبير و أعطانا تركيز ل
+
+97
+00:07:21,120 --> 00:07:25,080
+homoglobin A1C عالي هذه هي الفكرة إذا homoglobin
+
+98
+00:07:25,080 --> 00:07:29,820
+A1C this test provide an overview for your blood
+
+99
+00:07:29,820 --> 00:07:33,880
+sugar glucose level over a three month time span
+
+100
+00:07:34,440 --> 00:07:38,120
+خلال تلت شهور بيحكم ليه على وضرة السكر في الجسم،
+
+101
+00:07:38,120 --> 00:07:41,820
+هل كان فيه تنظيم، هل كان السكر طبيعي خلال الفترات
+
+102
+00:07:41,820 --> 00:07:47,840
+هذه، هل كان فيه ارتفاع او لا fasting blood glucose
+
+103
+00:07:47,840 --> 00:07:52,320
+fasting blood glucose اللي هو عبارة كان زمان نسميه
+
+104
+00:07:52,320 --> 00:07:55,620
+أو لساتنا يعني لازال الاسم دارش fasting blood
+
+105
+00:07:55,620 --> 00:08:00,140
+sugarتمام؟ سواء fasting blood glucose أو fasting
+
+106
+00:08:00,140 --> 00:08:03,960
+blood sugar هو نفس المعنى هو الفحص اللي احنا بنقيز
+
+107
+00:08:03,960 --> 00:08:09,840
+فيه مستوى السكر في الدم لشخص صايم تمام؟ على الأقل
+
+108
+00:08:09,840 --> 00:08:14,520
+تمان ساعات احنا زمان او في بداية المساق يعني مش
+
+109
+00:08:14,520 --> 00:08:18,480
+زمان كتير انه حكينا انه كل فحص له شروط وحكيتلكم
+
+110
+00:08:18,480 --> 00:08:22,120
+انه احيانا بيتطلب الفحص ان الشخص يكون صايم تمان
+
+111
+00:08:22,120 --> 00:08:28,940
+ساعات مثلاو لحتى ما تتأثر النتيجة فإذا فحص ال
+
+112
+00:08:28,940 --> 00:08:31,900
+fasting blood sugar أو fasting blood glucose هو
+
+113
+00:08:31,900 --> 00:08:38,140
+أحد الفحوصات اللي بتطلب انه المريض ييجي صايم على
+
+114
+00:08:38,140 --> 00:08:41,760
+الأقل تمان ساعات مش أقل منهم أو أكتر منهم يعني
+
+115
+00:08:41,760 --> 00:08:46,810
+بكتيرRandom blood glucose هو الفحص السكري
+
+116
+00:08:46,810 --> 00:08:50,930
+العشوائي، يعني أنه بدون تحضيرات، بدون ما الشخص
+
+117
+00:08:50,930 --> 00:08:54,730
+ييجي صايم، مش شرط إيش ما أكل، يعني فجأة هيك، يعني
+
+118
+00:08:54,730 --> 00:08:57,370
+في نص اليوم أو في نص النهار إجاك شخص يحكيلك و الله
+
+119
+00:08:57,370 --> 00:09:00,290
+بدي .. بدي أشوف وضع السكر عندي، طب صايم؟ لأ، ما
+
+120
+00:09:00,290 --> 00:09:04,530
+أكلت؟ أه، طب خلاص، ماشي، هذه طالما أنه أجى بدون
+
+121
+00:09:04,530 --> 00:09:09,960
+تحضيرات، بنسميها random blood glucoseإذن this test
+
+122
+00:09:09,960 --> 00:09:13,460
+is performed via blood draw at the lab when you
+
+123
+00:09:13,460 --> 00:09:17,200
+are not fasting إذا شخص مش صايم سحبناله عين الدم
+
+124
+00:09:17,200 --> 00:09:21,740
+بنجيسله random blood glucose معناها هادية الفحص
+
+125
+00:09:21,740 --> 00:09:26,040
+يعني بنسميه random blood glucose testit gives an
+
+126
+00:09:26,040 --> 00:09:29,440
+indication in two hours your body handle the
+
+127
+00:09:29,440 --> 00:09:34,560
+increased blood sugar level triggered by eating طب
+
+128
+00:09:34,560 --> 00:09:38,840
+إيش فايدة هذا الفحص؟ بيعطيني indication دلالة كيف
+
+129
+00:09:38,840 --> 00:09:43,280
+الجسم بيتعامل مع السكر أو نسبة الغذاء أو نسبة
+
+130
+00:09:43,280 --> 00:09:47,240
+السكريات اللي أنا تناولتها أو ال carbohydrate اللي
+
+131
+00:09:47,240 --> 00:09:54,560
+تناولتها على الأقل قبل ساعتين هلتخلص منها أو نظمها
+
+132
+00:09:54,560 --> 00:10:00,560
+أو لا، تمام؟ هذه الفائدة الفحص هذه طبعا a random
+
+133
+00:10:00,560 --> 00:10:04,080
+blood glucose test result over 200 mg per
+
+134
+00:10:04,080 --> 00:10:07,440
+deciliter may indicate diabetes إذا كانت العيلة
+
+135
+00:10:07,440 --> 00:10:12,010
+العشوائيةنتيجة السكر فيها أعلى من 200 milligram
+
+136
+00:10:12,010 --> 00:10:16,310
+per deciliter معناها هذا الشخص بنشك أن هو عنده
+
+137
+00:10:16,310 --> 00:10:19,710
+diabetes ممكن يكون دلالة على ال diabetes فانا بروح
+
+138
+00:10:19,710 --> 00:10:24,070
+بتأكد بفحوصات تانية جابل أحكم أن هذا الشخص مريض
+
+139
+00:10:24,070 --> 00:10:29,110
+diabetes، تمام؟لازم انه على الأقل .. على الأقل
+
+140
+00:10:29,110 --> 00:10:36,010
+خلال ساعتين يكون ال .. السكر في الدم رجع للطبيعي
+
+141
+00:10:36,010 --> 00:10:41,110
+أو أقل من 140 milligram per deciliter، تمام؟ فإذا
+
+142
+00:10:41,110 --> 00:10:47,530
+كان يعني جاني شخص ..يعني بده اعمله random blood
+
+143
+00:10:47,530 --> 00:10:51,850
+glucose test عينة عشوائية بدون fasting فبسأله مثلا
+
+144
+00:10:51,850 --> 00:10:56,690
+اه امتى اخر مرة تناول طعام حكالي خلال ساعة ساعتين
+
+145
+00:10:56,690 --> 00:11:00,950
+مثلا ماشي okay تمام ب .. بجريله الفحص ولكن بكون
+
+146
+00:11:00,950 --> 00:11:04,740
+حاطة في الاعتبار ان هو والله ماكل ..جابل الساعتين
+
+147
+00:11:04,740 --> 00:11:09,880
+ما ي .. ما يخلصوا يعني انه .. انه أخر مرة أكل فيها
+
+148
+00:11:09,880 --> 00:11:14,580
+كان المدة ما بينها و ما بين أخد العينة أقل من
+
+149
+00:11:14,580 --> 00:11:19,640
+ساعتين إذا ساعتين تمام لازم النتيجة ما تكونش ..
+
+150
+00:11:19,640 --> 00:11:23,020
+يعني ما تكونش تتخطى ال 200 milligram per deciliter
+
+151
+00:11:23,020 --> 00:11:27,360
+لإن هاي معناها indicate diabetes glucose tolerance
+
+152
+00:11:27,360 --> 00:11:32,880
+testاللي هو الفحص اللي أنا بيجيني الشخص صايم أول
+
+153
+00:11:32,880 --> 00:11:37,760
+إشي بعمله fasting blood glucose لما بيجي صايم و
+
+154
+00:11:37,760 --> 00:11:42,900
+بعد هيك أنا بعطيه محلول سكري فيه خمسة و سبعين جرام
+
+155
+00:11:42,900 --> 00:11:49,790
+من ال glucoseو ببلش أقيسله السكر تمام بيصير هيك
+
+156
+00:11:49,790 --> 00:11:53,110
+random صار لما أنا بدى أعمله افحاصات سكر بعد ما
+
+157
+00:11:53,110 --> 00:11:57,330
+أكل خمسة و سبعين جرام صارت random تمام؟ فبعمله فحص
+
+158
+00:11:57,330 --> 00:12:03,630
+خلال مثلا بعد نص ساعة، بعد ساعة، بعد ساعتينتمام؟ و
+
+159
+00:12:03,630 --> 00:12:06,130
+في أحيانا لأ بيعملوا بس على ال fasting و بعد
+
+160
+00:12:06,130 --> 00:12:09,870
+ساعتين، في لأ بيعملوا على ال fasting لما بيجيني
+
+161
+00:12:09,870 --> 00:12:14,750
+صايم و في بعد نص ساعة من تناوله ال glucose drink و
+
+162
+00:12:14,750 --> 00:12:18,900
+بعد ساعة .. بعد ساعة و نص .. بعد ساعتينتمام؟ إذا
+
+163
+00:12:18,900 --> 00:12:22,580
+هو هذا عبارة عن multi-test لـ Glucose Tolerance
+
+164
+00:12:22,580 --> 00:12:28,580
+Test هو يعني أكتر من فحص في واحد أول إشي بعمله عال
+
+165
+00:12:28,580 --> 00:12:34,140
+fasting تمام؟ بعدين بعمله بعد ما ياكل 75 gram كذا
+
+166
+00:12:34,140 --> 00:12:37,620
+random يعني إما random واحد بعد ساعتين أو كل
+
+167
+00:12:37,620 --> 00:12:42,680
+مصارعة بعمله random testتمام؟ ويبرسم curve في
+
+168
+00:12:42,680 --> 00:12:47,040
+القيم اللي طلعت معايا لازم تكون حكينا النتيجة خلال
+
+169
+00:12:47,040 --> 00:12:51,660
+الساعتين هدول انه رجعت لأ الطبيعي او على الأقل
+
+170
+00:12:51,660 --> 00:12:57,790
+تكون اقل من 140 milligram per deciliterطبعا إذا
+
+171
+00:12:57,790 --> 00:13:03,650
+أنا الشخص أجاني عملتله random و طلع القيمة تبعته
+
+172
+00:13:03,650 --> 00:13:07,290
+أكتر من 200 فعلى طول باتجه لل blood .. لل fasting
+
+173
+00:13:07,290 --> 00:13:11,010
+blood glucose لجيته عالي على طول باتجه لل glucose
+
+174
+00:13:11,010 --> 00:13:15,170
+tolerance test لجيت أيضا هو abnormal فخلاص يعني
+
+175
+00:13:15,170 --> 00:13:19,030
+مابكون شبه متأكدة أن هو الشخص هذا يعاني من
+
+176
+00:13:19,030 --> 00:13:24,370
+diabetes مرض السكريطيب إيش مبدأ أعمل الفحص؟ the
+
+177
+00:13:24,370 --> 00:13:28,530
+principle of glucose test هلأ ال glucose مو .. وين
+
+178
+00:13:28,530 --> 00:13:31,330
+موجود هيكون؟ موجود في البلازمة، إذا العيلة تبع ..
+
+179
+00:13:31,330 --> 00:13:35,890
+العينة تبعتى بدها تكون إما بلازمة أو حتى سيرم، ما
+
+180
+00:13:35,890 --> 00:13:38,710
+هو السيرم هو نفسه البلازمة، بس اللهم إنه فقد ال
+
+181
+00:13:38,710 --> 00:13:43,390
+fibrinogenتمام، إذا العينة تبعتي هتكون إما plasma
+
+182
+00:13:43,390 --> 00:13:47,610
+أو serum، إذا ال blood اللي أنا بدي أجمعه من
+
+183
+00:13:47,610 --> 00:13:52,770
+المريض بدي أفصله على جهاز ال centrifuge علشان أحصل
+
+184
+00:13:52,770 --> 00:13:57,600
+إما على plasma أو serumهذا ال .. ال .. طبعا رح
+
+185
+00:13:57,600 --> 00:14:03,060
+أضيف كمية من ال plasma على ال .. ال reagent تبعي
+
+186
+00:14:03,060 --> 00:14:06,660
+طبعا احنا حكينا .. عرفنا المحليل قبل هيك و حكينا
+
+187
+00:14:06,660 --> 00:14:10,780
+إنه لازم يكون في عندي reagent هو اللي بيجري تغيير
+
+188
+00:14:10,780 --> 00:14:14,160
+ما، change معين على العينة، ممكن هذا التغيير يكون
+
+189
+00:14:14,160 --> 00:14:18,320
+measurable، يمكن قياسه، و هنا الفكرة اليوم ان شاء
+
+190
+00:14:18,320 --> 00:14:21,260
+الله رح نوظف إيش معنا كلمة reagent و إيش معنا كلمة
+
+191
+00:14:21,260 --> 00:14:27,810
+standardتمام؟ فال reagent تبعي بيكون موجود فيه
+
+192
+00:14:27,810 --> 00:14:31,070
+انزيم .. هاي طبعا .. هاي ال glucose جاي من وين؟
+
+193
+00:14:31,070 --> 00:14:34,750
+جاي من العينة تبعتي، من ال plasma، مع oxygen، مع
+
+194
+00:14:34,750 --> 00:14:40,010
+water، جاي أيضا من العينة تبعتي ال reagent glucose
+
+195
+00:14:40,010 --> 00:14:44,730
+.. موجود فيه اللي هو ال glucose oxidase enzyme هي
+
+196
+00:14:44,730 --> 00:14:50,370
+oxid ال glucose ويحوله من glucose لgluconate أو
+
+197
+00:14:50,370 --> 00:14:55,870
+لgluconic acidمع hydrogen peroxide، هذه الـ
+
+198
+00:14:55,870 --> 00:15:00,650
+hydrogen peroxide رح تتفاعل مع مكون أخر من .. أو
+
+199
+00:15:00,650 --> 00:15:04,150
+مكونات أخرى من الـ reagent اللي هي الأربع
+
+200
+00:15:04,150 --> 00:15:07,810
+أمينوفينازون مع فينول في وجود أنزايم اللي هو
+
+201
+00:15:07,810 --> 00:15:12,690
+peroxideaseهذا طبعا ال amino phenazone هو عبارة عن
+
+202
+00:15:12,690 --> 00:15:16,650
+oxygen receptor هياخد oxygen من ال peroxide و يتحد
+
+203
+00:15:16,650 --> 00:15:20,230
+مع الفينول و يعطيهم quinamine و هذا ال quinamine
+
+204
+00:15:20,230 --> 00:15:23,710
+اللي هو عبارة عن colored complex لونه pink لونه
+
+205
+00:15:23,710 --> 00:15:28,710
+زهري تمام؟فإنا .. إذا أنا بقيس التغير في اللون
+
+206
+00:15:28,710 --> 00:15:32,330
+العينة طبيعتي بتكون اللون ال straw color لما أضيف
+
+207
+00:15:32,330 --> 00:15:36,910
+عليها ال reagent و أعطيها مدة للتفاعل راح تحقي ..
+
+208
+00:15:36,910 --> 00:15:39,990
+تعطيني اللون ال pink هذا دليل على إنه ال reagent
+
+209
+00:15:39,990 --> 00:15:44,630
+عمل exchange على العينة تبعتي و هذا ال exchange
+
+210
+00:15:44,630 --> 00:15:48,330
+اللي هي تغير في اللون أنا بدي أقيصه باستخدام جهاز
+
+211
+00:15:48,330 --> 00:15:51,950
+معيناللي هو جهاز ال spectrophotometer اللي احنا
+
+212
+00:15:51,950 --> 00:15:57,770
+راح نتحدث عنه تركيبه أجزاءه وظيفته فكرة عمله كلها
+
+213
+00:15:57,770 --> 00:16:04,270
+راح نحكي عنها الإسبوع اللي جاي طيب فإذا الفكرة
+
+214
+00:16:04,270 --> 00:16:07,130
+خلينا نشوف إيش مكتوب لجلوكوز اللي موجود في
+
+215
+00:16:07,130 --> 00:16:11,630
+البلازمة راح يتأكسد بفعل ال enzyme لجلوكوز
+
+216
+00:16:11,630 --> 00:16:15,690
+اكسيدازي اللي موجود في ال reagent و هيحوله إلى
+
+217
+00:16:15,690 --> 00:16:20,790
+gluconic acid أو gluconateطبعا و مع تحرر hydrogen
+
+218
+00:16:20,790 --> 00:16:27,010
+peroxide hydrogen peroxide اللي هي هتتحول لماء
+
+219
+00:16:27,010 --> 00:16:32,150
+بفعل ال peroxidase و طبعا الإلكترونات أو ال oxygen
+
+220
+00:16:32,150 --> 00:16:35,560
+اللي راح يتحرر منهاراح يرتبط مع الأربع
+
+221
+00:16:35,560 --> 00:16:39,900
+أمينوفينازون لإنها oxygen receptor و هذا ال oxygen
+
+222
+00:16:39,900 --> 00:16:44,040
+receptor راح أيضا يتحد مع ال phenol ويعطيني اللي
+
+223
+00:16:44,040 --> 00:16:47,480
+هو ال colored chromogene المادة الملوقة المنتجة
+
+224
+00:16:47,480 --> 00:16:51,120
+لللون chromogene يعني منتجة لللون chromolone و
+
+225
+00:16:51,120 --> 00:16:55,520
+gene منتج producingفإذا color reproducing و
+
+226
+00:16:55,520 --> 00:16:58,440
+هيعطيني لون اللي هو اللون ال pink اللي أنا بقيسه
+
+227
+00:16:58,440 --> 00:17:01,540
+باستخدام جهاز المقياف الدوقي أو ال
+
+228
+00:17:01,540 --> 00:17:05,660
+spectrophotometer اللي هو على طول موجي 500
+
+229
+00:17:05,660 --> 00:17:10,320
+nanometer حكينا إنه هذا الجهاز راح نتحدث عنه
+
+230
+00:17:10,320 --> 00:17:15,800
+الإسبوع الجايلـ clinical significance إيش أهمية أو
+
+231
+00:17:15,800 --> 00:17:19,640
+الأهمية الطبية لفحص ال glucose test the detection
+
+232
+00:17:19,640 --> 00:17:24,080
+of glucose in body fluid is important in the
+
+233
+00:17:24,080 --> 00:17:29,320
+diagnosis of diabetes إذا هو مهم جدا في تشخيص مرض
+
+234
+00:17:29,320 --> 00:17:33,440
+السكر تمام اللي هو يعني ارتفاع السكر في الدم،
+
+235
+00:17:33,440 --> 00:17:37,380
+diabetes يعني ارتفاع السكر في الدم و أيضا للكشف عن
+
+236
+00:17:37,380 --> 00:17:41,500
+حالات الhypoglycemiaطيب خلينا بس نشوف إيش يعني
+
+237
+00:17:41,500 --> 00:17:46,160
+كلمة hypoglycemia hypo يعني low، glyce يعني
+
+238
+00:17:46,160 --> 00:17:49,820
+glucose وحكيتلكم emia يعني في الدم، وين ما تشوفي
+
+239
+00:17:49,820 --> 00:17:54,400
+كلمة emia يعني في الدم، إذا ال .. ال hypo low
+
+240
+00:17:54,400 --> 00:17:58,660
+blood glucose level in .. يعني أو low blood
+
+241
+00:17:58,660 --> 00:18:03,170
+glucose in bloodلو blood glucose level، هيك هيك
+
+242
+00:18:03,170 --> 00:18:09,110
+بتصير، تمام؟ هيبقوا لو glycemia glucose level in
+
+243
+00:18:09,110 --> 00:18:14,920
+blood، low level of glucose in bloodطبعا؟ و طيب لو
+
+244
+00:18:14,920 --> 00:18:20,200
+أنا بدي أعبر عن ال diabetes بهذا ال .. ب .. ب term
+
+245
+00:18:20,200 --> 00:18:23,740
+أو بمصطلح مشابه لهذا إيش بدي أحكي؟ ال diabetes
+
+246
+00:18:23,740 --> 00:18:28,320
+إحنا حكينا ارتفاع السكر في الدم فإذا بدها تصير
+
+247
+00:18:28,320 --> 00:18:34,080
+hyperglycemia إذا hyperglycemia اللي هي يعني
+
+248
+00:18:34,080 --> 00:18:37,980
+diabetes طبعا؟ أو ارتفاع مستوى السكر في الدم
+
+249
+00:18:39,300 --> 00:18:43,120
+hyperiglycemia hyperارتفاع إجليسيميا حكينا السكر
+
+250
+00:18:43,120 --> 00:18:47,280
+في الدم طب العين اللي أنا بستخدمها حكينا إما تكون
+
+251
+00:18:47,280 --> 00:18:54,760
+serum أو plasma ال plasma هي الخيار الأمثل لقياس
+
+252
+00:18:54,760 --> 00:19:00,070
+مستوى السكر في الدمو طبعا ال plasma glucose level،
+
+253
+00:19:00,070 --> 00:19:04,890
+نسبة السكر في ال plasma بتكون ثابتة خلال 6 ساعات
+
+254
+00:19:04,890 --> 00:19:08,210
+إذا ضلت العينة في ال room temperature، يعني أنا
+
+255
+00:19:08,210 --> 00:19:12,130
+حاطة ال plasma في ال room temperature، بيضل نسبة
+
+256
+00:19:12,130 --> 00:19:17,210
+السكر ثابتة لمدة 6 ساعات، ممكن تضل ثابتة ل 24 ساعة
+
+257
+00:19:17,210 --> 00:19:22,370
+إذا أنا حاطتها في التلاجةIt's important that the
+
+258
+00:19:22,370 --> 00:19:26,150
+plasma should be separated from the cell soon
+
+259
+00:19:26,150 --> 00:19:31,230
+after collection طبعا هذا احنا بنحكي عن ثابت مستوى
+
+260
+00:19:31,230 --> 00:19:35,090
+الجلوكوز في البلازمة طبعا لازم تكون البلازمة
+
+261
+00:19:35,090 --> 00:19:39,850
+منفصلة عن الخلايا لإنه احنا اذا مافصلناها عن
+
+262
+00:19:39,850 --> 00:19:44,570
+الخلايا فالخلايا راح تظل تسحب جلوكوز يعني هي خلايا
+
+263
+00:19:44,570 --> 00:19:49,090
+عايشة وعم تعمل glycolysis و بتنتج طاقةو بتشوف
+
+264
+00:19:49,090 --> 00:19:52,150
+شغلها فممكن تسحب ال glucose اللي موجود في ال
+
+265
+00:19:52,150 --> 00:19:55,870
+plasma فيبين عندي مثلا انه ال glucose ممكن يكون
+
+266
+00:19:55,870 --> 00:19:59,750
+طبيعي او اقل من الطبيعي و المشكلة تكون عندي سببها
+
+267
+00:19:59,750 --> 00:20:04,130
+ان انا مافصلتش ال plasma عن الخلايا اذا لازم افصل
+
+268
+00:20:04,130 --> 00:20:08,030
+ال plasma عن الخلايا على الأقل خلال نص ساعة من سحب
+
+269
+00:20:08,030 --> 00:20:13,530
+العينة و يفضل كمان اقل من نص ساعةلحتى الخلايا
+
+270
+00:20:13,530 --> 00:20:19,050
+حكينا ما تستهلك السكر اللي موجود في البلازمة، أنا
+
+271
+00:20:19,050 --> 00:20:23,690
+بدي أقيس مستوى السكر اللي في البلازمة عشان أاخد
+
+272
+00:20:23,690 --> 00:20:26,850
+indication دلالة على وضع المريض، هو عنده
+
+273
+00:20:26,850 --> 00:20:31,610
+hyperglycemia ولا عنده hypoglycemiaفما بدي عامل
+
+274
+00:20:31,610 --> 00:20:34,970
+آخر ييجي يأثر على النتيجة زي مثلا وجود الخلايا
+
+275
+00:20:34,970 --> 00:20:39,610
+هتستهلك السكر فهتأثرلي على النتيجة انا مش هقيز كل
+
+276
+00:20:39,610 --> 00:20:44,110
+مستوى السكر ساعتها لإن في جزء تماشي استهلاكه
+
+277
+00:20:44,110 --> 00:20:48,950
+بواسطة الخلايا فلأ يفضل فصل الملازمة عن الخلايا
+
+278
+00:20:48,950 --> 00:20:55,740
+على طول فورا بعد سحب العينة أفضلأو خلال نص ساعة
+
+279
+00:20:55,740 --> 00:20:58,900
+طيب التجربة تبعتي إيش بدني أعمل؟ بدي أجيب تلت
+
+280
+00:20:58,900 --> 00:21:04,560
+قنابيد و أعلمهم انبوبة بسميها blank انبوبة بسميها
+
+281
+00:21:04,560 --> 00:21:10,980
+standard و انبوبة بسميها ال sample أو ال testطيب
+
+282
+00:21:10,980 --> 00:21:14,020
+الانبوبة الأولى blank لا يوجد فيها غير ال reagent
+
+283
+00:21:14,020 --> 00:21:17,040
+هي فاضية مافيش فيها أي مادة تانية يتفاعل معها ال
+
+284
+00:21:17,040 --> 00:21:23,580
+reagent لا standard ولا sample طيب التقيوب اللي
+
+285
+00:21:23,580 --> 00:21:27,520
+فيها standard فيها ال reagent مع مين؟ مع ال
+
+286
+00:21:27,520 --> 00:21:32,540
+standardوالتيوب اللي فيها ال sample هيكون فيها ال
+
+287
+00:21:32,540 --> 00:21:36,940
+reagent مع ال sample، اذا التيوب ال standard هيكون
+
+288
+00:21:36,940 --> 00:21:40,160
+فيها reagent و standard وتيوب ال sample هيكون فيها
+
+289
+00:21:40,160 --> 00:21:45,270
+ال reagent و ال sample أو ال specimenطيب احنا
+
+290
+00:21:45,270 --> 00:21:49,730
+بتتذكروا المحاضرة اليدوية اللي كتبتها بإيدي و لما
+
+291
+00:21:49,730 --> 00:21:54,090
+رسمتلكم two tubes و حكيتلكم هي في عينة فيها أو
+
+292
+00:21:54,090 --> 00:21:57,150
+tube فيها عينة أو tube فيها standard و بضيف عليهم
+
+293
+00:21:57,150 --> 00:22:01,210
+reagent هيصير فيهم تغير في اللون و طبعا ال
+
+294
+00:22:01,210 --> 00:22:05,410
+standard بيكون معلوم التركيز فانا بجيب ال .. يعني
+
+295
+00:22:05,410 --> 00:22:09,050
+اذا كانت تغير باللون مثلافي عينة ال sample ضعف
+
+296
+00:22:09,050 --> 00:22:11,550
+التغير في ال standard معناها انه التركيز في ال
+
+297
+00:22:11,550 --> 00:22:15,730
+sample ضعف التغير التركيز في ال standard وطالما
+
+298
+00:22:15,730 --> 00:22:18,870
+واذا كان ال standard تركيزه مثلا مية معناها العينة
+
+299
+00:22:18,870 --> 00:22:22,770
+هيكون تركيزها 200 اذا انا بجيب تركيز ال sample
+
+300
+00:22:22,770 --> 00:22:27,070
+المجهول بدلالة المعلوم اللي هو ال standard اذا ان
+
+301
+00:22:27,070 --> 00:22:30,630
+هي ان هي عرفت ال sample ايش وظيفتها هالتيوب والله
+
+302
+00:22:30,630 --> 00:22:34,450
+انا بقيس فحص او بعمل فحص لمريض طبيعي يعني بدي ا ..
+
+303
+00:22:34,450 --> 00:22:38,460
+بدي يكون عندي تيوب فيها العينة تبعتهطيب إيش أهمية
+
+304
+00:22:38,460 --> 00:22:42,000
+ال standard؟ والله هذا محلول معلوم التركيز من
+
+305
+00:22:42,000 --> 00:22:45,640
+السكر، يحتوي على سكر فقط، سكر و ماء، ولكن معلوم
+
+306
+00:22:45,640 --> 00:22:53,660
+التركيز، تمام؟ و هذا المحلول، المعلوم التركيز أنا
+
+307
+00:22:53,660 --> 00:22:58,140
+بدلالته بجيب المجهول اللي موجود في ال sample طيب
+
+308
+00:22:58,140 --> 00:23:02,580
+إيش وظيفة ال blank؟مش وظيفة ال blank اللي هو
+
+309
+00:23:02,580 --> 00:23:05,980
+الفاضي هذا ال blank يعني فاضي مش فيه إشي غير agent
+
+310
+00:23:05,980 --> 00:23:10,780
+طيب ال وظيفة tube ل blank إحنا حكينا إنه النتيجة
+
+311
+00:23:10,780 --> 00:23:15,040
+أنا بقرأها .. بقرأ شدة التغير في اللون أو ال ..
+
+312
+00:23:15,040 --> 00:23:18,400
+بقرأ اللون تمام باستخدام جهاز ال spectrophotometer
+
+313
+00:23:19,140 --> 00:23:22,940
+طيب ال .. طب أنا ب .. بقيس التغير في اللون بال
+
+314
+00:23:22,940 --> 00:23:26,540
+standard و التغير في ال .. ال .. اللون في ال
+
+315
+00:23:26,540 --> 00:23:31,120
+sample و بقارنهم مع بعض طب إيش وظيفة ال blank؟ طيب
+
+316
+00:23:31,120 --> 00:23:36,180
+هو مش ال reagent نفسه إله لون؟ أه إله لون طيب أنا
+
+317
+00:23:36,180 --> 00:23:41,170
+لازم ألغي اللون اللي جاي من ال reagentتمام؟ علشان
+
+318
+00:23:41,170 --> 00:23:45,230
+بس لما أقيس على الجهاز أقيس اللون اللي جاي فقط من
+
+319
+00:23:45,230 --> 00:23:48,590
+تفاعل ال reagent مع ال standard أو من تفاعل ال
+
+320
+00:23:48,590 --> 00:23:53,910
+reagent مع ال sample في tube ال sample تمام؟ فإذا
+
+321
+00:23:53,910 --> 00:23:58,930
+ال .. ال blank بس علشان أصفر عليه و ألغي اللون
+
+322
+00:23:58,930 --> 00:24:04,930
+اللي جاي من ال reagent تمام؟إذا بحضر التلات قنابيب
+
+323
+00:24:04,930 --> 00:24:08,730
+بحط في كل انبوبة one ML من ال reagent بعد ما
+
+324
+00:24:08,730 --> 00:24:12,610
+أعلمهم بعد ما أعمللهم labeling و ال blank بسيبها
+
+325
+00:24:12,610 --> 00:24:16,450
+فاضية ال standard بضيف عليها عشرة microliter من ال
+
+326
+00:24:16,450 --> 00:24:19,530
+standard و عينة ال sample بضيف عليها عشرة
+
+327
+00:24:19,530 --> 00:24:24,490
+microliter من عينة المريض اللي هي إما تكون plasma
+
+328
+00:24:24,490 --> 00:24:29,490
+أو serum و بعد هيك بعمل mixing منيح للقنابيب و
+
+329
+00:24:29,490 --> 00:24:32,590
+بعمل incubation يعني بتركها تتفاعل فترة التفاعل
+
+330
+00:24:32,590 --> 00:24:37,040
+incubationحضانة فترة التفاعل لمدة عشر دقائق على
+
+331
+00:24:37,040 --> 00:24:40,420
+درجة حرارة الغرفة أو خمس دقائق في ال incubator على
+
+332
+00:24:40,420 --> 00:24:44,320
+درجة حرارة سبعة وتلاتين أو في ال water bath في ال
+
+333
+00:24:44,320 --> 00:24:49,840
+water bath تمام measure the absorbance of the
+
+334
+00:24:49,840 --> 00:24:54,260
+standard بقيس التغير في النون من خلال ال ..
+
+335
+00:24:54,260 --> 00:24:59,580
+باستخدام الجهاز و طبعا against the blank لازم أصفر
+
+336
+00:24:59,580 --> 00:25:02,720
+على ال blankبقيس التغير في اللون في ال standard و
+
+337
+00:25:02,720 --> 00:25:06,900
+في ال specimen tube على طول موجي 500 nanometer و
+
+338
+00:25:06,900 --> 00:25:09,800
+القراءة ممكن تظل ثابتة يعني اللي أنا بيبهد لما
+
+339
+00:25:09,800 --> 00:25:13,320
+أحضرها لو انشغلت عنها ممكن خلال ساعة أرجعلها و
+
+340
+00:25:13,320 --> 00:25:16,720
+أشتغللها أكثر من ساعة لأ بيكون صار تغير في النتيجة
+
+341
+00:25:16,720 --> 00:25:22,080
+يعني ممكنش النتيجة دقيقةطيب بعد هيك أنا جيبت
+
+342
+00:25:22,080 --> 00:25:25,100
+القراقة أو التغير اللى فى اللون اللى حدث فى ال
+
+343
+00:25:25,100 --> 00:25:28,140
+sample على التغير اللى فى اللون اللى حدث فى ال
+
+344
+00:25:28,140 --> 00:25:32,640
+standard ضرب تركيز ال standard بجيب هيك تركيز ال
+
+345
+00:25:32,640 --> 00:25:36,540
+glucose ووحدة القياس milligram per deciliter هذا
+
+346
+00:25:36,540 --> 00:25:42,560
+القانون بنسميه peers lambert law و قانون peers و
+
+347
+00:25:42,560 --> 00:25:46,840
+lambert ورح نشرحه ان شاء الله لما نحكى على جهاز ال
+
+348
+00:25:46,840 --> 00:25:49,840
+spectrophotometer نعرف من وين أجى هذا القانون
+
+349
+00:25:50,170 --> 00:25:55,050
+linearity إيش يعني ال linearity؟ يعني أقصى قيمة بي
+
+350
+00:25:55,050 --> 00:26:00,370
+.. بيقيصها ال .. ال .. الطريقة هذه أو ال .. يعني
+
+351
+00:26:00,370 --> 00:26:05,310
+الفحص طبيعي هنا في الطريقة هاي اللي ذكرناها طبعا،
+
+352
+00:26:05,310 --> 00:26:10,830
+طريقة ل .. لglucose oxidase و ال .. ال peroxidase
+
+353
+00:26:10,830 --> 00:26:17,110
+في هاي الطريقة و إنتاج الكلو .. الكوينونأعلى قيمة
+
+354
+00:26:17,110 --> 00:26:19,870
+بيقيسها بتقيسها هاي الطريقة 500 milligram per
+
+355
+00:26:19,870 --> 00:26:23,070
+deciliter يعني لو العينة تركيزها أعلى من 500
+
+356
+00:26:23,070 --> 00:26:26,370
+milligram per deciliter الطريقة هاي مش هتتمكن من
+
+357
+00:26:26,370 --> 00:26:30,230
+قياسها و لازم انا إيش أعمل؟ أعمل dilution لل
+
+358
+00:26:30,230 --> 00:26:35,570
+sample أخفف واحد لاتنين مثلا و بعد هيك لما بجيب
+
+359
+00:26:35,570 --> 00:26:38,990
+القراءة بدربها باتنين اللي هو ال dilution factor
+
+360
+00:26:38,990 --> 00:26:43,850
+علشان أحصل على التركيز الأصلي زي ما احنا اتعلمنا
+
+361
+00:26:43,850 --> 00:26:49,620
+في محاضرة ال dilutionطيب إيش يعني .. طيب من وين
+
+362
+00:26:49,620 --> 00:26:53,080
+جاية كلمة linearity؟ شوفوا معايا هو العلاقة ما بين
+
+363
+00:26:53,080 --> 00:26:55,920
+ال absorbance اللي هي القراءة اللي بيعطينا إياها
+
+364
+00:26:55,920 --> 00:27:00,540
+الجهاز و التركيز دايما علاقة تردية يعني أو خلينا
+
+365
+00:27:00,540 --> 00:27:03,340
+نحكي غالبا بتكون علاقة تردية في بعض الفحوصات
+
+366
+00:27:03,340 --> 00:27:07,180
+بتكونش علاقة تردية بس خلينا نحكي غالبا الغالب أنه
+
+367
+00:27:07,180 --> 00:27:11,020
+كل ما زاد التركيز هتزيد التفاعل فهيزيد شدة اللون
+
+368
+00:27:11,020 --> 00:27:14,940
+اللي ناتج عن التفاعل فهتزيد قراءة ال .. ال ..
+
+369
+00:27:14,940 --> 00:27:19,090
+الجهازفإذا القراءة اللي بيعطيني الجهة جهاز تتناسب
+
+370
+00:27:19,090 --> 00:27:24,130
+ترضيا مع التركيز في العينة طبعا طيب لو زادت .. لو
+
+371
+00:27:24,130 --> 00:27:27,210
+زادت التركيز في العينة كتير كتير كتير يعني تجاوز
+
+372
+00:27:27,210 --> 00:27:31,010
+مثلا ال 500 milligram per deciliter طب ما هو ال ..
+
+373
+00:27:31,010 --> 00:27:35,110
+يعني أنا ماعنديش كمية reaction كفاية تتفاعل مع كل
+
+374
+00:27:35,110 --> 00:27:37,950
+هال glucose اللي موجود في العينة عشان أول إشي
+
+375
+00:27:37,950 --> 00:27:43,190
+يعطيني شدة لون كافيةتانيا لو أعطاني شدة لون عالية
+
+376
+00:27:43,190 --> 00:27:46,830
+الجهاز نفسه ممكن مايتحمل يقرأها يعني مايستطيع ..
+
+377
+00:27:46,830 --> 00:27:51,370
+يعني مايستطيع يقرأها فبالتالي تنعدم العلاقة
+
+378
+00:27:51,370 --> 00:27:55,130
+الترضية ما بين ال .. ال .. ال absorbance أو القيمة
+
+379
+00:27:55,130 --> 00:28:00,620
+اللي بيعطينيها الجهاز و التركيزفبالتالي احنا بنحكي
+
+380
+00:28:00,620 --> 00:28:04,660
+والله هذا الفحص بتضل العلاقة ترضية ما بين القراءة
+
+381
+00:28:04,660 --> 00:28:08,560
+اللي على الجهاز و التركيز لحد قيمة خمسمية زادت
+
+382
+00:28:08,560 --> 00:28:12,280
+القي التركيز في العين عن خمسمية بيبدأ الجهاز يخربط
+
+383
+00:28:12,280 --> 00:28:17,220
+بيبدأ يعطيني قراءة .. قراءات او شدة لون مالهاش
+
+384
+00:28:17,220 --> 00:28:21,480
+علاقة بالتركيز مش ترضية مية لمية العلاقة فبتنعدم
+
+385
+00:28:21,480 --> 00:28:25,800
+ال linearity بتنعدم العلاقة الخطية ما بينهم تمام؟
+
+386
+00:28:25,800 --> 00:28:31,330
+فهي هي الفكرةال reference value القيمة الطبيعية ل
+
+387
+00:28:31,330 --> 00:28:35,890
+fasting blood glucose أو ال plasma glucose إذا
+
+388
+00:28:35,890 --> 00:28:39,610
+الشخص صايم طبعا من 70 ل110 ميلي جرام per
+
+389
+00:28:39,610 --> 00:28:44,030
+deciliter، هذا الطبيعي ال postprandial plasma
+
+390
+00:28:44,030 --> 00:28:47,890
+glucose ال two hour يعني بعد وجبات أو بين الوجبات
+
+391
+00:28:48,030 --> 00:28:53,410
+ولكن يعني بعد .. بعد ساعتين مثلا من الواجبة لازم
+
+392
+00:28:53,410 --> 00:28:56,950
+يكون اقل من 140 ميلي جرام per deciliter و هذه
+
+393
+00:28:56,950 --> 00:29:01,430
+المعلومة احنا حاكيناها انه سواء في ال random او في
+
+394
+00:29:01,430 --> 00:29:08,780
+ال glucose oral tolerance test سواء كانيعني الشخص
+
+395
+00:29:08,780 --> 00:29:14,280
+جيتله .. عملتله عينة random أو بال .. بال GOT اللي
+
+396
+00:29:14,280 --> 00:29:19,320
+هو ال glucose tolerance test لازم يعني الشخص خلال
+
+397
+00:29:19,320 --> 00:29:24,120
+ساعتين نسبة السكر تكون رجعت للطبيعي أو أتكون أقل
+
+398
+00:29:24,120 --> 00:29:28,950
+من 140 milligram per deciliterو في ال random في
+
+399
+00:29:28,950 --> 00:29:31,910
+العينة ال random برضه كمان حكينا لازم تكون اقل من
+
+400
+00:29:31,910 --> 00:29:34,950
+140 milligram per deciliter اذا كانت اكتر من 200
+
+401
+00:29:34,950 --> 00:29:38,750
+ببدأ شك ان الشخص هذا عنده diabetes فلازم اروح
+
+402
+00:29:38,750 --> 00:29:43,490
+اتأكد بفحوصات تانية serum glucose value are 1
+
+403
+00:29:43,490 --> 00:29:49,150
+point 15% lower than plasma glucose value يعني
+
+404
+00:29:49,150 --> 00:29:57,760
+دايما لو اجاني شخصيعني صايم و أنا عملتله فحص سكر
+
+405
+00:29:57,760 --> 00:30:02,020
+fasting blood sugar على عينة أخدت سحب منه عينة و
+
+406
+00:30:02,020 --> 00:30:05,820
+فضيتها واحدة في إيديتا تيوب و واحدة في بلان تيوب
+
+407
+00:30:05,820 --> 00:30:09,840
+الإيديتا هتعطيني بلازمة و البلان تيوب هتعطيني
+
+408
+00:30:09,840 --> 00:30:14,710
+سيرامتمام؟ لو انا خدت .. طبعا انا الشخص نفسه في
+
+409
+00:30:14,710 --> 00:30:18,750
+نفس اللحظة سحبت العينا و هو جاييني صايم بس اللهم
+
+410
+00:30:18,750 --> 00:30:22,450
+ان واحدة عمل .. خليتها تعطيني plasma يعني جزء
+
+411
+00:30:22,450 --> 00:30:26,030
+فصلته plasma من العينا و جزء فصلته يعطيني serum
+
+412
+00:30:26,840 --> 00:30:30,600
+تمام؟ و لو مشيت الفحص مع بعض و روحت اشتغلتلهم للـ
+
+413
+00:30:30,600 --> 00:30:35,520
+serum و لبلازمة لنفس الشخص عملتلهم glucose test
+
+414
+00:30:35,520 --> 00:30:39,980
+راح ألاحظ أنه ال serum فيه قيمة السكر أقل من
+
+415
+00:30:39,980 --> 00:30:49,890
+البلازمة بكم؟ بنسبة 1.15%ليش؟ لإنه ال serum احتاج
+
+416
+00:30:49,890 --> 00:30:55,230
+إنه لازم الخلايا أو لازم الدم يتجلط بالأول و عشان
+
+417
+00:30:55,230 --> 00:31:01,510
+الدم يتجلط طبعا هذه عمليات .. عمليات التجلط و إنه
+
+418
+00:31:01,510 --> 00:31:05,970
+يتكون فيبرين و إنه الدم يمسك و يتكون و يعمل ال
+
+419
+00:31:05,970 --> 00:31:11,250
+clot هذه عمليات تتطلب إنتاج طاقة من الخلاياتمام؟
+
+420
+00:31:11,250 --> 00:31:15,090
+فعشان تنتج الخلايا هي الطاقة و تقوي تجلط الدم
+
+421
+00:31:15,090 --> 00:31:19,170
+بتكون ساحبت لها شوية glucose من ال serum تمام؟
+
+422
+00:31:19,170 --> 00:31:22,670
+عشان هيك دايما قيمة السيرا ال glucose .. السكر في
+
+423
+00:31:22,670 --> 00:31:28,140
+ال serum أقل منه في البلازمةال plasma لأ عادي يعني
+
+424
+00:31:28,140 --> 00:31:31,980
+أنا سحبت العين أو على طول روحت فصلتها و الدم لسه
+
+425
+00:31:31,980 --> 00:31:36,680
+تسائل و أخدت ال plasma اللي جمعتها من .. من فوق
+
+426
+00:31:36,680 --> 00:31:40,580
+الخلايا و فصلتها و خلاص يعني ما .. ما .. ماخلتش
+
+427
+00:31:40,580 --> 00:31:44,000
+احتكاك يعني بين ال plasma و الخلايا فترة طويلة لكن
+
+428
+00:31:44,000 --> 00:31:47,020
+لأ السيرم عشان أنا أفصله لازم الأول الدم يتجلط
+
+429
+00:31:47,020 --> 00:31:51,380
+بعدين أنا أفصله فعشان الدم يتجلط هادي بيكون إيش
+
+430
+00:31:51,380 --> 00:31:56,830
+استهلاك طاقةهيك بنكون وصلنا لنهاية محاضرتنا لليوم
+
+431
+00:31:56,830 --> 00:32:00,210
+أتمنى أنها تكون بسيطة وواضحة لإلكم ويعطيكم ألف
+
+432
+00:32:00,210 --> 00:32:00,690
+عافية
+
diff --git a/PL9fwy3NUQKwY9jl8xw-bWkVZkWcGGyspd/QS6fztFTb_Y_raw.json b/PL9fwy3NUQKwY9jl8xw-bWkVZkWcGGyspd/QS6fztFTb_Y_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..37261d23b94bb050da0710b0ad4b68be7b0f6743
--- /dev/null
+++ b/PL9fwy3NUQKwY9jl8xw-bWkVZkWcGGyspd/QS6fztFTb_Y_raw.json
@@ -0,0 +1 @@
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"طيب إيش الفرق ما بين laboratory و medical laboratory؟ حكينا laboratory هي الكلمة العامة أو التعريف العام لمصطلح مختبر، طبعا انتوا يمكن ارتدتوا او شوفتوا مبنى لمختبرات كان مكون من رد التوابق، الفيزيا عندهم مختبرات", "tokens": [9566, 1829, 3555, 11933, 1829, 8592, 27188, 2288, 4587, 19446, 49374, 16523, 4032, 4625, 16523, 22807, 11331, 4117, 1829, 8315, 16523, 39896, 33251, 19528, 3660, 18863, 10943, 3660, 34051, 16712, 3615, 16572, 5172, 18863, 10943, 32767, 9381, 9566, 1211, 5016, 3714, 46456, 26890, 12399, 23032, 3555, 3615, 995, 16472, 2655, 14407, 7251, 43020, 1975, 43500, 3215, 2655, 14407, 1975, 2407, 13412, 38688, 2655, 14407, 3714, 3555, 1863, 7578, 32767, 46456, 26890, 9307, 25961, 3714, 30544, 9154, 12602, 3215, 16712, 14407, 3555, 4587, 12399, 27188, 1829, 11622, 25528, 43242, 16095, 3714, 46456, 26890, 9307], "avg_logprob": -0.11934840100559782, "compression_ratio": 1.7135922330097086, "no_speech_prob": 1.1920928955078125e-07, "words": [{"start": 1211.24, "end": 1211.74, 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new file mode 100644
index 0000000000000000000000000000000000000000..2dc8d71dcead0b8fa99bb15ecd537a53906cbbf7
--- /dev/null
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{"start": 131.24, "end": 131.46, "word": " أنها", "probability": 0.72216796875}, {"start": 131.46, "end": 131.94, "word": " تعملى", "probability": 0.728271484375}, {"start": 131.94, "end": 132.74, "word": " accurate", "probability": 0.765625}, {"start": 132.74, "end": 133.48, "word": " transfer", "probability": 0.935546875}, {"start": 133.48, "end": 133.7, "word": " of", "probability": 0.982421875}, {"start": 133.7, "end": 134.16, "word": " volume", "probability": 0.93994140625}, {"start": 134.16, "end": 134.82, "word": " يعني", "probability": 0.86376953125}, {"start": 134.82, "end": 135.08, "word": " أنها", "probability": 0.907958984375}, {"start": 135.08, "end": 135.5, "word": " تنقل", "probability": 0.9815673828125}, {"start": 135.5, "end": 136.02, "word": " الحجوم", "probability": 0.97216796875}, {"start": 136.02, "end": 136.48, "word": " بشكل", "probability": 0.9957682291666666}, {"start": 136.48, "end": 136.96, "word": " دقيق", "probability": 0.9938151041666666}, {"start": 136.96, "end": 137.4, "word": " جدا", "probability": 0.99658203125}, {"start": 137.4, "end": 138.5, "word": " بمثاق", "probability": 0.834375}, {"start": 138.5, "end": 138.98, "word": " الكيميا", "probability": 0.77880859375}, {"start": 138.98, "end": 139.18, "word": " يمكن", "probability": 0.93994140625}, {"start": 139.18, "end": 139.66, "word": " أخدتوا", "probability": 0.88818359375}, {"start": 139.66, "end": 140.06, "word": " معامل", "probability": 0.9456380208333334}, {"start": 140.06, "end": 140.42, "word": " كيميا", "probability": 0.9197591145833334}, {"start": 140.42, "end": 140.7, "word": " قبل", "probability": 0.8740234375}, {"start": 140.7, "end": 141.02, "word": " هك", "probability": 0.588134765625}], "temperature": 1.0}, {"id": 8, "seek": 15616, "start": 141.31, "end": 156.17, "text": "و كنتوا تستخدموا بايبتات اللي هي زي ال glass pipe اللي كان عبارة عن بايبت glass أداة زجاجية و في آخرها أو في نهايتها بيكون في عندي مستودع من المطاط انا بتحكم بدخول و خروج الهواء و دخول و خروج السائل", "tokens": [2407, 9122, 29399, 14407, 6055, 14851, 9778, 40448, 14407, 4724, 47302, 3555, 2655, 9307, 13672, 1829, 39896, 30767, 1829, 2423, 4276, 11240, 13672, 1829, 25961, 6225, 3555, 9640, 3660, 18871, 4724, 47302, 3555, 2655, 4276, 5551, 28259, 3660, 30767, 7435, 26108, 10632, 4032, 8978, 19753, 34740, 11296, 34051, 8978, 8717, 11296, 36081, 11296, 4724, 1829, 30544, 8978, 18871, 16254, 3714, 14851, 23328, 3615, 9154, 9673, 9566, 41193, 1975, 8315, 39894, 5016, 24793, 4724, 3215, 9778, 12610, 4032, 16490, 2288, 29245, 2423, 3224, 2407, 16606, 4032, 11778, 9778, 12610, 4032, 16490, 2288, 29245, 21136, 16373, 1211], "avg_logprob": -0.16463216161355376, "compression_ratio": 1.736040609137056, "no_speech_prob": 7.152557373046875e-07, "words": [{"start": 141.31, "end": 141.55, "word": "و", "probability": 0.9833984375}, {"start": 141.55, "end": 142.05, "word": " كنتوا", "probability": 0.6705729166666666}, {"start": 142.05, "end": 142.71, "word": " تستخدموا", "probability": 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151.49, "word": " مستودع", "probability": 0.9639892578125}, {"start": 151.49, "end": 151.87, "word": " من", "probability": 0.99609375}, {"start": 151.87, "end": 152.53, "word": " المطاط", "probability": 0.884765625}, {"start": 152.53, "end": 152.73, "word": " انا", "probability": 0.762939453125}, {"start": 152.73, "end": 153.21, "word": " بتحكم", "probability": 0.9567057291666666}, {"start": 153.21, "end": 153.83, "word": " بدخول", "probability": 0.8782958984375}, {"start": 153.83, "end": 153.95, "word": " و", "probability": 0.99755859375}, {"start": 153.95, "end": 154.35, "word": " خروج", "probability": 0.8489583333333334}, {"start": 154.35, "end": 154.83, "word": " الهواء", "probability": 0.92333984375}, {"start": 154.83, "end": 154.93, "word": " و", "probability": 0.91259765625}, {"start": 154.93, "end": 155.23, "word": " دخول", "probability": 0.8855794270833334}, {"start": 155.23, "end": 155.35, "word": " و", "probability": 0.9931640625}, {"start": 155.35, "end": 155.63, "word": " 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176.04, "end": 176.52, "word": " صغيرة", "probability": 0.9949544270833334}, {"start": 176.52, "end": 176.82, "word": " جدا", "probability": 0.99560546875}, {"start": 176.82, "end": 177.0, "word": " بال", "probability": 0.98291015625}, {"start": 177.0, "end": 177.74, "word": " microliter", "probability": 0.78076171875}, {"start": 177.74, "end": 178.04, "word": " يعني", "probability": 0.9072265625}, {"start": 178.04, "end": 178.42, "word": " أقل", "probability": 0.94140625}, {"start": 178.42, "end": 178.6, "word": " من", "probability": 0.99853515625}, {"start": 178.6, "end": 178.78, "word": " one", "probability": 0.953125}, {"start": 178.78, "end": 179.14, "word": " ml", "probability": 0.96923828125}], "temperature": 1.0}, {"id": 10, "seek": 20443, "start": 179.99, "end": 204.43, "text": "فبالتالي انا بدي أداة تنقل الحجم هذا الصغير او الحجم القليل بطريقة more accurate and more precise how باستخدام ال automatic pipet اذا ال glass pipet هي تستخدم بال chemical laboratory ولكن للأسف في الحجوم الصغيرة not accurate not precise انا محتاجة أداة تكون", "tokens": [5172, 3555, 6027, 2655, 6027, 1829, 1975, 8315, 4724, 16254, 5551, 28259, 3660, 6055, 1863, 4587, 1211, 21542, 7435, 2304, 23758, 31767, 17082, 13546, 1975, 2407, 21542, 7435, 2304, 25062, 20292, 1211, 4724, 9566, 16572, 28671, 544, 8559, 293, 544, 13600, 577, 4724, 995, 14851, 9778, 3215, 10943, 2423, 12509, 8489, 302, 1975, 15730, 2423, 4276, 8489, 302, 39896, 6055, 14851, 9778, 40448, 20666, 7313, 16523, 35525, 19452, 24976, 10721, 3794, 5172, 8978, 21542, 7435, 20498, 31767, 17082, 48923, 406, 8559, 406, 13600, 1975, 8315, 3714, 33753, 26108, 3660, 5551, 28259, 3660, 6055, 30544], "avg_logprob": -0.11167763393176229, "compression_ratio": 1.662280701754386, "no_speech_prob": 7.748603820800781e-07, "words": [{"start": 179.99, "end": 180.75, "word": "فبالتالي", "probability": 0.976806640625}, {"start": 180.75, "end": 181.29, "word": " انا", "probability": 0.72802734375}, {"start": 181.29, "end": 181.55, "word": 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"word": " هل", "probability": 0.934814453125}, {"start": 3593.29, "end": 3593.53, "word": " انها", "probability": 0.708251953125}, {"start": 3593.53, "end": 3594.07, "word": " محتاجة", "probability": 0.985595703125}, {"start": 3594.07, "end": 3594.33, "word": " انها", "probability": 0.744384765625}, {"start": 3594.33, "end": 3594.83, "word": " يتم", "probability": 0.745361328125}, {"start": 3594.83, "end": 3595.75, "word": " تصليحها", "probability": 0.97646484375}, {"start": 3595.75, "end": 3596.35, "word": " او", "probability": 0.87353515625}, {"start": 3596.35, "end": 3597.03, "word": " انه", "probability": 0.94873046875}, {"start": 3597.03, "end": 3597.79, "word": " لأ", "probability": 0.93701171875}, {"start": 3597.79, "end": 3598.79, "word": " مناسبة", "probability": 0.97314453125}, {"start": 3598.79, "end": 3599.05, "word": " و", "probability": 0.89697265625}, {"start": 3599.05, "end": 3600.01, "word": " تستخدم", "probability": 0.966552734375}, {"start": 3600.01, "end": 3600.69, 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3607.77, "word": " تكون", "probability": 0.96044921875}, {"start": 3607.77, "end": 3608.09, "word": " هيك", "probability": 0.826904296875}, {"start": 3608.09, "end": 3608.97, "word": " الاشياء", "probability": 0.900146484375}, {"start": 3608.97, "end": 3609.51, "word": " واضحة", "probability": 0.874267578125}, {"start": 3609.51, "end": 3609.93, "word": " حولت", "probability": 0.83935546875}, {"start": 3609.93, "end": 3610.03, "word": " ان", "probability": 0.6640625}, {"start": 3610.03, "end": 3610.23, "word": " انا", "probability": 0.94482421875}, {"start": 3610.23, "end": 3611.01, "word": " اورجيكم", "probability": 0.93076171875}, {"start": 3611.01, "end": 3611.71, "word": " صور", "probability": 0.978271484375}, {"start": 3611.71, "end": 3613.23, "word": " اورجيكم", "probability": 0.90224609375}, {"start": 3613.23, "end": 3613.91, "word": " فيديو", "probability": 0.8728841145833334}, {"start": 3613.91, "end": 3614.39, "word": " لكيف", "probability": 0.87548828125}, {"start": 3614.39, "end": 3614.59, "word": " ال", "probability": 0.97900390625}, {"start": 3614.59, "end": 3614.81, "word": " by", "probability": 0.275390625}, {"start": 3614.81, "end": 3615.21, "word": " بتاعي", "probability": 0.873046875}, {"start": 3615.21, "end": 3615.35, "word": " كنت", "probability": 0.75537109375}, {"start": 3615.35, "end": 3616.17, "word": " نستخدمها", "probability": 0.88994140625}, {"start": 3616.17, "end": 3616.73, "word": " و", "probability": 0.91162109375}, {"start": 3616.73, "end": 3617.37, "word": " تعليمات", "probability": 0.9136962890625}, {"start": 3617.37, "end": 3617.51, "word": " اللي", "probability": 0.90966796875}, {"start": 3617.51, "end": 3618.09, "word": " بنتابعها", "probability": 0.8634765625}, {"start": 3618.09, "end": 3618.49, "word": " أثناء", "probability": 0.9039306640625}, {"start": 3618.49, "end": 3618.61, "word": " ال", "probability": 0.97900390625}, {"start": 3618.61, "end": 3618.81, "word": " by", "probability": 0.79638671875}, {"start": 3618.81, "end": 3619.19, "word": " betting", "probability": 0.2349853515625}], "temperature": 1.0}, {"id": 163, "seek": 364043, "start": 3619.45, "end": 3640.43, "text": "لعسى انه يعني تكون الاشي مش مبهم لقلكم لإنه يعني احنا مقدرين انه بداية التخصص لازم تكون .. تكون يعني كل إشي سهل ومستثار لحتى تتمكنوا من الفهم المعلومة وإدراكها يعطيكم ألف عافية وشكرا لكم", "tokens": [1211, 3615, 3794, 7578, 16472, 3224, 37495, 22653, 6055, 30544, 2423, 33599, 1829, 37893, 3714, 3555, 16095, 5296, 4587, 23275, 2304, 5296, 28814, 1863, 3224, 37495, 22653, 1975, 5016, 8315, 3714, 28543, 2288, 9957, 16472, 3224, 4724, 28259, 10632, 16712, 9778, 9381, 9381, 5296, 31377, 2304, 6055, 30544, 4386, 6055, 30544, 37495, 22653, 28242, 11933, 8592, 1829, 8608, 3224, 1211, 4032, 2304, 14851, 12984, 9640, 5296, 33753, 7578, 6055, 39237, 19452, 14407, 9154, 27188, 16095, 9673, 30241, 20498, 3660, 4032, 28814, 3215, 23557, 4117, 11296, 37495, 9566, 1829, 24793, 5551, 46538, 6225, 31845, 10632, 4032, 8592, 4117, 23557, 5296, 24793], "avg_logprob": -0.13219368929910189, "compression_ratio": 1.7872340425531914, "no_speech_prob": 9.655952453613281e-06, "words": [{"start": 3619.45, "end": 3621.35, "word": "لعسى", "probability": 0.8140869140625}, {"start": 3621.35, "end": 3621.73, "word": " انه", "probability": 0.73291015625}, {"start": 3621.73, "end": 3621.97, "word": " يعني", "probability": 0.833251953125}, {"start": 3621.97, "end": 3622.25, "word": " تكون", "probability": 0.9873046875}, {"start": 3622.25, "end": 3622.79, "word": " الاشي", "probability": 0.9138997395833334}, {"start": 3622.79, "end": 3623.39, "word": " مش", "probability": 0.9912109375}, {"start": 3623.39, "end": 3623.87, "word": " مبهم", "probability": 0.9378255208333334}, {"start": 3623.87, "end": 3624.59, "word": " لقلكم", "probability": 0.8323974609375}, {"start": 3624.59, "end": 3625.49, "word": " لإنه", "probability": 0.9534912109375}, {"start": 3625.49, "end": 3625.93, "word": " يعني", "probability": 0.88671875}, {"start": 3625.93, "end": 3626.35, "word": " احنا", "probability": 0.9080403645833334}, {"start": 3626.35, "end": 3626.99, "word": " مقدرين", "probability": 0.9825439453125}, {"start": 3626.99, "end": 3627.31, "word": " انه", "probability": 0.748046875}, {"start": 3627.31, "end": 3627.89, "word": " بداية", "probability": 0.9703776041666666}, {"start": 3627.89, "end": 3629.03, "word": " التخصص", "probability": 0.9774169921875}, {"start": 3629.03, "end": 3629.35, "word": " لازم", "probability": 0.9959309895833334}, {"start": 3629.35, "end": 3629.65, "word": " تكون", "probability": 0.990234375}, {"start": 3629.65, "end": 3629.81, "word": " ..", "probability": 0.56396484375}, {"start": 3629.81, "end": 3630.15, "word": " تكون", "probability": 0.96484375}, {"start": 3630.15, "end": 3630.39, "word": " يعني", "probability": 0.978759765625}, {"start": 3630.39, "end": 3630.61, "word": " كل", "probability": 0.97900390625}, {"start": 3630.61, "end": 3631.31, "word": " إشي", "probability": 0.8275553385416666}, {"start": 3631.31, "end": 3632.05, "word": " سهل", "probability": 0.9986979166666666}, {"start": 3632.05, "end": 3633.11, "word": " ومستثار", "probability": 0.681298828125}, {"start": 3633.11, "end": 3633.99, "word": " لحتى", "probability": 0.931640625}, {"start": 3633.99, "end": 3634.71, "word": " تتمكنوا", "probability": 0.98095703125}, {"start": 3634.71, "end": 3634.97, "word": " من", "probability": 0.9970703125}, {"start": 3634.97, "end": 3635.65, "word": " الفهم", "probability": 0.679443359375}, {"start": 3635.65, "end": 3636.31, "word": " المعلومة", "probability": 0.986083984375}, {"start": 3636.31, "end": 3637.03, "word": " وإدراكها", "probability": 0.8951416015625}, {"start": 3637.03, "end": 3638.13, "word": " يعطيكم", "probability": 0.8792724609375}, {"start": 3638.13, "end": 3638.39, "word": " ألف", "probability": 0.77001953125}, {"start": 3638.39, "end": 3638.97, "word": " عافية", "probability": 0.9928385416666666}, {"start": 3638.97, "end": 3639.83, "word": " وشكرا", "probability": 0.9139404296875}, {"start": 3639.83, "end": 3640.43, "word": " لكم", "probability": 0.830078125}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 3642.23575, "duration_after_vad": 3615.1143749999974}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwY9jl8xw-bWkVZkWcGGyspd/Vo0zfcjPiBQ_postprocess.srt b/PL9fwy3NUQKwY9jl8xw-bWkVZkWcGGyspd/Vo0zfcjPiBQ_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..c6913293b2e74394ceed347cdcb2d7be5230b8d2
--- /dev/null
+++ b/PL9fwy3NUQKwY9jl8xw-bWkVZkWcGGyspd/Vo0zfcjPiBQ_postprocess.srt
@@ -0,0 +1,3344 @@
+1
+00:00:04,520 --> 00:00:07,580
+السلام عليكم ورحمة الله وبركاته طالبتي اليوم ان
+
+2
+00:00:07,580 --> 00:00:12,060
+شاء الله رح ناخد معملنا رقم اتنين بعنوان automatic
+
+3
+00:00:12,060 --> 00:00:15,600
+by-produce and calibration معمل رقم اتنين فيه مساق
+
+4
+00:00:15,600 --> 00:00:20,760
+مقدمة في التحليل الطبية طبعا هذا كان اول موضوع كان
+
+5
+00:00:20,760 --> 00:00:25,100
+المفروض ان احنا ناخده عملي و نشتغل بادانا ولكن
+
+6
+00:00:25,100 --> 00:00:30,440
+للأسف نظرا لزروف المحيطة فيناراح ناخد ان شاء الله
+
+7
+00:00:30,440 --> 00:00:33,660
+.. راح ناخد النظري تبعه و ان شاء الله بعودتنا
+
+8
+00:00:33,660 --> 00:00:38,460
+للمختبرات بناخد التطبيق العملي لإله فاليوم ان شاء
+
+9
+00:00:38,460 --> 00:00:41,060
+الله موضوعنا عن ال automatic by bit use and
+
+10
+00:00:41,060 --> 00:00:44,280
+calibration خلينا نشوف إيش يعني automatic by bit
+
+11
+00:00:44,280 --> 00:00:47,480
+هلأ احنا المحاضرة الماضية خلينا بس نحكي هالنقطة
+
+12
+00:00:47,790 --> 00:00:53,150
+المحاضرة الماضية كانت بتحكي عن ال .. ال .. ال
+
+13
+00:00:53,150 --> 00:00:58,270
+volumes و الحجوم و المحاليل و كيف أنا بتعامل مع
+
+14
+00:00:58,270 --> 00:01:01,110
+المحاليل هاي و إيش أنواع المحاليل اللي تستخدم في
+
+15
+00:01:01,110 --> 00:01:05,930
+ال medical laboratories و .. و كيف أنا أخسف هاي
+
+16
+00:01:05,930 --> 00:01:10,690
+المحاليل، تمام؟طيب لما انا .. انا بدي أجي أنقل
+
+17
+00:01:10,690 --> 00:01:13,950
+المحلول من إلى يعني مثلا انا عندي عينة بدي
+
+18
+00:01:13,950 --> 00:01:17,970
+أضيفيلها reagent علشان أعمل فحص معين أو بدي أاخد
+
+19
+00:01:17,970 --> 00:01:22,130
+.. بدي أنقل حجوم علشان أعمل dilution زي ما أخدنا
+
+20
+00:01:22,130 --> 00:01:25,800
+ال .. مسائل ال dilution المحاضرة الماضيةكيف أنا
+
+21
+00:01:25,800 --> 00:01:29,140
+بدي أنقلها؟ هنا بال medical laboratories
+
+22
+00:01:29,140 --> 00:01:32,660
+بالمختبرات الطبية احنا بنستخدم اشي اسمه automatic
+
+23
+00:01:32,660 --> 00:01:37,100
+pipet اللي هو الأداة اللي موجودة بهذه الصورة اسمها
+
+24
+00:01:37,100 --> 00:01:40,740
+automatic pipet خلينا نشوف اش يعني automatic pipet
+
+25
+00:01:41,150 --> 00:01:45,250
+هلأ automatic pipet هي عبارة عن أداة تستخدم في ال
+
+26
+00:01:45,250 --> 00:01:48,110
+biological و ال biochemical و ال microbiological
+
+27
+00:01:48,110 --> 00:01:52,310
+labs سواء كانت لل teaching purposes أو لل research
+
+28
+00:01:52,310 --> 00:01:56,490
+purposes، تمام؟ يعني تستخدم في مختبرات الأحياء و
+
+29
+00:01:56,490 --> 00:01:59,750
+مختبرات ال biochemistry و ال microbiology في كل
+
+30
+00:01:59,750 --> 00:02:04,700
+أقسام المختبرات الطبيةوتستخدم إما للتدريس أو حتى
+
+31
+00:02:04,700 --> 00:02:09,640
+للعمل لممارسة المهنة أو لأغراض البحث العلمى طبعا
+
+32
+00:02:09,640 --> 00:02:13,700
+من شأنهاي ال bybit أنها تعملى accurate transfer of
+
+33
+00:02:13,700 --> 00:02:18,500
+volume يعني أنها تنقل الحجوم بشكل دقيق جدا بمثاق
+
+34
+00:02:18,500 --> 00:02:22,050
+الكيميا يمكن أخدتوا معامل كيميا قبل هكو كنتوا
+
+35
+00:02:22,050 --> 00:02:25,250
+تستخدموا بايبتات اللي هي زي ال glass pipe اللي كان
+
+36
+00:02:25,250 --> 00:02:29,490
+عبارة عن بايبت glass أداة زجاجية و في آخرها أو في
+
+37
+00:02:29,490 --> 00:02:33,210
+نهايتها بيكون في عندي مستودع من المطاط انا بتحكم
+
+38
+00:02:33,210 --> 00:02:37,160
+بدخول و خروج الهواء و دخول و خروج السائلالى ال by
+
+39
+00:02:37,160 --> 00:02:41,280
+bit طبعا هاي ال glass by bit بتستخدم بال chemical
+
+40
+00:02:41,280 --> 00:02:45,380
+laboratory ولكن للأسف هي not accurate و not
+
+41
+00:02:45,380 --> 00:02:49,820
+precise مش accurate و مش precise متى؟ طبعا لما بدي
+
+42
+00:02:49,820 --> 00:02:53,640
+أنقل حجوم أقل من one ml و احنا هنا بالمختبرات
+
+43
+00:02:53,640 --> 00:02:57,000
+الطبية بنتعامل دائما مع حجوم صغيرة جدا بال
+
+44
+00:02:57,000 --> 00:03:01,970
+microliter يعني أقل من one mlفبالتالي انا بدي أداة
+
+45
+00:03:01,970 --> 00:03:07,230
+تنقل الحجم هذا الصغير او الحجم القليل بطريقة more
+
+46
+00:03:07,230 --> 00:03:11,170
+accurate and more precise how باستخدام ال
+
+47
+00:03:11,170 --> 00:03:15,470
+automatic pipet اذا ال glass pipet هي تستخدم بال
+
+48
+00:03:15,470 --> 00:03:19,670
+chemical laboratory ولكن للأسف في الحجوم الصغيرة
+
+49
+00:03:19,670 --> 00:03:25,060
+not accurate not precise انا محتاجة أداة تكونأكثر
+
+50
+00:03:25,060 --> 00:03:28,560
+دقة more accurate more precise لهيك أنا بستخدم ال
+
+51
+00:03:28,560 --> 00:03:32,200
+automatic by bit لإن كل شغلي بيكون على ال volumes
+
+52
+00:03:32,200 --> 00:03:37,480
+اللي أقل من one ml طبعا طيب كل by bit من هدول ال
+
+53
+00:03:37,480 --> 00:03:42,440
+automatic by bit مصممة إن هي تنقل يعني مدى أو
+
+54
+00:03:42,440 --> 00:03:47,050
+range من الحجوم من إلىيعني في بايبت متكون مصممة
+
+55
+00:03:47,050 --> 00:03:50,930
+تنقل من واحد microliter لعشرة microliter في من ..
+
+56
+00:03:50,930 --> 00:03:54,770
+مصممة بتكون من عشرة microliter لمية microliter في
+
+57
+00:03:54,770 --> 00:03:58,610
+من مية microliter ل one ml تمام ف .. و في من one
+
+58
+00:03:58,610 --> 00:04:04,050
+ml لخمسة ml فإذا ال .. في بايبتات أنواع و حجوم و
+
+59
+00:04:04,050 --> 00:04:08,390
+كل بايبت بتكون إلها range يعني مدى من إلى
+
+60
+00:04:08,390 --> 00:04:15,140
+بتستخدموا في ال .. ال .. ال ..نقل الحجوم هذه و
+
+61
+00:04:15,140 --> 00:04:19,600
+طبعا احنا المفروض احنا مانتخطى هذا ال .. ال .. ال
+
+62
+00:04:19,600 --> 00:04:23,820
+range تبعها يعني لازم انا مثلا اذا بدي انقل خمسين
+
+63
+00:04:23,820 --> 00:04:28,320
+microliter يفضل ان انا اخد بايبت ال range تبعها
+
+64
+00:04:28,320 --> 00:04:31,480
+بحيث انه الخمسين تكون واقعة فيه ال range في داخل
+
+65
+00:04:31,480 --> 00:04:34,980
+هذا ال range يعني مثلا باخد بايبتبتنقل من عشرة
+
+66
+00:04:34,980 --> 00:04:38,420
+microliter لمية microliter ال volume رقم خمسين
+
+67
+00:04:38,420 --> 00:04:42,580
+هيكون already موجود يعني في المدى و ال by بتحتقدر
+
+68
+00:04:42,580 --> 00:04:46,880
+انها تنقلي هذا ال volume فبالتالي انا هكون ضمنت ال
+
+69
+00:04:46,880 --> 00:04:50,250
+accuracy و ال precision لناقل ال volumesطيب إذا
+
+70
+00:04:50,250 --> 00:04:54,850
+إحنا نوّهنا إنه أنا في عندي أنواع وحجوم ويعني قدرة
+
+71
+00:04:54,850 --> 00:04:58,930
+استيعابية لال buy bits يعني مش كلها واحد مش كلها
+
+72
+00:04:58,930 --> 00:05:03,930
+مصممة إنها تنقلني نفس الحجم طيب فإذا في عندي حاجة
+
+73
+00:05:03,930 --> 00:05:08,010
+اسمها buy bit man model طبعا هي سبع أنواع من ال
+
+74
+00:05:08,010 --> 00:05:12,440
+buy bits مصممة إنها تنقل حجوم بطريقة مختلفةطبعا
+
+75
+00:05:12,440 --> 00:05:17,560
+هذه ال .. ال man model يعني لو هم السبعة بيكونوا
+
+76
+00:05:17,560 --> 00:05:20,980
+بينقلولي من point one microliter يعني من اقل من
+
+77
+00:05:20,980 --> 00:05:24,680
+واحد microliter لحد خمس تلاف microliter يعني لحد
+
+78
+00:05:24,680 --> 00:05:30,100
+خمس ML يعني في تنوع من ال by بتات هذه و هلأ بنشوف
+
+79
+00:05:30,100 --> 00:05:35,090
+بالجدوة اللي في ال slide ال ..التالية هيوضحلي إيش
+
+80
+00:05:35,090 --> 00:05:38,970
+يعني by bit مع الموديل ولكن هنا بيحكيلنا إنه the
+
+81
+00:05:38,970 --> 00:05:42,710
+most often used يعني الأكثر استخداما هي ال by
+
+82
+00:05:42,710 --> 00:05:49,150
+bitات اللي تسمى ال B20 و ال B200 و ال B1000 هدول
+
+83
+00:05:49,150 --> 00:05:54,150
+ال models هم الأكثر استخداما اللي بينقلولي حجم من
+
+84
+00:05:54,150 --> 00:05:58,450
+اتنين لعشرينو من خمسين ل متين و من مية ل ألف
+
+85
+00:05:58,450 --> 00:06:02,170
+microliter تمام هاي المدى تبعهم respectively مرتب
+
+86
+00:06:02,170 --> 00:06:07,410
+بالترتيب ال B20 بتنقل من اتنين ل عشرين microliter
+
+87
+00:06:07,410 --> 00:06:12,990
+تمام و ال بايبت B20 بتنقل volume من خمسين ل متين
+
+88
+00:06:12,990 --> 00:06:16,730
+microliter و البايبت الف بتاخد من مية ل الف
+
+89
+00:06:16,730 --> 00:06:20,970
+microliter يعني الرقم اللي جنب ال B تمام بي يعني
+
+90
+00:06:20,970 --> 00:06:25,240
+بايبت و الرقم هذا يعني أقصى قيمة بتقدر تاخدهاطبعا
+
+91
+00:06:25,240 --> 00:06:28,800
+ومش .. مش أدنى قيمة لأ فى أدنى .. الأدنى قيمة غير
+
+92
+00:06:28,800 --> 00:06:32,080
+مذكورة هلأ نيجى نشوف ال buy bet man model هى فى
+
+93
+00:06:32,080 --> 00:06:36,960
+عندى واحد اتنين أربع ستة سبع أنواع من ال buy bet
+
+94
+00:06:36,960 --> 00:06:43,870
+طبعا ومسمى بي تو يعنى بتنقل من zero لتنين طبعاو ال
+
+95
+00:06:43,870 --> 00:06:51,010
+B20 من 0 ل 10 بتاخد ال B20 بتاخد من 0 ل 20 ال B100
+
+96
+00:06:51,010 --> 00:06:55,250
+بتاخد من 0 ل 100 و 200 من 0 ل 200 و هكذا من 0 ل
+
+97
+00:06:55,250 --> 00:07:00,570
+1000 يعني من 1 أمال و هنا من 0 ل 5000 لحد one ..
+
+98
+00:07:00,570 --> 00:07:04,310
+لحد خمس أمال هذا ال range بصي بالهذا اللي بيكون
+
+99
+00:07:04,310 --> 00:07:07,690
+مسجل على ال by بت نفسها يعني بيكون .. بيكون ..
+
+100
+00:07:07,690 --> 00:07:12,960
+بيعطين ال range انه من .. من كذا لكذاأنا لما بدى
+
+101
+00:07:12,960 --> 00:07:16,040
+أستخدم ال by bet هذه طبعا انا مابستخدم ال by bet
+
+102
+00:07:16,040 --> 00:07:18,700
+عشان أنقله zero volume يعني انا مابديش أنقل volume
+
+103
+00:07:18,700 --> 00:07:21,840
+ليش أستخدم ال by bet؟ zero volume يعني no volume
+
+104
+00:07:21,840 --> 00:07:26,160
+طبعا فإذا في عندي حاجة اسمها recommended range
+
+105
+00:07:26,160 --> 00:07:29,600
+يعني ال range الموصفة يعني أنا بستخدم ال by bet
+
+106
+00:07:29,600 --> 00:07:36,260
+لحتى انه انا يعني في range مسموحلي فيه ايش هو اللي
+
+107
+00:07:36,260 --> 00:07:42,040
+مسموحلي فيه؟ من point واحد لاتنين طبعاو ال .. و
+
+108
+00:07:42,040 --> 00:07:45,880
+هنا من نص لعشرة من اتنين لعشرين من عشرة لمية و
+
+109
+00:07:45,880 --> 00:07:50,400
+هكذا من خمسين لمتان طيب هذه ال by bet اللي من
+
+110
+00:07:50,400 --> 00:07:53,780
+خمسين لمتان ممكن تسحب لأقل من خمسين اه ممكن تسحب
+
+111
+00:07:53,780 --> 00:07:56,560
+لأقل من خمسين ال range تبعها اصلا من zero لمتان
+
+112
+00:07:56,900 --> 00:08:00,800
+ولكن هو اذا سحبت اقل من خمسين فهي بتكون inaccurate
+
+113
+00:08:00,800 --> 00:08:05,200
+and imprecise يعني مش accurate ومش precise فانا
+
+114
+00:08:05,200 --> 00:08:08,300
+يفضل ان انا استخ .. اخت .. يعني اتبع ال
+
+115
+00:08:08,300 --> 00:08:13,460
+recommended range علشان أستخ .. أختار ال .. ال ..
+
+116
+00:08:13,460 --> 00:08:18,170
+ضيبة المناسبة لإلي تمام؟طيب يعني مثلا لو أنا بدي
+
+117
+00:08:18,170 --> 00:08:23,030
+أنقل خمسين microliter تمام؟ خمسين microliter مين
+
+118
+00:08:23,030 --> 00:08:29,190
+أفضل أختار ال .. ال by بت مثلا رقم ال B100 ولا ال
+
+119
+00:08:29,190 --> 00:08:33,410
+B200؟ يفضل أن أنا أختار ال B100 لإنه الخمسين
+
+120
+00:08:33,410 --> 00:08:36,570
+القيمة خمسين تقع في نص ال range يعني أنا ب .. بكون
+
+121
+00:08:36,570 --> 00:08:41,710
+ضمنة إنه مافيش أخطاءتمام ال by بت على ال border
+
+122
+00:08:41,710 --> 00:08:45,850
+على الحدود تمام ممكن يكون فيها نسبة خطأ لكن في
+
+123
+00:08:45,850 --> 00:08:49,950
+منتصف ال range بتكون دقيقة فإذا انا بفضل ان انا
+
+124
+00:08:49,950 --> 00:08:54,810
+لما بدي اختار اللي بدي انقل volume بختار ال by بت
+
+125
+00:08:54,810 --> 00:08:57,870
+اللي هذا ال volume يتوسط ال range تبعها او موجود
+
+126
+00:08:57,870 --> 00:09:02,120
+في ال range تبعهاطبعا طيب هلأ لو بدي أنقل مثلا ميت
+
+127
+00:09:02,120 --> 00:09:08,300
+microliter مين أفضل أختار ال B100 طبعا ولا ال B200
+
+128
+00:09:08,300 --> 00:09:15,620
+ولا ال B1000 يفضل أن أنا أختار ال B200 طبعا و ممكن
+
+129
+00:09:15,620 --> 00:09:18,560
+أنا أختار ال B100 بتكون دقيقة يعني ال higher range
+
+130
+00:09:18,560 --> 00:09:23,040
+تبعتها بتكون أدق دايما طبعا ال higher range بتكون
+
+131
+00:09:23,040 --> 00:09:26,680
+أدق من ال lower range لل bybit طبعا يعني هذه ال
+
+132
+00:09:26,680 --> 00:09:32,120
+bybit ال B100يعني لو بدأ أنقل 100 microliter من ال
+
+133
+00:09:32,120 --> 00:09:37,620
+volume ممكن أستخدم ال B200 ال .. ال .. ال B100
+
+134
+00:09:37,620 --> 00:09:43,440
+ممكن أستخدم ال B1000 تمام؟ و .. لكن مثلا هذه ال by
+
+135
+00:09:43,440 --> 00:09:47,500
+bit اللي هو ال range تبعها من عشرة لمية تمام؟ عند
+
+136
+00:09:47,500 --> 00:09:50,800
+المية بتكون أضاق من من .. من .. من أني أسحب فيها
+
+137
+00:09:50,800 --> 00:09:54,640
+عشرة microliter يعني دايما ال higher limit تبعتها
+
+138
+00:09:54,640 --> 00:09:57,990
+بتكون أضاق من ال lower limit لل by bit نفسهاطبعا
+
+139
+00:09:57,990 --> 00:10:02,750
+إذا نرجع نعيد الصياغة تاني لو أنا في عندى .. بدي
+
+140
+00:10:02,750 --> 00:10:05,690
+أنقل 100 microliter مين أفضل أستخدم؟ الأفضل أن أنا
+
+141
+00:10:05,690 --> 00:10:09,990
+أستخدم ال B200 لإنها المية تتوسط ال range ممكن
+
+142
+00:10:09,990 --> 00:10:13,730
+أستخدم ال B100 لإنه حكينا ال higher limit بتكون
+
+143
+00:10:13,730 --> 00:10:16,990
+أدق دايما من ال lower limit لل by bit ولكن أنا
+
+144
+00:10:16,990 --> 00:10:20,110
+مابستخدم .. يعني ممكن أستخدمها بس مابكنش دقيقة و
+
+145
+00:10:20,110 --> 00:10:24,170
+.. و .. كتير لإنه دايما حكينا إنه ال lower limit
+
+146
+00:10:24,170 --> 00:10:27,370
+لل by bit بتكون أقل دقة من ال higher limitهذا
+
+147
+00:10:27,370 --> 00:10:31,690
+بالنسبة ل .. ال .. ال .. ال by bit man model حكينا
+
+148
+00:10:31,690 --> 00:10:36,770
+مين هم اكتر شيوعا و اكتر استخداما بي twenty و ال
+
+149
+00:10:36,770 --> 00:10:41,910
+by one hundred و ال by two hundred تمام؟ اذا ال by
+
+150
+00:10:41,910 --> 00:10:46,570
+عشرين ال by مية و ال by متين هم اكتر ال .. ال by
+
+151
+00:10:46,570 --> 00:10:50,570
+بتات شيوعا و استخداماتمام طيب هلا بنا نحكي عن
+
+152
+00:10:50,570 --> 00:10:56,150
+أنواع .. يعني sorry مكونات البيبت و أجزاقها طيب
+
+153
+00:10:56,150 --> 00:11:00,430
+البيبت زي ما انتوا شايفين بهذا الشكل مكونة من حاجة
+
+154
+00:11:00,430 --> 00:11:05,030
+اسمها ال .. البش .. البشبطن أو البلنجر نحكي عنه
+
+155
+00:11:05,030 --> 00:11:09,770
+إما بشبطن أو بلنجر إيش يعني بشبطن أو بلنجر؟زي ما
+
+156
+00:11:09,770 --> 00:11:13,250
+انتوا شايفين هذا ال push button هو عبارة عن كبسة
+
+157
+00:11:13,250 --> 00:11:18,830
+push انا ممكن انا اضغط عليها و تطلع و تنزل من ال
+
+158
+00:11:18,830 --> 00:11:24,030
+by button تمام؟ و هذا الرد تبعها طبعا هذا الرد ال
+
+159
+00:11:24,030 --> 00:11:29,980
+.. ال .. ال .. ال ..القضيب هذا ممكن انه يلتف دائري
+
+160
+00:11:29,980 --> 00:11:35,500
+علشان يتحكم في ال volume تمام؟ يتحكم في ال volume
+
+161
+00:11:35,500 --> 00:11:39,620
+اللي موجودة على ال digital screen هنا تمام؟ هلأ في
+
+162
+00:11:39,620 --> 00:11:45,240
+هنا adapter موجود هذا يعني علشان انا اقلل من حركة
+
+163
+00:11:45,240 --> 00:11:47,800
+ال vibe يعني ممكن انا اسبط هذا ال adapter على
+
+164
+00:11:47,800 --> 00:11:51,880
+أصبعي .. على أصبعي السبابة وامسكها بشكل انه يكون
+
+165
+00:11:51,880 --> 00:11:58,230
+انا متحكمة فيها ومسكاها بشكل صحيحهذا بسميه tip
+
+166
+00:11:58,230 --> 00:12:04,410
+eject .. tip ejector أو tip eject button تمام؟ هو
+
+167
+00:12:04,410 --> 00:12:09,730
+عبارة عن كبسة بتتخلص من ال tip يعني بتتحرك .. مجرد
+
+168
+00:12:09,730 --> 00:12:14,360
+ما أضغط عليها ال tip اللي هنا بتفكطبعا هذا عبارة
+
+169
+00:12:14,360 --> 00:12:19,020
+عن ال tip ejector و هنا tip holder و زي ما انتوا
+
+170
+00:12:19,020 --> 00:12:23,560
+شايفين هنا في مكان لأ ال handle من هنا بمسكها و
+
+171
+00:12:23,560 --> 00:12:29,220
+هنا الشاشة اللي بتكون موجود عليها القراءة بتكون
+
+172
+00:12:29,220 --> 00:12:35,070
+موجود عليها القراءة تبعتيطيب، هلأ بالنسبة لل .. ال
+
+173
+00:12:35,070 --> 00:12:39,110
+.. بايبت هي بتيجي تمام لحالها هيك و فيه انا عندي
+
+174
+00:12:39,110 --> 00:12:43,370
+حاجة اسمها tips او بايبت tip طبعا هذه ال .. بايبت
+
+175
+00:12:43,370 --> 00:12:48,400
+tip هي عبارة عن قطع بلاستيكيةهذه زي ما انتوا
+
+176
+00:12:48,400 --> 00:12:54,520
+شايفين في الصورة هنا هي عبارة عن قطع بلاستيكية لت
+
+177
+00:12:54,520 --> 00:12:59,980
+.. ت .. يعني بتتركب على ال .. تستخدم لبيبتات و هي
+
+178
+00:12:59,980 --> 00:13:02,960
+تتراوح في الأحجام تبعتها يعني البيبتات الصغيرة
+
+179
+00:13:02,960 --> 00:13:06,900
+بيكون إلها تبات، بيكون إلها تب صغيرة، البيبتات
+
+180
+00:13:06,900 --> 00:13:11,630
+الأكبر بيكون إلها تب أكبر و هكذاهي قطع بلاستيكية و
+
+181
+00:13:11,630 --> 00:13:16,170
+هذه القطع البلاستيكية بستخدمها انا one use ايش
+
+182
+00:13:16,170 --> 00:13:20,090
+يعني one use يعني بستستخدم لمرة واحدة فقط لنقل حجم
+
+183
+00:13:20,090 --> 00:13:24,210
+لمرة واحدة فقط و بعد هيك انا بتلفها بتخلص منها
+
+184
+00:13:24,210 --> 00:13:29,490
+طبعا فإذا مابرجع استخدمها مرة تانية فهذه هي التبات
+
+185
+00:13:29,490 --> 00:13:35,870
+او القطع اللي بتتركب على ال by bit وبيكون الحجم او
+
+186
+00:13:35,870 --> 00:13:39,550
+ال volume داخلها يعني انا السائل اللي انا بنقله
+
+187
+00:13:39,700 --> 00:13:44,480
+بيكون موجود داخل هاي التب وبيتم ال .. ال .. نقله
+
+188
+00:13:44,480 --> 00:13:48,760
+من مكان إلى آخر حسب أنا وين بدي أو كيف بدي أشتغل
+
+189
+00:13:48,760 --> 00:13:55,780
+طيب، إذا هاي مكونات البايبت و أجزاقها و يعرفنا إنه
+
+190
+00:13:55,780 --> 00:14:00,250
+التب هي قطعة خارجيةتتركب لل by bet مش ثابتة في ال
+
+191
+00:14:00,250 --> 00:14:05,490
+by bet و انه هذه القطعة ايضا ممكن اني استخدمها
+
+192
+00:14:05,490 --> 00:14:09,210
+لمرة واحدة فقط يعني بتلفها بعد ما استخدمها خلاص
+
+193
+00:14:09,210 --> 00:14:13,430
+برميها و اذا هذه يطلق عليها مصطلح disposable
+
+194
+00:14:13,430 --> 00:14:19,040
+disposable يعني استخدام لمرة واحدة فقطوحكينا ايضا
+
+195
+00:14:19,040 --> 00:14:24,320
+انه هذه ال .. ال .. التب يعني بتتنقل .. بيكون
+
+196
+00:14:24,320 --> 00:14:27,980
+حجمها متناسب مع ال bybit ال by بتاعة اللي بتنقل
+
+197
+00:14:27,980 --> 00:14:31,780
+حجوم صغيرة بيكون لها تب صغيرة و ال by بتاعة اللي
+
+198
+00:14:31,780 --> 00:14:37,440
+بتنقل حجم أكبر بيكون لها تب حجمه أكبر نوعا ماطيب
+
+199
+00:14:37,440 --> 00:14:40,980
+فيه هنا نصائح لاستخدام ال micro bibit اللي هي
+
+200
+00:14:40,980 --> 00:14:45,120
+عبارة عن إيش هذه النصائح؟ أول حاجة never exceed
+
+201
+00:14:45,120 --> 00:14:49,140
+the upper or lower limit of this bibit يعني أنه
+
+202
+00:14:49,140 --> 00:14:55,710
+يعني مثلا هاي ال bibit هايبتنقللي مثلا من عشرة
+
+203
+00:14:55,710 --> 00:15:00,350
+لمية، يعني ممنوع أنا أسحب أقل من عشرة و ممنوع أسحب
+
+204
+00:15:00,350 --> 00:15:04,590
+فيها أكتر من مية، يعني ما أسحب أقل من عشرة ولا
+
+205
+00:15:04,590 --> 00:15:09,350
+أكتر من مية، يعني ما أتخطأ ال range هادا، إما بأقل
+
+206
+00:15:09,350 --> 00:15:13,840
+منه أو بأكتر منههذا معناه الجملة هاى الجملة هاى
+
+207
+00:15:13,840 --> 00:15:18,300
+معناها انه never exceed ما اتخطى ال upper او ال
+
+208
+00:15:18,300 --> 00:15:22,320
+lower limit لل range لل by bit ال by bit يعني
+
+209
+00:15:22,320 --> 00:15:28,180
+مصممة بأنها تنقلي داخل range معين فانا باحترم هذا
+
+210
+00:15:28,180 --> 00:15:32,880
+ال range بلتزم فيه ما بستخدمها ال by bit الاقل منه
+
+211
+00:15:32,880 --> 00:15:37,900
+ولا الاكثر منه على نقل حجوم علشان ما اكون بنقل
+
+212
+00:15:37,900 --> 00:15:42,840
+حجوم بطريقة مش precise و مش accurateتمام طيب so
+
+213
+00:15:42,840 --> 00:15:46,840
+the desired volume by turning centrally located
+
+214
+00:15:46,840 --> 00:15:49,700
+ring clockwise to increase volume or
+
+215
+00:15:49,700 --> 00:15:53,120
+counterclockwise to decrease احنا حكينا انه هذا
+
+216
+00:15:53,120 --> 00:15:59,290
+القضيب او ال .. ال .. ال ..الرد تمام هذا بيتحرك
+
+217
+00:15:59,290 --> 00:16:02,530
+بشكل دائري و من خلاله انا بتحكم بالحجم اللى موجود
+
+218
+00:16:02,530 --> 00:16:06,290
+على الشاشة هنا تمام يعني من خلاله انا بحدد الحجم
+
+219
+00:16:06,290 --> 00:16:11,450
+اللى بديها بحكيلك هنا انه تحركيه ال ال ال
+
+220
+00:16:11,450 --> 00:16:18,530
+clockwise تمام و عشان يزيد الحجم و بنحركه counter
+
+221
+00:16:18,530 --> 00:16:25,520
+clockwise to decrease ال volumeطبعا انا هنا بالشكل
+
+222
+00:16:25,520 --> 00:16:29,140
+او بالتجربة العملية لما بنشرح احنا كيف نستخدم ال
+
+223
+00:16:29,140 --> 00:16:32,720
+bybit في المعامل انا بخل ال bybit .. بخل الطالبة
+
+224
+00:16:32,720 --> 00:16:37,120
+تمسك ال bybit تمام و بحيث انه ال digital screen
+
+225
+00:16:37,120 --> 00:16:41,300
+تكون مواجهةلإلها تمام يعني تكون عينها على ال
+
+226
+00:16:41,300 --> 00:16:45,800
+digital screen وبالتالي بما أنه بيكون عينها على ال
+
+227
+00:16:45,800 --> 00:16:49,660
+digital screen إذا حركت هذا الرد بشكل دائري
+
+228
+00:16:49,660 --> 00:16:54,260
+باتجاهها يعني لعندها تمام هيك بيزيد ال volume أما
+
+229
+00:16:54,260 --> 00:16:59,180
+إذا حركته باتجاه المعاكس يعني بعيد عنها فهو بيقل
+
+230
+00:16:59,180 --> 00:17:02,340
+ال volume تمام هذا بده ممارسة ان شاء الله بنشرحه
+
+231
+00:17:02,340 --> 00:17:09,020
+بالطريقة أو بالتجربة العمليةتمام؟ هذا بالنسبة ل ..
+
+232
+00:17:09,020 --> 00:17:14,320
+ال .. ال .. ال by bet و الطرق أو اللي هي الخطوات
+
+233
+00:17:14,320 --> 00:17:17,740
+أو اللي .. ال .. التعليمات اللي لازم أنا ألتزم
+
+234
+00:17:17,740 --> 00:17:22,920
+فيها أثناء السحب أو نقل الحجوم باستخدام ال by bet
+
+235
+00:17:23,850 --> 00:17:29,330
+في شغل هنا انه ال .. ال by bit هنا طبعا هي بتكون
+
+236
+00:17:29,330 --> 00:17:33,210
+مصممة انها تنقلي او تقفز قفزات في ال volume يعني
+
+237
+00:17:33,210 --> 00:17:38,970
+مثلا هاي هنا بحكيلي انه هي صح يعني من خمسين ل متين
+
+238
+00:17:38,970 --> 00:17:45,210
+بتسحب لكن انه مثلا انا لما بدي ..أحرك بصير بحرك
+
+239
+00:17:45,210 --> 00:17:48,450
+بيزيد ال volume كل شوية point اتنين point اتنين
+
+240
+00:17:48,450 --> 00:17:51,890
+لحد ما اصل لل volume اللي بديها لذا هذه هي ال ..
+
+241
+00:17:51,890 --> 00:17:55,450
+ال .. مدى التحريك او اللي هي القافزات في ال
+
+242
+00:17:55,450 --> 00:18:01,330
+volumes طبعا طيب بليت ا tip place a tip on the
+
+243
+00:18:01,330 --> 00:18:05,230
+discharge end of the pipet طبعا انا ب .. بركب ال
+
+244
+00:18:05,230 --> 00:18:10,370
+tip في المكان المخصص لإلها و بعد هيك طبعا ب ..
+
+245
+00:18:12,600 --> 00:18:16,600
+باستخدام البلانجر ب .. باستخدمه علشان اسحب ال
+
+246
+00:18:16,600 --> 00:18:20,520
+volumes هذا البلانجر اللي احنا شايفينه تمام مش ما
+
+247
+00:18:20,520 --> 00:18:24,180
+.. ايضا هو يعني فايد .. فايديته مش بس انه متصل
+
+248
+00:18:24,180 --> 00:18:28,360
+بالرد high بال .. و بتحكم بال volume لأ هذا
+
+249
+00:18:28,360 --> 00:18:31,600
+البلانجر احنا كتركم push button يعني انا ممكن اكدس
+
+250
+00:18:31,600 --> 00:18:35,480
+عليا بيطلع و بينزلطبعا انا هذا لما بدي أكبس عليه و
+
+251
+00:18:35,480 --> 00:18:39,860
+يطلع و ينزل بينزل عند ضغطتين، الضغطة الأولى لما
+
+252
+00:18:39,860 --> 00:18:43,840
+أضغط الضغطة الأولى بيقللي ال exact volume اللي
+
+253
+00:18:43,840 --> 00:18:50,720
+موجود ع الشاشة تمام؟ لما أضغط ضغطتين تمام؟بينقلي
+
+254
+00:18:50,720 --> 00:18:54,280
+extra volume ممكن يكون حجم مضاعف او extra volume
+
+255
+00:18:54,280 --> 00:18:59,560
+من ال volume اللي مصمم او موجود على الشاشة تمام؟
+
+256
+00:18:59,560 --> 00:19:04,400
+اذا هذا ال bush هذا البلنجر عبارة عن كبسة فيها two
+
+257
+00:19:04,400 --> 00:19:07,680
+stops يعني انا لما اضغط اول ضغطة بلاحظ انه خلاص
+
+258
+00:19:07,680 --> 00:19:12,780
+وجه اصبعي لدرجة معينة وانا بضغط لو ضغطت بقوة اكبر
+
+259
+00:19:12,780 --> 00:19:16,910
+ممكن اضغط الضغطة التانية يعني بنزل كمان مرةفالضغطة
+
+260
+00:19:16,910 --> 00:19:21,410
+الأولى لما أنا بكون ضغطاها بتكون ال by بتها تسحبلي
+
+261
+00:19:21,410 --> 00:19:25,750
+volume نفس ال volume اللى موجودة ع الشاشة لكن لو
+
+262
+00:19:25,750 --> 00:19:29,690
+أنا بدى أسحب two volumes او يعني بصري بدى أسحب و
+
+263
+00:19:29,690 --> 00:19:33,110
+أنا ضغطة ضغطتين هيسحبلي ال volume اللى موجودة ع
+
+264
+00:19:33,110 --> 00:19:37,610
+الشاشة وكمان extra volume تانى يعني volume بزيادة
+
+265
+00:19:37,610 --> 00:19:40,710
+طب انا ليش امتى بستخدم الضغطة الأولى و امتى بستخدم
+
+266
+00:19:40,710 --> 00:19:45,100
+الضغطة التانية او الضغطتين هلأ بنشوف كدههي هنا
+
+267
+00:19:45,100 --> 00:19:47,920
+بيحكيلي انه البلانجر او اللي هو ال push button
+
+268
+00:19:47,920 --> 00:19:53,140
+تمام و ال stop at two different positions يعني هذا
+
+269
+00:19:53,140 --> 00:19:57,740
+البلانجر بيتوقف عند .. عند مكانين و انا لما اجي
+
+270
+00:19:57,740 --> 00:20:00,820
+اضغط عليه بلاحظ انه في عندي two resistance في
+
+271
+00:20:00,820 --> 00:20:05,020
+مقاومتين للضغطة تبعتي ال .. ال stop الأول او
+
+272
+00:20:05,020 --> 00:20:10,160
+الضغطة الأولى تمام و لو انا زودت ال .. الضغط تبعي
+
+273
+00:20:10,160 --> 00:20:16,630
+بنزل كمان ضغطة تانية فبالتاليال .. ال .. ال first
+
+274
+00:20:16,630 --> 00:20:21,870
+stopping تمام عند ال initial resistant تمام عند
+
+275
+00:20:21,870 --> 00:20:27,610
+أول يعني stop عند أول إعاقة لضغطة تبعتي بيجف ال ..
+
+276
+00:20:27,610 --> 00:20:30,850
+ال plunger عندها بتكون هذه عبارة عن الضغطة الأولى
+
+277
+00:20:31,230 --> 00:20:37,590
+طبعا و ال .. و هذه معناها انه انا هسحب ايش ال
+
+278
+00:20:37,590 --> 00:20:40,810
+desired volume يعني انا هاخد ال volume اللي موجود
+
+279
+00:20:40,810 --> 00:20:47,720
+ع الشاشة exactly باخده طبعا ال second stoppingلما
+
+280
+00:20:47,720 --> 00:20:53,380
+يكون .. لما انا بدي اضغط على الضغط التاني يعني انا
+
+281
+00:20:53,380 --> 00:20:58,900
+بدي اظل نازلة في البلانجر ضغطين فساعتها انا بكون
+
+282
+00:20:58,900 --> 00:21:02,540
+تجاوزت ال initial resistance عند .. تجاوزت الإعاقة
+
+283
+00:21:02,540 --> 00:21:06,540
+الأولى و انزلت كمان مرة في ال .. في البلانجرطبعا
+
+284
+00:21:06,540 --> 00:21:12,600
+فهدى ال .. الاشي معناها انه ال by bit راح تسحبلي
+
+285
+00:21:12,600 --> 00:21:17,940
+volume extra طبعا هتسحبلي ال .. ال volume extra
+
+286
+00:21:17,940 --> 00:21:22,720
+ساعتها انا لما بلقل الحجم بفضيه بضغط ضغطة واحدة
+
+287
+00:21:22,950 --> 00:21:26,350
+هتنقل الحجم و هيضل في عندي extra volume موجود في
+
+288
+00:21:26,350 --> 00:21:31,130
+ال tip ممكن أتخلص منه تمام؟ اذا في عندي ال .. ال
+
+289
+00:21:31,130 --> 00:21:34,370
+.. بلانجر ال .. او ال .. ال push button بيجف عن
+
+290
+00:21:34,370 --> 00:21:38,430
+ضغطين، الدغطة الأولى بتن .. لما انا أكون ضغطاها و
+
+291
+00:21:38,430 --> 00:21:42,270
+أسحب حجم من السائل معناها أنا سحبت نفس الحجم اللي
+
+292
+00:21:42,270 --> 00:21:45,600
+موجودة على الشاشةلكن اذا انا كنت ضغطة ضغطتين و
+
+293
+00:21:45,600 --> 00:21:50,120
+سحبت حجم معناها انا سحبت الحجم مع extra تمام لما
+
+294
+00:21:50,120 --> 00:21:54,040
+اجي افضية بدي انتبه ان انا اضغط ضغطة واحدة فقط
+
+295
+00:21:54,040 --> 00:21:57,520
+افضي ال volume اللي من ضغطة واحدة لان ضغطة واحدة
+
+296
+00:21:57,520 --> 00:22:00,380
+يعني ايش ال desired volume يعني ال volume اللي
+
+297
+00:22:00,380 --> 00:22:04,580
+بديها و بيضل في عندي extra طبعا طب ليش الغلبة هذه
+
+298
+00:22:04,580 --> 00:22:07,880
+ليش ضغطة واحدة و ضغطتين و ليش انا اخد extra volume
+
+299
+00:22:08,030 --> 00:22:11,550
+علشان في عندي نوعين من ال by betting نوع اسمه
+
+300
+00:22:11,550 --> 00:22:16,450
+forward by betting و reverse by betting ايش يعني
+
+301
+00:22:16,450 --> 00:22:19,770
+forward by betting يعني انه انا افوت في المحلول
+
+302
+00:22:19,770 --> 00:22:23,870
+تمام و انا ضغطة ضغطة واحدة اخد الحجم اللي بدياه هو
+
+303
+00:22:23,870 --> 00:22:27,390
+نفس الحجم اللي موجود على الشاشة exactly بالضبط
+
+304
+00:22:27,390 --> 00:22:32,530
+بدون زيادة و بعد هيك اجي افضيه افضيه في المحلول في
+
+305
+00:22:32,530 --> 00:22:37,350
+الوعاء اللي انا بدي اشتغل فيه و بفضيه و بضل ضغطة
+
+306
+00:22:37,540 --> 00:22:40,020
+ممكن اضغط اكتر من مرة او ممكن اضغط اكتر من مرة او
+
+307
+00:22:40,020 --> 00:22:44,880
+ممكن اضغط اكتر من مرة او ممكن اضغط اكتر من مرة او
+
+308
+00:22:44,880 --> 00:22:48,820
+ممكن اضغط اكتر من مرة او ممكن اضغط اكتر من مرة او
+
+309
+00:22:48,820 --> 00:22:48,960
+ممكن اضغط اكتر من مرة او ممكن اضغط اكتر من مرة او
+
+310
+00:22:48,960 --> 00:22:49,180
+ممكن اضغط اكتر من مرة او ممكن اضغط اكتر من مرة او
+
+311
+00:22:49,180 --> 00:22:49,860
+ممكن اضغط اكتر من مرة او ممكن اضغط اكتر من مرة او
+
+312
+00:22:49,860 --> 00:22:52,000
+ممكن اضغط اكتر من مرة او ممكن اضغط اكتر من مرة او
+
+313
+00:22:52,000 --> 00:22:53,780
+ممكن اضغط اكتر من مرة اإذا إيش ال forward
+
+314
+00:22:53,780 --> 00:22:57,380
+bybiting؟ معناها .. معناها إن أنا أضغط ضغطة على ال
+
+315
+00:22:57,380 --> 00:23:01,680
+bybit بعدين أجي أس .. أ .. أنقل الحجم أاخد الحجم
+
+316
+00:23:01,680 --> 00:23:04,200
+اللي بدياه هو ال exact volume اللي موجود على
+
+317
+00:23:04,200 --> 00:23:08,120
+الشاشة و لما أجي أفضيه في الوعاء ممكن أضغط ضغط أو
+
+318
+00:23:08,120 --> 00:23:11,040
+ضغطتين عشان أتأكد إن أنا فضيته كله و إن أنا
+
+319
+00:23:11,040 --> 00:23:14,700
+استخدمت ال volume بالضبط هو نفس اللي موجود على
+
+320
+00:23:14,700 --> 00:23:17,720
+الشاشة تمام؟ مايكونش ضاي .. إيش يضاي العالق في ال
+
+321
+00:23:17,720 --> 00:23:23,070
+tip تمام؟ إذا ..هذا معناه ال forward وهذه الطريقة
+
+322
+00:23:23,070 --> 00:23:27,410
+تستخدم عشان انا لو بدى انقل حجوم زى مين زى ال
+
+323
+00:23:27,410 --> 00:23:31,450
+aqueous solution المحليل اللى أصلها مية ال buffers
+
+324
+00:23:31,450 --> 00:23:35,310
+ال acid ال bases كل الأشياء المحليل هذه اللى أصلها
+
+325
+00:23:35,310 --> 00:23:39,750
+مية بستخدم معاها طريقة ال forward by bettingأما
+
+326
+00:23:39,750 --> 00:23:43,390
+طريقة ال reverse by betting فهي عبارة عن انه انا
+
+327
+00:23:43,390 --> 00:23:47,990
+باخد larger volume of solution بصحب larger volume
+
+328
+00:23:47,990 --> 00:23:51,990
+of solution ايش يعني؟ يعني بصحب extra يعني معناها
+
+329
+00:23:51,990 --> 00:23:55,430
+انا لما باجي باخد ال by bet او بنقل في ال by bet
+
+330
+00:23:55,430 --> 00:24:00,870
+بكون ضغطة، ضغطتين تمام؟ باخد الحجم اللي بديها مع
+
+331
+00:24:00,870 --> 00:24:05,750
+extra تمام؟و لما اجى افضى فى المحلول بتغضى تواحدة
+
+332
+00:24:05,750 --> 00:24:11,030
+بحيث ان انا افضى فقط المحلول الحجم اللى بديه و يضل
+
+333
+00:24:11,030 --> 00:24:14,330
+ال extra اللى موجود فى التب اتخلص منه طب انا ليش
+
+334
+00:24:14,330 --> 00:24:20,430
+يعني بلجأ لهذه الطريقة بحكيلي لإنه فى سوائل عبارة
+
+335
+00:24:20,430 --> 00:24:25,250
+عن لازجة viscous طبعا هاد اش يعني viscous لازجة
+
+336
+00:24:25,250 --> 00:24:29,130
+يعني بصعوبة هتطلع جوا التب المحليل بصعوبة هتطلع
+
+337
+00:24:29,130 --> 00:24:35,520
+جوا التب طبعا طيبفبالتالي لما اجي انا اكون ماخدة
+
+338
+00:24:35,520 --> 00:24:39,200
+ال volume وزيادة شوية هكون ضامنة ان انا اخدت ال
+
+339
+00:24:39,200 --> 00:24:42,060
+volume ..يعني ضامنة ان انا هنزل ال volume على
+
+340
+00:24:42,060 --> 00:24:47,480
+الأقل اللي بديها، تمام؟ لكن مثلا لو انا ده استخدمت
+
+341
+00:24:47,480 --> 00:24:52,430
+مع الهادي المحلي للviscousاستخدمت نظامة ضغطة لوحدة
+
+342
+00:24:52,430 --> 00:24:57,050
+ما هي بتطلع جوا التب بطء يعني انا ممكن افوت و اطلع
+
+343
+00:24:57,050 --> 00:25:01,590
+و اخد ال باقي الحجم اللي بدياه بس لسه السائل من
+
+344
+00:25:01,590 --> 00:25:08,200
+كتر لزوجته ماعباش جوا التب بشكلكامل فبالتالي ممكن
+
+345
+00:25:08,200 --> 00:25:12,800
+اخد volume اقل من اللي انا بديها فهنا ممكن يكون في
+
+346
+00:25:12,800 --> 00:25:17,120
+خطأ عشان هيك بحكيلي انه استخدمي مع السوائل اللازجة
+
+347
+00:25:17,120 --> 00:25:21,200
+انه طريقة انك انت تاخدي بزيادة و لما تفض تفضي
+
+348
+00:25:21,200 --> 00:25:27,230
+الحجم اللي بدكياتمام هذا بالنسبة لمين ل .. ال ..
+
+349
+00:25:27,230 --> 00:25:31,150
+ال .. السواقل اللازجة بستخدم معاها ال reverse
+
+350
+00:25:31,150 --> 00:25:34,330
+technique يعني نظام الضغطين عشان أخد extra volume
+
+351
+00:25:34,330 --> 00:25:37,590
+أيضا بيحكيلي فيه محاليل volatile إيش يعني
+
+352
+00:25:37,590 --> 00:25:42,030
+volatile؟ يعني متطايرة يعني مجرد مثلا ما أسحبها في
+
+353
+00:25:42,030 --> 00:25:46,350
+ال pipe و أنقلها لل .. للوعائل عشان أفضيها ممكن
+
+354
+00:25:46,350 --> 00:25:50,810
+تكون اتبخرت فهنا بيصير في عندي فاقد في الحجم
+
+355
+00:25:50,810 --> 00:25:58,290
+فبالتالي أنا بكون نقلت حجمأقل من اللازم فهنا باع
+
+356
+00:25:58,290 --> 00:26:05,490
+هذه النوع من السوائل ايضا ممكن انه استخدم نظام
+
+357
+00:26:05,490 --> 00:26:09,230
+الضغطين بحيث ان انا اخد حجم بزيادة و لما افضل افضل
+
+358
+00:26:09,230 --> 00:26:14,030
+exact volume عشان اذا مهما يكون الطاير من هذا ال
+
+359
+00:26:14,030 --> 00:26:18,050
+solution اكون على الأقل مازلة محتفظة بال volume
+
+360
+00:26:18,050 --> 00:26:21,890
+اللي انا بديهاتمام؟ أيضا في بعض المحاليل اللي
+
+361
+00:26:21,890 --> 00:26:24,510
+بنسميها foaming solution ايش يعني foaming
+
+362
+00:26:24,510 --> 00:26:28,950
+solution؟ يعني محاليل بتعمل رغبة تمام؟ فيها مادة
+
+363
+00:26:28,950 --> 00:26:33,190
+صابون او يعني مادة ..الها ملمة الصابونة هذه
+
+364
+00:26:33,190 --> 00:26:37,690
+المحاليل اللي فيها مواد ذات ملمة الصابونة تمام؟
+
+365
+00:26:37,690 --> 00:26:41,120
+ممكن تعملي رغبةو بالتالي لما أجي أصحب أصحب من
+
+366
+00:26:41,120 --> 00:26:45,220
+الرغبة high فبالتالي أكون نقلت volume أقل من
+
+367
+00:26:45,220 --> 00:26:49,520
+اللازم لإن أنا يعني جزء من الرغبة احتلت ال tub
+
+368
+00:26:49,520 --> 00:26:53,300
+تمام؟ و أفكر حالي إن أنا أخدت الحجم اللي بدياه و
+
+369
+00:26:53,300 --> 00:26:59,700
+فعليا أنا بكون ماخدة حجم أقل من ال ..المفروض
+
+370
+00:26:59,700 --> 00:27:03,300
+فبالتالي بستخدم برضه نظام ال larger volume of
+
+371
+00:27:03,300 --> 00:27:06,120
+solution يعني ان انا بدي اخد ال extra volume يعني
+
+372
+00:27:06,120 --> 00:27:09,700
+بدي استخدم ال reverse technique يعني نظام ضغطتين و
+
+373
+00:27:09,700 --> 00:27:17,300
+.. و بعد هيك شسمه بروح بفضي بضغطة واحدةتمام؟ عشان
+
+374
+00:27:17,300 --> 00:27:21,780
+لو كان في رغبة في المحلول أكون ضامنة أنها ما تأثر
+
+375
+00:27:21,780 --> 00:27:25,360
+على الحجم اللي أنا بدي أنقله تمام؟ و أيضا عشان لو
+
+376
+00:27:25,360 --> 00:27:29,180
+أنا بدي أنقل حجوم صغيرة جدا جدا يعني أنا خايفة ..
+
+377
+00:27:29,180 --> 00:27:32,260
+يعني مش متأكدة أخدت ال volume ولا لأ لأنه في حجوم
+
+378
+00:27:32,260 --> 00:27:35,600
+يعني زي مثلا حجم one microliterيعني انت حتى ما
+
+379
+00:27:35,600 --> 00:27:39,040
+بتشوفيه على التب يعني صعب تشوفيه على التب انه انت
+
+380
+00:27:39,040 --> 00:27:42,720
+أخدتي او ما أخدتي فالأفضل ان انا ااخد حجم بزيادة و
+
+381
+00:27:42,720 --> 00:27:45,560
+لما افضي داخل ال solution او المقلوعه اللي انا بدي
+
+382
+00:27:45,560 --> 00:27:50,640
+اشتغل فيه بفضي بالحجم اللي بديها اذا .. اذا لما
+
+383
+00:27:50,640 --> 00:27:56,550
+انا اسحب الحجمبضغطة و افضيه بدغطتين معناها انا بدي
+
+384
+00:27:56,550 --> 00:28:01,050
+اخدت exact volume و افضيته بدغطتين عشان اضمن ان
+
+385
+00:28:01,050 --> 00:28:05,270
+انا افضيته كويس تمام هذه طريقة forward bibuting
+
+386
+00:28:05,270 --> 00:28:10,510
+لكن لما انا اسحب الحجم بدغطتين و افضيه بدغطة واحدة
+
+387
+00:28:10,510 --> 00:28:14,590
+معناها انا استخدمت طريقة ال reverse bibuting و هذا
+
+388
+00:28:14,590 --> 00:28:20,490
+طبعا بيختلفهلأ ال .. ال .. اذا هذه ال bybit شايفين
+
+389
+00:28:20,490 --> 00:28:24,570
+هي البلانجر بالكبس عليه في عندى ضغطة واحدة او
+
+390
+00:28:24,570 --> 00:28:28,690
+ضغطتان depress the blanger until you feel the
+
+391
+00:28:28,690 --> 00:28:32,090
+initial resistance مجرد ما انت تضغطي طبعا ان شاء
+
+392
+00:28:32,090 --> 00:28:35,670
+الله راح نرجع على المعامل و امسكهم ال bybit كل بنت
+
+393
+00:28:35,670 --> 00:28:39,770
+راح يكونيلها bybitو تشوف و تجرب كيف تشتغل عليها
+
+394
+00:28:39,770 --> 00:28:43,130
+كيف تضغط .. كيف لما بتضغط بتقابل ال resistant
+
+395
+00:28:43,130 --> 00:28:46,750
+الأولى اللي هي الإعاقة الأولى يعني إشي بيعيط مصاري
+
+396
+00:28:46,750 --> 00:28:50,590
+ال blanket إشي بيوقفه هذه بتكون الدغطة الأولى و
+
+397
+00:28:50,590 --> 00:28:55,390
+بقى لو .. لو كبست بقوة أكبر بتكون ساعتها أخدت ال
+
+398
+00:28:55,390 --> 00:28:59,730
+.. ال .. ال vibe أخدت الدغطتين تمام فيعني بصير ده
+
+399
+00:28:59,730 --> 00:29:05,530
+تسحب extra volumeطيب فبالتالي لما احنا بدنا نفوت
+
+400
+00:29:05,530 --> 00:29:09,090
+في ال .. ال .. ال vibe طبعا لما اجي افوتها بفوتها
+
+401
+00:29:09,090 --> 00:29:13,190
+بحيث انها تكون مغموقة جزء منها مغمور او جزء من
+
+402
+00:29:13,190 --> 00:29:18,330
+التب مغمور داخل ال solution تمام؟ مابروح اخلي
+
+403
+00:29:18,330 --> 00:29:23,290
+الفتحة التب او هنا يعني الفوهة التب ملامسة للسطح
+
+404
+00:29:23,290 --> 00:29:26,450
+لإنه انا ممكن اسحب سائل و هوا مع بعض مدام ها على
+
+405
+00:29:26,450 --> 00:29:31,690
+السطحو أيضا كمان ما بخليها تلامس البطم لل solution
+
+406
+00:29:31,690 --> 00:29:36,630
+ليش؟ لإن هذه الفوهة أو فتحة التب ممكن يغلقها اللي
+
+407
+00:29:36,630 --> 00:29:43,810
+هي قاع ال container او ال tube فبالتالي انه انا
+
+408
+00:29:43,810 --> 00:29:48,550
+بكون هي كعملت انسداد للتب و مش راح اسحب ال volume
+
+409
+00:29:48,550 --> 00:29:52,730
+اللي بدي يعني تمام؟ اذا بضغطال .. الضغطة أولة أو
+
+410
+00:29:52,730 --> 00:29:57,510
+ضغطة تانية حسب نوع ال .. ال .. ال bybiting لو أنا
+
+411
+00:29:57,510 --> 00:30:01,890
+بستخدم forward bybiting هضغط ضغطة واحدة تمام بفوت
+
+412
+00:30:01,890 --> 00:30:04,830
+ال tip بحيث أنه يكون جزء منها مغمور داخل ال
+
+413
+00:30:04,830 --> 00:30:08,050
+solution مش على السطح ولا على .. في القاع م ..
+
+414
+00:30:08,050 --> 00:30:12,630
+ملامسة للقاع و ببدأ بعد هيك إيش أعمل أرفع إيدي
+
+415
+00:30:12,630 --> 00:30:18,350
+بالتدريج عن البلانجر بالتدريج تمام مهم جدا أن أنا
+
+416
+00:30:18,350 --> 00:30:22,860
+أرفع إيدي بالتدريج عن البلانجرمارفعش هيك فجأة
+
+417
+00:30:22,860 --> 00:30:28,380
+واحدة ليش؟ لإن لو رفعت فجأة راح يندفع ال solution
+
+418
+00:30:28,380 --> 00:30:33,520
+بقوة داخل ال .. ال .. التب فهذا هيسببلي أخطاء ممكن
+
+419
+00:30:33,520 --> 00:30:37,340
+ما أخد ال volume اللي بديه ممكن ال .. ال .. السائل
+
+420
+00:30:37,340 --> 00:30:40,940
+يندفع ويفوت داخل ال pipe ذات نفسها تمام؟ يعني يطلع
+
+421
+00:30:40,940 --> 00:30:44,560
+من التب ويفوت داخل ال pipe ويقدي إلى الصدق ل ..
+
+422
+00:30:44,560 --> 00:30:49,380
+لإلها أو إلى التلف تمام؟ وممكن أكون يعني يسحب هوا
+
+423
+00:30:49,750 --> 00:30:52,750
+معاها يعني يكون فيه فقاعات فبالتالي يكون فيه error
+
+424
+00:30:52,750 --> 00:30:56,830
+في ال volume اللي نقلته فبالتالي يفضل انه انا لما
+
+425
+00:30:56,830 --> 00:31:00,910
+اجي ارفع البلانجر ارفعه بالتدريج عشان المحلول يفوت
+
+426
+00:31:00,910 --> 00:31:05,710
+بالتدريج او ببطء داخل ال pipet ويفوت بشكل دقيق و
+
+427
+00:31:05,710 --> 00:31:11,220
+اكون انا عم باخد الحجم الدقيق تمام؟بعد هيك بروح
+
+428
+00:31:11,220 --> 00:31:15,120
+على ال container التاني و ب .. أضغط على البلانجر
+
+429
+00:31:15,120 --> 00:31:19,720
+مرتين يعني على ال initials ال resistant و بفضيه و
+
+430
+00:31:19,720 --> 00:31:22,320
+ممكن أضغط على ال second resistant عشان أتأكد أن
+
+431
+00:31:22,320 --> 00:31:26,040
+أنا فضيت كل ال volume و بعد هيك بتخلص من ال tip
+
+432
+00:31:26,040 --> 00:31:29,080
+كيف بتخلص من ال tip؟ حكينا أنه في هنا على الطرف
+
+433
+00:31:29,080 --> 00:31:33,720
+حاجة اسمها ejector لل tipهنا مجرد ما انا اضغط على
+
+434
+00:31:33,720 --> 00:31:37,500
+هذا ال ejector لل tip ال tip بتكون خلاص فانفصلت عن
+
+435
+00:31:37,500 --> 00:31:43,100
+ال pipet و انا بتخلص منها فلما بدي اتخلص من ال tip
+
+436
+00:31:43,100 --> 00:31:47,520
+بوجه ال pipet هذه باتجاه السلة تمام و بضغط على ال
+
+437
+00:31:47,520 --> 00:31:53,860
+ejector فلحالها ال pipet بتروح على الفضلات
+
+438
+00:31:54,650 --> 00:31:59,550
+ع الوسط طبعا هذا بالنسبة ل .. ال .. ال forward
+
+439
+00:31:59,550 --> 00:32:05,230
+بالنسبة ل reverse طبعا يعني تقريبا نفس التعليمات
+
+440
+00:32:05,230 --> 00:32:08,270
+ولكن انه انا لما بدي افوت ضغطة بدي اكون ضغطة
+
+441
+00:32:08,270 --> 00:32:13,250
+ضغطتين و بدي افوت ب .. و اكون جزء من الطب مغمور
+
+442
+00:32:13,250 --> 00:32:17,510
+داخل ال solution طبعا بفوت بشكل عمودي يا بنات لو
+
+443
+00:32:17,510 --> 00:32:20,710
+انا بدي افوت بشكل مائل بيأثر على الحجم اللي انا
+
+444
+00:32:20,710 --> 00:32:24,510
+مخدعةبفوت بشكل عمودي داخل ال solution جزء من ال
+
+445
+00:32:24,510 --> 00:32:29,230
+tip مغمور داخل ال solution و برفع ايدي بالتدريج عن
+
+446
+00:32:29,230 --> 00:32:32,670
+البلنجر بسحبلي ال volume طبعا هنا في ال reverse
+
+447
+00:32:32,670 --> 00:32:37,190
+انا ضغطت ضغطتين فهيسحبلي extra volume تمام؟بعدين
+
+448
+00:32:37,190 --> 00:32:40,570
+بروح على ال container اللي انا بدي افض فيه و بضغط
+
+449
+00:32:40,570 --> 00:32:44,230
+ضغطة واحدة علشان تنزلي ال solution اللي انا بديها
+
+450
+00:32:44,230 --> 00:32:48,210
+فقط الحجم اللي بديها فقط و ال extra هو و ال tab
+
+451
+00:32:48,210 --> 00:32:50,730
+بتخلص منه في ال west من خلال ان انا اضغط على ال
+
+452
+00:32:50,730 --> 00:32:54,590
+ejector و تنفصل ال tab عن ال pipet و تروح في حال
+
+453
+00:32:54,590 --> 00:33:00,370
+سبيلهمتمام؟ أول حاجة مع .. يعني ملاحظات لاستخدام
+
+454
+00:33:00,370 --> 00:33:04,650
+ال bybit, never point a bybit up ممنوع أنك انت
+
+455
+00:33:04,650 --> 00:33:07,970
+تستخدمي ال bybit تقليبيها بهذا الشكل بحيث انها
+
+456
+00:33:07,970 --> 00:33:13,600
+تكون ال tip صارت فوق و ال bybit تحتطبعا و انا
+
+457
+00:33:13,600 --> 00:33:16,300
+دايما لما بستخدم ال bible بتكون بهذا الاتجاه بحيث
+
+458
+00:33:16,300 --> 00:33:19,620
+أنه التب لا تحت لإنه لو أنا بدي أجلبها ال volume
+
+459
+00:33:19,620 --> 00:33:22,680
+اللي موجود في التب راح يفوت داخل ال bible طبعا هذه
+
+460
+00:33:22,680 --> 00:33:28,420
+عبارة عن أنا بيب طبعا و في كمان نظام ال .. ال ..
+
+461
+00:33:28,420 --> 00:33:33,460
+الذنبركاتفبالتالي ممكن تصدق داخل ال .. يعني يصير
+
+462
+00:33:33,460 --> 00:33:37,300
+صدق او يصير فيه تلف و ممكن في محاليل بترسب بتعمل
+
+463
+00:33:37,300 --> 00:33:41,440
+رواس بتعمل انسداد فهذا بيأثر على دقة ال pipet فهو
+
+464
+00:33:41,440 --> 00:33:45,340
+يفضل ان انا ممنوع اوجهها الى اعلى بحيث ان ال
+
+465
+00:33:45,340 --> 00:33:48,580
+liquid يفوت داخل ال pipet و يعملها destroying
+
+466
+00:33:48,580 --> 00:33:53,060
+تمام؟طيب when with a drawing liquid with with a
+
+467
+00:33:53,060 --> 00:33:56,540
+pipe it always release the plunger slowly طبعا
+
+468
+00:33:56,540 --> 00:34:00,720
+لحظة لاحظته انتوا حتى بنبرت صوتي ركزتي كتير منيح و
+
+469
+00:34:00,720 --> 00:34:04,020
+انا بحكيلكم لما ترفع ايدك عن ال plunger ارفعيه
+
+470
+00:34:04,020 --> 00:34:09,040
+slowly شويه شويه بالتدريج بهدوء مابرفع ايدي فجأة
+
+471
+00:34:09,040 --> 00:34:13,800
+ليش لإن هنا هي بحكيلك انه ال .. ال .. ال ..الشغل
+
+472
+00:34:13,800 --> 00:34:19,280
+رافعت ايدك بشكل تدريجي او بشكل بطيء عن البلانجر
+
+473
+00:34:19,280 --> 00:34:24,080
+هيمنع من انه ال liquid يصير له rushing into انه
+
+474
+00:34:24,080 --> 00:34:28,160
+يندفع داخل ال pipe و بالتالي ممكن يسببلها انسداد
+
+475
+00:34:28,160 --> 00:34:35,100
+او صدق او تلف فبالتاليمهم جدا طبعا انه ارفع ايدي
+
+476
+00:34:35,100 --> 00:34:38,020
+بالتدريج this is especially important with large
+
+477
+00:34:38,020 --> 00:34:41,860
+volumes يعني و هذا الاشي بنتبهله كتير منيح و انا
+
+478
+00:34:41,860 --> 00:34:46,740
+بصحب حجوم كبيرة حجوم كبيرة معناها السائل هيندفع
+
+479
+00:34:46,740 --> 00:34:50,720
+بشكل قوي هو كميته كبيرة فهيفوت داخل ال bipe هيصل ل
+
+480
+00:34:50,720 --> 00:34:55,240
+ال bipe من جوا و يتلفها be sure you use the proper
+
+481
+00:34:55,240 --> 00:35:02,780
+size tip for each bipe حكينا انه لكلبيبت طبعا لكل
+
+482
+00:35:02,780 --> 00:35:08,040
+بيبت في عندى تب خاصة فيها تبعا لحجمها أو تبعا ل ال
+
+483
+00:35:08,040 --> 00:35:12,380
+range تبعها فانا كل بيبت بستخدملها التب الخاصة
+
+484
+00:35:12,380 --> 00:35:15,340
+فيها ما بنفع مثلا مع البيبتات الصغيرة أستخدم تب
+
+485
+00:35:15,340 --> 00:35:19,040
+كبيرة أصلا مش راح تركب عليها وما بنفع مع البيبتات
+
+486
+00:35:19,040 --> 00:35:21,980
+الكبيرة أستخدم تب صغيرة مش راح تكفي لل volume اللي
+
+487
+00:35:21,980 --> 00:35:26,520
+أنا بدني أنقله طبعا فإذا كل بيبت لها تب خاصة فيها
+
+488
+00:35:26,520 --> 00:35:30,740
+بستخدمهاalways use a new tip for each different
+
+489
+00:35:30,740 --> 00:35:35,960
+liquid طبعا كل حجم بدي أنقله بستخدمله a new tip
+
+490
+00:35:35,960 --> 00:35:40,020
+طبعا ال tip جديدة و حكينا انه هاي ال tip أشمالها
+
+491
+00:35:40,020 --> 00:35:44,460
+disposable طبعا فهيمر معانا ان شاء الله مصطلح
+
+492
+00:35:44,460 --> 00:35:48,360
+disposable و أذكركم فيه يعني تستخدم لمرة واحدة فقط
+
+493
+00:35:48,640 --> 00:35:52,580
+طيب use the correct pipet for the volume to be
+
+494
+00:35:52,580 --> 00:35:56,260
+dispended يعني انا بدي استخدم ال pipet اختار ال
+
+495
+00:35:56,260 --> 00:36:02,180
+pipet اللي ال range تبعها تمام مناسب ل .. ال .. ال
+
+496
+00:36:02,180 --> 00:36:04,980
+.. ال pipet ل الحجم اللي بدي أنقله هى مثلا هنا
+
+497
+00:36:04,980 --> 00:36:09,420
+بيحكيلك never use the متين ل الف microliter pipet
+
+498
+00:36:09,420 --> 00:36:12,720
+to dispense متين تمام هى هنا مثلا هى ال range من
+
+499
+00:36:12,720 --> 00:36:18,210
+متين ل الف مابستخدمها عشان انقل حجم متينلأن حكينا
+
+500
+00:36:18,210 --> 00:36:20,870
+إن هي مش هتكون دقيقة على lower limit لكن ممكن تكون
+
+501
+00:36:20,870 --> 00:36:23,630
+دقيقة على upper limit أو بتكون أدقهي على upper
+
+502
+00:36:23,630 --> 00:36:28,750
+limit تمام؟ و لو أنا بدي أخد حجوم أقل من 200 أو
+
+503
+00:36:28,750 --> 00:36:33,790
+أكتر من ألف هذا إيش ممكن يعملي سببلي damage للأداة
+
+504
+00:36:33,790 --> 00:36:39,710
+هذه فبالتالي لازم أكون حذرة و حريصة في استخدام ال
+
+505
+00:36:39,710 --> 00:36:44,850
+bybit without the bybitwithdraw the pipet from the
+
+506
+00:36:44,850 --> 00:36:48,290
+receiving vessels carefully sliding the tip along
+
+507
+00:36:48,290 --> 00:36:51,890
+the wall هلأ مجرد ما انا ارفع ال pipet بعد ما اخد
+
+508
+00:36:51,890 --> 00:36:55,610
+الحجم اللي بديا لازم اعمل حاجة اسمها sliding يعني
+
+509
+00:36:55,610 --> 00:37:00,750
+انا امرر ال tip هادي امسحها على فتحة ال container
+
+510
+00:37:00,750 --> 00:37:05,690
+يعني مثلابهذا الشكل يعني ارفع وانزل ال buy bet على
+
+511
+00:37:05,690 --> 00:37:11,130
+اللي فوهت او فتحت ال container تبع المحلول بحيث
+
+512
+00:37:11,130 --> 00:37:15,910
+انه اي اشي عالق على جدار ال tip من برا اتخلص منه
+
+513
+00:37:15,910 --> 00:37:19,330
+انا بعنيني فقط ال volume اللي انا نقلته في الداخل
+
+514
+00:37:19,330 --> 00:37:23,670
+طبعا فبالتالي عشان ما اخد excess volume remove the
+
+515
+00:37:23,670 --> 00:37:30,770
+tip from the sample liquidتمام؟ و no liquid should
+
+516
+00:37:30,770 --> 00:37:35,130
+remain on the outside of the tip طبعا يعني لما ..
+
+517
+00:37:35,130 --> 00:37:40,130
+مجرد ما انا اطلع من ال .. ال .. يعني اخد الحجم
+
+518
+00:37:40,130 --> 00:37:43,410
+اللي بديها و اطلع من ال container مش لازم يضل
+
+519
+00:37:43,410 --> 00:37:47,910
+بقايا من ال solution على ال tip فيفضل ان انا امسح
+
+520
+00:37:47,910 --> 00:37:52,620
+باستخدام ال wipe تمام؟او ال .. ال جوز او اي قطعة
+
+521
+00:37:52,620 --> 00:37:58,780
+.. قطعة ت .. clinics او قطن او شاش باجفف ال .. ال
+
+522
+00:37:58,780 --> 00:38:02,780
+.. ال bybit بمسحها بمررها عليها بحيث ان انا اجفف
+
+523
+00:38:02,780 --> 00:38:07,300
+اي بقايا عالقة عليها ولكن يف .. بكون حريصة انه
+
+524
+00:38:07,300 --> 00:38:12,600
+هادي ال .. ال .. ال vibe تمامما تلامس فوهة التب
+
+525
+00:38:12,600 --> 00:38:17,540
+ليش لإنها لو لامست فوهة التب هذا absorbent المحارم
+
+526
+00:38:17,540 --> 00:38:21,000
+و ال clinics و الاشي بينطس السائل فممكن تمطس
+
+527
+00:38:21,000 --> 00:38:25,820
+السائل اللي موجود داخل التب و بالتالي بينقص ال
+
+528
+00:38:25,820 --> 00:38:28,560
+volume اللي أخدته و بيكون أنا هيك عم باخد volumes
+
+529
+00:38:28,560 --> 00:38:32,260
+مش accurate و مش precise تمام مهم جدا لها هاي
+
+530
+00:38:32,260 --> 00:38:37,440
+الشغل اذا بعد هى مجرد ما إنه أسحب ال .. ال .. ال
+
+531
+00:38:37,440 --> 00:38:37,860
+.. ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال ..
+
+532
+00:38:37,860 --> 00:38:38,800
+ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال
+
+533
+00:38:38,800 --> 00:38:39,540
+.. ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال ..
+
+534
+00:38:39,540 --> 00:38:39,680
+ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال
+
+535
+00:38:39,680 --> 00:38:43,650
+ال .. المش لازم no liquid should remain on the
+
+536
+00:38:43,650 --> 00:38:46,950
+outside مش لازم ال liquid يضل على خارج ال tip
+
+537
+00:38:46,950 --> 00:38:51,470
+فبالتالي بمسح قطارات اللي .. اللي موجودة على ال
+
+538
+00:38:51,470 --> 00:38:56,190
+outside of the tip بستخدام tissue, paper, جوز,
+
+539
+00:38:56,730 --> 00:39:01,130
+wipes أي إش .. أي نوع محارب أو clinics بحيث انه ما
+
+540
+00:39:01,130 --> 00:39:04,790
+ألامس never touch the tip orifice مافتحق ماألامسش
+
+541
+00:39:04,910 --> 00:39:08,290
+ال tip orifice يعني فتحة ال .. ال tip ال opening
+
+542
+00:39:08,290 --> 00:39:12,410
+تبع ال tip طبعا ماقلامسه بحيث انه ماينطست السائل و
+
+543
+00:39:12,410 --> 00:39:16,770
+بهك انا اكون عم باخد volume اقل من اللازم و اكون
+
+544
+00:39:16,770 --> 00:39:19,870
+مش .. مش accurate و مش precise في عملية ال volume
+
+545
+00:39:19,870 --> 00:39:25,090
+transfer طبعا طيب pre-rinsing ايش يعني كلمة pre
+
+546
+00:39:25,090 --> 00:39:31,610
+-rinsing يفضل انه انا .. انا لما بدي انقل حجوم ان
+
+547
+00:39:31,610 --> 00:39:39,390
+انا ابلليعني مثلا هنا يفضل إن أنا أبلل ال .. ال ..
+
+548
+00:39:39,390 --> 00:39:44,290
+التب من جوا في .. في .. في السائل اللي بدي أنقله،
+
+549
+00:39:44,290 --> 00:39:47,510
+هاي معناه pre runs، طبعا؟ يعني أول حاجة بصحب أول
+
+550
+00:39:47,510 --> 00:39:52,330
+volume و بتخلص منه بكبه، هيك أنا بضمن إنه جزء من
+
+551
+00:39:52,330 --> 00:39:56,570
+السائل لمس ال .. ال .. التب من الداخل فبالتالي
+
+552
+00:39:56,570 --> 00:40:02,570
+صارت التب إشمالها مبللة، طيب فلمّا أجي أنقل volume
+
+553
+00:40:03,230 --> 00:40:06,390
+و أاخد ال volume و أنقله هيك بكون أنا عم باخد
+
+554
+00:40:06,390 --> 00:40:10,490
+volume بشكل أدق ليش؟ لأنه لو .. لو أنا ماعملت ال
+
+555
+00:40:10,490 --> 00:40:14,490
+pre-rinsing هذه طبعا لو ماعملت pre-rinsing أخدت
+
+556
+00:40:14,490 --> 00:40:18,350
+volume و روحت فضيته في جزء من السائل اللي أنا
+
+557
+00:40:18,350 --> 00:40:24,370
+أخدته بيضل ملتصق بجدران التب مبلل لإلها وهذا جزء
+
+558
+00:40:24,370 --> 00:40:29,190
+يعني في نسبة فقد لل volume في نسبة errorطبعا لكن
+
+559
+00:40:29,190 --> 00:40:34,490
+لما انا استخدم tip already مبللة يعني tip انا سحبت
+
+560
+00:40:34,490 --> 00:40:36,970
+اول volume فيها و كبيته و بعدين سحبت ال volume
+
+561
+00:40:36,970 --> 00:40:40,290
+اللى بدي استخدمه ال volume الفعلي معناه انا بللت
+
+562
+00:40:40,290 --> 00:40:45,850
+ال tip من الداخل فبالتالي فبطل في عندي نسبة فقد من
+
+563
+00:40:45,850 --> 00:40:49,890
+الحجم و بطل في عندي نسبة ال error هذه معناه كلمة
+
+564
+00:40:49,890 --> 00:40:53,670
+pre-rinsing minimize اشمالها ال variances
+
+565
+00:40:53,670 --> 00:40:59,560
+الاختلافات في ال .. ال ..الحجوم طبعا when by
+
+566
+00:40:59,560 --> 00:41:03,080
+beating some solutions زي ال serum اللي هي العينات
+
+567
+00:41:03,080 --> 00:41:08,260
+يعني الشخ .. المرضى ال serum البلازما ال protein
+
+568
+00:41:08,260 --> 00:41:11,300
+containing solution المحليل اللي بتحتوي على
+
+569
+00:41:11,300 --> 00:41:14,420
+البروتينات ال organic solvents المضيبات العضوية
+
+570
+00:41:14,420 --> 00:41:19,700
+هذه طبعا في جزء منها بيكون حكينا انه هيصير في فيلم
+
+571
+00:41:19,700 --> 00:41:24,500
+هيفي جزء منها هيبطن هيلامس ال inside of the tipو
+
+572
+00:41:24,500 --> 00:41:29,200
+هذا حكينا اشماله error فبالتالي لما انا اعمل عملية
+
+573
+00:41:29,200 --> 00:41:33,540
+pre-rinsing فبالتالي انا بقلل ال error هذه من خلال
+
+574
+00:41:33,540 --> 00:41:39,120
+ان انا خلاص استخدمت already جزء بيبة مبللة جزء ..
+
+575
+00:41:39,120 --> 00:41:43,040
+بيبة عملنا لها pre-rinsing فبالتالي مش هيكون في
+
+576
+00:41:43,040 --> 00:41:47,400
+عندي فقد في ال volume و مش هيكون في عندي نسبة
+
+577
+00:41:47,400 --> 00:41:51,780
+errorطيب when by beating concentrated acid or
+
+578
+00:41:51,780 --> 00:41:56,100
+highly corrosive solution such as halite salts
+
+579
+00:41:56,100 --> 00:42:01,540
+it's recommended to that by bit be disassembled
+
+580
+00:42:01,540 --> 00:42:07,680
+after used to inspect the shaft و المكونات تبعتها،
+
+581
+00:42:07,680 --> 00:42:11,800
+هلأ بيحكيلك أنه لما بنستخدم بعض المحاليل اللي هي
+
+582
+00:42:11,800 --> 00:42:18,100
+corrosive تمامحارقة او يعني مؤدية وبيتطير منها
+
+583
+00:42:18,100 --> 00:42:24,160
+ابخرة او يعني فيه بيتصعد منها قترانات او ابخرة او
+
+584
+00:42:24,160 --> 00:42:28,960
+رذاذ زي ال .. ال .. الهاليد سالتز هاي فيفضل ان انا
+
+585
+00:42:28,960 --> 00:42:32,620
+افك البعيبة و انظفها من الداخل و ارجع اركبها مرتان
+
+586
+00:42:32,620 --> 00:42:38,940
+علشان اتأكد انها هي يعني ما رح تتعطل ما رح تخرب ال
+
+587
+00:42:38,940 --> 00:42:44,050
+air bubbleطبعا يعني ان في عندي تقطع في السائل اللي
+
+588
+00:42:44,050 --> 00:42:47,170
+انا عم باخده في هنا فيه قطارات في فيه .. فيه هوا
+
+589
+00:42:47,170 --> 00:42:52,670
+تمام؟طب هذا ال .. ال .. الهواء إيش سببه؟ سببه أول
+
+590
+00:42:52,670 --> 00:42:55,970
+حاجة إما إن أنا رفعت إيدي عن ال plunger بشكل سريع
+
+591
+00:42:55,970 --> 00:43:00,010
+أو كانت ال tip مش مغمورة كويس في ال solution سحبت
+
+592
+00:43:00,010 --> 00:43:03,550
+من عن السطح فبالتالي بما إن سحبت عن السطح معناها
+
+593
+00:43:03,550 --> 00:43:10,810
+صار في عرض لإنه يدخل air bubble تمام ممكن يكون إنه
+
+594
+00:43:11,460 --> 00:43:19,940
+سببها ال .. ال .. يعني السائل نفسه يكون يعني فومي
+
+595
+00:43:19,940 --> 00:43:26,480
+بي .. بيكون رغوة فبالتالي انا ما اتبعت التعليمات ل
+
+596
+00:43:26,480 --> 00:43:31,360
+.. ل .. ل .. ال by betting من فومي reagent
+
+597
+00:43:31,360 --> 00:43:36,240
+فبالتالي ممكن تظهر عندى air bubble طبعا ال .. ال
+
+598
+00:43:36,240 --> 00:43:40,190
+.. ال air bubble إذا ظهرت طبعاطبعا أول حاجة إذا
+
+599
+00:43:40,190 --> 00:43:43,910
+ظهرت في .. في ال by bit بفضل solution و برجع باخد
+
+600
+00:43:43,910 --> 00:43:47,490
+مرة تانية، ضالت موجودة معناها بيده أتخلص من التب و
+
+601
+00:43:47,490 --> 00:43:51,090
+أركب تب جديدة و أاخد volume مع ال .. التزام
+
+602
+00:43:51,090 --> 00:43:56,410
+بالتعليمات حتى أتجنب من ظهور air bubble، ليش؟ لإن
+
+603
+00:43:56,410 --> 00:43:59,150
+ال air bubble طبعا هذه محتلة جزء من الحجم اللي
+
+604
+00:43:59,150 --> 00:44:03,580
+موجود يعني هذا المفروض كله يكون سائلطبعا فوجود air
+
+605
+00:44:03,580 --> 00:44:06,860
+bubble وجود تقطع في السائل يعني فيه هوى فبالتالي
+
+606
+00:44:06,860 --> 00:44:09,900
+الهوى محتل حجم اذا انا مش ماخدة الحجم المناسب
+
+607
+00:44:09,900 --> 00:44:14,360
+ماخدة اقل منه اذا انا مش accurate ومش precise طبعا
+
+608
+00:44:14,360 --> 00:44:19,420
+هذا بالنسبة ل ال bybit طيب خلينا بس قبل ما نشوف ال
+
+609
+00:44:19,420 --> 00:44:23,580
+calibration ل ال bybit نتابع مع بعض نشوف هذا
+
+610
+00:44:23,580 --> 00:44:30,040
+الفيديو بيعلمناكيف انا بدي استخدم ال .. ال by bet
+
+611
+00:44:30,040 --> 00:44:34,000
+و هنرجع نحكي نفس التعليمات او نفس المعلومات اللي
+
+612
+00:44:34,000 --> 00:44:37,560
+انا ذكرتهم باستخدام ال by bet هاي زي ما انتوا
+
+613
+00:44:37,560 --> 00:44:42,340
+شايفين هنا خليني بس ارجع شوية هنا تمام هاي ال by
+
+614
+00:44:42,340 --> 00:44:48,640
+bet نفس المكونات زي ما انتوا شايفين هنا نفس
+
+615
+00:44:48,640 --> 00:44:52,400
+المكونات لحظة خليني ارجع
+
+616
+00:44:55,930 --> 00:44:59,770
+خلص من هاي، هاي ال pipe هاي البلانجر تمام و الرد
+
+617
+00:44:59,770 --> 00:45:03,090
+هذا اللي بيلتف يمين و يسار تمام عكس حقارب الساعة و
+
+618
+00:45:03,090 --> 00:45:06,470
+باتجاه حقارب الساعة باتجاهي او بعيد عني حسب ما انا
+
+619
+00:45:06,470 --> 00:45:10,930
+هعلمكم ان شاء الله و هاي ال .. ال .. ال screen
+
+620
+00:45:10,930 --> 00:45:16,350
+تمام هذا ال .. ال .. ال ejector طبع التب على الجهة
+
+621
+00:45:16,350 --> 00:45:21,470
+التانية في هنا ال adapter هذا ال handle طبع ال ..
+
+622
+00:45:23,100 --> 00:45:27,640
+البيبت وهنا الموجود فيه ال adapter تبع التب تمام
+
+623
+00:45:27,640 --> 00:45:33,970
+ومهي المكونات كلها موجودة طيب خلينا نشوفكيف بيتم
+
+624
+00:45:33,970 --> 00:45:38,030
+تحويل حجم يعني من خلال .. يعني إما ب .. في بيبتات
+
+625
+00:45:38,030 --> 00:45:42,250
+بلف ال .. ال .. بلانجر نفسه بكون بحاركه، في بيبتات
+
+626
+00:45:42,250 --> 00:45:48,030
+بيكون لأ، في بيكون زي منظم موجود لأسفل منها و من
+
+627
+00:45:48,030 --> 00:45:51,970
+خلاله أنا بتحكم في الحجم، إذا بلفه علشان أتحكم
+
+628
+00:45:51,970 --> 00:45:56,840
+بالحجم اللي موجود هنا، شايفين؟ ها يعني تمام؟زي ما
+
+629
+00:45:56,840 --> 00:46:01,760
+انتوا شايفين بحرك بحيث ان انا اختار الحجم اللى بدى
+
+630
+00:46:01,760 --> 00:46:05,240
+طبعا ال by bit هى مكتوب هنا بتاخد من مية لألف هينا
+
+631
+00:46:05,240 --> 00:46:10,240
+ضبطناها على الف و بدى بعد هيك اروح اركبلها التب
+
+632
+00:46:10,240 --> 00:46:14,440
+الخاصة فيها طبعا لازم تكون تب مناسبة لإلها شايفين
+
+633
+00:46:14,440 --> 00:46:17,940
+التبات طبعا disposable يا بنات ال by bit التب اللى
+
+634
+00:46:17,940 --> 00:46:21,720
+بستخدمها برجعهاش مكانها بتخلص منها على طول هى التب
+
+635
+00:46:21,720 --> 00:46:29,190
+تمام هنا بيكون في هذه التب بيكون عندىsorry في هذه
+
+636
+00:46:29,190 --> 00:46:31,890
+ال tip بيكون في عندى الحجم اللى انا بدى انجله هاي
+
+637
+00:46:31,890 --> 00:46:35,830
+البلانجة طبعا انا لما اجى اكبس عليه بيفي عندى
+
+638
+00:46:35,830 --> 00:46:38,850
+first stop هاي first stop شايفين هادى اول
+
+639
+00:46:38,850 --> 00:46:42,190
+resistant بتقابلني هاي في عندى اذا هادى ال first
+
+640
+00:46:42,190 --> 00:46:47,900
+stop شايفين هنامجرد هي ضغطت فاتت عمودي في داخل
+
+641
+00:46:47,900 --> 00:46:52,680
+السائل طبعا خلينا ال tip يعني تكون مغمورة داخل
+
+642
+00:46:52,680 --> 00:46:57,400
+السائل و بنبدأ نرفع شوي شوي بالتدريج ايدنا عن
+
+643
+00:46:57,400 --> 00:47:01,540
+البلانجر ايش اللي هيصير بالظبط هيصير ان دخول
+
+644
+00:47:01,540 --> 00:47:05,220
+السائل داخل ال tip و هيك انا بكون أخدت الحجم اللي
+
+645
+00:47:05,220 --> 00:47:09,020
+موجود على ال screen طبعا لحظة انها ضغطت ضغطة واحدة
+
+646
+00:47:09,020 --> 00:47:13,660
+يعني هي ايش بتعملبتكون .. بتكون عم تعمل forward by
+
+647
+00:47:13,660 --> 00:47:17,900
+betting طبعا فهذا ال by bet او هذا ال volume بروح
+
+648
+00:47:17,900 --> 00:47:21,100
+باخده في container و بفضيه من خلال ضغطة أولى او
+
+649
+00:47:21,100 --> 00:47:24,140
+ضغطة تانية طبعا هاي شايفين الضغطة التانية هذه هي
+
+650
+00:47:24,140 --> 00:47:27,420
+الضغطة التانية طبعا هاي .. طبعا اذا انا .. انا هاي
+
+651
+00:47:27,420 --> 00:47:32,120
+هنا الضغطة بانقل ب .. باخد ال volume و بنقله لهذا
+
+652
+00:47:32,120 --> 00:47:41,050
+بفوت عمودي و لازم اتبع كل التعليمات طبعالو رجع
+
+653
+00:47:41,050 --> 00:47:48,310
+نركز عليها مرة تانية نشوف
+
+654
+00:47:48,310 --> 00:47:53,490
+هنا هى
+
+655
+00:47:53,490 --> 00:47:57,830
+هى هنا شايفين هادى الضغط
+
+656
+00:48:02,970 --> 00:48:07,490
+هي ضغطة وهي الضغطة التانية شايفين؟ هى معانا ضغطة
+
+657
+00:48:07,490 --> 00:48:13,530
+وضغطتين طبعا؟ طيب و هيك بيتم نقل حجوم بالشكل هذا
+
+658
+00:48:13,530 --> 00:48:17,800
+من الى طبعا؟ من الىال container الأصلي ل ال
+
+659
+00:48:17,800 --> 00:48:20,380
+container اللى بدى أشتغل فيه بنقل حجم اللى بديه
+
+660
+00:48:20,380 --> 00:48:25,340
+علشان أنا بكون بدى أجري تجربة معينة تمام لما باجى
+
+661
+00:48:25,340 --> 00:48:29,620
+بفضى لازم أنا أضغط على البلانجر بحيث أنه يفضى طبعا
+
+662
+00:48:29,620 --> 00:48:33,200
+البلانجر بضغط عليه بسحب بضغط عليه مرتان يدفضى و
+
+663
+00:48:33,200 --> 00:48:38,680
+هكذا يفضل يا بنات لما أنا أجى أسحب طبعا اللى أنتوا
+
+664
+00:48:38,680 --> 00:48:47,870
+شايفين هنا هي ال ..هنا شايفين كيف انا بفوت ضغطة
+
+665
+00:48:47,870 --> 00:48:51,790
+تمام لو
+
+666
+00:48:51,790 --> 00:48:52,390
+نرجع
+
+667
+00:48:55,290 --> 00:48:59,850
+تمام هى هنا فضة ال volume هى هنا ضغطة هى ضغطتين
+
+668
+00:48:59,850 --> 00:49:03,690
+تمام تعلمنا الضغطة و الضغطتين و هى هنا شايفين كده
+
+669
+00:49:03,690 --> 00:49:08,430
+أنا بفوت ضغطة و بعدين ب .. بسحب ال .. ب .. بترك
+
+670
+00:49:08,430 --> 00:49:12,630
+إيدي شوية شوية عن البلانجر مابنفع أنا أفوت مش ضغطة
+
+671
+00:49:12,630 --> 00:49:16,250
+و أضغط جوا ال solution ليش؟ لإنه ساعتها أنا بكون
+
+672
+00:49:16,250 --> 00:49:18,890
+بدخل هوا جوا ال solution إذا هو من النوع الفومي
+
+673
+00:49:18,890 --> 00:49:21,890
+اللى بيكون رغوة هيصير فيه رغوات و يصير في عندى air
+
+674
+00:49:21,890 --> 00:49:26,950
+bubble و مشاكل في نقل الحجومطبعا طيب هلأ انا بعد
+
+675
+00:49:26,950 --> 00:49:29,730
+ما انا فضيت ال volume ضغطت على البلانجر و فضيت ال
+
+676
+00:49:29,730 --> 00:49:32,350
+volume اش بده اعمل بده اضغط على ال ejector عشان
+
+677
+00:49:32,350 --> 00:49:36,370
+اتخلص من التب شايفين مجرد ما اضغط عليها ال .. ال
+
+678
+00:49:36,370 --> 00:49:40,890
+.. التب بتفصل عن ال bibert و بت .. بتم التخلص منها
+
+679
+00:49:40,890 --> 00:49:46,460
+طبعاهذا بالنسباله ال .. ال .. ال bybite اذا اول
+
+680
+00:49:46,460 --> 00:49:52,560
+حاجة بنحدد الحجم ب .. أركب ال tip بعمل rinsing pre
+
+681
+00:49:52,560 --> 00:49:58,200
+-rinsing ببللها تمام و بعدين باخد الحجم اللي بدياه
+
+682
+00:49:58,200 --> 00:50:01,960
+سواء كان باخده بطريقة ال .. ال .. ال forward
+
+683
+00:50:01,960 --> 00:50:06,000
+bybiting او ال reverse bybiting حسب اللي انا الحجم
+
+684
+00:50:06,000 --> 00:50:09,930
+اللي ال .. ال .. او السائل اللي انا بتعامل معاهو
+
+685
+00:50:09,930 --> 00:50:15,030
+بانقله من و إلى بعد هيك بتخلص من التب بهذا الشكل
+
+686
+00:50:15,030 --> 00:50:21,550
+تمام؟ ان شاء الله هيكون شغلنا على ال .. ال bybit و
+
+687
+00:50:21,550 --> 00:50:24,630
+طبعا معظم .. كل الفحوصات بتنعمل باستخدام ال bybit
+
+688
+00:50:24,630 --> 00:50:28,630
+انا بدي اضيف حجم من ال reagent و حجم من العينة حجم
+
+689
+00:50:28,630 --> 00:50:31,510
+من ال standard و حجم من ال reagent كل شغلي
+
+690
+00:50:31,510 --> 00:50:33,710
+باستخدام ال bybit اذا هذه صديقتنا هذه اللي
+
+691
+00:50:33,710 --> 00:50:36,390
+هترافقنا من شاء الله من سنة تانية لسنة رابعة لجهة
+
+692
+00:50:36,390 --> 00:50:39,950
+الأداء فبالتالي لازم نكون دقيقين في استخدامهاو
+
+693
+00:50:39,950 --> 00:50:42,690
+عشان .. عشان نكون دقيقين باستخدامها و تكون ال vibe
+
+694
+00:50:42,690 --> 00:50:46,370
+تهدي احنا بنعمللها صيانة و بنضمن دقتها باستمرار
+
+695
+00:50:46,370 --> 00:50:49,530
+لازم انه انا اعمللها calibration اش يعني
+
+696
+00:50:49,530 --> 00:50:52,890
+calibration يعني اعادة ضبط وتهيئة علشان اتأكد من
+
+697
+00:50:52,890 --> 00:50:57,070
+شغلها ان هي عم تاخدلي شغل دقيق طبعا كيف انا بدي
+
+698
+00:50:57,070 --> 00:51:01,660
+اخد ال .. ال .. اكيد اعمللها calibration؟بدي
+
+699
+00:51:01,660 --> 00:51:06,200
+استخدمها يعني او اظبط شغلها او اتأكد من انها عم
+
+700
+00:51:06,200 --> 00:51:10,820
+تاخد volumes بشكل دقيق باستخدام الحجوم الماء ال
+
+701
+00:51:10,820 --> 00:51:14,960
+distilled water تمام؟ هنا بيحكيلي انه تحت درجة
+
+702
+00:51:14,960 --> 00:51:21,200
+الحرارة و الضغط الثابت الكثافة الماء أيضا ثابتة
+
+703
+00:51:21,200 --> 00:51:26,860
+فالحجم من الماء تمام ممكن انا يعني one ml من الميه
+
+704
+00:51:26,860 --> 00:51:31,820
+بيعادل one gramمن الميه تمام ال .. ال one ml ال
+
+705
+00:51:31,820 --> 00:51:36,360
+volume one ml لو أنا جيت وزنته تحت درجة حرارة وضغط
+
+706
+00:51:36,360 --> 00:51:40,400
+ثابت وكثافة ثابتة للماء فهي .. ال .. ال one ml
+
+707
+00:51:40,400 --> 00:51:46,710
+هيعطيني one gram من ال water تمام؟ طيب فبالتاليال
+
+708
+00:51:46,710 --> 00:51:51,330
+.. ال calibration لل بايبت لازم انا اكون بس يعني
+
+709
+00:51:51,330 --> 00:51:54,390
+بدي اعرف ال volume اللي عم تاخده حجم الماء اللي
+
+710
+00:51:54,390 --> 00:51:59,890
+بتاخده و هل هو accurate او precise و طبعا هذا
+
+711
+00:51:59,890 --> 00:52:06,910
+بيتأثر بدرجة حرارة الغرفة و ايضا الضغط الجوي و
+
+712
+00:52:06,910 --> 00:52:10,190
+الرطوبة نسبة الرطوبة اللي موجودة في الوسط او في
+
+713
+00:52:10,190 --> 00:52:14,320
+البيئة المحيطة لإجراء التجربةعشان هيك انا بستخدم
+
+714
+00:52:14,320 --> 00:52:17,980
+factor او ثابت اسمه z factor في الحسابات طبعتي
+
+715
+00:52:17,980 --> 00:52:23,340
+هنحكي عنه كمان شوية هذا ال z factor فالفكرة طبعتي
+
+716
+00:52:23,340 --> 00:52:27,660
+انه انا بدي اخد one ml من ال distilled water يعني
+
+717
+00:52:27,660 --> 00:52:30,980
+بدي اجيب ال by bit بدي اعمللها setting بدي ا ..
+
+718
+00:52:30,980 --> 00:52:35,700
+اضب .. اضبطها على one ml اركب tip اخد اعمل ال pre
+
+719
+00:52:35,700 --> 00:52:39,920
+-rinsing ابلل ال tip من .. و اتخلص من ال solution
+
+720
+00:52:39,920 --> 00:52:44,350
+اللي أخدته في المرة الأولىبعد هيك إيش بدي أعمل؟
+
+721
+00:52:44,350 --> 00:52:50,110
+بدي أخد one ml من distilled water و أحطه في cup ال
+
+722
+00:52:50,110 --> 00:52:53,990
+cup هذا بدي أكون مسفر عليه في الميزان بدي أسفر
+
+723
+00:52:53,990 --> 00:52:57,590
+عليه و أحط ال one ml و أشوف الوزنة تبعتي الوزنة
+
+724
+00:52:57,590 --> 00:53:00,090
+تبعتي هتكون إذا هو مسفر على ال cup فالوزنة اللي
+
+725
+00:53:00,090 --> 00:53:05,050
+هتطلع معايا هي وزنت ال one ml المفروض تكون مقاربة
+
+726
+00:53:05,050 --> 00:53:08,470
+ل one gram تمام؟ المفروض انها تكون مقاربة ل one
+
+727
+00:53:08,470 --> 00:53:13,310
+gram او .. او يعني exactly one gramطبعا فعشان ان
+
+728
+00:53:13,310 --> 00:53:16,130
+احنا عندنا درجة الحرارة و الدغط الجوي و ال
+
+729
+00:53:16,130 --> 00:53:21,070
+humidity متغيرة فانا بروح بدرب الوزن هذه تبعتي بال
+
+730
+00:53:21,070 --> 00:53:25,390
+Z factor و في جدول في اخر ال .. ال .. ال slide
+
+731
+00:53:25,390 --> 00:53:29,590
+بعلمني كيف انا اختار ال Z factor المناسب اللي بدي
+
+732
+00:53:29,590 --> 00:53:36,880
+ادرب في القراءات تبعتي طبعا فإذا ال ..الحجم هي هنا
+
+733
+00:53:36,880 --> 00:53:41,300
+مثلا إيش بلزمني sorry إيش بلزمني لأ التجربة تبعتي؟
+
+734
+00:53:41,300 --> 00:53:46,100
+بلزمني by bit و tip بلزمني beaker أو cup لحتى أحطه
+
+735
+00:53:46,100 --> 00:53:49,220
+على الميزان و أصفر عليه تمام؟ بلزمني distilled
+
+736
+00:53:49,220 --> 00:53:54,260
+water بلزمني أقيس درجة الحرارة و ميزان و أقيس ال
+
+737
+00:53:54,260 --> 00:54:00,850
+pressure الدغط عشان أطلع z factorأول إشي بدي أقيس
+
+738
+00:54:00,850 --> 00:54:07,510
+درجة حرارة الماء و أسجلها بعد هيك باستخدام beaker
+
+739
+00:54:07,510 --> 00:54:10,950
+طبعا انه انا بدي أحطه على ال .. طبعا مش راح أقرأ
+
+740
+00:54:10,950 --> 00:54:18,900
+كل الخطوات هايراح اختصرها باستخدام ال beaker او ال
+
+741
+00:54:18,900 --> 00:54:23,080
+cup راح احطه على ال analytical balance و راح هصفر
+
+742
+00:54:23,080 --> 00:54:27,080
+عليه طبعا دي خلي ا .. ا .. اخلي الميزان يعتبر ان
+
+743
+00:54:27,080 --> 00:54:32,040
+وزن ال cup هذا zero طبعابعد هيك بدي أعمل pre ..
+
+744
+00:54:32,040 --> 00:54:35,520
+بدي أركب تب للبيبط و بعد ما أكون أنا حددت الحجم
+
+745
+00:54:35,520 --> 00:54:40,840
+المناسب لإلها اللي هو one ml يعني الف microliter و
+
+746
+00:54:40,840 --> 00:54:44,940
+بعد هيك بدي أعمل pre-rinsing عرفنا إيش يعني pre
+
+747
+00:54:44,940 --> 00:54:49,040
+-rinsing يعني أنا بدي أسحب أسبيرات and spins يعني
+
+748
+00:54:49,040 --> 00:54:53,640
+بدي أسحب و أتخلص من الحجم على أساس ممكن أعيد هذه
+
+749
+00:54:53,640 --> 00:54:56,860
+الخطوة تلت مرات على أساس أتأكد أنه ال .. ال ..
+
+750
+00:54:56,860 --> 00:54:59,580
+التب صارت مبللة من الداخل يعني مش هيكون في عندى لا
+
+751
+00:54:59,580 --> 00:55:05,320
+.. لا فقطولا error في ال volume تمامو بعد هيك إيش
+
+752
+00:55:05,320 --> 00:55:09,880
+بدي أعمل؟ بدي أضغط على ال .. ال .. ال .. ال .. ال
+
+753
+00:55:09,880 --> 00:55:11,120
+.. ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال ..
+
+754
+00:55:11,120 --> 00:55:11,380
+ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال
+
+755
+00:55:11,380 --> 00:55:11,580
+.. ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال ..
+
+756
+00:55:11,580 --> 00:55:13,040
+ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال
+
+757
+00:55:13,040 --> 00:55:13,160
+.. ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال ..
+
+758
+00:55:13,160 --> 00:55:13,660
+ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال
+
+759
+00:55:13,660 --> 00:55:14,400
+ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال
+
+760
+00:55:14,400 --> 00:55:21,420
+.. ال .. ال ..
+
+761
+00:55:21,420 --> 00:55:21,440
+ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال
+
+762
+00:55:21,440 --> 00:55:25,140
+.. ال ..
+
+763
+00:55:34,190 --> 00:55:40,910
+عشان السائل يفوت داخل التب أيضا بشكل متأني يعني
+
+764
+00:55:40,910 --> 00:55:44,210
+انه مايصير فيه اندفاع لا solution و هي air bubble
+
+765
+00:55:44,210 --> 00:55:48,260
+و المشاكل اللي ممكن تحدث في البيت انجلتمام؟ هيك
+
+766
+00:55:48,260 --> 00:55:51,980
+أنا أخدت الحجم اللي بدياه بروح بفضيه في ال beaker
+
+767
+00:55:51,980 --> 00:55:55,340
+أو ال cup اللي موجود على الميزان و باخد القراءة
+
+768
+00:55:55,340 --> 00:55:59,760
+تمام؟ بعد هيك ممكن أنا أرجع أصفر على ال cup و ال
+
+769
+00:55:59,760 --> 00:56:03,420
+.. ال volume اللي موجود فيه أو أن أنا أستخدم cup
+
+770
+00:56:03,420 --> 00:56:08,100
+جديد إيه للخيار؟بسفر و بعيد الخطوة مرة تانية باخد
+
+771
+00:56:08,100 --> 00:56:13,560
+one amal بالبيبت و بفضيه و باخد كمان وزنة و كمان
+
+772
+00:56:13,560 --> 00:56:17,340
+مرة تالتة باخد one amal و بفضيه في الميزان و باخد
+
+773
+00:56:17,340 --> 00:56:22,320
+وزنة تالتة فإذا صار في عندي تلت وزنات لتلت حجوم
+
+774
+00:56:22,320 --> 00:56:25,400
+تمام فإيش بدي أعمل في التلت وزنات هدول؟ بدي أجيب
+
+775
+00:56:25,400 --> 00:56:28,740
+ال average تبعهم يعني بدي أجيب مجموعهم على تلتة
+
+776
+00:56:29,100 --> 00:56:34,400
+تمام؟ ال .. هذه ال ..ش اسمه؟ ال .. يعني تكملت
+
+777
+00:56:34,400 --> 00:56:37,220
+التجربة اللي انا حكيتها يعني انه .. انه عيدي
+
+778
+00:56:37,220 --> 00:56:41,380
+الخطوات تلت مرات و جيبي القراءة هي هنا مثلا
+
+779
+00:56:41,380 --> 00:56:44,340
+بيحكيلي ممكن تعديها اربعتاشر مرات حسب يعني ممكن
+
+780
+00:56:44,340 --> 00:56:48,200
+تعديها تلت مرات اربع مرات خمس مرات المهم بالنهاية
+
+781
+00:56:48,200 --> 00:56:51,640
+الوزنات اللي تطلع معاكي بدك تاخديلها average ايش
+
+782
+00:56:51,640 --> 00:56:56,440
+يعني average؟ يعني مجموعها على عددهاو اطلع قراءة
+
+783
+00:56:56,440 --> 00:56:59,680
+واحدة القراءة واحدة هي هذه اللي بدك تروحي اتعاوضي
+
+784
+00:56:59,680 --> 00:57:02,940
+فيها بالقانون ال weight او ال average of weight
+
+785
+00:57:02,940 --> 00:57:06,180
+اللي طلع معاكي و بدك تضربيه في ال z factor اللي هو
+
+786
+00:57:06,180 --> 00:57:10,980
+معامل اللي هو الحرارة و الضغط تمام اللي موجود عندك
+
+787
+00:57:10,980 --> 00:57:14,980
+و بالنهاية بحسب ال volumeانا خدت ال bybit كانت
+
+788
+00:57:14,980 --> 00:57:18,940
+بتحكيلي ان انا باخد one ml على الشاشة تبع ال bybit
+
+789
+00:57:18,940 --> 00:57:22,840
+مكتوب one ml فالمفروض ان هذا الكلام ال wet في ال
+
+790
+00:57:22,840 --> 00:57:27,020
+zip factor يكون one ml ايضا يعني او مقارب ل one ml
+
+791
+00:57:27,020 --> 00:57:34,050
+فممكن اناأطبق قوانين التحليلية يعني هي ان انا بجيب
+
+792
+00:57:34,050 --> 00:57:39,050
+ال average لقراءات الوزنة اللي هي مجموع القراءات
+
+793
+00:57:39,050 --> 00:57:43,170
+على عددها تمام ممكن اطبق ايضا احسب ال standard
+
+794
+00:57:43,170 --> 00:57:47,870
+deviation اجيب ال accuracy يعني القيمة الوزنة اللي
+
+795
+00:57:47,870 --> 00:57:50,610
+طلعت معايا و اللي المفروض تطلع مثلا طلعت معايا
+
+796
+00:57:50,610 --> 00:57:54,690
+point 999 الوزنة و المفروض انها تطلع one milligram
+
+797
+00:57:54,690 --> 00:57:58,280
+بحسبهابس شوف .. شوف نسبة ال accuracy تبعت القيمة
+
+798
+00:57:58,280 --> 00:58:02,100
+تبعتي و ال coefficient of variation اللي هي ..
+
+799
+00:58:02,100 --> 00:58:04,560
+اللي هي عبارة عن ال standard deviation على ال mean
+
+800
+00:58:04,560 --> 00:58:11,920
+ضارب 100% لازم ال accuracy هذه تطلع من 99 ل 101% و
+
+801
+00:58:11,920 --> 00:58:16,470
+لازمال coefficient of variation يكون اقل من واحد
+
+802
+00:58:16,470 --> 00:58:19,690
+في المية هذا يكون اقل من واحد في المية عشان اقول
+
+803
+00:58:19,690 --> 00:58:22,290
+ان ال by bit هذه accurate و precise و بتعطيني
+
+804
+00:58:22,290 --> 00:58:25,570
+volumes دقيقة و الحجم اللي انا باخده هو نفسه اللي
+
+805
+00:58:25,570 --> 00:58:28,990
+موجود على الشاشة و شغلها مية لمية اذا انا لما بدي
+
+806
+00:58:28,990 --> 00:58:31,930
+اجري افحصات و بدي انقل volume باستخدام هذه ال by
+
+807
+00:58:31,930 --> 00:58:36,740
+bit اذا انا عم بشتغل بشكل صحيح و بشكل دقيقطبعا هذا
+
+808
+00:58:36,740 --> 00:58:40,740
+الجدول اللى انا من خلاله بختار مثلا ال .. ال z
+
+809
+00:58:40,740 --> 00:58:45,180
+value او اللى هو معامل ال .. الحرارة و الضغط طبعا
+
+810
+00:58:45,180 --> 00:58:47,980
+ال z value مثلا انا بشوف ايش الضغط اللى موجود عندى
+
+811
+00:58:47,980 --> 00:58:50,040
+حسب المنطقة اللى انا .. اللى انا فيها لان افرض
+
+812
+00:58:50,040 --> 00:58:54,620
+مثلا ان انا موجودة في منطقة ضغطها الف و ست .. سبعة
+
+813
+00:58:54,620 --> 00:58:59,420
+و ستين ملي بار طبعاو درجة الحرارة عندي خمسة و
+
+814
+00:58:59,420 --> 00:59:04,240
+عشرين فبروح هنا هي خمسة و عشرين بمشي لعند مين لعند
+
+815
+00:59:04,240 --> 00:59:08,100
+ال .. ال .. ال .. المنطقة اللي هي ال .. اللي فيها
+
+816
+00:59:08,100 --> 00:59:11,600
+الضغط تبعي تمام؟ اللي فيها الضغط تبعي هنا هيك هي
+
+817
+00:59:11,600 --> 00:59:15,480
+هذه القيمة تقاطع درجة الحرارة اللي بديها مع الضغط
+
+818
+00:59:15,480 --> 00:59:18,480
+اللي .. اللي بديها هي هذه قيمة ال Z factor اللي
+
+819
+00:59:18,480 --> 00:59:22,300
+بروح ب .. ب .. أطبق فيهاتمام هي هذه قيمة ال z
+
+820
+00:59:22,300 --> 00:59:26,060
+factor اللي بروح بطبق فيها و بحسب حسابات تبعتي زي
+
+821
+00:59:26,060 --> 00:59:29,820
+ما حكينا لو انا عديت التجربة مرة مرتين تلاتة اربع
+
+822
+00:59:29,820 --> 00:59:34,900
+عشرة و حصلت على مثلا عشر قيم باخد ال average تبعهم
+
+823
+00:59:34,900 --> 00:59:39,100
+بدربهم بال z factor بحصل على ال volume و بطبق في
+
+824
+00:59:39,100 --> 00:59:43,180
+القوانين تبعتي القيمة اللي انا جستها على القيمة
+
+825
+00:59:43,180 --> 00:59:46,570
+اللي المفروض تطلعضرب 100% بحسب ال accuracy بحسب ال
+
+826
+00:59:46,570 --> 00:59:50,450
+coefficient of variation بشوف نسبة دقة و صحة ال ..
+
+827
+00:59:50,450 --> 00:59:54,070
+ال vibe بتاعي و بحكم على شغلها و هل انها محتاجة
+
+828
+00:59:54,070 --> 01:00:00,690
+انها يتم تصليحها او انه لأ مناسبة و تستخدم يعني
+
+829
+01:00:00,690 --> 01:00:05,350
+موثوقة للاستخدام تمام؟بهيك بنكون خلصنا محاضرتنا
+
+830
+01:00:05,350 --> 01:00:10,030
+لليوم ان شاء الله تكون هيك الاشياء واضحة حولت ان
+
+831
+01:00:10,030 --> 01:00:15,350
+انا اورجيكم صور اورجيكم فيديو لكيف ال by بتاعي كنت
+
+832
+01:00:15,350 --> 01:00:18,810
+نستخدمها و تعليمات اللي بنتابعها أثناء ال by
+
+833
+01:00:18,810 --> 01:00:25,490
+bettingلعسى انه يعني تكون الاشي مش مبهم لقلكم لإنه
+
+834
+01:00:25,490 --> 01:00:29,810
+يعني احنا مقدرين انه بداية التخصص لازم تكون ..
+
+835
+01:00:29,810 --> 01:00:35,650
+تكون يعني كل إشي سهل ومستثار لحتى تتمكنوا من الفهم
+
+836
+01:00:35,650 --> 01:00:40,430
+المعلومة وإدراكها يعطيكم ألف عافية وشكرا لكم
+
diff --git a/PL9fwy3NUQKwY9jl8xw-bWkVZkWcGGyspd/pYa8qDaMM00_raw.json b/PL9fwy3NUQKwY9jl8xw-bWkVZkWcGGyspd/pYa8qDaMM00_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..b73dee78f8cd98a40bd30db62d3b3ec47f0a9b11
--- /dev/null
+++ b/PL9fwy3NUQKwY9jl8xw-bWkVZkWcGGyspd/pYa8qDaMM00_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 2497, "start": 3.93, "end": 24.97, "text": "السلام عليكم ورحمة الله وبركاته طالبات العزيزات اليوم ان شاء الله رح نشرح محاضرة بعنوان calorie meter or photometer في البداية ماذا يعني calorie meter? color معناها لون تمام؟ meter قياس إذا قياس شدة اللون أو photometer photo معناها ضوء", "tokens": [6027, 3794, 37440, 25894, 24793, 4032, 2288, 35571, 3660, 21984, 4032, 26890, 4117, 9307, 3224, 23032, 6027, 3555, 9307, 18863, 11622, 1829, 11622, 9307, 45595, 20498, 16472, 13412, 16606, 21984, 12602, 5016, 8717, 46309, 5016, 3714, 5016, 46958, 25720, 45030, 1863, 2407, 7649, 35004, 9255, 420, 2409, 13606, 8978, 29739, 28259, 10632, 3714, 45636, 995, 37495, 22653, 35004, 9255, 30, 2017, 20449, 8315, 11296, 5296, 11536, 46811, 10943, 22807, 9255, 12174, 25528, 3794, 11933, 15730, 12174, 25528, 3794, 13412, 41891, 13672, 11536, 34051, 2409, 13606, 5052, 20449, 8315, 11296, 48812, 2407, 38207], "avg_logprob": -0.12415995072293025, "compression_ratio": 1.7655502392344498, "no_speech_prob": 8.046627044677734e-06, "words": [{"start": 3.93, "end": 4.39, "word": "السلام", "probability": 0.8312174479166666}, {"start": 4.39, "end": 4.79, "word": " عليكم", "probability": 0.95263671875}, {"start": 4.79, "end": 5.17, "word": " ورحمة", "probability": 0.9014892578125}, {"start": 5.17, "end": 5.37, "word": " الله", "probability": 0.974609375}, {"start": 5.37, "end": 6.05, "word": " وبركاته", "probability": 0.99140625}, {"start": 6.05, "end": 6.81, "word": " طالبات", "probability": 0.9813232421875}, {"start": 6.81, "end": 7.41, "word": " العزيزات", "probability": 0.98974609375}, {"start": 7.41, "end": 7.79, "word": " اليوم", "probability": 0.9287109375}, {"start": 7.79, "end": 7.93, "word": " ان", "probability": 0.78125}, {"start": 7.93, "end": 8.09, "word": " شاء", "probability": 0.9833984375}, {"start": 8.09, "end": 8.21, "word": " الله", "probability": 0.9580078125}, {"start": 8.21, "end": 8.41, "word": " رح", "probability": 0.7578125}, 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15.53, "word": " meter?", "probability": 0.82470703125}, {"start": 15.65, "end": 15.95, "word": " color", "probability": 0.63232421875}, {"start": 15.95, "end": 16.77, "word": " معناها", "probability": 0.978515625}, {"start": 16.77, "end": 17.47, "word": " لون", "probability": 0.971923828125}, {"start": 17.47, "end": 18.73, "word": " تمام؟", "probability": 0.619140625}, {"start": 18.73, "end": 19.13, "word": " meter", "probability": 0.671875}, {"start": 19.13, "end": 19.69, "word": " قياس", "probability": 0.9656575520833334}, {"start": 19.69, "end": 19.89, "word": " إذا", "probability": 0.573974609375}, {"start": 19.89, "end": 20.61, "word": " قياس", "probability": 0.9619140625}, {"start": 20.61, "end": 20.99, "word": " شدة", "probability": 0.968017578125}, {"start": 20.99, "end": 21.79, "word": " اللون", "probability": 0.994140625}, {"start": 21.79, "end": 22.21, "word": " أو", "probability": 0.7265625}, {"start": 22.21, "end": 23.49, "word": " photometer", "probability": 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{"start": 50.0, "end": 50.26, "word": " calorie", "probability": 0.87109375}, {"start": 50.26, "end": 50.62, "word": " meter", "probability": 0.82666015625}, {"start": 50.62, "end": 50.82, "word": " و", "probability": 0.90185546875}, {"start": 50.82, "end": 50.98, "word": " ال", "probability": 0.8154296875}, {"start": 50.98, "end": 51.5, "word": " photometer", "probability": 0.6943359375}], "temperature": 1.0}, {"id": 3, "seek": 7303, "start": 52.45, "end": 73.03, "text": "طيب ما علاقة قياس شدة اللون أو الضوء بالتركيز راح نتعرف خلال ال slides القادمة ولكن في البداية لابد من تقديم بسيط انعرف فيه ماذا يعني photometry photo حكينا معناها ضوء متري قياس", "tokens": [9566, 1829, 3555, 19446, 11203, 995, 28671, 12174, 25528, 3794, 13412, 41891, 13672, 11536, 34051, 6024, 114, 2407, 38207, 20666, 2655, 31747, 1829, 11622, 12602, 39319, 8717, 2655, 3615, 28480, 16490, 1211, 6027, 2423, 9788, 25062, 18513, 46007, 35525, 19452, 8978, 29739, 28259, 10632, 5296, 16758, 3215, 9154, 6055, 4587, 16254, 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"end": 58.11, "word": " بالتركيز", "probability": 0.9525390625}, {"start": 58.11, "end": 58.53, "word": " راح", "probability": 0.6510009765625}, {"start": 58.53, "end": 59.01, "word": " نتعرف", "probability": 0.9932861328125}, {"start": 59.01, "end": 59.49, "word": " خلال", "probability": 0.99462890625}, {"start": 59.49, "end": 59.65, "word": " ال", "probability": 0.947265625}, {"start": 59.65, "end": 59.97, "word": " slides", "probability": 0.69580078125}, {"start": 59.97, "end": 61.93, "word": " القادمة", "probability": 0.9842122395833334}, {"start": 61.93, "end": 62.83, "word": " ولكن", "probability": 0.849365234375}, {"start": 62.83, "end": 63.01, "word": " في", "probability": 0.65283203125}, {"start": 63.01, "end": 63.67, "word": " البداية", "probability": 0.9920247395833334}, {"start": 63.67, "end": 64.31, "word": " لابد", "probability": 0.9781901041666666}, {"start": 64.31, "end": 64.55, "word": " من", "probability": 0.99755859375}, {"start": 64.55, "end": 65.07, "word": " تقديم", "probability": 0.962646484375}, {"start": 65.07, "end": 65.65, "word": " بسيط", "probability": 0.9979248046875}, {"start": 65.65, "end": 66.53, "word": " انعرف", "probability": 0.7269694010416666}, {"start": 66.53, "end": 66.89, "word": " فيه", "probability": 0.974609375}, {"start": 66.89, "end": 67.33, "word": " ماذا", "probability": 0.9443359375}, {"start": 67.33, "end": 67.63, "word": " يعني", "probability": 0.96484375}, {"start": 67.63, "end": 68.37, "word": " photometry", "probability": 0.824951171875}, {"start": 68.37, "end": 69.25, "word": " photo", "probability": 0.491943359375}, {"start": 69.25, "end": 69.89, "word": " حكينا", "probability": 0.9818115234375}, {"start": 69.89, "end": 70.97, "word": " معناها", "probability": 0.8859049479166666}, {"start": 70.97, "end": 71.57, "word": " ضوء", "probability": 0.9684244791666666}, {"start": 71.57, "end": 72.23, "word": " متري", "probability": 0.851806640625}, {"start": 72.23, "end": 73.03, "word": " قياس", "probability": 0.9791666666666666}], "temperature": 1.0}, {"id": 4, "seek": 9127, "start": 73.49, "end": 91.27, "text": "إذن photometry معناها the measurement of light قياس الضوء تمام؟ في عندي أجهزة تسمى photometer أو spectrophotometer هي عبارة عن أجهزة تعمل على مبدأ قياس الضوء the measurement of light", "tokens": [28814, 8848, 1863, 2409, 34730, 20449, 8315, 11296, 264, 13160, 295, 1442, 12174, 25528, 3794, 6024, 114, 2407, 38207, 46811, 10943, 22807, 8978, 18871, 16254, 5551, 7435, 3224, 11622, 3660, 6055, 38251, 7578, 2409, 13606, 34051, 6177, 11741, 310, 13606, 39896, 6225, 3555, 9640, 3660, 18871, 5551, 7435, 3224, 11622, 3660, 6055, 25957, 1211, 15844, 3714, 44510, 10721, 12174, 25528, 3794, 6024, 114, 2407, 38207, 264, 13160, 295, 1442], "avg_logprob": -0.1041852714759963, "compression_ratio": 1.5609756097560976, "no_speech_prob": 1.1920928955078125e-07, "words": [{"start": 73.49, "end": 74.01, "word": "إذن", "probability": 0.6382649739583334}, {"start": 74.01, "end": 75.07, "word": " photometry", "probability": 0.6954345703125}, {"start": 75.07, "end": 75.77, "word": " معناها", "probability": 0.9842122395833334}, {"start": 75.77, "end": 76.29, "word": " the", "probability": 0.716796875}, {"start": 76.29, "end": 76.79, "word": " measurement", "probability": 0.82958984375}, {"start": 76.79, "end": 77.13, "word": " of", "probability": 0.98828125}, {"start": 77.13, "end": 77.57, "word": " light", "probability": 0.8974609375}, {"start": 77.57, "end": 78.65, "word": " قياس", "probability": 0.8907877604166666}, {"start": 78.65, "end": 79.35, "word": " الضوء", "probability": 0.938720703125}, {"start": 79.35, "end": 80.31, "word": " تمام؟", "probability": 0.7970377604166666}, {"start": 80.31, "end": 80.43, "word": " في", "probability": 0.84912109375}, {"start": 80.43, "end": 80.73, "word": " عندي", "probability": 0.908447265625}, {"start": 80.73, "end": 81.55, "word": " أجهزة", "probability": 0.9880859375}, {"start": 81.55, "end": 82.69, "word": " تسمى", "probability": 0.9690755208333334}, {"start": 82.69, "end": 83.69, "word": " photometer", "probability": 0.828857421875}, {"start": 83.69, "end": 84.05, "word": " أو", "probability": 0.69287109375}, {"start": 84.05, "end": 85.51, "word": " spectrophotometer", "probability": 0.94384765625}, {"start": 85.51, "end": 86.11, "word": " هي", "probability": 0.85107421875}, {"start": 86.11, "end": 86.89, "word": " عبارة", "probability": 0.9989013671875}, {"start": 86.89, "end": 87.17, "word": " عن", "probability": 0.99560546875}, {"start": 87.17, "end": 87.93, "word": " أجهزة", "probability": 0.9955078125}, {"start": 87.93, "end": 88.45, "word": " تعمل", "probability": 0.9241536458333334}, {"start": 88.45, "end": 88.67, "word": " على", "probability": 0.9296875}, {"start": 88.67, "end": 89.09, "word": " مبدأ", "probability": 0.9607747395833334}, {"start": 89.09, "end": 89.59, "word": " قياس", "probability": 0.9915364583333334}, {"start": 89.59, "end": 90.03, "word": " الضوء", "probability": 0.9840087890625}, {"start": 90.03, "end": 90.23, "word": " the", "probability": 0.65625}, {"start": 90.23, "end": 90.59, "word": " measurement", "probability": 0.865234375}, {"start": 90.59, "end": 90.91, "word": " of", "probability": 0.98291015625}, {"start": 90.91, "end": 91.27, "word": " light", "probability": 0.8935546875}], "temperature": 1.0}, {"id": 5, "seek": 11119, "start": 91.81, "end": 111.19, "text": "و هذه الأجهزة they are instruments used to detect the measurement أو to detect the concentration و هذه الأجهزة يوجد فيها أدوات أو أداة تسمى photocell أو photo multiplier tube", "tokens": [2407, 29538, 16247, 7435, 3224, 11622, 3660, 436, 366, 12190, 1143, 281, 5531, 264, 13160, 34051, 281, 5531, 264, 9856, 4032, 29538, 16247, 7435, 3224, 11622, 3660, 7251, 29245, 3215, 8978, 11296, 5551, 3215, 2407, 9307, 34051, 5551, 28259, 3660, 6055, 38251, 7578, 5052, 4164, 34051, 5052, 44106, 9917], "avg_logprob": -0.14718749552965163, "compression_ratio": 1.457516339869281, "no_speech_prob": 0.0, "words": 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"probability": 0.896484375}, {"start": 100.75, "end": 101.17, "word": " detect", "probability": 0.986328125}, {"start": 101.17, "end": 101.37, "word": " the", "probability": 0.90283203125}, {"start": 101.37, "end": 102.25, "word": " concentration", "probability": 0.89111328125}, {"start": 102.25, "end": 102.99, "word": " و", "probability": 0.82568359375}, {"start": 102.99, "end": 103.47, "word": " هذه", "probability": 0.95361328125}, {"start": 103.47, "end": 104.25, "word": " الأجهزة", "probability": 0.99814453125}, {"start": 104.25, "end": 104.87, "word": " يوجد", "probability": 0.9749348958333334}, {"start": 104.87, "end": 105.39, "word": " فيها", "probability": 0.992431640625}, {"start": 105.39, "end": 106.13, "word": " أدوات", "probability": 0.96435546875}, {"start": 106.13, "end": 106.31, "word": " أو", "probability": 0.76953125}, {"start": 106.31, "end": 106.99, "word": " أداة", "probability": 0.8025716145833334}, {"start": 106.99, "end": 107.71, "word": " تسمى", "probability": 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"probability": 0.966796875}, {"start": 115.54, "end": 116.3, "word": " خصائصها", "probability": 0.9916015625}, {"start": 116.3, "end": 116.82, "word": " إنه", "probability": 0.5982666015625}, {"start": 116.82, "end": 117.4, "word": " لديها", "probability": 0.9583333333333334}, {"start": 117.4, "end": 118.04, "word": " القدرة", "probability": 0.9763997395833334}, {"start": 118.04, "end": 118.3, "word": " على", "probability": 0.63427734375}, {"start": 118.3, "end": 118.64, "word": " إنها", "probability": 0.9287109375}, {"start": 118.64, "end": 119.22, "word": " تقيس", "probability": 0.8509114583333334}, {"start": 119.22, "end": 119.88, "word": " كمية", "probability": 0.9931640625}, {"start": 119.88, "end": 120.46, "word": " الضوء", "probability": 0.9722900390625}, {"start": 120.46, "end": 121.16, "word": " الواصلة", "probability": 0.88330078125}, {"start": 121.16, "end": 121.84, "word": " إليها", "probability": 0.9539388020833334}, {"start": 121.84, "end": 122.6, "word": " بعد", "probability": 0.96875}, {"start": 122.6, "end": 123.54, "word": " مرورها", "probability": 0.9769287109375}, {"start": 123.54, "end": 124.6, "word": " بمحلول", "probability": 0.99150390625}, {"start": 124.6, "end": 125.46, "word": " ملون،", "probability": 0.8277587890625}, {"start": 125.46, "end": 126.24, "word": " تمام؟", "probability": 0.84521484375}, {"start": 126.24, "end": 126.6, "word": " فإذا", "probability": 0.9816080729166666}, {"start": 126.6, "end": 126.96, "word": " كان", "probability": 0.95703125}, {"start": 126.96, "end": 127.1, "word": " في", "probability": 0.78125}, {"start": 127.1, "end": 127.54, "word": " عندي", "probability": 0.79248046875}, {"start": 127.54, "end": 128.28, "word": " محلول", "probability": 0.994873046875}, {"start": 128.28, "end": 128.88, "word": " ملون", "probability": 0.9905598958333334}], "temperature": 1.0}, {"id": 7, "seek": 14421, "start": 129.39, "end": 144.21, "text": "و .. او يعني reaction حدث نتيجة مثلا ال combination الإضافة ما بين ال sample و ال reagent حكينا ال reagent هو عبارة عن إيش؟ هو عبارة عن محلول بيعمللي measurable change", "tokens": [2407, 4386, 1975, 2407, 37495, 22653, 5480, 11331, 3215, 12984, 8717, 31371, 7435, 3660, 50113, 15040, 2423, 6562, 33688, 11242, 31845, 3660, 19446, 49374, 2423, 6889, 4032, 2423, 26949, 317, 11331, 4117, 1829, 8315, 2423, 26949, 317, 31439, 6225, 3555, 9640, 3660, 18871, 11933, 1829, 8592, 22807, 31439, 6225, 3555, 9640, 3660, 18871, 3714, 5016, 1211, 12610, 4724, 1829, 25957, 1211, 20292, 43615, 1319], "avg_logprob": -0.09915865384615384, "compression_ratio": 1.4470588235294117, "no_speech_prob": 2.3245811462402344e-06, "words": [{"start": 129.39, "end": 129.69, "word": "و", "probability": 0.88330078125}, {"start": 129.69, "end": 129.87, "word": " ..", "probability": 0.90283203125}, {"start": 129.87, "end": 130.21, "word": " او", "probability": 0.786376953125}, {"start": 130.21, "end": 130.69, "word": " يعني", "probability": 0.970703125}, {"start": 130.69, "end": 131.49, "word": " reaction", "probability": 0.9609375}, {"start": 131.49, "end": 132.67, "word": " حدث", "probability": 0.9912109375}, {"start": 132.67, "end": 134.03, "word": " نتيجة", "probability": 0.9847412109375}, {"start": 134.03, "end": 134.43, "word": " مثلا", "probability": 0.9853515625}, {"start": 134.43, "end": 134.77, "word": " ال", "probability": 0.98046875}, {"start": 134.77, "end": 135.25, "word": " combination", "probability": 0.95654296875}, {"start": 135.25, "end": 136.25, "word": " الإضافة", "probability": 0.83929443359375}, {"start": 136.25, "end": 136.39, "word": " ما", "probability": 0.94970703125}, {"start": 136.39, "end": 136.69, "word": " بين", "probability": 0.98095703125}, {"start": 136.69, "end": 136.89, "word": " ال", "probability": 0.98974609375}, {"start": 136.89, "end": 137.49, "word": " sample", "probability": 0.81640625}, {"start": 137.49, "end": 137.79, "word": " و", "probability": 0.6494140625}, {"start": 137.79, "end": 137.87, "word": " ال", "probability": 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{"start": 142.39, "end": 143.09, "word": " بيعمللي", "probability": 0.834033203125}, {"start": 143.09, "end": 143.61, "word": " measurable", "probability": 0.955078125}, {"start": 143.61, "end": 144.21, "word": " change", "probability": 0.8427734375}], "temperature": 1.0}, {"id": 8, "seek": 17084, "start": 145.16, "end": 170.84, "text": "تغير يمكن قياسه و هي على أغلب التغيرات ممكن تكون تغير في اللون طبعا فإذا نتيجة reaction معين ما بين ال sample و ال reagent نتج colored solution نتج محلول ملون هذا المحلول إذا مر من خلاله ضوء فإن جزء من هذا الضوء اللي مر أو اصطدم بهذا المحلول", "tokens": [2655, 17082, 13546, 7251, 43020, 12174, 25528, 3794, 3224, 4032, 39896, 15844, 5551, 17082, 46152, 16712, 17082, 13546, 9307, 3714, 43020, 6055, 30544, 6055, 17082, 13546, 8978, 13672, 11536, 23032, 3555, 3615, 995, 6156, 28814, 15730, 8717, 31371, 7435, 3660, 5480, 20449, 9957, 19446, 49374, 2423, 6889, 4032, 2423, 26949, 317, 8717, 2655, 7435, 14332, 3827, 8717, 2655, 7435, 3714, 5016, 1211, 12610, 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{"start": 154.46, "end": 154.68, "word": " بين", "probability": 0.93994140625}, {"start": 154.68, "end": 154.88, "word": " ال", "probability": 0.92724609375}, {"start": 154.88, "end": 155.2, "word": " sample", "probability": 0.85546875}, {"start": 155.2, "end": 155.44, "word": " و", "probability": 0.85546875}, {"start": 155.44, "end": 155.54, "word": " ال", "probability": 0.74267578125}, {"start": 155.54, "end": 156.02, "word": " reagent", "probability": 0.805419921875}, {"start": 156.02, "end": 157.0, "word": " نتج", "probability": 0.9319661458333334}, {"start": 157.0, "end": 157.64, "word": " colored", "probability": 0.580078125}, {"start": 157.64, "end": 158.28, "word": " solution", "probability": 0.96337890625}, {"start": 158.28, "end": 158.88, "word": " نتج", "probability": 0.77880859375}, {"start": 158.88, "end": 159.94, "word": " محلول", "probability": 0.9857177734375}, {"start": 159.94, "end": 160.76, "word": " ملون", "probability": 0.9640299479166666}, {"start": 160.76, "end": 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اللي", "probability": 0.603759765625}, {"start": 168.72, "end": 169.08, "word": " مر", "probability": 0.947998046875}, {"start": 169.08, "end": 169.26, "word": " أو", "probability": 0.68017578125}, {"start": 169.26, "end": 169.7, "word": " اصطدم", "probability": 0.8218994140625}, {"start": 169.7, "end": 170.18, "word": " بهذا", "probability": 0.972900390625}, {"start": 170.18, "end": 170.84, "word": " المحلول", "probability": 0.9947509765625}], "temperature": 1.0}, {"id": 9, "seek": 18942, "start": 171.38, "end": 189.42, "text": "جزء من هذا الضوء يتبدد ويتلاشى أو يتم انتصاصه من قبل المحلول الملون والجزء الآخر ينفذ هذا الجزء النافذ يصل إلى أداة في الجهاز اسمها photocell أو photo multiplier tube", "tokens": [7435, 11622, 38207, 9154, 23758, 6024, 114, 2407, 38207, 7251, 2655, 44510, 3215, 4032, 36081, 1211, 33599, 7578, 34051, 7251, 39237, 16472, 2655, 9381, 33546, 3224, 9154, 12174, 36150, 9673, 5016, 1211, 12610, 9673, 1211, 11536, 16070, 7435, 11622, 38207, 6024, 95, 34740, 7251, 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175.98, "word": " انتصاصه", "probability": 0.93603515625}, {"start": 175.98, "end": 176.42, "word": " من", "probability": 0.9892578125}, {"start": 176.42, "end": 176.78, "word": " قبل", "probability": 0.91650390625}, {"start": 176.78, "end": 177.42, "word": " المحلول", "probability": 0.9940185546875}, {"start": 177.42, "end": 177.96, "word": " الملون", "probability": 0.9793294270833334}, {"start": 177.96, "end": 179.3, "word": " والجزء", "probability": 0.929931640625}, {"start": 179.3, "end": 180.02, "word": " الآخر", "probability": 0.8411458333333334}, {"start": 180.02, "end": 180.92, "word": " ينفذ", "probability": 0.987060546875}, {"start": 180.92, "end": 181.74, "word": " هذا", "probability": 0.76220703125}, {"start": 181.74, "end": 182.26, "word": " الجزء", "probability": 0.9903971354166666}, {"start": 182.26, "end": 183.08, "word": " النافذ", "probability": 0.9136962890625}, {"start": 183.08, "end": 183.74, "word": " يصل", "probability": 0.983154296875}, {"start": 183.74, "end": 184.12, "word": " إلى", "probability": 0.81201171875}, {"start": 184.12, "end": 184.58, "word": " أداة", "probability": 0.9461263020833334}, {"start": 184.58, "end": 184.66, "word": " في", "probability": 0.962890625}, {"start": 184.66, "end": 185.26, "word": " الجهاز", "probability": 0.9840494791666666}, {"start": 185.26, "end": 185.8, "word": " اسمها", "probability": 0.95654296875}, {"start": 185.8, "end": 186.82, "word": " photocell", "probability": 0.51123046875}, {"start": 186.82, "end": 187.42, "word": " أو", "probability": 0.5478515625}, {"start": 187.42, "end": 188.2, "word": " photo", "probability": 0.728515625}, {"start": 188.2, "end": 188.88, "word": " multiplier", "probability": 0.861328125}, {"start": 188.88, "end": 189.42, "word": " tube", "probability": 0.900390625}], "temperature": 1.0}, {"id": 10, "seek": 21584, "start": 190.4, "end": 215.84, "text": "هى اللى بتقيسلى كمية الضوء اللى واصلة إليها و بالنهاية بتعبرلى عن تركيز المحلول الملون تمام؟ بتعبرلى عن تركيز المحلول الملون خلينا بس لحتى نقرب الفكرة نحكي عن هذا الموضوع هى هنا مثلا فى عندي light", "tokens": [3224, 7578, 13672, 7578, 39894, 38436, 3794, 23942, 9122, 2304, 10632, 6024, 114, 2407, 38207, 13672, 7578, 4032, 33546, 37977, 11933, 20292, 11296, 4032, 20666, 1863, 11296, 10632, 39894, 3615, 26890, 23942, 18871, 6055, 31747, 1829, 11622, 9673, 5016, 1211, 12610, 9673, 1211, 11536, 46811, 10943, 22807, 39894, 3615, 26890, 23942, 18871, 6055, 31747, 1829, 11622, 9673, 5016, 1211, 12610, 9673, 1211, 11536, 16490, 1211, 9957, 995, 4724, 3794, 5296, 33753, 7578, 8717, 4587, 25513, 27188, 4117, 25720, 8717, 5016, 4117, 1829, 18871, 23758, 9673, 2407, 11242, 45367, 8032, 7578, 34105, 50113, 15040, 6156, 7578, 18871, 16254, 1442], "avg_logprob": -0.11426767390785796, "compression_ratio": 1.9664804469273742, "no_speech_prob": 1.7881393432617188e-06, "words": [{"start": 190.4, "end": 190.86, "word": "هى", "probability": 0.8134765625}, {"start": 190.86, "end": 191.06, "word": " اللى", "probability": 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0.9920654296875}, {"start": 197.68, "end": 198.2, "word": " الملون", "probability": 0.93701171875}, {"start": 198.2, "end": 199.54, "word": " تمام؟", "probability": 0.6798502604166666}, {"start": 199.54, "end": 200.08, "word": " بتعبرلى", "probability": 0.9447021484375}, {"start": 200.08, "end": 200.26, "word": " عن", "probability": 0.98876953125}, {"start": 200.26, "end": 200.6, "word": " تركيز", "probability": 0.9951171875}, {"start": 200.6, "end": 201.16, "word": " المحلول", "probability": 0.997314453125}, {"start": 201.16, "end": 201.78, "word": " الملون", "probability": 0.9949544270833334}, {"start": 201.78, "end": 202.94, "word": " خلينا", "probability": 0.712890625}, {"start": 202.94, "end": 203.24, "word": " بس", "probability": 0.98583984375}, {"start": 203.24, "end": 203.92, "word": " لحتى", "probability": 0.9251302083333334}, {"start": 203.92, "end": 204.92, "word": " نقرب", "probability": 0.9332682291666666}, {"start": 204.92, "end": 205.6, "word": " الفكرة", "probability": 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الضوء تم امتصاصه فقدانه او تلاشيه عبر المحلول تمام او من خلال المحلول داخل المحلول تم امتصاصه", "tokens": [11242, 2407, 38207, 3714, 9381, 3215, 2288, 48812, 2407, 38207, 23032, 3555, 3615, 995, 1975, 9381, 9566, 40448, 4724, 7649, 3555, 37746, 8978, 11296, 3714, 5016, 1211, 12610, 3714, 1211, 11536, 46811, 10943, 1975, 9381, 9566, 40448, 4724, 7649, 3555, 37746, 8978, 11296, 3714, 5016, 1211, 12610, 3714, 1211, 11536, 10874, 11622, 38207, 9154, 23758, 6024, 114, 2407, 38207, 46811, 1975, 2304, 2655, 9381, 33546, 3224, 6156, 28543, 7649, 3224, 1975, 2407, 6055, 1211, 33599, 1829, 3224, 6225, 26890, 9673, 5016, 1211, 12610, 46811, 10943, 1975, 2407, 9154, 16490, 1211, 6027, 9673, 5016, 1211, 12610, 11778, 47283, 1211, 9673, 5016, 1211, 12610, 46811, 1975, 2304, 2655, 9381, 33546, 3224], "avg_logprob": -0.1071022752333771, "compression_ratio": 2.210526315789474, "no_speech_prob": 1.0728836059570312e-06, "words": [{"start": 216.61, "end": 217.09, "word": "ضوء", "probability": 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{"start": 233.23, "end": 233.95, "word": " المحلول", "probability": 0.99609375}, {"start": 233.95, "end": 234.59, "word": " تمام", "probability": 0.766845703125}, {"start": 234.59, "end": 234.79, "word": " او", "probability": 0.912353515625}, {"start": 234.79, "end": 234.95, "word": " من", "probability": 0.9912109375}, {"start": 234.95, "end": 235.39, "word": " خلال", "probability": 0.9947916666666666}, {"start": 235.39, "end": 236.07, "word": " المحلول", "probability": 0.9947509765625}, {"start": 236.07, "end": 236.53, "word": " داخل", "probability": 0.8214518229166666}, {"start": 236.53, "end": 237.03, "word": " المحلول", "probability": 0.996826171875}, {"start": 237.03, "end": 237.27, "word": " تم", "probability": 0.994140625}, {"start": 237.27, "end": 238.05, "word": " امتصاصه", "probability": 0.987548828125}], "temperature": 1.0}, {"id": 12, "seek": 26307, "start": 238.73, "end": 263.07, "text": "والجزء الأخر نفذ تمام؟ هذا الجزء النافذ هو الذي يصل إلى أداة ال photocell أو ال photo multiplier tube في جهاز ال photo meter أو ال spectrophotometer وبيعبرلي عن تركيز المحلول كيف يعبر عن تركيز المحلول؟ ببساطة لإنه", "tokens": [2407, 6027, 7435, 11622, 38207, 16247, 34740, 8717, 5172, 8848, 46811, 10943, 22807, 23758, 25724, 11622, 38207, 2423, 8315, 5172, 8848, 31439, 43527, 7251, 36520, 30731, 5551, 28259, 3660, 2423, 5052, 4164, 34051, 2423, 5052, 44106, 9917, 8978, 10874, 3224, 31377, 2423, 5052, 9255, 34051, 2423, 6177, 11741, 310, 13606, 4032, 21292, 3615, 26890, 20292, 18871, 6055, 31747, 1829, 11622, 9673, 5016, 1211, 12610, 9122, 33911, 37495, 26890, 18871, 6055, 31747, 1829, 11622, 9673, 5016, 1211, 12610, 22807, 4724, 3555, 3794, 41193, 3660, 5296, 28814, 1863, 3224], "avg_logprob": -0.1332563983107155, "compression_ratio": 1.6954314720812182, "no_speech_prob": 8.165836334228516e-06, "words": [{"start": 238.73, "end": 239.45, "word": "والجزء", "probability": 0.93564453125}, {"start": 239.45, "end": 240.17, "word": " الأخر", "probability": 0.721923828125}, 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{"start": 564.22, "end": 564.52, "word": " many", "probability": 0.9189453125}, {"start": 564.52, "end": 564.88, "word": " shades", "probability": 0.90625}, {"start": 564.88, "end": 565.1, "word": " of", "probability": 0.98291015625}, {"start": 565.1, "end": 565.44, "word": " color", "probability": 0.8876953125}, {"start": 565.44, "end": 566.04, "word": " إيش", "probability": 0.7782389322916666}, {"start": 566.04, "end": 566.36, "word": " معنى", "probability": 0.8509114583333334}, {"start": 566.36, "end": 566.6, "word": " هذه", "probability": 0.54638671875}, {"start": 566.6, "end": 567.16, "word": " الجملة؟", "probability": 0.9617919921875}], "temperature": 1.0}, {"id": 27, "seek": 58748, "start": 567.2, "end": 587.48, "text": "حكينا إنه المحلول اللي يبدو ملونا تمام colored solution absorb light يمتص الضوء على طول موجي معين ويعكس أو ينفذ من خلاله الضوء الآخر أو ما تبقى the other parts ما تبقى من هذا الضوء", "tokens": [5016, 4117, 1829, 8315, 36145, 3224, 9673, 5016, 1211, 12610, 13672, 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570.72, "end": 571.56, "word": " ملونا", "probability": 0.843505859375}, {"start": 571.56, "end": 572.28, "word": " تمام", "probability": 0.9521484375}, {"start": 572.28, "end": 572.98, "word": " colored", "probability": 0.1617431640625}, {"start": 572.98, "end": 574.26, "word": " solution", "probability": 0.5}, {"start": 574.26, "end": 574.96, "word": " absorb", "probability": 0.70751953125}, {"start": 574.96, "end": 575.58, "word": " light", "probability": 0.92578125}, {"start": 575.58, "end": 576.16, "word": " يمتص", "probability": 0.8675537109375}, {"start": 576.16, "end": 576.76, "word": " الضوء", "probability": 0.9556884765625}, {"start": 576.76, "end": 577.18, "word": " على", "probability": 0.94140625}, {"start": 577.18, "end": 577.46, "word": " طول", "probability": 0.99560546875}, {"start": 577.46, "end": 577.9, "word": " موجي", "probability": 0.92333984375}, {"start": 577.9, "end": 578.58, "word": " معين", "probability": 0.9892578125}, {"start": 578.58, "end": 579.96, "word": " ويعكس", "probability": 0.90478515625}, {"start": 579.96, "end": 580.18, "word": " أو", "probability": 0.77490234375}, {"start": 580.18, "end": 580.86, "word": " ينفذ", "probability": 0.9892578125}, {"start": 580.86, "end": 581.12, "word": " من", "probability": 0.99755859375}, {"start": 581.12, "end": 581.8, "word": " خلاله", "probability": 0.99560546875}, {"start": 581.8, "end": 582.56, "word": " الضوء", "probability": 0.9691162109375}, {"start": 582.56, "end": 583.06, "word": " الآخر", "probability": 0.8997395833333334}, {"start": 583.06, "end": 583.24, "word": " أو", "probability": 0.75732421875}, {"start": 583.24, "end": 583.36, "word": " ما", "probability": 0.8486328125}, {"start": 583.36, "end": 584.16, "word": " تبقى", "probability": 0.967529296875}, {"start": 584.16, "end": 584.44, "word": " the", "probability": 0.65869140625}, {"start": 584.44, "end": 584.76, "word": " other", "probability": 0.90966796875}, {"start": 584.76, "end": 585.14, "word": " parts", "probability": 0.7333984375}, {"start": 585.14, "end": 585.32, "word": " ما", "probability": 0.48828125}, {"start": 585.32, "end": 586.08, "word": " تبقى", "probability": 0.978759765625}, {"start": 586.08, "end": 586.52, "word": " من", "probability": 0.990234375}, {"start": 586.52, "end": 587.02, "word": " هذا", "probability": 0.974609375}, {"start": 587.02, "end": 587.48, "word": " الضوء", "probability": 0.9703369140625}], "temperature": 1.0}, {"id": 28, "seek": 61362, "start": 588.46, "end": 613.62, "text": "و مثل ما عرضنا من شوية في الصورة مبدأ عمل هذا الجهاز بيحكيلي انه if a substance تمام؟ if a substance can be converted to soluble and colored material إذا كان في عندي محلول أو مادة أو نتيجة تفاعل هي عبارة عن سولابل ذائبة وملونة فممكن أنا أعمل determination", "tokens": [2407, 50113, 1211, 19446, 6225, 43042, 8315, 9154, 13412, 2407, 10632, 8978, 31767, 13063, 3660, 3714, 44510, 10721, 6225, 42213, 23758, 25724, 3224, 31377, 4724, 1829, 5016, 4117, 1829, 20292, 16472, 3224, 498, 257, 12961, 46811, 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"end": 604.1, "word": " كان", "probability": 0.98681640625}, {"start": 604.1, "end": 604.22, "word": " في", "probability": 0.939453125}, {"start": 604.22, "end": 604.74, "word": " عندي", "probability": 0.64794921875}, {"start": 604.74, "end": 605.68, "word": " محلول", "probability": 0.99169921875}, {"start": 605.68, "end": 605.94, "word": " أو", "probability": 0.8447265625}, {"start": 605.94, "end": 606.44, "word": " مادة", "probability": 0.9375}, {"start": 606.44, "end": 606.74, "word": " أو", "probability": 0.919921875}, {"start": 606.74, "end": 607.62, "word": " نتيجة", "probability": 0.9849853515625}, {"start": 607.62, "end": 608.2, "word": " تفاعل", "probability": 0.84356689453125}, {"start": 608.2, "end": 608.38, "word": " هي", "probability": 0.57421875}, {"start": 608.38, "end": 608.92, "word": " عبارة", "probability": 0.9971923828125}, {"start": 608.92, "end": 609.14, "word": " عن", "probability": 0.9970703125}, {"start": 609.14, "end": 609.56, "word": " سولابل", "probability": 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0.9033203125}, {"start": 629.38, "end": 629.74, "word": " صورة", "probability": 0.9825846354166666}, {"start": 629.74, "end": 630.18, "word": " حكينا", "probability": 0.9786376953125}, {"start": 630.18, "end": 630.76, "word": " انه", "probability": 0.927490234375}, {"start": 630.76, "end": 631.18, "word": " كل", "probability": 0.96875}, {"start": 631.18, "end": 631.42, "word": " ما", "probability": 0.8671875}, {"start": 631.42, "end": 631.76, "word": " زاد", "probability": 0.98779296875}, {"start": 631.76, "end": 632.56, "word": " التركيز", "probability": 0.9921875}, {"start": 632.56, "end": 633.22, "word": " بتزيد", "probability": 0.9703776041666666}, {"start": 633.22, "end": 633.54, "word": " شدة", "probability": 0.946044921875}, {"start": 633.54, "end": 634.02, "word": " اللون", "probability": 0.99658203125}, {"start": 634.02, "end": 634.56, "word": " طبعا", "probability": 0.7857666015625}, {"start": 634.56, "end": 635.0, "word": " كل", "probability": 0.61328125}, {"start": 635.0, 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646.33, "end": 673.25, "text": "أخفف فيها باستخدام مثلا distilled water ماء طبعا أضيف عليها ميه أكتر فأكتر فأكتر هلاحظ أنه تركيزها بيقل مع ال dilution كل ما خففت أكتر التركيز بيقل وبالتالي اللون بيقل طبعا فإذا دايما التركيز ممكن أن اعمله determination من خلال شدة اللون لهذا المحلول", "tokens": [10721, 9778, 5172, 5172, 8978, 11296, 4724, 995, 14851, 9778, 3215, 10943, 50113, 15040, 1483, 6261, 1281, 3714, 16606, 23032, 3555, 3615, 995, 5551, 11242, 33911, 25894, 11296, 3714, 1829, 3224, 5551, 4117, 2655, 2288, 6156, 10721, 4117, 2655, 2288, 6156, 10721, 4117, 2655, 2288, 8032, 15040, 5016, 19913, 14739, 3224, 6055, 31747, 1829, 11622, 11296, 4724, 1829, 4587, 1211, 20449, 2423, 11504, 1448, 28242, 19446, 16490, 5172, 5172, 2655, 5551, 4117, 2655, 2288, 16712, 31747, 1829, 11622, 4724, 1829, 4587, 1211, 46599, 6027, 2655, 6027, 1829, 13672, 11536, 4724, 1829, 4587, 1211, 23032, 3555, 3615, 995, 6156, 28814, 15730, 11778, 47302, 15042, 16712, 31747, 1829, 11622, 3714, 43020, 14739, 1975, 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permitted to pass through the solution of its particular wavelength طبعا عشان تكون هذه الطريقة حساسة جدا يعني لقياس التركيز لابد يا بنات أنه أنا أستخدم الطول الموجي اللي يحدث عنده أقصى كمية امتصاص أقصى كمية امتصاص", "tokens": [2278, 6636, 19392, 307, 14879, 562, 264, 1442, 28658, 281, 1320, 807, 264, 3827, 295, 1080, 1729, 22907, 23032, 3555, 3615, 995, 6225, 8592, 7649, 6055, 30544, 29538, 41950, 16572, 28671, 11331, 3794, 32277, 3660, 10874, 28259, 37495, 22653, 5296, 4587, 25528, 3794, 16712, 31747, 1829, 11622, 5296, 16758, 3215, 35186, 4724, 8315, 2655, 14739, 3224, 41850, 5551, 14851, 9778, 40448, 41950, 12610, 9673, 29245, 1829, 13672, 1829, 7251, 24401, 12984, 43242, 3224, 5551, 4587, 9381, 7578, 9122, 2304, 10632, 1975, 2304, 2655, 9381, 33546, 5551, 4587, 9381, 7578, 9122, 2304, 10632, 1975, 2304, 2655, 9381, 33546], "avg_logprob": -0.12802934160037915, "compression_ratio": 1.5298804780876494, "no_speech_prob": 9.5367431640625e-07, "words": [{"start": 673.85, "end": 674.15, 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إلى الـ detector هو الـ IT شدت الضوء لـ transmittance اللي هو النافذ طيب معناها ال percent of transmittance هي الـ IT على ال I note درمية في المية زي قانون النسبة المئوية العادى اللي إحنا بنستخدمه بحياتنا اليومية الجزء على الكل درمية في المية هو هذه نسبة لـ transmittance", "tokens": [2407, 1863, 5172, 2655, 43042, 36145, 6024, 114, 2407, 38207, 13672, 1829, 8717, 5172, 3215, 9154, 16490, 1211, 6027, 2423, 39184, 9917, 4032, 24192, 3555, 30731, 2423, 39184, 25712, 31439, 2423, 39184, 6783, 13412, 3215, 2655, 6024, 114, 2407, 38207, 5296, 39184, 7715, 593, 719, 13672, 1829, 31439, 28239, 31845, 8848, 23032, 1829, 3555, 20449, 8315, 11296, 2423, 3043, 295, 7715, 593, 719, 39896, 2423, 39184, 6783, 15844, 2423, 286, 3637, 11778, 2288, 2304, 10632, 8978, 9673, 10632, 30767, 1829, 12174, 7649, 11536, 28239, 35457, 3660, 9673, 19986, 2407, 10632, 18863, 18513, 7578, 13672, 1829, 11933, 5016, 8315, 44945, 14851, 9778, 40448, 3224, 4724, 5016, 1829, 9307, 8315, 45595, 20498, 10632, 25724, 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"end": 1260.98, "word": " و", "probability": 0.90380859375}, {"start": 1260.98, "end": 1261.62, "word": " التركيز", "probability": 0.98974609375}, {"start": 1261.62, "end": 1261.8, "word": " كل", "probability": 0.93310546875}, {"start": 1261.8, "end": 1261.94, "word": " ما", "probability": 0.79833984375}, {"start": 1261.94, "end": 1262.22, "word": " زاد", "probability": 0.981201171875}, {"start": 1262.22, "end": 1262.88, "word": " التركيز", "probability": 0.9945068359375}, {"start": 1262.88, "end": 1263.26, "word": " كل", "probability": 0.95361328125}, {"start": 1263.26, "end": 1263.42, "word": " ما", "probability": 0.9130859375}, {"start": 1263.42, "end": 1263.72, "word": " زاد", "probability": 0.986328125}, {"start": 1263.72, "end": 1264.14, "word": " اللون", "probability": 0.9921875}, {"start": 1264.14, "end": 1264.82, "word": " الضوء", "probability": 0.9427490234375}, {"start": 1264.82, "end": 1265.04, "word": " اللي", "probability": 0.833251953125}, {"start": 1265.04, "end": 1265.56, "word": " هيمتص", "probability": 0.85546875}, {"start": 1265.56, "end": 1266.02, "word": " أعلى", "probability": 0.9485677083333334}, {"start": 1266.02, "end": 1266.52, "word": " إذا", "probability": 0.90673828125}], "temperature": 1.0}, {"id": 60, "seek": 128803, "start": 1267.11, "end": 1288.03, "text": "الـ transmittance هيكون أقل و هذا هو قانون بيرز، بينص .. هو بيرز درس علاقة التركيز بالـ transmitted light و عبّر عنه بهذه العلاقة حتى إن العلاقة عكسية طبعا، العلاقة عكسية ما بين مين و مين، ما بين التركيز و ال transmittance", "tokens": [6027, 39184, 7715, 593, 719, 39896, 30544, 5551, 4587, 1211, 4032, 23758, 31439, 12174, 7649, 11536, 4724, 13546, 11622, 12399, 4724, 1829, 1863, 9381, 4386, 31439, 4724, 13546, 11622, 11778, 2288, 3794, 11203, 995, 28671, 16712, 31747, 1829, 11622, 20666, 39184, 25355, 1442, 4032, 6225, 3555, 11703, 2288, 18871, 3224, 39627, 24192, 18863, 15040, 28671, 11331, 49975, 36145, 18863, 15040, 28671, 6225, 4117, 3794, 10632, 23032, 3555, 3615, 995, 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"probability": 0.67724609375}, {"start": 1283.53, "end": 1283.75, "word": " بين", "probability": 0.99072265625}, {"start": 1283.75, "end": 1283.99, "word": " مين", "probability": 0.93505859375}, {"start": 1283.99, "end": 1284.11, "word": " و", "probability": 0.9873046875}, {"start": 1284.11, "end": 1284.81, "word": " مين،", "probability": 0.8527018229166666}, {"start": 1284.81, "end": 1284.99, "word": " ما", "probability": 0.95849609375}, {"start": 1284.99, "end": 1285.29, "word": " بين", "probability": 0.9931640625}, {"start": 1285.29, "end": 1286.29, "word": " التركيز", "probability": 0.9970703125}, {"start": 1286.29, "end": 1286.73, "word": " و", "probability": 0.84912109375}, {"start": 1286.73, "end": 1286.93, "word": " ال", "probability": 0.72412109375}, {"start": 1286.93, "end": 1288.03, "word": " transmittance", "probability": 0.8225911458333334}], "temperature": 1.0}, {"id": 61, "seek": 130279, "start": 1288.05, "end": 1302.79, "text": "حكى انه كل ما زاد التركيز بيصير في عندي بتقل شدة الضوء المنبعث اللي هو ال transmitted اه ال I transmitted او ال I T وبالتالي نسبة الضوء المنبعث بالنسبة للكل هتكون ايضا اقليلة", "tokens": [5016, 4117, 7578, 16472, 3224, 28242, 19446, 30767, 18513, 16712, 31747, 1829, 11622, 4724, 1829, 9381, 13546, 8978, 18871, 16254, 39894, 4587, 1211, 13412, 3215, 3660, 6024, 114, 2407, 38207, 9673, 1863, 3555, 3615, 12984, 13672, 1829, 31439, 2423, 25355, 1975, 3224, 2423, 286, 25355, 1975, 2407, 2423, 286, 314, 46599, 6027, 2655, 6027, 1829, 8717, 35457, 3660, 6024, 114, 2407, 38207, 9673, 1863, 3555, 3615, 12984, 20666, 1863, 35457, 3660, 5296, 23275, 1211, 8032, 2655, 30544, 1975, 1829, 11242, 995, 1975, 4587, 1211, 26895, 3660], "avg_logprob": -0.18292025930580053, "compression_ratio": 1.695906432748538, "no_speech_prob": 4.76837158203125e-07, "words": [{"start": 1288.05, "end": 1288.57, "word": "حكى", "probability": 0.89697265625}, {"start": 1288.57, "end": 1288.93, "word": " انه", "probability": 0.5291748046875}, {"start": 1288.93, 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1295.11, "end": 1295.21, "word": " هو", "probability": 0.80908203125}, {"start": 1295.21, "end": 1295.29, "word": " ال", "probability": 0.54443359375}, {"start": 1295.29, "end": 1295.79, "word": " transmitted", "probability": 0.91552734375}, {"start": 1295.79, "end": 1296.25, "word": " اه", "probability": 0.3394775390625}, {"start": 1296.25, "end": 1296.37, "word": " ال", "probability": 0.69580078125}, {"start": 1296.37, "end": 1296.57, "word": " I", "probability": 0.83447265625}, {"start": 1296.57, "end": 1297.17, "word": " transmitted", "probability": 0.93408203125}, {"start": 1297.17, "end": 1297.45, "word": " او", "probability": 0.95458984375}, {"start": 1297.45, "end": 1297.53, "word": " ال", "probability": 0.759765625}, {"start": 1297.53, "end": 1297.71, "word": " I", "probability": 0.50927734375}, {"start": 1297.71, "end": 1298.05, "word": " T", "probability": 0.62646484375}, {"start": 1298.05, "end": 1298.91, "word": " وبالتالي", "probability": 0.873095703125}, {"start": 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"probability": 0.798828125}, {"start": 3250.83, "end": 3250.93, "word": " ال", "probability": 0.99755859375}, {"start": 3250.93, "end": 3251.15, "word": " UV", "probability": 0.97216796875}, {"start": 3251.15, "end": 3251.51, "word": " light", "probability": 0.8828125}], "temperature": 1.0}, {"id": 154, "seek": 326788, "start": 3251.76, "end": 3267.88, "text": "طيب ال detector احنا حكينا ال detector اما هيكون photo cell او photo multiplier tube هلأ photo tube او photo cell نفس المعنى او photo multiplier tube ال photo اللي بديكم تعرفوا او اللي مطلوب منكم ان ال photo cell بتشتغل بطريقة ال photo conductivity", "tokens": [9566, 1829, 3555, 2423, 25712, 1975, 5016, 8315, 11331, 4117, 1829, 8315, 2423, 25712, 1975, 15042, 39896, 30544, 5052, 2815, 1975, 2407, 5052, 44106, 9917, 8032, 1211, 10721, 5052, 9917, 1975, 2407, 5052, 2815, 8717, 36178, 9673, 3615, 1863, 7578, 1975, 2407, 5052, 44106, 9917, 2423, 5052, 13672, 1829, 4724, 16254, 24793, 37279, 28480, 14407, 1975, 2407, 13672, 1829, 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0.89404296875}], "temperature": 1.0}, {"id": 155, "seek": 328794, "start": 3268.74, "end": 3287.94, "text": "أما ال photo multiplier مبدأ عملها بالأقطاب أقطاب السيليكون silicon diode electrode هلأ كيف بالظبط و تفاصيل حق حول مصطلح ال photo conductivity التوصيلية الضوئية أو تفاصيل حول ال silicon diode electrode ما رح نخوض فيها كل اللي مطلوب منكم انه ال photo tubes", "tokens": [10721, 15042, 2423, 5052, 44106, 3714, 44510, 10721, 6225, 42213, 11296, 20666, 10721, 47432, 16758, 5551, 47432, 16758, 21136, 1829, 20292, 30544, 22848, 40787, 38346, 8032, 1211, 10721, 9122, 33911, 20666, 19913, 3555, 9566, 4032, 6055, 5172, 33546, 26895, 11331, 4587, 11331, 12610, 3714, 9381, 9566, 1211, 5016, 2423, 5052, 42982, 16712, 2407, 9381, 26895, 10632, 6024, 114, 2407, 19986, 10632, 34051, 6055, 5172, 33546, 26895, 11331, 12610, 2423, 22848, 40787, 38346, 19446, 12602, 5016, 8717, 9778, 2407, 11242, 8978, 11296, 28242, 13672, 1829, 3714, 9566, 1211, 37746, 9154, 24793, 16472, 3224, 2423, 5052, 21458], "avg_logprob": -0.187500004346172, "compression_ratio": 1.7174887892376682, "no_speech_prob": 1.3709068298339844e-06, "words": [{"start": 3268.74, "end": 3269.04, "word": "أما", "probability": 0.97802734375}, {"start": 3269.04, "end": 3269.16, "word": " ال", "probability": 0.9423828125}, {"start": 3269.16, "end": 3269.34, "word": " photo", "probability": 0.64892578125}, {"start": 3269.34, "end": 3269.94, "word": " multiplier", "probability": 0.609375}, {"start": 3269.94, "end": 3270.66, "word": " مبدأ", "probability": 0.6832682291666666}, {"start": 3270.66, "end": 3271.1, "word": " عملها", "probability": 0.9755859375}, {"start": 3271.1, "end": 3272.04, "word": " بالأقطاب", "probability": 0.67462158203125}, {"start": 3272.04, "end": 3272.6, "word": " أقطاب", "probability": 0.7180582682291666}, {"start": 3272.6, "end": 3273.06, "word": " السيليكون", "probability": 0.7926025390625}, {"start": 3273.06, "end": 3273.4, "word": " silicon", "probability": 0.302978515625}, {"start": 3273.4, 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3279.08, "word": " conductivity", "probability": 0.8115234375}, {"start": 3279.08, "end": 3279.78, "word": " التوصيلية", "probability": 0.92548828125}, {"start": 3279.78, "end": 3280.36, "word": " الضوئية", "probability": 0.905078125}, {"start": 3280.36, "end": 3280.76, "word": " أو", "probability": 0.67529296875}, {"start": 3280.76, "end": 3281.7, "word": " تفاصيل", "probability": 0.9776611328125}, {"start": 3281.7, "end": 3282.12, "word": " حول", "probability": 0.99365234375}, {"start": 3282.12, "end": 3282.5, "word": " ال", "probability": 0.89794921875}, {"start": 3282.5, "end": 3282.82, "word": " silicon", "probability": 0.94580078125}, {"start": 3282.82, "end": 3283.2, "word": " diode", "probability": 0.8798828125}, {"start": 3283.2, "end": 3283.82, "word": " electrode", "probability": 0.98046875}, {"start": 3283.82, "end": 3284.22, "word": " ما", "probability": 0.89599609375}, {"start": 3284.22, "end": 3284.4, "word": " رح", "probability": 0.732421875}, {"start": 3284.4, "end": 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diode electrode تمام؟ و هذا ال detector حكينا أنه بتصلوا الطاقة الضوئية من الضوء النافذ و بيحولها إلى طاقة كهربائية إلى electrical energy عبر جهاز galvanometer موجود داخل ال detector تمام؟", "tokens": [10721, 2407, 2423, 5052, 5438, 39894, 25957, 1211, 4724, 2304, 44510, 10721, 6225, 42213, 2423, 5052, 42982, 4032, 2423, 5052, 44106, 9917, 39894, 25957, 1211, 4724, 2304, 44510, 10721, 2423, 22848, 40787, 38346, 46811, 10943, 22807, 4032, 23758, 2423, 25712, 11331, 4117, 1829, 8315, 14739, 3224, 39894, 36520, 14407, 41950, 995, 28671, 6024, 114, 2407, 19986, 10632, 9154, 6024, 114, 2407, 38207, 2423, 8315, 5172, 8848, 4032, 4724, 1829, 5016, 12610, 11296, 30731, 23032, 995, 28671, 9122, 3224, 25513, 16373, 10632, 30731, 12147, 2281, 6225, 26890, 10874, 3224, 31377, 7660, 9768, 13606, 3714, 29245, 23328, 11778, 47283, 1211, 2423, 25712, 46811, 10943, 22807], "avg_logprob": -0.13551682305450624, "compression_ratio": 1.691699604743083, "no_speech_prob": 0.00010228157043457031, "words": 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0.8017578125}, {"start": 3388.19, "end": 3388.79, "word": " ضوء", "probability": 0.94580078125}, {"start": 3388.79, "end": 3389.59, "word": " عبر", "probability": 0.994384765625}, {"start": 3389.59, "end": 3390.05, "word": " ال", "probability": 0.65869140625}, {"start": 3390.05, "end": 3390.57, "word": " tube", "probability": 0.372314453125}, {"start": 3390.57, "end": 3391.43, "word": " المحلول", "probability": 0.9820556640625}, {"start": 3391.43, "end": 3391.95, "word": " الملون", "probability": 0.9752604166666666}, {"start": 3391.95, "end": 3392.75, "word": " نفذ", "probability": 0.9171549479166666}, {"start": 3392.75, "end": 3392.95, "word": " من", "probability": 0.99755859375}, {"start": 3392.95, "end": 3393.57, "word": " خلاله", "probability": 0.9912109375}, {"start": 3393.57, "end": 3394.19, "word": " هذا", "probability": 0.83447265625}, {"start": 3394.19, "end": 3394.75, "word": " الضوء", "probability": 0.953125}, {"start": 3394.75, "end": 3395.27, "word": " ضرب", "probability": 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السالب", "probability": 0.9547526041666666}, {"start": 3401.69, "end": 3401.95, "word": " إلى", "probability": 0.833984375}, {"start": 3401.95, "end": 3402.51, "word": " القطب", "probability": 0.9654947916666666}, {"start": 3402.51, "end": 3403.07, "word": " الموجب", "probability": 0.9698893229166666}, {"start": 3403.07, "end": 3403.39, "word": " إذا", "probability": 0.67236328125}, {"start": 3403.39, "end": 3403.63, "word": " انتي", "probability": 0.529052734375}, {"start": 3403.63, "end": 3404.03, "word": " عندى", "probability": 0.749755859375}, {"start": 3404.03, "end": 3404.41, "word": " ضوء", "probability": 0.9833984375}, {"start": 3404.41, "end": 3404.95, "word": " photon", "probability": 0.40380859375}], "temperature": 1.0}, {"id": 161, "seek": 343443, "start": 3405.79, "end": 3434.43, "text": "وكمية transmitted light راحت إلى ال cathode حررت إلكترونات الإلكترونات هذه تحركت إلى ال anode بتكون عندي طيار شدت الطيار تقاس بال galvanometer و راح تظهر على ال readout إما ك transmittance كقيمة transmittance أو راح تظهر كقيمة absorbance مين اللي بيحدد أن الجهاز يعمل حسابته و يقيص لل absorbance أو يقيص لل transmittance directly", "tokens": [2407, 24793, 10632, 25355, 1442, 12602, 39319, 2655, 30731, 2423, 17763, 1429, 11331, 2288, 43500, 11933, 23275, 2655, 2288, 11536, 9307, 33688, 23275, 2655, 2288, 11536, 9307, 29538, 6055, 5016, 31747, 2655, 30731, 2423, 364, 1429, 39894, 30544, 18871, 16254, 23032, 1829, 9640, 13412, 3215, 2655, 41950, 1829, 9640, 6055, 4587, 32277, 20666, 7660, 9768, 13606, 4032, 12602, 39319, 6055, 19913, 3224, 2288, 15844, 2423, 1401, 346, 11933, 15042, 9122, 7715, 593, 719, 9122, 4587, 32640, 3660, 7715, 593, 719, 34051, 12602, 39319, 6055, 19913, 3224, 2288, 9122, 4587, 32640, 3660, 15631, 719, 3714, 9957, 13672, 1829, 4724, 1829, 24401, 3215, 14739, 25724, 3224, 31377, 7251, 25957, 1211, 11331, 3794, 16758, 47395, 4032, 7251, 4587, 1829, 9381, 24976, 15631, 719, 34051, 7251, 4587, 1829, 9381, 24976, 7715, 593, 719, 3838], "avg_logprob": -0.19143607438975618, "compression_ratio": 1.8773946360153257, "no_speech_prob": 1.430511474609375e-06, "words": [{"start": 3405.79, "end": 3406.61, "word": "وكمية", "probability": 0.9163411458333334}, {"start": 3406.61, "end": 3407.17, "word": " transmitted", "probability": 0.60302734375}, {"start": 3407.17, "end": 3407.75, "word": " light", "probability": 0.88037109375}, {"start": 3407.75, "end": 3408.61, "word": " راحت", "probability": 0.8494466145833334}, {"start": 3408.61, "end": 3408.85, "word": " إلى", "probability": 0.48583984375}, {"start": 3408.85, "end": 3409.07, "word": " ال", "probability": 0.69775390625}, {"start": 3409.07, "end": 3409.67, "word": " cathode", "probability": 0.6619873046875}, {"start": 3409.67, "end": 3410.49, "word": " حررت", "probability": 0.9205729166666666}, {"start": 3410.49, "end": 3411.25, "word": " إلكترونات", "probability": 0.8053792317708334}, {"start": 3411.25, "end": 3412.05, "word": " الإلكترونات", "probability": 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"probability": 0.951171875}, {"start": 3418.11, "end": 3418.97, "word": " galvanometer", "probability": 0.6883138020833334}, {"start": 3418.97, "end": 3419.65, "word": " و", "probability": 0.94775390625}, {"start": 3419.65, "end": 3419.99, "word": " راح", "probability": 0.703125}, {"start": 3419.99, "end": 3420.45, "word": " تظهر", "probability": 0.9974365234375}, {"start": 3420.45, "end": 3420.71, "word": " على", "probability": 0.93798828125}, {"start": 3420.71, "end": 3420.99, "word": " ال", "probability": 0.91748046875}, {"start": 3420.99, "end": 3421.59, "word": " readout", "probability": 0.771484375}, {"start": 3421.59, "end": 3422.01, "word": " إما", "probability": 0.830078125}, {"start": 3422.01, "end": 3422.33, "word": " ك", "probability": 0.92724609375}, {"start": 3422.33, "end": 3423.47, "word": " transmittance", "probability": 0.70947265625}, {"start": 3423.47, "end": 3423.93, "word": " كقيمة", "probability": 0.865234375}, {"start": 3423.93, "end": 3424.65, "word": " transmittance", "probability": 0.8894856770833334}, {"start": 3424.65, "end": 3424.93, "word": " أو", "probability": 0.88525390625}, {"start": 3424.93, "end": 3425.19, "word": " راح", "probability": 0.950439453125}, {"start": 3425.19, "end": 3425.67, "word": " تظهر", "probability": 0.99853515625}, {"start": 3425.67, "end": 3426.51, "word": " كقيمة", "probability": 0.941162109375}, {"start": 3426.51, "end": 3427.55, "word": " absorbance", "probability": 0.93212890625}, {"start": 3427.55, "end": 3427.97, "word": " مين", "probability": 0.870849609375}, {"start": 3427.97, "end": 3428.09, "word": " اللي", "probability": 0.956787109375}, {"start": 3428.09, "end": 3428.67, "word": " بيحدد", "probability": 0.9725341796875}, {"start": 3428.67, "end": 3429.05, "word": " أن", "probability": 0.430908203125}, {"start": 3429.05, "end": 3429.61, "word": " الجهاز", "probability": 0.8224283854166666}, {"start": 3429.61, "end": 3429.95, "word": " يعمل", "probability": 0.98779296875}, {"start": 3429.95, "end": 3430.65, "word": " حسابته", "probability": 0.80224609375}, {"start": 3430.65, "end": 3431.03, "word": " و", "probability": 0.97705078125}, {"start": 3431.03, "end": 3431.35, "word": " يقيص", "probability": 0.801513671875}, {"start": 3431.35, "end": 3431.51, "word": " لل", "probability": 0.87060546875}, {"start": 3431.51, "end": 3432.23, "word": " absorbance", "probability": 0.935546875}, {"start": 3432.23, "end": 3432.41, "word": " أو", "probability": 0.75244140625}, {"start": 3432.41, "end": 3432.73, "word": " يقيص", "probability": 0.9156494140625}, {"start": 3432.73, "end": 3432.91, "word": " لل", "probability": 0.544921875}, {"start": 3432.91, "end": 3433.75, "word": " transmittance", "probability": 0.9698893229166666}, {"start": 3433.75, "end": 3434.43, "word": " directly", "probability": 0.9443359375}], "temperature": 1.0}, {"id": 162, "seek": 345176, "start": 3435.46, "end": 3451.76, "text": "أنا اللي ب .. ب .. بدخل ال mood of read يعني أنت إيش تقرألي يا جهاز؟ تقرألي absorbance ولا تقرألي transmittance؟ وكل تعاملاتنا أو معظم تعاملاتنا بتكون يا بنات بال absorbance و ليس بال transmittance، تمام؟ طيب", "tokens": [10721, 8315, 13672, 1829, 4724, 4386, 4724, 4386, 4724, 3215, 9778, 1211, 2423, 9268, 295, 1401, 37495, 22653, 14739, 2655, 11933, 1829, 8592, 6055, 4587, 2288, 10721, 20292, 35186, 10874, 3224, 31377, 22807, 6055, 4587, 2288, 10721, 20292, 15631, 719, 49429, 6055, 4587, 2288, 10721, 20292, 7715, 593, 719, 22807, 4032, 28820, 37279, 10943, 1211, 9307, 8315, 34051, 20449, 19913, 2304, 37279, 10943, 1211, 9307, 8315, 39894, 30544, 35186, 4724, 8315, 2655, 20666, 15631, 719, 4032, 32239, 3794, 20666, 7715, 593, 719, 12399, 46811, 10943, 22807, 23032, 1829, 3555], "avg_logprob": -0.11310763955116272, "compression_ratio": 1.7150537634408602, "no_speech_prob": 2.0265579223632812e-06, "words": [{"start": 3435.46, "end": 3435.78, "word": "أنا", "probability": 0.783935546875}, {"start": 3435.78, "end": 3435.9, "word": " اللي", "probability": 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"end": 3439.88, "word": " تقرألي", "probability": 0.9271484375}, {"start": 3439.88, "end": 3440.0, "word": " يا", "probability": 0.98876953125}, {"start": 3440.0, "end": 3440.44, "word": " جهاز؟", "probability": 0.892822265625}, {"start": 3440.44, "end": 3440.88, "word": " تقرألي", "probability": 0.99091796875}, {"start": 3440.88, "end": 3441.54, "word": " absorbance", "probability": 0.874267578125}, {"start": 3441.54, "end": 3441.7, "word": " ولا", "probability": 0.8330078125}, {"start": 3441.7, "end": 3442.3, "word": " تقرألي", "probability": 0.99482421875}, {"start": 3442.3, "end": 3443.52, "word": " transmittance؟", "probability": 0.7763671875}, {"start": 3443.52, "end": 3443.78, "word": " وكل", "probability": 0.873291015625}, {"start": 3443.78, "end": 3444.68, "word": " تعاملاتنا", "probability": 0.986328125}, {"start": 3444.68, "end": 3444.94, "word": " أو", "probability": 0.90185546875}, {"start": 3444.94, "end": 3445.42, "word": " معظم", "probability": 0.9983723958333334}, {"start": 3445.42, "end": 3446.26, "word": " تعاملاتنا", "probability": 0.99228515625}, {"start": 3446.26, "end": 3446.68, "word": " بتكون", "probability": 0.9580078125}, {"start": 3446.68, "end": 3446.8, "word": " يا", "probability": 0.97705078125}, {"start": 3446.8, "end": 3447.32, "word": " بنات", "probability": 0.9578450520833334}, {"start": 3447.32, "end": 3447.76, "word": " بال", "probability": 0.75927734375}, {"start": 3447.76, "end": 3448.64, "word": " absorbance", "probability": 0.947021484375}, {"start": 3448.64, "end": 3448.8, "word": " و", "probability": 0.974609375}, {"start": 3448.8, "end": 3449.04, "word": " ليس", "probability": 0.861572265625}, {"start": 3449.04, "end": 3449.2, "word": " بال", "probability": 0.98828125}, {"start": 3449.2, "end": 3450.4, "word": " transmittance،", "probability": 0.79736328125}, {"start": 3450.4, "end": 3451.3, "word": " تمام؟", "probability": 0.87841796875}, {"start": 3451.3, "end": 3451.76, "word": " طيب", "probability": 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"probability": 0.38525390625}, {"start": 3769.42, "end": 3769.96, "word": " اشتعلي", "probability": 0.7384765625}, {"start": 3769.96, "end": 3770.3, "word": " كتير", "probability": 0.98291015625}, {"start": 3770.3, "end": 3771.0, "word": " فهذه", "probability": 0.9296875}, {"start": 3771.0, "end": 3771.68, "word": " علاقة", "probability": 0.98291015625}, {"start": 3771.68, "end": 3772.5, "word": " حكينا", "probability": 0.9638671875}, {"start": 3772.5, "end": 3773.24, "word": " علاقة", "probability": 0.97412109375}, {"start": 3773.24, "end": 3774.16, "word": " ترضية", "probability": 0.7666829427083334}, {"start": 3774.16, "end": 3774.92, "word": " على", "probability": 0.9296875}, {"start": 3774.92, "end": 3775.28, "word": " عكس", "probability": 0.9920247395833334}, {"start": 3775.28, "end": 3775.72, "word": " مثلا", "probability": 0.989013671875}], "temperature": 1.0}, {"id": 178, "seek": 380621, "start": 3776.55, "end": 3806.21, "text": "إنه في ال spectrophotometer حكينا في ال spectrophotometer كمية الضوء اللي واصل لل detector هو ال transmittance ويتناسب تناسبان عكسي مع العينة مع تركيز العينة إنما ال absorbance اللي تبدأت في العينة هو اللي يتناسب تناسبان ترضيا مع العينة تمام؟ فحلو إنه اتفرقوا و تربطوا الأمور ببعضها البعض لحتى تعمقوا الفهم عندكم هيك بنكون وصلنا لنهاية محاضرتنا لليوم يعطيكم ألف عافية", "tokens": [28814, 1863, 3224, 8978, 2423, 6177, 11741, 310, 13606, 11331, 4117, 1829, 8315, 8978, 2423, 6177, 11741, 310, 13606, 9122, 2304, 10632, 6024, 114, 2407, 38207, 13672, 1829, 4032, 33546, 1211, 24976, 25712, 31439, 2423, 7715, 593, 719, 4032, 36081, 8315, 35457, 6055, 8315, 35457, 7649, 6225, 4117, 3794, 1829, 20449, 18863, 9957, 3660, 20449, 6055, 31747, 1829, 11622, 18863, 9957, 3660, 36145, 15042, 2423, 15631, 719, 13672, 1829, 6055, 44510, 10721, 2655, 8978, 18863, 9957, 3660, 31439, 13672, 1829, 7251, 2655, 8315, 35457, 6055, 8315, 35457, 7649, 6055, 43042, 25528, 20449, 18863, 9957, 3660, 46811, 10943, 22807, 6156, 5016, 1211, 2407, 36145, 3224, 1975, 2655, 5172, 2288, 4587, 14407, 4032, 6055, 25513, 9566, 14407, 16247, 2304, 13063, 4724, 3555, 3615, 11242, 11296, 29739, 3615, 11242, 5296, 33753, 7578, 6055, 25957, 4587, 14407, 27188, 16095, 43242, 24793, 39896, 4117, 44945, 30544, 4032, 36520, 8315, 5296, 1863, 11296, 10632, 3714, 5016, 46958, 43500, 8315, 5296, 20292, 20498, 37495, 9566, 1829, 24793, 5551, 46538, 6225, 31845, 10632], "avg_logprob": -0.1455195728375251, "compression_ratio": 1.9901960784313726, "no_speech_prob": 0.484619140625, "words": [{"start": 3776.55, "end": 3777.07, "word": "إنه", "probability": 0.7332356770833334}, {"start": 3777.07, "end": 3777.35, "word": " في", "probability": 0.9267578125}, {"start": 3777.35, "end": 3777.41, "word": " ال", "probability": 0.84228515625}, {"start": 3777.41, "end": 3778.23, "word": " spectrophotometer", "probability": 0.760284423828125}, {"start": 3778.23, "end": 3778.61, "word": " حكينا", "probability": 0.945556640625}, {"start": 3778.61, "end": 3778.75, "word": " في", "probability": 0.955078125}, {"start": 3778.75, "end": 3778.89, "word": " ال", "probability": 0.82373046875}, {"start": 3778.89, "end": 3779.81, "word": " spectrophotometer", "probability": 0.9393310546875}, {"start": 3779.81, "end": 3780.23, "word": " كمية", "probability": 0.9744466145833334}, {"start": 3780.23, "end": 3780.57, "word": " الضوء", "probability": 0.9493408203125}, {"start": 3780.57, "end": 3780.73, "word": " اللي", "probability": 0.76953125}, {"start": 3780.73, "end": 3781.05, "word": " واصل", "probability": 0.9625651041666666}, {"start": 3781.05, "end": 3781.17, "word": " لل", "probability": 0.74951171875}, {"start": 3781.17, "end": 3781.51, "word": " detector", "probability": 0.58837890625}, {"start": 3781.51, "end": 3781.75, "word": " هو", "probability": 0.95068359375}, {"start": 3781.75, "end": 3781.91, "word": " ال", "probability": 0.427734375}, {"start": 3781.91, "end": 3782.71, "word": " transmittance", "probability": 0.8956705729166666}, {"start": 3782.71, "end": 3783.63, "word": " ويتناسب", "probability": 0.9501953125}, {"start": 3783.63, "end": 3784.19, "word": " تناسبان", "probability": 0.8748779296875}, {"start": 3784.19, "end": 3785.09, "word": " عكسي", "probability": 0.9752197265625}, {"start": 3785.09, "end": 3785.65, "word": " مع", "probability": 0.9951171875}, {"start": 3785.65, "end": 3787.81, "word": " العينة", "probability": 0.69775390625}, {"start": 3787.81, "end": 3787.95, "word": " مع", "probability": 0.7578125}, {"start": 3787.95, "end": 3788.35, "word": " تركيز", "probability": 0.990234375}, {"start": 3788.35, "end": 3788.95, "word": " العينة", "probability": 0.978515625}, {"start": 3788.95, "end": 3789.47, "word": " إنما", "probability": 0.736328125}, {"start": 3789.47, "end": 3789.61, "word": " ال", "probability": 0.98095703125}, {"start": 3789.61, "end": 3790.25, "word": " absorbance", "probability": 0.873046875}, {"start": 3790.25, "end": 3790.41, "word": " اللي", "probability": 0.978271484375}, {"start": 3790.41, "end": 3790.91, "word": " تبدأت", "probability": 0.7620849609375}, {"start": 3790.91, "end": 3790.99, "word": " في", "probability": 0.978515625}, {"start": 3790.99, "end": 3791.57, "word": " العينة", "probability": 0.9689127604166666}, {"start": 3791.57, "end": 3791.91, "word": " هو", "probability": 0.97265625}, {"start": 3791.91, "end": 3792.15, "word": " اللي", "probability": 0.752685546875}, {"start": 3792.15, "end": 3792.65, "word": " يتناسب", "probability": 0.9342041015625}, {"start": 3792.65, "end": 3793.21, "word": " تناسبان", "probability": 0.84033203125}, {"start": 3793.21, "end": 3793.61, "word": " ترضيا", "probability": 0.76904296875}, {"start": 3793.61, "end": 3793.81, "word": " مع", "probability": 0.95556640625}, {"start": 3793.81, "end": 3794.43, "word": " العينة", "probability": 0.9876302083333334}, {"start": 3794.43, "end": 3795.13, "word": " تمام؟", "probability": 0.6131998697916666}, {"start": 3795.13, "end": 3795.51, "word": " فحلو", "probability": 0.9412841796875}, {"start": 3795.51, "end": 3795.81, "word": " إنه", "probability": 0.830322265625}, {"start": 3795.81, "end": 3796.51, "word": " اتفرقوا", "probability": 0.94677734375}, {"start": 3796.51, "end": 3796.79, "word": " و", "probability": 0.52001953125}, {"start": 3796.79, "end": 3797.35, "word": " تربطوا", "probability": 0.968505859375}, {"start": 3797.35, "end": 3797.63, "word": " الأمور", "probability": 0.98876953125}, {"start": 3797.63, "end": 3798.07, "word": " ببعضها", "probability": 0.837109375}, {"start": 3798.07, "end": 3798.39, "word": " البعض", "probability": 0.8850911458333334}, {"start": 3798.39, "end": 3799.35, "word": " لحتى", "probability": 0.9309895833333334}, {"start": 3799.35, "end": 3800.63, "word": " تعمقوا", "probability": 0.79852294921875}, {"start": 3800.63, "end": 3800.87, "word": " الفهم", "probability": 0.969482421875}, {"start": 3800.87, "end": 3801.37, "word": " عندكم", "probability": 0.981201171875}, {"start": 3801.37, "end": 3802.15, "word": " هيك", "probability": 0.84814453125}, {"start": 3802.15, "end": 3802.55, "word": " بنكون", "probability": 0.95068359375}, {"start": 3802.55, "end": 3803.23, "word": " وصلنا", "probability": 0.96826171875}, {"start": 3803.23, "end": 3803.81, "word": " لنهاية", "probability": 0.917236328125}, {"start": 3803.81, "end": 3804.53, "word": " محاضرتنا", "probability": 0.94912109375}, {"start": 3804.53, "end": 3804.95, "word": " لليوم", "probability": 0.9412434895833334}, {"start": 3804.95, "end": 3805.47, "word": " يعطيكم", "probability": 0.9454345703125}, {"start": 3805.47, "end": 3805.77, "word": " ألف", "probability": 0.7744140625}, {"start": 3805.77, "end": 3806.21, "word": " عافية", "probability": 0.9720052083333334}], "temperature": 1.0}, {"id": 179, "seek": 380686, "start": 3806.54, "end": 3806.86, "text": "السلام عليكم", "tokens": [6027, 3794, 37440, 25894, 24793], "avg_logprob": -0.9635416666666666, "compression_ratio": 0.7419354838709677, "no_speech_prob": 0.701171875, "words": [{"start": 3806.54, "end": 3806.86, "word": "السلام", "probability": 0.3407999674479167}, {"start": 3806.86, "end": 3806.86, "word": " عليكم", "probability": 0.943115234375}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 3811.62525, "duration_after_vad": 3755.3118749999885}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwY9jl8xw-bWkVZkWcGGyspd/pYa8qDaMM00_raw.srt b/PL9fwy3NUQKwY9jl8xw-bWkVZkWcGGyspd/pYa8qDaMM00_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..be1eda29d11bfd0e6d0f81ce2a0815c02f68887c
--- /dev/null
+++ b/PL9fwy3NUQKwY9jl8xw-bWkVZkWcGGyspd/pYa8qDaMM00_raw.srt
@@ -0,0 +1,3260 @@
+1
+00:00:03,930 --> 00:00:07,410
+السلام عليكم ورحمة الله وبركاته طالبات العزيزات
+
+2
+00:00:07,410 --> 00:00:10,610
+اليوم ان شاء الله رح نشرح محاضرة بعنوان calorie
+
+3
+00:00:10,610 --> 00:00:15,090
+meter or photometer في البداية ماذا يعني calorie
+
+4
+00:00:15,090 --> 00:00:20,610
+meter? color معناها لون تمام؟ meter قياس إذا قياس
+
+5
+00:00:20,610 --> 00:00:26,040
+شدة اللون أو photometer photo معناها ضوءو meter
+
+6
+00:00:26,040 --> 00:00:31,540
+قياس أو قياس شدة الضوء قياس شدة اللون أو قياس شدة
+
+7
+00:00:31,540 --> 00:00:36,020
+الضوء هي طريقة تستخدم for concentration،
+
+8
+00:00:36,020 --> 00:00:39,060
+determination في ال medical laboratories في
+
+9
+00:00:39,060 --> 00:00:44,420
+المختبرات الطبية هذا مبدأ عمل أجهزة تستخدم في
+
+10
+00:00:44,420 --> 00:00:48,300
+معرفة التركيز أو قياس تركيز المحاليل و العينات
+
+11
+00:00:48,300 --> 00:00:53,290
+بمبدأ عمل ال calorie meter و ال photometerطيب ما
+
+12
+00:00:53,290 --> 00:00:59,010
+علاقة قياس شدة اللون أو الضوء بالتركيز راح نتعرف
+
+13
+00:00:59,010 --> 00:01:04,550
+خلال ال slides القادمة ولكن في البداية لابد من
+
+14
+00:01:04,550 --> 00:01:09,250
+تقديم بسيط انعرف فيه ماذا يعني photometry photo
+
+15
+00:01:09,250 --> 00:01:15,770
+حكينا معناها ضوء متري قياسإذن photometry معناها
+
+16
+00:01:15,770 --> 00:01:20,730
+the measurement of light قياس الضوء تمام؟ في عندي
+
+17
+00:01:20,730 --> 00:01:26,110
+أجهزة تسمى photometer أو spectrophotometer هي
+
+18
+00:01:26,110 --> 00:01:30,230
+عبارة عن أجهزة تعمل على مبدأ قياس الضوء the
+
+19
+00:01:30,230 --> 00:01:33,970
+measurement of lightو هذه الأجهزة they are
+
+20
+00:01:33,970 --> 00:01:40,750
+instruments used to detect the measurement أو to
+
+21
+00:01:40,750 --> 00:01:45,390
+detect the concentration و هذه الأجهزة يوجد فيها
+
+22
+00:01:45,390 --> 00:01:50,690
+أدوات أو أداة تسمى photocell أو photo multiplier
+
+23
+00:01:50,690 --> 00:01:54,940
+tubeهذه ال photocell أو ال photo multiplier tube
+
+24
+00:01:54,940 --> 00:01:59,880
+من خصائصها إنه لديها القدرة على إنها تقيس كمية
+
+25
+00:01:59,880 --> 00:02:06,240
+الضوء الواصلة إليها بعد مرورها بمحلول ملون، تمام؟
+
+26
+00:02:06,240 --> 00:02:11,490
+فإذا كان في عندي محلول ملونو .. او يعني reaction
+
+27
+00:02:11,490 --> 00:02:16,890
+حدث نتيجة مثلا ال combination الإضافة ما بين ال
+
+28
+00:02:16,890 --> 00:02:19,890
+sample و ال reagent حكينا ال reagent هو عبارة عن
+
+29
+00:02:19,890 --> 00:02:24,210
+إيش؟ هو عبارة عن محلول بيعمللي measurable change
+
+30
+00:02:25,160 --> 00:02:30,260
+تغير يمكن قياسه و هي على أغلب التغيرات ممكن تكون
+
+31
+00:02:30,260 --> 00:02:34,680
+تغير في اللون طبعا فإذا نتيجة reaction معين ما بين
+
+32
+00:02:34,680 --> 00:02:38,880
+ال sample و ال reagent نتج colored solution نتج
+
+33
+00:02:38,880 --> 00:02:46,320
+محلول ملون هذا المحلول إذا مر من خلاله ضوء فإن جزء
+
+34
+00:02:46,320 --> 00:02:51,920
+من هذا الضوء اللي مر أو اصطدم بهذا المحلولجزء من
+
+35
+00:02:51,920 --> 00:02:56,780
+هذا الضوء يتبدد ويتلاشى أو يتم انتصاصه من قبل
+
+36
+00:02:56,780 --> 00:03:03,080
+المحلول الملون والجزء الآخر ينفذ هذا الجزء النافذ
+
+37
+00:03:03,080 --> 00:03:08,200
+يصل إلى أداة في الجهاز اسمها photocell أو photo
+
+38
+00:03:08,200 --> 00:03:13,420
+multiplier tubeهى اللى بتقيسلى كمية الضوء اللى
+
+39
+00:03:13,420 --> 00:03:17,680
+واصلة إليها و بالنهاية بتعبرلى عن تركيز المحلول
+
+40
+00:03:17,680 --> 00:03:22,940
+الملون تمام؟ بتعبرلى عن تركيز المحلول الملون خلينا
+
+41
+00:03:22,940 --> 00:03:34,500
+بس لحتى نقرب الفكرة نحكي عن هذا الموضوع هى هنا
+
+42
+00:03:34,500 --> 00:03:41,270
+مثلا فى عندي lightضوء مصدر ضوء طبعا اصطدم بانبوب
+
+43
+00:03:41,270 --> 00:03:45,890
+فيها محلول ملون تمام اصطدم بانبوب فيها محلول ملون
+
+44
+00:03:45,890 --> 00:03:53,230
+جزء من هذا الضوء تم امتصاصه فقدانه او تلاشيه عبر
+
+45
+00:03:53,230 --> 00:03:57,270
+المحلول تمام او من خلال المحلول داخل المحلول تم
+
+46
+00:03:57,270 --> 00:04:03,970
+امتصاصهوالجزء الأخر نفذ تمام؟ هذا الجزء النافذ هو
+
+47
+00:04:03,970 --> 00:04:07,310
+الذي يصل إلى أداة ال photocell أو ال photo
+
+48
+00:04:07,310 --> 00:04:11,810
+multiplier tube في جهاز ال photo meter أو ال
+
+49
+00:04:11,810 --> 00:04:19,110
+spectrophotometer وبيعبرلي عن تركيز المحلول كيف
+
+50
+00:04:19,110 --> 00:04:26,140
+يعبر عن تركيز المحلول؟ ببساطة لإنهتركيز أي محلول
+
+51
+00:04:26,140 --> 00:04:31,320
+تمام هو عبارة عن function of its color تركيز أي
+
+52
+00:04:31,320 --> 00:04:36,220
+محلول هو يعني ب .. بيمكن التعبير عنه أو يمكن قياسه
+
+53
+00:04:36,220 --> 00:04:40,720
+من خلال شدة لونه فمثلا لو أنا حصلت على صبغة معينة
+
+54
+00:04:40,720 --> 00:04:46,020
+لنفرض أنه صبغة لونها أحمربلشت أخفف فيها طبعا؟ بلشت
+
+55
+00:04:46,020 --> 00:04:50,560
+أخفف فيها كل ما بعمل dilution أكتر أنا عم بقل ال
+
+56
+00:04:50,560 --> 00:04:55,220
+concentration عندي و كذلك تقل شدة اللون للمحلول
+
+57
+00:04:55,220 --> 00:05:01,860
+أعلى concentration هو أكثر شدة لللون و أخف
+
+58
+00:05:02,310 --> 00:05:05,370
+concentration أو أقل concentration هو أخف شدة
+
+59
+00:05:05,370 --> 00:05:10,470
+لللون تمام؟ إذا يتم التعبير عن تركيز المحاليل من
+
+60
+00:05:10,470 --> 00:05:17,590
+خلال لونها وأيضا للتالي يمكن قياس هذه المحاليل من
+
+61
+00:05:17,590 --> 00:05:22,930
+يعني من خلال تعبير عن درجة لونها وذلك بمرور الضوء
+
+62
+00:05:23,120 --> 00:05:27,800
+يعني كمية الضوء اللي يتلاشى في هذه المحلول و الضوء
+
+63
+00:05:27,800 --> 00:05:32,660
+اللي ينفذ عبر هذه المحلول يعبرلي بطريقة غير مباشرة
+
+64
+00:05:32,660 --> 00:05:37,080
+عن تركيز المحلول تمام؟ يعبرلي بطريقة غير مباشرة عن
+
+65
+00:05:37,080 --> 00:05:44,270
+تركيز المحلولفكرة أخرى، لو أنا جبت لمبة، لمبة ضوء
+
+66
+00:05:44,270 --> 00:05:49,570
+وحطيت أمامها قطعة زجاجية ملونة، هل كل الضوء اللي
+
+67
+00:05:49,570 --> 00:05:53,230
+موجود في ال light source، في المصدر، في اللمبة،
+
+68
+00:05:53,230 --> 00:05:56,310
+سينفذ إلى الجهة الأخرى من القطعة الزجاجية؟ بالطبع
+
+69
+00:05:56,310 --> 00:06:00,150
+لا، يعني لأ جزء من هذا الضوء سيتلاشى عبر القطعة
+
+70
+00:06:00,150 --> 00:06:05,950
+الزجاجية وجزء آخر سينفذ، فبالتالي لو كل ما كان لون
+
+71
+00:06:05,950 --> 00:06:11,820
+الزجاج داكن أكثر، غامق أكثرفبالتالي هيحجب لكمية
+
+72
+00:06:11,820 --> 00:06:16,180
+الضوء أكتر، تمام؟ وكمية الضوء اللي نعفد عبر هذه
+
+73
+00:06:16,180 --> 00:06:20,660
+القطعة الذجاجية هيكون أقل، تمام؟ فهذه هي فكرة
+
+74
+00:06:20,660 --> 00:06:27,280
+القياس .. التركيز تبع لشدة لونها و لمرور الضوء من
+
+75
+00:06:27,280 --> 00:06:27,780
+خلالها
+
+76
+00:06:35,350 --> 00:06:39,630
+طيب لنتحدث عن characteristics of light خواص الدوق
+
+77
+00:06:39,630 --> 00:06:44,230
+الدوق هو عبارة عن electromagnetic energy that
+
+78
+00:06:44,230 --> 00:06:48,830
+travels in waves هو عبارة عن طاقة كهرومغناطيسية
+
+79
+00:06:48,830 --> 00:06:53,930
+تسير في موجات ومانها تسير في موجات إذا الطول
+
+80
+00:06:53,930 --> 00:06:58,210
+الموجي لهذا الدوق هو عبارة عن the wavelength of
+
+81
+00:06:58,210 --> 00:07:03,410
+light is the distanceهو عبارة عن المسافة ما بين
+
+82
+00:07:03,410 --> 00:07:08,390
+two peaks two peaks يعني ما بين قمتين متتاليتين أو
+
+83
+00:07:08,390 --> 00:07:13,350
+قاعين متتالين أعلى نقطة في القمة بنسميها peak وأقل
+
+84
+00:07:13,350 --> 00:07:19,110
+نقطة في القاع أيضا بنسميها peak إذا بما أنه الطول
+
+85
+00:07:19,110 --> 00:07:22,230
+الموجي إذا بدنا نحكي عنه بنعبر عنه بالعربي هو
+
+86
+00:07:22,230 --> 00:07:27,940
+المسافة ما بينقمتين متتاليين أو قاعين متتاليين و
+
+87
+00:07:27,940 --> 00:07:31,020
+أعلى نقطة في القمة بنسميها beak و أعلى نقطة أو
+
+88
+00:07:31,020 --> 00:07:35,740
+أدنى نقطة في القاع بنسميه أيضًا beak إذا هو في
+
+89
+00:07:35,740 --> 00:07:39,540
+اللغة الإنجليزية نعرفه the distance between two
+
+90
+00:07:39,540 --> 00:07:44,920
+peaks of the light waveهذا الطول الموجي يتناسب
+
+91
+00:07:44,920 --> 00:07:50,620
+عكسيا مع طاقة الضوء إذا إذا كانت عندي ضوء بطول
+
+92
+00:07:50,620 --> 00:07:56,500
+موجي كبير هتكون طاقة هذا الضوء قليلة و العكس صحيح
+
+93
+00:07:56,500 --> 00:08:01,300
+إذا كان الطول الموجي قليل إذا طاقة هذا الضوء هتكون
+
+94
+00:08:01,300 --> 00:08:05,780
+عالية جدا، تمام؟ العلاقة عكسية ما بين الطول الموجي
+
+95
+00:08:05,780 --> 00:08:11,200
+وطاقة الضوءطيب أنا في عندي أنواع من الضوء في ضوء
+
+96
+00:08:11,200 --> 00:08:15,040
+مرئي، في ضوء أشعة فوق بنفسجية، أشعة تحت حمراء،
+
+97
+00:08:15,040 --> 00:08:18,660
+gamma، X-ray، radio waves في عندي أنواع كتير من
+
+98
+00:08:18,660 --> 00:08:24,220
+الأشعة الضوئية طيب لو كنا بنتحدث عن الأشعة المرئية
+
+99
+00:08:24,220 --> 00:08:27,780
+اللتي يمكن رؤيتها بالعين تمام؟ the visible region
+
+100
+00:08:27,780 --> 00:08:31,860
+ال visible region هي الأشعة المرئية تمام؟ هذه
+
+101
+00:08:31,860 --> 00:08:37,050
+الأشعة المرئية بيحكيلي إنه the color of lightis
+
+102
+00:08:37,050 --> 00:08:43,780
+function of its wavelengthلون الضوء عبارة عن دالة
+
+103
+00:08:43,780 --> 00:08:48,700
+أو يعبر عنه الطول الموجي طبعا، اللون اللي .. اللون
+
+104
+00:08:48,700 --> 00:08:53,160
+اللي الضوء يعبر عنه الطول الموجي هذا الطول الموجي
+
+105
+00:08:53,160 --> 00:08:58,540
+يزداد من اللون ال violet اللي هو أول لون في مرحلة
+
+106
+00:08:58,540 --> 00:09:03,080
+ال visible و بيظل يزيد باتجاه ال red color اللي هو
+
+107
+00:09:03,080 --> 00:09:06,700
+أخر لون في مرحلة ال visible كمان شوية راح نستعرض
+
+108
+00:09:06,700 --> 00:09:11,100
+جدول و راح نفهم أش يعني ال visible regionتمام؟
+
+109
+00:09:11,100 --> 00:09:14,660
+خلّينا بس ننتقل إلى النقطة الأخيرة اللي بتحكيلي
+
+110
+00:09:14,660 --> 00:09:18,300
+objects that appear colored absorb light at
+
+111
+00:09:18,300 --> 00:09:21,840
+particular wavelengths and reflect the other parts
+
+112
+00:09:21,840 --> 00:09:24,880
+at the visible spectrum resulting in many shades
+
+113
+00:09:24,880 --> 00:09:29,780
+of color إيش معنى هذه الجملة؟حكينا إنه المحلول
+
+114
+00:09:29,780 --> 00:09:35,580
+اللي يبدو ملونا تمام colored solution absorb light
+
+115
+00:09:35,580 --> 00:09:41,120
+يمتص الضوء على طول موجي معين ويعكس أو ينفذ من
+
+116
+00:09:41,120 --> 00:09:45,320
+خلاله الضوء الآخر أو ما تبقى the other parts ما
+
+117
+00:09:45,320 --> 00:09:53,140
+تبقى من هذا الضوءو مثل ما عرضنا من شوية في الصورة
+
+118
+00:09:53,140 --> 00:09:57,280
+مبدأ عمل هذا الجهاز بيحكيلي انه if a substance
+
+119
+00:09:57,280 --> 00:10:02,000
+تمام؟ if a substance can be converted to soluble
+
+120
+00:10:02,000 --> 00:10:06,440
+and colored material إذا كان في عندي محلول أو مادة
+
+121
+00:10:06,440 --> 00:10:11,020
+أو نتيجة تفاعل هي عبارة عن سولابل ذائبة وملونة
+
+122
+00:10:11,020 --> 00:10:16,000
+فممكن أنا أعمل determinationلل concentration لهذا
+
+123
+00:10:16,000 --> 00:10:19,440
+المحلول its concentration may be determined ممكن
+
+124
+00:10:19,440 --> 00:10:25,760
+اعرف التركيز من خلال كمية اللون اللي موجودة في
+
+125
+00:10:25,760 --> 00:10:30,180
+المحلول و هذا الكلام ايضا استعرضناه في صورة حكينا
+
+126
+00:10:30,180 --> 00:10:35,180
+انه كل ما زاد التركيز بتزيد شدة اللون طبعا كل ما
+
+127
+00:10:35,180 --> 00:10:40,880
+زاد التركيز بتزيد شدة اللون للمحلول لو جبنا صبغة و
+
+128
+00:10:40,880 --> 00:10:45,120
+الصبغة هدي لونها move مثلاتمام؟ وبلشت أخفف فيها
+
+129
+00:10:46,330 --> 00:10:50,510
+أخفف فيها باستخدام مثلا distilled water ماء طبعا
+
+130
+00:10:50,510 --> 00:10:54,650
+أضيف عليها ميه أكتر فأكتر فأكتر هلاحظ أنه تركيزها
+
+131
+00:10:54,650 --> 00:11:00,330
+بيقل مع ال dilution كل ما خففت أكتر التركيز بيقل
+
+132
+00:11:00,330 --> 00:11:08,410
+وبالتالي اللون بيقل طبعا فإذا دايما التركيز
+
+133
+00:11:08,410 --> 00:11:12,710
+ممكن أن اعمله determination من خلال شدة اللون لهذا
+
+134
+00:11:12,710 --> 00:11:16,550
+المحلولThe greatest sensitivity is obtained when
+
+135
+00:11:16,550 --> 00:11:19,370
+the light permitted to pass through the solution
+
+136
+00:11:19,370 --> 00:11:23,450
+of its particular wavelength طبعا عشان تكون هذه
+
+137
+00:11:23,450 --> 00:11:32,430
+الطريقة حساسة جدا يعني لقياس التركيز لابد يا بنات
+
+138
+00:11:32,430 --> 00:11:37,590
+أنه أنا أستخدم الطول الموجي اللي يحدث عنده أقصى
+
+139
+00:11:37,590 --> 00:11:43,670
+كمية امتصاص أقصى كمية امتصاصماذا يعني هذا الكلام؟
+
+140
+00:11:43,670 --> 00:11:47,690
+خلّينا بس نشوف الصورة اللي هنا هلأ أنا كان في عندي
+
+141
+00:11:47,690 --> 00:11:52,510
+light source تمام؟ لمبة بتعطيني أطوال موجية مختلفة
+
+142
+00:11:52,510 --> 00:11:57,870
+هذه الأطوال الموجية المختلفة لابد من إنه أنا أختار
+
+143
+00:11:57,870 --> 00:12:02,770
+طول موجي واحد فقط إنه اللي يعبر من خلال الإنبوبة
+
+144
+00:12:02,770 --> 00:12:08,350
+وجزء منه يتم انتصاصه و الجزء الآخر ينفذ يروح على
+
+145
+00:12:08,350 --> 00:12:11,710
+ال detector ال detector يقيس كمية الضوء اللي وصلته
+
+146
+00:12:11,920 --> 00:12:16,930
+يعرف ليه تركيز العينةطبعا طيب على أي أساس هذا
+
+147
+00:12:16,930 --> 00:12:20,450
+الطول الموجي الواحد اللي لازم أختاره من عدة أطوال
+
+148
+00:12:20,450 --> 00:12:25,070
+موجية موجودة في ال light source بنختاره طبعا لإنه
+
+149
+00:12:25,070 --> 00:12:31,610
+لازم يكون المحلول يمتصه أقصى امتصاص إذا الجزء
+
+150
+00:12:31,610 --> 00:12:35,870
+النافذ يكون أقل كمية يمكن نفادها عبر هذا المحلول
+
+151
+00:12:35,870 --> 00:12:39,730
+مادامه ممتص أكبر كمية ممكنة من المحلول إذا اللي
+
+152
+00:12:39,730 --> 00:12:45,860
+نافذ هنا هيكون أقل كمية من الضوءإذن بما إنه امتص
+
+153
+00:12:45,860 --> 00:12:50,860
+أكبر كمية من الضوء the maximum absorbance of
+
+154
+00:12:50,860 --> 00:12:55,320
+light، تمام؟ معناها اللي نفد هو أقل كمية يمكن أن
+
+155
+00:12:55,320 --> 00:12:59,600
+تنفذ من هذا الضوء، تمام؟ إذن لابد من إنه اختيار
+
+156
+00:12:59,600 --> 00:13:05,740
+طول موجي واحد ومحدد، اللي خواص إنه عنده المحلول
+
+157
+00:13:05,740 --> 00:13:10,040
+بيقوم بـthe maximum absorbance فبالتالي هيكون the
+
+158
+00:13:10,040 --> 00:13:14,630
+least أو the lowesttransmitted light طبعا the
+
+159
+00:13:14,630 --> 00:13:23,410
+lowest transmitted light طيب بالنسبة لأنواع
+
+160
+00:13:23,410 --> 00:13:27,430
+الطاقة الضوئية احنا حكينا انه في عندي اكثر من نوع
+
+161
+00:13:27,430 --> 00:13:32,330
+من ال .. الأشعة الضوئية gamma x-ray ultraviolet
+
+162
+00:13:32,330 --> 00:13:37,090
+visible infrared radio waves طبعا هنا بيكون اقل
+
+163
+00:13:37,090 --> 00:13:43,200
+طول موجي طبعاو هنا أعلى طول موجي، إذا هنا هيكون
+
+164
+00:13:43,200 --> 00:13:48,760
+أكثرها طاقة و هنا هيكون أقلها طاقة، ليش؟ لإن
+
+165
+00:13:48,760 --> 00:13:57,020
+العلاقة عكسية ما بين الطول الموجي و الطاقة
+
+166
+00:13:57,670 --> 00:14:02,910
+تمام؟ إذا زادت الطاقة يقل الطول الموجي، هيك بهذا
+
+167
+00:14:02,910 --> 00:14:06,310
+الاتجاه بيزيد الطول الموجي، هذا أقلها طول موجي و
+
+168
+00:14:06,310 --> 00:14:10,950
+هذا أكثرها طول موجي، هيك بتزيد الطاقة، هذه أقلها
+
+169
+00:14:10,950 --> 00:14:15,950
+طاقة و هذه أعلاها طاقة من نوع الأشعة، تمام؟ إحنا
+
+170
+00:14:15,950 --> 00:14:19,700
+حكينا في ال visibleتمام؟ هذه المنطقة تبدأ
+
+171
+00:14:19,700 --> 00:14:23,000
+بالviolet لإنه أصلا المنطقة اللي فوقها ultraviolet
+
+172
+00:14:23,000 --> 00:14:27,120
+ما فوق البنفسجية فبتبدا بالviolet و بتنتهي بال red
+
+173
+00:14:27,120 --> 00:14:30,560
+لإن المنطقة اللي بعدها infrared تحت حمرا فتدرج
+
+174
+00:14:30,560 --> 00:14:33,640
+الألوان بيكون بدايته في منطقة ال visible بدايته
+
+175
+00:14:33,640 --> 00:14:37,840
+violet و نهايته red طبعا الطول الموجي يزداد من
+
+176
+00:14:37,840 --> 00:14:41,500
+منطقة الviolet باتجاه من؟ باتجاه ال red لإن احنا
+
+177
+00:14:41,500 --> 00:14:46,490
+هيك حكينااتجاه زيادة الطول الموجي هذه أقلها طاقة
+
+178
+00:14:46,490 --> 00:14:53,310
+وهذه أقلها طول موجي وهذه أعلاها طول موجي تمام؟ بما
+
+179
+00:14:53,310 --> 00:14:56,790
+أن هذه أقلها طول موجي وهذه أعلاها طول موجي إذا
+
+180
+00:14:56,790 --> 00:14:59,830
+منطقة ال visible هيكون بدايتها أقل طول موجي
+
+181
+00:14:59,830 --> 00:15:03,250
+ونهايتها أعلى طول موجي طيب
+
+182
+00:15:05,220 --> 00:15:09,620
+the visible spectrum إيش معنى هذا الجدول؟ بحكيلي
+
+183
+00:15:09,620 --> 00:15:14,960
+لو تم محلول عندي، في عندي محلول مثلا بيمتص اللون
+
+184
+00:15:14,960 --> 00:15:18,540
+ال violet عند هذا الطول الموجي أقصى امتصاص، إذا
+
+185
+00:15:18,540 --> 00:15:22,020
+اللون ال .. الضوء اللي نافذ من خلال المحلول راح
+
+186
+00:15:22,020 --> 00:15:27,070
+يكون من green ليلة، تمام؟ من green ليلةو هي هنا في
+
+187
+00:15:27,070 --> 00:15:30,830
+عندي شريح ليها بالكلام حكالي if a substance that
+
+188
+00:15:30,830 --> 00:15:34,050
+absorbs violet إذا كان هي بتمتص اللون ال move على
+
+189
+00:15:34,050 --> 00:15:39,090
+طول موجي 400 مثلا هي ال range ما بين 400 ل450 هي
+
+190
+00:15:39,090 --> 00:15:43,290
+مثلا محلول بيمتص اللون ال violet على طول موجي 400
+
+191
+00:15:43,290 --> 00:15:48,130
+تمام طبعا إحنا لما نحدد طول موجي واحد يعني مش
+
+192
+00:15:48,130 --> 00:15:52,550
+range ما بنحدد range لحتى يصطدم بالعينة أو
+
+193
+00:15:52,550 --> 00:16:00,440
+بالمحلول بنحدد طول موجي واحدطيب إذا كان بينضس
+
+194
+00:16:00,440 --> 00:16:05,480
+اللون ال violet معناه it reflect هيعكس اللون اللي
+
+195
+00:16:05,480 --> 00:16:09,900
+.. او الضوء اللي أطوعله yellow ل green yellow ل
+
+196
+00:16:09,900 --> 00:16:12,800
+green to measure the concentration of a blue
+
+197
+00:16:12,800 --> 00:16:17,420
+solution تمام؟ إذا كان في عندي محلول لونه blueفهذا
+
+198
+00:16:17,420 --> 00:16:22,380
+المحلول اللي لونه blue أفضل طول موجي لحتى تنقيزه
+
+199
+00:16:22,380 --> 00:16:27,620
+عنده أو تنقيز تركيزه هو ال 590 590 يقع في هذا ال
+
+200
+00:16:27,620 --> 00:16:32,200
+range إذا هو أفضل امتصاص أو أفضل ضوء يمتصه هو
+
+201
+00:16:32,200 --> 00:16:37,120
+اللون ال yellow وينفذ من خلاله اللون ال blue اللي
+
+202
+00:16:37,120 --> 00:16:41,590
+بيروح على ال detectorفقط هي لحتى نشوف إنه كيف ..
+
+203
+00:16:41,590 --> 00:16:45,810
+إيش معناه كلمة إنه الضوء إنه أو المحلول لابد من
+
+204
+00:16:45,810 --> 00:16:52,370
+إنه نختارله طول موجي يحدث عنده أقصى امتصاص تمام؟
+
+205
+00:16:52,370 --> 00:16:57,600
+وأقل ال transmittedطيب خلينا نشوف مع بعض beers law
+
+206
+00:16:57,600 --> 00:17:01,660
+قانون beers اش يعني beers law او اش يعني قانون
+
+207
+00:17:01,660 --> 00:17:05,840
+beer؟ when a light of appropriate wavelength
+
+208
+00:17:05,840 --> 00:17:10,100
+strikes a cuvette that contain a colored sample
+
+209
+00:17:10,100 --> 00:17:13,500
+some of the light is absorbed and the rest is
+
+210
+00:17:13,500 --> 00:17:16,710
+transmitted through the sample to the detectorو
+
+211
+00:17:16,710 --> 00:17:21,270
+هذا الكلام تقريبا .. تقريبا احنا وضحنا لو كان في
+
+212
+00:17:21,270 --> 00:17:24,930
+عندي light source و هذا ال light source انا طبعا
+
+213
+00:17:24,930 --> 00:17:29,770
+بيعطيني أطوال موجية يعني عديدة تمام؟ أطوال موجية
+
+214
+00:17:29,770 --> 00:17:34,240
+عديدة هذا ال light source لمبة مثلا لمبة ضوءفاحنا
+
+215
+00:17:34,240 --> 00:17:38,440
+بنختار طول موجي واحد لحتى يخترق ال cuvette أش يعني
+
+216
+00:17:38,440 --> 00:17:43,260
+cuvette؟ ال cuvette معناها الوعاء أو الانبوبة اللي
+
+217
+00:17:43,260 --> 00:17:47,400
+بنحطها في داخل الجهاز و بيكون فيها المحلول الملون
+
+218
+00:17:47,400 --> 00:17:52,200
+المراد قياسهنتيجة ال reaction أو نتيجة فحص أو
+
+219
+00:17:52,200 --> 00:17:56,820
+محلول بدنا نعرف تركيزه فإذا بنحطه بالكيوفيت اللي
+
+220
+00:17:56,820 --> 00:18:01,560
+هي عبارة عن انبوبة تمام بهذا الشكل و بنحطها في
+
+221
+00:18:01,560 --> 00:18:04,860
+الجهاز تمام فإذا الضوء هذا اللي جاي من ال light
+
+222
+00:18:04,860 --> 00:18:09,800
+source و اللي احنا حكيناه طول موجي معينيحدث عنده
+
+223
+00:18:09,800 --> 00:18:14,280
+إنه المحلول يمطصه أقصى امتصاص طبعا مش .. مش أنا
+
+224
+00:18:14,280 --> 00:18:18,180
+range ما بدي قاعدة لعديد من الأطوار الموجية تختارق
+
+225
+00:18:18,180 --> 00:18:22,820
+المحلول، لأ أنا بدي طول موجي واحد فقط ليختارق
+
+226
+00:18:22,820 --> 00:18:27,820
+المحلولتمام؟ فإن جزء من هذا الضوء يتم امتصاصه راح
+
+227
+00:18:27,820 --> 00:18:32,720
+يصيرله absorbed قولنا يتلاشى أو يتم امتصاصه من
+
+228
+00:18:32,720 --> 00:18:37,920
+داخل المحلول تمام؟ و ال .. ال rest الباقي ما تبقى
+
+229
+00:18:37,920 --> 00:18:42,810
+من هذا الضوء تمام؟اش راح يصيرله؟ راح يصيرله
+
+230
+00:18:42,810 --> 00:18:47,690
+transmitted تمام؟ ينفذ، transmitted يعني ينفذ و
+
+231
+00:18:47,690 --> 00:18:51,090
+وين راح يروح؟ راح يروح على ال detector اللي موجود
+
+232
+00:18:51,090 --> 00:18:55,570
+في الجهاز اش هو هذا ال detector؟ هو ال photo cell
+
+233
+00:18:55,570 --> 00:19:00,390
+او ال photo multiplier tube اللي موجودة في الجهاز
+
+234
+00:19:00,390 --> 00:19:04,850
+و اللي ذكرناها بأول slideطبعا طيب لو جينا حسبنا
+
+235
+00:19:04,850 --> 00:19:07,590
+نسبة ال transmittance النسبة المقاوية لل
+
+236
+00:19:07,590 --> 00:19:11,510
+transmittance عن افترض ان الضوء اللي جاي من ال
+
+237
+00:19:11,510 --> 00:19:15,870
+light source هو ال I NOT شدة الضوء الابتدائية I
+
+238
+00:19:15,870 --> 00:19:22,850
+NOTونفترض إن الضوء اللي نفد من خلال الـ tube وذهب
+
+239
+00:19:22,850 --> 00:19:26,850
+إلى الـ detector هو الـ IT شدت الضوء لـ
+
+240
+00:19:26,850 --> 00:19:31,130
+transmittance اللي هو النافذ طيب معناها ال percent
+
+241
+00:19:31,130 --> 00:19:36,350
+of transmittance هي الـ IT على ال I note درمية في
+
+242
+00:19:36,350 --> 00:19:39,410
+المية زي قانون النسبة المئوية العادى اللي إحنا
+
+243
+00:19:39,410 --> 00:19:43,090
+بنستخدمه بحياتنا اليومية الجزء على الكل درمية في
+
+244
+00:19:43,090 --> 00:19:47,570
+المية هو هذه نسبة لـ transmittanceطيب، هل هذا ما
+
+245
+00:19:47,570 --> 00:19:53,170
+قالوا بيرز كله؟ لأ، بيرز حكالنا كمان إنهif the
+
+246
+00:19:53,170 --> 00:19:56,630
+concentration of solution is increased the I
+
+247
+00:19:56,630 --> 00:20:02,470
+transmitted will decrease and the transmitted
+
+248
+00:20:02,470 --> 00:20:06,170
+percentage is decreased إيش معنى هذا الكلام؟ خلينا
+
+249
+00:20:06,170 --> 00:20:10,870
+نشوف لو كان في عندي .. لو زاد تركيز هذا المحلول
+
+250
+00:20:10,870 --> 00:20:15,590
+إذا هتزيد شدة لونه، تمام؟ إذا هتزيد العتامة لهذا
+
+251
+00:20:15,590 --> 00:20:20,960
+المحلول، تمام؟ زادت شدة لونه، اتخيلي هل ..الضوء
+
+252
+00:20:20,960 --> 00:20:26,780
+سينفذ بشكل كبير من خلاله، بالعكس، إذا كل ما زادت
+
+253
+00:20:26,780 --> 00:20:32,200
+شدة اللون تمام؟ أو كل ما زادت تركيز هيزيد شدة
+
+254
+00:20:32,200 --> 00:20:41,540
+اللون، إذا هذا المحلول راح ينتص أو راح يعني يتلاشى
+
+255
+00:20:41,540 --> 00:20:47,860
+من خلاله أو يتلاشى فيهأكثر تمام كمية الضوء الممتص
+
+256
+00:20:47,860 --> 00:20:53,240
+من خلاله أكثر ال absorbance أعلى تمام إذا كمية
+
+257
+00:20:53,240 --> 00:20:58,020
+الضوء النافذة هتكون أقل إذا هناك علاقة عكسية ما
+
+258
+00:20:58,020 --> 00:21:01,940
+بين ال IT و نسبة ال transmittance و التركيز كل ما
+
+259
+00:21:01,940 --> 00:21:06,020
+زاد التركيز كل ما زاد اللون الضوء اللي هيمتص أعلى
+
+260
+00:21:06,020 --> 00:21:10,930
+إذاالـ transmittance هيكون أقل و هذا هو قانون
+
+261
+00:21:10,930 --> 00:21:16,010
+بيرز، بينص .. هو بيرز درس علاقة التركيز بالـ
+
+262
+00:21:16,010 --> 00:21:19,590
+transmitted light و عبّر عنه بهذه العلاقة حتى إن
+
+263
+00:21:19,590 --> 00:21:24,110
+العلاقة عكسية طبعا، العلاقة عكسية ما بين مين و
+
+264
+00:21:24,110 --> 00:21:29,230
+مين، ما بين التركيز و ال transmittanceحكى انه كل
+
+265
+00:21:29,230 --> 00:21:34,330
+ما زاد التركيز بيصير في عندي بتقل شدة الضوء
+
+266
+00:21:34,330 --> 00:21:37,170
+المنبعث اللي هو ال transmitted اه ال I transmitted
+
+267
+00:21:37,170 --> 00:21:41,130
+او ال I T وبالتالي نسبة الضوء المنبعث بالنسبة للكل
+
+268
+00:21:41,130 --> 00:21:45,730
+هتكون ايضا اقليلةthe relationship between the
+
+269
+00:21:45,730 --> 00:21:48,410
+concentration and transmitted is not linear
+
+270
+00:21:48,410 --> 00:21:52,090
+العلاقة مش linear ما بين التركيز و ال
+
+271
+00:21:52,090 --> 00:21:55,890
+transmittance احنا شوي حكينا العلاقة عكسية و كلمة
+
+272
+00:21:55,890 --> 00:21:59,590
+linear يعني علاقة خطية او علاقة تردية اذا the
+
+273
+00:21:59,590 --> 00:22:03,790
+relation between concentration and transmittance
+
+274
+00:22:03,790 --> 00:22:07,410
+is not linear ليست خطية و ليست تردية انما they are
+
+275
+00:22:07,410 --> 00:22:12,530
+universally proportional هم يتناسبوا تناسب عكسي
+
+276
+00:22:12,530 --> 00:22:20,550
+universallyطيبوالعلاقة هاي بيوضحها هذا ال curve
+
+277
+00:22:20,550 --> 00:22:25,330
+هلأ هاي هنا على ال y-axis نسبة ال transmittance
+
+278
+00:22:25,330 --> 00:22:30,630
+نسبة الضوء المنبعث أو النافذ تمام؟ وعلى ال x-axis
+
+279
+00:22:30,630 --> 00:22:35,750
+في عندى التركيز ال concentration طيب خلينا نشوف
+
+280
+00:22:35,750 --> 00:22:38,890
+هاي أقل تركيز هنا هتكون تمام؟ بالقرب من ال zero
+
+281
+00:22:38,890 --> 00:22:43,770
+أقل تركيز هاد الأقل من التركيز إيش؟ إلها .. إلها
+
+282
+00:22:43,770 --> 00:22:51,020
+أعلى transmittanceتمام؟ و أعلى تراكيز إيش إلها؟
+
+283
+00:22:51,020 --> 00:22:54,820
+إلها أقل transmittance تمام؟ إلها أقل
+
+284
+00:22:54,820 --> 00:22:58,620
+transmittance إذا العلاقة عكسية و لو جينا نربطها
+
+285
+00:22:58,620 --> 00:23:02,380
+منطقيا .. لو نيجي .. لو نيجي نربطها منطقيا نرجع
+
+286
+00:23:02,380 --> 00:23:06,570
+للصورة اللي فيها تدرج الألوان هذهأعلى تركيز يعني
+
+287
+00:23:06,570 --> 00:23:10,630
+أعلى شدة لون، لو مر الضوء كمية قليلة اللي هتنفذ من
+
+288
+00:23:10,630 --> 00:23:15,870
+خلاله، تمام؟ لكن أقل تركيز يعني أقل شدة لون، إذا
+
+289
+00:23:15,870 --> 00:23:20,170
+مر الضوء من خلاله كمية كبيرة من الضوء راح تنفذ،
+
+290
+00:23:20,170 --> 00:23:24,730
+تمام؟ لو أنا جيبت لمبة وحطيت أمامها زجاجة شفافةهذه
+
+291
+00:23:24,730 --> 00:23:29,050
+الزجاجة الشفاف راح تنفذ لكمية ضوء كبيرة طيب لو
+
+292
+00:23:29,050 --> 00:23:33,850
+وانت هذه الزجاجة بلون أبيض هينفذ كمية ضوء أقل طيب
+
+293
+00:23:33,850 --> 00:23:39,490
+لو وانت هذه الزجاجة اللي أمام اللامبا بلون رمادي
+
+294
+00:23:39,490 --> 00:23:43,630
+إذا هتحجب ضوء أكثر وكمية نوق الضوء النافذ هتكون
+
+295
+00:23:43,630 --> 00:23:49,200
+أقل طيب لو وانتها بلون أسود هيقل الضوءأكثر فأكثر
+
+296
+00:23:49,200 --> 00:23:53,440
+النافذ من خلال قطعة الزجاج إذا هذه هي العلاقة ما
+
+297
+00:23:53,440 --> 00:23:55,980
+بين شدة اللون كل ما زادت شدة اللون يعني زاد
+
+298
+00:23:55,980 --> 00:24:00,840
+التركيز كمية الضوء النافذ هتكون قليلة هتكون كمية
+
+299
+00:24:00,840 --> 00:24:04,500
+الضوء اللي نافذ أو المنبعث عبر ال tube ال
+
+300
+00:24:04,500 --> 00:24:07,960
+transmitted light هيكون إشماله قليل
+
+301
+00:24:10,670 --> 00:24:16,530
+طيب، ماذا تصبح العلاقة linear، ترضية، إذا أنا مثلت
+
+302
+00:24:16,530 --> 00:24:21,890
+على ال Y axis لسالي بلوجة T، مش نسبة ال T، سالي
+
+303
+00:24:21,890 --> 00:24:26,450
+بلوجة T، و هذا سالي بلوجة T بنعبر عنه بال A اللي
+
+304
+00:24:26,450 --> 00:24:33,690
+هو absorbance، تمام؟ absorbanceطيب احنا طبعا كمية
+
+305
+00:24:33,690 --> 00:24:37,990
+الضوء الممتص كل ما زاد التركيز بيزيد اللون إذا
+
+306
+00:24:37,990 --> 00:24:43,630
+هيزيد الامتصاص فإذا العلاقة linear و ترضية ما بين
+
+307
+00:24:43,630 --> 00:24:48,990
+التركيز و الامتصاص و العلاقة عكسية universally not
+
+308
+00:24:48,990 --> 00:24:55,940
+linear ما بين التركيز و ال transmittanceطيب بير
+
+309
+00:24:55,940 --> 00:25:01,140
+لامبرت لاو اجى لامبرت ويتعاون مع بير وقصاه قانون
+
+310
+00:25:01,140 --> 00:25:07,260
+اخر هذا القانون سموه a يساوي a في b في c اش يعني a
+
+311
+00:25:07,260 --> 00:25:11,340
+في b في c؟ خلينا بالاول ناخد نص القانون و بعدين
+
+312
+00:25:11,340 --> 00:25:16,000
+ناخد اللي هو التعبير الحسابي او الرياضي عن هذا
+
+313
+00:25:16,000 --> 00:25:21,300
+القانونBeer Lambert قانونهم بينص على أنه
+
+314
+00:25:21,300 --> 00:25:26,720
+الـabsorbance of solution is directly proportional
+
+315
+00:25:26,720 --> 00:25:30,000
+يعني العلاقة linear directly proportional يتناسب
+
+316
+00:25:30,000 --> 00:25:33,400
+ترضيا العلاقة linear with ash with the
+
+317
+00:25:33,400 --> 00:25:39,940
+concentration of substanceتمام؟ إذا بير لحاله درس
+
+318
+00:25:39,940 --> 00:25:43,980
+علاقة ال transmittance مع ال concentration و حكى
+
+319
+00:25:43,980 --> 00:25:50,340
+إنه العلاقة عكسية بير و Lambert درسوا التركيز و ال
+
+320
+00:25:50,340 --> 00:25:53,880
+.. ال concentration مع ال absorbance و حكوا إنه
+
+321
+00:25:53,880 --> 00:25:58,760
+العلاقة ترضية و هذا الكلام صار بديهي و صرنا بنعرفه
+
+322
+00:25:59,250 --> 00:26:02,750
+طيب التعبير الرياضي عبروا عن ال A capital بال
+
+323
+00:26:02,750 --> 00:26:06,190
+absorbance يعني هلا بدهم يدرسوا ال absorbance طبعا
+
+324
+00:26:06,190 --> 00:26:12,970
+فلازم يصيغوله تعبير رياضي غير سالب log Tفحكوا إن
+
+325
+00:26:12,970 --> 00:26:20,070
+هو يساوي a small b في c، تمام؟ طيب a هي عبارة عن
+
+326
+00:26:20,070 --> 00:26:25,310
+ال molar absorptivity coefficient و ال b هو عبارة
+
+327
+00:26:25,310 --> 00:26:30,550
+عن المسار الضوء ما بين ال light source و العينة
+
+328
+00:26:30,740 --> 00:26:35,500
+الضوء اللي ذي يقطعه في الجهاز الضوء المسار أو
+
+329
+00:26:35,500 --> 00:26:39,040
+المسافة اللي ذي يقطعها الدوء داخل الجهاز ما بين ال
+
+330
+00:26:39,040 --> 00:26:42,280
+light source اللمبة طبعة الضوء اللي بتزودني أطوار
+
+331
+00:26:42,280 --> 00:26:47,040
+موجية عديدة و ما بين ال .. ال .. المكان اللي أنا
+
+332
+00:26:47,040 --> 00:26:50,020
+بحط فيه ال cuvette الإنبوبة اللي فيها المحلول
+
+333
+00:26:50,020 --> 00:26:55,860
+الملون المراد قياس ترجزه تمام هذه هي BB إلها علاقة
+
+334
+00:26:55,860 --> 00:26:59,960
+بالجهاز وليس .. يعني أنا مابلعب فيها إذا هي ثابت
+
+335
+00:26:59,960 --> 00:27:05,120
+.. ثابت إله علاقة بالجهاز المستخدم A إلها علاقة
+
+336
+00:27:05,120 --> 00:27:07,380
+بنوع المادة المراد قياسها
+
+337
+00:27:10,330 --> 00:27:15,310
+احنا حكينا في البداية إنه إذا أنا بدي أقيص تركيز
+
+338
+00:27:15,310 --> 00:27:20,590
+مجهول في عينة لابد إني أقيصه بدلالة معلوم ألا وهو
+
+339
+00:27:20,590 --> 00:27:26,350
+ال standard، تمام؟ و مثلا لو أنا بدي أشتغل أو أبدي
+
+340
+00:27:26,350 --> 00:27:32,060
+أعمل فحص السكربدي أعمل فحص السكر حكينا إنه إذا
+
+341
+00:27:32,060 --> 00:27:35,200
+بتتذكروا محاضرة ال delution رسمتلكم two tubes
+
+342
+00:27:35,200 --> 00:27:39,800
+حكيتلكم أنا بجيب عينة أو tube فيها العينة و ال
+
+343
+00:27:39,800 --> 00:27:43,580
+reagent متفاعلين طبعا ال reagent بضيفه أو بضيف
+
+344
+00:27:43,580 --> 00:27:48,080
+العينة لل reagent فيحدث تغير تغير في اللون و أيضا
+
+345
+00:27:48,080 --> 00:27:51,440
+بضيف ال standard لل reagent و يحدث تغير في اللون
+
+346
+00:27:51,550 --> 00:27:55,830
+إذا كانت تغير في اللون الحادث في العينة نصف التغير
+
+347
+00:27:55,830 --> 00:27:58,570
+الحادث في ال standard إذا تركيزه نصف تركيز ال
+
+348
+00:27:58,570 --> 00:28:03,430
+standard وإذا كانت تغير الحادث في tube العينة ضعف
+
+349
+00:28:03,430 --> 00:28:11,420
+فإذا التركيز ضعف تركيز ال standardو هذا الكلام ال
+
+350
+00:28:11,420 --> 00:28:15,880
+.. النظري اللي احنا بنحكي ل .. لحتى ان نوصل فكرة
+
+351
+00:28:15,880 --> 00:28:20,220
+طب الكلام اللي عملي او الكلام اللي علمي ما .. اش
+
+352
+00:28:20,220 --> 00:28:25,620
+يعني؟ شوفوا معايا لو انا ضفت على reaction تعينة
+
+353
+00:28:25,620 --> 00:28:29,950
+طبعا عشان ا .. اقيس نسبة السكر في الدمرح يتفاعل ال
+
+354
+00:28:29,950 --> 00:28:34,550
+reagent مع السكر ويعطيني measurable change، تغير،
+
+355
+00:28:34,550 --> 00:28:39,190
+يمكن قياسه تغير في اللون فمثلا ممكن يتحول اللون
+
+356
+00:28:39,190 --> 00:28:43,150
+المحلول من colorless، من عديم اللون إلى لون pink،
+
+357
+00:28:43,150 --> 00:28:47,470
+ينتجلي مادةو اللون هذه .. المادة هاي لونها pink
+
+358
+00:28:47,470 --> 00:28:51,810
+تمام؟ فهذه هي اللي بدي أقيس ال .. ال .. ال
+
+359
+00:28:51,810 --> 00:28:55,710
+absorbance تبعها هي اللي أنا بدي أمرر ضوء من
+
+360
+00:28:55,710 --> 00:29:01,050
+خلالها و أشوف كام هي تنتص من الضوء و كام تنفذ
+
+361
+00:29:01,050 --> 00:29:05,890
+علشان يعبرلي كمية الضوء الممتص أو كمية الضوء
+
+362
+00:29:05,890 --> 00:29:08,810
+النافذ عن تركيزها، عن شدة لونها
+
+363
+00:29:16,970 --> 00:29:22,830
+طبعا يكون في عندي reagent هذا ال reagent أناباضيف
+
+364
+00:29:22,830 --> 00:29:28,730
+لإله standard و ال standard بيكون محلول من نفس نوع
+
+365
+00:29:28,730 --> 00:29:32,770
+الفحص يعني أنا بشتغل فحص سكر لازم يكون محلول سكري
+
+366
+00:29:32,770 --> 00:29:36,450
+معلوم التركيز بشتغل فحص protein لازم يكون محلولي
+
+367
+00:29:36,450 --> 00:29:40,170
+protein معلوم التركيز بشتغل فحص دهون لازم يكون
+
+368
+00:29:40,170 --> 00:29:44,910
+محلول دهون معلوم التركيز مابنفع أنه مثلا أكون
+
+369
+00:29:44,910 --> 00:29:49,170
+بشتغل فحص سكر للعينة و فحص مثلا .. او دهون لل
+
+370
+00:29:49,170 --> 00:29:54,370
+standard غلطغلط، لازم المادة اللي ناتجها الملونة
+
+371
+00:29:54,370 --> 00:29:59,150
+هتكون نفسها، تمام؟ المادة الملونة والناتج هتكون
+
+372
+00:29:59,150 --> 00:30:04,050
+نفسها علشان يكون لها نفس ال molar absorptivity
+
+373
+00:30:04,050 --> 00:30:08,810
+coefficient، تمام؟ طيب، طب لو أنا جيت .. طبقت هذا
+
+374
+00:30:08,810 --> 00:30:15,230
+القانون مرة لعينة مجهولة و مرة لل standard فهيو
+
+375
+00:30:15,230 --> 00:30:20,190
+مثلا عندي ال absorbanceلل X اللي هو المجهول يساوي
+
+376
+00:30:20,190 --> 00:30:25,050
+A في B في تركيز ال X اللي هو احنا ما بنعرفه ال
+
+377
+00:30:25,050 --> 00:30:27,530
+absorbance لل standard طبعا ال absorbance هدى
+
+378
+00:30:27,530 --> 00:30:30,550
+قراءات بيعطينيها الجهاز يعني هو اللى بيقيص كمية ال
+
+379
+00:30:30,550 --> 00:30:33,730
+absorbance كمية الضوء المتلاشى بيصلوا ل
+
+380
+00:30:33,730 --> 00:30:38,030
+transmittance على ال detector وبيطرحوا من ال .. ال
+
+381
+00:30:38,030 --> 00:30:42,150
+ضوء كمية الضوء الأساسية اللى جاية من ال source من
+
+382
+00:30:42,150 --> 00:30:47,030
+المصدر وبيعرفوا كمية ال absorbanceطمام؟ طيب فال
+
+383
+00:30:47,030 --> 00:30:50,590
+absorbance لل standard يساوي a في b في ال
+
+384
+00:30:50,590 --> 00:30:53,870
+concentration لل standard طب لو أنا جيت قسمت ال
+
+385
+00:30:53,870 --> 00:30:57,150
+absorbance لل standard لل x على ال absorbance لل
+
+386
+00:30:57,150 --> 00:31:02,830
+standard جيت قسمتهم على بعض مثل هيكabsorbance لل X
+
+387
+00:31:02,830 --> 00:31:06,850
+على absorbance لل standard طيب مش احنا حكينا انه
+
+388
+00:31:06,850 --> 00:31:11,110
+ال .. ال .. ال .. ال .. ال .. ال standard و ال ..
+
+389
+00:31:11,110 --> 00:31:15,850
+ال .. ال sample لازم يكونوا من نفس النوع و ينتجولي
+
+390
+00:31:15,850 --> 00:31:20,450
+بعد التفاعل نفس المادة و هيكونلها نفس ال A تمام
+
+391
+00:31:20,450 --> 00:31:24,070
+اللي هو ال molar absorptivity معامل الانتصاص لإلها
+
+392
+00:31:24,830 --> 00:31:29,590
+تمام إذا a عمّا a هتروح طيب و ال b مش هي واحدة
+
+393
+00:31:29,590 --> 00:31:32,350
+لإنه أنا بستخدم نفسي الجهاز و هي أصلاً إلها علاقة
+
+394
+00:31:32,350 --> 00:31:37,390
+بالجهاز و أنا مابغ .. يعني .. يعني صعب أ .. ألعب
+
+395
+00:31:37,390 --> 00:31:42,490
+فيها أو أغير فيها فإذا ..دي ايضا هتروح فاش هيضل
+
+396
+00:31:42,490 --> 00:31:48,370
+عندى ال absorbance ل ال test او ل ال unknown على
+
+397
+00:31:48,370 --> 00:31:52,190
+ال absorbance ل ال standard و يساوي تركيز ال test
+
+398
+00:31:52,190 --> 00:31:56,190
+او ال unknown او ال patient على تركيز ال standard
+
+399
+00:31:56,190 --> 00:31:59,750
+طيب مين اللى عندي مجهول؟ هدول بيعطيني اياهم الجهاز
+
+400
+00:31:59,750 --> 00:32:03,530
+و هذا معلومة تركيز معروف اذا تركيز ال unknown او
+
+401
+00:32:03,530 --> 00:32:07,230
+ال test او ال patient sample هو اللى مش معروفلو
+
+402
+00:32:07,230 --> 00:32:10,730
+أنا جيت طلعته في علاقة هيحكيلي ان هو عبارة عن ال
+
+403
+00:32:10,730 --> 00:32:13,610
+absorbance لل test او لل X على ال absorbance لل
+
+404
+00:32:13,610 --> 00:32:17,450
+standard درب تركيز ل standard تمام؟
+
+405
+00:32:20,050 --> 00:32:23,750
+طيب هناك requirements for the Beers Lambert Law to
+
+406
+00:32:23,750 --> 00:32:29,730
+hold true هناك لحتى ال Beers Lambert Law هاي قانون
+
+407
+00:32:29,730 --> 00:32:33,770
+Beero Lambert انهم .. انه يتم تطبيقه بطريقة صحيحة
+
+408
+00:32:33,770 --> 00:32:37,910
+و دقيقة لابد ان يكون في عندى شروط تتوفر في المحلي
+
+409
+00:32:37,910 --> 00:32:42,430
+للمستخدمة و شروط تتوفر في الجهاز المستخدم للقياسات
+
+410
+00:32:42,430 --> 00:32:46,110
+اول اشي solution requirement الشروط اللى .. الواجب
+
+411
+00:32:46,110 --> 00:32:53,440
+توفرها بال ..بالمحاليل لازم تكون the same نفس
+
+412
+00:32:53,440 --> 00:32:57,720
+المحاليل حكينا فحص السكر، السكر اللي موجود في
+
+413
+00:32:57,720 --> 00:33:02,220
+العينة مع ال reagent بيعطيلي مثلا مادة، المادة ده
+
+414
+00:33:02,220 --> 00:33:08,920
+دي لنفرض انها Y تمام؟ و لونها pinkلازم ال .. ال
+
+415
+00:33:08,920 --> 00:33:13,060
+standard يكون محلول سكري معلوم التركيز عشان لما
+
+416
+00:33:13,060 --> 00:33:17,260
+أضيفه مع ال reagent ال reagent يتفاعل و يعطيني نفس
+
+417
+00:33:17,260 --> 00:33:21,320
+المادة why اللي إلها نفس اللون pink تمام؟
+
+418
+00:33:23,350 --> 00:33:28,710
+والمادتين هدول اللي ده نتجوا إما في تيوب ال test
+
+419
+00:33:28,710 --> 00:33:33,670
+أو في تيوب ال standard اللي هم نفس ال A نفس معامل
+
+420
+00:33:33,670 --> 00:33:37,370
+الامتصاص تمام؟ اللي هم نفس ال small a اللي هو
+
+421
+00:33:37,370 --> 00:33:40,390
+معامل الامتصاص اللي هو ال molar absorptivity
+
+422
+00:33:40,390 --> 00:33:45,300
+coefficientطبعا يا بنات هذه ال .. ال .. ال إيه؟
+
+423
+00:33:45,300 --> 00:33:51,220
+تعتمد على نوع المادة و ليس تركيزها يعني مثلا الدوق
+
+424
+00:33:51,220 --> 00:33:55,840
+لما ينفذ خلال ماء غير ما ينفذ خلال زيت غير ما ينفذ
+
+425
+00:33:55,840 --> 00:33:59,220
+خلال خل أو خلال كحول أو خلال مادة لونها pink أو
+
+426
+00:33:59,220 --> 00:34:03,820
+خلال مادة لونها red أو مادة blue يعني بيعتمد على
+
+427
+00:34:03,820 --> 00:34:08,540
+نوع المادة و لونها و ليس على شدة لونها و تركيزها
+
+428
+00:34:08,540 --> 00:34:15,600
+تمام؟ طيبو أيضًا إذا اتفقنا ليش لازم يكونوا دسام
+
+429
+00:34:15,600 --> 00:34:19,960
+عشان يعطون نفس ال .. ال .. ال product نفس الناتج،
+
+430
+00:34:19,960 --> 00:34:24,880
+نفس اللون و بيتم طب أيضًا ال .. ال a تروح مع ال a
+
+431
+00:34:24,880 --> 00:34:30,510
+هنا و يتم تطبيق القانون بشكل صحيحتمام؟ و أيضًا
+
+432
+00:34:30,510 --> 00:34:36,750
+المادة الناتجة هي dy تكون ثابتة خلال فترة ال
+
+433
+00:34:36,750 --> 00:34:41,630
+reaction تظلها the same throughout the test تظلها
+
+434
+00:34:41,630 --> 00:34:46,790
+زي ما هي طول فترة الفحص إيش يعني؟ يعني not .. not
+
+435
+00:34:46,790 --> 00:34:51,630
+associate or dissociate يعني ما .. ما أشوفها ترثبت
+
+436
+00:34:51,870 --> 00:34:58,850
+تكسرت، تحللت، تبخرت، امتصت رطوبة، خفت، شدت اللون
+
+437
+00:34:58,850 --> 00:35:02,110
+فيها؟ لأ لازم تكون ثابتة طول فترة الفحص عشان انا
+
+438
+00:35:02,110 --> 00:35:05,530
+لما اخد قراءة على الجهاز الجهاز يعطيني قراءة
+
+439
+00:35:05,530 --> 00:35:10,190
+دقيقة، تمام؟ اذا لازم يكونوا the same و لازم
+
+440
+00:35:10,190 --> 00:35:14,070
+يكونوا ايضا the same throughout the test not
+
+441
+00:35:14,070 --> 00:35:20,130
+associate or dissociateأيضًا خلّيني ندكر كمان فكرة
+
+442
+00:35:20,130 --> 00:35:25,050
+تانية، اتخيلي لو أنا كان عندي عينة و العينة هذه تم
+
+443
+00:35:25,050 --> 00:35:28,950
+إضافتها إلى reagent علشان يتفاعل لي مع .. مع السكر
+
+444
+00:35:28,950 --> 00:35:32,810
+اللي فيها، مع ال glucose اللي فيها و يعطيني Y
+
+445
+00:35:32,810 --> 00:35:37,680
+product اللي لونه pinkلو أنا استخدمت different
+
+446
+00:35:37,680 --> 00:35:41,100
+standard مثلا يعني protein standard محلول ال
+
+447
+00:35:41,100 --> 00:35:45,100
+protein معلومة تركيزي و أضفته ل .. هذا ال standard
+
+448
+00:35:45,100 --> 00:35:48,620
+إلى .. إلى reagent السكر
+
+449
+00:35:50,560 --> 00:35:54,380
+معناها ال .. ال .. ال protein هذا ممكن يت .. ممكن
+
+450
+00:35:54,380 --> 00:35:58,640
+يتفاعل و ممكن لا يتفاعل مع reagent السكر فمثلا لو
+
+451
+00:35:58,640 --> 00:36:03,040
+تفاعل ممكن يعطيني مادة مش Y مادة Z لأنها move طب
+
+452
+00:36:03,040 --> 00:36:10,460
+أنا بنفع أقارن المادة Yفي العينة مجهولة التركيز
+
+453
+00:36:10,460 --> 00:36:15,920
+اللي لونها pink تمام في المادة Z اللي نتجت من تيوب
+
+454
+00:36:15,920 --> 00:36:20,100
+ال standard اللي لونها move غلط مابنفع عشان هيك
+
+455
+00:36:20,100 --> 00:36:23,260
+لازم يكونوا the same نفس المادة نفس التركيب و نفس
+
+456
+00:36:23,260 --> 00:36:26,740
+ال reaction يحدث عشان يعطيني نفس ال product و نفس
+
+457
+00:36:26,740 --> 00:36:30,860
+اللون بغض النظر عن شدته تمام لإنه ممكن التركيز ..
+
+458
+00:36:30,860 --> 00:36:33,960
+تركيز العينة يكون مختلف عن تركيز ال standard لازم
+
+459
+00:36:33,960 --> 00:36:38,530
+يعطيني نفس المادة نفس اللوننوعه نفس نوع اللون يعني
+
+460
+00:36:38,530 --> 00:36:43,430
+pink, mauve, blue, green, yellow هذه الألوان يعني
+
+461
+00:36:43,430 --> 00:36:47,550
+بس أنا بحكي على نوع اللون يعني اسم اللون تمام؟ و
+
+462
+00:36:47,550 --> 00:36:52,890
+لحتى أيضا يكون لهم نفس السبت a small اللي هو ال
+
+463
+00:36:52,890 --> 00:36:57,450
+coefficient of absorptivity of substance عشان يتم
+
+464
+00:36:57,450 --> 00:37:01,110
+تطبيق قانون له صحيح و يروح ال a مع ال a و يروح ال
+
+465
+00:37:01,110 --> 00:37:07,080
+b مع ال b و يتم تطبيق قانون Bear Lambert لهطيب إيه
+
+466
+00:37:07,080 --> 00:37:11,880
+instrument requirement؟الشروط الواجب توفرها في
+
+467
+00:37:11,880 --> 00:37:17,060
+الجهاز طبعا لازم يكون at satisfactory إله يعني
+
+468
+00:37:17,060 --> 00:37:21,380
+درجة مرضية من ال accuracy الدقة ال sensitivity
+
+469
+00:37:21,380 --> 00:37:25,520
+الحساسية and reproducibility منتج يعني ما .. يعني
+
+470
+00:37:25,520 --> 00:37:28,860
+ما بده يقرأ لعينتين تلاتة وبيطلف بده صيانة بده إيه
+
+471
+00:37:28,860 --> 00:37:33,740
+عدد calibration بده أرجع شغله مرة تانية بي ..
+
+472
+00:37:33,740 --> 00:37:39,620
+بيعلج مثلا أو إشي فهذه كل هالشغلات لازم يكون طبعا
+
+473
+00:37:39,850 --> 00:37:45,130
+بيشتغل بكفاءة عالية ده cubits الأنابيب اللي إحنا
+
+474
+00:37:45,130 --> 00:37:52,930
+بنستخدمهم لحتى يعني يتم إدراجهم داخل الجهاز و فيهم
+
+475
+00:37:52,930 --> 00:37:57,790
+المحلول الملون و يتم قياس عبرهم هادول لازم يكونوا
+
+476
+00:37:57,790 --> 00:38:02,840
+أول إشي cleanو أيضا free from scratches، إيش يعني
+
+477
+00:38:02,840 --> 00:38:08,580
+free from scratches؟ يعني خالي من الشقوق، الكثور،
+
+478
+00:38:08,580 --> 00:38:17,960
+الخدوش، الشطوبلازم تكون ملساق و تكون يعني سليمة ال
+
+479
+00:38:17,960 --> 00:38:21,240
+tube هاي مافيش فيها اي خدوش او شقوق او كسور لإن
+
+480
+00:38:21,240 --> 00:38:25,480
+هذا هيأثر على مسار الضوء من خلالها و جزء من الضوء
+
+481
+00:38:25,480 --> 00:38:32,180
+راح يتبدد بسبب انه هي مشققة او عليها كسور او خدوش
+
+482
+00:38:32,180 --> 00:38:38,600
+او لإنها مش نظيفة من برا فبالتالي هذا هيأثر على
+
+483
+00:38:38,770 --> 00:38:42,850
+كمية الضوء اللي هيقرأها الجهاز او يسجلها الجهاز
+
+484
+00:38:42,850 --> 00:38:49,090
+طيب لو انا جيت تصور التصور منطقي من ايش مكون
+
+485
+00:38:49,090 --> 00:38:53,590
+الجهاز لابد ان يكون مكون من light source مصدر
+
+486
+00:38:53,590 --> 00:38:58,130
+للضوء بيعطيني أطوال موجية معينة ولكن هناك طول موجي
+
+487
+00:38:58,130 --> 00:39:02,150
+واحد اللي يجب ان يخترق الى ال .. يعني او يصل الى
+
+488
+00:39:02,150 --> 00:39:04,830
+العينة او المحلول .. ال .. ال tube اللي فيها
+
+489
+00:39:04,830 --> 00:39:08,150
+العينة أو ال tube اللي فيها المحلولطبعا فلابد من
+
+490
+00:39:08,150 --> 00:39:11,310
+أنه يكون ما بين ال light source و ال sample holder
+
+491
+00:39:11,310 --> 00:39:16,890
+يكون في عندي wavelength selector تمام؟ و هو عازل
+
+492
+00:39:16,890 --> 00:39:22,230
+أو أدالي عازل طول موجي واحد ليعبر من خلال ال tube
+
+493
+00:39:22,230 --> 00:39:27,110
+ليش؟ لأن هذا الطول الموجي لابد أن يكون عليه أقصى
+
+494
+00:39:27,110 --> 00:39:32,530
+كمية امتصاص من المحلول المراد قياسهطبعا جزء من
+
+495
+00:39:32,530 --> 00:39:36,570
+الضوء سيتم امتصاصه و جزء سينفذ راح يروح الى ال
+
+496
+00:39:36,570 --> 00:39:40,130
+detector هذا ال detector راح يحول الطاقة الضوئية
+
+497
+00:39:40,130 --> 00:39:45,430
+اللى وصلته الى طاقة كهربائية و راح يطلع لي لابد ان
+
+498
+00:39:45,430 --> 00:39:49,070
+يكون في عندي شاشة او مكان اقرأ عليه النتيجة فراح
+
+499
+00:39:49,070 --> 00:39:52,630
+يكون في عندي read out مكان تطلع عليه النتيجة تبعتي
+
+500
+00:39:52,630 --> 00:39:58,720
+و النتيجة يا بنات بتكون عبارة عن شد الطيارمعبّر عن
+
+501
+00:39:58,720 --> 00:40:03,200
+كمية الضوء إما ال transmittance أو ال absorbance
+
+502
+00:40:03,200 --> 00:40:07,320
+طبعا؟ طب على أي أساس هو بيختار ليه .. يعطيني ال
+
+503
+00:40:07,320 --> 00:40:10,360
+transmittance أو ال absorbance؟ أنا بختار لما
+
+504
+00:40:10,360 --> 00:40:16,440
+ببرمج الجهاز أو لما بدي أجيأجهزه لقراءة فحص معين
+
+505
+00:40:16,440 --> 00:40:22,040
+أنا بختار هذا الطول الموجي اللي بده الواعي المحدد
+
+506
+00:40:22,040 --> 00:40:25,660
+اللي بده يصطدم بالعينة وانا بختار الجهاز يعطيني
+
+507
+00:40:25,660 --> 00:40:28,540
+قراءة Transmittance إذا Transmittance قعدوا ال bus
+
+508
+00:40:28,540 --> 00:40:31,920
+بده يحسب الضوء اللي يواصل لل detector يحولوا لطيار
+
+509
+00:40:31,920 --> 00:40:35,090
+كهربائي و يطلعوا على readoutإذا بدياه يقرألي
+
+510
+00:40:35,090 --> 00:40:37,790
+absorbance معناها هو بديه .. بديه يحسب ال
+
+511
+00:40:37,790 --> 00:40:41,910
+transmittance و يطرحه من الضوء الأساسي و يحسبلي
+
+512
+00:40:41,910 --> 00:40:46,450
+كمية ال absorbance و هذا ..ال absorbance هو اللي
+
+513
+00:40:46,450 --> 00:40:52,310
+راح يتحول لطيار كهربائي ويعطيني قيمته على ال
+
+514
+00:40:52,310 --> 00:40:55,950
+readout، اذا انا بحدد شغلتان، انا بحدد ال
+
+515
+00:40:55,950 --> 00:40:59,070
+wavelength، الطول الموجي المعين اللي يعزله ال
+
+516
+00:40:59,070 --> 00:41:02,530
+selector، وانا بحدد القراءة تظهر على هيئة
+
+517
+00:41:02,530 --> 00:41:06,820
+transmittance أو absorbanceتمام؟ طيب كيف ب .. بحدد
+
+518
+00:41:06,820 --> 00:41:11,540
+هذه الشركات و الفحوصات اللي بتجيني من الشركة
+
+519
+00:41:11,540 --> 00:41:15,640
+بيحكيلي والله فحص السكر يفضل انك انت تقرا ايه على
+
+520
+00:41:15,640 --> 00:41:20,400
+طول موجي خمسمية فحص الهوموجلوبين يفضل انك انت تقرا
+
+521
+00:41:20,400 --> 00:41:24,320
+ايه على طول موجي خمسمية واربعين فحسب لون الن ..
+
+522
+00:41:24,320 --> 00:41:29,240
+المحلول الناتج بعد التفاعلتمام؟ أو lonely product
+
+523
+00:41:29,240 --> 00:41:34,340
+اللي ناتج بيحدده الشركات الطول الموجي المناسب
+
+524
+00:41:34,340 --> 00:41:38,300
+لقراءة النتيجة عليه اللي بيكون عنده أقصى كمية
+
+525
+00:41:38,300 --> 00:41:44,670
+امتصاص وأقل كمية transmittance تمام؟إذن لازم يكون
+
+526
+00:41:44,670 --> 00:41:48,210
+في عندي stable source of radiation energy مصدر
+
+527
+00:41:48,210 --> 00:41:52,630
+ثابت للطاقة لازم يكون في عندي أداة that isolate
+
+528
+00:41:52,630 --> 00:41:55,950
+restricted region of the spectrum لازم يكون عندي
+
+529
+00:41:55,950 --> 00:42:04,310
+أداة تعزل restricted محدد أو يعني طول موجي محدد من
+
+530
+00:42:04,310 --> 00:42:08,210
+الطيف أو من الضوء transparent container هيكون في
+
+531
+00:42:08,210 --> 00:42:15,020
+عندي وعاءو شفاف هذا يوضع فيه المحلول الملون او
+
+532
+00:42:15,020 --> 00:42:18,740
+ناتج التفاعل او اللي هي نتائج الفحص على اللي يتم
+
+533
+00:42:18,740 --> 00:42:21,980
+قراءته لازم يكون في عندي detector و هذا ال
+
+534
+00:42:21,980 --> 00:42:25,420
+detector وظيفته انه يحول اللي هو ال radiation
+
+535
+00:42:25,420 --> 00:42:29,420
+energy او الطاقة الضوئية الى electrical energy الى
+
+536
+00:42:29,420 --> 00:42:34,860
+طاقة كهربائية و هذه كيمية التيار الكهربائي او شدة
+
+537
+00:42:34,860 --> 00:42:40,770
+التيار الكهربائي اللي بينتج من ال detectorبيظهر
+
+538
+00:42:40,770 --> 00:42:47,650
+على ال readout على شاشة أو يعني مكان مخصص لقراءة
+
+539
+00:42:47,650 --> 00:42:53,510
+النتائج تمام؟ إذا هذا هو تمثيل لمكونات الجهاز من
+
+540
+00:42:53,510 --> 00:42:58,150
+الداخل سواء كان photometry أو visible يعني UV
+
+541
+00:42:58,150 --> 00:43:02,650
+light photometry أو visible photometryطيب ال
+
+542
+00:43:02,650 --> 00:43:08,670
+slides القادمة رح تتحدث عن مكونات أو تفاصيل عن هذه
+
+543
+00:43:08,670 --> 00:43:12,550
+المكونات تفاصيل مكونات الجهاز نبدأ بال light
+
+544
+00:43:12,550 --> 00:43:17,990
+source هلأ في عندي أجهزة بيعني ال light source
+
+545
+00:43:17,990 --> 00:43:21,890
+مصدر الضوء بيعطيني أطوار موجية تقع في منطقة ال
+
+546
+00:43:21,890 --> 00:43:26,810
+ultraviolet احنا هنا ذكرناإنه في عندي مناطق أو
+
+547
+00:43:26,810 --> 00:43:31,490
+يعني regions من الطاقة الضوئية وكل طاقة ضوئية إلها
+
+548
+00:43:31,490 --> 00:43:36,370
+طول موجي معين في عندي أجهزة بتعطيني أطوار موجية
+
+549
+00:43:36,370 --> 00:43:40,190
+تقع في منطقة ال ultraviolet طب يعني ال ultraviolet
+
+550
+00:43:40,190 --> 00:43:45,880
+هدي إيش هيكون range الأطوار الموجية تبعتها؟من 160
+
+551
+00:43:45,880 --> 00:43:51,180
+ل 375 هذه اللمبة اللي بتعطيني أطوال موجية تقع في
+
+552
+00:43:51,180 --> 00:43:54,560
+منطقة ال ultraviolet اللي هو الأشعة فوق البنفسجية
+
+553
+00:43:54,560 --> 00:43:59,000
+و اللي بتعطيني أطوال موجية في range طبعا أطوال
+
+554
+00:43:59,000 --> 00:44:06,140
+موجية في range ما بين 160 ل 375 بتكون إما لمبة
+
+555
+00:44:06,140 --> 00:44:10,220
+Deuterium أو Hydrogen مصنوعة من ال Deuterium أو ال
+
+556
+00:44:10,220 --> 00:44:15,140
+Hydrogenتمام؟ إذا بتكون في عندي لمبة Deuterium أو
+
+557
+00:44:15,140 --> 00:44:19,760
+Hydrogen بتعطيني أطوال موجية معاقم يعني في range
+
+558
+00:44:19,760 --> 00:44:25,340
+ما بين 160 ل 375 و في النهاية ال selector بيعزللي
+
+559
+00:44:25,340 --> 00:44:29,480
+طول موجي واحد فقط ليصطدم بالعينة و بيكمل الشغل
+
+560
+00:44:29,480 --> 00:44:34,800
+تمام؟ في ال visible region إذا كان الجهاز بيعطيني
+
+561
+00:44:34,800 --> 00:44:40,250
+أو بيقرأ فقط في منطقة الضوء المرئيطمام؟ معناها
+
+562
+00:44:40,250 --> 00:44:44,210
+هيعطيني ال light source أطوار الموجية ما بين 350
+
+563
+00:44:44,210 --> 00:44:49,090
+ل2500 نانومتر و اللمبة اللي هتكون موجودة في الجهاز
+
+564
+00:44:49,090 --> 00:44:52,310
+هي تنجستن إذا في فحوصات تنقرأ على منطقة ال UV
+
+565
+00:44:52,310 --> 00:44:56,010
+light و في فحوصات تتنقرأ على ال visible ال UV
+
+566
+00:44:56,010 --> 00:45:01,190
+light بيكون الجهاز اللي بيقرأ الفحوصات هاي ال
+
+567
+00:45:01,190 --> 00:45:04,270
+light source تبعه إما Deuterium lamp أو hydrogen
+
+568
+00:45:04,270 --> 00:45:07,550
+lamp و الأطوار الموجية اللي بتوفرها هاي ال lampمن
+
+569
+00:45:07,550 --> 00:45:12,010
+160 ل 375 اما الفحوصات اللى بتقرا على ال visible
+
+570
+00:45:12,010 --> 00:45:18,090
+region ف .. او في ال visible photometer بيكون ال
+
+571
+00:45:18,090 --> 00:45:21,830
+.. الجهاز اللمبة طبعته عبارة عن tungsten و بتعطينى
+
+572
+00:45:21,830 --> 00:45:26,710
+أطوال موجية ما بين 350 ل 2500 نانومتر احنا عندنا
+
+573
+00:45:26,710 --> 00:45:31,550
+جهاز مكتوب عليه UV شرطة visible فى
+
+574
+00:45:31,550 --> 00:45:35,200
+spectrophotometerيعني بيعطيني أطواع الموجية في
+
+575
+00:45:35,200 --> 00:45:38,320
+منطقة ال ultraviolet و في ال visible الفحوصات اللي
+
+576
+00:45:38,320 --> 00:45:41,960
+بتنقرأ علي ال UV light ممكن أقرأها عليه و الفحوصات
+
+577
+00:45:41,960 --> 00:45:45,280
+اللي بتنقرأ علي ال visible أيضا بتنقرأ عليه إذا هو
+
+578
+00:45:45,280 --> 00:45:50,640
+هيزودلي أطواع الموجية ما بين 160 إلى 2500 نانومتر
+
+579
+00:45:50,640 --> 00:45:55,310
+و هيكون عنده lump نوعين أو two lumpsالـ Deuterium
+
+580
+00:45:55,310 --> 00:45:59,950
+و Hydrogen Lamp .. Deuterium او Hydrogen هذه لما
+
+581
+00:45:59,950 --> 00:46:03,590
+بدي اش .. لما بدي ادخله طول موجي في منطقة ال UV
+
+582
+00:46:03,590 --> 00:46:08,550
+مثلا 200 او 260 معناها هو هيحولها .. هيشغل ال
+
+583
+00:46:08,550 --> 00:46:12,150
+Deuterium او ال Hydrogen Lamp ويطيني الطول الموجي
+
+584
+00:46:12,150 --> 00:46:16,030
+اللي بديها طبعا؟ لو انا مثلا بدي اقرأ على 400 او
+
+585
+00:46:16,030 --> 00:46:19,670
+540 اللي هو مغلوب اني بنقرأ على 540 يعني على منطقة
+
+586
+00:46:19,670 --> 00:46:23,340
+ال visible طبعا؟معناها اللي هتشتغل ال tungsten
+
+587
+00:46:23,340 --> 00:46:28,060
+بيكون عنده two types of lamp و بيشغل واحدة منهم
+
+588
+00:46:28,060 --> 00:46:31,280
+حسب نوع الطول الموجي اللي أنا دخلته احنا حكينا
+
+589
+00:46:31,280 --> 00:46:34,900
+الطول الموجي انا بدخله و انا اللي بحدده و بيكون
+
+590
+00:46:34,900 --> 00:46:40,800
+الشركة اللي اعطتنيا تمام تبع الله الفحصطيب ال
+
+591
+00:46:40,800 --> 00:46:44,280
+wavelength selector هذا اللى بيعزلى طول موجى معين
+
+592
+00:46:44,280 --> 00:46:49,660
+اللى هو يتم ادخاله للجهاز هذا بيكون اما filter او
+
+593
+00:46:49,660 --> 00:46:55,520
+monochromator طبعا اذا كان filter فهو بيكون مصنوع
+
+594
+00:46:55,520 --> 00:46:59,960
+من طبقة transparent dielectric layer طبقة شفاف
+
+595
+00:46:59,960 --> 00:47:04,020
+مقطبة الها اقطاب ومصنوعة من ال calcium fluoride
+
+596
+00:47:04,020 --> 00:47:08,000
+وسمك هاى الطبقة هو اللى بيتحكم بالطول الموجى اللى
+
+597
+00:47:08,000 --> 00:47:13,930
+مار من خلالهاأو يعني إذا ما كان من ال transparent
+
+598
+00:47:13,930 --> 00:47:18,430
+dielectric layer of calcium chloride معناها بدي
+
+599
+00:47:18,430 --> 00:47:22,630
+يكون مصنوع من colored glass تمام؟ إذا calcium
+
+600
+00:47:22,630 --> 00:47:28,820
+fluoride layer أو colored glass هذا ال filterتمام؟
+
+601
+00:47:28,820 --> 00:47:31,740
+أو بيكون ال .. ال .. ال selector مش filter بيكون
+
+602
+00:47:31,740 --> 00:47:34,380
+monochromator إيش يعني monochromator؟ ال
+
+603
+00:47:34,380 --> 00:47:38,840
+monochromator هذا بيكون إما grating أو prism أنا
+
+604
+00:47:38,840 --> 00:47:43,560
+أقدر إنه المصطلحات هذه أول مرة ت .. تمر عليكم ولكن
+
+605
+00:47:43,560 --> 00:47:46,940
+إذا أنتم يعني بس .. يعني انتبهتوا للكلام اللي بحكي
+
+606
+00:47:46,940 --> 00:47:51,340
+هو فقط اللي مطلوب منكم و هيكون واضح بالنسبة لقلكم
+
+607
+00:47:51,340 --> 00:47:55,450
+إذا ال .. ال selector هذا ممكن يكون filterال
+
+608
+00:47:55,450 --> 00:47:58,910
+filter هذا ممكن يكون طبقة transparent، dielectric
+
+609
+00:47:58,910 --> 00:48:02,570
+layer مصنوعة من الكالسيمو فلورايد و سمك هذه الطبقة
+
+610
+00:48:02,570 --> 00:48:06,190
+هو اللي بيتحكم بالطول الموجي، كام طول موجي مر من
+
+611
+00:48:06,190 --> 00:48:13,220
+خلالها يعني طول الموجي يعني قيمته تمامأو .. أو إنه
+
+612
+00:48:13,220 --> 00:48:17,420
+يكون هذا ال filter مصنوع من الزجاج الملون و من
+
+613
+00:48:17,420 --> 00:48:22,060
+شوية ضربنا مثال حكينا الزجاج لو كان ملون و حطيته
+
+614
+00:48:22,060 --> 00:48:25,700
+أنا أمام لمبة هيحجز الضوء، هيحجب الضوء المارر،
+
+615
+00:48:25,700 --> 00:48:30,890
+تمام؟ يعني فكرة عمل filterطيب إذا كان ال .. ال
+
+616
+00:48:30,890 --> 00:48:33,510
+wavelength selected عبارة عن monochromator فبيكون
+
+617
+00:48:33,510 --> 00:48:37,250
+إما a grating أو a prism تمام؟ إيش يعني grating؟
+
+618
+00:48:37,250 --> 00:48:41,270
+ال grating هو عبارة عن قطعة زجاجية مشرشرة تمام؟
+
+619
+00:48:41,270 --> 00:48:47,050
+محففة، إلها حواف، إلها grooves تمام؟زي الزجاج و
+
+620
+00:48:47,050 --> 00:48:51,270
+هذه القطعة الزجاجية، الضوء بينعكس وينكسر، ينعكس
+
+621
+00:48:51,270 --> 00:48:55,530
+وينكسر عليها، بينعكس وبينكسر، عدة انكسارات و عدة
+
+622
+00:48:55,530 --> 00:49:01,210
+انعكاسات للضوء تؤدي إلى تحلله و بالتالي كل مرة
+
+623
+00:49:01,210 --> 00:49:06,750
+بيتحلل وبيتشتت فبيفقد جزء منهانكسر، انعكس، انكسر،
+
+624
+00:49:06,750 --> 00:49:11,410
+انعكس وانكسر وانعكس و هكذا على هذه الحواف تمام ال
+
+625
+00:49:11,410 --> 00:49:17,790
+.. ال .. ال mirror تمام فبالتالي هذه الحواف يعني
+
+626
+00:49:17,790 --> 00:49:22,370
+راح تتقضي إلى فقدان الدوء، فقدان ال spectrum
+
+627
+00:49:25,430 --> 00:49:29,970
+كمية الضوء اللى راح تنفذ من هذا ال selector هي
+
+628
+00:49:29,970 --> 00:49:34,730
+عبارة عن طول موجى واحد طيب إذا كان ال prism كلنا
+
+629
+00:49:34,730 --> 00:49:39,190
+بنعرف أنه ال prism المنشور الثلاثى بيحلل الأضواء
+
+630
+00:49:39,190 --> 00:49:45,130
+.. الضوء إلى أطياف تمام؟ إلى عدة أطياف فمثلا لو
+
+631
+00:49:45,130 --> 00:49:48,790
+كان في عندى هنا light source هذه العدسة بس عشان
+
+632
+00:49:48,790 --> 00:49:52,610
+تجمع للضوء و تمرره خلال ال prism ال prism هو ال
+
+633
+00:49:52,610 --> 00:49:53,550
+wavelength selector
+
+634
+00:49:56,140 --> 00:50:01,120
+طيب هذا الـ wavelength selector راح يحلل الضوء
+
+635
+00:50:02,820 --> 00:50:08,100
+تمام؟ و .. إلى عدة أطياف و بيكون في عندها حاجة
+
+636
+00:50:08,100 --> 00:50:13,660
+اسمها slit تمام؟ حاجة اسمها slit يعني زي جدار أو
+
+637
+00:50:13,660 --> 00:50:17,900
+حائط مفتوح متقوم هذا الجدار يتحرك أماما و يعني
+
+638
+00:50:17,900 --> 00:50:24,120
+بتحرك ال .. بت .. ب .. ساعدا و نزولا يعني لحتى إن
+
+639
+00:50:24,120 --> 00:50:28,120
+طيف واحد من هذه الأضواء هواللي بيعبر .. أي طفل
+
+640
+00:50:28,120 --> 00:50:30,980
+اللي هيعبر اللي أنا دخلته على الجهاز أثناء برمجته
+
+641
+00:50:30,980 --> 00:50:34,760
+أو أثناء إعداده لقراءة الفحص وعلى أي أساس تم
+
+642
+00:50:34,760 --> 00:50:39,360
+اختياره لإنه بيكون عنده أقصى كمية انتصاص المحلول
+
+643
+00:50:39,360 --> 00:50:43,180
+بينطست ضوء تمام؟ وأقل كمية transmittance بتروح لل
+
+644
+00:50:43,180 --> 00:50:46,680
+detector ال detector هيحول القراءة ل electric
+
+645
+00:50:46,680 --> 00:50:50,560
+current وهتروح على ال readout على ال digital
+
+646
+00:50:50,560 --> 00:50:55,350
+screenتمام؟ إذا كل من ال .. ال grading
+
+647
+00:50:55,350 --> 00:50:59,810
+monochromator و ال prism بيعتمد على تحلل الضوء
+
+648
+00:50:59,810 --> 00:51:04,690
+ولكن هنا عدة انكسارات و انعكسات للضوء تؤدي إلى
+
+649
+00:51:04,690 --> 00:51:09,870
+تشتتته و تحلله تمام؟ أما هنا مروره عبر ال prism
+
+650
+00:51:09,870 --> 00:51:13,930
+المنشور التلاتي راح يؤدي إلى تحلله إلى أطياف و في
+
+651
+00:51:13,930 --> 00:51:17,630
+عند سلك بتتحكم بأي ضوء أو أي طيف هو ال lemur طبعا
+
+652
+00:51:17,630 --> 00:51:21,450
+كل طيف بيكون له طول موجي معينحسب انا .. مين اللي
+
+653
+00:51:21,450 --> 00:51:25,250
+بدياه هو اللي بيعدي طيب
+
+654
+00:51:26,450 --> 00:51:30,210
+تختلف الأجهزة باحتواءها على ال .. ال wavelength
+
+655
+00:51:30,210 --> 00:51:34,990
+selector فجهاز ال photo meter بيكون ال selector
+
+656
+00:51:34,990 --> 00:51:39,950
+عبارة عن filter و اربطوها F F photo meter filter
+
+657
+00:51:39,950 --> 00:51:44,770
+أما جهاز ال spectrophotometer ال .. ال wavelength
+
+658
+00:51:44,770 --> 00:51:48,230
+selector عبارة عن monochromator تمام؟ هنا ال
+
+659
+00:51:48,230 --> 00:51:53,350
+filter إما calcium fluoride layer أوcolored glass
+
+660
+00:51:53,350 --> 00:51:58,130
+أما هنا ال filter أو ال wavelength selector عبارة
+
+661
+00:51:58,130 --> 00:52:01,990
+عن monochromator وهذا ال monochromator إما grating
+
+662
+00:52:01,990 --> 00:52:08,950
+monochromator أو a prism أصبح الأن في عندنافي
+
+663
+00:52:08,950 --> 00:52:14,090
+عندنا نوعين من الأجهزة وصيرنا بنفرق ما بين ال
+
+664
+00:52:14,090 --> 00:52:16,630
+photometer و ال spectrophotometer في البداية ال
+
+665
+00:52:16,630 --> 00:52:20,250
+chapter كنا بنحكي photometer و spectrophotometer
+
+666
+00:52:20,250 --> 00:52:24,210
+على أساس إن هم واحد و إن هم هم أجهزة فيهم detector
+
+667
+00:52:24,210 --> 00:52:27,650
+فيهم إما photocell أو photo multiplier tube
+
+668
+00:52:27,650 --> 00:52:30,790
+وبيقيصوا كمية الضوء اللي نافذة عبر المحلول الملون
+
+669
+00:52:30,790 --> 00:52:34,640
+لإلهمبقصول كمية اما transmittance او absorbance
+
+670
+00:52:34,640 --> 00:52:39,680
+تمام هذا كله كلام لا خلاف عليه ولكن يختلفوا في نوع
+
+671
+00:52:39,680 --> 00:52:43,080
+ال wavelength selector اللي موجود فيهم فال
+
+672
+00:52:43,080 --> 00:52:46,540
+photometer فيه filter يعني اما calcium fluoride او
+
+673
+00:52:46,540 --> 00:52:49,660
+color deglass و ال spectrophotometer فيه
+
+674
+00:52:49,660 --> 00:52:54,120
+monochromator يعني اما agrating او abrasive تمام؟
+
+675
+00:52:54,120 --> 00:53:00,000
+طيبsample container المعاقلة دي يحتوي على المحلول
+
+676
+00:53:00,000 --> 00:53:04,740
+الملون لكيوفيت مرت معانا لكيوفيت كتير وذكرناها
+
+677
+00:53:04,740 --> 00:53:08,620
+وفسرت إيش يعني كلمتي كيوفيت وفي المعمل أيضا راح
+
+678
+00:53:08,620 --> 00:53:12,480
+أورجيكم إياها و أحكيلكم تعليمات كيف إحنا نستخدمها
+
+679
+00:53:12,480 --> 00:53:17,290
+كيف أمسكها كيف نشتغل فيها فبالتاليhigh liquid هي
+
+680
+00:53:17,290 --> 00:53:21,530
+اللي that hold the sample بتحتوي .. هي عبارة عن ال
+
+681
+00:53:21,530 --> 00:53:26,190
+sample container بتحتوي ال sample المراد قياسها أو
+
+682
+00:53:26,190 --> 00:53:30,730
+المحلول المراد قياسه في الجهاز بتكون مصنوعة إما لل
+
+683
+00:53:30,730 --> 00:53:35,430
+glass أو لل quartz أو لل silicaالـ Silica تستخدم
+
+684
+00:53:35,430 --> 00:53:38,510
+في القراءات على الـ visible light و الـ glass
+
+685
+00:53:38,510 --> 00:53:43,710
+بتكون تستخدم للقراءات على ال UV light طبعا فإحنا
+
+686
+00:53:43,710 --> 00:53:49,490
+كل شغلنا معظم الشغل هذه الفترة هيكون على ال
+
+687
+00:53:49,490 --> 00:53:52,270
+visible فهتستخدموا ال Silica أو ال plastic
+
+688
+00:53:55,090 --> 00:53:59,450
+أما في .. ان شاء الله في معامل متقدمة هتاخدوا
+
+689
+00:53:59,450 --> 00:54:02,090
+فحوصات بتنقرع على ال UV light و هتلاحظوا أن
+
+690
+00:54:02,090 --> 00:54:07,130
+المستات بتطلعولكم equivitat خاصة من ال quarts أو
+
+691
+00:54:07,130 --> 00:54:11,150
+من ال glass لحتى تشتغلوا عليها تمام؟ على ال UV
+
+692
+00:54:11,150 --> 00:54:14,320
+lightطيب ال detector احنا حكينا ال detector اما
+
+693
+00:54:14,320 --> 00:54:17,700
+هيكون photo cell او photo multiplier tube هلأ
+
+694
+00:54:17,700 --> 00:54:20,380
+photo tube او photo cell نفس المعنى او photo
+
+695
+00:54:20,380 --> 00:54:23,620
+multiplier tube ال photo اللي بديكم تعرفوا او اللي
+
+696
+00:54:23,620 --> 00:54:27,320
+مطلوب منكم ان ال photo cell بتشتغل بطريقة ال photo
+
+697
+00:54:27,320 --> 00:54:31,100
+conductivityأما ال photo multiplier مبدأ عملها
+
+698
+00:54:31,100 --> 00:54:34,500
+بالأقطاب أقطاب السيليكون silicon diode electrode
+
+699
+00:54:34,500 --> 00:54:38,400
+هلأ كيف بالظبط و تفاصيل حق حول مصطلح ال photo
+
+700
+00:54:38,400 --> 00:54:42,500
+conductivity التوصيلية الضوئية أو تفاصيل حول ال
+
+701
+00:54:42,500 --> 00:54:45,800
+silicon diode electrode ما رح نخوض فيها كل اللي
+
+702
+00:54:45,800 --> 00:54:50,110
+مطلوب منكم انه ال photo tubesأو ال photo cells
+
+703
+00:54:50,110 --> 00:54:53,970
+بتعمل بمبدأ عمل ال photo conductivity و ال photo
+
+704
+00:54:53,970 --> 00:54:57,630
+multiplier tube بتعمل بمبدأ ال silicon diode
+
+705
+00:54:57,630 --> 00:55:02,370
+electrode تمام؟ و هذا ال detector حكينا أنه بتصلوا
+
+706
+00:55:02,370 --> 00:55:07,690
+الطاقة الضوئية من الضوء النافذ و بيحولها إلى طاقة
+
+707
+00:55:07,690 --> 00:55:11,510
+كهربائية إلى electrical energy عبر جهاز
+
+708
+00:55:11,510 --> 00:55:16,860
+galvanometer موجود داخل ال detector تمام؟سواء كان
+
+709
+00:55:16,860 --> 00:55:19,940
+photocell او photo multiplier تيوب خلونا بس نشوف
+
+710
+00:55:19,940 --> 00:55:24,240
+كيف هي تم تحويل الطاقة الضوئية إلى طاقة كهربائية
+
+711
+00:55:24,240 --> 00:55:28,960
+هلأ اللي بيصير انه الضوء اللي نافذ عبر المحلول ل
+
+712
+00:55:28,960 --> 00:55:32,580
+transmittance رح يصل ال detector اول ما طبعا ال
+
+713
+00:55:32,580 --> 00:55:35,960
+detector فيه cathode وفيه anode قطب موجب و قطب
+
+714
+00:55:35,960 --> 00:55:41,940
+سالمهذا الضوء راح يصطدم بالقطب السالب، هو فوتونات،
+
+715
+00:55:41,940 --> 00:55:45,620
+تمام؟ هذه الفوتونات راح تصطدم بالقطب السالب اللي
+
+716
+00:55:45,620 --> 00:55:49,560
+هو الـ cathode فراح يتحرر من هذا ال cathode
+
+717
+00:55:49,560 --> 00:55:55,020
+إلكترونات، تمام؟ و هذه الإلكترونات راح تتجه باتجاه
+
+718
+00:55:55,020 --> 00:55:59,340
+الأعناض، القطب الموجب، تمام؟ هيها، هذا اتجاهها
+
+719
+00:55:59,340 --> 00:56:05,800
+للإلكترونات، بالاتجاه القطب الموجبتمام؟ طيب سرايان
+
+720
+00:56:05,800 --> 00:56:10,500
+إلكترونات أو شحنات سالبة من القطب السالب إلى القطب
+
+721
+00:56:10,500 --> 00:56:14,720
+الموجب هذا معناه إنه في عندي دارة كهربائية يمر
+
+722
+00:56:14,720 --> 00:56:19,300
+فيها طيار تمام؟ جهاز ال galvanometer رح يقيصلي
+
+723
+00:56:19,300 --> 00:56:27,370
+كمية شدة الطيار اللي نشأتنشأت نتيجة إيش؟ نتيجة
+
+724
+00:56:27,370 --> 00:56:33,570
+انبعاث ضوء عبر ال tube المحلول الملون نفذ من خلاله
+
+725
+00:56:33,570 --> 00:56:39,250
+هذا الضوء ضرب في ال cathode و اتحرر الإلكترونات
+
+726
+00:56:39,250 --> 00:56:42,510
+هاي الإلكترونات انتقلت من القطب السالب إلى القطب
+
+727
+00:56:42,510 --> 00:56:47,170
+الموجب إذا انتي عندى ضوء photonوكمية transmitted
+
+728
+00:56:47,170 --> 00:56:51,250
+light راحت إلى ال cathode حررت إلكترونات
+
+729
+00:56:51,250 --> 00:56:56,490
+الإلكترونات هذه تحركت إلى ال anode بتكون عندي طيار
+
+730
+00:56:56,490 --> 00:57:00,990
+شدت الطيار تقاس بال galvanometer و راح تظهر على ال
+
+731
+00:57:00,990 --> 00:57:04,930
+readout إما ك transmittance كقيمة transmittance أو
+
+732
+00:57:04,930 --> 00:57:09,610
+راح تظهر كقيمة absorbance مين اللي بيحدد أن الجهاز
+
+733
+00:57:09,610 --> 00:57:12,910
+يعمل حسابته و يقيص لل absorbance أو يقيص لل
+
+734
+00:57:12,910 --> 00:57:17,360
+transmittance directlyأنا اللي ب .. ب .. بدخل ال
+
+735
+00:57:17,360 --> 00:57:20,880
+mood of read يعني أنت إيش تقرألي يا جهاز؟ تقرألي
+
+736
+00:57:20,880 --> 00:57:24,680
+absorbance ولا تقرألي transmittance؟ وكل تعاملاتنا
+
+737
+00:57:24,680 --> 00:57:28,800
+أو معظم تعاملاتنا بتكون يا بنات بال absorbance و
+
+738
+00:57:28,800 --> 00:57:34,970
+ليس بال transmittance، تمام؟ طيببالنسبة لجهاز آخر
+
+739
+00:57:34,970 --> 00:57:38,930
+تمام اسمه flame photometry أو flame emission
+
+740
+00:57:38,930 --> 00:57:43,450
+spectroscopy هو جهاز بيشتغل نفس مبدأ عمل لـ
+
+741
+00:57:43,450 --> 00:57:47,350
+spectrophotometer flame photometry is a spectral
+
+742
+00:57:47,350 --> 00:57:51,130
+method in which excitation is caused by spraying a
+
+743
+00:57:51,130 --> 00:57:54,970
+solution of the sample in a hot flame طبعا هو
+
+744
+00:57:54,970 --> 00:57:59,640
+عبارة عنالجهاز بيشتغل برضه كمان ب spectral method
+
+745
+00:57:59,640 --> 00:58:04,100
+بطريقة قياس type الضوء او كمية الضوء من خلال انه
+
+746
+00:58:04,100 --> 00:58:09,320
+انا بعمل spraying للعينة على لهب اذا مصدر الضوء
+
+747
+00:58:09,320 --> 00:58:14,300
+هنا ال light source لهب و ليس لمبةتمام؟ هذا
+
+748
+00:58:14,300 --> 00:58:18,240
+الإختلاف و characteristic radiation is emitted in
+
+749
+00:58:18,240 --> 00:58:21,360
+flame by individual element and the emission
+
+750
+00:58:21,360 --> 00:58:24,800
+intensity is proportional to the concentration of
+
+751
+00:58:24,800 --> 00:58:28,660
+the element introduced into the flame شوفوا معايا
+
+752
+00:58:29,370 --> 00:58:34,970
+هلأ ال .. ال .. كمية الضوء اللي بينبعث من هذا
+
+753
+00:58:34,970 --> 00:58:42,470
+اللهب بتتناسب تناسبا طرضيا مع تركيز المواد اللي
+
+754
+00:58:42,470 --> 00:58:47,310
+موجودة في العينة هذا الجهاز بيستخدم لقياس ال
+
+755
+00:58:47,310 --> 00:58:50,850
+electrolytes في العينة، في عينات الدم أو سواء
+
+756
+00:58:50,850 --> 00:58:55,560
+الجسم تمام؟ إيش يعني electrolytes؟يعني الأيونات
+
+757
+00:58:55,560 --> 00:58:58,540
+Sodium, Potassium, Calcium, Magnesium, Fluoride,
+
+758
+00:58:58,640 --> 00:59:03,560
+Chloride, Sodium، هاي كلها عبارة عن أيونات يتم
+
+759
+00:59:03,560 --> 00:59:08,760
+قياسها بطريقة الفيلم فوتومتري أو الفيلم Emission
+
+760
+00:59:08,760 --> 00:59:12,980
+Spectroscopyماذا يحدث في هذا الجهاز؟ اول اشي انا
+
+761
+00:59:12,980 --> 00:59:17,400
+مافي عنده cuvette يعني انا مابدخل ل tube او يعني
+
+762
+00:59:17,400 --> 00:59:21,840
+المحلول في tube cuvette ويداخل الجهاز الجهاز يتلقى
+
+763
+00:59:21,840 --> 00:59:25,680
+العينة بطريقة ال suction اذا في عنده زي suction زي
+
+764
+00:59:25,680 --> 00:59:34,140
+..أداة أو جزء بينطس العينة امتصاص تمام؟ و هذه
+
+765
+00:59:34,140 --> 00:59:38,280
+العينة اللي يتم امتصاصها بتدخل إلى حجرة داخل
+
+766
+00:59:38,280 --> 00:59:44,820
+الجهاز مكان صغير مخصص للعينة هذه الحجرة درجة
+
+767
+00:59:44,820 --> 00:59:49,860
+حرارتها عالية جدا لإنه يعني موجود في أعلاها إفلام
+
+768
+00:59:49,860 --> 00:59:55,740
+لهبطبعا طيب نتيجة درجة الحرارة العالية هذه العينة
+
+769
+00:59:55,740 --> 01:00:01,440
+السائلة سواء blood أو سواء الجسم راح تتحول من ..
+
+770
+01:00:01,440 --> 01:00:06,920
+من حالة سائلة إلى حالة ما بين السائلة والغازية
+
+771
+01:00:06,920 --> 01:00:12,460
+اللي هي ال spray راح تصير رذاذ طبعا هذا الرذاذ
+
+772
+01:00:12,460 --> 01:00:19,060
+يتصعد و .. يعني يتصعد باتجاه ال flame باتجاه اللهب
+
+773
+01:00:19,470 --> 01:00:27,630
+إذا تساعد باتجاه اللهب إذا تمام إذا رح يغيرلي خواص
+
+774
+01:00:27,630 --> 01:00:33,870
+اللهب رح يغير لون اللهب تمام إذا عينة يتم إمتصاصها
+
+775
+01:00:33,870 --> 01:00:38,410
+بتروح على حجرة هذه الحجرة اسمها nebulizer هذه
+
+776
+01:00:38,410 --> 01:00:42,870
+الحجرة طبعا درجة حررتها عالية لإن في عندي على
+
+777
+01:00:42,870 --> 01:00:50,080
+أعلاها أو على سقفها فيلهب فهي العينة اللي دخلت لل
+
+778
+01:00:50,080 --> 01:00:55,940
+nebulizer بتتحول من حالة سائلة إلى حالة ما بين
+
+779
+01:00:55,940 --> 01:01:00,060
+السائلة والغازية اللي هي حالة ال spray بتصير رذاذ
+
+780
+01:01:00,060 --> 01:01:07,220
+الرذاذ هذا يتصاعد وطبعا بيأثر على خواص اللهبطمام؟
+
+781
+01:01:07,220 --> 01:01:11,740
+هذا خواص اللهب مثلا لو انا كنت عارفة انه ال sodium
+
+782
+01:01:11,740 --> 01:01:16,660
+بيعطيني اللهب لونه أحمر نفترض مثلا انه اشتعال ال
+
+783
+01:01:16,660 --> 01:01:19,840
+sodium هيعطيني لون أحمر هيغير لون اللهب للون
+
+784
+01:01:19,840 --> 01:01:25,240
+الأحمر اذا في عندي أشعة هنا بتجمع اللون الأحمر
+
+785
+01:01:25,240 --> 01:01:29,820
+كمية اللون الأحمر اللي موجودة بتتجمع و بتعبرخ من
+
+786
+01:01:29,820 --> 01:01:33,220
+خلال filter ال filter هذا اوزميت الضوء بشكل عام
+
+787
+01:01:33,220 --> 01:01:36,600
+اللى جاي من اللهب بيتجمع و بيروح على ال filter ال
+
+788
+01:01:36,600 --> 01:01:40,140
+filter هيفوت لفقط الضوء اللون الأحمر فهيروح على ال
+
+789
+01:01:40,140 --> 01:01:43,980
+photo detector و يتحول الضوء إلى طاقة كهربائية و
+
+790
+01:01:43,980 --> 01:01:46,940
+بتطلع على ال readout هنا ال readout اللى بيطلع
+
+791
+01:01:46,940 --> 01:01:52,440
+بيتناسب تناسبان طرديا مع ان هو emitted تمام؟ ولكن
+
+792
+01:01:52,440 --> 01:01:57,540
+يتناسب تناسبان طرديا مع التركيزعلى كام ال sodium
+
+793
+01:01:57,540 --> 01:02:01,580
+اللي موجود هيعطيني لها بأحمر شديد إذا كمية القراءة
+
+794
+01:02:01,580 --> 01:02:05,320
+اللي نتجت بتاع التناسب ترضيا هتكون كمية الضوء اللي
+
+795
+01:02:05,320 --> 01:02:09,940
+وصل لل detector هيكون كبير فبالتالي بيتعبر لتناسب
+
+796
+01:02:09,940 --> 01:02:14,340
+ترضي مع ال sodiumنفترض اشتعالي البوتاسيوم بينتج
+
+797
+01:02:14,340 --> 01:02:19,400
+عنه لون أزرق، إذا هيتغير خواص اللهب و يصير فيه لون
+
+798
+01:02:19,400 --> 01:02:25,600
+أزرق، فالقشعة، العدسة الجامعة هاي بتجمعلي الضوء
+
+799
+01:02:25,600 --> 01:02:28,500
+كله ككل، و بتفوته على ال filter، ال filter فقط
+
+800
+01:02:28,500 --> 01:02:31,420
+بعزل اللون الأزرقبيفوتوا .. بيفوتوا على ال photo
+
+801
+01:02:31,420 --> 01:02:35,380
+detector اللي هو ال detector فبالتالي بيحول الطاقة
+
+802
+01:02:35,380 --> 01:02:37,820
+الضوئية اللي أجته من اللون الأزرق إلى طاقة
+
+803
+01:02:37,820 --> 01:02:40,900
+كهربائية و بتطلع على ال read out كمية الطاقة اللي
+
+804
+01:02:40,900 --> 01:02:43,540
+طلعت أو القراءة اللي طلعت كل ما كانت أعلى يعني
+
+805
+01:02:43,540 --> 01:02:47,360
+كمية الضوء أعلى يعني هنا صار في عندي لون أزرق كتير
+
+806
+01:02:47,360 --> 01:02:51,680
+إذا في عندي مثلا potassium اشتعلي كتير فهذه علاقة
+
+807
+01:02:51,680 --> 01:02:57,410
+حكينا علاقة ترضية على عكس مثلاإنه في ال
+
+808
+01:02:57,410 --> 01:02:59,810
+spectrophotometer حكينا في ال spectrophotometer
+
+809
+01:02:59,810 --> 01:03:01,910
+كمية الضوء اللي واصل لل detector هو ال
+
+810
+01:03:01,910 --> 01:03:07,950
+transmittance ويتناسب تناسبان عكسي مع العينة مع
+
+811
+01:03:07,950 --> 01:03:10,990
+تركيز العينة إنما ال absorbance اللي تبدأت في
+
+812
+01:03:10,990 --> 01:03:14,430
+العينة هو اللي يتناسب تناسبان ترضيا مع العينة
+
+813
+01:03:14,430 --> 01:03:18,070
+تمام؟ فحلو إنه اتفرقوا و تربطوا الأمور ببعضها
+
+814
+01:03:18,070 --> 01:03:23,230
+البعض لحتى تعمقوا الفهم عندكم هيك بنكون وصلنا
+
+815
+01:03:23,230 --> 01:03:26,860
+لنهاية محاضرتنا لليوم يعطيكم ألف عافيةالسلام عليكم
+
diff --git a/PL9fwy3NUQKwY9jl8xw-bWkVZkWcGGyspd/xD3hYPD-Pa0_raw.srt b/PL9fwy3NUQKwY9jl8xw-bWkVZkWcGGyspd/xD3hYPD-Pa0_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..1e871ab7cd2cbaaaa8ab30dcc03c32b648e26440
--- /dev/null
+++ b/PL9fwy3NUQKwY9jl8xw-bWkVZkWcGGyspd/xD3hYPD-Pa0_raw.srt
@@ -0,0 +1,1340 @@
+1
+00:00:03,740 --> 00:00:07,540
+السلام عليكم ورحمة الله وبركاته أهلا وسهلا بيكم
+
+2
+00:00:07,540 --> 00:00:10,260
+عزيزتي طالبات نفس التواتر التاني من قسم العلم
+
+3
+00:00:10,260 --> 00:00:15,360
+الطبية المخبرية أنا عم بسجل هذه المحاضرة للمرة
+
+4
+00:00:15,360 --> 00:00:20,440
+التانية بعد ما جزء من الطالبات أو عدد من الطالبات
+
+5
+00:00:20,440 --> 00:00:25,520
+اشتكى أنه في نص ال record أو في نص التسجيل بيروح
+
+6
+00:00:25,520 --> 00:00:29,420
+.. بتروح الصورة فطلبت من البعض أنه يتبعوا مع ..
+
+7
+00:00:29,420 --> 00:00:32,740
+يعني يفتحوا ملف ال word زي ما أنا فاتحته هكو
+
+8
+00:00:32,740 --> 00:00:36,440
+يتبعوا معايا على كلامي بس يبدو أنه لسه كان المشكلة
+
+9
+00:00:36,440 --> 00:00:43,250
+قائمة و مش .. يعني كبداية لسه مش عارفين ف ..حابة
+
+10
+00:00:43,250 --> 00:00:46,110
+يعني خلاص بالآخر قررت أنه بدي أسجل هذه المحاضرة
+
+11
+00:00:46,110 --> 00:00:50,470
+مرة تانية أول إشي احنا أهلنا وسهلنا فيكم و حكنا
+
+12
+00:00:50,470 --> 00:00:54,650
+لكم أهلا وسهلا فيكم في القسم و أنه يعني كان بودنا
+
+13
+00:00:54,650 --> 00:00:59,350
+أنه نشوفكم face to face و نلتقي فيكم و نعرفكم عن
+
+14
+00:00:59,350 --> 00:01:03,410
+القسم بس يعني هاي الأزمة حالت دون ذلك و ب .. و لكن
+
+15
+00:01:03,410 --> 00:01:06,570
+ان شاء الله يعني كلنا أمل أنه هيتعالي الأزمة تعزي
+
+16
+00:01:06,570 --> 00:01:11,070
+على خير بأقل الخسائر و نرجع لمختبراتنا و نرجع لل
+
+17
+00:01:11,070 --> 00:01:15,230
+..القسم نرجع نشوفكم و نقرب ان شاء الله و لعله خير
+
+18
+00:01:15,230 --> 00:01:19,270
+يعني نأمل ده عليه راح نكون مع بعض ان شاء الله
+
+19
+00:01:19,270 --> 00:01:25,030
+بمثاق مقدمة في العلوم الطبية المخبرية او مقدمة في
+
+20
+00:01:25,030 --> 00:01:30,130
+التحليل الطبية اللي هي عبارة عن مثاق تأسيسي و
+
+21
+00:01:30,130 --> 00:01:35,900
+أساسي يسبق المواد و المثاقات التخصص الأخرىيعني من
+
+22
+00:01:35,900 --> 00:01:39,040
+خلال هذا ال course احنا بنتعلم كيف نتعامل مع
+
+23
+00:01:39,040 --> 00:01:42,740
+المختبر، كيف نتعامل مع عينات المختبر، كيف نحصل على
+
+24
+00:01:42,740 --> 00:01:47,700
+عينة من المريض، كيف أتعامل مع المريض و مع زملاء مع
+
+25
+00:01:47,700 --> 00:01:51,540
+الأدوات و الأجهزة اللي موجودة داخل المختبر بحيث
+
+26
+00:01:51,540 --> 00:01:57,080
+انه انا يعني تتأهلوا انه بالمثلقات الأخرى الأكثر
+
+27
+00:01:57,080 --> 00:02:01,100
+تخصيصية تكون عندكم background يكون عندكم خلفيةكيف
+
+28
+00:02:01,100 --> 00:02:05,380
+أنتوا يعني تجرب حوصات أكتر تخصصا و أكتر تقدما،
+
+29
+00:02:05,380 --> 00:02:10,240
+تمام؟ فهنا الحاجة للأساس، هنا يعني الأساسية
+
+30
+00:02:10,240 --> 00:02:14,160
+والتأسيس للتخصص،
+
+31
+00:02:14,160 --> 00:02:18,740
+إذا هو تخصص لازم يسبق أي مادة تخصص أخر أو يعني هو
+
+32
+00:02:18,740 --> 00:02:24,400
+مساق لازم يسبق أي تخصص أو sorry يعني هو مساق لازم
+
+33
+00:02:24,400 --> 00:02:31,590
+يسبق أي مساق تخصص آخرلحتى يكون عندكم ال .. الأساس
+
+34
+00:02:31,590 --> 00:02:37,370
+اللى تتمكنوا من بعد هيك تبنع عليه أي معرفة أكثر
+
+35
+00:02:37,370 --> 00:02:44,350
+عمقا أو أكثر اتساعا، طبعا؟ فى النهاية ال .. يعني
+
+36
+00:02:44,350 --> 00:02:47,350
+راح أكون معاكم أنا ناس نور أبوتيم، أستاذة نور
+
+37
+00:02:47,350 --> 00:02:51,520
+أبوتيم بكالوريوس علوم طبية مخبريةمن الجامعة
+
+38
+00:02:51,520 --> 00:02:55,280
+الإسلامية و master علم دم وبنك دم من جامعة العلم
+
+39
+00:02:55,280 --> 00:02:57,980
+والتكنولوجيا الأردنية و ..
+
+40
+00:03:01,020 --> 00:03:05,800
+أتحدث معاكم المواضيع اللي راح نتناولها بداية تقديم
+
+41
+00:03:05,800 --> 00:03:09,280
+اللي احنا عم نحكي فيه هلأ هو introduction to the
+
+42
+00:03:09,280 --> 00:03:12,380
+course بعد هيك راح نحكي عن اشي اسمه medical
+
+43
+00:03:12,380 --> 00:03:16,340
+laboratories راح نعرف المختبرات الطبية أنواع
+
+44
+00:03:16,340 --> 00:03:22,530
+المختبرات الطبية ورسالة الأخصائيالمختبرات الطبية
+
+45
+00:03:22,530 --> 00:03:28,330
+كيف أنه هو يعني لأ كيف يجب أن يتعامل داخل المختبر
+
+46
+00:03:28,330 --> 00:03:33,150
+و كل ما يتعلق بالمختبرات الطبية أنواع أو بعض
+
+47
+00:03:33,150 --> 00:03:36,840
+المصطلحات و التعريفات المتعلقة فيهارح ناخدها في
+
+48
+00:03:36,840 --> 00:03:41,880
+هذا الجزئية، في الموضوع التالت رح نحكي عن ال
+
+49
+00:03:41,880 --> 00:03:47,500
+general laboratory safety طبعا حالنا حال أي مادة
+
+50
+00:03:47,500 --> 00:03:52,860
+عملية لازم نبلش بالحكي عن قوانين السلامة والأمان
+
+51
+00:03:52,860 --> 00:03:57,310
+اللي موجودة أو اللي يجب أن تطبقداخل المختبرات راح
+
+52
+00:03:57,310 --> 00:04:02,210
+نحكي عنها اليوم او يعني الفصل هاد او في المساق هاد
+
+53
+00:04:02,210 --> 00:04:05,710
+و راح نحكي طبعا كيف احنا ممكن يعني او كيف ال
+
+54
+00:04:05,710 --> 00:04:08,750
+medical laboratory scientist خاصة العلوم الطبية
+
+55
+00:04:08,750 --> 00:04:13,530
+المخبرية لازم عنده تلت اهداف يحققها اول حاجة to
+
+56
+00:04:13,530 --> 00:04:19,540
+save himself يعني ان هو بدييحفظ على نفسه، يحمي
+
+57
+00:04:19,540 --> 00:04:23,660
+نفسه to save patient يعني أنه يحافظ على المريض ما
+
+58
+00:04:23,660 --> 00:04:26,780
+تنتقله عدوى من المختبر أو من العينات اللى موجودة
+
+59
+00:04:26,780 --> 00:04:29,860
+داخل المختبر إذا يجب أن تكون البيئة اللى بيشتغل
+
+60
+00:04:29,860 --> 00:04:34,460
+فيها نظيفة و to save colleagues اللى هو يعني يحافظ
+
+61
+00:04:34,460 --> 00:04:39,740
+على نسلة ميدز هو لأ من خلال أنه ما يكون هو سبب
+
+62
+00:04:39,740 --> 00:04:43,790
+لانتقال العدوى من مثلا المرضى لإلهماللي معاكم هو
+
+63
+00:04:43,790 --> 00:04:48,270
+حلقة الوصل في انتقال العدوى، تمام؟ و راح نحكي أيضا
+
+64
+00:04:48,270 --> 00:04:56,080
+عن ال infection control اللي هي عبارة عن كيف أناال
+
+65
+00:04:56,080 --> 00:04:59,660
+infection control كيف ان انا احد من انتشار العدوى
+
+66
+00:04:59,660 --> 00:05:05,280
+و طبعا راح احكي عنها ب ISAB هاي المجلة لإنه راح
+
+67
+00:05:05,280 --> 00:05:09,900
+نربطها بكيف انه انا اكون جزء من الحد من انتشار
+
+68
+00:05:09,900 --> 00:05:13,580
+العدوى و نربطها ب COVID-19 pandemic اللي هي جائحة
+
+69
+00:05:13,580 --> 00:05:18,510
+ال virus coronaاللي موجودة حاليا لحتى نتعلم كيف ان
+
+70
+00:05:18,510 --> 00:05:24,310
+احنا نوظف علمنا في ال .. ال .. الظروف والمواقف
+
+71
+00:05:24,310 --> 00:05:28,410
+اللي بنمر فيها biosafety الأمانة والسلام اللي
+
+72
+00:05:28,410 --> 00:05:32,110
+موجود داخل المختبر كيف انا اتخلص من العينات بسلامة
+
+73
+00:05:32,110 --> 00:05:38,730
+كيف .. ان .. ان المواد الكيميائية وال ..و المحاليل
+
+74
+00:05:38,730 --> 00:05:43,190
+اللي أنا بتعامل معها ما تكون خاطرة عليا أو على
+
+75
+00:05:43,190 --> 00:05:49,410
+حياتي، في محاليل خانقة، في محاليل حارقة، في محاليل
+
+76
+00:05:49,410 --> 00:05:56,390
+ممكن أنها تؤدي إلى .. يعني تسربها يؤدي إلى إشعاع،
+
+77
+00:05:56,390 --> 00:06:03,360
+في محاليل ممكن تؤدي إلى حرائق لصمح اللهفي أيضا
+
+78
+00:06:03,360 --> 00:06:06,960
+عينات لازم طبعا ممكن تكون infectious كيف انا ممكن
+
+79
+00:06:06,960 --> 00:06:11,360
+اتلفها، هي كل الشغلات اللي بتتعلق بيه انه انا كده
+
+80
+00:06:11,360 --> 00:06:14,140
+احمي حالي من الأشياء اللي موجودة داخل المختبر سواء
+
+81
+00:06:14,140 --> 00:06:18,150
+كانت أدوات أو أجهزة أو محاليل أو عيناتراح يندرج
+
+82
+00:06:18,150 --> 00:06:22,310
+تحت مصطلح ال biosafety lab equipments راح نحكي
+
+83
+00:06:22,310 --> 00:06:27,550
+أيضا عن الأدوات اللي موجودة داخل المختبر و كيف أنا
+
+84
+00:06:27,550 --> 00:06:32,650
+بستخدمها و أشوف فائدتها و راح نتطرق أيضا ل ..
+
+85
+00:06:32,650 --> 00:06:37,310
+أحيانا للمفادلة ما بين أنواع الأدوات اللي موجودة و
+
+86
+00:06:37,310 --> 00:06:42,250
+دقتهاOkay طيب بعد ذلك رح نحكي عن المحاليل اللي
+
+87
+00:06:42,250 --> 00:06:46,050
+بتستخدم داخل المختبر أنواع المحاليل هاي و كيف
+
+88
+00:06:46,050 --> 00:06:49,610
+تتحضر و كيف أنا أعملها تخفيفة لحتى أستخدمها و تكون
+
+89
+00:06:49,610 --> 00:06:53,570
+جاهزة للاستخدام و طبعا يعني احنا بنعرف انه كل
+
+90
+00:06:54,750 --> 00:06:57,750
+ابحثاتنا هي عبارة عن تفاعلات كيميائية الفحوصات
+
+91
+00:06:57,750 --> 00:07:00,050
+اللي أنا بدي أجريها على عينة المريض هي عبارة عن
+
+92
+00:07:00,050 --> 00:07:03,470
+تفاعلات كيميائية محتاجة العينة ومحتاجة المادة
+
+93
+00:07:03,470 --> 00:07:06,810
+المتفاعلة معها المادة المتفاعلة معها هذه عبارة عن
+
+94
+00:07:06,810 --> 00:07:11,830
+محاليل كيف تستخدم كيف تتحضر كيف بنحصل عليها هذه
+
+95
+00:07:11,830 --> 00:07:17,550
+كلها راح تكون موجودة في المعلومات في تحت عنوان
+
+96
+00:07:17,550 --> 00:07:20,390
+solution used in medical laboratory كل المحاليل
+
+97
+00:07:20,390 --> 00:07:23,250
+اللي تستخدم في الأختبارات الطبية راح نحكي عنها
+
+98
+00:07:24,320 --> 00:07:28,280
+أنواعها كمان راح نحكي عن حاجة اسمها automatic by
+
+99
+00:07:28,280 --> 00:07:31,840
+-bet use and calibration شو يعني automatic by-bet؟
+
+100
+00:07:31,840 --> 00:07:35,480
+اذا اخدتوا انتوا معاهم ال .. ال .. الكيميا
+
+101
+00:07:35,480 --> 00:07:40,860
+الأساسية ال .. أكيد مر معاكم اللي هي لفظ الصحاحة
+
+102
+00:07:40,860 --> 00:07:43,360
+أو ال by-betاللي كنتوا تستخدمها to transfer
+
+103
+00:07:43,360 --> 00:07:48,240
+volumes يعني لتنقلها حجوم طبعا فاتعلمتوا كيف ال
+
+104
+00:07:48,240 --> 00:07:52,860
+use ليلها كيف استخدامها و أيضا كيف ان انا اعمل لها
+
+105
+00:07:52,860 --> 00:07:58,480
+calibration كيف يعني طبعا استخدامها طبعا احنا في
+
+106
+00:07:58,480 --> 00:08:02,920
+المعامل هنا بت .. بنحكي عن نوع من ال bybit اللي هو
+
+107
+00:08:02,920 --> 00:08:05,900
+متقدم استخدامه نوع عامة اللي هو automatic bybit
+
+108
+00:08:06,330 --> 00:08:09,130
+طبعا انا ليش بستخدم ال bibet ال automatic اول حاجة
+
+109
+00:08:09,130 --> 00:08:13,250
+لإنه بدي درجة عالية من ال accuracy و ده درجة عالية
+
+110
+00:08:13,250 --> 00:08:17,330
+من ال precision الصحة و الدقة ليش؟ انا معنية انه
+
+111
+00:08:17,330 --> 00:08:21,230
+انا استخدم bibet دقيقة bibet accurate and precise
+
+112
+00:08:21,230 --> 00:08:27,480
+لحتى انقل حجم بدقةومن ثم اجري تفاعل دقيق احصل على
+
+113
+00:08:27,480 --> 00:08:31,340
+نتائج صحيحة وبالتالي انا اعبر عن صحة البقى المريض
+
+114
+00:08:31,340 --> 00:08:36,180
+او اعبر عن حالته بشكل صحيح وهك انا بساهم ان انا
+
+115
+00:08:36,180 --> 00:08:41,540
+بانقاد روح هذا المريض ايضا نحتاج ل ال calibration
+
+116
+00:08:41,540 --> 00:08:46,160
+يعني ان انا كيف اعيد تهيئة او ضبط هاي ال vibe في
+
+117
+00:08:46,160 --> 00:08:50,280
+حال لو كان اكتشفت ان فيها خلل او error كيف انا بدي
+
+118
+00:08:50,280 --> 00:08:55,690
+اضبطهارح نحكي أيضا عن ال blood blood sample
+
+119
+00:08:55,690 --> 00:08:59,790
+collection and processing كيف أنا أسحب عينة دم من
+
+120
+00:08:59,790 --> 00:09:04,850
+مريض سواء كان هذا المريض adult سواء يعني شخص كبير
+
+121
+00:09:04,850 --> 00:09:12,510
+بالعمر بالغ أو شخص newborn طفل حديث الولادة من وين
+
+122
+00:09:12,510 --> 00:09:15,870
+أنا باخد العينة سواء كانت من الوريد أو من ال skin
+
+123
+00:09:15,870 --> 00:09:19,570
+كيف طريقة أخذه العينة كل هذا رح نتعلمه في ال blood
+
+124
+00:09:19,570 --> 00:09:24,730
+sample collection و أيضارح نتعرف كيف أنا بتعامل مع
+
+125
+00:09:24,730 --> 00:09:28,670
+عينة الدم هذه يعني في بعض الفحوصات بتحتاج أنه أنا
+
+126
+00:09:28,670 --> 00:09:33,770
+بدي أفصل هذه العينة لحتى أحصل على مثلا جزء من
+
+127
+00:09:33,770 --> 00:09:38,090
+مكونات المادة يعني انا لو بدي فحص بيشتغل على
+
+128
+00:09:38,090 --> 00:09:42,530
+بلازمة أو على خلايا فانا محتاجة لفحص بيشتغل على
+
+129
+00:09:42,530 --> 00:09:48,020
+جزء من مكونات العينة لحتىأكمل عليه احيانا في
+
+130
+00:09:48,020 --> 00:09:50,920
+فحوصات بتحتاج ال whole blood يعني الدم ككل اشتغل
+
+131
+00:09:50,920 --> 00:09:54,000
+عليه فهنا محتاجة ان انا مثلا فقط ان انا اخزن
+
+132
+00:09:54,000 --> 00:09:58,320
+العينة او احتفظ فيها لحين استخدامها تحت ظروف معينة
+
+133
+00:09:58,320 --> 00:10:02,140
+انه ما تخرب العينة فهد كله راح نتعلمه في ال blood
+
+134
+00:10:02,140 --> 00:10:04,720
+sample collection and processing حكينا انه
+
+135
+00:10:04,720 --> 00:10:08,140
+المعلومات ان شاء الله راح تكون بالنسبة ل .. يعني
+
+136
+00:10:08,140 --> 00:10:11,020
+لما ن .. نفردها و نحكي عنها بالتفصيل ان شاء الله
+
+137
+00:10:11,020 --> 00:10:15,760
+ماراح يكون في اشيصعب أو يكون في اشي غامض كلش ان
+
+138
+00:10:15,760 --> 00:10:20,160
+شاء الله رح نبسطه و نسهله لإلكم بحيث انه تستفيدوا
+
+139
+00:10:20,160 --> 00:10:24,300
+رح نحكي عن بعض الأدوات sorry مش الأدوات الأجهزة
+
+140
+00:10:24,300 --> 00:10:28,040
+اللي موجودة داخل المختبر لبقى instruments رح نحكي
+
+141
+00:10:28,040 --> 00:10:32,580
+عن ال microscope أنواعه طريقة استخدامه طريقة
+
+142
+00:10:32,580 --> 00:10:38,760
+التعامل معاه مبدأ عمله أدواته مكوناته sorry أجزاءه
+
+143
+00:10:39,070 --> 00:10:44,530
+و كتطبيق على استخدام ال microscope راح ناخد طريقة
+
+144
+00:10:44,530 --> 00:10:48,090
+عد ال white pieces و ال RPCs كيف انا اعد خلايا
+
+145
+00:10:48,090 --> 00:10:51,290
+الدم البيضاء عدد خلايا الدم البيضاء و خلايا الدم
+
+146
+00:10:51,290 --> 00:10:56,830
+الحمراء في عينة الدم تمام اذا بعد ما احصل على عينة
+
+147
+00:10:56,830 --> 00:10:59,490
+الدم بدي اتعلم كيف اعد ال white pieces و كيف اعد
+
+148
+00:10:59,490 --> 00:11:05,110
+ال RPCsبدي أتعلم كيف أجيب hematocrit يعني كيف
+
+149
+00:11:05,110 --> 00:11:09,550
+أشتغل على ال hematocrit ال hematocrit هو عبارة عن
+
+150
+00:11:09,550 --> 00:11:15,750
+النسبة أو المساحة أو ال volume اللي بيحتلها ال
+
+151
+00:11:15,750 --> 00:11:20,050
+RBCs بالنسبة لل whole sample يعني كمية يعني الحجم
+
+152
+00:11:20,050 --> 00:11:23,750
+اللي بيحتله ال RBCs أو خلايا الدم الحمراء بالنسبة
+
+153
+00:11:23,750 --> 00:11:29,500
+للحجم اللي بيحتله العينة كاملةفطبعا هذا أيضا يجري
+
+154
+00:11:29,500 --> 00:11:34,600
+على عينة الدم بتطبيق جهاز اسمه centrifuge راح ناخد
+
+155
+00:11:34,600 --> 00:11:37,900
+ايضا فحص اللي هو ال hemoglobin concentration
+
+156
+00:11:37,900 --> 00:11:42,380
+determination يعني انا بدي احسب تركيز بروتين ال
+
+157
+00:11:42,380 --> 00:11:46,230
+hemoglobinاللي هو يعني بالبلدي أو بالعربي بنحكي
+
+158
+00:11:46,230 --> 00:11:50,750
+عنه قوة الدم، بدي أقيص قوة الدم فبدي أقيص تركيز ال
+
+159
+00:11:50,750 --> 00:11:53,710
+homoglobin اللي هو عبارة عن ال oxygen carrying
+
+160
+00:11:53,710 --> 00:11:57,290
+protein اللي هو ال protein اللي ناقل ال oxygen
+
+161
+00:11:57,290 --> 00:12:02,650
+داخل خلايا الدم الحمراء و بهك تقريبا تقريبا أنا
+
+162
+00:12:02,650 --> 00:12:09,290
+بكون طبعا مع محاضرة ال blood indices يعني محاضرة
+
+163
+00:12:09,290 --> 00:12:16,800
+نظرية راح نحكي عنهاهيك تقريبا انا بكون عملت حاجة
+
+164
+00:12:16,800 --> 00:12:22,820
+اسمها CBC بس اخلص هاي المواضيع و تشتغلوها بتكونوا
+
+165
+00:12:22,820 --> 00:12:28,640
+اشتغلتوا CBC ولكن يدوي، اش يعني CBC؟ يعني complete
+
+166
+00:12:28,640 --> 00:12:35,460
+blood countيعني عد كامل أو فحص شامل لدم، تمام؟ هذا
+
+167
+00:12:35,460 --> 00:12:40,340
+الفحص أنتوا في معامل علم الدم و الدم التشقيسي يعني
+
+168
+00:12:40,340 --> 00:12:45,020
+في المختبرات التخصص القادمة يعني في سنة تالتة و
+
+169
+00:12:45,020 --> 00:12:50,300
+رابعة راح تشتغلوا باستخدام أجهزة هذا الفحص يعني
+
+170
+00:12:50,300 --> 00:12:54,960
+فقط الدخل عين على الجهاز و الجهاز يطلع لك كل الاشي
+
+171
+00:12:54,960 --> 00:13:02,240
+مقروه جاهزلكن هنا بتشتغلوا بإيدكم و هذا هو ميزة
+
+172
+00:13:02,240 --> 00:13:06,240
+المصاق .. ميزة المصاق أنه أنتوا بتاخدوا ال ..
+
+173
+00:13:06,240 --> 00:13:11,420
+الاشي بتعمق أكتر و بتاخدوا الأساسيات فعليا أنه
+
+174
+00:13:11,420 --> 00:13:15,220
+أنتوا تشتغليه بإيدك أفضل بكتير من ما أنه العينة
+
+175
+00:13:15,220 --> 00:13:18,980
+يشتغلها جهاز .. الجهاز أنت ما بتعرفي هو كيف اشتغل
+
+176
+00:13:18,980 --> 00:13:22,040
+ولا .. ولا على أي مبدأ اعتمد لكن لما أنتوا تشتغلي
+
+177
+00:13:22,040 --> 00:13:27,010
+بإيدكبتكوني عارفة كل كبيرة و صغيرة كل محلول ليش
+
+178
+00:13:27,010 --> 00:13:30,630
+استخدمتيه و إيش فايدته و إيش مبدأ العمل و ليش
+
+179
+00:13:30,630 --> 00:13:33,810
+تخطيطات اللي استخدمتيها و إيش القوانين اللي
+
+180
+00:13:33,810 --> 00:13:37,610
+بتطبيها لحتى تحصل على النتيجة النهائية ففي النهاية
+
+181
+00:13:37,610 --> 00:13:41,950
+بتكوني أنتي ال counter لل blood أحسن يعني أنتي
+
+182
+00:13:41,950 --> 00:13:48,190
+أحسن من .. من الجهاز بتشتغليفلهيك يعني الجهة ..
+
+183
+00:13:48,190 --> 00:13:53,670
+المادة تبعتنا تأسيسية و أساسية للمثاقات الأخرى و
+
+184
+00:13:53,670 --> 00:13:58,150
+.. اذا انا .. اذا بتلاحظوا يعني تركت بعض المواضيع
+
+185
+00:13:58,150 --> 00:14:02,130
+لإن المواضيع اللي عرجت عليها كانت شوي مترابطة راح
+
+186
+00:14:02,130 --> 00:14:05,570
+نحكي عن جهة M فحص ال glucose test راح تاخدوا فحص
+
+187
+00:14:05,570 --> 00:14:09,450
+قياس مستوى السكر في الدم و تقرؤوها على جهاز ال
+
+188
+00:14:09,450 --> 00:14:12,480
+spectrophotometer اللي هو المطياف الدوئياللي هو
+
+189
+00:14:12,480 --> 00:14:16,900
+عبارة عن جهاز بيقيص لتركيز كتير من ال parameters
+
+190
+00:14:16,900 --> 00:14:21,440
+أو المواد اللي موجودة داخل عينات الدم يعني بجريلي
+
+191
+00:14:21,440 --> 00:14:25,560
+بحوصات كتير في معمل في السنة الرابعة اسمه ال
+
+192
+00:14:25,560 --> 00:14:29,260
+clinical chemistry اللي هو الكيميا الطبية راح يكون
+
+193
+00:14:29,260 --> 00:14:34,710
+كل شغلكم على هذا الجهاز ويعني إذا سمعتوايعني
+
+194
+00:14:34,710 --> 00:14:38,450
+فحوصات وظائف الأعضاء زي وظائف الكبد وظائف الكلا
+
+195
+00:14:38,450 --> 00:14:44,030
+وظائف القلب وظائف ال .. كل جزء من .. جزء من أجزاء
+
+196
+00:14:44,030 --> 00:14:49,110
+الإنسان يجرى طبعا على .. يعني هذه فحوصات هتجرى على
+
+197
+00:14:49,110 --> 00:14:52,710
+جهاز ال spectrophotometer فإحنا هنا دورنا أنه أنا
+
+198
+00:14:52,710 --> 00:14:56,250
+أعرف إيش يعني جهاز ال spectrophotometer إيش مبدأ
+
+199
+00:14:56,250 --> 00:15:02,230
+أعمله، إيش مكوناته وطريقة استخدامه و أطبق كتطبيق
+
+200
+00:15:02,230 --> 00:15:06,450
+بسيط عليه فحص السكرعشان لما أنتقل على المختبر
+
+201
+00:15:06,450 --> 00:15:10,910
+التخصص اللي هو اللي .. اللي بيعتمد بدرجة أولى على
+
+202
+00:15:10,910 --> 00:15:13,610
+استخدام ال spectrophotometer يكون عندي خلفية
+
+203
+00:15:13,610 --> 00:15:20,650
+ومعرفة عنه تمام حكينا أنه فحص ال hematocrit
+
+204
+00:15:20,650 --> 00:15:23,570
+هنستخدمله جهاز ال centrifuge اللي هو جهاز التارد
+
+205
+00:15:23,570 --> 00:15:28,650
+المركزي راح نحكي عنه ال estimated sedimentation
+
+206
+00:15:28,650 --> 00:15:32,190
+rate اللي هو فحص الترسيب أكيد سمعتوا عن حاجة اسمها
+
+207
+00:15:32,190 --> 00:15:37,830
+فحص الترسيب بالعربيراح أيضا تشتغلوا بهذه .. بهذا
+
+208
+00:15:37,830 --> 00:15:42,710
+المصاق بعد هيك في نهاية المصاق راح نعلمكم كيف
+
+209
+00:15:42,710 --> 00:15:46,450
+تحضروا blood smear preparation إيش يعني blood
+
+210
+00:15:46,450 --> 00:15:50,030
+smear preparation يعني أنه أنا أاخد جزء من عينة
+
+211
+00:15:50,030 --> 00:15:55,530
+الدم أفردها على شريحة زجاجية و أسبغها و أحاول تكون
+
+212
+00:15:55,530 --> 00:16:00,290
+واضحة لرؤية الخلايا تحت ال microscope طبعا .. طبعا
+
+213
+00:16:00,290 --> 00:16:05,850
+أنا ليش بعمل هاي الشغلة أو هذا التحضيرلإنه يعني
+
+214
+00:16:05,850 --> 00:16:11,530
+كتير أنواع من ال anemia و من ال leukemia يعني فقر
+
+215
+00:16:11,530 --> 00:16:15,190
+الدم، أنواع فقر الدم و أنواع سرطانات الدم عفوا
+
+216
+00:16:15,190 --> 00:16:20,770
+الله و إياكم بتتم تشقيصها من رؤية شكل الخلايا على
+
+217
+00:16:20,770 --> 00:16:24,640
+ال microscopeفأنا لازم أكون بعرف كيف أحضر مسحة
+
+218
+00:16:24,640 --> 00:16:29,280
+الدم على شريحة، كيف أصبغها وكيف أنا أشوفها تحت ال
+
+219
+00:16:29,280 --> 00:16:33,600
+microscope و أتعرف على الخلايا علشان بعد هيك لما
+
+220
+00:16:33,600 --> 00:16:41,120
+نتعلم في المواد التخصصي بتانية ان .. ان نربط أنواع
+
+221
+00:16:41,560 --> 00:16:46,460
+خلايا abnormal يعني مش طبيعية بمرض معين أول ما
+
+222
+00:16:46,460 --> 00:16:49,840
+أشوف الخلية هذه اللي مش .. مش تمام اللي هي
+
+223
+00:16:49,840 --> 00:16:54,360
+abnormal اه ييجي في بالي المرض الفلاني فطبعا يعني
+
+224
+00:16:54,360 --> 00:16:58,820
+مش .. لازم تمروا بمراحل اللي هي التعلم مراحل تعلم
+
+225
+00:16:58,820 --> 00:17:05,100
+تحضير المسحة مع مراحل تعلم صبغ المسحة و أيضا رؤية
+
+226
+00:17:05,100 --> 00:17:09,360
+الخلايا على الأقل اللي تشوفه normalعشان لما بقعد
+
+227
+00:17:09,360 --> 00:17:12,780
+هيك في المساقات أخرى تشوفوا ال abnormal تكونوا
+
+228
+00:17:12,780 --> 00:17:16,580
+جادرين يتميزوا ما بين الطبيعي والغير طبيعي، هذا
+
+229
+00:17:16,580 --> 00:17:21,700
+بالنسبة لالمواضيع اللي احنا اتناولها خلال ال ..
+
+230
+00:17:22,430 --> 00:17:30,070
+المصاق هنا فعليا زي ما انتوا شايفين في مواضيع هي
+
+231
+00:17:30,070 --> 00:17:36,010
+مواضيع نظرية بحتة وفي مواضيع لأ هي نظرية وعملية
+
+232
+00:17:36,010 --> 00:17:40,050
+علشان هيك بتلاحظوا ان المصاق لما انتوا جيتوا سجلته
+
+233
+00:17:40,050 --> 00:17:45,210
+عبارة عن مقدمة في التحليل الطبية مناقشة يعني بينا
+
+234
+00:17:45,210 --> 00:17:49,110
+.. احنا راح نحكي في تحت هذا ال band كل المواضيع
+
+235
+00:17:49,110 --> 00:17:54,280
+اللي هي نظرية بحتة مش فيها عملي خالص بيكونو راح
+
+236
+00:17:54,280 --> 00:17:57,840
+نحكي تحت band المقدمة في التحليل اللي هو العملي
+
+237
+00:17:57,840 --> 00:18:03,580
+المواضيع العملية هلأ احنا راح نغطي جزء النظري
+
+238
+00:18:03,580 --> 00:18:08,940
+الباحن و نظري العملي و راح ان شاء الله يعني زي ما
+
+239
+00:18:08,940 --> 00:18:12,140
+صار في الفصول .. في الفصل السابق احنا يعني أعطينا
+
+240
+00:18:12,140 --> 00:18:16,600
+المثقات بعد هي أعطينا شهر استدراكي تعويضي ان كل
+
+241
+00:18:16,600 --> 00:18:22,550
+المعامل عوضناها يعني جيبنا الطالبات على ال ..معامل
+
+242
+00:18:22,550 --> 00:18:26,990
+ووزعناهم جروبات بحيث ما يكون فيه تكدس، يكون فيه
+
+243
+00:18:26,990 --> 00:18:32,250
+تباعد، سبل وقاية وخلينهم يشتغلوا الجزئية العملي
+
+244
+00:18:32,250 --> 00:18:38,550
+اللي موجودة معاهم، فيعني أنا أتوقع ويعني القسم
+
+245
+00:18:38,550 --> 00:18:42,310
+أكيد يعني راح ان شاء الله يطبق هذا ال .. الاشياء
+
+246
+00:18:42,780 --> 00:18:48,880
+فالجزئية العملي راح ن .. ن .. نأجلها لحين عودتنا
+
+247
+00:18:48,880 --> 00:18:54,080
+ان شاء الله او لحين وضع خطة للتعويض العملي تمام؟
+
+248
+00:18:54,080 --> 00:18:58,280
+ولكن لحتى ما يسرقنا الوقت احنا راح نظل مستمرين على
+
+249
+00:18:58,280 --> 00:19:01,920
+الأقل لنغطي الجزئية النظرى من خلال المحادرات ال
+
+250
+00:19:01,920 --> 00:19:07,230
+onlineزي ما أنتوا عارفين طبيعة المساق هو ساعة
+
+251
+00:19:07,230 --> 00:19:11,590
+مناقشة و تلت ساعات lab يعني كان مطلوب منكم لو
+
+252
+00:19:11,590 --> 00:19:14,350
+أنتوا بتيجوا على المختبرات و بتداوموا كان مطلوب
+
+253
+00:19:14,350 --> 00:19:18,270
+منكم و أربع ساعات تلتزمي بال .. بيوتعطيها من وقتك
+
+254
+00:19:18,270 --> 00:19:23,730
+حق للمادة فأنا هلأ بدي أطلب منكم أنه اتحضرولي يعني
+
+255
+00:19:23,730 --> 00:19:29,290
+تتفقوا على ساعة أنزللكم فيها أو يعني توقيت أنزللكم
+
+256
+00:19:29,290 --> 00:19:35,240
+فيهالمحاضرة النظرية اللي هي المناقشة و المحاضرة
+
+257
+00:19:35,240 --> 00:19:41,180
+العملية راح نشرح الجزء النظري منها و نسيب العملي
+
+258
+00:19:41,180 --> 00:19:47,840
+لحين التعويض و جزء ساعة لإن .. إن نكون موجودين
+
+259
+00:19:47,840 --> 00:19:53,820
+كلنا في نفس ذات اللحظة على موقع ال BB اللي هو يعني
+
+260
+00:19:53,820 --> 00:19:59,260
+موقع ال online تباع ال model أو ال ..ال zoom او
+
+261
+00:19:59,260 --> 00:20:03,660
+موقع class, google meeting, اي موقع انتوا بتختاروه
+
+262
+00:20:03,660 --> 00:20:07,660
+بيكون فيه اجماعة ليه انا ماعندي مشكلة و بحيث انه
+
+263
+00:20:07,660 --> 00:20:11,660
+نكون كلنا موجودين لو مافهمتوا اشي اثناء شرح
+
+264
+00:20:11,660 --> 00:20:15,640
+المحاضرة او تسجيل المحاضرة بنفتح المحاضرة بنرجع ل
+
+265
+00:20:15,640 --> 00:20:21,660
+ال slides بنعرج عليها بنفهمهاإذا في عندكم أي
+
+266
+00:20:21,660 --> 00:20:25,980
+استفسار أو أي سؤال بتجاوب .. يعني بس تسألوني و
+
+267
+00:20:25,980 --> 00:20:30,340
+بجاوبكم عليه ممكن يكون في نقاش و النقاش طبعا معروف
+
+268
+00:20:30,340 --> 00:20:37,480
+أن هو يثري المعلومات ف .. و بعمق الفهم فيعني هدول
+
+269
+00:20:37,480 --> 00:20:41,300
+التلت ساعات لغن عنهم لازم أنه .. يعني يكون في عندك
+
+270
+00:20:41,660 --> 00:20:46,940
+ساعة تسمع فيها تسجيل المحاضرة النظري .. المحاضرة
+
+271
+00:20:46,940 --> 00:20:51,720
+العملي ساعة أيضا و ساعة النقاش. هلأ نيجي لتوزيع
+
+272
+00:20:51,720 --> 00:20:56,980
+الدرجات 30% من المادة راح يكون على ال quizzes و ال
+
+273
+00:20:56,980 --> 00:21:01,800
+midterm exam يعني راح أعطيكم مثلابعد ما نخلص تلت
+
+274
+00:21:01,800 --> 00:21:05,840
+معامل مثلا او اربعة رح احدد بالاتفاق معاكم على
+
+275
+00:21:05,840 --> 00:21:11,700
+موعد و توقيت ل quiz بنزللكم الأسئلة على ال model
+
+276
+00:21:11,700 --> 00:21:16,440
+بتفوتوا في موعد ال quiz بتقدمي ال quiz و بتطلعي
+
+277
+00:21:16,440 --> 00:21:19,620
+ففي النهاية انا بحسبلكم على مجموع ال quiz ذات و
+
+278
+00:21:19,620 --> 00:21:23,540
+الامتحان النصفي تلاتين درجةاربعين درجة على ال
+
+279
+00:21:23,540 --> 00:21:27,460
+final exam و تلاتين على ما على ال lab work و ال
+
+280
+00:21:27,460 --> 00:21:30,880
+experiment هذا في حالة لما يكون نرجع على المختبرات
+
+281
+00:21:30,880 --> 00:21:35,240
+و نطبق التجارب راح يكون في تلاتين درجة على التزامك
+
+282
+00:21:35,240 --> 00:21:40,000
+بالدوام أثناء التعويض التزامك بالمعرفة .. بالتجربة
+
+283
+00:21:40,000 --> 00:21:45,420
+ب .. فهمك للتجربة شغلك و حرصك على أنك انت تشتغلي و
+
+284
+00:21:45,420 --> 00:21:49,180
+تسلمي نتائج ما .. مش راح يكون فيه تقييم على صحة
+
+285
+00:21:49,180 --> 00:21:52,330
+النتائج لإن انتوا جايين تتعلمواو أنتوا بتفوتوا
+
+286
+00:21:52,330 --> 00:21:56,930
+مختبرات طبية لأول مرة فمش رح أجي أحقق .. أقيمك أن
+
+287
+00:21:56,930 --> 00:22:00,610
+والله نتيجتك اللي سلمتينيها صح أو خطأ و أنت جاي
+
+288
+00:22:00,610 --> 00:22:04,910
+تتعلمي لأ رح أسال .. رح .. رح أقايمك في حال أنه
+
+289
+00:22:04,910 --> 00:22:09,570
+يعني ال attitude تبعك يعني أن أنت هل كنت على
+
+290
+00:22:09,570 --> 00:22:14,670
+استعداد أنك تتعلمي ولا كنت care less سلمتيني نتائج
+
+291
+00:22:14,670 --> 00:22:18,490
+ولا ما سلمتي اشتغلتي ولا ما اشتغلتي طبقت التعليمات
+
+292
+00:22:18,490 --> 00:22:22,760
+اللي أنا حكيتهابحدافيرها ولا لأ ال .. ال .. مدى
+
+293
+00:22:22,760 --> 00:22:29,420
+الالتزام و مدى الاهتمام بالحضور و بالمدى الجدية
+
+294
+00:22:29,420 --> 00:22:33,960
+داخل المختبر هدول اللي عليهم تلاتين علامة مش صحة
+
+295
+00:22:33,960 --> 00:22:37,940
+النتائج نفسها لإن في مختبرات تانيةالمواد التخصص
+
+296
+00:22:37,940 --> 00:22:42,740
+التانية هتبدو تتحاسبوا على صحة النتائج لكن انت هنا
+
+297
+00:22:42,740 --> 00:22:46,540
+اليوم جاية تتعلمي جاية تستخدمي أدوات و تعملي
+
+298
+00:22:46,540 --> 00:22:51,480
+فحوصات و تستخدمي أجهزة لأول مرة تستخدميهم فانا مش
+
+299
+00:22:51,480 --> 00:22:56,920
+راح أحاسبك على خطأ في .. في كون انك انت جاية لأول
+
+300
+00:22:56,920 --> 00:23:01,520
+مرة بتفوتي مختبر طبي و بتمارسي ال .. الفحوصات و
+
+301
+00:23:01,520 --> 00:23:06,830
+النشاطات اللي موجودة داخل المختبرفي عندي جزء
+
+302
+00:23:06,830 --> 00:23:12,110
+باللغة العربية على شرح المادة و توزيع الدرجات
+
+303
+00:23:12,110 --> 00:23:16,550
+عندكم إيمالي إذا حابين ترسلوني عليها في أيضا حساب
+
+304
+00:23:16,550 --> 00:23:19,450
+ال facebook و حساب ال instagram و ال whatsapp على
+
+305
+00:23:19,450 --> 00:23:22,550
+حسابكم يعني كل إشي حابين تتواصلوا معايا فيه
+
+306
+00:23:22,550 --> 00:23:28,590
+اتواصلوا معايا أنا جاهزة لأقدم لكم يعني أي جوابة
+
+307
+00:23:28,590 --> 00:23:34,260
+لأي استفسار أو أي سؤال عندكمهلأ أنا ممكن ما أكون
+
+308
+00:23:34,260 --> 00:23:37,620
+ذكرت كل المعلومات اللي أنتم حابين تعرفوها ممكن
+
+309
+00:23:37,620 --> 00:23:44,220
+أكون خلفت عن جزئية معينة فلهيك بحب أنه إذا كان في
+
+310
+00:23:44,220 --> 00:23:48,260
+عندكم استفسار حابين تعرفوا أي إشي بيتعلق ب ..
+
+311
+00:23:48,400 --> 00:23:54,560
+التقديم للمادة او محتوى المادة او اي اش بيتعلق
+
+312
+00:23:54,560 --> 00:23:59,880
+بالمادة ككل عادي اسألوني و برجع بجاوبكم سواء كان
+
+313
+00:23:59,880 --> 00:24:02,700
+على group ال whatsapp او على اي موقع من مواقع ال
+
+314
+00:24:02,700 --> 00:24:07,160
+social media اللي انتوا بتعرفوا حسابي عليهم هيك
+
+315
+00:24:07,160 --> 00:24:14,560
+انا بكون خلصت يعطيكم العافية طبعا مهطن شوف يعنيتلت
+
+316
+00:24:14,560 --> 00:24:17,560
+مواعيد انا بديهم يتحددوا بالاتفاق ما بينكم بلاش
+
+317
+00:24:17,560 --> 00:24:22,660
+افرضهم عليكم يعني بش ما اكون شريرة من أولها طبعا
+
+318
+00:24:22,660 --> 00:24:30,130
+اه بالنسبة للجزئية العملي زي ما حكيتلكمإنه إحنا
+
+319
+00:24:30,130 --> 00:24:34,930
+هنعوض ولكن في بعض ال .. النشاطات أو بعض التجارب
+
+320
+00:24:34,930 --> 00:24:39,910
+راح نشوفها مع بعض مثلا من خلال فيديوهات أجيبلكم
+
+321
+00:24:39,910 --> 00:24:43,190
+فيديو نحضره أنا و أنتم سوا على .. في ال .. في ال
+
+322
+00:24:43,190 --> 00:24:49,610
+discussion لحتى تفهموا أكتر أنا عن شو بحكي في مثلا
+
+323
+00:24:49,610 --> 00:24:56,470
+ممكن يعني أجيب حدا من عائلتي يتبرع إنه مثلا أسحبله
+
+324
+00:24:56,470 --> 00:25:01,370
+عين الدمقدامكم تشوفوا كيف بتتم عملية السحاب يعني
+
+325
+00:25:01,370 --> 00:25:04,950
+نحاول على الأقل يكون في عندكم تصور لإن احنا إش
+
+326
+00:25:04,950 --> 00:25:09,550
+بنشتغل حتى يعني لما تيجوا تمارسوا بإيدكم يكون سهل
+
+327
+00:25:09,550 --> 00:25:14,750
+عليكم هذا الاشي فان شاء الله انا راح أحاولانه اتبع
+
+328
+00:25:14,750 --> 00:25:18,090
+معاكم هذا الاسلوب ان شاء الله ماريح يكون في صعوبة
+
+329
+00:25:18,090 --> 00:25:23,370
+مابدى انه مثلا تخافوا او ترتبكوا او اشي كل بداية
+
+330
+00:25:23,370 --> 00:25:28,270
+بتكون في الها رهبة اي نعم ولكن يعني ماخاب
+
+331
+00:25:28,270 --> 00:25:32,150
+مانستعانى بالله و حاولوا انه هيك تكونوا relaxed
+
+332
+00:25:32,150 --> 00:25:37,370
+تكونوا بكل اريحية يعني على استعداد انكم تتواصلوا
+
+333
+00:25:37,370 --> 00:25:44,560
+معايا لحتى يعني اوضحلكم اي اشي مبهم بالنسبة لكمو
+
+334
+00:25:44,560 --> 00:25:50,980
+بس هيك يعطيكم العافية و شكرا كتير لاستماعكم موفقين
+
+335
+00:25:50,980 --> 00:25:51,600
+بإبن الله
+
diff --git a/PL9fwy3NUQKwY9jl8xw-bWkVZkWcGGyspd/yuOrEl54r0w.srt b/PL9fwy3NUQKwY9jl8xw-bWkVZkWcGGyspd/yuOrEl54r0w.srt
new file mode 100644
index 0000000000000000000000000000000000000000..8b11e91b8aee273e782fe2dfe65e0ce6fe6bfc32
--- /dev/null
+++ b/PL9fwy3NUQKwY9jl8xw-bWkVZkWcGGyspd/yuOrEl54r0w.srt
@@ -0,0 +1,1322 @@
+1
+00:00:03,800 --> 00:00:07,540
+السلام عليكم ورحمة الله وبركاته طالبات العزيزات
+
+2
+00:00:07,540 --> 00:00:11,800
+اليوم إن شاء الله راح نستعرض مع بعض فيديو منزلي
+
+3
+00:00:11,800 --> 00:00:16,100
+صورته أنا بالمنزل، بعد توفير الأدوات اللازمة، و
+
+4
+00:00:16,100 --> 00:00:21,160
+هذا الفيديو بيشرح كيفية سحب عينة دم من منطقة
+
+5
+00:00:21,160 --> 00:00:24,500
+الوريد، تمام؟ راح نسحب عينة الدم من منطقة ال
+
+6
+00:00:24,500 --> 00:00:30,140
+antecubital، وراح نذكر أيضًا بعض النقاط المهمة
+
+7
+00:00:30,140 --> 00:00:34,460
+المتعلقة بعملية السحب. هذه النقاط المهمة احنا
+
+8
+00:00:34,460 --> 00:00:39,360
+ذكرناها في المحاضرة النظرية وحكينا أنها هي تعليمات
+
+9
+00:00:39,360 --> 00:00:44,600
+مهمة لازم نتبعها أثناء عملية السحب، و... لكن طبعًا
+
+10
+00:00:44,600 --> 00:00:48,280
+ما... ما... ال... الاشي ما بيكون متخيل بدون ما
+
+11
+00:00:48,280 --> 00:00:52,220
+نطبقه عمليًا، وبدون ما نشوفه بعيوننا.لهيك أنا اليوم
+
+12
+00:00:52,220 --> 00:00:57,420
+قررت أصور لكم هذا الـvideo لحتى أقرب الأشياء لأذهانكم
+
+13
+00:00:57,420 --> 00:01:01,900
+تشوفوا الأشياء بعيونكم لما نذكر المعلومة ونطبقها
+
+14
+00:01:01,900 --> 00:01:07,540
+تعرفوا إيش كان المقصود بهذه التعليمات أثناء ذكرها
+
+15
+00:01:07,540 --> 00:01:12,980
+في المحاضرة النظرية. بدايةً، أنا عندي لازم أُوّفر الأدوات
+
+16
+00:01:12,980 --> 00:01:19,520
+اللازمة في عملية السحب. محتاجة string، تمام؟ ومحتاجة
+
+17
+00:01:19,520 --> 00:01:23,180
+needles، هي الـneedles شايفينهم؟ تمام؟ محتاجة alcohol
+
+18
+00:01:23,180 --> 00:01:29,440
+ومحتاجة swab. وهلأ بشوف، طبعًا احنا أخذنا أنّه ال...
+
+19
+00:01:29,440 --> 00:01:36,800
+ال... الـsyringe مكوّنة من قطعتين، تمام؟ قطعة اللي
+
+20
+00:01:36,800 --> 00:01:41,680
+هي زي الأنبوب المدرج هذا، هاي القطعة بسميها الـ
+
+21
+00:01:41,680 --> 00:01:45,260
+barrel، تمام؟ بسميها الـbarrel، وهاي القطعة
+
+22
+00:01:45,260 --> 00:01:50,140
+المتحركة أنا بسميها plunger، تمام؟ بسميها plunger،
+
+23
+00:01:50,140 --> 00:01:55,060
+إذًا الـsyringe مكوّنة من قطعتين: الـbarrel والـ
+
+24
+00:01:55,060 --> 00:01:58,160
+...ال... الـplunger. هاي هم زي ما أنتم شايفين الـ
+
+25
+00:01:58,160 --> 00:02:02,580
+...الـbarrel المدرج، والـplunger اللي هو القطعة
+
+26
+00:02:02,580 --> 00:02:07,140
+المتحركة. طبعًا زي ما أنتم شايفين كمان ال... الـ
+
+27
+00:02:07,140 --> 00:02:11,940
+needle مكونة من ال... الـcap تبعها، الغطا تبعها،
+
+28
+00:02:11,940 --> 00:02:17,020
+تمام؟ وإيضًا طبعًا هذا الكاب أنا خلاص بتخلص منه.
+
+29
+00:02:17,020 --> 00:02:22,500
+هي ال... الـneedle مكوّنة من عدة أدوات. طبعًا احنا
+
+30
+00:02:22,500 --> 00:02:26,640
+حكينا معلومة، وإنه ذكرناها كثير أثناء المحاضرة
+
+31
+00:02:26,640 --> 00:02:32,950
+النظرية، حكينا إنه never ever recap, bend, or break
+
+32
+00:02:32,950 --> 00:02:39,390
+needle. يعني أنا ممنوع أرجع أغطي الـneedle بعد ما
+
+33
+00:02:39,390 --> 00:02:45,350
+أفتحها، ممنوع أحاول أُثنيها أو أكسرها لحد ما أتخلص
+
+34
+00:02:45,350 --> 00:02:49,670
+منها، لأنها ممكن يعني أثناء عملية إعادة الـcovering
+
+35
+00:02:49,670 --> 00:02:53,670
+مثلًا ممكن أنا وأنا بحاول أرجع الـneedle للـ
+
+36
+00:02:53,670 --> 00:02:57,690
+cover تبعها، أني أُنْخذ نفسي، وتكون الـneedle ملوثة بدم
+
+37
+00:02:57,690 --> 00:03:02,270
+المريض، ساعتها أنا بكون حقنت نفسي بدم المريض، تمام؟
+
+38
+00:03:02,270 --> 00:03:05,230
+هتلاحظوا أنه أنا خلال الـvideo ممكن أغطيها، بس أنا
+
+39
+00:03:05,230 --> 00:03:08,910
+حاضرة يعني في الاستخدام، ولكن أنتم هنا لأنكم لسه
+
+40
+00:03:08,910 --> 00:03:12,900
+هتكونوا مبتدئين وبتتعلموا، ممنوع ترجعوا تغطوها. على
+
+41
+00:03:12,900 --> 00:03:16,440
+طول، تتخلصوا من الـcap والـneedle بعد ما نخلص... سحب
+
+42
+00:03:16,440 --> 00:03:19,860
+عينة الدم، بنتخلص منها بالـsafety box، وإن شاء
+
+43
+00:03:19,860 --> 00:03:23,760
+الله راح نرجع للمعامل وترجعوا تشوفوا التطبيق
+
+44
+00:03:23,760 --> 00:03:27,360
+العملي كيف، وراح برضه كمان أحاول إن أنا أشوف...
+
+45
+00:03:27,360 --> 00:03:31,520
+يعني أسحب أمامكم عينة وأورجيكم كيف أنا بعمل
+
+46
+00:03:31,520 --> 00:03:36,480
+discard لكل شيء بال... بالـproper container، يعني
+
+47
+00:03:36,480 --> 00:03:42,760
+مثلًا ال... ال... الـgauze، والغطا تبع ال... الـ
+
+48
+00:03:42,760 --> 00:03:47,480
+needle، والـsyringes، بتخلص منها بالسلة العادية. الـ
+
+49
+00:03:47,480 --> 00:03:50,960
+cap، مثلًا ممكن بالسلة العادية. الـcotton swab بعد ما
+
+50
+00:03:50,960 --> 00:03:56,160
+يتلوث بالـblood، مثلًا إذا تلوث بالـblood بتخلص منه
+
+51
+00:03:56,160 --> 00:03:59,960
+في الـbiohazard container. الـsyringe لإنه بيكون
+
+52
+00:03:59,960 --> 00:04:03,760
+فيها بقايا، بتخلص منها في الـbiohazard
+
+53
+00:04:03,760 --> 00:04:07,520
+container. أيضًا ال... ال... الـneedle، الـneedle
+
+54
+00:04:07,520 --> 00:04:11,260
+بتخلص منها بالـsharp box، اللي هو الصندوق اللي
+
+55
+00:04:11,260 --> 00:04:15,900
+بتخلص من الأدوات الحادة فيه، من خلاله، تمام؟ إذًا
+
+56
+00:04:15,900 --> 00:04:21,920
+...إذًا ممنوع أنا أرجع أغطي هاي الـneedle، تمام؟ زي
+
+57
+00:04:21,920 --> 00:04:26,670
+ما أنتم شايفين، الـneedle مكونة من عدة أقسام. القسم
+
+58
+00:04:26,670 --> 00:04:31,750
+هذا البلاستيك الملون اللي بسميه hub، تمام؟ بسميه hub
+
+59
+00:04:31,750 --> 00:04:37,510
+هذا القسم كان موجود أو مدكور في المحاضرة، أنه بيكون
+
+60
+00:04:37,510 --> 00:04:40,050
+عليه الـgauge number، بس هنا مش موجود الـgauge
+
+61
+00:04:40,050 --> 00:04:44,110
+number. الـgauge number موجود على الغلاف تبع الـ
+
+62
+00:04:44,110 --> 00:04:48,850
+needle، وهورّجيكم إياه كمان شوية. الجزء الثاني من الـ
+
+63
+00:04:48,850 --> 00:04:52,770
+needle، اللي هو الشافت. هذا الجزء المعدني اللي
+
+64
+00:04:52,770 --> 00:04:56,950
+بنسميه الشافت. الجزء الثالث هو الفتحة هاي المائلة
+
+65
+00:04:56,950 --> 00:05:00,570
+اللي جاية بزاوية. هاي الفتحة اللي جاية بزاوية
+
+66
+00:05:00,570 --> 00:05:04,430
+بسميها الـbevel. الـneedle... bevel... فتحة الـ
+
+67
+00:05:04,430 --> 00:05:08,910
+needle، بسميها bevel، تمام؟ مذكورة هاي الأجزاء في
+
+68
+00:05:08,910 --> 00:05:13,090
+المحاضرة النظرية، وهاي أنتم هلأ شفتوها بعيونكم
+
+69
+00:05:13,090 --> 00:05:18,910
+عشان إنكم تحاولوا تربطوا النظري مع العملي، تمام؟
+
+70
+00:05:19,760 --> 00:05:24,380
+طيب، هلأ أنا بدي أبدأ عملية سحب الدم، إيش بدي
+
+71
+00:05:24,380 --> 00:05:28,940
+أسوي؟ أول شيء بدي أحضر أدواتي، يعني هاي عندي الـ
+
+72
+00:05:28,940 --> 00:05:32,340
+needle والـsyringe، بدي أحضرهم، بس قبل أن أحضرهم
+
+73
+00:05:32,340 --> 00:05:35,520
+بدي أورجيكم كيف بيكون مكتوب الـgauge number، هاي
+
+74
+00:05:35,520 --> 00:05:37,760
+الـgauge number، هاي الـneedle، هاي الزرقاء، مكتوب
+
+75
+00:05:37,760 --> 00:05:42,800
+عليها 23 gauge، يعني رقم الـgauge number 23. هي الـ
+
+76
+00:05:42,800 --> 00:05:46,600
+orange، الـneedle اللي لونها orange، إيش الـgauge
+
+77
+00:05:46,600 --> 00:05:49,220
+number اللي مكتوب عليها؟ زي ما أنتم شايفين هي هنا
+
+78
+00:05:49,220 --> 00:05:52,660
+مكتوب 25 G، يعني الـgauge number هذا
+
+79
+00:05:52,660 --> 00:05:57,060
+أكبر، إذًا هي في القطر أصغر، تمام؟ قطرها أصغر، إذًا
+
+80
+00:05:57,060 --> 00:06:01,470
+أصغر، إيش يعني أنا حاليًا؟ الـneedle الـorange، تمام؟
+
+81
+00:06:01,470 --> 00:06:04,870
+لأنها أكبر gauge number موجود، بعدين بيجي وراها الـ
+
+82
+00:06:04,870 --> 00:06:08,570
+...الـneedle الزرقاء، الـneedle الرمادية. الـgauge
+
+83
+00:06:08,570 --> 00:06:14,410
+number 22، هنا 23، لحظوا: 25، 23، 22، يعني أصغر
+
+84
+00:06:14,410 --> 00:06:21,730
+فأصغر فأكبر القطر، تمام؟ وهي الـneedle الخضراء 21
+
+85
+00:06:21,730 --> 00:06:26,870
+gauge، يعني هم مرتبين من الأصغر قطرًا والأكبر
+
+86
+00:06:26,870 --> 00:06:31,190
+gauge number، لحد اللي هو الأكبر قطرًا والأصغر gauge
+
+87
+00:06:31,190 --> 00:06:33,810
+number، تمام؟ من الأصغر gauge number للأكبر gauge
+
+88
+00:06:33,810 --> 00:06:37,850
+number... sorry، من الأكبر gauge number للأصغر gauge
+
+89
+00:06:37,850 --> 00:06:41,690
+number، والقطر طبعًا علاقة عكسية ما بين الـgauge
+
+90
+00:06:41,690 --> 00:06:45,990
+number وما بين الـneedle. هلأ هي زي ما أنتم
+
+91
+00:06:45,990 --> 00:06:51,130
+شايفين، الـsyringe طبعًا بتكون مغلّفة. هستخدم هذه الـ
+
+92
+00:06:51,130 --> 00:06:57,270
+...الـneedle، بحيث إنّي أورجيكم كيف نفتحها. طبعًا هي
+
+93
+00:06:57,270 --> 00:06:59,830
+زي ما أنتم شايفين مغلّفة بنيلون، وبالجزء الثاني
+
+94
+00:06:59,830 --> 00:07:05,030
+ورقي. أنا بفتحها من جهة الورق بهذا الشكل، تمام؟ لأنّه
+
+95
+00:07:05,030 --> 00:07:08,730
+لو بدي أفتحها من ناحية النيلون بدي قوة، وأنا لأمزّع
+
+96
+00:07:08,730 --> 00:07:12,750
+النيلون. فأسرع شيء من جهة الورقية. هاي الـneedle هنا
+
+97
+00:07:12,750 --> 00:07:15,870
+مش مستخدمة، بدي أورجيكم كيف بدي أفتحها من الجهة
+
+98
+00:07:15,870 --> 00:07:20,630
+اللي بدي استخدمها، من جهة الورق. بفتحها هيك شوي، و
+
+99
+00:07:20,630 --> 00:07:24,870
+بركبهم على بعض. بعدين بتخلص من الغلاف الورقي اللي
+
+100
+00:07:24,870 --> 00:07:28,590
+موجود على كل من الـsyringe والـneedle بهذا الشكل.
+
+101
+00:07:28,590 --> 00:07:32,750
+بتأكد من أنّ الـbevel، فتحة الـneedle، مقابلة
+
+102
+00:07:32,750 --> 00:07:37,190
+للتدريج. طبعًا عندي هي الـsyringe 3 سم بتاخد
+
+103
+00:07:37,190 --> 00:07:39,730
+في عندي الـsyringes بتاخد... هيها، دي الـsyringe بتاخد
+
+104
+00:07:39,730 --> 00:07:42,970
+5 سم، في syringes بتاخد 10 سم، في
+
+105
+00:07:42,970 --> 00:07:46,550
+2 سم، هيها بتاخد 3 سم مكعب، يعني
+
+106
+00:07:46,550 --> 00:07:53,100
+3 مل. طيب، وزي ما حكينا، بتأكد أنه فتحة الـ
+
+107
+00:07:53,100 --> 00:07:57,640
+needle اللي هنا مقابلة لإيش؟ للتدريج اللي على الـ
+
+108
+00:07:57,640 --> 00:08:02,580
+syringe. ب... بعد هيك بثبت الـneedle، بخلق... بتأكد
+
+109
+00:08:02,580 --> 00:08:07,780
+أنّها شاكة كويس. بحاول إنّي يعني أفكّ ال... ال...
+
+110
+00:08:07,780 --> 00:08:12,930
+cap، أرخي شوية وألين الـplunger. طبعًا زي ما أنتم
+
+111
+00:08:12,930 --> 00:08:17,050
+شايفين، هي هنا في الـsyringe هذه، بدي قوة لحتى أفتح
+
+112
+00:08:17,050 --> 00:08:20,850
+الـplunger، لأنّه الـplunger بيكون tight، طبعًا ب...
+
+113
+00:08:20,850 --> 00:08:25,390
+بقوة ب... بافتحه، فالأفضل إنّي ألينه، يعني أحركه، و
+
+114
+00:08:25,390 --> 00:08:28,890
+بعدين أرجع أفرّغ الهواء منه مرة ثانية عشان يصير لين.
+
+115
+00:08:28,890 --> 00:08:33,910
+طبعًا لحتى يصير لين وسهل إنّي أرجعه لورا أثناء
+
+116
+00:08:33,910 --> 00:08:39,550
+السحب، وأبدأ آخذ الـvolume اللي بدي إياها. طبعًا إذا هاي
+
+117
+00:08:39,550 --> 00:08:42,790
+الـneedle والـsyringe جاهزين، الـneedle ثابتة
+
+118
+00:08:42,790 --> 00:08:48,110
+مركبة كويس على الـsyringe، وال... زي ما أنتم
+
+119
+00:08:48,110 --> 00:08:53,070
+شايفين، مركبة كويس الـneedle على الـsyringe، و
+
+120
+00:08:53,070 --> 00:08:57,510
+الفتحة مقابل التدريج. رَخّيت شوية الغطاء، وألّنت
+
+121
+00:08:57,510 --> 00:09:02,650
+الـplunger. وطبعًا إيش بيلزمني بعد هيك؟ بيلزمني كحول 70%
+
+122
+00:09:02,650 --> 00:09:08,670
+الكحول، وبيلزمني swab. وطبعًا هاي إيد المريض بخليها
+
+123
+00:09:08,670 --> 00:09:13,090
+إنها ممتدة أمامي على الـbench، وعلشان أبدأ أسحب
+
+124
+00:09:13,090 --> 00:09:16,450
+العينة. طبعًا أنا بدي أسحب من منطقة الـAntecubital
+
+125
+00:09:16,450 --> 00:09:20,430
+يعني هنا في عندي median وفي عندي cephalic veins.
+
+126
+00:09:20,430 --> 00:09:24,130
+طبعًا هذه الأوردة اللي بتكون واضحة أكثر شيء
+
+127
+00:09:24,130 --> 00:09:29,190
+للاستخدام، فأنا من خلالهم بسحب عينة الدم اللي بدي
+
+128
+00:09:29,190 --> 00:09:36,350
+أسحبها، تمام؟ طيب، بدي... إذا هيني أنا حضرت أدواتي: الـ
+
+129
+00:09:36,350 --> 00:09:43,350
+syringe والـneedle وجاهزين، الكحول 70% ethanol أو
+
+130
+00:09:43,350 --> 00:09:48,630
+70% isopropanol، حكينا، تمام؟ بعدين طبعًا الـswab، بدي
+
+131
+00:09:48,630 --> 00:09:52,350
+أنا محتاجة اثنتين، واحدة أبلّلها بالكحول وتكون
+
+132
+00:09:52,350 --> 00:09:58,450
+للتعقيم، وواحدة ثانية جافة، dry swab، لحتى أحطها على
+
+133
+00:09:58,450 --> 00:10:02,650
+مكان الجرح أو مكان الـneedle، يعني بعد ما أخلص سحب
+
+134
+00:10:02,650 --> 00:10:07,730
+عينة الدم، تمام؟ طيب، بعد ما أحضر أدواتي، إيش بدي
+
+135
+00:10:07,730 --> 00:10:12,030
+أعمل؟ طبعًا أنا بعد ما حددت الوريد تبعي، أو يعني...
+
+136
+00:10:12,030 --> 00:10:16,910
+يعني حددت المنطقة اللي بدي أسحب منها، بروح إيش
+
+137
+00:10:16,910 --> 00:10:22,170
+بعمل؟ بربط الـtourniquet. طبعًا هاي أدواتي: هاي الـswab
+
+138
+00:10:22,170 --> 00:10:27,350
+المبلّل، وهاي الـswab الجافة. طبعًا المبلل بالكحول، الـdry
+
+139
+00:10:27,350 --> 00:10:32,830
+swab علشان أحطه مكان ال... بعد السحب. وبعد هيك بدي
+
+140
+00:10:32,830 --> 00:10:39,330
+أربط الـtourniquet تبعي. طبعًا الـtourniquet وظيفتها إنّه
+
+141
+00:10:39,330 --> 00:10:44,670
+أنا لما بدي أربط الـtourniquet، وظيفتها إنّها تعملي ضغط
+
+142
+00:10:44,670 --> 00:10:49,790
+على منطقة الأوردة، بحيث إنّها تبرزها، يعني، تمام؟ إذًا
+
+143
+00:10:49,790 --> 00:10:53,950
+بس هي apply pressure، هاي وظيفتها، تمام؟ حتى تبرز لي
+
+144
+00:10:53,950 --> 00:11:00,940
+الأوردة، ويسهل سحب العينة، تمام؟ ال... الـtourniquet
+
+145
+00:11:00,940 --> 00:11:05,040
+اللي أنا ممكن أستخدمها، يعني الرابطة، ممكن أستخدم الـ
+
+146
+00:11:05,040 --> 00:11:08,860
+gloves العادية، أو ممكن في رابطة خاصة بأستخدمها، بتكون
+
+147
+00:11:08,860 --> 00:11:12,420
+موجودة في المختبرات. إذا ما توفرت الرابطة اللي
+
+148
+00:11:12,420 --> 00:11:15,500
+موجودة في المختبرات، ممكن أستخدم الـgloves، وعادي
+
+149
+00:11:15,500 --> 00:11:18,740
+سهل جدًا إنّي أستخدم الـgloves. طبعًا كيف أنا بدي
+
+150
+00:11:18,740 --> 00:11:21,420
+...هي طبعًا هي الرابطة اللي بتكون موجودة في
+
+151
+00:11:21,420 --> 00:11:24,640
+المختبرات، بحطها هنا علشان تعملي pressure، طبعًا
+
+152
+00:11:24,640 --> 00:11:30,920
+ببعدها، بتكون هذه الرابطة، أنا ببعدها عن منطقة السحب
+
+153
+00:11:30,920 --> 00:11:34,600
+بـ3 inches، يعني أنا مثلًا ب... بحط أصابعي ثلاثة
+
+154
+00:11:34,600 --> 00:11:39,480
+...ثلاثة أصابع، وبعدين بحط الرابطة بعدهم، تمام؟ فوق
+
+155
+00:11:39,480 --> 00:11:44,380
+منطقة السحب. ممكن كمان في خيار ثاني، لو أنا مش متوفر
+
+156
+00:11:44,380 --> 00:11:48,340
+عندي هذه الرابطة، ممكن أستخدم الـgloves زي ما حكينا.
+
+157
+00:11:48,750 --> 00:11:52,190
+هلأ بنشوف كيف أنا بدي أربط الـgloves بالأول، و
+
+158
+00:11:52,190 --> 00:11:57,970
+بعدين بنشوف كيف بنستخدم الـtourniquet الثانية،
+
+159
+00:11:57,970 --> 00:12:03,490
+تمام؟ إذًا حكينا إنّه ال... الـtourniquet وظيفتها
+
+160
+00:12:03,490 --> 00:12:08,270
+إنّها فقط to apply pressure، علشان إيش تعملي؟ to...
+
+161
+00:12:08,270 --> 00:12:12,090
+علشان تبرز الأوردة، ويسهل استخدام... يسهل سحب
+
+162
+00:12:12,090 --> 00:12:16,650
+عينة الدم. هلأ الـturn... الـtourniquet اللي هي الـ
+
+163
+00:12:16,650 --> 00:12:19,370
+gloves، أنا بمسكها بهذا الشكل، يعني من... هي خمس
+
+164
+00:12:19,370 --> 00:12:22,470
+أصابع، أنا بأستخدم الأصبع... ب... بمسك من الأصبع
+
+165
+00:12:22,470 --> 00:12:25,370
+الوسطى، ومن الط
+
+223
+00:17:31,440 --> 00:17:36,060
+الـ gloves سيان، المهم إذا ما اتوفر عندي هاي الرابطة
+
+224
+00:17:36,060 --> 00:17:40,220
+أنا بستخدم الـ gloves، طبعًا احنا حكينا أنه لازم تكون
+
+225
+00:17:40,220 --> 00:17:43,360
+الرابطة على بعد ثلاثة inches، يعني أنا بجيب ثلاثة
+
+226
+00:17:43,360 --> 00:17:46,400
+أصابع فوق منطقة الوريد اللي أنا بدي أسحب منه، و
+
+227
+00:17:46,400 --> 00:17:49,100
+بعدين بربط الرابطة طبعًا
+
+228
+00:17:52,190 --> 00:18:01,310
+طبعًا بركبها على بعض ثلاثة inches وبسكر بضغطها
+
+229
+00:18:01,310 --> 00:18:11,170
+بشدها، وبيصير عندي الوريد بارز وجاهز لعملية السحب
+
+230
+00:18:11,320 --> 00:18:15,980
+طيب، إذا أنا ربطت الـ tourniquet ولمست
+
+231
+00:18:15,980 --> 00:18:19,640
+الوريد، حددته طبعًا، بسأل المريض، بخلي المريض أنه يعمل
+
+232
+00:18:19,640 --> 00:18:23,620
+قبضة بإيده، ما يظل يفتح ويسكر، لأ، بس قبضة ويغلقها
+
+233
+00:18:23,620 --> 00:18:27,580
+وحددت الوريد اللي أنا بدي أسحبه، بعد ما لمسته، و
+
+234
+00:18:27,580 --> 00:18:31,900
+اتحسسته طبعًا، وحكينا أنه لما ألمسه مطاطي، بحس أنه في
+
+235
+00:18:31,900 --> 00:18:36,650
+إشي مطاطي تحت إيدي، مع الممارسة راح تعرفوا تمام؟ كيف
+
+236
+00:18:36,650 --> 00:18:40,690
+عملية التعقيم بالـ سواب اللي مبللة بالكحول
+
+237
+00:18:40,690 --> 00:18:45,710
+بعمل بشكل دائري، ببدأ من دائرة ضيقة،
+
+238
+00:18:45,710 --> 00:18:50,270
+وببدأ أوسع في الدائرة زي ما أنتم شايفين، ليش طيب؟
+
+239
+00:18:50,270 --> 00:18:52,990
+أنا بعمل هيك، علشان أنا بأخذ الـ contamination من
+
+240
+00:18:52,990 --> 00:18:56,710
+منطقة، يعني أي contamination موجودة في منطقة السحب
+
+241
+00:18:56,710 --> 00:19:01,090
+بأخذها وببعدها على الأطراف، تمام؟ لو أنا بدي
+
+242
+00:19:01,090 --> 00:19:04,550
+أعمل العكس، تمام؟ لو بدي أعمل العكس، يعني بدي ألمس
+
+243
+00:19:04,550 --> 00:19:07,890
+وأجي أركز وكله في المنتصف، يعني أنا هيك
+
+244
+00:19:07,890 --> 00:19:10,950
+لميت الـ contamination كلها وحطيتها في منطقة
+
+245
+00:19:10,950 --> 00:19:16,360
+المنتصف، وهذا إشي غلط، يعني ببدأ
+
+246
+00:19:16,360 --> 00:19:20,380
+ضيق وببدأ أوسع الدائرة، هذا هو الطريقة الصحيحة
+
+247
+00:19:20,380 --> 00:19:23,960
+للتعقيم، أو ممكن مسحة زي ما أنتم شايفين، هيك مسحة
+
+248
+00:19:23,960 --> 00:19:27,780
+واحدة فقط، ولو كان في عندي excess alcohol بنشفه
+
+249
+00:19:27,780 --> 00:19:33,920
+بسواب، لأن الـ alcohol حكينا أنه ممكن يعمل لي
+
+250
+00:19:33,920 --> 00:19:38,900
+مشاكل hemoconcentration أو hemolysis، أو يعني يأثر
+
+251
+00:19:38,900 --> 00:19:44,340
+فبالتالي حكينا أنه بأخلص منه، هذا هو الوريد اللي
+
+252
+00:19:44,340 --> 00:19:48,300
+أنا بدي أسحب منه، حكينا أنه ما بيصير ألمس الوريد بعد التعقيم
+
+253
+00:19:48,300 --> 00:19:53,060
+طبعًا أنا بس هنا جاية بأحدد، بس أحكي لكم أن هذا هو الوريد اللي بدي أسحب
+
+254
+00:19:53,060 --> 00:19:55,680
+منه، وهرجع أعقب مرة ثانية، أنا لازم أكون لمسته و
+
+255
+00:19:55,680 --> 00:20:00,160
+حددته قبل عملية التعقيم، طبعًا إذا بعقم مرة ثانية، و
+
+256
+00:20:00,160 --> 00:20:05,820
+بجفف الـ excess alcohol اللي موجود، وبعد هيك بأجي
+
+257
+00:20:05,820 --> 00:20:11,800
+بالـ syringe والـ needle، بفتحها، بمسك الـ
+
+258
+00:20:11,800 --> 00:20:16,740
+syringe والـ needle مسكة خاصة، بحيث أن الـ زي ما
+
+259
+00:20:16,740 --> 00:20:23,790
+أنتم شايفين، الثلاث أصابع تبعوني تحت الـ
+
+260
+00:20:23,790 --> 00:20:28,270
+الثلاث أصابع هدول تحت الـ syringe، تمام؟
+
+261
+00:20:28,270 --> 00:20:31,650
+الإبهام فوق الـ syringe، والسبابة عند منطقة الـ hub
+
+262
+00:20:31,650 --> 00:20:34,790
+زي ما أنتم شايفين، فتحت الـ needle مقابلة للتدريج، و
+
+263
+00:20:34,790 --> 00:20:39,050
+ممكن أنا أشد الـ skin بالإبهام، أو ممكن أتركها، أنا
+
+264
+00:20:39,050 --> 00:20:42,830
+في هذه الحالة الوريد واضح، ومش محتاجة أشد الـ
+
+265
+00:20:42,830 --> 00:20:45,630
+أشد الـ skin بإصبعي الثاني، الإبهام، إذا بمسك
+
+266
+00:20:45,630 --> 00:20:49,870
+و زي ما أنتم شايفين، هذا هو اتجاه الوريد، أنا بفوت
+
+267
+00:20:49,870 --> 00:20:53,810
+في نفس اتجاه الوريد، تمام؟ ما بنفع أنا أجي هيك بهذا
+
+268
+00:20:53,810 --> 00:20:58,670
+الشكل، أفوت، لأ، بفوت في نفس اتجاه الوريد، حكينا لأنه
+
+269
+00:20:58,670 --> 00:21:04,050
+لو أنا بدي أفوت مثلًا في اتجاه معاكس، ممكن أنا أخرق
+
+270
+00:21:04,050 --> 00:21:07,430
+الوريد من الجهة الثانية، ويبدأ يتراكم الدم تحت الـ
+
+271
+00:21:07,430 --> 00:21:11,330
+skin ويعمل لي hematoma، وممكن يتوقف عندي السحب في
+
+272
+00:21:11,330 --> 00:21:14,850
+داخل الـ syringe، إذا أنا بأجي في نفس اتجاه الوريد، و
+
+273
+00:21:14,850 --> 00:21:20,660
+بفوت، طبعًا بفوت في زاوية معينة، اللي طبعًا إذا كانت
+
+274
+00:21:20,660 --> 00:21:25,840
+الوريد superficial، سطحي زي ما أنتم شايفين هنا
+
+275
+00:21:25,840 --> 00:21:28,840
+واضح، بتكون الزاوية قليلة، إذا كان الوريد
+
+276
+00:21:28,840 --> 00:21:33,600
+أنا حاساه بس مش شايفاه، يعني هو عميق، تمام؟ بكبر
+
+277
+00:21:33,600 --> 00:21:39,230
+الزاوية، وهذه أشياء إن شاء الله رح تتعلموها مع
+
+278
+00:21:39,230 --> 00:21:42,510
+الممارسة، بذكرها الآن، ولكن رح تتعلموها مع الممارسة
+
+279
+00:21:42,510 --> 00:21:46,890
+و زي ما أنتم شايفين، بفوت في، طبعًا بكون طبعًا زي
+
+280
+00:21:46,890 --> 00:21:51,890
+ما أنتم شايفين هنا، إيدي على الـ skin تبع المريض
+
+281
+00:21:51,890 --> 00:21:56,680
+بثبت إيدي على الـ skin، إيدي، هالثلاث أصابع اللي هم
+
+282
+00:21:56,680 --> 00:22:00,640
+تحت الـ syringe، بثبتهم على إيد المريض، عشان لما أجي
+
+283
+00:22:00,640 --> 00:22:04,800
+أسحب الـ plunger تبع الـ syringe، تكون إيدي ثابتة، ما أرجعش
+
+284
+00:22:04,800 --> 00:22:11,060
+لا إراديًا، ولا شعوريًا، أحس حالي برجع بطلع من
+
+285
+00:22:12,160 --> 00:22:16,360
+الوريد بدون ما أسحب الكمية اللازمة، لأ، فإذا بثبت
+
+286
+00:22:16,360 --> 00:22:20,380
+زي ما أنتم شايفين، بثبت إيدي على إيد المريض
+
+287
+00:22:20,380 --> 00:22:24,140
+وبفوت في نفس اتجاه الوريد، تمام، بزاوية قليلة، لأن هو
+
+288
+00:22:24,140 --> 00:22:30,460
+superficial، وبعد هيك، أول ما بفوت في الوريد الصح
+
+289
+00:22:30,460 --> 00:22:35,780
+بتعلم عندي زي ما أنتم شايفين هنا، بتعلم عندي نقطة
+
+290
+00:22:35,780 --> 00:22:39,700
+blood في منطقة الـ hub، يعني معناها إنه خلاص المسار
+
+291
+00:22:39,700 --> 00:22:43,380
+الدم فاتح، ببدأ إيش أعمل؟ برجع الـ plunger لورا طبعًا
+
+292
+00:22:43,380 --> 00:22:50,750
+إذا تكونت عندي نقطة دم، برجع الـ plunger لورا زي ما
+
+293
+00:22:50,750 --> 00:22:54,170
+أنتم شايفين، ويبدأ يعبي blood داخل الـ syringe، طبعًا
+
+294
+00:22:54,170 --> 00:23:00,890
+هيتعبي، أنا هنا بأخذ الـ volume اللي بدي إياه، طبعًا حسب
+
+295
+00:23:00,890 --> 00:23:04,990
+الـ volume اللي بدي إياه، أنا محتاجة اليوم أخد بس 1 cm
+
+296
+00:23:04,990 --> 00:23:08,830
+لأن هذا فيديو تعليمي، بس بوضح لكم قياس السحب فقط، لا
+
+297
+00:23:08,830 --> 00:23:12,850
+غير، لكن إذا كان، يعني أنا محتاجة volume أكثر، بأخذ
+
+298
+00:23:12,850 --> 00:23:19,060
+volume أكثر، بعدين طبعًا زي ما أنتم شايفين، بعد ما
+
+299
+00:23:19,060 --> 00:23:23,280
+أخذ الـ volume اللي بدي إياه، أول خطوة وأنا لساني جوا
+
+300
+00:23:23,280 --> 00:23:26,680
+إيش بعمل؟ بفك الـ tourniquet طبعًا، وبعدين خلصت فكيت
+
+301
+00:23:33,290 --> 00:23:38,310
+الـ tourniquet، بحط الـ dry swab على منطقة السحب، بطلع
+
+302
+00:23:38,310 --> 00:23:41,770
+بدون ما أضغط، بعدين بخليه يضغط، بحكي للمريض اضغط، و
+
+303
+00:23:41,770 --> 00:23:45,910
+بتأكد أنه عندي يضغط هكذا، أنا أخدت الـ
+
+304
+00:23:45,910 --> 00:23:52,340
+volume اللي أنا بدي إياه، تمام؟ وبعد هيك بفضيه في الـ
+
+305
+00:23:52,340 --> 00:23:56,440
+tube، سواء كان الـ tube هذه فيها EDTA أو heparin أو
+
+306
+00:23:56,440 --> 00:24:00,840
+sodium citrate، أو كانت فاضية، مش فيها إشي، أي نوع الـ
+
+307
+00:24:00,840 --> 00:24:04,560
+tube، طبعًا حسب نوع الفحص اللي أنا بدي أعمله، بكون
+
+308
+00:24:04,560 --> 00:24:07,720
+عارفة الفحص اللي بدي أعمله، وعارفة الـ tube اللي
+
+309
+00:24:07,720 --> 00:24:12,040
+بدي أستخدمها، وإيش فيها additive، إيش نوع الـ
+
+310
+00:24:12,040 --> 00:24:15,910
+anticoagulant اللي فيها، تمام؟ وإذا كان أصلاً فيها
+
+311
+00:24:15,910 --> 00:24:19,950
+anticoagulant أو لا، ممكن أكون محتاجة أنه أنا بدي
+
+312
+00:24:19,950 --> 00:24:24,970
+serum، فأحطها في tube إما إبلان فاضية، مش فيها إشي
+
+313
+00:24:24,970 --> 00:24:30,570
+أو tube مثلًا فيها clot activator، أو clot activator
+
+314
+00:24:30,570 --> 00:24:33,490
+مع جل، أو أي إشي من الجدول اللي احنا ذكرناها في
+
+315
+00:24:33,490 --> 00:24:39,850
+محاضرة الـ blood component، تمام؟ طيب، محتويات الـ
+
+316
+00:24:39,850 --> 00:24:43,690
+syringe اللي فيها عينة الدم، أنا بفضيها immediately، حالا
+
+317
+00:24:43,690 --> 00:24:45,890
+يعني ما بستنى عليها، ما بحطها على الـ bench وأروح
+
+318
+00:24:45,890 --> 00:24:51,390
+مثلًا أعمل شغل، بعدين ارجع أفرغها داخل الـ tube، لإني
+
+319
+00:24:51,390 --> 00:24:54,600
+هنا الـ blood راح يتجلط، تمام؟ راح يصير في
+
+320
+00:24:54,600 --> 00:24:59,380
+coagulation، فبالتالي لازم أنا أفرغها مباشرة أو
+
+321
+00:24:59,380 --> 00:25:03,300
+immediately، في الحال، في داخل الـ tube، طبعًا أنا
+
+322
+00:25:03,300 --> 00:25:10,920
+اليوم أنا جايب لكم مثال الـ tube، يعني هو ما فيش فيه
+
+323
+00:25:10,920 --> 00:25:15,620
+إشي، بس فيه clot activator، طبعًا، لذا أنا بفضل محتوى
+
+324
+00:25:15,620 --> 00:25:20,660
+الـ blood في الـ tube الخاصة، وطبعًا immediately، فورًا
+
+325
+00:25:20,660 --> 00:25:24,910
+هيه، أنا في عندنا مثلًا الـ tube زي ما أنتم شايفين
+
+326
+00:25:24,910 --> 00:25:31,110
+نعمل هون Red color، نعمل focus بس على منطقة الـ
+
+327
+00:25:31,110 --> 00:25:36,030
+labeling، زي ما أنتم شايفين هنا مكتوب أن في Clot
+
+328
+00:25:36,030 --> 00:25:39,310
+activator، هاي الـ additives اللي أنا حكيت لكم، الـ additive
+
+329
+00:25:39,310 --> 00:25:41,730
+أنتم ما بتشوفوها، يعني الـ anticoagulant داخل الـ
+
+330
+00:25:41,730 --> 00:25:44,950
+tube ممكن يكون عبارة عن قطرات، ممكن يكون عبارة عن
+
+331
+00:25:44,950 --> 00:25:47,430
+powder موجودة على الجدار، يعني أنتم ما بتشوفوها، زي
+
+332
+00:25:47,430 --> 00:25:52,730
+ما شايفين هاي الـ الأشياء اللي موجودة داخل
+
+333
+00:25:52,730 --> 00:25:57,330
+الـ tube اللي عاملة زي تمشية، هذه اللي احنا بنحكي
+
+334
+00:25:57,330 --> 00:26:01,350
+عنها clot activator، تمام، أنا بحط الـ blood فيه، فهذا
+
+335
+00:26:01,350 --> 00:26:05,950
+بيشجع أنه يصير في عندي عملية coagulation، تجلط للدم
+
+336
+00:26:05,950 --> 00:26:11,920
+فإذا لما أنا بدي أفصل العينة، هذه اللي بيفصل فوق الـ
+
+337
+00:26:11,920 --> 00:26:16,280
+blood فوق الـ clot، لو أنا بدي اخذ طبعًا السائل اللي
+
+338
+00:26:16,280 --> 00:26:19,540
+بيكون موجود فوق الـ blood، هذا السائل بيكون عبارة عن
+
+339
+00:26:19,540 --> 00:26:22,200
+serum، طبعًا بيكون عبارة عن serum، يعني ما فيه
+
+340
+00:26:22,200 --> 00:26:26,700
+fibrin، طبعًا هذه، بنحكي عنها vacutainer tube
+
+341
+00:26:26,700 --> 00:26:32,560
+يعني أنا بحطها في، في الـ الأدوات الـ vacutainer، و
+
+342
+00:26:32,560 --> 00:26:35,560
+ببدأ أسحب على طول مباشرة، بيعبى دم منها من خلال
+
+343
+00:26:35,560 --> 00:26:39,840
+الوريد، مش بتوفر عندي vacutainer، ولكن هرجيكم يا
+
+344
+00:26:39,840 --> 00:26:43,900
+إن شاء الله خلال عودتنا لـ المعمل، إن شاء الله
+
+345
+00:26:43,900 --> 00:26:48,500
+إذا رجعنا بالسلامة، وراح تشوفوا، راح أسحب لكم
+
+346
+00:26:48,500 --> 00:26:51,180
+باستخدام vacutainer، لحتى تشوفوا كيف أنه أنا
+
+347
+00:26:51,180 --> 00:26:57,200
+باستخدام هاي القنابيب على طول بتعبي فيها الدم
+
+348
+00:26:59,190 --> 00:27:01,750
+زي ما أنتم شايفين هنا، الـ cover عبارة عن
+
+349
+00:27:01,750 --> 00:27:07,890
+مطاط، وسهل أنه يختَرَقَ الـ needle، و
+
+350
+00:27:07,890 --> 00:27:12,310
+يتم تعبئة الـ blood داخل الـ tube، طبعًا؟ اللي أنا لو
+
+351
+00:27:12,310 --> 00:27:17,170
+بدي أفرغ الـ blood داخل الـ tube هاي، في عندي طريقتين،
+
+352
+00:27:17,170 --> 00:27:21,770
+إما أنه أنا أفتح الـ tube، يعني أشيل الغطاء وأفضي على
+
+353
+00:27:21,770 --> 00:27:26,870
+الجدار، طبعًا؟ وأتخلص من الـ needle، بعدين أفضي
+
+354
+00:27:26,870 --> 00:27:30,270
+محتويات الـ syringe على الجدار، بحيث أنه ما يتكسر
+
+355
+00:27:30,270 --> 00:27:33,750
+الدم، بعدين أرجع أغطي الـ tube، أعمل mix وأعمل
+
+356
+00:27:33,750 --> 00:27:37,790
+labeling، أكتب الـ label، معلومات المريض في المكان
+
+357
+00:27:37,790 --> 00:27:44,610
+المخصص هنا، أو ممكن بطريقة ثانية، أنه باستخدام
+
+358
+00:27:44,610 --> 00:27:48,450
+الـ needle، أخترق الـ غطاء المطاطي، وهاد الأنبوب
+
+359
+00:27:48,450 --> 00:27:52,070
+مفرغ من الهواء، فعليًا، ما هو مفرغ من الهواء، راح
+
+360
+00:27:52,070 --> 00:27:56,030
+يسحب volume، راح يسحب السائل، فمجرد ما أنا أخترق الـ
+
+361
+00:27:56,030 --> 00:28:01,770
+needle، أخترق الغطاء بالـ needle، راح على طول يعبي الـ
+
+362
+00:28:01,770 --> 00:28:05,810
+blood داخل الـ tube، تمام؟ إذا هذه الـ tube مبسطة
+
+363
+00:28:05,810 --> 00:28:09,530
+عليا، إن أنا ممكن أعبيها إما على الجدار، أو باستخدام
+
+364
+00:28:09,530 --> 00:28:15,940
+الـ يعني أنه أنا أخترق الـ الغطاء المطاطي
+
+365
+00:28:15,940 --> 00:28:18,280
+اللي موجود فيه، وهي الغطاء المطاطي هذا اللي
+
+366
+00:28:18,280 --> 00:28:22,260
+لونه رمادي، سهل اختراقه بالـ needle، تمام؟ زي الـ
+
+367
+00:28:22,260 --> 00:28:29,470
+يعني إشي جلد، مطاطي، تمام؟ هذا بالنسبة لـ
+
+368
+00:28:29,470 --> 00:28:34,010
+YouTube، ضروري جدًا بعد ما أنا أعبي العينة، أفضيها
+
+369
+00:28:34,010 --> 00:28:41,050
+أعمل mix وأعمل labeling، أحط معلومات المريض، اسمه
+
+370
+00:28:41,050 --> 00:28:46,790
+الـ initial والـ surname والـ middle initial، وأحط
+
+371
+00:28:46,790 --> 00:28:50,430
+تاريخ ووقت السحب، والـ initial of الـ phlebotomist على
+
+372
+00:28:50,430 --> 00:28:57,060
+العينة، تمام؟ وهيك بتكون عندي صارت العينة جاهزة
+
+373
+00:28:57,060 --> 00:28:59,800
+للفحوصات، ممكن أنا أحطها داخل جهاز الـ
+
+374
+00:28:59,800 --> 00:29:07,840
+centrifuge، وأفصل، يعطيني طبعًا serum، طبعًا يعطيني
+
+375
+00:29:07,840 --> 00:29:12,280
+serum، طبعًا هيك احنا بنكون تعلمنا كيف أنا أسحب
+
+376
+00:29:12,280 --> 00:29:17,900
+عينة من الوريد، تمام؟ إن شاء الله فور توفر الـ
+
+377
+00:29:17,900 --> 00:29:23,240
+الأدوات الخاصة، بسحب عينة من الـ skin، سواء skin
+
+378
+00:29:23,240 --> 00:29:27,140
+puncture، يعني سواء من الإصبع أو من الـ heel، راح إن
+
+379
+00:29:27,140 --> 00:29:31,200
+شاء الله راح أشرح لكم إياها في فيديو تعليمي آخر، وإن
+
+380
+00:29:31,200 --> 00:29:34,440
+شاء الله تكونوا هيك استفدتم، والأشياء يعني، أو
+
+381
+00:29:34,440 --> 00:29:37,110
+المعلومات اللي احنا ذكرناها، كيف أنا أفوت فيها، في
+
+382
+00:29:37,110 --> 00:29:40,870
+اتجاه الوريد، كيف أعقم، كيف أربط الـ tourniquet، هذه
+
+383
+00:29:40,870 --> 00:29:44,290
+كلها الشغلات إن شاء الله تكون واضحة، وشفتوها
+
+384
+00:29:44,290 --> 00:29:50,690
+بعيونكم، وسعوا ممكن أنتم تتخيلوها، حاولوا أن توفرّوا
+
+385
+00:29:50,690 --> 00:29:55,550
+gloves، وتحاولوا تتعلموا كيف تربطوا الـ tourniquet مثلًا
+
+386
+00:29:55,550 --> 00:30:00,090
+على إيد أختك، أو إيد أحد من أسرتك، كمان يعني أنه
+
+387
+00:30:00,090 --> 00:30:04,290
+لحتى إيدك تأخذ على الرابطة، تمام؟ لحتى إيدك تأخذ على
+
+388
+00:30:04,
\ No newline at end of file
diff --git a/PL9fwy3NUQKwY9jl8xw-bWkVZkWcGGyspd/yuOrEl54r0w_postprocess.srt b/PL9fwy3NUQKwY9jl8xw-bWkVZkWcGGyspd/yuOrEl54r0w_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..c1f674c56b208750aaf00c54c2d87da2a69b649b
--- /dev/null
+++ b/PL9fwy3NUQKwY9jl8xw-bWkVZkWcGGyspd/yuOrEl54r0w_postprocess.srt
@@ -0,0 +1,1592 @@
+1
+00:00:03,800 --> 00:00:07,540
+السلام عليكم ورحمة الله وبركاته طالبات العزيزات
+
+2
+00:00:07,540 --> 00:00:11,800
+اليوم ان شاء الله راح نستعرض مع بعض فيديو منزلي
+
+3
+00:00:11,800 --> 00:00:16,100
+صورته أنا بالمنزل و بعد توفير الأدوات اللازمة و
+
+4
+00:00:16,100 --> 00:00:21,160
+هذا الفيديو بيشرح كيفية سحب عين الدم من منطقة
+
+5
+00:00:21,160 --> 00:00:24,500
+الوريد تمام؟ راح نسحب عين الدم من منطقة ال
+
+6
+00:00:24,500 --> 00:00:30,140
+antecubital و راح نذكر أيضا بعض النقاط المهمة
+
+7
+00:00:30,140 --> 00:00:34,460
+المتعلقة بعملية السحبهذه النقاط المهمة احنا
+
+8
+00:00:34,460 --> 00:00:39,360
+ذكرناها في المحاضرة النظرية وحكينا انها هي تعليمات
+
+9
+00:00:39,360 --> 00:00:44,600
+مهمة لازم نتبعها أثناء عملية السحب و .. لكن طبعا
+
+10
+00:00:44,600 --> 00:00:48,280
+ما .. ما .. ال .. الاشي ما بيكون متخيل بدون ما
+
+11
+00:00:48,280 --> 00:00:52,220
+انطبق عملي و بدون ما نشوفه بعينينالهيك أنا اليوم
+
+12
+00:00:52,220 --> 00:00:57,420
+قررت أصورلكم هذا ال video لحتى أقرب الأشي لأذهانكم
+
+13
+00:00:57,420 --> 00:01:01,900
+تشوفوا الأشي بعينيكم لما نذكر المعلومة و نطبقها
+
+14
+00:01:01,900 --> 00:01:07,540
+تعرفوا إيش كان المقصود بهي التعليمات أثناء ذكرها
+
+15
+00:01:07,540 --> 00:01:12,980
+بالمحاضرة، النظريةبداية انا عندى لازم اوفر الأدوات
+
+16
+00:01:12,980 --> 00:01:19,520
+اللازمة فى عملية السحب محتاجة string تمام ومحتاجة
+
+17
+00:01:19,520 --> 00:01:23,180
+needles هى ال needles شايفينهم تمام محتاجة alcohol
+
+18
+00:01:23,180 --> 00:01:29,440
+ومحتاجة swab وهلأ بشوف طبعا احنا أخدنا انه ال ..
+
+19
+00:01:29,440 --> 00:01:36,800
+ال ..الـ syringe مكوّنة من قطعتين، تمام؟ قطعة اللي
+
+20
+00:01:36,800 --> 00:01:41,680
+هي زي الأنبوب المدرج هذا، هاي القطعة بسميها ال
+
+21
+00:01:41,680 --> 00:01:45,260
+parallel، تمام؟ بسميها ال parallel و هاي القطعة
+
+22
+00:01:45,260 --> 00:01:50,140
+المتحركة أنا بسميها Plunger، تمام؟ بسميها Plunger،
+
+23
+00:01:50,140 --> 00:01:55,060
+إذاً ال syringe مكوّنةمن قطعتين ال parallel و ال
+
+24
+00:01:55,060 --> 00:01:58,160
+.. ال .. ال plunger هاي هم زي ما أنتوا شايفين ال
+
+25
+00:01:58,160 --> 00:02:02,580
+.. ال parallel المدرج و ال plunger اللي هو القطعة
+
+26
+00:02:02,580 --> 00:02:07,140
+المتحركة طبعا زي ما أنتوا شايفين كمان ال .. ال
+
+27
+00:02:07,140 --> 00:02:11,940
+needle مكونة من ال .. ال cap تبعها، الغطا تبعها،
+
+28
+00:02:11,940 --> 00:02:17,020
+تمام؟و أيضًا طبعًا هذا الكلاب أنا خلاص بتخلص منه
+
+29
+00:02:17,020 --> 00:02:22,500
+هي ال .. ال needle مكوّنة من عدة أدوات طبعًا إحنا
+
+30
+00:02:22,500 --> 00:02:26,640
+حكينا معلومة إنه و كذرناها كتير أثناء المحاضرة
+
+31
+00:02:26,640 --> 00:02:32,950
+النظرية حكينا إنه never everRecap bent or break
+
+32
+00:02:32,950 --> 00:02:39,390
+needle يعني أنا ممنوع أرجع أغطي ال needle بعد ما
+
+33
+00:02:39,390 --> 00:02:45,350
+أفتحها ممنوع أحاول أتنيها أو أكسرها لحد اللي اتخلص
+
+34
+00:02:45,350 --> 00:02:49,670
+منها لإنها ممكن يعني أثناء عمليةإعادة ال covering
+
+35
+00:02:49,670 --> 00:02:53,670
+مثلا ممكن أنا و أنا بحاول أرجع ال needle ل ال
+
+36
+00:02:53,670 --> 00:02:57,690
+cover تبعها أنخذ نفسي و تكون ال needle ملوثة بدم
+
+37
+00:02:57,690 --> 00:03:02,270
+المريض ساعتها أنا بكون حقنت نفسي بدم المريض تمام؟
+
+38
+00:03:02,270 --> 00:03:05,230
+هتلاحظوا أنه أنا خلال ال video ممكن أغطيها بس أنا
+
+39
+00:03:05,230 --> 00:03:08,910
+حاضرة يعني في الاستخدام ولكن أنتم هنا لأنكم لسه
+
+40
+00:03:08,910 --> 00:03:12,900
+هتكون مبتدئين و بتتعلموا ممنوع ترجعوا تغطوهاعلى
+
+41
+00:03:12,900 --> 00:03:16,440
+طول تتخلصي من ال cab و النيل بعد ما نخلص .. ساحب
+
+42
+00:03:16,440 --> 00:03:19,860
+عينة الدم، بنتخلص منها بال safety box و ان شاء
+
+43
+00:03:19,860 --> 00:03:23,760
+الله راح نرجع للمعامل و ترجعوا تشوفوا التطبيق
+
+44
+00:03:23,760 --> 00:03:27,360
+العملي كيف و راح برضه كمان احاول ان انا اشوف ..
+
+45
+00:03:27,360 --> 00:03:31,520
+يعني اسحب امامكم عينة و اورجيكم كيف انا بعمل
+
+46
+00:03:31,520 --> 00:03:36,480
+discard لكل اشي بال .. بالproper container يعني
+
+47
+00:03:36,480 --> 00:03:42,760
+مثلاال .. ال .. ال gelatin و الغطا تبع ال .. ال
+
+48
+00:03:42,760 --> 00:03:47,480
+needle و ال syringes بتخلص منه بالسلة العادية ال
+
+49
+00:03:47,480 --> 00:03:50,960
+cab مثلا ممكن بالسلة العادية ال cotton swab بعد ما
+
+50
+00:03:50,960 --> 00:03:56,160
+يتلوث بال blood مثلا إذا تلوث بال blood بتخلص منه
+
+51
+00:03:56,160 --> 00:03:59,960
+في ال bio hazard container ال syringe لإنه بيكون
+
+52
+00:03:59,960 --> 00:04:03,760
+فيها بقايا بتخلص فيهامنها في ال biohazard
+
+53
+00:04:03,760 --> 00:04:07,520
+container أيضا ال .. ال .. ال needle ال needle
+
+54
+00:04:07,520 --> 00:04:11,260
+بتخلص منها بال sharp box اللي هو الصندوق اللي
+
+55
+00:04:11,260 --> 00:04:15,900
+بتخلص من الأدوات الحاد ده فيه من خلاله تمام؟ اذا
+
+56
+00:04:15,900 --> 00:04:21,920
+.. اذا ممنوع انا ارجع اغطي هاي ال needle تمام؟ زي
+
+57
+00:04:21,920 --> 00:04:26,670
+ما انتوا شايفين ال needle مكونة من عدةأقسام القسم
+
+58
+00:04:26,670 --> 00:04:31,750
+هذا البلاستيك الملون اللي بسميه hub تمام بسميه hub
+
+59
+00:04:31,750 --> 00:04:37,510
+هذا القسم كان موجود او مدكور بالمحاضرة انه بيكون
+
+60
+00:04:37,510 --> 00:04:40,050
+عليه ال gauge number بس هنا مش موجود ال gauge
+
+61
+00:04:40,050 --> 00:04:44,110
+number ال gauge number موجود على الغلاف تبع ال
+
+62
+00:04:44,110 --> 00:04:48,850
+needle و هورجيكم إياه كمان شوية الجزء التاني من ال
+
+63
+00:04:48,850 --> 00:04:52,770
+needle اللي هو الشافت هذا الجزء المعدني اللي
+
+64
+00:04:52,770 --> 00:04:56,950
+بنسميه الشافتالجزء التالت هو الفتحة هاي المايلة
+
+65
+00:04:56,950 --> 00:05:00,570
+اللي جاية بزاوية هاي الفتحة اللي جاية بزاوية
+
+66
+00:05:00,570 --> 00:05:04,430
+بسميها ال bevel ال needle .. bevel .. فتحة ال
+
+67
+00:05:04,430 --> 00:05:08,910
+needle بسميها bevel تمام؟ مذكورة هاي الأجزاء في
+
+68
+00:05:08,910 --> 00:05:13,090
+المحاضرة النظرية و هاي انتوا هلأ شفتوها بعينيكم
+
+69
+00:05:13,090 --> 00:05:18,910
+علشان انه تحاولوا تربطوا النظري مع العملي تمام؟
+
+70
+00:05:19,760 --> 00:05:24,380
+طيب، هلأ أنا بدي أبدأ عملية سحب الدم، إيش بدي
+
+71
+00:05:24,380 --> 00:05:28,940
+أسوي؟ أول إشي بدي أحضر أدواتي، يعني هاي عندى ال
+
+72
+00:05:28,940 --> 00:05:32,340
+needle و ال syringe بدي أحضرهم، بس قبل أن أحضرهم
+
+73
+00:05:32,340 --> 00:05:35,520
+بدي أورجيكم كيف بيكون مكتوب ال gauge number، هاي
+
+74
+00:05:35,520 --> 00:05:37,760
+ال gauge number، هاي ال needle، هاي الزرقه، مكتوب
+
+75
+00:05:37,760 --> 00:05:42,800
+عليها 23 gauge، يعني رقم ال gauge number 23هي ال
+
+76
+00:05:42,800 --> 00:05:46,600
+orange ال needle اللي لونها orange ايش ال gauge
+
+77
+00:05:46,600 --> 00:05:49,220
+number اللي مكتوب عليها؟ زي ما انتوا شايفين هي هنا
+
+78
+00:05:49,220 --> 00:05:52,660
+مكتوب خمسة و عشرين جي يعني ال gauge number هادا
+
+79
+00:05:52,660 --> 00:05:57,060
+أكبر، اذا هي في القطر أصغر، تمام؟ قطرها أصغر، اذا
+
+80
+00:05:57,060 --> 00:06:01,470
+أصغر ايش ياندي انا حاليا؟ ال needle ال orangeتمام؟
+
+81
+00:06:01,470 --> 00:06:04,870
+لإنها أكبر gauge number موجود، بعدين بيجي وراها ال
+
+82
+00:06:04,870 --> 00:06:08,570
+.. ال needle الزرقى، ال needle الرمادية ال gauge
+
+83
+00:06:08,570 --> 00:06:14,410
+number 22، هنا 23، لحظوا 25، 23، 22، يعني أصغر
+
+84
+00:06:14,410 --> 00:06:21,730
+فأكبر فأكبرالقطر تمام؟ وهي ال needle الأخضر واحد
+
+85
+00:06:21,730 --> 00:06:26,870
+وعشرين gauge يعني هم مرتبين من الأصغر قطرا والأكبر
+
+86
+00:06:26,870 --> 00:06:31,190
+gauge number لحد اللي هو الأكبر قطرا والأصغر gauge
+
+87
+00:06:31,190 --> 00:06:33,810
+number تمام؟ من الأصغر gauge number للأكبر gauge
+
+88
+00:06:33,810 --> 00:06:37,850
+numbersorry من الأكبر gauge number للأصغر gauge
+
+89
+00:06:37,850 --> 00:06:41,690
+number والقطر طبعا علاقة عكسية ما بين ال gauge
+
+90
+00:06:41,690 --> 00:06:45,990
+number و ما بين ال needle هلأ هي زي ما انتوا
+
+91
+00:06:45,990 --> 00:06:51,130
+شايفين ال syringe طبعا بتكون مغلفة هستخدم هذه ال
+
+92
+00:06:51,130 --> 00:06:57,270
+..الـ needle بحيث انه اورجيكم كيف نفتحها طبعا هي
+
+93
+00:06:57,270 --> 00:06:59,830
+زي ما انتوا شايفين مغلفة بنيلون و بالجزء التاني
+
+94
+00:06:59,830 --> 00:07:05,030
+ورقي انا بفتحها من جهة الورق بهذا الشكل تمام لإنه
+
+95
+00:07:05,030 --> 00:07:08,730
+لو بدي افتحها من ناحية النيلون بدي قوة و انا لأمزع
+
+96
+00:07:08,730 --> 00:07:12,750
+النيلون فأسرع اشي من جهة الورقية هاي ال needle هنا
+
+97
+00:07:12,750 --> 00:07:15,870
+مش مستخدمة بدي اورجيكم كيف بدي افتحها من الجهة
+
+98
+00:07:15,870 --> 00:07:20,630
+اللي بدي استخدمها من جهة الورقبفتحها هيك شوي و
+
+99
+00:07:20,630 --> 00:07:24,870
+بركبهم على بعض بعدين بتخلص من الغلاف الورقي اللى
+
+100
+00:07:24,870 --> 00:07:28,590
+موجود على كل من ال syringe و ال needle بهذا الشكل
+
+101
+00:07:28,590 --> 00:07:32,750
+بتأكد من انه ال bevel فتحت ال needle مقابلة
+
+102
+00:07:32,750 --> 00:07:37,190
+للتدريج طبعا عندى هى ال syringe تلاتة سانتي بتاخد
+
+103
+00:07:37,190 --> 00:07:39,730
+فى عندى ال syringes بتاخد هيها دى ال syringe بتاخد
+
+104
+00:07:39,730 --> 00:07:42,970
+خمسة سانتي فى ال syringes بتاخد عشرة سانتي فى
+
+105
+00:07:42,970 --> 00:07:46,550
+اتنين سانتي هيها بتاخد ثلاثة سانتي متر مكعب يعني
+
+106
+00:07:46,550 --> 00:07:53,100
+تلاتة أمقالطيب و زي ما حكينا بتأكد أنه فتحت ال
+
+107
+00:07:53,100 --> 00:07:57,640
+needle اللي هنا مقابلة لإيش .. للتدريج اللي على ال
+
+108
+00:07:57,640 --> 00:08:02,580
+syringe ب .. بعد هيك بثبت ال needle بخلق .. بتأكد
+
+109
+00:08:02,580 --> 00:08:07,780
+أن هي شابقة كويس بحاول أن أنا يعني أفك ال .. ال ..
+
+110
+00:08:07,780 --> 00:08:12,930
+cap أرخي شوية و ألينالبلانجر طبعا زي ما انتوا
+
+111
+00:08:12,930 --> 00:08:17,050
+شايفين هي هنا في ال syringe هذه بدي قوة لحتى افتح
+
+112
+00:08:17,050 --> 00:08:20,850
+البلانجر لإنه البلانجر بيكون terrace طبعا ب ..
+
+113
+00:08:20,850 --> 00:08:25,390
+بقوة ب .. بافتحه فالأفضل إن أنا ألينه يعني أحركه و
+
+114
+00:08:25,390 --> 00:08:28,890
+بعدين أرجع أفرغ الهواء منه مرة تانية عشان يصير لين
+
+115
+00:08:28,890 --> 00:08:33,910
+طبعا لحتى يصير لين و سهل إن أنا أرجعه لورا أثناء
+
+116
+00:08:33,910 --> 00:08:39,550
+السحب و أبدأ أاخد ال volume اللي بديهاطبعا إذا هاي
+
+117
+00:08:39,550 --> 00:08:42,790
+ال needle و ال syringe جاهزين ال needle ثابتة
+
+118
+00:08:42,790 --> 00:08:48,110
+مركبة كويس على ال syringe و ال .. زي ما أنتوا
+
+119
+00:08:48,110 --> 00:08:53,070
+شايفين مركبة كويس ال needle على ال syringe و
+
+120
+00:08:53,070 --> 00:08:57,510
+الفتحة مقابل التدريج رخيت شوية الغطاء و لينت
+
+121
+00:08:57,510 --> 00:09:02,650
+البلنجر و طبعا إيش بلزمني بعد هيك؟ بلزمني كحول 70%
+
+122
+00:09:02,650 --> 00:09:08,670
+الكحول و بلزمني swap طبعاو هاي إيدي المريض بخليها
+
+123
+00:09:08,670 --> 00:09:13,090
+أنه ممتدة أمامي على ال bench و علشان أبدأ أسحب
+
+124
+00:09:13,090 --> 00:09:16,450
+العينة طبعا أنا بدي أسحب من منطقة ال Anticubital
+
+125
+00:09:16,450 --> 00:09:20,430
+يعني هنا في عندى median و في عندى cephalic veins
+
+126
+00:09:20,430 --> 00:09:24,130
+طبعا هذه الأوردة اللى بتكون واضحة أكتر إشي
+
+127
+00:09:24,130 --> 00:09:29,190
+للاستخدام فأنا من خلالهم بسحب عينة الدم اللى بدي
+
+128
+00:09:29,190 --> 00:09:36,350
+أسحبها تمام؟ طيب بدى .. إذا هيني أنا حضرت أدواتيال
+
+129
+00:09:36,350 --> 00:09:43,350
+syringe و ال needle و جاهزين الكحول 70% ethanol أو
+
+130
+00:09:43,350 --> 00:09:48,630
+70% isopropanol حكينا تمام بعدين طبعا ال swab بدي
+
+131
+00:09:48,630 --> 00:09:52,350
+أنا محتاجة تنتين واحدة أبللها بالكحول و تكون
+
+132
+00:09:52,350 --> 00:09:58,450
+للتعقيم و واحدة تانية جافة dry swab لحتى أحطها على
+
+133
+00:09:58,450 --> 00:10:02,650
+مكان الجرح أو مكان ال needle يعني بعد ما أخلص صاحب
+
+134
+00:10:02,650 --> 00:10:07,730
+عينة الدم تمام؟طيب بعد ما أحضر أدواتي إيش بدي
+
+135
+00:10:07,730 --> 00:10:12,030
+أعمل؟ طبعا أنا بعد ما حددت الوريد تبعي أو يعني ..
+
+136
+00:10:12,030 --> 00:10:16,910
+يعني أحددت المنطقة اللي بدي أسحب منها فبروح إيش
+
+137
+00:10:16,910 --> 00:10:22,170
+بعمل؟ بربط الternicate طبعا هاي أدواتي، هاي لسواب
+
+138
+00:10:22,170 --> 00:10:27,350
+المبلل و هاي لسواب ل dry طبعا مبلل بالكحول ال dry
+
+139
+00:10:27,350 --> 00:10:32,830
+swab علشان أحطه مكان ال .. بعد السحب و بعد هيك بدي
+
+140
+00:10:32,830 --> 00:10:39,330
+أربط الternicate تبعتيطبعا الternicate وظيفتها انه
+
+141
+00:10:39,330 --> 00:10:44,670
+انا لما بدي اربط الternicate وظيفتها انه تعملي ضغط
+
+142
+00:10:44,670 --> 00:10:49,790
+على منطقة الأوردة بحيث انها تبرزها يعني تمام؟ اذا
+
+143
+00:10:49,790 --> 00:10:53,950
+بس هي apply pressure هاي وظيفتها تمام؟ حتى تبرزلي
+
+144
+00:10:53,950 --> 00:11:00,940
+الأوردة ويسهل ساحب عينة تمام؟ال .. الternicate
+
+145
+00:11:00,940 --> 00:11:05,040
+اللي انا ممكن استخدمها يعني الرابطة ممكن استخدم ال
+
+146
+00:11:05,040 --> 00:11:08,860
+gloves العادي او ممكن في رابطة خاصة بستخدمها بتكون
+
+147
+00:11:08,860 --> 00:11:12,420
+موجودة في المختبرات اذا ما توفرت الرابطة اللي
+
+148
+00:11:12,420 --> 00:11:15,500
+موجودة في المختبرات ممكن استخدم ال gloves و عادي
+
+149
+00:11:15,500 --> 00:11:18,740
+سهل جدا ان انا استخدم ال gloves طبعا كيف انا بدي
+
+150
+00:11:18,740 --> 00:11:21,420
+.. هى طبعا هى الرابطة اللى بتكون موجودة في
+
+151
+00:11:21,420 --> 00:11:24,640
+المختبرات بحطها هنا علشان تعملى pressure طبعا
+
+152
+00:11:24,640 --> 00:11:30,920
+ببعدها بتكونهذه الرابطة أنا ببعدها عن منطقة السحب
+
+153
+00:11:30,920 --> 00:11:34,600
+بتلاتة inches يعني أنا مثلا ب .. بحط أصابعي تلاتة
+
+154
+00:11:34,600 --> 00:11:39,480
+.. تلات أصابع و بعدين بحط الرابطة بعدهم، تمام؟ فوق
+
+155
+00:11:39,480 --> 00:11:44,380
+منطقة السحب ممكن كمان في خيار تاني لو أنا مش متوفر
+
+156
+00:11:44,380 --> 00:11:48,340
+عندي هذه الرابطة ممكن أستخدم ال gloves زي ما حكينا
+
+157
+00:11:48,750 --> 00:11:52,190
+هلأ بنشوف كيف أنا بدي أربط ال gloves بالأول و
+
+158
+00:11:52,190 --> 00:11:57,970
+بعدين بنشوف كيف بنستخدم ال tourniquet التانية،
+
+159
+00:11:57,970 --> 00:12:03,490
+تمام؟ إذا حكينا إنه ال .. ال tourniquet وظيفتها
+
+160
+00:12:03,490 --> 00:12:08,270
+إنها فقط to apply pressure علشان إيش تعمليه؟ to ..
+
+161
+00:12:08,270 --> 00:12:12,090
+علشان تبرز الأوري ده و يسهل استخدام .. يسهل استحب
+
+162
+00:12:12,090 --> 00:12:16,650
+عينة الدمهلأ ال turn .. ال turniquet اللي هي ال
+
+163
+00:12:16,650 --> 00:12:19,370
+gloves أنا بمسيكها بهذا الشكل يعني من .. هي خمس
+
+164
+00:12:19,370 --> 00:12:22,470
+أصابع أنا بستخدم الأصبع .. ب .. بمسك من الأصبع
+
+165
+00:12:22,470 --> 00:12:25,370
+الوسطى و من الطرف التانى بحيث أنه تعطينى أقصى طول
+
+166
+00:12:25,370 --> 00:12:29,270
+طبعا بحيث أنه تعطينى أقصى طول و إيش بعمل؟ بربط
+
+167
+00:12:29,270 --> 00:12:32,930
+بهذا الشكل طبعا أنا هنا ماقصت تلاتة inches بس أنا
+
+168
+00:12:32,930 --> 00:12:37,110
+بدي أربط أورجيكم كيف أنا بربط بعدين ب .. بحطها على
+
+169
+00:12:37,110 --> 00:12:41,420
+المسافة اللازمة طبعاهلأ زي ما انتوا شايفين انا
+
+170
+00:12:41,420 --> 00:12:47,200
+باخدها بهذا الشكل و بعمل نص تانية تمام؟ بتنيها هيك
+
+171
+00:12:47,200 --> 00:12:53,200
+بهذا الشكل نص تانية و هيك بتكون tapped هيلاحظ ان
+
+172
+00:12:53,200 --> 00:12:58,410
+الأولي ده براليش أنا بعمل بهذا الشكل، بربط بهذا
+
+173
+00:12:58,410 --> 00:13:02,130
+الشكل؟ احنا حكينا نص فيونكا أو نص تانية ب .. بقتني
+
+174
+00:13:02,130 --> 00:13:09,090
+ال .. جانب من .. جوانب ال .. ال gloves بحيث انه لو
+
+175
+00:13:09,090 --> 00:13:12,810
+أنا خلصت سحب و بدي اجي طبعا احنا حكينا اول ما خلص
+
+176
+00:13:12,810 --> 00:13:15,910
+سحب اول اشي بعمل و برفع ال tourniquet بعدين بطلع
+
+177
+00:13:15,910 --> 00:13:21,610
+بال needle من برا لخارج ال van تمام؟ هلأ لو انا
+
+178
+00:13:23,120 --> 00:13:27,500
+ربطت هاي الربطة رح يسهل علي فكها شايفين بسهولة
+
+179
+00:13:27,500 --> 00:13:32,220
+بتفك معايا، تمام؟ لكن في حال لو أنا ربطت عقدة،
+
+180
+00:13:32,220 --> 00:13:35,540
+شوفوا كيف لو ربطت عقدة إيش بده يصير، هاي هنا أنا
+
+181
+00:13:35,540 --> 00:13:39,160
+ربطت عقدة، تمام؟ و جيت سحابة العينة و بدي أفكها
+
+182
+00:13:39,160 --> 00:13:44,660
+بصعوبة بتفك، تمام؟ بصعوبة بتفك، لكن الأفضل إنه أنا
+
+183
+00:13:44,660 --> 00:13:53,520
+أربط تمام ال .. ال .. الربطةبحيث انها تكون عندىزي
+
+184
+00:13:53,520 --> 00:13:56,580
+ما انتوا شايفين هاي جزء بكون طويل و جزء قصير بعدين
+
+185
+00:13:56,580 --> 00:14:02,060
+باخد هاي الجزء الطويل ويبتني لتحت شوي بحيث انه
+
+186
+00:14:02,060 --> 00:14:05,200
+يكون في عندي نص تانية او نص فينكة زي ما انتوا
+
+187
+00:14:05,200 --> 00:14:09,220
+شايفين هيك و هيك هي برزة الأور ده و جاهزة طبعا هنا
+
+188
+00:14:09,220 --> 00:14:13,900
+يعني ممكن يكون مش واضح قالية الربط فانا صورت فيديو
+
+189
+00:14:13,900 --> 00:14:20,280
+اخر تمام صورت فيديو بحيث انه يبينلي ال .. كيف انا
+
+190
+00:14:20,280 --> 00:14:22,820
+بربط هلأ بورجيكميا بعرضلكميا
+
+191
+00:14:25,050 --> 00:14:30,750
+تمام زى ما انتوا شايفين هى هنا هى ال gloves من
+
+192
+00:14:30,750 --> 00:14:34,250
+الإصبع الوسط بأمسكها و من الطرف التانى بحيث انها
+
+193
+00:14:34,250 --> 00:14:39,130
+بتعطينى أقصى طول و بلف بهذا الشكل على إيد المريض
+
+194
+00:14:39,130 --> 00:14:43,430
+طبعا بامسك
+
+195
+00:14:43,430 --> 00:14:51,930
+طرفينها تمامطرف طويل و طرف قصير باخد الطرف طبعا
+
+196
+00:14:51,930 --> 00:14:57,030
+يعني أنا بس عكستها على أساس يعني على هو مستوى إيدي
+
+197
+00:14:57,030 --> 00:15:03,350
+أنه انا أكون سهل علي أربطها الطرف الطويل بتنيه نص
+
+198
+00:15:03,350 --> 00:15:07,480
+تانية زي ما أنتوا شايفين هيك سحبته من هنابحيث انه
+
+199
+00:15:07,480 --> 00:15:11,140
+كان صار في عندي زي نص فينكا او نص رابطة بهذا الشكل
+
+200
+00:15:11,140 --> 00:15:17,160
+و صار في عندي اياش برزات الأوردة صار في بروز ل ال
+
+201
+00:15:17,160 --> 00:15:20,840
+.. الوريد زي ما انتوا شايفين بقى حاسس الوريد بيكون
+
+202
+00:15:20,840 --> 00:15:26,000
+شكله ملمس و مطاطي تحت ايدي تمام و هيك بفكها بكل
+
+203
+00:15:26,000 --> 00:15:30,680
+سهولة مرة تانية بربط في عندي جهة طويلة وجهة قصيرة
+
+204
+00:15:30,680 --> 00:15:33,400
+الجهة الطويلة هي اللي بتنيها تمام زي ما انتوا
+
+205
+00:15:33,400 --> 00:15:39,760
+شايفين هي بتنيها بهذا الشكلو بخليها انها مص تانية
+
+206
+00:15:39,760 --> 00:15:42,840
+او مص فيونكا يعني حسب انتوا اش فاهمين او انتوا كيف
+
+207
+00:15:42,840 --> 00:15:49,960
+ملاحظينها و بعد هيك بفكها بيبرز الوريد وسهل ان انا
+
+208
+00:15:49,960 --> 00:15:55,640
+افكها او اتخلص منها فالنهاية عملية السحب تمام؟ اذا
+
+209
+00:15:55,640 --> 00:16:05,920
+هذا هو ال .. كيف يمكن ربط ال .. الفيونكا تمام؟
+
+210
+00:16:08,660 --> 00:16:15,500
+بس نرجع تانى لحد ما كنا تمام
+
+211
+00:16:15,500 --> 00:16:27,520
+تمام
+
+212
+00:16:27,520 --> 00:16:32,580
+هيك ربطت تمام
+
+213
+00:16:32,580 --> 00:16:36,620
+بس هذه إعادة لعملية الربط
+
+214
+00:16:46,150 --> 00:16:50,690
+زي ما أنتوا شايفين نص .. ربطة نص فيونكا حسب أنتوا
+
+215
+00:16:50,690 --> 00:16:57,490
+إيش تسموها و ال .. قبل ال .. الأوردة بتبرز لإن دور
+
+216
+00:16:57,490 --> 00:17:03,030
+الternicate أو الربطة إنها تعملي ضغط فقط ضغططبعا،
+
+217
+00:17:03,030 --> 00:17:07,090
+النوع الآخر من الternicates زي ما أنتوا شايفين أنا
+
+218
+00:17:07,090 --> 00:17:10,890
+فيه عندي ternicate بتكون عبارة عن حزام، طبعا، فهذا
+
+219
+00:17:10,890 --> 00:17:15,590
+الحزام بس ما علي إنه غير أركبه يعني و أشده لحتى
+
+220
+00:17:15,590 --> 00:17:20,310
+يعطيني ضغط، اذا أنا بس علي أكبس الكبسة تبعته و
+
+221
+00:17:20,310 --> 00:17:26,600
+أشده لحتى يعملي ضغط، طبعابهذا الشكل طبعا فقط لا
+
+222
+00:17:26,600 --> 00:17:31,440
+غير بهذا الشكل انا بعمله اذا يا اما الرابطة هاي او
+
+223
+00:17:31,440 --> 00:17:36,060
+ال gloves سيان المهم اذا ما اتوفر عندي هاي الرابطة
+
+224
+00:17:36,060 --> 00:17:40,220
+انا بستخدم ال gloves طبعا احنا حكينا انه لازم تكون
+
+225
+00:17:40,220 --> 00:17:43,360
+الرابطة على بعد تلاتة inches يعني انا بجيس تلات
+
+226
+00:17:43,360 --> 00:17:46,400
+أصابع فوق منطقة الوريد اللي انا بده أسحب منها و
+
+227
+00:17:46,400 --> 00:17:49,100
+بعدين باربط الرابطة طبعا
+
+228
+00:17:52,190 --> 00:18:01,310
+طبعا بركبها على بعض تلاتة inches و بسكر بضغطها
+
+229
+00:18:01,310 --> 00:18:11,170
+بشدها و بصير عندى الوريد بارز و جاهز لعملية السحب
+
+230
+00:18:11,320 --> 00:18:15,980
+طبعا طيب إذا أنا ربطت ال .. ال tourniquet و لمست
+
+231
+00:18:15,980 --> 00:18:19,640
+الوريد حددته طبعا بسأل المريض بخلي المريض أنه يعمل
+
+232
+00:18:19,640 --> 00:18:23,620
+قبضة بإيده ما يظل يفتح و يسكر لأ بس قبضه و يغلقها
+
+233
+00:18:23,620 --> 00:18:27,580
+و حددت الوريد اللي أنا بدي أسحبه بعد ما لمسته و
+
+234
+00:18:27,580 --> 00:18:31,900
+اتحسسته طبعا و حكينا أنه مالمسه مطاطي بحس أنه في
+
+235
+00:18:31,900 --> 00:18:36,650
+إشي مطاطي تحت إيديمع الممارسة راح تعرفوا تمام؟ كيف
+
+236
+00:18:36,650 --> 00:18:40,690
+عملية التعقيم بال .. بالسواب اللي مبللة بالكحول
+
+237
+00:18:40,690 --> 00:18:45,710
+بعمل بشكل دائري ببدأ من دائر .. بدا .. من يعني ضيق
+
+238
+00:18:45,710 --> 00:18:50,270
+و ببدأ أوسع في الدائرة زي ما أنتوا شايفين ليش طيب
+
+239
+00:18:50,270 --> 00:18:52,990
+أنا بعمل هيك علشان أنا باخد ال contamination من
+
+240
+00:18:52,990 --> 00:18:56,710
+منطقة يعني أي contamination موجودة في منطقة الساحب
+
+241
+00:18:56,710 --> 00:19:01,090
+باخدها و ببعدها على ال .. الأطرافتمام؟ لو أنا بدي
+
+242
+00:19:01,090 --> 00:19:04,550
+أعمل العكس، تمام؟ لو بدي أعمل العكس، يعني بدي ألم
+
+243
+00:19:04,550 --> 00:19:07,890
+و أجي أ .. أركز و كله في المنتصف، يعني أنا هيك
+
+244
+00:19:07,890 --> 00:19:10,950
+لميت ال contamination كلها و حطيتها في منطقة
+
+245
+00:19:10,950 --> 00:19:16,360
+المنتصف، و هذا إشي غلط، إذا ال .. ال ..يعني ببدأ
+
+246
+00:19:16,360 --> 00:19:20,380
+ضايق و ببدأ أوسع الدائرة هذا هو الطريقة الصحيحة
+
+247
+00:19:20,380 --> 00:19:23,960
+لإتعاقيم أو ممكن مسحة زي ما انتوا شايفين هيك مسحة
+
+248
+00:19:23,960 --> 00:19:27,780
+واحدة فقط و لو كان في عندي excess alcohol بنشفه
+
+249
+00:19:27,780 --> 00:19:33,920
+بسوابجاف لإنه ال alcohol حكينا إنه ممكن يعملي
+
+250
+00:19:33,920 --> 00:19:38,900
+مشاكل hemoconcentration أو hemolysis أو يعني يأثر
+
+251
+00:19:38,900 --> 00:19:44,340
+فبالتالي حكينا إنه بأتخلص منه، هذا هو الوريد اللي
+
+252
+00:19:44,340 --> 00:19:48,300
+أنا بدي أسحب منه، حكينا إنه ما .. يعني ما بص ..
+
+253
+00:19:48,300 --> 00:19:53,060
+بيصير ألمس الوريد بعد التعقيمطبعا أنا بس هنا جاية
+
+254
+00:19:53,060 --> 00:19:55,680
+بحدد .. بس أحكيلكم أن هذا هو الوريد اللي بدي أسحب
+
+255
+00:19:55,680 --> 00:20:00,160
+منه و هرجع أعقب مرة تانية أنا لازم أكون لمسته و
+
+256
+00:20:00,160 --> 00:20:05,820
+حددته قبل عملية التعقيم طبعا إذا بعقم مرة تانية و
+
+257
+00:20:05,820 --> 00:20:11,800
+بجفف ال excess alcohol اللي موجود و بعد هيك باجي
+
+258
+00:20:11,800 --> 00:20:16,740
+بال syringe و ال needle بفتحها ب .. بمسك لل
+
+259
+00:20:16,740 --> 00:20:23,790
+syringe و ال needle مسكة خاصة بحيث أنهال .. زي ما
+
+260
+00:20:23,790 --> 00:20:28,270
+انتوا شايفين ال .. التلات أصابع تبعوني تحت ال ..
+
+261
+00:20:28,270 --> 00:20:31,650
+ال .. التلات أصابع هدول تحت ال syringe تمام؟
+
+262
+00:20:31,650 --> 00:20:34,790
+الإبهام فوق ال syringe و السبابة عند منطقة ال hub
+
+263
+00:20:34,790 --> 00:20:39,050
+زي ما انتوا شايفين فتحت ال needle مقابلة للتدريج و
+
+264
+00:20:39,050 --> 00:20:42,830
+ممكن أنا أشد ال skin بالإبهام أو ممكن أتركها أنا
+
+265
+00:20:42,830 --> 00:20:45,630
+في هذه الحالة الوريد واضح و مش محتاجة أشد ال ..
+
+266
+00:20:45,630 --> 00:20:49,870
+أشد ال skin بال .. بإصبعي التاني الإبهامفإذا بمسك
+
+267
+00:20:49,870 --> 00:20:53,810
+و زي ما انتوا شايفين هذا هو اتجاه الوريد انا بفوت
+
+268
+00:20:53,810 --> 00:20:58,670
+في نفس اتجاه الوريد تمام؟ مابنفع انا اجي هيك بهذا
+
+269
+00:20:58,670 --> 00:21:04,050
+الشكل افوت لأ بفوت في نفس اتجاه الوريد حكينا لإنه
+
+270
+00:21:04,050 --> 00:21:07,430
+لو انا بدي افوت مثلا في اتجاه معاكس ممكن انا اخترق
+
+271
+00:21:07,430 --> 00:21:11,330
+الوريد من الجهة التانية و يبدأ يتراكم الدم تحت ال
+
+272
+00:21:11,330 --> 00:21:14,850
+skin و يعمللي hematoma و ممكن يتوقف عند السحب في
+
+273
+00:21:14,850 --> 00:21:20,660
+داخل ال syringeفإذا أنا باجي في نفس اتجاه الوريد و
+
+274
+00:21:20,660 --> 00:21:25,840
+بفوت طبعا بفوت في زاوية معينة اللي طبعا إذا كانت
+
+275
+00:21:25,840 --> 00:21:28,840
+الوريد superficial سطحي زي ما أنتوا شايفين هنا
+
+276
+00:21:28,840 --> 00:21:33,600
+واضح ب .. بتكون الزاوية قليلة إذا كان ال .. الوريد
+
+277
+00:21:33,600 --> 00:21:39,230
+أنا حاساه بس مش شايفاه يعني هو ديب تمام؟بكبر
+
+278
+00:21:39,230 --> 00:21:42,510
+الزاوية و هذه أشياء ان شاء الله رح تتعلموها مع
+
+279
+00:21:42,510 --> 00:21:46,890
+الممارسة بذكرها الآن ولكن رح تتعلموها مع الممارسة
+
+280
+00:21:46,890 --> 00:21:51,890
+و زي ما انتوا شايفين بفوت في .. طبعا بكون طبعا زي
+
+281
+00:21:51,890 --> 00:21:56,680
+ما انتوا شايفين هنا إيديعلى ال skin تبعت المريض
+
+282
+00:21:56,680 --> 00:22:00,640
+بثبت إيدي على ال skin إيدي هاي التلت أصابع اللي هم
+
+283
+00:22:00,640 --> 00:22:04,800
+تحت ال syringe بثبتهم على إيدي المريض عشان لما أجي
+
+284
+00:22:04,800 --> 00:22:11,060
+أسحب البلنجر تبع ال syringe تكون إيدي ثابتة مارجعش
+
+285
+00:22:12,160 --> 00:22:16,360
+لاتلقائي و يعني لاشعوريا بحس حالي برجع و بطلع من
+
+286
+00:22:16,360 --> 00:22:20,380
+الواريد بدون ما اسحب الكمية اللازمة لأ فإذا بثبت
+
+287
+00:22:20,380 --> 00:22:24,140
+زي ما أنتوا شايفين بثبت إيدي على .. على إيد المريض
+
+288
+00:22:24,140 --> 00:22:30,460
+و بفوت في نفس اتجاهالوريد تمام بزاوية قليلة لإن هو
+
+289
+00:22:30,460 --> 00:22:35,780
+superficial و بعد هيك أول ما بفوت في الوريد الصح
+
+290
+00:22:35,780 --> 00:22:39,700
+بتعلم عندي زي ما انتوا شايفين هنا بتعلم عندي نقطة
+
+291
+00:22:39,700 --> 00:22:43,380
+blood في منطقة ال hub يعني معناها إنه خلاص المسار
+
+292
+00:22:43,380 --> 00:22:50,750
+الدم فاتح ببدأ إيش أعمل؟برجع البلانجر لورا طبعا
+
+293
+00:22:50,750 --> 00:22:54,170
+اذا هيتكونت عندى نقطة دم برجع البلانجر لورا زى ما
+
+294
+00:22:54,170 --> 00:23:00,890
+انتوا شايفين ويبدأ يعبي blood داخل ال syringe طبعا
+
+295
+00:23:00,890 --> 00:23:04,990
+هيتعبى انا هنا باخد ال volume اللى بديه طبعا حسب
+
+296
+00:23:04,990 --> 00:23:08,830
+ال volume اللى بديه انا محتاجة اليوم اخد بس 1 cm
+
+297
+00:23:08,830 --> 00:23:12,850
+لإن هذا فيديو تعليمى بس بوضحلكم قالية السحب فقط لا
+
+298
+00:23:12,850 --> 00:23:19,060
+غيرولكن إذا كان يعني أنا محتاجة volume أكتر باخد
+
+299
+00:23:19,060 --> 00:23:23,280
+volume أكتر بعدين طبعا زي ما أنتوا شايفين بعد ما
+
+300
+00:23:23,280 --> 00:23:26,680
+أخد ال volume اللي بديا أول خطوة و أنا لساتني جوا
+
+301
+00:23:26,680 --> 00:23:33,290
+إيش بعمل؟ بفك الternicate طبعاو بعدين هيخلصت فكات
+
+302
+00:23:33,290 --> 00:23:38,310
+ال turnicate بحط ال dry swab على منطقة السحب بطلع
+
+303
+00:23:38,310 --> 00:23:41,770
+بدون ما اضغط بعدين بخليه يضغط بحكي للمريض اضغط ف
+
+304
+00:23:41,770 --> 00:23:45,910
+.. و بخليه بتأكد ان هو عندى يضغط هكذا انا أخدت ال
+
+305
+00:23:45,910 --> 00:23:52,340
+volume اللى انا بدياه تمام؟و بعد هيك بفضيه في ال
+
+306
+00:23:52,340 --> 00:23:56,440
+tube سواء كان ال tube هذه فيها edita او heparin او
+
+307
+00:23:56,440 --> 00:24:00,840
+sodium citrate او كانت فاضية مش فيها اشي اي نوع ال
+
+308
+00:24:00,840 --> 00:24:04,560
+tube طبعا حسب نوع الفحص اللي انا بدي اعمله بكون
+
+309
+00:24:04,560 --> 00:24:07,720
+عارفة الفحص اللي بدي اعمله و عارفة ال tube اللي
+
+310
+00:24:07,720 --> 00:24:12,040
+بدي استخدمها و ايش فيها additive ايش نوع ال
+
+311
+00:24:12,040 --> 00:24:15,910
+anticoagulant اللي فيهاتمام؟ وإذا كان أصلا فيها
+
+312
+00:24:15,910 --> 00:24:19,950
+anticoagulant أو لا ممكن أكون محتاجة أنه أنا بدي
+
+313
+00:24:19,950 --> 00:24:24,970
+serum فأحطها في tube إما إبلان فاضية مش فيها إشي
+
+314
+00:24:24,970 --> 00:24:30,570
+أو tube مثلا فيها clot activator أو clot activator
+
+315
+00:24:30,570 --> 00:24:33,490
+مع جل أو أي إشي من الجدول اللي إحنا ذكرناها في
+
+316
+00:24:33,490 --> 00:24:39,850
+محاضرة ال blood component تمام؟ طيبالمحتويات ال
+
+317
+00:24:39,850 --> 00:24:43,690
+syringe اللى عينة الدم انا بفضيها immediately حالا
+
+318
+00:24:43,690 --> 00:24:45,890
+يعنى مابستنى عليها مابحطها على ال bench و اروح
+
+319
+00:24:45,890 --> 00:24:51,390
+مثلا اعمل شغل بعدين ارجع افرغها داخل ال tube لإنه
+
+320
+00:24:51,390 --> 00:24:54,600
+هنا ال blood راح يتجلط تمام؟راح يصير في
+
+321
+00:24:54,600 --> 00:24:59,380
+coagulation فبالتالي لازم انا افرغها مباشرة او
+
+322
+00:24:59,380 --> 00:25:03,300
+immediately في الحال في داخل ال tube طبعا انا
+
+323
+00:25:03,300 --> 00:25:10,920
+اليوم انا جايبالكم مثال ال tube يعني هو مافيش فيه
+
+324
+00:25:10,920 --> 00:25:15,620
+اشي بس فيه clot activator طبعا؟ لذا انا بفضل محتوى
+
+325
+00:25:15,620 --> 00:25:20,660
+ال blood في ال tube الخاصة و طبعا immediately فورا
+
+326
+00:25:20,660 --> 00:25:24,910
+هيهانا في عندنا مثلا ال tubeزي ما انتوا شايفين
+
+327
+00:25:24,910 --> 00:25:31,110
+نعمل هايو Red color نعمل focus بس على منطقة ال
+
+328
+00:25:31,110 --> 00:25:36,030
+labeling زي ما انتوا شايفين هنا مكتوب ان في Clot
+
+329
+00:25:36,030 --> 00:25:39,310
+activator هاي الزهادي اللي انا حكيتلكم ال additive
+
+330
+00:25:39,310 --> 00:25:41,730
+انتوا ما بتشوفوها يعني ال anticoagulant داخل ال
+
+331
+00:25:41,730 --> 00:25:44,950
+tube ممكن يكون عبارة عن قطارات ممكن يكون عبارة عن
+
+332
+00:25:44,950 --> 00:25:47,430
+powder موجودة على الجدار يعني انتوا ما بتشوفوه زي
+
+333
+00:25:47,430 --> 00:25:52,730
+ما شايفين هاي ال .. ال ..الأشياء اللي موجودة داخل
+
+334
+00:25:52,730 --> 00:25:57,330
+ال tube اللي عاملة زي تمشيحة هذه اللي احنا بنحكي
+
+335
+00:25:57,330 --> 00:26:01,350
+عنها clot activator تمام انا بحط ال blood فيه فهذا
+
+336
+00:26:01,350 --> 00:26:05,950
+بيشجع انه يصير في عندي عملية coagulation تجلط للدم
+
+337
+00:26:05,950 --> 00:26:11,920
+فإذا لما انا بدي افصل العينة هذه اللي بيفصل فوقال
+
+338
+00:26:11,920 --> 00:26:16,280
+blood فوق ال clot لو انا بدي ااخد طبعا السائل اللى
+
+339
+00:26:16,280 --> 00:26:19,540
+بيكون موجود فوق ال blood هذا السائل بيكون عبارة عن
+
+340
+00:26:19,540 --> 00:26:22,200
+serum طبعا بيكون عبارة عن serum يعني مافيش فيه
+
+341
+00:26:22,200 --> 00:26:26,700
+fibrin طبعا هذه بنات عبارة عن vacotainery tube
+
+342
+00:26:26,700 --> 00:26:32,560
+يعني انا بحطها في جهة .. في الادات ال vacotainer و
+
+343
+00:26:32,560 --> 00:26:35,560
+ببدأ أسحب على طول مباشرة بيعبئ دم منها من خلال
+
+344
+00:26:35,560 --> 00:26:39,840
+الوريدمش بتوفر عندى vacutainer ف .. ولكن هورجيكميا
+
+345
+00:26:39,840 --> 00:26:43,900
+ان شاء الله خلال عودتنا ل .. المعابل ان شاء الله
+
+346
+00:26:43,900 --> 00:26:48,500
+إذا رجعنا بالسلامة و راح تشوفوا راح أسحبلكم
+
+347
+00:26:48,500 --> 00:26:51,180
+باستخدام vacutainer لحتى تشوفوا كيف انه أنا
+
+348
+00:26:51,180 --> 00:26:57,200
+باستخدام هاي القنابيب على طول بتعبي فيها الدم
+
+349
+00:26:59,190 --> 00:27:01,750
+زي ما انتوا شايفين هنا ال .. ال cover عبارة عن
+
+350
+00:27:01,750 --> 00:27:07,890
+مطاط و .. يعني سهل انه يخت .. تخترقوا ال needle و
+
+351
+00:27:07,890 --> 00:27:12,310
+يتم تعبئة ال blood داخل ال tube طبعا؟ اللي انا لو
+
+352
+00:27:12,310 --> 00:27:17,170
+بدي افرغ ال blood داخل ال tube هاي في عندي طريقتين
+
+353
+00:27:17,170 --> 00:27:21,770
+اما انه انا افتح ال tube يعني اشيل الغطا و افض على
+
+354
+00:27:21,770 --> 00:27:26,870
+الجدار طبعا؟و أتخلص من ال needle بعدين أفضّي
+
+355
+00:27:26,870 --> 00:27:30,270
+محتويات ال syringe على الجدار بحيث انه ما يتكسر
+
+356
+00:27:30,270 --> 00:27:33,750
+الدم بعدين أرجع أغطي ال tube أعمل mix و أعمل
+
+357
+00:27:33,750 --> 00:27:37,790
+labeling أكتب ال label معلومات المريض في المكان
+
+358
+00:27:37,790 --> 00:27:44,610
+المخصص هنا أو الممكن بطريقة تانية انهإنه باستخدام
+
+359
+00:27:44,610 --> 00:27:48,450
+ال needle أخترق المرتقة المطاطية و يهادي الأنبوب
+
+360
+00:27:48,450 --> 00:27:52,070
+مفرغة من الهواء فعلي جد ما هي مفرغة من الهواء راح
+
+361
+00:27:52,070 --> 00:27:56,030
+تسحب volume راح تسحب سائل فمجرد ما أنا أخترق ال
+
+362
+00:27:56,030 --> 00:28:01,770
+needle أخترق الغطا بال needle راح على طول يعبي ال
+
+363
+00:28:01,770 --> 00:28:05,810
+blood داخل ال tube تمام؟ إذا هذه ال tube مبسطة
+
+364
+00:28:05,810 --> 00:28:09,530
+عليا إن أنا ممكن أعبيها إما على الجدار أو باستخدام
+
+365
+00:28:09,530 --> 00:28:15,940
+ال ..ال .. يعني أنه أنا أخترق ال .. الغطاء المطاطي
+
+366
+00:28:15,940 --> 00:28:18,280
+اللي موجود فيها وهي الغطاء المطاطي اللي هذا اللي
+
+367
+00:28:18,280 --> 00:28:22,260
+لونه رمادي سهل اختراقه بال needle تمام؟ زي ال ..
+
+368
+00:28:22,260 --> 00:28:29,470
+يعني اشي جلديس .. مطاطي تمام؟هذا بالنسبة لل
+
+369
+00:28:29,470 --> 00:28:34,010
+YouTube ضروري جدا بعد ما أنا أعبي العينة أفضيها
+
+370
+00:28:34,010 --> 00:28:41,050
+أعمل mix و أعمل labeling أحط معلومات المريض اسمه
+
+371
+00:28:41,050 --> 00:28:46,790
+ال initial و ال surname و ال middle initial و أحط
+
+372
+00:28:46,790 --> 00:28:50,430
+تاريخ و وقت السحب و ال initial of ال optimist على
+
+373
+00:28:50,430 --> 00:28:57,060
+العينة تمام؟و هيك بتكون عندى صارت العينة جاهزة
+
+374
+00:28:57,060 --> 00:28:59,800
+للفخصات ممكن انا احطها جهة .. داخل جهاز ال
+
+375
+00:28:59,800 --> 00:29:07,840
+centrifuge و افصل تعطينى طبعا serum طبعا تعطينى
+
+376
+00:29:07,840 --> 00:29:12,280
+serum طبعا هيك احنا بنكون اتعلمنا كيف انا اسحب
+
+377
+00:29:12,280 --> 00:29:17,900
+عينة من الوريد تمام ان شاء الله فور توفر ال ..
+
+378
+00:29:17,900 --> 00:29:23,240
+الأدواتالخاصة بسحب عينة من ال skin سواء skin
+
+379
+00:29:23,240 --> 00:29:27,140
+puncture يعني سواء من الإصبع أو من ال heel راح ان
+
+380
+00:29:27,140 --> 00:29:31,200
+شاء الله راح أشرحلكم إياها في فيديو تعليم آخر و ان
+
+381
+00:29:31,200 --> 00:29:34,440
+شاء الله تكونوا هيك استفدتوا و الأشياء يعني أو
+
+382
+00:29:34,440 --> 00:29:37,110
+المعلومات اللي احنا ذكرناها كيف أنا أفوت فيهافي
+
+383
+00:29:37,110 --> 00:29:40,870
+اتجاه الوريد، كيف اعقم، كيف اربط الternicate، هذه
+
+384
+00:29:40,870 --> 00:29:44,290
+كلها الشغلات ان شاء الله تكون واضحة وشوفتوها
+
+385
+00:29:44,290 --> 00:29:50,690
+بعينيكم و سهر ممكن انتوا تتخيلوها حاولوا انه توفري
+
+386
+00:29:50,690 --> 00:29:55,550
+gloves و تحاولوا تتعلمي كيف تربطي الternicate مثلا
+
+387
+00:29:55,550 --> 00:30:00,090
+على ايد أختك او ايد احد من أسرتك كمان يعني انه
+
+388
+00:30:00,090 --> 00:30:04,290
+لحتى ايدك تاخد على الرابطةتمام لحتى إيدك تاخد على
+
+389
+00:30:04,290 --> 00:30:07,650
+الربطة كرريها مرتين تلاتة شوفي حالك كده ممكن أنت
+
+390
+00:30:07,650 --> 00:30:11,530
+تعقمي بشكل دائي بس ماتجربي عملية السحب إلا لما
+
+391
+00:30:11,530 --> 00:30:15,530
+اتجربيها عندى بالمختبر بعدين بخليكي انه .. انه
+
+392
+00:30:15,530 --> 00:30:21,740
+مثلا اتجربيها على متطوعين او يعني whateverتمام؟
+
+393
+00:30:21,740 --> 00:30:26,960
+إذا هك بنكون خلصنا جزئية ال pheloptomy اللي هو سحب
+
+394
+00:30:26,960 --> 00:30:34,160
+عين الدم من الوريد تمام؟ هذا ال .. الجزء .. أو هذا
+
+395
+00:30:34,160 --> 00:30:36,500
+ال .. الفيديو التعليمي اللي أنا سجلتلكم إياه ان
+
+396
+00:30:36,500 --> 00:30:42,000
+شاء الله يكون .. تكونوا استفدته من خلاله و يعطيكم
+
+397
+00:30:42,000 --> 00:30:46,800
+العافية ان شاء الله بنسجللكم فيديوهات أخرى بتوضح
+
+398
+00:30:46,800 --> 00:30:48,700
+عملية ال skin puncture
+
diff --git a/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/-MSZz9sVQUk.srt b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/-MSZz9sVQUk.srt
new file mode 100644
index 0000000000000000000000000000000000000000..3b53dc55c0876815a07e3f37209fc7c9572eb4e1
--- /dev/null
+++ b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/-MSZz9sVQUk.srt
@@ -0,0 +1,1510 @@
+1
+00:00:21,850 --> 00:00:25,530
+بسم الله الرحمن الرحيم اليوم إن شاء الله يا شباب
+
+2
+00:00:25,530 --> 00:00:31,710
+نتحدث عن titration of a polybasic base، تكلمنا في
+
+3
+00:00:31,710 --> 00:00:34,870
+الحصة الماضية عن titration of polyprotic acids
+
+4
+00:00:34,870 --> 00:00:39,410
+وشفنا مثالًا على الـ polyprotic acids، أخذنا الـ
+
+5
+00:00:39,410 --> 00:00:43,810
+carbonic acid، اليوم إن شاء الله كمثال على الـ poly
+
+6
+00:00:43,810 --> 00:00:50,250
+basic bases،  بناخذ أو بنتكلم عن الـ sodium phosphate
+
+7
+00:00:50,250 --> 00:00:55,010
+فالـ sodium phosphate طبعًا هي الـ salt للـ
+
+8
+00:00:55,010 --> 00:00:58,830
+phosphoric acid، أو أحد الـ salts للـ phosphoric acid
+
+9
+00:00:58,830 --> 00:01:02,290
+في المدى، يعني ممكن نقول إن الـ phosphate كـ phosphate
+
+10
+00:01:02,290 --> 00:01:07,340
+sodium phosphate أو tri-sodium phosphate هي الـ
+
+11
+00:01:07,340 --> 00:01:12,240
+unprotonated salt للفوسفوريك أسد، لو جينا بدنا
+
+12
+00:01:12,240 --> 00:01:17,320
+نتكلم عن الـ unprotonated salt للفوسفوريك أسد اللي
+
+13
+00:01:17,320 --> 00:01:22,860
+هو الفوسفات، بنقول الفوسفات Na₃PO₄
+
+14
+00:01:26,470 --> 00:01:30,110
+PO₄⁻³، فلما نتكلم عن الـ Sodium أو Tri-Sodium
+
+15
+00:01:30,110 --> 00:01:34,410
+Phosphate، طبعًا الـ Sodium الـ spectator ما بيتفاعل مع
+
+16
+00:01:34,410 --> 00:01:38,430
+المية لأنه very weak conjugate acid، ليه very weak
+
+17
+00:01:38,430 --> 00:01:42,050
+conjugate acid، لأنه جاي من strong base، فبالتالي في
+
+18
+00:01:42,050 --> 00:01:50,990
+عندنا فقط PO₄⁻³، الـ phosphate، فبنقول جيد
+
+19
+00:01:50,990 --> 00:01:58,180
+جِدًّا أن نحاول نفهم مع بعض كيف بتتم عملية المعايرة
+
+20
+00:01:58,180 --> 00:02:04,960
+في البداية خالص قبل إضافة أي HCl، عندي يعني zero ml
+
+21
+00:02:04,960 --> 00:02:11,660
+من الـ HCl، ف أنا بقول والله عند هذه النقطة تحديدًا في
+
+22
+00:02:11,660 --> 00:02:21,000
+عندها فوسفات فقط، لكن مجرد ما إني أبدأ أضيف HCl على
+
+23
+00:02:21,000 --> 00:02:29,480
+الفسفيت، بلاحظ إنه الفوسفات بتبدأ تقل، و ببدأ يتكون
+
+24
+00:02:29,480 --> 00:02:38,660
+عندي HPO₄²⁻، مش هيك؟ طيب، تستمر عملية
+
+25
+00:02:38,660 --> 00:02:43,620
+الإضافة، فالفسفات بتقل، و الـ HPO₄²⁻ بتزيد
+
+26
+00:02:43,620 --> 00:02:48,640
+لغاية ما أوصل لنقطة، هذه النقطة هي نقطة التكافؤ
+
+27
+00:02:48,640 --> 00:02:55,380
+الأولى، اللي عندها كل الفوسفات تتحول لـ HPO₄²⁻
+
+28
+00:02:56,090 --> 00:03:02,630
+²⁻، هذه هي نقطة التكافؤ الأولى، بعد هيك تستمر
+
+29
+00:03:02,630 --> 00:03:07,670
+الإضافة، بضيف H⁺ إضافي، HCl الإضافي، فبلاحظ إن الـ
+
+30
+00:03:07,670 --> 00:03:09,630
+HPO₄²⁻ طبعًا
+
+31
+00:03:18,410 --> 00:03:25,030
+بتستمر عملية الإضافة لغاية ما كل الـ HPO₄²⁻
+
+32
+00:03:25,030 --> 00:03:33,990
+تنتهي، و بتتحول في نقطة النهاية إلى H₂PO₄⁻
+
+33
+00:03:33,990 --> 00:03:40,850
+⁻، يبقى عند نقطة النهاية الثانية بلاحظ إن في عندي
+
+34
+00:03:40,850 --> 00:03:52,310
+فقط H₂PO₄⁻، بضيف كمان H⁺، بلاحظ إن الـ H₂PO₄⁻
+
+35
+00:03:52,310 --> 00:04:00,510
+اللي هي ⁻ بتقل، و بيبدأ الـ H₃PO₄ يتكون
+
+36
+00:04:03,590 --> 00:04:09,590
+بيستمر هذا الشيء لغاية ما كل الـ H₂PO₄⁻ تنتهي
+
+37
+00:04:09,590 --> 00:04:15,030
+وبالتالي تتحول كلها لـ H₃PO₄
+
+38
+00:04:15,030 --> 00:04:24,650
+عند نقطة التكافؤ الثالثة، طيب، استمرنا في إضافة الـ HCl
+
+39
+00:04:24,650 --> 00:04:28,210
+بقول والله الـ H₃PO₄
+
+40
+00:04:29,370 --> 00:04:33,430
+أسد، و الـ HCl برضه أسد، ما بيتفاعلوش مع بعض، يعني كمية
+
+41
+00:04:33,430 --> 00:04:40,110
+الـ H⁺  عمالة بتزيد مع زيادة الإضافة من الـ HCl
+
+42
+00:04:40,110 --> 00:04:44,410
+لو جينا نطلع يا شباب في عندي عدة مواضع في الـ
+
+43
+00:04:44,410 --> 00:04:50,200
+curve، لازم أكون بعرف أحسب الـ pH بشكل ممتاز عندها،
+
+44
+00:04:50,200 --> 00:04:54,660
+يعني في البداية مثلًا عندي فوسفات، after addition of
+
+45
+00:04:54,660 --> 00:04:58,240
+zero ml، عندي بس فوسفات، فبقول والله كيف بدي
+
+46
+00:04:58,240 --> 00:05:02,400
+أحسب الـ pH للفوسفات؟ بقول الفوسفات هذا عبارة عن
+
+47
+00:05:02,400 --> 00:05:06,600
+unprotonated salt، unprotonated salt معناته بده
+
+48
+00:05:06,600 --> 00:05:11,150
+يتفاعل مع المية؟ بيتفكك في المية، بيعطينا Hydroxide
+
+49
+00:05:11,150 --> 00:05:14,610
+و HPO₄²⁻، مادام بيعطينا Hydroxide إذاً إن
+
+50
+00:05:14,610 --> 00:05:21,310
+هذا Kb، Kb بيساوي Kw على Ka₃، بجيب الـ Kb، و من
+
+51
+00:05:21,310 --> 00:05:26,670
+تفكك الفوسفات بعالجه بالضبط زي ما يكون salt of
+
+52
+00:05:26,670 --> 00:05:31,720
+monoprotic acid، نفس الكلام، مدام جبت الـ Kb خلاص
+
+53
+00:05:31,720 --> 00:05:36,580
+انتهى، طيب، بعد هيك بلاحظ إن هذه منطقة buffer عندي
+
+54
+00:05:36,580 --> 00:05:41,720
+acid اسمه HPO₄²⁻، وعندي conjugate base
+
+55
+00:05:41,720 --> 00:05:46,760
+فوسفات، بعرف كيف أحسب الـ pH للـ buffer عند نقطة
+
+56
+00:05:46,760 --> 00:05:53,440
+التكافؤ الأولى، عندي فقط HPO₄²⁻، هذه مادة
+
+57
+00:05:53,440 --> 00:06:00,020
+كيف بدي أحسب الـ pH لها؟ بطلع عليها بلاقي إنه هذا
+
+58
+00:06:00,020 --> 00:06:05,200
+عبارة عن salt of polyprotic acid، بس هذا الـ salt is
+
+59
+00:06:05,200 --> 00:06:09,540
+protonated، يبقى protonated salt، إذاً على القانون
+
+60
+00:06:09,540 --> 00:06:13,940
+لكن مش أي قانون، بطلع الشحنة اللي عليه، بلاقيها 2
+
+61
+00:06:13,940 --> 00:06:18,180
+سالب، إيش معناه 2 سالب؟ معناته الجذر التربيعي لـ
+
+62
+00:06:18,180 --> 00:06:26,110
+Ka₂ Kw + Ka₂ تركيز الملح على Ka₂ +
+
+63
+00:06:26,110 --> 00:06:32,010
+تركيز الملح، ممتاز، نمشي خطوة ثانية، بيبدأ يتكون
+
+64
+00:06:32,010 --> 00:06:35,370
+عندنا buffer ثاني، هي الـ acid، وهي الـ conjugate base
+
+65
+00:06:35,370 --> 00:06:39,970
+تبعه، يبقى منطقة buffers، حساب الـ pH للـ buffer سهل
+
+66
+00:06:39,970 --> 00:06:42,030
+جدًّا عند
+
+67
+00:06:43,720 --> 00:06:49,080
+هذا،  كافة الثانية، بلاحظ إن عندي H₂PO₄⁻، طب هذا
+
+68
+00:06:49,080 --> 00:06:55,120
+الـ H₂PO₄⁻، كيف أحسب الـ pH؟ آه، برضه هذا salt of
+
+69
+00:06:55,120 --> 00:06:59,000
+polyprotic acid، ومش بس هيك، هذا protonated salt، معناته
+
+70
+00:06:59,000 --> 00:07:02,600
+كلها برضه على القانون، إيش يعني على القانون؟ يعني
+
+71
+00:07:02,600 --> 00:07:07,780
+يعني الجذر التربيعي لـ Ka₁ Kw + Ka₁
+
+72
+00:07:07,780 --> 00:07:11,840
+Ka₂ تركيز الملح على Ka₁ +
+
+73
+00:07:11,840 --> 00:07:19,500
+تركيز الملح، بيساوي الـ H⁺ في هذه المنطقة، عندي
+
+74
+00:07:19,500 --> 00:07:24,300
+dihydrogen phosphate، و فوسفوريك أسد، أسد و its
+
+75
+00:07:24,300 --> 00:07:28,630
+conjugate base، إذاً برضه كمان عندي buffer ثالث، طيب
+
+76
+00:07:28,630 --> 00:07:32,990
+buffer ثالث، بقدر أحسب الـ pH بسهولة، عند نقطة التكافؤ
+
+77
+00:07:32,990 --> 00:07:37,150
+الثالثة، فقط عندي phosphoric acid، كيف بدي أحسب الـ
+
+78
+00:07:37,150 --> 00:07:40,570
+pH للـ phosphoric acid؟ آه، هذا polyprotic acid، بدي
+
+79
+00:07:40,570 --> 00:07:45,310
+أقول Ka₁ على Ka₂، إذا أكتر من 100 بدي ألغي Ka₂ و Ka₃
+
+80
+00:07:45,310 --> 00:07:48,730
+بيبقى عندي بس التفكك الأول للـ phosphoric acid
+
+81
+00:07:48,730 --> 00:07:56,860
+بقدر أجيب الـ pH، طيب، أخيرًا، الفوسفوريك أسد أضفت عليه
+
+82
+00:07:56,860 --> 00:08:01,780
+excess H⁺، قال والله هذا عبارة عن mixture
+
+83
+00:08:01,780 --> 00:08:06,940
+between two acids، strong acid و weak acid، كيف بده
+
+84
+00:08:06,940 --> 00:08:09,760
+أجيب الـ pH لـ الـ mixture هذا؟ اتعلمنا كيف نجيبها
+
+85
+00:08:09,760 --> 00:08:14,600
+سابقا، احنا حسبنا، احنا هنرجع نعيد هذا الكلام مرة
+
+86
+00:08:14,600 --> 00:08:21,400
+ثانية بعد شوية، يبقى هذه المناطق اللي احنا بنتحدث
+
+87
+00:08:21,400 --> 00:08:25,940
+عنها، و لو جينا  مثلاً وحطينا  50 ml، 50 ml
+
+88
+00:08:25,940 --> 00:08:30,260
+طبعًا بناء على المثال اللي بعد شوية هناخده، مش 50
+
+89
+00:08:30,260 --> 00:08:33,980
+ml، يعني خلاص هي 50 ml، لو كان عندنا 50
+
+90
+00:08:33,980 --> 00:08:41,140
+ml من 0.1 molar phosphate، و أنا بدي أعيرها بـ
+
+91
+00:08:41,140 --> 00:08:45,220
+0.1 molar HCl، آه، ساعتها دي بتكون 50 ml
+
+92
+00:08:45,220 --> 00:08:49,040
+ليه؟ لأن 50 ml 0.1 molar فوسفات يعني
+
+93
+00:08:49,040 --> 00:08:53,480
+5 ملي مول، طب إيش بدها من الـ HCl؟ بدها 5 ملي مول
+
+94
+00:08:53,480 --> 00:08:57,300
+زيها، 5 ملي مول، يعني 50 ml، 50 ml بتوصلنا
+
+95
+00:08:57,300 --> 00:09:00,060
+لنقطة تكافؤها الأولى، 50 ml نقطة تكافؤها
+
+96
+00:09:00,060 --> 00:09:03,240
+الثانية، 50 ml نقطة تكافؤها الثالثة، يعني مثلًا
+
+97
+00:09:03,690 --> 00:09:10,230
+لو أنا يعني أضفت 60 ml، بقول آه أنا أضفت أول حاجة
+
+98
+00:09:10,230 --> 00:09:13,950
+أول 50 راحوا في تحويل الفوسفات للهيدروجين
+
+99
+00:09:13,950 --> 00:09:18,790
+فوسفات، لما أضيف 60، إذًا  الـ 10 وين الـ 10؟
+
+100
+00:09:18,790 --> 00:09:23,970
+الـ 10 أنا أضفتهم على الهيدروجين فوسفات، لو أضفت
+
+101
+00:09:23,970 --> 00:09:28,330
+مثلًا 120 ml، بقول أول 50 حولت الفوسفات
+
+102
+00:09:28,330 --> 00:09:31,130
+للهيدروجين فوسفات، ثاني 50 حولت الهيدروجين
+
+103
+00:09:31,130 --> 00:09:36,010
+فوسفات لديهايدروجين فوسفات، هي الـ 20، قال
+
+104
+00:09:36,010 --> 00:09:38,770
+آه، يبقى أنا أضفت 20 ml من الـ HCl لديهايدروجين
+
+105
+00:09:38,770 --> 00:09:43,170
+فوسفات، واخدين بالكم إيش معنى الحجوم هذه؟ كويس جدًا
+
+106
+00:09:43,170 --> 00:09:49,300
+الآن، خلينا نطلع على مثال، و نحاول إننا نطبق المفاهيم
+
+107
+00:09:49,300 --> 00:09:55,260
+اللي ذكرناها هنا في حل المثال، أو في إيجاد الـ pH
+
+108
+00:09:55,260 --> 00:09:58,980
+at different additions، أو after different
+
+109
+00:09:58,980 --> 00:10:04,900
+additions من الـ HCl، فنطلع على المثال
+
+110
+00:10:07,750 --> 00:10:13,810
+المثال بيقول التالي، بيقول find the pH of a 50 ml
+
+111
+00:10:13,810 --> 00:10:19,330
+solution of a 0.1 molar sodium phosphate، يبقى عندي
+
+112
+00:10:19,330 --> 00:10:23,670
+0.1 molar sodium phosphate، ما عطينا طبعًا الـ Ka₁ و
+
+113
+00:10:23,670 --> 00:10:27,930
+الـ Ka₂ و الـ Ka₃، و أنت دبر حالك، بتجيب الـ Ka، بتجيبه
+
+114
+00:10:27,930 --> 00:10:33,390
+بتجيب Ka₁, تجيب Ka₂, تجيب Ka₃، أنت حر، دبر حالك، و
+
+115
+00:10:33,390 --> 00:10:38,120
+بيعطيك بس إيه؟ Ka₁, Ka₂, Ka₃، بيقول لك after
+
+116
+00:10:38,120 --> 00:10:45,020
+addition of 0, 25, 50, 75, 100, 125, 150, and 175
+
+117
+00:10:45,020 --> 00:10:54,920
+ml of 0.1 molar HCl، فنبدأ إضافة إضافة، بس
+
+118
+00:10:54,920 --> 00:10:58,900
+هاي الـ curve للمعلومات
+
+119
+00:11:01,620 --> 00:11:06,880
+لزيادة التأكد، هاي الـ ml HCl، و بده يقول أنا
+
+120
+00:11:06,880 --> 00:11:11,940
+after addition of zero ml من الـ HCl، أنا zero
+
+121
+00:11:11,940 --> 00:11:18,950
+ml، إيش في عندي؟ طبعًا pH عالي، لأن base لأن الـ base
+
+122
+00:11:18,950 --> 00:11:25,690
+الـ pH تبعته إيه؟ عالية، فهيطلع عندي لما أنا آجي
+
+123
+00:11:25,690 --> 00:11:29,290
+أقول والله فوسفات، zero ml، مع الكلام، أنا ما أضفتش
+
+124
+00:11:29,290 --> 00:11:32,630
+أي شيء، أنا عندي 0.1 molar صودا فوسفات، إذا
+
+125
+00:11:32,630 --> 00:11:36,330
+الفوسفات عندي 0.1 molar، ما اتغيرت، ليه؟ لأنه
+
+126
+00:11:36,330 --> 00:11:40,480
+ما أضفت عليها أي شيء، ما أضفت على الفوسفات أي شيء
+
+127
+00:11:40,480 --> 00:11:45,580
+فضا عندي 0.1 molar فوسفات، إذا كيف بدي أجيب الـ pH
+
+128
+00:11:45,580 --> 00:11:49,320
+إليها؟ بقول والله الـ unprotonated salt، هيك تحسب له
+
+129
+00:11:49,320 --> 00:11:54,120
+الـ pH، بقى أحط عليه مية، بيتفكك، هيدروجين فوسفات، و
+
+130
+00:11:54,120 --> 00:11:59,580
+hydroxide، Kb بيساوي Kw على Ka₃، يعني الـ Kb
+
+131
+00:11:59,580 --> 00:12:04,750
+بيساوى 2.2 × 10⁻²، وبعدين باجي بقول والله من
+
+132
+00:12:04,750 --> 00:12:09,930
+الجدول، 0.1، 0، 0، 0.1 - x، x، x، الـ
+
+133
+00:12:09,930 --> 00:12:13,830
+Kb بتساوي الـ x² على 0.1 - x، بقول
+
+134
+00:12:13,830 --> 00:12:18,970
+فرضية، 0.1 أكبر بكثير من الـ x، إذا الـ x بتساوي
+
+135
+00:12:18,970 --> 00:12:21,370
+0.045، الـ relative error 45%، مش مقبول، invalid assumption، إذاً
+
+136
+00:12:21,370 --> 00:12:26,470
+لازم نحل باستخدام الـ quadratic equation، لو حلنا
+
+137
+00:12:30,290 --> 00:12:34,850
+هييطلع 0.036، لكن مش مطلوب منك تحل باستخدام الـ
+
+138
+00:12:34,850 --> 00:12:37,650
+quadratic equation، فقط بتقول إن الـ assumption
+
+139
+00:12:37,650 --> 00:12:41,070
+invalid، يعني لازم نستخدم الـ quadratic equation
+
+140
+00:12:41,070 --> 00:12:47,320
+لإيجاد الـ x و الـ H⁺، بالنسبة لي هنا أنا الـ x 0.046
+
+141
+00:12:47,320 --> 00:12:49,600
+بتطلع باستخدام الـ quadratic
+
+142
+00:12:49,600 --> 00:12:52,640
+equation، معناه كده الـ pOH 1.34، و
+
+143
+00:12:52,640 --> 00:12:56,860
+الـ pH 12.66، هذا مباشر، معناته كيف
+
+144
+00:12:56,860 --> 00:13:01,140
+نحصل الـ pH للفوسفات قبل ما نضيف، ماشي يا شباب؟ فبالـ
+
+145
+00:13:01,140 --> 00:13:08,120
+نبدأ نضيف، نبدأ نضيف HCl، أي حجم من الـ HCl؟ نضيف 25
+
+146
+00:13:08,120 --> 00:13:13,020
+ml من الـ HCl، 25 ml، معناته والله
+
+147
+00:13:14,860 --> 00:13:23,500
+هي الـ PO₄⁻³ بدها تقل، والـ HPO₄²⁻ بدها تزيد، هذا buffer
+
+148
+00:13:23,500 --> 00:13:29,560
+solution، ما علينا، بنقول والله الـ initial millimole
+
+149
+00:13:29,560 --> 00:13:32,200
+of phosphate، 0.1 في 50، يعني 5
+
+150
+00:13:32,200 --> 00:13:35,940
+millimole، و اذكر هذا الرقم حيظل 5 طول المسألة
+
+151
+00:13:35,940 --> 00:13:40,200
+لإن ممكن الفوسفات تتحول من شكل لآخر، لكن مجموع
+
+152
+00:13:40,200 --> 00:13:44,620
+الفوسفات species دائماً 5، ما بيتغير، فهذا الرقم
+
+153
+00:13:44,620 --> 00:13:48,300
+حيظل معنا على طول، الـ millimole H⁺ added بعد
+
+154
+00:13:48,300 --> 00:13:50,940
+إضافة 25 ml، 0.1 في 25
+
+155
+00:13:51,620 --> 00:13:55,800
+معنى الكلام برضه 2.5، إذا الـ millimole فوسفات left
+
+156
+00:13:55,800 --> 00:14:01,340
+5 نقص 2.5 يعني 2.5، يبقى تركيز الفوسفات 2.5 على
+
+157
+00:14:01,340 --> 00:14:05,680
+الـ total volume، 50 + 25 = 75،
+
+158
+00:14:05,680 --> 00:14:10,360
+مش هيك؟ في نفس الوقت على طول، أنا بقول هذا قل، هذا
+
+159
+00:14:10,360 --> 00:14:14,620
+اتكون، هذا تفاعل، هذا اتكون، إذا الـ millimole
+
+160
+00:14:14,620 --> 00:14:21,130
+hydrogen فوسفات لازم يكون 2.5، ليه؟ لأنه مجموع الـ
+
+161
+00:14:21,130 --> 00:14:25,230
+hydrogen phosphate و الفوسفات لازم يكون 5، فإذا
+
+162
+00:14:25,230 --> 00:14:27,590
+كان هذا 2.5، إذا هذا لازم يكون 2.5،
+
+163
+00:14:27,590 --> 00:14:32,410
+مش هيك؟ و برضه كمان احنا فينا نعمل هذا الكلام
+
+164
+00:14:32,410 --> 00:14:38,820
+كالتالي، الـ PO₄⁻³ + H⁺ بتعطينا HPO₄²⁻، لو جيت
+
+165
+00:14:38,820 --> 00:14:44,780
+طلعت هنا إيش بلاقي؟ بلاقي buffer، buffer، كيف بدي أحل الـ
+
+166
+00:14:44,780 --> 00:14:51,530
+buffer solution علشان أوجد الـ H⁺؟ بقول والله بدي
+
+167
+00:14:51,530 --> 00:14:55,670
+أي معادلة بتحتوي على
+
+223
+00:19:45,230 --> 00:19:51,470
+Minimum of H₂PO₄⁻ formed 2.5، ولاحظوا 2.5 و 2
+
+224
+00:19:51,470 --> 00:19:58,020
+.5 دائما خمسة، الفوسفات يبقى الـ H₂PO₄ 2.5 على 125
+
+225
+00:19:58,020 --> 00:20:03,280
+ولو جئتَ، طلعت عليهم، بلاجئ أن هذين الاثنين يعملانِ
+
+226
+00:20:03,280 --> 00:20:08,440
+buffer،  هاي الـ acid وهي its conjugate base، يبقى هذا
+
+227
+00:20:08,440 --> 00:20:14,440
+buffer، كيف بدي أحسب الـ pH للـ buffer؟ أحسبه من
+
+228
+00:20:14,440 --> 00:20:21,140
+معادلة تحتوي على الـ two species، هاي الـ H₂PO₄ وهي
+
+229
+00:20:21,140 --> 00:20:25,780
+الـ HPO₄²⁻، والله هذا موجود في الكائنة، حلو كثير هاي 2
+
+230
+00:20:25,780 --> 00:20:31,260
+.5 على 125، 2.5 على 125، صفر، 2.5 على 125 − X، 2.5
+
+231
+00:20:31,260 --> 00:20:36,740
+على 125 + X، X، بتطلع هذه كائنة، جداش الكائنة؟ سبعة، و
+
+232
+00:20:36,740 --> 00:20:40,580
+نصف عشر أو سالب ثمانية، صغير كثير، بتوقع الـ X تكون
+
+233
+00:20:40,580 --> 00:20:46,690
+مهملة، لأ، ومع ذلك، يعني إحنا بنشوف فلجات لما نعوض في
+
+234
+00:20:46,690 --> 00:20:51,570
+الـ Ka₂، الـ X بتوع 7.5 × 10⁻⁸، لما نبدأ أجي أجمعها لـ
+
+235
+00:20:51,570 --> 00:20:57,510
+2.5 على 125، لا تجمع، قليلة جدا، وبالفعل هي مهملة
+
+236
+00:20:57,510 --> 00:21:03,450
+طيب إيش بنشوف كمان؟ بنشوف أن هنا عين نص الحجم
+
+237
+00:21:03,450 --> 00:21:10,850
+اللازم لنقطة التكافؤ الثانية بين، يعني الحجم بين
+
+238
+00:21:10,850 --> 00:21:15,560
+نقطة التكافؤ الأولى والثانية في نصه تماما،  الـ pH
+
+239
+00:21:15,560 --> 00:21:22,400
+بتساوي pKa₂، ليش؟ لأنه هي الـ X، اللي هي الـ H
+
+240
+00:21:22,400 --> 00:21:27,280
+⁺ بتساوي الـ Ka₂، يبقى الـ pH بتساوي الـ pK
+
+241
+00:21:27,280 --> 00:21:31,460
+a₂، يبقى أنا لو ما بعرفش الـ Ka، بقدر من الـ
+
+242
+00:21:31,460 --> 00:21:38,880
+titration curve أجيبها بسهولة، طيب معنى الكلام، الـ H
+
+243
+00:21:38,880 --> 00:21:41,460
+⁺ بتاع سبعة ونصف في عشرة أس سالب ثمانية، والـ pH
+
+244
+00:21:41,460 --> 00:21:47,780
+سبعة واثنا عشر من مئة، خلينا الآن نضيف كمية أكبر من
+
+245
+00:21:47,780 --> 00:21:52,740
+الـ HCl، نضيف 100 مل من الـ HCl، عند إضافة 100 مل
+
+246
+00:21:52,740 --> 00:21:58,660
+بقول 50 مل في الأول راحوا أو استهلكوا في تفاعل
+
+247
+00:21:58,660 --> 00:22:03,480
+الفوسفات لما تحولت للهيدروجين فوسفات، فبالخمسين
+
+248
+00:22:03,480 --> 00:22:07,880
+الثانية راح يستهلكوا لما الهيدروجين فوسفات تتحول
+
+249
+00:22:07,880 --> 00:22:11,980
+كلها للـ H₂PO₄⁻
+
+250
+00:22:13,870 --> 00:22:17,430
+ونشوف هذا الكلام، أنا عندي الـ initial millimole
+
+251
+00:22:17,430 --> 00:22:23,290
+HPO₄²⁻، 2.5 millimole، اللي هي اجت من الفوسفات
+
+252
+00:22:23,290 --> 00:22:26,970
+خمسة millimole، طب جداش أضفت عليها H⁺، أول خمسين
+
+253
+00:22:26,970 --> 00:22:30,750
+ما بحكيش فيهم، أضفت عليها خمسين من الـ H⁺، يعني
+
+254
+00:22:30,750 --> 00:22:35,010
+خمسة millimole، إذا الـ millimole HPO₄²⁻ left
+
+255
+00:22:35,010 --> 00:22:38,350
+خمسة ناقص خمسة، صفر، يبقى هذه هي الـ second
+
+256
+00:22:39,130 --> 00:22:45,450
+equivalence point، الـ H₂PO₄⁻ خمسة millimole، وخمسين، طب
+
+257
+00:22:45,450 --> 00:22:49,450
+كيف بدي أوجد الـ pH at equivalence point أو second
+
+258
+00:22:49,450 --> 00:22:54,770
+equivalence point، لما كل المحلول يكون H₂PO₄⁻
+
+259
+00:22:54,770 --> 00:22:58,990
+بقول هذا برضه protonated salt، هذا برضه protonated
+
+260
+00:22:58,990 --> 00:23:04,900
+salt، لكن كم شحنة عليه؟ شحنة واحدة، إذا Ka₁Kw +
+
+261
+00:23:04,900 --> 00:23:08,380
+Ka₁Ka₂، تركيز الصوت على Ka₁ + تركيز الصوت
+
+262
+00:23:08,380 --> 00:23:13,460
+كله تحت الجذر، لو عملت هيك، تطلع عندي الـ H⁺ 2
+
+263
+00:23:13,460 --> 00:23:18,240
+ونصف × 10⁻⁵، والـ pH أربعة وستة من عشرة
+
+264
+00:23:18,240 --> 00:23:22,080
+لكن، يعني ملاحظين معايا، أن كل نوع من أنواع المحاليل
+
+265
+00:23:22,080 --> 00:23:25,450
+له طريقة حساب، كل نوع من أنواع المحيط، اللي هو طريقة
+
+266
+00:23:25,450 --> 00:23:31,810
+حساب الـ H⁺ تبعته، طب الآن نيجي نضيف كمية أكبر
+
+267
+00:23:31,810 --> 00:23:36,050
+من الـ HCl، راح ألاحظ أنا أنه إذا كانت عندي كمية
+
+268
+00:23:36,050 --> 00:23:41,630
+أكبر من الـ HCl، الـ H₂PO₄⁻ هذا راح يجي، وراح
+
+269
+00:23:41,630 --> 00:23:47,970
+يبدأ يتكون عندنا الفوسفوريك أسيد، راح يبدأ يتكون
+
+270
+00:23:47,970 --> 00:23:53,800
+عندي، يعني صار عندي buffer جديد، طيب بنقول عند الـ
+
+271
+00:23:53,800 --> 00:23:59,920
+initial ml من إيش؟ هالـ H₂PO₄⁻، لأنه خلصت الـ
+
+272
+00:23:59,920 --> 00:24:06,140
+HPO₄²⁻، كلها اتحولت للـ H₂PO₄⁻، فأنا بدي أضيف 125 ml
+
+273
+00:24:06,140 --> 00:24:12,240
+بقول أول 50 ml راحوا في تحويل الفوسفات إلى الـ
+
+274
+00:24:12,240 --> 00:24:17,120
+hydrogen phosphate، ثاني 50 ml راحوا في تحويل الـ
+
+275
+00:24:17,120 --> 00:24:24,320
+hydrogen phosphate إلى الـ H₂PO₄⁻، هي كمان خمسين مل
+
+276
+00:24:24,320 --> 00:24:31,320
+إذا أضفت خمسة وعشرين مل على هذا، فبقول والله
+
+277
+00:24:31,320 --> 00:24:35,060
+أنا عندي الـ millimol من الـ H₂PO₄⁻ خمسة، أضفت عليها
+
+278
+00:24:35,060 --> 00:24:40,260
+خمسة وعشرين مل من الـ 0.1 molar HCl، يعني
+
+279
+00:24:40,260 --> 00:24:44,300
+2.5 millimol، إذا الـ millimol H₂PO₄⁻ left
+
+280
+00:24:44,300 --> 00:24:48,450
+خمسة ناقص 2.5، 2.5، التركيز هو
+
+281
+00:24:48,450 --> 00:24:54,350
+2.5 على 175، حجم الكل، طيب أنا
+
+282
+00:24:54,350 --> 00:24:58,950
+لما أضفت H⁺ على الـ H₂PO₄⁻، تحول لإيه؟ لـ
+
+283
+00:24:58,950 --> 00:25:04,370
+الفوسفوريك أسيد، تحول للفوسفوريك أسيد، إذا الملي
+
+284
+00:25:04,370 --> 00:25:08,310
+مول فوسفوريك أسيد 2.5، لأن مجموعة كل الفوسفات
+
+285
+00:25:08,310 --> 00:25:12,910
+فوسفوريك أسيد وهيدروجين فوسفات، مجموعهم كلهم خمسة
+
+286
+00:25:12,910 --> 00:25:14,250
+ماشي
+
+287
+00:25:16,100 --> 00:25:22,700
+إذا الفوسفوريك أسيد أيضا تركيزه 2.5 على 175، ولو جئتَ
+
+288
+00:25:22,700 --> 00:25:26,860
+طلعت بلاجئ، فوسفوريك أسيد ودي هيدروجين فوسفات، هذا
+
+289
+00:25:26,860 --> 00:25:31,240
+buffer، هاي الـ acid وهي الـ conjugate base تبعته، كيف
+
+290
+00:25:31,240 --> 00:25:36,360
+بدي أجيب الـ pH للـ buffer؟ بقول بسيطة، هاي 2.5 على
+
+291
+00:25:36,360 --> 00:25:43,340
+175، 2.5 على 175، 2.5 على 175 − X، 2.5 على 175 +
+
+292
+00:25:43,340 --> 00:25:51,140
+X، و X، بقول هذه عبارة عن إيه؟ Ka₁، جداش قيمته؟
+
+293
+00:25:51,140 --> 00:25:57,420
+7.1 × 10⁻³، إيش رأيكم؟ الـ X
+
+294
+00:25:57,420 --> 00:26:02,800
+متوقع تكون يعني مهملة؟ ولا متوقع تكون لها قيمة؟
+
+295
+00:26:02,800 --> 00:26:06,590
+والله إيه في شيء مشكوك فيه، يعني شيء مشكوك فيه لأن
+
+296
+00:26:06,590 --> 00:26:10,250
+عشرة أس سالب ثلاثة، مش صغير كثير، عشرة أس سالب ثلاثة
+
+297
+00:26:10,250 --> 00:26:15,510
+مش صغير كثير، فأنا بقول Ka₁، بنعوض عن الأرقام
+
+298
+00:26:15,510 --> 00:26:16,330
+اللي قدامي
+
+299
+00:26:20,110 --> 00:26:23,450
+بنعتبر أنه 2.5 أكبر كثير من الـ X، لكن طبعا يعني أنا
+
+300
+00:26:23,450 --> 00:26:27,370
+حاطط لكم علامات تعجب، أن Ka₁ is very small، لأ
+
+301
+00:26:27,370 --> 00:26:30,630
+علامات تعجب، لأ، مش very small، هو على أي حال الـ X
+
+302
+00:26:30,630 --> 00:26:34,490
+بتطلع 1.1 × 10⁻²، بجيب الـ relative
+
+303
+00:26:34,490 --> 00:26:39,850
+error، بتطلع 77%، إذا الـ relative error إيش بيقول
+
+304
+00:26:39,850 --> 00:26:44,760
+ليه؟ بيقول لأ والله هذه الـ X لا يمكن إهمالها، هذه أو
+
+305
+00:26:44,760 --> 00:26:53,040
+بمعنى آخر، الـ H⁺ اللي جاية من من تفكك الـ
+
+306
+00:26:58,360 --> 00:27:02,340
+من تفكك الفوسفوريك أسيد مهمة، لازم نأخذ بالنا منها
+
+307
+00:27:02,340 --> 00:27:07,340
+مهمة، لها قيمة، لها قيمة، بتأثر على الـ pH
+
+308
+00:27:07,340 --> 00:27:11,840
+وبالتالي، لو استخدمت الـ quadratic equation، تطلع 5.2 ×
+
+309
+00:27:11,840 --> 00:27:16,480
+10⁻³، الـ H⁺ أو الـ X، والـ pH 2.29، بينما لو حسبنا بدون الـ X
+
+310
+00:27:16,480 --> 00:27:26,600
+هتطلع الـ pH 1.96، طبعا
+
+311
+00:27:26,600 --> 00:27:33,620
+1.96 لـ 2.29، في فرق، للأمانة مش فرق كبير، لكن يعتبر
+
+312
+00:27:33,620 --> 00:27:37,840
+فرق كويس، يعني مش، للأمانة مش فرق كبير، لكن
+
+313
+00:27:37,840 --> 00:27:43,340
+يعتبر إيش؟ يعني حاجة لا يمكن إهمالها، ولا إهمالها، كويس
+
+314
+00:27:43,340 --> 00:27:49,840
+فشوفنا أنه ممكن الـ X، حتى لو كان buffer، حتى لو كان
+
+315
+00:27:49,840 --> 00:27:53,580
+buffer، ممكن أن الـ X تكون لها قيمة، لكن متى هذا
+
+316
+00:27:53,580 --> 00:28:00,470
+الكلام؟ دائما فقط إذا كان الـ Ka مش صغير، آه، مش صغير
+
+317
+00:28:00,470 --> 00:28:06,290
+الـ Ka مش صغير، طيب خلينا
+
+318
+00:28:06,290 --> 00:28:15,690
+نطلع على إيش بيحصل لما نضيف كمان H⁺
+
+319
+00:28:15,690 --> 00:28:20,830
+بقول والله الـ H₂PO₄⁻ كلها بتتحول لإيه؟ للـ
+
+320
+00:28:20,830 --> 00:28:26,830
+phosphoric acid، يبقى عند الـ equivalence point
+
+321
+00:28:26,830 --> 00:28:33,670
+بتاعتها، أو عند إضافة 150 ml، كل هذه كمان 50 ml، هذا
+
+322
+00:28:33,670 --> 00:28:45,150
+حول الـ H₂PO₄⁻ إلى H₃PO₄، خمسين مل برضه بتأخذ، يبقى
+
+323
+00:28:45,150 --> 00:28:49,750
+بقدر أقول أنا أنه عند 150 مل، الأصل أن كل
+
+324
+00:28:49,750 --> 00:28:53,250
+الهيدروجين أو الـ dihydrogen phosphate تتحول
+
+325
+00:28:53,250 --> 00:28:55,850
+إليه؟ للـ phosphoric acid، ما علينا، إحنا بنقول أول
+
+326
+00:28:55,850 --> 00:28:58,550
+50 مل راحوا في تحويل الفوسفات لـ hydrogen
+
+327
+00:28:58,550 --> 00:29:01,550
+phosphate، ثاني 50 مل راحوا في تحويل الـ hydrogen
+
+328
+00:29:01,550 --> 00:29:04,910
+phosphate للـ dihydrogen phosphate، إذا أنا أضفت
+
+329
+00:29:04,910 --> 00:29:09,190
+بس 50 مل على الـ dihydrogen phosphate، باجي بقول
+
+330
+00:29:09,190 --> 00:29:12,890
+هنا الـ initial millimole of hydrogen phosphate
+
+331
+00:29:12,890 --> 00:29:17,470
+خمسة، الـ millimole H⁺ added، 0.1 × 50
+
+332
+00:29:17,470 --> 00:29:23,270
+يعني خمسة، إذا الـ millimole H₂PO₄⁻ left، خمسة ناقص
+
+333
+00:29:23,270 --> 00:29:28,490
+خمسة، صفر، معناته إيه؟ this is the third equivalence
+
+334
+00:29:28,490 --> 00:29:32,710
+point، this is the third equivalence point، المليمول
+
+335
+00:29:32,710 --> 00:29:38,190
+الفوسفوريك أسيد خمسة
+
+336
+00:29:38,190 --> 00:29:44,760
+لأن كل الفوسفات خمسة، تركيز الفوسفوريك أسيد 5 على 150
+
+337
+00:29:44,760 --> 00:29:49,400
+و 250، يبقى الآن في عندي فقط فوسفوريك أسيد، طب كيف
+
+338
+00:29:49,400 --> 00:29:54,260
+بدي أوجد الـ pH للفوسفوريك أسيد اللي تركيزه 5 على 200؟
+
+339
+00:29:54,260 --> 00:29:59,040
+بقول، بكتب المعادلات، وبعدين بجسم Ka₁، Ka₂، K
+
+340
+00:29:59,040 --> 00:30:04,180
+a₁ على Ka₂ أكبر من 10 أس 2، إذا بُلغَ الـ Ka₂ و K
+
+341
+00:30:04,180 --> 00:30:08,720
+a₃، الـ equilibrium الثاني والثالث بُلغِهم، وبيبقى عند
+
+342
+00:30:08,720 --> 00:30:14,280
+فقط الـ phosphoric acid، باجي بقول هاي 5 على 200 أو
+
+343
+00:30:14,280 --> 00:30:20,640
+0.025، 0، 0، 0.025 − X، X، X، لكن بدي أتذكر أنه الـ
+
+344
+00:30:20,640 --> 00:30:24,980
+equilibrium constant، كيف وضعه؟ كبير ولا صغير؟
+
+345
+00:30:24,980 --> 00:30:29,140
+آه، بدي آخذ بالي منه، أنه مش صغير كثير، ما علينا،
+
+346
+00:30:29,140 --> 00:30:34,060
+هيَطلع معنا، سواء يعني أخذنا بالنا أو لأ، بنقول Ka₁
+
+347
+00:30:34,060 --> 00:30:37,640
+بتساوي X² على الـ 0.025 − X، بنعمل الفرضية
+
+348
+00:30:37,640 --> 00:30:42,960
+تبعِتنا، الـ X بتطلع 0.017، لو جيبنا الـ relative
+
+349
+00:30:42,960 --> 00:30:50,430
+error، بتطلع 68%، 68% غير مقبول، إذا we should use
+
+350
+00:30:50,430 --> 00:30:53,590
+the quadratic equation، معنى الكلام إيه؟ معنى
+
+351
+00:30:53,590 --> 00:30:58,170
+الكلام أن الـ X فيها قيمة، وبالتالي لا يمكن إهمالها
+
+352
+00:30:58,170 --> 00:31:03,970
+جنب الـ 0.025، علشان هيك لازم نحل باستخدام الـ
+
+353
+00:31:03,970 --> 00:31:11,130
+quadratic equation، بتأخذ آخر نقطة، بدي آخذ آخر نقطة
+
+354
+00:31:11,130 --> 00:31:15,710
+لما نقول أضيف كمان، بدي أضيف، هي عندي phosphoric
+
+355
+00:31:15,710 --> 00:31:20,670
+acid، هنا أضفت عليه H⁺، بتفاعلوا مع بعض، زي ما هم
+
+356
+00:31:20,670 --> 00:31:28,770
+بتفاعلوا، فبدي أوجد الـ pH، تعالوا نضيف 175 مل، بقول
+
+357
+00:31:28,770 --> 00:31:32,930
+أول 50 مل استهلكوا في تحويل الفوسفات لـ hydrogen
+
+358
+00:31:32,930 --> 00:31:36,470
+phosphate، ثاني 50 مل استهلكوا في تحويل الـ hydrogen
+
+359
+00:31:36,470 --> 00:31:39,820
+phosphate للـ dihydrogen phosphate، ثالث خمسين ملي
+
+360
+00:31:39,820 --> 00:31:44,260
+تستهلكوا في إيه؟ في تحويل الـ H₂PO₄⁻ للفسفوريك
+
+361
+00:31:44,260 --> 00:31:47,960
+أسيد، إذا هاي 150 مل راحوا، إذا أنا جداش
+
+362
+00:31:47,960 --> 00:31:51,840
+ضايف على الفوسفوريك أسيد خمسة وعشرين ملي، فباجي
+
+363
+00:31:51,840 --> 00:31:56,120
+بقول والله الـ millimol H⁺ excess بتساوي 0.1 ×
+
+364
+00:31:56,120 --> 00:31:59,260
+خمسة وعشرين، بس 2.5، تركيز الـ H
+
+365
+00:31:59,260 --> 00:32:03,280
+⁺ الـ excess، 2.5 على 200، خمسة وعشرين،
+
+366
+00:32:03,280 --> 00:32:07,240
+طيب جداش الـ millimols من الفوسفوريك أسيد؟ خمسة؟
+
+367
+00:32:08,140 --> 00:32:13,380
+بتركيزه 5 على 225، باجي بقول إذا الـ H⁺ بيساوي الـ
+
+368
+00:32:13,380 --> 00:32:15,720
+H⁺ الـ excess زائد الـ H⁺ اللي جاي من
+
+369
+00:32:15,720 --> 00:32:21,180
+الفوسفوريك أسيد، كيف
+
+370
+00:32:21,180 --> 00:32:25,710
+بدي أجيب الـ H⁺ الكلية؟ هل أعتبر زي ما اعتبرت
+
+371
+00:32:25,710 --> 00:32:30,410
+الحصة الماضية، أن الـ OH⁻ اللي جاي من الـ
+
+372
+00:32:30,410 --> 00:32:33,790
+excess أكبر كثير من الـ OH⁻ اللي جاي من الـ
+
+373
+00:32:33,790 --> 00:32:38,550
+carbonate، وبالتالي قُلت والله يعني الـ carbonate
+
+374
+00:32:38,550 --> 00:32:41,630
+كمية الـ OH⁻ اللي جاي منها مهملة، لأ، إذا ما
+
+375
+00:32:41,630 --> 00:32:46,900
+قُلت بالـ OH⁻ اللي جاية من الـ excess، وقُلت أن
+
+376
+00:32:46,900 --> 00:32:50,580
+في معظم الأحيان هذا كلام صحيح، في معظم التفاعلات
+
+377
+00:32:50,580 --> 00:32:56,420
+صحيح، لكن قلنا أنه بيكون فيه مشكلة فقط إذا كان الـ
+
+378
+00:32:56,420 --> 00:33:00,560
+equilibrium constant عالي، يعني مثلا الـ equilibrium
+
+379
+00:33:00,560 --> 00:33:04,660
+constant للتفاعل الكربونيت كان 10⁻⁴
+
+380
+00:33:04,660 --> 00:33:08,100
+يعني بنقدر نقول أنه منخفض، بينما كان الـ equilibrium
+
+381
+00:33:08,100 --> 00:33:11,940
+constant للـ phosphoric acid 10⁻²
+
+382
+00:33:12,800 --> 00:33:16,600
+تعال نشوف هل يمكن إلغاء الـ H⁺ اللي جاي من الـ
+
+383
+00:33:16,600 --> 00:33:20,820
+phosphoric acid ولا لأ، إحنا بنحل يعني عادي، هذه الـ
+
+384
+00:33:20,820 --> 00:33:24,140
+
+445
+00:38:53,440 --> 00:38:56,580
+available H+ فبما أن الـ H+ من الاثنين
+
+446
+00:38:56,580 --> 00:39:00,040
+موجود، بعرفش هذا تبع مين وهذا تبع مين الاثنين
+
+447
+00:39:00,040 --> 00:39:05,390
+موجودين ملخبطين، الـ H+ بتفرج همش عن بعض، وبالتالي
+
+448
+00:39:05,390 --> 00:39:11,350
+عملية المعايرة بتكون عادة one single equivalence
+
+449
+00:39:11,350 --> 00:39:19,290
+point للـاثنين، ماشي يا شباب؟ يعني على
+
+450
+00:39:19,290 --> 00:39:24,390
+سبيل المثال، ممكن نقول لما يكون في عندي two strong
+
+451
+00:39:24,390 --> 00:39:33,700
+acids، أنا في عندي male base hydroxide، خلّيني أقول
+
+452
+00:39:33,700 --> 00:39:38,280
+NaOH
+
+453
+00:39:38,280 --> 00:39:48,900
+pH، بلاحظ أنه ممكن نلاقي حاجة زي هيك أو حاجة زي هيك
+
+454
+00:39:48,900 --> 00:39:53,460
+بحسب جداش كمية الـ two acids، يعني هان الـ end point
+
+455
+00:39:53,460 --> 00:39:58,420
+بتقول لي والله هذا الحجم بكافئ الـ two acids أو هذه
+
+456
+00:39:58,420 --> 00:40:02,900
+المعايرة بتقول لي أن هذا الحجم بكافئ الـ two acids
+
+457
+00:40:02,900 --> 00:40:09,580
+فحسب كمية الـ acid حسب تركيز الـ two acids، أنا عندي
+
+458
+00:40:09,580 --> 00:40:15,480
+مجموعهم هو اللي بيساوي، أو الحجم اللي خاص فيهم الـ
+
+459
+00:40:15,480 --> 00:40:17,860
+millimoles تبعاتهم هي اللي بتساوي الـ millimoles من
+
+460
+00:40:17,860 --> 00:40:22,200
+الـ base، فجداش هذه millimoles كبيرة بتاخد
+
+461
+00:40:22,200 --> 00:40:26,660
+millimoles أكبر من الـ base، ليه؟ لأنه التفكك عندي
+
+462
+00:40:26,660 --> 00:40:31,720
+تفكك كامل، يبقى بنحكيش كتير عن معايرة two strong
+
+463
+00:40:31,720 --> 00:40:37,360
+acids، لأنه بنعملهم وكأنهم إيه؟ one acid، نقدرش نفرج
+
+464
+00:40:37,360 --> 00:40:42,920
+بين البروتونز لو واحد منهم عن الآخر، لكن اللي بدي
+
+465
+00:40:42,920 --> 00:40:50,440
+أحكيه أنا إيش بيحصل لما نعاير mixed strong
+
+466
+00:40:50,440 --> 00:40:53,960
+acid و weak acid، وخلينا ناخد في البداية strong
+
+467
+00:40:53,960 --> 00:41:00,080
+acid زي الـ HCl و weak acid monoprotic زي الـ acetic
+
+468
+00:41:00,080 --> 00:41:07,780
+acid، أنا عندي الـ acetic acid بتفتك بيعطي H+ زائد
+
+469
+00:41:07,780 --> 00:41:14,440
+أسيتات، والـHCl بيعطينا H+ زائد Cl-، فلمّا
+
+470
+00:41:14,440 --> 00:41:21,040
+بدي أجي أعاير، أنا أقول هاي الـ hydroxide وهي الـ
+
+471
+00:41:21,040 --> 00:41:24,460
+pH، إيش اللي بقى لما هدول يكونوا في mixture؟ إيش
+
+472
+00:41:24,460 --> 00:41:30,300
+اللي أنا بعايره بالظبط؟ بقول أنا بعاير الـH+ من
+
+473
+00:41:30,300 --> 00:41:35,610
+الـHCl فقط في البداية، ليه؟ قال لأنه أصلا هذا تفكك
+
+474
+00:41:35,610 --> 00:41:40,270
+قوي، ولما نكون عندنا H+ من هنا جاي راح يقول
+
+475
+00:41:40,270 --> 00:41:45,270
+إذا الـacetic acid حافظة حاله، مش إيه؟ مش متفكك، إذا إيش
+
+476
+00:41:45,270 --> 00:41:48,110
+اللي موجود؟ إيش الـ H+ اللي موجود في المحلول؟ الـ
+
+477
+00:41:48,110 --> 00:41:50,970
+HCl is M، في البداية هناخد
+
+478
+00:41:53,650 --> 00:41:59,170
+الـ HCl، لما نخلص الـ HCl، حد يعاير الـ acetic acid
+
+479
+00:41:59,170 --> 00:42:05,490
+لكن انتهى شوية عند نقطة النهاية، هذا الـ volume
+
+480
+00:42:05,490 --> 00:42:12,070
+equivalent للـ HCl هو
+
+481
+00:42:12,070 --> 00:42:16,910
+الـ volume من الـ hydroxide equivalent للـ HCl، ماشي؟
+
+482
+00:42:16,910 --> 00:42:24,120
+طب عند نقطة النهاية، جداش الـ pH؟ عين نقطة النهاية هان
+
+483
+00:42:24,120 --> 00:42:28,500
+عادي، بعاير عادي، فاش مشكلة، الـ H عمال بيجي لغاية ما
+
+484
+00:42:28,500 --> 00:42:33,200
+وصل لإن كل الـ HCl خلص، عين نقطة النهاية، جداش الـ pH
+
+485
+00:42:35,310 --> 00:42:40,370
+لأ، طبعا مش سبعة، لأن في عندي هنا، خلص الـ ..
+
+486
+00:42:40,370 --> 00:42:45,250
+خلص الـ HCl، إيش صار عندي في المحلول؟ acetic acid
+
+487
+00:42:45,250 --> 00:42:49,770
+إذا عند نقطة النهاية بدي أحسب الـ pH من كمية أو
+
+488
+00:42:49,770 --> 00:42:53,710
+تركيز الـ acetic acid اللي موجود، يبقى عند نقطة ..
+
+489
+00:42:53,710 --> 00:42:57,690
+هذه، فرق عن نقطة النهاية، بكون عندي بس acetic acid
+
+490
+00:42:57,690 --> 00:43:03,020
+إذا بدي أحسب الـ pH من تركيز الـ acetic acid اللي عندي
+
+491
+00:43:03,020 --> 00:43:07,700
+عموما، خلينا نجي في اليوم هان، والحصة الجاية، إذا
+
+492
+00:43:07,700 --> 00:43:12,640
+الله راد، بناخد مثال على هذا النوع من الأمثلة
+
+493
+00:43:12,640 --> 00:43:14,700
+فبنشوفكم الحصة الجاية، إذا الله راد
diff --git a/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/1F-jRJK6PwU.srt b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/1F-jRJK6PwU.srt
new file mode 100644
index 0000000000000000000000000000000000000000..c87fd17c5ee7b4cee4b79ada56f14d38630d8056
--- /dev/null
+++ b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/1F-jRJK6PwU.srt
@@ -0,0 +1,1859 @@
+1
+00:00:20,810 --> 00:00:24,710
+بسم الله الرحمن الرحيم طيب يا شباب اليوم إن شاء
+
+2
+00:00:24,710 --> 00:00:30,250
+الله نبدأ في الـ gravimetric analysis أول chapter
+
+3
+00:00:30,250 --> 00:00:34,710
+تقريباً من الشباتر اللي هناخدها في التحليل الكيميائي
+
+4
+00:00:34,710 --> 00:00:42,190
+الـ gravimetric analysis عادةً بيعالج تقدير قيمة
+
+5
+00:00:42,190 --> 00:00:46,750
+analyte عن طريق تكوين precipitate مع precipitating
+
+6
+00:00:46,750 --> 00:00:50,600
+agent. وبالتالي عند إضافة precipitating agent
+
+7
+00:00:50,600 --> 00:00:55,980
+للـ analyte بيتكون عندنا راسب، الراسب هذا بنأخذه
+
+8
+00:00:55,980 --> 00:01:03,860
+بنرشحه و بنغسله، وبعدين بنجففه أو بنحرقه، وبعدين
+
+9
+00:01:03,860 --> 00:01:11,650
+بنوزنه، ومن وزن الراسب بنقدر نوصل لوزن الـ analyte. على
+
+10
+00:01:11,650 --> 00:01:20,250
+أي حال بنقدر نقول أن الراسب نفسه لابد أن يتميز
+
+11
+00:01:20,250 --> 00:01:25,530
+بخصائص، الراسب نفسه لابد أن يتميز بخصائص، يعني مش
+
+12
+00:01:25,530 --> 00:01:29,530
+أي راسب ممكن أحصل عليه، ممكن نقول والله هذا تفاعل
+
+13
+00:01:29,530 --> 00:01:34,190
+ممكن أستخدمه كـ gravimetric analytical reaction، لأَنَّ
+
+14
+00:01:34,190 --> 00:01:38,270
+مش أي تفاعل بحصل منه على راسب يمكن استخدامه كـ
+
+15
+00:01:38,270 --> 00:01:44,460
+gravimetric analytical reaction، لكن اللي عندي أنا
+
+16
+00:01:44,460 --> 00:01:47,880
+أو التفاعل اللي ممكن أستخدمه كـ gravimetric
+
+17
+00:01:47,880 --> 00:01:52,600
+analytical reaction، بنقول لازم يعطيني precipitate
+
+18
+00:01:52,600 --> 00:01:56,240
+له low solubility، في الحقيقة very low
+
+19
+00:01:56,240 --> 00:02:00,300
+solubility، يعني لأن أي جزء من الراسب اللي بيدوب
+
+20
+00:02:00,300 --> 00:02:03,660
+معناه كلامي أنا ضيعت جزء من الـ analyte وبالتالي مش
+
+21
+00:02:03,660 --> 00:02:07,460
+راح أقدر الـ analyte بشكل دقيق.
+
+22
+00:02:09,380 --> 00:02:13,380
+الخاصية الثانية للـ precipitate أنه بدي يكون له
+
+23
+00:02:13,380 --> 00:02:18,420
+very high purity، ليه؟ لأن أنا من وزن الراسب بدي
+
+24
+00:02:18,420 --> 00:02:23,580
+أعرف وزن الـ analyte، وبالتالي إذا كان مش pure، كيف
+
+25
+00:02:23,580 --> 00:02:27,180
+بدي أعرف وزن الـ analyte؟ ما بيظبط، لازم يكون عندي of
+
+26
+00:02:27,180 --> 00:02:33,540
+very high purity، الـ precipitate. ثالث حاجة بدي الـ
+
+27
+00:02:33,540 --> 00:02:38,550
+precipitate يكون له known composition، known composition
+
+28
+00:02:38,550 --> 00:02:44,370
+يعني formula معروفة، formula معروفة، ليه؟ لأن أنا
+
+29
+00:02:44,370 --> 00:02:47,530
+برضه بدي أستخدم هذه الـ formula عشان أشوف كم
+
+30
+00:02:47,530 --> 00:02:50,790
+millimole من الـ analyte موجود في الـ ... في الـ ... في كل
+
+31
+00:02:50,790 --> 00:02:54,910
+millimole من الـ formula مثلاً، وبالتالي بدي أستخدم هذه الـ
+
+32
+00:02:54,910 --> 00:02:57,910
+formula في عملية الحسابات. إذا كان أنا رسبت مادة
+
+33
+00:02:57,910 --> 00:03:03,090
+لكن المادة اللي رسبتها صح، راسب حلو ممتاز، والكلام ده كله، لكن
+
+34
+00:03:03,090 --> 00:03:06,430
+مش عارف إيش الـ formula تبعته، على الفاضي، ما بقدرش
+
+35
+00:03:06,430 --> 00:03:11,070
+أستخدمه في الحسابات. علشان هيك بدنا يكون له known
+
+36
+00:03:11,070 --> 00:03:16,710
+composition. بقدر أقول إن كمان الراسب يجب أن تكون
+
+37
+00:03:16,710 --> 00:03:25,450
+عملية فصله من مكونات الـ mixture أو الـ reaction
+
+38
+00:03:25,450 --> 00:03:31,400
+mixture عملية سهلة، يعني عملية الترشيح بدها تكون
+
+39
+00:03:31,400 --> 00:03:36,620
+عملية جيدة، يعني الـ particle size للـ precipitates
+
+40
+00:03:36,620 --> 00:03:41,500
+بدها تكون عادة جيدة، اللي أقدر أرشحه بشكل ممتاز. كمان
+
+41
+00:03:41,500 --> 00:03:46,900
+الـ precipitates نفسه لازم يكون ثابت عند atmospheric
+
+42
+00:03:46,900 --> 00:03:50,200
+conditions، يعني في الأحوال العادية، في الأحوال
+
+43
+00:03:50,200 --> 00:03:54,240
+الجوية العادية، ليه؟ لأن التجربة عندي بتستمر لساعات
+
+44
+00:03:55,100 --> 00:03:58,240
+فإذا كان الـ precipitate اللي أنا حصلت عليه مش
+
+45
+00:03:58,240 --> 00:04:04,900
+ثابت، معنى الكلام مش راح أحصل على نتيجة حقيقية، ليه؟
+
+46
+00:04:04,900 --> 00:04:08,240
+لأن جزء من الـ precipitate بده يكون اتكسر أو اتحول
+
+47
+00:04:08,240 --> 00:04:13,460
+لحاجة ثانية، اتفاعل مع الهواء الجوي وما إلى ذلك.
+
+48
+00:04:13,460 --> 00:04:17,140
+فمعنى الكلام هذا بيؤدي لأخطاء، ممكن الأخطاء هذه
+
+49
+00:04:17,140 --> 00:04:21,440
+تكون أخطاء جسيمة للغاية، وتأثر على التحليل بشكل
+
+50
+00:04:21,440 --> 00:04:26,050
+كبير جداً، علشان هيك بنقول أن الـ precipitate يجب أن
+
+51
+00:04:26,050 --> 00:04:32,050
+يكون ثابت at atmospheric conditions، وللفترة زمنية
+
+52
+00:04:32,050 --> 00:04:38,190
+طويلة. في الحقيقة بنقول عموماً يعني الـ gravimetric
+
+53
+00:04:38,190 --> 00:04:43,130
+analysis هو عبارة عن technique بياخد وقت كثير،
+
+54
+00:04:43,130 --> 00:04:52,190
+الوقت اللي بياخده وقت إيه؟ طويل، وقت طويل، لكن
+
+55
+00:04:52,190 --> 00:04:58,660
+مع ذلك يعتبر من أدق الـ analytical methods، إذا كان
+
+56
+00:04:58,660 --> 00:05:02,340
+تم إجراء الـ gravimetric analysis بالشكل الصحيح،
+
+57
+00:05:02,340 --> 00:05:07,160
+فيعتبر من أدق الـ analytical methods، التحليل الوزني
+
+58
+00:05:07,160 --> 00:05:12,820
+يعتبر تحليل مثالي، تحليل دقيق جداً، لكن بشرط أنه
+
+59
+00:05:12,820 --> 00:05:20,300
+يتم عمله بطريقة صحيحة. صحيح هو تكنيك مكلف من ناحية
+
+60
+00:05:20,300 --> 00:05:23,280
+الوقت، بيأخذ وقت طويل جداً، يعني ممكن لما بدنا
+
+61
+00:05:23,280 --> 00:05:26,780
+نشتغل تحليل وزني، نقعد طول اليوم في تحليل واحد
+
+62
+00:05:26,780 --> 00:05:30,900
+فقط، طول اليوم، بينما المعايرة، خمس دقائق، بيكون
+
+63
+00:05:30,900 --> 00:05:35,160
+عملنا معايرتين أو تلاتة مثلاً. التحليل الوزني بياخد
+
+64
+00:05:35,160 --> 00:05:39,880
+تقريباً طول اليوم كمان، يعني التحليل الوزني في
+
+65
+00:05:39,880 --> 00:05:43,940
+الحقيقة يعتبر macro method، macro analytical method.
+
+66
+00:05:43,940 --> 00:05:48,460
+ليه؟ لأن أنا بدي راسب أوزنه، وأنا ما بأخدش بعين الاعتبار
+
+67
+00:05:48,460 --> 00:05:53,440
+إِنه كل ما كان الوزن اللي بدي أوزنه قليل،
+
+68
+00:05:53,440 --> 00:05:57,520
+كان قليل، يبقى الخطأ بيكون كبير، علشان هيك الوزن
+
+69
+00:05:57,520 --> 00:06:03,570
+بيكون مُحسوس. يعني مثلاً نص جرام، مش واحد من ألف ملي
+
+70
+00:06:03,570 --> 00:06:07,370
+جرام، ولا خمسة من ألف ملي جرام، لأ، يكون نص جرام،
+
+71
+00:06:07,370 --> 00:06:10,350
+ستة من عشرة جرام، أربعة من عشرة جرام، ثمانية من
+
+72
+00:06:10,350 --> 00:06:15,190
+عشرة جرام، واحد جرام، هذه أوزان تعتبر إيه؟ كبيرة
+
+73
+00:06:15,190 --> 00:06:18,550
+جداً، معنى الكلام الـ analyte لازم يكون كمية
+
+74
+00:06:18,550 --> 00:06:23,570
+كبيرة، علشان هيك تعتبر إيه زي ما قلت؟ macro
+
+75
+00:06:23,570 --> 00:06:27,540
+analytical method. فلا تستخدم إلا إذا كان وزن
+
+76
+00:06:27,540 --> 00:06:35,320
+الـ analyte عنده وزن كبير نسبياً. كمان ممكن نطلع على
+
+77
+00:06:35,320 --> 00:06:42,180
+الـ gravimetric analysis على إنها بالإضافة لإِنَّها
+
+78
+00:06:42,180 --> 00:06:46,120
+بتأخذ وقت طويل، وبالإضافة لإِنَّها macro analytical
+
+79
+00:06:46,120 --> 00:06:50,840
+method، ممكن نطلع عليها كميزة يعني غريبة، تعتبر في الـ
+
+80
+00:06:50,840 --> 00:06:53,260
+analytical chemistry، لأن في الـ analytical
+
+81
+00:06:53,260 --> 00:06:58,180
+chemistry إحنا عادة بنستخدم standard solution مع
+
+82
+00:06:58,180 --> 00:07:03,180
+solution unknown عشان نقدر الـ unknown بمعلومية الـ
+
+83
+00:07:03,180 --> 00:07:08,140
+standard، لكن للـ gravimetric analysis بنقدر نقول إنه
+
+84
+00:07:08,140 --> 00:07:13,440
+من الـ analytical techniques القليلة التي لا تحتاج
+
+85
+00:07:13,440 --> 00:07:17,320
+إلى standard solution، طب كيف بتعرف الـ unknown فقط
+
+86
+00:07:18,010 --> 00:07:22,450
+بنضيف كمية زيادة من الـ precipitating agent، فكل الـ
+
+87
+00:07:22,450 --> 00:07:27,330
+unknown بترسب، ومن وزن الراسب بعرف كمية الـ unknown.
+
+88
+00:07:27,330 --> 00:07:31,150
+فأنا لست بحاجة إلى standard solutions، وهذا يعني
+
+89
+00:07:31,150 --> 00:07:36,190
+هذا يعتبر ميزة مهمة جداً في الـ gravimetric analysis.
+
+90
+00:07:36,530 --> 00:07:39,390
+فالـ gravimetric analysis لها عيوب، بتأخذ وقت طويل،
+
+91
+00:07:39,390 --> 00:07:48,030
+صحيح، macro method، صحيح، لكن بنقدر نقول إنه لا
+
+92
+00:07:48,030 --> 00:07:53,710
+تحتاج إلى standard solution، هذه تعتبر ميزة يعني
+
+93
+00:07:53,710 --> 00:07:59,050
+ممتازة للغاية، وبرضه كمان ميزة أخرى إنها تعتبر
+
+94
+00:07:59,050 --> 00:08:05,150
+الدقة فيها عالية جداً، إذا كان يعني عملناها بالطريقة
+
+95
+00:08:05,150 --> 00:08:12,240
+الصحيحة. بنقول طيب هل إحنا مضطرين إن يعني نستخدم الـ
+
+96
+00:08:12,240 --> 00:08:16,200
+gravimetry؟ يعني بعض الـ standard methods of
+
+97
+00:08:16,200 --> 00:08:20,460
+analysis بتستخدم ليه gravimetry؟  ليوم يعني بعض
+
+98
+00:08:20,460 --> 00:08:24,820
+الطرق القياسية بتستخدم ليه gravimetry كـ standard
+
+99
+00:08:24,820 --> 00:08:28,190
+technique. علشان هيك بدنا نتعلم الـ gravimetry بشكل
+
+100
+00:08:28,190 --> 00:08:33,270
+كويس، نتعرف كيف نجري الـ procedure بشكل ممتاز، لأنه
+
+101
+00:08:33,270 --> 00:08:37,830
+هي تعتبر في ... لبعض الـ analytes الـ standard method،
+
+102
+00:08:37,830 --> 00:08:41,890
+الدقة تبعها يمكن أنت بتستغرب، يعني لو تصورت أنت
+
+103
+00:08:41,890 --> 00:08:46,670
+الـ atomic weights للعناصر، كيف تم تحديدها؟ كثير من
+
+104
+00:08:46,670 --> 00:08:50,310
+الـ atomic weights اللي بتعتبر من أدق الأرقام اللي
+
+105
+00:08:50,310 --> 00:08:54,350
+عندنا في الكيمياء، الـ atomic weights دقيقة جداً، تم
+
+106
+00:08:54,350 --> 00:08:58,170
+تحديد معظمها أو كثير منها باستخدام الـ gravimetry.
+
+107
+00:08:58,170 --> 00:09:02,550
+كان الـ gravimetry هو التكنيك المشهور لتعيين الـ
+
+108
+00:09:02,550 --> 00:09:07,910
+atomic weights، فالنتيجة طبعاً atomic weights of
+
+109
+00:09:07,910 --> 00:09:12,770
+very high precision، of very high accuracy، فبالفعل
+
+110
+00:09:12,770 --> 00:09:17,170
+بدنا نحس إن الـ gravimetry  كثير كثير كثير ممتازة،
+
+111
+00:09:17,170 --> 00:09:25,550
+كثير دقيقة، كثير مهمة، لكن الشرط إن تعمل بشكل
+
+112
+00:09:25,550 --> 00:09:30,430
+صحيح. فإحنا خلال يعني هذا الـ chapter بدنا نحاول
+
+113
+00:09:30,430 --> 00:09:34,850
+نعرف كيف نعمل الـ gravimetric analysis بالشكل
+
+114
+00:09:34,850 --> 00:09:38,690
+الصحيح، كيف نعمل الـ gravimetric analysis بالشكل
+
+115
+00:09:38,690 --> 00:09:44,030
+الصحيح، علشان يعني نقدم لهذا الموضوع في البداية
+
+116
+00:09:44,030 --> 00:09:50,680
+بنقول إنه كمثال، في عندي بعض الـ analytes وبعض الـ
+
+117
+00:09:50,680 --> 00:09:53,440
+precipitating agents اللي بنضيفه، بيتكون لنا
+
+118
+00:09:53,440 --> 00:10:00,360
+precipitates، وبنتطلع على إيش الشكل اللي بيتم وزنه، والـ
+
+119
+00:10:00,360 --> 00:10:05,040
+column الأخير بيعطي الـ interfering ions، فنجي
+
+120
+00:10:05,040 --> 00:10:09,500
+نطلع مثلاً الـ potassium، الـ potassium لو أضفنا عليه
+
+121
+00:10:09,500 --> 00:10:13,920
+tetraphenyl borate، بتتكون عندي راسب من الـ potassium
+
+122
+00:10:13,920 --> 00:10:19,080
+tetraphenyl borate، هو نفسه، بنغسله وبنجففه وبنوزنه، بنفس
+
+123
+00:10:19,080 --> 00:10:23,320
+الصورة، الـ form اللي طلعته معروفة بهذا الشكل، بنوزنه
+
+124
+00:10:23,320 --> 00:10:28,570
+بنفس الصورة. لكن يا شباب، لو كان عندي أمونيوم،
+
+125
+00:10:28,570 --> 00:10:32,810
+هيعطيني ammonium tetraphenyl borate، لو كان عندي silver،
+
+126
+00:10:32,810 --> 00:10:36,290
+هيعطيني silver tetraphenyl borate، لو كان عندي mercury،
+
+127
+00:10:36,290 --> 00:10:40,090
+لو كان عندي thallium، لو كان عندي rubidium، cesium،
+
+128
+00:10:40,090 --> 00:10:41,190
+كلهم بتداخله.
+
+129
+00:10:44,180 --> 00:10:48,860
+لابد من التخلص من هذه الـ interferences،  وَلا الراسب اللي
+
+130
+00:10:48,860 --> 00:10:53,060
+أنا بحصل عليه، مش فقط للـ analyte، مش بس للبوتاسيوم،
+
+131
+00:10:53,060 --> 00:10:57,540
+لأ، لكل اللي موجود معاه، إذا عندي خطأ جسيم للغاية،
+
+132
+00:10:58,360 --> 00:11:02,500
+معايا، إذا لازم أفصل البوتاسيوم لوحده قبل ما أجري
+
+133
+00:11:02,500 --> 00:11:08,780
+عملية الترسيب. مثلاً المغنيسيوم معروف بيرسب على هيئة
+
+134
+00:11:08,780 --> 00:11:12,980
+magnesium ammonium phosphate، لكن هذا الشكل عادة
+
+135
+00:11:12,980 --> 00:11:18,020
+فيه كمية من المية، لو إحنا جففناه ممكن تصير خمسة، ممكن تصير أربعة، ممكن تصير تلاتة، طب قد إيش هي
+
+136
+00:11:18,020 --> 00:11:21,460
+بالضبط؟ مش عارفين إحنا، علشان هيك ما بقدرش أستخدم الـ
+
+137
+00:11:21,460 --> 00:11:25,700
+formula هذه للحسابات. لهذا السبب إيش بعمل؟ بأحرق هذا
+
+138
+00:11:25,700 --> 00:11:31,810
+المركب، بيتكون عندي magnesium pyrophosphate، P2O7،
+
+139
+00:11:31,810 --> 00:11:37,990
+هذا الشكل ثابت، معروف، بقدر أوزنه، ومن وزنه بقدر
+
+140
+00:11:37,990 --> 00:11:44,130
+أجيب قد إيش عندي magnesium. مثلاً لو طلعنا على الـ
+
+141
+00:11:44,130 --> 00:11:49,130
+barium، تجربة هتأخدها في المختبر، الـ barium بنضيف
+
+142
+00:11:49,130 --> 00:11:52,450
+عليه سلفات، بتتكون عندنا راسب barium sulfate، الـ barium
+
+143
+00:11:52,450 --> 00:11:55,990
+sulfate فيها خيارين، هي ثابتة upon drying، يعني ممكن
+
+144
+00:11:55,990 --> 00:12:01,700
+توزنها على هيئة barium sulfate، أو برضه كتير من الناس
+
+145
+00:12:01,700 --> 00:12:05,680
+بيحبوا يحرقوها أسرع، يحولوها لـ barium sulfate، فبده
+
+146
+00:12:05,680 --> 00:12:12,100
+خيارين، إما إنك تعملها drying وإما إنك تحرقها،
+
+147
+00:12:12,100 --> 00:12:17,440
+الاتنين جيدين.
+
+148
+00:12:17,440 --> 00:12:19,020
+الاتنين جيدين.
+
+149
+00:12:21,300 --> 00:12:26,000
+ففيه عندنا، لكن كل مرة بنلاحظ إنه أي تحليل فيه
+
+150
+00:12:26,000 --> 00:12:30,720
+عندنا interfering ions، علشان هيك يعني مكلف جداً إنّه
+
+151
+00:12:30,720 --> 00:12:33,640
+نعمل عملية separation، مكلف جداً، يعني لازم نأخد
+
+152
+00:12:33,640 --> 00:12:37,840
+بالنا، لأنه إحنا إذا كان أخطأنا وما أخدناش بالنا من
+
+153
+00:12:37,840 --> 00:12:41,980
+الـ interference، هتتحول للراسب وأنا ما بعرفش يعني
+
+154
+00:12:41,980 --> 00:12:45,320
+الراسب اللي حصلت عليه، بفترض إنه راسب للـ analyte
+
+155
+00:12:46,190 --> 00:12:49,630
+مع الـ precipitating agent، وبده يحل على هذا الأساس،
+
+156
+00:12:49,630 --> 00:12:54,790
+لكن هل الحل هيكون حل صحيح؟ بالطبع مش حل صحيح
+
+157
+00:12:54,790 --> 00:13:00,950
+ نهائياً، ليه؟ لأن الراسب بيحتوي على أكتر من حاجة، مش
+
+158
+00:13:00,950 --> 00:13:06,850
+شرط أن الـ precipitating agent يكون inorganic، يعني
+
+159
+00:13:06,850 --> 00:13:12,870
+مثلاً الـ silver أرسبها بالـ chloride، الـ barium
+
+160
+00:13:12,870 --> 00:13:16,150
+أرسبها بالـ sulfate، الـ calcium أرسبها بالـ carbonate، أو
+
+161
+00:13:16,150 --> 00:13:20,630
+الأمور دي. مش شرط إنه يكون الـ precipitating agent
+
+162
+00:13:20,630 --> 00:13:26,310
+دائماً inorganic، لأ، ممكن يكون organic، فهذه حاجة
+
+163
+00:13:26,310 --> 00:13:30,750
+يقولها، مثلاً 8-hydroxyquinoline مع المغنيسيوم بيعطيني
+
+164
+00:13:30,750 --> 00:13:37,840
+راسب magnesium 8-hydroxyquinolate، ممكن تكون الجزيئة
+
+165
+00:13:37,840 --> 00:13:42,480
+organic، لكن الصيغة هي صيغة معروفة، بقدر آخدها،
+
+166
+00:13:42,480 --> 00:13:47,740
+أوزنها، ومن قيمة الوزن أطلع قد إيش في عندي مثلاً
+
+167
+00:13:47,740 --> 00:13:52,040
+مغنيسيوم. أيضاً تجربة هتأخدها في المختبر، إذا الله
+
+168
+00:13:52,040 --> 00:13:58,160
+راضى النيكل كيف بنعينه؟ بنضيف عليه organic
+
+169
+00:14:05,850 --> 00:14:10,050
+النيكل بياخد اتنين من dimethylglyoxime، وبيعطينا
+
+170
+00:14:10,050 --> 00:14:18,690
+nickel dimethylglyoxime، برضه هذا راسب أحمر تقريباً زي
+
+171
+00:14:18,690 --> 00:14:22,410
+المناكير، وريحته كمان ريحة مناكير، هتأخده في
+
+172
+00:14:22,410 --> 00:14:27,390
+المختبر، وتعيين الـ nickel باستخدام dimethyl
+
+173
+00:14:27,390 --> 00:14:30,830
+glyoxime، فمش شرط إن الـ precipitating agent يكون
+
+174
+00:14:30,830 --> 00:14:38,090
+دائماً inorganic، لأ، ممكن يكون organic أيضاً. طيب يا
+
+
+223
+00:18:04,020 --> 00:18:10,260
+جراب مثلاً، فبدي كمية الـanalyte المستخدَمة تعطيني
+
+224
+00:18:10,260 --> 00:18:13,540
+هذه الكمية تسألني: كمية الـanalyte تعطيني؟ أو خمسة
+
+225
+00:18:13,540 --> 00:18:19,480
+جراب، ولا عشرة جرابات، إذا لازم أُثبت الحجم.. لازم أُثبت
+
+226
+00:18:19,480 --> 00:18:24,880
+الحجم من الـanalyte اللي ممكن يعطيني
+
+227
+00:18:28,800 --> 00:18:36,900
+كمية كافية، أو جيدة، أو مناسبة من الـprecipitate قد
+
+228
+00:18:36,900 --> 00:18:40,480
+يكون في هناك شغلات إضافية ممكن أضيفها لـ
+
+229
+00:18:40,480 --> 00:18:44,120
+preparation of the solution، لكن يمكن هذه أهم
+
+230
+00:18:44,120 --> 00:18:48,440
+الحاجات اللي ممكن تواجهنا أول خطوة إذن، preparation
+
+231
+00:18:48,440 --> 00:18:53,200
+of the solution. حضرنا المحلول، الآن بدي أبدأ أعمل
+
+232
+00:18:53,200 --> 00:18:59,150
+عملية precipitation. بقول عملية الـprecipitation
+
+233
+00:18:59,150 --> 00:19:05,210
+عملية مش سهلة، مش سهلة، وهي أهم عملية، هي الـheart، هي
+
+234
+00:19:05,210 --> 00:19:09,790
+قلب الـgravimetric analysis. الحقيقة بقول بدي أجي
+
+235
+00:19:09,790 --> 00:19:12,590
+في البداية، أضيف الـprecipitating agent على
+
+236
+00:19:14,320 --> 00:19:18,200
+الـanalyte solution. بقول لما أضيف نقطة ولا نقطتين،
+
+237
+00:19:18,200 --> 00:19:23,200
+بلاحظ أنه فيش عندي أي راسب لسه، فيش راسب، طب هي وين
+
+238
+00:19:23,200 --> 00:19:27,980
+راحوا اللي أضفتهم. جال في البداية بتكون عندي
+
+239
+00:19:27,980 --> 00:19:34,760
+saturated solution، أو حتى super saturated solution.
+
+240
+00:19:34,760 --> 00:19:39,780
+مدام اتكون عندي محلول مشبع أو فوق مشبع، آه، طب الآن
+
+241
+00:19:39,780 --> 00:19:44,670
+أول نقطة إضافية بضيفها، بقول في البداية لسه ما بتكونش
+
+242
+00:19:44,670 --> 00:19:52,990
+راسب كمان، هايش، بتكون كلب، بتكون الـnuclei، أنوية، حجر
+
+243
+00:19:52,990 --> 00:19:56,870
+الأساس للراسب، لسه مش الراسب، إيش الأنوية؟ عملية
+
+244
+00:19:56,870 --> 00:20:00,990
+بنقولها الـnucleation، إيش هي الـnucleation؟ قال
+
+245
+00:20:00,990 --> 00:20:06,310
+والله أربع خمس أيونات من الـprecipitating agent مع
+
+246
+00:20:06,310 --> 00:20:12,180
+أربع خمس أيونات من الـanalyte بيكونوا نواة، هو حجر
+
+247
+00:20:12,180 --> 00:20:17,560
+أساس للراسب، و 4 أو 5 أيونات من الراسب من الـ
+
+248
+00:20:17,560 --> 00:20:24,880
+precipitating agent مع 4 أو 5 أيونات من الـanalyte
+
+249
+00:20:24,880 --> 00:20:30,140
+بيعطوني نواة، ونواة، ونواة، ونواة، ونواة، ونواة، ونواة، و
+
+250
+00:20:30,140 --> 00:20:30,580
+نواة، ونواة، ونواة، ونواة، ونواة، ونواة، ونواة، ونواة، و
+
+251
+00:20:30,580 --> 00:20:30,660
+نواة، ونواة، ونواة، ونواة، ونواة، ونواة، ونواة، ونواة، و
+
+252
+00:20:30,660 --> 00:20:30,720
+نواة، ونواة، ونواة، ونواة، ونواة، ونواة، ونواة، ونواة، و
+
+253
+00:20:30,720 --> 00:20:31,200
+نواة، ونواة، ونواة، ونواة، ونواة، ونواة، ونواة، ونواة، و
+
+254
+00:20:31,200 --> 00:20:37,810
+نواة، ونواة، ونواة، ونواة.. لسه ما يتكون الراسب، لأن
+
+255
+00:20:37,810 --> 00:20:40,570
+نيوكلياها دي لا تُرى بالعين المجردة، ولا بيقدر
+
+256
+00:20:40,570 --> 00:20:45,630
+يمسكها أحسن فلتر.
+
+257
+00:20:45,630 --> 00:20:50,630
+لأ، لو فلترتها كلها، بنزل محلول، لكن هي عبارة عن
+
+258
+00:20:50,630 --> 00:20:54,250
+particles دقيقة جداً جداً جداً، متناهية في
+
+259
+00:20:54,250 --> 00:20:57,010
+الصغر، عشان هيك بنقولها نيوكليا، عملياً بنقولها
+
+260
+00:20:57,010 --> 00:21:03,410
+nucleation. طب أضفت كمان، إيش بده يحصل؟ قال في عندي
+
+261
+00:21:03,410 --> 00:21:08,440
+أحد خيارين: يا إما بحصل عندي further nucleation،
+
+262
+00:21:08,440 --> 00:21:11,740
+الـnucleation زي اللي شفته قبل شوية، يا إما
+
+263
+00:21:11,740 --> 00:21:16,660
+particle growth، واحد من اثنين، يا بحصل عندنا
+
+264
+00:21:16,660 --> 00:21:20,520
+further nucleation، يا بحصل عندنا particle
+
+265
+00:21:20,520 --> 00:21:24,220
+growth، نمو للـparticle، طب إيش اللي بحكم هذا
+
+266
+00:21:24,220 --> 00:21:27,980
+الكلام، بدا ما عندي خيارين، إيش اللي بحكمه؟ قال،
+
+267
+00:21:27,980 --> 00:21:34,070
+قال اللي بحكمه حاجة بيقولها von Weimann ratio، هذا
+
+268
+00:21:34,070 --> 00:21:40,390
+الـratio هي عبارة عن relative supersaturation،
+
+269
+00:21:40,390 --> 00:21:45,490
+بحيث إنه إذا كان الـrelative supersaturation
+
+270
+00:21:45,490 --> 00:21:50,060
+قليلة، بحصل على particle growth. إذا كان
+
+271
+00:21:50,060 --> 00:21:54,720
+الـrelative supersaturation كبيرة، بحصل على further
+
+272
+00:21:54,720 --> 00:21:59,840
+nucleation. أنا بالطبع بدي أحصل على، أو بحب أحصل
+
+273
+00:21:59,840 --> 00:22:03,740
+على particle growth، بدي particles، بدي precipitates،
+
+274
+00:22:03,740 --> 00:22:09,280
+فإذا بدي أخلي الـrelative supersaturation أقل ما
+
+275
+00:22:09,280 --> 00:22:12,920
+يمكن، طب إيش هي relative supersaturation هذه؟ مدينة
+
+276
+00:22:12,920 --> 00:22:17,000
+بتأثرها لجد، قال الـrelative supersaturation بتساوي
+
+277
+00:22:17,000 --> 00:22:25,340
+Q ناقص S على S، إيش الـQ؟ قال الـQ هي الـreactant
+
+278
+00:22:25,340 --> 00:22:29,280
+concentrations، تركيز الـreactants، إيش هي الـ
+
+279
+00:22:29,280 --> 00:22:33,520
+reactants؟ الـprecipitating agent والـanalyte، جداش
+
+280
+00:22:33,520 --> 00:22:39,120
+تركيزاتهم، طب الـS؟ قال الـS هي solubility of
+
+281
+00:22:39,120 --> 00:22:42,520
+precipitate in the medium، في الوسط اللي عمال
+
+282
+00:22:42,520 --> 00:22:45,920
+بيترسب منه، in the medium، يبقى هي solubility للـ
+
+283
+00:22:45,920 --> 00:22:49,110
+precipitate. طيب معنى الكلام، للـrelative
+
+284
+00:22:49,110 --> 00:22:53,030
+supersaturation عبارة عن function في حاجتين، في الـ
+
+285
+00:22:53,030 --> 00:22:55,570
+Q وفي الـS، وأنا بدي الـrelative supersaturation
+
+286
+00:22:55,570 --> 00:22:59,490
+يكون أقل ما يمكن، كم يكون أقل ما يمكن؟ قال والله الـ
+
+287
+00:22:59,490 --> 00:23:04,150
+Q بدها تكون أقل ما يمكن، والـS بدها تكون إيه؟ أكبر
+
+288
+00:23:04,150 --> 00:23:07,370
+ما يمكن، هاي الحاجتين اللي بدنا نأخذ بالنا منهم
+
+289
+00:23:07,370 --> 00:23:14,140
+أثناء عملية الترسيب، إذا بدي أخلي الـQ أقل ما يمكن،
+
+290
+00:23:14,140 --> 00:23:17,040
+بدي أخلي الـS أكبر ما يمكن، كيف بدي أخلي الـQ أكبر
+
+291
+00:23:17,040 --> 00:23:21,020
+ما يمكن؟ في عندي أربعة عوامل بتخلي الـQ أقل ما
+
+292
+00:23:21,020 --> 00:23:26,120
+يمكن، هأقول ثلاثة منهم هالوقت، وواحد بعد شوية، طب
+
+293
+00:23:26,120 --> 00:23:31,220
+والـS كيف بدها تكون أعلى ما يمكن؟ هنشوف الآن، في
+
+294
+00:23:31,220 --> 00:23:37,020
+عندي عوامل تؤثر على الـprecipitation. بنقول أول عامل، و
+
+295
+00:23:37,020 --> 00:23:44,160
+ثاني عامل، وثالث عامل، بيخلوا الـQ أقل ما يمكن، أول
+
+296
+00:23:44,160 --> 00:23:47,500
+عامل، إيش بيقول؟ بيقول الـprecipitation using dilute
+
+297
+00:23:47,500 --> 00:23:51,660
+solutions. مدام الـQ بدي إياها تكون أقل ما يمكن، إذا
+
+298
+00:23:51,660 --> 00:23:55,760
+تركيزات الـreactants، الـprecipitating agent والـ
+
+299
+00:23:55,760 --> 00:24:02,820
+analyte، لازم تكون أقل ما يمكن، يبقى هذا واضح، طيب إيش
+
+300
+00:24:02,820 --> 00:24:05,900
+بيقول لي كمان عامل ثاني؟ بيقول لي الـprecipitating
+
+301
+00:24:05,900 --> 00:24:08,880
+agent ضيفه شوية شوية، slow addition of
+
+302
+00:24:08,880 --> 00:24:12,820
+precipitating agent. ليه؟ لأنه لما أضيفه شوية شوية،
+
+303
+00:24:12,820 --> 00:24:17,960
+معناته التركيز بيكون قليل، التركيز نسبياً بيكون قليل.
+
+304
+00:24:17,960 --> 00:24:21,540
+ليه؟ لأنه أنا ما بضيفوش كل مرة واحدة، تركيز عالي، لأ،
+
+305
+00:24:21,540 --> 00:24:26,240
+بضيف شوية شوية منه، هذا بيحفظ الـQ قليلة.
+
+306
+00:24:27,710 --> 00:24:32,570
+العامل الثالث اللي بقدر أستخدمه، أنه الإضافة شوية
+
+307
+00:24:32,570 --> 00:24:36,370
+شوية، آه، لكن مع التحريك، عشان حق النقطة لما بتيجي
+
+308
+00:24:36,370 --> 00:24:41,470
+تلامس الـanalyte، اسمها تركيزها عادي، لما أنا إيه؟
+
+309
+00:24:41,470 --> 00:24:46,670
+أحرك بسرعة، معنى الكلام، بتتشر في كل المحلول، بجه
+
+310
+00:24:46,670 --> 00:24:51,170
+التركيز صار أقل ما يمكن، هذه الثلاث حاجات بأخذ بالي
+
+311
+00:24:51,170 --> 00:24:55,630
+منها أثناء عملية الترسيب، عشان أُقلل الـQ. في عامل
+
+312
+00:24:55,630 --> 00:25:03,580
+رابع، بعد شوية هنقوله، في نمرة 7 من هذه العوامل، خلصنا
+
+313
+00:25:03,580 --> 00:25:08,140
+من الـQ مؤقتاً، والآن نريد أن نزود الـsolubility،
+
+314
+00:25:08,140 --> 00:25:12,200
+كيف نزود الـsolubility؟ لأن الحرارة بتزيد الـ
+
+315
+00:25:12,200 --> 00:25:17,080
+solubility، لذا بقول precipitation from hot
+
+316
+00:25:17,080 --> 00:25:23,690
+solution، لازم أكون مسخن الـsolution، لازم، ليه؟
+
+317
+00:25:23,690 --> 00:25:28,130
+لأنه، بدأ يكون سخن، ليه؟ لأن عملية التسخين تزيد من
+
+318
+00:25:28,130 --> 00:25:31,810
+قيمة الـS، الـsolubility، طبعاً لما نتكلم عن زيادة
+
+319
+00:25:31,810 --> 00:25:35,410
+الـsolubility، ما نتكلمش عن أن الـsolubility تصير لها
+
+320
+00:25:35,410 --> 00:25:39,670
+مثلاً عشرة ولا عشرين في المئة، ما أحكيش ده، هيك، عشرة
+
+321
+00:25:39,670 --> 00:25:41,310
+ولا عشرين في المئة، يعني عشرة ولا عشرين في المئة من
+
+322
+00:25:41,310 --> 00:25:45,850
+الـanalyte راحوا، لا، ما بنحكيش عن solubility يعني زيادة
+
+323
+00:25:45,850 --> 00:25:48,430
+في الـsolubility لهذه الدرجة، لا، بنحكي عن مثلاً
+
+324
+00:25:48,430 --> 00:25:54,070
+solubility على سبيل المثال 1 من 10%، معايا، يعني هذه
+
+325
+00:25:54,070 --> 00:26:00,410
+تُعتبر زيادة من مثلاً 1 من 1000% أو 1000% لـ1 من 10
+
+326
+00:26:00,410 --> 00:26:06,190
+زيادة كبيرة، لكن مش بنتكلم عن زيادة 10% ولا 20%، لأ،
+
+327
+00:26:06,190 --> 00:26:10,310
+لأنه هيك بنكون ضيعنا الراسب، فاحنا بدنا إياها، بدنا
+
+328
+00:26:10,310 --> 00:26:14,610
+التفاعل يكون complete، يعني كله يتحول لراسب، فلما
+
+329
+00:26:14,610 --> 00:26:17,630
+نتكلم عن زيادة الـsolubility، مش هذه الزيادة اللي
+
+330
+00:26:17,630 --> 00:26:20,990
+بتفكر فيها، يعني نخلي.. احنا بإمكاننا نخلي كل
+
+331
+00:26:20,990 --> 00:26:26,090
+الراسب يدوب، يعني لو أنا مرسب مثلاً calcium على هيئة
+
+332
+00:26:26,090 --> 00:26:31,100
+calcium carbonate، حط عليها شوية acid وهي بتدوب
+
+333
+00:26:31,100 --> 00:26:35,920
+مثلاً معايا، ولا لأ؟ احنا ما بدناش هيك، بدنا الـsolubility تكون
+
+334
+00:26:35,920 --> 00:26:39,820
+عالية، لكن عالية يعني جداش، يعني مثلاً واحد من
+
+335
+00:26:39,820 --> 00:26:44,080
+عشرة في المئة، maximum بس.
+
+336
+00:26:44,080 --> 00:26:50,540
+هذا ماشي، بس السكر مش precipitate، السكر مش
+
+337
+00:26:50,540 --> 00:26:54,480
+precipitate، السكر بيدوب في المية، فهذا عبارة عن
+
+338
+00:26:54,480 --> 00:26:58,020
+saturated solution أو super saturated solution، مش
+
+339
+00:26:58,020 --> 00:27:03,600
+راسب. بنقول كمان عشان أُزيد الـsolubility، ممكن أ
+
+340
+00:27:03,600 --> 00:27:07,820
+adjust الـpH. بجهز سبب ثاني للـpH، أول حاجة الـpH
+
+341
+00:27:07,820 --> 00:27:10,800
+بنظبطه عشان التفاعل يكون quantitative، لأن بعض
+
+342
+00:27:10,800 --> 00:27:14,520
+التفاعلات بتكونش quantitative إلا عند pH معينة،
+
+343
+00:27:14,520 --> 00:27:21,620
+وهذا سبب ثاني أن الـpH بتزيد الـsolubility. الـpH
+
+344
+00:27:21,620 --> 00:27:24,180
+يعني إيش؟ الـpH بالزود solubility؟ يعني الـpH
+
+345
+00:27:24,180 --> 00:27:30,180
+قليلة ولا كتيرة؟ بنقول في معظم الأحيان، إذا الـpH
+
+346
+00:27:30,180 --> 00:27:34,200
+بدي يكون لها تأثير، في معظم الأحيان، at low pH
+
+347
+00:27:34,200 --> 00:27:38,460
+الـsolubility بتزيد، في معظم الأحيان، لكن هذا مش دائماً
+
+348
+00:27:38,460 --> 00:27:42,020
+يا شباب، فاحنا بدنا نقول، عشان هيك إيش بنقول؟ adjust
+
+349
+00:27:42,020 --> 00:27:45,960
+the pH، يعني بدنا نحاول نظبط الـpH بحيث أنه نزيد الـ
+
+350
+00:27:45,960 --> 00:27:49,600
+solubility، وكمان مرة، زيادة الـsolubility مش
+
+351
+00:27:49,600 --> 00:27:52,480
+معناتها عشرة، عشرين، ثلاثين في المئة، لأ، في حدود
+
+352
+00:27:52,480 --> 00:27:58,710
+الواحد من عشرة في المئة، مش أكثر من هيك. الحاجة قبل
+
+353
+00:27:58,710 --> 00:28:04,670
+الأخيرة فيما يتعلق بـprecipitation process نفسها،
+
+354
+00:28:04,670 --> 00:28:10,030
+أن والله بدنا نضيف كمية زايدة شوية، little excess
+
+355
+00:28:10,030 --> 00:28:13,910
+من الـprecipitating agent، وبدنا نقول ليش هذا
+
+356
+00:28:13,910 --> 00:28:22,170
+الكلام، أنا في عندي هي الراسب بتكون مثلاً، وليكن
+
+357
+00:28:22,170 --> 00:28:28,890
+barium sulfate. بحط أنا الـsulfate على الـbarium، فبتكون
+
+358
+00:28:28,890 --> 00:28:33,510
+عندي barium sulfate، طب هل الـsulfate اللي أضفتها كافية
+
+359
+00:28:33,510 --> 00:28:38,930
+ولا غير كافية؟ مش عارف أنا إيش أعمل، قال بضيف نقطة
+
+360
+00:28:38,930 --> 00:28:43,070
+من الـsulfate، بعد ما المحلول يترجح، يصير clear، بضيف
+
+361
+00:28:43,070 --> 00:28:46,790
+نقطة من الـsulfate على إيه؟ على الجدار، فتنزل على
+
+362
+00:28:46,790 --> 00:28:51,010
+الجدار، والله إذا كان تكون هناك راسب، معناته لسه
+
+363
+00:28:51,010 --> 00:28:55,920
+بدها، ما تكونش عندي راسب، إذن خلاص، لو جالي راسب، هبقى
+
+364
+00:28:55,920 --> 00:28:59,960
+أضيف لي كمان كم مل من الـsulfate لغاية ما أنا
+
+365
+00:28:59,960 --> 00:29:04,120
+ما أحصلش على أي راسب، بهان، عشان أتأكد أنه خلاص
+
+366
+00:29:04,120 --> 00:29:08,380
+التفاعل تم مئة في المئة، كمان أضيف ثلاث أربع
+
+367
+00:29:08,380 --> 00:29:12,720
+نقاط من الـsulfate، الزيادة ليه؟ لأنه عندي أنا الـ
+
+368
+00:29:12,720 --> 00:29:19,260
+barium زائد الـsulfate، barium
+
+369
+00:29:19,260 --> 00:29:23,510
+sulfate solid. أنا لو زودت الـsulfate، إيش بيحصل للـ
+
+370
+00:29:23,510 --> 00:29:26,910
+equilibrium؟ بنشد حياتي الـbarium، يعني كمية الـ
+
+371
+00:29:26,910 --> 00:29:30,690
+barium اللي باقية، مش مترسبة، بتكون مهملة، فالتفاعل
+
+372
+00:29:30,690 --> 00:29:35,490
+بيكون تقريباً quantitative، فأنا دائماً لازم أضيف
+
+373
+00:29:35,490 --> 00:29:40,450
+little excess من الـprecipitating agent، ماشي يا
+
+374
+00:29:40,450 --> 00:29:48,330
+جماعة؟ طيب نيجي نتطلع الآن على آخر عامل بيأثر على
+
+375
+00:29:48,330 --> 00:29:53,290
+الـprecipitation process، وهذا العامل له علاقة برضه
+
+376
+00:29:53,290 --> 00:29:58,010
+بالـQ، لأن احنا قلنا في عندنا أربعة عوامل اللي لها
+
+377
+00:29:58,010 --> 00:30:02,570
+علاقة بالـQ، ذكرنا ثلاثة منها، وقلنا هنتكلم عن
+
+378
+00:30:02,570 --> 00:30:06,270
+الرابع بعدين، هالوقت، إيجي معادلة وبنقول
+
+379
+00:30:06,270 --> 00:30:12,450
+precipitation from homogeneous solution، وبقول بين
+
+380
+00:30:12,450 --> 00:30:18,590
+جثتين، ممكن نحطه، if possible، إن أمكن، بعض الـreactions،
+
+381
+00:30:18,590 --> 00:30:22,870
+الـprecipitation reactions يا شباب، بتأدي لرواسب،
+
+382
+00:30:22,870 --> 00:30:31,410
+الرواسب هذه gelatinous أو colloidal، غروية أو
+
+383
+00:30:31,410 --> 00:30:36,010
+gelatinous، يعني جيلاتينية، الـparticle size بيكون
+
+384
+00:30:36,010 --> 00:30:40,270
+صغير للغاية، الـparticle size بيكون صغير للغاية،
+
+385
+00:30:40,270 --> 00:30:46,240
+عشان هيك ما بعرفش أرشحها، بتغلبني كتير، هل في طريقة أن
+
+386
+00:30:46,240 --> 00:30:51,180
+نَخلّي الـparticle size أكبر؟ بنقول والله إن أمكن أن
+
+387
+00:30:51,180 --> 00:30:55,900
+نُرسب from homogeneous solution، بكون هذا كلام ممتاز
+
+388
+00:30:55,900 --> 00:30:59,200
+جداً، لما نقول homogeneous أو precipitation from
+
+389
+00:30:
+
+445
+00:35:42,670 --> 00:35:48,290
+بتقدرش تدوب، والأيونات تتجمع في المحلول، لا بتدوب
+
+446
+00:35:48,290 --> 00:35:51,630
+نفس الوجه بتترسم ليه؟ لأن هذا equilibrium يعني
+
+447
+00:35:51,630 --> 00:35:56,110
+مثلاً الـ AgCl بتعطيني Ag+ و Cl− لكن
+
+448
+00:35:56,110 --> 00:35:59,590
+المحلول مشبع بالـ Ag+ و Cl− عشان هيك
+
+449
+00:35:59,590 --> 00:36:04,350
+ببلش هدول اللي اتفككوا جديد بيجيني Ag+ و Cl−
+
+450
+00:36:04,350 --> 00:36:08,070
+ اللي بيترسبوا. الفكرة إيه؟ الفكرة أن الـ
+
+451
+00:36:08,070 --> 00:36:11,810
+particle الصغير عالماية بيدوب. طيب، والأيونات وإيش
+
+452
+00:36:11,810 --> 00:36:16,620
+بيحصلها؟ بتبدأ تترسب، ترسب على particle أكبر، فالصغير
+
+453
+00:36:16,620 --> 00:36:20,900
+مع الوقت، مع الحرارة، الصغير عمال بيدوب وبيصغر، و
+
+454
+00:36:20,900 --> 00:36:24,820
+الكبير عمال بيكبر، مع الوقت، الصغير بيختفي، و
+
+455
+00:36:24,820 --> 00:36:28,200
+الكبير إيش بِصِيره؟ بيكبر. هذه أول حاجة بنقولها
+
+456
+00:36:28,200 --> 00:36:32,620
+Ostwald ripening، Ostwald ripening،  المُضجّ Ostwald
+
+457
+00:36:32,620 --> 00:36:37,920
+عالم. هذا بنسميه حسب افتراض السيد Ostwald بنسميه
+
+458
+00:36:37,920 --> 00:36:42,800
+إحنا من بعده Ostwald ripening. فالـ AgCl زي ما
+
+459
+00:36:42,800 --> 00:36:47,480
+إحنا شايفين، الصغير عمال بيصغر والكبير عمال إيش
+
+460
+00:36:47,480 --> 00:36:51,940
+بيكبر. هذا الكلام بينشأ عنه particles كبيرة، مش بس
+
+461
+00:36:51,940 --> 00:36:57,200
+هيك. الحرارة إيش بتعمل؟ بتخلي حركة الـ particles أسرع
+
+462
+00:36:57,200 --> 00:37:03,000
+معنى الكلام، ممكن two particles يخبطوا في بعض نتيجة
+
+463
+00:37:03,000 --> 00:37:07,220
+الحرارة، إيش بيحصل لهم؟ بلتزجوا، يبقى في عندي حاجة
+
+464
+00:37:07,220 --> 00:37:11,300
+بنسميها agglomeration أو coagulation، coagulation،
+
+465
+00:37:11,300 --> 00:37:17,400
+تجمع، agglomeration برضه تجميع، تجمع، كويس. فمش بس
+
+466
+00:37:17,400 --> 00:37:20,940
+أنه الصغير بيصغر وبيتلآشى، والكبير بيكبر، لأ، و
+
+467
+00:37:20,940 --> 00:37:24,520
+كمان الكبير بيكبر كتير نتيجة؟ التصادم والـ
+
+468
+00:37:24,520 --> 00:37:28,280
+agglomeration اللي بيحصل عنها. عملية الـ digestion
+
+469
+00:37:28,280 --> 00:37:35,760
+عملية كتير كتير كتير مفيدة ومهمة في الـ
+
+470
+00:37:35,760 --> 00:37:39,420
+Gravimetric Analysis. يعني لازم... مادام بدنا نعمل الـ
+
+471
+00:37:39,420 --> 00:37:41,660
+Gravimetric Analysis لازم نعمل الـ digestion
+
+472
+00:37:41,660 --> 00:37:46,280
+العملية هي بتقلل نسبة الراسب. ليش بتقلل نسبة
+
+473
+00:37:46,280 --> 00:37:50,560
+الراسب؟ لأن الـ equilibrium إيش بيقول؟ هذا مفهوم الـ
+
+474
+00:37:50,560 --> 00:37:54,680
+equilibrium. لما يكون الراسب  يدوب، بتصيرش في عندي أيونات
+
+475
+00:37:54,680 --> 00:37:57,800
+دايماً في المحلول. لإنه في نفس الوقت اللي بيدوب جزء
+
+476
+00:37:57,800 --> 00:38:01,880
+من الراسب، نفس الكمية بالضبط بتترسب، لإنه عندي
+
+477
+00:38:01,880 --> 00:38:05,760
+equilibrium. فهي معنى الإتزان، فبتأثرش على الراسب
+
+478
+00:38:05,760 --> 00:38:13,480
+نهائياً. طيب يا شباب، ننتقل لمرحلة الرابعة، الـ
+
+479
+00:38:13,480 --> 00:38:18,020
+filtration وبعدين الـ washing. filtration و washing
+
+480
+00:38:18,020 --> 00:38:22,920
+بنِيجي، بدنا نعمل filtration لأن الراسب عندي جاهز
+
+481
+00:38:23,910 --> 00:38:28,970
+الراسب نزل، المحلول ترسب بالطريقة الصحيحة. اعمل الـ
+
+482
+00:38:28,970 --> 00:38:32,810
+digestion. الآن الراسب خلاص نزل تحت في قاع الـ
+
+483
+00:38:32,810 --> 00:38:38,650
+beaker كويس وجاهز لعملية الترشيح.  باشي، بدي أرشحه كيف؟
+
+484
+00:38:38,650 --> 00:38:45,000
+أرشحه؟ قال والله خذوا بالكم، مش عشوائي الشغل، لأ، بقول
+
+485
+00:38:45,000 --> 00:38:49,780
+هذه بتوقف على نوع الراسب. إذا كان الراسب يكفي فقط
+
+486
+00:38:49,780 --> 00:38:54,560
+عملية drying علشان أحصل على نوع formula، إذا ممكن
+
+487
+00:38:54,560 --> 00:38:59,680
+أرشحه باستخدام حاجة بقولها  Gooch
+
+488
+00:39:07,950 --> 00:39:16,430
+هذا عبارة عن قمع من الزجاج موجود، زي fritted glass
+
+489
+00:39:16,430 --> 00:39:22,790
+هذه fritted، fritted حاجة زي الفلتر يعني، الزجاج مكسر
+
+490
+00:39:22,790 --> 00:39:27,630
+هيك، عامل زي الفلتر. ما بيدخلش أيّ، ما بيدخلش الـ solids يعني
+
+491
+00:39:27,630 --> 00:39:31,270
+من خلاله، أو الـ precipitates. المحلول طبعاً سهل جداً
+
+492
+00:39:31,270 --> 00:39:35,290
+أنه ينزل، لكن الـ solids بيحفظها. فممكن تلاقي شكلها
+
+493
+00:39:35,290 --> 00:39:37,150
+زي هيك، أو تلاقي
+
+494
+00:39:40,500 --> 00:39:46,700
+شكلها زي هيك سيئة يعني. هذه اسمها Gooch. طبعاً الـ Gooch
+
+495
+00:39:46,700 --> 00:39:50,580
+بتيجي بأرقام. ممكن Gooch number one، Gooch number two،
+
+496
+00:39:50,580 --> 00:39:53,720
+Gooch number three، Gooch number four. لإنه هذا بيوقف
+
+497
+00:39:53,720 --> 00:39:58,960
+على الـ porosity، المفاذية يعني، أو المسامية للـ frit
+
+498
+00:39:58,960 --> 00:40:02,020
+فممكن
+
+499
+00:40:02,020 --> 00:40:07,500
+لو دخلت معك particles غير،  غيّر الـ Gooch. خذ frit تكون
+
+500
+00:40:07,500 --> 00:40:13,700
+أدقّ. على أي حال، هذه ما بنكتشف نستخدمها كمان مرة فقط
+
+501
+00:40:13,700 --> 00:40:20,560
+إذا كان الـ drying رح ينشأ عنه non-formula يعني
+
+502
+00:40:20,560 --> 00:40:26,540
+بقدر أحصل عنه non-formula بمجرد عملية التجفيف. لكن
+
+503
+00:40:26,540 --> 00:40:31,560
+يا شباب، لو أن عملية التجفيف بتعطيناش non-formula
+
+504
+00:40:31,560 --> 00:40:34,400
+زي مثلاً الـ iron hydroxide،
+
+505
+00:40:37,850 --> 00:40:43,210
+هذا لو جيت بدي أجففه في xH₂O. لو جيت بدي أجففه
+
+506
+00:40:43,210 --> 00:40:48,270
+بتبقى الـ x ممكن تتحول لـ y، ممكن تتحول لـ a، لـ b، لـ c، لـ
+
+507
+00:40:48,270 --> 00:40:56,970
+d، ما بعرفهاش قد ايش. عشان هيك هذا لازم يُحرّق عشان
+
+508
+00:40:56,970 --> 00:41:05,140
+أحاول. الـ Fe₂O₃ معروف. هذا ما نفعش أرشحه بـ Gooch. طيب ها
+
+509
+00:41:05,140 --> 00:41:13,280
+إيش قال؟ لازم نرشحه بورقة ترشيح. ورقة ترشيح هذه
+
+510
+00:41:13,280 --> 00:41:21,660
+اسمها إيش؟ filter paper. filter paper. لكن يا شباب مش
+
+511
+00:41:21,660 --> 00:41:26,240
+أيّ filter paper. ها إيش، إيش نوعها؟ قال هذه اسمها
+
+512
+00:41:26,240 --> 00:41:33,580
+ashless filter paper. ashless يعني لما نيجي نحرّقها
+
+513
+00:41:33,580 --> 00:41:40,120
+بتسيب أي رماد. كلها بتتبخر. أنا ما بديش أضيف أي شيء
+
+514
+00:41:40,120 --> 00:41:45,100
+للراسب. ما بديش أضيف أي وزن للراسب. عشان هيك الـ filter
+
+515
+00:41:45,100 --> 00:41:48,960
+paper اللي بتستخدمها ashless filter paper. نوع معين
+
+516
+00:41:48,960 --> 00:41:53,540
+من الـ filter papers. لما نيجي نحرّقها كلها بتطير
+
+517
+00:41:53,540 --> 00:41:59,600
+ما بتسيبش أي أثر ولا أي رماد. ماشي يا شباب؟ إذا، إذا
+
+518
+00:41:59,600 --> 00:42:04,760
+كان المادة تحتاج إلى حرق، كيف بدي أرشحها؟ أولاً بدي
+
+519
+00:42:04,760 --> 00:42:09,820
+أرشحها في ashless filter paper، وبعدين بعد ما أغسلها
+
+520
+00:42:09,820 --> 00:42:15,120
+بنحطّ الـ ashless filter paper بحاجة
+
+521
+00:42:15,120 --> 00:42:21,860
+بنقول لها crucible. بنحطها بحاجة زي الفنجان، بوتقة
+
+522
+00:42:21,860 --> 00:42:25,560
+زي الفنجان لكن طويلة شوية، والجدار بتاعها هرجيجي
+
+523
+00:42:25,560 --> 00:42:29,860
+كتير. بتتحمل حرارة، ممكن تتحمل حرارة لغاية الـ 1000
+
+524
+00:42:29,860 --> 00:42:37,070
+درجة. ففي البداية بحرقها حرق بسيط على النار، شيء
+
+525
+00:42:37,070 --> 00:42:44,990
+خفيف. الورقة هذه بتتهتك فبتنزل تحت شوية، ورجّ شوية، و
+
+526
+00:42:44,990 --> 00:42:51,330
+رماد أنا شايفه، والراسب هذه لما نحرّقها مثلاً 600،
+
+527
+00:42:51,330 --> 00:42:55,820
+700، 800 درجة، حسب الـ procedure. بنلاحظ أن كلّ
+
+528
+00:42:55,820 --> 00:43:00,000
+الورقة بتطير، والراسب بيتحول من الشكل اللاندى
+
+529
+00:43:00,000 --> 00:43:05,320
+لشكل المطلوب. إذا عملية الترشيح يمكن أن تتمّ
+
+530
+00:43:05,320 --> 00:43:12,780
+باستخدام Gooch  و fritted glass. Gooch و fritted ما بتنفعش إلا إذا
+
+531
+00:43:12,780 --> 00:43:20,550
+كان بس بدي أعمل drying، أو باستخدام crucible، يعني
+
+532
+00:43:20,550 --> 00:43:23,810
+filter paper، على أساس ashless filter paper، على أساس
+
+533
+00:43:23,810 --> 00:43:29,670
+أنه بدي أحرّقها. باستخدام porcelain crucible. طيب
+
+534
+00:43:29,670 --> 00:43:36,410
+بنيجي بنفس الخطوة، بنقول طيب، عملية الغسيل. عادة عملية
+
+535
+00:43:36,410 --> 00:43:41,190
+الغسيل بتتم باستخدام ماء مقطر. مثلاً 15، 20 مل. ما بديش أغسل بلتر ولا لترين. لإنه كل ما غسلنا أكثر
+
+536
+00:43:41,190 --> 00:43:46,650
+كل ما كمية من الراسب بتضيع. لإنه الراسب دائماً ما بيكون
+
+537
+00:43:46,650 --> 00:43:51,010
+شيء قليل الذوبان في الماء، لكن لما نغسل بكمية كبيرة من
+
+538
+00:43:51,010 --> 00:43:55,230
+الماء، جزء منه بنفقده، وبالتالي كمية الـ analyte
+
+539
+00:43:55,230 --> 00:43:59,970
+بتكون أقل من الحقيقة. فإحنا بنستخدم ماء مقطر 15 مل
+
+540
+00:43:59,970 --> 00:44:05,400
+إلى 20 مل. نحطهم كلهم مرة واحدة، ولا نحطهم على مراحل؟
+
+541
+00:44:05,400 --> 00:44:09,640
+مثلاً خمسة، خمسة، خمسة؟ بنقول نعم، الصح إن نحطهم على
+
+542
+00:44:09,640 --> 00:44:14,720
+مراحل. أول خمسة مثلاً، تقريباً أول أربعة مل نحطهم،
+
+543
+00:44:14,720 --> 00:44:21,010
+وبعدين نستنى لما كلهم ينزلوا. وبعدين نحط الخمسة
+
+544
+00:44:21,010 --> 00:44:24,550
+اللي بعدهم. لما كلهم ينزلوا، بعدين نحط الخمسة
+
+545
+00:44:24,550 --> 00:44:27,490
+اللي بعدهم. لما كلهم ينزلوا، وهكذا. لو حطيناهم كلهم مرة واحدة،
+
+546
+00:44:27,490 --> 00:44:31,330
+ما استفدناش من الغسيل. الغرض من الغسيل أنه ياخد كلّ
+
+547
+00:44:31,330 --> 00:44:35,050
+الـ adsorbed، والـ excess solvent، والـ adsorbed
+
+548
+00:44:35,050 --> 00:44:39,970
+material، والـ excess ions. ياخدها كلها وينزلها
+
+549
+00:44:39,970 --> 00:44:43,010
+وين؟ على الـ filtrate. ينظّف، يغسل الراسب منها، لأنها
+
+550
+00:44:43,010 --> 00:44:48,560
+بتكون adsorbed على السطح. حصل لها adsorbed على السطح.
+
+551
+00:44:48,560 --> 00:44:52,780
+فإحنا بدنا ننزلها. كيف بننزلها؟ بالميّة المقطّرة. لكن
+
+552
+00:44:52,780 --> 00:44:58,280
+يا شباب، في حالة واحدة ما بنغسلش بالميّة المقطّرة. في
+
+553
+00:44:58,280 --> 00:45:03,180
+حالة واحدة ما بنغسلش بالميّة المقطّرة. إيش هي هذه
+
+554
+00:45:03,180 --> 00:45:07,160
+الحالة؟ بنقول إذا كان الراسب كان عندي colloid
+
+555
+00:45:07,160 --> 00:45:11,680
+بعمل له عملية agglomeration أو
+
+556
+00:45:16,320 --> 00:45:22,240
+يعني coagulation. بحوّله لـ precipitate
+
+557
+00:45:22,240 --> 00:45:27,260
+إذا كان هذا النوع من الرواسب اللي هي colloidal،
+
+558
+00:45:32,150 --> 00:45:36,230
+أصلها colloidal، أصلها غروي. بحوّلها لـ precipitate
+
+559
+00:45:36,230 --> 00:45:40,090
+كيف؟ بالحرارة مثلاً زي ما شفنا. بتبعد، حولناها لـ
+
+560
+00:45:40,090 --> 00:45:43,670
+precipitate. لكن لو حطيت عليها ميّة، بتحصل عملية عكسية.
+
+561
+00:45:43,670 --> 00:45:48,870
+الراسب بيرجع  لـ colloid، أو الـ colloidal
+
+562
+00:45:48,870 --> 00:45:53,230
+state. عملية بنقولها peptization.
+
+563
+00:45:53,230 --> 00:45:57,030
+عكس الـ coagulation، عكس الـ agglomeration. عملية
+
+564
+00:45:58,790 --> 00:46:03,530
+بنقولها peptization. هنشوف إيش منشأها و ليش بتحصل.
+
+565
+00:46:03,530 --> 00:46:09,210
+إذا، إن شاء الله الحصة الجاية. أي أسئلة يا شباب؟ فبنوّجه
+
+566
+00:46:09,210 --> 00:46:15,750
+في اليوم، عند النقاط هذه. الحصة الجاية، إن شاء الله،
+
+567
+00:46:15,750 --> 00:46:18,970
+بنكمل
+
+568
+00:46:18,970 --> 00:46:19,530
+بنكمل
diff --git a/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/1F-jRJK6PwU_postprocess.srt b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/1F-jRJK6PwU_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..1ab57da7d2703e8bf6865d25e313dd34e7eb3f80
--- /dev/null
+++ b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/1F-jRJK6PwU_postprocess.srt
@@ -0,0 +1,2272 @@
+1
+00:00:20,810 --> 00:00:24,710
+بسم الله الرحمن الرحيم طيب يا شباب اليوم ان شاء
+
+2
+00:00:24,710 --> 00:00:30,250
+الله بنبدأ في ال gravimetric analysis اول chapter
+
+3
+00:00:30,250 --> 00:00:34,710
+تقريبا من الشباتر اللي هناخدها في التحليل مباشرة
+
+4
+00:00:34,710 --> 00:00:42,190
+ال gravimetric analysis عادة بيعالج تقدير قيمة
+
+5
+00:00:42,190 --> 00:00:46,750
+analyte عن طريق تكوين precipitate مع precipitating
+
+6
+00:00:46,750 --> 00:00:50,600
+agentوبالتالي عند إضافة precipitating agent
+
+7
+00:00:50,600 --> 00:00:55,980
+للانالايت بيتكون عندنا راسب الراسب هذا بناخده
+
+8
+00:00:55,980 --> 00:01:03,860
+بنرشه و بنغسله وبعدين بنجففه او بنحرقه وبعدين
+
+9
+00:01:03,860 --> 00:01:11,650
+بنوزنه ومن وزن الراسب بنقدر نوصل لوزن الانالايتعلى
+
+10
+00:01:11,650 --> 00:01:20,250
+اي حال بنقدر نقول انه الراسب نفسه لابد انه يتميز
+
+11
+00:01:20,250 --> 00:01:25,530
+بخصائص الراسب نفسه لابد انه يتميز بخصائص يعني مش
+
+12
+00:01:25,530 --> 00:01:29,530
+اي راسب ممكن احصل عليه ممكن نقول والله هذا تفاعل
+
+13
+00:01:29,530 --> 00:01:34,190
+ممكن استخدمه ك gravimetric analytical reaction لأ
+
+14
+00:01:34,190 --> 00:01:38,270
+مش اي تفاعل بحصل منه على راسب يمكن استخدامه ك
+
+15
+00:01:38,270 --> 00:01:44,460
+gravimetric analytical reactionلكن اللي عندي انا
+
+16
+00:01:44,460 --> 00:01:47,880
+او التفاعل اللي ممكن استخدمه ك gravimetric
+
+17
+00:01:47,880 --> 00:01:52,600
+analytical reaction بنقول لازم يعطيني precipitate
+
+18
+00:01:52,600 --> 00:01:56,240
+له ال low solubility في الحقيقة very low
+
+19
+00:01:56,240 --> 00:02:00,300
+solubility يعني لأنه اي جزء من الرأس اللي بيدوب
+
+20
+00:02:00,300 --> 00:02:03,660
+معناه كلام انا ضيعت جزء من ال analyte وبالتالي مش
+
+21
+00:02:03,660 --> 00:02:07,460
+راح اقدر ال analyte بشكل دقيق
+
+22
+00:02:09,380 --> 00:02:13,380
+الخاصية التانية للـ precipitate انه بدي يكون له
+
+23
+00:02:13,380 --> 00:02:18,420
+very high purity ليه؟ لأنه انا من وزن الراسب بدي
+
+24
+00:02:18,420 --> 00:02:23,580
+اعرف وزن الانالايت وبالتالي اذا كانه مش pure كيف
+
+25
+00:02:23,580 --> 00:02:27,180
+بدي اعرف وزن الانالايت؟ مابيظبط لازم يكون عندي of
+
+26
+00:02:27,180 --> 00:02:33,540
+very high purity ال precipitate تالت حاجة بدي ال
+
+27
+00:02:33,540 --> 00:02:38,550
+precipitate يكون له non compositionnon composition
+
+28
+00:02:38,550 --> 00:02:44,370
+يعني formula معروفة formula معروفة ليه لأنه انا
+
+29
+00:02:44,370 --> 00:02:47,530
+برضه بدي استخدم هذه ال formula عشان اشوف اكم
+
+30
+00:02:47,530 --> 00:02:50,790
+millimole انا light موجود في ال .. في ال .. في كل
+
+31
+00:02:50,790 --> 00:02:54,910
+millimole formula مثلا وبالتالي بدي استخدم هذه ال
+
+32
+00:02:54,910 --> 00:02:57,910
+formula في عملية الحسابات اذا كان انا رسبت مادة
+
+33
+00:02:57,910 --> 00:03:03,090
+لكن المادة اللي رسبتها صح راسب حلو ممتاز والتيرلكن
+
+34
+00:03:03,090 --> 00:03:06,430
+مش عارف ايش ال formula تبعته على الفاضي بقدرش
+
+35
+00:03:06,430 --> 00:03:11,070
+استخدمه في الحسابات علشان هيك بدنا يكون اله non
+
+36
+00:03:11,070 --> 00:03:16,710
+composition بقدر اقول انه كمان الراسب يجب ان تكون
+
+37
+00:03:16,710 --> 00:03:25,450
+عملية فصله من مكونات ال mixture او ال reaction
+
+38
+00:03:25,450 --> 00:03:31,400
+mixture عملية سهلة يعنيعملية الترشيح بدها تكون
+
+39
+00:03:31,400 --> 00:03:36,620
+عملية جيدة يعني ال particle size لل precipitates
+
+40
+00:03:36,620 --> 00:03:41,500
+بدوا يكون عادة جيد اللي أقدر أرشحه بشكل ممتاز كمان
+
+41
+00:03:41,500 --> 00:03:46,900
+ال precipitates نفسه لازم يكون ثابت atmospheric
+
+42
+00:03:46,900 --> 00:03:50,200
+conditions يعني في الأحوال العادية في الأحوال
+
+43
+00:03:50,200 --> 00:03:54,240
+الجوية العادية ليه؟ لأن التجربة عندى بتستمر لساعات
+
+44
+00:03:55,100 --> 00:03:58,240
+فإذا كان الـ precipitate اللي أنا حصلت عليه مش
+
+45
+00:03:58,240 --> 00:04:04,900
+ثابت معنى الكلام مش راح أحصل على نتيجة حقيقية ليه؟
+
+46
+00:04:04,900 --> 00:04:08,240
+لأن جزء من ال precipitate بدو يكون اتكسر أو اتحول
+
+47
+00:04:08,240 --> 00:04:13,460
+لحاجة تانية اتفاعل مع الهواء الجوي وما إلى ذلك
+
+48
+00:04:13,460 --> 00:04:17,140
+فمعنى الكلام هذا بيقدر لأخطاء ممكن الأخطاء هذه
+
+49
+00:04:17,140 --> 00:04:21,440
+تكون أخطاء جسيمة للغاية وتأثر على التحليل بشكل
+
+50
+00:04:21,440 --> 00:04:26,050
+كبير خالص علشان هيك بنقول أن ال precipitateيجب أن
+
+51
+00:04:26,050 --> 00:04:32,050
+يكون ثابت at atmospheric conditions و لفترة زمنية
+
+52
+00:04:32,050 --> 00:04:38,190
+طويلة في الحقيقة بنقول عموما يعني الـ gravimetric
+
+53
+00:04:38,190 --> 00:04:43,130
+analysis هو عبارة عن technique بياخد وقت كثير
+
+54
+00:04:43,130 --> 00:04:52,190
+الوقت اللي بياخده وقت ايه طويل وقت طويل لكن
+
+55
+00:04:52,190 --> 00:04:58,660
+مع ذلكيعتبر من أدق ال analytical methods إذا كان
+
+56
+00:04:58,660 --> 00:05:02,340
+تم إجراء ل gravimetric analysis بالشكل الصحيح
+
+57
+00:05:02,340 --> 00:05:07,160
+فيعتبر من أدق ال analytical methods التحليل الوزني
+
+58
+00:05:07,160 --> 00:05:12,820
+يعتبر تحليل مثالي تحليل دقيق جدا لكن بس بشرط أنه
+
+59
+00:05:12,820 --> 00:05:20,300
+يتم عمله بطريقة صحيحةصحيح هو تكنيك مكلف من ناحية
+
+60
+00:05:20,300 --> 00:05:23,280
+الوقت، بيأخذ وقت طويل جدا، يعني ممكن لما بدنا
+
+61
+00:05:23,280 --> 00:05:26,780
+نشتغل تحليل الوزن، نقعد طول اليوم في تحليل واحد
+
+62
+00:05:26,780 --> 00:05:30,900
+فقط، طول اليوم، بينما المعايرة، خمس دقايق، بيكون
+
+63
+00:05:30,900 --> 00:05:35,160
+عملنا معايرتين ولا تلاتةمثلا التحليل الوزن بياخد
+
+64
+00:05:35,160 --> 00:05:39,880
+تقريبا طول اليوم كمان يعني التحليل الوزن في
+
+65
+00:05:39,880 --> 00:05:43,940
+الحقيقة يعتبر macro method macro analytical method
+
+66
+00:05:43,940 --> 00:05:48,460
+ليه؟ لأنه انا بدي راسي بأوزنه وانا ماخد بايدلي
+
+67
+00:05:48,460 --> 00:05:53,440
+اعتبار انه كل ما وز الوزن اللي بدي اوزنها قليلة
+
+68
+00:05:53,440 --> 00:05:57,520
+كانت قليلة يبقى الخطأ بيكون كبير علشان هيك الوزن
+
+69
+00:05:57,520 --> 00:06:03,570
+بيكون محسوسةيعني مثلا نص جرام مش واحد من ألف ملي
+
+70
+00:06:03,570 --> 00:06:07,370
+جرام ولا خمسة من ألف ملي جرام، لأ، يكون نص جرام،
+
+71
+00:06:07,370 --> 00:06:10,350
+ستة من عشرة جرام، أربعة من عشرة جرام، تمانية من
+
+72
+00:06:10,350 --> 00:06:15,190
+عشرة جرام، واحد جرام، هذه وزنة تعتبر إيه شمالها؟
+
+73
+00:06:15,190 --> 00:06:18,550
+كبيرة جدا، معناه كلام الانالايت، لازم يكون كمية
+
+74
+00:06:18,550 --> 00:06:23,570
+كبيرة علشان هيك تعتبر إيه زي ما قلت macro
+
+75
+00:06:23,570 --> 00:06:27,540
+analytical methodفلا تستخدم إلا إذا كان وزنة
+
+76
+00:06:27,540 --> 00:06:35,320
+الانالايت عنده وزنة كبيرة نسبيا كمان ممكن نطلع على
+
+77
+00:06:35,320 --> 00:06:42,180
+ال graphometric analysis على إنها بالإضافة لإنها
+
+78
+00:06:42,180 --> 00:06:46,120
+بتاخد وجد طويل وبالإضافة لإنها macro analytical
+
+79
+00:06:46,120 --> 00:06:50,840
+methodممكن تطلع عليها كميزة يعني غريبة تعتبر في ال
+
+80
+00:06:50,840 --> 00:06:53,260
+analytical chemistry لأنه في ال analytical
+
+81
+00:06:53,260 --> 00:06:58,180
+chemistry احنا عادة بنستخدم standard solution مع
+
+82
+00:06:58,180 --> 00:07:03,180
+solution unknown عشان نقدر ال unknown بمعلومية ال
+
+83
+00:07:03,180 --> 00:07:08,140
+standard لكن ل gravimetric analysis بنقدر نقول انه
+
+84
+00:07:08,140 --> 00:07:13,440
+من ال analytical techniques القليلة التي لا تحتاج
+
+85
+00:07:13,440 --> 00:07:17,320
+إلى standard solution طب هكيف تتعرف ال unknown فقط
+
+86
+00:07:18,010 --> 00:07:22,450
+بنضيف كمية زيادة من ال precipitating agent فكل ال
+
+87
+00:07:22,450 --> 00:07:27,330
+unknown بترسب من وزنة الراسب بعرف كمية ال unknown
+
+88
+00:07:27,330 --> 00:07:31,150
+فانا لست بحاجة إلى standard solutions وهذا يعني
+
+89
+00:07:31,150 --> 00:07:36,190
+هذا يعتبر ميزة مهمة جدا في ال gravimetric analysis
+
+90
+00:07:36,530 --> 00:07:39,390
+فالـ Graphometric Analysis لها عيوب تاخد واجهة
+
+91
+00:07:39,390 --> 00:07:48,030
+طويل صحيح macro method صحيح لكن بنقدر نقول إنه لا
+
+92
+00:07:48,030 --> 00:07:53,710
+تحتاج إلى standard solution هذه تعتبر ميزة يعني
+
+93
+00:07:53,710 --> 00:07:59,050
+ممتازة للغاية وبرضه كمان ميزة أخرى إنها تعتبر
+
+94
+00:07:59,050 --> 00:08:05,150
+الدقة فيها عالية جدا إذا كان يعني عملناها بالطريقة
+
+95
+00:08:05,150 --> 00:08:12,240
+الصحيحةبنقول طيب هل احنا مضطرين انه يعني نستخدم ال
+
+96
+00:08:12,240 --> 00:08:16,200
+gravimetry؟ يعني بعض ال standard methods of
+
+97
+00:08:16,200 --> 00:08:20,460
+analysis بتستخدم ليه gravimetry لليوم يعني بعض
+
+98
+00:08:20,460 --> 00:08:24,820
+الطرق القياسية بتستخدم ليه gravimetry ك standard
+
+99
+00:08:24,820 --> 00:08:28,190
+techniqueعلشان هيك بدنا نتعلم الـ gravimetry بشكل
+
+100
+00:08:28,190 --> 00:08:33,270
+كويس، نتعرف كيف نجري ال procedure بشكل ممتاز، لأنه
+
+101
+00:08:33,270 --> 00:08:37,830
+هي تعتبر في .. لبعض ال analytes ال standard method
+
+102
+00:08:37,830 --> 00:08:41,890
+الدقة تبعتها يمكن أنت بتستغرب، يعني لو تصورت أنت
+
+103
+00:08:41,890 --> 00:08:46,670
+ال atomic weights للعناصر، كيف تم تحديدها؟ كتير من
+
+104
+00:08:46,670 --> 00:08:50,310
+ال atomic weights اللي بتعتبر من أدق الأرقام اللي
+
+105
+00:08:50,310 --> 00:08:54,350
+عندنا في الكيميا، ال atomic weights، دقيقة جداتم
+
+106
+00:08:54,350 --> 00:08:58,170
+تحديد معظمها او كثير منها باستخدام ال gravimetry
+
+107
+00:08:58,170 --> 00:09:02,550
+كان ال gravimetry هو التكنيك المشهور لتعيين ال
+
+108
+00:09:02,550 --> 00:09:07,910
+atomic weights فالنتيجة طبعا atomic weights of
+
+109
+00:09:07,910 --> 00:09:12,770
+very high precision of very high accuracy فبالفعل
+
+110
+00:09:12,770 --> 00:09:17,170
+بدنا نحس ان ال gravimetry كثير كثير كثير ممتازة
+
+111
+00:09:17,170 --> 00:09:25,550
+كثير دقيقة كثير مهمة لكن الشرطانه اه تنعمل بشكل
+
+112
+00:09:25,550 --> 00:09:30,430
+صحيح فاحنا خلال يعني هذا ال chapter بدنا نحاول
+
+113
+00:09:30,430 --> 00:09:34,850
+نعرف كيف نعمل ال graphometric analysis بالشكل
+
+114
+00:09:34,850 --> 00:09:38,690
+الصحيح كيف نعمل ال graphometric analysis بالشكل
+
+115
+00:09:38,690 --> 00:09:44,030
+الصحيح علشان يعني نقدم لهذا الموضوع في البداية
+
+116
+00:09:44,030 --> 00:09:50,680
+بنقول انه كمثال في عندي بعض ال analytesوبعض الـ
+
+117
+00:09:50,680 --> 00:09:53,440
+precipitating agents اللي بنضيفه يتكوّن لنا
+
+118
+00:09:53,440 --> 00:10:00,360
+precipitates وبنتطلع على إيش الشكل اللي بيتم وزنهو
+
+119
+00:10:00,360 --> 00:10:05,040
+ال column الأخير بيعطي ال interfering ions فنجي
+
+120
+00:10:05,040 --> 00:10:09,500
+نطلع مثلا ال potassium ال potassium لو أضافنا عليه
+
+121
+00:10:09,500 --> 00:10:13,920
+تترفن البوريت بتتوان عندي راسب من ال potassium
+
+122
+00:10:13,920 --> 00:10:19,080
+تترفن البوريت هو نفسه بغسله و بجففه و بوزنه بنفس
+
+123
+00:10:19,080 --> 00:10:23,320
+الصورة ال form اللي طلعته معروفة بهذا الشكل بوزنه
+
+124
+00:10:23,320 --> 00:10:28,570
+بنفس الصورةلكن يا شباب، لو كان عندي أمونيام،
+
+125
+00:10:28,570 --> 00:10:32,810
+هتعطيني أمونيام تترفن البوريت، لو كان عندي سلفر،
+
+126
+00:10:32,810 --> 00:10:36,290
+هتعطيني سلفر تترفن البوريت، لو كان عندي ميركوري،
+
+127
+00:10:36,290 --> 00:10:40,090
+لو كان عندي ثاليوم، لو كان عندي روبيديام، سيزيام،
+
+128
+00:10:40,090 --> 00:10:41,190
+كلهم بتداخله
+
+129
+00:10:44,180 --> 00:10:48,860
+لابد من التخلص من هذه الانترفيرنس و لا الرعصب اللي
+
+130
+00:10:48,860 --> 00:10:53,060
+انا بحصل عليه، مش فقط للانالايت، مش بس للبوتاسيوم،
+
+131
+00:10:53,060 --> 00:10:57,540
+لأ لكل اللي موجود معاه، اذا عندي خطأ جسيم للغاية
+
+132
+00:10:58,360 --> 00:11:02,500
+معايا اذا لازم افصل البوتاسيوم لوحده قبل ما اجري
+
+133
+00:11:02,500 --> 00:11:08,780
+عملية الترسيم مثلا المجنيزيوم معروف بترسب على هيئة
+
+134
+00:11:08,780 --> 00:11:12,980
+magnesium ammonium phosphate لكن هذا الشكل عادة
+
+135
+00:11:12,980 --> 00:11:18,020
+فيه كمية من الميه لو احنا جففنا الست ممكن تصير
+
+136
+00:11:18,020 --> 00:11:21,460
+خمسة ممكن تصير اربعة ممكن تصير تلاتة طب قداش هي
+
+137
+00:11:21,460 --> 00:11:25,700
+بالظبط مش عارفين احنا علشان هيك بقدرش استخدم ال
+
+138
+00:11:25,700 --> 00:11:31,810
+formula هذه للحساباتلهذا السبب ايش بعمل بأحرق هذا
+
+139
+00:11:31,810 --> 00:11:37,990
+المُركّب بيتكوّن عندى magnesium pyrophosphate P2O7
+
+140
+00:11:37,990 --> 00:11:44,130
+هذا الشكل ثابت معروف بقدر اوزنه ومن وزنته بقدر
+
+141
+00:11:44,130 --> 00:11:49,130
+اجيب جداش عندى magnesium مثلا لو طلعنا على ال
+
+142
+00:11:49,130 --> 00:11:52,450
+barium تجربة هتاخدها في المختبر ال barium مضيف
+
+143
+00:11:52,450 --> 00:11:55,990
+عليه صلفات بتكون عندنا رأس باريوم صلفات ال barium
+
+144
+00:11:55,990 --> 00:12:01,700
+صلفات فيها خيارينهي ثابتة upon drying يعني ممكن
+
+145
+00:12:01,700 --> 00:12:05,680
+توزنها عليا باريوم سالفايت أو برضه الكثير من الناس
+
+146
+00:12:05,680 --> 00:12:12,100
+بحبوا يحرجوها أسرع حولوها لباريوم سالفايت فبدانك
+
+147
+00:12:12,100 --> 00:12:17,440
+خيارين اما انك تعملها drying واما انك تحرجها
+
+148
+00:12:17,440 --> 00:12:19,020
+الاتنين جيدين
+
+149
+00:12:21,300 --> 00:12:26,000
+ففيه عندنا لكن كل مرة بنلاحظ انه اي تحليل فيه
+
+150
+00:12:26,000 --> 00:12:30,720
+عندنا interfering ions علشان هيك يعني مكلف جدا انه
+
+151
+00:12:30,720 --> 00:12:33,640
+نعمل عملية separation مكلف جدا يعني لازم ناخد
+
+152
+00:12:33,640 --> 00:12:37,840
+بالنا لأنه احنا اذا كان اخطأنا ومااخدناش بالنا من
+
+153
+00:12:37,840 --> 00:12:41,980
+ال interference هتتحول لراصب وانا بعرفش يعني
+
+154
+00:12:41,980 --> 00:12:45,320
+الراصب اللي حصلت عليه بفترض ان هو راصب لل analyte
+
+155
+00:12:46,190 --> 00:12:49,630
+مع ال precipitating agent وبده حل على هذا الأساس
+
+156
+00:12:49,630 --> 00:12:54,790
+لكن هل الحل هيكون حل صحيح؟ بالطبع مش حل صحيح
+
+157
+00:12:54,790 --> 00:13:00,950
+نهائيا ليه؟ لأن الراسب بيحتوي على أكتر من حاجة مش
+
+158
+00:13:00,950 --> 00:13:06,850
+شرط أنهالـ precipitating agent يكون inorganic يعني
+
+159
+00:13:06,850 --> 00:13:12,870
+مثلا السلفر أرصبه بالكلوريد البريوم
+
+160
+00:13:12,870 --> 00:13:16,150
+أرصبه بالصلفات الكالسيوم أرصبه بالكربونات أو
+
+161
+00:13:16,150 --> 00:13:20,630
+الأجزالات مش شرط انه يكون ال precipitating agent
+
+162
+00:13:20,630 --> 00:13:26,310
+دائما inorganic لأ ممكن يكون organic فهذا حاجة
+
+163
+00:13:26,310 --> 00:13:30,750
+يقولها ات هيدروكسي كوينولين مع المجنيزين بعطين
+
+164
+00:13:30,750 --> 00:13:37,840
+راسبمجنيزيام ات هيدروكسيكوينوليت ممكن تكون الجيزة
+
+165
+00:13:37,840 --> 00:13:42,480
+أورجانيك لكن الصيغة هي صيغة معروفة بقدر أخدها
+
+166
+00:13:42,480 --> 00:13:47,740
+أوزانها ومن قيمة الوزن أطلع جداش في عندي مثلا
+
+167
+00:13:47,740 --> 00:13:52,040
+مجنيزيام أيضا تجربة هتاخدها في المختبر إذا الله
+
+168
+00:13:52,040 --> 00:13:58,160
+راد النيكل كيف بنعينه بنضيف عليه organic
+
+169
+00:14:05,850 --> 00:14:10,050
+النكل بياخد اتنين من البيميثل إجليوكزيم وبيعطينا
+
+170
+00:14:10,050 --> 00:14:18,690
+نكل بيميثل إجليوكزيمبرضه هذا راسب أحمر تقريبا زي
+
+171
+00:14:18,690 --> 00:14:22,410
+المناكير و ريحته كمان ريحة مناكير هتاخده في
+
+172
+00:14:22,410 --> 00:14:27,390
+المختبر و تعيين ال nickel باستخدام ال bio methyl
+
+173
+00:14:27,390 --> 00:14:30,830
+glyoxime فمش شرط ان ال precipitating agent يكون
+
+174
+00:14:30,830 --> 00:14:38,090
+دائما inorganic لأ ممكن يكون organic أيضا طيب يا
+
+175
+00:14:38,090 --> 00:14:44,970
+شباب نيجي الان نتحدث عنأيش هي الخطوات الرئيسية في
+
+176
+00:14:44,970 --> 00:14:50,090
+الـ Gravimetric Analysis؟ بنقول عشان نشتغل صح و
+
+177
+00:14:50,090 --> 00:14:52,950
+احنا بدنا نشتغل صح لأنه ماشتغلناش صح في الـ
+
+178
+00:14:52,950 --> 00:14:56,110
+Gravimetric Analysis معناته كل شغل ما ليس له أي
+
+179
+00:14:56,110 --> 00:15:00,430
+قيمةمجال الخطأ في الـ Gravimetric Analysis كبير و
+
+180
+00:15:00,430 --> 00:15:05,870
+متعدد المصادر و هنشوف يعني أنواع مختلفة من الأخطاء
+
+181
+00:15:05,870 --> 00:15:09,210
+اللي ممكن أنها تواجهنا في الـ Gravimetric Analysis
+
+182
+00:15:09,210 --> 00:15:12,850
+لكن خلينا نطلع على الخطوات الرئيسية في الـ
+
+183
+00:15:12,850 --> 00:15:16,230
+Gravimetric Analysis انا بدي اعمل تحليل وزني ايش
+
+184
+00:15:16,230 --> 00:15:18,830
+في البداية بدي اعمل جالب preparation of the
+
+185
+00:15:18,830 --> 00:15:23,410
+solution اول خطوة بدي احضر المحلول يعني مثلا لو
+
+186
+00:15:23,410 --> 00:15:28,670
+المادة صلبة بدي في البداية ادوبهاطب عشان أدوّبها
+
+187
+00:15:28,670 --> 00:15:33,930
+بدّي مواد تكون خالية من ال analyte يعني بدور على
+
+188
+00:15:33,930 --> 00:15:39,090
+ال nickel مثلا بدّيش أدوّب ..
+
+189
+00:15:39,090 --> 00:15:45,270
+.. .. ..
+
+190
+00:15:45,270 --> 00:15:50,970
+.. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. ..
+
+191
+00:15:50,970 --> 00:15:52,230
+.. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. ..
+
+192
+00:15:52,230 --> 00:15:52,710
+.. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. ..
+
+193
+00:15:52,710 --> 00:15:52,750
+.. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. ..
+
+194
+00:15:52,750 --> 00:15:52,770
+.. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. ..
+
+195
+00:15:52,770 --> 00:15:52,810
+.. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. ..
+
+196
+00:15:52,810 --> 00:15:52,890
+.. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. ..
+
+197
+00:15:52,890 --> 00:15:53,230
+.. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. ..
+
+198
+00:15:53,230 --> 00:15:53,570
+.. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. ..
+
+199
+00:15:53,570 --> 00:15:53,710
+.. .. .. .. .. ..
+
+200
+00:15:57,420 --> 00:16:02,040
+الحاجة التانية مثلا بدي أظبط ال pH بتيجي الاتفاعل
+
+201
+00:16:02,040 --> 00:16:06,500
+يكون مبتدئة في عندي pH معينة و انا بدي التفاعل
+
+202
+00:16:06,500 --> 00:16:10,720
+يكون مبتدئة بدي التفاعل يكون بالنسبة 100% كل ال
+
+203
+00:16:10,720 --> 00:16:15,740
+analyte دي هيتحول لراسي بدي اتفاعل 100% عشان انا
+
+204
+00:16:15,740 --> 00:16:20,800
+بدي اظبط ال pH علشان اخلي التفاعل يمشي بالنسبة 100
+
+205
+00:16:20,800 --> 00:16:24,040
+% الحاجة
+
+206
+00:16:32,280 --> 00:16:36,000
+لأسباب أخرى، هنقولها بعد شوية، انت بينجب ال pH
+
+207
+00:16:36,000 --> 00:16:41,520
+مهمة لسبب ايه؟ أول سبب زي ما تكلمت عنه التفاعل
+
+208
+00:16:41,520 --> 00:16:46,620
+بيكون ال Quantitative عن ال pH معينة، و ثاني سبب
+
+209
+00:16:46,620 --> 00:16:52,720
+هنتحدث عنه بعد شوية، ريز، صح، فممكن نفتح ال pH،
+
+210
+00:16:52,720 --> 00:16:58,540
+ممكن أقول أنه أنا حكيت أنه في عن .. في عن ..
+
+211
+00:17:01,810 --> 00:17:05,490
+ممكن يكون هناك interference إذا قطعوا الطرق لعمل
+
+212
+00:17:05,490 --> 00:17:09,770
+عملية special هل هذا برضه من تحضير المحلول؟ من
+
+213
+00:17:09,770 --> 00:17:14,350
+تحضير المحلول؟ والله إذا كان المادة مثلًا وهل ياشي
+
+214
+00:17:14,350 --> 00:17:18,730
+منك تمشي؟ لازم كإنسان ك chemist ك analyst يكون في
+
+215
+00:17:18,730 --> 00:17:24,280
+عندكلإيش ممكن تعمل أشياء و لا مكانت مش مكتوبة،
+
+216
+00:17:24,280 --> 00:17:31,380
+يعني لو كانت مثلا المحلول Terrible، مؤكر، مؤكر
+
+217
+00:17:31,380 --> 00:17:35,180
+ليش؟ لإن في شغلات صلبة، مغلقة، فالهاجر راح يضيف
+
+218
+00:17:35,180 --> 00:17:40,100
+لراسه كمان، لأ، يجيب يقول المحلول .. يعني المسلطر
+
+219
+00:17:40,100 --> 00:17:42,760
+المنح، مافيش فيه أي .. أي رواصم جامد معنى عظيم
+
+220
+00:17:42,760 --> 00:17:49,460
+تتزيد، مثلا، يعني دايب بشكل 100%ممكن يكون فيه كمان
+
+221
+00:17:49,460 --> 00:17:56,980
+حاجة تبدأ منها انا بدي كمية راسي من مثلا حوالي
+
+222
+00:17:56,980 --> 00:18:04,020
+نص مثلا نص جراب اربعة من عشرة جراب ستة من عشرة
+
+223
+00:18:04,020 --> 00:18:10,260
+جراب مثلا فبدي كمية ال analyte المستخدمات تعطيني
+
+224
+00:18:10,260 --> 00:18:13,540
+هذه الكمية تسألني كمية ال analyte تعطيني او خمسة
+
+225
+00:18:13,540 --> 00:18:19,480
+جراب ولا عشرة جرابإذا لازم أصبط الحجم .. لازم أصبط
+
+226
+00:18:19,480 --> 00:18:24,880
+الحجم من الانالايت اللي ممكن يعطيني
+
+227
+00:18:28,800 --> 00:18:36,900
+كمية كافية أو جيدة أو مناسبة من ال precipitate قد
+
+228
+00:18:36,900 --> 00:18:40,480
+يكون في هناك شغلات إضافية ممكن أضيفها لـ
+
+229
+00:18:40,480 --> 00:18:44,120
+preparation of the solution لكن يمكن هذه أهم
+
+230
+00:18:44,120 --> 00:18:48,440
+الحاجات اللي ممكن تواجهنا أول خطوة إذن preparation
+
+231
+00:18:48,440 --> 00:18:53,200
+of the solution حضرنا المحلول الآن بدي أبدأ أعمل
+
+232
+00:18:53,200 --> 00:18:59,150
+عملية precipitationبقول عملية ال precipitation
+
+233
+00:18:59,150 --> 00:19:05,210
+عملية مش سهلة مش سهلة وهي أهم عملية هي ال heart هي
+
+234
+00:19:05,210 --> 00:19:09,790
+قلب ل graphimetric analysis الحقيقة بقول بدي أجي
+
+235
+00:19:09,790 --> 00:19:12,590
+في البداية أضيف ال precipitating agent على
+
+236
+00:19:14,320 --> 00:19:18,200
+الانالايت ساليوشن بقول لما اضيف نقطة ولا نقطين
+
+237
+00:19:18,200 --> 00:19:23,200
+بلاحظ انه فيش عندى اي راسب لسه فيش راسب طب هى وين
+
+238
+00:19:23,200 --> 00:19:27,980
+راحوا اللى اضفتهم جال فى البداية بتكون عندى
+
+239
+00:19:27,980 --> 00:19:34,760
+saturated solution او حتى super saturated solution
+
+240
+00:19:34,760 --> 00:19:39,780
+مدام اتكون عندى محلول مشبع او فوق مشبع اه طب الان
+
+241
+00:19:39,780 --> 00:19:44,670
+اول نقطة اضافية بضيفهابقول في البداية لسه بتكونش
+
+242
+00:19:44,670 --> 00:19:52,990
+راسب كمان هاش بتكون كلب بتكون ال nuclei أنوية حجر
+
+243
+00:19:52,990 --> 00:19:56,870
+الأساس للراسب لسه مش الراسب إيش الأنوية عملية
+
+244
+00:19:56,870 --> 00:20:00,990
+بنقولها ال nucleation إيش هي ال nucleation قال
+
+245
+00:20:00,990 --> 00:20:06,310
+والله أربع خمس أيونات من ال precipitating agent مع
+
+246
+00:20:06,310 --> 00:20:12,180
+أربع خمس أيونات من ال analyte بيكونولي نواةهو حجر
+
+247
+00:20:12,180 --> 00:20:17,560
+أساس للراسب و 4 او 5 أيونات من الراسب من ال
+
+248
+00:20:17,560 --> 00:20:24,880
+precipitating agent مع 4 او 5 أيونات من الانالايت
+
+249
+00:20:24,880 --> 00:20:30,140
+بيعطوني نوا و نوا و نوا و نوا و نوا و نوا و نوا و
+
+250
+00:20:30,140 --> 00:20:30,580
+نوا و نوا و نوا و نوا و نوا و نوا و نوا و نوا و
+
+251
+00:20:30,580 --> 00:20:30,660
+نوا و نوا و نوا و نوا و نوا و نوا و نوا و نوا و
+
+252
+00:20:30,660 --> 00:20:30,720
+نوا و نوا و نوا و نوا و نوا و نوا و نوا و نوا و
+
+253
+00:20:30,720 --> 00:20:31,200
+نوا و نوا و نوا و نوا و نوا و نوا و نوا و نوا و
+
+254
+00:20:31,200 --> 00:20:37,810
+نوا و نوا و نوا و نجامل لسه مايتكون الراسب لان
+
+255
+00:20:37,810 --> 00:20:40,570
+نيوكلياها دي لا تراب العين المجردة ولا بيقدر
+
+256
+00:20:40,570 --> 00:20:45,630
+يمسكها أحسن filter
+
+257
+00:20:45,630 --> 00:20:50,630
+لأ لو فلترتة كله بنزل محلول لكن هي عبارة عن
+
+258
+00:20:50,630 --> 00:20:54,250
+particles ده كان صغيرة جدا جدا جدا متناهية في
+
+259
+00:20:54,250 --> 00:20:57,010
+الصغر عشانك بنقولها نيوكليايا عماليا بنقولها
+
+260
+00:20:57,010 --> 00:21:03,410
+nucleation طب أضفت كمان إيش بده يحصل قال في عندي
+
+261
+00:21:03,410 --> 00:21:08,440
+أحد خيارينيا إما بحصل عندي further enucleation،
+
+262
+00:21:08,440 --> 00:21:11,740
+الـ enucleation زي اللي شفته قبل شوية، يا إما
+
+263
+00:21:11,740 --> 00:21:16,660
+particle growth، واحد من اتنين، يا بحصل عندنا
+
+264
+00:21:16,660 --> 00:21:20,520
+further enucleation، يا بحصل عندنا particle
+
+265
+00:21:20,520 --> 00:21:24,220
+growth، نمو لل particle، طب إيش اللي بحكم هذا
+
+266
+00:21:24,220 --> 00:21:27,980
+الكلام، بدا ما عندي خيارين، إيش اللي بحكمه؟ جال،
+
+267
+00:21:27,980 --> 00:21:34,070
+جال اللي بحكمه حاجة بيقولها von Weimann ratioهذا
+
+268
+00:21:34,070 --> 00:21:40,390
+ال ratio هي عبارة عن relative super
+
+269
+00:21:40,390 --> 00:21:45,490
+saturation بحيث إنه إذا كان ال relative super
+
+270
+00:21:45,490 --> 00:21:50,060
+saturation قليلة، بحصل على particle growthإذا كان
+
+271
+00:21:50,060 --> 00:21:54,720
+ال relative supersaturation كبيرة بحصل على further
+
+272
+00:21:54,720 --> 00:21:59,840
+enucleation أنا بالطبع بدي أحصل على أو بحب أحصل
+
+273
+00:21:59,840 --> 00:22:03,740
+على particle growth بدي particles بدي precipitates
+
+274
+00:22:03,740 --> 00:22:09,280
+فإذا بدي أخلي ال relative supersaturation أقل ما
+
+275
+00:22:09,280 --> 00:22:12,920
+يمكن طب إيش هي relative supersaturation هذه؟ مدينة
+
+276
+00:22:12,920 --> 00:22:17,000
+بتأثرها لجد جال ال relative supersaturation بتسوي
+
+277
+00:22:17,000 --> 00:22:25,340
+Q minusS على S ايش ال Q قال ال Q هي ال reactant
+
+278
+00:22:25,340 --> 00:22:29,280
+concentrations تركيز ال reactants ايش هي ال
+
+279
+00:22:29,280 --> 00:22:33,520
+reactants ال precipitating agent و ال analyte جداش
+
+280
+00:22:33,520 --> 00:22:39,120
+تركيزاتهم طب ال S قال ال S هي solubility of
+
+281
+00:22:39,120 --> 00:22:42,520
+precipitate in the medium في الوسط اللي عمال
+
+282
+00:22:42,520 --> 00:22:45,920
+بيترسب منه in the medium يبقى هي solubility للي
+
+283
+00:22:45,920 --> 00:22:49,110
+precipitateطيب معنى الكلام لل relative
+
+284
+00:22:49,110 --> 00:22:53,030
+supersaturation عبارة عن function في حاجتين في ال
+
+285
+00:22:53,030 --> 00:22:55,570
+Q وفي ال S وانا بد ال relative supersaturation
+
+286
+00:22:55,570 --> 00:22:59,490
+يكون أقل ما يمكن كم يكون أقل ما يمكن قال والله ال
+
+287
+00:22:59,490 --> 00:23:04,150
+Q بدها تكون أقل ما يمكن و ال S بدها تكون ايه أكبر
+
+288
+00:23:04,150 --> 00:23:07,370
+ما يمكن هاي الحاجتين اللي بدنا ناخد بالنا منهم
+
+289
+00:23:07,370 --> 00:23:14,140
+أثناء عمليةالترسيب، إذا بدي أخلي الـQ أقل ما يمكن،
+
+290
+00:23:14,140 --> 00:23:17,040
+بدي أخلي الـS أكبر ما يمكن كيف بدي أخلي الـQ أكبر
+
+291
+00:23:17,040 --> 00:23:21,020
+ما يمكن؟ في عندي أربع عوامل بتخلي الـQ أقل ما
+
+292
+00:23:21,020 --> 00:23:26,120
+يمكن، هقول تلاتة منهم هالجيت و واحد بعد شوية طب
+
+293
+00:23:26,120 --> 00:23:31,220
+والـS كيف بدها تكون أعلى ما يمكن، هنشوف الآن، في
+
+294
+00:23:31,220 --> 00:23:37,020
+عندي عوامل تحت ال precipitationبنقول أول عامل و
+
+295
+00:23:37,020 --> 00:23:44,160
+تاني عامل و تالت عامل بيخلوا ال Q أقل ما يمكن أول
+
+296
+00:23:44,160 --> 00:23:47,500
+عامل إيش بيقول بيقول ال precipitation using dilute
+
+297
+00:23:47,500 --> 00:23:51,660
+solutions مدام ال Q بديها تكون أقل ما يمكن إذا
+
+298
+00:23:51,660 --> 00:23:55,760
+تركيزات ال reactants ال precipitating agent و ال
+
+299
+00:23:55,760 --> 00:24:02,820
+analyte لازم تكون أقل ما يمكنيبقى هذا واضح طيب ايش
+
+300
+00:24:02,820 --> 00:24:05,900
+بيقوللي كمان عامل تاني بيقوللي ال precipitating
+
+301
+00:24:05,900 --> 00:24:08,880
+agent ضيفه شوية شوية slow addition of
+
+302
+00:24:08,880 --> 00:24:12,820
+precipitating agent ليه؟ لأنه لما أضيفه شوية شوية
+
+303
+00:24:12,820 --> 00:24:17,960
+معناته التركيز بيكون قليل التركيز نسبيا بيكون قليل
+
+304
+00:24:17,960 --> 00:24:21,540
+ليه؟ لأنه أنا بضفوش كل مرة واحدة تركيز عالي لأ
+
+305
+00:24:21,540 --> 00:24:26,240
+بضيف شوية شوية منه هذا بيحفظ ال Q قليلة
+
+306
+00:24:27,710 --> 00:24:32,570
+العامل التالت اللى بقدر استخدمه انه الإضاعف شوية
+
+307
+00:24:32,570 --> 00:24:36,370
+شوية اه لكن مع التحريك عشان حق النقطة لما بتيجي
+
+308
+00:24:36,370 --> 00:24:41,470
+اتلامس الانالايت اسمها تركيزها عادي لما انا ايه
+
+309
+00:24:41,470 --> 00:24:46,670
+احرك بسرعة معنى الكلامهتتشر في كل المحلول اللي بجه
+
+310
+00:24:46,670 --> 00:24:51,170
+التركيز صار أقل ما يمكن هذه التلت حاجات باخد بالي
+
+311
+00:24:51,170 --> 00:24:55,630
+منها أثناء عملية الترسيب عشان أقل ال Q في عامل
+
+312
+00:24:55,630 --> 00:25:03,580
+رابع بعد شوية هنقوله في نمرة 7 من هذه العواملخلصنا
+
+313
+00:25:03,580 --> 00:25:08,140
+من الـ Q مرحليا، والآن نريد أن نزود ال solubility،
+
+314
+00:25:08,140 --> 00:25:12,200
+كيف نزود ال solubility؟ لأن الحرارة بتزود ال
+
+315
+00:25:12,200 --> 00:25:17,080
+solubility، لذا بقول precipitation from hot
+
+316
+00:25:17,080 --> 00:25:23,690
+solution، لازم أكون مسخن ال solutionلازم، ليه؟
+
+317
+00:25:23,690 --> 00:25:28,130
+لأنه بدأ يكون سخن، ليه؟ لأن عملية التسخين تزيد من
+
+318
+00:25:28,130 --> 00:25:31,810
+قيمة الـS، الـSolubility، طبعا لما نتكلم عن زيادة
+
+319
+00:25:31,810 --> 00:25:35,410
+الـSolubility، نتكلمش عن أن الـSolubility تصير لها
+
+320
+00:25:35,410 --> 00:25:39,670
+مثلا عشرة ولا عشرين في المية، ماحكيش ده هيك، عشرة
+
+321
+00:25:39,670 --> 00:25:41,310
+ولا عشرين في المية يعني عشرة ولا عشرين في المية من
+
+322
+00:25:41,310 --> 00:25:45,850
+الـAnalyte راحوالا بنحكيش عن solubility يعني زيادة
+
+323
+00:25:45,850 --> 00:25:48,430
+في ال solubility لهذه الدرجة لأ بنحكي عن مثلا
+
+324
+00:25:48,430 --> 00:25:54,070
+solubility على سبيل المثال 1 من 10% معايا يعني هذه
+
+325
+00:25:54,070 --> 00:26:00,410
+تعتبر زيادة من مثلا 1 من 1000% او 1000% ل 1 من 10
+
+326
+00:26:00,410 --> 00:26:06,190
+زيادة كبيرةلكن مش بنتكلم عن زيادة 10% ولا 20% لأ
+
+327
+00:26:06,190 --> 00:26:10,310
+لأنه هيك بنكون ضيعنا الراصب فاحنا بدنا ياها بدنا
+
+328
+00:26:10,310 --> 00:26:14,610
+التفاعل يكون complete يعني كله يتحول لراصب فلما
+
+329
+00:26:14,610 --> 00:26:17,630
+نتكلم عن زيادة ال solubility مش هالزيادة اللي
+
+330
+00:26:17,630 --> 00:26:20,990
+بتفكر فيها يعني نخلي .. احنا بإمكاننا نخلي كل
+
+331
+00:26:20,990 --> 00:26:26,090
+الراصب يدوب يعني لو أنا مرصب مثلا calcium على هيئة
+
+332
+00:26:26,090 --> 00:26:31,100
+calcium carbonate حط عليها شوية acidو هى بتدوب
+
+333
+00:26:31,100 --> 00:26:35,920
+مثلا معايا ولا لأ احنا بدناش هيك بدنا الصلمية تقع
+
+334
+00:26:35,920 --> 00:26:39,820
+تكون عالية لكن عالية يعني جداش يعني مثلا واحد من
+
+335
+00:26:39,820 --> 00:26:44,080
+عشرة في المية maximum بس
+
+336
+00:26:44,080 --> 00:26:50,540
+هذا ماشي بس السكر مش مش precipitate السكر مش
+
+337
+00:26:50,540 --> 00:26:54,480
+precipitate السكر بيدوب في الميه فهذا عبارة عن
+
+338
+00:26:54,480 --> 00:26:58,020
+saturated solution او super saturated solution مش
+
+339
+00:26:58,020 --> 00:27:03,600
+راسلبنقول كمان عشان ازود ال solubility ممكن ا
+
+340
+00:27:03,600 --> 00:27:07,820
+adjust ال pH بجهيز سبب تاني لل pH أول حاجة ال pH
+
+341
+00:27:07,820 --> 00:27:10,800
+بنظبط عشان التفاعل يكون quantitative لأن بعض
+
+342
+00:27:10,800 --> 00:27:14,520
+التفاعلات بتكونش quantitative إلا عند pH معينة
+
+343
+00:27:14,520 --> 00:27:21,620
+وهذا سبب تاني أن ال pH بتزود ال solubilityالـ pH
+
+344
+00:27:21,620 --> 00:27:24,180
+يعني إيش الـ pH بالزود الصليبليتي؟ يعني الـ pH
+
+345
+00:27:24,180 --> 00:27:30,180
+قليلة ولا كتيرة؟ بنقول في معظم الأحيان إذا الـ pH
+
+346
+00:27:30,180 --> 00:27:34,200
+بدي يكون لها تأثير في معظم الأحيان at low pH
+
+347
+00:27:34,200 --> 00:27:38,460
+الصليبليتي بتزيدفي معظم الأحيان لكن هذا مش دائما
+
+348
+00:27:38,460 --> 00:27:42,020
+يا شباب فاحنا بدنا نقول عشان ذلك اش بنقول adjust
+
+349
+00:27:42,020 --> 00:27:45,960
+the pH يعني بدنا نحاول نظبط ال pH بحيث انه نزيد ال
+
+350
+00:27:45,960 --> 00:27:49,600
+solubility وكمان مرة زيادة ال solubility مش
+
+351
+00:27:49,600 --> 00:27:52,480
+معناتها عشرة عشرين تلاتين في المية لأ في حدود
+
+352
+00:27:52,480 --> 00:27:58,710
+الواحد من عشرة في المية مش اكتر من هيكالحاجة القبل
+
+353
+00:27:58,710 --> 00:28:04,670
+الأخيرة فيما يتعلق بال precipitation process نفسها
+
+354
+00:28:04,670 --> 00:28:10,030
+ان والله بدنا نضيف كمية زايدة شوية little excess
+
+355
+00:28:10,030 --> 00:28:13,910
+من ال precipitating agent وبدنا نقول ليش هذا
+
+356
+00:28:13,910 --> 00:28:22,170
+الكلام انا في عندى هاي الراسي بتكون مثلا وليكن
+
+357
+00:28:22,170 --> 00:28:28,890
+barium sulfateبحط أنا الصلفات على ال barium فاتكون
+
+358
+00:28:28,890 --> 00:28:33,510
+عند باريام صلفات طب هل الصلفات اللي أضفتها كافية
+
+359
+00:28:33,510 --> 00:28:38,930
+ولا غير كافية مش عارف انا ايش بعمل جال بضيف نقطة
+
+360
+00:28:38,930 --> 00:28:43,070
+من الصلفات بعد ما المحلول يروج يصير clear بضيف
+
+361
+00:28:43,070 --> 00:28:46,790
+نقطة من الصلفات على ايه؟ على الجدار فتنزل على
+
+362
+00:28:46,790 --> 00:28:51,010
+الجدار والله اذا كان اتكون هناك دراسة معناته لسه
+
+363
+00:28:51,010 --> 00:28:55,920
+بدهاماتكونش عند راسي بإذن خلاص لو جالي السميد هبقى
+
+364
+00:28:55,920 --> 00:28:59,960
+وضيفلي كمان اكم من مل من الصلفيت لغاية ما اني
+
+365
+00:28:59,960 --> 00:29:04,120
+ماحصلش على اي راسي بهان عشان اتأكد انه خلاص
+
+366
+00:29:04,120 --> 00:29:08,380
+التفاعل تم مية في المية كمان وضيفلي تالتة اربعة
+
+367
+00:29:08,380 --> 00:29:12,720
+نجاط من الصلفيت الزيادة ليه؟ لأن عندي أنا ال
+
+368
+00:29:12,720 --> 00:29:19,260
+barium زائد الصلفيت barium
+
+369
+00:29:19,260 --> 00:29:23,510
+sulfate solidأنا لو زودت الصلفات إيش بحصل ال
+
+370
+00:29:23,510 --> 00:29:26,910
+equilibrium؟ بنشد حياتي ال barium يعني كمية ال
+
+371
+00:29:26,910 --> 00:29:30,690
+barium اللي ضايلة مش مترصفة بتكون مهملة فالتفاعل
+
+372
+00:29:30,690 --> 00:29:35,490
+بيكون تقريبا quantitative فانا دائما لازم أضيف
+
+373
+00:29:35,490 --> 00:29:40,450
+little excess من ال precipitating agent ماشي يا
+
+374
+00:29:40,450 --> 00:29:48,330
+جماعة؟ طيب نيجي نتطلع الآن على آخرعامل بيأثر على
+
+375
+00:29:48,330 --> 00:29:53,290
+ال precipitation process وهذا العامل له علاقة برضه
+
+376
+00:29:53,290 --> 00:29:58,010
+بال Q لأن احنا قلنا في عنا اربع عوامل اللي لها
+
+377
+00:29:58,010 --> 00:30:02,570
+علاقة بال Q ذكرنا تلاتة منها وقلنا هنتكلم عن
+
+378
+00:30:02,570 --> 00:30:06,270
+الرابع بعدين هال جيت إيجي معاده وبنقول
+
+379
+00:30:06,270 --> 00:30:12,450
+precipitation from homogeneous solution وبقول بين
+
+380
+00:30:12,450 --> 00:30:18,590
+جثين ممكن نحط if possible إن أمكنبعض ال reactions
+
+381
+00:30:18,590 --> 00:30:22,870
+ال precipitation reactions يا شباب بتأدي لرواسب
+
+382
+00:30:22,870 --> 00:30:31,410
+الرواسب هذه gelatinous او colloidal غروية او
+
+383
+00:30:31,410 --> 00:30:36,010
+gelatinous يعني جيلاتينية ال particle size بيكون
+
+384
+00:30:36,010 --> 00:30:40,270
+صغير للغاية ال particle size بيكون صغير للغاية
+
+385
+00:30:40,270 --> 00:30:46,240
+عشان هيك ماعرفش ارشحها اتغلبني كتيرهل في طريقة ان
+
+386
+00:30:46,240 --> 00:30:51,180
+نخل ال particle size اكبر بنقول والله ان امكن ان
+
+387
+00:30:51,180 --> 00:30:55,900
+نرسب from homogeneous solution بكون هذا كلام ممتاز
+
+388
+00:30:55,900 --> 00:30:59,200
+جدا لما نقول homogeneous او precipitation from
+
+389
+00:30:59,200 --> 00:31:03,180
+homogeneous solution طب احنا بنرسب من محليل يعني
+
+390
+00:31:03,180 --> 00:31:09,900
+homogeneous لأ هذا مصطلح ايش معناه معنات تالي مثلا
+
+391
+00:31:09,900 --> 00:31:13,960
+انا بدرس بال iron
+
+392
+00:31:17,690 --> 00:31:26,170
+على هيئة iron hydroxide فين والله هيمها؟ هاي عندى
+
+393
+00:31:26,170 --> 00:31:33,150
+ال iron هاي
+
+394
+00:31:33,150 --> 00:31:38,750
+ال iron بدى
+
+395
+00:31:38,750 --> 00:31:39,870
+احط عليه hydroxide
+
+396
+00:31:42,200 --> 00:31:45,720
+لو حطيت على hydroxide من برا هذا الكلام معناته
+
+397
+00:31:45,720 --> 00:31:49,360
+عملية ترسيب عادية مش from homogeneous solution
+
+398
+00:31:49,360 --> 00:31:52,740
+عملية ترسيب إيه شبالها عادي أضيف ال hydroxide لأ
+
+399
+00:31:52,740 --> 00:31:57,420
+بديش أضيف ال hydroxide من برا طب ها كيف جال بدي
+
+400
+00:31:57,420 --> 00:32:01,420
+أعمله generation من داخل المحلول كيف جال ممكن نحط
+
+401
+00:32:01,420 --> 00:32:07,340
+urine المحلول
+
+402
+00:32:07,950 --> 00:32:12,590
+مش بس فيه iron لأ فيه urea و الله لما يكون ال iron
+
+403
+00:32:12,590 --> 00:32:16,990
+مع ال urea مافيش عندى اي تفاعل فعلوش لكن لو اجيت
+
+404
+00:32:16,990 --> 00:32:22,550
+انا سخنت بلاحظ
+
+405
+00:32:22,550 --> 00:32:29,330
+ان ال urea بتعطينى
+
+406
+00:32:29,330 --> 00:32:34,770
+ammonium و بتعطينى hydroxide ال co2 اذا ايش طلع
+
+407
+00:32:34,770 --> 00:32:39,660
+عندىهيدروكسايد لكن وين الهيدروكسايد موجود الآن؟ في
+
+408
+00:32:39,660 --> 00:32:45,020
+كل مكان في المحلول أول حاجة بقدر أتحكم كميته من
+
+409
+00:32:45,020 --> 00:32:48,400
+الحرارة اللي أنا بحطها وبالتالي ممكن التركيز يكون
+
+410
+00:32:48,400 --> 00:32:53,780
+مخفف جدا وهذا كيو جالكيو أشمالها قليلة ولاحظوا أنه
+
+411
+00:32:53,780 --> 00:32:57,780
+مهما حاولنا نضيف شوية شوية مهما حاولنا أنه نحرك
+
+412
+00:32:57,780 --> 00:33:01,900
+هيكون التركيز عالي شوية لكن لما نشتغل بالطريقة هذه
+
+413
+00:33:01,900 --> 00:33:08,480
+المحلول موزعأو تركيز الهيدروكسيد والأيرون موزعين
+
+414
+00:33:08,480 --> 00:33:14,060
+تماما على المحلول موزعين تماما بالتساوي هذه أقل
+
+415
+00:33:14,060 --> 00:33:19,180
+كيوب ممكن نحصل عليها النتيجة بتكون better particle
+
+416
+00:33:19,180 --> 00:33:25,230
+size larger particle sizeلكن للأسف مش دائما انا
+
+417
+00:33:25,230 --> 00:33:29,390
+بقدر اعمل precipitation from homogeneous solution
+
+418
+00:33:29,390 --> 00:33:33,250
+يعني هالهيوريا بتعطيني hydroxide حلو لكن لو بدي
+
+419
+00:33:33,250 --> 00:33:37,590
+مثلا حاجة تعطيني صلفات لو بدي حاجة تعطيني مثلا
+
+420
+00:33:37,590 --> 00:33:43,070
+أسيتات لو بدي حاجة مثلا مش هلاجي أما ال hydroxide
+
+421
+00:33:43,070 --> 00:33:46,250
+أه والله سهل ان حصله من الهيوريا فانا بقول
+
+422
+00:33:46,250 --> 00:33:51,590
+precipitation from homogeneous solution دائما بين
+
+423
+00:33:51,590 --> 00:33:56,780
+جثينif possible هذا كلام ينشأ عنه particle size
+
+424
+00:33:56,780 --> 00:34:02,880
+جيد طيب يبقى شفنا أول خطوة كانت ال preparation of
+
+425
+00:34:02,880 --> 00:34:06,680
+solution تاني خطوة اللي هي عملت ال precipitation
+
+426
+00:34:06,680 --> 00:34:11,620
+وبيندرج تحتها ايش العوامل اللي بتأثر على ال q و ال
+
+427
+00:34:11,620 --> 00:34:17,120
+s كويس و ال quantitative precipitation
+
+428
+00:34:18,900 --> 00:34:21,300
+بعد هيك بنتكلم عن الخطوة التالتة في الـ
+
+429
+00:34:21,300 --> 00:34:24,720
+Gravimetric Analysis اللي هي بيزيشن of the
+
+430
+00:34:24,720 --> 00:34:29,480
+precipitate ايش بيزيشن of the precipitate بيزيشن
+
+431
+00:34:29,480 --> 00:34:37,220
+يعني من معناتها الهضم ايش الهضم يعني حاجات نحاول
+
+432
+00:34:37,220 --> 00:34:45,350
+نقلل من حجمهاهي الهضم حاجة نقلل من ايه؟ من الحجم
+
+433
+00:34:45,350 --> 00:34:49,990
+تبعها عملية الهضم المقصود فيها هان هي عبارة عن
+
+434
+00:34:49,990 --> 00:34:55,870
+عملية التسخين لفترة زمانية محددة من مثلا نص ساعة
+
+435
+00:34:55,870 --> 00:35:00,410
+لساعة من نص ساعة لساعة تسخين أقل من درجة الغليان
+
+436
+00:35:00,410 --> 00:35:05,590
+من نص ساعة لساعة انا حصلت على ال precipitate هي ال
+
+437
+00:35:05,590 --> 00:35:10,090
+precipitate فبروح
+
+438
+00:35:10,090 --> 00:35:15,340
+بسخنهمن نص ساعة لساعة طب ليش بيحصل أثناء عملية
+
+439
+00:35:15,340 --> 00:35:19,220
+تسخين؟ ليش أنا مضطر إن أسخن ل precipitate؟ قال آه
+
+440
+00:35:19,220 --> 00:35:25,150
+عملية كتير كتير حلوة لازم ناخد بالنا منهالو اجينا
+
+441
+00:35:25,150 --> 00:35:28,870
+تقلقنا على ال precipitate بنلاحظ انه في particles
+
+442
+00:35:28,870 --> 00:35:34,410
+كبيرة و في particles ايش مالها؟ صغيرة اثناء عملية
+
+443
+00:35:34,410 --> 00:35:38,770
+التسخين ايش اللي بيحصل؟ طبعا هذه ال particles
+
+444
+00:35:38,770 --> 00:35:42,670
+بتدوب بالحرارة مش بتدوب يعني جزئيا بتدوب لكن
+
+445
+00:35:42,670 --> 00:35:48,290
+بتقدرش تدوب و الايونات تتجمع في المحلول لا بتدوب
+
+446
+00:35:48,290 --> 00:35:51,630
+نفس الوجه بتترسم ليه؟ لأن هذا equilibrium يعني
+
+447
+00:35:51,630 --> 00:35:56,110
+مثلا ال AGCLبتعطيني a g plus و c ال minus لكن
+
+448
+00:35:56,110 --> 00:35:59,590
+المحلول مشبع بال a g plus و c ال minus عشان هيك
+
+449
+00:35:59,590 --> 00:36:04,350
+ببل هدول اللي اتفككوا جديد بيجيني a g plus و c ال
+
+450
+00:36:04,350 --> 00:36:08,070
+minus اللي بيترسبوا الفكرة ايه الفكرة انه ال
+
+451
+00:36:08,070 --> 00:36:11,810
+particle الصغير ع المال بيدوم طب و ايونات و ايش
+
+452
+00:36:11,810 --> 00:36:16,620
+بحصلها؟بدا تترثب، ترثب على particle أكبر، فالصغير
+
+453
+00:36:16,620 --> 00:36:20,900
+مع الوجد، مع الحرارة، الصغير عمال بيدوب و بيصغر، و
+
+454
+00:36:20,900 --> 00:36:24,820
+الكبير عمال بيكبر، مع الوجد، الصغير بختفي، و
+
+455
+00:36:24,820 --> 00:36:28,200
+الكبير إيه شماله؟ بيكبر، هذه أول حاجة، بنقولها
+
+456
+00:36:28,200 --> 00:36:32,620
+Ostwald ripening، Ostwald ripening، المضجostwald
+
+457
+00:36:32,620 --> 00:36:37,920
+عالم فهذا بنسميه حسب افتراح السيد ostwald بنسميه
+
+458
+00:36:37,920 --> 00:36:42,800
+احنا من بعده ostwald ripening فال A G C L زي ما
+
+459
+00:36:42,800 --> 00:36:47,480
+احنا شايفين لصغير عمال بيصغر و الكبير عمال ايه
+
+460
+00:36:47,480 --> 00:36:51,940
+بيكبر هذا الكلام بينشأ عنه particles اكبيرة مش بس
+
+461
+00:36:51,940 --> 00:36:57,200
+هيك الحرارة ايش بتعمل بتخلي حركة ال particles أسرع
+
+462
+00:36:57,200 --> 00:37:03,000
+معنى الكلام ممكن two particlesيخبطوا في بعض نتيجة
+
+463
+00:37:03,000 --> 00:37:07,220
+الحرارة، أيش بحصلهم؟ بلزجوا، يبقى في عندي حاجة
+
+464
+00:37:07,220 --> 00:37:11,300
+تسميها agglomeration أو coagulation، coagulation،
+
+465
+00:37:11,300 --> 00:37:17,400
+تجمع، agglomeration برضه تجميع، تجمع، كويس، فمش بس
+
+466
+00:37:17,400 --> 00:37:20,940
+أنه الصغير بيصغر و بتلاشى، و الكبير بيكبر، لأ، و
+
+467
+00:37:20,940 --> 00:37:24,520
+كمان الكبير بيكبر كتير نتيجة؟التصادم والـ
+
+468
+00:37:24,520 --> 00:37:28,280
+agglomeration اللي بيحصل عنها فعملية الـ Digestion
+
+469
+00:37:28,280 --> 00:37:35,760
+عملية كتير كتير كتير مفيدة ومهمة في الـ
+
+470
+00:37:35,760 --> 00:37:39,420
+Gravimetric Analysis يعني لازم .. مدام نعمل الـ
+
+471
+00:37:39,420 --> 00:37:41,660
+Gravimetric Analysis لازم نعمل الـ Digestion
+
+472
+00:37:41,660 --> 00:37:46,280
+العملية هي تتقلل نسبة الراصم لأ ليش تتقلل نسبة
+
+473
+00:37:46,280 --> 00:37:50,560
+الراصم؟ لأن ال equilibrium ايش بيقول؟ هذه مفهوم ال
+
+474
+00:37:50,560 --> 00:37:54,680
+equilibrium لما نقش يدوببتصيرش في عندي أيونات
+
+475
+00:37:54,680 --> 00:37:57,800
+دايما في المحلول لإنه في نفس الوقت اللي بيدوب جزء
+
+476
+00:37:57,800 --> 00:38:01,880
+من الراصب نفس الكمية بالظبط بتترسب لإنه عندي
+
+477
+00:38:01,880 --> 00:38:05,760
+equilibrium فهي معنى الإتزان فبتأثرش على الراصب
+
+478
+00:38:05,760 --> 00:38:13,480
+نهائيا طيب يا شباب ننتقل لمرحلة الرابعة ال
+
+479
+00:38:13,480 --> 00:38:18,020
+filtration و بعدين ال washing filtration و washing
+
+480
+00:38:18,020 --> 00:38:22,920
+بنيجي بدنا نعمل filtration لإن الراصب عندي جاهز
+
+481
+00:38:23,910 --> 00:38:28,970
+الراسب خدرت المحلول رسمت بالطريقة الصحيحة اعمل ال
+
+482
+00:38:28,970 --> 00:38:32,810
+digestion الان الراسب خلاص نازل تحت فجاعة ال
+
+483
+00:38:32,810 --> 00:38:38,650
+beaker كويس وجاهز لعملية الترشيح باشي بدي ارشح كيف
+
+484
+00:38:38,650 --> 00:38:45,000
+ارشح؟ قال والله خدوا بالكم مش عشوائي الشغل لأبقول
+
+485
+00:38:45,000 --> 00:38:49,780
+هذه بتوقف على نوع الراسب إذا كان الراسب يكفي فقط
+
+486
+00:38:49,780 --> 00:38:54,560
+عملية drying علشان أحصل على نوع formula إذا ممكن
+
+487
+00:38:54,560 --> 00:38:59,680
+أرشحه باستخدام حاجة بقولها gouche
+
+488
+00:39:07,950 --> 00:39:16,430
+هذا عبارة عن فايل من الزجاج موجود زي فريتد جلاس
+
+489
+00:39:16,430 --> 00:39:22,790
+هذه فريتد فريتد حاجة زي الفلتر يعني الزجاج مكسر
+
+490
+00:39:22,790 --> 00:39:27,630
+هيك عامل زي الفلتر بدخلش أي بدخلش ال solids يعني
+
+491
+00:39:27,630 --> 00:39:31,270
+من خلاله او ال precipitates المحلول طبعا سهل جدا
+
+492
+00:39:31,270 --> 00:39:35,290
+انه ينزل لكن ال solids بيحفظها فممكن تلاقي شكلها
+
+493
+00:39:35,290 --> 00:39:37,150
+زي هيك او تلاقي
+
+494
+00:39:40,500 --> 00:39:46,700
+شكلها زي هيك سيئة يعني هذه اسمها جوش طبعا الجوش
+
+495
+00:39:46,700 --> 00:39:50,580
+بتيجي ب numbers ممكن جوش number one جوش number two
+
+496
+00:39:50,580 --> 00:39:53,720
+جوش number three جوش number four لإنه هذا بتوقف
+
+497
+00:39:53,720 --> 00:39:58,960
+على ال porosity المفاذية يعني او المسامية لل fret
+
+498
+00:39:58,960 --> 00:40:02,020
+فممكن
+
+499
+00:40:02,020 --> 00:40:07,500
+لو دخلت معاك particles اغير الجوش خد fret تكون
+
+500
+00:40:07,500 --> 00:40:13,700
+اديجي على اي حالهذه ما اكتشف نستخدمها كمان مرة فقط
+
+501
+00:40:13,700 --> 00:40:20,560
+اذا كان ال drying رح ينشأ عنه non formula يعني
+
+502
+00:40:20,560 --> 00:40:26,540
+بقدر احصل عنه non formula بمجرد عملية التجفيف لكن
+
+503
+00:40:26,540 --> 00:40:31,560
+يا شباب لو انه عملية التجفيف بتعطيناش non formula
+
+504
+00:40:31,560 --> 00:40:34,400
+زي مثلا ال iron hydroxide
+
+505
+00:40:37,850 --> 00:40:43,210
+هذا لو جيت بدى أجففه في X H2O لو جيت بدى أجففه
+
+506
+00:40:43,210 --> 00:40:48,270
+بتبقى ال X ممكن تتحول ل Y ممكن تتحول ل A ل B ل C ل
+
+507
+00:40:48,270 --> 00:40:56,970
+D ماعرفهاش قداش عشان هيك هذا لازم ينحرج عشان
+
+508
+00:40:56,970 --> 00:41:05,140
+أحاول ال F E2O3 معروف هذا مانفعش أرشحهبجوش طب ها
+
+509
+00:41:05,140 --> 00:41:13,280
+ايه قال لازم نرشحه بورقة ترشيح ورقة ترشيح هذه
+
+510
+00:41:13,280 --> 00:41:21,660
+اسمها ايه filter paper filter paper لكن يا شباب مش
+
+511
+00:41:21,660 --> 00:41:26,240
+اي filter paper ها ايش ايش نوعها قال هذه اسمها
+
+512
+00:41:26,240 --> 00:41:33,580
+ashless filter paperashless يعني لما نيجي نحرجها
+
+513
+00:41:33,580 --> 00:41:40,120
+بتسيبش أي رماد كلها بتتبخر انا بديش اضيف اي اشي
+
+514
+00:41:40,120 --> 00:41:45,100
+للراسل بديش اضيف اي وزن للراسل عشان هيك ال filter
+
+515
+00:41:45,100 --> 00:41:48,960
+paper اللي بتستخدمها ashless filter paper نوع معين
+
+516
+00:41:48,960 --> 00:41:53,540
+من ال filter papers لما نيجي نحرجها كلها بتطير
+
+517
+00:41:53,540 --> 00:41:59,600
+بيبينلهاش اي اثر ولا اي رماد ماشي يا شباب اذا اذا
+
+518
+00:41:59,600 --> 00:42:04,760
+كان المادةتحتاج إلى حرق كيف بدي ارشحها اول بدي
+
+519
+00:42:04,760 --> 00:42:09,820
+ارشحها في ashless filter paper و بعدين بعد ما اغسل
+
+520
+00:42:09,820 --> 00:42:15,120
+بنقول ال ashless filter paper لحاجة
+
+521
+00:42:15,120 --> 00:42:21,860
+بنقولها crossable بنقولها لحاجة زي الفنجان بوتقة
+
+522
+00:42:21,860 --> 00:42:25,560
+زي الفنجان لكن طويلة شوية و الجدار تبقى هرجيجي
+
+523
+00:42:25,560 --> 00:42:29,860
+كتير بتتحمل حرارة ممكن تتحمل حرارة لغاية الف و
+
+524
+00:42:29,860 --> 00:42:37,070
+متين درجةففي البداية بحرقها حرق بسيط على النار اشي
+
+525
+00:42:37,070 --> 00:42:44,990
+خفيف الورقة هذه بتتهتك فبتنزل تحت شوية ورج و شوية
+
+526
+00:42:44,990 --> 00:42:51,330
+رماد انا شايفه و الراصد هذه لما نحرجها مثلا ستمية
+
+527
+00:42:51,330 --> 00:42:55,820
+سبعمية تمامية حسب ال procedure ألففبلاحظ ان كل
+
+528
+00:42:55,820 --> 00:43:00,000
+الورقة بتطير و الراسب بيتحول من الشكل اللاندي
+
+529
+00:43:00,000 --> 00:43:05,320
+للشكل المطلوب، اذا عملية الترشيح يمكن أن تتم
+
+530
+00:43:05,320 --> 00:43:12,780
+باستخدام جوش وهد glass جوش وهد بتنفعش إلا غير إذا
+
+531
+00:43:12,780 --> 00:43:20,550
+كان بس بدعمل drying أو باستخدامacrossable يعني
+
+532
+00:43:20,550 --> 00:43:23,810
+filter paper على أساس أشلست filter paper على أساس
+
+533
+00:43:23,810 --> 00:43:29,670
+أنه بدي أحرجها باستخدام porcelain crossable طيب
+
+534
+00:43:29,670 --> 00:43:36,410
+بنيجي بنفس الخطوة بنقول طب عملية الغسيل عادة عملية
+
+535
+00:43:36,410 --> 00:43:41,190
+الغسيل تتم باستخدام ماء مقطر مثلا خمستاشر عشرين
+
+536
+00:43:41,190 --> 00:43:46,650
+ميلبديش اغسل بلتر ولا بلترين لإنه كل ما غسلنا أكتر
+
+537
+00:43:46,650 --> 00:43:51,010
+كل ما كمية من الراصب فقدت لإن الراصب دائما مش لا
+
+538
+00:43:51,010 --> 00:43:55,230
+يشحيح الذوبان في الماء لكن لما نغسل بكمية كبيرة من
+
+539
+00:43:55,230 --> 00:43:59,970
+الماء جزء منه بنفقده وبالتالي كمية ال analyte
+
+540
+00:43:59,970 --> 00:44:05,400
+بتكون أقل من الحقيقةفاحنا بنحصل المياه مجترة 15 مل
+
+541
+00:44:05,400 --> 00:44:09,640
+ل 20 مل، نحطهم كلهم مرة واحدة ولا نحطهم على مراحل
+
+542
+00:44:09,640 --> 00:44:14,720
+مثلا خمسة خمسة خمسة؟ بنقول نعم الصح إن نحطهم على
+
+543
+00:44:14,720 --> 00:44:21,010
+مراحل أول خمسة مثلا تقريبا أول خمسة أربعة ملنحطهم
+
+544
+00:44:21,010 --> 00:44:24,550
+و بعدين نستنى لما كلهم ينزلوا، بعدين نحط الخمسة
+
+545
+00:44:24,550 --> 00:44:27,490
+اللي بعدهم لما كلهم ينزلوا، الخمسة اللي بعدهم لما
+
+546
+00:44:27,490 --> 00:44:31,330
+كلهم ينزلوا، و هكذا، لو حطناهم كلهم مرة واحدة،
+
+547
+00:44:31,330 --> 00:44:35,050
+مااستفدناش من الغسيل، الغرض من الغسيل أنه ياخد كل
+
+548
+00:44:35,050 --> 00:44:39,970
+ال adsorbed و ال excess solvent و ال adsorbed
+
+549
+00:44:39,970 --> 00:44:43,010
+material، ال excess ions، ياخدها كلها و ينزلها
+
+550
+00:44:43,010 --> 00:44:48,560
+وين؟ على ال filtrate، ينظفيغسل الراسب منها لأنها
+
+551
+00:44:48,560 --> 00:44:52,780
+بتكون adsorbed على السطح حصلها adsorbed على السطح
+
+552
+00:44:52,780 --> 00:44:58,280
+فاحنا بدنا ننزلها كيف بننزلها؟ بالميه المجطرة لكن
+
+553
+00:44:58,280 --> 00:45:03,180
+يا شباب في حالة واحدة بنغسلش بالميه المجطرة في
+
+554
+00:45:03,180 --> 00:45:07,160
+حالة واحدة بنغسلش بالميه المجطرة ايش هي هذه
+
+555
+00:45:07,160 --> 00:45:11,680
+الحالة؟ بنقول اذا كان الراسب كان عندى colloid
+
+556
+00:45:16,320 --> 00:45:22,240
+بعمله عملية agglomeration أو
+
+557
+00:45:22,240 --> 00:45:27,260
+يعني coagulation بحوله ل precipitate
+
+558
+00:45:32,150 --> 00:45:36,230
+إذا كان هذا النوع من الرواسب اللي هي colloidal
+
+559
+00:45:36,230 --> 00:45:40,090
+أصلها colloidal أصلها غروي بحولها ل precipitate
+
+560
+00:45:40,090 --> 00:45:43,670
+كيف؟ بالحرارة مثلا زي ما شوفنا بتبعدش حولناها ل
+
+561
+00:45:43,670 --> 00:45:48,870
+precipitate لكن لو حطيت عليها ميه تحصل عملية عكسية
+
+562
+00:45:48,870 --> 00:45:53,230
+الراسب بيرجع كان إلى ال colloid أو ال colloidal
+
+563
+00:45:53,230 --> 00:45:57,030
+state عملية بنقولها peptization
+
+564
+00:45:58,790 --> 00:46:03,530
+عكس ال coagulation عكس ال agglomeration عملية
+
+565
+00:46:03,530 --> 00:46:09,210
+بنقولها peptization هنشوف إيش منشأها و ليش بتحصل
+
+566
+00:46:09,210 --> 00:46:15,750
+إذا الله راد الحصة الجاية أي أسئلة يا شباب؟ فبنوجه
+
+567
+00:46:15,750 --> 00:46:18,970
+في اليوم عند النقطة هدو الحصة الجاية إذا الله راد
+
+568
+00:46:18,970 --> 00:46:19,530
+بنكمل
+
diff --git a/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/1F-jRJK6PwU_raw.json b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/1F-jRJK6PwU_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..2694486a877827df8b95ef339d1a088b7a1d4fe1
--- /dev/null
+++ b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/1F-jRJK6PwU_raw.json
@@ -0,0 +1 @@
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"text": "فإذا كان الـ precipitate اللي أنا حصلت عليه مش ثابت معنى الكلام مش راح أحصل على نتيجة حقيقية ليه؟ لأن جزء من ال precipitate بدو يكون اتكسر أو اتحول لحاجة تانية اتفاعل مع الهواء الجوي وما إلى ذلك فمعنى الكلام هذا بيقدر لأخطاء ممكن الأخطاء هذه تكون أخطاء جسيمة للغاية وتأثر على التحليل بشكل كبير خالص علشان هيك بنقول أن ال precipitate", "tokens": [5172, 28814, 15730, 25961, 2423, 39184, 23354, 8086, 13672, 1829, 41850, 11331, 36520, 2655, 47356, 37893, 38637, 16758, 2655, 20449, 1863, 7578, 2423, 28820, 10943, 37893, 12602, 39319, 5551, 5016, 36520, 15844, 8717, 31371, 7435, 3660, 11331, 38436, 4587, 10632, 32239, 3224, 22807, 5296, 33456, 10874, 11622, 38207, 9154, 2423, 23354, 8086, 47525, 2407, 7251, 30544, 1975, 2655, 4117, 3794, 2288, 34051, 1975, 2655, 5016, 12610, 5296, 5016, 26108, 3660, 6055, 7649, 10632, 1975, 2655, 5172, 995, 30241, 20449, 2423, 3224, 2407, 16606, 25724, 45865, 4032, 15042, 30731, 29910, 23275, 6156, 2304, 3615, 1863, 7578, 2423, 28820, 10943, 23758, 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بتستغرب، يعني لو تصورت أنت ال atomic weights للعناصر، كيف تم تحديدها؟ كتير من ال atomic weights اللي بتعتبر من أدق الأرقام اللي عندنا في الكيميا، ال atomic weights، دقيقة جدا", "tokens": [30241, 8592, 7649, 39896, 4117, 47525, 8315, 8717, 2655, 3615, 19528, 2423, 39184, 7427, 332, 9889, 4724, 8592, 28820, 9122, 45865, 3794, 12399, 8717, 2655, 3615, 28480, 9122, 33911, 8717, 7435, 16572, 2423, 10747, 4724, 8592, 28820, 3714, 2304, 2655, 31377, 12399, 5296, 33456, 3224, 39896, 6055, 34268, 26890, 8978, 4386, 5296, 3555, 3615, 11242, 2423, 10783, 279, 2423, 3832, 3170, 32748, 28671, 6055, 3555, 34268, 11296, 7251, 43020, 14739, 2655, 39894, 14851, 17082, 25513, 12399, 37495, 22653, 45164, 6055, 9381, 13063, 2655, 14739, 2655, 2423, 22275, 17443, 24976, 3615, 1863, 33546, 2288, 12399, 9122, 33911, 46811, 6055, 5016, 16254, 3215, 11296, 22807, 9122, 2655, 13546, 9154, 2423, 22275, 17443, 13672, 1829, 39894, 34268, 26890, 9154, 5551, 3215, 4587, 16247, 2288, 4587, 10943, 13672, 1829, 43242, 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diff --git a/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/1Z5oXJ-V1to_raw.json b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/1Z5oXJ-V1to_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..d05682f3067af2ce3b297205e549651d16b6d04e
--- /dev/null
+++ b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/1Z5oXJ-V1to_raw.json
@@ -0,0 +1 @@
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"text": "أنا بدي أكتفي بهذا القدر فيما يتعلق بهذا ال chapter و بدي أنتقل مباشرة لل chapter الخاص بال Stoichiometry ايه ده يا شباب؟ يعني بنقول stoichiometric calculations", "tokens": [10721, 8315, 4724, 16254, 5551, 4117, 2655, 41185, 39627, 15730, 25062, 3215, 2288, 8978, 15042, 7251, 2655, 30241, 4587, 39627, 15730, 2423, 7187, 4032, 4724, 16254, 14739, 2655, 4587, 1211, 3714, 3555, 33599, 25720, 24976, 7187, 33962, 33546, 20666, 745, 78, 18543, 34730, 1975, 1829, 3224, 11778, 3224, 35186, 13412, 3555, 16758, 22807, 37495, 22653, 44945, 39648, 22784, 18543, 29470, 20448], "avg_logprob": -0.2259324560722997, "compression_ratio": 1.4695121951219512, "no_speech_prob": 0.0, "words": [{"start": 790.71, "end": 791.67, "word": "أنا", "probability": 0.77587890625}, {"start": 791.67, "end": 792.07, "word": " بدي", "probability": 0.6441650390625}, {"start": 792.07, "end": 792.63, "word": " أكتفي", "probability": 0.857421875}, {"start": 792.63, "end": 792.93, "word": " بهذا", "probability": 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"probability": 0.912109375}], "temperature": 1.0}, {"id": 49, "seek": 116018, "start": 1131.42, "end": 1160.18, "text": "لكن لما نقول formula تنطبق على المراكب الايوني وتنطبق على مراكب التساهم لكن كلمة molecular او مصطلح molecular لا تنطبق الا على المراكب التساهمى لهذا السبب احنا خدال الفصل هذا او ال course هذا هنستخدم مصطلح formula which تدلل على الاتنين سواء كان مراكب تساهمى او كان مراكب ايونى هنستخدم مصطلح formula which لان هذا صح لان المراكبات الايونية ليست", "tokens": [1211, 19452, 5296, 15042, 8717, 39648, 8513, 6055, 1863, 9566, 3555, 4587, 15844, 9673, 23557, 4117, 3555, 42963, 1829, 11536, 1829, 34683, 1863, 9566, 3555, 4587, 15844, 3714, 23557, 4117, 3555, 16712, 3794, 995, 16095, 44381, 9122, 19528, 3660, 19046, 1975, 2407, 3714, 9381, 9566, 1211, 5016, 19046, 20193, 6055, 1863, 9566, 3555, 4587, 42963, 15844, 9673, 23557, 4117, 3555, 16712, 3794, 995, 16095, 7578, 46740, 15730, 21136, 3555, 3555, 1975, 5016, 8315, 16490, 3215, 6027, 27188, 36520, 23758, 1975, 2407, 2423, 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لحظة شوية ال formula بتقاش الوحدة تبعتها جال اجرام على المول او ممكن انت تقول ملي جرام على الملي مول هي هي فهي كقيمة هي واحدة بغض النظر عن الوحدة هل هي جرام على المول او ملي جرام على الملي مول سيئة", "tokens": [2304, 43020, 6055, 30544, 4724, 43042, 3224, 3714, 20292, 10874, 2288, 10943, 22807, 5296, 10721, 39896, 8717, 36178, 2423, 8513, 39894, 3615, 3555, 9640, 18871, 12174, 32640, 3660, 5296, 33456, 3224, 5296, 5016, 19913, 3660, 13412, 2407, 10632, 2423, 8513, 39894, 4587, 33599, 2423, 2407, 24401, 3660, 6055, 3555, 34268, 11296, 10874, 6027, 1975, 7435, 2288, 10943, 15844, 9673, 12610, 1975, 2407, 3714, 43020, 16472, 2655, 6055, 39648, 3714, 20292, 10874, 2288, 10943, 15844, 9673, 20292, 3714, 12610, 39896, 39896, 6156, 3224, 1829, 9122, 4587, 32640, 3660, 39896, 36764, 24401, 3660, 4724, 17082, 11242, 28239, 19913, 2288, 18871, 2423, 2407, 24401, 3660, 8032, 1211, 39896, 10874, 2288, 10943, 15844, 9673, 12610, 1975, 2407, 3714, 20292, 10874, 2288, 10943, 15844, 9673, 20292, 3714, 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اللى بيهمنا حاجة واحدة بدي اطلع على اشي واحد بدي اطلع فقط على ال millimole فقط انا اذا كان جيبت ال millimole المسألة انحلت انتهى الموضوع طيب انحاول نطلع على المسألة التالية و بديك بديك فقط اتركز معايا على السؤال و تحاول تتخيل كيف بدك تحل المسألة", "tokens": [1211, 19452, 9122, 2304, 7649, 3714, 25720, 1975, 1829, 8592, 19446, 7251, 9566, 46152, 8978, 21136, 33604, 6027, 13672, 7578, 4724, 1829, 16095, 8315, 11331, 26108, 3660, 36764, 24401, 3660, 4724, 16254, 1975, 9566, 1211, 3615, 15844, 1975, 8592, 1829, 36764, 24401, 4724, 16254, 1975, 9566, 1211, 3615, 6156, 47432, 15844, 2423, 1728, 332, 4812, 6156, 47432, 1975, 8315, 1975, 15730, 25961, 10874, 1829, 3555, 2655, 2423, 1728, 332, 4812, 9673, 3794, 10721, 37977, 16472, 5016, 1211, 2655, 16472, 47395, 7578, 9673, 2407, 11242, 45367, 23032, 1829, 3555, 16472, 5016, 995, 12610, 8717, 9566, 1211, 3615, 15844, 9673, 3794, 10721, 37977, 16712, 6027, 10632, 4032, 4724, 16254, 4117, 4724, 16254, 4117, 6156, 47432, 1975, 2655, 31747, 11622, 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2495.91, "end": 2496.47, "word": " بدنا", "probability": 0.9111328125}, {"start": 2496.47, "end": 2496.91, "word": " نحاول", "probability": 0.996826171875}, {"start": 2496.91, "end": 2497.39, "word": " انه", "probability": 0.93798828125}, {"start": 2497.39, "end": 2497.75, "word": " لا", "probability": 0.66943359375}, {"start": 2497.75, "end": 2498.15, "word": " نحفظش", "probability": 0.9150390625}, {"start": 2498.15, "end": 2498.15, "word": " ..", "probability": 0.57275390625}, {"start": 2498.15, "end": 2498.35, "word": " فش", "probability": 0.5865478515625}, {"start": 2498.35, "end": 2498.83, "word": " القوانين", "probability": 0.98779296875}, {"start": 2498.83, "end": 2499.07, "word": " القوانين", "probability": 0.9388427734375}, {"start": 2499.07, "end": 2499.19, "word": " اللى", "probability": 0.6943359375}, {"start": 2499.19, "end": 2499.73, "word": " بتعرفها", "probability": 0.875732421875}, {"start": 2499.73, "end": 2500.13, "word": " هم", "probability": 0.9560546875}, {"start": 2500.13, "end": 2500.75, "word": " القانونين", "probability": 0.84881591796875}, {"start": 2500.75, "end": 2501.03, "word": " هدول", "probability": 0.9345703125}, {"start": 2501.03, "end": 2501.13, "word": " اللى", "probability": 0.85205078125}, {"start": 2501.13, "end": 2501.25, "word": " انا", "probability": 0.673828125}, {"start": 2501.25, "end": 2501.71, "word": " علمتك", "probability": 0.945068359375}, {"start": 2501.71, "end": 2502.07, "word": " اياهم", "probability": 0.74755859375}], "temperature": 1.0}, {"id": 107, "seek": 252785, "start": 2502.73, "end": 2527.85, "text": "أه إنه ال millimole يساوي milligram على ال formula weight أو إنه ال millimole يساوي molarity of volume أنه أستخدم اللي في السؤال حسب السؤال إذا أنا أعطاك milligram إذا milligram على ال formula weight إذا أنا أعطاك molarity of volume إذا molarity of volume ماشي يا شباب طيب ابنو جافهان وإذا الله راضي الحصة اللي جاي بنكمل في أي حد عنده سؤال", "tokens": [10721, 3224, 36145, 3224, 2423, 1728, 332, 4812, 7251, 3794, 995, 45865, 38298, 15844, 2423, 8513, 3364, 34051, 36145, 3224, 2423, 1728, 332, 4812, 7251, 3794, 995, 45865, 8015, 17409, 295, 5523, 14739, 3224, 5551, 14851, 9778, 40448, 13672, 1829, 8978, 21136, 33604, 6027, 11331, 35457, 21136, 33604, 6027, 11933, 15730, 41850, 5551, 3615, 9566, 995, 4117, 38298, 11933, 15730, 38298, 15844, 2423, 8513, 3364, 11933, 15730, 41850, 5551, 3615, 9566, 995, 4117, 8015, 17409, 295, 5523, 11933, 15730, 8015, 17409, 295, 5523, 3714, 33599, 1829, 35186, 13412, 3555, 16758, 23032, 1829, 3555, 48127, 1863, 2407, 10874, 31845, 3224, 7649, 4032, 28814, 15730, 21984, 12602, 46958, 1829, 21542, 9381, 3660, 13672, 1829, 10874, 47302, 44945, 24793, 1211, 8978, 36632, 11331, 3215, 43242, 3224, 8608, 33604, 6027], "avg_logprob": -0.21961122540038402, "compression_ratio": 2.1059322033898304, "no_speech_prob": 1.2516975402832031e-06, "words": [{"start": 2502.73, "end": 2503.17, "word": "أه", "probability": 0.4876708984375}, {"start": 2503.17, "end": 2503.63, "word": " إنه", "probability": 0.4658203125}, {"start": 2503.63, "end": 2503.93, "word": " ال", "probability": 0.71484375}, {"start": 2503.93, "end": 2504.43, "word": " millimole", "probability": 0.5496419270833334}, {"start": 2504.43, "end": 2504.97, "word": " يساوي", "probability": 0.78472900390625}, {"start": 2504.97, "end": 2505.93, "word": " milligram", "probability": 0.89697265625}, {"start": 2505.93, "end": 2506.47, "word": " على", "probability": 0.654296875}, {"start": 2506.47, "end": 2506.63, "word": " ال", "probability": 0.826171875}, {"start": 2506.63, "end": 2506.95, "word": " formula", "probability": 0.230712890625}, {"start": 2506.95, "end": 2507.33, "word": " weight", "probability": 0.81787109375}, {"start": 2507.33, "end": 2507.91, "word": " أو", "probability": 0.7578125}, {"start": 2507.91, "end": 2508.39, "word": " إنه", "probability": 0.836181640625}, {"start": 2508.39, "end": 2508.93, "word": " ال", "probability": 0.53564453125}, {"start": 2508.93, "end": 2509.37, "word": " millimole", "probability": 0.8758138020833334}, {"start": 2509.37, "end": 2509.89, "word": " يساوي", "probability": 0.967041015625}, {"start": 2509.89, "end": 2510.67, "word": " molarity", "probability": 0.61865234375}, {"start": 2510.67, "end": 2510.79, "word": " of", "probability": 0.7197265625}, {"start": 2510.79, "end": 2511.09, "word": " volume", "probability": 0.95556640625}, {"start": 2511.09, "end": 2511.59, "word": " أنه", "probability": 0.6004638671875}, {"start": 2511.59, "end": 2512.27, "word": " أستخدم", "probability": 0.9600830078125}, {"start": 2512.27, "end": 2512.85, "word": " اللي", "probability": 0.809326171875}, {"start": 2512.85, "end": 2512.95, "word": " في", "probability": 0.94921875}, {"start": 2512.95, "end": 2513.51, "word": " السؤال", "probability": 0.986328125}, {"start": 2513.51, "end": 2513.83, "word": " حسب", "probability": 0.84912109375}, {"start": 2513.83, "end": 2514.29, "word": " السؤال", "probability": 0.99609375}, {"start": 2514.29, "end": 2514.61, "word": " إذا", "probability": 0.77587890625}, {"start": 2514.61, "end": 2514.79, "word": " أنا", "probability": 0.269287109375}, {"start": 2514.79, "end": 2515.05, "word": " أعطاك", "probability": 0.9572265625}, {"start": 2515.05, "end": 2515.47, "word": " milligram", "probability": 0.9892578125}, {"start": 2515.47, "end": 2515.83, "word": " إذا", "probability": 0.795166015625}, {"start": 2515.83, "end": 2516.11, "word": " milligram", "probability": 0.53759765625}, {"start": 2516.11, "end": 2516.41, "word": " على", "probability": 0.69140625}, {"start": 2516.41, "end": 2516.47, "word": " ال", "probability": 0.775390625}, {"start": 2516.47, "end": 2516.65, "word": " formula", "probability": 0.80859375}, {"start": 2516.65, "end": 2516.97, "word": " weight", "probability": 0.94140625}, {"start": 2516.97, "end": 2517.47, "word": " إذا", "probability": 0.92578125}, {"start": 2517.47, "end": 2517.63, "word": " أنا", "probability": 0.904296875}, {"start": 2517.63, "end": 2517.89, "word": " أعطاك", "probability": 0.98779296875}, {"start": 2517.89, "end": 2518.37, "word": " molarity", "probability": 0.89892578125}, {"start": 2518.37, "end": 2518.71, "word": " of", "probability": 0.83740234375}, {"start": 2518.71, "end": 2519.01, "word": " volume", "probability": 0.97802734375}, {"start": 2519.01, "end": 2519.25, "word": " إذا", "probability": 0.955078125}, {"start": 2519.25, "end": 2519.65, "word": " molarity", "probability": 0.908447265625}, {"start": 2519.65, "end": 2519.81, "word": " of", "probability": 0.888671875}, {"start": 2519.81, "end": 2520.19, "word": " volume", "probability": 0.97802734375}, {"start": 2520.19, "end": 2521.09, "word": " ماشي", "probability": 0.8494466145833334}, {"start": 2521.09, "end": 2521.21, "word": " يا", "probability": 0.97265625}, {"start": 2521.21, "end": 2521.65, "word": " شباب", "probability": 0.99169921875}, {"start": 2521.65, "end": 2522.53, "word": " طيب", "probability": 0.9523111979166666}, {"start": 2522.53, "end": 2523.01, "word": " ابنو", "probability": 0.5851236979166666}, {"start": 2523.01, "end": 2523.53, "word": " جافهان", "probability": 0.810546875}, {"start": 2523.53, "end": 2523.81, "word": " وإذا", "probability": 0.88427734375}, {"start": 2523.81, "end": 2523.99, "word": " الله", "probability": 0.9365234375}, {"start": 2523.99, "end": 2524.21, "word": " راضي", "probability": 0.8990885416666666}, {"start": 2524.21, "end": 2524.51, "word": " الحصة", "probability": 0.8533528645833334}, {"start": 2524.51, "end": 2524.63, "word": " اللي", "probability": 0.632080078125}, {"start": 2524.63, "end": 2524.75, "word": " جاي", "probability": 0.7900390625}, {"start": 2524.75, "end": 2525.35, "word": " بنكمل", "probability": 0.9305013020833334}, {"start": 2525.35, "end": 2525.95, "word": " في", "probability": 0.5771484375}, {"start": 2525.95, "end": 2526.17, "word": " أي", "probability": 0.75732421875}, {"start": 2526.17, "end": 2526.41, "word": " حد", "probability": 0.972412109375}, {"start": 2526.41, "end": 2526.93, "word": " عنده", "probability": 0.98828125}, {"start": 2526.93, "end": 2527.85, "word": " سؤال", "probability": 0.9912109375}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2529.58175, "duration_after_vad": 2455.744374999992}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/4NfLk-2cEic.srt b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/4NfLk-2cEic.srt
new file mode 100644
index 0000000000000000000000000000000000000000..d0f841063a8cda274c320410a44902aa7e06c407
--- /dev/null
+++ b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/4NfLk-2cEic.srt
@@ -0,0 +1,1931 @@
+1
+00:00:20,690 --> 00:00:24,170
+بسم الله الرحمن الرحيم الحصة الماضية يا شباب كنا
+
+2
+00:00:24,170 --> 00:00:28,850
+بدأنا نتكلم عن التحليل الوزني وشفنا أنه
+
+3
+00:00:28,850 --> 00:00:35,490
+خطوات التحليل الوزني يعني متعددة بدأنا في
+
+4
+00:00:35,490 --> 00:00:39,510
+تحضير المحلول بداية، وبعدين اتكلمنا عن
+
+5
+00:00:39,510 --> 00:00:44,010
+عملية الترسيب ذاتها، ولجأنا إلى عدة عوامل
+
+6
+00:00:44,010 --> 00:00:48,610
+أو عدة اعتبارات يجب الاهتمام بها عندما نعمل
+
+7
+00:00:48,610 --> 00:00:53,850
+ترسيبا، تحديداً نريد أن نجعل EQ أقل ما يمكن
+
+8
+00:00:53,850 --> 00:00:59,370
+ونجعل الذوبان أعلى ما يمكن، لكي نتحكم في
+
+9
+00:00:59,370 --> 00:01:05,510
+الإشباع الفائق النسبي، تكون يعني قليلة وبالتالي
+
+10
+00:01:05,510 --> 00:01:09,210
+حجم الجسيمات يزيد، بعدين اتكلمنا عن
+
+11
+00:01:09,210 --> 00:01:12,430
+الهضم وشفنا إيش أهمية العملية، أو إيش تُستخدم
+
+12
+00:01:12,430 --> 00:01:18,810
+وبعدين بعد الهضم، قلنا إنه بدنا نتكلم عن
+
+13
+00:01:18,810 --> 00:01:23,700
+الترشيح والغسل للفلتر، الترشيح
+
+14
+00:01:23,700 --> 00:01:31,680
+قلنا يتم إما باستخدام جوش أو باستخدام ورق ترشيح خالٍ من الرماد
+
+15
+00:01:31,680 --> 00:01:36,860
+هذا يتوقف على نوع الجسيم، هل الصيغة
+
+16
+00:01:36,860 --> 00:01:42,500
+التابعة له معروفة بعد التجفيف، أم غير معروفة؟
+
+17
+00:01:42,500 --> 00:01:47,020
+وبالتالي أضطر أن أعمل عملية احتراق لتحويله إلى صيغة معروفة
+
+18
+00:01:47,020 --> 00:01:52,010
+وبالتالي إما أن أعمل ترشيحاً باستخدام
+
+19
+00:01:52,010 --> 00:01:55,970
+جوش، أو أن أعمل ترشيحاً باستخدام ورق الترشيح الخالي من الرماد
+
+20
+00:01:55,970 --> 00:01:59,930
+هذا الكلام يتوقف على، هل سأعمل
+
+21
+00:01:59,930 --> 00:02:06,890
+تجفيفاً أم عملية احتراق في النهاية، فاخترت
+
+22
+00:02:06,890 --> 00:02:11,190
+كيف سأعمل الترشيح، عملت الترشيح الآن سأبدأ
+
+23
+00:02:11,190 --> 00:02:17,030
+أغسل الفلتر، نقول عادةً نغسل الفلاتر باستخدام
+
+24
+00:02:17,030 --> 00:02:22,600
+كمية قليلة من الماء المقطر، وتكون مثلاً 15-20 مل
+
+25
+00:02:22,600 --> 00:02:27,300
+إضافة الماء المقطر لا تتم كلها مرة واحدة، يعني
+
+26
+00:02:27,300 --> 00:02:31,300
+الـ 15-20 مل، لا نضعها مرة واحدة على الراسب، بل
+
+27
+00:02:31,300 --> 00:02:35,220
+نضعها على دفعات، 3-4 مل كل مرة، 5 مل
+
+28
+00:02:35,220 --> 00:02:40,800
+مثلاً مرتين، ثلاث، أربع، وبالتالي أي مادة ممتصة
+
+29
+00:02:40,800 --> 00:02:46,640
+على السطح يتم التخلص منها، لكن في حالة
+
+30
+00:02:46,640 --> 00:02:50,780
+من الحالات، لا يجب غسله بالماء المقطر
+
+31
+00:02:50,780 --> 00:02:55,140
+ نهائياً، وهي في حالة ما يكون أصل الجسيم
+
+32
+00:02:55,140 --> 00:03:00,490
+غروياً أو هلامياً، حجم الجسيم يكون صغيراً
+
+33
+00:03:00,490 --> 00:03:04,570
+جداً في البداية، نحن نجمعه عن طريق الهضم
+
+34
+00:03:04,570 --> 00:03:09,570
+الحرارة، فهو يتجمع لا شك، ويصبح راسباً، لكن لو
+
+35
+00:03:09,570 --> 00:03:16,090
+غسلناه بالماء المقطر، نلاحظ أنه يعود ثانيةً إلى
+
+36
+00:03:16,090 --> 00:03:20,790
+الحالة الغروية، عملية عكس عملية التجميع، عملية
+
+37
+00:03:20,790 --> 00:03:23,590
+التجميع نقولها تكتل أو نقولها
+
+38
+00:03:23,590 --> 00:03:28,950
+تخثر، لكن لو غسلنا بالماء المقطر سألاحظ أن
+
+39
+00:03:28,950 --> 00:03:33,210
+الراسب الذي تكون أصلاً، سيعود ثانيةً للغروي
+
+40
+00:03:33,210 --> 00:03:39,250
+بعملية تسمى تشتت، فيجب الحذر من الغسل بالماء
+
+41
+00:03:39,250 --> 00:03:44,930
+المقطر، خاصةً عندما يكون عندي أصل الراسب
+
+42
+00:03:44,930 --> 00:03:49,570
+غروياً، في الحقيقة يعني الرواسب الغروية
+
+43
+00:03:49,570 --> 00:03:55,450
+هذه تُحدث مشكلة، ليس فقط في قضية الترشيح، و يعني جداً
+
+44
+00:03:55,450 --> 00:03:58,950
+تُعاني من عملية الترشيح، بل الرواسب الغروية
+
+45
+00:03:58,950 --> 00:04:03,230
+تُحدث مشكلة لأنّ المساحة السطحية
+
+46
+00:04:03,230 --> 00:04:07,390
+التابعة لها عادةً تكون كبيرة، معنى أن المساحة السطحية كبيرة
+
+47
+00:04:07,390 --> 00:04:13,540
+يعني أنها عرضة للامتصاص السطحي
+
+48
+00:04:13,540 --> 00:04:17,060
+بشكل كبير للغاية، معناه كده أن يُتوقع أن يكون عندي
+
+49
+00:04:17,060 --> 00:04:21,640
+خطأ جسيم، إذا لم أغسل جيداً، لماذا؟ لأن عندي
+
+50
+00:04:21,640 --> 00:04:27,320
+كمية من الأيونات الممتصة على السطح بشكل كبير جداً، لماذا؟
+
+51
+00:04:27,320 --> 00:04:30,780
+لأن المساحة السطحية، زي ما ذكرت، كبيرة، تكون لل
+
+52
+00:04:30,780 --> 00:04:33,380
+الرواسب الغروية
+
+53
+00:04:34,930 --> 00:04:42,290
+وفي الحقيقة، إذا كان الراسب مثلاً، حجم
+
+54
+00:04:42,290 --> 00:04:46,150
+الجسيمات التابعة له كان جيداً، معقولاً، وقارناه ب
+
+55
+00:04:46,150 --> 00:04:48,830
+حجم جسيمات صغير، ممكن نلاحظ أن المساحة السطحية
+
+56
+00:04:48,830 --> 00:04:53,600
+تزيد مئات، بل آلاف المرات في بعض الأحيان، آلاف
+
+57
+00:04:53,600 --> 00:04:57,560
+المرات تزيد المساحة السطحية، وبالتالي أتوقع أن
+
+58
+00:04:57,560 --> 00:05:04,240
+الامتصاص يعطيني خطأ عادةً جسيم، إذا كان عندي
+
+59
+00:05:04,240 --> 00:05:08,400
+راسب غروي، عندي شيء يجب أن نتذكره
+
+60
+00:05:08,400 --> 00:05:12,520
+جيد جداً، أي راسب يا شباب، أي راسب
+
+61
+00:05:12,520 --> 00:05:18,140
+يكون له قابلية لأنه يعمل امتصاصاً لأيوناته الخاصة
+
+62
+00:05:18,140 --> 00:05:24,730
+يعني مثلاً، أنا عندي راسب من كلوريد الفضة
+
+63
+00:05:24,730 --> 00:05:29,670
+ما هي أيوناته؟ الفضة أو الكلوريد، هذا
+
+64
+00:05:29,670 --> 00:05:33,490
+الراسب له قابلية أنه يعمل امتصاصاً لأيوناته الخاصة
+
+65
+00:05:33,490 --> 00:05:37,950
+الموجودة بزيادة، أشوف أيّ أيون موجود
+
+66
+00:05:37,950 --> 00:05:42,110
+بوفرة، وأقوم بامتصاصه، هو الأيون الموجود بوفرة
+
+67
+00:05:42,110 --> 00:05:45,630
+أقوم بامتصاصه على السطح، الأيون الثاني طبعاً لن يكون
+
+68
+00:05:45,630 --> 00:05:50,170
+موجوداً، لماذا؟ لأن وجود الاثنين معاً يعطي راسباً، فهو
+
+69
+00:05:50,170 --> 00:05:54,070
+دائماً عندي أيون واحد فقط موجود بوفرة، هذا الأيون
+
+70
+00:05:54,070 --> 00:05:58,490
+الذي يوجد بوفرة، ماذا يعطيني؟ طبقة امتصاصية
+
+71
+00:05:58,490 --> 00:06:03,710
+أسميها أنا طبقة الأيونات الأولية، أو امتصاص أولي
+
+72
+00:06:03,710 --> 00:06:08,630
+هذه الطبقة من أيونات الراسب نفسه
+
+73
+00:06:08,630 --> 00:06:13,210
+فمثلاً، لو عندي كلوريد الفضة، الفضة طبعاً
+
+74
+00:06:13,210 --> 00:06:16,630
+موجبة، والكلوريد سالبة، أنا أضع الفضة على
+
+75
+00:06:16,630 --> 00:06:20,790
+الكلوريد، سألاحظ طالما هذا، أثناء عملية الترسيب
+
+76
+00:06:20,790 --> 00:06:25,680
+لا يزال عندي كلوريد في المحلول، لماذا؟ لأنه لازلت
+
+77
+00:06:25,680 --> 00:06:29,280
+أضيف فضة، يعني لم ينتهِ الكلوريد، لذلك بما
+
+78
+00:06:29,280 --> 00:06:31,380
+أنه يوجد كلوريد في المحلول، غالبية الكلوريد
+
+79
+00:06:31,380 --> 00:06:36,260
+يكون عاملاً طبقة امتصاص أولي حول
+
+80
+00:06:36,260 --> 00:06:44,130
+جسيمات كلوريد الفضة، بينما عندما تقريباً
+
+81
+00:06:44,130 --> 00:06:49,170
+الطريقة تنتهي، وأضع زيادة من الفضة، سأجد بعض
+
+82
+00:06:49,170 --> 00:06:54,890
+أيونات الفضة موجودة حول الجسيمات من
+
+83
+00:06:54,890 --> 00:06:58,030
+كلوريد الفضة، هذا ما نسميه امتصاص أولي
+
+84
+00:06:58,030 --> 00:07:02,190
+الطبقة، طبعاً الطبقة الامتصاصية الأولية تجذب إليها
+
+85
+00:07:02,190 --> 00:07:09,340
+طبقة ثانية من الأيونات المضادة، من الأيونات المصاحبة، يعني
+
+86
+00:07:09,340 --> 00:07:13,680
+مثل كلوريد البوتاسيوم أو الصوديوم، يكون موجوداً أيضاً
+
+87
+00:07:13,680 --> 00:07:18,020
+حولها، هذه الطبقة المصاحبة للطبقة الأيونية الأولية
+
+88
+00:07:18,020 --> 00:07:22,820
+أو للطبقة الامتصاصية الأولية، نسميها عادةً
+
+89
+00:07:22,820 --> 00:07:26,980
+طبقة الأيونات المضادة، أو طبقة امتصاص ثانوية
+
+90
+00:07:26,980 --> 00:07:30,240
+عادةً تكون مُنتشرة، غير مُلتصقة بالجسيمات
+
+91
+00:07:30,880 --> 00:07:36,580
+بينما الطبقة الأيونية الأولية عادةً تكون يعني مُلتصقة
+
+92
+00:07:36,580 --> 00:07:41,840
+إلى حد كبير بالجسيمات، بينما الأيونات المضادة
+
+93
+00:07:41,840 --> 00:07:44,660
+تكون عادةً ما يسمى مُنتشرة
+
+94
+00:07:46,360 --> 00:07:54,320
+وجود الأيونات المضادة هذه، ووجود الأيونات الأولية هذه
+
+95
+00:07:54,320 --> 00:07:59,800
+يعني عندما نأتي لغسلها بالماء، ما يحصل هو أن
+
+96
+00:07:59,800 --> 00:08:06,180
+الأيونات الأولية مُلتصقة، صعب أن تتحرك، بينما الأيونات المضادة
+
+97
+00:08:06,180 --> 00:08:09,560
+قلت مُنتشرة، مُنتشرة يعني بعيدة قليلاً
+
+98
+00:08:09,560 --> 00:08:16,230
+فهذه الأيونات المضادة، يحصل لها غسل عندما نقوم بالغسل، نحن
+
+99
+00:08:16,230 --> 00:08:20,810
+نزيل الجسيمات من الأيونات المصاحبة، فماذا يحدث
+
+100
+00:08:20,810 --> 00:08:25,730
+عليها؟ أيونات لها نفس الشحنة، مثلاً لها كلوريد
+
+101
+00:08:27,110 --> 00:08:30,330
+جسيم كلوريد، عليه من الطبقة الخارجية أو
+
+102
+00:08:30,330 --> 00:08:32,730
+الطبقة الامتصاصية هي عبارة عن كلوريد، وجسيم
+
+103
+00:08:32,730 --> 00:08:35,510
+ثاني أيضاً عليه طبقة خارجية من الكلوريد
+
+104
+00:08:35,510 --> 00:08:38,710
+شحنته سالبة، وشحنته سالبة، بعدها كلهم يبدو ماذا
+
+105
+00:08:38,710 --> 00:08:44,110
+يتنافران، بعد ما كان يعني جسيمات متجمعة، إذا كان
+
+106
+00:08:44,110 --> 00:08:48,230
+غسلت بالماء المقطر فوراً، ألاحظ أن الجسيمات تبعد عن
+
+107
+00:08:48,230 --> 00:08:53,530
+بعضها، لأن بينها تنافر، طيب، فماذا سأغسل، إذا
+
+108
+00:08:53,530 --> 00:08:56,690
+كان عندي أصل الجسيم غروياً، أنا تعبت وأنا
+
+109
+00:08:56,690 --> 00:09:00,190
+أجمعه، تعبت وأنا أحاول أن أعمل تخثراً أو
+
+110
+00:09:00,190 --> 00:09:04,650
+تكتلاً بالحرارة، أو بإضافة مثلاً إلكتروليت قوي
+
+111
+00:09:04,650 --> 00:09:08,980
+على سبيل المثال، لكني مضطر أن أغسل
+
+112
+00:09:08,980 --> 00:09:14,300
+ وإلا أكيد الوزن سيكون أكبر من
+
+113
+00:09:14,300 --> 00:09:18,300
+الحقيقة، لأنه عليه كمية من المادة الممتصة
+
+114
+00:09:18,300 --> 00:09:24,020
+فكيف سأغسله؟  نستخدم عادة حمض نيتريك مخفف
+
+115
+00:09:24,020 --> 00:09:29,370
+نستخدم عادة حمض نيتريك مخفف، لماذا تحديداً حمض نيتريك مخفف؟
+
+116
+00:09:29,370 --> 00:09:33,390
+لأنه الحمض النيتريك المخفف، مثلاً، لماذا؟ لأنه
+
+117
+00:09:33,390 --> 00:09:38,750
+الحمض النيتريك المخفف عندما نأتي لعملية التجفيف عند حرارة عالية، يتطاير
+
+118
+00:09:38,750 --> 00:09:42,990
+وبالتالي، ليس لديه حتى لو بقي  قليل من الحمض النيتريك
+
+119
+00:09:42,990 --> 00:09:46,630
+على الراسب، عندما نأتي لعمل التجفيف أو
+
+120
+00:09:46,630 --> 00:09:51,070
+الاحتراق، ماذا سيحدث له؟ سيتطاير، وبالتالي لن يكون له
+
+121
+00:09:51,070 --> 00:09:56,740
+وجود، لأنه متطاير، لذلك نقول إنه إذا كان أصل
+
+122
+00:09:56,740 --> 00:10:05,430
+الراسب غروياً، الأصل ألا نقوم بأي غسل
+
+123
+00:10:05,430 --> 00:10:09,230
+باستخدام الماء المقطر، بل يجب استخدام شيء مثل
+
+124
+00:10:09,230 --> 00:10:15,450
+حمض النيتريك المخفف، الآن نأتي للخطوة التي بعد عملية
+
+125
+00:10:15,450 --> 00:10:20,210
+الغسل، أنا الآن حضرت المحلول، وعملت الترسيب،
+
+126
+00:10:20,210 --> 00:10:24,890
+وعملت الهضم، وعملت الترشيح باستخدام الأداة
+
+127
+00:10:24,890 --> 00:10:29,270
+المناسبة، جوش أو ورق ترشيح، غسلت الفلتر
+
+128
+00:10:29,270 --> 00:10:34,240
+صار نظيفاً، الآن ماذا سأفعل؟ سآخذه إلى الفرن، كان
+
+129
+00:10:34,240 --> 00:10:39,160
+جوش، فنأخذه إلى فرن التجفيف، أنا أعمل التجفيف
+
+130
+00:10:39,160 --> 00:10:44,460
+تقريباً، يعني عادةً من 120 إلى 150 درجة لمدة ساعة زمنية
+
+131
+00:10:44,460 --> 00:10:50,120
+مثلاً، يبقى أعمل التجفيف عند حرارة 120 إلى 150 درجة
+
+132
+00:10:50,120 --> 00:10:55,830
+في العادة لمدة ساعة من الزمن تقريباً، وإذا كان
+
+133
+00:10:55,830 --> 00:11:01,390
+أريد أن أحرق، ففي البداية أحرق الورقة باستخدام لهب، أضع
+
+134
+00:11:01,390 --> 00:11:05,050
+الورقة في بوتقة البورسلين، وأسخن
+
+135
+00:11:05,050 --> 00:11:08,910
+بوتقة البورسلين هذه باستخدام لهب قليلاً قليلاً
+
+136
+00:11:08,910 --> 00:11:15,310
+إلى أن تتهتك الورقة، عندما تتهتك الورقة جيداً، أحمل
+
+137
+00:11:15,310 --> 00:11:19,150
+البوتقة، وأضعها في فرن الاحتراق، أو الذي نسميه
+
+138
+00:11:19,150 --> 00:11:25,370
+فرن المقاومة، فرن المقاومة، هذا فرن
+
+139
+00:11:25,370 --> 00:11:30,380
+للاحترق، فرن الاحتراق أنا أحرق فيه باستخدام حرارة من
+
+140
+00:11:30,380 --> 00:11:35,360
+600 إلى 1200 درجة، يبقى فرن الاحتراق أستخدم
+
+141
+00:11:35,360 --> 00:11:39,600
+حرارة من 600 إلى 1200 درجة، هذه هي الجوش التي
+
+142
+00:11:39,600 --> 00:11:42,620
+أستخدمها للتجفيف، 120 إلى 150
+
+143
+00:11:42,620 --> 00:11:46,440
+درجة، تتحمل حتى حوالي 250 درجة، لكن بعد ذلك
+
+144
+00:11:46,440 --> 00:11:50,700
+ممكن أن يحصل بها مشكلة، بينما البوتقات هذه
+
+145
+00:11:50,700 --> 00:11:54,780
+بوتقات البورسلين تتحمل حرارة يعني 1200
+
+146
+00:11:54,780 --> 00:11:58,870
+درجة، عادي، ليس مشكلة، تكون يعني مُشتعلة مثل النار يعني
+
+147
+00:11:58,870 --> 00:12:01,750
+حُمراء اللون، لا مشكلة، لكنها تبقى صالحة
+
+148
+00:12:01,750 --> 00:12:09,930
+للاستخدام مئات المرات، هذا هو شكل فرن التجفيف،
+
+149
+00:12:09,930 --> 00:12:13,010
+فرن التجفيف هو الذي يُجفف فيه أدواتك الزجاجية
+
+150
+00:12:13,010 --> 00:12:16,370
+لو عندك أدوات زجاجية تريد أن تُجففها، ستضعها أين؟ في
+
+151
+00:12:16,370 --> 00:12:20,550
+فرن التجفيف، يشبه كثيراً من ناحية العمل الأفران التي
+
+152
+00:12:20,550 --> 00:12:24,010
+في السوق، أفران كهربائية التي تُباع في السوق، جيد؟
+
+153
+00:12:24,010 --> 00:12:30,100
+تابع ماذا؟ نعم، نعم، نعم، بالضبط، فرن كهربائي، ليس شرطاً
+
+154
+00:12:30,100 --> 00:12:33,960
+بالآلاف، أو لا، فرن كهربائي تشتريه مثل جهاز مثل
+
+155
+00:12:33,960 --> 00:12:42,480
+الميكروويف، لكن فيه ... فيه يعني حساسات حرارية يعني
+
+156
+00:12:42,480 --> 00:12:46,840
+فهذا هو فرن التجفيف، سهل جداً، يستخدم حتى
+
+157
+00:12:46,840 --> 00:12:50,000
+250 درجة، ليس أكثر من، ليس لابد أن استخدمه لأكثر من
+
+158
+00:12:50,000 --> 00:12:50,840
+250 درجة
+
+159
+00:12:55,740 --> 00:12:59,880
+هذا الشكل، هذا اسمه فرن المقاومة، لاحظ أنه حتى
+
+160
+00:12:59,880 --> 00:13:05,480
+المكان حجمه ضيق، يسع عادةً كم من، عادةً كم من
+
+161
+00:13:05,480 --> 00:13:11,190
+البوتقة، ليس كثيراً، الحرارة طبعاً هائلة، تصل إلى 1200 درجة
+
+162
+00:13:11,190 --> 00:13:14,990
+طبعاً لا أحد يحاول أن يضع البوتقة في يده بداخل،
+
+163
+00:13:14,990 --> 00:13:21,690
+لا يوجد فيه مُمسك طويل، ملاقط طويلة، تمسك ... ما اسمه
+
+164
+00:13:21,690 --> 00:13:24,670
+البوتقة، فيه، وتضعها، مثلاً، ونفس الكلام عندما
+
+165
+00:13:24,670 --> 00:13:29,970
+تأتِي لرفعها جيداً، هذا الشكل يُريك كيف تُحرق الورقة
+
+166
+00:13:29,970 --> 00:13:34,810
+إذا كان طبعاً بها الراسب، ليس مرة واحدة تضعها في
+
+167
+00:13:34,810 --> 00:13:37,940
+الفرن مباشرةً، لماذا؟ لأن لو وضعتها مرة واحدة في
+
+168
+00:13:37,940 --> 00:13:40,980
+الفرن، ودرجة حرارة عالية وهي لا تزال بها الراسب، ليس فقط
+
+169
+00:13:40,980 --> 00:13:44,860
+لا تُشتعل، ليس مشكلة، لو اشتعلت المشكلة أنها بها مذيب
+
+170
+00:13:44,860 --> 00:13:48,960
+كله سيحدث له عملية تناثر، لأن المذيب يخرج كله
+
+171
+00:13:48,960 --> 00:13:53,600
+مرة واحدة، من حرارة الغرفة إلى
+
+223
+00:17:54,820 --> 00:17:59,980
+يعني نص ساعة لساعة digestion برضه هذا كلام أيه
+
+224
+00:17:59,980 --> 00:18:03,820
+بياخد وقت بعد هيك بتنتقل لعملية الترشيح طبعا بتاخد
+
+225
+00:18:03,820 --> 00:18:08,200
+وقت عملية الغسيل برضه بتاخد وقت .. بدلا لو كان ال
+
+226
+00:18:08,200 --> 00:18:11,980
+particle size صغير شوية بتغلب عملية الترشيح وعملية
+
+227
+00:18:11,980 --> 00:18:15,080
+الغسيل يعني كل هذه الخطوات بتاخد وقت .. لكن
+
+228
+00:18:15,080 --> 00:18:18,080
+ما بديش أتكلم عن الوقت هذا أنا .. أنا بتكلم بس
+
+229
+00:18:18,080 --> 00:18:22,220
+عن الوقت المخصص للأوزان، بقول أنا علشان أعمل
+
+230
+00:18:22,220 --> 00:18:26,480
+gravimetric analysis بحاجة لجوش أو لـ crucibles
+
+231
+00:18:26,480 --> 00:18:30,800
+تكون معروفة الوزن، بدي أوزنها أعرف وزنها بعدين بدي
+
+232
+00:18:30,800 --> 00:18:35,220
+أحط فيها الراسب وأوزنها ثانياً، بأخذ الفرق اللي
+
+233
+00:18:35,220 --> 00:18:38,500
+هو عبارة عن وزن الراسب، بيكون فلما بدي آجي أبدأ
+
+234
+00:18:38,500 --> 00:18:43,900
+أشتغل مثلاً بدي أعمل تحليل و أكون مثلاً بدي آخذ
+
+235
+00:18:43,900 --> 00:18:48,220
+ثلاثة crucibles، ليش ثلاثة؟ لأن أنا عامل بعمل
+
+236
+00:18:48,220 --> 00:18:51,640
+التجربة ثلاث مرات علشان نسبة الخطأ يكون عندي قليلة
+
+237
+00:18:51,640 --> 00:18:55,460
+في النهاية بأخذ الـ average، كويس؟ فبأخذ ثلاثة
+
+238
+00:18:55,460 --> 00:19:00,160
+crucibles، بدي في الأول أنظفهم، طيب نظفتهم بذل
+
+239
+00:19:00,160 --> 00:19:03,360
+مجهود كبير في تنظيفهم خاصة لو كان فيهم مواد مش
+
+240
+00:19:03,360 --> 00:19:07,440
+دايبة كويس أو مواد على الجدران، بحب أن الـ الـ
+
+241
+00:19:07,440 --> 00:19:10,680
+الجوش اللي بشتغل فيها أو الـ crucibles تكون نظيفة
+
+242
+00:19:10,680 --> 00:19:13,980
+مئّة في المئة، فنظفتهم هذا الكلام أخذ مني وقت قد
+
+243
+00:19:13,980 --> 00:19:17,520
+اضطريت أن أضيف أو أستخدم بعض الـ acids مثلاً
+
+244
+00:19:17,520 --> 00:19:22,540
+concentrated أو ما شابه، فهذا الكلام هيأخذ مني وقت،
+
+245
+00:19:22,540 --> 00:19:25,480
+بعدين غسلتهم في النهاية بمية مقطرة مئة في المئة
+
+246
+00:19:25,480 --> 00:19:29,500
+وقلت والله بدي أوزنهم، فجبت الميزان وزنتهم وحطيتهم بالفرن
+
+247
+00:19:29,500 --> 00:19:34,810
+بجففهم بالفرن، بدخلهم في الفرن لمدة ساعة، بتكون أيه
+
+248
+00:19:34,810 --> 00:19:39,210
+مثلاً عند حرارة 120 ولا 150 درجة، بتوقع أنه تكون أيه
+
+249
+00:19:39,210 --> 00:19:43,690
+نشفتهم خلاص، بأخذها وبحطها في الـ desiccator
+
+250
+00:19:43,690 --> 00:19:47,390
+اللي شفناه قبل شوية، لما بتنزل في أيه في حرارة
+
+251
+00:19:47,390 --> 00:19:51,390
+الغرفة، بانتظر كمان عشر دقائق، بأخذها وبأوزنها، عرفت
+
+252
+00:19:51,390 --> 00:19:56,650
+الوزن، بسجل الوزن، غير صالحة للعمل لسه، بدخلها ع
+
+253
+00:19:56,650 --> 00:20:00,890
+الفرن كمان مرة، ليه؟ لأنه بس بدي أتأكد أنا إذا كان
+
+254
+00:20:00,890 --> 00:20:03,970
+بالفعل هي جافة ولا لأ، بأخذها على الفرن، بحطها نص
+
+255
+00:20:03,970 --> 00:20:07,610
+ساعة، بأخذها من الفرن، بحطها في الـ desiccator عشر
+
+256
+00:20:07,610 --> 00:20:11,130
+دقائق، بأخذها بعد هيك وبأوزنها، والله إذا كان
+
+257
+00:20:11,130 --> 00:20:15,930
+الوزنتين متطابقتين، إذا الشغل صحيح، بإمكاني أقول اه
+
+258
+00:20:15,930 --> 00:20:21,190
+هذه وزن الجوش، لكن لو لاقيت فيه تغيير في الوزن بعرف
+
+259
+00:20:21,190 --> 00:20:24,490
+أنه في عندي مشكلة، بدي أرجعها على الفرن كمان مرة
+
+260
+00:20:24,490 --> 00:20:30,090
+ولاازم أطلع وزنتين متتاليتين متساويتين، غير هيك
+
+261
+00:20:30,090 --> 00:20:33,310
+بيكون في عندي مشكلة، اتصوروا كده عمال بياخد مني وقت
+
+262
+00:20:33,310 --> 00:20:39,580
+ونفس الكلام بعد عملية الغسيل، غسلت الراسب، بدي آخذ
+
+263
+00:20:39,580 --> 00:20:44,300
+الـ crucible أو الجوش هي والراسب، وأحطها في
+
+264
+00:20:44,300 --> 00:20:48,300
+الفرن، بحطها في الفرن برضه لمدة ساعة على الـ
+
+265
+00:20:48,300 --> 00:20:52,680
+desiccator عشر دقائق، بوزنها، برجعها تاني على الفرن
+
+266
+00:20:52,680 --> 00:20:56,880
+يبقى مش أقل من خمس ساعات توزين بالضبط خمس ساعات
+
+267
+00:20:56,880 --> 00:21:02,380
+على الأقل، هذا غير الـ precipitation نفسها وغير
+
+268
+00:21:02,380 --> 00:21:07,010
+تحضير المحلول، فمعنى الكلام بالفعل لـ Gravimetric
+
+269
+00:21:07,010 --> 00:21:09,690
+Analysis أو الـ procedure طويل
+
+270
+00:21:14,360 --> 00:21:17,040
+نتكلم عن الـ calculation، الـ calculations في الـ
+
+271
+00:21:17,040 --> 00:21:20,680
+gravimetric analysis مش أبسط من هيك، بسيطة جداً جداً
+
+272
+00:21:20,680 --> 00:21:25,420
+جداً، تستخدم مفهوم واحد بنقوله gravimetric factor
+
+273
+00:21:25,420 --> 00:21:30,900
+احنا مش هنستخدم هذا المفهوم، هنرجع لكم بعد شوية ليش
+
+274
+00:21:30,900 --> 00:21:36,460
+هنستخدم بس الـ minimal concept اللي احنا متعودين
+
+275
+00:21:36,460 --> 00:21:40,780
+عليه، والحمدلله، المسألة تكون Gravimetric ولا
+
+276
+00:21:40,780 --> 00:21:41,520
+غير غير غير غير غير غير غير غير غير غير غير
+
+277
+00:21:41,520 --> 00:22:03,500
+غيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغير
+
+278
+00:22:03,520 --> 00:22:07,760
+الآن قبل ما نتحرك ونشوف الـ calculations اللي خاطر
+
+279
+00:22:07,760 --> 00:22:12,560
+أنه أطلع على الـ impurities اللي ممكن تكون موجودة
+
+280
+00:22:12,560 --> 00:22:16,800
+في الـ precipitates واللي ممكن تسبب أخطاء جسيمة
+
+281
+00:22:16,800 --> 00:22:21,300
+بقول في عندي أربعة أنواع من أنواع الـ impurities
+
+282
+00:22:21,300 --> 00:22:26,540
+لازم آخذ بالي منها، أول نوع بقوله occlusion
+
+283
+00:22:29,530 --> 00:22:34,450
+بنقول في الـ occlusion بعض مكونات المحلول يتم
+
+284
+00:22:34,450 --> 00:22:40,710
+احتجازها أو حبسها داخل الـ particle، داخل الـ
+
+285
+00:22:40,710 --> 00:22:50,110
+particle، يعني عند الـ particle بينمو و
+
+286
+00:22:50,110 --> 00:22:58,080
+بيحجز داخله أي جزء من المحلول، هذا الجزء اللي حجزه
+
+287
+00:22:58,080 --> 00:23:01,400
+من المحلول موجود فيه، مش بس solvent لأ موجود فيه
+
+288
+00:23:01,400 --> 00:23:07,900
+أيونات، فممكن يؤدي هذا الكلام لأخطاء، قبل أن أتحدث عن
+
+289
+00:23:07,900 --> 00:23:11,680
+الخطأ، أريد أن أقول، لماذا يحصل أشياء مثلها؟ لماذا
+
+290
+00:23:11,680 --> 00:23:14,280
+يحصل الـ Occlusion؟ بقول، يحصل الـ Occlusion بشكل
+
+291
+00:23:14,280 --> 00:23:19,500
+أساسي، إذا كان تم إضافة الـ precipitating agent على
+
+292
+00:23:19,500 --> 00:23:24,880
+الـ analyte بسرعة، مرة واحدة، ساعتها الـ particles تنمو
+
+293
+00:23:24,880 --> 00:23:29,100
+نمو سريع في كافة الإتجاهات، أثناء عملية النمو
+
+294
+00:23:29,100 --> 00:23:35,000
+السريع، ممكن يتم تكوين بُقَع أو مناطق داخل الـ
+
+295
+00:23:35,000 --> 00:23:39,400
+particle، هذه حجزت شوية من الـ medium اللي هي موجودة
+
+296
+00:23:39,400 --> 00:23:45,140
+فيه، فهنا مثلاً لو أنا برسب الـ chloride باستخدام الـ
+
+297
+00:23:45,140 --> 00:23:48,220
+silver، هي عندي chloride وأنا بضيف عليه silver
+
+298
+00:23:48,220 --> 00:23:53,200
+فتكون AgCl AgCl AgCl
+
+299
+00:23:56,090 --> 00:24:01,130
+شوية فراغ موجود فيه شوية من الـ medium، فإذا كان في
+
+300
+00:24:01,130 --> 00:24:04,730
+عندي هنا بعض الـ chloride مش متفاعل، يعني مثلاً زي الـ
+
+301
+00:24:04,730 --> 00:24:09,890
+NaCl، ما تفاعلش، ليش ما تفاعلش؟ لأنه ما لاقاش silver، هيلقى
+
+302
+00:24:09,890 --> 00:24:13,710
+انحجز جوا الـ chloride، محجوز في هذه الغرفة داخل هذا
+
+303
+00:24:13,710 --> 00:24:18,390
+البناء، لكن الـ silver might rate وين موجودة برا
+
+304
+00:24:18,390 --> 00:24:25,900
+ما تقدرش تعدى لأنه في جدران، ما بتقدر تعدى كويس، يبقى هذا
+
+305
+00:24:25,900 --> 00:24:28,220
+هيضل صوديوم كلوريد، الصوديوم كلوريد
+
+306
+00:24:28,220 --> 00:24:35,120
+الـ formula weight 58.5، لكن هذه الكلوريد الأصل أيش
+
+307
+00:24:35,120 --> 00:24:40,980
+أعطتني الأصل بتحول لأيش؟ الكلوريد في الأصل لـ silver
+
+308
+00:24:40,980 --> 00:24:46,720
+كلوريد، طيب قد ايش الـ formula weight للـ silver chloride جال
+
+309
+00:24:46,720 --> 00:24:51,980
+143، يبقى بدل ما الكلوريد هذه تعطيني 143 أيش
+
+310
+00:24:51,980 --> 00:24:57,230
+أعطتنِ 58.5، إذا هذا خطأ، أيه شغله؟
+
+311
+00:24:57,230 --> 00:25:01,230
+خطأ سالب، خطأ، يعني دي خطأ بدل ما تعطيني
+
+312
+00:25:01,230 --> 00:25:06,150
+formula weight 143 تتحول لـ silver chloride، جزء من
+
+313
+00:25:06,150 --> 00:25:09,750
+الكلوريد أيش ضال؟ ضال كلوريد زي ما هو، يعني
+
+314
+00:25:09,750 --> 00:25:13,970
+sodium chloride مثلاً، الـ counter ion تبعه، أعطانا 58
+
+315
+00:25:13,970 --> 00:25:19,230
+.5، فمن المفترض 143 أعطانا 58.5، ليه؟ لأنه تم
+
+316
+00:25:19,230 --> 00:25:24,070
+احتجازه جوا ومش لاقي Silver يتفاعل معه، هذه حاجة
+
+317
+00:25:24,070 --> 00:25:29,590
+ممكن، حاجة تانية، نقول اه والله تم احتباس كمية
+
+318
+00:25:29,590 --> 00:25:34,210
+معينة من الـ silver nitrate، كان فيه chloride اتفاعلت
+
+319
+00:25:34,210 --> 00:25:38,070
+معها وضال كمية من الـ silver nitrate داخل الـ
+
+320
+00:25:38,070 --> 00:25:42,790
+particle، هذا الـ silver nitrate مش بينفع، هي اتفاعل
+
+321
+00:25:42,790 --> 00:25:47,110
+معها، الأصل إنها ما تكونش موجودة، مش هيك ولا لأ؟ إذا
+
+322
+00:25:47,110 --> 00:25:53,270
+هذا كده أيش هيعطيني؟ formula weight 170، هذه مجرد ما أجفف
+
+323
+00:25:53,270 --> 00:25:58,520
+بخار الـ solvent بيطلع، ما فيش مشكلة، بيطلع الـ solvent
+
+324
+00:25:58,520 --> 00:26:02,160
+لكن المادة الـ silver nitrate اتحول لـ solid silver
+
+325
+00:26:02,160 --> 00:26:06,620
+nitrate، طب هذ أعطتني formula weight 170، إذا في عندي زيادة
+
+326
+00:26:06,620 --> 00:26:09,520
+في الوزن يبقى الـ occlusion ممكن والله يحصل
+
+327
+00:26:09,520 --> 00:26:14,580
+occlusion للـ medium، شوية من الـ analyte أو شوية
+
+328
+00:26:14,580 --> 00:26:18,900
+من الـ precipitating agent، في بعض الأحيان بحصل على
+
+329
+00:26:18,900 --> 00:26:21,220
+negative error وفي بعض الأحيان الأخرى بحصل على
+
+330
+00:26:21,220 --> 00:26:26,370
+positive error، طيب، هل يمكن التغلب على هذه المشكلة
+
+331
+00:26:26,370 --> 00:26:30,610
+بإني أغسل كويس؟ لأ، لأن غرفة مسكرة، مهما حاولت
+
+332
+00:26:30,610 --> 00:26:34,150
+تغسلها من برا، اللي جوا باقي أيه؟ باقي جوا، ما
+
+333
+00:26:34,150 --> 00:26:37,250
+بتتغير، طب، ها أيه أيش بدي أسوي؟ قال، بدي أهدم
+
+334
+00:26:37,250 --> 00:26:41,150
+الجدران علشان أحصل على اللي جوا، يعني بدي أدوب
+
+335
+00:26:41,150 --> 00:26:46,350
+الراسب وبعدين بدي أعيد ترسيبه مرة تانية، شوية شوية
+
+336
+00:26:46,350 --> 00:26:50,450
+عشان ما يحصلش عندي occlusion، بس ما بصلح الـ occlusion
+
+337
+00:26:50,450 --> 00:26:55,970
+بعملية غسيل عادية، لأ، ما ينفعش، ماشي يبقى الـ
+
+338
+00:26:55,970 --> 00:26:59,430
+inclusion يا إما بضيف لي positive يا negative error
+
+339
+00:26:59,430 --> 00:27:04,530
+في نوع ثاني من الأخطاء، حاجة بنقولها inclusion
+
+340
+00:27:04,530 --> 00:27:08,870
+شبيهة في الاسم بالـ occlusion لكن مفهومها مختلف
+
+341
+00:27:08,870 --> 00:27:14,170
+تماماً، الـ inclusion هو عبارة عن replacement
+
+342
+00:27:16,420 --> 00:27:21,240
+لأيون من الأيونات بأيون آخر، replacement يعني أنا
+
+343
+00:27:21,240 --> 00:27:26,520
+عندي crystal أو في عندي precipitate، الـ precipitate
+
+344
+00:27:26,520 --> 00:27:30,360
+له formula معينة، الـ formula عبارة عن عدة أيونات
+
+345
+00:27:31,470 --> 00:27:35,430
+نوع معين من الأيونات، بعضه يتم استبداله بأيون
+
+346
+00:27:35,430 --> 00:27:40,610
+آخر، الأيون هذا عشان يستبدل أيون ثاني، المفروض أن
+
+347
+00:27:40,610 --> 00:27:45,390
+الأيونين يكونوا متشابهين في الشحنة ومتشابهين في
+
+348
+00:27:45,390 --> 00:27:50,390
+الحجم، يعني مثلاً وأنا برسب المغنيسيوم على هيئة
+
+349
+00:27:50,390 --> 00:27:54,510
+magnesium ammonium phosphate، وأنا برسب المغنيسيوم
+
+350
+00:27:54,510 --> 00:28:01,870
+على هيئة magnesium ammonium phosphate، مثلاً، بلاحظ أن
+
+351
+00:28:01,870 --> 00:28:06,890
+لو في عندي أي كمية من البوتاسيوم، بعض الـ
+
+352
+00:28:06,890 --> 00:28:10,970
+potassium بيحل محل الـ ammonium، ليه؟ لأن الـ
+
+353
+00:28:10,970 --> 00:28:17,910
+potassium والـ ammonium، أول حاجة، اللي هم نفس
+
+354
+00:28:17,910 --> 00:28:24,830
+الشحنة، بعدين الحجم، الأيونات هي لهم واحد تقريباً، شبهين
+
+355
+00:28:24,830 --> 00:28:29,350
+جداً، عشانك سهل خالص أن البوتاسيوم يحل محل الأمونيوم
+
+356
+00:28:29,350 --> 00:28:33,410
+أو الأمونيوم يحل محل البوتاسيوم، سهل كتير، زي بعض
+
+357
+00:28:33,410 --> 00:28:37,470
+طيب الآن إذا كان أنا برسب المغنيسيوم أمونيوم
+
+358
+00:28:37,470 --> 00:28:42,540
+فوسفات في وجود، في المحلول اللي موجود فيه potassium
+
+359
+00:28:42,540 --> 00:28:46,500
+يبقى بعض أيونات الـ potassium هتحل محل أيه؟ الـ
+
+360
+00:28:46,500 --> 00:28:50,700
+ammonium، طب الـ ammonium هذه 18، formula weight الـ
+
+361
+00:28:50,700 --> 00:28:55,430
+potassium 39، إذا في هذه الحالة عندي
+
+362
+00:28:55,430 --> 00:29:01,530
+positive error، قد يكون الأيون اللي بيحل محل الأيون
+
+363
+00:29:01,530 --> 00:29:07,510
+الأصلي قد يكون أقل في الـ في الـ formula weight أو
+
+364
+00:29:07,510 --> 00:29:11,640
+أكثر، معناه كده، بتوقع أنه أحصل على positive أو
+
+365
+00:29:11,640 --> 00:29:15,720
+negative error، أيضاً ممكن يكون أكثر في الـ formula weight
+
+366
+00:29:15,720 --> 00:29:19,880
+أو أقل، وبالتالي ممكن نحصل على positive أو negative
+
+367
+00:29:19,880 --> 00:29:26,940
+error، بنسمي هذا الكلام isomorphous replacement
+
+368
+00:29:26,940 --> 00:29:31,620
+الأصل أنه هل أستطيع أن أتخلص من الـ inclusion عن
+
+369
+00:29:31,620 --> 00:29:36,450
+طريق الغسيل؟ فتقول لأ، أبداً نهائياً، ليه؟ لأنه خلاص
+
+370
+00:29:36,450 --> 00:29:39,910
+الأمونيوم راح، اتكون عندي particle، الـ particle فيه
+
+371
+00:29:39,910 --> 00:29:43,450
+potassium، بعض الـ potassium بالإضافة للأمونيوم، طب
+
+372
+00:29:43,450 --> 00:29:46,830
+هاي أيش بدي أعمل؟ قال خلاص التجربة خربت، الأصل أنه
+
+373
+00:29:46,830 --> 00:29:51,090
+مدام دخل المغنيسيوم، أرجع أدوب الـ precipitate وأشتغل
+
+374
+00:29:51,730 --> 00:29:56,630
+وأشتغل باستخدام مواد أو محلول ما فيش فيه potassium
+
+375
+00:29:56,630 --> 00:30:00,190
+نهائياً، يعني مثلاً بدل ما تستخدم الـ potassium
+
+376
+00:30:00,190 --> 00:30:06,210
+phosphate عشان ترسب المغنيسيوم في وجود أمونيا، كويس؟
+
+377
+00:30:06,210 --> 00:30:11,610
+لأ، استخدم الـ sodium مثلاً، الـ sodium phosphate، ما بيحلش
+
+378
+00:30:11,610 --> 00:30:16,810
+محل الـ ammonium، ليه؟ لأنه صح له نفس الشحنة، لكن
+
+379
+00:30:16,810 --> 00:30:23,460
+حجمه أصغر، كويس؟ حجمه أصغر، ماشي يا شباب، إذا برضه الـ
+
+380
+00:30:23,460 --> 00:30:30,620
+inclusion بيعطينا خطأ فادح، عشان هيك بقول أنا يعني
+
+381
+00:30:30,620 --> 00:30:34,240
+الـ gravimetric analysis بدنا نعملها بشكل سليم
+
+382
+00:30:34,240 --> 00:30:38,020
+لازم نفهم إيش تركيب المحلول وإذا كان في عندي أيونات
+
+383
+00:30:38,020 --> 00:30:44,280
+متشابهة في الحجم والشحنة، المفروض أني أستبعدها
+
+384
+00:30:44,280 --> 00:30:49,480
+ممنوع نستخدمها، أتأكد أنه ليس عندي أيونات متشابهة
+
+385
+00:30:49,480 --> 00:30:53,360
+في الحجم وفي الشحنة وإلا بتوقع يحصل عندي
+
+386
+00:30:53,360 --> 00:30:58,760
+isomorphous replacement أو inclusion، في
+
+387
+00:30:58,760 --> 00:31:03,320
+عندي خطأ تكلمنا عنه اللي هو الـ surface adsorption
+
+388
+00:31:03,320 --> 00:31:06,700
+adsorption، هذا طبعاً خطأ، دائماً بيعطي positive error
+
+389
+00:31:07,350 --> 00:31:10,750
+دائماً بيعطيه positive،
+
+445
+00:35:38,310 --> 00:35:42,860
+analyte تساوي وزنه الراسب فيه factor اسمه
+
+446
+00:35:42,860 --> 00:35:45,640
+graphometric factor فإنّ إذا حسبت graphometric
+
+447
+00:35:45,640 --> 00:35:51,080
+factor هو factor نظريّ نحسبه حسابًا نظريًا، لا عمليًا،  يعرف على
+
+448
+00:35:51,080 --> 00:35:56,760
+طول ووزن الـ analyte  الـ A  تبعي، إذا مجرد أني أعرف وزن
+
+449
+00:35:56,760 --> 00:36:01,300
+الـ Gravimetric factor وعندي وزن الراسب، أعرف وزن
+
+450
+00:36:01,300 --> 00:36:04,680
+الـ analyte. طيب، إيش هو الـ Gravimetric
+
+451
+00:36:04,680 --> 00:36:09,060
+factor؟  فالـ Gravimetric factor هو عبارة عن A
+
+452
+00:36:09,060 --> 00:36:14,620
+على B، A على B، هذه مولار ريشيو، Stoichiometric mole
+
+453
+00:36:14,620 --> 00:36:19,580
+ratio، مضروبة في الـ formula weight للـ analyte على الـ
+
+454
+00:36:19,580 --> 00:36:22,760
+formula weight للـ precipitate. طبعًا الـ formula weight للـ
+
+455
+00:36:22,760 --> 00:36:25,580
+analyte معروفة، والـ formula weight للـ precipitate
+
+456
+00:36:25,580 --> 00:36:29,100
+طبعًا معروفة، والمولار ريشيو أيضًا معروفة. إيش هي المولار
+
+457
+00:36:29,100 --> 00:36:32,960
+ratio؟ بنقول لكم:  مثلًا لو بدي أجيب الـ
+
+458
+00:36:32,960 --> 00:36:38,260
+gravimetric factor للكلور Cl2، فالـ A will be
+
+459
+00:36:38,260 --> 00:36:44,260
+بقول:  مول كلور واحد يعطيني مولين سلفريت كلوريد. هذا هو الـ stoichiometric factor، مول
+
+460
+00:36:44,260 --> 00:36:47,660
+ratio. كويس؟ فهنا في عندي مولين كلور تحت، لازم يكون
+
+461
+00:36:47,660 --> 00:36:52,340
+عندي مولين كلور، هذا الـ A، والـ B بدي أخلي البسط عدد
+
+462
+00:36:52,340 --> 00:36:56,720
+المولات زي المقام بالنسبة للـ analyte، بس البسط زي
+
+463
+00:36:56,720 --> 00:37:01,000
+الـ A زي المقام. البسط فيه مولين كلور، المقام بده يكون
+
+464
+00:37:01,000 --> 00:37:05,200
+فيه إيه؟ مولين كلور، AgCl اللي فيه كلور واحد.
+
+465
+00:37:05,200 --> 00:37:08,760
+إذًا بدي أحط هنا اثنين، لإني عندي اثنين كلور. هذا الـ
+
+466
+00:37:08,760 --> 00:37:11,830
+stoichiometric factor مضروب هذا الكلام في الـ
+
+467
+00:37:11,830 --> 00:37:15,930
+formula weight للـ analyte اللي هو الـ Cl2 على الـ
+
+468
+00:37:15,930 --> 00:37:18,930
+formula weight للـ precipitate اللي هو الـ AgCl. الآن
+
+469
+00:37:18,930 --> 00:37:21,830
+لو بدي أجيب وزن الـ Cl2 اللي هو الـ analyte بقول
+
+470
+00:37:21,830 --> 00:37:27,150
+والله وزن الراسب في الـ gravimetric factor، سهل
+
+471
+00:37:27,150 --> 00:37:30,670
+خالص، وزن الراسب في الـ gravimetric factor سهل جدًا
+
+472
+00:37:30,670 --> 00:37:34,820
+ومباشر. كل الحلول اللي عندنا بنفس الطريقة في
+
+473
+00:37:34,820 --> 00:37:40,040
+الكتاب، لكن إحنا ما بدنا نحل بهذه الطريقة. إحنا في
+
+474
+00:37:40,040 --> 00:37:45,760
+عندنا طريقة أسهل في الحل، إتعلمناها وعرفناها، و
+
+475
+00:37:45,760 --> 00:37:50,000
+اتعودنا عليها، وما بدنا نحفظها. لازم تتذكر إيش الـ
+
+476
+00:37:50,000 --> 00:37:54,340
+gravimetric factor علشان تستخدمه. ما بدنا نتذكر حاجة.
+
+477
+00:37:54,340 --> 00:37:57,920
+إحنا، إحنا بنحل باستخدام الـ millimoles. بكتب الـ
+
+478
+00:37:57,920 --> 00:38:02,150
+analyte على جهة، والـ precipitate على جهة، وبسوّيهم.
+
+479
+00:38:02,150 --> 00:38:04,850
+بقول: analyte Cl2، هذه AgCl. إذًا أنا هنا بدي أحط اثنين،
+
+480
+00:38:04,850 --> 00:38:09,810
+صح ولا لأ؟ على طول millimol Cl2 بتساوي نص الـ
+
+481
+00:38:09,810 --> 00:38:15,030
+millimol AgCl. وأنا عارف... أنا عارف إنّ الـ
+
+482
+00:38:15,030 --> 00:38:19,090
+millimol عبارة عن milligram على الـ formula weight، أو
+
+483
+00:38:19,090 --> 00:38:22,070
+مدارة عينة.  لأنّ الـ gravimetric كله، أغلبها، ملي
+
+484
+00:38:22,070 --> 00:38:24,330
+جرام على الـ formula weight، أو طبعًا مدارة الـ volume. مفهوم؟
+
+485
+00:38:24,330 --> 00:38:27,610
+هذا الكلام المهم، برجع عن الـ millimole، يبقى انتهى
+
+486
+00:38:27,610 --> 00:38:30,930
+الموضوع. أنا ما بحاجة، بطلّع الـ milligram، millimol Cl2.
+
+487
+00:38:30,930 --> 00:38:35,630
+يعني milligram Cl2 على الـ formula weight معروفة، نص millimol
+
+488
+00:38:35,630 --> 00:38:39,490
+جرام precipitate، معروف formula weight precipitate، طبعًا
+
+489
+00:38:39,490 --> 00:38:42,650
+معروفة. إذًا، على طول الـ milligram أنا like معروفة من
+
+490
+00:38:42,650 --> 00:38:45,950
+غير ما نروح نقول: والله gravimetric factor، وإيش الـ A
+
+491
+00:38:45,950 --> 00:38:48,730
+وإيش الـ B، وإيش اللي فوق وإيش اللي تحت. هذا كله حكي
+
+492
+00:38:48,730 --> 00:38:52,720
+مش كثير بالنسبة إلينا، يعني غير جوهري في الحل. إحنا الحل
+
+493
+00:38:52,720 --> 00:38:58,480
+اللي هستخدمه millimoles، إيش بتساوي من الـ
+
+494
+00:38:58,480 --> 00:39:01,940
+millimoles؟ millimoles من الـ analyte، إيش بتساوي من الـ
+
+495
+00:39:01,940 --> 00:39:04,280
+millimoles precipitate. طيب، نيجي نتحدث في بعض الأمثلة
+
+496
+00:39:04,280 --> 00:39:13,120
+الفعليّة. أوّل مثال، إيش بيقول؟ بيقول: calculate the
+
+497
+00:39:13,120 --> 00:39:18,180
+milligram analyte to milligram precipitate. لو اللي
+
+498
+00:39:18,180 --> 00:39:21,960
+بده الـ milligram analyte كقيمة كان عطانيها، إذا كان
+
+499
+00:39:21,960 --> 00:39:25,080
+وزن الـ precipitate هالجدر، لكن هو بده نسبة، يعني آه
+
+500
+00:39:25,080 --> 00:39:29,860
+سهل، مباشرة. for the following: الفسفور in silver
+
+501
+00:39:29,860 --> 00:39:33,980
+phosphate. بده الـ milligram فسفور لـ milligram
+
+502
+00:39:33,980 --> 00:39:37,160
+silver phosphate، والـ bismuth sulfide في الـ barium
+
+503
+00:39:37,160 --> 00:39:42,900
+sulfate. ناخد واحد واحد. هو بيقول لي الفسفور في إيش؟
+
+504
+00:39:42,900 --> 00:39:49,330
+في الـ silver.  هاي الفسفور، بيعطيني silver phosphate. الـ
+
+505
+00:39:49,330 --> 00:39:52,970
+P واحدة. والـ P، إذًا الـ millimol phosphorus تساوي
+
+506
+00:39:52,970 --> 00:39:57,730
+millimol silver phosphate. إذًا milligram phosphorus
+
+507
+00:39:57,730 --> 00:40:02,370
+على الـ atomic weight، milligram silver phosphate
+
+508
+00:40:02,370 --> 00:40:06,630
+على الـ formula weight. هو بده الـ milligram على الـ
+
+509
+00:40:06,630 --> 00:40:09,610
+milligram. حطّهم، جدع، ما يطلع، يطلع. ماشي يا شباب؟ مباشر،
+
+510
+00:40:09,610 --> 00:40:14,140
+سهل، سهل، يعني بشكل مش معقول. طيب، نيجي للخطوة الثانية،
+
+511
+00:40:14,140 --> 00:40:19,560
+أو المطلوب الثاني. بده الـ milligram bismuth
+
+512
+00:40:19,560 --> 00:40:23,180
+sulfide اللي موجود في الـ barium sulfate. بقول
+
+513
+00:40:23,180 --> 00:40:26,680
+bismuth sulfide، هنا فيه تلاتة sulfur، هنا في sulfur
+
+514
+00:40:26,680 --> 00:40:31,840
+واحدة. إذًا بدي أضِيف هنا ثلاثة. بقول:  معنى الكلام يبقى
+
+515
+00:40:31,840 --> 00:40:36,060
+أنا ما عندي غير الـ millimol، ما بعرف أحل أي مسألة، أو
+
+516
+00:40:36,060 --> 00:40:39,620
+مفتاح حلّي دائمًا هو الـ millimol. انسَ إنّك تفكّر
+
+517
+00:40:39,620 --> 00:40:43,500
+بحاجة ثانية، بدّك تحل أي مسألة. بس ما دام هي
+
+518
+00:40:43,500 --> 00:40:47,260
+stoichiometric، الـ millimol بس، هذا هو. هتلاقي
+
+519
+00:40:47,260 --> 00:40:50,740
+المطلوب داخلها، من غير ما تبدأ المجهود حتى. بقول:
+
+520
+00:40:50,740 --> 00:40:55,540
+millimol bismuth sulfate بتساوي تلت الـ millimol
+
+521
+00:40:55,540 --> 00:40:58,880
+barium sulfate. إذًا إيش الـ milligram على
+
+522
+00:40:58,880 --> 00:41:03,150
+الـ formula weight؟ إيش الـ milligram على الـ formula weight؟ إذًا
+
+523
+00:41:03,150 --> 00:41:06,450
+هاي الـ milligram على الـ milligram، النتيجة، الـ ratio
+
+524
+00:41:06,450 --> 00:41:10,030
+بتطلع معناها مباشرة.
+
+525
+00:41:10,030 --> 00:41:11,810
+بتطلع معنا مباشرة.
+
+526
+00:41:14,450 --> 00:41:20,590
+طيب، نتطلع على هذا المثال. الفوسفات يا شباب، في عينة
+
+527
+00:41:20,590 --> 00:41:24,590
+وزنها 0.2711 gram was
+
+528
+00:41:24,590 --> 00:41:29,270
+precipitated، رسبناها، giving 1.1682 gram من الـ ammonia phosphomolybdate. الـ ammonia
+
+529
+00:41:29,270 --> 00:41:33,230
+phosphomolybdate هذا راسب كتير كتير حلو، لأنّ الـ
+
+530
+00:41:33,230 --> 00:41:37,090
+formula weight تبعته عالية. لو طلّعت عليها، جدع، 1876
+
+531
+00:41:37,090 --> 00:41:41,800
+عشانك، لو عندك كمية قليلة من الفوسفات بتعطيك كمية
+
+532
+00:41:41,800 --> 00:41:46,020
+كبيرة من الراسب، يعني بتقدر تعيّن كميات الفوسفات
+
+533
+00:41:46,020 --> 00:41:48,960
+موجودة بإيه؟ بكميات قليلة للغاية. طيب، ما علينا، إحنا
+
+534
+00:41:48,960 --> 00:41:54,220
+بيقول: find percentage phosphorus. جدع، عندي
+
+535
+00:41:54,220 --> 00:41:57,200
+percentage phosphorus في العينة، وكمان مطلوب كمان
+
+536
+00:41:57,200 --> 00:42:01,400
+بيقول لك: find percentage P2O5.
+
+537
+00:42:01,400 --> 00:42:04,400
+بنقول:  ما في أبسط من هيك. ناخد المطلوب الأول. بدنا
+
+538
+00:42:06,650 --> 00:42:10,350
+percentage phosphorus. يعني بنجيب milligram
+
+539
+00:42:10,350 --> 00:42:12,630
+phosphorus. أنا معايا، بكتب الـ millimoles، يعني هيطلع
+
+540
+00:42:12,630 --> 00:42:16,590
+معايا المطلوب مباشرة، مش هلاجى حاجة غيره مطلوبة، أو
+
+541
+00:42:16,590 --> 00:42:19,990
+مجهولة. فبقول: الفسفور هنا واحد، هنا واحد. millimol
+
+542
+00:42:19,990 --> 00:42:25,210
+phosphorus تساوي millimol ammonia phosphomolybdate. فبقول:
+
+543
+00:42:25,210 --> 00:42:30,970
+milligram phosphorus على الـ atomic weight phosphorus، milligram
+
+544
+00:42:30,970 --> 00:42:35,330
+gram ammonia phosphomolybdate على formula weight
+
+545
+00:42:35,330 --> 00:42:39,670
+ammonia phosphomolybdate. الآن بنرجع: milligram phosphorus
+
+546
+00:42:39,670 --> 00:42:43,900
+بدها تساوي، طبعًا على 30.97،
+
+547
+00:42:43,900 --> 00:42:48,360
+تجهان، بنرجع عن جدع، الـ milligram راسب، جالنا والله
+
+548
+00:42:48,360 --> 00:42:53,800
+1.1682 grams، يعني بنضرب في
+
+549
+00:42:53,800 --> 00:42:59,020
+1000، على الـ formula weight للراسب، 1876.5.
+
+550
+00:42:59,020 --> 00:43:05,360
+بطلع عندي شوية milligramات. الـ percentage، وضع طبيعيّ،
+
+551
+00:43:05,360 --> 00:43:10,020
+اللي بنقسم عليه. ما دام عندي milligram بقسم على milligram
+
+552
+00:43:10,020 --> 00:43:13,820
+sample. بقسم على milligram sample، يعني 271.1
+
+553
+00:43:13,820 --> 00:43:19,220
+من 100 في 100. من 100، بطلع عندي 7.1 من 100. نفس
+
+554
+00:43:19,220 --> 00:43:24,330
+الـ procedure بالظبط بنطبقه عشان نجيب جدع، الـ
+
+555
+00:43:24,330 --> 00:43:27,610
+percentage من الـ P2O5. بقول: والله الـ P2O5 فيها
+
+556
+00:43:27,610 --> 00:43:32,850
+اثنين فسفور، هنا جدع فسفور واحد. إذًا أنا بدي أحط هنا
+
+557
+00:43:32,850 --> 00:43:35,930
+اثنين. إذًا الـ millimol P2O5 إيش بقت تساوي؟ نص الـ millimol
+
+558
+00:43:35,930 --> 00:43:41,090
+mol ammonia phosphomolybdate. نفس الكلام. إيش هي الـ millimol
+
+559
+00:43:41,090 --> 00:43:44,670
+mol؟ milligram على الـ formula weight. إيش هي الـ millimol؟
+
+560
+00:43:44,670 --> 00:43:48,110
+milligram على الـ formula weight. الكويس، هنا في millimol
+
+561
+00:43:48,110 --> 00:43:53,700
+طبعًا، يعني بدي أعوض، أنا، عن إيش؟ الـ formula weight لـ
+
+562
+00:43:53,700 --> 00:44:01,020
+الـ P2O5. أقول: نص الـ formula weight لـ P2O5، في الـ milligram
+
+563
+00:44:01,020 --> 00:44:06,800
+gram لـ الأمونيا، وزن الراسب، على الـ formula
+
+564
+00:44:06,800 --> 00:44:11,740
+weight للأمونيا، وزن الراسب، على الـ formula
+
+565
+00:44:11,740 --> 00:44:13,160
+weight للأمونيا، وزن الراسب، على الـ formula
+
+566
+00:44:13,160 --> 00:44:14,360
+weight للأمونيا، وزن الراسب، على الـ formula
+
+567
+00:44:14,360 --> 00:44:14,640
+weight للأمونيا، وزن الراسب، على الـ formula
+
+568
+00:44:14,640 --> 00:44:14,760
+weight للأمونيا، وزن الراسب، على الـ formula
+
+569
+00:44:14,760 --> 00:44:14,980
+weight للأمونيا، وزن الراسب، على الـ formula
+
+570
+00:44:14,980 --> 00:44:15,580
+weight للأمونيا، وزن الراسب، على الـ formula
+
+571
+00:44:15,580 --> 00:44:16,200
+weight للأمونيا، وزن الراسب، على الـ formula
+
+572
+00:44:16,200 --> 00:44:19,280
+weight للأمونيا، وزن الراسب، على الـ formula
+
+573
+00:44:19,280 --> 00:44:22,540
+weight للأمونيا، وزن الراسب، على 0.3 من 10%
+
+574
+00:44:22,540 --> 00:44:29,580
+الحسابات، الحسابات من أبسط ما يكون. هنلاقي حسابات، يا
+
+575
+00:44:29,580 --> 00:44:34,640
+شباب، مش بالصورة هذه. هناخد بعض الأمثلة عليها، لكن
+
+576
+00:44:34,640 --> 00:44:39,560
+معظم الحسابات اللي بدنا نتعلمها هي الحسابات بهذا
+
+577
+00:44:39,560 --> 00:44:44,730
+الشكل. ليه؟ لأنّ الحسابات اللي بهذا الشكل هي الحسابات
+
+578
+00:44:44,730 --> 00:44:50,890
+العمليّة، يعني في المختبر. أنت عادة عندك وزن راسب، و
+
+579
+00:44:50,890 --> 00:44:54,210
+formula weight للراسب معروفة، أو formula للراسب
+
+580
+00:44:54,210 --> 00:44:59,630
+معروفة، وعندك formula للـ analyte، وبدّك تجيب وزن
+
+581
+00:44:59,630 --> 00:45:03,530
+لها. فهذا النوع من المسائل هو أكثر نوع إحنا بنتعامل
+
+582
+00:45:03,530 --> 00:45:08,350
+فيه. لكن هنلاقي في الكتاب، على سبيل المثال، بعض
+
+583
+00:45:08,350 --> 00:45:11,690
+المسائل اللي... المسائل اللي بتكون يعني فرضيّة شويّة،
+
+584
+00:45:11,690 --> 00:45:15,530
+أو جدليّة شويّة. أنا الحصة الجاية هحاول إنّي أعطيك
+
+585
+00:45:15,530 --> 00:45:20,410
+بعض الأمثلة على مثل... يعني هذه المسائل. ودائمًا مهما
+
+586
+00:45:20,410 --> 00:45:23,770
+كانت المسألة تبدو لك إنّها مش في الدائرة، أو صعبة،
+
+587
+00:45:23,770 --> 00:45:27,970
+مفتاح حلّها دائمًا ابدأ بالـ millimol، هتوصل للحل.
+
+588
+00:45:27,970 --> 00:45:33,990
+فإذًا، والله، الحصة الجاية بنكمل. أي سؤال يا شباب؟
+
+589
+00:45:33,990 --> 00:45:37,210
+طيب، بنشوفكم الحصة الجاية إن شاء الله.
diff --git a/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/4NfLk-2cEic_postprocess.srt b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/4NfLk-2cEic_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..1ea50ecdc6efacb51bc9e105ac753c15138dbfd9
--- /dev/null
+++ b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/4NfLk-2cEic_postprocess.srt
@@ -0,0 +1,2356 @@
+1
+00:00:20,690 --> 00:00:24,170
+بسم الله الرحمن الرحيم الحصة الماضية يا شباب كنا
+
+2
+00:00:24,170 --> 00:00:28,850
+بدأنا نتكلم عن ال gravimetric analysis وشوفنا انه
+
+3
+00:00:28,850 --> 00:00:35,490
+خطوات ال gravimetric analysis يعني متعددة بدأنا في
+
+4
+00:00:35,490 --> 00:00:39,510
+تحضير المحلول بداية و بعدين اتكلمنا عن ال
+
+5
+00:00:39,510 --> 00:00:44,010
+precipitation process ذاتها و لجينا في عدة عوامل
+
+6
+00:00:44,010 --> 00:00:48,610
+او عدة اعتبارات يجب الاهتمام فيها لما نعمل
+
+7
+00:00:48,610 --> 00:00:53,850
+precipitationتحديداً بدنا نخل ال EQ أقل ما يمكن
+
+8
+00:00:53,850 --> 00:00:59,370
+ونخل ال solubility أعلى ما يمكن عشان نتحكم في ال
+
+9
+00:00:59,370 --> 00:01:05,510
+relative super saturation تكون يعني قليلة وبالتالي
+
+10
+00:01:05,510 --> 00:01:09,210
+ال particle size يزيد بعدين اتكلمنا عن ال
+
+11
+00:01:09,210 --> 00:01:12,430
+digestion وشوفنا إيش أهمية العملية ولا إيش بتستخدم
+
+12
+00:01:12,430 --> 00:01:18,810
+وبعدين بعد ال digestion قلنا إنه بدنا نتكلم عن ال
+
+13
+00:01:18,810 --> 00:01:23,700
+filtrationو ال washing للفيلترات ال filtration
+
+14
+00:01:23,700 --> 00:01:31,680
+قولنا بيتم اما باستخدام جوش او باستخدام ashless
+
+15
+00:01:31,680 --> 00:01:36,860
+filter paperهذا بيتوقف على نوع ال particle هل ال
+
+16
+00:01:36,860 --> 00:01:42,500
+formula تبعته معروفة upon drying ولا مش معروفة
+
+17
+00:01:42,500 --> 00:01:47,020
+وبالتالي بضطر ان اعمل ignition عشان احوله لknown
+
+18
+00:01:47,020 --> 00:01:52,010
+formula وبالتالي اما ان اعملfiltration باستخدام
+
+19
+00:01:52,010 --> 00:01:55,970
+gouche او ان اعمل filtration باستخدام الashless
+
+20
+00:01:55,970 --> 00:01:59,930
+filter paper هذا الكلام بيتوقف على هل بدى اعمل
+
+21
+00:01:59,930 --> 00:02:06,890
+drying ولا بدى اعمل ignition في النهاية فاخترت
+
+22
+00:02:06,890 --> 00:02:11,190
+كيف بدى اعمل filtration عملت filtration الآن بدى
+
+23
+00:02:11,190 --> 00:02:17,030
+اغسل الفلترات بنقول عادة بنغسل الفلترات باستخدام
+
+24
+00:02:17,030 --> 00:02:22,600
+كمية قليلة من الماء المقطرهو تكون مثلا 15-20 مل
+
+25
+00:02:22,600 --> 00:02:27,300
+إضافة الماء المقطر لا تتم كلها مرة واحدة يعني ال
+
+26
+00:02:27,300 --> 00:02:31,300
+15-20 مل بنحطهم مش مرة واحدة على ال precipitate لأ
+
+27
+00:02:31,300 --> 00:02:35,220
+بنحطهم على دفعات تلاتة أربعة مل كل مرة خمسة مل
+
+28
+00:02:35,220 --> 00:02:40,800
+مثلا مرتين تلاتة أربعةوبالتالي أي adsorbed
+
+29
+00:02:40,800 --> 00:02:46,640
+material على السطح بيتم التخلص منها، لكن في حالة
+
+30
+00:02:46,640 --> 00:02:50,780
+من الحالات مش لازم نغسل بال distilled water
+
+31
+00:02:50,780 --> 00:02:55,140
+نهائيا، اللي هي في حالة ما يكون أصل ال particle
+
+32
+00:02:55,140 --> 00:03:00,490
+colloid أو gelatinousالـ Particle Size بيكون صغير
+
+33
+00:03:00,490 --> 00:03:04,570
+كتير في البداية احنا بنجمعه عن طريق الـ Digestion
+
+34
+00:03:04,570 --> 00:03:09,570
+الحرارة فهو بيتجمع لا شك و بيصير راسب لكن لو
+
+35
+00:03:09,570 --> 00:03:16,090
+غسلناه بالميه المجطرة بنلاحظ انه بيرجع تاني ل ال
+
+36
+00:03:16,090 --> 00:03:20,790
+colloidal state عملية عكس عملية التجميع عملية
+
+37
+00:03:20,790 --> 00:03:23,590
+التجميع بنقولها Agglomeration او بنقولها
+
+38
+00:03:23,590 --> 00:03:28,950
+Coagulationلكن لو غسلنا بميه مقطرة هلاحظ ان ال
+
+39
+00:03:28,950 --> 00:03:33,210
+precipitate اللى اتكون اصلا راح يرجع تانى للكولويد
+
+40
+00:03:33,210 --> 00:03:39,250
+عملية اسمها peptization فلازم احذر من الغسيل بميه
+
+41
+00:03:39,250 --> 00:03:44,930
+مقطرة بالذات لما يكون في عندى اصل ال precipitate
+
+42
+00:03:44,930 --> 00:03:49,570
+كولويدفي الحقيقة يعني الـ colloidal precipitates
+
+43
+00:03:49,570 --> 00:03:55,450
+هذي بتعملي مشكلة مش بس في قضية الترشيح و يعني جداش
+
+44
+00:03:55,450 --> 00:03:58,950
+بتغلب من عملية الترشيح لأ الـ colloidal
+
+45
+00:03:58,950 --> 00:04:03,230
+precipitates بتعملي مشكلة لأن ال surface area
+
+46
+00:04:03,230 --> 00:04:07,390
+تبعها عادة بيكون كبير معنى أن ال surface area كبير
+
+47
+00:04:07,390 --> 00:04:13,540
+معناته أنه عرضةلل adsorption لل surface adsorption
+
+48
+00:04:13,540 --> 00:04:17,060
+بشكل كبير للغاية معناه كده ان بتوقع يكون في عندي
+
+49
+00:04:17,060 --> 00:04:21,640
+خطأ جسيم اذا كان ماغسلتش كويس ليه؟ لأن في عندي
+
+50
+00:04:21,640 --> 00:04:27,320
+كمية ايونات adsorbed على السطح بشكل كبير جدا ليه؟
+
+51
+00:04:27,320 --> 00:04:30,780
+لأن المساحة السطحية زي ما ذكرت كبيرة بتكون لل
+
+52
+00:04:30,780 --> 00:04:33,380
+colloidal precipitates
+
+53
+00:04:34,930 --> 00:04:42,290
+وفي الحقيقة يعني إذا كان ال precipitate مثلا ال
+
+54
+00:04:42,290 --> 00:04:46,150
+particle size تبعه كان جيد معقول وقارناه ب
+
+55
+00:04:46,150 --> 00:04:48,830
+particle size صغير ممكن نلاحظ أن ال surface area
+
+56
+00:04:48,830 --> 00:04:53,600
+بتزيد مئات بل آلاف المرات في بعض الأحيانألاف
+
+57
+00:04:53,600 --> 00:04:57,560
+المرات بتزيد ال surface area وبالتالي بتوقع أن ال
+
+58
+00:04:57,560 --> 00:05:04,240
+absorption يعطيني خطأ عادة جسيم إذا كان في عندي
+
+59
+00:05:04,240 --> 00:05:08,400
+colloidal precipitate في عندي حاجة لازم نتذكرها
+
+60
+00:05:08,400 --> 00:05:12,520
+كويس كتير أي precipitate يا شباب أي precipitate
+
+61
+00:05:12,520 --> 00:05:18,140
+بيكون له قابلية لإنه يعمل absorption ل its own
+
+62
+00:05:18,140 --> 00:05:24,730
+ions يعني مثلامثلا انا في عندى راسب من ال silver
+
+63
+00:05:24,730 --> 00:05:29,670
+chloride ايش ايوناته ال silver او ال chloride هذا
+
+64
+00:05:29,670 --> 00:05:33,490
+الراسب له قابلية انه يعمل absorption ل its own
+
+65
+00:05:33,490 --> 00:05:37,950
+ions present in excess بشوف ايش الايون اللى موجود
+
+66
+00:05:37,950 --> 00:05:42,110
+بوفرةو بعمله adverb هو الايون اللي موجود بوافر
+
+67
+00:05:42,110 --> 00:05:45,630
+بحصله adverb على السطح الايون التاني طبعا مش هيكون
+
+68
+00:05:45,630 --> 00:05:50,170
+موجود ليه؟ لأنه وجود الاتنين مع بعض بعتراسب فهو
+
+69
+00:05:50,170 --> 00:05:54,070
+دائما في عندي ايون واحد بس موجود بوافرة هذا الايون
+
+70
+00:05:54,070 --> 00:05:58,490
+اللي موجود بوافرة ايش بيعطيني؟adsorption layer
+
+71
+00:05:58,490 --> 00:06:03,710
+بسميها انا primary ion layer او primary adsorption
+
+72
+00:06:03,710 --> 00:06:08,630
+layer هذه layer من ايون من ايونات الراسب نفسه
+
+73
+00:06:08,630 --> 00:06:13,210
+فمثلا لو في عندي silver chloride ال silver طبعا
+
+74
+00:06:13,210 --> 00:06:16,630
+موجة و ال chloride سالب انا بحط silver على ال
+
+75
+00:06:16,630 --> 00:06:20,790
+chloride راح الاحظ مدام هيك اثناء عملية الترسيب
+
+76
+00:06:20,790 --> 00:06:25,680
+لسه في عندي chlorideفي المحلول ليه؟ لأنه لسه انا
+
+77
+00:06:25,680 --> 00:06:29,280
+بضيف silver يعني ماخلصش ال chloride عشان هيك بما
+
+78
+00:06:29,280 --> 00:06:31,380
+انه في chloride في المحلول حالة عظمه ال chloride
+
+79
+00:06:31,380 --> 00:06:36,260
+بيكون عامل a primary absorption layer حوالين ال
+
+80
+00:06:36,260 --> 00:06:44,130
+particles من ال silver chlorideبينما لما تقريبا ال
+
+81
+00:06:44,130 --> 00:06:49,170
+process يتخلص وحط زيادة من ال silver راح ألاجي بعض
+
+82
+00:06:49,170 --> 00:06:54,890
+أيونات ال silver موجودة حوالين ال particles من ال
+
+83
+00:06:54,890 --> 00:06:58,030
+silver chloride هذا بيقولها primary adsorption
+
+84
+00:06:58,030 --> 00:07:02,190
+layer طبعا ال primary adsorption layer بتجذب لها
+
+85
+00:07:02,190 --> 00:07:09,340
+layer تانيةمن counter ions من ايونات مصاحبة يعني
+
+86
+00:07:09,340 --> 00:07:13,680
+مثلا الchlor potassium او Sodium بكون موجود برضه
+
+87
+00:07:13,680 --> 00:07:18,020
+حواليه هذه ال layer المصاحبة لل primary ion layer
+
+88
+00:07:18,020 --> 00:07:22,820
+او لل primary adsorption layer بنسميها عادة
+
+89
+00:07:22,820 --> 00:07:26,980
+counter ion layer او secondary adsorption layer
+
+90
+00:07:26,980 --> 00:07:30,240
+عادة بتكون diffuse بتكونش ملزجة في ال particles
+
+91
+00:07:30,880 --> 00:07:36,580
+بينما ال primary ion layer عادة بتكون يعني ملتصقة
+
+92
+00:07:36,580 --> 00:07:41,840
+إلى حد كبير بال particles بينما ال counter ion
+
+93
+00:07:41,840 --> 00:07:44,660
+بتكون عادة اشمالها diffuse
+
+94
+00:07:46,360 --> 00:07:54,320
+وجود ال counter ions هذه ووجود ال primary ions هذه
+
+95
+00:07:54,320 --> 00:07:59,800
+يعني لما نيجي نغسل بالمية اللي بيحصل انه ال
+
+96
+00:07:59,800 --> 00:08:06,180
+primary ions ملتصقة صعب انه تتحرك بينما ال counter
+
+97
+00:08:06,180 --> 00:08:09,560
+ions انا قول ال diffuse منتشرة يعني بعيدة شوية
+
+98
+00:08:09,560 --> 00:08:16,230
+فهذه ال counter ions بيحصلها غسيل لما نحصل غسيلأنا
+
+99
+00:08:16,230 --> 00:08:20,810
+بعرّي ال particles من الأيونات المصاحبة فإيش بيصير
+
+100
+00:08:20,810 --> 00:08:25,730
+عليها؟ أيونات لها نفس الشحنة مثلا لها نكلورايد
+
+101
+00:08:27,110 --> 00:08:30,330
+Particle chloride عليه من الطبقة الخارجية او ال
+
+102
+00:08:30,330 --> 00:08:32,730
+adsorption layer هي عبارة عن ال chloride و ال
+
+103
+00:08:32,730 --> 00:08:35,510
+particle تاني برضه عليه طبقة خارجية من ال chloride
+
+104
+00:08:35,510 --> 00:08:38,710
+شحنته سالبة و شحنته سالبة بعدها كلهم يبدو ايه
+
+105
+00:08:38,710 --> 00:08:44,110
+يتنافروا بعد ما كان يعني particles متجمعة اذا كان
+
+106
+00:08:44,110 --> 00:08:48,230
+غسلت ميه مجترة فورا بلاحظ ان ال particles تبعد مع
+
+107
+00:08:48,230 --> 00:08:53,530
+بعض لأن في صربينها تنافرطب ها في ايش بدى اغسل اذا
+
+108
+00:08:53,530 --> 00:08:56,690
+كان عندى اصل ال particle colloid انا اتعبت وانا
+
+109
+00:08:56,690 --> 00:09:00,190
+بجمعه اتعبت وانا بحاول اعمله coagulation او
+
+110
+00:09:00,190 --> 00:09:04,650
+agglomeration بالحرارة او يعني باضافة مثلا strong
+
+111
+00:09:04,650 --> 00:09:08,980
+electrolyte على سبيل المثاللكن أنا مضطر إني أغسل
+
+112
+00:09:08,980 --> 00:09:14,300
+وإلا أكيد الرأس بتبقى هيكون وزنته وزن أكبر من
+
+113
+00:09:14,300 --> 00:09:18,300
+الحقيقة لإنه في عليه كمية من ال adsorbed material
+
+114
+00:09:18,300 --> 00:09:24,020
+فكيف بدي أغسله؟ جالب نستخدم عادة دايليوت نيتريك
+
+115
+00:09:24,020 --> 00:09:29,370
+أسدنستخدم عادة باليوت نيتريك أسد ليش تحديدا باليوت
+
+116
+00:09:29,370 --> 00:09:33,390
+نيتريك أسد مثلا يعني ليه كان لأنه ال باليوت نيتريك
+
+117
+00:09:33,390 --> 00:09:38,750
+أسد لما نقاجي أعمل drying عند حرارة عالية بيتطير
+
+118
+00:09:38,750 --> 00:09:42,990
+وبالتالي فش عنده حتى لو دل عنده نيتريك أسد شوية
+
+119
+00:09:42,990 --> 00:09:46,630
+على ال precipitate لما نقاجي أعمله drying أو
+
+120
+00:09:46,630 --> 00:09:51,070
+ignition إيش هيحصل له؟ هيطير وبالتالي مش هيكون له
+
+121
+00:09:51,070 --> 00:09:56,740
+وجود لأنه volatileفعلشان هيك بنقول انه اذا كان اصل
+
+122
+00:09:56,740 --> 00:10:05,430
+ال precipitate colloid الاصل انه ماعملشأي غسيل
+
+123
+00:10:05,430 --> 00:10:09,230
+باستخدام المي المجترة بل يجب استخدام حاجة زي
+
+124
+00:10:09,230 --> 00:10:15,450
+dilute nitric acid الان نيجي للخطوة اللى بعد عملية
+
+125
+00:10:15,450 --> 00:10:20,210
+الغسيل انا الان حضرت المحلول وعملت precipitation
+
+126
+00:10:20,210 --> 00:10:24,890
+وعملت digestion وعملت filtration باستخدام الأداة
+
+127
+00:10:24,890 --> 00:10:29,270
+المناسبة ياجوش يقشتس filter paper غسلت الفلترات
+
+128
+00:10:29,270 --> 00:10:34,240
+صار نظيف الان إيش بدي أسوي بدي أخده على الفرناسكان
+
+129
+00:10:34,240 --> 00:10:39,160
+جوش فبتاخدوا علي ال drying oven انا بعمل ال drying
+
+130
+00:10:39,160 --> 00:10:44,460
+تقريبا يعني عادة من 120 ل 150 درجة لمدة ساعة زمن
+
+131
+00:10:44,460 --> 00:10:50,120
+مثلا يبقى بعمل ال drying عند حرارة 120 ل 150 درجة
+
+132
+00:10:50,120 --> 00:10:55,830
+في العادة لمدة ساعة من الزمن تقريبا يعنيوإذا كان
+
+133
+00:10:55,830 --> 00:11:01,390
+بدي أحرق ففي البداية بأحرق الورقة باستخدام لهب بحط
+
+134
+00:11:01,390 --> 00:11:05,050
+الورقة يعني في porcelain crucible وبسخن ال
+
+135
+00:11:05,050 --> 00:11:08,910
+porcelain crucible هذه باستخدام لهب شوية شوية
+
+136
+00:11:08,910 --> 00:11:15,310
+لغاية ما الورقة تتهتكمدام اتهتكت الورقة كويس بأحمل
+
+137
+00:11:15,310 --> 00:11:19,150
+ال crossable و بحطها في فرن الحرق او اللي بسمي
+
+138
+00:11:19,150 --> 00:11:25,370
+fairness مافي ال fairness مافي ال fairness هذا فرن
+
+139
+00:11:25,370 --> 00:11:30,380
+للحرقفرن الحرق انا بحرق فيه باستخدام حرارة من
+
+140
+00:11:30,380 --> 00:11:35,360
+ستمية ل ألف و متين درجة يبقى فرن الحرق باستخدم
+
+141
+00:11:35,360 --> 00:11:39,600
+حرارة من ستمية ل ألف و متين درجة هذه هي الجوش اللي
+
+142
+00:11:39,600 --> 00:11:42,620
+باستخدم ال drying لها مائة و عشرين لمائة و خمسين
+
+143
+00:11:42,620 --> 00:11:46,440
+درجة تتحمل لحوالي مائتين و خمسين درجة بس بعد هيك
+
+144
+00:11:46,440 --> 00:11:50,700
+ممكن انه يحصل فيها مشكلة بينما ال crossables هذي
+
+145
+00:11:50,700 --> 00:11:54,780
+porcelain crossables تتحمل لحرارة يعني ألف و متين
+
+146
+00:11:54,780 --> 00:11:58,870
+درجة عادي مش مشكلةبتكون يعني مولعة زي النار يعني
+
+147
+00:11:58,870 --> 00:12:01,750
+حمرة حمرة بتكون مافيش مشكلة لكن بتبقى صالحة
+
+148
+00:12:01,750 --> 00:12:09,930
+للاستخدام مئات المرات هذا هو شكل ال drying oven ال
+
+149
+00:12:09,930 --> 00:12:13,010
+drying oven هو اللي بتحول تجف في ال glassware تبعك
+
+150
+00:12:13,010 --> 00:12:16,370
+لو جسلت glassware بدك تحطه يجف بتحطه في ايه؟ في ال
+
+151
+00:12:16,370 --> 00:12:20,550
+drying oven بشبه كتير من ناحية العمل الأفران اللي
+
+152
+00:12:20,550 --> 00:12:24,010
+في السوق أفران الكهربا اللي بتنبع في السوق كويس؟
+
+153
+00:12:24,010 --> 00:12:30,100
+تبع ايش؟أه أه أه بالظبط فرن الكهرة بقى مش شرط
+
+154
+00:12:30,100 --> 00:12:33,960
+بالوف ولا لأ الفرن الكهرة بتشتريه زي عامل زي ال
+
+155
+00:12:33,960 --> 00:12:42,480
+microwave لكن فيه .. فيه يعني أصابع حرارية يعني
+
+156
+00:12:42,480 --> 00:12:46,840
+فهذا هو ال drying oven سهل كتير يعني بيستخدم لغاية
+
+157
+00:12:46,840 --> 00:12:50,000
+250 درجة مش أكتر من هي مش لازم أستخدمه لأكتر من
+
+158
+00:12:50,000 --> 00:12:50,840
+250 درجة
+
+159
+00:12:55,740 --> 00:12:59,880
+هذا الشكل هذا اسمه waffle fairness لاحظ انه حتى
+
+160
+00:12:59,880 --> 00:13:05,480
+المكان حجمه ضيق يعني بسعله اكم من عادة اكم من ال
+
+161
+00:13:05,480 --> 00:13:11,190
+crossable مش كتيرحرارة طبعا هائلة بتوصل ل1200 درجة
+
+162
+00:13:11,190 --> 00:13:14,990
+طبعا ماحدش يحاول يحط ال crystal ball في إيده جوا،
+
+163
+00:13:14,990 --> 00:13:21,690
+مالفعش فيه ملجأ طويل تونس طويل بتمسك ال ..ش اسمه
+
+164
+00:13:21,690 --> 00:13:24,670
+ال crystal ball فيه و بتحطها مثلا و نفس الكلام لما
+
+165
+00:13:24,670 --> 00:13:29,970
+تيجي ترفعها كويس هذا الشكل بيفرجيك كيف تحرج الورقة
+
+166
+00:13:29,970 --> 00:13:34,810
+إذا كان طبعا هي فيها الراسب مش مرة واحدة بتحطها في
+
+167
+00:13:34,810 --> 00:13:37,940
+الفرن على طول، لاليه؟ لأن لو حاطيتها مرة واحدة من
+
+168
+00:13:37,940 --> 00:13:40,980
+الفرن و حاطيتها ببرجة و هي لسه فيها الراسب مش بس
+
+169
+00:13:40,980 --> 00:13:44,860
+مش بتولع مش مشكلة لو ولعت المشكلة أنه فيها solvent
+
+170
+00:13:44,860 --> 00:13:48,960
+كلها هيحصلها عملية تناثر لإن ال solvent بتطلع كل
+
+171
+00:13:48,960 --> 00:13:53,600
+مرة واحدة من حرارة الغرفة لمثلا تمن او الف تمنمية
+
+172
+00:13:53,600 --> 00:13:56,640
+درجة او الف درجة فبستناشى ال solvent تتبخر شوية
+
+173
+00:13:56,640 --> 00:14:00,160
+شويةلأ كله بيطلع مرة واحدة بيحمل ممكن الورقة و ال
+
+174
+00:14:00,160 --> 00:14:04,240
+precipitate و كله بتناطر داخل الفرن عشان هيك احنا
+
+175
+00:14:04,240 --> 00:14:08,820
+بنميلها شوية زي هيكة و بنشغل اللها بتحتها لغاية ما
+
+176
+00:14:08,820 --> 00:14:13,840
+نشوف ان الورقة اللي جوا تهتكت يعني صارت شبه
+
+177
+00:14:13,840 --> 00:14:17,900
+بالرمادبس ساعتها خلاص و ال solvent اتبقى شوية شوية
+
+178
+00:14:17,900 --> 00:14:22,460
+ساعتها باخدها و بنجولها وين على ال muffin furnace
+
+179
+00:14:22,460 --> 00:14:27,880
+بنقول انه في .. لو اشتغلت في مؤسسة عندها شغل كتير
+
+180
+00:14:27,880 --> 00:14:31,440
+فهذا ال muffin furnace اللي قدامنا مينفعاش ليه؟
+
+181
+00:14:31,440 --> 00:14:34,720
+لأنه مثلا تشتغلها خمسين، ستين، سبعين، مية عينة
+
+182
+00:14:34,720 --> 00:14:39,540
+فهذا الفرن طبعا كتير صغير فبنستخدمه فرن خصوصي أكبر
+
+183
+00:14:39,540 --> 00:14:44,990
+كتير من الفرن اللي شوفناه سابقا، لاحظ فيه traysزي
+
+184
+00:14:44,990 --> 00:14:50,910
+جوارير بتقعد فيها ال ايه ال ال porcelain
+
+185
+00:14:50,910 --> 00:14:54,910
+crossables فشايفين اكتر هذا ال tray وفيه تحته كمان
+
+186
+00:14:54,910 --> 00:14:59,330
+ال tray بتصنع على الأقل مية او يزيد فطبعا هذا
+
+187
+00:14:59,330 --> 00:15:04,230
+الشغل التجاري المعامل اللي في عندها شغل كتير وزارة
+
+188
+00:15:04,230 --> 00:15:09,370
+او مؤسسة في عندها gravimetric analysis بشكل واضح
+
+189
+00:15:09,370 --> 00:15:15,120
+يوميافطبعا سويا انه تشتري فرن زي الفرن اللي احنا
+
+190
+00:15:15,120 --> 00:15:20,700
+شايفينه بنقول
+
+191
+00:15:20,700 --> 00:15:26,300
+طيب احنا عملنا a drying او ignition الآن بدنا نطلع
+
+192
+00:15:26,300 --> 00:15:31,120
+ال crossable او نطلع الجوش من الفرن بقول بطلعهاش
+
+193
+00:15:31,120 --> 00:15:36,280
+من الفرن و بحطها ع ال benchأكيد هذا الكلام بتاخد
+
+194
+00:15:36,280 --> 00:15:40,140
+رطوبة كتير فهذا الكلام هيزيد من وزنها هيزيد من وزن
+
+195
+00:15:40,140 --> 00:15:43,400
+الراسب اذا هذه مشكلة عويصة علشان هيك لما ناخدها
+
+196
+00:15:43,400 --> 00:15:48,300
+بحطها وين في حاجة بقولها desiccator مجفف هذا
+
+197
+00:15:48,300 --> 00:15:51,780
+المجفف زي ما انتوا شايفين هو على زجاج له غطاء
+
+198
+00:15:51,780 --> 00:15:59,340
+والغطاء هذا حتى موجود في يعني مادة بتمنع تسرب
+
+199
+00:15:59,340 --> 00:16:07,100
+الهوى نهائيا يعني هيزي ال .. يعني نوع من أنواع
+
+200
+00:16:07,100 --> 00:16:13,200
+الشحوم يعني شحمة كويس فتمنع تسرب الهواء هان تحت
+
+201
+00:16:13,200 --> 00:16:17,200
+موجود فيه مادة بتمطص الميه انا بستخدم ال calcium
+
+202
+00:16:17,200 --> 00:16:24,180
+chloride عادة يعني بيمطص الميه فمنيح يا شباب فاش
+
+203
+00:16:24,180 --> 00:16:29,320
+.. اش بنسوي بننجل ال crucible هان او بننجل الجوش
+
+204
+00:16:29,320 --> 00:16:36,150
+هان و بعدينو بعدين نستنى عليها لما تبرد لغاية ما
+
+205
+00:16:36,150 --> 00:16:39,470
+تصير في حرارة الغرفة بدا حوالي عشر دقائق بعدين
+
+206
+00:16:39,470 --> 00:16:42,250
+بنطلعها و ساعتها أه ممكن نسيبها على ال bench لأن
+
+207
+00:16:42,250 --> 00:16:48,550
+قدرة المادة في حرارة الغرفة على الامتصاص
+
+208
+00:16:48,550 --> 00:16:52,110
+بخار الميه أقل كتير من قدرتها على امتصاص بخار
+
+209
+00:16:52,110 --> 00:16:55,230
+الميه و هي ساخرة و هي ساخرة بتمتص كمية مهولة من
+
+210
+00:16:55,230 --> 00:16:59,910
+بخار الميه طيب ده بالما اتكلم عن ال calculations
+
+211
+00:17:02,150 --> 00:17:08,050
+بقول تعالوا نتطلع بما انه بنتكلم عن graphometric
+
+212
+00:17:08,050 --> 00:17:11,230
+analysis قولنا سابقا انه graphometric analysis
+
+213
+00:17:11,230 --> 00:17:15,490
+يعتبر تكنيك ممتاز جدا، دقيق للغاية، بشرط انه نعمل
+
+214
+00:17:15,490 --> 00:17:23,260
+بشكل ايه؟ بشكل صحيحبنقول لكن كان في مشكلة المشكلة
+
+215
+00:17:23,260 --> 00:17:27,160
+انه time consuming بياخد وجد طويل جدا من وين بيجي
+
+216
+00:17:27,160 --> 00:17:31,840
+الوجد بقول انا لما بدي احضر المحلول لما بدي احضر
+
+217
+00:17:31,840 --> 00:17:36,880
+المحلول فهذا هياخد مني وجد طويل بدي احضره لعملية
+
+218
+00:17:36,880 --> 00:17:39,860
+الترسيب اجهزه لعملية الترسيب بياخد مني وجد طويل
+
+219
+00:17:39,860 --> 00:17:44,720
+وكمانلما نبدأ اجي اعمل عملية الترسيب شايفين بدنا
+
+220
+00:17:44,720 --> 00:17:47,520
+شوية شوية نضيف و بدنا hot solution و بدنا يعني
+
+221
+00:17:47,520 --> 00:17:50,780
+نعمل استراج و ناخد بالنا طيب منيح برضه بتاخد عملية
+
+222
+00:17:50,780 --> 00:17:54,820
+الترسيب بتاخد وجهة و digestion ده بتعمل يعني من
+
+223
+00:17:54,820 --> 00:17:59,980
+يعني نص ساعة لساعة digestion برضه هذا كلام ايه
+
+224
+00:17:59,980 --> 00:18:03,820
+بياخد وجهة بعد هيك تتقل لعملية الترشيح طبعا بتاخد
+
+225
+00:18:03,820 --> 00:18:08,200
+وجهةعملية الغسيل برضه بتاخد وجهة .. بدلا لو كان ال
+
+226
+00:18:08,200 --> 00:18:11,980
+particle size صغير شوية بتغلب عملية الترشيح وعملية
+
+227
+00:18:11,980 --> 00:18:15,080
+الغسيل يعني كل هذه الخطوات بتاخد وجهة .. لكن
+
+228
+00:18:15,080 --> 00:18:18,080
+مابنديش اتكلم عن الوجهة هذا انا .. انا بتتكلم بس
+
+229
+00:18:18,080 --> 00:18:22,220
+عن الوجهة المخصص للأوزانبقول انا علشان اعمل
+
+230
+00:18:22,220 --> 00:18:26,480
+graphimetric analysis بحاجة لجوش او ل crossable
+
+231
+00:18:26,480 --> 00:18:30,800
+تكون معروفة الوزن بدي اوزنها اعرف وزنها بعدين بدي
+
+232
+00:18:30,800 --> 00:18:35,220
+احط فيها الراصب و اوزنها مرتانيا باخد الفرق اللي
+
+233
+00:18:35,220 --> 00:18:38,500
+هو عبارة عن وزنة الراصب بيكون فلما بدي اجي ابدأ
+
+234
+00:18:38,500 --> 00:18:43,900
+اشتغل مثلا بدي اعمل تحليل ولي اكون مثلا بدي اخد
+
+235
+00:18:43,900 --> 00:18:48,220
+تلاتة crossablesليش تلاتة؟ لأن أنا عامل عامل بعمل
+
+236
+00:18:48,220 --> 00:18:51,640
+التجربة تلت مرات علشان نسبة الخطأ يكون عندي قليلة
+
+237
+00:18:51,640 --> 00:18:55,460
+في النهاية باخد ال averageكويس فباخد تلاتة
+
+238
+00:18:55,460 --> 00:19:00,160
+crossables بدي في الأول أنظفهم طيب نظفتهم بذلك
+
+239
+00:19:00,160 --> 00:19:03,360
+مجهود كبير في تنظيفهم خاصة لو كان فيهم مواد مش
+
+240
+00:19:03,360 --> 00:19:07,440
+دايبة كويس او مواد على الجدران بحب انه ال .. ال ..
+
+241
+00:19:07,440 --> 00:19:10,680
+الجوش اللي بشتغل فيها او ال crossable تكون نظيفة
+
+242
+00:19:10,680 --> 00:19:13,980
+مية في المية فنظفتهم هذا الكلام أخد مني وجد قد
+
+243
+00:19:13,980 --> 00:19:17,520
+اضطر ان اضيف او استخدم بعض ال acids مثلا
+
+244
+00:19:17,520 --> 00:19:22,540
+concentrated او ما شابهفهذا كلام هياخد مني وجدت،
+
+245
+00:19:22,540 --> 00:19:25,480
+بعدين غسلتهم في النهاية بميه مجبرة مية في المية
+
+246
+00:19:25,480 --> 00:19:29,500
+وقلت والله بدي اوزنهم، فجابي الموزنهم وحطي بالفرن
+
+247
+00:19:29,500 --> 00:19:34,810
+بجفف الفرن، بدخليها في الفرن لمدة ساعةبتكون ايه
+
+248
+00:19:34,810 --> 00:19:39,210
+مثلا عند حرارة 120 ولا 150 درجة بتوقع انه تكون ايه
+
+249
+00:19:39,210 --> 00:19:43,690
+شمالها خلاص جفت باخدها و بحطها في ال desicator
+
+250
+00:19:43,690 --> 00:19:47,390
+اللي شفناها قبل شوية لما نتسير في ايه في حرارة
+
+251
+00:19:47,390 --> 00:19:51,390
+الغرفة بيدا كمان عشر دقايق باخدها و بوزنها عرفت
+
+252
+00:19:51,390 --> 00:19:56,650
+الوزنة بسجل الوزنة غير صالحة للعمل لسه بيداخدها ع
+
+253
+00:19:56,650 --> 00:20:00,890
+الفرن كمان مرةليه؟ لأنه بس بدى أتأكد انا إذا كان
+
+254
+00:20:00,890 --> 00:20:03,970
+بالفعل هي جافة ولا لأ، باخدها على الفرن بحطها نص
+
+255
+00:20:03,970 --> 00:20:07,610
+ساعة، باخدها من الفرن بحطها في ال desiccator عشر
+
+256
+00:20:07,610 --> 00:20:11,130
+دقايقباخدها بعد هيك و بوزنها والله إذا كان
+
+257
+00:20:11,130 --> 00:20:15,930
+الوزنتين متطابقتين إذا الشغل صحيح بإمكاني أقول أه
+
+258
+00:20:15,930 --> 00:20:21,190
+هذه وزنة الجوش لكن لو لجيت فيه تغير في الوزن بعرف
+
+259
+00:20:21,190 --> 00:20:24,490
+إنه في عندى مشكلة بدي عوض رجعها على الفرن كمان مرة
+
+260
+00:20:24,490 --> 00:20:30,090
+و لازم أطلع وزنتين متتاليتين متساويتين غير هيك
+
+261
+00:20:30,090 --> 00:20:33,310
+بيكون في عندى مشكلة اتصوروا كده عمال بياخد مني وجد
+
+262
+00:20:33,310 --> 00:20:39,580
+و نفس الكلام بعد عملية الغسيل غسلت الراسببدي اخد
+
+263
+00:20:39,580 --> 00:20:44,300
+ال cross ball او الجوش هي و الرأسين و احطها في
+
+264
+00:20:44,300 --> 00:20:48,300
+الفرن حاطيها في الفرن برضه لمدة ساعة على ال
+
+265
+00:20:48,300 --> 00:20:52,680
+desiccator عشر دقايق وزنت برجعها تاني على الفرن
+
+266
+00:20:52,680 --> 00:20:56,880
+يبقى مش اقل من خمس ساعات توزين بالدقيق خمس ساعات
+
+267
+00:20:56,880 --> 00:21:02,380
+على الأقل هذا غير ال precipitation نفسها و غير
+
+268
+00:21:02,380 --> 00:21:07,010
+تحضير المحلولةفمعنى الكلام بالفعل لـ Gravimetric
+
+269
+00:21:07,010 --> 00:21:09,690
+Analysis أو ال procedure طويل
+
+270
+00:21:14,360 --> 00:21:17,040
+نتكلم عن ال calculation ال calculations في ال
+
+271
+00:21:17,040 --> 00:21:20,680
+graphimetric analysis مش أبسط من هيك بسيطة جدا جدا
+
+272
+00:21:20,680 --> 00:21:25,420
+جدا تستخدم مفهوم واحد بنقوله graphimetric factor
+
+273
+00:21:25,420 --> 00:21:30,900
+احنا مش هنستخدم هذا المفهوم هنفرجكم بعد شوية ليش
+
+274
+00:21:30,900 --> 00:21:36,460
+هنستخدم بس ال minimal concept اللي احنا متعودين
+
+275
+00:21:36,460 --> 00:21:40,780
+على الحال فيه و بهمنيش المسألة تكونGravimetric ولا
+
+276
+00:21:40,780 --> 00:21:41,520
+غير غير غير غير غير غير غير غير غير غير غير غير
+
+277
+00:21:41,520 --> 00:22:03,500
+غيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغيرغ
+
+278
+00:22:03,520 --> 00:22:07,760
+الان قبل ما نتحرك و نشوف ال calculations اللي خاطر
+
+279
+00:22:07,760 --> 00:22:12,560
+أنه أطلع على ال impurities اللي ممكن تكون موجودة
+
+280
+00:22:12,560 --> 00:22:16,800
+في ال precipitates و اللي ممكن تسبب أخطاء جسمة
+
+281
+00:22:16,800 --> 00:22:21,300
+بقول في عندي أربع أنواع من أنواع ال impurities
+
+282
+00:22:21,300 --> 00:22:26,540
+لازم أخد بالي منها أول نوع بقوله occlusion
+
+283
+00:22:29,530 --> 00:22:34,450
+بنقول في ال occlusion بعض مكونات المحلول يتم
+
+284
+00:22:34,450 --> 00:22:40,710
+احتجازها أو حبسها داخل ال particle، داخل ال
+
+285
+00:22:40,710 --> 00:22:50,110
+particle، يعني عند ال particle بينمو و
+
+286
+00:22:50,110 --> 00:22:58,080
+بيحجز داخلهأي جزء من المحلول هذا الجزء اللي حجزه
+
+287
+00:22:58,080 --> 00:23:01,400
+من المحلول موجود فيه مش بس solvent لأ موجود فيه
+
+288
+00:23:01,400 --> 00:23:07,900
+أيونات فممكن يؤدي هذا الكلام لأخطاءقبل أن أتحدث عن
+
+289
+00:23:07,900 --> 00:23:11,680
+الخطأ، أريد أن أقول، لماذا يحصل أشياء مثلها؟ لماذا
+
+290
+00:23:11,680 --> 00:23:14,280
+يحصل الـ Occlusion؟ بقول، يحصل الـ Occlusion بشكل
+
+291
+00:23:14,280 --> 00:23:19,500
+أساسي، إذا كان تم إضافة لـ precipitating agent على
+
+292
+00:23:19,500 --> 00:23:24,880
+الانالايت بسرعة، مرة واحدةساعتها ال particles تنمو
+
+293
+00:23:24,880 --> 00:23:29,100
+نمو سرطاني في كافة الإتجاهات أثناء عملية النمو
+
+294
+00:23:29,100 --> 00:23:35,000
+السريع ممكن يتم تكوين بُقَر أو مناطق داخل ال
+
+295
+00:23:35,000 --> 00:23:39,400
+particle هذه حجزت شوية من ال medium اللي هي موجودة
+
+296
+00:23:39,400 --> 00:23:45,140
+فيه فهنا مثلا لو أنا برسب لchloride باستخدام ال
+
+297
+00:23:45,140 --> 00:23:48,220
+silver هي عندي chloride و أنا بضيف عليه silver
+
+298
+00:23:48,220 --> 00:23:53,200
+فاتكون A G C L A G C LA G C L
+
+299
+00:23:56,090 --> 00:24:01,130
+شوية فراغ موجود فيه شوية من ال medium فإذا كان في
+
+300
+00:24:01,130 --> 00:24:04,730
+عندي هنا بعض ال chloride مش متفاعل يعني مثلا زي ال
+
+301
+00:24:04,730 --> 00:24:09,890
+NACL ماتفعلش ليش ماتفعلش لأنه مالجاش silver هلجيت
+
+302
+00:24:09,890 --> 00:24:13,710
+انحجز جوا ال chloride محجوز في هذه الغرفة داخل هذا
+
+303
+00:24:13,710 --> 00:24:18,390
+البناء لكن ال silver might rate وين موجودة برا
+
+304
+00:24:18,390 --> 00:24:25,900
+تقدرش تعدى لأنه في جدران مابتقدر تعدى كويسيبجى هذا
+
+305
+00:24:25,900 --> 00:24:28,220
+هيضل صوديوم اكلورايد الصوديوم اكلورايد
+
+306
+00:24:28,220 --> 00:24:35,120
+الفورمولاوية 58.5 لكن هذه الاخلورايدة الاصل ايش
+
+307
+00:24:35,120 --> 00:24:40,980
+اعطتني الاصل بتتحول لايش الاخلورايد في الاصل لسلفر
+
+308
+00:24:40,980 --> 00:24:46,720
+اكلورايد طب جداش الفورمولاوية للسلفر اكلورايد جال
+
+309
+00:24:46,720 --> 00:24:51,980
+143 يبجى بدل ما الاخلورايدة هذه تعطيني 143 ايش
+
+310
+00:24:51,980 --> 00:24:57,230
+اعطتنيتمنية و خمسية و نص .. إذا هذا خطأ إيه شماله؟
+
+311
+00:24:57,230 --> 00:25:01,230
+خطأ سالب .. خطأ .. يعني دي خطأ بدل ما تعطيني
+
+312
+00:25:01,230 --> 00:25:06,150
+formula weight 143 تتحول ل silver chlorideجزء من
+
+313
+00:25:06,150 --> 00:25:09,750
+الكلورايد ايش ضاله؟ ضالوا كلورايد زي ما هو يعني
+
+314
+00:25:09,750 --> 00:25:13,970
+Sodium chloride مثلا ال counter ion تبعه اعطانا 58
+
+315
+00:25:13,970 --> 00:25:19,230
+.5 فمن الميطين 143 اعطانا 58.5 ليه؟ لأنه تم
+
+316
+00:25:19,230 --> 00:25:24,070
+احتجازه جوا ومش ملاقي Silver يتفاعل معاه، هذه حاجة
+
+317
+00:25:24,070 --> 00:25:29,590
+ممكن حاجة تانية، انقول اه و الله تم احتباس كمية
+
+318
+00:25:29,590 --> 00:25:34,210
+معينة من ال silver nitrateكان فيه chloride اتفاعلت
+
+319
+00:25:34,210 --> 00:25:38,070
+معاها وضال كمية من ال silver nitrate داخل ال
+
+320
+00:25:38,070 --> 00:25:42,790
+particle هذا ال silver nitrate مش بناجح هي اتفاعل
+
+321
+00:25:42,790 --> 00:25:47,110
+معاها الاصل انها ماتكونش موجودة مش هيك ولا لأ؟ اذا
+
+322
+00:25:47,110 --> 00:25:53,270
+هذا كده اش هتعطيني؟ فورمولوية 170 هذه مجرد ما اجفف
+
+323
+00:25:53,270 --> 00:25:58,520
+بخار ال solvent بيطلع مافيش مشكلةبطلع ال solvent
+
+324
+00:25:58,520 --> 00:26:02,160
+لكن المادة ال silver nitrate اتحول ل solid silver
+
+325
+00:26:02,160 --> 00:26:06,620
+nitrate طب هد اعططنى formula 170 اذا في عند زيادة
+
+326
+00:26:06,620 --> 00:26:09,520
+في الوزن يبقى ال occlusion ممكن و الله يحصل
+
+327
+00:26:09,520 --> 00:26:14,580
+occlusion ل ال medium شوية من ال analyte او شوية
+
+328
+00:26:14,580 --> 00:26:18,900
+من ال precipitating agent في بعض الأحيان بحصل على
+
+329
+00:26:18,900 --> 00:26:21,220
+negative error و في بعض الأحيان الأخرى بحصل على
+
+330
+00:26:21,220 --> 00:26:26,370
+positive error طيبهل يمكن التغلب على هذه المشكلة
+
+331
+00:26:26,370 --> 00:26:30,610
+بإني أغسل كويس؟ لأ، لأن غرفة مسكرة، مهما حاولت
+
+332
+00:26:30,610 --> 00:26:34,150
+تغسلها من برا، اللي جوا بايل إيه؟ بايل جوا، ما
+
+333
+00:26:34,150 --> 00:26:37,250
+بتغير طب، ها إيه إيش بدي أسوي؟ جال، بدي أهد
+
+334
+00:26:37,250 --> 00:26:41,150
+الجدران علشان أحصل على اللي جوا، يعني بدي أدوب
+
+335
+00:26:41,150 --> 00:26:46,350
+الراسم و بعدين بدي أعيد ترسيبه مرة تانية شوية شوية
+
+336
+00:26:46,350 --> 00:26:50,450
+عشان مايحصلش عندي occlusion بس ما بصلح الocclusion
+
+337
+00:26:50,450 --> 00:26:55,970
+بعملية غسيل عادية، لأ، مينفعشماشي يبقى ال
+
+338
+00:26:55,970 --> 00:26:59,430
+inclusion يا إما بضيفلي positive يا negative error
+
+339
+00:26:59,430 --> 00:27:04,530
+في نوع تاني من الأخطاء حاجة بنقولها inclusion
+
+340
+00:27:04,530 --> 00:27:08,870
+شبيها في الاسم بال inclusion لكن مفهومها مختلف
+
+341
+00:27:08,870 --> 00:27:14,170
+تماما ال inclusion هو عبارة عن replacement
+
+342
+00:27:16,420 --> 00:27:21,240
+لأيون من الأيونات بأيون آخر replacement يعني انا
+
+343
+00:27:21,240 --> 00:27:26,520
+عندي crystal او في عندي precipitate ال precipitate
+
+344
+00:27:26,520 --> 00:27:30,360
+له formula معينة ال formula عبارة عن عدة أيونات
+
+345
+00:27:31,470 --> 00:27:35,430
+النوع معين من الايونات بعضه بيتم استبداله بايون
+
+346
+00:27:35,430 --> 00:27:40,610
+اخر الايون هذا عشان يستبدل ايون تاني المفروض ان
+
+347
+00:27:40,610 --> 00:27:45,390
+الايونين يكونوا متشابهين في الشحنة ومتشابهين في
+
+348
+00:27:45,390 --> 00:27:50,390
+الحجم يعني مثلا وانا برسم المجنيزيوم على هيئة
+
+349
+00:27:50,390 --> 00:27:54,510
+magnesium ammonium phosphate وانا برسم المجنيزيوم
+
+350
+00:27:54,510 --> 00:28:01,870
+على هيئة magnesium ammonium phosphate مثلابلاحظ ان
+
+351
+00:28:01,870 --> 00:28:06,890
+لو في عندى اي كمية من ال potassium بعض ال
+
+352
+00:28:06,890 --> 00:28:10,970
+potassium بيحل محل ال ammonium ليه؟ لأن ال
+
+353
+00:28:10,970 --> 00:28:17,910
+potassium و ال ammonium اول حاجة اللى هم نفس
+
+354
+00:28:17,910 --> 00:28:24,830
+الشحنة بعدين الحجمالايون هي لهم واحد تقريبا شبهين
+
+355
+00:28:24,830 --> 00:28:29,350
+جدا عشانك سهل خالص ان البوتاسيوم يحل محل الامونيوم
+
+356
+00:28:29,350 --> 00:28:33,410
+او الامونيوم يحل محل البوتاسيوم سهل كتير زي بعض
+
+357
+00:28:33,410 --> 00:28:37,470
+طيب الان اذا كان انا برسم المجنيزيوم امونيوم
+
+358
+00:28:37,470 --> 00:28:42,540
+فوسفات في وجودفي المحلول اللى موجود فيه potassium
+
+359
+00:28:42,540 --> 00:28:46,500
+يبقى بعض أيونات ال potassium هتحل محل ايه ال
+
+360
+00:28:46,500 --> 00:28:50,700
+ammonium طب ال ammonium هذه 18 فورميله ال
+
+361
+00:28:50,700 --> 00:28:55,430
+potassiumتسعة وتلاتين اذا في هذه الحالة عندى
+
+362
+00:28:55,430 --> 00:29:01,530
+positive error قد يكون الايون اللى بيحل محل الايون
+
+363
+00:29:01,530 --> 00:29:07,510
+الاصلي قد يكون اقل فى ال .. فى ال formulate او
+
+364
+00:29:07,510 --> 00:29:11,640
+اكتر معناه كده بتوقع انه احصل علىpositive او
+
+365
+00:29:11,640 --> 00:29:15,720
+negative error ايضا ممكن يكون اكتر في الفورمولات
+
+366
+00:29:15,720 --> 00:29:19,880
+او اقل وبالتالي ممكن نحصل على positive او negative
+
+367
+00:29:19,880 --> 00:29:26,940
+error بنسمي هذا كلام isomorphous replacement
+
+368
+00:29:26,940 --> 00:29:31,620
+الاصل انه هل بستطيع ان اتخلص من ال inclusion عن
+
+369
+00:29:31,620 --> 00:29:36,450
+طريق الغسيل؟فتقول لا أبدا نهائيا ليه لأنه خلاص
+
+370
+00:29:36,450 --> 00:29:39,910
+الأمونيوم راح اتكون عندى particle ال particle فيه
+
+371
+00:29:39,910 --> 00:29:43,450
+potassium بعض ال potassium بالاضافة للأمونيوم طب
+
+372
+00:29:43,450 --> 00:29:46,830
+هاي ايش بدى اعمل قال خلاص التجربة خربت الاصل انه
+
+373
+00:29:46,830 --> 00:29:51,090
+مدام دك المجنيزيوم اعود تدوب ال precipitate واشتغل
+
+374
+00:29:51,730 --> 00:29:56,630
+واشتغل باستخدام مواد او محلول مافيش فيه potassium
+
+375
+00:29:56,630 --> 00:30:00,190
+نهائيا يعني مثلا بدل ما تستخدم ال potassium
+
+376
+00:30:00,190 --> 00:30:06,210
+phosphate عشان ترسم المجنيزيوم في وجود أمونيا كويس
+
+377
+00:30:06,210 --> 00:30:11,610
+لأ استخدم ال sodium مثلا ال sodium phosphate بحلش
+
+378
+00:30:11,610 --> 00:30:16,810
+محل ال ammonium ليه؟ لأنه صح له نفس الشحنة لكن
+
+379
+00:30:16,810 --> 00:30:23,460
+حجمه أصغركويس حجمه أصغر ماشي يا شباب إذا برضه ال
+
+380
+00:30:23,460 --> 00:30:30,620
+inclusion بيعطينا خطأ فادح عشان هيك بقول أنا يعني
+
+381
+00:30:30,620 --> 00:30:34,240
+ال graphometric analysis بدنا نعملها بشكل سليم
+
+382
+00:30:34,240 --> 00:30:38,020
+لازم نفهم إيش تركيب المحلول وإذا كان في عند أيونات
+
+383
+00:30:38,020 --> 00:30:44,280
+متشابهة فيهالحجم والشحنة المفروض أني أستبعدها
+
+384
+00:30:44,280 --> 00:30:49,480
+ممنوع نستخدمها أتأكد أنه ليس عندي أيونات متشابهة
+
+385
+00:30:49,480 --> 00:30:53,360
+في الحجم وفي الشحنة وإلا بتوقع يحصل عندي
+
+386
+00:30:53,360 --> 00:30:58,760
+isomorphous replacement أو inclusion في
+
+387
+00:30:58,760 --> 00:31:03,320
+عندي خطأ تكلمنا عنه اللي هو ال absorption surface
+
+388
+00:31:03,320 --> 00:31:06,700
+absorption هذا طبعا خطأ دائما بعطي positive error
+
+389
+00:31:07,350 --> 00:31:10,750
+دائما بيعطيه positive ليه؟ لأن هو زيادة absorption
+
+390
+00:31:10,750 --> 00:31:16,110
+زيادة على السطحزيادة على الوزنة فدائما بيعطيني
+
+391
+00:31:16,110 --> 00:31:20,630
+positive error ال surface absorption بتكون كبيرة
+
+392
+00:31:20,630 --> 00:31:28,150
+جدا الخطأ لا يحتمل اذا كان عندى small particles او
+
+393
+00:31:28,150 --> 00:31:31,210
+colloidal precipitates ليه؟ كمان مرة لأن ال
+
+394
+00:31:31,210 --> 00:31:35,830
+surface area لها يعني كبيرة خالص علشان هيك لازم
+
+395
+00:31:35,830 --> 00:31:39,850
+اتأكد مية في المية انه انا غسلت ال precipitate
+
+396
+00:31:39,850 --> 00:31:45,060
+بشكل ممتازو إلا بتوقع يكون في عندي كمية من ال
+
+397
+00:31:45,060 --> 00:31:53,820
+adsorbed ions آخر نوع من أنواع ال impurities ممكن
+
+398
+00:31:53,820 --> 00:31:58,320
+تتكلم عن ال post precipitation كلمة post يعني فوج
+
+399
+00:31:58,320 --> 00:32:04,080
+يعني حاجة اتكون فوج الراسد و بنضرب مثلين بنقول
+
+400
+00:32:04,080 --> 00:32:09,480
+مثلا في البداية لو كان في عندي calcium و هذا
+
+401
+00:32:09,480 --> 00:32:16,950
+standard procedureوانا بدي ارصبه باستخدام ال
+
+402
+00:32:16,950 --> 00:32:22,070
+oxalate ففورا ال calcium oxalate بيترصب مافيش اي
+
+403
+00:32:22,070 --> 00:32:25,910
+مشكلة في هذا التفاعل التفاعل ممتاز جدا و ال
+
+404
+00:32:25,910 --> 00:32:29,310
+calcium بتحول ال calcium oxalate مافيش مشكلة لكن
+
+405
+00:32:29,310 --> 00:32:33,350
+يا شباب لو كان في عندها ال magnesium بقول تفاعل ال
+
+406
+00:32:33,350 --> 00:32:37,650
+magnesium مع ال magnesium oxalate تفاعل بطيء لكنه
+
+407
+00:32:37,650 --> 00:32:41,130
+بيحصل التفاعل ايش ماله بطيء يعني لو سبت انا
+
+408
+00:32:43,020 --> 00:32:47,320
+الكالسيوم اجزالات اللى اتكون موجود فى وجود
+
+409
+00:32:47,320 --> 00:32:50,960
+مجنيزيوم وفى عندى access طبعا اجزالات لأنه الوضع
+
+410
+00:32:50,960 --> 00:32:53,380
+طبيعى ان دائما فى عندى access من ال precipitating
+
+411
+00:32:53,380 --> 00:33:01,000
+agent بلاحظ ان فى عندى كمية من المجنيزيوم اجزالات
+
+412
+00:33:01,000 --> 00:33:04,820
+اتكونت فوق الرأس بالاصلي دائما ال post
+
+413
+00:33:04,820 --> 00:33:09,330
+precipitation بيعطينى positive errorطب إيش بدى
+
+414
+00:33:09,330 --> 00:33:13,270
+أعمل؟ بقول إذا كنت عارف أنا وهذا مهم إذا بدى تشتغل
+
+415
+00:33:13,270 --> 00:33:17,810
+Graphimetry لازم تدرس القضية اللى قدامك المحلول
+
+416
+00:33:17,810 --> 00:33:20,950
+اللى قدامك تدرسه كويس كتير مدام عارف إن في المحلول
+
+417
+00:33:20,950 --> 00:33:24,490
+مجنيزيوم ماعنك ترسم ال calcium على هيئة calcium
+
+418
+00:33:24,490 --> 00:33:31,160
+امزالية لكن بمجرد عملية الترسيم رشحتستناش تخليه in
+
+419
+00:33:31,160 --> 00:33:36,240
+contact مع المجنيزيوم لأنه خليته لفترة أطول معناته
+
+420
+00:33:36,240 --> 00:33:39,800
+خلاص هيترسب حيصير في عندك رسمين في بعض التنين
+
+421
+00:33:39,800 --> 00:33:42,700
+البيض مش هيبينهم ولا هتعرف أن هذا post
+
+422
+00:33:42,700 --> 00:33:46,540
+precipitation علشان هيك إذا كان أنت شكيت أنه ممكن
+
+423
+00:33:46,540 --> 00:33:50,420
+يحصل عندك post precipitation رشح و بعدين اعمل
+
+424
+00:33:50,420 --> 00:33:56,080
+عملية digestion وكمل شغلك لكن خد الرسم لحاله خد
+
+425
+00:33:56,080 --> 00:34:00,950
+الرسم لحاله في البدايةنفس الكلام هذا بنلاحظه إذا
+
+426
+00:34:00,950 --> 00:34:06,530
+كان في عيني محلول من ال cover و بدى أرسمه على هيئة
+
+427
+00:34:06,530 --> 00:34:11,410
+cover sulphide فعلى طول سريع جدا تفاعل حلو كتير ال
+
+428
+00:34:11,410 --> 00:34:14,230
+cover بترسم على هيئة cover sulphide لكن لو في عيني
+
+429
+00:34:14,230 --> 00:34:20,310
+zinc فتفاعل ال zinc مع ال sulphide تفاعل بطيء
+
+430
+00:34:20,310 --> 00:34:28,790
+تفاعل بطيء لكن لو أتحنل الفرصة عاد يحصلوبجيني راسب
+
+431
+00:34:28,790 --> 00:34:32,110
+فوق الراسب الأصلي post precipitation علشان ايك
+
+432
+00:34:32,110 --> 00:34:35,390
+برضه اذا كان انا حبيت ان ارسب الكبرة على هيئة
+
+433
+00:34:35,390 --> 00:34:38,510
+sulfite المفروض انه مايكونش فيها end zinc اذا كان
+
+434
+00:34:38,510 --> 00:34:42,850
+فيها end zinc بدي ارشح فورا ل post precipitation
+
+435
+00:34:42,850 --> 00:34:46,910
+اذا كان حصل دائما بيعطيني positive error
+
+436
+00:34:50,120 --> 00:34:56,400
+ماشي يا شباب اذا في عندى اربع اسباب واضحة لاخطاء
+
+437
+00:34:56,400 --> 00:35:02,840
+ممكن تحصل في ال gravimetric analysis الان خلينا
+
+438
+00:35:02,840 --> 00:35:11,590
+ننتقل لموضوع ال calculations الحسابات بقول انازي
+
+439
+00:35:11,590 --> 00:35:17,370
+ما ذكرت سابقا اغلب الناس بتستخدم اذا ماكانش كلها
+
+440
+00:35:17,370 --> 00:35:21,930
+يعني اغلب الناس بتستخدم ال gravimetric factor في
+
+441
+00:35:21,930 --> 00:35:28,210
+الحسابات ليه؟ لأنه انا دائما عارف وزنة الراصب لأنه
+
+442
+00:35:28,210 --> 00:35:31,490
+انا كل شغلي ان اطلع وزنة الراصب فوزنة الراصب حاجة
+
+443
+00:35:31,490 --> 00:35:34,830
+عملية experimental value experimental result عندي
+
+444
+00:35:34,830 --> 00:35:38,310
+وزنة الراصب انا مدي وزنة ال analyte وزنة ال
+
+445
+00:35:38,310 --> 00:35:42,860
+analyte تساويوزنة الراسب فيه factor اسمه
+
+446
+00:35:42,860 --> 00:35:45,640
+graphometric factor فانا اذا كان حسبت graphometric
+
+447
+00:35:45,640 --> 00:35:51,080
+factor هو factor نظري بنحسب حساب مش عمليبعرف على
+
+448
+00:35:51,080 --> 00:35:56,760
+طول وزنة الـA الانالايت تبعي إذا مجرد أني أعرف وزن
+
+449
+00:35:56,760 --> 00:36:01,300
+الـGravimetric factor وعندي وزنة الراسب بعرف على
+
+450
+00:36:01,300 --> 00:36:04,680
+طول وزنة الانالايت طب إيش هو الـGravimetric
+
+451
+00:36:04,680 --> 00:36:09,060
+factor؟ جال الـGravimetric factor هو عبارة عن A
+
+452
+00:36:09,060 --> 00:36:14,620
+على B A على B هذه مول ريشيو Stoichiometric mole
+
+453
+00:36:14,620 --> 00:36:19,580
+ratioمضروبة فيه ال formula wet ل ال analyte على ال
+
+454
+00:36:19,580 --> 00:36:22,760
+formula wet ل ال precipitate طبعا ال formula wet ل
+
+455
+00:36:22,760 --> 00:36:25,580
+ال analyte معروفة ال formula wet ل ال precipitate
+
+456
+00:36:25,580 --> 00:36:29,100
+طبعا معروفة ال mole ratio برضه معروفة ايش فيه ال
+
+457
+00:36:29,100 --> 00:36:32,960
+mole ratio؟ بنقولكم اه مثلا لو بدى اجيب ال
+
+458
+00:36:32,960 --> 00:36:38,260
+gravimetric factor للإكلورين CL2 فال a will be
+
+459
+00:36:38,260 --> 00:36:44,260
+بقول ال إكلورين واحد mole إكلورينبيعطيني اتنين مول
+
+460
+00:36:44,260 --> 00:36:47,660
+سلفري كلورايت فهذا is a stoichiometric factor مول
+
+461
+00:36:47,660 --> 00:36:52,340
+ratio كويس فهنا في عندى اتنين كلور تحت لازم يكون
+
+462
+00:36:52,340 --> 00:36:56,720
+عندى اتنين كلور هاي ال a و ال b بده اخلى البسط عدد
+
+463
+00:36:56,720 --> 00:37:01,000
+المولات زي المقام بالنسبة لل analyte بس البسط زي
+
+464
+00:37:01,000 --> 00:37:05,200
+ال a زي المقام البسط في اتنين كلور المقام بده يكون
+
+465
+00:37:05,200 --> 00:37:08,760
+في ايه اتنين كلور ال agc اللي فيه بس كلورة واحدة
+
+466
+00:37:08,760 --> 00:37:11,830
+اذا بده احط هنا اتنين لإني عندى اتنين كلورهذا الـ
+
+467
+00:37:11,830 --> 00:37:15,930
+Stoichiometric factor مضروب هذا الكلام في ال
+
+468
+00:37:15,930 --> 00:37:18,930
+formula ويتلى ال analyte اللى هو ال CL2 على ال
+
+469
+00:37:18,930 --> 00:37:21,830
+formula ويتلى ال precipitate اللى هو ال AGCL الان
+
+470
+00:37:21,830 --> 00:37:27,150
+لو بدى أجيب وزنة ال CL2 اللى هو ال analyte بقول
+
+471
+00:37:27,150 --> 00:37:30,670
+والله وزنة الراسب في ال gravimetric factor سهل
+
+472
+00:37:30,670 --> 00:37:34,820
+خالصوزنة الراسب في الـ gravimetric factor سهل جدا
+
+473
+00:37:34,820 --> 00:37:40,040
+و مباشر كل الحلول اللي عندنا بنفس الطريقة في
+
+474
+00:37:40,040 --> 00:37:45,760
+الكتاب لكن احنا بدناش نحل بهذه الطريقة احنا في
+
+475
+00:37:45,760 --> 00:37:50,000
+عندنا طريقة أسهل في الحل اتعلمناها و عرفناها و
+
+476
+00:37:50,000 --> 00:37:54,340
+اتعودنا عليها و بدهاش حافظها لازم تتذكر ايش ال
+
+477
+00:37:54,340 --> 00:37:57,920
+gravimetric factor علشان تستخدمه بدناش نتذكر حاجة
+
+478
+00:37:57,920 --> 00:38:02,150
+احنا احنا بنحل باستخدام ال millimolesبكتب ال
+
+479
+00:38:02,150 --> 00:38:04,850
+analyte على شجة و ال precipitate على شجة و بسويهم
+
+480
+00:38:04,850 --> 00:38:09,810
+بقول analyte Cl2 هذي AgCl إذا انا هنمت أحط اتنين
+
+481
+00:38:09,810 --> 00:38:15,030
+صح ولا لأ؟ على طول millimol Cl2 بتساوي نص ال
+
+482
+00:38:15,030 --> 00:38:19,090
+millimol AgCl و أنا عارف .. أنا عارف إن ال
+
+483
+00:38:19,090 --> 00:38:22,070
+millimol عبارة عن milligram على الفورمولواتأو
+
+484
+00:38:22,070 --> 00:38:24,330
+مدارة عينة عشان الـ Graphometer كله أغلب و ملي
+
+485
+00:38:24,330 --> 00:38:27,610
+جرام عال Formulates أو طبعا مدارة ال volume مفهوم
+
+486
+00:38:27,610 --> 00:38:30,930
+هذا الكلام المهم بعود عن الملي مول يبجى انتهى
+
+487
+00:38:30,930 --> 00:38:35,630
+الموضوع انا مش بحاجة بطلع الملي جراها ملي مول CL2
+
+488
+00:38:35,630 --> 00:38:39,490
+يعني ملي جرام CL2 عال Formulates معروفة نص ملي
+
+489
+00:38:39,490 --> 00:38:42,650
+جرام precipitate معروف Formulates precipitate طبعا
+
+490
+00:38:42,650 --> 00:38:45,950
+معروفة اذا على طول الملي جرام انا liked معروفة من
+
+491
+00:38:45,950 --> 00:38:48,730
+غير ما ينجول والله Graphometer اكفاتور وإيش ال A
+
+492
+00:38:48,730 --> 00:38:52,720
+وإيش ال B وانا اللي فوق وانا اللي تحتهذا كله حكي
+
+493
+00:38:52,720 --> 00:38:58,480
+مش كتير بالنسبة إلينا يعني جوهري في الحل إحنا الحل
+
+494
+00:38:58,480 --> 00:39:01,940
+اللي هستخدمه millimoles إيش بتساوي من ال
+
+495
+00:39:01,940 --> 00:39:04,280
+millimoles millimoles من ال analyte إيش بتساوي من
+
+496
+00:39:04,280 --> 00:39:13,120
+ال precipitate طب نيجي نتحدث في بعض الأمثلة
+
+497
+00:39:13,120 --> 00:39:18,180
+الفعليةأول مثال ايش بيقول بيقول calculate the
+
+498
+00:39:18,180 --> 00:39:21,960
+milligram analyte to milligram precipitate لو اللي
+
+499
+00:39:21,960 --> 00:39:25,080
+بده ال milligram analyte كقيمة كان دالي اذا كان
+
+500
+00:39:25,080 --> 00:39:29,860
+وزن ال precipitate هالجدر لكن هو بده نسبة يعني اه
+
+501
+00:39:29,860 --> 00:39:33,980
+سهل مباشرة for the following الفسفور in silver
+
+502
+00:39:33,980 --> 00:39:37,160
+phosphate بده ال milligram فسفور ل milligram
+
+503
+00:39:37,160 --> 00:39:42,900
+silver phosphate و ال bismuth sulfide في ال barium
+
+504
+00:39:42,900 --> 00:39:49,330
+sulfateناخد واحد واحد هو بيقول لي الفوسفور في إيش؟
+
+505
+00:39:49,330 --> 00:39:52,970
+في ال silver هاي الفوسفور بيعطيني silver فوسفيت ال
+
+506
+00:39:52,970 --> 00:39:57,730
+P واحدة و ال P إذا ال millimol phosphorus تساوي
+
+507
+00:39:57,730 --> 00:40:02,370
+millimol silver phosphate إذا milligram phosphorus
+
+508
+00:40:02,370 --> 00:40:06,630
+على ال atomic weight milligram silver phosphate
+
+509
+00:40:06,630 --> 00:40:09,610
+على ال formula weight هو بده ال milligram على ال
+
+510
+00:40:09,610 --> 00:40:14,140
+milligram حطهم جد ما يطلع يطلعماشي يا شباب مباشر
+
+511
+00:40:14,140 --> 00:40:19,560
+سهل سهل يعني بشكل مش معقول طيب نيجي للخطوة التانية
+
+512
+00:40:19,560 --> 00:40:23,180
+او المطلوب التاني بده ال milligram bismuth
+
+513
+00:40:23,180 --> 00:40:26,680
+sulphide اللي موجود في ال barium sulphate بقول
+
+514
+00:40:26,680 --> 00:40:31,840
+bismuth sulphide هنفيه تلاتة sulphurهنا في سلفر
+
+515
+00:40:31,840 --> 00:40:36,060
+واحدة اذا بدي اضافه هنا ثلاثة بقول ماعنى كلام يبجأ
+
+516
+00:40:36,060 --> 00:40:39,620
+انا ماعندي غير ال millimol بعرفش احل اي مسألة او
+
+517
+00:40:39,620 --> 00:40:43,500
+مفتاح حالي دائما هو ال millimol انسى انك تفكر
+
+518
+00:40:43,500 --> 00:40:47,260
+بحاجة تانية بدك تحل اي مسألة بس مدام هي
+
+519
+00:40:47,260 --> 00:40:50,740
+stoichiometric ال millimol بس هدا هو هتلاقي
+
+520
+00:40:50,740 --> 00:40:55,540
+المطلوب داخلها من غير ما تبدأ المجهود حتى بقول
+
+521
+00:40:55,540 --> 00:40:58,880
+millimol bismuth sulphate بساوية تلت ال millimol
+
+522
+00:40:58,880 --> 00:41:03,150
+barium sulphateاذا ايش ال milligram على
+
+523
+00:41:03,150 --> 00:41:06,450
+الفورمولوية؟ ايش ال milligram على الفورمولوية؟ اذا
+
+524
+00:41:06,450 --> 00:41:10,030
+هاي ال milligram على ال milligram النتيجة ال ratio
+
+525
+00:41:10,030 --> 00:41:11,810
+بتطلع معناها مباشرة
+
+526
+00:41:14,450 --> 00:41:20,590
+طيب نتطلع على هذا المثال الفوسفات يا شباب في عينة
+
+527
+00:41:20,590 --> 00:41:24,590
+وزنها point two seven one one gram was
+
+528
+00:41:24,590 --> 00:41:29,270
+precipitated رسبنا giving one point one six eight
+
+529
+00:41:29,270 --> 00:41:33,230
+two gram من ال ammonia phosphomolipate ال ammonia
+
+530
+00:41:33,230 --> 00:41:37,090
+phosphomolipate هذا رسب كتير كتير حلو لأن ال
+
+531
+00:41:37,090 --> 00:41:41,800
+formula وات تبعته عالية لو طلعت عليها جداش1876
+
+532
+00:41:41,800 --> 00:41:46,020
+عشانك لو عندك كمية قليلة من الفوسفات بتعطيك كمية
+
+533
+00:41:46,020 --> 00:41:48,960
+كبيرة من الراصد يعني بتقدر تعيين كميات الفوسفات
+
+534
+00:41:48,960 --> 00:41:54,220
+موجودة بإيه بكميات قليلة للغاية طيب ما علينا احنا
+
+535
+00:41:54,220 --> 00:41:57,200
+بيقول find percentage phosphorus جداش عندي
+
+536
+00:41:57,200 --> 00:42:01,400
+percentage phosphorus في العينة وكمان مطلوب كمان
+
+537
+00:42:01,400 --> 00:42:04,400
+بيقولك find percentage P2O5
+
+538
+00:42:06,650 --> 00:42:10,350
+بنقول فش أبسط من هيك ناخد المطلوب الأول بدنا
+
+539
+00:42:10,350 --> 00:42:12,630
+percentage phosphorus يعني بنجيب milligram
+
+540
+00:42:12,630 --> 00:42:16,590
+phosphorus انا معايا بكتب ال millimoles يعني هيطلع
+
+541
+00:42:16,590 --> 00:42:19,990
+معايا المطلوب مباشرة مش هلاجى حاجة غيره مطلوبة او
+
+542
+00:42:19,990 --> 00:42:25,210
+مجهولة فبقول الفوسفور هان واحد هان واحدملي مول
+
+543
+00:42:25,210 --> 00:42:30,970
+فوسفوراس تساوي ملي مول أمونيا فوسفوموليبديات فبقول
+
+544
+00:42:30,970 --> 00:42:35,330
+ملي جرام فوسفوراس ع ال atomic weight فوسفوراس ملي
+
+545
+00:42:35,330 --> 00:42:39,670
+جرام أمونيا فوسفوموليبديات على formula weight
+
+546
+00:42:39,670 --> 00:42:43,900
+أمونيا فوسفوموليبدياتالان بنعود ملي جرام فوسفوراس
+
+547
+00:42:43,900 --> 00:42:48,360
+بدها تساوي طبعا على تلاتين وتسعة و سبعة وتسعين
+
+548
+00:42:48,360 --> 00:42:53,800
+تجهان بنعود عن جداش الملي جرام راسب جالنا والله
+
+549
+00:42:53,800 --> 00:42:59,020
+one point one six eight two grams يعني بنضرب في
+
+550
+00:42:59,020 --> 00:43:05,360
+عشر أقصى تلاتةعلى ال formula وقت للراسب 1876.5
+
+551
+00:43:05,360 --> 00:43:10,020
+بطلع عندى شوية ملي جرامات ال percentage وضع طبيعى
+
+552
+00:43:10,020 --> 00:43:13,820
+اللى بنقسم على مدام عندى ملي جرام بقسم على ملي
+
+553
+00:43:13,820 --> 00:43:19,220
+جرام sample بقسم على ملي جرام sample يعني 271 و 1
+
+554
+00:43:19,220 --> 00:43:24,330
+من 10 في 100 من 100 بطلع عندى 71 من 10 في 100نفس
+
+555
+00:43:24,330 --> 00:43:27,610
+ال procedure بالظبط نطبقه عشان نجيب جداش ال
+
+556
+00:43:27,610 --> 00:43:32,850
+percentage من ال P2O5 بقول والله ال P2O5 فيها
+
+557
+00:43:32,850 --> 00:43:35,930
+اتنين فسفور هنجدش فسفور واحد اذا انا بدي احط هنا
+
+558
+00:43:35,930 --> 00:43:41,090
+اتنين اذا الميلي مول P2O5 ايش بقى تساوي نص الميلي
+
+559
+00:43:41,090 --> 00:43:44,670
+مول امونيا فسفور مليبديت نفس الكلام ايش هي الميلي
+
+560
+00:43:44,670 --> 00:43:48,110
+مول ميلي جرام على الفورمولوات ايش هي الميلي مول
+
+561
+00:43:48,110 --> 00:43:53,700
+ميلي جرام على الفورمولواتالكويس هان في ملي مول
+
+562
+00:43:53,700 --> 00:44:01,020
+طبعا يعني بدي اعوض انا عن ايش ال formula weight ل
+
+563
+00:44:01,020 --> 00:44:06,800
+ال P2O5 اقول نص ال formula weight ل P2O5 فالميلي
+
+564
+00:44:06,800 --> 00:44:11,740
+جرام ل الأمونيا الوزنة الراسب على ال formula
+
+565
+00:44:11,740 --> 00:44:13,160
+weight للأمونيا الوزنة الراسب على ال formula
+
+566
+00:44:13,160 --> 00:44:14,360
+weight للأمونيا الوزنة الراسب على ال formula
+
+567
+00:44:14,360 --> 00:44:14,640
+weight للأمونيا الوزنة الراسب على ال formula
+
+568
+00:44:14,640 --> 00:44:14,760
+weight للأمونيا الوزنة الراسب على ال formula
+
+569
+00:44:14,760 --> 00:44:14,980
+weight للأمونيا الوزنة الراسب على ال formula
+
+570
+00:44:14,980 --> 00:44:15,580
+weight للأمونيا الوزنة الراسب على ال formula
+
+571
+00:44:15,580 --> 00:44:16,200
+weight للأمونيا الوزنة الراسب على ال formula
+
+572
+00:44:16,200 --> 00:44:19,280
+weight للأمونيا الوزنة الراسب على ال formula
+
+573
+00:44:19,280 --> 00:44:22,540
+weight للأمونيا الوزنة الراسب علىو3 من 10%
+
+574
+00:44:22,540 --> 00:44:29,580
+الحسابات الحسابات من أبسط ما يكون هنلاقي حسابات يا
+
+575
+00:44:29,580 --> 00:44:34,640
+شباب مش بالصورة هذه هناخد بعض الأمثلة عليها لكن
+
+576
+00:44:34,640 --> 00:44:39,560
+معظم الحسابات اللي بدنا نتعلمها هي الحسابات بهذا
+
+577
+00:44:39,560 --> 00:44:44,730
+الشكل ليه؟ لأن الحسابات اللي بهذا الشكلهي الحسابات
+
+578
+00:44:44,730 --> 00:44:50,890
+العملية يعني في المختبر انت عادة عندك وزنة راسب و
+
+579
+00:44:50,890 --> 00:44:54,210
+formula weight للراسب معروفة او formula للراسب
+
+580
+00:44:54,210 --> 00:44:59,630
+معروفة و عندك formula لل analyte و بدك تجيب وزنة
+
+581
+00:44:59,630 --> 00:45:03,530
+لها فهذا النوع من المسائل هو اكتر نوع احنا متتمين
+
+582
+00:45:03,530 --> 00:45:08,350
+فيه لكن هنلاجي في الكتاب على سبيل المثالبعض
+
+583
+00:45:08,350 --> 00:45:11,690
+المثائل اللي .. المثائل اللي بتكون يعني فرضية شوية
+
+584
+00:45:11,690 --> 00:45:15,530
+او جدالية شوية انا الحصة الجاية هحاول انه اعطيك
+
+585
+00:45:15,530 --> 00:45:20,410
+بعض الأمثل على مثل يعني هذه المثائل و دائما مهما
+
+586
+00:45:20,410 --> 00:45:23,770
+كانت المسألة تبدولك انه مش في الدائرة او صعبة
+
+587
+00:45:23,770 --> 00:45:27,970
+مفتاح حالها دائما ابدأ بالـ minimal هتوصل للحل
+
+588
+00:45:27,970 --> 00:45:33,990
+فإذا الله رد الحصة الجاية بنكمل اي سؤال يا شباب
+
+589
+00:45:33,990 --> 00:45:37,210
+طيب بنشوفكم الحصة الجاية ان شاء الله
+
diff --git a/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/4NfLk-2cEic_raw.json b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/4NfLk-2cEic_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..b72272df8b296461f725179ddfb4dc33e32c5092
--- /dev/null
+++ b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/4NfLk-2cEic_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 4901, "start": 20.69, "end": 49.01, "text": "بسم الله الرحمن الرحيم الحصة الماضية يا شباب كنا بدأنا نتكلم عن ال gravimetric analysis وشوفنا انه خطوات ال gravimetric analysis يعني متعددة بدأنا في تحضير المحلول بداية و بعدين اتكلمنا عن ال precipitation process ذاتها و لجينا في عدة عوامل او عدة اعتبارات يجب الاهتمام فيها لما نعمل precipitation", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640, 21542, 9381, 3660, 9673, 46958, 10632, 35186, 13412, 3555, 16758, 9122, 8315, 47525, 10721, 8315, 8717, 2655, 4117, 19528, 18871, 2423, 7427, 332, 17475, 5215, 4032, 8592, 38688, 8315, 16472, 3224, 16490, 9566, 2407, 9307, 2423, 7427, 332, 17475, 5215, 37495, 22653, 44650, 22488, 41891, 47525, 10721, 8315, 8978, 6055, 5016, 11242, 13546, 9673, 5016, 1211, 12610, 4724, 28259, 10632, 4032, 39182, 9957, 1975, 2655, 4117, 19528, 8315, 18871, 2423, 37662, 1399, 29910, 9307, 11296, 4032, 5296, 7435, 1829, 8315, 8978, 6225, 41891, 6225, 2407, 10943, 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"probability": 0.974365234375}], "temperature": 1.0}, {"id": 14, "seek": 33863, "start": 320.25, "end": 338.63, "text": "مثلا انا في عندى راسب من ال silver chloride ايش ايوناته ال silver او ال chloride هذا الراسب له قابلية انه يعمل absorption ل its own ions present in excess بشوف ايش الايون اللى موجود بوفرة", "tokens": [2304, 12984, 15040, 1975, 8315, 8978, 43242, 7578, 12602, 32277, 3555, 9154, 2423, 8753, 35434, 1975, 1829, 8592, 1975, 1829, 2407, 8315, 47395, 2423, 8753, 1975, 2407, 2423, 35434, 23758, 34892, 32277, 3555, 46740, 12174, 16758, 1211, 10632, 16472, 3224, 7251, 25957, 1211, 27557, 5296, 1080, 1065, 27362, 1974, 294, 9310, 4724, 8592, 38688, 1975, 1829, 8592, 42963, 1829, 11536, 13672, 7578, 3714, 29245, 23328, 4724, 38688, 25720], "avg_logprob": -0.1512681133505227, "compression_ratio": 1.550561797752809, "no_speech_prob": 1.1920928955078125e-07, "words": [{"start": 320.25, "end": 320.77, "word": "مثلا", "probability": 0.8650716145833334}, {"start": 320.77, "end": 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او", "probability": 0.92919921875}, {"start": 328.09, "end": 328.19, "word": " ال", "probability": 0.935546875}, {"start": 328.19, "end": 328.61, "word": " chloride", "probability": 0.98388671875}, {"start": 328.61, "end": 329.67, "word": " هذا", "probability": 0.7685546875}, {"start": 329.67, "end": 330.31, "word": " الراسب", "probability": 0.92529296875}, {"start": 330.31, "end": 330.67, "word": " له", "probability": 0.95263671875}, {"start": 330.67, "end": 331.41, "word": " قابلية", "probability": 0.969970703125}, {"start": 331.41, "end": 331.69, "word": " انه", "probability": 0.92236328125}, {"start": 331.69, "end": 331.99, "word": " يعمل", "probability": 0.9816080729166666}, {"start": 331.99, "end": 332.57, "word": " absorption", "probability": 0.8974609375}, {"start": 332.57, "end": 332.91, "word": " ل", "probability": 0.9052734375}, {"start": 332.91, "end": 333.15, "word": " its", "probability": 0.81201171875}, {"start": 333.15, "end": 333.49, "word": " own", "probability": 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التاني طبعا مش هيكون موجود ليه؟ لأنه وجود الاتنين مع بعض بعتراسب فهو دائما في عندي ايون واحد بس موجود بوافرة هذا الايون اللي موجود بوافرة ايش بيعطيني؟", "tokens": [2407, 4724, 25957, 43761, 614, 25809, 31439, 42963, 1829, 11536, 13672, 1829, 3714, 29245, 23328, 4724, 14407, 5172, 2288, 4724, 5016, 36520, 3224, 614, 25809, 15844, 21136, 9566, 5016, 42963, 1829, 11536, 16712, 7649, 1829, 23032, 3555, 3615, 995, 37893, 39896, 30544, 3714, 29245, 23328, 32239, 3224, 22807, 5296, 33456, 3224, 49610, 23328, 2423, 9307, 1863, 9957, 20449, 45030, 11242, 4724, 34268, 23557, 35457, 6156, 3224, 2407, 11778, 16373, 15042, 8978, 18871, 16254, 1975, 1829, 11536, 36764, 24401, 4724, 3794, 3714, 29245, 23328, 4724, 14407, 5172, 25720, 23758, 42963, 1829, 11536, 13672, 1829, 3714, 29245, 23328, 4724, 14407, 5172, 25720, 1975, 1829, 8592, 4724, 40228, 9566, 1829, 22653, 22807], "avg_logprob": -0.24602272077040238, "compression_ratio": 2.01025641025641, "no_speech_prob": 1.3947486877441406e-05, "words": 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" chloride", "probability": 0.90576171875}, {"start": 389.88, "end": 390.08, "word": " في", "probability": 0.8837890625}, {"start": 390.08, "end": 390.38, "word": " المحلول", "probability": 0.9964599609375}, {"start": 390.38, "end": 390.58, "word": " حالة", "probability": 0.4032389322916667}, {"start": 390.58, "end": 390.86, "word": " عظمه", "probability": 0.7598876953125}, {"start": 390.86, "end": 390.92, "word": " ال", "probability": 0.73828125}, {"start": 390.92, "end": 391.38, "word": " chloride", "probability": 0.9892578125}, {"start": 391.38, "end": 392.14, "word": " بيكون", "probability": 0.8994140625}, {"start": 392.14, "end": 392.68, "word": " عامل", "probability": 0.9928385416666666}, {"start": 392.68, "end": 392.94, "word": " a", "probability": 0.5146484375}, {"start": 392.94, "end": 393.48, "word": " primary", "probability": 0.9462890625}, {"start": 393.48, "end": 394.14, "word": " absorption", "probability": 0.65283203125}, {"start": 394.14, "end": 394.74, "word": " 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عادة من 120 ل 150 درجة لمدة ساعة زمن مثلا يبقى بعمل ال drying عند حرارة 120 ل 150 درجة في العادة لمدة ساعة من الزمن تقريبا يعني", "tokens": [32277, 41361, 10874, 2407, 8592, 6156, 3555, 2655, 47283, 3215, 14407, 25894, 2423, 22709, 9090, 1975, 8315, 4724, 25957, 1211, 2423, 22709, 6055, 4587, 16572, 3555, 995, 37495, 22653, 6225, 18513, 3660, 9154, 10411, 5296, 8451, 11778, 47341, 3660, 32767, 41891, 8608, 995, 27884, 30767, 27842, 50113, 15040, 7251, 3555, 4587, 7578, 4724, 25957, 1211, 2423, 22709, 43242, 11331, 2288, 9640, 3660, 10411, 5296, 8451, 11778, 47341, 3660, 8978, 18863, 18513, 3660, 32767, 41891, 8608, 995, 27884, 9154, 6024, 110, 27842, 6055, 4587, 16572, 3555, 995, 37495, 22653], "avg_logprob": -0.1703827233796709, "compression_ratio": 1.8488372093023255, "no_speech_prob": 4.172325134277344e-07, "words": [{"start": 633.72, "end": 634.24, "word": "اسكان", "probability": 0.248809814453125}, {"start": 634.24, "end": 634.74, "word": " جوش", "probability": 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بحط", "probability": 0.9099934895833334}, {"start": 661.39, "end": 661.75, "word": " الورقة", "probability": 0.9752604166666666}, {"start": 661.75, "end": 661.99, "word": " يعني", "probability": 0.84423828125}, {"start": 661.99, "end": 662.13, "word": " في", "probability": 0.79833984375}, {"start": 662.13, "end": 662.77, "word": " porcelain", "probability": 0.7085774739583334}, {"start": 662.77, "end": 663.87, "word": " crucible", "probability": 0.7403564453125}, {"start": 663.87, "end": 664.97, "word": " وبسخن", "probability": 0.85211181640625}, {"start": 664.97, "end": 665.05, "word": " ال", "probability": 0.8076171875}, {"start": 665.05, "end": 665.55, "word": " porcelain", "probability": 0.91064453125}, {"start": 665.55, "end": 666.01, "word": " crucible", "probability": 0.97119140625}, {"start": 666.01, "end": 666.35, "word": " هذه", "probability": 0.5322265625}, {"start": 666.35, "end": 667.25, "word": " باستخدام", "probability": 0.98876953125}, {"start": 667.25, "end": 667.65, 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ايش ضاله؟ ضالوا كلورايد زي ما هو يعني Sodium chloride مثلا ال counter ion تبعه اعطانا 58.5 فمن الميطين 143 اعطانا 58.5 ليه؟ لأنه تم احتجازه جوا ومش ملاقي Silver يتفاعل معاه، هذه حاجة ممكن حاجة تانية، انقول اه و الله تم احتباس كمية معينة من ال silver nitrate", "tokens": [7435, 11622, 38207, 9154, 33251, 1211, 13063, 995, 25708, 1975, 1829, 8592, 48812, 6027, 3224, 22807, 48812, 6027, 14407, 9122, 1211, 13063, 995, 25708, 30767, 1829, 19446, 31439, 37495, 22653, 42059, 2197, 35434, 50113, 15040, 2423, 5682, 17437, 6055, 3555, 3615, 3224, 1975, 3615, 9566, 7649, 995, 21786, 13, 20, 6156, 27842, 9673, 1829, 9566, 9957, 3499, 18, 1975, 3615, 9566, 7649, 995, 21786, 13, 20, 32239, 3224, 22807, 5296, 33456, 3224, 46811, 1975, 33753, 7435, 31377, 3224, 10874, 14407, 4032, 2304, 8592, 3714, 15040, 38436, 15861, 7251, 2655, 5172, 995, 30241, 20449, 40294, 12399, 29538, 11331, 26108, 3660, 3714, 43020, 11331, 26108, 3660, 6055, 7649, 10632, 12399, 16472, 39648, 1975, 3224, 4032, 21984, 46811, 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0.1805419921875}, {"start": 2146.1, "end": 2146.58, "word": " factor", "probability": 0.80224609375}, {"start": 2146.58, "end": 2147.26, "word": " نظري", "probability": 0.97705078125}, {"start": 2147.26, "end": 2147.94, "word": " بنحسب", "probability": 0.8463541666666666}, {"start": 2147.94, "end": 2148.46, "word": " حساب", "probability": 0.9871419270833334}, {"start": 2148.46, "end": 2148.96, "word": " مش", "probability": 0.7939453125}, {"start": 2148.96, "end": 2149.36, "word": " عملي", "probability": 0.904296875}], "temperature": 1.0}, {"id": 97, "seek": 217512, "start": 2150.5, "end": 2175.12, "text": "بعرف على طول وزنة الـA الانالايت تبعي إذا مجرد أني أعرف وزن الـGravimetric factor وعندي وزنة الراسب بعرف على طول وزنة الانالايت طب إيش هو الـGravimetric factor؟ جال الـGravimetric factor هو عبارة عن A على B A على B هذه مول ريشيو Stoichiometric mole ratio", "tokens": [3555, 3615, 28480, 15844, 23032, 12610, 4032, 11622, 1863, 3660, 2423, 39184, 32, 2423, 7649, 6027, 995, 36081, 6055, 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"probability": 0.6160888671875}, {"start": 2165.58, "end": 2165.96, "word": " جال", "probability": 0.60546875}, {"start": 2165.96, "end": 2166.6, "word": " الـGravimetric", "probability": 0.9424641927083334}, {"start": 2166.6, "end": 2167.3, "word": " factor", "probability": 0.9208984375}, {"start": 2167.3, "end": 2168.08, "word": " هو", "probability": 0.96435546875}, {"start": 2168.08, "end": 2168.52, "word": " عبارة", "probability": 0.99560546875}, {"start": 2168.52, "end": 2168.82, "word": " عن", "probability": 0.98486328125}, {"start": 2168.82, "end": 2169.06, "word": " A", "probability": 0.54345703125}, {"start": 2169.06, "end": 2169.3, "word": " على", "probability": 0.69677734375}, {"start": 2169.3, "end": 2169.66, "word": " B", "probability": 0.923828125}, {"start": 2169.66, "end": 2170.4, "word": " A", "probability": 0.340087890625}, {"start": 2170.4, "end": 2170.58, "word": " على", "probability": 0.8515625}, {"start": 2170.58, "end": 2170.74, "word": " B", "probability": 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"temperature": 1.0}, {"id": 99, "seek": 223096, "start": 2202.74, "end": 2230.96, "text": "بيعطيني اتنين مول سلفري كلورايت فهذا is a stoichiometric factor مول ratio كويس فهنا في عندى اتنين كلور تحت لازم يكون عندى اتنين كلور هاي ال a و ال b بده اخلى البسط عدد المولات زي المقام بالنسبة لل analyte بس البسط زي ال a زي المقام البسط في اتنين كلور المقام بده يكون في ايه اتنين كلور ال agc اللي فيه بس كلورة واحدة اذا بده احط هنا اتنين لإني عندى اتنين كلور", "tokens": [3555, 40228, 9566, 1829, 22653, 1975, 2655, 1863, 9957, 3714, 12610, 8608, 46538, 16572, 9122, 1211, 13063, 995, 36081, 6156, 3224, 15730, 307, 257, 22784, 18543, 29470, 5952, 3714, 12610, 8509, 9122, 45865, 3794, 6156, 3224, 8315, 8978, 43242, 7578, 1975, 2655, 1863, 9957, 9122, 1211, 13063, 6055, 33753, 5296, 31377, 2304, 7251, 30544, 43242, 7578, 1975, 2655, 1863, 9957, 9122, 1211, 13063, 8032, 47302, 2423, 257, 4032, 2423, 272, 47525, 3224, 1975, 9778, 23942, 29739, 3794, 9566, 6225, 3215, 3215, 9673, 12610, 9307, 30767, 1829, 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101, "seek": 228080, "start": 2251.82, "end": 2280.8, "text": "وزنة الراسب في الـ gravimetric factor سهل جدا و مباشر كل الحلول اللي عندنا بنفس الطريقة في الكتاب لكن احنا بدناش نحل بهذه الطريقة احنا في عندنا طريقة أسهل في الحل اتعلمناها و عرفناها و اتعودنا عليها و بدهاش حافظها لازم تتذكر ايش ال gravimetric factor علشان تستخدمه بدناش نتذكر حاجة احنا احنا بنحل باستخدام ال millimoles", "tokens": [2407, 11622, 1863, 3660, 34892, 32277, 3555, 8978, 2423, 39184, 7427, 332, 17475, 5952, 8608, 3224, 1211, 10874, 28259, 4032, 3714, 3555, 33599, 2288, 28242, 21542, 1211, 12610, 13672, 1829, 43242, 8315, 44945, 36178, 41950, 16572, 28671, 8978, 33251, 2655, 16758, 44381, 1975, 5016, 8315, 47525, 8315, 8592, 8717, 5016, 1211, 39627, 24192, 41950, 16572, 28671, 1975, 5016, 8315, 8978, 43242, 8315, 23032, 16572, 28671, 5551, 3794, 3224, 1211, 8978, 21542, 1211, 1975, 2655, 3615, 19528, 8315, 11296, 4032, 6225, 28480, 8315, 11296, 4032, 1975, 2655, 3615, 23328, 8315, 25894, 11296, 4032, 47525, 3224, 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"end": 2428.66, "word": " sulphide", "probability": 0.950927734375}, {"start": 2428.66, "end": 2429.06, "word": " هنفيه", "probability": 0.62860107421875}, {"start": 2429.06, "end": 2429.46, "word": " تلاتة", "probability": 0.91162109375}, {"start": 2429.46, "end": 2429.94, "word": " sulphur", "probability": 0.6805419921875}], "temperature": 1.0}, {"id": 108, "seek": 245988, "start": 2430.76, "end": 2459.88, "text": "هنا في سلفر واحدة اذا بدي اضافه هنا ثلاثة بقول ماعنى كلام يبجأ انا ماعندي غير ال millimol بعرفش احل اي مسألة او مفتاح حالي دائما هو ال millimol انسى انك تفكر بحاجة تانية بدك تحل اي مسألة بس مدام هي stoichiometric ال millimol بس هدا هو هتلاقي المطلوب داخلها من غير ما تبدأ المجهود حتى بقول millimol bismuth sulphate بساوية تلت ال millimol barium sulphate", "tokens": [3224, 8315, 8978, 8608, 46538, 2288, 36764, 24401, 3660, 1975, 15730, 4724, 16254, 1975, 11242, 31845, 3224, 34105, 38637, 1211, 5718, 104, 3660, 4724, 39648, 19446, 3615, 1863, 7578, 28242, 10943, 7251, 3555, 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هتلاقي", "probability": 0.9534912109375}, {"start": 2450.74, "end": 2451.4, "word": " المطلوب", "probability": 0.9459228515625}, {"start": 2451.4, "end": 2452.28, "word": " داخلها", "probability": 0.9825439453125}, {"start": 2452.28, "end": 2452.5, "word": " من", "probability": 0.98193359375}, {"start": 2452.5, "end": 2452.74, "word": " غير", "probability": 0.997802734375}, {"start": 2452.74, "end": 2452.92, "word": " ما", "probability": 0.61669921875}, {"start": 2452.92, "end": 2453.76, "word": " تبدأ", "probability": 0.8577473958333334}, {"start": 2453.76, "end": 2454.14, "word": " المجهود", "probability": 0.9478759765625}, {"start": 2454.14, "end": 2454.56, "word": " حتى", "probability": 0.916259765625}, {"start": 2454.56, "end": 2455.54, "word": " بقول", "probability": 0.68603515625}, {"start": 2455.54, "end": 2456.06, "word": " millimol", "probability": 0.9484049479166666}, {"start": 2456.06, "end": 2456.54, "word": " bismuth", "probability": 0.6787516276041666}, {"start": 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2464.21, "end": 2464.43, "word": " milligram", "probability": 0.95361328125}, {"start": 2464.43, "end": 2465.25, "word": " على", "probability": 0.86767578125}, {"start": 2465.25, "end": 2466.23, "word": " الفورمولوية؟", "probability": 0.9787946428571429}, {"start": 2466.23, "end": 2466.45, "word": " اذا", "probability": 0.872314453125}, {"start": 2466.45, "end": 2466.67, "word": " هاي", "probability": 0.4989013671875}, {"start": 2466.67, "end": 2466.75, "word": " ال", "probability": 0.87255859375}, {"start": 2466.75, "end": 2467.27, "word": " milligram", "probability": 0.9765625}, {"start": 2467.27, "end": 2467.57, "word": " على", "probability": 0.70068359375}, {"start": 2467.57, "end": 2467.73, "word": " ال", "probability": 0.7373046875}, {"start": 2467.73, "end": 2468.33, "word": " milligram", "probability": 0.97314453125}, {"start": 2468.33, "end": 2469.51, "word": " النتيجة", "probability": 0.8892822265625}, {"start": 2469.51, "end": 2469.79, "word": " ال", "probability": 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2497.09, "end": 2497.39, "word": " formula", "probability": 0.814453125}, {"start": 2497.39, "end": 2497.61, "word": " وات", "probability": 0.205596923828125}, {"start": 2497.61, "end": 2498.03, "word": " تبعته", "probability": 0.8521728515625}, {"start": 2498.03, "end": 2498.41, "word": " عالية", "probability": 0.9708658854166666}, {"start": 2498.41, "end": 2498.57, "word": " لو", "probability": 0.91650390625}, {"start": 2498.57, "end": 2498.97, "word": " طلعت", "probability": 0.8772786458333334}, {"start": 2498.97, "end": 2499.23, "word": " عليها", "probability": 0.9521484375}, {"start": 2499.23, "end": 2499.73, "word": " جداش", "probability": 0.8240559895833334}], "temperature": 1.0}, {"id": 111, "seek": 252440, "start": 2500.92, "end": 2524.4, "text": "1876 عشانك لو عندك كمية قليلة من الفوسفات بتعطيك كمية كبيرة من الراصد يعني بتقدر تعيين كميات الفوسفات موجودة بإيه بكميات قليلة للغاية طيب ما علينا احنا بيقول find percentage phosphorus جداش عندي percentage phosphorus في العينة وكمان مطلوب كمان بيقولك find percentage P2O5", "tokens": [6494, 25026, 6225, 8592, 7649, 4117, 45164, 43242, 4117, 9122, 2304, 10632, 12174, 20292, 37977, 9154, 27188, 41779, 5172, 9307, 39894, 3615, 9566, 1829, 4117, 9122, 2304, 10632, 9122, 3555, 48923, 9154, 34892, 33546, 3215, 37495, 22653, 39894, 28543, 2288, 37279, 1829, 9957, 9122, 2304, 1829, 9307, 27188, 41779, 5172, 9307, 3714, 29245, 23328, 3660, 4724, 28814, 1829, 3224, 4724, 24793, 1829, 9307, 12174, 20292, 37977, 24976, 17082, 995, 10632, 23032, 1829, 3555, 19446, 25894, 8315, 1975, 5016, 8315, 4724, 1829, 39648, 915, 9668, 46741, 10874, 3215, 33599, 18871, 16254, 9668, 46741, 8978, 18863, 9957, 3660, 4032, 24793, 7649, 3714, 9566, 1211, 37746, 9122, 2304, 7649, 4724, 1829, 39648, 4117, 915, 9668, 430, 17, 46, 20], "avg_logprob": -0.18669872253369063, "compression_ratio": 1.819327731092437, "no_speech_prob": 4.172325134277344e-07, "words": [{"start": 2500.9199999999996, "end": 2501.7999999999997, "word": "1876", "probability": 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0.79736328125}, {"start": 2518.34, "end": 2519.36, "word": " العينة", "probability": 0.9093424479166666}, {"start": 2519.36, "end": 2520.28, "word": " وكمان", "probability": 0.8917643229166666}, {"start": 2520.28, "end": 2521.08, "word": " مطلوب", "probability": 0.9117431640625}, {"start": 2521.08, "end": 2521.4, "word": " كمان", "probability": 0.8408203125}, {"start": 2521.4, "end": 2521.78, "word": " بيقولك", "probability": 0.938232421875}, {"start": 2521.78, "end": 2522.12, "word": " find", "probability": 0.94970703125}, {"start": 2522.12, "end": 2523.02, "word": " percentage", "probability": 0.9072265625}, {"start": 2523.02, "end": 2524.4, "word": " P2O5", "probability": 0.885009765625}], "temperature": 1.0}, {"id": 112, "seek": 254325, "start": 2526.65, "end": 2543.25, "text": "بنقول فش أبسط من هيك ناخد المطلوب الأول بدنا percentage phosphorus يعني بنجيب milligram phosphorus انا معايا بكتب ال millimoles يعني هيطلع معايا المطلوب مباشرة مش هلاجى حاجة غيره مطلوبة او مجهولة فبقول الفوسفور هان واحد هان واحد", "tokens": [3555, 1863, 39648, 6156, 8592, 5551, 3555, 3794, 9566, 9154, 39896, 4117, 8717, 47283, 3215, 9673, 9566, 1211, 37746, 16247, 12610, 47525, 8315, 9668, 46741, 37495, 22653, 44945, 7435, 1829, 3555, 38298, 46741, 1975, 8315, 20449, 995, 25528, 4724, 4117, 2655, 3555, 2423, 1728, 332, 7456, 37495, 22653, 39896, 9566, 1211, 3615, 20449, 995, 25528, 9673, 9566, 1211, 37746, 3714, 3555, 33599, 25720, 37893, 8032, 15040, 7435, 7578, 11331, 26108, 3660, 32771, 13546, 3224, 3714, 9566, 1211, 37746, 3660, 1975, 2407, 3714, 7435, 3224, 12610, 3660, 6156, 3555, 39648, 27188, 41779, 5172, 13063, 8032, 7649, 36764, 24401, 8032, 7649, 36764, 24401], "avg_logprob": -0.2077205816612524, "compression_ratio": 1.7209302325581395, "no_speech_prob": 1.0728836059570312e-06, "words": [{"start": 2526.65, "end": 2527.51, "word": "بنقول", "probability": 0.6914876302083334}, {"start": 2527.51, "end": 2527.95, "word": " فش", "probability": 0.414306640625}, {"start": 2527.95, 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{"start": 2532.63, "end": 2533.33, "word": " phosphorus", "probability": 0.70654296875}, {"start": 2533.33, "end": 2533.87, "word": " انا", "probability": 0.6907958984375}, {"start": 2533.87, "end": 2534.19, "word": " معايا", "probability": 0.6901041666666666}, {"start": 2534.19, "end": 2534.59, "word": " بكتب", "probability": 0.71783447265625}, {"start": 2534.59, "end": 2534.71, "word": " ال", "probability": 0.70166015625}, {"start": 2534.71, "end": 2535.17, "word": " millimoles", "probability": 0.6996256510416666}, {"start": 2535.17, "end": 2535.99, "word": " يعني", "probability": 0.5904541015625}, {"start": 2535.99, "end": 2536.59, "word": " هيطلع", "probability": 0.86419677734375}, {"start": 2536.59, "end": 2536.83, "word": " معايا", "probability": 0.9778645833333334}, {"start": 2536.83, "end": 2537.19, "word": " المطلوب", "probability": 0.9903564453125}, {"start": 2537.19, "end": 2537.77, "word": " مباشرة", "probability": 0.9859619140625}, {"start": 2537.77, "end": 2538.21, 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"probability": 0.92333984375}, {"start": 2629.47, "end": 2630.35, "word": " الفورمولوات", "probability": 0.97998046875}], "temperature": 1.0}, {"id": 117, "seek": 266094, "start": 2632.26, "end": 2660.94, "text": "الكويس هان في ملي مول طبعا يعني بدي اعوض انا عن ايش ال formula weight ل ال P2O5 اقول نص ال formula weight ل P2O5 فالميلي جرام ل الأمونيا الوزنة الراسب على ال formula weight للأمونيا الوزنة الراسب على ال formula weight للأمونيا الوزنة الراسب على ال formula weight للأمونيا الوزنة الراسب على ال formula weight للأمونيا الوزنة الراسب على ال formula weight للأمونيا الوزنة الراسب على ال formula weight للأمونيا الوزنة الراسب على ال formula weight للأمونيا الوزنة الراسب على ال formula weight للأمونيا الوزنة الراسب على ال formula weight للأمونيا الوزنة الراسب على", "tokens": [6027, 4117, 45865, 3794, 8032, 7649, 8978, 3714, 20292, 3714, 12610, 23032, 3555, 3615, 995, 37495, 22653, 4724, 16254, 1975, 3615, 2407, 11242, 1975, 8315, 18871, 1975, 1829, 8592, 2423, 8513, 3364, 5296, 2423, 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طيب بنشوفكم الحصة الجاية ان شاء الله", "tokens": [3555, 3615, 11242, 9673, 12984, 16373, 1211, 13672, 1829, 4386, 9673, 12984, 16373, 1211, 13672, 1829, 39894, 30544, 37495, 22653, 6156, 43042, 10632, 13412, 2407, 10632, 1975, 2407, 10874, 3215, 6027, 10632, 13412, 2407, 10632, 1975, 8315, 21542, 9381, 3660, 25724, 995, 10632, 8032, 5016, 995, 12610, 16472, 3224, 1975, 3615, 9566, 1829, 4117, 45030, 11242, 16247, 2304, 12984, 1211, 15844, 50113, 1211, 37495, 22653, 29538, 9673, 12984, 16373, 1211, 4032, 11778, 16373, 15042, 3714, 3224, 15042, 25961, 2655, 9673, 3794, 10721, 37977, 6055, 44510, 12610, 4117, 16472, 3224, 37893, 8978, 32748, 16373, 25720, 1975, 2407, 20328, 3615, 49401, 3714, 5172, 2655, 39319, 11331, 6027, 11296, 11778, 16373, 15042, 1975, 44510, 10721, 20666, 39184, 13206, 8032, 2655, 2407, 36520, 24976, 5016, 1211, 6156, 28814, 15730, 21984, 12602, 3215, 21542, 9381, 3660, 25724, 995, 10632, 44945, 24793, 1211, 1975, 1829, 8608, 33604, 6027, 35186, 13412, 3555, 16758, 23032, 1829, 3555, 44945, 8592, 38688, 24793, 21542, 9381, 3660, 25724, 995, 10632, 16472, 13412, 16606, 21984], "avg_logprob": -0.12309450892413534, "compression_ratio": 2.11913357400722, "no_speech_prob": 9.59634780883789e-06, "words": [{"start": 2707.95, "end": 2708.35, "word": "بعض", "probability": 0.9890950520833334}, {"start": 2708.35, "end": 2708.95, "word": " المثائل", "probability": 0.9296875}, {"start": 2708.95, "end": 2709.13, "word": " اللي", "probability": 0.706787109375}, {"start": 2709.13, "end": 2709.27, "word": " ..", "probability": 0.273193359375}, {"start": 2709.27, "end": 2709.85, "word": " المثائل", "probability": 0.950439453125}, {"start": 2709.85, "end": 2709.97, "word": " اللي", "probability": 0.9755859375}, {"start": 2709.97, "end": 2710.47, "word": " بتكون", "probability": 0.984619140625}, {"start": 2710.47, "end": 2710.77, "word": " يعني", "probability": 0.948486328125}, {"start": 2710.77, "end": 2711.37, "word": " فرضية", "probability": 0.9357096354166666}, {"start": 2711.37, "end": 2711.69, "word": " شوية", "probability": 0.9148763020833334}, {"start": 2711.69, "end": 2711.87, "word": " او", "probability": 0.676513671875}, {"start": 2711.87, "end": 2712.29, "word": " جدالية", "probability": 0.88134765625}, {"start": 2712.29, "end": 2712.71, "word": " شوية", "probability": 0.9708658854166666}, {"start": 2712.71, "end": 2713.27, "word": " انا", "probability": 0.810791015625}, {"start": 2713.27, "end": 2713.63, "word": " الحصة", "probability": 0.9881184895833334}, {"start": 2713.63, "end": 2714.05, "word": " الجاية", "probability": 0.9518229166666666}, {"start": 2714.05, "end": 2714.79, "word": " هحاول", "probability": 0.987060546875}, {"start": 2714.79, "end": 2715.03, "word": " انه", "probability": 0.802001953125}, {"start": 2715.03, "end": 2715.53, "word": " اعطيك", "probability": 0.9806640625}, {"start": 2715.53, "end": 2715.79, "word": " بعض", "probability": 0.955810546875}, {"start": 2715.79, "end": 2716.19, "word": " الأمثل", "probability": 0.796630859375}, {"start": 2716.19, "end": 2716.47, "word": " على", "probability": 0.84130859375}, {"start": 2716.47, "end": 2717.23, "word": " مثل", "probability": 0.996826171875}, {"start": 2717.23, "end": 2717.63, "word": " يعني", "probability": 0.850830078125}, {"start": 2717.63, "end": 2717.89, "word": " هذه", "probability": 0.828125}, {"start": 2717.89, "end": 2718.47, "word": " المثائل", "probability": 0.973388671875}, {"start": 2718.47, "end": 2718.97, "word": " و", "probability": 0.892578125}, {"start": 2718.97, "end": 2719.53, "word": " دائما", "probability": 0.8196614583333334}, {"start": 2719.53, "end": 2720.41, "word": " مهما", "probability": 0.8893229166666666}, {"start": 2720.41, "end": 2720.81, "word": " كانت", "probability": 0.993408203125}, {"start": 2720.81, "end": 2721.27, "word": " المسألة", "probability": 0.8856201171875}, {"start": 2721.27, "end": 2722.11, "word": " تبدولك", "probability": 0.9114990234375}, {"start": 2722.11, "end": 2722.41, "word": " انه", "probability": 0.929443359375}, {"start": 2722.41, "end": 2722.55, "word": " مش", "probability": 0.99560546875}, {"start": 2722.55, "end": 2722.69, "word": " في", "probability": 0.81298828125}, {"start": 2722.69, "end": 2723.13, "word": " الدائرة", "probability": 0.8566080729166666}, {"start": 2723.13, "end": 2723.35, "word": " او", "probability": 0.924072265625}, {"start": 2723.35, "end": 2723.77, "word": " صعبة", "probability": 0.9876302083333334}, {"start": 2723.77, "end": 2724.67, "word": " مفتاح", "probability": 0.9693603515625}, {"start": 2724.67, "end": 2724.97, "word": " حالها", "probability": 0.9182942708333334}, {"start": 2724.97, "end": 2725.47, "word": " دائما", "probability": 0.9724934895833334}, {"start": 2725.47, "end": 2726.57, "word": " ابدأ", "probability": 0.8533528645833334}, {"start": 2726.57, "end": 2726.77, "word": " بالـ", "probability": 0.7181396484375}, {"start": 2726.77, "end": 2727.03, "word": " minimal", "probability": 0.1318359375}, {"start": 2727.03, "end": 2727.59, "word": " هتوصل", "probability": 0.900390625}, {"start": 2727.59, "end": 2727.97, "word": " للحل", "probability": 0.8162434895833334}, {"start": 2727.97, "end": 2729.49, "word": " فإذا", "probability": 0.7664388020833334}, {"start": 2729.49, "end": 2729.73, "word": " الله", "probability": 0.9208984375}, {"start": 2729.73, "end": 2730.09, "word": " رد", "probability": 0.96484375}, {"start": 2730.09, "end": 2730.65, "word": " الحصة", "probability": 0.99072265625}, {"start": 2730.65, "end": 2731.17, "word": " الجاية", "probability": 0.9793294270833334}, {"start": 2731.17, "end": 2732.47, "word": " بنكمل", "probability": 0.9324544270833334}, {"start": 2732.47, "end": 2733.05, "word": " اي", "probability": 0.79638671875}, {"start": 2733.05, "end": 2733.41, "word": " سؤال", "probability": 0.9807942708333334}, {"start": 2733.41, "end": 2733.53, "word": " يا", "probability": 0.98974609375}, {"start": 2733.53, "end": 2733.99, "word": " شباب", "probability": 0.99267578125}, {"start": 2733.99, "end": 2735.79, "word": " طيب", "probability": 0.7171223958333334}, {"start": 2735.79, "end": 2736.21, "word": " بنشوفكم", "probability": 0.932861328125}, {"start": 2736.21, "end": 2736.53, "word": " الحصة", "probability": 0.9959309895833334}, {"start": 2736.53, "end": 2736.81, "word": " الجاية", "probability": 0.9674479166666666}, {"start": 2736.81, "end": 2736.95, "word": " ان", "probability": 0.86962890625}, {"start": 2736.95, "end": 2737.15, "word": " شاء", "probability": 0.931396484375}, {"start": 2737.15, "end": 2737.21, "word": " الله", "probability": 0.9560546875}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2738.097, "duration_after_vad": 2660.0681249999902}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/4nyIYAzFnDE.srt b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/4nyIYAzFnDE.srt
new file mode 100644
index 0000000000000000000000000000000000000000..f50d10563f3827fcf34b5673e7f7456687b8f26d
--- /dev/null
+++ b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/4nyIYAzFnDE.srt
@@ -0,0 +1,1639 @@
+1
+00:00:20,650 --> 00:00:24,350
+بسم الله الرحمن الرحيم، اليوم إن شاء الله نكمل
+
+2
+00:00:24,350 --> 00:00:29,830
+شغلنا في الـ complexometric reactions أو titrations
+
+3
+00:00:29,830 --> 00:00:34,650
+بنتكلم في البداية عن الـ calculations اللي إحنا
+
+4
+00:00:34,650 --> 00:00:39,650
+بنجريها فيما يتعلق بالـ complexometric reactions
+
+5
+00:00:40,500 --> 00:00:43,920
+ونشوف طبيعة هذه الـ calculations وكيف بتختلف عن الـ
+
+6
+00:00:43,920 --> 00:00:48,360
+calculations اللي شفناها مثلاً في الـ acids والـ
+
+7
+00:00:48,360 --> 00:00:51,760
+bases. بشكل أساسي بنقول
+
+8
+00:00:53,930 --> 00:00:58,570
+الاختلاف الجوهري يتوقف، أو يعني يتعلق، بقيمة الـ
+
+9
+00:00:58,570 --> 00:01:02,390
+equilibrium constant. في المحاضرات الماضية كان
+
+10
+00:01:02,390 --> 00:01:07,190
+دائماً الـ equilibrium constant صغير، يعني عشر أس سالب كذا، لكن في الـ formation constant فيما يتعلق
+
+11
+00:01:07,190 --> 00:01:11,570
+بالـ complexometric reactions هنلاحظ أنه دائماً الـ
+
+12
+00:01:11,570 --> 00:01:15,970
+formation constant قيمة كبيرة. إلا أنه طبعاً يعني
+
+13
+00:01:15,970 --> 00:01:20,280
+ثابت تكوين، لابد إلا أنه يتكون الناتج بكميات محترمة
+
+14
+00:01:20,280 --> 00:01:26,480
+وهو يعني المتفاعلات يزيد منها كميات، لكن كميات
+
+15
+00:01:26,480 --> 00:01:31,760
+إشغالها بسيطة. فإحنا كنا ناقشنا هذا الموضوع سابقاً في
+
+16
+00:01:31,760 --> 00:01:36,710
+شباتر المقدمة، وقلنا أن حل أي مسألة equilibrium
+
+17
+00:01:36,710 --> 00:01:41,310
+يتوقف على قيمة الـ equilibrium constant، إما أن يكون
+
+18
+00:01:41,310 --> 00:01:44,990
+كبير زي هذا الشابتر، وهذا الشابتر فقط، يا إما يكون
+
+19
+00:01:44,990 --> 00:01:49,990
+غير كبير زي الشباتر اللي مرت معنا سابقاً، والشباتر اللي
+
+20
+00:01:49,990 --> 00:01:53,730
+بيجي كمان لاحقاً. هذا الـ chapter اللي بنعالج فيه
+
+21
+00:01:53,730 --> 00:01:59,260
+calculations في حالة ما إن الـ equilibrium
+
+22
+00:01:59,260 --> 00:02:02,700
+constant يكون عندي كبير. بنقول بشكل أساسي يعني نفس
+
+23
+00:02:02,700 --> 00:02:10,560
+الحسابات اللي شفناها سابقاً، لكن في الشباتر المقدمة
+
+24
+00:02:10,560 --> 00:02:14,100
+لكن كنا بنقول: والله A بيتفاعل مع B بيعطينا AB، والـ
+
+25
+00:02:14,100 --> 00:02:18,640
+equilibrium constant عالي أو كبير، هلأ هون ما بنقول
+
+26
+00:02:18,640 --> 00:02:23,040
+A بتفاعل مع B، بدنا نقول metal بتفاعل مع ligand أو
+
+27
+00:02:27,740 --> 00:02:31,140
+الفلان الفلاني بتفاعل مع ligand الفلاني، عشان
+
+28
+00:02:31,140 --> 00:02:35,700
+يعطيني complex. فهي لكن كحسابات نفس الكلام اللي
+
+29
+00:02:35,700 --> 00:02:39,380
+أخذناه في شباتر المقدمة، بس هنلاقيها أسهل كمان.
+
+30
+00:02:39,380 --> 00:02:45,590
+أبسط، مثلاً نطلع على المثال اللي قدامي، المثال بيقول:
+
+31
+00:02:45,590 --> 00:02:50,230
+A bivalent metal ion reacts with a ligand to form
+
+32
+00:02:50,230 --> 00:02:54,270
+a one to one complex. جملة مفيدة كتير، عندي metal
+
+33
+00:02:54,270 --> 00:02:58,850
+ion و ligand، والـ stoichiometry واحد لواحد. معادلة
+
+34
+00:02:58,850 --> 00:03:02,770
+سهلة جداً بيقول: find the concentration of the metal
+
+35
+00:03:02,770 --> 00:03:07,770
+ion in a solution prepared by mixing equal volumes
+
+36
+00:03:07,770 --> 00:03:12,590
+of 0.2 molar metal ion and 0.2 molar ligand.
+
+37
+00:03:12,590 --> 00:03:19,430
+وبيعطيني الـ KF عشرة أس ثمانية. عالي جداً، عشرة
+
+38
+00:03:19,430 --> 00:03:25,850
+أس ثمانية، معناته المتفاعلات هتتحول تقريباً كلها إلى
+
+39
+00:03:25,850 --> 00:03:32,390
+نواتج، إلا كمية قليلة مقدارها X، لأن الـ formation
+
+40
+00:03:32,390 --> 00:03:40,010
+constant طبعاً يعتبر large. لو
+
+41
+00:03:40,010 --> 00:03:45,200
+أجينا للمسألة بنقول: والله المعادلة metal ion و
+
+42
+00:03:45,200 --> 00:03:50,120
+ligand بيعطيني metal-ligand complex. بدي بس تنتبه
+
+43
+00:03:50,120 --> 00:03:53,160
+شوية، أنه دائماً ما دام نشتغل، أو بيعطيني formation
+
+44
+00:03:53,160 --> 00:03:57,380
+constant، يجب كتابة المعادلة على هيئة إيه؟
+
+45
+00:03:57,380 --> 00:04:00,900
+formation، مش dissociation زي ما كنا بنشوف سابقاً.
+
+46
+00:04:00,900 --> 00:04:04,360
+زمان كنا بنقول dissociation، لكن هلأ إيه؟
+
+47
+00:04:04,360 --> 00:04:07,960
+formation. هذه نقطة. النقطة الثانية اللي بحب ألفت
+
+48
+00:04:07,960 --> 00:04:15,240
+انتباهكم إليها، أنه هنجد equal volumes من الـ metal
+
+49
+00:04:15,240 --> 00:04:19,520
+والـ ligand، تم خلطهم مع بعض، أو إضافتهم لبعض. لما
+
+50
+00:04:19,520 --> 00:04:24,100
+نضيف equal volumes من حاجتين، معناته تركيزهم بده
+
+51
+00:04:24,100 --> 00:04:29,560
+ينزل للنصف. ليش بده ينزل للنصف؟ لأن الـ millimoles من
+
+52
+00:04:29,560 --> 00:04:33,980
+الأول، مثلاً الـ metal ion، الـ millimoles، millimoles
+
+53
+00:04:33,980 --> 00:04:41,070
+metal ion بدو يساوي 0.2 في الـ volume، فبتجد
+
+54
+00:04:41,070 --> 00:04:45,630
+تركيز الـ metal ion النهائي جاي 0.2 في V، هذه
+
+55
+00:04:45,630 --> 00:04:49,810
+الـ millimoles على الـ total volume. اتضاعف الـ volume.
+
+56
+00:04:49,810 --> 00:04:54,490
+ليش؟ لأنه خلطت metal ion مع ligand نفس الكمية، equal
+
+57
+00:04:54,490 --> 00:04:57,490
+volumes. هاي الـ volume مهما كان الـ volume مع الـ
+
+58
+00:04:57,490 --> 00:05:02,000
+volume، إذا صار 0.1 molar. معنى الكلام إيش حصل؟
+
+59
+00:05:02,000 --> 00:05:05,580
+لك تركيز، بدل ما كان 0.2 صار 0.1، نفس
+
+60
+00:05:05,580 --> 00:05:10,680
+الكلام. فلما نيجي نخلط two equal volumes
+
+61
+00:05:10,680 --> 00:05:14,640
+من حاجتين، على طول الحاجتين هدول كيف تركيزهم بينزل؟
+
+62
+00:05:14,640 --> 00:05:17,780
+للنصف مباشرةً. فما تتضايقش في الامتحان، إذا كان
+
+63
+00:05:17,780 --> 00:05:22,190
+ما أعطاكش الحجم. جاءك equal volumes، ليه؟ لأنه على طول
+
+64
+00:05:22,190 --> 00:05:25,670
+بتطلع التركيز الجديد مباشرةً. من حد يقول لك equal
+
+65
+00:05:25,670 --> 00:05:29,610
+volumes، معناته التركيز جاي للنصف، وهذا هو السبب. هي
+
+66
+00:05:29,610 --> 00:05:34,130
+الـ minimum. وهي الـ total volume، بما أنه الـ volume
+
+67
+00:05:34,130 --> 00:05:41,170
+اتضاعف، إذا التركيز بده ينزل للنصف. زي ما نحط اثنين
+
+68
+00:05:41,170 --> 00:05:45,930
+مولز في لتر solution، هذا اثنين مولر. طب لو حطينا
+
+69
+00:05:45,930 --> 00:05:49,910
+الاثنين مولز في اثنين لتر، مش لتر، بتقع النص طبعاً.
+
+70
+00:05:49,910 --> 00:05:53,510
+بيصير واحد مولر. ماشي يا شباب؟ فبس هذه النقطة برضه
+
+71
+00:05:53,510 --> 00:05:57,950
+كويس أنه نأخذ بالنا منها. الآن هو جالس أنه
+
+72
+00:05:57,950 --> 00:06:01,650
+بيتفعلوا بالنسبة واحد لواحد، حلو كتير. بنقول يا
+
+73
+00:06:01,650 --> 00:06:07,910
+شباب، لما يتفعلوا، بما أن الـ KF كبير، إذا تحولوا
+
+74
+00:06:07,910 --> 00:06:14,370
+لنواتج. النواتج هذه عبارة عن 0.1 molar من الـ
+
+75
+00:06:14,370 --> 00:06:19,810
+ML 2+، أو من الـ complex. يعني بمعنى آخر عندي
+
+76
+00:06:19,810 --> 00:06:28,590
+الـ metal زائد الـ ligand، خطوة، metal ligand، خطوة إيه؟
+
+77
+00:06:28,590 --> 00:06:32,910
+شبه هذه الخطوة. هذه الخطوة quantitative. عندي هذا
+
+78
+00:06:32,910 --> 00:06:36,530
+0.1 وهذا 0.1، هذا صفر، هذا صار صفر، هذا
+
+79
+00:06:36,530 --> 00:06:41,860
+صار 0.1. مثلاً. لكن عند الـ equilibrium طبعاً هذا
+
+80
+00:06:41,860 --> 00:06:45,980
+مش 0.1 بالظبط، لأ بده يجي مقدار X. فأنا عندي
+
+81
+00:06:45,980 --> 00:06:52,260
+هنا 0.1 - X، X، X. الـ KF هتساوي 0.1
+
+82
+00:06:52,260 --> 00:06:56,680
+- X على الـ X تربيع، وطبعاً بدي أعمل الفرضية
+
+83
+00:06:56,680 --> 00:07:02,520
+بتاعتي. الـ 0.1 أكبر كتير من الـ X، وبالتالي بطلع
+
+84
+00:07:02,520 --> 00:07:06,560
+قيمة الـ X. بتطلع 3.2 × 10⁻⁵. طب الـ
+
+85
+00:07:06,560 --> 00:07:10,240
+relative error قليل جداً، إذا بالفعل الـ 0.1
+
+86
+00:07:10,240 --> 00:07:14,380
+أكبر كتير من الـ X. طب إيش هي؟ يبقى الفرضية صحيحة.
+
+87
+00:07:14,380 --> 00:07:17,260
+إيش هي الـ X؟ قال هي تركيز الـ metal ion اللي هو
+
+88
+00:07:17,260 --> 00:07:21,220
+بدّي إياه. إذا تركيز الـ metal ion 3.2 × 10⁻⁵
+
+89
+00:07:21,220 --> 00:07:25,420
+مولار. لكن شوف منطق الحل، إنه
+
+90
+00:07:25,420 --> 00:07:30,620
+المتفاعلات تحولت لنواتج، وطبعاً مش بنسبة مئة في
+
+91
+00:07:30,620 --> 00:07:34,920
+المئة في الحقيقة، لأ، بس قليل مقدارها X، ضايل على
+
+92
+00:07:34,920 --> 00:07:38,600
+هيئة متفاعلات. ليش هذا الكلام؟ جاي لأنه الـ
+
+93
+00:07:38,600 --> 00:07:42,900
+formation constant كبير، بمعنى أنه رايح ناحية
+
+94
+00:07:42,900 --> 00:07:47,540
+النواتج بشكل كبير. التفاعل رايح ناحية النواتج بشكل
+
+95
+00:07:47,540 --> 00:07:52,680
+كبير. معظم المتفاعلات تحولت إلى نواتج، و بقى كمية
+
+96
+00:07:52,680 --> 00:07:59,020
+مهملة مقدارها إيه؟ X. وهذه X كمية قليلة للغاية.
+
+97
+00:07:59,020 --> 00:08:06,530
+طيب، كمان مثال. بيقول: في الـ silver ion forms a
+
+98
+00:08:06,530 --> 00:08:11,550
+stable one to one complex with the triene. عند الـ
+
+99
+00:08:11,550 --> 00:08:17,950
+silver ion بيتفاعل مع ligand اسمه triene. كويس. الـ
+
+100
+00:08:17,950 --> 00:08:20,970
+stoichiometry واحد لواحد، حلو كتير. واحد لواحد يعني
+
+101
+00:08:20,970 --> 00:08:24,650
+ما فيه أي تعقيد. لكن إيش بيقول؟ بيقول: calculate
+
+102
+00:08:24,650 --> 00:08:28,590
+the silver ion concentration at equilibrium when
+
+103
+00:08:28,590 --> 00:08:32,290
+25 مل من 0.01 molar silver
+
+104
+00:08:32,290 --> 00:08:40,210
+nitrate is added to 50 ml of 0.015 molar ethylene
+
+105
+00:08:47,220 --> 00:08:51,360
+في زيادة من واحد منهم. الاثنين بيتفعلوا بنسبة واحد
+
+106
+00:08:51,360 --> 00:08:54,980
+لواحد، لكن أنا مش ضايف الأول ضد الثاني بالظبط اللي
+
+107
+00:08:54,980 --> 00:08:58,820
+بيتفعل، ونهائي أنا كلهم ما يتحولوا لنواتج، أنا ضايف
+
+108
+00:08:58,820 --> 00:09:03,060
+حاجتين مختلفتين، مختلفات في الـ millimoles، يعني
+
+109
+00:09:03,060 --> 00:09:10,840
+تركيزات مختلفة، وبالتالي واحد منهم هيزيد. طيب، أنا
+
+110
+00:09:10,840 --> 00:09:14,440
+بقول في البداية: هي الـ Ag⁺ والـ triene بيعطوني الـ
+
+111
+00:09:14,440 --> 00:09:18,660
+complex. الـ millimoles silver added، طبعاً الـ volume
+
+112
+00:09:18,660 --> 00:09:22,560
+في الـ molarity. المليمولز يحاول أن يضيف الـ volume
+
+113
+00:09:22,560 --> 00:09:26,200
+في الـ molarity. يلاحظ أن هذه 0.25 وهذه 0.75، بما أنه
+
+114
+00:09:26,200 --> 00:09:31,240
+بيتفعل بنسبة واحد لواحد، ممكن أكتب هيك: 0.25، 0.75، 0
+
+115
+00:09:31,240 --> 00:09:37,600
+قبل التفاعل. هذه صارت 0.25 تتفاعل مع يعني هذه
+
+116
+00:09:37,600 --> 00:09:42,060
+صارت 0. هذه زاد منها 0.5، وهذه اتكون منها
+
+117
+00:09:42,060 --> 00:09:45,860
+0.25. لماذا؟ لأن 0.25 بتفاعل مع
+
+118
+00:09:45,860 --> 00:09:49,000
+0.25 بتعطيني 0.25 مش أكثر ولا
+
+119
+00:09:49,000 --> 00:09:55,460
+أقل. ماشي؟ إذا بقدر أجيب التركيزات الآن. للـ triene إيش
+
+120
+00:09:55,460 --> 00:09:58,540
+تركيزها؟ 0.25 millimole اللي تكونت على الـ
+
+121
+00:09:58,540 --> 00:10:02,160
+total volume 75. للـ triene اللي زادت 0.5 على الـ total volume 75، هي طبعاً
+
+122
+00:10:02,160 --> 00:10:09,310
+صفر. إذا هي عبارة عن صفر، ما فيش لها قيمة، ما فيش لها
+
+123
+00:10:09,310 --> 00:10:13,630
+تركيز. لكن هذا بالمعالجة على هيئة quantitative step.
+
+124
+00:10:13,630 --> 00:10:19,650
+خطوة quantitative. الآن خطوة الـ equilibrium بقول:
+
+125
+00:10:19,650 --> 00:10:24,890
+والله الـ silver، قلت راح يعطيني الـ silver، راح
+
+126
+00:10:24,890 --> 00:10:28,690
+هذه صفر كانت. هذه 0.5 على 75، اللي هي
+
+127
+00:10:28,690 --> 00:10:32,430
+زادت. هذه أصلاً 0.5 على 75، اللي أصلاً
+
+128
+00:10:32,430 --> 00:10:35,530
+تكونت. إلا طبعاً لازم تجيء مقدار X. عندها إن الـ 0.
+
+129
+00:10:35,530 --> 00:10:40,510
+5 على 75، طبعاً بدجيها X. وهنا x من الـ
+
+130
+00:10:40,510 --> 00:10:46,750
+formation constant. بقدر أقول: 0.5 على
+
+131
+00:10:46,750 --> 00:10:49,970
+75 - X على الـ X. في الـ 0.5 على
+
+132
+00:10:49,970 --> 00:10:56,750
+75 + X. وطبعاً بدي أرجع أعمل فرضية بديهية
+
+133
+00:10:56,750 --> 00:11:00,350
+أنه أستخدم 0.5 على 75 أكبر كتير من
+
+134
+00:11:00,350 --> 00:11:04,810
+الـ X. فالـ X بتطلع عندي 1 × 10⁻⁸.
+
+135
+00:11:09,360 --> 00:11:14,080
+لما بدي أجي أقارن الـ X بالـ 0.25 على 75، العشرة
+
+136
+00:11:14,080 --> 00:11:19,320
+أس سالب ثمانية أقل كتير من الربع على 75، وبالتالي الـ
+
+137
+00:11:19,320 --> 00:11:23,060
+relative error لما نحسبه، بيطلع 3 × 10⁻⁴
+
+138
+00:11:23,060 --> 00:11:28,850
+في المئة، ولا شيء. علشان هيك الـ X يمكن إلغاؤها
+
+139
+00:11:28,850 --> 00:11:33,790
+بسهولة. لهذا السبب بقول: يبقى الـ X هي عبارة عن الـ
+
+140
+00:11:33,790 --> 00:11:37,430
+silver. إذا تركيز الـ silver هو عبارة عن 1 × 10⁻⁸. واضح أنه يعني أسئلة زي هذه هي
+
+141
+00:11:37,430 --> 00:11:42,030
+أسئلة مكررة مرت معنا يعني في chapter المقدمة اللي
+
+142
+00:11:42,030 --> 00:11:46,830
+حكينا فيه عن الـ equilibrium، لكن كنا نستخدم A و B و
+
+143
+00:11:46,830 --> 00:11:50,540
+C وكلام زي هيك، لكن هالجية بتقولنا silver و triene
+
+144
+00:11:50,540 --> 00:11:54,440
+و complex مثلاً، يعني، لكن نفس المنهجية في الحل. طيب،
+
+145
+00:12:01,000 --> 00:12:07,190
+الآن ننتقل لموضوع الـ EDTA والمعايرات الخاصة بالـ
+
+146
+00:12:07,190 --> 00:12:10,950
+EDTA. وفي البداية بنتكلم عن الـ EDTA Equilibria في
+
+147
+00:12:10,950 --> 00:12:17,310
+الحقيقة. فبنقول يعني أن الـ EDTA تستخدم لمعايرة الـ
+
+148
+00:12:17,310 --> 00:12:21,730
+metal ions. الـ EDTA تستخدم لمعايرة الـ metal ions
+
+149
+00:12:21,730 --> 00:12:29,310
+بالتحديد. الـ metal ions يعني بخلاف المجموعة الأولى
+
+150
+00:12:29,310 --> 00:12:33,260
+عادةً. كل الـ metal ions لكن بخلاف المجموعة الأولى، لأن
+
+151
+00:12:33,260 --> 00:12:36,320
+المجموعة الأولى الـ metal ions تبعها مع الـ EDTA الـ
+
+152
+00:12:36,320 --> 00:12:40,180
+formation constant يعني قليل جداً، يعني لا يكاد يذكر
+
+153
+00:12:40,180 --> 00:12:44,820
+يعني قليل كتير. لكن المجموعة الثانية حلوة، هنفرجيكم
+
+154
+00:12:44,820 --> 00:12:49,060
+بعض القيم، والـ transition metals ممتازة جداً مع الـ
+
+155
+00:12:49,060 --> 00:12:54,190
+EDTA. لكن المجموعة الأولى هتكون رديئة، هذه نقطة.
+
+156
+00:12:54,190 --> 00:12:59,430
+نقطة ثانية، طبعاً الـ EDTA هي عبارة عن polydentate
+
+157
+00:12:59,430 --> 00:13:05,630
+ligand، chelating agent، لأنها طبعاً polydentate،
+
+158
+00:13:05,630 --> 00:13:08,550
+بتكون one to one complex مع الـ metal ions، هذا
+
+159
+00:13:08,550 --> 00:13:15,600
+الكلام مر معنا سابقاً وإحنا عارفينه كويس كتير. أيضاً
+
+160
+00:13:15,600 --> 00:13:21,840
+بتكون complexes مستقرة
+
+161
+00:13:21,840 --> 00:13:27,780
+عالية، لأنها
+
+162
+00:13:27,780 --> 00:13:30,740
+مستقرة عالية، لأنها مستقرة عالية، لأنها مستقرة
+
+163
+00:13:30,740 --> 00:13:38,480
+عالية، لأنها مستقرة عالية. والـ chelates طبعاً فيها multi
+
+164
+00:13:38,480 --> 00:13:44,080
+-dentate. هي عبارة عن multi-dentate chelating
+
+165
+00:13:44,080 --> 00:13:49,020
+agent أو ligand. ولاحظوا أنتو الـ EDTA تحديداً هذه
+
+166
+00:13:49,020 --> 00:13:49,880
+الـ EDTA
+
+167
+00:13:52,880 --> 00:13:57,680
+عند basic pH، هذه الـ H بتروح، بتصير الـ N فيها شحنة سالبة،
+
+168
+00:13:57,680 --> 00:14:01,240
+بتصير pair of electrons. وهذه الـ H كمان بتروح،
+
+169
+00:14:01,240 --> 00:14:04,600
+وهذه الـ H بتروح، بتصيرها سالبة، وهذه الـ H بتروح،
+
+170
+00:14:04,600 --> 00:1
+
+223
+00:19:06,320 --> 00:19:12,060
+رئيسي على الـ pH فإحنا لما نيجي نتكلم عن الـ Y4-
+
+224
+00:19:12,060 --> 00:19:16,830
+ونقول هي المهمة، بقول أنا عندي الـ Y4- يمكن الحصول
+
+225
+00:19:16,830 --> 00:19:21,090
+عليها، جداش عندي Y4-؟ أنا حطيت EDTA، لكن جداش عندي
+
+226
+00:19:21,090 --> 00:19:26,590
+Y4-؟ قال والله بقدر أحسبها، حسب الـ pH، الـ α4
+
+227
+00:19:26,590 --> 00:19:31,460
+بتساوي الـ Y4- على الـ CT، من وين جيبنا هذا الكلام؟ من
+
+228
+00:19:31,460 --> 00:19:34,880
+الـ fraction، جيبنا الـ fractions من الـ acid
+
+229
+00:19:34,880 --> 00:19:38,040
+fractions at different pH values، اشتقنا علاقة
+
+230
+00:19:38,040 --> 00:19:41,620
+باستخدام الفوسفوريك أسد، وشوفنا الفوسفوريك أسد اللي
+
+231
+00:19:41,620 --> 00:19:46,220
+هو Alpha 0 اللي ما تفككش، H3PO4 يعني Zero، Zero يعني
+
+232
+00:19:46,220 --> 00:19:51,160
+Zero تفكك، ما فيش عندنا أي شحنة، Alpha 1 H2PO4 سالب
+
+233
+00:19:51,160 --> 00:19:56,590
+كان شحنة واحدة، Alpha 2، Alpha 3، هذا نفس الكلام، بقول
+
+234
+00:19:56,590 --> 00:20:02,170
+أنا عندي، لو اعتبرنا أن التركيز الكلي لـ EDTA هو
+
+235
+00:20:02,170 --> 00:20:07,110
+عبارة عن الـ H4Y اللي ضايل زي ما هي، الـ H3Y سالب، الـ
+
+236
+00:20:07,110 --> 00:20:11,490
+H2Y2 سالب، الـ HY3 سالب، الـ Y4 سالب، هذا التركيز الكلي
+
+237
+00:20:11,490 --> 00:20:16,770
+لـ EDTA، لكن جداش موجود منه على هيئة Y4 سالب؟ Alpha 4
+
+238
+00:20:16,770 --> 00:20:23,220
+منه، ألفا فور من الـ CT، ألفا فور ليه؟ لأنه فقط جزء
+
+239
+00:20:23,220 --> 00:20:28,300
+موجود على هيئة Y4 سالب، طيب والباقي كله موجود على
+
+240
+00:20:28,300 --> 00:20:32,260
+هيئة أشكال أخرى، ممكن يكون هذه الأشكال، لكن مجموع
+
+241
+00:20:32,260 --> 00:20:36,970
+هذه الأشكال كلها هي التركيز الكلي للـ EDTA، طب كيف بده
+
+242
+00:20:36,970 --> 00:20:41,310
+أجيب الـ α4؟ جالس، كارب نتذكر هذه H4Y يعني
+
+243
+00:20:41,310 --> 00:20:46,750
+أربعة protons، فببدأ بالمقام H plus أس أربعة، K a1 H
+
+244
+00:20:46,750 --> 00:20:51,930
+plus أس تلاتة، K a1 K a2 H plus اتنين، K a1 K a2 K
+
+245
+00:20:51,930 --> 00:20:58,330
+a3 H plus، K a1 K a3 K a2 K a3 K a4، كويس؟ أنا بدي
+
+246
+00:20:58,330 --> 00:21:03,960
+الـ Y4-، إيش بدي أحط في البسط؟ يحتاج الـ Y4-، يحتاج الـ
+
+247
+00:21:03,960 --> 00:21:07,400
+Y4-، ليس فيها أي بروتون، يعني هي على طول KA1, KA2,
+
+248
+00:21:07,480 --> 00:21:11,240
+KA3, KA4، أو أنه قول والله هذه التباعة الـ α0, α1,
+
+249
+00:21:11,400 --> 00:21:16,620
+α2, α3، هي الـ α4، إذا الـ BUS بدي يكون KA1, KA2,
+
+250
+00:21:16,760 --> 00:21:20,820
+KA3, KA4، لحظن الحظ أن إحنا في الامتحان بنجيب الـ
+
+251
+00:21:20,820 --> 00:21:26,020
+cash، تحسبها، لإنه يعني بدها شوية وقت عند الطالب
+
+252
+00:21:26,020 --> 00:21:28,920
+اللي ما عندهوش خبرة، لكن طبعاً اللي عنده خبرة بتطلع
+
+253
+00:21:28,920 --> 00:21:32,500
+على الأرقام، وممكن يعني بثواني يحلها بمجرد النظر
+
+254
+00:21:33,470 --> 00:21:38,090
+ليه؟ لأنه مرات بيكون مثلاً عندك عشرة أس سالب عشرين
+
+255
+00:21:38,090 --> 00:21:41,210
+وعشرة أس سالب سبعة جنبها، وعشرة أس سالب ثمانية
+
+256
+00:21:41,210 --> 00:21:44,070
+خلاص، برمي الـ term اللي بيقول عشرة أس سالب عشرين
+
+257
+00:21:44,070 --> 00:21:48,870
+بمجرد النظر، بـ skimming يعني، باطلع يعني بس مجرد
+
+258
+00:21:48,870 --> 00:21:52,210
+النظر، باطلع أعرف بعض الـ terms قليلة جداً، بلغيها
+
+259
+00:21:52,790 --> 00:21:56,190
+فبالتالي الحسابات سهلة، ومع ذلك إحنا ما بنوش نكلفك
+
+260
+00:21:56,190 --> 00:22:01,630
+عناء الحسابات، هنعطيك قيمة الـ α4، بدك تتذكر أن الـ
+
+261
+00:22:01,630 --> 00:22:07,290
+α4، لو طلعت على هذه المعادلة، الـ α4 فقط تتوقف على
+
+262
+00:22:07,290 --> 00:22:10,730
+الـ pH، لأن هي constants، هذه ثوابت، ما لهاش ده
+
+263
+00:22:10,730 --> 00:22:13,070
+عرف حاجة، تتوقف على الحرارة يعني، الحرارة ثابتة هي
+
+264
+00:22:13,070 --> 00:22:17,390
+ثابتة، لكن فقط الـ H plus هي اللي موجودة في
+
+265
+00:22:17,390 --> 00:22:25,170
+المعادلة، إذا أنت تتوقف على الـ H plus، هي الـ pH
+
+266
+00:22:25,170 --> 00:22:31,610
+يعني الـ α4 تتوقف بس على الـ pH، عند 0 كانت الـ
+
+267
+00:22:31,610 --> 00:22:36,230
+α4 عشرة أس سالب 23، عند 1 كانت عشرة أس سالب 18،
+
+268
+00:22:36,230 --> 00:22:40,660
+0 و 1 يعني محلول very acidic، 0 و 1 يعني محلول إيش
+
+269
+00:22:40,660 --> 00:22:45,960
+ماله؟ very acidic أو كتير من الـ Y4 minus اتحول الـ
+
+270
+00:22:45,960 --> 00:22:52,880
+H4 و الـ H3 و الـ H2 و الـ HY، جزء قليل ضايل هيئة Y4
+
+271
+00:22:52,880 --> 00:22:58,500
+سالب، لأن الـ protons إيش مالها؟ كتيرة، يعني pH منخفضة
+
+272
+00:22:58,500 --> 00:23:04,100
+لكن لما تصير مثلاً الـ pH خمسة، بنلاحظ أن الـ Y4 سالب
+
+273
+00:23:04,100 --> 00:23:10,340
+عشرة أس سالب سبعة، طب لما الـ pH صارت عشرة، الـ Y4
+
+274
+00:23:10,340 --> 00:23:16,240
+سالب 36%، زادت كده، طب لما الـ PH صارت 13، very basic،
+
+275
+00:23:16,240 --> 00:23:24,320
+صار معظم الـ Y عبارة عن Y4 سالب، تقريباً كل الـ EDTA
+
+276
+00:23:24,320 --> 00:23:32,080
+على هيئة Y4 سالب، عند الـ PH مثلاً 13، ففي يعني اعتماد
+
+277
+00:23:32,080 --> 00:23:38,900
+طبعاً مهم جداً ورئيسي للـ α4، الـ value تبعتي
+
+278
+00:23:38,900 --> 00:23:41,320
+على الـ pH
+
+279
+00:23:45,490 --> 00:23:48,870
+فإحنا بنقول إنه إذا إحنا عرفنا الـ α4، حسبناها من
+
+280
+00:23:48,870 --> 00:23:53,810
+هنا، والتركيز الكلي للـ EDTA معايا، إذا بقدر أعرف
+
+281
+00:23:53,810 --> 00:23:58,550
+جداش من الـ EDTA موجودة على هيئة Y4-، علشان لما بدي
+
+282
+00:23:58,550 --> 00:24:04,870
+أجي أقول الـ Kf بدها تساوي calcium Y مثلاً، يعني Y2-
+
+283
+00:24:04,870 --> 00:24:11,150
+على الـ calcium في الـ Y4-، لما ما بتعرفش أعوض عن الـ Y4-
+
+284
+00:24:11,150 --> 00:24:15,270
+هذه ما بعرفش كده إيش قيمتها، أنا إلا أني أعوض عنها
+
+285
+00:24:15,270 --> 00:24:19,710
+بقيمتها
+
+286
+00:24:19,710 --> 00:24:25,170
+على هيئة Alpha 4 CT
+
+287
+00:24:26,180 --> 00:24:31,000
+الـ CT معايا، والـ Y4 بحسبها، بقدر أجيب الـ Y4- اللازمة
+
+288
+00:24:31,000 --> 00:24:36,760
+لحل المعادلة، لأن كيف بده أجيب الـ Kf expression
+
+289
+00:24:36,760 --> 00:24:40,640
+من هنا، بده أقول والله الـ calcium Y2- بقدر أعرفها
+
+290
+00:24:40,640 --> 00:24:44,760
+الـ calcium بقدر أعرفه، لكن الـ Y4- تتوقف على الـ pH
+
+291
+00:24:45,990 --> 00:24:51,230
+بحسب الـ pH لإيه؟ لأنها بتساوي α4 CT، هي الـ Y4
+
+292
+00:24:51,230 --> 00:24:54,430
+minus، فالـ α4 بقدر أحسبها، والـ CT total
+
+293
+00:24:54,430 --> 00:24:57,750
+concentration، ده الـ EDTA، عادة بقدر أحسبه، أو بيكون
+
+294
+00:24:57,750 --> 00:25:01,110
+معايا، فبالتالي بقدر أعرف الـ Y4 minus اللي أنا
+
+295
+00:25:01,110 --> 00:25:05,230
+هستخدمها في الـ Kf expression
+
+296
+00:25:10,380 --> 00:25:14,800
+قلنا يا شباب إنه هذا بنسميه Formation Constant
+
+297
+00:25:14,800 --> 00:25:19,180
+Formation Constant بالنسبة للكالسيوم والمغنيسيوم
+
+298
+00:25:19,180 --> 00:25:22,820
+الـ Formation Constant يعتبر صغير نسبياً، صغير يعني
+
+299
+00:25:22,820 --> 00:25:26,820
+جداش يعني المغنيسيوم مثلاً عشرة أس سالب اثنين في
+
+300
+00:25:26,820 --> 00:25:30,060
+عشرة أس سالب ثمانية، عشرة أس سالب ثمانية، صغير بنقول
+
+301
+00:25:30,060 --> 00:25:35,640
+آه بالنسبة لإيه؟ صغير بالنسبة لبقية الـ chelates، بقية
+
+302
+00:25:35,640 --> 00:25:40,400
+العناصر، صحيح، طب و الكالسيوم؟ قال كالسيوم خمسة في
+
+303
+00:25:40,400 --> 00:25:43,700
+عشرة أس عشرة، الصغير خمسة في عشرة أس عشرة، بنقول
+
+304
+00:25:43,700 --> 00:25:47,060
+آه بالنسبة لبقية العناصر، وهذا له إعكاسات مهمة
+
+305
+00:25:47,060 --> 00:25:51,220
+جداً، هذا له إعكاسات مهمة جداً، بالذات لما نتكلم،
+
+306
+00:25:51,220 --> 00:25:54,080
+إذا الله راضي، الحصة اللي جاية عن الـ indicators،
+
+307
+00:25:54,080 --> 00:25:57,100
+هذا إعكاساته كتير كتير كتير مهمة، بالذات الـ
+
+308
+00:25:57,100 --> 00:26:03,510
+magnesium، لما نتكلم عن الـ indicators، بنقول يا شباب
+
+309
+00:26:03,510 --> 00:26:07,110
+أن الـ formation constant، طبعاً لازم تكتب المعادلة
+
+310
+00:26:07,110 --> 00:26:14,050
+هي Formation، هي عبارة عن الـ EDTA metal ion complex
+
+311
+00:26:14,050 --> 00:26:18,690
+أو كلية على هذا، بالنسبالي كالسيوم في الـ Y4 minus
+
+312
+00:26:18,690 --> 00:26:22,610
+لكن الـ Y4 minus زي ما قلت بتساوي α4 CT، ولازم
+
+313
+00:26:22,610 --> 00:26:29,450
+نعرف قيمة الـ α4 علشان نقدر نحسب يعني المجهول
+
+314
+00:26:32,510 --> 00:26:38,490
+للمعلومات، بقول نجي نتطلع على العناصر المختلفة و
+
+315
+00:26:38,490 --> 00:26:43,170
+نشوف قداش قيمة الـ formation constant، وبرضه هذا
+
+316
+00:26:43,170 --> 00:26:48,290
+كلام مهم، هفرجيكم ليش بعد شوية، السلفر عشرة أس سبعة
+
+317
+00:26:48,290 --> 00:26:52,850
+المغنيسيوم عشرة أس ثمانية، الكالسيوم عشرة أس عشرة
+
+318
+00:26:52,850 --> 00:26:56,210
+السترونشيوم عشرة أس ثمانية، الباريوم عشرة أس سبعة
+
+319
+00:26:56,210 --> 00:26:59,030
+لاحظ أن المجموعة الثانية، المجموعة الأولى ما
+
+320
+00:26:59,030 --> 00:27:03,470
+بنذكرهاش لأنها قليلة كتير، صوديوم، بوتاسيوم، ليثيوم
+
+321
+00:27:03,470 --> 00:27:07,430
+قليلة فبنحكيش عنها، يعني المجموعة الثانية وفوق
+
+322
+00:27:07,430 --> 00:27:12,310
+المجموعة الثانية عشرة أس سبعة، عشرة أس عشرة، مش
+
+323
+00:27:12,310 --> 00:27:18,050
+كتير كبيرة، لكن نجي نروح للـ transition metals، كويس؟
+
+324
+00:27:18,050 --> 00:27:23,190
+فنقول مانجانيز عشرة أس 13، الحديد عشرة أس 14، يعني لما
+
+325
+00:27:23,190 --> 00:27:29,170
+نجي نقارن عشرة أس 14 مثلاً بعشرة أس 7، هي عشرة مليون مرة
+
+326
+00:27:29,170 --> 00:27:34,810
+عشرة مليون، مش بضعف، عشرة مليون مرة أكبر منها، عشرة أس 14
+
+327
+00:27:34,810 --> 00:27:39,590
+أكبر بعشرة مليون مرة من عشرة أس 7، بمليون مرة أكبر من
+
+328
+00:27:39,590 --> 00:27:45,200
+عشرة أس 8، طيب الكوبلت عشرة أس 16، النيكل عشرة أس 18
+
+329
+00:27:45,200 --> 00:27:50,700
+الكبر عشرة أس 18، الزنك، الكادميوم، الميركوري عشرة أس
+
+330
+00:27:50,700 --> 00:27:58,460
+21، الميركوري عشرة أس 21، الرصاص 18، الألومنيوم 16، الـ
+
+331
+00:27:58,460 --> 00:28:03,520
+حديد والفانديوم عشرة أس 25، يعني حاجة مهولة، حاجة
+
+332
+00:28:03,520 --> 00:28:07,260
+كبيرة خالص، حاجة يعني بتعطيني very very very highly
+
+333
+00:28:07,260 --> 00:28:12,130
+stable complex، يعني هذا الـ slide بس بتقولنا أنه في
+
+334
+00:28:12,130 --> 00:28:18,270
+تفاوت كبير في الـ formation constants للكلات
+
+335
+00:28:18,270 --> 00:28:22,250
+المختلفة، أو الـ complexes المختلفة لـ الـ metal ions
+
+336
+00:28:22,250 --> 00:28:31,110
+مع الـ EDTA، طيب إيش انعكاس هذا الكلام؟ تعالوا نعمل
+
+337
+00:28:31,110 --> 00:28:42,980
+plot ما بين الـ pH مع log الكيف للكلات المختلفة
+
+338
+00:28:42,980 --> 00:28:48,000
+للكمبلكس المختلفة، يعني الـ EDTA مع metal ion، complex
+
+339
+00:28:48,000 --> 00:28:53,400
+بنلاحظ أنه المغنيسيوم تحديداً، يعني المغنيسيوم
+
+340
+00:28:53,400 --> 00:28:57,020
+والكالسيوم، الكيف اللي هم إيه؟ شمال بالنسبة لغيرهم
+
+341
+00:28:58,060 --> 00:29:03,320
+قليل كتير، يعني قليل كتير خالص، قليل كتير جداً،
+
+342
+00:29:03,320 --> 00:29:08,340
+بينما لو جينا هنا، ولاحظوا وين بتتم عملية
+
+343
+00:29:08,340 --> 00:29:13,540
+معايرتهم، at high pH، أنت لما استخدمت معايرة
+
+344
+00:29:13,540 --> 00:29:16,600
+الكالسيوم والمغنيسيوم واشتغلت عند pH عشرة، إذا كانك
+
+345
+00:29:16,600 --> 00:29:22,490
+ناسي، اشتغلت عند pH عشرة، طيب في مجموعة ثانية لاحظوا
+
+346
+00:29:22,490 --> 00:29:29,350
+الـ pH يعني متوسطة، من تقريباً تلاتة ونص لـ .. تقريباً
+
+347
+00:29:29,350 --> 00:29:35,190
+يعني لستة، هذه مجموعة ثانية، في مجموعة ثالثة يعني الـ
+
+348
+00:29:35,190 --> 00:29:39,910
+pH acidic، يعني تقريباً، لكن اتطلعوا على بال الـ Kf
+
+349
+00:29:39,910 --> 00:29:43,530
+إيش ماله؟ بيزيد، هذا logarithmic، مش بيه على طبيعة هذا
+
+350
+00:29:43,530 --> 00:29:48,850
+logarithmic، يعني هذه عشرة أس 22، عشرة أس 24، عشرة أس 26
+
+351
+00:29:48,850 --> 00:29:54,570
+عشرة أس 18، يعني الخط هذا logarithmic، لأن الـ log الـ
+
+352
+00:29:54,570 --> 00:29:58,810
+formation constant، طيب إيش بنستفيد من هذا الكلام؟
+
+353
+00:29:58,810 --> 00:30:04,690
+إيش بنستفيد؟ أول فايدة أنا بقدر أقولها إنه الـ EDTA
+
+354
+00:30:04,690 --> 00:30:08,800
+complex مع الكالسيوم والمغنيسيوم، وتحديداً مع
+
+355
+00:30:08,800 --> 00:30:14,560
+المغنيسيوم ضعيف، الـ complex ضعيف، عشان هيك لو
+
+356
+00:30:14,560 --> 00:30:18,620
+كان عندي مغنيسيوم وأيون مثل أيون آخر، وحطيت EDTA
+
+357
+00:30:18,620 --> 00:30:23,140
+عليهم، الـ EDTA رح يتفاعل مع الـ other metal ion و
+
+358
+00:30:23,140 --> 00:30:30,360
+يُسيب المغنيسيوم للآخر، طيب لو أنا حطيت مغنيسيوم EDTA
+
+359
+00:30:30,360 --> 00:30:34,360
+complex، أنا عندي الـ complex مغنيسيوم EDTA وحطيت
+
+360
+00:30:34,360 --> 00:30:38,320
+عليه أيون، إيش هيسوي؟ الأيون راح يطرد
+
+361
+00:30:38,320 --> 00:30:42,600
+المغنيسيوم، وياخد الـ EDTA منه، اتذكر هذه الملاحظة في
+
+362
+00:30:42,600 --> 00:30:46,080
+الحصة الجاية، تذكر هذه الملاحظة على الحصة التالية،
+
+363
+00:30:46,080 --> 00:30:49,240
+يفيدنا هذه، ماذا بتقول الرسم؟ بتقول في الـ EDTA بتتكلم
+
+364
+00:30:49,240 --> 00:30:52,680
+عن المغنيسيوم، بقول إنه لو كان في عندي مغنيسيوم
+
+365
+00:30:52,680 --> 00:30:55,920
+مثلاً، ونكالسيوم، أو مغنيسيوم وكوبلت، مغنيسيوم ورصاص،
+
+366
+00:30:55,920 --> 00:30:58,980
+مغنيسيوم ولوتينيوم، مغنيسيوم وميركوري، مغنيسيوم
+
+367
+00:30:58,980 --> 00:31:02,540
+وانديوم، مغنيسيوم وأي حاجة ثانية، لو حطيت الاثنين
+
+368
+00:31:02,540 --> 00:31:07,700
+مع بعض، وحطيت أي، حطيت EDTA، بدأت تعاير، بلاحظ إن الـ
+
+369
+00:31:07,700 --> 00:31:10,680
+EDTA بتتفاعل مع الـ other metal ion، مش مع المغنيسيوم
+
+370
+00:31:11,200 --> 00:31:13,980
+لما نخلص الـ other metal ion، بعدين بتتفاعل مع
+
+371
+00:31:13,980 --> 00:31:18,320
+المغنيسيوم، هذه أول ملاحظة، ملاحظة ثانية، لو أنا
+
+372
+00:31:18,320 --> 00:31:22,860
+كان عندي complex مغنيسيوم EDTA complex ورحت حطيت
+
+373
+00:31:22,860 --> 00:31:26,320
+على هذا الـ complex metal ion، بلاحظ أن الـ metal ion
+
+374
+00:31:26,320 --> 00:31:29,860
+بيطرد المغنيسيوم وبياخد الـ EDTA، ليه؟ لأن
+
+375
+00:31:29,860 --> 00:31:33,900
+الـ metal ion EDTA complex أقوى من المغنيسيوم EDTA
+
+376
+00:31:33,900 --> 00:31:38,240
+complex، خذوا بالكم من هذه الملاحظة، الحصة الجاية
+
+377
+00:31:38,240 --> 00:31:42,380
+حنحاول أنه نستفيد منها، نتكلم عن الـ indicators، لكن
+
+378
+00:31:42,380 --> 00:31:47,320
+الآن، نكمل في الشكل، برضه مش بنستفيد منه، بنستفيد في
+
+379
+00:31:47,320 --> 00:31:51,740
+واقعي، دي كتير مهمة، زي زي مثلاً لو عندي أنا Iron
+
+380
+00:31:51,740 --> 00:31:59,980
+وفي عندي مثلاً Zinc، الـ Iron لو جت طلعت عند pH أقل
+
+381
+00:31:59,980 --> 00:32:04,800
+من 2، يعني بتتفاعل مع الـ EDTA، يبقى لو عندي Zinc و
+
+382
+00:32:04,800 --> 00:32:09,720
+Iron، إذا كان أنا بعمل معايرة عند pH 2، الايرون بس
+
+383
+00:32:09,720 --> 00:32:14,970
+هو اللي بيتفاعل، لكن لو عملتها عند pH مثلاً 
+
+445
+00:38:03,200 --> 00:38:06,980
+والـ α4 هي دالة في الـ pH فقط
+
+446
+00:38:10,710 --> 00:38:14,610
+الـ conditional formation constant ثابت التكوين
+
+447
+00:38:14,610 --> 00:38:19,850
+المشروط، ليش مشروط أو بإيش مشروط؟ هو مشروط بالـ pH
+
+448
+00:38:19,850 --> 00:38:26,680
+مشروط بقيمة الـ pH، لكن احنا مش هنستخدم الـ
+
+449
+00:38:26,680 --> 00:38:30,140
+Conditional Equilibrium أو Formation Constant، احنا
+
+450
+00:38:30,140 --> 00:38:36,140
+دائماً هنحل باستخدام الـ Formation Constant العادي، و
+
+451
+00:38:36,140 --> 00:38:41,440
+هنقول: و هو بيساوي التركيز الكلي على الـ metal ion
+
+452
+00:38:41,440 --> 00:38:46,860
+في الـ alpha for، في الـ CT، فهنستخدم هذه المعادلة، مش
+
+453
+00:38:46,860 --> 00:38:50,520
+هنستخدم المعادلة التقليدية
+
+454
+00:38:52,380 --> 00:38:57,300
+طيب، خلّينا نتطلع الآن على حاجة بنقولها: Titration
+
+455
+00:38:57,300 --> 00:39:01,940
+Curse، آه
+
+456
+00:39:01,940 --> 00:39:06,360
+منحنيات المعايرة. احنا شوفنا في الـ acid base
+
+457
+00:39:06,360 --> 00:39:11,640
+titrations أن منحنيات المعايرة كانت متوقفة على
+
+458
+00:39:11,640 --> 00:39:16,140
+ثابت التفكك للـ acid أو الـ base. كل ما زاد ثابت
+
+459
+00:39:16,140 --> 00:39:20,780
+التفكك، كل ما كان الـ break اللي عندي sharper
+
+460
+00:39:20,780 --> 00:39:24,400
+break at the equivalence point، و أيضاً كان الحاجة
+
+461
+00:39:24,400 --> 00:39:29,260
+التانية، الـ concentrations لـ الـ acid و الـ base. فكل
+
+462
+00:39:29,260 --> 00:39:34,740
+ما زادت تركيز الـ acid و الـ base، كل ما زادت
+
+463
+00:39:34,740 --> 00:39:38,320
+تركيز المتفاعلات، كان برضه بيعطيني sharper
+
+464
+00:39:39,860 --> 00:39:44,460
+break at the equivalence point. فيما يتعلق بالـ
+
+465
+00:39:44,460 --> 00:39:49,780
+فيما يتعلق بالـ complexometric reactions أو
+
+466
+00:39:49,780 --> 00:39:54,540
+titrations، بنقول بنفس الصورة تماماً... نفس الصورة
+
+467
+00:39:54,540 --> 00:39:58,320
+تماماً
+
+468
+00:39:58,320 --> 00:40:03,640
+الـ break at the equivalence point بتكون sharper
+
+469
+00:40:05,050 --> 00:40:10,330
+وبتتوقف على ثلاث حاجات، مش حاجتين. أول حاجة الـ
+
+470
+00:40:10,330 --> 00:40:14,230
+formation constant. فبنقول: كل ما زاد الـ formation
+
+471
+00:40:14,230 --> 00:40:19,310
+constant للـ complex، طبعاً هذا ما أقدرش أتحكم فيه لما
+
+472
+00:40:19,310 --> 00:40:23,590
+يكون عندك مثلاً calcium EDTA أو magnesium EDTA أو
+
+473
+00:40:23,590 --> 00:40:28,010
+iron EDTA أو copper EDTA أو cobalt EDTA. هذا كل
+
+474
+00:40:28,010 --> 00:40:31,590
+واحد فيهم له formation constant، احنا ما بنتحكم فيه
+
+475
+00:40:32,530 --> 00:40:35,730
+ما نتحكمش فيه، خلاص. الـ formation constant تبقى ثابتة،
+
+476
+00:40:35,730 --> 00:40:39,070
+لكن بنقول الملاحظة أنه لما يكون الـ formation
+
+477
+00:40:39,070 --> 00:40:44,070
+constant كبير، بتكون أيضاً الـ break كبيرة، يعني
+
+478
+00:40:44,070 --> 00:40:51,310
+هذه المسافة أطول، كويس؟ و sharper، sharp، كويس؟
+
+479
+00:40:51,310 --> 00:40:56,750
+لما يكون صغير، ببدأ يصير عندي شيء زي هيك، مال، مش
+
+480
+00:40:56,750 --> 00:41:04,160
+sharp. لما يكون الـ KF صغير، بيبدأ يحصل على شكل
+
+481
+00:41:04,160 --> 00:41:09,750
+سيجmoidال، زي الـ S. عامّة يبقى أول نقطة بقدر أقول بتأثر
+
+482
+00:41:09,750 --> 00:41:13,530
+على الـ titration curve، قيمة الـ KF أو ثابت الـ
+
+483
+00:41:13,530 --> 00:41:17,830
+complex. فكل ما زادت قيمة الـ KF، كل ما كانت الـ
+
+484
+00:41:17,830 --> 00:41:21,210
+break at the equivalence point sharper. هذه أول
+
+485
+00:41:21,210 --> 00:41:26,810
+نقطة. النقطة الثانية برضه كمان تأثير تركيز
+
+486
+00:41:26,810 --> 00:41:33,810
+المتفاعلات، بحيث أنه كل ما زاد تركيز المتفاعلات، كل
+
+487
+00:41:33,810 --> 00:41:40,970
+ما كان الـ break sharper. يبقى المتفاعلات بتكون الـ
+
+488
+00:41:40,970 --> 00:41:45,270
+break sharper إذا كان تركيز المتفاعلات كبير، بينما
+
+489
+00:41:45,270 --> 00:41:50,990
+كمان مرة، لو كان تركيز المتفاعلات قليل، أقل، بلاحظ
+
+490
+00:41:50,990 --> 00:41:54,970
+إنها ببدأ يصير عندي إيه؟ سيجmoidال، و هذا طبعاً
+
+491
+00:41:54,970 --> 00:41:58,710
+سيجmoidال هي ضرر كبير، لأنه بيأثر على قدرتي على
+
+492
+00:41:58,710 --> 00:42:02,860
+تعيين الـ end point. أنا بدي يكون sharp عشان نقطة
+
+493
+00:42:02,860 --> 00:42:07,020
+واحدة بس تعطيني التغير في لون الـ indicator أو
+
+494
+00:42:07,020 --> 00:42:10,040
+تعطيني الـ end point. لكن لما تكون sigmoidal
+
+495
+00:42:10,040 --> 00:42:16,220
+بتكون مشكلة، ما أقدرش أعين الـ equivalence point بشكل
+
+496
+00:42:16,220 --> 00:42:23,010
+دقيق. يبقى تركيز المتفاعلات، و هنا في ناس كتير
+
+497
+00:42:23,010 --> 00:42:27,210
+في الحقيقة بيقعوا في خطأ في أحيان كثيرة. احنا
+
+498
+00:42:27,210 --> 00:42:32,030
+بنحاول إنه نقدر كمية مثلاً metal ion في المية
+
+499
+00:42:32,030 --> 00:42:38,040
+بتركيزات منخفضة، و لأنه ما فيش عندنا زمان يعني، هاليوم
+
+500
+00:42:38,040 --> 00:42:41,880
+الحمد لله عندنا أجهزة كويسة كثيرة. أو بعض الناس اللي
+
+501
+00:42:41,880 --> 00:42:45,220
+ما فيش عندهم أجهزة، اليوم بيحاولوا يستخدموا الـ EDTA
+
+502
+00:42:45,220 --> 00:42:50,220
+titrations. بنقول إنه خطر كبير جداً إنه نيجي نعمل
+
+503
+00:42:50,220 --> 00:42:54,620
+معايرة، EDTA titration مثلاً بـ 10 أو 4 مولار EDTA
+
+504
+00:42:54,620 --> 00:43:00,000
+مع 10 أو 4 أو 5 مولار metal ion. صعب كتير تقدير الـ
+
+505
+00:43:00,000 --> 00:43:02,420
+end point أو تحديد الـ end point. بتكون يعني من
+
+506
+00:43:02,420 --> 00:43:07,820
+الصعوبة، لما يكون في خطأ جسيم في تقدير الـ... أو في
+
+507
+00:43:07,820 --> 00:43:12,700
+يعني تحديد الـ end point بدقة. علشان هيك بنقول إنه
+
+508
+00:43:12,700 --> 00:43:19,880
+تركيز المتفاعلات مهم جداً في قدرتنا على تحديد الـ
+
+509
+00:43:19,880 --> 00:43:22,520
+end point، و حصولنا على sharp break at the
+
+510
+00:43:22,520 --> 00:43:26,300
+equivalence point. بحيث إنه كل ما زادت التركيزات
+
+511
+00:43:27,080 --> 00:43:30,480
+EDTA و الـ metal ion، كل ما كانت هذه المنطقة sharper
+
+512
+00:43:30,480 --> 00:43:33,960
+العامل الثالث، زي ما هو قدامكم هنا، اللي هو الـ pH
+
+513
+00:43:33,960 --> 00:43:39,600
+بنلاحظ إنه كل ما زادت الـ... هذه نفس الـ... نفس الـ
+
+514
+00:43:39,600 --> 00:43:43,260
+titration، لكن هنا الـ titration معمولة عند pH 7
+
+515
+00:43:43,260 --> 00:43:47,780
+نفس الـ metal ion و نفس الـ EDTA، لكن هنا الـ pH 7، هي
+
+516
+00:43:47,780 --> 00:43:53,500
+المعمولة. لاحظوا الـ break جديش صغيرة، لكن لما الـ pH صارت
+
+517
+00:43:53,500 --> 00:43:58,740
+عشرة، إيش حصل في الـ break؟ آه، زادت. هذا بيعطيني يعني
+
+518
+00:43:58,740 --> 00:44:03,680
+برضه دقة أكبر في تحديد الـ end point. إذا الـ pH لما
+
+519
+00:44:03,680 --> 00:44:09,440
+بتزيد، برضه الـ break at the equivalence point بتزيد،
+
+520
+00:44:09,440 --> 00:44:13,860
+يبقى هذه العوامل اللي بتأثر على شكل الـ titration
+
+521
+00:44:13,860 --> 00:44:17,740
+curve. لازم آخد بالي: الـ KF كبير ولا مش كبير، هذا
+
+522
+00:44:17,740 --> 00:44:20,500
+ما أقدرش أتحكم فيه، لكن أقدر أتحكم في تركيز
+
+523
+00:44:20,500 --> 00:44:25,460
+المتفاعلات، أقدر أتحكم في الـ pH. طيب يا شباب، بنوقف هنا، و إن شاء الله الحصة الجاية بنكمل
+
diff --git a/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/4nyIYAzFnDE_raw.json b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/4nyIYAzFnDE_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..4f727ac0749d2b4c21bd1daebf21293537e8cb59
--- /dev/null
+++ b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/4nyIYAzFnDE_raw.json
@@ -0,0 +1 @@
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بده يكون عندنا h4y جدش h3y سالب جدش h2y2 سالب جدش h3y3 سالب جدش y4 سالب جدش بده يكون موجود من كل ال fraction قال والله الكل ينتبه قال هذا حسب ال pH إذا كان أنا ضابط ال pH عند pH معينة إذا", "tokens": [5172, 3224, 1829, 39894, 2655, 7435, 11622, 10721, 23032, 3555, 29538, 16247, 7435, 11622, 16606, 13672, 1829, 8032, 7435, 3215, 8592, 47525, 3224, 7251, 30544, 43242, 8315, 276, 19, 88, 10874, 3215, 8592, 276, 18, 88, 8608, 6027, 3555, 10874, 3215, 8592, 276, 17, 88, 17, 8608, 6027, 3555, 10874, 3215, 8592, 276, 18, 88, 18, 8608, 6027, 3555, 10874, 3215, 8592, 288, 19, 8608, 6027, 3555, 10874, 3215, 8592, 47525, 3224, 7251, 30544, 3714, 29245, 23328, 9154, 28242, 2423, 14135, 50239, 16070, 43761, 2423, 28820, 7251, 29399, 3555, 3224, 50239, 23758, 11331, 35457, 2423, 21677, 11933, 15730, 25961, 41850, 48812, 16758, 9566, 2423, 21677, 43242, 21677, 20449, 9957, 3660, 11933, 15730], "avg_logprob": -0.24599004002798974, "compression_ratio": 1.7990196078431373, "no_speech_prob": 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يعني بتفعل مع ال EDTA يبقى لو أندي زينكو ايرون اذا كان انا بعمل معايرة عند pH 2 الايرون بس هو اللي بتفعل لكن لو عملتها عند pH مثلا 4", "tokens": [6027, 39184, 13720, 45164, 10874, 2655, 23032, 1211, 34268, 43242, 21677, 5551, 4587, 1211, 9154, 568, 37495, 22653, 39894, 5172, 30241, 20449, 2423, 18050, 8241, 7251, 3555, 4587, 7578, 45164, 14739, 16254, 30767, 9957, 4117, 2407, 1975, 13546, 11536, 1975, 15730, 25961, 1975, 8315, 4724, 25957, 1211, 20449, 995, 48923, 43242, 21677, 568, 42963, 13546, 11536, 4724, 3794, 31439, 13672, 1829, 39894, 5172, 30241, 44381, 45164, 6225, 42213, 2655, 11296, 43242, 21677, 50113, 15040, 1017], "avg_logprob": -0.24671052631578946, "compression_ratio": 1.6374269005847952, "no_speech_prob": 2.980232238769531e-07, "words": [{"start": 1916.58, "end": 1917.0, "word": "الـ", "probability": 0.4366455078125}, {"start": 1917.0, "end": 1917.26, "word": " Iron", "probability": 0.45556640625}, {"start": 1917.26, "end": 1917.8, "word": " لو", "probability": 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"probability": 0.68408203125}, {"start": 2223.03, "end": 2224.45, "word": " pH", "probability": 0.435546875}, {"start": 2224.45, "end": 2225.53, "word": " معينة", "probability": 0.9541015625}, {"start": 2225.53, "end": 2226.11, "word": " فهذا", "probability": 0.8575846354166666}, {"start": 2226.11, "end": 2226.67, "word": " الثابت", "probability": 0.9488525390625}, {"start": 2226.67, "end": 2226.91, "word": " مع", "probability": 0.96533203125}, {"start": 2226.91, "end": 2227.19, "word": " هذا", "probability": 0.9677734375}, {"start": 2227.19, "end": 2227.83, "word": " الثابت", "probability": 0.9442138671875}, {"start": 2227.83, "end": 2228.27, "word": " يمكن", "probability": 0.57861328125}, {"start": 2228.27, "end": 2228.53, "word": " يصير", "probability": 0.9161783854166666}, {"start": 2228.53, "end": 2228.93, "word": " اسمه", "probability": 0.95458984375}, {"start": 2228.93, "end": 2229.33, "word": " KF'", "probability": 0.6134033203125}, {"start": 2229.83, "end": 2230.61, "word": " الجانب", "probability": 0.6417236328125}, {"start": 2230.61, "end": 2230.75, "word": " دي", "probability": 0.55828857421875}, {"start": 2230.75, "end": 2231.03, "word": " يساوي", "probability": 0.77008056640625}, {"start": 2231.03, "end": 2231.59, "word": " calcium", "probability": 0.446044921875}, {"start": 2231.59, "end": 2232.25, "word": " Y2", "probability": 0.77685546875}, {"start": 2232.25, "end": 2232.83, "word": "-", "probability": 0.417724609375}, {"start": 2232.83, "end": 2233.57, "word": " على", "probability": 0.64794921875}, {"start": 2233.57, "end": 2233.95, "word": " ال", "probability": 0.5615234375}, {"start": 2233.95, "end": 2234.51, "word": " calcium", "probability": 0.8515625}, {"start": 2234.51, "end": 2235.99, "word": " في", "probability": 0.9130859375}, {"start": 2235.99, "end": 2236.29, "word": " ال", "probability": 0.875}, {"start": 2236.29, "end": 2236.61, "word": " CT", "probability": 0.6982421875}, {"start": 2236.61, "end": 2236.91, "word": " ال", "probability": 0.75146484375}, {"start": 2236.91, "end": 2237.33, "word": " CT", "probability": 0.93798828125}, {"start": 2237.33, "end": 2237.89, "word": " هو", "probability": 0.95361328125}, {"start": 2237.89, "end": 2238.31, "word": " عبارة", "probability": 0.962890625}, {"start": 2238.31, "end": 2238.83, "word": " عن", "probability": 0.998046875}, {"start": 2238.83, "end": 2239.75, "word": " ال", "probability": 0.8154296875}, {"start": 2239.75, "end": 2240.47, "word": " total", "probability": 0.83740234375}, {"start": 2240.47, "end": 2242.93, "word": " EDTA", "probability": 0.8671875}, {"start": 2242.93, "end": 2245.53, "word": " concentration", "probability": 0.85595703125}], "temperature": 1.0}, {"id": 101, "seek": 227333, "start": 2246.69, "end": 2273.33, "text": "ماشي طيب ال KF شحطة هادى ايش بنسميه جال بنسميه conditional equilibrium constant بنسميه conditional equilibrium constant ايش يعني conditional equilibrium constant او conditional formation constant ايش يعني conditional formation constant جال conditional formation constant بتعني", "tokens": [2304, 33599, 1829, 23032, 1829, 3555, 2423, 591, 37, 13412, 5016, 9566, 3660, 8032, 18513, 7578, 1975, 1829, 8592, 44945, 38251, 1829, 3224, 10874, 6027, 44945, 38251, 1829, 3224, 27708, 15625, 5754, 44945, 38251, 1829, 3224, 27708, 15625, 5754, 1975, 1829, 8592, 37495, 22653, 27708, 15625, 5754, 1975, 2407, 27708, 11723, 5754, 1975, 1829, 8592, 37495, 22653, 27708, 11723, 5754, 10874, 6027, 27708, 11723, 5754, 39894, 3615, 22653], "avg_logprob": -0.1756114061327948, "compression_ratio": 2.3680555555555554, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 2246.69, "end": 2247.25, "word": "ماشي", "probability": 0.6754557291666666}, {"start": 2247.25, "end": 2247.97, "word": " طيب", "probability": 0.7770182291666666}, {"start": 2247.97, "end": 2248.25, "word": " ال", "probability": 0.685546875}, {"start": 2248.25, "end": 2248.77, "word": " KF", "probability": 0.6650390625}, {"start": 2248.77, "end": 2249.37, "word": " شحطة", "probability": 0.7437744140625}, {"start": 2249.37, "end": 2249.81, "word": " هادى", "probability": 0.7434895833333334}, {"start": 2249.81, "end": 2250.39, "word": " ايش", "probability": 0.6908365885416666}, {"start": 2250.39, "end": 2251.45, "word": " بنسميه", "probability": 0.95263671875}, {"start": 2251.45, "end": 2251.95, "word": " جال", "probability": 0.6497802734375}, {"start": 2251.95, "end": 2253.05, "word": " بنسميه", "probability": 0.9005126953125}, {"start": 2253.05, "end": 2253.81, "word": " conditional", "probability": 0.86279296875}, {"start": 2253.81, "end": 2255.17, "word": " equilibrium", "probability": 0.97802734375}, {"start": 2255.17, "end": 2256.39, "word": " constant", "probability": 0.94775390625}, {"start": 2256.39, "end": 2257.13, "word": " بنسميه", "probability": 0.86578369140625}, {"start": 2257.13, "end": 2257.83, "word": " conditional", "probability": 0.92919921875}, {"start": 2257.83, "end": 2258.97, "word": " equilibrium", "probability": 0.9931640625}, {"start": 2258.97, "end": 2259.61, "word": " constant", "probability": 0.96240234375}, {"start": 2259.61, "end": 2260.21, "word": " ايش", "probability": 0.9285481770833334}, {"start": 2260.21, "end": 2260.47, "word": " يعني", "probability": 0.934814453125}, {"start": 2260.47, "end": 2261.15, "word": " conditional", "probability": 0.94775390625}, {"start": 2261.15, "end": 2261.79, "word": " equilibrium", "probability": 0.99365234375}, {"start": 2261.79, "end": 2262.37, "word": " constant", "probability": 0.92724609375}, {"start": 2262.37, "end": 2262.79, "word": " او", "probability": 0.95703125}, {"start": 2262.79, "end": 2263.27, "word": " conditional", "probability": 0.93701171875}, {"start": 2263.27, "end": 2264.09, "word": " formation", "probability": 0.9765625}, {"start": 2264.09, "end": 2265.15, "word": " constant", "probability": 0.97265625}, {"start": 2265.15, "end": 2265.99, "word": " ايش", "probability": 0.9513346354166666}, {"start": 2265.99, "end": 2266.23, "word": " يعني", "probability": 0.9638671875}, {"start": 2266.23, "end": 2267.01, "word": " conditional", "probability": 0.9599609375}, {"start": 2267.01, "end": 2267.97, "word": " formation", "probability": 0.98828125}, {"start": 2267.97, "end": 2268.73, "word": " constant", "probability": 0.97607421875}, {"start": 2268.73, "end": 2269.63, "word": " جال", "probability": 0.9033203125}, {"start": 2269.63, "end": 2270.83, "word": " conditional", "probability": 0.94287109375}, {"start": 2270.83, "end": 2271.47, "word": " formation", "probability": 0.97998046875}, {"start": 2271.47, "end": 2272.23, "word": " constant", "probability": 0.96923828125}, {"start": 2272.23, "end": 2273.33, "word": " بتعني", "probability": 0.9163411458333334}], "temperature": 1.0}, {"id": 102, "seek": 228698, "start": 2274.42, "end": 2286.98, "text": "ثابت التكوين المشروط بالـ pH لأن هو مضرب بالـ α4 والـ α4 هي دالة في الـ pH فقط", "tokens": [12984, 16758, 2655, 16712, 4117, 2407, 9957, 9673, 8592, 32887, 9566, 20666, 39184, 21677, 5296, 33456, 31439, 3714, 11242, 25513, 20666, 39184, 5691, 19, 16070, 39184, 5691, 19, 39896, 11778, 6027, 3660, 8978, 2423, 39184, 21677, 6156, 47432], "avg_logprob": -0.3283253312110901, "compression_ratio": 1.3434343434343434, "no_speech_prob": 1.2516975402832031e-05, "words": [{"start": 2274.42, "end": 2275.48, "word": "ثابت", "probability": 0.6988932291666666}, {"start": 2275.48, "end": 2276.54, "word": " التكوين", "probability": 0.94580078125}, {"start": 2276.54, "end": 2277.62, "word": " المشروط", "probability": 0.9287109375}, {"start": 2277.62, "end": 2280.22, "word": " بالـ", "probability": 0.51220703125}, {"start": 2280.22, "end": 2280.66, "word": " pH", "probability": 0.513671875}, {"start": 2280.66, "end": 2281.82, "word": " لأن", "probability": 0.631103515625}, {"start": 2281.82, "end": 2281.98, "word": " هو", "probability": 0.238037109375}, {"start": 2281.98, "end": 2282.36, "word": " مضرب", "probability": 0.6949055989583334}, {"start": 2282.36, "end": 2282.58, "word": " بالـ", "probability": 0.737548828125}, {"start": 2282.58, "end": 2283.2, "word": " α4", "probability": 0.5657958984375}, {"start": 2283.2, "end": 2283.9, "word": " والـ", "probability": 0.7490234375}, {"start": 2283.9, "end": 2284.44, "word": " α4", "probability": 0.9443359375}, {"start": 2284.44, "end": 2284.66, "word": " هي", "probability": 0.7412109375}, {"start": 2284.66, "end": 2285.02, "word": " دالة", "probability": 0.9480794270833334}, {"start": 2285.02, "end": 2285.12, "word": " في", "probability": 0.78271484375}, {"start": 2285.12, "end": 2285.3, "word": " الـ", "probability": 0.808349609375}, {"start": 2285.3, "end": 2286.46, "word": " pH", "probability": 0.90625}, {"start": 2286.46, "end": 2286.98, "word": " فقط", "probability": 0.9873046875}], "temperature": 1.0}, {"id": 103, "seek": 230546, "start": 2290.71, "end": 2305.47, "text": "الـ conditional formation constant ثابت التكوين المشروط ليش مشروط أو بإيش مشروط جال مشروط بال pH مشروط بقيمة ال pH لكن احنا مش هنستخدم", "tokens": [6027, 39184, 27708, 11723, 5754, 38637, 16758, 2655, 16712, 4117, 2407, 9957, 9673, 8592, 32887, 9566, 32239, 8592, 37893, 32887, 9566, 34051, 4724, 28814, 1829, 8592, 37893, 32887, 9566, 10874, 6027, 37893, 32887, 9566, 20666, 21677, 37893, 32887, 9566, 4724, 4587, 32640, 3660, 2423, 21677, 44381, 1975, 5016, 8315, 37893, 8032, 1863, 14851, 9778, 40448], "avg_logprob": -0.22307477625352995, "compression_ratio": 1.5434782608695652, "no_speech_prob": 1.6093254089355469e-06, "words": [{"start": 2290.71, "end": 2291.21, "word": "الـ", "probability": 0.4302978515625}, {"start": 2291.21, "end": 2291.53, "word": " conditional", "probability": 0.35205078125}, {"start": 2291.53, "end": 2292.23, "word": " formation", "probability": 0.90380859375}, {"start": 2292.23, "end": 2292.85, "word": " constant", "probability": 0.91650390625}, {"start": 2292.85, "end": 2293.59, "word": " ثابت", "probability": 0.8889973958333334}, {"start": 2293.59, "end": 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2301.95, "word": " بقيمة", "probability": 0.98388671875}, {"start": 2301.95, "end": 2302.19, "word": " ال", "probability": 0.9375}, {"start": 2302.19, "end": 2303.09, "word": " pH", "probability": 0.72119140625}, {"start": 2303.09, "end": 2304.09, "word": " لكن", "probability": 0.724609375}, {"start": 2304.09, "end": 2304.47, "word": " احنا", "probability": 0.89306640625}, {"start": 2304.47, "end": 2304.67, "word": " مش", "probability": 0.98974609375}, {"start": 2304.67, "end": 2305.47, "word": " هنستخدم", "probability": 0.98818359375}], "temperature": 1.0}, {"id": 104, "seek": 233052, "start": 2306.0, "end": 2330.52, "text": "الـ Conditional Equilibrium او Formation Constant احنا دائما هنحل باستخدام ال Formation Constant العادى و هنقول و الله بيساوي تركيز الكلية على ال metal ion في ال alpha for في ال CT فهنستخدم هذه المعادلة مش هنستخدم المعادلة التحترية", "tokens": [6027, 39184, 21793, 2628, 15624, 12722, 13015, 1975, 2407, 10126, 399, 37413, 1975, 5016, 8315, 11778, 16373, 15042, 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"probability": 0.930419921875}, {"start": 2309.04, "end": 2309.5, "word": " Constant", "probability": 0.70849609375}, {"start": 2309.5, "end": 2310.14, "word": " احنا", "probability": 0.747314453125}, {"start": 2310.14, "end": 2310.58, "word": " دائما", "probability": 0.9417317708333334}, {"start": 2310.58, "end": 2311.28, "word": " هنحل", "probability": 0.901123046875}, {"start": 2311.28, "end": 2312.1, "word": " باستخدام", "probability": 0.9811197916666666}, {"start": 2312.1, "end": 2313.8, "word": " ال", "probability": 0.61279296875}, {"start": 2313.8, "end": 2314.7, "word": " Formation", "probability": 0.93896484375}, {"start": 2314.7, "end": 2315.14, "word": " Constant", "probability": 0.88037109375}, {"start": 2315.14, "end": 2315.8, "word": " العادى", "probability": 0.8409830729166666}, {"start": 2315.8, "end": 2316.14, "word": " و", "probability": 0.91162109375}, {"start": 2316.14, "end": 2316.46, "word": " هنقول", "probability": 0.8802083333333334}, {"start": 2316.46, "end": 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التغير في لون ال indicator أو تعطيني ال end point لكن لما تكون ال sigmoidal بتكون مشكلة بقدرش أعين ال equivalence point بشكل دقيق يبقى تركيز", "tokens": [3615, 8592, 7649, 8717, 47432, 3660, 36764, 24401, 3660, 4724, 3794, 6055, 3615, 9566, 9957, 1829, 16712, 17082, 13546, 8978, 5296, 11536, 2423, 16961, 34051, 6055, 3615, 9566, 9957, 1829, 2423, 917, 935, 44381, 5296, 15042, 6055, 30544, 2423, 4556, 3280, 22151, 39894, 30544, 37893, 28820, 3660, 4724, 28543, 2288, 8592, 5551, 3615, 9957, 2423, 9052, 655, 935, 4724, 8592, 28820, 11778, 38436, 4587, 7251, 3555, 4587, 7578, 6055, 31747, 1829, 11622], "avg_logprob": -0.1781892123287671, "compression_ratio": 1.5116279069767442, "no_speech_prob": 3.5762786865234375e-07, "words": [{"start": 2522.12, "end": 2522.56, "word": "عشان", "probability": 0.87841796875}, {"start": 2522.56, "end": 2522.86, "word": " نقطة", "probability": 0.93310546875}, {"start": 2522.86, "end": 2523.18, "word": " واحدة", "probability": 0.9825846354166666}, {"start": 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2655, 5016, 24793, 8978, 3224, 12399, 44381, 3714, 28543, 2288, 5551, 2655, 5016, 24793, 8978, 6055, 31747, 1829, 11622, 9673, 2655, 5172, 995, 30241, 9307, 12399, 3714, 28543, 2288, 5551, 2655, 5016, 24793, 8978, 2423, 16530, 23032, 1829, 3555, 35186, 13412, 3555, 16758, 44945, 2407, 7435, 5551, 5172, 3224, 7649, 4032, 28814, 15730, 21984, 12602, 26108, 21542, 9381, 3660, 13672, 1829, 10874, 995, 10632, 44945, 24793, 1211], "avg_logprob": -0.15716911714617945, "compression_ratio": 1.7339055793991416, "no_speech_prob": 0.000415802001953125, "words": [{"start": 2648.7200000000003, "end": 2649.44, "word": "بتزيد،", "probability": 0.78505859375}, {"start": 2649.44, "end": 2649.68, "word": " يبقى", "probability": 0.6776123046875}, {"start": 2649.68, "end": 2649.92, "word": " هذه", "probability": 0.81689453125}, {"start": 2649.92, "end": 2650.44, "word": " العوامل", "probability": 0.893310546875}, {"start": 2650.44, "end": 2650.54, "word": " اللي", "probability": 0.8125}, {"start": 2650.54, "end": 2651.0, "word": " بتأثر", "probability": 0.93994140625}, {"start": 2651.0, "end": 2651.36, "word": " على", "probability": 0.865234375}, {"start": 2651.36, "end": 2652.84, "word": " شكل", "probability": 0.986083984375}, {"start": 2652.84, "end": 2653.2, "word": " ال", "probability": 0.92138671875}, {"start": 2653.2, "end": 2653.86, "word": " titration", "probability": 0.742431640625}, {"start": 2653.86, "end": 2654.28, "word": " curve", "probability": 0.98779296875}, {"start": 2654.28, "end": 2654.86, "word": " لازم", "probability": 0.9142252604166666}, {"start": 2654.86, "end": 2655.16, "word": " أخد", "probability": 0.7236328125}, {"start": 2655.16, "end": 2655.36, "word": " بال", "probability": 0.95849609375}, {"start": 2655.36, "end": 2655.5, "word": " ال", "probability": 0.55419921875}, {"start": 2655.5, "end": 2655.98, "word": " KF", "probability": 0.6337890625}, {"start": 2655.98, "end": 2656.64, "word": " كبير", "probability": 0.9873046875}, {"start": 2656.64, "end": 2656.88, "word": " ولا", "probability": 0.75732421875}, {"start": 2656.88, "end": 2657.08, "word": " مش", "probability": 0.9853515625}, {"start": 2657.08, "end": 2657.56, "word": " كبير،", "probability": 0.9053955078125}, {"start": 2657.56, "end": 2657.74, "word": " هذا", "probability": 0.9287109375}, {"start": 2657.74, "end": 2658.08, "word": " مقدرش", "probability": 0.7542724609375}, {"start": 2658.08, "end": 2658.44, "word": " أتحكم", "probability": 0.9398193359375}, {"start": 2658.44, "end": 2659.14, "word": " فيه،", "probability": 0.9070638020833334}, {"start": 2659.14, "end": 2659.38, "word": " لكن", "probability": 0.96435546875}, {"start": 2659.38, "end": 2659.66, "word": " مقدر", "probability": 0.9469401041666666}, {"start": 2659.66, "end": 2660.02, "word": " أتحكم", "probability": 0.938720703125}, {"start": 2660.02, "end": 2660.14, "word": " في", "probability": 0.89794921875}, {"start": 2660.14, "end": 2660.5, "word": " تركيز", "probability": 0.9896240234375}, {"start": 2660.5, "end": 2661.92, "word": " المتفاعلات،", "probability": 0.9330357142857143}, {"start": 2661.92, "end": 2662.22, "word": " مقدر", "probability": 0.9832356770833334}, {"start": 2662.22, "end": 2662.76, "word": " أتحكم", "probability": 0.9654541015625}, {"start": 2662.76, "end": 2663.14, "word": " في", "probability": 0.97119140625}, {"start": 2663.14, "end": 2663.24, "word": " ال", "probability": 0.97314453125}, {"start": 2663.24, "end": 2663.64, "word": " PH", "probability": 0.451171875}, {"start": 2663.64, "end": 2664.28, "word": " طيب", "probability": 0.8484700520833334}, {"start": 2664.28, "end": 2664.4, "word": " يا", "probability": 0.978515625}, {"start": 2664.4, "end": 2664.86, "word": " شباب", "probability": 0.9900716145833334}, {"start": 2664.86, "end": 2665.46, "word": " بنوج", "probability": 0.615966796875}, {"start": 2665.46, "end": 2665.98, "word": " أفهان", "probability": 0.9302978515625}, {"start": 2665.98, "end": 2666.36, "word": " وإذا", "probability": 0.7461751302083334}, {"start": 2666.36, "end": 2666.54, "word": " الله", "probability": 0.939453125}, {"start": 2666.54, "end": 2666.92, "word": " راج", "probability": 0.8076171875}, {"start": 2666.92, "end": 2667.7, "word": " الحصة", "probability": 0.9404296875}, {"start": 2667.7, "end": 2667.8, "word": " اللي", "probability": 0.875732421875}, {"start": 2667.8, "end": 2668.0, "word": " جاية", "probability": 0.8968098958333334}, {"start": 2668.0, "end": 2668.4, "word": " بنكمل", "probability": 0.9366861979166666}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2668.9945, "duration_after_vad": 2569.8331249999865}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/4nyIYAzFnDE_raw.srt b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/4nyIYAzFnDE_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..8bb0dc6d76c05794b09a147ea3c668a8ae449a51
--- /dev/null
+++ b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/4nyIYAzFnDE_raw.srt
@@ -0,0 +1,2096 @@
+1
+00:00:20,650 --> 00:00:24,350
+بسم الله الرحمن الرحيم اليوم إذا الله أراد بنكمل
+
+2
+00:00:24,350 --> 00:00:29,830
+شغلنا في ال complexometric reactions أو titrations
+
+3
+00:00:29,830 --> 00:00:34,650
+بنتكلم في البداية عن ال calculations اللي إحنا
+
+4
+00:00:34,650 --> 00:00:39,650
+بنجريها فيما يتعلق بال complexometric reactions
+
+5
+00:00:40,500 --> 00:00:43,920
+ونشوف طبيعة هذه ال calculations وكيف بتختلف عن ال
+
+6
+00:00:43,920 --> 00:00:48,360
+calculations اللي شفناها مثلا في ال acids و ال
+
+7
+00:00:48,360 --> 00:00:51,760
+bases بشكل أساسي بنقول
+
+8
+00:00:53,930 --> 00:00:58,570
+الاختلاف الجوهري يتوقف أو يعني يتعلق بقيمة ال
+
+9
+00:00:58,570 --> 00:01:02,390
+equilibrium constant في المحاضرات الماضية كان
+
+10
+00:01:02,390 --> 00:01:07,190
+دائما ال equilibrium constant صغير يعني عشر أقل
+
+11
+00:01:07,190 --> 00:01:11,570
+سالب كذا لكن في ال formation constant فيما يتعلق
+
+12
+00:01:11,570 --> 00:01:15,970
+بال complexometric reactions هنلاحظ أنه دائما ال
+
+13
+00:01:15,970 --> 00:01:20,280
+formation constantقيمة كبيرة لإلا أنه طبعا يعني
+
+14
+00:01:20,280 --> 00:01:26,480
+ثابت تكوين لابد إلا أنه يتكون الناتج بكميات محترمة
+
+15
+00:01:26,480 --> 00:01:31,760
+وهو يعني المتفاعلات يزيد منها كميات لكن كميات
+
+16
+00:01:31,760 --> 00:01:36,710
+إشمالهابسيطة فاحنا كنا نقشنا هذا الموضوع سابقا في
+
+17
+00:01:36,710 --> 00:01:41,310
+شباتر المقدمة وقلنا ان حل اي مثلة equilibrium
+
+18
+00:01:41,310 --> 00:01:44,990
+يتوقف على قيمة ال equilibrium constant اما ان يكون
+
+19
+00:01:44,990 --> 00:01:49,990
+كبير زي هذا الشبتر و هذا الشبتر فقط يا اما يكون مش
+
+20
+00:01:49,990 --> 00:01:53,730
+كبير زي الشباتر اللي مرت معنا سابقا و الشباتر اللي
+
+21
+00:01:53,730 --> 00:01:59,260
+بيتيجي كمان لاحقابس هاد ال chapter اللي بنعالج فيه
+
+22
+00:01:59,260 --> 00:02:02,700
+calculations في حالة ما انه ال equilibrium
+
+23
+00:02:02,700 --> 00:02:10,560
+constant يكون عندى كبيربنقول بشكل أساسي يعني نفس
+
+24
+00:02:10,560 --> 00:02:14,100
+الحسابات اللي شفناها سابقا لكن في الشبكات المقدمة
+
+25
+00:02:14,100 --> 00:02:18,640
+لكن كنا بنقول والله A بيتفاعل مع B بيعطينا AB وال
+
+26
+00:02:18,640 --> 00:02:23,040
+equilibrium constant عالي أو كبير هلجيت مداش نقول
+
+27
+00:02:23,040 --> 00:02:27,740
+A بتفاعل مع B بدنا نقول metal بتفاعل مع legendأو
+
+28
+00:02:27,740 --> 00:02:31,140
+المثل الفلاني بتفعل مع ال legend الفلاني عشان
+
+29
+00:02:31,140 --> 00:02:35,700
+يعطيني complex فهي لكن كحسابات نفس الكلام اللي
+
+30
+00:02:35,700 --> 00:02:39,380
+مارناه في شبهة المقدمة بس هنلاجيه على أبسط كمان
+
+31
+00:02:39,380 --> 00:02:45,590
+أبسطفمثلا نطلع على المثال اللي قدامي، المثال بتقول
+
+32
+00:02:45,590 --> 00:02:50,230
+a bivalent metal ion reacts with a ligand to form
+
+33
+00:02:50,230 --> 00:02:54,270
+a one to one complex جملة مفيدة كتير، عندي metal
+
+34
+00:02:54,270 --> 00:02:58,850
+ion و ligand و ال stoichiometry واحد لواحدمعادلة
+
+35
+00:02:58,850 --> 00:03:02,770
+سهلة جدا بيقول find the concentration of the metal
+
+36
+00:03:02,770 --> 00:03:07,770
+ion in a solution prepared by mixing equal volumes
+
+37
+00:03:07,770 --> 00:03:12,590
+of 0.2 molar metal ion and 0.2 molar ligand
+
+38
+00:03:12,590 --> 00:03:19,430
+وبيعطيني ال KF عشرة عقل ايه؟ عقل 8 عالي جدا عشرة
+
+39
+00:03:19,430 --> 00:03:25,850
+عقل 8 معناته المتفاعلاتهتتحول تقريبا كلها إلى
+
+40
+00:03:25,850 --> 00:03:32,390
+نواتج إلا كمية قليلة مقدارها X لأن ال formation
+
+41
+00:03:32,390 --> 00:03:40,010
+constant طبعا يعتبر large لو
+
+42
+00:03:40,010 --> 00:03:45,200
+أجينا للمسألة بنقول والله المعادلة metal ionو
+
+43
+00:03:45,200 --> 00:03:50,120
+legend بيعطيني مثل legend complex بدي بس تنتبه
+
+44
+00:03:50,120 --> 00:03:53,160
+شوية انه دائما مادام نشتغل او بيعطيني formation
+
+45
+00:03:53,160 --> 00:03:57,380
+constant يجب كتابة المعادلة على هيئة ايه؟
+
+46
+00:03:57,380 --> 00:04:00,900
+formation مش dissociation زي ما كنا بنشوف سابقا
+
+47
+00:04:00,900 --> 00:04:04,360
+زمان كنا بنقول dissociation لكن لأ هن ايه؟
+
+48
+00:04:04,360 --> 00:04:07,960
+formation هذه نقطة النقطة التانية اللي بحب الفة
+
+49
+00:04:07,960 --> 00:04:15,240
+انتباهكم اليها انه هنجلي equal volumesمن الـmetal
+
+50
+00:04:15,240 --> 00:04:19,520
+والـlegend تم خلطهم مع بعض أو أضافتهم لبعض لما
+
+51
+00:04:19,520 --> 00:04:24,100
+نضيف equal volumes من حاجتين معناته تركيزهم بده
+
+52
+00:04:24,100 --> 00:04:29,560
+ينزل للنص ليش بده ينزل للنص؟ لأنه الـmillimole من
+
+53
+00:04:29,560 --> 00:04:33,980
+الأول مثلا الـmetal ion الـmillimole millimole
+
+54
+00:04:33,980 --> 00:04:41,070
+metal ionبدو يساوي point two في ال volume فتجدش
+
+55
+00:04:41,070 --> 00:04:45,630
+تركيز ال metal ion النهائي جال point two في V هذه
+
+56
+00:04:45,630 --> 00:04:49,810
+ال millimoles على ال total volume اتضاعف ال volume
+
+57
+00:04:49,810 --> 00:04:54,490
+ليه؟ لأنه خلطت metal ion مع لجن نفس الكمية equal
+
+58
+00:04:54,490 --> 00:04:57,490
+volumes هاي ال volume مهما كان ال volume مع ال
+
+59
+00:04:57,490 --> 00:05:02,000
+volume إذا صار point one molarمعنى الكلام ايش حصل
+
+60
+00:05:02,000 --> 00:05:05,580
+لك تركيز بدل ما كان point two صار point one نفس
+
+61
+00:05:05,580 --> 00:05:10,680
+الكلام اللي جانت فلما نيجي نخلط two equal volumes
+
+62
+00:05:10,680 --> 00:05:14,640
+من حاجتين على طول الحاجتين هدول كيف تركيزهم بضيقين
+
+63
+00:05:14,640 --> 00:05:17,780
+للنص مباشرة فما تتضايقش في الامتحان اذا كان
+
+64
+00:05:17,780 --> 00:05:22,190
+ماعطكاش الحجمجالك equal volumes ليه؟ لأنه على طول
+
+65
+00:05:22,190 --> 00:05:25,670
+تبطلع التركيز لجديد مباشرة من حد يقولك equal
+
+66
+00:05:25,670 --> 00:05:29,610
+volumes معناته التركيز جال للنص وهذا هو السبب هي
+
+67
+00:05:29,610 --> 00:05:34,130
+ال minimum وهي ال total volume بما أنه ال volume
+
+68
+00:05:34,130 --> 00:05:41,170
+اتضاعف إذا التركيز بده ينزل للنص زي ما نحطاتنين
+
+69
+00:05:41,170 --> 00:05:45,930
+مولز في لتر solution هذا اتنين مولر طب لو حطينا
+
+70
+00:05:45,930 --> 00:05:49,910
+الاتنين مولز في اتنين لتر مش لتر بتقع النص طبعا
+
+71
+00:05:49,910 --> 00:05:53,510
+بيصير واحد مولر ماشي يا شباب فبس هذه النقطة برضه
+
+72
+00:05:53,510 --> 00:05:57,950
+اكويس انه ناخد بالنا منها الان هو جالس انه
+
+73
+00:05:57,950 --> 00:06:01,650
+باتفعلوا بالنسبة واحد لو واحد حلو كتير بنقول يا
+
+74
+00:06:01,650 --> 00:06:07,910
+شباب لما اتفعلوا بما ان ال KF كبير اذا اتحولوا
+
+75
+00:06:07,910 --> 00:06:14,370
+لنواتجالنواتج هذه عبارة عن point one molar من ال
+
+76
+00:06:14,370 --> 00:06:19,810
+ML اتنين plus او من ال complex يعني بمعنى اخر عندي
+
+77
+00:06:19,810 --> 00:06:28,590
+ال metal زائد ال legend خطوة metal legend خطوة ايه
+
+78
+00:06:28,590 --> 00:06:32,910
+شبه هذه الخطوة هذه الخطوة quantitative عندي هذا
+
+79
+00:06:32,910 --> 00:06:36,530
+point one و هذا point one هذا صفر هذا صار صفر هذا
+
+80
+00:06:36,530 --> 00:06:41,860
+صار point one مثلالكن عند ال equilibrium طبعا هذا
+
+81
+00:06:41,860 --> 00:06:45,980
+مش point one بالظبط لأ بده يجلب مقدار X فانا عندي
+
+82
+00:06:45,980 --> 00:06:52,260
+هنا point one minus X X X ال KF هتساوي point one
+
+83
+00:06:52,260 --> 00:06:56,680
+minus X على ال X تربية و طبعا بدي أعمل الفرضية
+
+84
+00:06:56,680 --> 00:07:02,520
+تبعتي ال point one أكبر كتير من ال X وبالتالي بطلع
+
+85
+00:07:02,520 --> 00:07:06,560
+قيمة ال X بتطلع 3 و 2 فعشرة أو سالب خمسةطب ال
+
+86
+00:07:06,560 --> 00:07:10,240
+relative error قليل جدا، إذا بالفعل ال point one
+
+87
+00:07:10,240 --> 00:07:14,380
+أكبر كتير من ال X، طب إيش هي؟ يبقى الفرضية صحيحة،
+
+88
+00:07:14,380 --> 00:07:17,260
+إيش هي ال X؟ قال هي تركيز ال metal ion اللي هو
+
+89
+00:07:17,260 --> 00:07:21,220
+بدوياه، إذا تركيز ال metal ion تلاتة و اتنين فعشرة
+
+90
+00:07:21,220 --> 00:07:25,420
+أساري بخمسة مولار، لكن شوف منطق الحل إنه
+
+91
+00:07:25,420 --> 00:07:30,620
+المتفاعلات تحولت لنواتج و طبعا مش بنسبة مية في
+
+92
+00:07:30,620 --> 00:07:34,920
+المية في الحقيقة، لأ، بس قليل مقدار و Xضايل على
+
+93
+00:07:34,920 --> 00:07:38,600
+هيئة متفاعلات ليش هذا الكلام؟ جال لأنه ال
+
+94
+00:07:38,600 --> 00:07:42,900
+formation constant كبير بمعنى أنه رايح ناحية
+
+95
+00:07:42,900 --> 00:07:47,540
+النواتج بشكل كبير التفاعل رايح ناحية النواتج بشكل
+
+96
+00:07:47,540 --> 00:07:52,680
+كبير معظم المتفاعلات تحولت إلى نواتج و تم كمية
+
+97
+00:07:52,680 --> 00:07:59,020
+مهمة لها مقدارها ايه؟ X وهذه X كمية قليلة للغاية
+
+98
+00:07:59,020 --> 00:08:06,530
+طيب كمان مثالبيقول في الـ silver ion forms a
+
+99
+00:08:06,530 --> 00:08:11,550
+stable one to one complex with the triene عند ال
+
+100
+00:08:11,550 --> 00:08:17,950
+silver ion بتفاعل مع legend اسمه triene كويس ال
+
+101
+00:08:17,950 --> 00:08:20,970
+stoichiometry واحد لواحد حلو كتير واحد لواحد يعني
+
+102
+00:08:20,970 --> 00:08:24,650
+مافيش عنده اي تعقيد لكن ايش بيقول بيقول calculate
+
+103
+00:08:24,650 --> 00:08:28,590
+the silver ion concentration at equilibrium when
+
+104
+00:08:28,590 --> 00:08:32,290
+خمسة و عشرين مل من point O one molar silver
+
+105
+00:08:32,290 --> 00:08:40,210
+nitrateis added to 50 ml of 0.015 molar ethylene
+
+106
+00:08:47,220 --> 00:08:51,360
+في زيادة من واحد منهم الاتنين بتفعل بنسبة واحد
+
+107
+00:08:51,360 --> 00:08:54,980
+لواحد لكن انا مش ضايف الاول ضد التاني بالظبط اللي
+
+108
+00:08:54,980 --> 00:08:58,820
+يتفعل و نهائي انا كلهم يتحولوا لنواتج انا ضايف
+
+109
+00:08:58,820 --> 00:09:03,060
+حاجتين مختلفة مختلفات في ال millimoles يعني
+
+110
+00:09:03,060 --> 00:09:10,840
+تركيزات مختلفة وبالتالي واحد منهم هيزيد طيب انا
+
+111
+00:09:10,840 --> 00:09:14,440
+بقول في البداية هي ال AJ plus والاتراين بيعطون ال
+
+112
+00:09:14,440 --> 00:09:18,660
+complexالـ millimoles silver added طبعا ال volume
+
+113
+00:09:18,660 --> 00:09:22,560
+في ال molarity المليمولز يحاول ان يضيف ال volume
+
+114
+00:09:22,560 --> 00:09:26,200
+في ال molarity يلاحظ ان هذه 0.25 وهذه 0.75 بما انه
+
+115
+00:09:26,200 --> 00:09:31,240
+يتفاعل نسبة واحد لواحد ممكن اكتب هيك 0.25 0.75 0
+
+116
+00:09:31,240 --> 00:09:37,600
+قبل التفاعل هذه صارت 0.25 تتفاعل مع جد يعني هذه
+
+117
+00:09:37,600 --> 00:09:42,060
+صارت 0هذه زاد منها point five وهذه اتكوّن منها
+
+118
+00:09:42,060 --> 00:09:45,860
+point two five لماذا؟ لأن point two five تتفاعل مع
+
+119
+00:09:45,860 --> 00:09:49,000
+point two five بتعطيني point two five مش اكتر ولا
+
+120
+00:09:49,000 --> 00:09:55,460
+اقل ماشي اذا بقدر اجيب التركيزات الان لتراين ايش
+
+121
+00:09:55,460 --> 00:09:58,540
+تركيزها point two five millimole اللي تكونت على ال
+
+122
+00:09:58,540 --> 00:10:02,160
+total volume خمسين وخمسة وعشرين وخمسة وسبعين
+
+123
+00:10:02,160 --> 00:10:09,310
+لتراين اللي زادت0.5 على ال total volume 75 هي طبعا
+
+124
+00:10:09,310 --> 00:10:13,630
+صفر إذا هي عبارة عن صفر مافيش لها قيمة مافيش لها
+
+125
+00:10:13,630 --> 00:10:19,650
+تركيز لكن هذا بالمعالجة على هيئة quantitative step
+
+126
+00:10:19,650 --> 00:10:24,890
+خطوة quantitativeالان خطوة ال equilibrium بقول
+
+127
+00:10:24,890 --> 00:10:28,690
+والله ال silver قولت رايين تعطيني ال silver رايين
+
+128
+00:10:28,690 --> 00:10:32,430
+هذه صفر كانت هذه point five عالى خمس سبعين اللي هي
+
+129
+00:10:32,430 --> 00:10:35,530
+زادت هذه اصلا point five عالى خمس سبعين اللي اصلا
+
+130
+00:10:35,530 --> 00:10:40,510
+تكون الا طبعا لازم تجلب مقدار X عندها ان ال point
+
+131
+00:10:40,510 --> 00:10:46,750
+five عالى خمس سبعين طبعا بدجيها Xوهنا x من ال
+
+132
+00:10:46,750 --> 00:10:49,970
+formation constant بقدر ا google point five على
+
+133
+00:10:49,970 --> 00:10:56,750
+خمسة وسبعين minus x على ال x في ال point five على
+
+134
+00:10:56,750 --> 00:11:00,350
+خمسة وسبعين زائد x وطبعا بدي اتر اعمل فرضية بديهي
+
+135
+00:11:00,350 --> 00:11:04,810
+انه استخدم point five على خمسة وسبعين اكبر كتير من
+
+136
+00:11:04,810 --> 00:11:08,570
+ال x فال x بتطلع عندى واحد في عشر أقل سالب تمانية
+
+137
+00:11:09,360 --> 00:11:14,080
+لما بدّي أجي أقارن ال X بال 0.25 على 75 العشرة
+
+138
+00:11:14,080 --> 00:11:19,320
+أسالب تمانية أقل كتير من الربع على 75 وبالتالي ال
+
+139
+00:11:19,320 --> 00:11:23,060
+relative error لما نحسبه بطلع تلاتة في عشرة أسالب
+
+140
+00:11:23,060 --> 00:11:28,850
+أربعة في المية ولا إشيعلشان هيك ال X يمكن إلغاها
+
+141
+00:11:28,850 --> 00:11:33,790
+بسهولة لهذا السبب بقول يبقى ال X هي عبارة عن ال
+
+142
+00:11:33,790 --> 00:11:37,430
+silver إذا تركيز ال silver هو عبارة عن واحد في
+
+143
+00:11:37,430 --> 00:11:42,030
+عشرة أس سالب تمانية واضح أنه يعني أسئلة زي هذه هي
+
+144
+00:11:42,030 --> 00:11:46,830
+أسئلة مكررة مرت معنا يعني في chapter المقدمة اللي
+
+145
+00:11:46,830 --> 00:11:50,540
+حكينا فيه عن ال equilibriumلكن كنا نستخدم a و b و
+
+146
+00:11:50,540 --> 00:11:54,440
+c و كلام زي هيك لكن هالجهة تقولنا silver و trayen
+
+147
+00:11:54,440 --> 00:12:01,000
+و complex مثلا يعني لكن نفس المنهجية في الحل طيب
+
+148
+00:12:01,000 --> 00:12:07,190
+الآن ننتقل لموضوع ال EDTA و المعاييراتالخاصة بال
+
+149
+00:12:07,190 --> 00:12:10,950
+EDTA وفي البداية بنتكلم عن ال EDTA Equilibria في
+
+150
+00:12:10,950 --> 00:12:17,310
+الحقيقة فبنقول يعني أن ال EDTA تستخدم لمعايرة ال
+
+151
+00:12:17,310 --> 00:12:21,730
+metal ions ال EDTA تستخدم لمعايرة ال metal ions
+
+152
+00:12:21,730 --> 00:12:29,310
+بالتحديد ال metal ions يعني بخلاف المجموعة الأولى
+
+153
+00:12:29,310 --> 00:12:33,260
+عادةكل ال metal ions لكن بخلاف المجموعة الأولى لأن
+
+154
+00:12:33,260 --> 00:12:36,320
+المجموعة الأولى ال metal ions تبعتها مع ال EDTA ال
+
+155
+00:12:36,320 --> 00:12:40,180
+formation constant يعني قليل جدا يعني لا يكاد يذكر
+
+156
+00:12:40,180 --> 00:12:44,820
+يعني قليل كتير لكن المجموعة التانية حلوة هنفرجيكم
+
+157
+00:12:44,820 --> 00:12:49,060
+بعض القيم و ال transition metals ممتازة جدا مع ال
+
+158
+00:12:49,060 --> 00:12:54,190
+EDTAلكن المجموعة الأولى هتكون رديقة، هذه نقطة،
+
+159
+00:12:54,190 --> 00:12:59,430
+نقطة تانية طبعا ال EDTA هي عبارة عن polydentate
+
+160
+00:12:59,430 --> 00:13:05,630
+ليجاند، chelating agent لأنها طبعا polydentate،
+
+161
+00:13:05,630 --> 00:13:08,550
+بتكون one to one complex مع ال metal ions، هذا
+
+162
+00:13:08,550 --> 00:13:15,600
+الكلام مر معناه سابقا واحنا عارفينه كويس كتيرأيضًا
+
+163
+00:13:15,600 --> 00:13:21,840
+بتكون كومبليكزات مستقلات
+
+164
+00:13:21,840 --> 00:13:27,780
+عالية لأنها
+
+165
+00:13:27,780 --> 00:13:30,740
+مستقلات عالية لأنها مستقلات عالية لأنها مستقلات
+
+166
+00:13:30,740 --> 00:13:38,480
+عالية لأنها مستقلات عاليةوالكلات طبعا فيها multi
+
+167
+00:13:38,480 --> 00:13:44,080
+-dentate هي عبارة عن multi-dentate collecting
+
+168
+00:13:44,080 --> 00:13:49,020
+agent او legend ولاحظوا انتوا ال EDTA تحديدا هذه
+
+169
+00:13:49,020 --> 00:13:49,880
+ال EDTA
+
+170
+00:13:52,880 --> 00:13:57,680
+باسيك PH هذي ال H بتروح بتصير ال N فش عليها شحنة
+
+171
+00:13:57,680 --> 00:14:01,240
+بتصير اللون pair of electrons وهذه ال H كمان بتروح
+
+172
+00:14:01,240 --> 00:14:04,600
+وهذه ال H بتروح بتصيرها سالب وهذه ال H بتروح
+
+173
+00:14:04,600 --> 00:14:08,610
+بتصيرها سالب يعني صار في عليها أربعة سالبأربعة
+
+174
+00:14:08,610 --> 00:14:12,670
+سالب الأربعة سالب هي التنتين موجودات و لما تكون ال
+
+175
+00:14:12,670 --> 00:14:17,570
+pH low بيكونوا كمان هدول التنتين ال protons رايحين
+
+176
+00:14:17,570 --> 00:14:20,190
+معناه الكلام بيصير عليها أربعة سالب و طبيعي أن
+
+177
+00:14:20,190 --> 00:14:26,070
+هدول ال protons طبعا هم محتوطين hand بس بحسب ال pH
+
+178
+00:14:26,070 --> 00:14:30,630
+حسب ال pH إذا كان ال pH acidic بتصير protonated ال
+
+179
+00:14:30,630 --> 00:14:34,870
+nitrogen أو ال amine بتصير protonated لكن لو كانت
+
+180
+00:14:34,870 --> 00:14:39,480
+basic طبعا مافيش عندى ال protonsلاحظ الشيء الأهم
+
+181
+00:14:39,480 --> 00:14:44,200
+يعني اتطلع كيف بتعمل complex مع ال metal ion هاي
+
+182
+00:14:44,200 --> 00:14:48,540
+ال metal ion في النص، هاي ال ethylene دا يامينهذا
+
+183
+00:14:48,540 --> 00:14:55,080
+بس جزيء EDTA 1، هاي الاثيليين بيمين، وهي تترا
+
+184
+00:14:55,080 --> 00:14:57,980
+أستيك أسد، هاي واحدة أستيك أسد، هاي تنتين، هاي
+
+185
+00:14:57,980 --> 00:15:03,800
+تلاتة، هاي أربع، لاحظ هاي ال Nitrogens و ال Oxygen
+
+186
+00:15:03,800 --> 00:15:07,860
+تنتين هدول، هدول عبارة عن ال square حوالين ال
+
+187
+00:15:07,860 --> 00:15:13,200
+metal ionوهي أكسوجينة فوق و أكسوجينة تحت، يعني هي
+
+188
+00:15:13,200 --> 00:15:18,140
+square و هي أكتاهيدرال complex، و ال metal ion
+
+189
+00:15:18,140 --> 00:15:23,460
+موجود جوا مكلبش، مش عارف يطلع نهائيا، عشان هيك ال
+
+190
+00:15:23,460 --> 00:15:30,150
+KFA شماله كبير، مش سهل أنه يعني المركب يتفككمش
+
+191
+00:15:30,150 --> 00:15:34,830
+سهل، طبعا هذه بتوقع فعلا انها زي ما شوفنا في أسباب
+
+192
+00:15:34,830 --> 00:15:38,810
+ثابات ال complexes، واش العوامل اللي بتأثر على
+
+193
+00:15:38,810 --> 00:15:43,170
+ثابات ال complexes، مش كل ال metal ions واحد، لأ
+
+194
+00:15:43,170 --> 00:15:47,970
+ال metal ions يعني بتختلف في ثابتها تحديدا بحسب
+
+195
+00:15:47,970 --> 00:15:54,190
+حجم هو الشحنة اللي عليها غالباو هل في عندها d
+
+196
+00:15:54,190 --> 00:15:59,830
+-orbitals كافية لإنه تعمل strong complexes ولا لأ
+
+197
+00:15:59,830 --> 00:16:05,210
+لكن لو طلعت على الشكل الشكل هذا بيعطيك جزء قوي جدا
+
+198
+00:16:05,210 --> 00:16:11,590
+complex very stable very high KF value المفروض
+
+199
+00:16:11,590 --> 00:16:16,190
+طبعا هذا الشكل هو هذا لكن مرسوم بال models يعني
+
+200
+00:16:19,480 --> 00:16:27,420
+هنيجي لبعض القيم بعد شوية بقول ال EDTA equilibria
+
+201
+00:16:27,420 --> 00:16:32,420
+هذا مهم يا شباب نفهمه الاتزانات الخاصة بال EDTA
+
+202
+00:16:32,420 --> 00:16:40,560
+بقول احنا علشان نقدر نعمل ال complex اللي شفناه في
+
+203
+00:16:40,560 --> 00:16:46,710
+الصورة هان المفروض انه يكون فيسالب تنتهي تلاتة
+
+204
+00:16:46,710 --> 00:16:51,870
+أربعة و ال legend هذا ما هو الأمين موجودين فمعنى
+
+205
+00:16:51,870 --> 00:17:00,630
+ليش يعني سالب أربعة احنا لو عبرنا عن ال EDTA بصيغة
+
+206
+00:17:00,630 --> 00:17:06,670
+H4Y تترا أسيتيك أسد فمعنى كلام اللي بتفاعل في
+
+207
+00:17:06,670 --> 00:17:09,130
+الحقيقة مع متل آيون زي الكالسيوم
+
+208
+00:17:38,790 --> 00:17:43,020
+هو ال Y4- إذا كانت لاحظتبيكون Complex قوي مع ال
+
+209
+00:17:43,020 --> 00:17:49,940
+EDTA فاحنا هنعتبر ان ال EDTA هي عبارة عن H4Y لكن
+
+210
+00:17:49,940 --> 00:17:53,480
+ال form اللي بيدخل ال equilibrium هو عبارة عن ال
+
+211
+00:17:53,480 --> 00:18:03,920
+Y4- لكن بنقول .. بنقولإنه ال EDTA لو حطيناها في
+
+212
+00:18:03,920 --> 00:18:09,420
+الميه طبعا بتتفكك ال H4Y بيبقى لهاش في الميه H4Y
+
+213
+00:18:09,420 --> 00:18:13,560
+لأ طبعا زي ال phosphoric acid زي ال carbonic acid
+
+214
+00:18:13,560 --> 00:18:21,420
+ايش تحول لإيه والله جزء منها بتحول ل مثلا H3Y سالب
+
+215
+00:18:21,420 --> 00:18:26,320
+جزء منها لH2Y2 سالب جزء منها لHY3 سالب جزء منها
+
+216
+00:18:26,320 --> 00:18:31,710
+لY4 سالب طبعا جزء منها مضلوا علاقة H4Yفهي بتتجزأ
+
+217
+00:18:31,710 --> 00:18:37,090
+طب هذه الأجزاء اللي هجدش بده يكون عندنا h4y جدش
+
+218
+00:18:37,090 --> 00:18:44,390
+h3y سالب جدش h2y2 سالب جدش h3y3 سالب جدش y4 سالب
+
+219
+00:18:44,390 --> 00:18:47,830
+جدش بده يكون موجود من كل ال fraction قال والله
+
+220
+00:18:47,830 --> 00:18:52,470
+الكل ينتبه قال هذا حسب ال pH إذا كان أنا ضابط ال
+
+221
+00:18:52,470 --> 00:19:00,340
+pH عند pH معينة إذاقيمة الـ fractions هتتغير بتغير
+
+222
+00:19:00,340 --> 00:19:06,320
+ال pH او هتعتمد بشكل رئيسي على ال pH هتعتمد بشكل
+
+223
+00:19:06,320 --> 00:19:12,060
+رئيسي على ال pH فاحنا لما نيجي نتكلم عن ال Y4-
+
+224
+00:19:12,060 --> 00:19:16,830
+ونقول هي المهمةبقول أنا عندي ال Y4- يمكن الحصول
+
+225
+00:19:16,830 --> 00:19:21,090
+عليها جداش عندي Y4- أنا حطيت EDTA، لكن جداش عندي
+
+226
+00:19:21,090 --> 00:19:26,590
+Y4-؟ قال والله بقدر أحسبها، حسب ال pH، ال α4
+
+227
+00:19:26,590 --> 00:19:31,460
+بتساوي ال Y4- على ال CTمن وين جيبنا هذا الكلام؟ من
+
+228
+00:19:31,460 --> 00:19:34,880
+ال fraction جيبنا ال fractions من ال acid
+
+229
+00:19:34,880 --> 00:19:38,040
+fractions at different pH values اشتقنا علاقة
+
+230
+00:19:38,040 --> 00:19:41,620
+باستخدام الفوسفوريك أسد وشوفنا الفوسفوريك أسد اللي
+
+231
+00:19:41,620 --> 00:19:46,220
+هو Alpha 0 اللي ماتفككش H3PO4 يعني Zero Zero يعني
+
+232
+00:19:46,220 --> 00:19:51,160
+Zero تفكك مافيش عندنا أي شحنة Alpha 1 H2PO4 سالب
+
+233
+00:19:51,160 --> 00:19:56,590
+كان شحنة واحدة Alpha 2 Alpha 3 هذا نفس الكلامبقول
+
+234
+00:19:56,590 --> 00:20:02,170
+انا عندي لو اعتبرنا ان التركيز الكل ل EDTA هو
+
+235
+00:20:02,170 --> 00:20:07,110
+عبارة عن ال H4Y اللي ضايل زي ما هى ال H3Y سالب ال
+
+236
+00:20:07,110 --> 00:20:11,490
+H2Y2 سالب ال HY3 سالب ال Y4 سالب هذا التركيز الكل
+
+237
+00:20:11,490 --> 00:20:16,770
+ل EDTA لكن جداش موجود منه على هيئة Y4 سالب Alpha 4
+
+238
+00:20:16,770 --> 00:20:23,220
+منهالفا فور من ال CT الفا فور ليه لأنه فقط جزء
+
+239
+00:20:23,220 --> 00:20:28,300
+موجود على هيئة Y4 سالم طيب والباقي الجال موجود على
+
+240
+00:20:28,300 --> 00:20:32,260
+هيئة أشكال أخرى ممكن يكون هذه الأشكال لكن مجموع
+
+241
+00:20:32,260 --> 00:20:36,970
+هذه الأشكال كلها هي التركيز الكل لل EDTAطب كيف بده
+
+242
+00:20:36,970 --> 00:20:41,310
+اجيب ال alpha 4؟ جالس كارب نتذكر هذه H4Y يعني
+
+243
+00:20:41,310 --> 00:20:46,750
+أربعة protons فببدأ بالمقام H plus أس أربعة K a1 H
+
+244
+00:20:46,750 --> 00:20:51,930
+plus أس تلاتة K a1 K a2 H plus اتنين K a1 K a2 K
+
+245
+00:20:51,930 --> 00:20:58,330
+a3 H plus K a1 K a3 K a2 K a3 K a4 كويس؟ انا بدي
+
+246
+00:20:58,330 --> 00:21:03,960
+ال Y4- ايش بدي أحط في البصيحتاج الـ Y4- يحتاج الـ
+
+247
+00:21:03,960 --> 00:21:07,400
+Y4- ليس فيها أي بروتون يعني هي على طول KA1, KA2,
+
+248
+00:21:07,480 --> 00:21:11,240
+KA3, KA4 أو انه قول والله هذه التباعة الـ α0, α1,
+
+249
+00:21:11,400 --> 00:21:16,620
+α2, α3 هي الـ α4 إذا الـ BUS بدي يكون KA1, KA2,
+
+250
+00:21:16,760 --> 00:21:20,820
+KA3, KA4لحظن الحظ ان احنا في الامتحان بنجيب ال
+
+251
+00:21:20,820 --> 00:21:26,020
+cash تحسبها لإنه يعني بدها شوية وجد عند الطالب
+
+252
+00:21:26,020 --> 00:21:28,920
+اللي ماعندهش خبرة لكن طبعا اللي عنده خبرة بتطلع
+
+253
+00:21:28,920 --> 00:21:32,500
+على الأرقام وممكن يعني بثواني يحلها بمجرد النظر
+
+254
+00:21:33,470 --> 00:21:38,090
+ليه؟ لأنه مرات بيكون مثلا عندك عشرة أُس سالب عشرين
+
+255
+00:21:38,090 --> 00:21:41,210
+وعشرة أُس سالب سبعة جانبها وعشرة أُس سالب تمانية
+
+256
+00:21:41,210 --> 00:21:44,070
+خلاص برمي ال term اللي بيقول عشرة أُس سالب عشرين
+
+257
+00:21:44,070 --> 00:21:48,870
+بمجرد النظر ب skimming يعني باطلع يعني بس مجرد
+
+258
+00:21:48,870 --> 00:21:52,210
+النظر باطلع أعرف بعض ال terms قليل جدا بلغيها
+
+259
+00:21:52,790 --> 00:21:56,190
+فبالتالي الحسابات سهلة و مع ذلك احنا مابناش نكلفك
+
+260
+00:21:56,190 --> 00:22:01,630
+عناء الحسابات هنعطيك قيمة الـ α4 بدك تتذكر ان الـ
+
+261
+00:22:01,630 --> 00:22:07,290
+α4 لو طلعت على هذه المعادلة الـ α4 فقط تتوقف على
+
+262
+00:22:07,290 --> 00:22:10,730
+الـ pH لأن هي كيوبان كيتو كتر، هذه ثوابت، مالاش ده
+
+263
+00:22:10,730 --> 00:22:13,070
+عرف حاجة، تتوقف على الحرارة يعني، الحرارة تابت هي
+
+264
+00:22:13,070 --> 00:22:17,390
+تابتة لكن فقط الـ H plus هي اللي موجودة في
+
+265
+00:22:17,390 --> 00:22:25,170
+المعادلة، إذا انت تتوقف على الـ H plusهي ال pH
+
+266
+00:22:25,170 --> 00:22:31,610
+يعني ال alpha4 تتوقف بس على ال pH عند 0 كانت ال
+
+267
+00:22:31,610 --> 00:22:36,230
+alpha4 عشر أقل سلب 23 عند 1 كانت عشر أقل سلب 18 ،
+
+268
+00:22:36,230 --> 00:22:40,660
+01 يعني محلول very acidic0 و 1 يعني محلول ايش
+
+269
+00:22:40,660 --> 00:22:45,960
+ماله؟ very acidic او كتير من ال Y4 minus اتحول ال
+
+270
+00:22:45,960 --> 00:22:52,880
+H4 و ال H3 و ال H2 و ال HY جزء قليل ضايع هيئة Y4
+
+271
+00:22:52,880 --> 00:22:58,500
+سالب لإن ال protons ايش مالها كتيرة يعني pH منخفبة
+
+272
+00:22:58,500 --> 00:23:04,100
+لكن لما تصير مثلا ال pH خمسة بنلاحظ ان ال Y4 سالب
+
+273
+00:23:04,100 --> 00:23:10,340
+عشر أقل سالب سبعة طب لما ال pH صارت عشرةالواي فور
+
+274
+00:23:10,340 --> 00:23:16,240
+سالب 36%زالت كده طب لما ال PH صارت 13 very basic
+
+275
+00:23:16,240 --> 00:23:24,320
+صار معظم ال Y عبارة عن Y4 سالف تقريبا كل ال EDTA
+
+276
+00:23:24,320 --> 00:23:32,080
+على هيئة Y4 سالف عن ال PH مثلا 13 ففي يعني اعتماد
+
+277
+00:23:32,080 --> 00:23:38,900
+طبعا مهم جدا و رئيسي لل alpha for ال value تبعتي
+
+278
+00:23:38,900 --> 00:23:41,320
+على ال PH
+
+279
+00:23:45,490 --> 00:23:48,870
+فاحنا بنقول إنه إذا كان عارفنا ال a4 حسبناها من
+
+280
+00:23:48,870 --> 00:23:53,810
+هنا والتركيز الكلي لل EDTA معايا إذا بقدر أعرف
+
+281
+00:23:53,810 --> 00:23:58,550
+جداش من ال EDTA موجودة على هيئة Y4- علشان لما بدي
+
+282
+00:23:58,550 --> 00:24:04,870
+أجي أقول ال Kf بدها تساوي calcium Y مثلا يعني Y2-
+
+283
+00:24:04,870 --> 00:24:11,150
+على ال calciumفي ال Y4- لما مابتداش اعوض عن ال Y4-
+
+284
+00:24:11,150 --> 00:24:15,270
+هذه ماعرفش كده ايش قيمتها انا الا اني اعوض عنها
+
+285
+00:24:15,270 --> 00:24:19,710
+بقيمتها
+
+286
+00:24:19,710 --> 00:24:25,170
+على هيئة Alpha for CT
+
+287
+00:24:26,180 --> 00:24:31,000
+الـCT معايا والـY4 بحسبها بقدر أجيب الـY4- اللازمة
+
+288
+00:24:31,000 --> 00:24:36,760
+لحل المعادلة لأن كيف بده أجيب الـK if expression
+
+289
+00:24:36,760 --> 00:24:40,640
+من هنا بده أقول والله ال calcium Y2- بقدر أعرفها
+
+290
+00:24:40,640 --> 00:24:44,760
+ال calcium بقدر أعرفه لكن ال Y4- تتوقف على ال pH
+
+291
+00:24:45,990 --> 00:24:51,230
+بحسب ال pH لإيه؟ لأنها بتساوي alpha4 CT هي ال Y4
+
+292
+00:24:51,230 --> 00:24:54,430
+minus فال alpha4 بقدر أحسبها و ال CT total
+
+293
+00:24:54,430 --> 00:24:57,750
+concentration ده ال EDT عادة بقدر أحسبه أو بيكون
+
+294
+00:24:57,750 --> 00:25:01,110
+معايا فبالتالي بقدر أعرف ال Y4 minus اللي أنا
+
+295
+00:25:01,110 --> 00:25:05,230
+هستخدمها في ال KF expression
+
+296
+00:25:10,380 --> 00:25:14,800
+قلنا يا شباب إنه هذا بنسميه Formation Constant
+
+297
+00:25:14,800 --> 00:25:19,180
+Formation Constant بالنسبة للكالسيوم والمجنيزيوم
+
+298
+00:25:19,180 --> 00:25:22,820
+ال Formation Constant يعتبر صغير نسبيا صغير يعني
+
+299
+00:25:22,820 --> 00:25:26,820
+جداش يعني المجنيزيوم مثلا عشر أقل سالب اتنين في
+
+300
+00:25:26,820 --> 00:25:30,060
+عشر أقل سالب تمانية عشر أقل سالب تمانية صغير بنقول
+
+301
+00:25:30,060 --> 00:25:35,640
+اه بالنسبة لإيه صغير بالنسبة لبجيت ال الكلات بجيت
+
+302
+00:25:35,640 --> 00:25:40,400
+العناصر صحيحطب و ال calcium جال calcium خمسة في
+
+303
+00:25:40,400 --> 00:25:43,700
+عشرة أقص عشرة، الصغير خمسة في عشرة أقص عشرة، بنقول
+
+304
+00:25:43,700 --> 00:25:47,060
+أه بالنسبة لما جيت العناصر، وهذا يلهم إعكاسات مهمة
+
+305
+00:25:47,060 --> 00:25:51,220
+جدا، هذا يلهم إعكاسات مهمة جدا، بالذات لما نتكلم،
+
+306
+00:25:51,220 --> 00:25:54,080
+إذا الله راضي الحصة اللي جاية عن ال indicators،
+
+307
+00:25:54,080 --> 00:25:57,100
+هذا إعكاساته كتير كتير كتير مهمة، بالذات ال
+
+308
+00:25:57,100 --> 00:26:03,510
+magnesium، لما نتكلم عن ال indicatorsبنقول يا شباب
+
+309
+00:26:03,510 --> 00:26:07,110
+انه ال formation constant طبعا لازم تكتب المعادلة
+
+310
+00:26:07,110 --> 00:26:14,050
+هي Formation هي عبارة عن ال EDTA metal ion complex
+
+311
+00:26:14,050 --> 00:26:18,690
+او كلية على هاد بالنسبالي كالسيوم في ال Y4 minus
+
+312
+00:26:18,690 --> 00:26:22,610
+لكن ال Y4 minus زي ما قلت بتسوى Alpha 4 CT و لازم
+
+313
+00:26:22,610 --> 00:26:29,450
+نعرف قيمة ال Alpha 4 علشان نقدر نحسب يعني المجهول
+
+314
+00:26:32,510 --> 00:26:38,490
+للمعلومات بقول نجي نتطلع على العناصر المختلفة و
+
+315
+00:26:38,490 --> 00:26:43,170
+نشوف قداش قيمة ال formation constant و برضه هذا
+
+316
+00:26:43,170 --> 00:26:48,290
+كلام مهم هفرجيكم ليش بعد شويةالسلفر عشرة أقص سبعة
+
+317
+00:26:48,290 --> 00:26:52,850
+المجنيزيوم عشرة أقص تمانية الكالسيوم عشرة أقص عشرة
+
+318
+00:26:52,850 --> 00:26:56,210
+السترانشيوم عشرة أقص تمانية الباريوم عشرة أقص سبعة
+
+319
+00:26:56,210 --> 00:26:59,030
+لاحظ أن المجموعة التانية المجموعة الأولى ما
+
+320
+00:26:59,030 --> 00:27:03,470
+بنذكرهاش لإنها قليلة كتير صوديوم بوتاسيوم ليثيوم
+
+321
+00:27:03,470 --> 00:27:07,430
+قليلة فبنحكيش عنها يعني المجموعة التانية وفوق
+
+322
+00:27:07,430 --> 00:27:12,310
+المجموعة التانية عشرة أقص سبعة عشرة أقص عشرة مش
+
+323
+00:27:12,310 --> 00:27:18,050
+كتير كبيرةلكن نجي نروح لل transition metals كويس
+
+324
+00:27:18,050 --> 00:27:23,190
+فنقول مانجانيز 10 أقص 13 الفرس 10 أقص 14 يعني لما
+
+325
+00:27:23,190 --> 00:27:29,170
+نجي نقارن 10 أقص 14 مثلا ب10 أقص 7 هي 10 مليون مرة
+
+326
+00:27:29,170 --> 00:27:34,810
+10 مليون مش بضعف 10 مليون مرة أكبر منها 10 أقص 14
+
+327
+00:27:34,810 --> 00:27:39,590
+أكبر ب10 مليون مرة من 10 أقص 7 بمليون مرة أكبر من
+
+328
+00:27:39,590 --> 00:27:45,200
+10 أقص 8طيب الكوبلت 10 أقص 16 النكل 10 أقص 18
+
+329
+00:27:45,200 --> 00:27:50,700
+الكبر 10 أقص 18 الذنك الكدميوم ال ميركوري 10 أقص
+
+330
+00:27:50,700 --> 00:27:58,460
+21 ال ميركوري 10 أقص 21 ال ليد 18 ال ألومنم 16 ال
+
+331
+00:27:58,460 --> 00:28:03,520
+ايرون و الفانديام 10 أقص 5 يعني حاجة مهولة حاجة
+
+332
+00:28:03,520 --> 00:28:07,260
+كبيرة خالص حاجة يعني بتعطيني very very very highly
+
+333
+00:28:07,260 --> 00:28:12,130
+stable complex يعنيهذا الـ slide بس بتقولنا انه في
+
+334
+00:28:12,130 --> 00:28:18,270
+تفاوت كبير في ال formation constants للكلات
+
+335
+00:28:18,270 --> 00:28:22,250
+المختلفة أو ال complexes المختلفة ل ال metal ions
+
+336
+00:28:22,250 --> 00:28:31,110
+مع ال EDTA طيب ايش انعكاس هذا الكلام تعالوا نعمل
+
+337
+00:28:31,110 --> 00:28:42,980
+plot ما بين ال pHمع log الكيف للكليات المختلفة
+
+338
+00:28:42,980 --> 00:28:48,000
+لكمبليكس المختلفة يعني ال EDTA متل ايونكمبليكس
+
+339
+00:28:48,000 --> 00:28:53,400
+بنلاحظ أنه المجنيزيوم تحديدًا يعني المجنيزيوم
+
+340
+00:28:53,400 --> 00:28:57,020
+والكالسيوم الكيف اللي هم إيه شماله بالنسبة لغيرهم
+
+341
+00:28:58,060 --> 00:29:03,320
+قليل كتير، يعني قليل كتير خالص، قليل كتير جدا،
+
+342
+00:29:03,320 --> 00:29:08,340
+بينما لو جينا هان، و لاحظوا وين بتتم عملية
+
+343
+00:29:08,340 --> 00:29:13,540
+معاييرتهم، at high pH انت لما استخدمت معايرة
+
+344
+00:29:13,540 --> 00:29:16,600
+الكالسوم والمجنزة واشتغلت عند pH عشرة، اذا كانك
+
+345
+00:29:16,600 --> 00:29:22,490
+ناسي، اشتغلت عند pH عشرةطيب في مجموعة تانية لاحظوا
+
+346
+00:29:22,490 --> 00:29:29,350
+ال pH يعني متوسطة من تقريبا تلاتة و نص ل .. تقريبا
+
+347
+00:29:29,350 --> 00:29:35,190
+يعني لستة هذه مجموعة تانية في مجموعة تالتة يعني ال
+
+348
+00:29:35,190 --> 00:29:39,910
+pH acidic يعني تقريبالكن اتطلعوا على بال الـ KF
+
+349
+00:29:39,910 --> 00:29:43,530
+اشماله بزيده هذا logarithmic مش بيه على طبيعه هذا
+
+350
+00:29:43,530 --> 00:29:48,850
+logarithmic يعني هذه 10 أقص 22 10 أقص 24 10 أقص 26
+
+351
+00:29:48,850 --> 00:29:54,570
+10 أقص 18 يعني الخط هذا logarithmic لإن ال log ال
+
+352
+00:29:54,570 --> 00:29:58,810
+formation constant طيب إيش بنستفيد من هذا الكلام؟
+
+353
+00:29:58,810 --> 00:30:04,690
+إيش بنستفيد؟ أول فايدة أنا بقدر أقولها إنه ال EDTA
+
+354
+00:30:04,690 --> 00:30:08,800
+Complex مع الكالسيوم والمجنيزيامو تحديدا مع
+
+355
+00:30:08,800 --> 00:30:14,560
+المجنيزيوم ضعيف .. ال complex ضعيف .. عشان هيك لو
+
+356
+00:30:14,560 --> 00:30:18,620
+كان عندى مجنيزيوم و اي متل ايون اخر و حطيت EDTA
+
+357
+00:30:18,620 --> 00:30:23,140
+عليهم ال EDTA رح يتفاعل مع ال other metal ion و
+
+358
+00:30:23,140 --> 00:30:30,360
+يسيب المجنيزيوم للاخرطيب لو انا حطيت مجنيزين EDTA
+
+359
+00:30:30,360 --> 00:30:34,360
+complex انا عندي ال complex مجنيزين EDTA وحطيت
+
+360
+00:30:34,360 --> 00:30:38,320
+عليه متل عيون ايش هيسوي؟ المتل عين راح يطرد
+
+361
+00:30:38,320 --> 00:30:42,600
+المجنيزين وياخد ال EDTA منه اتذكر هذه الملاحظة في
+
+362
+00:30:42,600 --> 00:30:46,080
+الحصة الجايةتذكر هذه الملاحظة على الحصة التالية،
+
+363
+00:30:46,080 --> 00:30:49,240
+يفجأة هذه ماذا بتقول الرسم، بتقول في الوداق تتكلم
+
+364
+00:30:49,240 --> 00:30:52,680
+عن المجنيزيوم، بقول إنه لو كان في انديا مجنيزيوم
+
+365
+00:30:52,680 --> 00:30:55,920
+مثلا نوكالسيوم أو مجنيزيوم وكوبلت، مجنيزيوم وليد،
+
+366
+00:30:55,920 --> 00:30:58,980
+مجنيزيوم ولوتينيوم، مجنيزيوم ومايكوري، مجنيزيوم
+
+367
+00:30:58,980 --> 00:31:02,540
+وانديوم، مجنيزيوم واي حاجة تانية، لو حطيت الاتنين
+
+368
+00:31:02,540 --> 00:31:07,700
+مع بعض وحطيت اي حطيت EDTA بدأ تعاير، بلاحظ إن ال
+
+369
+00:31:07,700 --> 00:31:10,680
+EDTA بتفعل مع ال other metal ion، مش مع المجنيزيوم
+
+370
+00:31:11,200 --> 00:31:13,980
+لما نخلص الاذر متلايون بعدين بتتفاعل مع
+
+371
+00:31:13,980 --> 00:31:18,320
+المجنيزيام، هذه أول ملاحظة ملاحظة تانية، لو أنا
+
+372
+00:31:18,320 --> 00:31:22,860
+كان عندي complex مجنيزيام EDTA complex و روحت خطيت
+
+373
+00:31:22,860 --> 00:31:26,320
+على هذا ال complex متلايون، بلاحظ أن المتلايون
+
+374
+00:31:26,320 --> 00:31:29,860
+بيطرد المجنيزيام و بياخد ال EDTA، ليه؟ لأن
+
+375
+00:31:29,860 --> 00:31:33,900
+المتلايون EDTA complex أجوى من المجنيزيام EDTA
+
+376
+00:31:33,900 --> 00:31:38,240
+complexماخد فالك من هذه الملاحظة الحصة الجاية
+
+377
+00:31:38,240 --> 00:31:42,380
+هحنحاول أنه نستفيد منها نتكلم عن ال indicators لكن
+
+378
+00:31:42,380 --> 00:31:47,320
+الآن نكمل في الشكل برضه مش بنستفيد منه بنستفيد في
+
+379
+00:31:47,320 --> 00:31:51,740
+واقعي دي كتير مهمة زيش زي مثلا لو عندي انا iron
+
+380
+00:31:51,740 --> 00:31:59,980
+وفي عندي مثلا zincالـ Iron لو جت طلعت عند pH أقل
+
+381
+00:31:59,980 --> 00:32:04,800
+من 2 يعني بتفعل مع ال EDTA يبقى لو أندي زينكو
+
+382
+00:32:04,800 --> 00:32:09,720
+ايرون اذا كان انا بعمل معايرة عند pH 2 الايرون بس
+
+383
+00:32:09,720 --> 00:32:14,970
+هو اللي بتفعل لكن لو عملتها عند pH مثلا 4بلاحظ ان
+
+384
+00:32:14,970 --> 00:32:18,870
+ال zinc و ال iron بتفاعلوا يبقى اول مرة بشتغل
+
+385
+00:32:18,870 --> 00:32:23,530
+معايير عن ph2 ال iron بتفاعل اشتغل تاني مرة عن ph4
+
+386
+00:32:23,530 --> 00:32:27,050
+ال iron و ال zinc بتفاعلوا اذا لو طرحت ال اتنين من
+
+387
+00:32:27,050 --> 00:32:30,130
+بعض بعرف ال iron جديش لحاله و ال zinc جديش لحاله
+
+388
+00:32:30,130 --> 00:32:36,110
+يبقى لو عندي mixtureبقدر أظبط ال pH بحيث أنه أقدر
+
+389
+00:32:36,110 --> 00:32:40,990
+أعير مكونات ال mixture هذا لو عندي تلاتة عندي Iron
+
+390
+00:32:40,990 --> 00:32:46,670
+وعندي Copper وعندي Calcium بقدر والله أعير مثلا
+
+391
+00:32:46,670 --> 00:32:53,850
+عندي pH 2 بس ال Iron بيتعير عندي pH 4 بس ال Copper
+
+392
+00:32:53,850 --> 00:32:57,350
+بيتعير عفوا ال Copper زاد ال Iron بيتعير عندي pH
+
+393
+00:32:57,350 --> 00:33:01,830
+10 ال Calciumوالكبر و ال iron بتعيروا من التلت
+
+394
+00:33:01,830 --> 00:33:06,890
+معاييرات بقدر اعرف جداش موجود عندى من ال iron و
+
+395
+00:33:06,890 --> 00:33:12,210
+الكبر و ال calcium يبقى هذه فوائد مهمة جدا هذا
+
+396
+00:33:12,210 --> 00:33:15,010
+الشكل اللى بيعطيها ليه؟ هذا الشكل الجوهري بالنسبة
+
+397
+00:33:15,010 --> 00:33:19,330
+لنا في ال EDTA titration جوهر كتيرجوهر ايه؟ كتير
+
+398
+00:33:19,330 --> 00:33:24,170
+جدا لأنه بيفهمني بالظبط ايش اللي حصل معايا وكمان
+
+399
+00:33:24,170 --> 00:33:30,690
+بعطيني شوية دلالات عملية استفيد منها فى حل مشاكل
+
+400
+00:33:30,690 --> 00:33:37,970
+عملية حقيقية لو كان في عندى mixtures من ال metal
+
+401
+00:33:37,970 --> 00:33:38,470
+ions
+
+402
+00:33:52,370 --> 00:34:00,310
+بقول على فرض .. على فرض انه عندي EDTA و كالسيوم
+
+403
+00:34:00,310 --> 00:34:08,310
+عندي EDTA و كالسيوم و انا عندي اتفاعلوا مع بعض و
+
+404
+00:34:08,310 --> 00:34:09,790
+اعطوني كالسيوم EDTA
+
+405
+00:34:12,490 --> 00:34:18,310
+يعني بشكل فقط يعني بس calcium EDTA زاد عندي hand
+
+406
+00:34:18,310 --> 00:34:21,450
+صفر و عندي hand .. يعني هذه كانت مثلا point one و
+
+407
+00:34:21,450 --> 00:34:24,650
+هذه كانت point one و هذه كانت صفر و هذه صارت point
+
+408
+00:34:24,650 --> 00:34:30,350
+one point one بدقول minus x إيش بدقول hand؟بدي
+
+409
+00:34:30,350 --> 00:34:36,010
+أقول X طب ال Y4- أقول كمان X بقول لأ مش X هذه
+
+410
+00:34:36,010 --> 00:34:42,590
+عبارة عن Alpha 4 من ال X ليش؟ لأنه أه هي صح ال
+
+411
+00:34:42,590 --> 00:34:47,450
+calcium Y2- لما تفكر بتعطيني calcium و بتعطيني
+
+412
+00:34:47,450 --> 00:34:55,430
+كمان EDTA لكن ال EDTA ال Y4- هذه Y4- الكليةهذه
+
+413
+00:34:55,430 --> 00:35:05,010
+الجزءات للـH4Y والـH3Y سالب والـH2Y2 سالب والـHY3
+
+414
+00:35:05,010 --> 00:35:10,470
+سالب وطن جزء منها على هيئة Y4 سالب فانا اللي عندي
+
+415
+00:35:10,470 --> 00:35:14,870
+في المعادلة هو الـY4 سالب هذه كلها يا جماعة هي
+
+416
+00:35:14,870 --> 00:35:17,290
+عبارة عن X هدول كلهم
+
+417
+00:35:19,820 --> 00:35:25,480
+هم عبارة عن X جداش موجود منهم على هيئة Y4- Alpha 4
+
+418
+00:35:25,480 --> 00:35:30,420
+من ال X يبجى بخلاف الكلام اللى خدناه سابقا عندي
+
+419
+00:35:30,420 --> 00:35:35,520
+هان انا ال Y4- تعتمد على قولنا ساعة ده الكلام قبل
+
+420
+00:35:35,520 --> 00:35:41,110
+شوية قيمتها تعتمد على ال pHقيمة الـ Y4- ستعتمد على
+
+421
+00:35:41,110 --> 00:35:46,030
+الـ pH علشان هيك بنقول أن الـ Y4- هي عبارة عن
+
+422
+00:35:46,030 --> 00:35:51,550
+Alpha 4 من الـ CT من التركيز الكلي Alpha 4 من الـ
+
+423
+00:35:51,550 --> 00:35:57,450
+X الكالسيوم بسوء التركيز الكلي للـ EDTA الكالسيوم
+
+424
+00:35:57,450 --> 00:36:03,450
+.. تركيز الكالسيوم بسوء الـ TotalE D T A
+
+425
+00:36:03,450 --> 00:36:10,590
+concentration كل ال E D T A لكن هذه اتجزأت جزء
+
+426
+00:36:10,590 --> 00:36:14,550
+منها بس دلوا على هيئة Y4- طب جداش دلوا على هيئة Y4
+
+427
+00:36:14,550 --> 00:36:22,710
+- Alpha 4 من ال CT اذا بقدر اقول انا بقدر
+
+428
+00:36:22,710 --> 00:36:23,810
+اقول انه
+
+429
+00:36:26,610 --> 00:36:36,150
+الـ Kf بدها تساوي الكالسيوم
+
+430
+00:36:36,150 --> 00:36:45,840
+Y2- على الكالسيومفي alpha 4 من ال city ممكن يا
+
+431
+00:36:45,840 --> 00:36:52,080
+شباب ال alpha 4 هذه ثابت برضه عند ph معينة ثابت مش
+
+432
+00:36:52,080 --> 00:36:56,760
+ثابت على طول لأ مثلا عند ph عشرة خمسة و تلاتين في
+
+433
+00:36:56,760 --> 00:37:02,430
+المية او ستة و تلاتين في الميةعن pH 13 واحد فهي
+
+434
+00:37:02,430 --> 00:37:08,270
+ثابت عن pH معينة فهذا الثابت مع هذا الثابت يمكن
+
+435
+00:37:08,270 --> 00:37:13,950
+يصير اسمه KF' الجانب دي يساوي calcium Y2- على ال
+
+436
+00:37:13,950 --> 00:37:22,930
+calcium في ال CT ال CT هو عبارة عن ال total EDTA
+
+437
+00:37:22,930 --> 00:37:25,530
+concentration
+
+438
+00:37:26,690 --> 00:37:33,050
+ماشي طيب ال KF شحطة هادى ايش بنسميه جال بنسميه
+
+439
+00:37:33,050 --> 00:37:37,130
+conditional equilibrium constant بنسميه
+
+440
+00:37:37,130 --> 00:37:40,470
+conditional equilibrium constant ايش يعني
+
+441
+00:37:40,470 --> 00:37:43,270
+conditional equilibrium constant او conditional
+
+442
+00:37:43,270 --> 00:37:47,970
+formation constant ايش يعني conditional formation
+
+443
+00:37:47,970 --> 00:37:53,330
+constant جال conditional formation constant بتعني
+
+444
+00:37:54,420 --> 00:38:03,200
+ثابت التكوين المشروط بالـ pH لأن هو مضرب بالـ α4
+
+445
+00:38:03,200 --> 00:38:06,980
+والـ α4 هي دالة في الـ pH فقط
+
+446
+00:38:10,710 --> 00:38:14,610
+الـ conditional formation constant ثابت التكوين
+
+447
+00:38:14,610 --> 00:38:19,850
+المشروط ليش مشروط أو بإيش مشروط جال مشروط بال pH
+
+448
+00:38:19,850 --> 00:38:26,680
+مشروط بقيمة ال pH لكن احنا مش هنستخدمالـ
+
+449
+00:38:26,680 --> 00:38:30,140
+Conditional Equilibrium او Formation Constant احنا
+
+450
+00:38:30,140 --> 00:38:36,140
+دائما هنحل باستخدام ال Formation Constant العادى و
+
+451
+00:38:36,140 --> 00:38:41,440
+هنقول و الله بيساوي تركيز الكلية على ال metal ion
+
+452
+00:38:41,440 --> 00:38:46,860
+في ال alpha for في ال CT فهنستخدم هذه المعادلة مش
+
+453
+00:38:46,860 --> 00:38:50,520
+هنستخدم المعادلة التحترية
+
+454
+00:38:52,380 --> 00:38:57,300
+طيب خلّينا نتطلع الآن على حاجة بنقولها Titration
+
+455
+00:38:57,300 --> 00:39:01,940
+Curse اه
+
+456
+00:39:01,940 --> 00:39:06,360
+منحنيات المعايرة احنا شوفنا في ال acid base
+
+457
+00:39:06,360 --> 00:39:11,640
+titrations ان منحنيات المعايرة كانت متوقفة على
+
+458
+00:39:11,640 --> 00:39:16,140
+ثابت التفكك لل acid أو ال base كل ما زاد ثابت
+
+459
+00:39:16,140 --> 00:39:20,780
+التفكك كل ما كان ل break اللي عندي sharpersharper
+
+460
+00:39:20,780 --> 00:39:24,400
+break at the equivalence point و أيضا كان الحاجة
+
+461
+00:39:24,400 --> 00:39:29,260
+التانية ال concentrations ل ال acid و ال base فكل
+
+462
+00:39:29,260 --> 00:39:34,740
+ما زادت تركيز تركيز ال acid و ال base كل ما زادت
+
+463
+00:39:34,740 --> 00:39:38,320
+تركيز تركيز المتفاعلات كان برضه بيعطيني sharper
+
+464
+00:39:39,860 --> 00:39:44,460
+break at the equivalence point فيما يتعلق بال ..
+
+465
+00:39:44,460 --> 00:39:49,780
+فيما يتعلق بال complexometric reactions أو
+
+466
+00:39:49,780 --> 00:39:54,540
+titrations بنقول بنفس الصورة تماما .. نفس الصورة
+
+467
+00:39:54,540 --> 00:39:58,320
+تماما
+
+468
+00:39:58,320 --> 00:40:03,640
+ال break at the equivalence point بتكون sharper
+
+469
+00:40:05,050 --> 00:40:10,330
+وبتتوقف على تلت حاجات مش حاجتين اول حاجة ال
+
+470
+00:40:10,330 --> 00:40:14,230
+formation constant فبنقول كل ما زاد ال formation
+
+471
+00:40:14,230 --> 00:40:19,310
+constant لل complex طبعا هذا ماقدرش اتحكم فيه لما
+
+472
+00:40:19,310 --> 00:40:23,590
+يكون عندك مثلا calcium EDTA او magnesium EDTA او
+
+473
+00:40:23,590 --> 00:40:28,010
+iron EDTA او copper EDTA او cobalt EDTA هذا كل
+
+474
+00:40:28,010 --> 00:40:31,590
+واحد فيهم له formation constant احنا مابنتحكم فيه
+
+475
+00:40:32,530 --> 00:40:35,730
+نتحكمش فيه، خلاص ال formation constant تبقى ويك،
+
+476
+00:40:35,730 --> 00:40:39,070
+لكن بنقول الملاحظة أنه لما يكون ال formation
+
+477
+00:40:39,070 --> 00:40:44,070
+constant كبير، بتكون أيضًا ال break كبيرة، يعني
+
+478
+00:40:44,070 --> 00:40:51,310
+هذه المسافة أطول، كويس؟ و sharper، sharp، كويس؟
+
+479
+00:40:51,310 --> 00:40:56,750
+لما نكون صغير، ببدأ يصير عندي إشي زي هيك، مال، مش
+
+480
+00:40:56,750 --> 00:41:04,160
+sharpلما يكون ال KF صغير بيبدأ بحصل على شكل
+
+481
+00:41:04,160 --> 00:41:09,750
+سيجمويدل زي ال S عامليبقى أول نقطة بقدر أقول بتأثر
+
+482
+00:41:09,750 --> 00:41:13,530
+على الـ titration curve قيمة الـ KF أو ثبات ال
+
+483
+00:41:13,530 --> 00:41:17,830
+complex فكل ما زادت قيمة الـ KF كل ما كانت ال
+
+484
+00:41:17,830 --> 00:41:21,210
+break at the equivalence point sharper هذه أول
+
+485
+00:41:21,210 --> 00:41:26,810
+نقطة النقطة التانية برضه كمان تأثير تركيز
+
+486
+00:41:26,810 --> 00:41:33,810
+المتفاعلات بحيث أنه كل ما زاد تركيز المتفاعلات كل
+
+487
+00:41:33,810 --> 00:41:40,970
+ما كان ل break sharperيبقى المتفاعلات بتكون ال
+
+488
+00:41:40,970 --> 00:41:45,270
+break sharper إذا كان تركيز المتفاعلات كبير، بينما
+
+489
+00:41:45,270 --> 00:41:50,990
+كمان مرة، لو كان تركيز المتفاعلات قليل، أقل، بلاحظ
+
+490
+00:41:50,990 --> 00:41:54,970
+إن هان ببدأ يصير عند إيه؟ سيجمويدل، و هان طبعا
+
+491
+00:41:54,970 --> 00:41:58,710
+سيجمويدل هيضارة كبيرة، لأنه بيأثر على قدرتي على
+
+492
+00:41:58,710 --> 00:42:02,860
+تعيين ال end point، أنا بدي هيكون sharpعشان نقطة
+
+493
+00:42:02,860 --> 00:42:07,020
+واحدة بس تعطيني التغير في لون ال indicator أو
+
+494
+00:42:07,020 --> 00:42:10,040
+تعطيني ال end point لكن لما تكون ال sigmoidal
+
+495
+00:42:10,040 --> 00:42:16,220
+بتكون مشكلة بقدرش أعين ال equivalence point بشكل
+
+496
+00:42:16,220 --> 00:42:23,010
+دقيق يبقى تركيزتركيز المتفاعلات وهنا في ناس كتير
+
+497
+00:42:23,010 --> 00:42:27,210
+في الحقيقة بيوجعوا في خطأ في أحيان كتيرة احنا
+
+498
+00:42:27,210 --> 00:42:32,030
+بنحاول انه نقدر كمية مثلا metal ion في الميه
+
+499
+00:42:32,030 --> 00:42:38,040
+بتركيزات منخفضةو لأنه فيش عندنا زمان يعني هاليام
+
+500
+00:42:38,040 --> 00:42:41,880
+الحمد لله عندنا أجهزة كويسة كتير أو بعض الناس اللي
+
+501
+00:42:41,880 --> 00:42:45,220
+فيش عندهم أجهزة لليوم بيحاولوا يستخدموا ال EDTA
+
+502
+00:42:45,220 --> 00:42:50,220
+titrations بنقول إنه خطر كبير جدا إنه نيجي نعمل
+
+503
+00:42:50,220 --> 00:42:54,620
+معايرة ل EDTA titration مثلا ب10 أو 4 مولار EDTA
+
+504
+00:42:54,620 --> 00:43:00,000
+مع 10 أو 4 أو 5 مولار متالايون صعب كتيرتقدير الـ
+
+505
+00:43:00,000 --> 00:43:02,420
+end point أو تحديد الـ end point بتكون يعني من
+
+506
+00:43:02,420 --> 00:43:07,820
+الصعوبة لما كان في خطأ جسيم في تقدير ال .. او في
+
+507
+00:43:07,820 --> 00:43:12,700
+يعني تحديد ال end point بدقة علشان هيك بنقول انه
+
+508
+00:43:12,700 --> 00:43:19,880
+تركيزات المتفاعلات مهمة جدا في قدرتنا على تحديد ال
+
+509
+00:43:19,880 --> 00:43:22,520
+end point وحصولنا على sharp break at the
+
+510
+00:43:22,520 --> 00:43:26,300
+equivalence point بحيث انه كل ما زادت التركيزات
+
+511
+00:43:27,080 --> 00:43:30,480
+EDTA والمتالعيون كل ما كانت هذه المنطقة شرفة
+
+512
+00:43:30,480 --> 00:43:33,960
+العامل التالت زي ما هو قدامكم هان اللي هو ال PH
+
+513
+00:43:33,960 --> 00:43:39,600
+بنلاحظ انه كل ما زادت ال .. هذه نفس ال .. نفس ال
+
+514
+00:43:39,600 --> 00:43:43,260
+titration لكن هان ال titration معمولة عن ال PH7
+
+515
+00:43:43,260 --> 00:43:47,780
+نفس المتالعيون و نفس ال EDTA لكن هان ال PH7 هي
+
+516
+00:43:47,780 --> 00:43:53,500
+المعمولة لحظة ال break جديششوية لكن لما ال pH صارت
+
+517
+00:43:53,500 --> 00:43:58,740
+عشرة ايش حصل في ال break؟ اه زادت هذا بيعطيني يعني
+
+518
+00:43:58,740 --> 00:44:03,680
+برضه دقة اكبر في تحديد ال end point اذا ال pH لما
+
+519
+00:44:03,680 --> 00:44:09,440
+نتزيد برضه ال break at the equivalence pointبتزيد،
+
+520
+00:44:09,440 --> 00:44:13,860
+يبقى هذه العوامل اللي بتأثر على شكل ال titration
+
+521
+00:44:13,860 --> 00:44:17,740
+curve لازم أخد بال ال KF كبير ولا مش كبير، هذا
+
+522
+00:44:17,740 --> 00:44:20,500
+مقدرش أتحكم فيه، لكن مقدر أتحكم في تركيز
+
+523
+00:44:20,500 --> 00:44:25,460
+المتفاعلات، مقدر أتحكم في ال PH طيب يا شباب بنوج
+
+524
+00:44:25,460 --> 00:44:28,400
+أفهان وإذا الله راج الحصة اللي جاية بنكمل
+
diff --git a/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/5hkBYzuMqWQ_postprocess.srt b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/5hkBYzuMqWQ_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..3724e5bf24604e0f736c86317f8d79b8c00c60c7
--- /dev/null
+++ b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/5hkBYzuMqWQ_postprocess.srt
@@ -0,0 +1,2180 @@
+1
+00:00:21,630 --> 00:00:24,930
+بسم الله الرحمن الرحيم الحصة الماضية يا شباب كنا
+
+2
+00:00:24,930 --> 00:00:28,190
+بدنا نتكلم عن ال gravimetric calculations و أخدنا
+
+3
+00:00:28,190 --> 00:00:34,830
+بعض الأمثلة اليوم ان شاء الله بنحاول أنه نستكمل ال
+
+4
+00:00:34,830 --> 00:00:37,370
+gravimetric analysis بشكل عام ال calculations
+
+5
+00:00:37,370 --> 00:00:45,870
+خصوصا و بعدين بننتقل لموضوع كتير مهم بيتكلم
+
+6
+00:00:45,870 --> 00:00:50,020
+عن ال precipitation equilibriaفنبدأ باستكمال الـ
+
+7
+00:00:50,020 --> 00:00:54,320
+Gravimetric Analysis شوفنا يمكن الحصة الماضية هذا
+
+8
+00:00:54,320 --> 00:00:58,340
+المثال كان اخر مثال طلعنا عليه لكن بسرعة شوية
+
+9
+00:00:58,340 --> 00:01:05,280
+بنقول انه بيهمن فكرة الحل دائما فكرة الحل دائما ان
+
+10
+00:01:05,280 --> 00:01:12,580
+انابحط ال millimole من ال analyte على ناحية و ال
+
+11
+00:01:12,580 --> 00:01:15,260
+millimole من ال precipitate على ناحية تانية وبحاول
+
+12
+00:01:15,260 --> 00:01:18,200
+اشوف ايش ال stoichiometric factor اللي لازم
+
+13
+00:01:18,200 --> 00:01:24,400
+استخدامه فمثلا في المثال اللي قدامي بقول manganese
+
+14
+00:01:24,400 --> 00:01:28,300
+in a 1.52 gram sample was precipitated as
+
+15
+00:01:28,300 --> 00:01:34,190
+manganese 3 او 4 weighing 0.126 gramsFind
+
+16
+00:01:34,190 --> 00:01:39,110
+percentage of manganese 203and percentage
+
+17
+00:01:39,110 --> 00:01:45,890
+manganese بقول البساطة خالص انا بدي افصل الانالايت
+
+18
+00:01:45,890 --> 00:01:51,670
+عن ال precipitate فبقول هاي الانالايت مانجانيز
+
+19
+00:01:51,670 --> 00:01:55,390
+اتنين او تلاتة هنبدأ فيها وهي مانجانيز تلاتة او
+
+20
+00:01:55,390 --> 00:01:58,730
+اربعة بلاحظ تلاتة مانجانيز هنا وهنا اتنين مانجانيز
+
+21
+00:01:58,730 --> 00:02:03,310
+عشان اخلى عدد المانجانيز في الطرفين واحد فببطر
+
+22
+00:02:03,310 --> 00:02:07,680
+اضرب في تلاتةواتنين الان اذا كان اقدر تكون
+
+23
+00:02:07,680 --> 00:02:11,700
+المعادلة لـ stoichiometric equation بشكل سليم الحل
+
+24
+00:02:11,700 --> 00:02:16,220
+خلاص انتهى الموضوع الحل بسيط جدا فعندي دائما الحل
+
+25
+00:02:16,220 --> 00:02:19,320
+في ال graphometric analysis بيطلب ان اقول ملي مول
+
+26
+00:02:19,320 --> 00:02:22,200
+من ال analyte ايش بيساوي من الملي مول من ال
+
+27
+00:02:22,200 --> 00:02:27,420
+precipitate فأقول ملي مول MN2O3 بيساوي طبيعي 3 على
+
+28
+00:02:27,420 --> 00:02:30,180
+2 ملي مول MN3O4
+
+29
+00:02:32,530 --> 00:02:37,810
+مدام كوّنت المعادلة فقط ان اعوض من ملي مول بالملي
+
+30
+00:02:37,810 --> 00:02:40,930
+جرام على ال formula weight او موليراتيوبوليوم وانا
+
+31
+00:02:40,930 --> 00:02:44,650
+طبعا ماعندي موليراتيوبوليوم فبعوض عنه بالملي جرام
+
+32
+00:02:44,650 --> 00:02:49,230
+على ال formula weight لل analyte والملي جرام على
+
+33
+00:02:49,230 --> 00:02:53,610
+ال formula weight لل precipitate الملي جراموال
+
+34
+00:02:53,610 --> 00:02:58,370
+formula weight لل precipitates معروفين وال formula
+
+35
+00:02:58,370 --> 00:03:03,050
+weight لل analyte ايضا معروفة اذا فش عندي لغير ال
+
+36
+00:03:03,050 --> 00:03:07,150
+milligram analyte هو المجهول معناه الكلام بطلعه
+
+37
+00:03:07,150 --> 00:03:12,370
+بسهولة و ال percentage بحسبها قسمة وزنة ال analyte
+
+38
+00:03:12,370 --> 00:03:16,040
+على وزنة العينة في مية من ميةنفس الكلام لو كان
+
+39
+00:03:16,040 --> 00:03:19,240
+عندي او المطلوب التاني لما يكون عندي مانجانيز فقط
+
+40
+00:03:19,240 --> 00:03:24,940
+ما اطلع المانجانيز هي الانالايت هان في عندي ال
+
+41
+00:03:24,940 --> 00:03:27,820
+precipitate فعندي تلاتة مانجانيز هان مانجانيز
+
+42
+00:03:27,820 --> 00:03:31,020
+واحدة اذا بده احط هان تلاتة يبقى الميلي مول
+
+43
+00:03:31,020 --> 00:03:35,080
+مانجانيز اللي هو الانالايت بده يساوي ايش من ال من
+
+44
+00:03:35,080 --> 00:03:38,020
+الميلي موز ال precipitate طبعا تلت اضعاف الميلي
+
+45
+00:03:38,020 --> 00:03:42,240
+مول ال precipitateهان بتبعوض بنفس الصيغة ملي جرام
+
+46
+00:03:42,240 --> 00:03:44,220
+على الفورمولوية، هان برضه ملي جرام على
+
+47
+00:03:44,220 --> 00:03:47,200
+الفورمولوية، ملي جرام ال precipitate والفورمولوية
+
+48
+00:03:47,200 --> 00:03:51,000
+معروفين، ال atomic weight المنجانيز معروف، معناه
+
+49
+00:03:51,000 --> 00:03:54,640
+كله مافيش عنده مجهول إلا الملي جرام منجانيز، بجيبه
+
+50
+00:03:54,640 --> 00:03:57,800
+برضه بجسمه على وزنة العينة في الميلي امبير بيعطيين
+
+51
+00:03:57,800 --> 00:04:03,920
+ال percentageفي بعض الأحيان زي ما ذكرت ممكن إنه
+
+52
+00:04:03,920 --> 00:04:09,720
+يكون في عندي أسئلة افتراضية وإن كنا في هذا الفصل
+
+53
+00:04:09,720 --> 00:04:16,180
+مش حابين إنه نتطرق لأسئلة افتراضية كتيرة أو إنه
+
+54
+00:04:16,180 --> 00:04:20,120
+نحاول نضيع وجتنا في حلها لكن أيضا حل أي سؤال
+
+55
+00:04:20,120 --> 00:04:24,400
+افتراضيبيرجع لاستخدام مفهوم الـ millimole مافيش
+
+56
+00:04:24,400 --> 00:04:27,340
+حاجة غير هي الـ gravimetric analysis يعني او
+
+57
+00:04:27,340 --> 00:04:29,560
+stoichiometric analysis stoichiometric
+
+58
+00:04:29,560 --> 00:04:33,340
+calculations معناتها فقط الملي مولو منها بده ينبثق
+
+59
+00:04:33,340 --> 00:04:37,520
+الحل فنتطلع علي هذا المثال بيقول what weight of
+
+60
+00:04:37,520 --> 00:04:41,560
+sulfur ore which should be taken so that the
+
+61
+00:04:41,560 --> 00:04:45,220
+weight of barium sulfate precipitated will be
+
+62
+00:04:45,220 --> 00:04:48,600
+equal to half the percentage of sulfur in the
+
+63
+00:04:48,600 --> 00:04:57,340
+sampleفي عنا sample ore او عينة من ال sulphur بدنا
+
+64
+00:04:57,340 --> 00:05:02,600
+ناخد وزن معين من هذا ال ore بحيث انه وزن الراسب
+
+65
+00:05:02,600 --> 00:05:06,780
+تساوي نص ال percentage sulphur في العينةبدنا ناخد
+
+66
+00:05:06,780 --> 00:05:13,040
+وزنة من العينات بحيث انه وزنة الراسب تكون نص ال
+
+67
+00:05:13,040 --> 00:05:15,840
+percent of sulfur مش بعطيني بيانات مش بعطيني جداش
+
+68
+00:05:15,840 --> 00:05:20,440
+حتى ال percent of sulfur مثلا يعني فإيش بدي أعمل
+
+69
+00:05:20,440 --> 00:05:26,130
+في حالة زي هذه إيش بدي أعمل في حالة زي هذهبقول نفس
+
+70
+00:05:26,130 --> 00:05:28,870
+الكلام فش عندي مفارقة إلا إن أستخدم ال millimole
+
+71
+00:05:28,870 --> 00:05:33,470
+إذا كان بدي أوصل للنتيجة فبقول والله ال millimole
+
+72
+00:05:33,470 --> 00:05:37,010
+sulfur أنا عندي ال sulfur بتحول البريام صار في هاي
+
+73
+00:05:37,010 --> 00:05:41,670
+التفاعل اللي عندي في هاي ال analyteوهي الـ
+
+74
+00:05:41,670 --> 00:05:45,550
+precipitate الـ S1 و الـ S1 معنى الكلام الـ
+
+75
+00:05:45,550 --> 00:05:47,830
+millimole sulfur تساوي millimole barium sulfate
+
+76
+00:05:47,830 --> 00:05:50,570
+لأن انت بي .. مافيش برضه قدام خيارات و ال
+
+77
+00:05:50,570 --> 00:05:53,670
+millimole بدي اعوض عنها باحد حاجتين يا milligram
+
+78
+00:05:53,670 --> 00:05:55,590
+على ال formula weight يا اما molarity of volume
+
+79
+00:05:55,590 --> 00:05:58,990
+طبعا بدي اعوض عنها milligram على ال formula weight
+
+80
+00:05:58,990 --> 00:06:02,190
+لأنه مافيش عند molarity of volume فبقول millimole
+
+81
+00:06:02,190 --> 00:06:05,400
+sulfur بتساوي millimole barium sulfate يعنيملي
+
+82
+00:06:05,400 --> 00:06:08,560
+جرام سلفر ع ال atomic weight سلفر تسوى ملي جرام
+
+83
+00:06:08,560 --> 00:06:10,920
+باريام صلفية ع ال formula weight باريام صلفية
+
+84
+00:06:14,370 --> 00:06:17,750
+أي معلومات عن الـ milligram barium sulphate إلا
+
+85
+00:06:17,750 --> 00:06:20,510
+المعلومات اللي أتهلى قال لي إن وزن الـ barium
+
+86
+00:06:20,510 --> 00:06:23,510
+sulphate تساوي نص ال percentage sulfur باعود عنها
+
+87
+00:06:23,510 --> 00:06:27,410
+زي ما قال لي نص percentage sulfur هاي اللي جدامي
+
+88
+00:06:27,410 --> 00:06:32,150
+ماعطانيش قيمة فبقول إذا ال milligram sulfur بدي
+
+89
+00:06:32,150 --> 00:06:34,850
+ساوي ال atomic weight ل ال sulfur كام تحيطها لو
+
+90
+00:06:34,850 --> 00:06:39,750
+حطيته 32 مثلاالـ milligram barium sulphate نُص
+
+91
+00:06:39,750 --> 00:06:43,850
+percentage sulphur على ال formula weight للـ
+
+92
+00:06:43,850 --> 00:06:46,110
+barium sulphate، هذا هو عبارة عن الـ milligram
+
+93
+00:06:46,110 --> 00:06:48,750
+sulphur، بطلع هذه القيمة مضروبة في ال percentage
+
+94
+00:06:48,750 --> 00:06:53,140
+sulphurحلو كثير الان انا بدى اقول طب من ال
+
+95
+00:06:53,140 --> 00:06:55,520
+percentage percentage sulfur تسمى ال milligram
+
+96
+00:06:55,520 --> 00:06:59,140
+sulfur او ال milligram sample في 100 من 100 خلينا
+
+97
+00:06:59,140 --> 00:07:02,560
+نعوض عن ال milligram sulfur بهذه القيمة اللى حصلت
+
+98
+00:07:02,560 --> 00:07:07,560
+عليها من ال stoichiometry فبعوض عنها على ال
+
+99
+00:07:07,560 --> 00:07:10,940
+milligram sample مجهولة في 100 من 100 بلاحظ ان ال
+
+100
+00:07:10,940 --> 00:07:15,120
+percentage sulfur مع ال percentage sulfurبيروح و
+
+101
+00:07:15,120 --> 00:07:20,000
+خلصت منها كانت يعني مجهولة وهيها راحت الانفش ايندي
+
+102
+00:07:20,000 --> 00:07:23,200
+الا غير بس مجهول واحد هو ال milligram ال sample
+
+103
+00:07:23,200 --> 00:07:29,120
+بتطلع عندي 6.869 milligram يعني مع انه المسألة
+
+104
+00:07:29,120 --> 00:07:34,040
+كانت تبدو لنا انه و كأنها يعني اه صعبة و كيف بدنا
+
+105
+00:07:34,040 --> 00:07:38,100
+نحلها لكن انت استخدم فقط هالمفهوم الوحيد اللي
+
+106
+00:07:38,100 --> 00:07:43,100
+اتعلمناه اللي هو مفهوم ال millimole ال factor اللي
+
+107
+00:07:43,100 --> 00:07:48,140
+هيكون موجودطيب خلينا نتطلع على مسألة تانية و أحاول
+
+108
+00:07:48,140 --> 00:07:52,000
+أني أفرجيك كيف بتنحل أكتر من أني أحل هلك بالتفصيل،
+
+109
+00:07:52,000 --> 00:07:55,980
+مابناش نضيع وجد، فلكن طريقة الحل كتير كتير كتير
+
+110
+00:07:55,980 --> 00:07:59,260
+بسيطة، سهلة خالص، فنتطلع على المسألة التالية،
+
+111
+00:07:59,260 --> 00:08:03,380
+بتقول a mixture containing only iron chloride
+
+112
+00:08:04,560 --> 00:08:09,500
+الفورمولا وياته 162 والألومناميكلورايد الفورمولا
+
+113
+00:08:09,500 --> 00:08:16,320
+وياته 133 و 5.95 يعني في عندي خليط يحتوي على
+
+114
+00:08:16,320 --> 00:08:20,440
+الايرونيكلورايد والألومناميكلورايد جداش وزنتهم مع
+
+115
+00:08:20,440 --> 00:08:25,630
+بعض5.95 يعني المعادلة الأولى اجرام ايرون اكلورايد
+
+116
+00:08:25,630 --> 00:08:29,410
+زائد اجرام ألوملم اكلورايد ايش بتساوي 5.95 هيك هو
+
+117
+00:08:29,410 --> 00:08:33,830
+معطيني طيب كويس نكمل المثلة بيقول that the
+
+118
+00:08:33,830 --> 00:08:37,690
+chlorides are converted to hydroxides حولنا
+
+119
+00:08:37,690 --> 00:08:42,530
+الاخلورايد للهيدروكسايدبعدين and ignited وحرجناهم
+
+120
+00:08:42,530 --> 00:08:48,330
+فاتحولوا لل iron 2O3 و ال aluminum 2O3 بحيث انه
+
+121
+00:08:48,330 --> 00:08:54,950
+وزنة ال oxide mixture كانت 2.62 يعني وزنة ال Fe2O3
+
+122
+00:08:54,950 --> 00:09:01,090
+و ال aluminum 2O3 2.62 هذه المعلومات اللي عندى
+
+123
+00:09:01,090 --> 00:09:05,470
+بقول اوجد ال percentage iron و ال percentage
+
+124
+00:09:06,410 --> 00:09:11,370
+الومينام انا بقول الحل كتير كتير كتير بسيط هو ايش
+
+125
+00:09:11,370 --> 00:09:17,630
+اللي بده ياه ايش اللي مطلوب يعني ماعنى الكلام بده
+
+126
+00:09:17,630 --> 00:09:22,730
+جيب جدش وزنة ال iron ووزنة ال ايه يعني بده احول
+
+127
+00:09:22,730 --> 00:09:31,390
+هذا ل gram iron او في الاول بده احوله ل mole iron
+
+128
+00:09:31,390 --> 00:09:36,550
+و ال mole iron بده احوله ل gram iron حلووهنا نفس
+
+129
+00:09:36,550 --> 00:09:39,890
+الكلام هذا بتحول لمول ألومنام والمول ألومنام بتحول
+
+130
+00:09:39,890 --> 00:09:44,050
+لجرام ألومنام صارت المعادلة الأولى عبارة عن ايش
+
+131
+00:09:44,050 --> 00:09:49,630
+جرام ايرون وجرام ألومنام مجموعهم 5.95 بعدين هذا
+
+132
+00:09:49,630 --> 00:09:54,790
+برضه بده حوله لمول ايرون وبعدين لمول ايرون بده
+
+133
+00:09:54,790 --> 00:10:00,310
+حوله لجرام ايرونإذا المعادلة تانية صارت gram-iron
+
+134
+00:10:00,310 --> 00:10:04,950
+طب و ال aluminum oxide برضه بده يحول لمol aluminum
+
+135
+00:10:04,950 --> 00:10:08,330
+بعدين لمol aluminum يحول ل gram aluminum معنى
+
+136
+00:10:08,330 --> 00:10:13,110
+الكلام نفس الصيغة هحاول أن أحصل على معادلة فيها x
+
+137
+00:10:13,110 --> 00:10:18,310
+gram iron و y gram aluminum بتساوي هالجد و x gram
+
+138
+00:10:18,310 --> 00:10:22,370
+iron و y gram aluminum بتساوي هالجد إذا معادلتين
+
+139
+00:10:22,370 --> 00:10:26,910
+في المجهولينطيب كيف بدى احول ل gram iron chloride
+
+140
+00:10:26,910 --> 00:10:33,050
+ل mole iron بقول والله من المعادلة على طول بقدر ال
+
+141
+00:10:33,050 --> 00:10:37,090
+Fe بتسوى FeCl تلاتة واحد لواحد اذا ال mole iron
+
+142
+00:10:37,090 --> 00:10:40,920
+بتسوى mole iron chlorideطب بتحولها لجرام بقول
+
+143
+00:10:40,920 --> 00:10:44,680
+اجرام ايرون على اتم كويت اجرام ايرون اكلورايد هي
+
+144
+00:10:44,680 --> 00:10:47,880
+اللي في المعادلة اللي اتكلمت لاحظت على ال formula
+
+145
+00:10:47,880 --> 00:10:50,620
+weight ايرون اكلورايد بجيب لجرام ايرون اكلورايد
+
+146
+00:10:50,620 --> 00:10:55,930
+بساوي جرام ايرون formula weightايرون اكلورايد
+
+147
+00:10:55,930 --> 00:10:59,630
+معروفة اتوميك ويت ايرون معروف اذا صار هذا رقم
+
+148
+00:10:59,630 --> 00:11:03,130
+مضروب في ايه في الجرام ايرون ده حولت ال ايرون
+
+149
+00:11:03,130 --> 00:11:10,510
+اكلورايد في المعادلة لجرام ايرون بنفس الكلام
+
+150
+00:11:10,510 --> 00:11:16,810
+بالظبط بقدر احول الجرام الومنام اكلورايد لجرام
+
+151
+00:11:16,810 --> 00:11:25,620
+الومناموبنفس الكلام تماما بقدر اقول بقدر اقول انه
+
+152
+00:11:25,620 --> 00:11:32,060
+ال iron 2O3 برضه بحولها ل gram iron عن طريق
+
+153
+00:11:32,060 --> 00:11:37,660
+المعادلة ال Fe2O3 بتعطيل 2Fe اذا الميلي مول ايرن
+
+154
+00:11:37,660 --> 00:11:43,820
+ضعف الميلي مول ايرن 2O3 بعدين بحول المول ل gram
+
+155
+00:11:43,820 --> 00:11:46,280
+على ال atomic weight او gram على ال formula weight
+
+156
+00:11:46,620 --> 00:11:51,180
+فبلاحظ انه حصلت على المعادلة التالية و قبلها كنت
+
+157
+00:11:51,180 --> 00:11:55,720
+حصلت على المعادلة الأولى معادلتين في مجهولين بقدر
+
+158
+00:11:55,720 --> 00:12:00,200
+أحلهم و أحصل على الناتج ال percentage ده القائلة
+
+159
+00:12:00,200 --> 00:12:06,380
+طبعا 18% و ال aluminum 9.8% ماشي يا شباب كمان مرة
+
+160
+00:12:06,380 --> 00:12:11,590
+مهما بدت المسألة يعني صعبة و متشعبةمافيش عندك
+
+161
+00:12:11,590 --> 00:12:15,450
+مفتاح حل الا الملي مول مافي عندك مفتاح حل الا
+
+162
+00:12:15,450 --> 00:12:26,370
+الملي مول طيب نطلع على مثال اخر المثال
+
+163
+00:12:26,370 --> 00:12:31,750
+كالتالي في عندي خليط من two metal sulfates في عندي
+
+164
+00:12:31,750 --> 00:12:36,270
+metal sulfate و metal اخر sulfate رسبت ال sulfate
+
+165
+00:12:36,270 --> 00:12:41,680
+على هيئة barium sulfateواحد من الـ metal ions اللي
+
+166
+00:12:41,680 --> 00:12:45,000
+بيكون الصلفات .. واحد من الـ metal ions لأحد
+
+167
+00:12:45,000 --> 00:12:51,600
+الصلفات مجهول M فبتعرف ال atomic weight تبعه نقرأ
+
+168
+00:12:51,600 --> 00:12:55,580
+المسألة و نحاول نفكر كيف ممكن يكون الحل we'll
+
+169
+00:12:55,580 --> 00:12:59,600
+consider a one gram sample يعني في عندي عينة جداش
+
+170
+00:12:59,600 --> 00:13:07,930
+وزنتها واحد gram containing75% بتاسيوم صلفية و 25%
+
+171
+00:13:07,930 --> 00:13:09,450
+متل صلفية
+
+172
+00:13:13,940 --> 00:13:19,960
+لما نقول 75% من 1 جرام يعني 0.75 جرام متل صلفات و
+
+173
+00:13:19,960 --> 00:13:24,220
+لما نقول 25% من 1 جرام متل صلفات يعني 0.25 جرام
+
+174
+00:13:24,220 --> 00:13:28,080
+متل صلفات بيقول the sample is dissolved دوّبنا
+
+175
+00:13:28,080 --> 00:13:31,060
+العيّنة اللي فيها الصلفات and the sulfate is
+
+176
+00:13:31,060 --> 00:13:34,580
+precipitated as barium sulfate رسبنا الصلفات كلها
+
+177
+00:13:34,580 --> 00:13:39,310
+على هيئة barium sulfateبقول لو كان if the barium
+
+178
+00:13:39,310 --> 00:13:46,330
+sulfate precipitate weighs 1.490 gram واطد
+
+179
+00:13:46,330 --> 00:13:50,790
+the atomic weight of the metal 2 plus in metal
+
+180
+00:13:50,790 --> 00:13:54,970
+sulfate؟ بيبدو ال atomic weightالحل يا شباب مافيش
+
+181
+00:13:54,970 --> 00:13:59,130
+أبسط من هيك انا بقول البوتاسيوم صلفية اتحولت
+
+182
+00:13:59,130 --> 00:14:03,690
+للباريوم صلفية صح؟ واحد لواحد لان فيها صلفية طيب و
+
+183
+00:14:03,690 --> 00:14:08,010
+الميتل صلفية اتحولت للباريوم صلفية واحد لواحد اذا
+
+184
+00:14:08,010 --> 00:14:12,210
+الملي مول من ال باريوم صلفية او المول من ال باريوم
+
+185
+00:14:12,210 --> 00:14:16,130
+صلفية اللي هو الصلفية اللي في ال باريوم صلفية مش
+
+186
+00:14:16,130 --> 00:14:19,190
+بتساويالمول من السلفات اللى فى ال potassium
+
+187
+00:14:19,190 --> 00:14:21,650
+sulfate زي المول من السلفات اللى فى ال metal
+
+188
+00:14:21,650 --> 00:14:25,710
+sulfate اذا الملي مول او المولز اللى اتكونت من
+
+189
+00:14:25,710 --> 00:14:30,590
+الراسب تساوى مجموع المولات من الاتنين ليه؟ لأنه كل
+
+190
+00:14:30,590 --> 00:14:34,950
+واحد اعطى جزء من ال barium sulfate فمقدر اقول انا
+
+191
+00:14:34,950 --> 00:14:39,190
+كتبها ملي مولز ومعوض بمولز مش مشكلة ملي مول barium
+
+192
+00:14:39,190 --> 00:14:42,270
+sulfate بتساوي ملي مول potassium sulfate زي ملي
+
+193
+00:14:42,270 --> 00:14:48,050
+مول metal sulfate برضه الآن الحل تبعى فقطان احول
+
+194
+00:14:48,050 --> 00:14:51,830
+ملي مول لإجراء اجراء انا بدأ استخدم هذه مول اكتبها
+
+195
+00:14:51,830 --> 00:14:56,630
+ملي مول لكن هي مول ف one point four nine gram على
+
+196
+00:14:56,630 --> 00:15:00,750
+ال formula weight بتساوي هذه وزنتها point seven
+
+197
+00:15:00,750 --> 00:15:04,450
+five gram على ال formula weight هذه وزنتها point
+
+198
+00:15:04,450 --> 00:15:06,730
+two five على ال formula weight ال formula weight
+
+199
+00:15:06,730 --> 00:15:13,490
+متل صلفة المتل X والصلفات ستة وتسعينفلو جيت طلعت
+
+200
+00:15:13,490 --> 00:15:16,570
+أنا هذا كله ال X زائد 96 هو ال formula weight
+
+201
+00:15:16,570 --> 00:15:20,950
+للميتل صلفيت لكن ال X هو ال atomic weight للميتل
+
+202
+00:15:20,950 --> 00:15:25,190
+فلو جيت طلعت هذه معادلة بمجهول واحد ال X ع طول
+
+203
+00:15:25,190 --> 00:15:29,950
+بتطلع عندي 24 و شوية يعني بمعنى أخر الميتل اللي
+
+204
+00:15:29,950 --> 00:15:33,770
+عندي هو الماجنيزيوم يعني عندي ماجنيزيوم صلفيت و
+
+205
+00:15:33,770 --> 00:15:39,450
+بوتاسيوم صلفيت فال .. لأنه طلع ال atomic weight 24
+
+206
+00:15:39,450 --> 00:15:45,650
+24 هو الماجنيزيومفعندي ميجنيزيوم صلفيت مخلوط مع
+
+207
+00:15:45,650 --> 00:15:50,790
+البوتاسيوم صلفيت طب
+
+208
+00:15:50,790 --> 00:15:55,110
+كمان سؤال سؤال برضه كتير كويس بيقول ايه mixture of
+
+209
+00:15:55,110 --> 00:16:01,210
+mercurous chloride and mercurous bromide weighs
+
+210
+00:16:01,210 --> 00:16:05,990
+two grams يعني وزنة ال mixture الاتنين مع بعض
+
+211
+00:16:05,990 --> 00:16:10,810
+وزنتهم جداش يعني لو واحد وزنته x التاني جداش وزنته
+
+212
+00:16:12,560 --> 00:16:17,140
+صحيح لو واحد وزن 2x ايش التاني بيكون؟ اتنين ناقص x
+
+213
+00:16:17,140 --> 00:16:21,300
+طيب بيقول the mixture is quantitatively reduced
+
+214
+00:16:21,300 --> 00:16:27,740
+يعني كله اختزلنا to mercury metal كله حولنا ل
+
+215
+00:16:27,740 --> 00:16:33,810
+mercury metalwhich was 1.5 gram يعني وزن المركوري
+
+216
+00:16:33,810 --> 00:16:39,030
+اللي حصلنا عليها من المخلوط لما اختزلناه كانت واحد
+
+217
+00:16:39,030 --> 00:16:41,950
+و نص جرام بيقول احسب ال percentage mercuracy
+
+218
+00:16:41,950 --> 00:16:45,830
+chloride و ال percentage mercurous ابرة و ميه كمان
+
+219
+00:16:45,830 --> 00:16:49,830
+مرة بقول mercuracy chloride اتحول ل mercury هنا في
+
+220
+00:16:49,830 --> 00:16:53,640
+عندى تنتين mercury ايش ده تعطينيتنين وهي نفس
+
+221
+00:16:53,640 --> 00:16:57,240
+الكلام مركز البرومية تعطيني ايه؟ برضه تنين حلو
+
+222
+00:16:57,240 --> 00:17:01,680
+كتير حلو كتير معنى الكلام بجل ال millimoles ال
+
+223
+00:17:01,680 --> 00:17:06,400
+millimoles من ال mercury اللي اتكون هذا بيساوي ضعف
+
+224
+00:17:06,400 --> 00:17:10,900
+هذا و هذا بيساوي ضعف هذا ال millimoles الكل بيساوي
+
+225
+00:17:10,900 --> 00:17:15,490
+ضعف هذا زائد ضعف هذا مش هيك كمان هذا هيبنقول ملي
+
+226
+00:17:15,490 --> 00:17:20,090
+مول ميركوري اللي اتكوّن بساوي ضعف الملي مول
+
+227
+00:17:20,090 --> 00:17:24,950
+ميركوراس كلورايد زائد ضعف الملي مول من الميركوراس
+
+228
+00:17:24,950 --> 00:17:29,390
+برومايد الان برضه نفس الكلمة ماعوض ملي مول لكن انا
+
+229
+00:17:29,390 --> 00:17:33,670
+هان مستخدم القياسات بالمول واحد و نص جرام على ال
+
+230
+00:17:33,670 --> 00:17:37,110
+formula weight او ال atomic weight للميركوري هد هي
+
+231
+00:17:37,110 --> 00:17:41,630
+الملي مول او المول بالنسبة لناالاتنين هي هذه
+
+232
+00:17:41,630 --> 00:17:44,930
+الاتنين هي الـ stoichiometric factor هذه الاتنين X
+
+233
+00:17:44,930 --> 00:17:48,710
+هي وزنة المركوراس الكلوريد على ال formula weight
+
+234
+00:17:48,710 --> 00:17:55,850
+لمركوراس الكلوريد طيب الاتنين هي وزنة المركوراس
+
+235
+00:17:55,850 --> 00:17:59,830
+بروميد إذا كان هذه وزنتها X فهذه اتنين ناقص X على
+
+236
+00:17:59,830 --> 00:18:03,740
+ال formula weight لمركوراس بروميدمعاهدة اللى بتطلع
+
+237
+00:18:03,740 --> 00:18:08,020
+فيها بلاجة بس مجهول واحد بتنحل على طول ال X بتطلع
+
+238
+00:18:08,020 --> 00:18:11,880
+point five one eight two grams اذا وزنة ال mercury
+
+239
+00:18:11,880 --> 00:18:20,660
+cycloride0.5182 جرام لو جسمتها على وزنة العينة
+
+240
+00:18:20,660 --> 00:18:27,580
+اللى هى 2 في 100 من 100 وزنة العينة اه اتنين في
+
+241
+00:18:27,580 --> 00:18:31,900
+100 من 100 بتطلع ان جداش عندي وزنه من ال mercury
+
+242
+00:18:31,900 --> 00:18:35,950
+chloride جداش percentage من ال mercury chlorideولو
+
+243
+00:18:35,950 --> 00:18:41,890
+حسبت 2 ناقص x يعني 2 ناقص 0.5182 فعندي قيمة بجسمها
+
+244
+00:18:41,890 --> 00:18:46,110
+برضه على 2 في 100 من 100 بتعطيني ال percentage
+
+245
+00:18:46,110 --> 00:18:52,130
+mercurous bromide كمان مرة استخدام مفهوم الملي مول
+
+246
+00:18:52,130 --> 00:18:57,890
+كتير كتير بيبسط حل المسائل نيجي لمسألةخلّيني أقول
+
+247
+00:18:57,890 --> 00:19:02,330
+أخيرة معنى في هذا ال chapter أو في هذا الجزء من ال
+
+248
+00:19:02,330 --> 00:19:04,810
+chapter اللي هو ال graphometric analysis ومسألة
+
+249
+00:19:04,810 --> 00:19:08,250
+كتير كتير جميلة يعنى كتير حلوة صحيح يعنى فبنقول
+
+250
+00:19:08,250 --> 00:19:11,790
+فيها إيه في عندي عشرة solution containing chloride
+
+251
+00:19:11,790 --> 00:19:15,590
+was treated with excess silver nitrate حاطين عليها
+
+252
+00:19:15,590 --> 00:19:18,770
+excess silver nitrate على طول بتكون عندنا agcl
+
+253
+00:19:18,770 --> 00:19:25,400
+trustable agcl جداش وزنته0.43680 grams of AgCl
+
+254
+00:19:25,400 --> 00:19:28,740
+يبقى الكلورايد اللى اترسب على هيئة AgCl اللى
+
+255
+00:19:28,740 --> 00:19:35,380
+اعطانى AgCl وزنتها 0.43680 grams من ال AgCl عايز
+
+256
+00:19:35,380 --> 00:19:39,560
+يعرف قداش تركيز الكلورايد هذه مسألة كتير جميلة
+
+257
+00:19:39,560 --> 00:19:44,240
+لأنه ممكن تستخدم فعليا يعني تجريبيا في تعيين تركيز
+
+258
+00:19:44,240 --> 00:19:50,410
+الكلورايدفبننصب على هيئة AGC اللى بعدين بنقول
+
+259
+00:19:50,410 --> 00:19:54,430
+والله الملي مول اكلورايد بتساوي الملي مول AGC اللى
+
+260
+00:19:54,430 --> 00:19:58,690
+انا بتفعله بالنسبة واحد لواحد مش هيكطيب نشوف ال
+
+261
+00:19:58,690 --> 00:20:03,730
+millimol agcl عبارة عن ال milligram على ال formula
+
+262
+00:20:03,730 --> 00:20:07,010
+و هي بتعطيني ال millimol agcl ايه اللي بتساوي؟
+
+263
+00:20:07,010 --> 00:20:10,230
+millimol الكلورايد فبما دام عندي ال millimol
+
+264
+00:20:10,230 --> 00:20:14,050
+الكلورايد و عندي حجم الكلورايد millimol على ال
+
+265
+00:20:14,050 --> 00:20:18,510
+milliliter هذه هي ال ايه؟ ال molarity exam التركيز
+
+266
+00:20:18,510 --> 00:20:21,570
+هو عبارة عن ال millimol على ال milliliter بيعطيني
+
+267
+00:20:21,570 --> 00:20:26,890
+point3, 0, 4, 8, molar .. مسألة كتير كتير جميلة
+
+268
+00:20:26,890 --> 00:20:31,370
+وسهلة وكويس اللي بدأ أقوله يا شباب من مجمل هذه
+
+269
+00:20:31,370 --> 00:20:37,090
+الأمثلة أنه أي سؤال في ال graphometric analysis
+
+270
+00:20:37,090 --> 00:20:44,870
+يعني هيكون سهل جدا لا يجوز أنه نغلق فيه أهم حاجة
+
+271
+00:20:44,870 --> 00:20:48,030
+أنك تقدر تعبر عن ال stoichiometric factor بشكل
+
+272
+00:20:48,030 --> 00:20:52,300
+صحيحأهم شيء تقدر تتعبر عن ال Stoichiometric factor
+
+273
+00:20:52,300 --> 00:20:57,540
+نسبة الملاتب بشكل صحيح خاصة أنه احنا درسنا chapter
+
+274
+00:20:57,540 --> 00:21:01,100
+كامل في ال Stoichiometric calculations و أخدنا
+
+275
+00:21:01,100 --> 00:21:04,000
+يعني معادلات إلى حد ما يعني حتى لو كانت معادلات
+
+276
+00:21:04,000 --> 00:21:08,910
+معقدة كنا بنقدر نطلع ال Stoichiometricfactor فيرجو
+
+277
+00:21:08,910 --> 00:21:12,330
+انك اتركز دائما انك تطلع ال Stoichiometric factor
+
+278
+00:21:12,330 --> 00:21:16,410
+بشكل صحيح لان اذا كان طلعته بشكل صحيح بجيت الحل
+
+279
+00:21:16,410 --> 00:21:21,730
+يعني ما يعني لا يستدعي مطلقا ان واحد يخطئ في الحل
+
+280
+00:21:21,730 --> 00:21:24,690
+ليه؟ لأنه بدك تأوض عن ال milli mole بعد ما تجيبها
+
+281
+00:21:24,690 --> 00:21:27,290
+بس milligram على ال formula weight او مثلا
+
+282
+00:21:27,290 --> 00:21:30,030
+modality of volume وهذا نادر في ال gravimetric
+
+283
+00:21:30,030 --> 00:21:36,070
+analysis الآن خلّيني ننتقل لموضوع تاني بدنا نتكلم
+
+284
+00:21:36,070 --> 00:21:40,600
+فيه عنالـ precipitation equilibria الـ
+
+285
+00:21:40,600 --> 00:21:45,420
+precipitation equilibria في الحقيقة الـ
+
+286
+00:21:45,420 --> 00:21:49,660
+precipitation equilibria هي عبارة عن الاتزانات
+
+287
+00:21:49,660 --> 00:21:56,620
+اللي بتحصل في وجود رواسب في المحليل رواسب يعني في
+
+288
+00:21:56,620 --> 00:22:02,300
+عيني محلول يحتوي على راسب موجود في حالة اتزان مع
+
+289
+00:22:02,300 --> 00:22:07,840
+ايوناتهراسب موجود في حالة اتزان مع قيوناته يعني
+
+290
+00:22:07,840 --> 00:22:15,620
+مثلا عندي ال AGCL هذا ال AGCL عبارة عن مادة شححت
+
+291
+00:22:15,620 --> 00:22:18,880
+الذوبان في الميه لو تركناها في الميه فترة زمنية
+
+292
+00:22:18,880 --> 00:22:21,580
+طويلة لغاية ما حصل اتزان
+
+293
+00:22:24,110 --> 00:22:27,830
+كويس و طبعا كان في عندي كمية من الراصب لازالت
+
+294
+00:22:27,830 --> 00:22:30,790
+موجودة وهيك احنا بندرس عادة ال precipitation
+
+295
+00:22:30,790 --> 00:22:35,210
+equilibrium في وجود الراصب و ايضا في وجود ايوناته
+
+296
+00:22:35,210 --> 00:22:38,510
+يعني لازم يكون في عندي كمية من الراصب متوفرة
+
+297
+00:22:38,510 --> 00:22:46,490
+وموجودة في المحلول فعندها ممكن اقول والله ال A,G,C
+
+298
+00:22:46,490 --> 00:22:51,900
+,L عندما يحصل اتزانممكن اقول انه ممكن نكتب ال
+
+299
+00:22:51,900 --> 00:22:58,220
+equilibrium constant ال K ال K جالب تساوي ال AG
+
+300
+00:22:58,220 --> 00:23:05,680
+plus في ال CL minus على ال AGCL الصالد لكن ال AGCL
+
+301
+00:23:05,680 --> 00:23:10,990
+الصالد دائما تركيزه ثابتبمعنى إنه لما نكون فيه
+
+302
+00:23:10,990 --> 00:23:15,210
+عندك كمية من الصليد تركيزها لا يتغير إذا كان والله
+
+303
+00:23:15,210 --> 00:23:19,710
+جزء يسير منها حصله دوبان ليه؟ لأن احنا بنتكلم عن
+
+304
+00:23:19,710 --> 00:23:25,010
+precipitation equilibria بمعنى إنه في عند محالي ..
+
+305
+00:23:25,010 --> 00:23:29,350
+في عند رواسب شحيحة الدوبان في المياه في الواقع جدا
+
+306
+00:23:29,350 --> 00:23:34,850
+يعنيفبالتالي دائما بنعتبر احنا انه تركيز المادة
+
+307
+00:23:34,850 --> 00:23:39,570
+النقية سواء كانت صلب زي الحال اللي بنتكلم عنها او
+
+308
+00:23:39,570 --> 00:23:44,480
+كانت سائل زي الميهتركيز المواد النقية في ال
+
+309
+00:23:44,480 --> 00:23:49,460
+equilibrium بنعتبرها تركيزات ثابتة solvent مثلا
+
+310
+00:23:49,460 --> 00:23:53,440
+مادة نقية بنعتبره تركيزه ثابت يعني مثلا لو ماتيش
+
+311
+00:23:53,440 --> 00:23:57,680
+تتكلم عن الميه و الله بتتفكك جزئيا فبتقول اه و
+
+312
+00:23:57,680 --> 00:24:02,140
+الله بتتفكك طب جداش مثلا الميه بتتفكك ال H plus و
+
+313
+00:24:02,140 --> 00:24:04,620
+ال hydroxide يبقى ال H plus في ال hydroxide على
+
+314
+00:24:04,620 --> 00:24:08,180
+تركيز الميه طب جداش تركيز الميه احنا بنعتبره ثابت
+
+315
+00:24:08,180 --> 00:24:12,620
+وهنا كمان تركيز ال solid عادة بنعتبرهثابت فلو
+
+316
+00:24:12,620 --> 00:24:16,900
+اعتبرناه ثابت فهذا ثابت وهذا equilibrium constant
+
+317
+00:24:16,900 --> 00:24:21,560
+ثابت معنى الكلام ثابت في ثابت بيعطينا ثابت جديد
+
+318
+00:24:21,560 --> 00:24:28,560
+بنسميه Ksp ال Ksp هذا بنقوله solubility product
+
+319
+00:24:28,560 --> 00:24:35,090
+solubility productعاموما يا شباب لازم نعرف ان حالة
+
+320
+00:24:35,090 --> 00:24:40,010
+الاتزان هي حالة ديناميكية بمعنى انه لما يكون في
+
+321
+00:24:40,010 --> 00:24:44,950
+عندي AgCl Solid ويتفكك جزءيا للـ Ag Plus والـ Cl
+
+322
+00:24:44,950 --> 00:24:49,330
+Minus بنقول هو بيستمر في التفكك إلى أن يصل إلى
+
+323
+00:24:49,330 --> 00:24:58,570
+درجة مابحيث ان معدل تفكك ال agcl يساوي معدل تكون
+
+324
+00:24:58,570 --> 00:25:03,930
+ال agcl ماذا يتكون من ال ag plus وال c ال minus هي
+
+325
+00:25:03,930 --> 00:25:07,310
+ال ag plus وال c ال minus هدول بيكونوا agcl وال
+
+326
+00:25:07,310 --> 00:25:11,390
+agcl بتفكك لل ag plus وال c ال minus هدول معدل
+
+327
+00:25:12,060 --> 00:25:16,600
+التفكك يساوي معدل التكون فهذا اسمه equilibrium او
+
+328
+00:25:16,600 --> 00:25:20,640
+اتزان يعني احنا في الواقع لما يكون في عند راسب
+
+329
+00:25:20,640 --> 00:25:26,540
+ونحطه في الميه ما يعني .. يعني مابيحصلش ان الراسب
+
+330
+00:25:26,540 --> 00:25:31,500
+يتفكك لغاية ما يصل لوقت معين ثم يتوقف مافيش حزب ان
+
+331
+00:25:31,500 --> 00:25:37,160
+يتوقف لأ هو بيضل يتفكك لكن معدل التفكك يساوي معدل
+
+332
+00:25:37,160 --> 00:25:41,040
+التكون فبيكون في عنده نوع من الاتزان هذا بنقوله
+
+333
+00:25:41,040 --> 00:25:46,970
+dynamicequilibrium على أي حال ال ksp يا شباب بدها
+
+334
+00:25:46,970 --> 00:25:50,330
+تساوي ال ag plus في ال c ال minus في هذه الحالة
+
+335
+00:25:50,330 --> 00:25:57,830
+طيب في عندي تلت أحوال ل ال ksp عندي تلت أحوال ل ال
+
+336
+00:25:57,830 --> 00:26:06,490
+ksp أول حالة منهم قال والله إذا كان حاصل ضرب ال ag
+
+337
+00:26:06,490 --> 00:26:12,490
+plus في ال c ال minus أقل من قيمة ال kspحاصل ضرب
+
+338
+00:26:12,490 --> 00:26:18,270
+تركيز السلفر في تركيز لكلورايد أقل من ال Ksp في
+
+339
+00:26:18,270 --> 00:26:22,270
+هذه الحالة يا شباب بيكون فش عندى اي راسب بيكون
+
+340
+00:26:22,270 --> 00:26:26,270
+المحلول clear هي عضر عن ايونات متناثرة في المحلول
+
+341
+00:26:26,270 --> 00:26:31,410
+مش متجمعة نهائياأيونات متناثرة في المحلول موجودة
+
+342
+00:26:31,410 --> 00:26:38,470
+نعم لكن لا تكون راسم مطلقا فمحلول clear صافي
+
+343
+00:26:38,470 --> 00:26:42,550
+ماعندي اي راسم فهذا لما يكون ال ag plus تركيزه في
+
+344
+00:26:42,550 --> 00:26:49,170
+ال c ال minus تركيزه اقل من ال ksp في عندي حالة
+
+345
+00:26:49,170 --> 00:26:54,880
+تانية ممكن نواجهها لما يكون ال ag plusتركيز الـ Ag
+
+346
+00:26:54,880 --> 00:26:59,280
+Plus في تركيز الـ Cl-, سوى تماما الـ Ksp، بنقول
+
+347
+00:26:59,280 --> 00:27:03,420
+كمان هان في الحقيقة مش عند راسه، لكن هذا يعتبر
+
+348
+00:27:03,420 --> 00:27:09,300
+محلول مشبع، بحيث أنه لو أضافنا أيون واحد من
+
+349
+00:27:09,300 --> 00:27:12,120
+الchlorida أو أيون واحد من ال silver الزيادة،
+
+350
+00:27:12,120 --> 00:27:16,790
+بيحصل عند راسه،بيحصل عند راسب لكن بدنا ناخد بالنا
+
+351
+00:27:16,790 --> 00:27:21,550
+الراسب اللى بيحصل مش انه كله الايونات بتترثب لأ
+
+352
+00:27:21,550 --> 00:27:27,190
+فقط لزيادة عن ال Ksp هي اللى بتترثب اما حاصل ضرب
+
+353
+00:27:27,190 --> 00:27:31,390
+التركيز ال silver بالchloride في المحلول لازم
+
+354
+00:27:31,390 --> 00:27:34,410
+دائما يساوي ال Ksp اذا كان عنده جزء من ال solid
+
+355
+00:27:34,410 --> 00:27:38,830
+اذا كان عنده راسب فلازم دائما يساوي ال Ksp وهذه
+
+356
+00:27:38,830 --> 00:27:43,800
+الحالة اللى احنا بندرسهابنقول والله إيش بحصل لو
+
+357
+00:27:43,800 --> 00:27:48,940
+كان حاصل ضرب ال silver بالchloride أكبر من ال Ksp
+
+358
+00:27:48,940 --> 00:27:55,440
+بنقول في هذه الحالة طبعا بحصل على راسب لكن مش كل
+
+359
+00:27:55,440 --> 00:27:58,580
+أيونات ال silver كمان مرة ومش كل أيونات ال
+
+360
+00:27:58,580 --> 00:28:04,090
+chloride بتترسب لأالزيادة عن ال Ksp هو اللي بترسب
+
+361
+00:28:04,090 --> 00:28:08,070
+لكن دائما حاصل ضرب تركيز ال silver اللي هو في
+
+362
+00:28:08,070 --> 00:28:11,670
+المحلول يعني في تركيز ال chloride لازم يساوي ال
+
+363
+00:28:11,670 --> 00:28:16,410
+Ksp مدام في عنده راسب مدام في عنده راسب لازم حاصل
+
+364
+00:28:16,410 --> 00:28:21,050
+ضرب تركيز ال silver في تركيز ال chloride يكون عنده
+
+365
+00:28:21,050 --> 00:28:25,970
+بساوي ال Ksp إذا زاد عن ال Ksp الزيادة هي اللي
+
+366
+00:28:25,970 --> 00:28:33,760
+بتترسب فقط الزيادة هي اللي بتترسبإذا إحنا الشيء
+
+367
+00:28:33,760 --> 00:28:38,920
+اللي بندرسه هو عبارة عن اتزان المواد الصلبة مع
+
+368
+00:28:38,920 --> 00:28:43,120
+أيوناتها في المحلول اتزان المواد الصلبة مع
+
+369
+00:28:43,120 --> 00:28:50,610
+أيوناتها في المحلولفي عندى كتير من المواد فى
+
+370
+00:28:50,610 --> 00:28:54,350
+الحقيقة بت .. احنا بقول عنها بتدوبش فى الميه لكن
+
+371
+00:28:54,350 --> 00:29:00,170
+المعنى الأصح او المصطلح الأصح انها شحيحة الذوبان
+
+372
+00:29:00,170 --> 00:29:03,430
+فى الميه sparingly soluble in water شحيحة الذوبان
+
+373
+00:29:03,430 --> 00:29:08,930
+لأنه فى الواقع بنقدرش نقول ان فى مادة يعنى بتدوبش
+
+374
+00:29:08,930 --> 00:29:13,360
+فى الميه نهائيا او بتدوبش فى ال solvent نهائيالأ
+
+375
+00:29:13,360 --> 00:29:17,200
+الأصل إنها بتدوب لكن ممكن تدوب بدرجة قليلة جدا لا
+
+376
+00:29:17,200 --> 00:29:21,840
+تكاد تذكر أو ممكن تدوب بدرجة كبيرة إلى حد ما يعني
+
+377
+00:29:21,840 --> 00:29:26,480
+كمية مهمة منها بتدوب ففي عندي بعض المواد في هذا
+
+378
+00:29:26,480 --> 00:29:31,020
+الجدول مثلا تتبين هذا المفهوم فمثلا ال led sulfate
+
+379
+00:29:31,020 --> 00:29:35,700
+ال Ksp اللي هي عشرة أس سالب تمانية ال solubility
+
+380
+00:29:35,700 --> 00:29:41,890
+عشرة أس سالب أربعة ال silver chlorideال Ksp عشرة
+
+381
+00:29:41,890 --> 00:29:47,390
+أس سالب عشرة ال solubility عشرة أس سالب خمسة ال
+
+382
+00:29:47,390 --> 00:29:52,210
+AGI مثلا عشرة أس سالب ستاشت ال solubility عشرة أس
+
+383
+00:29:52,210 --> 00:29:58,810
+سالب تمانية لو أخدنا مثلا ال iron hydroxide ال Ksp
+
+384
+00:29:58,810 --> 00:30:05,900
+أربعة عشرة أس سالب تمانية وتلاتينعنا ال solubility
+
+385
+00:30:05,900 --> 00:30:13,040
+2 في 10 أس سالب 10 لو طلعنا على ال HGS مثلا ال HGS
+
+386
+00:30:13,040 --> 00:30:19,540
+عندي ال Ksp 4 في 10 أس سالب 53و ال solubility 6 في
+
+387
+00:30:19,540 --> 00:30:23,540
+10 أقل 27 لما نقول هذا ال solubility له 10 أقل
+
+388
+00:30:23,540 --> 00:30:28,820
+سالب 4 وهذا 10 أقل سالب 27 تصوروا الفروقات الشاسعة
+
+389
+00:30:28,820 --> 00:30:32,060
+ما بين ال solubilities للمواد المختلفة لكن ما
+
+390
+00:30:32,060 --> 00:30:35,710
+تقدرش نقول إنه مثلا حالة زي ال HGSبدوب الشولمية
+
+391
+00:30:35,710 --> 00:30:39,130
+نهائيا، لأ هو بدوب، لكن إيش درجة ذوبانه؟ قليل
+
+392
+00:30:39,130 --> 00:30:42,670
+للغاية، لكن لأ بدوب، أي مادة صلبة بنقول والله
+
+393
+00:30:42,670 --> 00:30:45,650
+بتتفكك جزئيا للإيونات تبعتها أي مادة inorganic
+
+394
+00:30:45,650 --> 00:30:50,450
+substance، بتتفكك جزئيا للموارد inorganic ولا
+
+395
+00:30:50,450 --> 00:30:54,050
+organic حتى، بتتفكك جزئيا إذا كانها complex،
+
+396
+00:30:54,050 --> 00:30:57,050
+organic complex، بتتفكك جزئيا للإيونات تبعتها إذا
+
+397
+00:30:57,050 --> 00:31:02,060
+كانت متكونة من أيونات طبعاو بيكون إلها solubility
+
+398
+00:31:02,060 --> 00:31:04,360
+product معين و ال solubility معينة توقف على
+
+399
+00:31:04,360 --> 00:31:07,520
+طبيعتها فممكن طبيعة المادة تكون والله أه ال
+
+400
+00:31:07,520 --> 00:31:13,660
+solubility إلها عالية و ممكن تكون طبيعتها إنها لأ
+
+401
+00:31:13,660 --> 00:31:16,940
+شحيحة شحيحة الذوبان جدا في المي وال solubility
+
+402
+00:31:16,940 --> 00:31:21,640
+تكون إلها إيه منخفضة للغاية فالمواد بتختلف
+
+403
+00:31:21,640 --> 00:31:29,280
+بطبيعتهااحنا يا شباب هندرس ال precipitation
+
+404
+00:31:29,280 --> 00:31:34,680
+equilibria و هندرس ال solubility في خمس أحوال
+
+405
+00:31:34,680 --> 00:31:40,060
+هندرس ال solubility في أيه؟ في خمس أحوال أول حالة
+
+406
+00:31:40,060 --> 00:31:43,220
+هندرسها ال solubility في المي المجترة وهذا اللي
+
+407
+00:31:43,220 --> 00:31:48,960
+أنت درسته في سنة أولى في كيميا عامةبعدين هندرس ال
+
+408
+00:31:48,960 --> 00:31:54,180
+solubility في وجود common ion وبرضه هذا مر معنا في
+
+409
+00:31:54,180 --> 00:31:59,380
+سنة أولى بعتقد الحاله التالته هندرس ال solubility
+
+410
+00:31:59,380 --> 00:32:04,640
+في وجود diverse ions هذا هندرسها خلال ال chapter
+
+411
+00:32:04,640 --> 00:32:09,720
+اللى معناه بعدين هيظل عنا حالتين عشان اكمل احوال
+
+412
+00:32:09,720 --> 00:32:13,640
+هظل عنا حالتين هندرس ال solubility في وجود acid او
+
+413
+00:32:13,640 --> 00:32:18,470
+in acidic mediumو هندرس ايضا ال solubility في وجود
+
+414
+00:32:18,470 --> 00:32:22,210
+complexing agent او legend هدول اتنين هندرسهم لما
+
+415
+00:32:22,210 --> 00:32:25,670
+نتكلم عن ال precipitation, titrations و reactions
+
+416
+00:32:25,670 --> 00:32:29,910
+في اخر الفصل
+
+417
+00:32:29,910 --> 00:32:34,120
+الدراسي اذا الله رعانيفي آخر الفصل الدراسي فهندرس
+
+418
+00:32:34,120 --> 00:32:38,020
+تلت أحوال لل solubility في هذا ال chapter و هنأجل
+
+419
+00:32:38,020 --> 00:32:44,360
+حلقين للمستقبل لأن الحلقين هدول بدهم مقدمات بدهم
+
+420
+00:32:44,360 --> 00:32:47,260
+شوية شغل هل جهتي احنا لسه مش جاهزين ناخدهم
+
+421
+00:32:47,260 --> 00:32:53,260
+فهناخدهم اذا الله راد في المستقبل هنبدأ في حالة
+
+422
+00:32:53,260 --> 00:32:59,650
+حالة نتكلم عن ال solubility in pure waterبنطلع على
+
+423
+00:32:59,650 --> 00:33:02,470
+المثال اللى جدامى بس هذا مراجعة لسنة أولى مش اشي
+
+424
+00:33:02,470 --> 00:33:07,070
+جديد الأكتر من مثال الأوائل اللى لان هي عبارة عن
+
+425
+00:33:07,070 --> 00:33:12,190
+مراجعة لمعلومات مرت معاها سابقا لكن بدنا نأكد
+
+426
+00:33:12,190 --> 00:33:15,890
+عليها و بدنا نقولكم كيف احنا هنحل فهنطلع مع بعض
+
+427
+00:33:15,890 --> 00:33:21,310
+ايش بيحصل معانا في حال مثال من هالنوع بنقول نتكلم
+
+428
+00:33:21,310 --> 00:33:27,860
+عن الميهالميه حل مباشر فش عندى اي مشكلة فيها بيقول
+
+429
+00:33:27,860 --> 00:33:31,080
+calculate the concentration of Ag plus and Cl
+
+430
+00:33:31,080 --> 00:33:36,740
+minus in pure water containing solid AgCl يعني فيه
+
+431
+00:33:36,740 --> 00:33:40,890
+عندى AgCl سيبناه لما حصل ال equilibriumلما حصل
+
+432
+00:33:40,890 --> 00:33:45,350
+equilibrium طبعا ده بجزء بسيط منه لل silver موجة
+
+433
+00:33:45,350 --> 00:33:50,370
+بأوليكلوريد سالب فبيقول احسب تركيز ال silver plus
+
+434
+00:33:50,370 --> 00:33:54,170
+و ال c ال minus if the solubility product is واحد
+
+435
+00:33:54,170 --> 00:33:59,970
+في عشرة أس سالب عشرة باجي بقولفي الأول بنحط
+
+436
+00:33:59,970 --> 00:34:05,770
+المعادلة مهم جدا المعادلة مهم جدا ال agcl ال solid
+
+437
+00:34:05,770 --> 00:34:13,330
+بيتفكك بعطيني ag plus و cl minus الآن ببني الجدول
+
+438
+00:34:13,330 --> 00:34:20,130
+تبعي ببني الجدول تبعي بقول المعادلة agcl solid
+
+439
+00:34:20,130 --> 00:34:26,610
+بتعطيني ag plus و cl minus التركيزات قبل الإتزان
+
+440
+00:34:28,650 --> 00:34:35,030
+الـ AgCl صليد تركيزه solid solid ماشي تركيزه ثابت
+
+441
+00:34:35,030 --> 00:34:40,030
+يعني solid طيب ال silver plus صفر لchloride صفر
+
+442
+00:34:40,030 --> 00:34:44,370
+طبقات equilibrium ال solid بيضله solid تركيزه إيش
+
+443
+00:34:44,370 --> 00:34:50,450
+ماله ثابت آه ال silver X بس بدنا بنقول X إيش بدنا
+
+444
+00:34:50,450 --> 00:34:57,400
+نقول S يعني solubilityوالكلورايد S إذا بقدر أقول
+
+445
+00:34:57,400 --> 00:35:01,920
+Ksp بدها تساوي ال A G Plus في ال C المينوس يعني
+
+446
+00:35:01,920 --> 00:35:05,800
+تركيز ال A G Plus بتطلع إيش بتساوي S تركيز C
+
+447
+00:35:05,800 --> 00:35:10,500
+المينوس S إذا S تربية يبقى ال S بتساوي جزر ال K سي
+
+448
+00:35:10,500 --> 00:35:14,020
+بتساوي واحد في عشر أقل سالم خمسة طب إيش بتساوي ال
+
+449
+00:35:14,020 --> 00:35:17,480
+S ده اللي والله ال S هي تركيز ال silver وتركيز
+
+450
+00:35:17,480 --> 00:35:20,780
+الكلورايد إذا ال silver بيساوي الكلورايد بيساوي
+
+451
+00:35:20,780 --> 00:35:25,580
+عشرة أقل سالم خمسةماشي يا شباب طبعا شوفنا هذا كلام
+
+452
+00:35:25,580 --> 00:35:31,040
+سابقا نتطلع على مثال نفس المثال تقريبا calculate
+
+453
+00:35:31,040 --> 00:35:35,420
+the molar solubility of lead sulfate in pure water
+
+454
+00:35:35,420 --> 00:35:40,960
+if the solubility product is 1 6 10 8 نفس الكلام
+
+455
+00:35:40,960 --> 00:35:45,480
+بقول المعادلة lead sulfate بتعطيني lead و sulfate
+
+456
+00:35:45,480 --> 00:35:47,040
+واحد لواحد
+
+457
+00:35:50,940 --> 00:35:57,280
+قبل الاتزان تركيز الصليد صفر صفر صليد بيظل صليد
+
+458
+00:35:57,280 --> 00:36:03,220
+تركيز ال LED S تركيز الصلفات S إذا ال KSP بيتساوي
+
+459
+00:36:03,220 --> 00:36:07,860
+ال LED في الصلفات أو ال KS بيتساوي ال S تربيع
+
+460
+00:36:07,860 --> 00:36:10,340
+معناه الكلام ال S تساوي واحد و ثلاثة في عشر أقل
+
+461
+00:36:10,340 --> 00:36:14,960
+سالب أربعة لو إجينا قارننا between the
+
+462
+00:36:14,960 --> 00:36:19,260
+solubilitiesللاتنين ونلاحظ هذا عشرة أس سالب أربعة
+
+463
+00:36:19,260 --> 00:36:24,480
+واللي قبله عشرة أس سالب خمسة ولو قررنا بين ال KSPs
+
+464
+00:36:24,480 --> 00:36:28,660
+هذا عشرة أس سالب عشرة والتاني عشرة أس سالب تمانية
+
+465
+00:36:28,660 --> 00:36:34,860
+يعني بقدر أقول والله بما أن ال KSP لل AGCL أقل من
+
+466
+00:36:34,860 --> 00:36:38,200
+ال KSP لل lead sulfate إذن الصلابيريتي له أقل
+
+467
+00:36:38,200 --> 00:36:43,340
+بإمكاني أقارن هذا الكلام مباشرة فقط في حالة ما
+
+468
+00:36:43,340 --> 00:36:49,850
+يكون في عنديالراشيو واحد لواحد يعني مثلا ال agcl
+
+469
+00:36:49,850 --> 00:36:53,750
+واحد لواحد وال lead sulfate ال lead ل ال sulfate
+
+470
+00:36:53,750 --> 00:36:58,970
+واحد ل واحد بانفعش اقارن ال solubility مباشرة او
+
+471
+00:36:58,970 --> 00:37:02,690
+اقارن ال Ksp مباشرة و اقول والله هذا ال solubility
+
+472
+00:37:02,690 --> 00:37:05,650
+هو اقل من هذا اذا كان النسبة مش نفس ال
+
+473
+00:37:05,650 --> 00:37:09,220
+stoichiometryيعني اذا كان واحد لواحد لاثنين يكون
+
+474
+00:37:09,220 --> 00:37:13,720
+كويس لاثنين اتنين لواحد منيح بس لاثنين زي بعض
+
+475
+00:37:13,720 --> 00:37:19,180
+ماينفعش اقارن واحد لواحد مع اتنين لواحد مثلا فنيجي
+
+476
+00:37:19,180 --> 00:37:22,840
+نتطلع على هالمثال اللي فيه مش واحد لواحد فيه اتنين
+
+477
+00:37:22,840 --> 00:37:27,360
+لواحد وخلينا
+
+478
+00:37:27,360 --> 00:37:31,020
+نتطلع على القيم لأنه هنقارن هذا باللي جابله بنقول
+
+479
+00:37:31,020 --> 00:37:34,800
+calculate the molar solubility of lead iodide in
+
+480
+00:37:34,800 --> 00:37:35,660
+pure water
+
+481
+00:37:40,690 --> 00:37:45,850
+بقول بعمل الجدول طبعا هي ال equation led-iodide
+
+482
+00:37:45,850 --> 00:37:50,690
+solid تتفكك اللي بتعطيني led زائد اتنين I minus
+
+483
+00:37:50,690 --> 00:37:54,250
+لازم نعرف ان ال led عليه اتنين موجب و ال I سالب
+
+484
+00:37:54,250 --> 00:37:57,270
+عليها واحد سالب يعني لازم يكون فيه اتنين لأنه عندي
+
+485
+00:37:57,270 --> 00:38:03,500
+PPI2 طيب بنقول والله قبل الاتزال هذا solidقبل
+
+486
+00:38:03,500 --> 00:38:08,080
+اتزان ال LED صفر قبل اتزان ال I سالد صفر بعد
+
+487
+00:38:08,080 --> 00:38:12,280
+الاتزان ال LED ايودايد ضاير زي ما هو solid لأنه
+
+488
+00:38:12,280 --> 00:38:20,500
+لايتغيرش تركيزه ال LED S ال I سالب اتنين S طيب
+
+489
+00:38:20,500 --> 00:38:25,880
+بنقول ال Ksp بسوء ال LED في ال أيودايد تربيع لأنه
+
+490
+00:38:25,880 --> 00:38:30,180
+اتنين I سالب ال LED في ال أيودايد تربيع بعض الشباب
+
+491
+00:38:30,180 --> 00:38:35,990
+كانوا بكتبوا ليه LEDموجب اي اتنين سالب مش اي سالل
+
+492
+00:38:35,990 --> 00:38:39,410
+اتنين اي سالب بيقولوا اي اتنين لأ بينافهم ان هذا
+
+493
+00:38:39,410 --> 00:38:44,410
+اسمه led-iodide ال iodide اسمه اي سالل لازم نفهم
+
+494
+00:38:44,410 --> 00:38:48,850
+المعادلات بشكل صحيح فبدي اعوض عن ال led ال led
+
+495
+00:38:48,850 --> 00:38:55,310
+والله هي اس اس هذا هي طيب وال iodide اتنين اس او
+
+496
+00:38:55,310 --> 00:39:00,610
+بما انه في عند اتنين اذا هي التربيةإذا ال KSP بدو
+
+497
+00:39:00,610 --> 00:39:06,510
+يساوي أربعة S تكعيب أو ال S بتساوي الجزر التالت لل
+
+498
+00:39:06,510 --> 00:39:09,590
+KSP
+
+499
+00:39:09,590 --> 00:39:13,530
+على أربعة بتطلع لنا one point two في عشرة أس سالب
+
+500
+00:39:13,530 --> 00:39:19,510
+تلاتة لو أجينا نقارن هذه القيمة مع القيمة اللي
+
+501
+00:39:19,510 --> 00:39:25,830
+جابلها لاحظوا انتوا ال KSP جداش KSP
+
+502
+00:39:25,830 --> 00:39:31,710
+ل ال LEDأيو دايت بده يساوي سبعة و واحد فى عشرة
+
+503
+00:39:31,710 --> 00:39:41,670
+أسالم جداش تسعة طب ال KSP لل LED صلفت ايش بده
+
+504
+00:39:41,670 --> 00:39:46,930
+يساوي نتطلع على المثال اللى جابله واحد و ستة فى
+
+505
+00:39:46,930 --> 00:39:53,470
+عشرة أسالم تمانية اذا لو قلنا عليهم أنه أقل صلبية
+
+506
+00:39:53,470 --> 00:39:57,370
+احنا بنقوللو بدنا نقل على ال case يبقى بيقول اللي
+
+507
+00:39:57,370 --> 00:40:02,150
+فوق أقل، لكن لحظة أن هذه أعطتني solubility جديش، و
+
+508
+00:40:02,150 --> 00:40:04,950
+هذه أعطتني solubility .. لأ كنت هذه في الأول، واحد
+
+509
+00:40:04,950 --> 00:40:08,790
+و تلاتة في عشر أقل سالب أربعة، هذه واحد و اتنين في
+
+510
+00:40:08,790 --> 00:40:14,350
+عشر أقل سالب تلاتة، أظن هيك كان الرقم، لحظة مع أن
+
+511
+00:40:14,350 --> 00:40:19,490
+هذا إيه اش ماله؟ ال case بيقوله أقلالمفروض يعطيني
+
+512
+00:40:19,490 --> 00:40:24,950
+S أقل لكن هذا الـ S أعلى بعشر مرت ليه؟ لأن هذا ليس
+
+513
+00:40:24,950 --> 00:40:29,090
+واحد، هذا واحد لاتنينبينما هذي واحد لو مانفعش
+
+514
+00:40:29,090 --> 00:40:36,050
+اقارن ال KSPs لما يكون في عندي اه ال ratio مختلفة
+
+515
+00:40:36,050 --> 00:40:39,890
+لازم نفس ال stoichiometry اه بقدر اقارن ال KSPs و
+
+516
+00:40:39,890 --> 00:40:44,390
+اقول والله اه ممكن ال KSP الأقل هو اللي له
+
+517
+00:40:44,390 --> 00:40:48,570
+solubility أقل و في هذه المناسبة بنقول انه لو في
+
+518
+00:40:48,570 --> 00:40:56,470
+عنديلو في عندى عدة مواد إلها طبعا كل مادة إلها Ksp
+
+519
+00:40:56,470 --> 00:41:03,270
+فبنقول إحنا المادة اللى إلها Ksp أقل بتترثب أولا
+
+520
+00:41:03,270 --> 00:41:07,450
+كل ما قلل Ksp كل ما ترثبت أولا لإن صلability أقل
+
+521
+00:41:08,630 --> 00:41:12,270
+الكويس اذا كان لدي نفس الستوكيومتري نتكلم لو عندي
+
+522
+00:41:12,270 --> 00:41:15,850
+عدة مواد فممكن اتطلع على ال KSP مدام لدي نفس
+
+523
+00:41:15,850 --> 00:41:21,530
+الستوكيومتري و بشوف ال KSP والله كل ما قل ال KSP
+
+524
+00:41:21,530 --> 00:41:30,590
+اذا المادة بتترسم اولا المادة بتترسم اولا ممكن
+
+525
+00:41:30,590 --> 00:41:36,670
+نتطلع على المثال التالي بيقول what mustbe the
+
+526
+00:41:36,670 --> 00:41:40,250
+concentration of silver to just start
+
+527
+00:41:40,250 --> 00:41:45,070
+precipitation of AgCl in a 1 في 10 أقل ثالث تلاتة
+
+528
+00:41:45,070 --> 00:41:50,130
+مولار in a Cl solution يعني أنا في عندي محلول من
+
+529
+00:41:50,130 --> 00:41:55,770
+الصوديوم إكلورايد تركيزه 1 في 10 أقل ثالث تلاتة
+
+530
+00:41:55,770 --> 00:42:01,470
+مولار بدي أحط عليه silver فبدي أعرف إيش تركيز ال
+
+531
+00:42:01,470 --> 00:42:08,010
+silver اللي يعني لازم عشان يبدأالترثب الـ AgCl
+
+532
+00:42:08,010 --> 00:42:12,630
+طبعا واضح من هذا الكلام أني بدي أقول والله ال ..
+
+533
+00:42:12,630 --> 00:42:18,970
+ال Ag .. AgCl
+
+534
+00:42:18,970 --> 00:42:24,430
+solid Ag plus زائد Cl minus بيبدأ الترثب لما يكون
+
+535
+00:42:24,430 --> 00:42:28,550
+عندي saturated solution أول شيء بعده يعني بدي أجيب
+
+536
+00:42:28,550 --> 00:42:32,070
+تركيز ال silver اللي بيعطيني saturated solution
+
+537
+00:42:32,070 --> 00:42:38,080
+بقول Kc بيساوي ال silverفي الكلورايد انا ال silver
+
+538
+00:42:38,080 --> 00:42:42,200
+مجهول عندى بينما الكلورايد عندى عشرة اقصالب تلاتة
+
+539
+00:42:42,200 --> 00:42:46,840
+اذا ال AJ plus واحد في عشرة اقصالب سبعة مولار بقول
+
+540
+00:42:46,840 --> 00:42:51,260
+اذا كان اضافت انا واحد في عشرة اقصالب سبعة مولار
+
+541
+00:42:51,260 --> 00:42:54,600
+او اذا كان خليه التركيز ال silver واحد في عشرة
+
+542
+00:42:54,600 --> 00:42:59,400
+اقصالب سبعة مولار الان حصلت على ايه such
+
+543
+00:42:59,400 --> 00:43:06,750
+resolution اي تركيز بعدههيعطيني الراصد، ماشي يا
+
+544
+00:43:06,750 --> 00:43:15,530
+شباب، خلينا نتحدث عن هذا المثال الحصة الجاية،
+
+545
+00:43:15,530 --> 00:43:20,110
+بيكفي الحصة هذه، إذا الله راد، الحصة الجاية، بنكمل
+
diff --git a/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/5hkBYzuMqWQ_raw.json b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/5hkBYzuMqWQ_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..a8b4a0afafd51ce68999e820cf062802df824086
--- /dev/null
+++ b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/5hkBYzuMqWQ_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 4773, "start": 21.63, "end": 47.73, "text": "بسم الله الرحمن الرحيم الحصة الماضية يا شباب كنا بدنا نتكلم عن ال gravimetric calculations و أخدنا بعض الأمثلة اليوم ان شاء الله بنحاول أنه نستكمل ال gravimetric analysis بشكل عام ال calculations خصوصا و بعدين بننتقل لموضوع كتير مهم بيتكلم عن ال precipitation equilibria", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640, 21542, 9381, 3660, 9673, 46958, 10632, 35186, 13412, 3555, 16758, 9122, 8315, 47525, 8315, 8717, 2655, 4117, 19528, 18871, 2423, 7427, 332, 17475, 20448, 4032, 5551, 9778, 3215, 8315, 45030, 11242, 16247, 2304, 12984, 37977, 45595, 20498, 16472, 13412, 16606, 21984, 44945, 5016, 995, 12610, 14739, 3224, 8717, 14851, 24793, 1211, 2423, 7427, 332, 17475, 5215, 4724, 8592, 28820, 6225, 10943, 2423, 20448, 16490, 9381, 2407, 9381, 995, 4032, 39182, 9957, 44945, 29399, 4587, 1211, 32767, 2407, 11242, 45367, 9122, 2655, 13546, 3714, 16095, 4724, 36081, 4117, 19528, 18871, 2423, 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"temperature": 1.0}, {"id": 15, "seek": 33981, "start": 325.31, "end": 339.81, "text": "بقول نفس الكلام فش عندي مفارقة إلا إن أستخدم ال millimole إذا كان بدي أوصل للنتيجة فبقول والله ال millimole sulfur أنا عندي ال sulfur بتحول البريام صار في هاي التفاعل اللي عندي في هاي ال analyte", "tokens": [3555, 39648, 8717, 36178, 2423, 28820, 10943, 6156, 8592, 18871, 16254, 3714, 5172, 9640, 28671, 11933, 15040, 36145, 5551, 14851, 9778, 40448, 2423, 1728, 332, 4812, 11933, 15730, 25961, 4724, 16254, 34051, 36520, 24976, 29399, 1829, 7435, 3660, 6156, 3555, 39648, 16070, 43761, 2423, 1728, 332, 4812, 33831, 41850, 18871, 16254, 2423, 33831, 39894, 5016, 12610, 2423, 26890, 1829, 10943, 20328, 9640, 8978, 8032, 47302, 16712, 5172, 995, 30241, 13672, 1829, 18871, 16254, 8978, 8032, 47302, 2423, 6459, 975], "avg_logprob": -0.29375000968575476, "compression_ratio": 1.6844919786096257, "no_speech_prob": 2.980232238769531e-07, "words": [{"start": 325.31, "end": 325.75, "word": "بقول", "probability": 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"start": 340.79, "end": 364.79, "text": "وهي الـ precipitate الـ S1 و الـ S1 معنى الكلام الـ millimole sulfur تساوي millimole barium sulfate لأن انت بي .. مافيش برضه قدام خيارات و ال millimole بدي اعوض عنها باحد حاجتين يا milligram على ال formula weight يا اما molarity of volume طبعا بدي اعوض عنها milligram على ال formula weight لأنه مافيش عند molarity of volume فبقول millimole sulfur بتساوي millimole barium sulfate يعني", "tokens": [2407, 3224, 1829, 2423, 39184, 23354, 8086, 2423, 39184, 318, 16, 4032, 2423, 39184, 318, 16, 20449, 1863, 7578, 2423, 28820, 10943, 2423, 39184, 1728, 332, 4812, 33831, 6055, 3794, 995, 45865, 1728, 332, 4812, 2159, 2197, 22925, 473, 5296, 33456, 16472, 2655, 4724, 1829, 4386, 19446, 41185, 8592, 4724, 43042, 3224, 12174, 3215, 10943, 16490, 1829, 9640, 9307, 4032, 2423, 1728, 332, 4812, 4724, 16254, 1975, 3615, 2407, 11242, 18871, 11296, 4724, 995, 24401, 11331, 26108, 2655, 9957, 35186, 1728, 328, 2356, 15844, 2423, 8513, 3364, 35186, 1975, 15042, 8015, 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0.72021484375}, {"start": 355.27, "end": 355.59, "word": " volume", "probability": 0.97509765625}, {"start": 355.59, "end": 356.05, "word": " طبعا", "probability": 0.9854736328125}, {"start": 356.05, "end": 356.57, "word": " بدي", "probability": 0.711669921875}, {"start": 356.57, "end": 356.85, "word": " اعوض", "probability": 0.974853515625}, {"start": 356.85, "end": 357.09, "word": " عنها", "probability": 0.9501953125}, {"start": 357.09, "end": 357.61, "word": " milligram", "probability": 0.8401692708333334}, {"start": 357.61, "end": 357.81, "word": " على", "probability": 0.86474609375}, {"start": 357.81, "end": 357.97, "word": " ال", "probability": 0.80859375}, {"start": 357.97, "end": 358.25, "word": " formula", "probability": 0.857421875}, {"start": 358.25, "end": 358.99, "word": " weight", "probability": 0.93359375}, {"start": 358.99, "end": 359.27, "word": " لأنه", "probability": 0.69580078125}, {"start": 359.27, "end": 359.53, "word": " مافيش", "probability": 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"probability": 0.916015625}], "temperature": 1.0}, {"id": 17, "seek": 37092, "start": 365.04, "end": 370.92, "text": "ملي جرام سلفر ع ال atomic weight سلفر تسوى ملي جرام باريام صلفية ع ال formula weight باريام صلفية", "tokens": [2304, 20292, 10874, 2288, 10943, 8608, 46538, 2288, 6225, 2423, 22275, 3364, 8608, 46538, 2288, 6055, 3794, 2407, 7578, 3714, 20292, 10874, 2288, 10943, 4724, 9640, 1829, 10943, 20328, 46538, 10632, 6225, 2423, 8513, 3364, 4724, 9640, 1829, 10943, 20328, 46538, 10632], "avg_logprob": -0.32667151717252507, "compression_ratio": 1.5894736842105264, "no_speech_prob": 4.76837158203125e-07, "words": [{"start": 365.04, "end": 365.4, "word": "ملي", "probability": 0.26104736328125}, {"start": 365.4, "end": 365.72, "word": " جرام", "probability": 0.8802083333333334}, {"start": 365.72, "end": 366.1, "word": " سلفر", "probability": 0.7542317708333334}, {"start": 366.1, "end": 366.2, "word": " ع", "probability": 0.2139892578125}, {"start": 366.2, "end": 366.28, "word": " ال", "probability": 0.591796875}, {"start": 366.28, "end": 366.56, "word": " atomic", "probability": 0.52880859375}, {"start": 366.56, "end": 366.86, "word": " weight", "probability": 0.90625}, {"start": 366.86, "end": 367.34, "word": " سلفر", "probability": 0.8014322916666666}, {"start": 367.34, "end": 367.98, "word": " تسوى", "probability": 0.7320556640625}, {"start": 367.98, "end": 368.22, "word": " ملي", "probability": 0.873779296875}, {"start": 368.22, "end": 368.56, "word": " جرام", "probability": 0.9822591145833334}, {"start": 368.56, "end": 368.9, "word": " باريام", "probability": 0.76666259765625}, {"start": 368.9, "end": 369.3, "word": " صلفية", "probability": 0.7340494791666666}, {"start": 369.3, "end": 369.46, "word": " ع", "probability": 0.54541015625}, {"start": 369.46, "end": 369.58, "word": " ال", "probability": 0.6533203125}, {"start": 369.58, "end": 369.88, "word": " formula", "probability": 0.78662109375}, {"start": 369.88, "end": 370.12, "word": " weight", "probability": 0.890625}, {"start": 370.12, "end": 370.42, "word": " باريام", "probability": 0.95654296875}, {"start": 370.42, "end": 370.92, "word": " صلفية", "probability": 0.9798177083333334}], "temperature": 1.0}, {"id": 18, "seek": 39661, "start": 374.37, "end": 396.61, "text": "أي معلومات عن الـ milligram barium sulphate إلا المعلومات اللي أتهلى قال لي إن وزن الـ barium sulphate تساوي نص ال percentage sulfur باعود عنها زي ما قال لي نص percentage sulfur هاي اللي جدامي ماعطانيش قيمة فبقول إذا ال milligram sulfur بدي ساوي ال atomic weight ل ال sulfur كام تحيطها لو حطيته 32 مثلا", "tokens": [10721, 1829, 20449, 1211, 20498, 9307, 18871, 2423, 39184, 38298, 2159, 2197, 47286, 473, 11933, 15040, 9673, 30241, 20498, 9307, 13672, 1829, 5551, 2655, 3224, 23942, 50239, 32239, 36145, 4032, 11622, 1863, 2423, 39184, 2159, 2197, 47286, 473, 6055, 3794, 995, 45865, 8717, 9381, 2423, 9668, 33831, 4724, 45761, 23328, 18871, 11296, 30767, 1829, 19446, 50239, 32239, 8717, 9381, 9668, 33831, 8032, 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0.9111328125}, {"start": 385.39, "end": 385.97, "word": " sulfur", "probability": 0.7373046875}, {"start": 385.97, "end": 386.79, "word": " هاي", "probability": 0.5849609375}, {"start": 386.79, "end": 386.89, "word": " اللي", "probability": 0.974365234375}, {"start": 386.89, "end": 387.41, "word": " جدامي", "probability": 0.8934326171875}, {"start": 387.41, "end": 387.93, "word": " ماعطانيش", "probability": 0.8524576822916666}, {"start": 387.93, "end": 388.53, "word": " قيمة", "probability": 0.9908854166666666}, {"start": 388.53, "end": 389.39, "word": " فبقول", "probability": 0.9583333333333334}, {"start": 389.39, "end": 389.77, "word": " إذا", "probability": 0.7978515625}, {"start": 389.77, "end": 390.63, "word": " ال", "probability": 0.93212890625}, {"start": 390.63, "end": 391.31, "word": " milligram", "probability": 0.93798828125}, {"start": 391.31, "end": 391.85, "word": " sulfur", "probability": 0.671875}, {"start": 391.85, "end": 392.15, "word": " بدي", "probability": 0.7105712890625}, {"start": 392.15, "end": 392.67, "word": " ساوي", "probability": 0.8937174479166666}, {"start": 392.67, "end": 392.97, "word": " ال", "probability": 0.98388671875}, {"start": 392.97, "end": 393.25, "word": " atomic", "probability": 0.859375}, {"start": 393.25, "end": 393.53, "word": " weight", "probability": 0.90478515625}, {"start": 393.53, "end": 393.65, "word": " ل", "probability": 0.40185546875}, {"start": 393.65, "end": 393.73, "word": " ال", "probability": 0.2305908203125}, {"start": 393.73, "end": 393.97, "word": " sulfur", "probability": 0.53173828125}, {"start": 393.97, "end": 394.35, "word": " كام", "probability": 0.556396484375}, {"start": 394.35, "end": 394.77, "word": " تحيطها", "probability": 0.7439453125}, {"start": 394.77, "end": 394.85, "word": " لو", "probability": 0.257080078125}, {"start": 394.85, "end": 395.33, "word": " حطيته", "probability": 0.8438720703125}, {"start": 395.33, "end": 396.03, "word": " 32", "probability": 0.72900390625}, 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398.27, "end": 398.71, "word": " barium", "probability": 0.892333984375}, {"start": 398.71, "end": 399.15, "word": " sulphate", "probability": 0.72998046875}, {"start": 399.15, "end": 399.75, "word": " نُص", "probability": 0.7581380208333334}, {"start": 399.75, "end": 400.93, "word": " percentage", "probability": 0.8291015625}, {"start": 400.93, "end": 402.09, "word": " sulphur", "probability": 0.644775390625}, {"start": 402.09, "end": 402.75, "word": " على", "probability": 0.74755859375}, {"start": 402.75, "end": 403.09, "word": " ال", "probability": 0.88037109375}, {"start": 403.09, "end": 403.37, "word": " formula", "probability": 0.302490234375}, {"start": 403.37, "end": 403.63, "word": " weight", "probability": 0.732421875}, {"start": 403.63, "end": 403.85, "word": " للـ", "probability": 0.4501953125}, {"start": 403.85, "end": 404.05, "word": " barium", "probability": 0.86083984375}, {"start": 404.05, "end": 404.77, "word": " sulphate،", "probability": 0.7530110677083334}, {"start": 404.77, "end": 405.05, "word": " هذا", "probability": 0.86962890625}, {"start": 405.05, "end": 405.25, "word": " هو", "probability": 0.8623046875}, {"start": 405.25, "end": 405.55, "word": " عبارة", "probability": 0.9852294921875}, {"start": 405.55, "end": 405.69, "word": " عن", "probability": 0.99560546875}, {"start": 405.69, "end": 405.85, "word": " الـ", "probability": 0.652099609375}, {"start": 405.85, "end": 406.11, "word": " milligram", "probability": 0.966796875}, {"start": 406.11, "end": 406.87, "word": " sulphur،", "probability": 0.9088541666666666}, {"start": 406.87, "end": 407.19, "word": " بطلع", "probability": 0.7779541015625}, {"start": 407.19, "end": 407.43, "word": " هذه", "probability": 0.9033203125}, {"start": 407.43, "end": 407.81, "word": " القيمة", "probability": 0.8328450520833334}, {"start": 407.81, "end": 408.17, "word": " مضروبة", "probability": 0.9453125}, {"start": 408.17, "end": 408.29, "word": " في", "probability": 0.8974609375}, {"start": 408.29, 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" اخر", "probability": 0.7188720703125}, {"start": 740.71, "end": 746.37, "word": " المثال", "probability": 0.9384765625}, {"start": 746.37, "end": 747.09, "word": " كالتالي", "probability": 0.80302734375}, {"start": 747.09, "end": 747.39, "word": " في", "probability": 0.71533203125}, {"start": 747.39, "end": 747.87, "word": " عندي", "probability": 0.7191162109375}, {"start": 747.87, "end": 748.73, "word": " خليط", "probability": 0.9446614583333334}, {"start": 748.73, "end": 749.09, "word": " من", "probability": 0.99169921875}, {"start": 749.09, "end": 750.33, "word": " two", "probability": 0.84130859375}, {"start": 750.33, "end": 750.65, "word": " metal", "probability": 0.7666015625}, {"start": 750.65, "end": 751.33, "word": " sulfates", "probability": 0.842041015625}, {"start": 751.33, "end": 751.55, "word": " في", "probability": 0.2958984375}, {"start": 751.55, "end": 751.75, "word": " عندي", "probability": 0.795654296875}, {"start": 751.75, "end": 751.97, "word": " metal", 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0.92578125}], "temperature": 1.0}, {"id": 35, "seek": 78220, "start": 759.44, "end": 782.2, "text": "واحد من الـ metal ions اللي بيكون الصلفات .. واحد من الـ metal ions لأحد الصلفات مجهول M فبتعرف ال atomic weight تبعه نقرأ المسألة و نحاول نفكر كيف ممكن يكون الحل we'll consider a one gram sample يعني في عندي عينة جداش وزنتها واحد gram containing", "tokens": [14407, 24401, 9154, 2423, 39184, 5760, 27362, 13672, 1829, 4724, 1829, 30544, 31767, 46538, 9307, 4386, 36764, 24401, 9154, 2423, 39184, 5760, 27362, 5296, 10721, 24401, 31767, 46538, 9307, 3714, 7435, 3224, 12610, 376, 6156, 3555, 2655, 3615, 28480, 2423, 22275, 3364, 6055, 3555, 3615, 3224, 8717, 4587, 2288, 10721, 9673, 3794, 10721, 37977, 4032, 8717, 5016, 995, 12610, 8717, 5172, 37983, 9122, 33911, 3714, 43020, 7251, 30544, 21542, 1211, 321, 603, 1949, 257, 472, 21353, 6889, 37495, 22653, 8978, 18871, 16254, 6225, 9957, 3660, 10874, 3215, 33599, 4032, 11622, 29399, 11296, 36764, 24401, 21353, 19273], "avg_logprob": 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"75% بتاسيوم صلفية و 25% متل صلفية", "tokens": [11901, 4, 39894, 32277, 1829, 20498, 20328, 46538, 10632, 4032, 3552, 4, 44650, 1211, 20328, 46538, 10632], "avg_logprob": -0.3459201521343655, "compression_ratio": 0.9818181818181818, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 783.27, "end": 783.87, "word": "75", "probability": 0.317626953125}, {"start": 783.87, "end": 784.61, "word": "%", "probability": 0.91357421875}, {"start": 784.61, "end": 785.23, "word": " بتاسيوم", "probability": 0.757537841796875}, {"start": 785.23, "end": 785.93, "word": " صلفية", "probability": 0.7726236979166666}, {"start": 785.93, "end": 786.43, "word": " و", "probability": 0.6650390625}, {"start": 786.43, "end": 786.83, "word": " 25", "probability": 0.8330078125}, {"start": 786.83, "end": 787.93, "word": "%", "probability": 0.9453125}, {"start": 787.93, "end": 788.65, "word": " متل", "probability": 0.780517578125}, {"start": 788.65, "end": 789.45, "word": " صلفية", "probability": 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"probability": 0.8704427083333334}, {"start": 1799.71, "end": 1799.91, "word": " أس", "probability": 0.993408203125}, {"start": 1799.91, "end": 1800.15, "word": " سالب", "probability": 0.9694010416666666}, {"start": 1800.15, "end": 1800.47, "word": " تمانية", "probability": 0.9518229166666666}, {"start": 1800.47, "end": 1801.05, "word": " وتلاتين", "probability": 0.84368896484375}], "temperature": 1.0}, {"id": 81, "seek": 181706, "start": 1803.04, "end": 1817.06, "text": "عنا ال solubility 2 في 10 أس سالب 10 لو طلعنا على ال HGS مثلا ال HGS عندي ال Ksp 4 في 10 أس سالب 53", "tokens": [3615, 8315, 2423, 1404, 836, 1140, 568, 8978, 1266, 5551, 3794, 8608, 6027, 3555, 1266, 45164, 23032, 1211, 3615, 8315, 15844, 2423, 389, 24446, 50113, 15040, 2423, 389, 24446, 18871, 16254, 2423, 591, 4952, 1017, 8978, 1266, 5551, 3794, 8608, 6027, 3555, 21860], "avg_logprob": -0.34712356667626987, "compression_ratio": 1.3980582524271845, "no_speech_prob": 0.0, "words": [{"start": 1803.04, "end": 1803.6, 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{"start": 1832.38, "end": 1832.64, "word": " نقول", "probability": 0.886962890625}, {"start": 1832.64, "end": 1832.82, "word": " إنه", "probability": 0.39990234375}, {"start": 1832.82, "end": 1833.06, "word": " مثلا", "probability": 0.96826171875}, {"start": 1833.06, "end": 1833.36, "word": " حالة", "probability": 0.9195963541666666}, {"start": 1833.36, "end": 1833.52, "word": " زي", "probability": 0.939208984375}, {"start": 1833.52, "end": 1833.62, "word": " ال", "probability": 0.9248046875}, {"start": 1833.62, "end": 1834.26, "word": " HGS", "probability": 0.52294921875}], "temperature": 1.0}, {"id": 83, "seek": 185841, "start": 1834.87, "end": 1858.41, "text": "بدوب الشولمية نهائيا، لأ هو بدوب، لكن إيش درجة ذوبانه؟ قليل للغاية، لكن لأ بدوب، أي مادة صلبة بنقول والله بتتفكك جزئيا للإيونات تبعتها أي مادة inorganic substance، بتتفكك جزئيا للموارد inorganic ولا organic حتى، بتتفكك جزئيا إذا كانها complex، organic complex، بتتفكك جزئيا للإيونات تبعتها إذا كانت متكونة من أيونات طبعا", 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"word": " جزئيا", "probability": 0.863525390625}, {"start": 1843.53, "end": 1844.07, "word": " للإيونات", "probability": 0.7680257161458334}, {"start": 1844.07, "end": 1844.51, "word": " تبعتها", "probability": 0.8541259765625}, {"start": 1844.51, "end": 1844.67, "word": " أي", "probability": 0.5830078125}, {"start": 1844.67, "end": 1844.97, "word": " مادة", "probability": 0.98486328125}, {"start": 1844.97, "end": 1845.65, "word": " inorganic", "probability": 0.7607421875}, {"start": 1845.65, "end": 1846.61, "word": " substance،", "probability": 0.648193359375}, {"start": 1846.61, "end": 1847.13, "word": " بتتفكك", "probability": 0.95322265625}, {"start": 1847.13, "end": 1847.69, "word": " جزئيا", "probability": 0.98095703125}, {"start": 1847.69, "end": 1849.67, "word": " للموارد", "probability": 0.72880859375}, {"start": 1849.67, "end": 1850.29, "word": " inorganic", "probability": 0.8102213541666666}, {"start": 1850.29, "end": 1850.45, "word": " ولا", "probability": 0.77734375}, {"start": 1850.45, "end": 1850.85, "word": " organic", "probability": 0.96484375}, {"start": 1850.85, "end": 1852.07, "word": " حتى،", "probability": 0.9098307291666666}, {"start": 1852.07, "end": 1852.65, "word": " بتتفكك", "probability": 0.9466796875}, {"start": 1852.65, "end": 1853.07, "word": " جزئيا", "probability": 0.9864501953125}, {"start": 1853.07, "end": 1853.25, "word": " إذا", "probability": 0.79931640625}, {"start": 1853.25, "end": 1853.45, "word": " كانها", "probability": 0.942138671875}, {"start": 1853.45, "end": 1854.05, "word": " complex،", "probability": 0.75537109375}, {"start": 1854.05, "end": 1854.29, "word": " organic", "probability": 0.8623046875}, {"start": 1854.29, "end": 1855.27, "word": " complex،", "probability": 0.841552734375}, {"start": 1855.27, "end": 1855.73, "word": " بتتفكك", "probability": 0.9765625}, {"start": 1855.73, "end": 1855.99, "word": " جزئيا", "probability": 0.9869384765625}, {"start": 1855.99, "end": 1856.53, "word": " للإيونات", "probability": 0.9073079427083334}, {"start": 1856.53, "end": 1856.95, "word": " تبعتها", "probability": 0.973876953125}, {"start": 1856.95, "end": 1857.05, "word": " إذا", "probability": 0.9248046875}, {"start": 1857.05, "end": 1857.23, "word": " كانت", "probability": 0.983642578125}, {"start": 1857.23, "end": 1857.51, "word": " متكونة", "probability": 0.7630208333333334}, {"start": 1857.51, "end": 1857.61, "word": " من", "probability": 0.9921875}, {"start": 1857.61, "end": 1858.01, "word": " أيونات", "probability": 0.8450927734375}, {"start": 1858.01, "end": 1858.41, "word": " طبعا", "probability": 0.9803466796875}], "temperature": 1.0}, {"id": 84, "seek": 188288, "start": 1858.98, "end": 1882.88, "text": "و بيكون إلها solubility product معين و ال solubility معينة توقف على طبيعتها فممكن طبيعة المادة تكون والله أه ال solubility إلها عالية و ممكن تكون طبيعتها إنها لأ شحيحة شحيحة الذوبان جدا في المي وال solubility تكون إلها إيه منخفضة للغاية فالمواد بتختلف بطبيعتها", "tokens": [2407, 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عشرة أسالم جداش تسعة طب ال KSP لل LED صلفت ايش بده يساوي نتطلع على المثال اللى جابله واحد و ستة فى عشرة أسالم تمانية اذا لو قلنا عليهم أنه أقل صلبية احنا بنقول", "tokens": [10721, 1829, 2407, 11778, 995, 36081, 47525, 3224, 7251, 3794, 995, 45865, 8608, 3555, 27884, 4032, 36764, 24401, 6156, 7578, 6225, 8592, 25720, 5551, 3794, 45340, 10874, 3215, 33599, 6055, 3794, 27884, 23032, 3555, 2423, 591, 27921, 24976, 11261, 20328, 46538, 2655, 1975, 1829, 8592, 47525, 3224, 7251, 3794, 995, 45865, 8717, 2655, 9566, 1211, 3615, 15844, 9673, 12984, 6027, 13672, 7578, 10874, 16758, 43761, 36764, 24401, 4032, 8608, 2655, 3660, 6156, 7578, 6225, 8592, 25720, 5551, 3794, 45340, 46811, 7649, 10632, 1975, 15730, 45164, 12174, 1211, 8315, 25894, 16095, 14739, 3224, 5551, 4587, 1211, 20328, 46152, 10632, 1975, 5016, 8315, 44945, 39648], "avg_logprob": -0.2883112874741738, "compression_ratio": 1.7842105263157895, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 2368.35, "end": 2368.77, 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\ No newline at end of file
diff --git a/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/5whk8TfNHmI_raw.json b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/5whk8TfNHmI_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..cf55f29a87441188cb007de3dac32c66f97b7e17
--- /dev/null
+++ b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/5whk8TfNHmI_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 4483, "start": 21.63, "end": 44.83, "text": "بسم الله الرحمن الرحيم اليوم إذا أراد بنكمل آخر جزئية تمت معانا في ال chapter الماضي ال complexometric reactions و titrations فبنتكلم عن ال fractions of different species أو metal ion species in the presence of ligand", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640, 45595, 20498, 11933, 15730, 5551, 2288, 18513, 44945, 24793, 1211, 19753, 34740, 10874, 11622, 19986, 10632, 46811, 2655, 20449, 7649, 995, 8978, 2423, 7187, 9673, 46958, 1829, 2423, 3997, 29470, 12215, 4032, 3459, 12154, 6156, 3555, 29399, 4117, 19528, 18871, 2423, 36058, 295, 819, 6172, 34051, 5760, 17437, 6172, 294, 264, 6814, 295, 11742, 474], "avg_logprob": -0.2536057692307692, "compression_ratio": 1.4532019704433496, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 21.63, "end": 21.95, "word": "بسم", "probability": 0.797119140625}, {"start": 21.95, "end": 22.11, "word": " الله", "probability": 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عندى اي H+, اذا خلصت بنقول البسط حسب ال alpha والله اذا كان عندى او بدي alpha 0 معناته فش عندى اي تفكك اذا البسط H plus تربيه", "tokens": [3555, 1863, 7435, 1211, 1211, 389, 46797, 46599, 1863, 5016, 9566, 10988, 6156, 3555, 9381, 13546, 10988, 16, 389, 46797, 44945, 7435, 1211, 1211, 9122, 2304, 7649, 389, 46797, 46599, 1863, 5016, 9566, 10988, 6156, 3555, 9381, 13546, 10988, 16, 10988, 17, 16490, 1211, 33546, 6156, 8592, 43242, 7578, 1975, 1829, 389, 46797, 1975, 15730, 16490, 1211, 9381, 2655, 44945, 39648, 29739, 3794, 9566, 11331, 35457, 2423, 8961, 16070, 43761, 1975, 15730, 25961, 43242, 7578, 1975, 2407, 4724, 16254, 8961, 1958, 20449, 8315, 47395, 6156, 8592, 43242, 7578, 1975, 1829, 6055, 5172, 4117, 4117, 1975, 15730, 29739, 3794, 9566, 389, 1804, 6055, 2288, 21292, 3224], "avg_logprob": -0.3172169696047621, "compression_ratio": 1.7845303867403315, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 112.81, "end": 113.45, "word": "بنجلل", "probability": 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"إذا كان بدى الأول تفكك يعني فيه عنده شحنة سالبة واحدة K A1 H Plus إذا كان عندى أو بدى Alpha 2 يعني تاني تفكك K A1 K A2 في البصرة ده كلام شفناه وعرفنا كيف نحسب أو نوجد المعادلة الخاصة بكل fraction بمجرد النظر نفس المنطق فينا يعني انكره رهان بشكل يعني مختلف شوية", "tokens": [28814, 15730, 25961, 47525, 7578, 16247, 12610, 6055, 5172, 4117, 4117, 37495, 22653, 8978, 3224, 43242, 3224, 13412, 5016, 1863, 3660, 8608, 6027, 49401, 36764, 24401, 3660, 591, 316, 16, 389, 7721, 11933, 15730, 25961, 43242, 7578, 34051, 47525, 7578, 20588, 568, 37495, 22653, 6055, 7649, 1829, 6055, 5172, 4117, 4117, 591, 316, 16, 591, 316, 17, 8978, 29739, 9381, 25720, 11778, 3224, 28242, 10943, 13412, 5172, 8315, 3224, 4032, 3615, 28480, 8315, 9122, 33911, 8717, 5016, 35457, 34051, 8717, 29245, 3215, 9673, 3615, 18513, 37977, 33962, 33546, 3660, 4724, 28820, 14135, 4724, 2304, 7435, 2288, 3215, 28239, 19913, 2288, 8717, 36178, 9673, 1863, 9566, 4587, 8978, 8315, 37495, 22653, 16472, 37983, 3224, 12602, 3224, 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المنطق", "probability": 0.98095703125}, {"start": 161.01, "end": 161.79, "word": " فينا", "probability": 0.90087890625}, {"start": 161.79, "end": 162.37, "word": " يعني", "probability": 0.93310546875}, {"start": 162.37, "end": 162.95, "word": " انكره", "probability": 0.85205078125}, {"start": 162.95, "end": 163.23, "word": " رهان", "probability": 0.7841796875}, {"start": 163.23, "end": 163.71, "word": " بشكل", "probability": 0.9666341145833334}, {"start": 163.71, "end": 164.19, "word": " يعني", "probability": 0.947998046875}, {"start": 164.19, "end": 164.61, "word": " مختلف", "probability": 0.9957682291666666}, {"start": 164.61, "end": 165.07, "word": " شوية", "probability": 0.8990885416666666}], "temperature": 1.0}, {"id": 7, "seek": 19084, "start": 166.1, "end": 190.84, "text": "كيف؟ لو قلنا في عندنا silver ion ال silver ion هذا حطناه في محلول أمونيا معروف إن ال silver مع الأمونيا بيكون والله أكتر من complex فمثلا ال silver مع الأمونيا بيعطينا silver ammonia complex وهيقله KF1 وكمان ال silver ammonia complex في وجود أمونيا", "tokens": [4117, 33911, 22807, 45164, 12174, 1211, 8315, 8978, 43242, 8315, 8753, 17437, 2423, 8753, 17437, 23758, 11331, 9566, 8315, 3224, 8978, 3714, 5016, 1211, 12610, 5551, 2304, 11536, 25528, 20449, 32887, 5172, 36145, 2423, 8753, 20449, 16247, 2304, 11536, 25528, 4724, 1829, 30544, 16070, 43761, 5551, 4117, 2655, 2288, 9154, 3997, 6156, 2304, 12984, 15040, 2423, 8753, 20449, 16247, 2304, 11536, 25528, 4724, 40228, 9566, 1829, 8315, 8753, 46833, 3997, 37037, 1829, 4587, 43761, 591, 37, 16, 4032, 24793, 7649, 2423, 8753, 46833, 3997, 8978, 49610, 23328, 5551, 2304, 11536, 25528], "avg_logprob": -0.21076766061394112, "compression_ratio": 1.8883248730964468, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 166.1, "end": 166.88, "word": "كيف؟", "probability": 0.7692057291666666}, {"start": 166.88, "end": 167.22, "word": " لو", "probability": 0.8310546875}, {"start": 167.22, "end": 167.74, "word": " قلنا", "probability": 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" ال", "probability": 0.841796875}, {"start": 182.44, "end": 182.72, "word": " silver", "probability": 0.96728515625}, {"start": 182.72, "end": 182.9, "word": " مع", "probability": 0.99169921875}, {"start": 182.9, "end": 183.48, "word": " الأمونيا", "probability": 0.9525146484375}, {"start": 183.48, "end": 184.12, "word": " بيعطينا", "probability": 0.75595703125}, {"start": 184.12, "end": 184.46, "word": " silver", "probability": 0.87353515625}, {"start": 184.46, "end": 184.92, "word": " ammonia", "probability": 0.8037109375}, {"start": 184.92, "end": 185.62, "word": " complex", "probability": 0.9482421875}, {"start": 185.62, "end": 186.9, "word": " وهيقله", "probability": 0.660919189453125}, {"start": 186.9, "end": 187.6, "word": " KF1", "probability": 0.7023111979166666}, {"start": 187.6, "end": 188.5, "word": " وكمان", "probability": 0.9161783854166666}, {"start": 188.5, "end": 188.66, "word": " ال", "probability": 0.65966796875}, {"start": 188.66, "end": 188.94, "word": " silver", "probability": 0.95751953125}, {"start": 188.94, "end": 189.3, "word": " ammonia", "probability": 0.9716796875}, {"start": 189.3, "end": 189.82, "word": " complex", "probability": 0.93310546875}, {"start": 189.82, "end": 190.0, "word": " في", "probability": 0.63818359375}, {"start": 190.0, "end": 190.28, "word": " وجود", "probability": 0.965576171875}, {"start": 190.28, "end": 190.84, "word": " أمونيا", "probability": 0.9512939453125}], "temperature": 1.0}, {"id": 8, "seek": 21123, "start": 191.65, "end": 211.23, "text": "بيعطيني silver by ammonia اذا ال silver اللي انا حطيته جزء منه المفروض انه ضايل على هيئة silver plus ماتفاعلش جزء منه موجود على هيئة silver ammonia واحدة ammonia بس one ligand silver ammonia وجزء منه موجود على هيئة ايه؟", "tokens": [21292, 3615, 9566, 1829, 22653, 8753, 538, 46833, 1975, 15730, 2423, 8753, 13672, 1829, 1975, 8315, 11331, 9566, 36081, 3224, 10874, 11622, 38207, 9154, 3224, 9673, 5172, 32887, 11242, 16472, 3224, 48812, 995, 26895, 15844, 39896, 19986, 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{"start": 200.13, "end": 201.33, "word": " ماتفاعلش", "probability": 0.8590087890625}, {"start": 201.33, "end": 202.33, "word": " جزء", "probability": 0.91796875}, {"start": 202.33, "end": 202.79, "word": " منه", "probability": 0.98974609375}, {"start": 202.79, "end": 203.27, "word": " موجود", "probability": 0.9873046875}, {"start": 203.27, "end": 203.39, "word": " على", "probability": 0.921875}, {"start": 203.39, "end": 203.63, "word": " هيئة", "probability": 0.9720052083333334}, {"start": 203.63, "end": 204.03, "word": " silver", "probability": 0.7939453125}, {"start": 204.03, "end": 204.97, "word": " ammonia", "probability": 0.94580078125}, {"start": 204.97, "end": 205.91, "word": " واحدة", "probability": 0.9365234375}, {"start": 205.91, "end": 206.29, "word": " ammonia", "probability": 0.69970703125}, {"start": 206.29, "end": 206.63, "word": " بس", "probability": 0.973876953125}, {"start": 206.63, "end": 207.07, "word": " one", "probability": 0.72021484375}, {"start": 207.07, 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0.641357421875}, {"start": 215.3, "end": 216.08, "word": " للسلفر", "probability": 0.892822265625}, {"start": 216.08, "end": 217.06, "word": " بده", "probability": 0.597412109375}, {"start": 217.06, "end": 217.6, "word": " يساوي", "probability": 0.9710693359375}, {"start": 217.6, "end": 218.94, "word": " السلفر", "probability": 0.7705078125}, {"start": 218.94, "end": 219.38, "word": " ايون", "probability": 0.8076171875}, {"start": 219.38, "end": 220.02, "word": " زائد", "probability": 0.7115885416666666}, {"start": 220.02, "end": 220.5, "word": " السلفر", "probability": 0.9500325520833334}, {"start": 220.5, "end": 220.98, "word": " أمونيا", "probability": 0.9306640625}, {"start": 220.98, "end": 221.32, "word": " زائد", "probability": 0.9269205729166666}, {"start": 221.32, "end": 221.74, "word": " السلفر", "probability": 0.96337890625}, {"start": 221.74, "end": 221.82, "word": " داي", "probability": 0.844482421875}, {"start": 221.82, "end": 221.86, "word": " أمونيا", "probability": 0.812744140625}], "temperature": 1.0}, {"id": 10, "seek": 25060, "start": 224.42, "end": 250.6, "text": "طيب السؤال هل يمكن إيجاد علاقة من خلالها بنقدر نوجد تركيز ال silver لحاله جديش عندي silver ماتفاعلش جديش عندي silver اتفاعل بس مع أمونيا واحد جديش عندي silver اتفاعل مع اتنين ligands من الأمونيا هاي السؤال بنقول الإجابة على هذا السؤال كتير بسيطة إذا كان اقدرنا نحسب ال beta values", "tokens": [9566, 1829, 3555, 21136, 33604, 6027, 8032, 1211, 7251, 43020, 11933, 1829, 7435, 18513, 11203, 995, 28671, 9154, 16490, 1211, 6027, 11296, 44945, 28543, 2288, 8717, 29245, 3215, 6055, 31747, 1829, 11622, 2423, 8753, 5296, 5016, 6027, 3224, 10874, 16254, 8592, 18871, 16254, 8753, 3714, 9307, 5172, 995, 30241, 8592, 10874, 16254, 8592, 18871, 16254, 8753, 1975, 2655, 5172, 995, 30241, 4724, 3794, 20449, 5551, 2304, 11536, 25528, 36764, 24401, 10874, 16254, 8592, 18871, 16254, 8753, 1975, 2655, 5172, 995, 30241, 20449, 1975, 2655, 1863, 9957, 11742, 2967, 9154, 16247, 2304, 11536, 25528, 8032, 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ion على التركيز الكلي لل silver يعني ايون ال silver اللي ماتفاعلش اللي ضايل بصورته الأصلية a g plus بدون اي legend على التركيز الكلي ال zero ها دي يعني zero legend مافيش معاه اي legend مافيش معاه اللي لعاله مافيش معاه هاي ال zero", "tokens": [6027, 9861, 4190, 13672, 1829, 1975, 5016, 8315, 47525, 8315, 8717, 5016, 35457, 11296, 2423, 9861, 4018, 50239, 16070, 43761, 39894, 3794, 995, 45865, 2423, 8753, 17437, 15844, 16712, 31747, 1829, 11622, 33251, 20292, 24976, 8753, 37495, 22653, 1975, 1829, 11536, 2423, 8753, 13672, 1829, 3714, 9307, 5172, 995, 30241, 8592, 13672, 1829, 48812, 995, 26895, 4724, 9381, 13063, 47395, 16247, 9381, 20292, 3660, 257, 290, 1804, 47525, 11536, 1975, 1829, 9451, 15844, 16712, 31747, 1829, 11622, 33251, 20292, 2423, 4018, 8032, 995, 11778, 1829, 37495, 22653, 4018, 9451, 19446, 41185, 8592, 20449, 40294, 1975, 1829, 9451, 19446, 41185, 8592, 20449, 40294, 13672, 1829, 5296, 3615, 6027, 3224, 19446, 41185, 8592, 20449, 40294, 8032, 47302, 2423, 4018], 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"الفكرة الأن أن نحاول نشتق أولاقة للـ Beta 0 والـ Beta 1 والـ Beta 2 وانا بدي أعلمكم تشتقوا الأولاقة في البداية و بعدين by inspection لو عندى أي polylegent complex نطلعله الـ Beta values بمجرد النظر زي ما عملنا للأسد ماشي يا شباب؟ فبقول مفتاح الحل يتوقف على هذه المعادلة C للـ Ag بتساوي تركيز الـ Ag Plus زائد الـ Ag Ammonia زائد الـ Ag Di Ammonia أنا لو بدي أديه الـ Beta 0", "tokens": [6027, 5172, 4117, 25720, 16247, 1863, 14739, 8717, 5016, 995, 12610, 8717, 8592, 2655, 4587, 5551, 12610, 995, 28671, 24976, 39184, 33286, 1958, 16070, 39184, 33286, 502, 16070, 39184, 33286, 568, 4032, 7649, 995, 4724, 16254, 5551, 3615, 19528, 24793, 6055, 8592, 2655, 4587, 14407, 16247, 12610, 995, 28671, 8978, 29739, 28259, 10632, 4032, 39182, 9957, 538, 22085, 45164, 43242, 7578, 36632, 6754, 6363, 317, 3997, 8717, 9566, 1211, 30241, 3224, 2423, 39184, 33286, 4190, 4724, 2304, 7435, 2288, 3215, 28239, 19913, 2288, 30767, 1829, 19446, 6225, 42213, 8315, 24976, 10721, 3794, 3215, 3714, 33599, 1829, 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ammonia يعني ال AG ammonia هتسوى KF1 في ال AG plus في ال ammonia", "tokens": [1211, 2407, 47525, 3224, 1975, 7435, 1829, 3555, 2423, 9861, 1958, 2423, 9861, 1958, 11203, 995, 38149, 11296, 20666, 28406, 1804, 20328, 5016, 49429, 5296, 10721, 22807, 1975, 15730, 27188, 4117, 25720, 16472, 1975, 5016, 12610, 28242, 8032, 3215, 12610, 24976, 28406, 1804, 2423, 28406, 1804, 8032, 3215, 11296, 39896, 48812, 995, 26895, 3660, 30767, 1829, 19446, 39896, 16490, 20292, 11296, 30767, 1829, 19446, 39896, 16472, 2423, 28406, 46833, 4724, 1829, 7435, 1829, 9154, 2423, 591, 37, 16, 2423, 591, 37, 16, 39894, 3794, 45865, 28406, 46833, 6225, 2423, 28406, 1804, 8978, 2423, 46833, 37495, 22653, 2423, 28406, 46833, 8032, 2655, 3794, 2407, 7578, 591, 37, 16, 8978, 2423, 28406, 1804, 8978, 2423, 46833], "avg_logprob": -0.22581521272659302, "compression_ratio": 2.0096153846153846, "no_speech_prob": 2.384185791015625e-07, "words": [{"start": 435.22, "end": 435.46, "word": "لو", "probability": 0.86572265625}, 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"probability": 0.402587890625}, {"start": 449.1, "end": 449.3, "word": " ال", "probability": 0.9658203125}, {"start": 449.3, "end": 449.58, "word": " AG", "probability": 0.859375}, {"start": 449.58, "end": 450.08, "word": " ammonia", "probability": 0.810546875}, {"start": 450.08, "end": 451.2, "word": " بيجي", "probability": 0.95703125}, {"start": 451.2, "end": 451.34, "word": " من", "probability": 0.72412109375}, {"start": 451.34, "end": 451.5, "word": " ال", "probability": 0.80712890625}, {"start": 451.5, "end": 452.34, "word": " KF1", "probability": 0.7379557291666666}, {"start": 452.34, "end": 452.62, "word": " ال", "probability": 0.759765625}, {"start": 452.62, "end": 453.16, "word": " KF1", "probability": 0.97998046875}, {"start": 453.16, "end": 453.66, "word": " بتسوي", "probability": 0.7022298177083334}, {"start": 453.66, "end": 454.0, "word": " AG", "probability": 0.9404296875}, {"start": 454.0, "end": 454.5, "word": " ammonia", "probability": 0.98095703125}, {"start": 454.5, "end": 454.98, "word": " ع", "probability": 0.61669921875}, {"start": 454.98, "end": 455.08, "word": " ال", "probability": 0.66748046875}, {"start": 455.08, "end": 455.32, "word": " AG", "probability": 0.94482421875}, {"start": 455.32, "end": 455.66, "word": " plus", "probability": 0.89501953125}, {"start": 455.66, "end": 455.82, "word": " في", "probability": 0.90576171875}, {"start": 455.82, "end": 455.9, "word": " ال", "probability": 0.72216796875}, {"start": 455.9, "end": 456.18, "word": " ammonia", "probability": 0.986328125}, {"start": 456.18, "end": 456.64, "word": " يعني", "probability": 0.88623046875}, {"start": 456.64, "end": 457.16, "word": " ال", "probability": 0.943359375}, {"start": 457.16, "end": 457.54, "word": " AG", "probability": 0.96826171875}, {"start": 457.54, "end": 458.42, "word": " ammonia", "probability": 0.9873046875}, {"start": 458.42, "end": 459.24, "word": " هتسوى", "probability": 0.84912109375}, {"start": 459.24, "end": 459.88, "word": " KF1", 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"probability": 0.8912760416666666}, {"start": 553.12, "end": 553.36, "word": " زي", "probability": 0.978759765625}, {"start": 553.36, "end": 553.46, "word": " ال", "probability": 0.96142578125}, {"start": 553.46, "end": 553.62, "word": " alpha", "probability": 0.85546875}, {"start": 553.62, "end": 554.12, "word": " values", "probability": 0.92333984375}], "temperature": 1.0}, {"id": 25, "seek": 57771, "start": 555.89, "end": 577.71, "text": "ببدأ بشوف اكم اكم legend مع ال metal ion مثلا نولي اكون عندي هنا انا silver ammonia معروف في اتنين بس انت باهي معايا بقول ببدأ بواحد صحيح يعني فيش عندي اي legend فيش عندي اي legend بعدين بقول", "tokens": [3555, 44510, 10721, 4724, 8592, 38688, 1975, 24793, 1975, 24793, 9451, 20449, 2423, 5760, 17437, 50113, 15040, 8717, 12610, 1829, 1975, 30544, 18871, 16254, 34105, 1975, 8315, 8753, 46833, 20449, 32887, 5172, 8978, 1975, 2655, 1863, 9957, 4724, 3794, 16472, 2655, 4724, 40294, 1829, 20449, 995, 25528, 4724, 39648, 4724, 44510, 10721, 4724, 14407, 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{"start": 568.57, "end": 568.75, "word": " انت", "probability": 0.896728515625}, {"start": 568.75, "end": 568.95, "word": " باهي", "probability": 0.6199544270833334}, {"start": 568.95, "end": 569.21, "word": " معايا", "probability": 0.8023274739583334}, {"start": 569.21, "end": 570.13, "word": " بقول", "probability": 0.9482421875}, {"start": 570.13, "end": 570.59, "word": " ببدأ", "probability": 0.7701822916666666}, {"start": 570.59, "end": 570.87, "word": " بواحد", "probability": 0.9778645833333334}, {"start": 570.87, "end": 571.33, "word": " صحيح", "probability": 0.998046875}, {"start": 571.33, "end": 571.63, "word": " يعني", "probability": 0.927734375}, {"start": 571.63, "end": 571.85, "word": " فيش", "probability": 0.7236328125}, {"start": 571.85, "end": 572.13, "word": " عندي", "probability": 0.755615234375}, {"start": 572.13, "end": 572.29, "word": " اي", "probability": 0.882080078125}, {"start": 572.29, "end": 572.65, "word": " legend", "probability": 0.9716796875}, {"start": 572.65, "end": 574.09, "word": " فيش", "probability": 0.682373046875}, {"start": 574.09, "end": 574.39, "word": " عندي", "probability": 0.91650390625}, {"start": 574.39, "end": 574.65, "word": " اي", "probability": 0.95947265625}, {"start": 574.65, "end": 575.17, "word": " legend", "probability": 0.97998046875}, {"start": 575.17, "end": 577.15, "word": " بعدين", "probability": 0.919677734375}, {"start": 577.15, "end": 577.71, "word": " بقول", "probability": 0.992431640625}], "temperature": 1.0}, {"id": 26, "seek": 60753, "start": 579.33, "end": 607.53, "text": "في عندي اتكون complex legend واحد اول complex يعني زي ال silver يعني عندي هان ع سبيل المثال a g plus وفي عندي a g ammonia هاي ال fraction هاي ال .. ال .. ال .. ال complexes اللي اتكونت a g di ammonia خد بالك هان فيش عندي اي legend هاي واحد صحيح", "tokens": [41185, 18871, 16254, 1975, 2655, 30544, 3997, 9451, 36764, 24401, 1975, 12610, 3997, 37495, 22653, 30767, 1829, 2423, 8753, 37495, 22653, 18871, 16254, 8032, 7649, 6225, 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603.63, "word": " ammonia", "probability": 0.7314453125}, {"start": 603.63, "end": 604.57, "word": " خد", "probability": 0.960205078125}, {"start": 604.57, "end": 605.03, "word": " بالك", "probability": 0.953125}, {"start": 605.03, "end": 605.49, "word": " هان", "probability": 0.888427734375}, {"start": 605.49, "end": 605.75, "word": " فيش", "probability": 0.704833984375}, {"start": 605.75, "end": 605.99, "word": " عندي", "probability": 0.91650390625}, {"start": 605.99, "end": 606.13, "word": " اي", "probability": 0.850341796875}, {"start": 606.13, "end": 606.47, "word": " legend", "probability": 0.9736328125}, {"start": 606.47, "end": 606.83, "word": " هاي", "probability": 0.789794921875}, {"start": 606.83, "end": 607.07, "word": " واحد", "probability": 0.9912109375}, {"start": 607.07, "end": 607.53, "word": " صحيح", "probability": 0.996826171875}], "temperature": 1.0}, {"id": 27, "seek": 63316, "start": 609.58, "end": 633.16, "text": "كويس؟ هان في عندي legend واحد اذا formation اتكون عندي complex KF1 في الأمونيا هان عندي اتنين يعني KF1 و بعدين كمان KF2 لإن اصلا عندي ايه؟ two legends KF1 KF2 الأمونيا كم واحدة عندي؟ تنتين اذا تنتين اتنين يعني أمونيا تربية", "tokens": [4117, 45865, 3794, 22807, 8032, 7649, 8978, 18871, 16254, 9451, 36764, 24401, 1975, 15730, 11723, 1975, 2655, 30544, 18871, 16254, 3997, 591, 37, 16, 8978, 16247, 2304, 11536, 25528, 8032, 7649, 18871, 16254, 1975, 2655, 1863, 9957, 37495, 22653, 591, 37, 16, 4032, 39182, 9957, 9122, 2304, 7649, 591, 37, 17, 5296, 28814, 1863, 1975, 9381, 15040, 18871, 16254, 1975, 1829, 3224, 22807, 732, 27695, 591, 37, 16, 591, 37, 17, 16247, 2304, 11536, 25528, 9122, 2304, 36764, 24401, 3660, 18871, 16254, 22807, 6055, 29399, 9957, 1975, 15730, 6055, 29399, 9957, 1975, 2655, 1863, 9957, 37495, 22653, 5551, 2304, 11536, 25528, 6055, 25513, 10632], "avg_logprob": -0.22500000227065314, "compression_ratio": 1.797979797979798, "no_speech_prob": 0.0, "words": [{"start": 609.5799999999999, "end": 610.54, "word": "كويس؟", 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0.919921875}, {"start": 617.48, "end": 618.12, "word": " الأمونيا", "probability": 0.80712890625}, {"start": 618.12, "end": 620.08, "word": " هان", "probability": 0.78857421875}, {"start": 620.08, "end": 620.5, "word": " عندي", "probability": 0.938232421875}, {"start": 620.5, "end": 621.12, "word": " اتنين", "probability": 0.9608154296875}, {"start": 621.12, "end": 621.4, "word": " يعني", "probability": 0.91650390625}, {"start": 621.4, "end": 622.18, "word": " KF1", "probability": 0.8396809895833334}, {"start": 622.18, "end": 622.4, "word": " و", "probability": 0.60791015625}, {"start": 622.4, "end": 622.78, "word": " بعدين", "probability": 0.847900390625}, {"start": 622.78, "end": 623.1, "word": " كمان", "probability": 0.9853515625}, {"start": 623.1, "end": 624.04, "word": " KF2", "probability": 0.9759114583333334}, {"start": 624.04, "end": 624.66, "word": " لإن", "probability": 0.8059895833333334}, {"start": 624.66, "end": 624.88, "word": " اصلا", "probability": 0.6913248697916666}, {"start": 624.88, "end": 625.16, "word": " عندي", "probability": 0.9248046875}, {"start": 625.16, "end": 625.72, "word": " ايه؟", "probability": 0.831787109375}, {"start": 625.72, "end": 626.02, "word": " two", "probability": 0.697265625}, {"start": 626.02, "end": 626.4, "word": " legends", "probability": 0.72314453125}, {"start": 626.4, "end": 627.04, "word": " KF1", "probability": 0.9248046875}, {"start": 627.04, "end": 627.84, "word": " KF2", "probability": 0.8313802083333334}, {"start": 627.84, "end": 628.7, "word": " الأمونيا", "probability": 0.85986328125}, {"start": 628.7, "end": 628.92, "word": " كم", "probability": 0.9072265625}, {"start": 628.92, "end": 629.18, "word": " واحدة", "probability": 0.9505208333333334}, {"start": 629.18, "end": 630.12, "word": " عندي؟", "probability": 0.8444010416666666}, {"start": 630.12, "end": 630.48, "word": " تنتين", "probability": 0.723388671875}, {"start": 630.48, "end": 630.64, "word": " اذا", "probability": 0.783935546875}, {"start": 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بعدين KF1 في ال legend KF1 KF2 في ال legend تربية KF1 KF2 KF3 في ال legend تكييب وهكذا لما تخلص عدد ال legends اللي عندك ماشي يا شباب ابدأ بواحد دائما في ال beta values تبدأ بواحد لإن مافيش عندك اي legend مافيش عندك اي formation لسه يعني", "tokens": [6027, 20292, 47525, 4117, 39896, 8032, 2655, 5016, 9566, 11296, 8978, 2423, 1255, 4724, 3794, 6225, 28480, 2655, 9122, 33911, 6055, 30544, 9673, 4587, 10943, 22807, 39896, 21136, 33604, 6027, 39896, 21136, 33604, 6027, 6055, 44510, 10721, 4724, 14407, 24401, 39182, 9957, 591, 37, 16, 8978, 2423, 9451, 591, 37, 16, 591, 37, 17, 8978, 2423, 9451, 6055, 25513, 10632, 591, 37, 16, 591, 37, 17, 591, 37, 18, 8978, 2423, 9451, 6055, 4117, 1829, 1829, 3555, 37037, 4117, 15730, 5296, 15042, 6055, 9778, 1211, 9381, 6225, 3215, 3215, 2423, 27695, 13672, 1829, 43242, 4117, 3714, 33599, 1829, 35186, 13412, 3555, 16758, 1975, 44510, 10721, 4724, 14407, 24401, 11778, 16373, 15042, 8978, 2423, 9861, 4190, 6055, 44510, 10721, 4724, 14407, 24401, 5296, 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"temperature": 1.0}, {"id": 53, "seek": 124494, "start": 1218.7, "end": 1244.94, "text": "لو إيجينا قولنا مثلا AGI هذا مادة صلبة silver iodide تعطينا A G plus زائد I سالب ايش بيحصل لما نحط عليها H plus برتقط مع اليوت يعني بدي أقول H plus زائد I سالب HI طب برتقطش مع الفضة؟", "tokens": [1211, 2407, 11933, 1829, 7435, 1829, 8315, 12174, 12610, 8315, 50113, 15040, 316, 26252, 23758, 3714, 18513, 3660, 20328, 46152, 3660, 8753, 44422, 482, 37279, 9566, 1829, 8315, 316, 460, 1804, 30767, 16373, 3215, 286, 8608, 6027, 3555, 1975, 1829, 8592, 4724, 1829, 5016, 36520, 5296, 15042, 8717, 5016, 9566, 25894, 11296, 389, 1804, 4724, 43500, 4587, 9566, 20449, 45595, 35473, 37495, 22653, 4724, 16254, 5551, 39648, 389, 1804, 30767, 16373, 3215, 286, 8608, 6027, 3555, 44376, 23032, 3555, 4724, 43500, 4587, 9566, 8592, 20449, 27188, 11242, 3660, 22807], "avg_logprob": -0.2607638782925076, "compression_ratio": 1.5591397849462365, "no_speech_prob": 0.0, "words": [{"start": 1218.7, "end": 1219.72, "word": 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خليني اطلع على مثال خليني اطلع على مثال", "tokens": [3615, 23942, 1975, 1829, 11331, 6027, 2423, 591, 4952, 39894, 3794, 995, 45865, 2423, 318, 8978, 2423, 5691, 16, 50, 20449, 28242, 10943, 2423, 318, 39894, 3794, 995, 45865, 25724, 11622, 2288, 16712, 2288, 21292, 3615, 1829, 24976, 591, 4952, 15844, 2423, 5691, 16, 8717, 36178, 2423, 28820, 10943, 13672, 1829, 1975, 5016, 8315, 12174, 1211, 8315, 3224, 8608, 16758, 4587, 995, 24976, 20918, 5954, 473, 12174, 36150, 13412, 2407, 10632, 16490, 1211, 9957, 1829, 1975, 9566, 1211, 3615, 15844, 50113, 6027, 16490, 1211, 9957, 1829, 1975, 9566, 1211, 3615, 15844, 50113, 6027], "avg_logprob": -0.2240691416441126, "compression_ratio": 1.7679558011049723, "no_speech_prob": 1.1920928955078125e-07, "words": [{"start": 1835.31, "end": 1835.61, "word": "على", "probability": 0.932861328125}, {"start": 1835.61, "end": 1835.79, "word": " اي", "probability": 0.5504150390625}, {"start": 1835.79, "end": 1836.19, "word": " حال", "probability": 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207139, "start": 2048.91, "end": 2071.39, "text": "الـ Ksp S Alpha 2 S الـ S بيساوي جزر التربيه على الـ Ksp على الـ Alpha 2 لو عوضت عن الـ Ksp و الـ Alpha 2 تحت الجزر بيعطينا 2 و 1 في 10 أقل سالب 4 ماشي يا شباب إذن ال solubility 2 و 1 في 10 أقل سالب 4 molar لو جلك هتلي ال solubility بالجرام ع ال letter إيه إيش بدك تعمل؟", "tokens": [6027, 39184, 591, 4952, 318, 20588, 568, 318, 2423, 39184, 318, 4724, 1829, 3794, 995, 45865, 10874, 11622, 2288, 16712, 2288, 21292, 3224, 15844, 2423, 39184, 591, 4952, 15844, 2423, 39184, 20588, 568, 45164, 6225, 2407, 11242, 2655, 18871, 2423, 39184, 591, 4952, 4032, 2423, 39184, 20588, 568, 6055, 33753, 25724, 11622, 2288, 4724, 40228, 9566, 1829, 8315, 568, 4032, 502, 8978, 1266, 5551, 4587, 1211, 8608, 6027, 3555, 1017, 3714, 33599, 1829, 35186, 13412, 3555, 16758, 11933, 8848, 1863, 2423, 1404, 836, 1140, 568, 4032, 502, 8978, 1266, 5551, 4587, 1211, 8608, 6027, 3555, 1017, 45712, 45164, 10874, 23275, 8032, 2655, 20292, 2423, 1404, 836, 1140, 20666, 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التربيع الى Ksp بتساوي 5 و 1 في 10 عقل سالم 5 لو اجينا نقارن هذا الرقم بهذا الرقم ايش بنلاقي؟", "tokens": [9566, 3555, 3615, 995, 8717, 11242, 25513, 8978, 2423, 1254, 84, 875, 3364, 5296, 33456, 29538, 6353, 15844, 2733, 1975, 8315, 4724, 16254, 8592, 6353, 4724, 16254, 4295, 4724, 11242, 25513, 8978, 2423, 8513, 3364, 23032, 1829, 3555, 45164, 1975, 7435, 1829, 8315, 35186, 13412, 3555, 16758, 11331, 35457, 8315, 2423, 1404, 836, 1140, 8978, 9673, 1829, 3224, 9673, 7435, 2655, 25720, 29538, 8032, 2655, 30544, 318, 37037, 24192, 8032, 2655, 30544, 318, 1975, 15730, 2423, 318, 39894, 3794, 995, 45865, 25724, 11622, 2288, 16712, 2288, 21292, 3615, 2423, 7578, 591, 4952, 39894, 3794, 995, 45865, 1025, 4032, 502, 8978, 1266, 6225, 4587, 1211, 8608, 45340, 1025, 45164, 1975, 7435, 1829, 8315, 8717, 4587, 9640, 1863, 23758, 34892, 4587, 2304, 39627, 15730, 34892, 4587, 2304, 1975, 1829, 8592, 44945, 15040, 38436, 22807], "avg_logprob": -0.2953477362941082, "compression_ratio": 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"word": " بيقول", "probability": 0.74267578125}, {"start": 2163.6, "end": 2163.92, "word": " find", "probability": 0.6884765625}, {"start": 2163.92, "end": 2164.1, "word": " the", "probability": 0.837890625}, {"start": 2164.1, "end": 2164.56, "word": " solubility", "probability": 0.9482421875}, {"start": 2164.56, "end": 2164.78, "word": " of", "probability": 0.97412109375}, {"start": 2164.78, "end": 2165.14, "word": " silver", "probability": 0.85107421875}, {"start": 2165.14, "end": 2165.8, "word": " phosphate", "probability": 0.92529296875}, {"start": 2165.8, "end": 2166.92, "word": " at", "probability": 0.87353515625}, {"start": 2166.92, "end": 2167.34, "word": " pH", "probability": 0.818359375}, {"start": 2167.34, "end": 2167.94, "word": " 3", "probability": 0.73486328125}, {"start": 2167.94, "end": 2169.18, "word": " علما", "probability": 0.79345703125}, {"start": 2169.18, "end": 2169.54, "word": " بإن", "probability": 0.7443033854166666}, {"start": 2169.54, "end": 2169.72, "word": " ال", "probability": 0.7177734375}, {"start": 2169.72, "end": 2169.94, "word": " alpha", "probability": 0.4814453125}, {"start": 2169.94, "end": 2170.28, "word": " 3", "probability": 0.64697265625}, {"start": 2170.28, "end": 2170.5, "word": " at", "probability": 0.87353515625}, {"start": 2170.5, "end": 2170.84, "word": " pH", "probability": 0.9833984375}, {"start": 2170.84, "end": 2171.38, "word": " 3", "probability": 0.88037109375}, {"start": 2171.38, "end": 2172.5, "word": " بتساوي", "probability": 0.6812744140625}, {"start": 2172.5, "end": 2174.6, "word": " 33×10−14", "probability": 0.5206705729166666}, {"start": 2174.6, "end": 2175.36, "word": " وال", "probability": 0.494384765625}, {"start": 2175.36, "end": 2175.92, "word": " Ksp", "probability": 0.82373046875}, {"start": 2175.92, "end": 2178.18, "word": " 13×10−20", "probability": 0.7994791666666666}, {"start": 2178.18, "end": 2178.94, "word": " انتبه", "probability": 0.66741943359375}, {"start": 2178.94, "end": 2179.48, "word": " شوية", "probability": 0.8966471354166666}, {"start": 2179.48, "end": 2180.36, "word": " لو", "probability": 0.81201171875}, {"start": 2180.36, "end": 2181.74, "word": " لو", "probability": 0.392333984375}, {"start": 2181.74, "end": 2183.36, "word": " احتاج", "probability": 0.9329427083333334}, {"start": 2183.36, "end": 2183.76, "word": " الأمر", "probability": 0.805908203125}, {"start": 2183.76, "end": 2184.48, "word": " لإنك", "probability": 0.9259033203125}, {"start": 2184.48, "end": 2185.6, "word": " تستخدم", "probability": 0.991943359375}, {"start": 2185.6, "end": 2185.74, "word": " ال", "probability": 0.9365234375}, {"start": 2185.74, "end": 2185.96, "word": " alpha", "probability": 0.85595703125}, {"start": 2185.96, "end": 2186.38, "word": " 3", "probability": 0.953125}], "temperature": 1.0}, {"id": 90, "seek": 219391, "start": 2187.39, "end": 2193.91, "text": "فانا عادة بعطيك قيمتها او ال alpha 4 برضه بعطيك قيمتها لكن alpha 1 و alpha 2 انت بتحسبها", "tokens": [5172, 7649, 995, 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"seek": 221975, "start": 2196.85, "end": 2219.75, "text": "اذ كان بده يجيك حسابات تستخدم Alpha 3 او Alpha 4 انا بعطيك هذه القيمة لان مانديش تضيع وقتك في الاشتقاق والحسابات فانا بعطيك قيمة لكن لو كان Alpha 1 او Alpha 2 انا طول بتنحل فانا بعتقد ان انت تقدر تعملها بسهولة على اي حال بدنا نجد solubility لل silver phosphate في ايه؟", "tokens": [45636, 25961, 47525, 3224, 7251, 7435, 1829, 4117, 11331, 3794, 16758, 9307, 6055, 14851, 9778, 40448, 20588, 805, 1975, 2407, 20588, 1017, 1975, 8315, 4724, 3615, 9566, 1829, 4117, 29538, 25062, 32640, 3660, 5296, 7649, 3714, 7649, 16254, 8592, 6055, 11242, 40228, 4032, 38149, 4117, 8978, 2423, 33599, 2655, 4587, 995, 4587, 16070, 5016, 3794, 16758, 9307, 6156, 7649, 995, 4724, 3615, 9566, 1829, 4117, 12174, 32640, 3660, 44381, 45164, 25961, 20588, 502, 1975, 2407, 20588, 568, 1975, 8315, 23032, 12610, 39894, 1863, 5016, 1211, 6156, 7649, 995, 4724, 34268, 28543, 16472, 16472, 2655, 6055, 28543, 2288, 6055, 25957, 1211, 11296, 4724, 3794, 3224, 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القصر ان هذه تلاتة S وهذه كلها S لكن الفوسفات للأسف تتجزأ تتجزأ كل هذا", "tokens": [41185, 8258, 3827, 10874, 6027, 1829, 1975, 4117, 4724, 1829, 1975, 2655, 8592, 6055, 1211, 9307, 3660, 23032, 3555, 11331, 1211, 2407, 9122, 2655, 13546, 4724, 39648, 8032, 47302, 2423, 8753, 6156, 41779, 5172, 9307, 37279, 9566, 1829, 8315, 6055, 1211, 9307, 3660, 8753, 30767, 16373, 3215, 6156, 41779, 5172, 9307, 25062, 9381, 2288, 16472, 29538, 6055, 1211, 9307, 3660, 318, 37037, 24192, 28242, 11296, 318, 44381, 27188, 41779, 5172, 9307, 24976, 10721, 3794, 5172, 6055, 2655, 7435, 11622, 10721, 6055, 2655, 7435, 11622, 10721, 28242, 23758], "avg_logprob": -0.23757102679122577, "compression_ratio": 1.6761363636363635, "no_speech_prob": 0.0, "words": [{"start": 2220.7, "end": 2220.92, "word": "في", "probability": 0.70556640625}, {"start": 2220.92, "end": 2221.22, "word": " acid", "probability": 0.464111328125}, {"start": 2221.22, "end": 2221.84, "word": " solution", "probability": 0.93798828125}, 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"word": " يعني", "probability": 0.647216796875}, {"start": 2621.09, "end": 2621.51, "word": " بيطلع", "probability": 0.9220703125}, {"start": 2621.51, "end": 2621.77, "word": " ان", "probability": 0.484375}, {"start": 2621.77, "end": 2622.49, "word": " ال", "probability": 0.93994140625}, {"start": 2622.49, "end": 2622.69, "word": " S", "probability": 0.927734375}, {"start": 2622.69, "end": 2623.25, "word": " بتساوي", "probability": 0.8619384765625}, {"start": 2623.25, "end": 2623.77, "word": " الجزر", "probability": 0.8997395833333334}, {"start": 2623.77, "end": 2624.51, "word": " الرابع", "probability": 0.98046875}, {"start": 2624.51, "end": 2625.49, "word": " لل", "probability": 0.568359375}, {"start": 2625.49, "end": 2626.59, "word": " KSP", "probability": 0.5419921875}, {"start": 2626.59, "end": 2627.17, "word": " على", "probability": 0.703125}], "temperature": 1.0}, {"id": 110, "seek": 265367, "start": 2628.37, "end": 2653.67, "text": "27 beta 0 تكييب وهيك بيطلع عنا عموما يعني solubility عالية جدا برضه في وجود concentrated solution من ال legend إذا الله راد يعني إحنا بنوقفان وإذا الله راد الحصة الجاية بتكمل ناخد أمثلة الحصة الجاية إذا الله راد", "tokens": [10076, 9861, 1958, 6055, 4117, 1829, 1829, 3555, 37037, 1829, 4117, 4724, 1829, 9566, 1211, 3615, 6225, 8315, 6225, 2304, 2407, 15042, 37495, 22653, 1404, 836, 1140, 6225, 6027, 10632, 10874, 28259, 4724, 43042, 3224, 8978, 49610, 23328, 21321, 3827, 9154, 2423, 9451, 11933, 15730, 21984, 12602, 18513, 37495, 22653, 11933, 5016, 8315, 44945, 30543, 5172, 7649, 4032, 28814, 15730, 21984, 12602, 18513, 21542, 9381, 3660, 25724, 995, 10632, 39894, 24793, 1211, 8717, 47283, 3215, 5551, 2304, 12984, 37977, 21542, 9381, 3660, 25724, 995, 10632, 11933, 15730, 21984, 12602, 18513], "avg_logprob": -0.21840659144160512, "compression_ratio": 1.688118811881188, "no_speech_prob": 6.735324859619141e-06, "words": [{"start": 2628.37, "end": 2629.33, "word": "27", "probability": 0.146240234375}, {"start": 2629.33, "end": 2630.15, "word": " beta", "probability": 0.272216796875}, {"start": 2630.15, "end": 2630.75, "word": " 0", "probability": 0.46533203125}, {"start": 2630.75, "end": 2632.17, "word": " تكييب", "probability": 0.75859375}, {"start": 2632.17, "end": 2634.39, "word": " وهيك", "probability": 0.7169596354166666}, {"start": 2634.39, "end": 2634.77, "word": " بيطلع", "probability": 0.88466796875}, {"start": 2634.77, "end": 2635.09, "word": " عنا", "probability": 0.5787353515625}, {"start": 2635.09, "end": 2635.85, "word": " عموما", "probability": 0.9027099609375}, {"start": 2635.85, "end": 2636.35, "word": " يعني", "probability": 0.6064453125}, {"start": 2636.35, "end": 2637.97, "word": " solubility", "probability": 0.86083984375}, {"start": 2637.97, "end": 2639.01, "word": " عالية", "probability": 0.9777018229166666}, {"start": 2639.01, "end": 2639.41, "word": " جدا", "probability": 0.99462890625}, {"start": 2639.41, "end": 2639.79, "word": " برضه", "probability": 0.912109375}, {"start": 2639.79, "end": 2639.93, "word": " في", "probability": 0.83837890625}, {"start": 2639.93, "end": 2640.37, "word": " وجود", "probability": 0.972412109375}, {"start": 2640.37, "end": 2641.53, "word": " concentrated", "probability": 0.49072265625}, {"start": 2641.53, "end": 2642.93, "word": " solution", "probability": 0.95849609375}, {"start": 2642.93, "end": 2643.41, "word": " من", "probability": 0.98779296875}, {"start": 2643.41, "end": 2643.75, "word": " ال", "probability": 0.7626953125}, {"start": 2643.75, "end": 2644.11, "word": " legend", "probability": 0.43310546875}, {"start": 2644.11, "end": 2644.65, "word": " إذا", "probability": 0.8154296875}, {"start": 2644.65, "end": 2644.87, "word": " الله", "probability": 0.9013671875}, {"start": 2644.87, "end": 2645.31, "word": " راد", "probability": 0.5535888671875}, {"start": 2645.31, "end": 2646.45, "word": " يعني", "probability": 0.776123046875}, {"start": 2646.45, "end": 2646.77, "word": " إحنا", "probability": 0.8107096354166666}, {"start": 2646.77, "end": 2647.65, "word": " بنوقفان", "probability": 0.887939453125}, {"start": 2647.65, "end": 2648.71, "word": " وإذا", "probability": 0.8658854166666666}, {"start": 2648.71, "end": 2648.93, "word": " الله", "probability": 0.96435546875}, {"start": 2648.93, "end": 2649.35, "word": " راد", "probability": 0.98876953125}, {"start": 2649.35, "end": 2650.01, "word": " الحصة", "probability": 0.99267578125}, {"start": 2650.01, "end": 2650.55, "word": " الجاية", "probability": 0.9119466145833334}, {"start": 2650.55, "end": 2651.39, "word": " بتكمل", "probability": 0.8640950520833334}, {"start": 2651.39, "end": 2652.11, "word": " ناخد", "probability": 0.91357421875}, {"start": 2652.11, "end": 2652.45, "word": " أمثلة", "probability": 0.93701171875}, {"start": 2652.45, "end": 2652.75, "word": " الحصة", "probability": 0.865234375}, {"start": 2652.75, "end": 2653.05, "word": " الجاية", "probability": 0.9739583333333334}, {"start": 2653.05, "end": 2653.23, "word": " إذا", "probability": 0.98046875}, {"start": 2653.23, "end": 2653.41, "word": " الله", "probability": 0.97314453125}, {"start": 2653.41, "end": 2653.67, "word": " راد", "probability": 0.982177734375}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2654.87675, "duration_after_vad": 2530.5156249999886}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/6wMKSdBbxPs_raw.srt b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/6wMKSdBbxPs_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..8d913336a965e3fccaafa559caf5345d0025b2b3
--- /dev/null
+++ b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/6wMKSdBbxPs_raw.srt
@@ -0,0 +1,1612 @@
+1
+00:00:20,650 --> 00:00:24,870
+بسم الله الرحمن الرحيم اليوم إذا الله راد بنكمل في
+
+2
+00:00:24,870 --> 00:00:29,470
+ال complexometric reactions و titrations في الحصة
+
+3
+00:00:29,470 --> 00:00:35,530
+الماضية كنا اتكلمنا عن تفاعل كمية زائدة من ال
+
+4
+00:00:35,530 --> 00:00:42,160
+calcium مع ال EDTAو بعدين اتكلمنا عن تفاعل كمية
+
+5
+00:00:42,160 --> 00:00:47,280
+مكافئة من ال calcium مع ال EDTA اليوم بنكمل في نفس
+
+6
+00:00:47,280 --> 00:00:52,200
+الاتجاه لكن قبل ما ندرس الحالة التالتة في حالة ما
+
+7
+00:00:52,200 --> 00:00:58,260
+يكون كمية ال EDTA هي الزائدة بدنا نرجع لورا شوية و
+
+8
+00:00:58,260 --> 00:01:04,440
+نحاول نأكد على بعض المفاهيم البسيطة اتكلمنا عن ال
+
+9
+00:01:04,440 --> 00:01:09,130
+tighter في المحاضرات الماضية في شباتر المقدمةو هان
+
+10
+00:01:09,130 --> 00:01:14,270
+بس بنأكد على كيفية حساب ال title لأنه زي ما انتوا
+
+11
+00:01:14,270 --> 00:01:21,670
+عارفين في المعامل او المخابر المختلفة بنعمل آلاف
+
+12
+00:01:21,670 --> 00:01:26,230
+التجارب الخاصة بال EDTA titrations فعلشان نتريح
+
+13
+00:01:26,230 --> 00:01:32,350
+شوية من الحسابات كويس كتير انه يعني يكون عندنا ال
+
+14
+00:01:32,350 --> 00:01:38,340
+titleلل EDTA مش التركيز لأن معايا التركيز بدي اضطر
+
+15
+00:01:38,340 --> 00:01:42,720
+ان اعمل حسابات لكل ال titrations اللي انا بديها
+
+16
+00:01:42,720 --> 00:01:46,500
+بينما لو كان عندى ال titer على طول من المعايرة
+
+17
+00:01:46,500 --> 00:01:50,020
+بعرف جداش الحجم مضربه في ال titer بطلعلي اكم
+
+18
+00:01:50,020 --> 00:01:55,700
+milligram calcium مثلا carbonate في حالة ما اكون
+
+19
+00:01:55,700 --> 00:02:00,060
+بتطلع على عصر المياه اللي هي اكتر تجارب بتنعمل
+
+20
+00:02:00,060 --> 00:02:05,870
+باستخدام ال EDTA في الوقت الحاضرفبس مراجعة كيفية
+
+21
+00:02:05,870 --> 00:02:09,270
+حساب ال title نطلع على المثال اللي قدامي بيقول
+
+22
+00:02:09,270 --> 00:02:15,120
+calculatethe title of a 0.1 molar EDTA solution in
+
+23
+00:02:15,120 --> 00:02:20,420
+terms of milligram calcium carbonate ومعطينا ال
+
+24
+00:02:20,420 --> 00:02:26,080
+formula weight 100 milligram per mole طبعا per mil
+
+25
+00:02:26,080 --> 00:02:33,280
+EDTA هذا كلام مهم كتير علشان نقدر يعني نعمل
+
+26
+00:02:33,280 --> 00:02:36,000
+حساباتنا بشكل سهل وسريع
+
+27
+00:02:38,640 --> 00:02:44,180
+عصر المياه عادة يا شباب بنجيثه بالملي جرام كالسيوم
+
+28
+00:02:44,180 --> 00:02:47,600
+كربونيت حتى انت لما عملت تجربة في المختبر عملت
+
+29
+00:02:47,600 --> 00:02:54,060
+تجربة وعيرت الميه باستخدام ال EBT او الاريكروم
+
+30
+00:02:54,060 --> 00:03:01,370
+بلاك تي انديكاتورفانت في هذه الحالة بتوجد تركيز ال
+
+31
+00:03:01,370 --> 00:03:05,390
+calcium وال magnesium الموجودين في الميه و بتعمل
+
+32
+00:03:05,390 --> 00:03:08,350
+report الاصل اللي لك تعمل report لنتائج تبعتك
+
+33
+00:03:08,350 --> 00:03:12,550
+اتنين يعني الاصل الميه الكلي على هيئة calcium
+
+34
+00:03:12,550 --> 00:03:18,780
+carbonateفالتعبير عن عصر المياه عادة بيتم باستخدام
+
+35
+00:03:18,780 --> 00:03:22,580
+milligram كالسيوم carbonate على اي حال الفكرة الآن
+
+36
+00:03:22,580 --> 00:03:27,080
+هي فقط كيف احسب ال titer بقول في حساب ال titer بدي
+
+37
+00:03:27,080 --> 00:03:30,180
+اشوف ال millimole زي ما شوفنا سابقا ال millimole
+
+38
+00:03:30,180 --> 00:03:34,640
+من ال titrantأيش بيكافح أو أيش بيساوي من ال
+
+39
+00:03:34,640 --> 00:03:39,720
+millimoles من ال analyte فبقول millimole calcium
+
+40
+00:03:39,720 --> 00:03:43,600
+carbonate بيساوي millimole EDTA هذا وضع طبيعي لأن
+
+41
+00:03:43,600 --> 00:03:48,600
+ال calcium بيتفاعل بنسبة واحد لواحد مع ال EDTA و
+
+42
+00:03:48,600 --> 00:03:51,180
+أنا عندي calcium carbonate ال calcium carbonate هو
+
+43
+00:03:51,180 --> 00:03:54,840
+بس واحد calcium إذا millimole calcium carbonate
+
+44
+00:03:54,840 --> 00:03:59,390
+بتساوي millimole EDTAالكالسيوم كربونيت تعاوض عنها
+
+45
+00:03:59,390 --> 00:04:02,710
+ملي موالز معروفة واحد من اتنين يا اما ملي جرام على
+
+46
+00:04:02,710 --> 00:04:05,450
+الفورمولاويت يا اما molarity و volume فعندها انا
+
+47
+00:04:05,450 --> 00:04:08,530
+اكيد ملي جرام على الفورمولاويت لان انا بدي الملي
+
+48
+00:04:08,530 --> 00:04:12,950
+جرام فبقول ملي جرام على الفورمولاويت مية طب الملي
+
+49
+00:04:12,950 --> 00:04:16,840
+مول ايه دي ايجا ال molarity1 من 10 في ال volume
+
+50
+00:04:16,840 --> 00:04:21,960
+وقلنا احنا في حساب ال titrate ال volume تبعنا 1 مل
+
+51
+00:04:21,960 --> 00:04:26,620
+لانه انا بدي اعرف اكم milligram per mil من ال
+
+52
+00:04:26,620 --> 00:04:33,340
+titrate وبالتالي دائما هذا عبارة عن 1 مل هيك بطلع
+
+53
+00:04:33,340 --> 00:04:36,560
+عندي ال milligram calcium carbonate per mil EDTA
+
+54
+00:04:36,560 --> 00:04:41,340
+10 هذا هو ال titrateإيش معنى هذا الكلام؟ معنى هذا
+
+55
+00:04:41,340 --> 00:04:46,140
+الكلام إنه لو عملت معايرة أخدت مثلا تمانية مل EDTA
+
+56
+00:04:46,140 --> 00:04:52,040
+معناته أنا عندى تمانين ملي جرام كالسيوم كربونيت
+
+57
+00:04:52,040 --> 00:04:57,180
+اقول يا شباب لو عملنا معايرة أخدت خمستعشر مل من ال
+
+58
+00:04:57,180 --> 00:05:00,780
+EDTA معناته عندنا مية وخمسين ملي جرام كالسيوم
+
+59
+00:05:00,780 --> 00:05:06,240
+كربونيت لو عملنا معايرة أخدت سبعتعش وتمانية من
+
+60
+00:05:06,240 --> 00:05:13,970
+عشرةمل من ال EDTA معناته عند 178 من أفضل الطرق
+
+61
+00:05:13,970 --> 00:05:18,570
+المستخدمة لعمل standardization لل EDTA هي تفاعلها
+
+62
+00:05:18,570 --> 00:05:23,870
+مع ال calcium carbonate لكن ال calcium carbonate
+
+63
+00:05:23,870 --> 00:05:28,930
+بحد ذاتها لا تذوب في الماء هي الطباشير لا تذوب في
+
+64
+00:05:28,930 --> 00:05:34,080
+الماء علشان هيكأنا باخد وزنة معينة من ال calcium
+
+65
+00:05:34,080 --> 00:05:39,220
+carbonate و بدوبها في HCl طبعا carbonate مع ال HCl
+
+66
+00:05:39,220 --> 00:05:42,700
+فورا بتفعل فيه فورا و بتطلع ثانو أكسيد الكربون
+
+67
+00:05:42,700 --> 00:05:46,800
+فبيدوب او بتدوب ال calcium carbonate في ال HCl
+
+68
+00:05:46,800 --> 00:05:51,480
+بعدين بظبط ال pH عند 10 لأن ال calcium احنا شفنا
+
+69
+00:05:51,480 --> 00:05:56,740
+في المختبر انه بنعينه او بنعيره عند pH 10 فبظبط ال
+
+70
+00:05:56,740 --> 00:06:00,380
+pH عند pH 10 بالبعفة شوية sodium hydroxide او اي
+
+71
+00:06:00,380 --> 00:06:07,920
+buffer مثلاوبعدين بعايرمحلول الكلسيوم هذا بال EDTA
+
+72
+00:06:07,920 --> 00:06:12,280
+وبعمل الحسابات تبعتي ليش ال calcium carbonate
+
+73
+00:06:12,280 --> 00:06:21,080
+تحديدا تعتبر من المواد الجيدة جدا في استخدامها
+
+74
+00:06:21,080 --> 00:06:25,860
+لمعايرة ال EDTA جان لأن ال calcium carbonate يمكن
+
+75
+00:06:25,860 --> 00:06:30,740
+الحصول عليها بنقاوة عالية للغاية عالية جدا نقية
+
+76
+00:06:30,740 --> 00:06:37,410
+نحصل بشكل نقي تقريبا 100%علشان هيك تقدير تركيز ال
+
+77
+00:06:37,410 --> 00:06:43,050
+EDTA بيكون يعني قريب جدا من الصحة كويس كتير غير عن
+
+78
+00:06:43,050 --> 00:06:46,790
+مواد أخرى يمكن استخدامها بشكل كبير احنا ممكن
+
+79
+00:06:46,790 --> 00:06:50,050
+نستخدم في المختبر أسهل نستخدم ال magnesium
+
+80
+00:06:50,050 --> 00:06:54,990
+chloride أو ال zinc chloride لكن ال calcium
+
+81
+00:06:54,990 --> 00:07:04,750
+carbonate نتائجها تعتبر عادة أفضل فنتطلع علىنتقل
+
+82
+00:07:04,750 --> 00:07:08,650
+على المعايير
+
+83
+00:07:08,650 --> 00:07:16,270
+التالية وهذا المثال يعبر عن طريقة العملية لتقدير
+
+84
+00:07:16,270 --> 00:07:21,150
+تركيز ال EDTA فنقول An EDTA solution is
+
+85
+00:07:21,150 --> 00:07:25,230
+standardized against high purity calcium carbonate
+
+86
+00:07:25,230 --> 00:07:33,340
+by dissolving0.3982 اربع من عشرة جرام من كالسيوم
+
+87
+00:07:33,340 --> 00:07:37,020
+كاربونيت في الهش سيئيل ماعندي خيار لأن الكالسيوم
+
+88
+00:07:37,020 --> 00:07:40,580
+كاربونيت لا تذوب في الماء فبحط عليها شوية هش سيئيل
+
+89
+00:07:40,580 --> 00:07:47,440
+جداش مش مش مهم لأنه انا بعد شوية بدي أضيف صوديوم
+
+90
+00:07:47,440 --> 00:07:50,600
+هيدروكسايد هي و جالنا and adjusting the pH to 10
+
+91
+00:07:50,600 --> 00:07:54,340
+فانا بعد ما حطيت ال acid دهبط حطيت صوديوم
+
+92
+00:07:54,340 --> 00:07:59,520
+هيدروكسايد زبطت ال pH مثلا لإيه؟ لعشرةبقول the
+
+93
+00:07:59,520 --> 00:08:03,880
+solution is then titrated with EDTA بعد هيك بعد ما
+
+94
+00:08:03,880 --> 00:08:09,720
+حصلنا على المحلول عيرنا بال EDTA فأخد 38.26% من ال
+
+95
+00:08:09,720 --> 00:08:14,540
+mill فعايز يحسب المدارس إلى ال EDTA كمان مرة بنقول
+
+96
+00:08:14,540 --> 00:08:18,060
+milli mole calcium carbonate بتسوى milli mole EDTA
+
+97
+00:08:18,060 --> 00:08:23,920
+طريقة حساباتنا احنا بنعرف بس يا اما milli moleيا
+
+98
+00:08:23,920 --> 00:08:26,760
+إما equilibrium constant هذا مش مثلة equilibrium
+
+99
+00:08:26,760 --> 00:08:31,360
+فانا هدف الحلب الملي مول لا خلاف فأقول ملي مول
+
+100
+00:08:31,360 --> 00:08:34,220
+calcium carbonate طبعا تتفاعل واحد لواحد مع ال
+
+101
+00:08:34,220 --> 00:08:39,380
+EDTA إذا بتسوى ملي مول EDTA ال carbonate والله
+
+102
+00:08:39,380 --> 00:08:43,360
+milligram على ال formula weight ال EDTA is
+
+103
+00:08:43,360 --> 00:08:47,940
+molarity of volume ال milligram معايا 398.2
+
+104
+00:08:47,940 --> 00:08:53,140
+milligram ال formula weight 100الـMolarity مجهولة،
+
+105
+00:08:53,140 --> 00:08:58,300
+الـVolume معاها حجم الأخر 38% والـ26%، إذا
+
+106
+00:08:58,300 --> 00:09:04,860
+المolarity للـEDTA 0.1041 هذه هي الطريقة تفاعل
+
+107
+00:09:04,860 --> 00:09:09,160
+الـmetal ions مع الـEDTA، واخدنا الكالسيوم كمثال،
+
+108
+00:09:09,160 --> 00:09:13,240
+أي معدن يعتبر بنفس الطريقة، أي metal ion آخر يعتبر
+
+109
+00:09:13,240 --> 00:09:16,920
+بنفس الطريقة، لكنأحنا أخدنا الكالسيوم تالب كان
+
+110
+00:09:16,920 --> 00:09:20,800
+الكالسيوم مكافئ بالظبط لل EDTA هذا المثال لأ في
+
+111
+00:09:20,800 --> 00:09:28,320
+EDTA زيادة فنشوف كيفية الحساب في هذه الحالة المثال
+
+112
+00:09:28,320 --> 00:09:32,320
+بيقول التالي find the concentration of calcium in
+
+113
+00:09:32,320 --> 00:09:37,600
+a 20 ml of 0.2 molar solution at pH 10 بيعطينا ال
+
+114
+00:09:37,600 --> 00:09:43,150
+pH جديش لأن ال alpha تعتمد على ال pHafter addition
+
+115
+00:09:43,150 --> 00:09:48,010
+of 100 ml of 0.1 molar EDTA فانا حطيت 20 ml من 0.2
+
+116
+00:09:48,010 --> 00:09:51,450
+molar كالسيوم و حطيت عليهم 100 ml من 0.1 molar
+
+117
+00:09:51,450 --> 00:09:55,910
+EDTA ماعطيني معلومة alpha 4 at pH 10 لازم يعطيها
+
+118
+00:09:55,910 --> 00:10:01,770
+اللي او يعطيني ال K's ال K is تبعت ال EDTA طبعا
+
+119
+00:10:01,770 --> 00:10:04,570
+احنا قولنا اذا كان يعني اكتر من alpha 2 هيعطيني
+
+120
+00:10:04,570 --> 00:10:08,790
+القيمة تبعتها فال alpha 4 بيقولي 0.35 وال K is 5
+
+121
+00:10:08,790 --> 00:10:14,880
+في 10 أقصى 10لازم نفهم يا شباب بداية ان الكالسيوم
+
+122
+00:10:14,880 --> 00:10:19,580
+بتفاعل مع ال EDTA اذا بدنا نشوف والله جداش بيزيد
+
+123
+00:10:19,580 --> 00:10:24,680
+من الكالسيوم او جداش بيزيد من ال EDTA كمان بيتكون
+
+124
+00:10:24,680 --> 00:10:27,580
+كالسيوم EDTA بدنا نشوف جداش بتكون كالسيوم EDTA
+
+125
+00:10:27,580 --> 00:10:32,120
+فبنقول millimole EDTA excess عشرة ناقص اربعة ستة
+
+126
+00:10:32,120 --> 00:10:36,040
+millimole EDTA excess اذا ال total concentration
+
+127
+00:10:36,040 --> 00:10:42,770
+لل EDTAهي عبارة عن 6 على 120 يعني 120 يبقى 0.05
+
+128
+00:10:42,770 --> 00:10:49,010
+مولار يبقى زاد عندي في المحلول EDTA كله مقداره 0
+
+129
+00:10:49,010 --> 00:10:55,960
+.05 مولار الان الملي مول كالسيوم Y2-طبعاً أربعة
+
+130
+00:10:55,960 --> 00:11:01,440
+ليه؟ لأن الكالسيوم كله اتحول لكالسيوم Y2- إذا
+
+131
+00:11:01,440 --> 00:11:05,660
+تركيز الكالسيوم Y2- أربعة أيضا على مائة و عشرين
+
+132
+00:11:05,660 --> 00:11:14,000
+بيعطينا point O33 لو إجينا، هتقولنا كالسيوم زائد
+
+133
+00:11:14,000 --> 00:11:19,960
+Y4- بيعطينا كالسيوم Y2- عند هذه أربعة، هذه عشرة،
+
+134
+00:11:19,960 --> 00:11:24,870
+هذه صفر، هذه صفر، هذه ستة، هذه أربعةأه يا شباب حتى
+
+135
+00:11:24,870 --> 00:11:29,890
+يعني على طول بدهاش كل هال أسطور اللي كتبناها سهلة
+
+136
+00:11:29,890 --> 00:11:33,570
+خالص لكن لازم نكتبها بالذات في الامتحان اما ان هي
+
+137
+00:11:33,570 --> 00:11:37,530
+على طول يعني ايش اللي اتفاعل جداش ضايل منه ايش
+
+138
+00:11:37,530 --> 00:11:40,730
+اللي اتكون سهل كتير بعدين نقسم على total volume
+
+139
+00:11:40,730 --> 00:11:46,750
+بيعطينا ايه التركيز الان بدي اوجد تركيز ال calcium
+
+140
+00:11:48,900 --> 00:11:52,720
+فبقول والله ال calcium هو خلص لكن مانفعش يخلص يعني
+
+141
+00:11:52,720 --> 00:11:57,000
+يكون صفر ليه؟ لأنه في عندي كمية من ال calcium
+
+142
+00:11:57,000 --> 00:12:01,780
+بتيجي من تفكك ال calcium Y2- ليه؟ علشان ال Kf
+
+143
+00:12:01,780 --> 00:12:07,550
+دائما أي محلول at equilibrium ال Kf لهكالسيوم Y2-
+
+144
+00:12:07,550 --> 00:12:35,990
+على الكالسيوم Y4-
+
+145
+00:12:36,590 --> 00:12:41,990
+هن بدها تصير هذه X هن هذي بتنزل زي ما هي point O5
+
+146
+00:12:41,990 --> 00:12:45,670
+الان باستخدام ال formation constant expression
+
+147
+00:12:45,670 --> 00:12:50,870
+بقول والله point O33 minus X اللي هي النواتج على
+
+148
+00:12:50,870 --> 00:12:56,270
+ال X في alpha 4 في point O5 زائد X والان بفرض ان
+
+149
+00:12:56,270 --> 00:13:01,670
+ال point O33 أكبر كتير من ال X بطلع قيمة ال X بتاع
+
+150
+00:13:01,670 --> 00:13:07,450
+3.9 في 10 أقل ثالث ب11تلاتة وتسعة فعشرة أسالب أحد
+
+151
+00:13:07,450 --> 00:13:11,210
+عشر هل بالفعل العشرة أسالب أحد عشر أقل كتير من
+
+152
+00:13:11,210 --> 00:13:15,850
+التلاتة من المائة طبعا أقل كتير حتى يعني by
+
+153
+00:13:15,850 --> 00:13:18,770
+inspection فانا بقول the assumption is valid by
+
+154
+00:13:18,770 --> 00:13:24,310
+مجرد النظر يعني بالتفحص البسيط يعني بعرف أن ال X
+
+155
+00:13:24,310 --> 00:13:30,560
+قليلة جدايمكن إلغاءها، مافي مشكلة، الـ X يبقى
+
+156
+00:13:30,560 --> 00:13:34,060
+الفرضية صحيحة، يبقى الـ X هي الكالسيوم، معناه كلام
+
+157
+00:13:34,060 --> 00:13:37,360
+الكالسيوم بيساوي تلاتة وتسعة في عشرة أقصال ب11
+
+158
+00:13:37,360 --> 00:13:40,880
+مولار، و ال P للكالسيوم، يعني مايناس له بتركيز
+
+159
+00:13:40,880 --> 00:13:45,880
+الكالسيوم، بيساوي عشرة واحد وأربعين، يبقى هذه
+
+160
+00:13:45,880 --> 00:13:50,900
+الحالة التالتة لمن يكون عند ال EDTA زيادة، كويس يا
+
+161
+00:13:50,900 --> 00:14:02,370
+شباب؟الان بدي اطلع على مثال يجمع
+
+162
+00:14:02,370 --> 00:14:08,370
+التلت حالات لما ال calcium يكون زيادة لما يكون
+
+163
+00:14:08,370 --> 00:14:12,590
+متكافئين لما ال EDTA يكون زيادة اللي هو مثال
+
+164
+00:14:12,590 --> 00:14:18,180
+بعتبره مثال معايرةهذا هو المثال اللي تطبيق على
+
+165
+00:14:18,180 --> 00:14:22,880
+الكلام اللي أخدناه كله، الآن هنلخصه بحل مسألة
+
+166
+00:14:22,880 --> 00:14:30,080
+المعايرة اللي قدامي بقول في المثال find PCA يعني
+
+167
+00:14:30,080 --> 00:14:33,940
+minus لب تركيز الكالسيوم in a hundred ml solution
+
+168
+00:14:33,940 --> 00:14:42,560
+of point one molar calcium يعني في عندي ناخده هاي
+
+169
+00:14:42,560 --> 00:14:54,230
+ميت ميل0.1 مولار كالسيون بدي اعير ب
+
+170
+00:14:54,230 --> 00:15:01,970
+EDTA حلو بقول at pH 10 عشان التفاعل بيتم at pH 10
+
+171
+00:15:02,860 --> 00:15:09,000
+كويس after addition of 0 25 50 100 150 and 200 ml
+
+172
+00:15:09,000 --> 00:15:14,620
+of 0.1 molar EDTA يعني بعد إضافات متعددة أول إضافة
+
+173
+00:15:14,620 --> 00:15:17,860
+عن صفر بعدين قبل نقطة النهاية عند نقطة النهاية بعد
+
+174
+00:15:17,860 --> 00:15:22,760
+نقطة النهاية كويس ومعطينها ال alpha 4 at pH 10 0
+
+175
+00:15:22,760 --> 00:15:28,400
+.35 و ال KF 5 ف10 أقصى عشرة جميع أنواع معاييرات ال
+
+176
+00:15:28,400 --> 00:15:32,650
+EDTA بتتم بنفس الطريقةفقط اللى بتغير اسم الـ metal
+
+177
+00:15:32,650 --> 00:15:37,090
+ion وإذا تغير اسم الـ metal ion بتغير الـ Kf تبعه
+
+178
+00:15:37,090 --> 00:15:41,930
+لكن الحسابات هي هي و أيضا ممكن تتغير ال pH إذا
+
+179
+00:15:41,930 --> 00:15:45,570
+تغيرت ال pH ال alpha 4 بتتغير لكن ال alpha 4 و ال
+
+180
+00:15:45,570 --> 00:15:48,570
+pH 10 ثابتة لإنه متوقفش اللي غير على ال
+
+181
+00:15:48,570 --> 00:15:53,370
+equilibrium constants لل EDTA و ال H plus وال
+
+182
+00:15:53,370 --> 00:15:56,810
+equilibrium constants EDTA ثابتةإذا فقط توقف على
+
+183
+00:15:56,810 --> 00:16:02,150
+الـ H+, فإذا تغيرت الـ pH الـ α4، بتتغير، إذا تغير
+
+184
+00:16:02,150 --> 00:16:06,680
+الـmetal ion، الـKf تبعه بيتغيروبالتالي نفس
+
+185
+00:16:06,680 --> 00:16:10,880
+الحسابات اللى هنشوفها هي الحسابات اللى بتنطبق على
+
+186
+00:16:10,880 --> 00:16:15,060
+أي metal ion ممكن يمر معانا عشان هيك نصحى كويس
+
+187
+00:16:15,060 --> 00:16:20,660
+لأنه سؤال زى هذا الاصل أنه نقدر نحل لو إجالنا في
+
+188
+00:16:20,660 --> 00:16:24,760
+الامتحان لل calcium أو لغير ال calcium نفس الكلام
+
+189
+00:16:24,760 --> 00:16:25,660
+مافرجش
+
+190
+00:16:27,930 --> 00:16:32,990
+طيب نيجي نقول على طول after addition of 0 من ال
+
+191
+00:16:32,990 --> 00:16:37,570
+EDTA أنا بدي أحسب تركيز الكالسيوم بقول قبل إضافة
+
+192
+00:16:37,570 --> 00:16:43,350
+أي EDTA جديش تركيز الكالسيوم 1 من 10 ماتغيرش إذا
+
+193
+00:16:43,350 --> 00:16:48,050
+كان تركيز الكالسيوم 1 من 10 يبقى ال PCA minus log
+
+194
+00:16:48,050 --> 00:16:54,430
+1 من 10 يعني 1 minus log 1 من 10 يعني 1 معنى كامل
+
+195
+00:16:54,430 --> 00:17:02,890
+PCA ب1 يعني لو جينا هانقلنا هاي ال mail EDTA او
+
+196
+00:17:02,890 --> 00:17:07,510
+titrate يعني EDTA وهي
+
+197
+00:17:07,510 --> 00:17:13,730
+ال P لـCA ال P دائما يا شباب بتكتب بحرف صغير مش
+
+198
+00:17:13,730 --> 00:17:18,170
+capital small letter مش capital letter ماشي يا
+
+199
+00:17:18,170 --> 00:17:25,090
+شباب فبقول عن صفر كانت ال PCA واحد هذا quatration
+
+200
+00:17:25,090 --> 00:17:30,990
+curveعندي في ال titration curve ال P لـ CA مع ال
+
+201
+00:17:30,990 --> 00:17:38,110
+mil EDTA فقلنا انه عند صفر قبل ما اضيف اي calcium
+
+202
+00:17:38,110 --> 00:17:43,550
+اي EDTA عفوا كان تركيز ال calcium واحد من عشرة
+
+203
+00:17:43,550 --> 00:17:50,650
+يعني ال PCA واحد طيب نيجي الان نضيف اضافة غير
+
+204
+00:17:50,650 --> 00:17:56,120
+الصفر فخليني اخد 25 mil من ال EDTAأيش بيحصل عند
+
+205
+00:17:56,120 --> 00:18:00,820
+ضافة 25 مل من ال EDT؟ أنا بعرف أنه عندي كالسيون 10
+
+206
+00:18:00,820 --> 00:18:04,820
+ملي مول point one في مية يعني عشرة point one في
+
+207
+00:18:04,820 --> 00:18:12,140
+مية يعني عشرة طيب جداش اضافت عليه EDT ايه؟ اه 25
+
+208
+00:18:12,140 --> 00:18:16,640
+ملي بيجي point one في 25 بيجي 2.5 ملي مول جداش
+
+209
+00:18:16,640 --> 00:18:21,990
+كالسيون تبقى 7.5أذا ال calcium left 7.5 على ال
+
+210
+00:18:21,990 --> 00:18:25,290
+total volume التركيز ال millimole على ال total
+
+211
+00:18:25,290 --> 00:18:33,170
+volume 7.5 على 125 بتسوي 0.06 هذا الايه؟ ال
+
+212
+00:18:33,170 --> 00:18:39,110
+calcium المتبقي ال calcium المتبقي طب لو أجينا
+
+213
+00:18:39,110 --> 00:18:46,020
+احنا سألة حالة سؤال هل جيت في المحلول؟الكالسيوم هو
+
+214
+00:18:46,020 --> 00:18:48,980
+فقط الكالسيوم المتبقى ولا فيه كمان كالسيوم جاى من
+
+215
+00:18:48,980 --> 00:18:54,400
+تفكك الكالسيوم Y2-؟ أنا بس اتكلم عن الكالسيوم اللى
+
+216
+00:18:54,400 --> 00:18:59,080
+فى المحلول اه يعنى بعد ما اتفاعلوا اه تبقى والله 0
+
+217
+00:18:59,080 --> 00:19:03,140
+.06 مولار كالسيوم لكن هل هذا هو كل الكالسيوم اللى
+
+218
+00:19:03,140 --> 00:19:07,960
+فى المحلول؟ لأ فى جزء جاى من وين؟ من الكالسيوم Y2-
+
+219
+00:19:07,960 --> 00:19:12,440
+لكن يا شباب بقول ان هذا الجزء قليل جدا ليه؟ جاى
+
+220
+00:19:12,440 --> 00:19:13,500
+لأنه الـKf
+
+221
+00:19:16,460 --> 00:19:20,860
+عالي كتير عشرة أقص عشرة لما يكون ال K إفعالي
+
+222
+00:19:20,860 --> 00:19:27,340
+قابلية ال calcium y2 minus inها تعطيني x بتكون
+
+223
+00:19:27,340 --> 00:19:27,880
+قليلة
+
+224
+00:19:30,430 --> 00:19:33,830
+صح ولا لأ؟ لأن الـKF كبير، بتحب تتكوّر، بتحب مش
+
+225
+00:19:33,830 --> 00:19:38,910
+تتفكك، هي معناه stable، الـKF كبير يعني stable،
+
+226
+00:19:38,910 --> 00:19:42,430
+هذه نقطة، في نقطة تانية يمكن أهم منها أو بتوازيها
+
+227
+00:19:42,430 --> 00:19:47,450
+في الأهمية، إنه زاد عندي كالسيوم point O6، طب لما
+
+228
+00:19:47,450 --> 00:19:50,090
+بيزيد كالسيوم، كيف ال equilibrium بيمشي؟
+
+229
+00:19:53,620 --> 00:19:56,600
+يعني هذا الـ Calcium Y تمارس إله خاطر يعطيني فرص
+
+230
+00:19:56,600 --> 00:20:01,280
+small amount من الـ X لكن مجرد وجود Calcium زيادة
+
+231
+00:20:01,280 --> 00:20:04,100
+بيخلي التفاعل يمشي .. بيخلي كمان قيمة الـ X هذه
+
+232
+00:20:04,100 --> 00:20:08,980
+أشمالها تقل علشان هيك .. أه تقل بشكل ملحوظ للغاية
+
+233
+00:20:08,980 --> 00:20:13,080
+علشان هيك تقريبا بنقدر نقول أن قبل نقطة النهاية
+
+234
+00:20:13,080 --> 00:20:17,300
+كمية الـ Calcium الموجودة في المحلول هي الكمية
+
+235
+00:20:17,300 --> 00:20:24,060
+الزائدة أو المتبقية من الـ Calciumبمعنى أخر
+
+236
+00:20:24,060 --> 00:20:29,300
+الكالسيوم Y2- لا تشارك بأي كمية محسوسة من
+
+237
+00:20:29,300 --> 00:20:36,620
+الكالسيوم نتيجة تفكك يعني لا تشارك طيب عشان احنا
+
+238
+00:20:36,620 --> 00:20:41,140
+نكون متأكدين بدنا نحسب كمية الكالسيوم اللى جاية من
+
+239
+00:20:41,140 --> 00:20:44,980
+تفكك الكالسيوم Y2- ونشوف هل بالفعل هي كمية مهمة لا
+
+240
+00:20:44,980 --> 00:20:51,380
+ولا لأ ماشي يا شبابأحنا حسبنا كمية الكالسيوم لفترة
+
+241
+00:20:51,380 --> 00:20:55,320
+عندنا 0.06 طب مين يقول يجديش كالسيوم Y2- تكون؟
+
+242
+00:20:57,540 --> 00:21:01,020
+والان من الـ Kf expression اللى فىش عيننا غيره
+
+243
+00:21:01,020 --> 00:21:05,540
+لأنه مدام مسألة equilibrium بتنحل على طول من وين
+
+244
+00:21:05,540 --> 00:21:09,860
+فورا من ال K او ال equilibrium constant expression
+
+245
+00:21:09,860 --> 00:21:14,600
+فانا عندي ال calcium زائد y4 minus بيعطينا calcium
+
+246
+00:21:14,600 --> 00:21:20,460
+y2 minus هذا عندي 0.06 قبل الإتزان هذا عندي 0.02
+
+247
+00:21:20,460 --> 00:21:25,310
+قبل الإتزان بدى أشوف بعد الإتزان ببدأ من هذاليش
+
+248
+00:21:25,310 --> 00:21:30,010
+منها؟ لأن الـKF كبير، فبقول الـpoint O2 بدها تقل
+
+249
+00:21:30,010 --> 00:21:35,090
+بمقدار X، هذا بنزل زي ما هو، لكن بزيد بمقدار X من
+
+250
+00:21:35,090 --> 00:21:40,030
+وين جاية؟ من تفكك الـCalcium Y2-، هذا بدوا يعطيني
+
+251
+00:21:40,030 --> 00:21:44,930
+X، بس الـX هي الـEDTA كلها، أنا بدي Y4 is an Alpha
+
+252
+00:21:44,930 --> 00:21:51,270
+4 من الـX هي الـY4-,هك بقدر اطبق ال formation
+
+253
+00:21:51,270 --> 00:21:56,070
+constant و اعوض عن القيم في السطر الأخير بيقول
+
+254
+00:21:56,070 --> 00:21:59,770
+point o2 minus x على point o6 زاد x في ال alpha
+
+255
+00:21:59,770 --> 00:22:03,650
+for x و بفترض ان ال point o2 اكبر كتير من ال x ال
+
+256
+00:22:03,650 --> 00:22:07,960
+x بتطلع عندى جداشلاحظ جداش صغيرة، لاحظ 9×10 أو
+
+257
+00:22:07,960 --> 00:22:12,480
+سالب 11 هل يمكن مقارنتها بال point O2؟ لأ ال point
+
+258
+00:22:12,480 --> 00:22:17,600
+O2 أكبر كتير من ال X ال X كمية مهملة جدا جدا زاد
+
+259
+00:22:17,600 --> 00:22:23,480
+تفكر علشان هيك بنقول، طيب ال X صغيرة جدا، إذا ال
+
+260
+00:22:23,480 --> 00:22:27,520
+calcium بدي سوى point O6 زاد ال X، ال X لا تجمع،
+
+261
+00:22:27,520 --> 00:22:32,680
+إذا point O6 و ال PCA 1.22، دي في جهية النقطة
+
+262
+00:22:32,680 --> 00:22:34,720
+التانية 1.22
+
+263
+00:22:37,290 --> 00:22:41,330
+ماشي يا شباب، بدي أعيد نفس الكلام، بدي أضيف خمسين
+
+264
+00:22:41,330 --> 00:22:47,690
+مل، بدي أضيف خمسين مل من ال EDTA، فبقول والله أنا
+
+265
+00:22:47,690 --> 00:22:51,390
+عندي ال millimol EDTA added خمسة، جدش عندي
+
+266
+00:22:51,390 --> 00:22:55,070
+millimol كالسيوم عشرة، إذا ال millimol calcium
+
+267
+00:22:55,070 --> 00:22:59,350
+left عشرة ناقص خمسة بزيد خمسة، أنا أعملك هدول بنفس
+
+268
+00:22:59,350 --> 00:23:02,470
+اللون، إذا كانت بلاحظ، عشان مشبوحهم دايما عشرة
+
+269
+00:23:03,380 --> 00:23:06,300
+مجموعهم دايما عشرة لإن هذا ال calcium ال calcium
+
+270
+00:23:06,300 --> 00:23:09,080
+عشرة millimole زاد منه خمسة و اين راحوا الخمسة
+
+271
+00:23:09,080 --> 00:23:13,920
+التانية؟ اتحولوا ل calcium Y2- طيب إذا ال calcium
+
+272
+00:23:13,920 --> 00:23:17,880
+left هو خمسة على ال total volume خمسين و مية يعني
+
+273
+00:23:17,880 --> 00:23:21,660
+مية و خمسين باطين ال point O33 فهذا ال calcium نفس
+
+274
+00:23:21,660 --> 00:23:28,810
+الطريقة بقول إن ال Kf عالي كتيرعشان هيك متوقع ان
+
+275
+00:23:28,810 --> 00:23:31,230
+ال X اللي جاية اللي هي الكالسيوم اللي جاية من
+
+276
+00:23:31,230 --> 00:23:36,510
+الكالسيوم يكون قليلا جدا لكن هذه الكمية هتكون اقل
+
+277
+00:23:36,510 --> 00:23:40,910
+كتير من هيك لأن في عندي كالسيوم فده هو point O33
+
+278
+00:23:40,910 --> 00:23:44,670
+كالسيوم هذا هيخلي كمان التفاعل يمشي للامان اذا ال
+
+279
+00:23:44,670 --> 00:23:49,310
+X هتكون كمية مهمة للغاية قليلة جدا جدا جدا هيك
+
+280
+00:23:49,310 --> 00:23:54,410
+بتوقع انا عشان هيك النتيجة بتوقع انهالكالسيوم
+
+281
+00:23:54,410 --> 00:23:59,570
+تركيزه في المحلول يساوي تركيز الكالسيوم المتبقي
+
+282
+00:23:59,570 --> 00:24:05,210
+فقطبمعنى انه مافيش عندى اى calcium جاى من ال
+
+283
+00:24:05,210 --> 00:24:10,550
+calcium y2 minus بشكل يعني ملحوظ لأ مهمل كميته
+
+284
+00:24:10,550 --> 00:24:16,630
+مهملة لكن مع ذلك مع ذلك بدي احسبه عشان احسبه بقول
+
+285
+00:24:16,630 --> 00:24:19,490
+من اللي بقول calcium y2 minus formed خمسة معنى
+
+286
+00:24:19,490 --> 00:24:23,490
+الكلام انه تركيز ال calcium y2 minus خمسة على مية
+
+287
+00:24:23,490 --> 00:24:28,490
+وخمسين او point O33الان بدى احسب كمية الكلسيوم
+
+288
+00:24:28,490 --> 00:24:33,030
+اللى جاية بالفعل من الكلسيوم y2- وانا بعرف انه
+
+289
+00:24:33,030 --> 00:24:38,050
+هتكون كمية ايش مالها مهمة للغاية فمن المعادلة
+
+290
+00:24:38,050 --> 00:24:43,790
+calcium زائد y4- calcium y2- اندي point 0.033 صفر
+
+291
+00:24:43,790 --> 00:24:49,530
+خلصت point 0.033 ببدأ من هنا لأن ال Kf كبير فبقول
+
+292
+00:24:49,530 --> 00:24:53,890
+point 0.033 minus x بتقل المقدار x على طول هن بجيب
+
+293
+00:24:53,890 --> 00:25:00,630
+xوهن بجيب X لكن ال Y-Format هي α4 من ال X كويس
+
+294
+00:25:00,630 --> 00:25:03,490
+فبطبق ال equilibrium constant او ال formation
+
+295
+00:25:03,490 --> 00:25:08,870
+constant expression بلاقي انه 0.033 minus X على 0
+
+296
+00:25:08,870 --> 00:25:14,070
+.033 زاد X في ال α4 X بفترض ان ال 0.033 أكبر كتير
+
+297
+00:25:14,070 --> 00:25:18,590
+من ال X ال X بتطلع عندى 5 و 7 في 10 أقل سالب 11
+
+298
+00:25:19,950 --> 00:25:24,670
+خمسة و سبعة في عشرة أس سالب إحدى عشر معنى الكلام
+
+299
+00:25:24,670 --> 00:25:28,270
+واضح أن العشرة أس سالب أحد عشر أقل كتير من التلاتة
+
+300
+00:25:28,270 --> 00:25:31,990
+من مية العشرة أس سالب أحد عشر مافيش وجه شبه بينها
+
+301
+00:25:31,990 --> 00:25:35,350
+و بين التلاتة من مية أقل كتير جدا مهملة جدا من اسم
+
+302
+00:25:35,350 --> 00:25:39,210
+التلاتة من مية علشان هيك تركيز الكالسيوم point O33
+
+303
+00:25:39,210 --> 00:25:44,130
+وكمية لا تحسب يعني point O33 molar أو ال P
+
+304
+00:25:44,130 --> 00:25:50,220
+للكالسيوم واحد و تمانية و أربعين هي كمان نقطة1.48
+
+305
+00:25:50,220 --> 00:25:57,440
+طيب اي نقطة بدنا نحسب ال calcium تركيزه عندها قبل
+
+306
+00:25:57,440 --> 00:26:00,380
+نقطة النهاية بنفس الطريقة في اي خلاف على هذا
+
+307
+00:26:00,380 --> 00:26:06,620
+الكلام؟فيش خلاف طيب نيجي يا شباب نشتغل عند 100 مل
+
+308
+00:26:06,620 --> 00:26:11,900
+منالـ EDTA بقول والله انا عندي عشرة ملي مول
+
+309
+00:26:11,900 --> 00:26:16,360
+كالسيوم وعندي عشرة ملي مول EDTA انا عرفتهم اذا
+
+310
+00:26:16,360 --> 00:26:20,440
+الملي مول كالسيوم لفت جداش صفر يبجدسي ال
+
+311
+00:26:20,440 --> 00:26:25,970
+equivalence pointبقى معنى الكلام ال calcium y2-
+
+312
+00:26:25,970 --> 00:26:31,850
+جدش عشرة مجموعه دائما عشرة يبقى ال calcium y2-
+
+313
+00:26:31,850 --> 00:26:36,050
+عشرة عالمتين يعني 0.05 الان لا في عندي EDTA زيادة
+
+314
+00:26:36,050 --> 00:26:39,990
+ولا عندي كالسيوم زيادة فش عندي لغير بس calcium y2-
+
+315
+00:26:39,990 --> 00:26:46,290
+هذه ال calcium y2- 0.05 مولان بقول بيدها تجلب
+
+316
+00:26:46,290 --> 00:26:50,550
+مقدار x يبقى بتعطيني هان x بتعطيني هان alpha 4 من
+
+317
+00:26:50,550 --> 00:26:54,780
+ال x على 8 y4 minusومن ال equilibrium constant
+
+318
+00:26:54,780 --> 00:26:58,620
+اللي هو ال formation constant بقول والله point O5
+
+319
+00:26:58,620 --> 00:27:04,160
+minus X على ال X Alpha 4 X وبنفترض أن ال point O5
+
+320
+00:27:04,160 --> 00:27:07,820
+أكبر كتير من ال X مع الكلام ال X تطلع أن واحد
+
+321
+00:27:07,820 --> 00:27:12,060
+وسبعة في عشر أقل سالب ستة العشر أقل سالب ستة برضه
+
+322
+00:27:12,060 --> 00:27:17,680
+واضحة أنها أقل كتير من ال point O5 مع ذلك مع ذلكلو
+
+323
+00:27:17,680 --> 00:27:20,040
+حسبت ال relative error بطلع تلاتة وأربعة فى عشر
+
+324
+00:27:20,040 --> 00:27:23,720
+أقل سالب تلاتة في المية يعني ولا إشي مافيش عندي
+
+325
+00:27:23,720 --> 00:27:28,280
+خطأ في إلغاء ال X نهائيًا معنى الكلام تركيز ال
+
+326
+00:27:28,280 --> 00:27:31,660
+calcium واحد وسبعة فى عشر أقل سالب ستة molar أو ال
+
+327
+00:27:31,660 --> 00:27:36,500
+P للكالسيوم خمسة وسبعة وسبعين هذا الكلام at
+
+328
+00:27:36,500 --> 00:27:40,860
+equivalence point يبقى at equivalence point ال P
+
+329
+00:27:40,860 --> 00:27:45,970
+للكالسيوم خمسة وسبعة وسبعينطبعا مافيش عندنا إلا
+
+330
+00:27:45,970 --> 00:27:51,830
+نقطة تكافؤ واحدة وهذه طريقة الحساب الكالسيوم خلص
+
+331
+00:27:51,830 --> 00:27:55,950
+ال EDTA خلصت طبعا .. شوف قداش عندي كالسيوم ده
+
+332
+00:27:55,950 --> 00:28:01,590
+المصدر الوحيد للكالسيوم وهو تفكك ال calcium EDTA
+
+333
+00:28:01,590 --> 00:28:06,770
+مش هيك؟و من التفكك بقدر احسب كمية الكالسيوم فلاجئت
+
+334
+00:28:06,770 --> 00:28:11,190
+ان ال P للكالسيوم خمسة و سبعة و سبعين الان ننتقل
+
+335
+00:28:11,190 --> 00:28:16,190
+للمرحلة الأخيرة ايش بيحصل بعد إضافة كمية زائدة من
+
+336
+00:28:16,190 --> 00:28:20,730
+ال EDTA ايش بيحصل بعد إضافة كمية زائدة من ال EDTA
+
+337
+00:28:20,730 --> 00:28:25,630
+فانضيف مية و خمسين من ال EDTA يعني خمستاشر ميلي
+
+338
+00:28:25,630 --> 00:28:30,720
+مول EDTA طب انا عندي عشرة ميلي مول كالسيوميبجى اه
+
+339
+00:28:30,720 --> 00:28:34,820
+يبجى الملي مول EDTA excess خمساش ناقص عشرة بزيد
+
+340
+00:28:34,820 --> 00:28:40,420
+خمسة ملي مول EDTA طب تركيز ال EDTA ال excess خمسة
+
+341
+00:28:40,420 --> 00:28:45,040
+على مية ومية وخمسين متين وخمسين يعني point O two
+
+342
+00:28:45,040 --> 00:28:50,640
+يبجى زاد عندي EDTA point O two molar point O two
+
+343
+00:28:50,640 --> 00:28:57,300
+molar جداش زاد عندي كالسيوم فش كالسيومجديش اتكون
+
+344
+00:28:57,300 --> 00:29:02,680
+عندى calcium y2- عشرة كمين بتغيروش لإن كل
+
+345
+00:29:02,680 --> 00:29:07,080
+الكالسيوم اتحول لكالسيوم y2- جديش تركيز الكالسيوم
+
+346
+00:29:07,080 --> 00:29:12,300
+y2- عشر على 250 يعني أربعة من مية طب أنا بدى أحسب
+
+347
+00:29:12,300 --> 00:29:16,180
+جديش عندي كالسيوم بقول المصدر الوحيد ده الكالسيوم
+
+348
+00:29:16,180 --> 00:29:20,380
+هو اللى جاي من الكالسيوم y2- مافيش اي مصدر اخرطب
+
+349
+00:29:20,380 --> 00:29:23,860
+كيف بدى احسبه؟ من ال formation constant نفس الكلام
+
+350
+00:29:23,860 --> 00:29:28,220
+يا شباب كلام كتير كتير مافيش اندرها المعادلة كلام
+
+351
+00:29:28,220 --> 00:29:32,580
+بسيط جدا جدا مافيش اندرها المعادلة هي ال calcium
+
+352
+00:29:32,580 --> 00:29:37,580
+صفر قبل الاتزان ال Y for minus ال EDTA كلها point
+
+353
+00:29:37,580 --> 00:29:44,280
+O2الكالسيوم y2-0.04 بما ان ال Kf كبير كيف طريقة
+
+354
+00:29:44,280 --> 00:29:49,600
+التفكك بقول من النواتج 0.04 بتقل بمقدار X إذا
+
+355
+00:29:49,600 --> 00:29:56,420
+الكالسيوم عبارة عن X هذه بتنزل و بيجيها X جديش
+
+356
+00:29:56,420 --> 00:30:01,260
+عندي y4- منها Alpha 4 منها هو عبارة عن y4- يبدأ
+
+357
+00:30:01,260 --> 00:30:06,380
+خلصت المعادلة بنعود في ال Kf expression بقول 0.04
+
+358
+00:30:06,380 --> 00:30:12,710
+-xعلى x α4 point o2 زائد x بفترض ان ال point o2
+
+359
+00:30:12,710 --> 00:30:16,170
+أكبر كتير من ال x ال x بتطلع عند واحد واحد فعشرة
+
+360
+00:30:16,170 --> 00:30:21,130
+أس سالب عشرة هل بالفعل العشرة أس سالب عشرة أقل
+
+361
+00:30:21,130 --> 00:30:26,090
+كتير من ال point o2 ولا نحسب ال relative error لا
+
+362
+00:30:26,090 --> 00:30:30,110
+بدنا إيش نحسبه عشرة أس سالب عشرة أقل كتير جدا جدا
+
+363
+00:30:30,110 --> 00:30:34,210
+من ال point o2 يعني point o2 أكبر بحوالي 100 مليون
+
+364
+00:30:34,210 --> 00:30:39,960
+مرة من العشرة أس سالب عشرةماشي يا شباب اذا ال
+
+365
+00:30:39,960 --> 00:30:42,960
+assumption valid اكيد بدون حساب relative error
+
+366
+00:30:42,960 --> 00:30:47,480
+الكالسيوم بده ساعة واحد واحد فعشرة أو سالب عشرة او
+
+367
+00:30:47,480 --> 00:30:50,840
+ال P للكالسيوم تسعة و خمسة وتسعين اد مية و خمسين
+
+368
+00:30:50,840 --> 00:30:57,120
+هذا بنشتغل هنا كويس هيك كمان نقطة بعد ال
+
+369
+00:30:57,120 --> 00:31:01,920
+equivalence point خليني اضيف متين mil من ال EDTA
+
+370
+00:31:03,880 --> 00:31:07,840
+انا بقولكم 200 ملي مول EDTA معناته ايه؟ معناته انه
+
+371
+00:31:07,840 --> 00:31:13,580
+20 ملي مول EDTA طب انا عندى 10 ملي مول كالسيوم اذا
+
+372
+00:31:13,580 --> 00:31:18,940
+بزيد 10 ملي مول EDTA يبقى تركيز ال EDTA اللى زاد
+
+373
+00:31:18,940 --> 00:31:24,880
+10 على 300 بتثوى 0.033 مولر طيب جداش ال calcium y2
+
+374
+00:31:24,880 --> 00:31:30,000
+- اللى اتتول دائما عشرة هو نفس الكالسيوم اذا تركيز
+
+375
+00:31:30,000 --> 00:31:35,070
+ال calcium y2- 10 على 300 0.033 مولرطب انا بدي
+
+376
+00:31:35,070 --> 00:31:39,150
+احسب الكلسيوم مافيش عندي اي مصدر للكلسيوم الا
+
+377
+00:31:39,150 --> 00:31:44,610
+الكلسيوم y2- تفككها فليش بقول بقول والله هاي
+
+378
+00:31:44,610 --> 00:31:49,490
+الكلسيوم صفر point o33 point o33 ببدأ من هنا at
+
+379
+00:31:49,490 --> 00:31:55,270
+equilibrium point o33 minus x ال x هي بتعطيني هنا
+
+380
+00:31:55,270 --> 00:31:59,750
+x هنا ال point o33 بتنزل وهي ال x جنبها لكن جدياش
+
+381
+00:31:59,750 --> 00:32:05,920
+موجود منها علاقة y4 minus alpha 4من ال Y Alpha 4
+
+382
+00:32:05,920 --> 00:32:11,360
+فهيك صار عندي ال equation ال formation constant
+
+383
+00:32:11,360 --> 00:32:15,620
+expression جاهز فيه اعوض و فيه افترض ان ال point
+
+384
+00:32:15,620 --> 00:32:20,460
+O33 اكبر كتير من ال X في هذه الحالة ال X بتطلع
+
+385
+00:32:20,460 --> 00:32:25,160
+خمسة و سبعة في عشر عقل سالب 11 هل بالفعل العشر عقل
+
+386
+00:32:25,160 --> 00:32:31,300
+سالب 11 اقل كتير من ال point O3 طبعا اقل كتير الف
+
+387
+00:32:31,300 --> 00:32:36,010
+مليون مرة اقل منهامش بحاجة the assumption is
+
+388
+00:32:36,010 --> 00:32:40,430
+undoubtedly valid بدون أي يعني شك valid 100% بدون
+
+389
+00:32:40,430 --> 00:32:45,390
+حساب لإن العشرة أسالب 11 أقل كتير جدا جدا من ال
+
+390
+00:32:45,390 --> 00:32:49,970
+point 03 طيب يا جماعة يبقى ال calcium هو ال X 5.7
+
+391
+00:32:49,970 --> 00:32:55,510
+في عشرة أسالب 11 وال P للكالسيوم 10 و 24 يعني هدا
+
+392
+00:32:55,510 --> 00:32:59,050
+هي هذا يبقى لو جيت بدي أرسم
+
+393
+00:33:01,900 --> 00:33:04,480
+الـ Titration Curve هاي الـ Titration Curve طبعا
+
+394
+00:33:04,480 --> 00:33:07,960
+لو خير اتعدد يعني نقاط اكتر كتير من هيك بقصم
+
+395
+00:33:07,960 --> 00:33:14,860
+Titration Curve امرتب يبقى يا شباب سهل جدا نوصل لـ
+
+396
+00:33:14,860 --> 00:33:21,480
+Titration Curve في حالة معيارات ال EDTA مع الmetal
+
+397
+00:33:21,480 --> 00:33:25,140
+ions و زي ما حكيت سابقا مافيش اشي بيتغير عندى الا
+
+398
+00:33:25,140 --> 00:33:31,030
+اسم المتل و لما يتغير اسم المتل بتغير ال KFوكمان
+
+399
+00:33:31,030 --> 00:33:34,630
+ال metal بيعتمد والله ال pH تعتمد على نوع ال metal
+
+400
+00:33:34,630 --> 00:33:38,010
+فممكن تتغير ال pH إذا كانت تغيرت ال pH يبقى ال
+
+401
+00:33:38,010 --> 00:33:42,230
+alpha 4a برضه بتاخد قيمة تانية غير ال 0.35 لكن
+
+402
+00:33:42,230 --> 00:33:47,970
+بجيت الحال كله زي ما شوفناها هيك بنكون احنا خلصنا
+
+403
+00:33:47,970 --> 00:33:52,310
+حاجة اسمها EDTA reactions و titrations
+
diff --git a/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/9CTPmf94pcg.srt b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/9CTPmf94pcg.srt
new file mode 100644
index 0000000000000000000000000000000000000000..4f9323d1ab1d165cf1b54fe537b45e4443f52394
--- /dev/null
+++ b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/9CTPmf94pcg.srt
@@ -0,0 +1,2018 @@
+1
+00:00:20,670 --> 00:00:25,070
+طيب اليوم إن شاء الله سنحاول أن نستكمل الـ chapter
+
+2
+00:00:25,070 --> 00:00:29,930
+الذي بدأناه بخصوص الـ general equilibrium concepts
+
+3
+00:00:29,930 --> 00:00:36,390
+أو المفاهيم الأساسية في الاتزان سنتكلم اليوم إذ
+
+4
+00:00:36,390 --> 00:00:40,390
+الله راد، عن موضوع مهم جدًا وسيتكرر معنا في أكثر من
+
+5
+00:00:40,390 --> 00:00:45,450
+مرحلة قادمة سنتكلم عن الـ activity و الـ activity
+
+6
+00:00:45,450 --> 00:00:48,290
+coefficients وما علاقة الـ activity بالـ
+
+7
+00:00:48,290 --> 00:00:50,290
+equilibrium constant
+
+8
+00:00:53,150 --> 00:00:58,310
+في البداية، لو أردنا التكلم عن الـ activity، نقول
+
+9
+00:00:58,310 --> 00:01:01,630
+ما هي الـ activity؟ كثير من الناس قد يعرفها ويقول
+
+10
+00:01:01,630 --> 00:01:05,050
+والله الـ activity هي عبارة عن الـ effective
+
+11
+00:01:05,050 --> 00:01:10,750
+concentration، عندما نتكلم عن الـ activity فيما
+
+12
+00:01:10,750 --> 00:01:17,890
+يتعلق بتفاعلات الاتزان، عادةً يكون لدي، ما دام
+
+13
+00:01:17,890 --> 00:01:22,120
+لدي اتزان، يكون لديّ weak electrolyte، لديّ
+
+14
+00:01:22,120 --> 00:01:25,640
+weak electrolyte موجود في المحلول، weak
+
+15
+00:01:25,640 --> 00:01:31,740
+electrolyte في الأصل، يتفكك جزئيًا ويعطينا نواتج
+
+16
+00:01:31,740 --> 00:01:36,380
+يمكن كتابة equilibrium constant، طيب ماذا يحدث لو
+
+17
+00:01:36,380 --> 00:01:40,760
+أن هذا الـ weak electrolyte، أضفنا إليه strong
+
+18
+00:01:40,760 --> 00:01:45,900
+electrolyte، لكن يحتوي الـ strong electrolyte على
+
+19
+00:01:45,900 --> 00:01:50,840
+أيونات مخالفة، غير مشابهة، غير common ions للـ
+
+20
+00:01:50,840 --> 00:01:54,560
+strong electrolyte، فهو يحتوي على diverse ions، diverse
+
+21
+00:01:54,560 --> 00:01:59,960
+مختلفة عن الأيونات التي في المحلول، نلاحظ
+
+22
+00:01:59,960 --> 00:02:06,740
+ببساطة شديدة، أن الـ acetic acid مثلًا، كـ weak
+
+23
+00:02:06,740 --> 00:02:12,010
+electrolyte، يتفكك ويعطيني H+ و Acetate في
+
+24
+00:02:12,010 --> 00:02:15,510
+الماء، عادي H+ و Acetate، ليس لديّ مشكلة، لكن لو
+
+25
+00:02:15,510 --> 00:02:21,070
+وضعنا عليه strong electrolyte مثل الـ KNO3، أو أن
+
+26
+00:02:21,070 --> 00:02:27,590
+أضفنا الـ acetic acid إلى محلول KNO3، نلاحظ أن
+
+27
+00:02:30,220 --> 00:02:35,360
+الـ H+ يجذب الأيونات المخالفة في
+
+28
+00:02:35,360 --> 00:02:39,140
+الشحنة، وفي هذه الحالة هي الـ Nitrate، لأنه
+
+29
+00:02:39,140 --> 00:02:43,360
+موجودة بكمية كبيرة من الـ Nitrate، وبالتالي تكون
+
+30
+00:02:43,360 --> 00:02:47,460
+سحابة من الـ Nitrate حول الـ H+، وبنفس
+
+31
+00:02:47,460 --> 00:02:52,060
+الطريقة، الأسيتات يجذب الأيونات المخالفة في
+
+32
+00:02:52,060 --> 00:02:56,900
+الشحنة، فيتكون حوله سحابة من الـ potassium ions
+
+33
+00:02:56,900 --> 00:02:59,280
+حول الأسيتات
+
+34
+00:03:01,340 --> 00:03:06,800
+في الحقيقة، إذا كان تركيز الـ diverse ions الذي
+
+35
+00:03:06,800 --> 00:03:11,180
+هو الـ potassium nitrate كبير، يحدث حجب كامل،
+
+36
+00:03:11,180 --> 00:03:15,680
+shielding كامل للـ acetate عن الـ H+، عن الـ
+
+37
+00:03:15,680 --> 00:03:20,920
+acetic acid، فيضطر الـ acetic acid إلى التفكك لكي
+
+38
+00:03:20,920 --> 00:03:28,360
+يعطيني H+ و acetate،  ليبرر أو لي... يعني
+
+39
+00:03:28,360 --> 00:03:28,680
+...
+
+40
+00:03:32,120 --> 00:03:35,600
+ليُحافظ على قيمة الـ equilibrium constant، قيمة الـ
+
+41
+00:03:35,600 --> 00:03:39,040
+equilibrium constant،  لأنه يضطر، لأنه لا يجد
+
+42
+00:03:39,040 --> 00:03:42,400
+أيوناته، الـ H+ و الـ Acetate، أصبحت محجوبة
+
+43
+00:03:42,400 --> 00:03:49,920
+فالـ acetic acid يتفكك أكثر ليعوض الـ H+
+
+44
+00:03:49,920 --> 00:03:53,120
+و الأسيتات التي حصل لها حجب، وبالتالي ماذا يحدث
+
+45
+00:03:53,120 --> 00:03:57,700
+للاتزان؟ يتجه نحو الاتجاه الأمامي، طيب
+
+46
+00:03:57,700 --> 00:04:00,740
+لأننا نقول، الـ acetic acid يضطر إلى التفكك
+
+47
+00:04:00,740 --> 00:04:04,640
+أكثر، لأن أيوناته محجوبة، فيجب أن يعوض عن الأيونات
+
+48
+00:04:04,640 --> 00:04:09,090
+المحجوبة، فيتفكك، طيب على أي أساس هذا الكلام؟ يعني
+
+49
+00:04:09,090 --> 00:04:12,210
+نعرف أن،  ليه بيقول، والله إذا أضفنا
+
+50
+00:04:12,210 --> 00:04:15,650
+H+، التفاعل يرجع للخلف، إذا أضفنا Acetate،
+
+51
+00:04:15,650 --> 00:04:18,350
+التفاعل يرجع للخلف، إذا أضفنا Acetic acid،
+
+52
+00:04:18,350 --> 00:04:22,730
+التفاعل يتجه للأمام، طيب، عندما نضيف K+، الـ K+
+
+53
+00:04:22,730 --> 00:04:28,310
+ليس له علاقة بالاتزان، الـ الـ nitrate أيضًا
+
+54
+00:04:28,310 --> 00:04:34,390
+ليس له علاقة بالاتزان، فـ لكن نظرًا للـ
+
+55
+00:04:34,390 --> 00:04:39,130
+shielding الذي يحدث، كما رأينا،  الـ الاتزان
+
+56
+00:04:39,130 --> 00:04:42,370
+يتجه للأمام، معنى هذا الكلام
+
+57
+00:04:42,370 --> 00:04:48,070
+قيمة الـ equilibrium constant تزداد،  فيمكن الآن أن نرجع
+
+58
+00:04:48,070 --> 00:04:52,970
+ونعرف الـ activity لأي أيون I، وليكن H+ أو
+
+59
+00:04:52,970 --> 00:04:56,950
+الـ acetate مثلًا، فنقول إن الـ activity للأيون I هي
+
+60
+00:04:56,950 --> 00:05:03,250
+عبارة عن تركيز الأيون I في وجود
+
+61
+00:05:05,690 --> 00:05:11,990
+strong electrolyte من diverse ions، أيونات
+
+62
+00:05:11,990 --> 00:05:14,990
+مخالفة للأيونات التي في الاتزان، فالـ
+
+63
+00:05:14,990 --> 00:05:18,010
+activity هي عبارة عن التركيز،  يعني molar
+
+64
+00:05:18,010 --> 00:05:22,770
+مولارية، هي عبارة عن تركيز الأيون، لكن
+
+65
+00:05:22,770 --> 00:05:28,570
+في ماذا؟ في وجود strong electrolyte من ماذا؟ من
+
+66
+00:05:28,570 --> 00:05:33,030
+diverse ions، فأنا أقول إن الـ AI، التي هي
+
+67
+00:05:33,030 --> 00:05:39,650
+activity للأيون I، تساوي تركيز الأيون I، CI، في معامل
+
+68
+00:05:39,650 --> 00:05:46,050
+أو factor،  نسميه activity coefficient، Fi، activity
+
+69
+00:05:46,050 --> 00:05:49,530
+coefficient، ومن هذه العلاقة أقول شيئًا، أنا
+
+70
+00:05:49,530 --> 00:05:53,770
+أقول إن الـ activity هو التركيز، إذا كان الـ F هذا
+
+71
+00:05:53,770 --> 00:05:58,170
+يساوي ماذا؟ واحد، متى يكون الـ F يساوي واحد؟ قال
+
+72
+00:05:58,170 --> 00:06:01,550
+والله الـ F يساوي واحد، إذا لم يكن لديّ diverse
+
+73
+00:06:01,550 --> 00:06:07,230
+ions، إذا لم يكن لديّ diverse ions، فالـ F يساوي واحد، أو
+
+74
+00:06:07,230 --> 00:06:11,350
+قد يكون لديّ diverse ions، لكن تركيز الـ diverse
+
+75
+00:06:11,350 --> 00:06:15,850
+ions صغير جدًا، لدرجة أنه لا يستطيع أن يعمل
+
+76
+00:06:15,850 --> 00:06:20,750
+shielding، يعني الـ F أيضًا تساوي 1، لو كان تركيز الـ
+
+77
+00:06:20,750 --> 00:06:25,010
+diverse ions أقل من 10⁻⁴ مولار، أقل من 10
+
+78
+00:06:25,010 --> 00:06:30,210
+⁻⁴ مولار، لا يستطيع الـ diverse ions أن يعمل
+
+79
+00:06:30,210 --> 00:06:34,630
+سُحبًا من الأيونات المخالفة للأيونات الموجودة
+
+80
+00:06:34,630 --> 00:06:39,050
+ويعطيني shielding، وبالتالي الاتزان أيضًا
+
+81
+00:06:39,050 --> 00:06:42,070
+يبقى كما هو، لأن الـ F أو الـ activity coefficient
+
+82
+00:06:42,070 --> 00:06:47,320
+في هذه الحالة تساوي 1، من هذا الكلام يمكن، يعني
+
+83
+00:06:47,320 --> 00:06:51,880
+نتعرف على الخصائص العامة للـ activity coefficient
+
+84
+00:06:51,880 --> 00:06:55,560
+لأنني أريد حساب الـ activity، التركيز معروف،
+
+85
+00:06:55,560 --> 00:07:00,060
+التركيز معروف، لكن لحساب الـ activity يجب
+
+86
+00:07:00,060 --> 00:07:03,360
+أن أعرف الـ activity coefficient، فمن المهم أن
+
+87
+00:07:03,360 --> 00:07:07,820
+أعرف خصائص الـ activity coefficient،  ذكرت خاصيتين من
+
+88
+00:07:07,820 --> 00:07:11,650
+خصائص الـ activity coefficient، أنه في البداية يساوي
+
+89
+00:07:11,650 --> 00:07:17,950
+واحدًا، إذا لم يكن لدي أيونات مختلفة، أو إذا أضفت مادة
+
+90
+00:07:17,950 --> 00:07:21,930
+مختلفة، ولكن غير متأينة، إذا لم تكن المادة لديها شحنة،
+
+91
+00:07:21,930 --> 00:07:26,350
+فليس لديها أيونات مختلفة،  الـ F يساوي واحد ما دام لا
+
+92
+00:07:26,350 --> 00:07:31,670
+يوجد شحنة على المادة المضافة، جيد، يعني لم تتأين،
+
+93
+00:07:31,670 --> 00:07:37,190
+معناه الـ F يساوي واحد، يبقى أيونات مختلفة لـ
+
+94
+00:07:37,190 --> 00:07:43,460
+uncharged species is equal to one، جيد، هكذا إذا كان
+
+95
+00:07:43,460 --> 00:07:46,740
+المادة غير مشحونة، فالـ activity coefficient له واحد،
+
+96
+00:07:46,740 --> 00:07:51,640
+أيضًا، الـ activity coefficient يساوي واحدًا إذا
+
+97
+00:07:51,640 --> 00:07:56,580
+كان التركيز الذي لديّ أقل من عشرة أس سالب أربعة،
+
+98
+00:07:56,580 --> 00:08:00,520
+molar، يعني very dilute solution، و الـ very dilute
+
+99
+00:08:00,520 --> 00:08:03,300
+solution، يعني نحن نستخدمها كثيرًا في الكيمياء
+
+100
+00:08:03,300 --> 00:08:07,840
+التحليلية، فلما يكون لديّ تركيز قليل جدًا، معناه
+
+101
+00:08:07,840 --> 00:08:13,440
+أيضًا الـ F تساوي واحد، لكن لاحظنا، وشيء متوقع
+
+102
+00:08:13,440 --> 00:08:16,700
+هنا، بعد ما عرفنا كيف أن الاتزان
+
+103
+00:08:16,700 --> 00:08:21,500
+يزيد في وجود الـ diverse ions، أقول والله كلما
+
+104
+00:08:21,500 --> 00:08:27,460
+زاد تركيز الـ diverse ions، كلما زاد، يزداد التفكك
+
+105
+00:08:27,460 --> 00:08:33,380
+هكذا، معنى هذا الكلام أن الـ F تقل، يبقى الـ F تقل كلما
+
+106
+00:08:33,380 --> 00:08:39,130
+زاد التركيز، هذا شيء، وأيضًا عملية الحجب
+
+107
+00:08:39,130 --> 00:08:43,430
+كثيرًا تتأثر بالشحنة، فلما الشحنة تكون بدلًا من أن تكون
+
+108
+00:08:43,430 --> 00:08:47,870
+أحادية، ثنائية، قدرة الشحنة الثنائية على الحجب أكثر
+
+109
+00:08:47,870 --> 00:08:53,090
+كثيرًا من قدرة الشحنة الأحادية على الحجب، لذلك
+
+110
+00:08:53,090 --> 00:09:01,350
+التفكك يزداد كثيرًا عندما يكون لديّ multi-valent ion،
+
+111
+00:09:01,350 --> 00:09:06,500
+أو multi-charged ion، عندما يكون على الأيون charges
+
+112
+00:09:06,500 --> 00:09:10,180
+متعددة، اثنتين أو ثلاث، معناه القدرة على الحجب تزداد،
+
+113
+00:09:10,180 --> 00:09:15,080
+وبالتالي لديّ الـ F، طبعًا التفكك يزداد، يعني الـ F
+
+114
+00:09:15,080 --> 00:09:23,200
+لذلك تقل بشكل ملحوظ، هذه خصائص الـ activity
+
+115
+00:09:23,200 --> 00:09:27,160
+coefficient، من هذه الخصائص أقول إن الـ
+
+116
+00:09:27,160 --> 00:09:31,400
+activity coefficient يعتمد على شيئين، يعتمد على
+
+117
+00:09:31,400 --> 00:09:37,180
+شيئين، يعتمد على التركيز، تركيز الـ diverse ions،
+
+118
+00:09:37,180 --> 00:09:43,800
+هذا شيء، ودالة أيضًا في الشحنة، ودالة في الشحنة،
+
+119
+00:09:43,800 --> 00:09:48,700
+فيتأثر بالتركيز ويتأثر بالشحنة، طيب عندما نتكلم
+
+120
+00:09:48,700 --> 00:09:54,100
+في الكيمياء، ما علاقة التركيز بالشحنة بالمحلول؟
+
+121
+00:09:54,100 --> 00:09:56,180
+نقُول والله يمكن تعريف
+
+122
+00:09:59,720 --> 00:10:05,500
+شيء نسميه القوة الأيونية للمحلول، القوة الأيونية
+
+123
+00:10:05,500 --> 00:10:10,480
+للمحلول، ما هي القوة الأيونية للمحلول؟ قال والله القوة
+
+124
+00:10:10,480 --> 00:10:19,900
+الأيونية للمحلول تساوي نصف مجموع تركيز الأيون I،
+
+125
+00:10:19,900 --> 00:10:28,820
+CI، في مربع شحنة الأيون I²، Zi²، فأنا أستطيع إيجاد
+
+126
+00:10:28,820 --> 00:10:33,900
+خاصية من خصائص المحلول نسميها Ionic strength، القوة
+
+127
+00:10:33,900 --> 00:10:37,840
+الأيونية للمحلول، ما هي القوة الأيونية للمحلول؟ تساوي
+
+128
+00:10:37,840 --> 00:10:43,960
+قال الله، تساوي نصف مجموع Ci Zi²
+
+129
+00:10:45,550 --> 00:10:49,710
+طبعًا القوة الأيونية للمحلول تؤثر على الـ F، سنرى
+
+130
+00:10:49,710 --> 00:10:53,270
+كيف تؤثر على الـ F بعد قليل، لكن الآن ما دام عرفنا
+
+131
+00:10:53,270 --> 00:10:56,750
+ما هي القوة الأيونية للمحلول، تعالوا أولًا
+
+132
+00:10:56,750 --> 00:11:00,370
+نأخذ أمثلة عن كيفية حساب القوة الأيونية للمحلول، و
+
+133
+00:11:00,370 --> 00:11:03,790
+بعدها سنرى تأثيرها على الـ activity
+
+134
+00:11:03,790 --> 00:11:08,940
+coefficient، فسنأخذ مثالًا بسيطًا مباشرًا
+
+135
+00:11:08,940 --> 00:11:13,140
+يقول، احسب القوة الأيونية لمحلول 0.2 molar
+
+136
+00:11:13,140 --> 00:11:18,540
+KNO3، لديّ potassium nitrate، طبعًا هذا strong
+
+137
+00:11:18,540 --> 00:11:23,600
+electrolyte، أريد إيجاد القوة الأيونية للمحلول، 0.2
+
+138
+00:11:23,600 --> 00:11:27,260
+molar، ما هي القوة الأيونية للمحلول؟ أقول والله نصف
+
+139
+00:11:27,260 --> 00:11:33,450
+مجموع CIZI squared، أقول يعني نصف، نفتح قوس
+
+140
+00:11:33,450 --> 00:11:38,270
+تركيز البوتاسيوم،  نصف
+
+141
+00:11:38,270 --> 00:11:42,690
+تركيز البوتاسيوم، شحنة البوتاسيوم تربيع، زائد تركيز
+
+142
+00:11:42,690 --> 00:11:46,150
+النيتريت، شحنة النيتريت تربيع، هذه الأيونات، لديّ
+
+143
+00:11:46,150 --> 00:11:49,610
+أيونات أخرى، هذه الأيونات، نقول والله تساوي نصف
+
+144
+00:11:49,610 --> 00:11:54,070
+في 0.2، تركيز البوتاسيوم، شحنة البوتاسيوم
+
+145
+00:11:54,070 --> 00:12:00,140
+واحد تربيع، زائد 0.2،  شحنة تركيز الـ nitrate،
+
+146
+00:12:00,140 --> 00:12:03,820
+one squared، وهي واحد، وهي شحنة الـ nitrate،
+
+147
+00:12:03,820 --> 00:12:09,060
+فيكون لديّ القوة الأيونية للمحلول 0.2، لا أحد
+
+148
+00:12:09,060 --> 00:12:12,000
+يحاول أن يقول لي والله، هذا الـ potassium 0.2
+
+149
+00:12:12,000 --> 00:12:17,470
+و الـ nitrogen 0.2 و الـ oxygen 0.6، مثلًا،
+
+150
+00:12:17,470 --> 00:12:21,790
+لا، هذا potassium nitrate، القوة الأيونية للمحلول
+
+151
+00:12:21,790 --> 00:12:24,950
+تحسب من البوتاسيوم،  من البوتاسيوم و الـ
+
+152
+00:12:24,950 --> 00:12:28,770
+nitrate، هذه الـ nitrate عبارة عن ماذا؟ عبارة عن
+
+153
+00:12:28,770 --> 00:12:35,470
+مجموعة وظيفية، مجموعة، هي group، مجموعة،
+
+154
+00:12:35,470 --> 00:12:39,240
+لا نقول والله هذا كل واحد لحاله،  كثير من
+
+155
+00:12:39,240 --> 00:12:42,880
+الطلاب يفعلون في الامتحان، يحسبون الـ N لحالها، والـ O
+
+156
+00:12:42,880 --> 00:12:46,080
+لحالها، والبوتاسيوم لحاله،  ليس منطقيًا، اسمها
+
+157
+00:12:46,080 --> 00:12:50,180
+potassium nitrate، يعني potassium و nitrate، طيب
+
+158
+00:12:50,180 --> 00:12:54,680
+دعونا نتذكر هذه القيمة، و لنأخذ مثالًا أيضًا، 0.2
+
+159
+00:12:54,680 --> 00:12:58,460
+molar solution، لكن يأخذ في هذا المثال شحنة
+
+160
+00:12:58,460 --> 00:13:02,660
+ثنائية، ونرى تأثير الشحنة على الـ ionic
+
+161
+00:13:02,660 --> 00:13:06,240
+strength، على القوة الأيونية للمحلول، ما تأثير
+
+162
+00:13:06,240 --> 00:13:11,610
+الشحنة؟ سنأخذ المحلول التالي، يقول، احسب الـ ionic
+
+163
+00:13:11,610 --> 00:13:15,110
+strength لمحلول 0.2 molar potassium sulfate، ما الذي
+
+164
+00:13:15,110 --> 00:13:20,090
+اختلف؟ لديّ sulfate بدلًا من nitrate، لكن 0.2 molar
+
+165
+00:13:20,090 --> 00:13:24,550
+potassium، potassium، ليس لديّ مشكلة، لكن بدلًا من الـ
+
+166
+00:13:24,550 --> 00:13:28,450
+nitrate التي هي أحادية، لديّ sulfate ثنائية، أقول
+
+167
+00:13:28,450 --> 00:13:33,830
+والله، μ تساوي نصف مجموع cizi squared، إذًا
+
+168
+00:13:33,830 --> 00:13:39,970
+μ تساوي نصف،  C للبوتاسيوم Zi squared للبوتاسيوم، زائد
+
+169
+00:13:39,970 --> 00:13:46,750
+C للsulfate، Zi squared للsulfate،  يعني الذي يساوي،
+
+170
+00:13:46,750 --> 00:13:50,290
+لو أخذنا تركيز البوتاسيوم، لو لاحظتم أنتم في هذا
+
+171
+00:13:50,290 --> 00:13:57,210
+المركب، طبعًا ضعف تركيز البوتاسيوم، الـ sulfate، يعني 2 في 0.2، شحنته واحد، يعني واحد تربيع، زائد
+
+172
+00:13:57,210 --> 00:14:02,370
+الـ sulfate 0.2،  إذا 0.2 في شحنتها
+
+173
+00:14:02,370 --> 00:14:06,290
+2 تربيع، تخرج القوة الأيونية لديّ 0.6، لو
+
+174
+00:14:06,290 --> 00:14:11,070
+
+223
+00:17:42,210 --> 00:17:46,410
+زي الكرة حول الـ H بلس هذه الكرة لها
+
+224
+00:17:46,410 --> 00:17:53,170
+قطر هذا الـ diameter هو المقصود بالـ effective
+
+225
+00:17:53,170 --> 00:17:58,990
+diameter of the hydrated ion،  نقيسه بال Angstrom
+
+226
+00:17:58,990 --> 00:18:03,310
+الـ Angstrom عشرة أس سالب عشرة من المتر، الـ Acetate
+
+227
+00:18:03,310 --> 00:18:09,330
+نفس الكلام برضه، يحط فيها جزيء أو كرة من المية بس
+
+228
+00:18:09,330 --> 00:18:14,230
+بيكون شكل المية الـ H  اللي هي partial positive هي
+
+229
+00:18:14,230 --> 00:18:17,450
+المقتربة من الـ Acetate لأنه الـ Acetate بتكون
+
+230
+00:18:17,450 --> 00:18:22,150
+negative، فالـ diameter عندي هذا هو اللي احنا بنقول
+
+231
+00:18:22,150 --> 00:18:25,030
+إنه effective diameter
+
+232
+00:18:26,920 --> 00:18:31,700
+فيبقى الـ Ionic Strength والـ Charge على الأيون
+
+233
+00:18:31,700 --> 00:18:35,660
+والـ Effective Diameter بالأنغستروم هي الثلاثة
+
+234
+00:18:35,660 --> 00:18:39,740
+عوامل اللي بتأثر على الـ activity coefficient
+
+235
+00:18:39,740 --> 00:18:42,960
+وبتعطيني قيمة الـ activity coefficient، هذه الثلاثة
+
+236
+00:18:42,960 --> 00:18:47,400
+عوامل مجتمعة في معادلة، بنسمي المعادلة Debye-Hückel
+
+237
+00:18:47,400 --> 00:18:52,720
+equation بتقول
+
+238
+00:18:52,720 --> 00:18:55,640
+المعادلة أو Debye-Hückel equation بتقول minus log
+
+239
+00:18:55,640 --> 00:19:02,680
+f  بتساوي 0.51 زي اي تربيع جذر الميو على واحد
+
+240
+00:19:02,680 --> 00:19:07,620
+زائد 0.33 ألفا اي، ألفا اي هي عبارة عن
+
+241
+00:19:07,620 --> 00:19:13,720
+الـ diameter للـ hydrated ion، ألفا اي جذر الميو هذا
+
+242
+00:19:13,720 --> 00:19:18,240
+عبارة عن Debye-Hückel equation، في بعض الأحيان خاصة
+
+243
+00:19:18,240 --> 00:19:22,160
+في المساقات، يعني مش في الحياة العملية، في المساقات
+
+244
+00:19:22,160 --> 00:19:25,960
+عشان نخفف عملية الحسابات ممكن ما نعطيكش قيمة الـ
+
+245
+00:19:25,960 --> 00:19:28,200
+ألفا لأن الـ ألفا موجودة في الجداول، موجودة بنقدر
+
+246
+00:19:28,200 --> 00:19:32,680
+نجيبها، لكن يعني لو ما عطيناهاش، ما عطيناهاش يعني في
+
+247
+00:19:32,680 --> 00:19:36,780
+الامتحان أو في مسألة معينة، اعتبر إن الـ ألفا اي
+
+248
+00:19:36,780 --> 00:19:40,910
+ثلاثة أنجستروم، وفي هذه الحالة لما تكون ثلاثة في
+
+249
+00:19:40,910 --> 00:19:44,590
+0.33 صارت واحد، المعادلة بتكون أبسط
+
+250
+00:19:44,590 --> 00:19:48,830
+شوية من هيك بتصير minus log الـ f  بتساوي 0.5
+
+251
+00:19:48,830 --> 00:19:52,670
+واحد زي اي تربيع جذر الميو على واحد زائد جذر الميو
+
+252
+00:19:52,670 --> 00:19:57,460
+لكن هذه المعادلة فقط صحيحة إذا كان الـ α I إيش
+
+253
+00:19:57,460 --> 00:20:01,100
+بتساوي؟ ثلاثة، يعني في شرط لها، لكن لو ما كانش عندك
+
+254
+00:20:01,100 --> 00:20:05,280
+الـ α I معلومة، يعني مش ثلاثة أنجستروم، فطبعا
+
+255
+00:20:05,280 --> 00:20:09,020
+نستخدم المعادلة الأصلية اللي شفناها قبل شوية، هذه
+
+256
+00:20:09,020 --> 00:20:12,680
+معادلة Debye-Hückel equation، كتير من العلماء أو
+
+257
+00:20:12,680 --> 00:20:15,380
+بعض العلماء حاولوا يعملوا عليها بعض التعديلات اللي
+
+258
+00:20:15,380 --> 00:20:19,910
+بتعطيهم يعني قياسات أدق، فيه عندنا Davis
+
+259
+00:20:19,910 --> 00:20:22,790
+Modification، وفيه عندنا تعديل بسيط على معادلة
+
+260
+00:20:22,790 --> 00:20:26,270
+Debye-Hückel، وهنشوف تعديلات أخرى أيضًا، لكن هذه
+
+261
+00:20:26,270 --> 00:20:29,730
+التعديلات كلها ما تهمناش احنا في هذا المثال، احنا
+
+262
+00:20:29,730 --> 00:20:33,730
+هنستخدم فقط Debye-Hückel equation، يا المعادلة اللي
+
+263
+00:20:33,730 --> 00:20:37,250
+قدامي، يا المعادلة في الـ slide اللي جايبة الهادي حسب
+
+264
+00:20:37,250 --> 00:20:41,790
+هل معي الـ α I معلومة ثلاثة أنجستروم ولا لأ، ماشي
+
+265
+00:20:41,790 --> 00:20:46,510
+يا شباب، مش بس يعني احنا لما نستخدم the biological
+
+266
+00:20:46,510 --> 00:20:49,810
+equation فبنعملش عملية تبسيط، معظم العلماء
+
+267
+00:20:49,810 --> 00:20:53,470
+بيستخدموا biological equation للوصول إلى قيمة الـ
+
+268
+00:20:53,470 --> 00:20:57,330
+activity coefficient، فاحنا لما نستخدمها مش عاملين
+
+269
+00:20:57,330 --> 00:21:04,120
+خطأ ملحوظ، طيب الآن مدام عرفنا نحسب الـ ionic
+
+270
+00:21:04,120 --> 00:21:07,060
+strength وشوفنا العلاقة اللي بتربط الـ ionic
+
+271
+00:21:07,060 --> 00:21:10,780
+strength مع الـ activity coefficient، فقال لنا نتعلم
+
+272
+00:21:10,780 --> 00:21:14,860
+كيف نحسب الـ activity coefficient، فنتطلع على
+
+273
+00:21:14,860 --> 00:21:20,020
+هالمثال اللي قدامي، المثال بيقول calculate the
+
+274
+00:21:20,020 --> 00:21:25,080
+activity coefficients of potassium and sulfate in
+
+275
+00:21:25,080 --> 00:21:32,350
+a 0.002 molar بوتاسيوم كبريتات solution assuming an
+
+276
+00:21:32,350 --> 00:21:35,730
+effective diameter of three angstrom for both ions
+
+277
+00:21:35,730 --> 00:21:39,510
+طبعًا لما نقول إن الـ effective diameter للـ hydrated
+
+278
+00:21:39,510 --> 00:21:44,110
+ion للـ both ions يعني للبوتاسيوم والكبريتات هو عبارة
+
+279
+00:21:44,110 --> 00:21:48,230
+عن ثلاثة أنجستروم، هذا مش صحيح لأن البوتاسيوم يعني
+
+280
+00:21:48,230 --> 00:21:52,890
+حجمه صغير، والـ hydrated ion بتاعه صغير، لكن الكبريتات
+
+281
+00:21:52,890 --> 00:21:57,210
+عليه أربع أكسجين، حجمها كبير، فالـ hydrated ion
+
+282
+00:21:57,210 --> 00:22:01,050
+بتاعه هيكون كبير، لكن يعني هو مش مهتم في إن أنتَ
+
+283
+00:22:01,050 --> 00:22:05,370
+يعني تجيب الـ hydrated ion بالضبط أو تستخدمه بالضبط
+
+284
+00:22:05,370 --> 00:22:10,030
+هو بس المهم عنده في هذا المثال إنك تعرف طريقة حساب
+
+285
+00:22:10,030 --> 00:22:13,870
+الـ activity coefficient، لكن طبعًا من ناحية عملية
+
+286
+00:22:13,870 --> 00:22:18,330
+غلط، الكبريتات أكبر كتير هيكون من الـ potassium على أي
+
+287
+00:22:18,330 --> 00:22:24,440
+حال، إحنا علشان نطبق الـ equation التي بتعطينا الـ
+
+288
+00:22:24,440 --> 00:22:27,700
+activity coefficients لازم في البداية أجيب الـ
+
+289
+00:22:27,700 --> 00:22:32,140
+ionic strength، الـ ionic strength للمحلول بتساوي نص
+
+290
+00:22:32,140 --> 00:22:35,720
+summation cizi squared، تبقى الـ μ بتساوي نص في الـ
+
+291
+00:22:35,720 --> 00:22:40,340
+0.002 في 2، هذا هو تركيز البوتاسيوم، ضعف تركيز
+
+292
+00:22:40,340 --> 00:22:44,630
+البوتاسيوم كبريتات، في 1 اللي هي شحنة البوتاسيوم تربيع
+
+293
+00:22:44,630 --> 00:22:49,730
+زائد 0.002 في 2 تربيع، تطلع عندي 0.006، الـ ionic strength، الآن مدام عندي الـ ionic
+
+294
+00:22:49,730 --> 00:22:53,870
+strength، بقدر أحطها في Debye-Hückel equation وأطلع
+
+295
+00:22:53,870 --> 00:22:57,710
+قيمة الـ f، لأنه عندي minus log الـ f I بتساوي 0.
+
+296
+00:22:57,710 --> 00:23:01,470
+51 زي اي تربيع، يعني بتكلم عن .. لما أتكلّم عن
+
+297
+00:23:06,550 --> 00:23:11,490
+البوتاسيوم بقول minus log الـ f للـ K Plus بتساوي
+
+298
+00:23:11,490 --> 00:23:17,730
+0.51 في Z للبوتاسيوم 1 يعني 1 تربيع، جذر μ يعني
+
+299
+00:23:17,730 --> 00:23:22,330
+0.006 تحت الجذر على 1 زائد جذر μ، لأن قيمة
+
+300
+00:23:22,330 --> 00:23:26,390
+الألفا ثلاثة أنجستروم، بتطلع عندي minus log الـ f
+
+301
+00:23:26,390 --> 00:23:32,070
+للـ K Plus 0.037، الآن الـ f لـ K بلس عشر أس سالب
+
+302
+00:23:32,070 --> 00:23:35,950
+0.037 بتطلع 0.918، إذًا الـ f أو الـ activity coefficient للبوتاسيوم طلع
+
+303
+00:23:35,950 --> 00:23:39,950
+تقريبًا دي حوالي 0.92، نفس الطريقة بقدر أحسب
+
+304
+00:23:39,950 --> 00:23:45,870
+الـ f للكبريتات، وانتبهوا على قيمة الـ f للكبريتات، بقول
+
+305
+00:23:45,870 --> 00:23:51,070
+minus log f للكبريتات بتساوي 0.51 في 2 تربيع
+
+306
+00:23:51,070 --> 00:23:55,490
+شحنة الكبريتات، جذر μ على واحد زائد جذر μ،
+
+307
+00:23:55,490 --> 00:23:58,750
+بتطلع عندي قيمة، بجيب الـ f للكبريتات بتطلع عندي 0.71
+
+308
+00:24:03,770 --> 00:24:08,450
+لاحظ الـ f للكبريتات أقل كتير من الـ f للبوتاسيوم، لأن
+
+309
+00:24:08,450 --> 00:24:14,710
+شحنة الكبريتات أكبر، مع إن البوتاسيوم تركيزه أكبر، لكن
+
+310
+00:24:14,710 --> 00:24:18,050
+تأثيره على الـ activity coefficient، التركيز تأثيره
+
+311
+00:24:18,050 --> 00:24:24,310
+أقل من تأثير الشحنة، الشحنة تأثيرها أكبر، لو عملنا
+
+312
+00:24:24,310 --> 00:24:29,810
+نفس المسألة يا شباب وبدل ما أنه نستخدم 0.002
+
+313
+00:24:29,810 --> 00:24:33,730
+molar، لو استخدمنا 0.02 molar يعني 2 من 100 بدل
+
+314
+00:24:33,730 --> 00:24:38,250
+2 من 1000، راح ألاحظ، وحسبت الـ f للبوتاسيوم والـ f
+
+315
+00:24:38,250 --> 00:24:43,250
+للكبريتات، راح ألاحظ إن الـ f للبوتاسيوم بتصير 0.79
+
+316
+00:24:43,250 --> 00:24:48,350
+يعني لما نزود التركيز إيش بيحصل للـ f؟ بتقل، هي كانت
+
+317
+00:24:48,350 --> 00:24:55,110
+0.92 صارت 0.79، لكن اتطلع للكبريتات كمان، لما زودت
+
+318
+00:24:55,110 --> 00:25:01,330
+التركيز، التركيز حصل مش بس قلت، قلت بشكل كبير جدًا، آه
+
+319
+00:25:01,330 --> 00:25:07,610
+لأن تأثير الشحنة كبير جدًا على الـ f، فكل ما زادت
+
+320
+00:25:07,610 --> 00:25:12,950
+التركيز الـ f بيقل، وكل ما زادت الشحنة الـ f بيقل
+
+321
+00:25:12,950 --> 00:25:18,630
+بشكل كبير للغاية، إذًا الآن بنقدر نحسب الـ ionic
+
+322
+00:25:18,630 --> 00:25:23,860
+strength للمحلول، وأيضًا بنقدر نحسب الـ activity
+
+323
+00:25:23,860 --> 00:25:29,080
+coefficients للأيونات المختلفة، طيب كيف بنستخدم هذا
+
+324
+00:25:29,080 --> 00:25:32,040
+الكلام في الحياة العملية؟ إيش معنى هذا الكلام؟ كيف
+
+325
+00:25:32,040 --> 00:25:34,300
+بنستخدمه؟ خليني أطلع على
+
+326
+00:25:37,290 --> 00:25:42,890
+معادلة كتير بسيطة، نتكلم فيها عن إيش علاقة أو ليش
+
+327
+00:25:42,890 --> 00:25:47,490
+بيه، إيش أهمية الـ activity coefficients في دراستنا
+
+328
+00:25:47,490 --> 00:25:51,130
+في شغلنا، ليش احنا مهتمين فيه؟ قال لأن الـ activity
+
+329
+00:25:51,130 --> 00:25:54,990
+بتساوي التركيز في الـ activity coefficient، فأنا إذا
+
+330
+00:25:54,990 --> 00:25:59,030
+قدرت أحسب الـ activity coefficient بقدر أحسب
+
+331
+00:25:59,030 --> 00:26:04,450
+الـ activity، كويس، هذه حاجة، الحاجة الثانية بقدر أنا
+
+332
+00:26:05,490 --> 00:26:12,510
+أقارن الآن بين الـ activity والتركيز، بالمعلومات الـ
+
+333
+00:26:12,510 --> 00:26:15,810
+activity coefficient وبالتالي بقدر أقارن بين حاجة
+
+334
+00:26:15,810 --> 00:26:18,670
+تسمى thermodynamic equilibrium constant و
+
+335
+00:26:18,670 --> 00:26:21,730
+concentration equilibrium constant، الـ activity
+
+336
+00:26:21,730 --> 00:26:23,870
+اللي هي علاقة بالـ thermodynamic equilibrium
+
+337
+00:26:23,870 --> 00:26:28,810
+constant، التركيز اللي هي علاقة بالـ concentration
+
+338
+00:26:28,810 --> 00:26:32,800
+equilibrium constant، إيش يعني thermodynamic
+
+339
+00:26:32,800 --> 00:26:36,740
+equilibrium constant؟
+
+340
+00:26:36,740 --> 00:26:39,880
+شوفنا سابقًا إن الـ thermodynamic equilibrium
+
+341
+00:26:39,880 --> 00:26:45,540
+constant هو الـ equilibrium constant اللي أنا بحصل
+
+342
+00:26:45,540 --> 00:26:48,420
+عليه من الـ thermodynamic equations
+
+343
+00:26:53,330 --> 00:26:57,010
+والـ ΔG° بقدر أجيبها ΔH° - T
+
+344
+00:26:57,010 --> 00:27:00,790
+ΔS°، بقدر أجيبها الـ ΔH° من الجداول و
+
+345
+00:27:00,790 --> 00:27:03,130
+ΔS° من الجداول، والحرارة هي الحرارة اللي
+
+346
+00:27:03,130 --> 00:27:07,270
+بشتغل عندها، فأنا بسهولة بقدر أحسب، قلنا الـ
+
+347
+00:27:07,270 --> 00:27:09,970
+thermodynamic equilibrium constant من الـ
+
+348
+00:27:09,970 --> 00:27:14,230
+thermodynamics، طيب إيش بيحصل لو أنا حسبت الـ
+
+349
+00:27:14,230 --> 00:27:19,930
+activity coefficient وحوّلت التركيز لـ activity؟ قال
+
+350
+00:27:23,670 --> 00:27:26,750
+الـ thermodynamic equilibrium constant، انتبهوا عليه،
+
+351
+00:27:26,750 --> 00:27:29,750
+بيساوي الـ activity للنواتج على الـ activity
+
+352
+00:27:29,750 --> 00:27:34,570
+للمتفاعلات، طب لو حسبت الـ thermodynamic equilibrium
+
+353
+00:27:34,570 --> 00:27:37,990
+constant من التركيز والـ activity coefficients، يعني من
+
+354
+00:27:37,990 --> 00:27:43,190
+الـ activities، هل اللي بيجي بيشبه الـ activity الـ
+
+355
+00:27:43,190 --> 00:27:47,330
+thermodynamic equilibrium constant من الـ
+
+356
+00:27:47,330 --> 00:27:51,250
+thermodynamic equations؟ بقول هو نفسه، هو نفسه، بحصل
+
+357
+00:27:51,250 --> 00:27:55,610
+على نفس النتيجة، لكن احنا قلنا سابقًا إنه الـ
+
+358
+00:27:55,610 --> 00:27:59,410
+thermodynamic equilibrium constant المحسوب من الـ
+
+359
+00:27:59,410 --> 00:28:02,810
+thermodynamics بيختلف عن الـ concentration
+
+360
+00:28:02,810 --> 00:28:07,170
+equilibrium constants في أحيان كثيرة، ولا يساوي إلا
+
+361
+00:28:07,170 --> 00:28:10,410
+تحت شروط، لكن الـ thermodynamic equilibrium constant
+
+362
+00:28:10,410 --> 00:28:14,030
+المحسوب من الـ activities دائمًا بيساوي الـ
+
+363
+00:28:14,030 --> 00:28:16,670
+thermodynamic equilibrium constant المحسوب من الـ
+
+364
+00:28:16,670 --> 00:28:25,110
+thermodynamic equations، فنرجع ثاني، بس شوية، بدنا بس
+
+365
+00:28:25,110 --> 00:28:28,870
+نشوف إن الـ equilibrium constant اللي هو قدامي هذا
+
+366
+00:28:28,870 --> 00:28:32,430
+اسمه concentration equilibrium constant لأنه
+
+367
+00:28:32,430 --> 00:28:38,290
+مستخدم التركيزات، طيب أنا لما بدي أستخدم الـ
+
+368
+00:28:38,290 --> 00:28:41,170
+activities وأطلع الـ K thermodynamic بقول، طب ما هي
+
+369
+00:28:41,170 --> 00:28:44,450
+الـ activity عبارة عن التركيز في الـ A في الـ
+
+370
+00:28:44,450 --> 00:28:46,970
+activity coefficient، يبقى الـ K thermodynamic
+
+371
+00:28:46,970 --> 00:28:50,630
+تعالوا نعوّض عن الـ activity لـ A، بنعوّض عنها بتركيز A
+
+372
+00:28:50,630 --> 00:28:56,030
+مضروب في الـ f لـ A، طب والـ activity لـ B؟ قال تركيز
+
+373
+00:28:56,030 --> 00:28:59,750
+B مضروب في الـ f لـ B، طب والـ activity لـ AB؟
+
+374
+00:28:59,750 --> 00:29:06,570
+تركيز الـ AB في الـ f لـ AB، مش هيك؟ طب ما نطول
+
+375
+00:29:06,570 --> 00:29:09,630
+الشرح، اللي في الـ slide اللي جايبه، إن الـ A في الـ B
+
+376
+00:29:09,630 --> 00:29:12,630
+على الـ AB هذا عبارة عن الـ concentration
+
+377
+00:29:12,630 --> 00:29:16,710
+equilibrium constant، إذًا الـ K thermodynamic هلاحظ
+
+378
+00:29:16,710 --> 00:29:24,120
+إنه بيساوي الـ K concentration في حاصل ضرب fA fB على
+
+379
+00:29:24,120 --> 00:29:30,560
+fAB، معناه الكلام في علاقة بين الـ concentration
+
+380
+00:29:30,560 --> 00:29:33,200
+equilibrium constant والـ thermodynamic
+
+381
+00:29:33,200 --> 00:29:36,980
+equilibrium constant، لكن العلاقة هذه محكومة بقيم
+
+382
+00:29:36,980 --> 00:29:43,520
+الـ f، طب احنا يا شباب الـ equilibrium constants اللي
+
+383
+00:29:43,520 --> 00:29:47,260
+معنا هذه، هل هي في الجداول اللي بنجيبها في الكتب و
+
+384
+00:29:47,260 --> 00:29:50,120
+في الأسئلة وفي الامتحانات، هل هي thermodynamic
+
+385
+00:29:50,120 --> 00:29:53,340
+equilibrium constants ولا concentration
+
+386
+00:29:53,340 --> 00:29:57,450
+equilibrium constants؟ بنقول هي thermodynamic
+
+387
+00:29:57,450 --> 00:30:02,910
+equilibrium constants دائمًا، ليه؟ لأنه لو بدي أحط
+
+388
+00:30:02,910 --> 00:30:07,130
+قيمة الـ concentration equilibrium constant يجب علي
+
+389
+00:30:07,130 --> 00:30:13,650
+أن أحط إيش الـ ionic strength للمحلول، ليه؟ لأنه أنا
+
+390
+00:30:13,650 --> 00:30:17,530
+بحسب قيمة الـ concentration equilibrium constant
+
+391
+00:30:17,530 --> 00:30:24,050
+عند ionic strength معينة، عند تركيز معين من الـ
+
+392
+00:30:24,050 --> 00:30:28,290
+diverse ions، وإلا لو ما كانش فيه عندي diverse ions
+
+393
+00:30:28,290 --> 00:30:34,610
+معنى الكلام fA وfB وfAB كلها إيش بتساوي؟ واحد، لأنه
+
+394
+00:30:34,610 --> 00:30:37,910
+ما فيش عندي diverse ions، معنى الكلام آه الـ K بتساوي
+
+395
+00:30:37
+
+445
+00:34:02,970 --> 00:34:08,450
+F<sub>AB</sub> بتساوي واحد لإنه احنا قولنا من خصائص  الـ F أنه
+
+446
+00:34:08,450 --> 00:34:12,550
+الـ F تساوي واحد for uncharged species فأي مادة
+
+447
+00:34:12,550 --> 00:34:17,410
+مافيش عليها شحنة معناته الـ F لها قيمة واحد. طيب  تمام
+
+448
+00:34:17,410 --> 00:34:20,930
+الـ thermodynamic equilibrium constant = 2 × 10<sup>−8</sup>
+
+449
+00:34:20,930 --> 00:34:24,530
+طبعا هذه المسألة اللي حللناها قبل شوية
+
+450
+00:34:24,530 --> 00:34:28,090
+وشوفنا أن الـ K<sub>thermodynamic</sub>  بساوي K<sub>F</sub>  للـ A
+
+451
+00:34:28,090 --> 00:34:32,630
++ F للـ B − F للـ AB = 2 × 10
+
+452
+00:34:32,630 --> 00:34:36,230
+<sup>−8</sup>  بیتساوي الـ K<sub>concentration</sub>
+
+453
+00:34:36,230 --> 00:34:41,730
+equilibrium constant if للـ A + 0.6 if للـ B
+
+454
+00:34:41,730 --> 00:34:47,110
+− 0.7 if للـ AB = 1. إذا الـ concentration
+
+455
+00:34:47,110 --> 00:34:51,490
+equilibrium constant بده يساوي 5 × 10<sup>−8</sup>
+
+456
+00:34:51,490 --> 00:34:54,990
+يا ريت تتقارن ما بينه وما بين الـ
+
+457
+00:34:54,990 --> 00:34:58,350
+thermodynamic equilibrium constant. إيش بتلاحظ؟
+
+458
+00:35:01,210 --> 00:35:09,690
+الـ K<sub>concentration</sub> أكبر، وضعه طبيعي، ليش طيب أكبر؟
+
+459
+00:35:09,690 --> 00:35:15,380
+ليش أكبر؟ ليش أكبر؟ لأنه ببساطة خلاص احنا قلنا أنه
+
+460
+00:35:15,380 --> 00:35:20,200
+لما يكون في عينة diverse ions بتضطر المادة في
+
+461
+00:35:20,200 --> 00:35:25,000
+تتفكك أكثر. ليش بتتفكك أكثر؟ بيحصل shielding للـ
+
+462
+00:35:25,000 --> 00:35:29,120
+أيونات المادة وبالتالي التفكك بيزيد. لما التفكك
+
+463
+00:35:29,120 --> 00:35:34,600
+بيزيد،  النواتج بتزيد والمتفاعلات بتقل. الـ
+
+464
+00:35:34,600 --> 00:35:37,960
+equilibrium constant حاصل قسمة النواتج على
+
+465
+00:35:37,960 --> 00:35:41,250
+المتفاعلات. إذن، وضع طبيعي أن الـ concentration
+
+466
+00:35:41,250 --> 00:35:45,590
+equilibrium constant يكبر، يزيد عن الـ thermodynamic
+
+467
+00:35:45,590 --> 00:35:51,430
+equilibrium constant، لأنه التفكك بشكل طبيعي زاد. طيب
+
+468
+00:35:51,430 --> 00:35:58,150
+نيجي نتطلع على مسألة مقارنة. في الأول، هاخد تفكك
+
+469
+00:35:58,150 --> 00:36:02,610
+هالمادة اللي هي AB في الماء. بعدين هاخد تفكك الـ AB
+
+470
+00:36:02,610 --> 00:36:09,900
+في وجود diverse ions وأقارن بين الحالتين. بدي آخد
+
+471
+00:36:09,900 --> 00:36:15,100
+أول حاجة، تفكك الـ AB في الماء، وهاخد تفكك الـ AB بعدين
+
+472
+00:36:15,100 --> 00:36:19,660
+في وجود إيه؟ diverse ions، وأشوف إيش كيف بتزيد
+
+473
+00:36:19,660 --> 00:36:23,360
+نسبة التفكك. فخلينا نطلع على المثال اللي قدامي
+
+474
+00:36:23,360 --> 00:36:26,640
+المثال إيش بيقول؟ calculate the percent
+
+475
+00:36:26,640 --> 00:36:29,440
+dissociation of 1 × 10<sup>−4</sup>
+
+476
+00:36:29,440 --> 00:36:34,820
+molar AB in water. مش شرط يقول لي in water، الوضع
+
+477
+00:36:34,820 --> 00:36:38,460
+الطبيعي أنه in water، لكن أحيانا بيعطيني
+
+478
+00:36:38,460 --> 00:36:42,480
+معلومات. بس إذا كان هو في diverse ions، إذا كان في
+
+479
+00:36:42,480 --> 00:36:45,520
+وجود diverse ions بيعطيني هذه المعلومات أو بيقول لي الـ
+
+480
+00:36:45,520 --> 00:36:48,560
+ionic strength هالجديد، أو بيقول لي الـ activity
+
+481
+00:36:48,560 --> 00:36:52,340
+coefficients هالجديد. ساعتها بعرف، لكن إذا ما جاب لي
+
+482
+00:36:52,340 --> 00:36:56,660
+الـ ionic strength الجديد، أو في وجود diverse ions، أو
+
+483
+00:36:56,660 --> 00:36:59,900
+ما عطانيش قيمة الـ F، إذا الوضع الطبيعي أنه في الماء.
+
+484
+00:37:00,980 --> 00:37:07,160
+معظم شغلنا في الماء، إلا لما نحدد حاجة ثانية. الـ
+
+485
+00:37:07,160 --> 00:37:09,460
+thermodynamic equilibrium constant = 2 × 10
+
+486
+00:37:09,460 --> 00:37:13,260
+<sup>−8</sup>. مجرد أنه قال لي في الماء ما جاب لي  
+
+487
+00:37:13,260 --> 00:37:17,660
+diverse ions. إذا الـ K<sub>thermodynamic</sub> يساوي الـ K<sub>
+
+488
+00:37:17,660 --> 00:37:21,660
+concentration</sub>. بعوض عنه تعويض مباشر. ليه؟ لأنه على
+
+489
+00:37:21,660 --> 00:37:26,060
+طول ما دام في الماء، إذا الـ F بتساوي واحد لكل… لكل
+
+490
+00:37:26,060 --> 00:37:30,390
+شيء، والـ K<sub>thermodynamic</sub> = K<sub>concentration</sub> طبعا
+
+491
+00:37:30,390 --> 00:37:34,010
+أنا بحل المسائل هذه بأن أكتب المعادلة، أحط
+
+492
+00:37:34,010 --> 00:37:39,090
+الأيونات أو التركيزات قبل الاتزان فوق، والتركيزات
+
+493
+00:37:39,090 --> 00:37:42,710
+بعد الاتزان تحت، بمراعاة قيمة الـ equilibrium
+
+494
+00:37:42,710 --> 00:37:46,470
+constant. طبعا الـ equilibrium constant أنه صغير
+
+495
+00:37:46,470 --> 00:37:51,250
+كتير، علشان هيك الـ AB بدها تتحول  بمقدار كمية ضئيلة جدا
+
+496
+00:37:51,250 --> 00:37:56,750
+مقدارها X، والنواتج راح تعطيني كميات برضه ضئيلة جدا
+
+497
+00:37:56,750 --> 00:38:00,550
+مقدارها X للـ A<sup>+</sup> و X للـ B<sup>−</sup>
+
+498
+00:38:04,000 --> 00:38:08,460
+عوّضت عنه مباشرة، الـ K حطيته محل الـ K<sub>concentration</sub>
+
+499
+00:38:08,460 --> 00:38:12,200
+إذا كنتم ملاحظين، الـ K حطيته محل الـ K<sub>concentration</sub>
+
+500
+00:38:12,200 --> 00:38:17,880
+يعني على طول K بتساوي A<sup>+</sup> × B<sup>−</sup> على الـ
+
+501
+00:38:17,880 --> 00:38:24,400
+AB. الـ A<sup>+</sup> = X، الـ B<sup>−</sup> = X، الـ AB = 10<sup>−4</sup> − X. لكن افترضت أنا أن الـ 10<sup>−4</sup>
+
+502
+00:38:24,400 --> 00:38:27,300
+أكبر بكثير من الـ X، لأن الـ equilibrium
+
+503
+00:38:27,300 --> 00:38:30,840
+constant صغير. فمعنى الكلام، الـ X بيطلع أنه 1.4 × 10<sup>−6</sup>
+
+504
+00:38:30,840 --> 00:38:35,290
+لو حبيت أجيب الـ relative
+
+505
+00:38:35,290 --> 00:38:37,790
+error بيطلع عندي 1.4%
+
+506
+00:38:37,790 --> 00:38:41,670
+مقبول… مقبول. الـ assumption is valid. مش عندي
+
+507
+00:38:41,670 --> 00:38:46,130
+مشكلة. percent dissociation: جداش كمية المتفكك
+
+508
+00:38:46,130 --> 00:38:51,750
+واللي تفكك على الكل في 100%. اللي تفكك
+
+509
+00:38:51,750 --> 00:38:56,250
+هو الـ X على الكل: 1 × 10<sup>−4</sup> × 100%.
+
+510
+00:38:56,250 --> 00:39:01,260
+بتطلع عندي 1.4%. هذه هي نسبة
+
+511
+00:39:01,260 --> 00:39:05,900
+التفكك. طيب، مش مشكلة. جداش حسب الـ equilibrium
+
+512
+00:39:05,900 --> 00:39:10,520
+constant، فهي صغيرة. ماشي يا شباب. طيب الآن، نحاول نأخذ
+
+513
+00:39:17,070 --> 00:39:22,170
+نفس المسألة لكن في وجود diverse ions. شوف شوف
+
+514
+00:39:22,170 --> 00:39:25,350
+صيغة السؤال. السؤال إيش بيقول؟ بيقول: calculate the
+
+515
+00:39:25,350 --> 00:39:30,190
+percent dissociation of 1 × 10<sup>−4</sup>
+
+516
+00:39:30,190 --> 00:39:35,820
+molar AB in presence of diverse ions. جالك  
+
+517
+00:39:35,820 --> 00:39:40,400
+عمليا في عنده إيه؟ diverse ions where the ionic strength is
+
+518
+00:39:40,400 --> 00:39:43,640
+0.1. كان كافي يعطيني بس الـ ionic strength. أنا ما أنا
+
+519
+00:39:43,640 --> 00:39:48,160
+بحسب الـ f values، لكن لأ، جالك and f للـ A<sup>+</sup> و f
+
+520
+00:39:48,160 --> 00:39:53,800
+للـ B<sup>−</sup> are 0.6 and 0.7. يعني، أعطيتني الـ F وكأنها
+
+521
+00:39:53,800 --> 00:39:57,320
+يعني هذه الـ 0.1 مش راح أستخدمها. لإيش بستخدم
+
+522
+00:39:57,320 --> 00:40:00,280
+الـ ionic strength؟ أنا بستخدمها عشان أجيب الـ F للـ A
+
+523
+00:40:00,280 --> 00:40:05,220
+<sup>+</sup> و F للـ B<sup>−</sup>. ما دام هو أعطاني  F للـ A<sup>+</sup> و
+
+524
+00:40:05,220 --> 00:40:08,580
+F للـ B، إذن ما بلزمنيش الـ 0.1 هذه، ما بلزمنيش إياها أصلا.
+
+525
+00:40:08,580 --> 00:40:14,180
+معلومة زيادة، كويس. لكن لو ما أعطانيش قيمة الـ f values، اه
+
+526
+00:40:14,180 --> 00:40:16,940
+بدي أحسبها باستخدام الـ 0.1. بقول الـ
+
+527
+00:40:16,940 --> 00:40:19,300
+thermodynamic equilibrium constant = 2 × 10
+
+528
+00:40:19,300 --> 00:40:23,580
+<sup>−8</sup>. طبعا أنا على طول بمجرد أنه جالي في
+
+529
+00:40:23,580 --> 00:40:27,540
+عنده diverse ions بعرف أن الـ K<sub>concentration</sub> مش هي
+
+530
+00:40:27,540 --> 00:40:30,780
+الـ K<sub>thermodynamic</sub>. كويس. لازم أحسب الـ K<sub>
+
+531
+00:40:30,780 --> 00:40:34,970
+concentration</sub> أو الـ Concentration Equilibrium
+
+532
+00:40:34,970 --> 00:40:38,210
+Constant. كيف بدي أحسبها؟ بنفس الطريقة حسبناها
+
+533
+00:40:38,210 --> 00:40:42,690
+سابقا، لكن بنفس الطريقة. يعني الـ K<sub>thermodynamic</sub> =
+
+534
+00:40:42,690 --> 00:40:46,190
+K × F<sub>A<sup>+</sup></sub>. طبعا لازم تعرف تعمل معادلة  هادئة لأي
+
+535
+00:40:46,190 --> 00:40:49,510
+equilibrium ولو كان في الـ equilibrium في عندك
+
+536
+00:40:49,510 --> 00:40:56,070
+مثلا 2C، مثلا بيصير تركيز الـ C<sup>2</sup>، بيصير
+
+537
+00:40:56,070 --> 00:41:01,800
+التركيز تربيع، والـ F كمان تربيع. كويس، لأنه بيكون الـ
+
+538
+00:41:01,800 --> 00:41:05,460
+activity تربيع. فإيش يعني activity تربيع؟ يعني
+
+539
+00:41:05,460 --> 00:41:09,680
+التركيز تربيع، والـ F تربيع. فأنت بتعرف تعمل الـ
+
+540
+00:41:09,680 --> 00:41:13,280
+equation في البداية، فبتقول: والله الـ K<sub>thermodynamic</sub> =
+
+541
+00:41:13,280 --> 00:41:18,190
+K<sub>concentration</sub> × F ratio. كبير. سلة عندك حسب
+
+542
+00:41:18,190 --> 00:41:22,610
+الاتزان، فبيقول: 2 × 10<sup>−8</sup> = K × (0.6 × 0.7 / 1)
+
+543
+00:41:22,610 --> 00:41:29,090
+لأن الـ F<sub>AB</sub> بتساوي 1، لأن الـ FAB غير
+
+544
+00:41:29,090 --> 00:41:35,150
+مشحون. K = 5 × 10<sup>−8</sup>. يعني سبق و
+
+545
+00:41:35,150 --> 00:41:40,150
+حسبناها قبل شوية. المهم أنه أول خطوة بنعملها بنحسب
+
+546
+00:41:41,850 --> 00:41:49,150
+الـ K<sub>concentration</sub>. طبعا، يعني بعد هيك بتصير
+
+547
+00:41:49,150 --> 00:41:54,650
+المسألة سهلة، بنعوض. إيش اللي استخدمنا K<sub>
+
+548
+00:41:54,650 --> 00:42:00,130
+concentration</sub>؟ بتساوي X × X اللي هي النواتج على
+
+549
+00:42:03,350 --> 00:42:07,350
+اللي هو عبارة عن 10<sup>−4</sup>
+
+550
+00:42:07,350 --> 00:42:11,190
+− X. لكن بنفترض أن الـ 10<sup>−4</sup> أكبر
+
+551
+00:42:11,190 --> 00:42:14,530
+كتير من الـ X، فبتصير عندي 10<sup>−4</sup>. الـ
+
+552
+00:42:14,530 --> 00:42:18,590
+X بتطلع 2.2 × 10<sup>−6</sup>. لو حسبنا
+
+553
+00:42:18,590 --> 00:42:21,710
+الـ relative error بتطلع عندي 2.2%
+
+554
+00:42:21,710 --> 00:42:25,270
+هو بده الـ percent dissociation، إيش بتساوي؟
+
+555
+00:42:25,270 --> 00:42:29,390
+الـ percent dissociation: بقول الـ percent dissociation
+
+556
+00:42:29,390 --> 00:42:34,640
+بتساوي الـ amount dissociated (الكمية اللي تفككت) على
+
+557
+00:42:34,640 --> 00:42:37,780
+الكل × 100%. اللي تفككت 2.2 × 10
+
+558
+00:42:37,780 --> 00:42:41,300
+<sup>−6</sup> على الكل 1 × 10<sup>−4</sup> × 100%.
+
+559
+00:42:41,300 --> 00:42:45,760
+بتطلع عندي 2.2%. طيب، هي جداش كانت قيمتها في الأول في
+
+560
+00:42:45,760 --> 00:42:49,700
+الماء؟ جداش كانت 1.4%. زيادة لـ 2.2%
+
+561
+00:42:49,700 --> 00:42:54,200
+من عشرة. هل الزيادة زيادة ملحوظة كبيرة؟ الزيادة
+
+562
+00:42:54,200 --> 00:43:01,550
+بنقول عادة من الخطأ أن نقارن القيم المجردة، أو
+
+563
+00:43:01,550 --> 00:43:06,170
+النتائج المجردة. الأفضل لنا عشان نعرف هل الزيادة
+
+564
+00:43:06,170 --> 00:43:10,810
+زيادة كبيرة محسوسة ولا زيادة ضئيلة غير محسوسة، أنه
+
+565
+00:43:10,810 --> 00:43:14,990
+نجيب حاجة نقولها: percent increase in solubility.
+
+566
+00:43:15,610 --> 00:43:19,850
+percent increase: يعني نسبة الزيادة في الذوبانية.
+
+567
+00:43:19,850 --> 00:43:25,450
+فنسبة الزيادة في الذوبانية: النسبة الجديدة 2.2%
+
+568
+00:43:25,450 --> 00:43:32,230
+− النسبة القديمة 1.4% / 1.4% × 100%. بيطلع عند
+
+569
+00:43:32,230 --> 00:43:38,410
+نسبة زيادة نقدرها 57%. أنا بالنسبة لي نسبة زيادة 57%
+
+570
+00:43:38,410 --> 00:43:44,350
+تعتبر زيادة كبيرة جدا، كبيرة جدا. صح، لما نقارن 1.4%
+
+571
+00:43:44,350 --> 00:43:49,510
+لـ 2.2% لا تبدو هالزيادة يعني ملحوظة، لكن لما نجيب
+
+572
+00:43:49,510 --> 00:43:53,130
+الـ percent increase بيبين عندنا أن في عندنا نسبة
+
+573
+00:43:53,130 --> 00:43:59,310
+زيادة مقدارها حوالي 57%. هذه نسبة تعتبر نسبة عالية
+
+574
+00:43:59,310 --> 00:44:00,730
+للغاية.
+
+575
+00:44:03,160 --> 00:44:11,680
+بس يعني بأحب أن ألفت انتباهك لإنه الموضوع هذا
+
+576
+00:44:11,680 --> 00:44:16,720
+هيمر معنا في عدة مراحل أو عدة نقاط في شباتر
+
+577
+00:44:16,720 --> 00:44:22,560
+مختلفة جاية. لكن ما تستخدمش… أو أنت هتحل عادي زي ما
+
+578
+00:44:22,560 --> 00:44:26,620
+كنا بنحل سابقا قبل المقارنة، دائما إلا إذا كان
+
+579
+00:44:26,620 --> 00:44:30,920
+أعطيتك أن التفكك بيحصل في وجود ionic strength
+
+580
+00:44:30,920 --> 00:44:35,990
+معينة أو تركيز معين من مادة مالهاش علاقة في الـ
+
+581
+00:44:35,990 --> 00:44:40,290
+equilibrium. هذه تعتبر diverse ions، أو أعطتك قيمة الـ
+
+582
+00:44:40,290 --> 00:44:47,790
+F. ساعتها بدك تحاول ترجع ثانية وتقول: لأ، بدي أجيب
+
+583
+00:44:47,790 --> 00:44:50,490
+الـ concentration equilibrium constant في الأول.
+
+584
+00:44:50,490 --> 00:44:55,350
+وبرضه كمان، بنصحك بحاجة. ممكن ما تجيبش الـ
+
+585
+00:44:55,350 --> 00:45:01,150
+concentration equilibrium constant، يعني في خطوة
+
+586
+00:45:01,150 --> 00:45:07,070
+مُستقلة، دائما اعتبر أنت أن الـ K<sub>thermodynamic</sub>
+
+587
+00:45:07,070 --> 00:45:10,990
+بيساوي activity النواتج على activity
+
+588
+00:45:10,990 --> 00:45:16,830
+للمتفاعلات. أعوض عن الـ activities بالتركيزات مضروبة
+
+589
+00:45:16,830 --> 00:45:24,200
+في الـ F ratio. في الـ ratio f مثلا للـ A<sup>+</sup>، f للـ B
+
+590
+00:45:24,200 --> 00:45:28,760
+<sup>−</sup> على الـ f للـ AB. التركيزات هذه ما أنت بتعوض
+
+591
+00:45:28,760 --> 00:45:34,340
+عنها من الجدول. الآن، مثلا الـ A<sup>+</sup> = X، الـ B<sup>−</sup> = X،
+
+592
+00:45:34,340 --> 00:45:39,040
+الـ AB = 10<sup>−4</sup> − X. ممكن تحسبها
+
+593
+00:45:39,040 --> 00:45:43,030
+كلها بخطوة واحدة بإمكانك. أو إنك تجيب في الأول
+
+594
+00:45:43,030 --> 00:45:45,710
+concentration equilibrium constant وهو اللي
+
+595
+00:45:45,710 --> 00:45:50,670
+تستخدمه في التعويض. هنحاول نجمعك في المرحلة الجاية
+
+596
+00:45:50,670 --> 00:45:56,350
+أنه: لأ، نستخدم خطوة واحدة أسهل عليك. فهل تستخدم
+
+597
+00:45:56,350 --> 00:45:58,850
+الفكرة الآن؟ هل تستخدم الـ activity ولا الـ
+
+598
+00:45:58,850 --> 00:46:04,310
+concentration؟ هذا بتوقف على هل معاك diverse ions
+
+599
+00:46:04,310 --> 00:46:11,140
+أو ionic strength أو قيمة للـ F. ماشي يا شباب، هيك
+
+600
+00:46:11,140 --> 00:46:14,740
+بنكون خلصنا الـ chapter الخاص بالـ equilibrium وإذا
+
+601
+00:46:14,740 --> 00:46:18,400
+الله راد، الحصة الجاية بنتكلم عن حاجة بنقولها
+
+602
+00:46:18,400 --> 00:46:21,200
+gravimetric analysis أو تحليل وزني
+
diff --git a/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/9CTPmf94pcg_raw.srt b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/9CTPmf94pcg_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..3daccac4ff33b65ca9496f61b556452cf284fb72
--- /dev/null
+++ b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/9CTPmf94pcg_raw.srt
@@ -0,0 +1,2412 @@
+1
+00:00:20,670 --> 00:00:25,070
+طيب اليوم ان شاء الله بنحاول انه نستكمل ال chapter
+
+2
+00:00:25,070 --> 00:00:29,930
+اللي بدأناه بخصوص ال general equilibrium concepts
+
+3
+00:00:29,930 --> 00:00:36,390
+او المفاهيم الأساسية في الإتزان بنتكلم اليوم إذا
+
+4
+00:00:36,390 --> 00:00:40,390
+الله راد عن موضوع كتير مهم و حيمور معنا في أكتر من
+
+5
+00:00:40,390 --> 00:00:45,450
+مرحلة جاية نتكلم عن ال activity و ال activity
+
+6
+00:00:45,450 --> 00:00:48,290
+coefficients و إيش علاقة ال activity بال
+
+7
+00:00:48,290 --> 00:00:50,290
+equilibrium constant
+
+8
+00:00:53,150 --> 00:00:58,310
+في البداية لو أجينا نتكلم عن ال activity، بنقول
+
+9
+00:00:58,310 --> 00:01:01,630
+إيش هي ال activity؟ كثير من الناس ممكن يعرفها يقول
+
+10
+00:01:01,630 --> 00:01:05,050
+والله ال activity هي عبارة عن ال effective
+
+11
+00:01:05,050 --> 00:01:10,750
+concentration احنا لما بنتكلم عن ال activity فيما
+
+12
+00:01:10,750 --> 00:01:17,890
+يتعلق بال equilibrium reactions عادة في عندي، مدام
+
+13
+00:01:17,890 --> 00:01:22,120
+عندي equilibrium في عندي weak electrolyteفي عندى
+
+14
+00:01:22,120 --> 00:01:25,640
+weak electrolyte موجود فى المحلول ال weak
+
+15
+00:01:25,640 --> 00:01:31,740
+electrolyte الاصل انه بيتفكك جزئيا و بيعطينا نواتج
+
+16
+00:01:31,740 --> 00:01:36,380
+ممكن اكتب equilibrium constant طيب ايش بيحصل لو
+
+17
+00:01:36,380 --> 00:01:40,760
+انه هال weak electrolyte هذا اضفنا عليه strong
+
+18
+00:01:40,760 --> 00:01:45,900
+electrolyte لكنيحتوي ال strong electrolyte على
+
+19
+00:01:45,900 --> 00:01:50,840
+ايونات مخالفة مش مشابهة مش common ions لأ ال
+
+20
+00:01:50,840 --> 00:01:54,560
+strong electrolyte هو قدر عن diverse ions diverse
+
+21
+00:01:54,560 --> 00:01:59,960
+مختلفة عن الايونات اللي عندي في المحلول بنلاحظ
+
+22
+00:01:59,960 --> 00:02:06,740
+ببساطة خالص ان ال acetic acid مثلا ك weak
+
+23
+00:02:06,740 --> 00:02:12,010
+electrolyte بيتفكك وبعطيني H plus و Acetateفي
+
+24
+00:02:12,010 --> 00:02:15,510
+الميّه عادي H بلس و Acetate مش عندى مشكلة لكن لو
+
+25
+00:02:15,510 --> 00:02:21,070
+حطينا عليه strong electrolyte زى ال KNO3 او انه
+
+26
+00:02:21,070 --> 00:02:27,590
+اضافنا ال acetic acid على محلول KNO3 بنلاحظ انه
+
+27
+00:02:30,220 --> 00:02:35,360
+الـ H Plus بيجذب له الأيونات المخالفة اللي في
+
+28
+00:02:35,360 --> 00:02:39,140
+الشحنة وفي هذه الحالة هي عبارة عن الـ Nitrate لأنه
+
+29
+00:02:39,140 --> 00:02:43,360
+موجود كمية كبيرة من الـ Nitrate فبالتالي بتكون
+
+30
+00:02:43,360 --> 00:02:47,460
+سفير من الـ Nitrate حوالين الـ H Plus وبنفس
+
+31
+00:02:47,460 --> 00:02:52,060
+الطريقة الأسيتات بيجذب الأيونات المخالفة اللي في
+
+32
+00:02:52,060 --> 00:02:56,900
+الشحنة فبيتكون عند سفير من ال potassium ions
+
+33
+00:02:56,900 --> 00:02:59,280
+حوالين الأسيتات
+
+34
+00:03:01,340 --> 00:03:06,800
+ففي الحقيقة إذا كان التركيز لل diverse ions اللي
+
+35
+00:03:06,800 --> 00:03:11,180
+هو ال potassium نيتريت كان كبير فبيحصل حجب كامل
+
+36
+00:03:11,180 --> 00:03:15,680
+shielding كامل ل ال acetate عن ال H plus عن ال
+
+37
+00:03:15,680 --> 00:03:20,920
+acetic acid فال acetic acid بيتطر إنه يتفكك علشان
+
+38
+00:03:20,920 --> 00:03:28,360
+يعطيني H plus و acetate to justify أو to .. يعني
+
+39
+00:03:28,360 --> 00:03:28,680
+..
+
+40
+00:03:32,120 --> 00:03:35,600
+ماتش الهو ال equilibrium constant قيمة ال
+
+41
+00:03:35,600 --> 00:03:39,040
+equilibrium constant اللي عنده فبضطر لإنه مش ملاقي
+
+42
+00:03:39,040 --> 00:03:42,400
+الايونات تبعته ال H بلس و ال Acetate صارت محجوبة
+
+43
+00:03:42,400 --> 00:03:49,920
+فالacetic acid بيتفكك بالزيادة علشان يعوضالـ H
+
+44
+00:03:49,920 --> 00:03:53,120
+Plus والأسيتات اللي حصلها حجب وبالتالي إيش بيحصل
+
+45
+00:03:53,120 --> 00:03:57,700
+عمال للـ equilibrium؟ بيمشي في الاتجاه الأماني طيب
+
+46
+00:03:57,700 --> 00:04:00,740
+لأنه احنا عمال بنقول أستيكاسد بضطر أنه يتفكك
+
+47
+00:04:00,740 --> 00:04:04,640
+بزيادة لأن آيوناته محجوبة فبده يعوض عن الآيونات
+
+48
+00:04:04,640 --> 00:04:09,090
+المحجوبة فبيتفكك طب على أي أساس هذا الكلام؟يعني
+
+49
+00:04:09,090 --> 00:04:12,210
+احنا بنعرف انه لتشت ليه بيقول والله إذا كان قضفنا
+
+50
+00:04:12,210 --> 00:04:15,650
+H بلس التفاعل بيرجي على ورا إذا كان قضفنا أسيتيت
+
+51
+00:04:15,650 --> 00:04:18,350
+التفاعل بيرجي على ورا إذا كان قضفنا أستيك أسيتيت
+
+52
+00:04:18,350 --> 00:04:22,730
+التفاعل بيمشي للأمام طب لما نضيف K بلس ال K بلس
+
+53
+00:04:22,730 --> 00:04:28,310
+مالهاش علاقة بال equilibrium ال .. ال nitrate أيضا
+
+54
+00:04:28,310 --> 00:04:34,390
+مالهاش علاقة بال equilibrium ف .. لكن نظرا لها ال
+
+55
+00:04:34,390 --> 00:04:39,130
+shielding اللي بيحصلزي ما شفناها الـ gate اه ال
+
+56
+00:04:39,130 --> 00:04:42,370
+equilibrium بيمشي في الاتجاه الأمامي معنى الكلام
+
+57
+00:04:42,370 --> 00:04:48,070
+قيمة ال equilibrium constant بتزيد فممكن الآن نرجع
+
+58
+00:04:48,070 --> 00:04:52,970
+و نعرف ال activity لأي ion I و ليكن H plus او
+
+59
+00:04:52,970 --> 00:04:56,950
+الacetate مثلا فبنقول ال activity لل ion I هي
+
+60
+00:04:56,950 --> 00:05:03,250
+عبارة عن ال concentration لل ion I في وجود
+
+61
+00:05:05,690 --> 00:05:11,990
+strong electrolyte من diverse ions ايونات
+
+62
+00:05:11,990 --> 00:05:14,990
+مخالفة الايونات اللي في ال equilibrium فال
+
+63
+00:05:14,990 --> 00:05:18,010
+activity هي عبارة عن ال concentration يعني molar
+
+64
+00:05:18,010 --> 00:05:22,770
+مولاريتي هي عبارة عن ال concentration لل ايون لكن
+
+65
+00:05:22,770 --> 00:05:28,570
+في ايش في وجودstrong electrolyte من ايه؟ من
+
+66
+00:05:28,570 --> 00:05:33,030
+diverse ions فانا بقدر اقول ان ال AI اللي هي ال
+
+67
+00:05:33,030 --> 00:05:39,650
+activity للايون I تساوي تركيز الايون I CI في معامل
+
+68
+00:05:39,650 --> 00:05:46,050
+او factor بنقوله activity coefficient Fi activity
+
+69
+00:05:46,050 --> 00:05:49,530
+coefficient ومن هذه العلاقة بقدر اقول حاجة انا
+
+70
+00:05:49,530 --> 00:05:53,770
+بقدر اقول ال activity هو التركيز اذا كان ال F دي
+
+71
+00:05:53,770 --> 00:05:58,170
+ايش بتساوي؟ واحدطب وقتاش ال F بتساوي واحد قال
+
+72
+00:05:58,170 --> 00:06:01,550
+والله ال F بتساوي واحد اذا كان فش عندي diverse
+
+73
+00:06:01,550 --> 00:06:07,230
+ions لو فش عندي diverse ions فال F ابوا واحد او او
+
+74
+00:06:07,230 --> 00:06:11,350
+ممكن يكون عندي diverse ions لكن تركيز ال diverse
+
+75
+00:06:11,350 --> 00:06:15,850
+ion صغير جدا ابحث انه مش لايستطيع انه يعمل
+
+76
+00:06:15,850 --> 00:06:20,750
+shielding يعنيالـ F برضه بتساوي 1 لو كان تركيز ال
+
+77
+00:06:20,750 --> 00:06:25,010
+diverse ion أقل من 10 أقل سالب 4 مولار أقل من 10
+
+78
+00:06:25,010 --> 00:06:30,210
+أقل سالب 4 مولار لا يستطيع ال diverse ion أنه يعمل
+
+79
+00:06:30,210 --> 00:06:34,630
+spheres من الأيونات المخالفة للأيونات الموجودة
+
+80
+00:06:34,630 --> 00:06:39,050
+ويعطيني shielding وبالتالي ال equilibrium برضه
+
+81
+00:06:39,050 --> 00:06:42,070
+بيظل زي ما هو لأن ال F أو ال activity coefficient
+
+82
+00:06:42,070 --> 00:06:47,320
+في هذه الحالة بتساوي 1من هذا الكلام ممكن يعني
+
+83
+00:06:47,320 --> 00:06:51,880
+نتعرف على الخصائص العامة لل activity coefficient
+
+84
+00:06:51,880 --> 00:06:55,560
+لأنه أنا بهمني أحسب ال activity التركيز معروف
+
+85
+00:06:55,560 --> 00:07:00,060
+التركيز معروف لكن عشان أقدر أحسب ال activity لازم
+
+86
+00:07:00,060 --> 00:07:03,360
+أكون عارف ال activity coefficient فمهم عندي أني
+
+87
+00:07:03,360 --> 00:07:07,820
+أعرف خصائص ال activity coefficient قلت خاصيتين من
+
+88
+00:07:07,820 --> 00:07:11,650
+خصائص ال activity coefficientإنه في البداية بيساوي
+
+89
+00:07:11,650 --> 00:07:17,950
+واحد إذا لم يكن لدي عيون مختلفة او اذا اضافت مادة
+
+90
+00:07:17,950 --> 00:07:21,930
+مختلفة ولكن غير تحميل إذا لم يكن المادة لديها شحنة
+
+91
+00:07:21,930 --> 00:07:26,350
+فليس لديها عيون مختلفة التي بيساوي واحد مادام لا
+
+92
+00:07:26,350 --> 00:07:31,670
+يوجد شحنة على المادة المضافة كويس يعني ما اتأينتش
+
+93
+00:07:31,670 --> 00:07:37,190
+معناته ال if بيساوي واحد يبقى عيون مختلفة of
+
+94
+00:07:37,190 --> 00:07:43,460
+uncharged species is equal toone كويس هيك إذا كان
+
+95
+00:07:43,460 --> 00:07:46,740
+المادة غير مشحونة فال activity coefficient لهب
+
+96
+00:07:46,740 --> 00:07:51,640
+واحد أيضا ال activity coefficient بيساوي واحد إذا
+
+97
+00:07:51,640 --> 00:07:56,580
+كان التركيز اللي عندي أقل من عشرة أسالب أربعة
+
+98
+00:07:56,580 --> 00:08:00,520
+molar يعني very dilute solution و ال very dilute
+
+99
+00:08:00,520 --> 00:08:03,300
+solution يعني احنا كتير بنستخدمها في الكيمة
+
+100
+00:08:03,300 --> 00:08:07,840
+التحتية فلما يكون عندي التركيز قليل جدا معناته
+
+101
+00:08:07,840 --> 00:08:13,440
+برضه ال F بتساوي واحدلكن لاحظنا و إشي ممكن نستوقعه
+
+102
+00:08:13,440 --> 00:08:16,700
+هالجيت بعد ما طلعنا على كيف إن ال equilibrium
+
+103
+00:08:16,700 --> 00:08:21,500
+بيزيد في وجود ال diverse ions بقدر أقول والله كل
+
+104
+00:08:21,500 --> 00:08:27,460
+ما زاد تركيز ال diverse ion كل ما زاد بزيد التفكك
+
+105
+00:08:27,460 --> 00:08:33,380
+مش هيك معنى الكلام ال if بتجل يبقى ال if بتجل كل
+
+106
+00:08:33,380 --> 00:08:39,130
+ما زاد التركيز هذه حاجة و أيضا كمانعملية الحجب
+
+107
+00:08:39,130 --> 00:08:43,430
+كتير بتتأثر بالشحنة فلما الشحنة تكون بدل ما هي
+
+108
+00:08:43,430 --> 00:08:47,870
+أحادية ثنائية قدرة الشحنة الثنائية على الحجب أكتر
+
+109
+00:08:47,870 --> 00:08:53,090
+كتير من قدرة الشحنة الأحادية على الحجب علشان هيك
+
+110
+00:08:53,090 --> 00:09:01,350
+التفكك بيزيد كتير لما تكون في عند multi-valent ion
+
+111
+00:09:01,350 --> 00:09:06,500
+او multi-charged ionلما الايون يكون عليه charges
+
+112
+00:09:06,500 --> 00:09:10,180
+متعددة تين او تلاتة معناته القدرة على الحاجب بتزيد
+
+113
+00:09:10,180 --> 00:09:15,080
+وبالتالي عندي ال F طبعا التفكك بيزيد يعني ال F
+
+114
+00:09:15,080 --> 00:09:23,200
+اشماله بيقل بشكل ملحوظ هذه خصائص ال activity
+
+115
+00:09:23,200 --> 00:09:27,160
+coefficient من هذه الخصائص بقدر اقول ان ال
+
+116
+00:09:27,160 --> 00:09:31,400
+activity coefficient ده اللي في حاجتين ده اللي في
+
+117
+00:09:31,400 --> 00:09:37,180
+حاجتين ده اللي فيهالتركيز تركيز ال diverse ions
+
+118
+00:09:37,180 --> 00:09:43,800
+هذه خاشة ودالة أيضا في الشحنة ودالة في الشحنة
+
+119
+00:09:43,800 --> 00:09:48,700
+فيتأثر بالتركيز ويتأثر بالشحنة طيب لما نيجي نتكلم
+
+120
+00:09:48,700 --> 00:09:54,100
+في الكيميا احنا ايش علاقة التركيز بالشحنة بالمحلول
+
+121
+00:09:54,100 --> 00:09:56,180
+بنقول والله يمكن تعريف
+
+122
+00:09:59,720 --> 00:10:05,500
+شيء بنسميه القوة الأيونية للمحلول القوة الأيونية
+
+123
+00:10:05,500 --> 00:10:10,480
+للمحلول ايش القوة الأيونية للمحلول قال والله القوة
+
+124
+00:10:10,480 --> 00:10:19,900
+الأيونية للمحلول تساوي نص summation تركيز ال ion I
+
+125
+00:10:19,900 --> 00:10:28,820
+CI يعنيفي شحنة الايون I² Zi² فانا عندى بقدر اجيب
+
+126
+00:10:28,820 --> 00:10:33,900
+خاصية من خصائص المحلول سميتها Ionic strength القوة
+
+127
+00:10:33,900 --> 00:10:37,840
+الايونية للمحلول ايش القوة الايونية للمحلول بتساوي
+
+128
+00:10:37,840 --> 00:10:43,960
+جالب الله بتساوي نص summation Ci Zi²
+
+129
+00:10:45,550 --> 00:10:49,710
+طبعا القوة الأيونية للمحلول بتأثر على ال F، هنشوف
+
+130
+00:10:49,710 --> 00:10:53,270
+كيف بتأثر على ال F بعد شوية، لكن الآن مدام عرفنا
+
+131
+00:10:53,270 --> 00:10:56,750
+إيش هي القوة الأيونية للمحلول، تعالوا في الأول
+
+132
+00:10:56,750 --> 00:11:00,370
+ناخد أمثلة كيف نحسب القوة الأيونية للمحلول، و
+
+133
+00:11:00,370 --> 00:11:03,790
+بعدين بتشوف إيش تأثيرها على ال activity
+
+134
+00:11:03,790 --> 00:11:08,940
+coefficientفبقول نطلع على مثال كتير بسيط مباشر
+
+135
+00:11:08,940 --> 00:11:13,140
+بيقول calculate the ionic strength of a 0.2 molar
+
+136
+00:11:13,140 --> 00:11:18,540
+KNO3 عندي potassium nitrate طبعا هذا strong
+
+137
+00:11:18,540 --> 00:11:23,600
+electrolyte بدي أجيبنه القوة الايونية المحلول 0.2
+
+138
+00:11:23,600 --> 00:11:27,260
+molar ايش القوة الايونية المحلول فبقول والله نص
+
+139
+00:11:27,260 --> 00:11:33,450
+summation CIZI squared فبقول يعني نصفي نفتح جوس
+
+140
+00:11:33,450 --> 00:11:38,270
+تركيز البوتاسيوم نص
+
+141
+00:11:38,270 --> 00:11:42,690
+تركيز البوتاسيوم شحنة البوتاسيوم تربية زائد تركيز
+
+142
+00:11:42,690 --> 00:11:46,150
+النيتريت شحنة النيتريت تربية هي الايونات في عندي
+
+143
+00:11:46,150 --> 00:11:49,610
+ايونات تانية هي الايونات فبنقول و الله بتساوي نص
+
+144
+00:11:49,610 --> 00:11:54,070
+في point two التركيز للبوتاسيوم شحنة البوتاسيوم
+
+145
+00:11:54,070 --> 00:12:00,140
+واحد تربيةزائد point two شحنة التركيز ال nitrate
+
+146
+00:12:00,140 --> 00:12:03,820
+one squared اللي هي one اللي هي شحنة ال nitrate
+
+147
+00:12:03,820 --> 00:12:09,060
+بيطلع عندى القوة الايونية المحلول point two ماحدش
+
+148
+00:12:09,060 --> 00:12:12,000
+يحاول ييجي يقولي والله اه هذا ال potassium point
+
+149
+00:12:12,000 --> 00:12:17,470
+two ال nitrogen point two ال oxygen point sixمثلا
+
+150
+00:12:17,470 --> 00:12:21,790
+لأ هذا potassium nitrate القوة الايونية المحلولة
+
+151
+00:12:21,790 --> 00:12:24,950
+بتنحسب لها ال potassium من ال potassium و ال
+
+152
+00:12:24,950 --> 00:12:28,770
+nitrate هذه ال nitrate عبارة عن ايه عبارة عن
+
+153
+00:12:28,770 --> 00:12:35,470
+مجموعة functional group مجموعة فهي group مجموعة
+
+154
+00:12:35,470 --> 00:12:39,240
+بنقدرش نقول والله هذه كل واحد لحالةماشي كتير من
+
+155
+00:12:39,240 --> 00:12:42,880
+الطلاب بيجي في الامتحان بيعملي ال N لحالها و ال O
+
+156
+00:12:42,880 --> 00:12:46,080
+لحالها و ال potassium لحاله مش منطقي يعني اسمها
+
+157
+00:12:46,080 --> 00:12:50,180
+potassium nitrate يعني potassium o nitrate طب
+
+158
+00:12:50,180 --> 00:12:54,680
+خليني اتذكر هذه القيمة و خليني اخد مثال برضه point
+
+159
+00:12:54,680 --> 00:12:58,460
+two molar solution لكن بتاخد في هذا المثال شحنة
+
+160
+00:12:58,460 --> 00:13:02,660
+ثنائية و اشوف ايش تأثير الشحنة على ال ionic
+
+161
+00:13:02,660 --> 00:13:06,240
+strength على القوة الايونية المحلول ايش تأثير
+
+162
+00:13:06,240 --> 00:13:11,610
+الشحنة فنتطلع علىالـ equilibrium مش ال equilibrium
+
+163
+00:13:11,610 --> 00:13:15,110
+طلع على المحلول التالي بيقول calculate the ionic
+
+164
+00:13:15,110 --> 00:13:20,090
+strength of a 0.2 molar potassium sulfate ايش اللي
+
+165
+00:13:20,090 --> 00:13:24,550
+اختلف عند ال sulfate بدل ال nitrate لكن 0.2 molar
+
+166
+00:13:24,550 --> 00:13:28,450
+potassium potassium مش عندى مشكلة لكن بدل ال
+
+167
+00:13:28,450 --> 00:13:33,830
+nitrate اللي هي أحديةفي عند صلفات ثنائية بقول
+
+168
+00:13:33,830 --> 00:13:39,970
+والله ل ميو بتساوي نص summation cizi squared اذا ل
+
+169
+00:13:39,970 --> 00:13:46,750
+ميو بتساوي نص c للبوتاسيوزي سكويرد للبوتاسيوم زائد
+
+170
+00:13:46,750 --> 00:13:50,290
+C للصلفات زي سكويرد للصلفات يعني اللي بيبقى بتساوي
+
+171
+00:13:50,290 --> 00:13:53,870
+لو أخدنا تركيز البوتاسيوم لو لاحظته انتوا في هذا
+
+172
+00:13:53,870 --> 00:13:57,210
+المركب طبعا ضعف تركيز البوتاسيوم الصلفات يعني
+
+173
+00:13:57,210 --> 00:14:02,370
+اتنين في point two شحنته واحد يعني واحد تربيع زائد
+
+174
+00:14:02,370 --> 00:14:06,290
+الصلفات اتنين من عشرة اذا اتنين من عشرة في شحنتها
+
+175
+00:14:06,290 --> 00:14:11,070
+اتنين تربيع تطلع القوة الايونية عندى ستة من عشرةلو
+
+176
+00:14:11,070 --> 00:14:17,530
+قرنناها بالمسألة الماضية اتنين من عشرة بنلاحظ انه
+
+177
+00:14:17,530 --> 00:14:22,370
+زادت القوة الايونية ايه تلت أضعاف تلاقي يعني مجرد
+
+178
+00:14:22,370 --> 00:14:26,070
+ان الشحنة صارت ثنائية القوة الايونية عندنا زادت
+
+179
+00:14:26,070 --> 00:14:30,870
+بشكل كبير عشان هيك الشحنة من المتوقع انها بتأثر
+
+180
+00:14:30,870 --> 00:14:34,290
+على ال activity coefficient أكتر كتير من التركيز
+
+181
+00:14:34,290 --> 00:14:41,040
+أكتر كتير من التركيزطيب إيش بيحصل لو كان في عيننا
+
+182
+00:14:41,040 --> 00:14:45,500
+محلول بيحتوي على أكتر من strong electrolyte في
+
+183
+00:14:45,500 --> 00:14:50,200
+عيننا أكتر من strong electrolyte فمثلا بيقول
+
+184
+00:14:50,200 --> 00:14:52,960
+calculate the ionic strength of the solution
+
+185
+00:14:52,960 --> 00:14:59,920
+containing 0.3 molar KCl and 0.2 molar K2SO4 بقول
+
+186
+00:14:59,920 --> 00:15:03,640
+في هذه الحالة يمكن حساب ال ionic strength للمحلول
+
+187
+00:15:03,640 --> 00:15:10,000
+الأولوبعدين للمحلول التاني وجمع الاتنين ممكن او
+
+188
+00:15:10,000 --> 00:15:14,160
+انك تشوف مثلا تقول والله نص summation c i z i
+
+189
+00:15:14,160 --> 00:15:19,040
+squared هذا c لك بلس z squared لك بلس c ل c ال
+
+190
+00:15:19,040 --> 00:15:22,720
+minus z squared ل c ال minus c للصلفات z squared
+
+191
+00:15:22,720 --> 00:15:28,150
+للصلفات لكن ال potassium موجودفي ال KCL و موجود في
+
+192
+00:15:28,150 --> 00:15:32,230
+ال K2SO4 عشان هيك لما تيجي تعوض على تركيز
+
+193
+00:15:32,230 --> 00:15:36,030
+البوتاسيوم انا عندي 3 من 10 وانا عندي 4 من 10
+
+194
+00:15:36,030 --> 00:15:39,510
+بتعود عنه ب7 من 10 يعني انك تحاول انك تجمع
+
+195
+00:15:39,510 --> 00:15:43,720
+الايونات المتشابهة بها مش شرط تشتغل زي هيكممكن زي
+
+196
+00:15:43,720 --> 00:15:47,120
+ما قلتلك تجيب ال ionic strength للأول وال ionic
+
+197
+00:15:47,120 --> 00:15:51,300
+strength للثاني وتجمع الاتنين و رايح راسك حابب إنك
+
+198
+00:15:51,300 --> 00:15:55,400
+تجمع الايونات كل مجموعة لواحد مافيش عندي مشكلة زي
+
+199
+00:15:55,400 --> 00:15:58,060
+ما أنا حالي الآن كويس لكن إذا كانت اللي جاية أنه
+
+200
+00:15:58,060 --> 00:16:03,340
+أسهلك إنك تشتغل المحلول و تجمعهم برضه مافيش مانع
+
+201
+00:16:03,340 --> 00:16:09,810
+من هذا الكلاميبجى يا شباب احنا الان بنقدر نقول ان
+
+202
+00:16:09,810 --> 00:16:13,650
+ال ionic strength هي عبارة عن خاصية من خصائص
+
+203
+00:16:13,650 --> 00:16:20,830
+المحلول دالة فى التركيز و الشحنة للايونات المختلفة
+
+204
+00:16:20,830 --> 00:16:24,690
+بنقدر نحسبها نعم أخدنا أمثلة على حساباتها و بنقدر
+
+205
+00:16:24,690 --> 00:16:30,010
+نحسب ال ionic strength لأى محلول طب الآن نمشي خطوة
+
+206
+00:16:30,010 --> 00:16:35,280
+إضافية و نحاول نشوفإيش علاقة الـ Ionic Strength
+
+207
+00:16:35,280 --> 00:16:38,620
+بالـ Activity Coefficient اللي هو أنا بديها ال
+
+208
+00:16:38,620 --> 00:16:41,760
+activity coefficient هو اللي بيهمني في الحقيقة أنا
+
+209
+00:16:41,760 --> 00:16:46,240
+ال Ionic Strength عايزها كخطوة من خطوات الوصول إلى
+
+210
+00:16:46,240 --> 00:16:49,180
+ال activity coefficient بقول ال activity
+
+211
+00:16:49,180 --> 00:16:54,440
+coefficient يا شباب هو عبارة عن دالة في تلت حاجات
+
+212
+00:16:54,440 --> 00:16:59,690
+في الحقيقة دالة في الشحنةشحنة الايون بدي أجيب ال
+
+213
+00:16:59,690 --> 00:17:02,350
+activity coefficient لأيون معين طلع على شحنة
+
+214
+00:17:02,350 --> 00:17:06,710
+الايون بدي أطلع على ال ionic strength للمحلول بدي
+
+215
+00:17:06,710 --> 00:17:12,250
+أطلع على حاجة بنقولها effective hydrated diameter
+
+216
+00:17:12,250 --> 00:17:17,430
+effective hydrated diameter للايون اللي عندي ايش
+
+217
+00:17:17,430 --> 00:17:19,530
+هو ال effective hydrated diameter بقدرجه على
+
+218
+00:17:19,530 --> 00:17:25,660
+المعادلة بقول ان انا عندي مثلا H plusبقول H Plus
+
+219
+00:17:25,660 --> 00:17:29,910
+في الميّه، إيش بيكون فيه حوالي إيه؟جزيئات مية زي
+
+220
+00:17:29,910 --> 00:17:33,590
+ما أنا شايف بما انه هذا موجة يبقى ال oxygen السالب
+
+221
+00:17:33,590 --> 00:17:38,530
+نسبيا او جزئيا بيقترب من ال H بلس ال oxygen بيقترب
+
+222
+00:17:38,530 --> 00:17:42,210
+ال oxygen بيقترب ال oxygen بيقترب و بيكون هيك سفير
+
+223
+00:17:42,210 --> 00:17:46,410
+زي الكرة حوالين ال ايه ال H بلس هذه الكرة لها
+
+224
+00:17:46,410 --> 00:17:53,170
+ديامتر هذا ال diameter هو المقصود بال effective
+
+225
+00:17:53,170 --> 00:17:58,990
+diameter of the hydrated ionبنعود عنه بال Angstrom
+
+226
+00:17:58,990 --> 00:18:03,310
+ال Angstrom عشرة وسالب عشرة من المتر ال Acetate
+
+227
+00:18:03,310 --> 00:18:09,330
+نفس الكلام برضه يحط فيها سفير او كرة من الميه بس
+
+228
+00:18:09,330 --> 00:18:14,230
+بيكون شكل الميه ال H اللي هي partial positive هي
+
+229
+00:18:14,230 --> 00:18:17,450
+المقتربة من ال Acetate لأنه ال Acetate بتكون
+
+230
+00:18:17,450 --> 00:18:22,150
+negative فال diameter عندي هذا هو اللي احنا بنقول
+
+231
+00:18:22,150 --> 00:18:25,030
+انه effective diameter
+
+232
+00:18:26,920 --> 00:18:31,700
+فيبقى الـ Ionic Strength والـ Charge على الايون
+
+233
+00:18:31,700 --> 00:18:35,660
+والـ Effective Diameter بالانجوستروم هي التلت
+
+234
+00:18:35,660 --> 00:18:39,740
+عوامل اللي بتأثر على ال activity coefficient
+
+235
+00:18:39,740 --> 00:18:42,960
+وبتعطيني قيمة ال activity coefficient هدول التلت
+
+236
+00:18:42,960 --> 00:18:47,400
+عوامل مجمعين في معادلةبسمى المعادلة Dubai-Heckel
+
+237
+00:18:47,400 --> 00:18:52,720
+equation بتقول
+
+238
+00:18:52,720 --> 00:18:55,640
+المعادلة او Dubai-Heckel equation بتقول minus log
+
+239
+00:18:55,640 --> 00:19:02,680
+fi بتسوى ال 0.51زي اي squared جزر لميو على واحد
+
+240
+00:19:02,680 --> 00:19:07,620
+زائد point three three Alpha I Alpha I هي عبارة عن
+
+241
+00:19:07,620 --> 00:19:13,720
+ال diameter لل hydrated ion Alpha I جزر لميو هذا
+
+242
+00:19:13,720 --> 00:19:18,240
+عبارة عن دي باي هيكل equationفي بعض الأحيان خاصة
+
+243
+00:19:18,240 --> 00:19:22,160
+في المساقات يعني مش في الحياة العملية في المساقات
+
+244
+00:19:22,160 --> 00:19:25,960
+عشان نخفف عملية الحسابات ممكن ما نعطيكاش قيمة ال
+
+245
+00:19:25,960 --> 00:19:28,200
+alpha لأن ال alpha موجودة في الجداول موجودة بنقدر
+
+246
+00:19:28,200 --> 00:19:32,680
+نجيبها لكن يعني لو ماعطيناها ماعطينا cash يعني في
+
+247
+00:19:32,680 --> 00:19:36,780
+الامتحان أو في مسألة معينة اعتبر ان ال alpha I
+
+248
+00:19:36,780 --> 00:19:40,910
+تلاتة angstromوفي هذه الحالة لما تكون تلاتة في
+
+249
+00:19:40,910 --> 00:19:44,590
+point three three صارت واحد المعادلة بتكون أبسط
+
+250
+00:19:44,590 --> 00:19:48,830
+شوية من هيك بتصير minus log ال FI بتسوى point five
+
+251
+00:19:48,830 --> 00:19:52,670
+one ZI square جزر الميو على واحد زائد جزر الميو
+
+252
+00:19:52,670 --> 00:19:57,460
+لكن هذه المعادلة فقطصحيحة إذا كان الـ α I إيش
+
+253
+00:19:57,460 --> 00:20:01,100
+بتساوي؟ تلاتة يعني في شرط لها لكن لو ماكنش عندك
+
+254
+00:20:01,100 --> 00:20:05,280
+الـ α I معلومة يعني مش تلاتة أنجوشتروم فطبعا
+
+255
+00:20:05,280 --> 00:20:09,020
+تستخدم المعادلة القصدية اللي شفناها قبل شوية هذه
+
+256
+00:20:09,020 --> 00:20:12,680
+معادلة Dubai-Heckel equation كتير من العلماء أو
+
+257
+00:20:12,680 --> 00:20:15,380
+بعض العلماء حاولوا يعملوا عليها بعض التعديلات اللي
+
+258
+00:20:15,380 --> 00:20:19,910
+بتعطيهم يعني قياسات أدقففيه عندنا Davis
+
+259
+00:20:19,910 --> 00:20:22,790
+Modification وفيه عندنا تعديل بسيط على معادلة
+
+260
+00:20:22,790 --> 00:20:26,270
+Debye-Hickel وحنشوف تعديلات أخرى أيضًا لكن هذه
+
+261
+00:20:26,270 --> 00:20:29,730
+التعديلات كلها بتهمناش احنا في هذا المثال احنا
+
+262
+00:20:29,730 --> 00:20:33,730
+هنستخدم فقط Debye-Hickel equation يا المعادلة اللي
+
+263
+00:20:33,730 --> 00:20:37,250
+جدامي يا المعادلة في ال slide اللي جاب الهادي حسب
+
+264
+00:20:37,250 --> 00:20:41,790
+هل معي ال alpha I معلومة لتان جوشترون ولا لأ ماشي
+
+265
+00:20:41,790 --> 00:20:46,510
+يا شبابمش بس يعني احنا لما نستخدم the biological
+
+266
+00:20:46,510 --> 00:20:49,810
+equation فبنعملش عملية تبسيط، معظم العلماء
+
+267
+00:20:49,810 --> 00:20:53,470
+بيستخدموا biological equation للوصول الى قيمة ال
+
+268
+00:20:53,470 --> 00:20:57,330
+activity coefficient فاحنا لما نستخدمها مش عاملين
+
+269
+00:20:57,330 --> 00:21:04,120
+خطأ ملحوظطيب الآن مدام عرفنا نحسب ال ionic
+
+270
+00:21:04,120 --> 00:21:07,060
+strength وشوفنا العلاقة اللى بتربط ال ionic
+
+271
+00:21:07,060 --> 00:21:10,780
+strength مع ال activity coefficient فقالينا نتعلم
+
+272
+00:21:10,780 --> 00:21:14,860
+كيف نحسب ال activity coefficient فنتطلع على
+
+273
+00:21:14,860 --> 00:21:20,020
+هالمثال اللى جدامي المثال بيقول calculate the
+
+274
+00:21:20,020 --> 00:21:25,080
+activity coefficients of potassium and sulfate in
+
+275
+00:21:25,080 --> 00:21:32,350
+a 0.002 molarبوتاسيوم صلفيت solution assuming an
+
+276
+00:21:32,350 --> 00:21:35,730
+effective diameter of three angstrom for both ions
+
+277
+00:21:35,730 --> 00:21:39,510
+طبعا لما نقول ان ال effective diameter لل hydrated
+
+278
+00:21:39,510 --> 00:21:44,110
+ion لل both ions يعني للبوتاسيوم والصلفيت هو عبارة
+
+279
+00:21:44,110 --> 00:21:48,230
+عن تلاتة angstrom هذا مش صحيح لأن البوتاسيوم يعني
+
+280
+00:21:48,230 --> 00:21:52,890
+حجمه صغيروالـ hydrated ion بتاعه صغير لكن الصلفات
+
+281
+00:21:52,890 --> 00:21:57,210
+اسه عليها أربع أكسوجين حجمها كبير فال hydrated ion
+
+282
+00:21:57,210 --> 00:22:01,050
+بتاعه هيكون كبير لكن يعني هو مش مهتم في أنه أنت
+
+283
+00:22:01,050 --> 00:22:05,370
+يعني توجد ال hydrated ion بالظبط أو تستخدمه بالظبط
+
+284
+00:22:05,370 --> 00:22:10,030
+هو بس المهم عنده في هذا المثال أنك تعرف طريقة حساب
+
+285
+00:22:10,030 --> 00:22:13,870
+ال activity coefficient لكن طبعا من ناحية عملية
+
+286
+00:22:13,870 --> 00:22:18,330
+غلط الصلفات أكبر كتير هيكون من ال potassium على أي
+
+287
+00:22:18,330 --> 00:22:24,440
+حالفإحنا علشان نطبق ال equation التي بتعطينا ال
+
+288
+00:22:24,440 --> 00:22:27,700
+activity coefficients لازم في البداية أجيب ال
+
+289
+00:22:27,700 --> 00:22:32,140
+ionic strength ال ionic strength المحلول بتساوي نص
+
+290
+00:22:32,140 --> 00:22:35,720
+summation cizi squared تبقى ال mu بتساوي نص في ال
+
+291
+00:22:35,720 --> 00:22:40,340
+point 002 في 2 هذا هو تركيز البوتاسيوم ضعف تركيز
+
+292
+00:22:40,340 --> 00:22:44,630
+البوتاسيوم صلفية في 1 اللي هي شحنة البوتاسيومتربيع
+
+293
+00:22:44,630 --> 00:22:49,730
+زائد point o o two في اتنين تربيع تطلع عند point o
+
+294
+00:22:49,730 --> 00:22:53,870
+o six ال ionic string الان مدام عندي ال ionic
+
+295
+00:22:53,870 --> 00:22:57,710
+string بقدر احطها في دي بايهيكل equation و اطلع
+
+296
+00:22:57,710 --> 00:23:01,470
+قيمة ال F لأنه عندي minus log ال F I بتساوي point
+
+297
+00:23:01,470 --> 00:23:06,550
+five one Z I squared يعني بتكلم عن .. لما اتكلم عن
+
+298
+00:23:06,550 --> 00:23:11,490
+ال potassium بقول minus log ال Fللـ K Plus بتساوي
+
+299
+00:23:11,490 --> 00:23:17,730
+0.51 في Z للبوتاسيوم 1 يعني 1 تربية جزر لميو يعني
+
+300
+00:23:17,730 --> 00:23:22,330
+0.006 تحت الجزير على 1 زائد جزر لميو لأن وقان
+
+301
+00:23:22,330 --> 00:23:26,390
+الالفة التلاتة أنجسترون بتطلع عنده minus لجه ال F
+
+302
+00:23:26,390 --> 00:23:32,070
+لل K Plus 0.037الان ال F لكي بلس عشر عقوس سالب
+
+303
+00:23:32,070 --> 00:23:35,950
+point oh three seven بتطلع point nine one eight
+
+304
+00:23:35,950 --> 00:23:39,950
+اذا ال F او ال activity coefficient للبوتاسيوم طلع
+
+305
+00:23:39,950 --> 00:23:45,870
+تاني دي حوالي point nine twoنفس الطريقة بقدر احسب
+
+306
+00:23:45,870 --> 00:23:51,070
+ال F للصلفات وانتبهوا على قيمة ال F للصلفات بقول
+
+307
+00:23:51,070 --> 00:23:55,490
+minus log F للصلفات بتساوي 0.51 في اتنين تربيع
+
+308
+00:23:55,490 --> 00:23:58,750
+شحنة الصلفات جزر الميو على واحد ازاى جزر الميو
+
+309
+00:23:58,750 --> 00:24:03,770
+بتطلع عندى قيمة بجيب ال F للصلفات بتطلع عندى 0.71
+
+310
+00:24:03,770 --> 00:24:08,450
+لاحظ ال F للصلفات اقل كتير من ال F للبوتاسيوم لان
+
+311
+00:24:08,450 --> 00:24:14,710
+شحنة الصلفات اكبر مع ان البوتاسيوم تركيزه اكبرلكن
+
+312
+00:24:14,710 --> 00:24:18,050
+تأثيره على ال activity coefficient التركيز تأثيره
+
+313
+00:24:18,050 --> 00:24:24,310
+أقل من تأثير الشحنة الشحنة تأثيرها أكبر لو عملنا
+
+314
+00:24:24,310 --> 00:24:29,810
+نفس المسألة يا شباب و بدل ما أنه نستخدم point O O2
+
+315
+00:24:29,810 --> 00:24:33,730
+molar لو استخدمنا point O2 molar يعني 2 من 100 بدل
+
+316
+00:24:33,730 --> 00:24:38,250
+2 من 1000راح ألاحظ و حسبت ال F للبوتاسيوم و ال F
+
+317
+00:24:38,250 --> 00:24:43,250
+للصلفيت راح ألاحظ أن ال F للبوتاسيوم بتصير 0.79
+
+318
+00:24:43,250 --> 00:24:48,350
+يعني لما نزود التركيز ايش بحصل لل F؟ بتقل هي كانت
+
+319
+00:24:48,350 --> 00:24:55,110
+0.92 صارت 0.79لكن اتطلع للصلفات كمان لما زودت
+
+320
+00:24:55,110 --> 00:25:01,330
+التركيز التركيز حصل مش بس قلت قلت بشكل كبير جدا اه
+
+321
+00:25:01,330 --> 00:25:07,610
+لأنه تأثير الشحنة كبير جدا على ال F فكل ما زادت
+
+322
+00:25:07,610 --> 00:25:12,950
+التركيز ال F بيقل و كل ما زادت الشحنة ال F بيقل
+
+323
+00:25:12,950 --> 00:25:18,630
+بشكل كبير للغاية اذا الان بنقدر نحسب ال ionic
+
+324
+00:25:18,630 --> 00:25:23,860
+stringللمحلول و أيضا بنقدر نحسب ال activity
+
+325
+00:25:23,860 --> 00:25:29,080
+coefficients للأيونات المختلفة طيب كيف بنستخدم هذا
+
+326
+00:25:29,080 --> 00:25:32,040
+الكلام في الحياة العملية؟ ايش معنى هذا الكلام؟ كيف
+
+327
+00:25:32,040 --> 00:25:34,300
+بنستخدمه؟ خلّيني أطلع على
+
+328
+00:25:37,290 --> 00:25:42,890
+معادلة كتير بسيطة نتكلم فيها عن ايش علاقة او ليش
+
+329
+00:25:42,890 --> 00:25:47,490
+بيه ايش اهمية ال activity coefficients في دراستنا
+
+330
+00:25:47,490 --> 00:25:51,130
+في شغلنا ليش احنا مهتمين فيه جال لأنه ال activity
+
+331
+00:25:51,130 --> 00:25:54,990
+بتساوي التركيز في ال activity coefficient فانا اذا
+
+332
+00:25:54,990 --> 00:25:59,030
+كان اقدرت احسب ال activity coefficient بقدر احسب
+
+333
+00:25:59,030 --> 00:26:04,450
+ال activity كويس هذه حاجة الحاجة التانية بقدر انا
+
+334
+00:26:05,490 --> 00:26:12,510
+أقارن الآن بين ال activity و التركيز بالمعلومات ال
+
+335
+00:26:12,510 --> 00:26:15,810
+activity coefficient وبالتالي بقدر اقارن بين حاجة
+
+336
+00:26:15,810 --> 00:26:18,670
+تسمى thermodynamic equilibrium constant و
+
+337
+00:26:18,670 --> 00:26:21,730
+concentration equilibrium constant ال activity
+
+338
+00:26:21,730 --> 00:26:23,870
+اللي هي علاقة بال thermodynamic equilibrium
+
+339
+00:26:23,870 --> 00:26:28,810
+constant التركيز اللي هي علاقة بال concentration
+
+340
+00:26:28,810 --> 00:26:32,800
+equilibrium constantأيش يعني thermodynamic
+
+341
+00:26:32,800 --> 00:26:36,740
+equilibrium constant؟
+
+342
+00:26:36,740 --> 00:26:39,880
+شوفنا سابقا ان ال thermodynamic equilibrium
+
+343
+00:26:39,880 --> 00:26:45,540
+constant هو ال equilibrium constant اللي انا بحصل
+
+344
+00:26:45,540 --> 00:26:48,420
+عليه من ال thermodynamic equations
+
+345
+00:26:53,330 --> 00:26:57,010
+والـ Delta Gnot بقدر أجيبها Delta Hnot minus T
+
+346
+00:26:57,010 --> 00:27:00,790
+Delta Snot بقدر أجيبها ال Delta Hnot من الجداول و
+
+347
+00:27:00,790 --> 00:27:03,130
+Delta Snot من الجداول و الحرارة هي الحرارة اللي
+
+348
+00:27:03,130 --> 00:27:07,270
+بشتغل عندها فانا بسهولة بقدر أحسب قولنا ال
+
+349
+00:27:07,270 --> 00:27:09,970
+thermodynamic equilibrium constant من ال
+
+350
+00:27:09,970 --> 00:27:14,230
+thermodynamics طيب إيش بيحصل لو أنا حسبت ال
+
+351
+00:27:14,230 --> 00:27:19,930
+activity coefficient و حولت التركيز ل activity جال
+
+352
+00:27:23,670 --> 00:27:26,750
+الثيرمو دايناميك اكوليبريان كونستانت انتبهوا عليه
+
+353
+00:27:26,750 --> 00:27:29,750
+بيساوي ال activity للنواتج على ال activity
+
+354
+00:27:29,750 --> 00:27:34,570
+للمتفاعلات طب لو حسبت ال thermodynamic equilibrium
+
+355
+00:27:34,570 --> 00:27:37,990
+constant من التركيز وال activity coefficients يعني
+
+356
+00:27:37,990 --> 00:27:43,190
+من ال activitiesهل بلاجيه بيشبه ال activity ال
+
+357
+00:27:43,190 --> 00:27:47,330
+thermodynamic equilibrium constant من ال
+
+358
+00:27:47,330 --> 00:27:51,250
+thermodynamic equations بقول هو نفسه هو نفسه بحصل
+
+359
+00:27:51,250 --> 00:27:55,610
+على نفس النتيجة لكن احنا قلنا سابقا انه ال
+
+360
+00:27:55,610 --> 00:27:59,410
+thermodynamic equilibrium constant المحسوب من ال
+
+361
+00:27:59,410 --> 00:28:02,810
+thermodynamics بيختلف عن ال concentration
+
+362
+00:28:02,810 --> 00:28:07,170
+equilibrium constants في أحيان كتيرةولا يسوي إلا
+
+363
+00:28:07,170 --> 00:28:10,410
+تحت شروط لكن ال thermodynamic equilibrium constant
+
+364
+00:28:10,410 --> 00:28:14,030
+المحسوب من ال activities دائما بساوي ال
+
+365
+00:28:14,030 --> 00:28:16,670
+thermodynamic equilibrium constant المحسوب من ال
+
+366
+00:28:16,670 --> 00:28:25,110
+thermodynamic equations فنرجع تاني بس شويةبدنا بس
+
+367
+00:28:25,110 --> 00:28:28,870
+نشوف ان ال equilibrium constant اللي هو قدامها هذا
+
+368
+00:28:28,870 --> 00:28:32,430
+اسمه concentration equilibrium constant لأنه
+
+369
+00:28:32,430 --> 00:28:38,290
+مستخدم التركيزات طيب انا لما بدي استخدم ال
+
+370
+00:28:38,290 --> 00:28:41,170
+activities واطلع ال K thermodynamic بقول طب ما هي
+
+371
+00:28:41,170 --> 00:28:44,450
+ال activity عبارة عن التركيز في ال A في ال
+
+372
+00:28:44,450 --> 00:28:46,970
+activity coefficient يبقى ال K thermodynamic
+
+373
+00:28:46,970 --> 00:28:50,630
+تعالوا نعوض عن ال activity ل A بنعوض عنها بتركيز A
+
+374
+00:28:50,630 --> 00:28:56,030
+مضروب في Aفى ال F A طب و ال activity ل B جال تركيز
+
+375
+00:28:56,030 --> 00:28:59,750
+B مضروب فى A فى ال F ل B طب و ال activity ل ال A B
+
+376
+00:28:59,750 --> 00:29:06,570
+تركيز ال A B فى ال F ل ال A B مش هيك طب ما نطول
+
+377
+00:29:06,570 --> 00:29:09,630
+السجوليت فى ال slide اللى جابلها ان ال A فى ال B
+
+378
+00:29:09,630 --> 00:29:12,630
+على ال A B هذا عبارة عن ال concentration
+
+379
+00:29:12,630 --> 00:29:16,710
+equilibrium constant اذا ال K thermodynamic هلاحظ
+
+380
+00:29:16,710 --> 00:29:24,120
+انه بيساوي ال K concentrationفي حصل ضرب Fafb على
+
+381
+00:29:24,120 --> 00:29:30,560
+Fab معناه الكلام في علاقة بين ال concentration
+
+382
+00:29:30,560 --> 00:29:33,200
+equilibrium constant و ال thermodynamic
+
+383
+00:29:33,200 --> 00:29:36,980
+equilibrium constant لكن العلاقة هذه محكومة بقيم
+
+384
+00:29:36,980 --> 00:29:43,520
+ال F طب احنا يا شبابالـ equilibrium constants اللي
+
+385
+00:29:43,520 --> 00:29:47,260
+معانا هذه هل هي في الجداول اللي بنجيها في الكتب و
+
+386
+00:29:47,260 --> 00:29:50,120
+في الأسئلة و في الامتحانات هل هي thermodynamic
+
+387
+00:29:50,120 --> 00:29:53,340
+equilibrium constants ولا concentration
+
+388
+00:29:53,340 --> 00:29:57,450
+equilibrium constants؟بنقول هي thermodynamic
+
+389
+00:29:57,450 --> 00:30:02,910
+equilibrium constants دائما ليه لأنه لو بده احط
+
+390
+00:30:02,910 --> 00:30:07,130
+قيمة ال concentration equilibrium constant يجب علي
+
+391
+00:30:07,130 --> 00:30:13,650
+ان احط ايش ال ionic strength المحلول ليه لأنه انا
+
+392
+00:30:13,650 --> 00:30:17,530
+بحسب قيمة ال concentration equilibrium constant
+
+393
+00:30:17,530 --> 00:30:24,050
+عندIonic strength معينة عند تركيز معين من ال
+
+394
+00:30:24,050 --> 00:30:28,290
+diverse ions وإلا لو ماكنش فيه عند أي diverse ions
+
+395
+00:30:28,290 --> 00:30:34,610
+معنى الكلام FA وFB وFAB كلها إيش بتساوي؟ واحد لأنه
+
+396
+00:30:34,610 --> 00:30:37,910
+مافيش عيني diverse ions معنى الكلام آه ال K بتساوي
+
+397
+00:30:37,910 --> 00:30:41,310
+ال K thermodynamic يعني لما بدي أشتغل في الميه
+
+398
+00:30:41,310 --> 00:30:45,690
+المجترة زي العادة زي ما إحنا بنشتغل أنا بدي أعتبر
+
+399
+00:30:45,690 --> 00:30:50,290
+إن ال K thermodynamic إيش بساوي؟الكيك ليش؟ قال
+
+400
+00:30:50,290 --> 00:30:53,870
+لأنه ماعندى diverse ions لكن لو عندى diverse ions
+
+401
+00:30:53,870 --> 00:30:57,650
+لأ بيبطلوا يسووا بعض فانا عندى دائما ال
+
+402
+00:30:57,650 --> 00:30:59,970
+equilibrium constants اللى موجودة فى الكتب فى
+
+403
+00:30:59,970 --> 00:31:02,950
+الجداول فغيره كلها thermodynamic equilibrium
+
+404
+00:31:02,950 --> 00:31:07,150
+constants لأنه لو بدى أحط قيم ال concentration
+
+405
+00:31:07,150 --> 00:31:11,550
+equilibrium constants كل جدول بيكون موجود معاه عند
+
+406
+00:31:11,550 --> 00:31:14,910
+أي ionic strength تم قياسه لأن حسب ال ionic
+
+407
+00:31:14,910 --> 00:31:20,000
+strength ال activity coefficient بتغيرأذن مدام
+
+408
+00:31:20,000 --> 00:31:24,480
+اتغير يذن بطل ال K ثرمو دينامك يساوي ال K فانا
+
+409
+00:31:24,480 --> 00:31:29,580
+بشتغل في الميه او باستخدام very dilute solutions
+
+410
+00:31:29,580 --> 00:31:34,360
+عندها ال F عادة ايش بتساوي واحدطيب يبقى ال K ثيرمو
+
+411
+00:31:34,360 --> 00:31:38,920
+دايناميك بسوء ال K concentration إذا كان ال F
+
+412
+00:31:38,920 --> 00:31:41,840
+عندنا ال F values بتساوي واحد وماكتشف ال F values
+
+413
+00:31:41,840 --> 00:31:46,360
+بتساوي واحد في أحد حالتين يا إما مافيش عندي
+
+414
+00:31:46,360 --> 00:31:51,580
+diverse ions نهائيا يا إما المحلول مخفف جدا أقل من
+
+415
+00:31:51,580 --> 00:31:56,160
+عشر أقل سالب أربعة molar يعني كمية الأيونات غير
+
+416
+00:31:56,160 --> 00:32:03,300
+كافية أن تعمل shielding ل ..أيونات المادة ضعيفة
+
+417
+00:32:03,300 --> 00:32:07,180
+التفكك ماشي يا شباب اذا في علاقة بين ال
+
+418
+00:32:07,180 --> 00:32:09,720
+concentration equilibrium constant و ال
+
+419
+00:32:09,720 --> 00:32:13,260
+thermodynamic equilibrium constant و مقدر اقول ان
+
+420
+00:32:13,260 --> 00:32:16,800
+الاتنين واحد في الميه او في ال very dilute
+
+421
+00:32:16,800 --> 00:32:20,860
+solutions لكن مجرد ما يقول ال ionic strength عندك
+
+422
+00:32:20,860 --> 00:32:24,720
+هالجد بدى استخدم ال ionic strength علشان احسب منها
+
+423
+00:32:24,720 --> 00:32:29,680
+قيمة ال F و قيمة ال F و قيمة ال Fو اعوض عنهم عشان
+
+424
+00:32:29,680 --> 00:32:36,260
+اجيب قيمة ال K اذا لو اعطاني قيمة ال Ionic Strings
+
+425
+00:32:36,260 --> 00:32:41,420
+او لو اعطاني محلول جالي والله ال F ل A هالجد و ال
+
+426
+00:32:41,420 --> 00:32:46,640
+F ل B هالجد اذا برضه كمان مدام فيه قيمة لل F لل
+
+427
+00:32:46,640 --> 00:32:51,240
+activity coefficients اذا بطل ال concentration
+
+428
+00:32:51,240 --> 00:32:53,860
+equilibrium constant يساوي ال thermodynamic
+
+429
+00:32:53,860 --> 00:32:57,810
+equilibrium لازم حسابالـ Concentration Equilibrium
+
+430
+00:32:57,810 --> 00:33:06,330
+Constant فخلينا نشوف بعض الأمثلة في البداية ناخد
+
+431
+00:33:06,330 --> 00:33:09,370
+مثال بسيط نحسب الـ Concentration Equilibrium
+
+432
+00:33:09,370 --> 00:33:13,630
+Constant من الـ Thermodynamic Equilibrium Constant
+
+433
+00:33:13,630 --> 00:33:17,350
+فبقول Calculate the Concentration Equilibrium
+
+434
+00:33:17,350 --> 00:33:20,570
+Constant for the dissociation of AB
+
+435
+00:33:23,480 --> 00:33:29,080
+F للـ A plus و F لل B minus are 0.6 و 0.7 مدام
+
+436
+00:33:29,080 --> 00:33:32,040
+اعطاني قيمة ال F انتهى الموضوع كانوا يقدرون اعطاني
+
+437
+00:33:32,040 --> 00:33:33,500
+قيمة ال F كانوا يقدرون اعطاني قيمة ال ionic
+
+438
+00:33:33,500 --> 00:33:36,860
+strength او يقدرون اعطاني تركيز ال diverse ion و
+
+439
+00:33:36,860 --> 00:33:39,860
+انا من تركيز ال diverse ion بجيب ال ionic strength
+
+440
+00:33:39,860 --> 00:33:44,040
+و من ال ionic strength بجيب ال F لكن هنا اعطاني ال
+
+441
+00:33:44,040 --> 00:33:49,260
+F على طول فخلاص ريحنيفبقول اذا كان ال f ل ال a
+
+442
+00:33:49,260 --> 00:33:51,960
+plus و ال f ل ال b minus are point six and point
+
+443
+00:33:51,960 --> 00:33:57,600
+seven طب ماعطانيش ال f ل ال a b بتلزمني جداش كيبت
+
+444
+00:33:57,600 --> 00:34:02,970
+ال f ل ال a b بتكون؟ ليش واحد؟الصحيحة ده الكلام ال
+
+445
+00:34:02,970 --> 00:34:08,450
+FAB بتساوي واحد لإنه احنا قولنا من خصائص ال F انه
+
+446
+00:34:08,450 --> 00:34:12,550
+ال F تساوي واحد for uncharged species فأي مادة
+
+447
+00:34:12,550 --> 00:34:17,410
+مافيش عليها شخناه معناته ال F لها F واحد طيب ماتين
+
+448
+00:34:17,410 --> 00:34:20,930
+ال thermodynamic equilibrium constant 2 ف10 أساليب
+
+449
+00:34:20,930 --> 00:34:24,530
+تمانية طبعا هذه المسألة اللي حللناها قبل شوية
+
+450
+00:34:24,530 --> 00:34:28,090
+وشوفنا ان ال K thermodynamic بساوي ال K F ل ال A
+
+451
+00:34:28,090 --> 00:34:32,630
+plus F ل ال B minus على ال Fللـ AB بيتعوب 2 فى 10
+
+452
+00:34:32,630 --> 00:34:36,230
+أقل سالب تمانية بيتساوي ال K concentration
+
+453
+00:34:36,230 --> 00:34:41,730
+equilibrium constant if لل A plus 0.6 if لل B
+
+454
+00:34:41,730 --> 00:34:47,110
+minus 0.7 if لل AB واحد إذا ال concentration
+
+455
+00:34:47,110 --> 00:34:51,490
+equilibrium constant بده يساوي 5 فى 10 أقل سالب
+
+456
+00:34:51,490 --> 00:34:54,990
+تمانية يا ريت تتقارن ما بينه وما بين ال
+
+457
+00:34:54,990 --> 00:34:58,350
+thermodynamic equilibrium constant إيش بتلاحظ؟
+
+458
+00:35:01,210 --> 00:35:09,690
+ال K concentration أكبر، وضعه طبيعي، ليش طيب أكبر؟
+
+459
+00:35:09,690 --> 00:35:15,380
+ليش أكبر؟ليش أكبر؟ لأنه ببساطة خلاص احنا قلنا انه
+
+460
+00:35:15,380 --> 00:35:20,200
+لما يكون في عينة diverse ion بتضطر الميكجبعي فيانا
+
+461
+00:35:20,200 --> 00:35:25,000
+تتفكك اكتر ليش بيتفكك اكتر؟ بيحصل shielding لل
+
+462
+00:35:25,000 --> 00:35:29,120
+ionات تبعتها وبالتالي التفكك بيزيد لما التفكك
+
+463
+00:35:29,120 --> 00:35:34,600
+بيزيد عاملا النواتج بتزيد والمتفاعلات بتجيل ال
+
+464
+00:35:34,600 --> 00:35:37,960
+equilibrium constant حاصل قسمة النواتج على
+
+465
+00:35:37,960 --> 00:35:41,250
+المتفاعلات اذاوضع طبيعي ان ال concentration
+
+466
+00:35:41,250 --> 00:35:45,590
+equilibrium constant يكبر يزيد عن ال thermodynamic
+
+467
+00:35:45,590 --> 00:35:51,430
+equilibrium constant لأنه التفكك بالطبيعي زاد طيب
+
+468
+00:35:51,430 --> 00:35:58,150
+نيجي نتطلع على مسألة مقارنة في الأول هاخد تفكك
+
+469
+00:35:58,150 --> 00:36:02,610
+هالمادة اللي هي AB في الميه بعدين هاخد تفكك ال AB
+
+470
+00:36:02,610 --> 00:36:09,900
+في وجود diverse ions وأقارن بين الحالتينبدي اخد
+
+471
+00:36:09,900 --> 00:36:15,100
+اول حاجة تفكك الAB في الميه و هاخد تفكك الAB بعدين
+
+472
+00:36:15,100 --> 00:36:19,660
+في وجود ايه؟ diverse ions و اشوف ايش كيف بتزيد
+
+473
+00:36:19,660 --> 00:36:23,360
+نسبة التفكك فخلينا نطلع على المثال اللي جدامي
+
+474
+00:36:23,360 --> 00:36:26,640
+المثال ايش بيقول calculate the pairs and
+
+475
+00:36:26,640 --> 00:36:29,440
+dissociation of one times ten to the minus four
+
+476
+00:36:29,440 --> 00:36:34,820
+molar AB in waterمش شرط يقولي in water الوضع
+
+477
+00:36:34,820 --> 00:36:38,460
+الطبيعي أن هو in water لكن واتاش بعوز يعطيني
+
+478
+00:36:38,460 --> 00:36:42,480
+معلومات بس إذا كان هو في diverse ion إذا كان في
+
+479
+00:36:42,480 --> 00:36:45,520
+وجود diverse ion بيعطيني هذه المعلومات أو بقولي ال
+
+480
+00:36:45,520 --> 00:36:48,560
+ionic strength هالجد أو بقولي ال activity
+
+481
+00:36:48,560 --> 00:36:52,340
+coefficients هالجد ساعتها بعرف لكن إذا كان مجليش
+
+482
+00:36:52,340 --> 00:36:56,660
+ال ionic strength هالجد أو في وجود diverse ion أو
+
+483
+00:36:56,660 --> 00:36:59,900
+ماعطانيش قيمة ال F إذا الوضع الطبيعي أنه في الميه
+
+484
+00:37:00,980 --> 00:37:07,160
+معظم شغلنا في المية إلا لما نحدد حاجة تانية ال
+
+485
+00:37:07,160 --> 00:37:09,460
+thermodynamic equilibrium constant 2 في عشراء
+
+486
+00:37:09,460 --> 00:37:13,260
+السالب تمانية مجرد إنه جالف المية ما جابليش صيرت
+
+487
+00:37:13,260 --> 00:37:17,660
+diverse ions إذا ال K thermodynamic يساوي ال K
+
+488
+00:37:17,660 --> 00:37:21,660
+concentration بعوض عنه تعويض مباشر ليه؟ لأنه على
+
+489
+00:37:21,660 --> 00:37:26,060
+طول مدام في المية إذا ال F بتساوي واحد لكل .. لكل
+
+490
+00:37:26,060 --> 00:37:30,390
+شيء و ال K thermodynamicبساول K concentration طبعا
+
+491
+00:37:30,390 --> 00:37:34,010
+انا بحل المسائل هذه باني اكتب المعادلة احط
+
+492
+00:37:34,010 --> 00:37:39,090
+الايونات او التركيزات قبل الاتزان فوق والتركيزات
+
+493
+00:37:39,090 --> 00:37:42,710
+بعد الاتزان تحت بمراعات قيمة ال equilibrium
+
+494
+00:37:42,710 --> 00:37:46,470
+constant طبعا ال equilibrium constant انه صغير
+
+495
+00:37:46,470 --> 00:37:51,250
+كتير علشان هيكالـ AB بدي يقلب مقدار كمية ضئيلة جدا
+
+496
+00:37:51,250 --> 00:37:56,750
+مقدارها X والنواتج راح تعطيني كميات برضه ضئيلة جدا
+
+497
+00:37:56,750 --> 00:38:00,550
+مقدارها X للـ A plus و X للـ B minus
+
+498
+00:38:04,000 --> 00:38:08,460
+عوّنت عنه مباشرة ال K حطته محل ال K concentration
+
+499
+00:38:08,460 --> 00:38:12,200
+إذا كنتوا ملاحظين ال K حطته محل ال K concentration
+
+500
+00:38:12,200 --> 00:38:17,880
+يعني على طول K بتساوي A plus في ال B minus على ال
+
+501
+00:38:17,880 --> 00:38:24,400
+AB ال A plus X ال B minus X ال AB عشرة أقل سالب
+
+502
+00:38:24,400 --> 00:38:27,300
+أربعة minus X لكن افترضت أنا أن العشرة أقل سالب
+
+503
+00:38:27,300 --> 00:38:30,840
+أربعة أكبر كتير من ال X لأن ال equilibrium
+
+504
+00:38:30,840 --> 00:38:35,290
+constant صغيرفمعنى كلام ال X بيطلع أنه واحد واربعة
+
+505
+00:38:35,290 --> 00:38:37,790
+في عشرة أقل سالب ستة لو حبيت أجيب ال relative
+
+506
+00:38:37,790 --> 00:38:41,670
+error بيطلع عندي واحد واربعة من عشرة في المية
+
+507
+00:38:41,670 --> 00:38:46,130
+مقبول .. مقبول ال assumption is valid مش عندي
+
+508
+00:38:46,130 --> 00:38:51,750
+مشكلة ال person dissociation جداش كمية المتفكك
+
+509
+00:38:51,750 --> 00:38:56,250
+والله اللي تفكك على الكل في مية من مية اللي تفكك
+
+510
+00:38:56,250 --> 00:39:01,260
+هو ال Xعالكل واحد فى عشرة او سالب اربعة فى ميانوية
+
+511
+00:39:01,260 --> 00:39:05,900
+تطلع عندى واحد واربعة من عشرة فى المية هذه هي نسبة
+
+512
+00:39:05,900 --> 00:39:10,520
+التفكك صدت طب مش مشكلة جداش وحسب ال equilibrium
+
+513
+00:39:10,520 --> 00:39:17,070
+constant فهى صغيرة ماشي يا شبابطيب الآن نحاول ناخد
+
+514
+00:39:17,070 --> 00:39:22,170
+نفس المسألة لكن في وجود diverse ايوان شوف لك شوف
+
+515
+00:39:22,170 --> 00:39:25,350
+صيغة السؤال السؤال ايش بيقول بيقول calculate the
+
+516
+00:39:25,350 --> 00:39:30,190
+percent dissociation of A1 times 10 to the minus 4
+
+517
+00:39:30,190 --> 00:39:35,820
+molar ABin presence of diverse ions جالك عملاطة في
+
+518
+00:39:35,820 --> 00:39:40,400
+عنده أيه؟ diverse ions where the ionic strength is
+
+519
+00:39:40,400 --> 00:39:43,640
+0.1 كان كافي يعطيني بس ال ionic strength أنا مانا
+
+520
+00:39:43,640 --> 00:39:48,160
+بحسب ال if values لكن لأ جالك and if a plus و if
+
+521
+00:39:48,160 --> 00:39:53,800
+لل b minus are 0.6 and 0.7يعني اعتقمت ال F وكأنه
+
+522
+00:39:53,800 --> 00:39:57,320
+يعني هذه ال point one مش روح استخدمها لإيش بستخدم
+
+523
+00:39:57,320 --> 00:40:00,280
+ال ionic strength انا بستخدمها عشان اجيب ال F A
+
+524
+00:40:00,280 --> 00:40:05,220
+plus و F B minus مدام هو اعطاها ليه ال F A plus و
+
+525
+00:40:05,220 --> 00:40:08,580
+F B اذا بلزمنيش ال point one هذه مابتلزمنها اصلا
+
+526
+00:40:08,580 --> 00:40:14,180
+معلومة زايدةكويس لكن لو ماعطيش كمة ال F values اه
+
+527
+00:40:14,180 --> 00:40:16,940
+بدي احسبها باستخدام ال point one بقول ال
+
+528
+00:40:16,940 --> 00:40:19,300
+thermodynamic equilibrium constant اتنين في عشر
+
+529
+00:40:19,300 --> 00:40:23,580
+أقل سالم تمانية طبعا انا على طول بمجرد انه جالي في
+
+530
+00:40:23,580 --> 00:40:27,540
+عنا diverse ions بعرف ان ال K concentration مش هي
+
+531
+00:40:27,540 --> 00:40:30,780
+ال K thermodynamic كويس لازم احسب ال K
+
+532
+00:40:30,780 --> 00:40:34,970
+concentrationأو الـ Concentration Equilibrium
+
+533
+00:40:34,970 --> 00:40:38,210
+Constant كيف بدي أحسبها؟ بنفس الطريقة حسبناها
+
+534
+00:40:38,210 --> 00:40:42,690
+سابقا لكن بنفس الطريقة يعني ال K ثيرمو دانفر ثاول
+
+535
+00:40:42,690 --> 00:40:46,190
+K F A Plus طبعا لازم تعرف تعمل معادلة هادئ لأي
+
+536
+00:40:46,190 --> 00:40:49,510
+equilibrium و لو كان في ال equilibrium في عندك
+
+537
+00:40:49,510 --> 00:40:56,070
+مثلا اتنين C مثلا بيصير تركيز ال C تربيع بيصير
+
+538
+00:40:56,070 --> 00:41:01,800
+التركيز تربيع و ال F كمان تربيعكويس لأنه بيكون ال
+
+539
+00:41:01,800 --> 00:41:05,460
+activity تربيع فإيش يعني activity تربيع يعني
+
+540
+00:41:05,460 --> 00:41:09,680
+التركيز تربيع و ال F تربيع فانت بتعرف تعمل ال
+
+541
+00:41:09,680 --> 00:41:13,280
+equation فى البداية فبتقول والله ال K ثرموضانوسة و
+
+542
+00:41:13,280 --> 00:41:18,190
+ال K concentration فى ال F ratioكبار سلة عندك حسب
+
+543
+00:41:18,190 --> 00:41:22,610
+الاتزار فبيقول 2 ف 10 أقصى الاتمانية بتساوي ال K 0
+
+544
+00:41:22,610 --> 00:41:29,090
+.6 0.7 على 1 لإن ال FAB بتساوي 1 لإن ال FAB غير
+
+545
+00:41:29,090 --> 00:41:35,150
+مشحون ال K 5 ف 10 أقصى الاتمانية يعني سبق و
+
+546
+00:41:35,150 --> 00:41:40,150
+حسبناها قبل شوية المهم إنه أول خطوة بنعملها بنحسب
+
+547
+00:41:41,850 --> 00:41:49,150
+الـ K-concentration طبعا يعني بعد هيك بتصير
+
+548
+00:41:49,150 --> 00:41:54,650
+المسألة سهلة بنعوض ايش اللي استخدمنا K
+
+549
+00:41:54,650 --> 00:42:00,130
+-concentration بتساوي X في X اللي هي النواتج على
+
+550
+00:42:03,350 --> 00:42:07,350
+اللي هو عبارة عن point او عشرة أقل سالب أربعة
+
+551
+00:42:07,350 --> 00:42:11,190
+minus X لكن بنفترض انه العشرة أقل سالب أربعة أكبر
+
+552
+00:42:11,190 --> 00:42:14,530
+كتير من ال X فبتاع ما عندي عشرة أقل سالب أربعة ال
+
+553
+00:42:14,530 --> 00:42:18,590
+X بتطلع اتنين و اتنين فعشرة أقل سالب ستة لو حسبنا
+
+554
+00:42:18,590 --> 00:42:21,710
+ال relative error بتطلع عند اتنين و اتنين من عشرة
+
+555
+00:42:21,710 --> 00:42:25,270
+في المية هو بده ال person dissociation ايش بتساوي
+
+556
+00:42:25,270 --> 00:42:29,390
+ال person dissociation بقول ال person dissociation
+
+557
+00:42:29,390 --> 00:42:34,640
+بتساويالـ amount dissociated الكمية اللى تفككت على
+
+558
+00:42:34,640 --> 00:42:37,780
+الكلى فى مية من مية اللى تفككت اتنين و اتنين فى
+
+559
+00:42:37,780 --> 00:42:41,300
+عشرة و سالب ستة ع الكل واحد فى عشرة و سالب اتنين و
+
+560
+00:42:41,300 --> 00:42:45,760
+اتنين من عشرة طب هى جداش كانت عيننا فى الأول فى
+
+561
+00:42:45,760 --> 00:42:49,700
+الميه جداش كانت واحد و اربع زيادة لاتنين و اتنين
+
+562
+00:42:49,700 --> 00:42:54,200
+من عشرة هل الزيادة زيادة ملحوظة كبيرة الزيادة
+
+563
+00:42:54,200 --> 00:43:01,550
+بنقول عادة من الخطأ ان نقارنالقيم المجردة أو
+
+564
+00:43:01,550 --> 00:43:06,170
+النتائج المجردة الأفضل لنا عشان نعرف هل الزيادة
+
+565
+00:43:06,170 --> 00:43:10,810
+زيادة كبيرة محسوسة ولا زيادة ضئيلة غير محسوسة أنه
+
+566
+00:43:10,810 --> 00:43:14,990
+نجيب حاجة نقولها percent increase in solubility
+
+567
+00:43:15,610 --> 00:43:19,850
+percent increase يعني نسبة الزيادة في الذوبانية
+
+568
+00:43:19,850 --> 00:43:25,450
+فنسبة الزيادة في الذوبانية النسبة الجديدة 2.2%
+
+569
+00:43:25,450 --> 00:43:32,230
+النسبة القديمة 1.4% على 1.4% في 100% بيطلع عند
+
+570
+00:43:32,230 --> 00:43:38,410
+نسبة زيادة نقدرها 57% أنا بالنسبة لي نسبة زيادة 57
+
+571
+00:43:38,410 --> 00:43:44,350
+% تعتبر زيادة كبيرة جداكبيرة جدا صح لما نقارن 1.4%
+
+572
+00:43:44,350 --> 00:43:49,510
+ل 2.2% لا تبدو هالزيادة يعني ملحوظة لكن لما نجيب
+
+573
+00:43:49,510 --> 00:43:53,130
+ال percent increase بيبين عندنا ان في عندنا نسبة
+
+574
+00:43:53,130 --> 00:43:59,310
+زيادة مقدارها حوالي 57% هذه نسبة تعتبر نسبة عالية
+
+575
+00:43:59,310 --> 00:44:00,730
+للغاية
+
+576
+00:44:03,160 --> 00:44:11,680
+بس يعني بأحب أني ألفت انتباهك لإنه الموضوع هذا
+
+577
+00:44:11,680 --> 00:44:16,720
+هيمر معناه في عدة مراحل أو عدة نقاط في شباتر
+
+578
+00:44:16,720 --> 00:44:22,560
+مختلفة جاية لكن ما تستخدمش أو انت هتحل عادي زي ما
+
+579
+00:44:22,560 --> 00:44:26,620
+كنا بنحل سابقا قبل المقادرة دائما إلا إذا كان
+
+580
+00:44:26,620 --> 00:44:30,920
+أعطيتك إن التفكك بيحصل في وجود Ionic strength
+
+581
+00:44:30,920 --> 00:44:35,990
+معينةأو تركيز معين من مادة مالهاش دعوة في ال
+
+582
+00:44:35,990 --> 00:44:40,290
+equilibrium هذه تعتبر diverse ion او اعطتك قيمة ال
+
+583
+00:44:40,290 --> 00:44:47,790
+F ساعتها بدك تحاول ترجع تاني وتقول انه لأ بدي اجيب
+
+584
+00:44:47,790 --> 00:44:50,490
+ال concentration equilibrium constant في الأول
+
+585
+00:44:50,490 --> 00:44:55,350
+وبرضه كمانبنصحك بحاجة ممكن ما تجيبش ال
+
+586
+00:44:55,350 --> 00:45:01,150
+concentration equilibrium constant يعني في خطوة
+
+587
+00:45:01,150 --> 00:45:07,070
+مستقلة دائما اعتبر انت انه ال K thermodynamic
+
+588
+00:45:07,070 --> 00:45:10,990
+بيساوي ال activity للنواتج على ال activity
+
+589
+00:45:10,990 --> 00:45:16,830
+للمتفاعلين اعوض عن ال activities بالتركيزات مضروبة
+
+590
+00:45:16,830 --> 00:45:24,200
+في ال F ratioفي ال ratio f مثلا لل a plus f لل b
+
+591
+00:45:24,200 --> 00:45:28,760
+minus على ال f لل a b التركيزات هذه ما أنت بتعوض
+
+592
+00:45:28,760 --> 00:45:34,340
+عنها من الجدول الآن مثلا ال a plus x ال b minus x
+
+593
+00:45:34,340 --> 00:45:39,040
+ال a b عشرة أقل سالب أربعة minus x ممكن تشترها
+
+594
+00:45:39,040 --> 00:45:43,030
+كلها بخطوة واحدة بإمكانكأو إنك تجيب في الأول
+
+595
+00:45:43,030 --> 00:45:45,710
+concentration equilibrium constant وهو اللي
+
+596
+00:45:45,710 --> 00:45:50,670
+تستخدمه في التعويض هنحاول نجنعك في المرحلة الجاية
+
+597
+00:45:50,670 --> 00:45:56,350
+أنه لأ نستخدم خطوة واحدة أسهل إليك فهل تستخدم
+
+598
+00:45:56,350 --> 00:45:58,850
+الفكرة الآن؟ هل تستخدم ال activity ولا ال
+
+599
+00:45:58,850 --> 00:46:04,310
+concentration؟ هذا بتوقف على هل معاك diverse ion
+
+600
+00:46:04,310 --> 00:46:11,140
+أو ionic strength أو قيمة لل Fماشي يا شباب، هيك
+
+601
+00:46:11,140 --> 00:46:14,740
+بنكون خلصنا ال chapter الخاص بال equilibrium وإذا
+
+602
+00:46:14,740 --> 00:46:18,400
+الله راد الحصة الجاية بنتكلم عن حاجة بنقولها
+
+603
+00:46:18,400 --> 00:46:21,200
+gravimetric analysis أو تحليل وزني
+
diff --git a/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/BLgP0bGMojc_raw.srt b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/BLgP0bGMojc_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..fef3d13cbfff78a78e5a95a1e220df91e6e8970d
--- /dev/null
+++ b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/BLgP0bGMojc_raw.srt
@@ -0,0 +1,2220 @@
+1
+00:00:20,650 --> 00:00:24,150
+الله الرحمن الرحيم اليوم يا شباب برضه بنستكمل
+
+2
+00:00:24,150 --> 00:00:27,950
+موضوعنا اللي كنا بدناها قبل عدة محاضرات نتكلم عن
+
+3
+00:00:27,950 --> 00:00:31,930
+ال stoichiometric calculations هنبدأ نتكلم عن ال
+
+4
+00:00:31,930 --> 00:00:36,130
+volumetric analysis ال volumetric analysis نتكلم
+
+5
+00:00:36,130 --> 00:00:41,770
+فيها عن المعاييرات بشكل عام بكافة أنواعها كمفهوم
+
+6
+00:00:41,770 --> 00:00:47,250
+خاص بال calculationsففي البداية بنتكلم عن
+
+7
+00:00:47,250 --> 00:00:53,450
+المعاييرات من ناحية التفاعل هل أي تفاعل بين A وB
+
+8
+00:00:53,450 --> 00:00:56,710
+مدى ان بتفاعل التانية مع بعض يمكن اعتبار هذا
+
+9
+00:00:56,710 --> 00:01:01,410
+التفاعل تفاعل معايرة بنقول في الحقيقة لأ تفاعل
+
+10
+00:01:01,410 --> 00:01:08,730
+المعايرة يتصف بصفات وخصائص معينة يجب أن تكون
+
+11
+00:01:08,730 --> 00:01:13,390
+موجودة فيه وإلا لا يعتبر التفاعل تفاعل معايرة من
+
+12
+00:01:13,390 --> 00:01:18,330
+هذه الخصائص أو الصفاتإن الـ Stoichiometry لتفاعل
+
+13
+00:01:18,330 --> 00:01:22,930
+المعايرة يجب أن تكون معلومة ليه ال Stoichiometry
+
+14
+00:01:22,930 --> 00:01:27,530
+يجب أن تكون معلومة؟ لأن في النهاية أنا بدي أستخدم
+
+15
+00:01:27,530 --> 00:01:31,290
+هذه ال Stoichiometry في الحسابات بدي أعرف أكم Mol
+
+16
+00:01:31,290 --> 00:01:34,930
+من A بتفاعل مع أكم Mol من B لأنه بدي أستخدم هذه
+
+17
+00:01:34,930 --> 00:01:38,090
+العلاقة في الحسابات في المستقبل فيجب أن تكون ال
+
+18
+00:01:38,090 --> 00:01:43,180
+Stoichiometry معلومةالصفة التانية او الخاصية
+
+19
+00:01:43,180 --> 00:01:48,760
+التانية بقدر اقول انه لابد الا ان التفاعل يكون
+
+20
+00:01:48,760 --> 00:01:53,740
+سريع التفاعل المعايرة خطأ انه يكون تفاعل بطيق
+
+21
+00:01:53,740 --> 00:01:59,860
+بينفعش لازم التفاعل يكون سريع طيب اذا كان بطيق
+
+22
+00:01:59,860 --> 00:02:02,840
+يعني بدي اضيف كل نقطة و اصبر عليها مثلا خمس دجاج
+
+23
+00:02:02,840 --> 00:02:06,460
+او عشر دجاج او ربع ساعة قبل ما تتفاعل بعدين اضيف
+
+24
+00:02:06,460 --> 00:02:09,680
+النقطة اللي وراها و هكذا يعني بدي يوم في المعايرة
+
+25
+00:02:09,680 --> 00:02:13,680
+طبعا هذا الكلاملا يجوز، فالتفاعل يجب أن يكون تفاعل
+
+26
+00:02:13,680 --> 00:02:20,080
+سريع، أيضا يجب ألا يكون هناك أي تفاعلات جانبية،
+
+27
+00:02:20,080 --> 00:02:23,900
+فيش عند side reactions وإلا إذا كان عند side
+
+28
+00:02:23,900 --> 00:02:26,300
+reactions معناته عملية الحسابات تبعتي مش هتكون
+
+29
+00:02:26,300 --> 00:02:33,520
+صحيحة، يجب أن يكون التفاعل تفاعل وحيد، فيش عند أي
+
+30
+00:02:33,520 --> 00:02:38,830
+side reactions أو تفاعلات جانبيةالشرط الرابع ان
+
+31
+00:02:38,830 --> 00:02:42,890
+التفاعل يجب ان يكون تفاعل تم quantitative يعني ايه
+
+32
+00:02:42,890 --> 00:02:47,710
+بتفاعل مع بي بنسبة 100% بمشي التفاعل للاخر مش
+
+33
+00:02:47,710 --> 00:02:51,070
+تفاعل اتزان تفاعلات الاتزان مانفعش تستخدمها في
+
+34
+00:02:51,070 --> 00:02:59,810
+المعايرة فيجب ان يكون التفاعل تفاعل تم ايضا يجب ان
+
+35
+00:02:59,810 --> 00:03:05,170
+يتوفرindicator مناسب، كاشف مناسب للتفاعل المستخدم
+
+36
+00:03:05,170 --> 00:03:09,810
+أو اللي تحت الدراسة، ليه؟ لأن معظم المواد اللي
+
+37
+00:03:09,810 --> 00:03:13,090
+احنا نتعامل معاها في ال titrations هي مواد ليس لها
+
+38
+00:03:13,090 --> 00:03:18,750
+لون، colorless فكاس بدي أعرف إذا كان وصلت ال end
+
+39
+00:03:18,750 --> 00:03:22,010
+point ولا لسه ماوصلت ال end point يجب أن يكون هناك
+
+40
+00:03:22,010 --> 00:03:26,410
+كاشف مناسب والكاشف في الحقيقة مشكلة في معظم أنواع
+
+41
+00:03:26,410 --> 00:03:29,550
+ال titrations لأنه لا يوجد كاشف universal يعني
+
+42
+00:03:29,550 --> 00:03:33,100
+بنفعلكل أنواع ال titrations حتى لل titration من
+
+43
+00:03:33,100 --> 00:03:36,500
+نوع معين مثلا acid-base titration لا يمكن استخدام
+
+44
+00:03:36,500 --> 00:03:41,960
+كاشف واحد فقط لجميع معاييرات ال acids و ال bases
+
+45
+00:03:41,960 --> 00:03:45,980
+أو كاشف واحد فقط لل oxidation reduction reactions
+
+46
+00:03:45,980 --> 00:03:52,620
+لأ كل نوع من أنواع التفاعلات له كواشف معينة يجب
+
+47
+00:03:52,620 --> 00:03:57,460
+اختيار الكاشف المناسبللتفاعل تحت الدراسة مش أي
+
+48
+00:03:57,460 --> 00:04:03,140
+كاشف بينفع هنشوف تفاصيل الكواشف وإيش طبيعتها وليش
+
+49
+00:04:03,140 --> 00:04:08,640
+يعني في عليها قيود أو استخدامها في عليها قيود أنه
+
+50
+00:04:08,640 --> 00:04:12,060
+كاشف لأنه تفاعل هنشوف كل هذا كلام بالتفصيل لما
+
+51
+00:04:12,060 --> 00:04:18,840
+نتكلم عن ال techniques المختلفةممكن نقول كمان نقطة
+
+52
+00:04:18,840 --> 00:04:23,220
+جوهرية في الحقيقة ويلها علاقة بالكواشف إلى حد ما
+
+53
+00:04:23,220 --> 00:04:28,540
+بنقول يجب أن تتوافق ال equivalence point أو نقطة
+
+54
+00:04:28,540 --> 00:04:33,840
+التكافؤ مع ال end point أو نقطة النهاية إيش الفرق
+
+55
+00:04:33,840 --> 00:04:38,080
+بين نقطة التكافؤ ونقطة النهاية؟ نقطة التكافؤ يا
+
+56
+00:04:38,080 --> 00:04:44,650
+شباب هي نقطة نظرية حسابيةمش مخبرية كيف يعني؟ يعني
+
+57
+00:04:44,650 --> 00:04:48,710
+مثلا عندك خمسة مل من ال Sodium Hydroxide تركيزه
+
+58
+00:04:48,710 --> 00:04:53,310
+واحد من عشرة بدنا نحسب أكمل من ال sulphuric acid
+
+59
+00:04:53,310 --> 00:04:58,010
+اللي تركيزه point five molar بتفاعل معاها هذه قضية
+
+60
+00:04:58,010 --> 00:05:02,640
+حسابيةلكن لو أخدت ال 5 مل من ال Sodium Hydroxide و
+
+61
+00:05:02,640 --> 00:05:07,080
+عيرتهم بال H2SO4 و استخدمت Indicator مناسب و
+
+62
+00:05:07,080 --> 00:05:11,640
+اتطلعت مين بتحصل ال end point فهذه بقولها نقطة
+
+63
+00:05:11,640 --> 00:05:17,230
+نهاية او end point هذه نقطة تجريبية بصريةكويس،
+
+64
+00:05:17,230 --> 00:05:21,770
+نقطة تجريبية، فيجب أن تتوافق النقطة النظرية مع
+
+65
+00:05:21,770 --> 00:05:26,650
+النقطة التجريبية، يعني بمعنى آخر، يجب أن أستدل على
+
+66
+00:05:26,650 --> 00:05:30,210
+النقطة النظرية تقريبا من النقطة البصرية أو من
+
+67
+00:05:30,210 --> 00:05:34,430
+النقطة النهائية اللي أنا بحسب، اللي أنا بشوفها أو
+
+68
+00:05:34,430 --> 00:05:39,150
+بقرأها على ال buret نتيجة المعاهرةفهيجب أن يكون
+
+69
+00:05:39,150 --> 00:05:42,470
+هناك توافق طبعا في بعض الأحيان بيكونش هناك توافق
+
+70
+00:05:42,470 --> 00:05:46,490
+ممكن النقطة العملية تكون بعيد او قبل النقطة
+
+71
+00:05:46,490 --> 00:05:50,250
+النظرية او ممكن تكون بعدي كتير او قبل كتير هذا
+
+72
+00:05:50,250 --> 00:05:53,650
+بيؤدي طبعا لخطأ جسيم انا بد النقطة تانية يكونوا
+
+73
+00:05:53,650 --> 00:05:58,570
+متطابقات ان ان كان او قريبين جدا من بعض يعني شبه
+
+74
+00:05:58,570 --> 00:06:03,890
+مستحيل يكونوا متطابقات قد يحدث لكن الصح او اللي
+
+75
+00:06:03,890 --> 00:06:06,950
+احنا بنشتغل عليه على انهم يكونوا قريبات جدا من
+
+76
+00:06:06,950 --> 00:06:12,760
+بعضهم البعضهذه كلها شروط يجب أن تتوفر في التفاعل
+
+77
+00:06:12,760 --> 00:06:17,360
+علشان التفاعل نطلق عليه تفاعل معاهرة او titration
+
+78
+00:06:17,360 --> 00:06:22,600
+reaction ايضا يا شباب لما بدي اجي اعمل titration
+
+79
+00:06:22,600 --> 00:06:29,400
+بقول لابد الا ان احد المواد يكون معلوم التركيزأو
+
+80
+00:06:29,400 --> 00:06:33,580
+بمعنى أخر standard solution ليه؟ لأنه إذا كان عندي
+
+81
+00:06:33,580 --> 00:06:38,000
+مجهولين كيف بدي أحسب يعني ال analyze أو التركيز
+
+82
+00:06:38,000 --> 00:06:43,740
+اللي عندي؟ لازم واحد منهم يكون معلوم التركيز أو
+
+83
+00:06:43,740 --> 00:06:47,740
+standard solution وفي هذه الحالة لابد من التعرف
+
+84
+00:06:47,740 --> 00:06:51,220
+على أنواع مختلفة من ال standard solutions يعني
+
+85
+00:06:51,220 --> 00:06:53,880
+مثلا ممكن أقول في عندي حاجة بقولها primary
+
+86
+00:06:53,880 --> 00:06:57,610
+standard solutionمحلول ال primary standard،
+
+87
+00:06:57,610 --> 00:07:01,970
+standard أولى، قياسي أولى، إيش يعني؟ هذا النوع من
+
+88
+00:07:01,970 --> 00:07:06,210
+أنواع المحليل هو النوع اللي بحصل عليه من إذابة
+
+89
+00:07:06,210 --> 00:07:11,630
+كمية معينة من المادة في حجم معين من ال solutionأنا
+
+90
+00:07:11,630 --> 00:07:15,270
+بدوّم كمية معينة من المادة و وزنة معينة من المادة
+
+91
+00:07:15,270 --> 00:07:19,070
+في حجم معين من ال solution فانا بعرف التركيز من
+
+92
+00:07:19,070 --> 00:07:22,090
+عدد ال millimoles و ال milliliters ال millimoles
+
+93
+00:07:22,090 --> 00:07:24,250
+اللي أنا بدوها في ال milliliters و ال millimoles
+
+94
+00:07:24,250 --> 00:07:27,190
+على ال milliliter هو ال molarity فهذا النوع يسمى
+
+95
+00:07:27,190 --> 00:07:31,790
+primary standard solution لكن لو أخدت هذا ال
+
+96
+00:07:31,790 --> 00:07:37,960
+primary standard و عيرت فيهالمادة الأخرى المعايرة
+
+97
+00:07:37,960 --> 00:07:41,940
+الآن أصبحت معروفة معلومة التركيز يعني standard لكن
+
+98
+00:07:41,940 --> 00:07:46,600
+تسمى secondary standard مش primary ال primary اللي
+
+99
+00:07:46,600 --> 00:07:51,800
+بقى أحضرها من إذابة وزن معين من المادة في حجم معين
+
+100
+00:07:51,800 --> 00:07:57,300
+من ال solutionلو عيرت هذه المادة بمادة أخرى،
+
+101
+00:07:57,300 --> 00:07:59,600
+المادة الأخرى صارت standard، بيسميها secondary
+
+102
+00:07:59,600 --> 00:08:03,540
+standard، لو أخدت ال secondary standard هذا، وعيرت
+
+103
+00:08:03,540 --> 00:08:07,540
+فيه مادة تالتة، صارت المادة التالتة standard، لكن
+
+104
+00:08:07,540 --> 00:08:11,440
+اسمه tertiary standard، و هكذا، فهذا الفرق بين ال
+
+105
+00:08:11,440 --> 00:08:14,640
+primary standard و ال secondary standard و ال
+
+106
+00:08:14,640 --> 00:08:23,590
+tertiary standard إلى آخرهاهل معنى الكلام يعني سهل
+
+107
+00:08:23,590 --> 00:08:25,910
+أنه ألاجى primary standards لأن هو ال standard
+
+108
+00:08:25,910 --> 00:08:31,770
+الأول اللي بدى أستخدمه في يعني ال standardization
+
+109
+00:08:31,770 --> 00:08:36,070
+للمحالين المختلفة فهو الأول فهل من السهل أن أحصل
+
+110
+00:08:36,070 --> 00:08:41,080
+على primary standard في الحقيقةيعني مش تائما بكون
+
+111
+00:08:41,080 --> 00:08:45,040
+سهل عليا ألاقي primary standard جيد، ليه؟ لأن ال
+
+112
+00:08:45,040 --> 00:08:50,960
+primary standard يجب أن يتصف بصفات متعددة، أول صفة
+
+113
+00:08:50,960 --> 00:08:53,340
+من صفات ال primary standard، المادة اللي بدي
+
+114
+00:08:53,340 --> 00:08:57,100
+أستخدمها ك primary standard، يجب أن تكون عالية
+
+115
+00:08:57,100 --> 00:09:02,350
+النقاءhighly pure أو إلها high purity بمعنى إن ال
+
+116
+00:09:02,350 --> 00:09:06,790
+purity تكون أعلى من تسعة وتسعين وتمانية وتسعين في
+
+117
+00:09:06,790 --> 00:09:09,950
+المية على الأقل يعني تسعة وتسعين وتمانية وتسعين في
+
+118
+00:09:09,950 --> 00:09:15,310
+المية فهذا شرط ليه لأنه أنا بدي أستخدم هذه المادة
+
+119
+00:09:15,310 --> 00:09:19,350
+ال purity تبعتها في برضه القياسات يعني بدي أعرف
+
+120
+00:09:19,350 --> 00:09:23,710
+أكمل لمول بناء على ال percentage تبعتها فأنا بدي
+
+121
+00:09:23,710 --> 00:09:29,770
+المادة تكون نقية للغايةهذا أول شرط من شروط المادة
+
+122
+00:09:29,770 --> 00:09:33,610
+إذا كانت بنستخدمها ك primary standard ممكن نطلع
+
+123
+00:09:33,610 --> 00:09:38,610
+على شرط آخر اللي هو إنها تكون stable to drying
+
+124
+00:09:38,610 --> 00:09:43,830
+يعني بدي أجي أجففها أثناء عملية التجفيف يجب أن
+
+125
+00:09:43,830 --> 00:09:50,360
+تكونثابتة، إيش يعني يجب أن تكون ثابتة، بتتفعلش مع
+
+126
+00:09:50,360 --> 00:09:55,580
+أي حاجة تانية مثلا، هي نفسها بتنصهرش، بتنصهرش،
+
+127
+00:09:55,580 --> 00:10:00,660
+يعني بتصير عبارة عن محلول وما إلى ذلك، يعني بتكون
+
+128
+00:10:00,660 --> 00:10:04,080
+ثابتة أثناء عملية التشريف، طب ليش أنا بطلع عملية
+
+129
+00:10:04,080 --> 00:10:08,090
+التشريف من أصله؟جال لأنه المادة لما نكون مخزنة
+
+130
+00:10:08,090 --> 00:10:12,030
+موجودة في العبوة اللي هي موجودة أو في ال bottle
+
+131
+00:10:12,030 --> 00:10:14,970
+اللي هي موجودة فيها أثناء هذه العملية أو أثناء هذا
+
+132
+00:10:14,970 --> 00:10:21,420
+الوقت الطويل اللي بنلاحظه أنهنعم تمتص رطوبة تمتص
+
+133
+00:10:21,420 --> 00:10:23,860
+ثاني اكسيد كربونا على السطح الخارجي تبعها في
+
+134
+00:10:23,860 --> 00:10:29,940
+الحقيقة فكيف بدي اتخلص من المواد المضنصة و خاصة
+
+135
+00:10:29,940 --> 00:10:34,460
+الميه بشكل أساسي بخار الميه قال والله الأفضل شيء
+
+136
+00:10:34,460 --> 00:10:38,360
+انه اعملها عملية drying انه 80 درجة 90 درجة 100
+
+137
+00:10:38,360 --> 00:10:41,420
+درجة حسب ال procedure حسب نوع المادة حسب ال
+
+138
+00:10:41,420 --> 00:10:44,420
+procedure ما بيقوليحسب نوع المادة وحسب ال
+
+139
+00:10:44,420 --> 00:10:47,400
+procedure ما بيقول ليه تستمر عملية تشفيف ل مثلا
+
+140
+00:10:47,400 --> 00:10:51,980
+ساعة و نص ساعتين تلاتة أثناء عملية التشفيف كل
+
+141
+00:10:51,980 --> 00:10:56,080
+المواد اللي حصلها absorption على السطح يعني بتتطير
+
+142
+00:10:56,080 --> 00:11:00,600
+وبتبقى المادة نقية كما هي أه ساعتها لو أخلت وزنة
+
+143
+00:11:00,600 --> 00:11:05,920
+معينة من .. بتكون الوزن وزن حقيقيةمش صحيحة بتعبر
+
+144
+00:11:05,920 --> 00:11:11,260
+عن المادة الموزونة تماما، مش بتعبر عن المادة زائد
+
+145
+00:11:11,260 --> 00:11:15,440
+مواد أخرى مضافة إلها، فلازم المادة تكون stable to
+
+146
+00:11:15,440 --> 00:11:21,130
+drying لأنه أنا مضطر أعمل عملية drying دائمابحب
+
+147
+00:11:21,130 --> 00:11:25,430
+كتير ان المادة يكون لها high formula weight ليه؟
+
+148
+00:11:25,430 --> 00:11:29,270
+كان لأنه كل ما زالت الوزنة اللي انا بدي اخدها كل
+
+149
+00:11:29,270 --> 00:11:33,930
+ما قلت نسبة الخطأ كل ما زالت الوزنة كل ما قلت نسبة
+
+150
+00:11:33,930 --> 00:11:38,030
+الخطأ وهذا الكلام يعني بتهيألي كتير مهم في الكيمة
+
+151
+00:11:38,030 --> 00:11:43,320
+التحليلية انه اقل نسبة الخطألكن طبعا يعني احنا ال
+
+152
+00:11:43,320 --> 00:11:47,980
+analyst الجيد اللي بيعرف يستخدم الميزان بشكل كويس
+
+153
+00:11:47,980 --> 00:11:53,500
+الشخص اللي بيحلل و يكون بيعرف يستخدم الميزان و
+
+154
+00:11:53,500 --> 00:11:59,280
+الأدوات تباعته جيدا و مع وجود أدوات وزن ممتازةيعني
+
+155
+00:11:59,280 --> 00:12:03,320
+نسبة الخطأ بتكون قليلة، قليلة جدا في الحقيقة، ليه؟
+
+156
+00:12:03,320 --> 00:12:06,760
+لأن معينة موازينة بتوزن لأربع أرقام عشرية أو لخمس
+
+157
+00:12:06,760 --> 00:12:10,220
+أرقام عشرية حتى، فإذا كان اللي بيشتغل الإنسان يعني
+
+158
+00:12:10,220 --> 00:12:13,400
+إيده جيدة، نسبة الخطأ بتكون قليلة، لكن لو خيّرنا
+
+159
+00:12:13,400 --> 00:12:16,840
+بين مادتين بينفعوا، مادة إلها high formula weight
+
+160
+00:12:16,840 --> 00:12:20,160
+والتانية إلها low formula weight، بالطبع يجب
+
+161
+00:12:20,160 --> 00:12:25,160
+اختيار المادة اللي إلها high formula weightالشرط
+
+162
+00:12:25,160 --> 00:12:30,000
+برضه الرابع ان المادة تكون non-hygroscopic بمعنى
+
+163
+00:12:30,000 --> 00:12:37,740
+انه لا تنتص الماء بخار الماء أبسط مثاله أوضح مثال
+
+164
+00:12:37,740 --> 00:12:41,270
+على هذا الكلام اللي هو ال sodium hydroxideأحنا
+
+165
+00:12:41,270 --> 00:12:45,730
+بنحاول نوزنه على الميزان فبنلاحظ أنه أثناء عملية
+
+166
+00:12:45,730 --> 00:12:49,190
+الوزن لو وزنته على ميزان حساس مثلا يعني و احنا
+
+167
+00:12:49,190 --> 00:12:54,030
+بننصحيش أنه ينوزن على ميزان حساس لأن هو يعني مش
+
+168
+00:12:54,030 --> 00:12:57,850
+primary standardفلو وزرناها على الميزان، بنلاحظ
+
+169
+00:12:57,850 --> 00:13:05,030
+أنه أثناء نظرنا للـ Scale، للقراءة، بنلاحظ أن
+
+170
+00:13:05,030 --> 00:13:08,970
+القراءة عامال بتزيد، طب ليش؟ طب الميزان جيد، مش
+
+171
+00:13:08,970 --> 00:13:12,890
+خربان، الميزان كويس و جديد و بجيس بدقة عالية جدا
+
+172
+00:13:13,630 --> 00:13:17,290
+أثناء عملية الوزن ال sodium hydroxide يمتص بخار
+
+173
+00:13:17,290 --> 00:13:21,690
+الماء اللي موجود في الجو و بالتالي الوزنة بتزيد
+
+174
+00:13:21,690 --> 00:13:25,450
+باستمرار فحاجة زي ال sodium hydroxide لا يمكن
+
+175
+00:13:25,450 --> 00:13:28,650
+استخدامه ك primary standard لأنه very hygroscopic
+
+176
+00:13:28,650 --> 00:13:33,630
+برضه كمان المادة اللي بتستخدمها ك primary standard
+
+177
+00:13:33,630 --> 00:13:38,830
+بيتعدى تفاعل معايرة فيجب أن تتصف بجميع الصفات
+
+178
+00:13:39,530 --> 00:13:43,530
+الخاصة بتفاعل المعايرة، يعني تفاعلها مع المادة
+
+179
+00:13:43,530 --> 00:13:49,910
+الأخرى يجب أن يكون تفاعل سريع مثلا، يجب أن يكون
+
+180
+00:13:49,910 --> 00:13:53,250
+تفاعل quantitative، الـ Stoichiometry معروفة،
+
+181
+00:13:53,250 --> 00:13:58,850
+مافيش side reactions، ممكن نقول .. قولنا .. ممكن
+
+182
+00:13:58,850 --> 00:14:01,910
+نقول في عندنا very good indicator، في عندنا توافق
+
+183
+00:14:01,910 --> 00:14:05,710
+بين ال equivalence، كل هذه ال ..حاجات اللي ذكرناها
+
+184
+00:14:05,710 --> 00:14:09,770
+في تفريق المعايرة يجب أن تتصف أو يتصف بيها اللي هو
+
+185
+00:14:09,770 --> 00:14:10,650
+ال primary standard
+
+186
+00:14:16,090 --> 00:14:19,870
+ماوصلناش لهذا الكلام هو مابينفعش يعني لإنه
+
+187
+00:14:19,870 --> 00:14:27,050
+التفاعلات المواد اللي هي الضعيفة عادة يعني بطيئة
+
+188
+00:14:27,050 --> 00:14:30,090
+في التفاعل بطيئة كتير هنشوف هذا الكلام في المستقبل
+
+189
+00:14:30,090 --> 00:14:34,750
+لكن ماحكيناش عنه مش موضوعنا يعني بس بذكركم إنه أهم
+
+190
+00:14:34,750 --> 00:14:39,330
+مادتين بنتعامل معهم في المختبر اللي هم ال Sodium
+
+191
+00:14:39,330 --> 00:14:43,200
+Hydroxide و ال HCl هدول مادتين للأسفمش primary
+
+192
+00:14:43,200 --> 00:14:47,640
+standards الآن يا شباب هنحاول نطلع على أمثل هذه
+
+193
+00:14:47,640 --> 00:14:51,360
+الحسابات الخاصة بال volume metric analysis
+
+194
+00:14:51,360 --> 00:14:56,920
+المعاييرات المختلفة بجميع أنواعها لأنها حسابات
+
+195
+00:14:56,920 --> 00:15:04,780
+عامة الفكرة من وراء هذا النوع من الحسابات انه
+
+196
+00:15:04,780 --> 00:15:11,950
+نتعرف علىكيفية الحصول على نتائج بشكل مبسط للغاية
+
+197
+00:15:11,950 --> 00:15:16,790
+باستخدام مفهوم الـ minimum اللى كنا ذكرنا سابقا
+
+198
+00:15:16,790 --> 00:15:22,050
+فهناخد أمثلة بداية أمثلة مباشرة وبعدين هناخد أمثلة
+
+199
+00:15:22,050 --> 00:15:26,150
+متعددة في كل مثال هنلاقي ولو نقطة صغيرة نتعلمها
+
+200
+00:15:26,150 --> 00:15:30,030
+علشان في المستقبل نستفيد منها في حل الأسئلة
+
+201
+00:15:30,030 --> 00:15:34,150
+فهنلاحظ أنه في أننا تدرج في أنواع الأمثلة اللى
+
+202
+00:15:34,150 --> 00:15:39,060
+هنتطلع عليهانجي نتطلع في البداية على التفاعل
+
+203
+00:15:39,060 --> 00:15:45,040
+التالي عندنا Sodium Carbonate مع HCl طلع على مثال
+
+204
+00:15:45,040 --> 00:15:50,740
+مثال بيقول a 0.4671 gram sample containing Sodium
+
+205
+00:15:50,740 --> 00:15:57,000
+Carbonate لما نقول sample معناته أن هذه العينة مش
+
+206
+00:15:57,000 --> 00:16:01,600
+نقية معناة الكلام الرقم أو الوزنة تبعتها لا تستخدم
+
+207
+00:16:01,600 --> 00:16:07,280
+لأي شيء إلا للحصول على ال percentageإذا كان طلبها
+
+208
+00:16:07,280 --> 00:16:09,940
+ما طلبش ال percentage إذا هذا الرقم اللي بيعطيه
+
+209
+00:16:09,940 --> 00:16:12,640
+ليه و الوزن اللي بيعطيه ليه عالفاضي مايلها أي قيمة
+
+210
+00:16:12,640 --> 00:16:15,640
+في السؤال لا تستخدم في الحلول مالهاش دعوة ليه؟
+
+211
+00:16:15,640 --> 00:16:20,120
+لأنها عينة عينة معناته غير نقية عينة معناته غير
+
+212
+00:16:20,120 --> 00:16:23,600
+نقية فبيقول ليه هذه العينة اللي بتحتوي على السودان
+
+213
+00:16:23,600 --> 00:16:26,060
+بيكربونيت دوبناها
+
+214
+00:16:28,060 --> 00:16:32,860
+Untitrated لما ندوبناها صارت محلول عيرنا بال HCl
+
+215
+00:16:32,860 --> 00:16:40,140
+اللى تركيزه 0.1067 مولار فأخدت 40.72 مل عايز يحسب
+
+216
+00:16:40,140 --> 00:16:44,120
+ال percentage بيه carbonate in the sample بقول يا
+
+217
+00:16:44,120 --> 00:16:50,890
+شباب مهما كانت المسألة مهما كانت الحل عندىبسيط جدا
+
+218
+00:16:50,890 --> 00:16:56,490
+الحل عندى تفاعل بين اتنين بدى اشوف الملي مول من
+
+219
+00:16:56,490 --> 00:17:00,030
+الاول ايش بتساوي من الملي مول من التانى فعندى
+
+220
+00:17:00,030 --> 00:17:03,530
+التفاعل اللى جدامى واحد لواحد واحد ملي مول Sodium
+
+221
+00:17:03,530 --> 00:17:08,230
+B Carbonate واحد ملي مول HCl اذا بدى اقول عدد ملي
+
+222
+00:17:08,230 --> 00:17:13,030
+مولات ال Sodium Carbonate يساوي عدد ملي مولات ال
+
+223
+00:17:13,030 --> 00:17:19,320
+HCl هذه مش صعبة هذه من المعادلة صح ولا لأالان
+
+224
+00:17:19,320 --> 00:17:24,760
+المسألة خلصت، كيف؟ جال لأن الجزء اللي فاضل هو
+
+225
+00:17:24,760 --> 00:17:28,780
+التعويض في ال millimoles والتعويض في ال millimoles
+
+226
+00:17:28,780 --> 00:17:32,700
+هو أحد حاجتين، يا milligram على الفورمولويت، يا
+
+227
+00:17:32,700 --> 00:17:38,110
+مدارة ال volume ولا ثالثة لهما، فشكويس فانا عندى
+
+228
+00:17:38,110 --> 00:17:40,650
+مثلا بدى milligram of sodium bicarbonate هو بدى
+
+229
+00:17:40,650 --> 00:17:44,030
+وزدة ال sodium bicarbonate معنى الكلام milligram
+
+230
+00:17:44,030 --> 00:17:46,850
+على ال formula way لأ ماعطينى molarity ولا ماعطينى
+
+231
+00:17:46,850 --> 00:17:50,210
+volume فاش قدامي الا ان اوضعنها milligram على ال
+
+232
+00:17:50,210 --> 00:17:53,590
+formula way طب وال HCl لأ ماعطينى ال molarity و ال
+
+233
+00:17:53,590 --> 00:17:57,070
+volume لل HCl اذا ال molarity في ال volume فبتطلع
+
+234
+00:17:57,070 --> 00:18:01,050
+ان ال milligram sodium bicarbonate عبارة عن 365
+
+235
+00:18:01,050 --> 00:18:07,240
+milligram بدى اجيب ال percentageبحولها لجرام بجسم
+
+236
+00:18:07,240 --> 00:18:12,920
+على جرام عيناه في 100 من 100 بتطلع 78% مثلا كويس
+
+237
+00:18:12,920 --> 00:18:16,520
+كمان مرة بقول مفتاح الحال على طول من المعادلة
+
+238
+00:18:16,520 --> 00:18:19,680
+millimole of sodium b-carbonate بتساوي أكم
+
+239
+00:18:19,680 --> 00:18:22,620
+millimole من ال HCl بيساوي بعض واحد millimole
+
+240
+00:18:22,620 --> 00:18:28,080
+لواحد millimole بس الفكرة أنه بتدعوض عن ال
+
+241
+00:18:28,080 --> 00:18:31,500
+millimole في بعض الأحيان ممكن ما تفهمش المسألة
+
+242
+00:18:31,500 --> 00:18:35,440
+كتيرلكن إذا كانت تبعت هذا الأسلوب من المعادلة هات
+
+243
+00:18:35,440 --> 00:18:38,160
+ال millimoles و عوض في ال millimoles هتلاقي
+
+244
+00:18:38,160 --> 00:18:41,820
+المطلوب قدامك أو اللي بده يدلك على المطلوب قدامك
+
+245
+00:18:41,820 --> 00:18:45,460
+صار، ياما المطلوب بشكل مباشر، ياما اللي بده يدلك
+
+246
+00:18:45,460 --> 00:18:48,980
+على المطلوب بشكل مباشر، أول خطوة تعملها، فيش عندك
+
+247
+00:18:48,980 --> 00:18:52,960
+حاجة إلا إنك توجد ال millimoles للإتنين، إيش ال
+
+248
+00:18:52,960 --> 00:18:54,740
+millimoles من الأول، أكم millimoles من التاني
+
+249
+00:18:54,740 --> 00:18:59,290
+بتساوي؟ممكن نحل بخطوة واحدة نعم ممكن نحل المسألة
+
+250
+00:18:59,290 --> 00:19:04,590
+بخطوة واحدة هي يعني واضحة عندك ممكن إذا بتحب ترجع
+
+251
+00:19:04,590 --> 00:19:09,190
+في البيت ممكن ترجعها يبقى هذا إذا كان في عيننا
+
+252
+00:19:10,180 --> 00:19:15,120
+تفاعل بيعطينا واحد لواحد لو اجينا لتفاعل اخر ناخد
+
+253
+00:19:15,120 --> 00:19:19,540
+نفس المسألة لكن بدل ما هي Sodium B Carbonate ناخد
+
+254
+00:19:19,540 --> 00:19:23,520
+Sodium Carbonate فالمثلة بتقول a 0.4671 gram
+
+255
+00:19:23,520 --> 00:19:27,260
+sample containing sodium carbonate was dissolved
+
+256
+00:19:27,260 --> 00:19:33,860
+and titrated with HCl 0.1067 requiring 40.72 نفس
+
+257
+00:19:33,860 --> 00:19:36,720
+المثلة ايش بس بيقول find the percentage of
+
+258
+00:19:36,720 --> 00:19:41,180
+carbonate in the sample اوجدالـ percentage
+
+259
+00:19:41,180 --> 00:19:45,280
+للكربونات بقول هاي معادلة الكربونات مع ال HCl
+
+260
+00:19:45,280 --> 00:19:50,980
+الكربونات بتتفعل مع اتنين HCl ماشي باجي بعد يا
+
+261
+00:19:50,980 --> 00:19:58,060
+شباب بقول اكمل الكربوناتاكمل HCl، اذا عدد ميلي
+
+262
+00:19:58,060 --> 00:20:03,240
+مولات الكربونيت نص عدد .. لا هذه واحد، الواحد نص
+
+263
+00:20:03,240 --> 00:20:08,240
+التانية، عدد ميلي مولات السوديوم كربونيت نص عدد
+
+264
+00:20:08,240 --> 00:20:12,840
+ميلي مولات الـHCl، اتغلبت، ماعرفتش، من المعادلة
+
+265
+00:20:12,840 --> 00:20:18,520
+على طول، قول والله ميلي مولسوديام كربونيت جداش
+
+266
+00:20:18,520 --> 00:20:25,260
+أعدد مولاتها واحد هي على واحد تساوي ميلي مول HCl
+
+267
+00:20:25,260 --> 00:20:29,700
+جداش أعدد ميلي مولاتها على اتنين ممكن تعمل زيه كل
+
+268
+00:20:29,700 --> 00:20:35,380
+مادة على عدد ميلي مول على عدد الاستوكيومتر اللي
+
+269
+00:20:35,380 --> 00:20:40,280
+موجودة الاستوكيومتر اللي موجودة وهي واضح هنا عندك
+
+270
+00:20:40,280 --> 00:20:45,020
+عدد كعدد ميلي مولات ال HCl ضعف الكربونيت
+
+271
+00:20:45,460 --> 00:20:50,380
+الcarbonate واحد نص ال HCl لازم تفهم هذا كلام كويس
+
+272
+00:20:50,380 --> 00:20:56,260
+كتير ليه؟ لأن هذا أساس حساباتنا وهذا من الحسابات
+
+273
+00:20:56,260 --> 00:21:02,180
+حسابات يعني مرحلة ابتدائية فقط لما أجي أقولك هذا
+
+274
+00:21:02,180 --> 00:21:07,100
+واحد وهذا اتنين بتقول الواحد نص التنين او التنين
+
+275
+00:21:07,100 --> 00:21:12,660
+ضعف الواحديعني هذا اشي من ابسط الحسابات اللى ممكن
+
+276
+00:21:12,660 --> 00:21:17,220
+تمر علينا بشكل عام الان مادام قولنا يا شباب ان
+
+277
+00:21:17,220 --> 00:21:19,740
+ميلي مول Sodium Carbonate نص الميلي مول HCl
+
+278
+00:21:19,740 --> 00:21:23,600
+المسألة خلصت لإن مافيش قدامنا إلا حاجة واحدة بس
+
+279
+00:21:23,600 --> 00:21:26,680
+إما نعوض عن الميلي مول طب إيش بدنا نعوض عن الميلي
+
+280
+00:21:26,680 --> 00:21:29,700
+مول؟ يا ما ميلي جرام ع الفورمولويت يا ما مولارتي ب
+
+281
+00:21:29,700 --> 00:21:32,440
+volume باجرى الكربونيت مافيش عندى لا ميلي جرام ع
+
+282
+00:21:32,440 --> 00:21:35,950
+الفورمولويت مافيش عندى لا مولارتي ولا volumeالـ
+
+283
+00:21:35,950 --> 00:21:39,970
+HCl اه انديمولاريتي او volume فبتطلع ان ال
+
+284
+00:21:39,970 --> 00:21:42,150
+milligram صوديا و كربونيت بتان و تلاتين و ال
+
+285
+00:21:42,150 --> 00:21:45,110
+percentage تسعة و اربعين و تلاتة من عشر احاول اتحل
+
+286
+00:21:45,110 --> 00:21:56,070
+بحط واحدة في البيت اذا كان حب بيت فضل انت
+
+287
+00:21:56,070 --> 00:21:59,790
+ممكن تقول حاجة تانية ممكن تقول التالت ممكن تقول
+
+288
+00:21:59,790 --> 00:22:07,600
+انه كل milligramسوديوم كربونيت بتفاعل مع 2 ميلي
+
+289
+00:22:07,600 --> 00:22:15,360
+مول HCl هذا اسمه conversion مش conversion يعني
+
+290
+00:22:15,360 --> 00:22:18,620
+ممكن نسميه stoichiometric factor stoichiometric
+
+291
+00:22:18,620 --> 00:22:19,580
+conversion factor
+
+292
+00:22:24,750 --> 00:22:28,590
+هذا لما تيجي تحل بخطوة واحدة صحيح كل ملي مول
+
+293
+00:22:28,590 --> 00:22:32,130
+Sodium Carbonate بتفاعل او كل واحد ملي مول Sodium
+
+294
+00:22:32,130 --> 00:22:35,170
+Carbonate بتفاعل مع اتنين ملي مول AC لكن انا لما
+
+295
+00:22:35,170 --> 00:22:39,790
+اقولك ملي مول بيساوي عدد عدد ملي مولات Sodium
+
+296
+00:22:39,790 --> 00:22:45,690
+Hydroxide ضعف عدد ملي مولات ال H2SO4 احنا بنشتغل
+
+297
+00:22:45,690 --> 00:22:51,870
+بمستوى حسابي بسيط جدا احنا بنشوف ايه العدد معايا
+
+298
+00:22:53,000 --> 00:22:57,700
+بنعد عدد .. عدد ملي مولات ال sodium hydroxide ضعيف
+
+299
+00:22:57,700 --> 00:23:00,980
+عدد ملي مولات ال H2SO4 مثلا في المعادلة .. هيك
+
+300
+00:23:00,980 --> 00:23:04,260
+بنقراها في المعادلة اللي قدامي فنيجي نتطلع على
+
+301
+00:23:04,260 --> 00:23:10,240
+مسألةمعايرة بين محلولين مش مادة صلباء و محلول
+
+302
+00:23:10,240 --> 00:23:17,380
+فبتقول how many ml of 0.25 molar sodium hydroxide
+
+303
+00:23:17,380 --> 00:23:21,960
+will react with 5 ml of 0.1 molar H2SO4 بقول
+
+304
+00:23:21,960 --> 00:23:26,340
+المعادلة بعض المعادلات باطحة يعني مثلا sodium b
+
+305
+00:23:26,340 --> 00:23:28,720
+carbonate مع HCl معروف واحد لواحد
+
+306
+00:23:32,850 --> 00:23:38,790
+معروف واحد لا اتنين Sodium hydroxide ل H2SO4 اتنين
+
+307
+00:23:38,790 --> 00:23:43,150
+لا واحد مفهومة بعض المعادلات معروفة يعني ليه لأنه
+
+308
+00:23:43,150 --> 00:23:46,570
+مرت معانا كتير و خلاص صارت معلومة بالنسبة لنا
+
+309
+00:23:46,570 --> 00:23:51,130
+المعادل اللي جدامي انا بقول بدي millimol hydroxide
+
+310
+00:23:51,130 --> 00:23:54,670
+هاي المليمول هاي اتنين طب المليمول H2SO4 جديش
+
+311
+00:23:54,670 --> 00:23:57,750
+لاتنين ضعف الواحد فبتقول والله المليمول Sodium
+
+312
+00:23:57,750 --> 00:24:04,050
+hydroxide ضعف المليمول H2SO4 بتكاشفحط هذه على
+
+313
+00:24:04,050 --> 00:24:08,670
+اتنين وحط هذه على واحد فش مشكلة تطلع معاك نفس
+
+314
+00:24:08,670 --> 00:24:13,310
+الحاجة زي ما بتتريح يشتغل المهم تشتغل صح بعدين
+
+315
+00:24:13,310 --> 00:24:16,770
+باجي بقول حل المسألة مدام كتبتي ال millimoles
+
+316
+00:24:16,770 --> 00:24:20,370
+تقريبا نص المسألة خلصت النص التاني اني بتعود عن ال
+
+317
+00:24:20,370 --> 00:24:21,730
+millimoles ايش بتعود؟
+
+318
+00:24:26,690 --> 00:24:31,530
+معنى الكلام ال volume بيطلق أربعة mil لو حبينا أن
+
+319
+00:24:31,530 --> 00:24:35,830
+نحلها بخطوة واحدة بإمكاننا لكن هنلاقيها يعني بدها
+
+320
+00:24:35,830 --> 00:24:39,590
+شوية معلومات لو احنا بناخد هذا النوع من الحسابات
+
+321
+00:24:39,590 --> 00:24:43,810
+كان ممكن نعطيكم بعض ال clues أو بعض ال يعني ال
+
+322
+00:24:43,810 --> 00:24:48,970
+يعني خلّيني أقول الأشياء المساعدة كيف تستخدم هذا
+
+323
+00:24:48,970 --> 00:24:53,320
+النوع من الحسابات كيف تحل بشكلممتاز لكن احنا
+
+324
+00:24:53,320 --> 00:24:56,840
+بنحاولش نغطي هذا النوع من الحسابات بدنا نستخدم
+
+325
+00:24:56,840 --> 00:25:01,220
+مفهوم الـ millimoles لأنه أسهل بشكل كبير و لا مجال
+
+326
+00:25:01,220 --> 00:25:06,120
+فيه للخطأ لا مجال فيه للخطأ فنحاول نتطلع على مسألة
+
+327
+00:25:06,120 --> 00:25:12,560
+عملية في الحقيقة انا لما بدي اعرف تركيز ال HCl
+
+328
+00:25:12,560 --> 00:25:17,880
+عادة باخد وزنة معينة من ال بيكربونيت النقية ال
+
+329
+00:25:17,880 --> 00:25:20,220
+بيكربونيت تعتبر ال primary standard solution
+
+330
+00:25:22,790 --> 00:25:29,130
+وبعايرها، بعاير المحلول أو بعاير الوزن هذي من الـ
+
+331
+00:25:29,130 --> 00:25:33,050
+B-Carbonate اللي معروف جداش مع المحلول وبشوف والله
+
+332
+00:25:33,050 --> 00:25:38,950
+جداش تركيز الـ HCl فنتطلع على المثال، هذا مثال زي
+
+333
+00:25:38,950 --> 00:25:43,030
+ما قلت عملي جيد يعني واستخدم في المختبر بشكل كبير
+
+334
+00:25:43,600 --> 00:25:47,740
+الـ 0.18760 جرام كربونات صادمة صادمة صادمة صادمة
+
+335
+00:25:47,740 --> 00:25:49,220
+صادمة صادمة صادمة صادمة صادمة صادمة صادمة صادمة
+
+336
+00:25:49,220 --> 00:25:50,460
+صادمة صادمة صادمة صادمة صادمة صادمة صادمة صادمة
+
+337
+00:25:50,460 --> 00:25:52,140
+صادمة صادمة صادمة صادمة صادمة صادمة صادمة صادمة
+
+338
+00:25:52,140 --> 00:25:55,040
+صادمة صادمة صادمة صادمة صادمة صادمة صادمة صادمة
+
+339
+00:25:55,040 --> 00:25:59,440
+صادمة صادمة صادمة صادمة صادمة صادمة صادمة صادمة
+
+340
+00:25:59,440 --> 00:25:59,440
+صادمة صادمة صادمة صادمة صادمة صادمة صادمة صادمة
+
+341
+00:25:59,440 --> 00:25:59,440
+صادمة صادمة صادمة صادمة صادمة صادمة صادمة صادمة
+
+342
+00:25:59,440 --> 00:26:02,280
+صادمة صادمة صادمة صادمة صادمة صادمة صادمة صادمة
+
+343
+00:26:02,280 --> 00:26:09,740
+صادمة صادمةrequiring 35.86 يعني عيرنا هذه الوزنة
+
+344
+00:26:09,740 --> 00:26:15,820
+فأخدت 35.86 مل بيقول find the molarity of HCl ايش
+
+345
+00:26:15,820 --> 00:26:19,580
+ما يطلب مني اي مسألة يا شباب المعادلة المعادلة
+
+346
+00:26:19,580 --> 00:26:23,320
+والله صدم الكربونات بتساوي مع اتنين HCl بتعطينا
+
+347
+00:26:23,320 --> 00:26:28,500
+نواتج اذا ال millimol HCl ايه اللي بدهيا هو لانه
+
+348
+00:26:28,500 --> 00:26:32,240
+بده مولارتي HCl بيقول millimol HCl ايش بتساوي من
+
+349
+00:26:32,240 --> 00:26:39,590
+الكربونات؟دعفها طبعا ال HCl تنين الكربونيت واحد
+
+350
+00:26:39,590 --> 00:26:44,510
+اذا ال HCl ضعف الكربونيت صحيح حد ايه ملي مول HCl
+
+351
+00:26:44,510 --> 00:26:49,650
+بسوا تنين ملي مول صوديوم كربونيت او عدد ملي مولات
+
+352
+00:26:49,650 --> 00:26:56,030
+ال HCl ضعف عدد ملي مولات الكربونيت هيك بتقرأ يا
+
+353
+00:26:56,030 --> 00:27:01,280
+شباب عدد ملي مولات ال HClضعف عدد millimoles
+
+354
+00:27:01,280 --> 00:27:07,500
+الكربونيات الان المسألة مانهي مجرد انه بدنا نعوض
+
+355
+00:27:07,500 --> 00:27:12,260
+عن ال millimoles والتعويض هيوصلك للمطلوب يعني حتى
+
+356
+00:27:12,260 --> 00:27:15,600
+لو انت مش عارف المطلوب كويس مجرد انك تحط المعاد لو
+
+357
+00:27:15,600 --> 00:27:21,210
+اتعوب هتلاقي المطلوب قدامكماشي فحنقول millimol hcl
+
+358
+00:27:21,210 --> 00:27:23,910
+يعني molarity في volume ال volume معايا ال
+
+359
+00:27:23,910 --> 00:27:27,230
+molarity مجهولة ال millimol sodium carbonate
+
+360
+00:27:27,230 --> 00:27:31,810
+milligram milligram هو نعطينا اذا كان لحظة اه gram
+
+361
+00:27:31,810 --> 00:27:35,990
+بدنا نحوله ل milligram عشان هيك باجي بدرب هي ال
+
+362
+00:27:35,990 --> 00:27:39,450
+milligram كانت point one eight seven six صارت one
+
+363
+00:27:39,450 --> 00:27:42,480
+eight seven يعني وكأني ضربت في الف على طوللكن أنا
+
+364
+00:27:42,480 --> 00:27:45,540
+ما كتبت ال cash يعني point one eight seven six في
+
+365
+00:27:45,540 --> 00:27:48,580
+عشرة أقصى ثلاثة لأ عملتها على طول و أنت كمان عملها
+
+366
+00:27:48,580 --> 00:27:53,160
+على طول مش فرق فبتطلع ال modality لل HCL point oh
+
+367
+00:27:53,160 --> 00:27:59,280
+nine eight seven two بإمكاننا نشتغل يعني المسألة
+
+368
+00:27:59,280 --> 00:28:03,380
+بخطوة واحدة زي ما احنا شايفين لكن احنا طبعا بنعالج
+
+369
+00:28:03,380 --> 00:28:04,260
+مفهوم ال minimum
+
+370
+00:28:07,310 --> 00:28:10,850
+نجي نتطلع على المثال اللي قدامي، مسألة كتير جميلة
+
+371
+00:28:10,850 --> 00:28:15,350
+و برضه فيها مفهوم جديد، إيش المثلة بتقول؟ بتقول an
+
+372
+00:28:15,350 --> 00:28:20,470
+acidified and reduced iron sample، يعني عينة من
+
+373
+00:28:20,470 --> 00:28:23,870
+الحديد، حطينا عليها شوية acid و عملنا reduction
+
+374
+00:28:23,870 --> 00:28:27,910
+للحديد، حولناها لحديد 2، لأن جزء من الحديد بيكون
+
+375
+00:28:27,910 --> 00:28:34,490
+حديد 3، حولناها كلها لحديد 2required 42 من 10 ml
+
+376
+00:28:34,490 --> 00:28:38,550
+of 0.0206 molar potassium permanganate عيرناه
+
+377
+00:28:38,550 --> 00:28:42,250
+بالبرمجانات فأخد حجم معين من البرمجانات اللي
+
+378
+00:28:42,250 --> 00:28:47,950
+تركيزها 0.0206 molar فعايز يحسب ال milligram iron
+
+379
+00:28:47,950 --> 00:28:53,910
+فش مشكلة لكن كمان عايز يحسب and milligram iron 203
+
+380
+00:28:55,200 --> 00:28:59,860
+ماشي احنا بنطلع على المعادلة يا شباب المعادلة هي
+
+381
+00:28:59,860 --> 00:29:04,120
+ال permanganate زائد خمسة iron اتنين زائد تمانية H
+
+382
+00:29:04,120 --> 00:29:07,980
+plus تعطينا مانجانيز اتنين زائد خمسة iron تلاتة
+
+383
+00:29:07,980 --> 00:29:12,720
+زائد اربعة مية هي المعادلة المعادلة فيها بس iron
+
+384
+00:29:12,720 --> 00:29:16,100
+مافيش فيها iron 203 مش مشكلة هي هذا النقطة اللى
+
+385
+00:29:16,100 --> 00:29:19,140
+بنحاول نعالجها لكن فى البداية خلانى أجد ال
+
+386
+00:29:19,140 --> 00:29:24,110
+milligram iron والله بقول مافيش عندى حاجةماذا لو
+
+387
+00:29:24,110 --> 00:29:28,030
+كنت بتحصل على ملي مول؟ مافي عندى اي طريقة تانية
+
+388
+00:29:28,030 --> 00:29:31,910
+فهو الملي مول ايرون بالنسبة للبرمجانات عدد ملي
+
+389
+00:29:31,910 --> 00:29:36,250
+مولات الايرون بالنسبة للبرمجانات كانت خمس أضعافة
+
+390
+00:29:36,250 --> 00:29:40,570
+صحيح خمسة ملي مول برمجانات الآن بدى اعوض بس عن
+
+391
+00:29:40,570 --> 00:29:44,560
+الملي مولالملي مول ايرون هو ملي جرام على ال
+
+392
+00:29:44,560 --> 00:29:48,520
+formula weight الملي جرام بدناياها ال formula
+
+393
+00:29:48,520 --> 00:29:54,380
+weight طبعا atomic weight لأنه ions الملي مول
+
+394
+00:29:54,380 --> 00:29:57,840
+permanganate مولاريته ب volume فبس تعويض مباشر
+
+395
+00:29:57,840 --> 00:30:05,000
+بيعطينا الملي جرام ايرون متين وواحد وتلاتين الاصل
+
+396
+00:30:05,000 --> 00:30:08,340
+انه انت بتعرفها لحالك يعني في بعض الحالات انا
+
+397
+00:30:08,340 --> 00:30:09,060
+بعطيها لك
+
+398
+00:30:12,070 --> 00:30:15,450
+ممكن أفهمك إياها، أقولك إن هذه المعادلة مرت عليك
+
+399
+00:30:15,450 --> 00:30:19,630
+في كيميا عامة بقى، وعرفت كيف كنت توزنها يعني، أنا
+
+400
+00:30:19,630 --> 00:30:24,290
+ممكن أعطيك دلالة، بقولك إن ال permanganate .. أه
+
+401
+00:30:24,290 --> 00:30:27,250
+ال permanganate .. ممكن أعطيك إن ال permanganate
+
+402
+00:30:27,250 --> 00:30:30,570
+اتحولت لمنجانيز اتنينمدى ما اعطيتك هذا الكلام
+
+403
+00:30:30,570 --> 00:30:34,890
+المسألة عندك انتهت ليه؟ لأنه من ال permanganate
+
+404
+00:30:34,890 --> 00:30:37,770
+اتحول لمنجانيز اتنين انت بتقدر توزن المعادلة تقول
+
+405
+00:30:37,770 --> 00:30:41,030
+في عندنا مثلا اربعة اكسوجين اذا في عندنا اربعة مية
+
+406
+00:30:41,030 --> 00:30:45,450
+في عندنا تمانية H اذا تمانية H plus بنوزنها بيصير
+
+407
+00:30:45,450 --> 00:30:49,510
+خمس إلكترونات ايرون اتنين بتعطينا ايرون تلاتة زائد
+
+408
+00:30:49,510 --> 00:30:52,510
+إلكترون عشان في عندي خمس إلكترونات في الأولى اذا
+
+409
+00:30:52,510 --> 00:30:56,190
+بضرب في خمسة تجمع المعادلتين بتطلع معاك المعادلة
+
+410
+00:30:56,190 --> 00:31:03,120
+هذا أخدته في سنة أولىطيب يا شباب الفكرة الآن اللى
+
+411
+00:31:03,120 --> 00:31:06,880
+أهم من هيك بالنسبة ليه انه انا بدي اوجد اكم
+
+412
+00:31:06,880 --> 00:31:13,800
+milligram iron 2O3 بقول في البداية انا في عندى
+
+413
+00:31:13,800 --> 00:31:19,460
+حاجة بتقول ايش بتقول milligram iron بتساوي خمسة
+
+414
+00:31:19,460 --> 00:31:24,680
+milligram permanganate صحيح؟ من المعادلة الأولى
+
+415
+00:31:25,770 --> 00:31:30,330
+الان انا بديش ملي مول ايرون بدي ملي مول ايرون
+
+416
+00:31:30,330 --> 00:31:34,590
+اتنين او تلاتة طب كيف بدي اجيبها قال بعمل معادلة
+
+417
+00:31:34,590 --> 00:31:39,550
+اتنين ايرون بتعطينا ايرون اتنين او تلاتة اول ايرون
+
+418
+00:31:39,550 --> 00:31:42,300
+اتنين او تلاتة فيه اتنين ايرونالايرون اتنين او
+
+419
+00:31:42,300 --> 00:31:46,320
+تلاتة فيه جداش ايرون اتنين ايرون فباش بقول يبقى
+
+420
+00:31:46,320 --> 00:31:49,120
+الميلي مول ايرون ايش بيساوي من الميلي مول ايرون
+
+421
+00:31:49,120 --> 00:31:53,360
+اتنين او تلاتة ضعف الميلي مول ايرون في اتنين
+
+422
+00:31:53,360 --> 00:31:56,900
+الميلي مول ايرون اتنين او تلاتة واحد الواقع اتنين
+
+423
+00:31:56,900 --> 00:32:02,720
+ضعف الميلي مول ايرون اللي هي هيها ايش بتساوي اتنين
+
+424
+00:32:02,720 --> 00:32:09,240
+ميلي مول ايرون اتنين او تلاتة بتساوي خمسة ميلي مول
+
+425
+00:32:11,550 --> 00:32:15,890
+فيرمينجانيت كمان مرة بقول هو مش معطيني في المعادلة
+
+426
+00:32:15,890 --> 00:32:18,910
+ايرون اتنين او تلاتة ما هو معطيني ايرون اتنين او
+
+427
+00:32:18,910 --> 00:32:21,690
+تلاتة طب كيف بده اجيبها بقول اللي في المعادلة
+
+428
+00:32:21,690 --> 00:32:27,350
+بحاول اني احوله لإيه للمطلوب فعندي اتنين ايرون
+
+429
+00:32:27,350 --> 00:32:31,350
+تعطينا ايرون اتنين او تلاتة اذا ال minimum of iron
+
+430
+00:32:31,350 --> 00:32:35,660
+اللي هو اللي موجود في المعادلة هيضعف الملي مول
+
+431
+00:32:35,660 --> 00:32:40,260
+ايرون اتنين او تلاتة يبقى بحط هذا محل هذا هاي
+
+432
+00:32:40,260 --> 00:32:44,340
+الملي مول ايرون بحط اتنين ملي مول ايرون اتنين او
+
+433
+00:32:44,340 --> 00:32:49,240
+تلاتة لإن هدول اتنين متساوين هاي الملي مول ايرون
+
+434
+00:32:49,240 --> 00:32:52,180
+يساوي اتنين ملي مول ايرون اتنين او تلاتة هاي
+
+435
+00:32:52,180 --> 00:33:01,460
+المعادلة اتفضل صحيح من عندك لأ هذه هيها مش موجودة
+
+436
+00:33:01,460 --> 00:33:07,190
+عندكانت بتقدر تطلعها تقدر تقول انه كل iron اتنين
+
+437
+00:33:07,190 --> 00:33:11,410
+او تلاتة فيها اتنين iron فبتشوف ال millimoles
+
+438
+00:33:11,410 --> 00:33:15,690
+مباشرة كيف؟ كيف عليه اساس انت قوللي حاجة تانية ال
+
+439
+00:33:15,690 --> 00:33:19,150
+iron اتنين او تلاتة اكم iron فيها انت قوللي فيها
+
+440
+00:33:19,150 --> 00:33:22,410
+حاجة غير الاتنين هذا مش فعال يعني مش اشي يعني صعب
+
+441
+00:33:23,090 --> 00:33:27,790
+بإمكانك تجيب هذا الكلام شكل مباشر طيب، مدام جيبنا
+
+442
+00:33:27,790 --> 00:33:31,450
+هيك صارت 2 millimole of iron 2O3 بتساوي 5
+
+443
+00:33:31,450 --> 00:33:36,050
+millimole of permanganate إذا بدنا نعوّب عن هذا
+
+444
+00:33:36,050 --> 00:33:39,810
+بالمليجرام على الفورمولاويت مولارتي في volume هي
+
+445
+00:33:39,810 --> 00:33:43,770
+مليجرام على الفورمولاويت مولارتي في volume اللي
+
+446
+00:33:43,770 --> 00:33:51,130
+بيطلع عنا المليجرام iron 2O3 331 مليجرام ممكن
+
+447
+00:33:51,130 --> 00:33:56,340
+يقولك حاجة تانيةفهمنا بس لهان؟ افهمنا لهان؟ طيب لو
+
+448
+00:33:56,340 --> 00:34:01,700
+قالك مثلا والله هاتلي milligram iron تلاتة او
+
+449
+00:34:01,700 --> 00:34:07,420
+اربعة عادي بنقوله والله ال iron تلاتة او خلينا
+
+450
+00:34:07,420 --> 00:34:13,420
+نقول تلاتة iron تعطينا iron تلاتة او اربعة، اذا ال
+
+451
+00:34:13,420 --> 00:34:14,600
+milligram iron
+
+452
+00:34:17,530 --> 00:34:24,090
+بدو يساوي تلاتة millimole FE3O4 زي ما بدو هذا و
+
+453
+00:34:24,090 --> 00:34:29,390
+هذا بدو يروح محل ال millimole iron مااخد بالك؟ ايش
+
+454
+00:34:29,390 --> 00:34:32,390
+مايقول؟ مش مشكلة ايش يقولك ايش طريقة التعبير اللي
+
+455
+00:34:32,390 --> 00:34:38,070
+بدوياها مدام انت عندك المعادلة بقى شوف ايش الخاص
+
+456
+00:34:38,070 --> 00:34:45,170
+الجزء الخاص بالموضوع و بحوله للمطلوب سهل اكتير
+
+457
+00:34:45,170 --> 00:34:47,030
+تفضل
+
+458
+00:34:49,820 --> 00:34:56,460
+موجود يعني ال F E 2 بتعامل معاه ال empirical
+
+459
+00:34:56,460 --> 00:34:59,880
+بتعمله ولا .. زي ما هو زي ما هو موجود ايش مكان
+
+460
+00:34:59,880 --> 00:35:04,040
+يكون موجود فاش مشكلة ايش مكان ايش مكان يكون فاش
+
+461
+00:35:04,040 --> 00:35:08,200
+عندى مشكلة iron 2 iron 3 زي ما هو مكتوب في
+
+462
+00:35:08,200 --> 00:35:14,290
+المعادلة بتتعامل معاه المهم ايش فيه جابلههذا المهم
+
+463
+00:35:14,290 --> 00:35:17,950
+يعني ال Stoichiometry طيب يا شباب نيجي نتطلع على
+
+464
+00:35:17,950 --> 00:35:26,410
+هالمثال المثال هذا خاص بمادة كتير احنا بنستخدمها
+
+465
+00:35:26,410 --> 00:35:33,490
+في المختبر اسمها EDTA او يعني بعض الناس بيقول يعني
+
+466
+00:35:33,490 --> 00:35:37,490
+او احنا العرب يعني بيقولها Edita صحيح يعني لكن هي
+
+467
+00:35:37,490 --> 00:35:43,020
+طبعا يعني في بلاد برا بيقولها اختصارها EDTAهي
+
+468
+00:35:43,020 --> 00:35:48,000
+اختصار لـ Ethylenediamine Tetraacetic Acid هذه
+
+469
+00:35:48,000 --> 00:35:53,440
+المادة هناخد عليها chapter كامل بالمناسبة ال
+
+470
+00:35:53,440 --> 00:35:58,580
+chapter تقريبا هيتعلق بال complexometric reactions
+
+471
+00:35:58,580 --> 00:36:02,700
+و titrations و هيكون دراستنا بشكل أساسي عن ال EDTA
+
+472
+00:36:03,240 --> 00:36:10,620
+لكن الان بس ملاحظة ونحاول نفهم يعني شيء عن ال EDTA
+
+473
+00:36:10,620 --> 00:36:17,180
+بنقول ان ما يميز ال EDTA انه بتتفاعل مع ال metal
+
+474
+00:36:17,180 --> 00:36:23,220
+ions ال polyvalent metal ions بنسبة 1 ل 1يعني أنا
+
+475
+00:36:23,220 --> 00:36:28,360
+مش بحاجة لإني أكتب معادلات في تفاعلات ال EDTA ليه؟
+
+476
+00:36:28,360 --> 00:36:33,000
+ده لأن ال EDTA دائما هتتفاعل بالنسبة واحد لواحد مع
+
+477
+00:36:33,000 --> 00:36:38,610
+ال polyvalent metal ionsما دايما عرفنا هذه
+
+478
+00:36:38,610 --> 00:36:42,470
+المعلومة تعالوا نتطلع على المثال اللي عندي يبقى
+
+479
+00:36:42,470 --> 00:36:47,150
+وين بتلاقي EDTA تسألش عن معادلة ولا تتعب نفسك تكتب
+
+480
+00:36:47,150 --> 00:36:51,690
+معادلة ولا تقول ايش رمز ال EDTA ولا غيره اعرف انه
+
+481
+00:36:51,690 --> 00:36:55,070
+تسبت التفاعل بين المتفاعلات ال EDTA و ال
+
+482
+00:36:55,070 --> 00:37:00,020
+polyvalent metal ion واحد لواحد وانتهى الموضوعطيب،
+
+483
+00:37:00,020 --> 00:37:03,480
+نيجي نتطلع عليها المثال، المثال إيش بيقول؟ بيقول
+
+484
+00:37:03,480 --> 00:37:08,280
+ايه؟ one gram aluminum sample required عشرين و نص
+
+485
+00:37:08,280 --> 00:37:15,680
+من ال EDTA يعني إجيت، أخدت، عينت aluminum دايبة،
+
+486
+00:37:15,680 --> 00:37:19,460
+فأخدت، عيرتها بال EDTA، أخدت عشرين و نص من ال
+
+487
+00:37:19,460 --> 00:37:25,370
+EDTA، لاحظ إنه ما جاليش تركيز ال EDTA جديشبنفعش لأ
+
+488
+00:37:25,370 --> 00:37:29,610
+مش معروفة لسه مش مش معروفة ليش معروفة التركيز ما
+
+489
+00:37:29,610 --> 00:37:34,090
+جاليا طيب بنكمل المثالة بيقول find the percentage
+
+490
+00:37:34,090 --> 00:37:37,030
+aluminum 2O3 طبعا ماليش ده عمري aluminum 2O3 انا
+
+491
+00:37:37,030 --> 00:37:40,290
+بعرف ان ال aluminum بتفاعل مع ال EDTA واحد لواحد
+
+492
+00:37:40,290 --> 00:37:45,750
+هذه aluminum 2O3 ايه اللي هاجصة معايا aluminum 2O3
+
+493
+00:37:45,750 --> 00:37:49,610
+مش aluminum انا عندى ال metal ion بتفاعل مع ال
+
+494
+00:37:49,610 --> 00:37:53,350
+EDTA واحد لواحد هذه aluminum 2O3 بدنا نشوف كيف
+
+495
+00:37:53,350 --> 00:37:58,460
+نعملهافبيقول اوجد ال percentage لـ LM2O3 in this
+
+496
+00:37:58,460 --> 00:38:06,260
+sample if 30 ml من ال EDTA required 25 ml of 0.1
+
+497
+00:38:06,260 --> 00:38:10,860
+molar calcium chloride لاحظ معايا انه عير ال EDTA
+
+498
+00:38:10,860 --> 00:38:15,440
+مع ال calcium chloride من هذه المعايرة بيقدر يوجد
+
+499
+00:38:15,440 --> 00:38:19,820
+تركيز ال EDTA عشان يستخدمه في السطر الأول في
+
+500
+00:38:19,820 --> 00:38:23,100
+الخطوة الأولى يعني يبقى الخطوة التانية اللي اعطاه
+
+501
+00:38:23,100 --> 00:38:28,370
+الليلإيجاد تركيز ال EDTA وإلا لو أعطاني جالي one
+
+502
+00:38:28,370 --> 00:38:32,410
+gram of aluminum sulphur required عشرين mil of كذا
+
+503
+00:38:32,410 --> 00:38:35,210
+molar EDTA كان المثال محلول على طول مش بحاجة
+
+504
+00:38:35,210 --> 00:38:40,550
+لالسطر اللي بيقولك if تلاتين mil EDTA required إلى
+
+505
+00:38:40,550 --> 00:38:46,840
+أخرها يبقى أول خطوة إحنا بنعملهابنوجد تركيز ال
+
+506
+00:38:46,840 --> 00:38:50,900
+EDTA طبعا انا ماعليه انا ايه الخطوة التانية بقول
+
+507
+00:38:50,900 --> 00:38:55,320
+ملي مول EDTA بتسوى ملي مول calcium chloride لأنه
+
+508
+00:38:55,320 --> 00:38:59,020
+calcium واحد ال calcium واحد هيه شايفينه واحد
+
+509
+00:38:59,020 --> 00:39:02,740
+لواحد هي واحد وهي واحد اه اذا ملي مول EDTA بتسوى
+
+510
+00:39:02,740 --> 00:39:08,050
+ملي مول calcium chlorideالان التعويض بيدعوض ملي
+
+511
+00:39:08,050 --> 00:39:10,670
+جرام ع الفورمولويت و لا مولاريت ال volume انا
+
+512
+00:39:10,670 --> 00:39:13,590
+عندها مولاريت مجهولة ال volume معلوم مولاريت
+
+513
+00:39:13,590 --> 00:39:18,370
+معلومة ال volume معلوم فالمولاريت لل EDTA بتكون 0
+
+514
+00:39:18,370 --> 00:39:24,110
+.0833 يبقى هذه الخطوة استفدنا منها في حساب
+
+515
+00:39:24,110 --> 00:39:26,350
+المولاريت لل EDTA
+
+516
+00:39:30,160 --> 00:39:33,300
+أول المعايير اللي قلناه لسه ماوصلنا لهاش احنا
+
+517
+00:39:33,300 --> 00:39:37,640
+حكينا عن المعايير التانية لأنها بتحدد لتركيز ال
+
+518
+00:39:37,640 --> 00:39:42,360
+EDTA بالظبط نستخدمها في المعادلة اللي فوق يعني
+
+519
+00:39:42,360 --> 00:39:46,540
+بتصير المسألة و كأنها الآن مدام عرفنا التركيز ال
+
+520
+00:39:46,540 --> 00:39:49,440
+EDTA بيصير المسألة كالتالي a one gram aluminum
+
+521
+00:39:49,440 --> 00:39:58,120
+sample required 20.5 ml of 0.0833 molar EDTAبين
+
+522
+00:39:58,120 --> 00:40:00,980
+كام خلصت المسألة بيقول find percentage of aluminum
+
+523
+00:40:00,980 --> 00:40:04,540
+203 in the sample بس يبقى السفر الأخير بطل لازم
+
+524
+00:40:04,540 --> 00:40:11,520
+لما نحطه فوق بطل لازم طيب الآن انا بعرف ان ال
+
+525
+00:40:11,520 --> 00:40:13,900
+aluminum بتفعل مع ال EDTA اذا millimol aluminum
+
+526
+00:40:13,900 --> 00:40:18,600
+تساوي millimol EDTA لكن انا المسألة بدهاش millimol
+
+527
+00:40:18,600 --> 00:40:23,070
+aluminum بدهاش percentage aluminum بدها ايه؟بدها
+
+528
+00:40:23,070 --> 00:40:28,990
+percentage AL2O3 عشانك بقول اتنين الومنام ابتعطيني
+
+529
+00:40:28,990 --> 00:40:32,270
+الومنام اتنين او تلاتة معايا نفس الكلام اللي
+
+530
+00:40:32,270 --> 00:40:36,070
+شوفناه بالمثال السابق يبقى ال minimum الومنام ايش
+
+531
+00:40:36,070 --> 00:40:40,930
+بيساوي ضعف ال minimum الومنام 2O3 طب بعوض هذه
+
+532
+00:40:40,930 --> 00:40:44,350
+minimum الومنام وهذه minimum الومنام بعوض هي بحط
+
+533
+00:40:44,350 --> 00:40:47,690
+هذا محل ال minimum الومنام تصير اتنين في ال
+
+534
+00:40:47,690 --> 00:40:53,510
+minimum الومنام 2O3 بتساوي minimum ال EDTA هيهذا
+
+535
+00:40:53,510 --> 00:40:58,350
+بده يساوي هذا الان مدام وصلت لهذه المرحلة بقدر
+
+536
+00:40:58,350 --> 00:41:04,520
+بسهولة اقول بدي اعوض عنالملي مول ايش عوض عن الملي
+
+537
+00:41:04,520 --> 00:41:07,260
+مول؟ يا اما مولارتي في ال volume يا اما ملي جرام
+
+538
+00:41:07,260 --> 00:41:11,620
+على الفورمولوات طبعا الملي مول aluminum 203 ملي
+
+539
+00:41:11,620 --> 00:41:16,160
+جرام على الفورمولوات الملي مول EDTA مولارتي اللي
+
+540
+00:41:16,160 --> 00:41:19,560
+حسبناها في ال volume فبيطلع الملي جرام aluminum
+
+541
+00:41:19,560 --> 00:41:26,030
+203 87.1 ملي جرامطبعا ال percentage بده اجسم
+
+542
+00:41:26,030 --> 00:41:29,090
+milligram على milligram عشان هيك لاحظ العينة كانت
+
+543
+00:41:29,090 --> 00:41:33,050
+واحد gram لكن ايش كتبتها؟ واحد فعشرة او ثلاثة او
+
+544
+00:41:33,050 --> 00:41:37,410
+يعني الف milligram لأن هدول اتنين لازم يكونوا نفس
+
+545
+00:41:37,410 --> 00:41:41,320
+الوحدة مانفعش اجسمالـPercentage إجرام صليوط على
+
+546
+00:41:41,320 --> 00:41:46,640
+جرام سامبل في مية من مية أو ملي جرام على ملي جرام
+
+547
+00:41:46,640 --> 00:41:50,140
+في مية من مية نفس الكلام نفس الوحدة كويس يا شباب
+
+548
+00:41:50,140 --> 00:41:56,280
+انا بطل عندي 8.71 بإمكاننا نحل المسألة بالشكل اللي
+
+549
+00:41:56,280 --> 00:41:59,840
+قدامي بخطوة واحدة نعم بإمكاني أحلها بخطوة واحدة
+
+550
+00:41:59,840 --> 00:42:05,180
+لكن بعد ما أجيب تركيز ال EDTA لأنه من غير ما أجيب
+
+551
+00:42:05,180 --> 00:42:10,650
+تركيز ال EDTA ماقدرش أعمل حاجةبنفس الطريقة يا شباب
+
+552
+00:42:10,650 --> 00:42:18,310
+إذا الله راض الحصة الجاية هناخد استكمال لهذا
+
+553
+00:42:18,310 --> 00:42:22,470
+النوع من أنواع الحسابات طول المحاضرة الجاية برضه
+
+554
+00:42:22,470 --> 00:42:28,570
+نفس الكلام تقريبا، أي أسئلة؟ طيب ماعلا كلام،
+
+555
+00:42:28,570 --> 00:42:30,210
+بنشوفكم الحصة الجاية إذا الله راض
+
diff --git a/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/FfysUG1dLFU_raw.srt b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/FfysUG1dLFU_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..2aa0395b1dfae866ccddb4e8d37c76a04ea94d15
--- /dev/null
+++ b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/FfysUG1dLFU_raw.srt
@@ -0,0 +1,1608 @@
+1
+00:00:20,700 --> 00:00:24,260
+بسم الله الرحمن الرحيم طيب عشان بالحصة الماضية كنا
+
+2
+00:00:24,260 --> 00:00:28,920
+بدأنا نتكلم عن ال redox titrations و أخدنا في
+
+3
+00:00:28,920 --> 00:00:34,800
+الآخر مثال على معايرة ال iron 2 باستخدام ال cerium
+
+4
+00:00:34,800 --> 00:00:40,160
+4 وشوفنا كيف ممكن نحسب ال pH after addition of 0
+
+5
+00:00:40,160 --> 00:00:44,440
+ml أو before equivalence pointو بعدين at
+
+6
+00:00:44,440 --> 00:00:48,040
+equivalence point و after equivalence point لكن
+
+7
+00:00:48,040 --> 00:00:52,400
+التفاعل اللى كان عندنا تفاعل ال sirium 4 مع ال
+
+8
+00:00:52,400 --> 00:00:57,740
+iron 2 تفاعل اه equal molar ratios يعني واحد لواحد
+
+9
+00:00:57,740 --> 00:01:00,700
+ال stoichiometric factor واحد في الاتنين يعني
+
+10
+00:01:01,340 --> 00:01:08,520
+فبالتالي يعني حبينا ناخد مثال آخر نعرف فيه كيف
+
+11
+00:01:08,520 --> 00:01:13,120
+ممكن نحسب ال potential في او ل titration after
+
+12
+00:01:13,120 --> 00:01:16,980
+different additions من titrant لكن لما ال
+
+13
+00:01:16,980 --> 00:01:20,840
+stoichiometric coefficients ما تكونش واحد لواحد،
+
+14
+00:01:20,840 --> 00:01:25,760
+اي نسبة أخرى غير الواحد لواحد فاليوم بنتكلم عن
+
+15
+00:01:25,760 --> 00:01:33,530
+معايرة ال permanganateلمحلول iron 2 طبعا كلنا
+
+16
+00:01:33,530 --> 00:01:39,430
+بنعرف ان ال permanganate في acidic medium بتتفاعل
+
+17
+00:01:39,430 --> 00:01:44,910
+مع ال iron 2 plus و بتعطيني manganese 2 plus و
+
+18
+00:01:44,910 --> 00:01:51,870
+iron 3 و طبعا ممكن احنا نجسم معادلة زي هذه لنصين
+
+19
+00:01:51,870 --> 00:01:58,830
+نص عبارة عن ال iron half reaction او half cell
+
+20
+00:01:59,080 --> 00:02:03,040
+والاخر هو عبارة عن ال permanent half reaction او
+
+21
+00:02:03,040 --> 00:02:07,860
+half cell بإمكانه يعرف اذا كان التفاعل هذا بشكل
+
+22
+00:02:07,860 --> 00:02:13,480
+اللي مكتوب ممكن ينتج عنه potential او انه بحاجة ل
+
+23
+00:02:13,480 --> 00:02:17,780
+potential عشان يحصل او بمعنى اخر هل التفاعل زي ما
+
+24
+00:02:17,780 --> 00:02:22,100
+هو مكتوب spontaneous ولا non spontaneous والله اذا
+
+25
+00:02:22,100 --> 00:02:26,360
+كانالـ Potential موجبه فهو spontaneous إذا كان الـ
+
+26
+00:02:26,360 --> 00:02:30,120
+Potential سالبه فهو non spontaneous فطبعا عشان
+
+27
+00:02:30,120 --> 00:02:33,380
+نعرف إذا كان التفاعل بيتم ولا لأ جولنا بنجسم
+
+28
+00:02:33,380 --> 00:02:39,220
+المعادلة لنصين بعدين بنوضع النص اللي قلو ينوت أكبر
+
+29
+00:02:39,220 --> 00:02:43,310
+فوق يعني ال permanganate هتكون فوقوالنص اللي قلو E
+
+30
+00:02:43,310 --> 00:02:46,610
+note أقل تحت يبقى البرمجانات فوق هي بتتفاعل مع ال
+
+31
+00:02:46,610 --> 00:02:50,470
+iron 2 زي ما هو مطوب بإذن التفاعل اللي قدامي هذا
+
+32
+00:02:50,470 --> 00:02:55,970
+ال potential تبعته أكيد potential موجبة والتفاعل
+
+33
+00:02:55,970 --> 00:03:00,690
+spontaneous بمعنى أخر البرمجانات بت exceed ال iron
+
+34
+00:03:00,690 --> 00:03:05,670
+2 والبرمجانات تختزل للمنجانيز 2 plus والiron 2 بت
+
+35
+00:03:05,670 --> 00:03:10,630
+exceed ال iron 3خلّيني أطلع على المثال و نشوف كيف
+
+36
+00:03:10,630 --> 00:03:13,870
+ممكن نحسب ال potential after different additions
+
+37
+00:03:13,870 --> 00:03:19,090
+من البرمجانات على محلول iron المثال بيقول find the
+
+38
+00:03:19,090 --> 00:03:24,150
+electrode potential of a 50 ml of a 0.1 molar
+
+39
+00:03:24,150 --> 00:03:28,010
+solution of iron-2 يعني عندي 50 مل
+
+40
+00:03:30,550 --> 00:03:35,590
+ايرون اتنين بلس بقول after addition of zero five
+
+41
+00:03:35,590 --> 00:03:39,690
+ten and twenty mil of point one molar potassium
+
+42
+00:03:39,690 --> 00:03:44,530
+permanganate ففي عندي permanganate
+
+43
+00:03:46,280 --> 00:03:50,820
+كتائتران بيقول لي at ph1 ليش قال لي at ph1 لأن لو
+
+44
+00:03:50,820 --> 00:03:54,960
+احنا طلعنا على التفاعل بنلاقي فيه عنده H بلس والـ
+
+45
+00:03:54,960 --> 00:03:59,300
+H بلس هذا جزء مكون من مكونات التفاعل فلازم نكون
+
+46
+00:03:59,300 --> 00:04:05,060
+عارفين تركيزه إذا كان بدنا نحسبالـ Potential لازم
+
+47
+00:04:05,060 --> 00:04:08,960
+نكون عارفين تركيز ال H بلس لهذا السبب أعطاني أن ال
+
+48
+00:04:08,960 --> 00:04:12,600
+pH بتساوي 1 بينما في التفاعل اللي أخدنا الحصة
+
+49
+00:04:12,600 --> 00:04:16,280
+الماضية تفاعل ال iron 2 plus مع ال cerium 4 plus
+
+50
+00:04:16,280 --> 00:04:21,470
+ماتكلمناش عن جداش ال pHليه؟ لأن ال pH أو ال H بلس
+
+51
+00:04:21,470 --> 00:04:26,790
+لا تظهر ضمن المعادلة النهائية او اي half cell لا
+
+52
+00:04:26,790 --> 00:04:30,750
+تظهر لكن هان واضح ان ال half cell لل permanganate
+
+53
+00:04:30,750 --> 00:04:36,330
+موجود في H بلس وبالتالي يجب ان اعرف جديش عند ال H
+
+54
+00:04:36,330 --> 00:04:42,550
+بلس علشان اقدر احسب ال potentialطيب يا شباب بدون
+
+55
+00:04:42,550 --> 00:04:48,950
+تأخير نبدأ شغلنا و نحاول نضيف zero mil من ال
+
+56
+00:04:48,950 --> 00:04:52,510
+permanganate بقول عندي bucket zero mil من ال
+
+57
+00:04:52,510 --> 00:04:55,750
+permanganate انا فش عندي الا iron اتنين فش عندي اي
+
+58
+00:04:55,750 --> 00:04:58,870
+permanganate وبالتالي فى عندي بس iron اتنين اذا
+
+59
+00:04:58,870 --> 00:05:02,970
+بدي استخدم معادلة ال iron لحساب ال cell potential
+
+60
+00:05:02,970 --> 00:05:07,470
+او ال solution potential لحساب ال potential لمحلول
+
+61
+00:05:07,470 --> 00:05:14,510
+ال iron اتنين فبقول واللههي اللي بتعطيني قيمة ال
+
+62
+00:05:14,510 --> 00:05:18,370
+potential فبقول E باستخدام معادلة ال iron هيك انا
+
+63
+00:05:18,370 --> 00:05:22,070
+بقراها E باستخدام معادلة ال iron بتساوي ال E note
+
+64
+00:05:22,070 --> 00:05:27,890
+لل iron minus 0.0592 على واحد لأن عدد الإلكترونات
+
+65
+00:05:27,890 --> 00:05:31,650
+في معادلة ال iron واحد log ال iron اتنين على ال
+
+66
+00:05:31,650 --> 00:05:35,970
+iron تلاتة هذا كلام جيبناه من هي معادلة ال iron
+
+67
+00:05:35,970 --> 00:05:41,160
+iron اتنين على ال iron تلاتةعدد الإلكترونات اللي
+
+68
+00:05:41,160 --> 00:05:44,900
+هو إيه هذا pair mole يعني لما أجي أضربها مثلا في
+
+69
+00:05:44,900 --> 00:05:48,740
+تلاتة و هان في تلاتة و هان في تلاتة عدد
+
+70
+00:05:48,740 --> 00:05:54,300
+الإلكترونات واحد مش تلاتةليه؟ لأن الإلكترونات اللي
+
+71
+00:05:54,300 --> 00:05:58,560
+بعيدها أنا per ايه؟ per mole فهي تلاتة على تلاتة
+
+72
+00:05:58,560 --> 00:06:02,480
+يعني واحد مالناش دعوة في داداش دوراب المعادلة
+
+73
+00:06:02,480 --> 00:06:08,680
+دائما عدد الإلكترونات المحسوب per mole للمول اللي
+
+74
+00:06:08,680 --> 00:06:11,420
+بحصل حتى ال E note قيمتها لا تتغير لما نضرب في
+
+75
+00:06:11,420 --> 00:06:14,220
+تلاتة في أربعة في خمسة في ستة ال E note فات لا
+
+76
+00:06:14,220 --> 00:06:18,480
+تتغير ولاتيش قيمة ال E note بتتغير فقط standard
+
+77
+00:06:18,480 --> 00:06:25,100
+التاليف2 بلس بتعطيني ف3 بلس زاد إلكترون يعني عكست
+
+78
+00:06:25,100 --> 00:06:30,080
+المعادلة لما ناقص المعادلة ساعتها نعم ال E note
+
+79
+00:06:30,080 --> 00:06:36,740
+سالب point seven seven one volts بس أما لو ضربت
+
+80
+00:06:36,740 --> 00:06:39,820
+هذه المعادلة في اتنين في تلاتة في أربعة في خمسة في
+
+81
+00:06:39,820 --> 00:06:43,780
+عشرة ال E note بتنضربش في الشيء لأنها قيمة ثابتة
+
+82
+00:06:45,280 --> 00:06:49,740
+أيضًا عدد الإلكترونات per mole ثابت مهما ضربت
+
+83
+00:06:49,740 --> 00:06:54,460
+المعادلة في أي رقم بس هذه معلومة جانبية كويسة لأن
+
+84
+00:06:54,460 --> 00:06:58,760
+في بعض الأحيان ممكن أن يكون فينا اتنين mole من
+
+85
+00:06:58,760 --> 00:07:02,620
+reactant و بقى و بياخدوا اتنين إلكترون فمعناته
+
+86
+00:07:02,620 --> 00:07:05,960
+برضه one electron زي ال
+
+87
+00:07:12,340 --> 00:07:18,500
+الـ S406 اتنين سالب زاد اتنين إلكترون بيعطونا
+
+88
+00:07:18,500 --> 00:07:25,600
+اتنين فيوصلفات فعدد الإلكترونات per mole هو المهم
+
+89
+00:07:25,600 --> 00:07:26,320
+بالنسبة لي
+
+90
+00:07:29,860 --> 00:07:34,440
+بنقول الآن هى المعادلة اللى بدي استخدمها باجب اعوض
+
+91
+00:07:34,440 --> 00:07:38,420
+ال iron اتنين واحد من عشرة ال iron تلاتة مافيش
+
+92
+00:07:38,420 --> 00:07:40,980
+عندي لسه iron تلاتة لإنه ما اضفت اي permanganate
+
+93
+00:07:40,980 --> 00:07:44,180
+after addition of zero مل ما اضفت اي permanganate
+
+94
+00:07:44,180 --> 00:07:48,260
+يبقى ال iron تلاتة هيكون صفر طيب واحد على صفر كمان
+
+95
+00:07:48,260 --> 00:07:53,750
+مرة هيساوي infinity بالسالب صار سالب infinityجمعت
+
+96
+00:07:53,750 --> 00:07:59,250
+لها كمية قليلة جدا 0.7 volt 0.8 volt 0.771 volt
+
+97
+00:07:59,250 --> 00:08:04,320
+بالظبط قمت سالب infinityمعنى هذا الكلام ان ال iron
+
+98
+00:08:04,320 --> 00:08:08,400
+2 plus is a very very very good reducing agent
+
+99
+00:08:08,400 --> 00:08:11,660
+very strong reducing agent which is scientifically
+
+100
+00:08:11,660 --> 00:08:15,580
+incorrect من ناحية العلمية هذا الكلام مش صحيح ليه؟
+
+101
+00:08:15,580 --> 00:08:20,420
+لأن ال iron 2 plus is a mild reducing agent زي ما
+
+102
+00:08:20,420 --> 00:08:23,400
+شفنا في الحصة الماضية اتكلمنا عن هذا الكلام فهو a
+
+103
+00:08:23,400 --> 00:08:26,840
+mild oxidizing agent معنى الكلام بما ان معادلة
+
+104
+00:08:26,840 --> 00:08:29,080
+نيرنس بتعطي قراءة خاطئة
+
+105
+00:08:39,160 --> 00:08:43,620
+بالطبع احنا شفنا في الحصة الماضية ان لو استخدمنا
+
+106
+00:08:43,620 --> 00:08:48,400
+Indicator electrode و Reference electrodeو
+
+107
+00:08:48,400 --> 00:08:52,180
+استخدمنا يعني voltmeter فال voltmeter روح يقرع
+
+108
+00:08:52,180 --> 00:08:56,480
+قيمة معقولة و قولنا هذا كلام مرده لإنه ال iron 3
+
+109
+00:08:56,480 --> 00:09:01,600
+مش صفر في الحقيقة ال iron 3 هو موجود كشوائب في ال
+
+110
+00:09:01,600 --> 00:09:05,020
+iron 2 plus و لو كانت واحد من عشرة او واحد من مية
+
+111
+00:09:05,020 --> 00:09:09,480
+في المية فهو موجود مش صفرهذه أول نقطة والنقطة
+
+112
+00:09:09,480 --> 00:09:13,740
+التانية حتى لو ماكنش موجود وعندي 100% iron 2 أثناء
+
+113
+00:09:13,740 --> 00:09:18,000
+تخضير ال iron 2 لابد إلا إنه يتأكسد جزئيا من
+
+114
+00:09:18,000 --> 00:09:21,700
+الهواء الجوي ع سبيل المثال ويتحول جزء منه لل iron
+
+115
+00:09:21,700 --> 00:09:28,180
+3 في عندي طبعا iron 3 لكن في المحصلة في المحصلة
+
+116
+00:09:28,770 --> 00:09:33,910
+باستخدام نيرنس اكواشن لا يمكن حساب ال potential
+
+117
+00:09:33,910 --> 00:09:38,930
+للمحلول اللي عنده after addition of 0 مل من ال
+
+118
+00:09:38,930 --> 00:09:42,870
+permanganate ماشي يا شباب يبقى نفس ال argument
+
+119
+00:09:42,870 --> 00:09:48,470
+اللي ذكرناها لما نتكلمنا عن تفاعل السيريام 4 مع
+
+120
+00:09:48,470 --> 00:09:51,830
+الايرون 2 after addition of 0 مل سيريام 4 برضه
+
+121
+00:09:51,830 --> 00:09:57,670
+ماكنش عند الايرون 2 نفس الكلام هذا بالظبطقلنا او
+
+122
+00:09:57,670 --> 00:10:03,350
+هو نفسه ممكن نبرر فيه ليش ما نقدر نحسب ال
+
+123
+00:10:03,350 --> 00:10:07,910
+potential after addition of 0 مل من البرمجانات في
+
+124
+00:10:07,910 --> 00:10:13,910
+هذه الحالة طيب نيجي نضيف اي اضافة قبل نقطة النهاية
+
+125
+00:10:13,910 --> 00:10:18,410
+و احنا ماخدين مثال 5 مل من البرمجانات و تعالوا
+
+126
+00:10:18,410 --> 00:10:21,650
+نطلع لأن ال stoichiometry مش واحد لواحد ماقدرش
+
+127
+00:10:21,650 --> 00:10:26,350
+يعني او يعني منمش من الحكمة ان اقول والله ال
+
+128
+00:10:26,350 --> 00:10:29,090
+initial من اللي مول و ال added من اللي مول و اجر
+
+129
+00:10:29,090 --> 00:10:34,410
+اطرح طرح يعني هذا الكلام بيعطيني خليني اقول يعني
+
+130
+00:10:34,410 --> 00:10:37,530
+بغلبني شوية فانا بدي اعمل عدة خطوات و بعدين بدي
+
+131
+00:10:37,530 --> 00:10:43,500
+اعمل من ضمنها ال more relationships لأ باستخدمسطر
+
+132
+00:10:43,500 --> 00:10:48,660
+واحد بس شبيه جدا بال back titration بقول والله
+
+133
+00:10:48,660 --> 00:10:52,880
+الملي مول ايرون ال lift المتبقى جانب النقطة
+
+134
+00:10:52,880 --> 00:10:56,320
+النهائية في عندي ايرون بيزيد ايش بيساوي جانب الله
+
+135
+00:10:56,320 --> 00:11:00,640
+الايرون الكلي ناقص اللي اتفعلناقص ال iron اللي
+
+136
+00:11:00,640 --> 00:11:04,500
+اتفعل يبقى ال iron المتبقي بيساوي ال iron الكلي
+
+137
+00:11:04,500 --> 00:11:08,640
+ناقص ال iron اللي اتفعل المتبقي بيساوي الكلي ناقص
+
+138
+00:11:08,640 --> 00:11:13,640
+اللي اتفعل كويس بقول طيب هو اتفعل مع ايه بس اذكركم
+
+139
+00:11:13,640 --> 00:11:19,680
+هاي التفاعل per منجانات زائد خمسة iron اتنين plus
+
+140
+00:11:19,680 --> 00:11:26,340
+زائد تمانية H plus منجانيز اتنين plus زائد خمسة
+
+141
+00:11:27,940 --> 00:11:33,120
+Iron تلاتة زائد أربعة مية فهو اتفاعل مع ال iron
+
+142
+00:11:33,120 --> 00:11:33,840
+اتنين
+
+143
+00:11:36,330 --> 00:11:40,910
+دقيقش الـ Millimole Iron اللي اتفاعله أكم بالنسبة
+
+144
+00:11:40,910 --> 00:11:44,170
+لـ Millimoles per Mengane خمس أمثال البرمنجانات
+
+145
+00:11:44,170 --> 00:11:48,170
+صحيح إذا انت عوض عن الـ Iron reacted بخمسة
+
+146
+00:11:48,170 --> 00:11:52,190
+Millimoles per Mengane خمس أمثاله خمسة Millimoles
+
+147
+00:11:52,190 --> 00:11:55,270
+per Mengane بعدين بقول والله point one في خمسين
+
+148
+00:11:55,270 --> 00:11:59,310
+هذا الكل ناقص اللي اتفاعل خمس أمثال Millimoles per
+
+149
+00:11:59,310 --> 00:12:03,720
+Mengane يبقى خمسة فيه0.1 في خمسة ملي لتر هذا
+
+150
+00:12:03,720 --> 00:12:07,480
+بيعطينا الميلي مول البرامينجانات وبالتالي بحصل على
+
+151
+00:12:07,480 --> 00:12:11,760
+الميلي مول ايرون لفت اتنين و نص اذا تركيز الايرون
+
+152
+00:12:11,760 --> 00:12:16,130
+اتنين اتنين و نص على خمسين و خمسة خمسة و خمسينطيب
+
+153
+00:12:16,130 --> 00:12:20,150
+انا كان عندي خمسة millimoles ايرون اتنين plus في
+
+154
+00:12:20,150 --> 00:12:23,050
+اتنين و نص بايلين زي ما هم ايرون اتنين plus طب وين
+
+155
+00:12:23,050 --> 00:12:26,230
+راحوا الاتنين و نص ال بايلين؟ اه اذا ال millimoles
+
+156
+00:12:26,230 --> 00:12:29,410
+ايرون تلاتة form برضه اتنين و نص لأن مجموع هدول
+
+157
+00:12:29,410 --> 00:12:37,170
+الاتنين دائما بدي يساوي الخمسة لازم اذا بقدر اقول
+
+158
+00:12:37,170 --> 00:12:40,550
+تركيز ال ايرون تلاتة اتنين و نص على خمسة و خمسين
+
+159
+00:12:41,770 --> 00:12:44,990
+الان صار في عندي Redox couple ايرن اتنين ايرن
+
+160
+00:12:44,990 --> 00:12:49,070
+تلاتة معادلة الايرن يعني موجودة كل مكوناتها موجودة
+
+161
+00:12:49,070 --> 00:12:52,310
+ايرن اتنين وايرن تلاتة بقدر استخدم معادلة الايرن
+
+162
+00:12:52,310 --> 00:12:56,800
+لحساب ال solution potentialفنقول بالله ال E بتساوي
+
+163
+00:12:56,800 --> 00:13:03,040
+ال E نوت لل iron minus 0.0592 على واحد log ال iron
+
+164
+00:13:03,040 --> 00:13:06,500
+اتنين اتنين و نص على خمس و خمسين على ال iron تلاتة
+
+165
+00:13:06,500 --> 00:13:09,140
+اتنين و نص على خمس و خمسين بما ان ال log ال واحد
+
+166
+00:13:09,140 --> 00:13:15,480
+صفر اذا ال E بتساوي ال E نوت بتساوي 0.771 وهذه
+
+167
+00:13:15,480 --> 00:13:20,940
+ملاحظة كتير مهمة لان انا لما انا ارسم ال mill
+
+168
+00:13:20,940 --> 00:13:29,930
+برمجاناتمع ال a راح أحصل على حاجة زي هي فبقول انا
+
+169
+00:13:29,930 --> 00:13:36,690
+اذا كان استخدمت حجم نص الحجمالحجم اللازم للـ
+
+170
+00:13:36,690 --> 00:13:39,230
+equivalence point هذا الحجم اللازم للـ equivalence
+
+171
+00:13:39,230 --> 00:13:47,150
+point طب نصه عند نص الحجم جال عند هذا الحجم ال E
+
+172
+00:13:47,150 --> 00:13:53,030
+بتساوي ال E note إذا لو كان عندي تفاعل أنا بعرفش
+
+173
+00:13:53,030 --> 00:13:57,110
+ال E note تبعه بعرفش ال E note تبعه روحت عيرته
+
+174
+00:13:57,110 --> 00:14:00,530
+عملت معايرة فعرفت وين ال equivalence point جداش
+
+175
+00:14:00,530 --> 00:14:06,330
+بتاخد حجم عند نص الحجمالنازم لل equivalence point
+
+176
+00:14:06,330 --> 00:14:11,550
+عن نص الحجم بالظبط ال a بتساوي ال a نوتزي ما كنا
+
+177
+00:14:11,550 --> 00:14:17,370
+بنقول في ال acid-base equilibrium ال pH بيساوي ال
+
+178
+00:14:17,370 --> 00:14:21,410
+PKA1 او ال PKA1 فيها عندنا بس ال E بتساوي ال E
+
+179
+00:14:21,410 --> 00:14:26,430
+note اذا عند نص الحجم اللازم له نقطة النهاية انا
+
+180
+00:14:26,430 --> 00:14:28,390
+هلاحظ بعد شوية ان الحجم اللازم له نقطة النهاية
+
+181
+00:14:28,390 --> 00:14:33,330
+عشرة عند خمسة عند النص ال E ايش طلعت معناه بتساوي
+
+182
+00:14:33,330 --> 00:14:37,790
+ال E note اذا انا لو مش عارف ال E noteبقدر اعمل
+
+183
+00:14:37,790 --> 00:14:42,230
+معايرة اعرف وين بالظبط ال .. وين ال equivalence
+
+184
+00:14:42,230 --> 00:14:45,670
+point جداش اخدت حجم او النص الحجم بشوف ال
+
+185
+00:14:45,670 --> 00:14:49,530
+potential المناظرة بتكون هي ال E note وهذا يعني
+
+186
+00:14:49,530 --> 00:14:53,590
+شيء ممتاز جدا بخليني احسب ال E note من غير ما
+
+187
+00:14:53,590 --> 00:14:58,650
+استخدم لا SHE ولا reference electrode بقدر مباشرة
+
+188
+00:14:58,650 --> 00:15:04,860
+من ال titration curve احسب ال E noteماشي يا شباب
+
+189
+00:15:04,860 --> 00:15:10,740
+بهذه الطريقة بضل نحسب قبل نقطة النهاية قبل نقطة
+
+190
+00:15:10,740 --> 00:15:15,520
+النهاية نفس الشكل و نفس الطريقة اللي قدامي نيجي
+
+191
+00:15:15,520 --> 00:15:19,460
+نطلع عند نقطة النهاية اللي هو after addition of 10
+
+192
+00:15:19,460 --> 00:15:23,460
+mil من البرمجانات بقول نفس الكلام milli mole iron
+
+193
+00:15:23,460 --> 00:15:26,840
+left المتبق من ال iron بساوي الكل من ال iron نقص
+
+194
+00:15:26,840 --> 00:15:32,070
+ال iron اللي اتفاعلطيب ايه اللي اتفعل اتفعل معايش
+
+195
+00:15:32,070 --> 00:15:35,230
+اتفعل معاه ال permanganate اذا ال millimole iron
+
+196
+00:15:35,230 --> 00:15:38,070
+خمس امثال ال permanganate نفس الكلام اللي شفناه
+
+197
+00:15:38,070 --> 00:15:42,330
+سابقة خمس خمسة millimole permanganate اذا بقول
+
+198
+00:15:42,330 --> 00:15:45,030
+والله انا عند ال initial millimole point one في
+
+199
+00:15:45,030 --> 00:15:50,390
+خمسين يعني خمسة minus الخمسة هذه هي هي تركيز ال
+
+200
+00:15:50,390 --> 00:15:55,130
+permanganate point one عشرة mil اذا بعطينا صفر صفر
+
+201
+00:15:55,130 --> 00:16:00,150
+صفرمعناته ايه؟ this is the equivalence point طب
+
+202
+00:16:00,150 --> 00:16:04,970
+كيف انا بشتغل at equivalence point؟ قال اه بقدرش
+
+203
+00:16:04,970 --> 00:16:09,230
+استخدم معادلة ال permanganate لأنه تركيز ال
+
+204
+00:16:09,230 --> 00:16:14,170
+permanganate صفر و اي محلول
+
+205
+00:16:14,610 --> 00:16:19,470
+أحد مكوناته الاكوليبريا و صفر لا يمكن استخدام
+
+206
+00:16:19,470 --> 00:16:23,090
+ناناستيكواشن زي ما شوفنا لحساب ال potential إذا لا
+
+207
+00:16:23,090 --> 00:16:28,850
+يمكن استخدام ال permanent half cell reaction عشان
+
+208
+00:16:28,850 --> 00:16:32,030
+أحسب ال potential طب نجيب نستخدم ال iron ده اللي
+
+209
+00:16:32,030 --> 00:16:36,660
+هو ال iron 2 برضه صفرلأنه at equivalence point
+
+210
+00:16:36,660 --> 00:16:40,640
+البرمجانية اتخلصت والايرون اتنين كمان خلصت اذا
+
+211
+00:16:40,640 --> 00:16:45,400
+برضه لا يمكن استخدام معادلة الايرون half cell
+
+212
+00:16:45,400 --> 00:16:49,500
+لحساب ال potential at equivalence point وقلنا احنا
+
+213
+00:16:49,500 --> 00:16:54,400
+دائما في حالة ال redox titrations عشان اجيب ال
+
+214
+00:16:54,400 --> 00:16:57,280
+potential at equivalence point لازم اجمع
+
+215
+00:16:57,280 --> 00:17:03,690
+المعادلتين فكتبت المعادلتين وهيني الآن باجمعهمبقول
+
+216
+00:17:03,690 --> 00:17:07,570
+ايه طبعا في المحلول احنا لما نكون فيه عندنا
+
+217
+00:17:07,570 --> 00:17:12,510
+equivalence point او في اي محلول بيكون شئ له اكتر
+
+218
+00:17:12,510 --> 00:17:16,430
+من potential دائما one single potential سواء
+
+219
+00:17:16,430 --> 00:17:20,910
+استخدمنا ال iron لحسابها او ال permanganate نفس
+
+220
+00:17:20,910 --> 00:17:25,270
+الكلامنفس الكلام دائما المحلول issue الهدوء بتفعل
+
+221
+00:17:25,270 --> 00:17:28,690
+و في النهاية بيصير محلول موقّد له تركيبة معينة
+
+222
+00:17:28,690 --> 00:17:33,030
+فهذه التركيبة هي potential معينة فبقول at
+
+223
+00:17:33,030 --> 00:17:37,050
+equivalence point ال E اللي بحسبها من ال permanent
+
+224
+00:17:37,050 --> 00:17:39,250
+genetic عبارة عن E at equivalence point و at
+
+225
+00:17:39,250 --> 00:17:41,890
+equivalence point برضه ال E اللي بحسبها من الirony
+
+226
+00:17:41,890 --> 00:17:46,880
+عبارة عن E at equivalence pointفبكتب ال E
+
+227
+00:17:46,880 --> 00:17:52,340
+equivalence بتساوي E not minus 0.0592 على خمسة log
+
+228
+00:17:52,340 --> 00:17:55,880
+المنجانيز على ال permanganate في ال H plus أس
+
+229
+00:17:55,880 --> 00:18:01,100
+تمانية هذه المعادلة ماحدش ينسى ال H plus ال H plus
+
+230
+00:18:01,100 --> 00:18:05,460
+مكون من مكونات ال equilibrium ال E at equivalence
+
+231
+00:18:05,460 --> 00:18:09,480
+point باستخدام معالجة ال iron بتساوي 0.0592 على
+
+232
+00:18:09,480 --> 00:18:13,800
+واحد log ال iron اتنين على ال iron تلاتة بقول انا
+
+233
+00:18:15,320 --> 00:18:21,000
+والله إذا كان بدي أجمع المعادلتين هدول لازم أضيع
+
+234
+00:18:21,000 --> 00:18:24,180
+المقام
+
+235
+00:18:24,180 --> 00:18:26,940
+كيف بني أضيعه؟ هان بضرب في واحد و في واحد لأنه هاد
+
+236
+00:18:26,940 --> 00:18:30,220
+بواحد هان هاد بخمسة بضرب هان في خمسة و هان في خمسة
+
+237
+00:18:30,220 --> 00:18:34,460
+إذا سارة هندي خمسة equivalent point زائد واحد E at
+
+238
+00:18:34,460 --> 00:18:38,440
+equivalent point بدها تساوي خمسة E naught
+
+239
+00:18:38,440 --> 00:18:44,260
+للبرمجانات زائد واحد E naught للiron minus 0.0592
+
+240
+00:18:44,260 --> 00:18:44,920
+log
+
+241
+00:18:50,650 --> 00:18:56,590
+هذا log هذا زائد log هذا مجموعهم هو عبارة عن log
+
+242
+00:18:56,590 --> 00:19:00,250
+المنجانيز اتنين plus ايرون اتنين plus على الائرون
+
+243
+00:19:00,250 --> 00:19:04,210
+تلاتة plus في المنجانات سالب اتش plus اص تمانية
+
+244
+00:19:04,210 --> 00:19:08,890
+جامع عادي جامع عادي البسط بحطه في البسط و المقام
+
+245
+00:19:08,890 --> 00:19:12,830
+في المقام مدام وحط المقامات خلت هذه على واحد وهذه
+
+246
+00:19:12,830 --> 00:19:18,240
+على واحد يمكن انا اخد minus 0.0592 عامل مشتركبعدين
+
+247
+00:19:18,240 --> 00:19:22,600
+باخد ال log بطلع عندي log iron 2 على ال iron 3
+
+248
+00:19:22,600 --> 00:19:28,720
+زائد log منجنيز 2 على permanganate في ال H plus of
+
+249
+00:19:28,720 --> 00:19:35,220
+8 لما بتقول log كذا زائد log كذا هذا كلام الجامع
+
+250
+00:19:35,220 --> 00:19:39,540
+بتحول لضرب برفع ال log و بكون قيمة مضروبة فبطلع
+
+251
+00:19:39,540 --> 00:19:44,720
+عندي هذه القيمة حاضر
+
+252
+00:19:45,860 --> 00:19:53,420
+خلّيني أعملك هذا الكلام، مافي مشكلة أنا عندي E at
+
+253
+00:19:53,420 --> 00:19:58,020
+equivalence point بتساوي E0 للبرمجانات minus 0
+
+254
+00:19:58,020 --> 00:20:06,680
+.0592 على خمسة log منجانيز اتنين plus على برمجانات
+
+255
+00:20:08,300 --> 00:20:13,120
+H بلس أس تمانية صحيح هذا من ال permanganate وعندي
+
+256
+00:20:13,120 --> 00:20:20,100
+كمان انا بدى بيع الخمسة هذه ايش بعمل فيها بضرب هذا
+
+257
+00:20:20,100 --> 00:20:23,720
+كله في خمسة في خمسة و هذا في خمسة على خمسة بتروح
+
+258
+00:20:23,720 --> 00:20:29,340
+الخمسة وبرضه عندي E at equivalence point بيتساوي E
+
+259
+00:20:29,340 --> 00:20:34,240
+not لل iron minus 0.0592 على واحد على واحد يعني
+
+260
+00:20:34,240 --> 00:20:41,180
+ولا اي شيlog iron 2 plus على iron 3 plus الان هدول
+
+261
+00:20:41,180 --> 00:20:46,480
+بدي أجمعهم خمسة واحد ستة E at equivalence point صح
+
+262
+00:20:46,480 --> 00:20:51,040
+بدها تساوي high ghost لهدول خمسة E naught
+
+263
+00:20:51,040 --> 00:20:58,580
+للمنجانيز زائد E naught للiron minus 0.0592 log
+
+264
+00:20:59,080 --> 00:21:02,860
+البس بس و المقام مقام على طول مانجانيز اتنين هيها
+
+265
+00:21:02,860 --> 00:21:06,720
+زي ما هي مانجانيز اتنين ايرون اتنين فوق هيها ايرون
+
+266
+00:21:06,720 --> 00:21:12,960
+اتنين plus على تحت بيرمينجانيت هي بيرمينجانيت تحت
+
+267
+00:21:12,960 --> 00:21:16,520
+H plus از تمانية هي H plus از تمانية تحت ايرون
+
+268
+00:21:16,520 --> 00:21:22,720
+تلاتة هي ايرون تلاتة خد بالك يعني جمع سهل جدا
+
+269
+00:21:22,720 --> 00:21:27,530
+مباشر على طولبعدين ايش بنقول؟ بنقول كلام مهم جدا
+
+270
+00:21:27,530 --> 00:21:32,770
+بنقول لازم اعوض في المعادلة هذه يا بدل يا اضاء على
+
+271
+00:21:32,770 --> 00:21:36,850
+ال iron بدلالة اللي بتفعل معاها المنجانيز يا اما
+
+272
+00:21:36,850 --> 00:21:41,030
+ال permanganate او ال iron تلاتة اللي هو المنجانيز
+
+273
+00:21:41,030 --> 00:21:44,910
+بدي اعوض عنهم يا اما بعوض على المنجانيز بال iron
+
+274
+00:21:44,910 --> 00:21:48,670
+تلاتة و بعوض على ال permanganate بال iron اتنين
+
+275
+00:21:48,670 --> 00:21:54,850
+سيان اي واحدة لأن ان عندي ال iron اتنينهيو بدي
+
+276
+00:21:54,850 --> 00:21:58,850
+ساوي خمسة تركيز ال permanganate طب و ال iron تلاتة
+
+277
+00:21:58,850 --> 00:22:03,990
+بدي ساوي خمسة تركيز ال ايه؟ المنجانيز ال iron
+
+278
+00:22:03,990 --> 00:22:08,650
+تلاتة بدي ساوي خمسة تركيز ال ايه؟ المنجانيز ممكن
+
+279
+00:22:08,650 --> 00:22:11,270
+اقول والله ال permanganate بتساوي خمس ال iron و
+
+280
+00:22:11,270 --> 00:22:14,170
+المنجانيز اتنين بتساوي خمس ال iron تلاتة و اعوض
+
+281
+00:22:14,170 --> 00:22:20,010
+عنهمها نفس الكلام فانا لما اجي اعوض بقول هاي عندي
+
+282
+00:22:20,010 --> 00:22:26,530
+كان هان ايه؟ايرون اتنين plus ايش عوّط عنه؟ خمسة
+
+283
+00:22:26,530 --> 00:22:31,710
+permanganate وكان تحت مانجانيز ايرون تلاتة plus
+
+284
+00:22:31,710 --> 00:22:36,650
+ايش عوّط عنه؟ خمسة مانجانيز طب هي المانجانيز مع
+
+285
+00:22:36,650 --> 00:22:40,950
+المانجانيز وهي ال permanganate مع ال permanganate
+
+286
+00:22:40,950 --> 00:22:47,640
+وهي كمان الخمسة مع الخمسة ايش زاد؟H بلس أس تمانية
+
+287
+00:22:47,640 --> 00:22:51,600
+في المقعد H بلس أس تمانية في المقعد باجب عوّب أنا
+
+288
+00:22:51,600 --> 00:22:56,900
+ستة E at equivalence point بدها تساوي خمسة في one
+
+289
+00:22:56,900 --> 00:22:59,560
+point five one اللي هي ال E naught للبرمجانيات
+
+290
+00:22:59,560 --> 00:23:02,600
+زائد point seven seven one اللي هي ال E naught
+
+291
+00:23:02,600 --> 00:23:05,120
+للiron minus point zero five nine two اللي هو
+
+292
+00:23:05,120 --> 00:23:09,750
+الواحد على point one أس تمانيةكلهم معاه ال E at
+
+293
+00:23:09,750 --> 00:23:13,570
+equivalence point تطلع 1.31 يبقى ال E at
+
+294
+00:23:13,570 --> 00:23:20,050
+equivalence point 1.31 ماشي يا شباب هذه هي طريقة
+
+295
+00:23:20,050 --> 00:23:24,050
+الحسابات بغض النظر إيش بتفعل مع إيش يعني ممكن أنا
+
+296
+00:23:24,050 --> 00:23:28,010
+بدل ما أجيبك ال iron أجيبك حاجة زي ال oxalic acid
+
+297
+00:23:28,010 --> 00:23:33,330
+كويس ال oxalic acid بدل ما هو ال iron إلكترون واحد
+
+298
+00:23:33,330 --> 00:23:35,370
+ال oxalic acid two electrons مثلا
+
+299
+00:23:38,130 --> 00:23:41,570
+بدل ما يجيبلك ال permanganate ممكن يجيبلك ال
+
+300
+00:23:41,570 --> 00:23:47,390
+biochromate بدل ما هو خمس إلكترونات ست إلكترونات و
+
+301
+00:23:47,390 --> 00:23:53,990
+هي كذا سهل كتير بدل ما يجيبلك مثلا ال permanganate
+
+302
+00:23:53,990 --> 00:23:59,700
+يجيبلك ال iodine ال iodine اتنين إلكترونماشي الحال
+
+303
+00:23:59,700 --> 00:24:04,000
+يعني سهل كتير انت دائما استخدم نفس المفاهيم اللي
+
+304
+00:24:04,000 --> 00:24:07,640
+بتتعلمها جول دائما قبل نقطة النهاية لعند نقطة
+
+305
+00:24:07,640 --> 00:24:12,900
+النهاية millimole iron lift او millimole analyte
+
+306
+00:24:12,900 --> 00:24:16,420
+lift بساوي ال analyte كله ناقص ال analyte اللي
+
+307
+00:24:16,420 --> 00:24:21,020
+اتفاعل هو اتفاعل مع ايش المواد العين ده بتعود عدد
+
+308
+00:24:21,020 --> 00:24:25,480
+المواد ايش اللي بينظرها من عدد المواد اللي اتفاعل
+
+309
+00:24:25,480 --> 00:24:31,560
+معاها و هكذا يبقىالحسابات لغاية ال equivalence
+
+310
+00:24:31,560 --> 00:24:39,980
+point حسابات منطقية سهلة كتير النقطة
+
+311
+00:24:39,980 --> 00:24:41,800
+عند ال equivalence point هي انك تعرف ايش بيساوي
+
+312
+00:24:41,800 --> 00:24:47,340
+ايش وهذا كلام من وين بتجيبه من المعادلة مباشرة طيب
+
+313
+00:24:47,340 --> 00:24:52,540
+خلينا نضيف حاجة بعد ال equivalence pointخلينا نضيف
+
+314
+00:24:52,540 --> 00:24:57,200
+حاجة بعد ال equivalence point يعني عندما يكون
+
+315
+00:24:57,200 --> 00:25:00,820
+عندنا excess من ال titan فساعتها ماحدش طبعا بيقدر
+
+316
+00:25:00,820 --> 00:25:05,080
+يقول الان اكتب millimole iron left لأنه خلص بال
+
+317
+00:25:05,080 --> 00:25:07,640
+equivalence point خلص ولا ضايف ازيادة من ال
+
+318
+00:25:07,640 --> 00:25:10,900
+permanganate بدي اقول millimole permanganate
+
+319
+00:25:10,900 --> 00:25:15,260
+excess ازيادة بساوي قال والله ال permanganate الكل
+
+320
+00:25:17,230 --> 00:25:20,050
+يعني الملي مول البرمجانات قاعدة بناقص الملي مول
+
+321
+00:25:20,050 --> 00:25:23,710
+البرمجانات اللي اتفاعل طب هو اتفاعل مع ايه؟ اتفاعل
+
+322
+00:25:23,710 --> 00:25:27,950
+مع ال iron طب ايش بيساوي الملي مول البرمجانات؟ خمس
+
+323
+00:25:27,950 --> 00:25:31,010
+ال iron واطلع طب يعني ال iron بيساوي خمس امثال
+
+324
+00:25:31,010 --> 00:25:34,530
+البرمجانات انا بتعود على البرمجانات خمس ال iron
+
+325
+00:25:35,230 --> 00:25:38,770
+فبقول والله يبقى الميلي مول البرمجانات reacted خمس
+
+326
+00:25:38,770 --> 00:25:41,950
+الميلي مول ايرون اذا الميلي مول البرمجانات excess
+
+327
+00:25:41,950 --> 00:25:45,430
+بدي سبع ميلي مول البرمجانات added ناقص خمس الميلي
+
+328
+00:25:45,430 --> 00:25:49,730
+مول ايرون ال added point one في عشرين قاللي اتفت
+
+329
+00:25:49,730 --> 00:25:53,230
+عشرين ميل وتركيز واحد من عشرة اذا point one في
+
+330
+00:25:53,230 --> 00:25:58,570
+عشرين minus الخمس هذه هي هي في جداش عندي ال iron
+
+331
+00:25:58,570 --> 00:26:03,570
+point one في خمسين اذا بيزيد واحد ميلي مول من
+
+332
+00:26:03,570 --> 00:26:08,570
+البرمجاناتبيزيد واحد ملي مول من البرمجانات انا كان
+
+333
+00:26:08,570 --> 00:26:13,390
+عندى اكمل برمجانات اكمل فى القصر انا عندى
+
+334
+00:26:13,390 --> 00:26:17,470
+البرمجانات الكلية جداش اتنين point one في عشرين
+
+335
+00:26:17,470 --> 00:26:21,290
+زاد واحد منهم طب وين راح الواحد التانى مانجانيز
+
+336
+00:26:21,290 --> 00:26:24,610
+اتنين plus اذا الملي مول مانجانيز اتنين plus
+
+337
+00:26:24,610 --> 00:26:29,230
+formed واحد ممكن كمان انت تجيب المانجانيز اتنين
+
+338
+00:26:29,230 --> 00:26:35,350
+plus ال formed هو عبارة عن ايه شايهكل خمسة بيعطوا
+
+339
+00:26:35,350 --> 00:26:40,170
+واحد يبقى الميلي مول مانجانيز خمس الايرون الايرون
+
+340
+00:26:40,170 --> 00:26:42,750
+عندك خمس ميلي مول يبقى المانجانيز اتنين بلس اللي
+
+341
+00:26:42,750 --> 00:26:47,490
+اتكون عبارة عن واحد لانه خمس الايرون وممكن تقول ان
+
+342
+00:26:47,490 --> 00:26:50,730
+البرمجانات عندنا اتنين واحد ضاله برمجانات يبقى
+
+343
+00:26:50,730 --> 00:26:55,620
+التاني اتحول لايه لمانجانيز اتنين بلس سيئاسيّه زي
+
+344
+00:26:55,620 --> 00:26:59,000
+ما بتحب اعمل فعندي انا بما انه هاد واحد من اللي
+
+345
+00:26:59,000 --> 00:27:03,040
+مول اذا الفيرمنجانات واحد على عشرين وخمسين سبعين
+
+346
+00:27:03,040 --> 00:27:07,560
+والمنجانيز اتنين plus واحد اذا واحد على خمسين
+
+347
+00:27:07,560 --> 00:27:12,280
+وعشرين مجا سبعين باجي بقول لا يمكن استخدام معادلة
+
+348
+00:27:12,280 --> 00:27:16,680
+ال iron لان لان ال iron اتنين بسوا صفر من ناحية
+
+349
+00:27:16,680 --> 00:27:21,410
+حسابية نظرية بسوا صفرفلا يمكن استخدام معادلة ال
+
+350
+00:27:21,410 --> 00:27:24,750
+iron لكن هو طبعا بسويس صفر بالظبط لكن لو كنا
+
+351
+00:27:24,750 --> 00:27:28,750
+عارفين جداش iron بالظبط iron 3 او iron 2 مابنر
+
+352
+00:27:28,750 --> 00:27:32,670
+استخدم معادلة ال iron لكن مش موجود عندى و هتعطيني
+
+353
+00:27:32,670 --> 00:27:36,330
+نفس القيمة اللى بعطيها لليه ال fermentganateلكن مش
+
+354
+00:27:36,330 --> 00:27:40,690
+موجود عندي فبستخدم معادلة البرمجانات لإن عندي
+
+355
+00:27:40,690 --> 00:27:44,730
+برمجانات وعندي مانجانيز 2 plus و ال H plus معروفة
+
+356
+00:27:44,730 --> 00:27:48,930
+لإن أنا بشتغل عن ال PH1 فبستخدم معادلة البرمجانات
+
+357
+00:27:48,930 --> 00:27:54,110
+ال E بتساوي E نقطة البرمجانات reaction هفصل 0.0592
+
+358
+00:27:54,110 --> 00:27:57,930
+على 5 لجد المانجانيز 2 plus في البرمجانات على
+
+359
+00:27:57,930 --> 00:28:03,480
+البرمجانات في ال H plus قص 8يبقى الـ E بتساوي 1.51
+
+360
+00:28:03,480 --> 00:28:07,800
+هي الـ E نوت minus 0.0592 على خمسة هي عدد
+
+361
+00:28:07,800 --> 00:28:13,260
+الإلكترونات log ميجانيز الـ 2 plus 1 على سبعين per
+
+362
+00:28:13,260 --> 00:28:17,380
+ميجانيز 1 على سبعين each plus 1 من عشرة قصة تمانية
+
+363
+00:28:17,380 --> 00:28:23,800
+طبعا حسب عدد المولات فالـ E بتطلع 1.42 volts الـ E
+
+364
+00:28:23,800 --> 00:28:30,790
+بتساوي 1.42 volts أي قيمة بنضيفهابعد نقطة النهاية
+
+365
+00:28:30,790 --> 00:28:34,290
+يعني أكتر من عشرة مل بنفس الطريقة اللى جدامى أي
+
+366
+00:28:34,290 --> 00:28:38,450
+قيمة بنضيفها بعد نقطة النهاية يعني أكتر من عشرة مل
+
+367
+00:28:38,450 --> 00:28:44,890
+معناته بنفس الطريقة اللى جدامى واضح الكلام هذه يا
+
+368
+00:28:44,890 --> 00:28:51,550
+شباب طيب احنا بنقول انه هيك بنكون خلصنا حاجة اسمها
+
+369
+00:28:51,550 --> 00:28:59,780
+Redox Titrationsو هيك كمان بشكل أساسي بنكون خلصنا
+
+370
+00:28:59,780 --> 00:29:06,280
+المساق المتعلق بالكيميا
+
+371
+00:29:06,280 --> 00:29:10,520
+التحليلية بتمنى
+
+372
+00:29:10,520 --> 00:29:16,940
+ان شاء الله انه نكون استفدنا واستوعبنا يعني
+
+373
+00:29:16,940 --> 00:29:22,840
+المفاهيم الأساسية لهذا العلم و زي ما شفنا يعني
+
+374
+00:29:25,210 --> 00:29:29,890
+كان قدامي بس احد حاجتين او اي مسألة من المسائل
+
+375
+00:29:29,890 --> 00:29:34,490
+كانت بتنحل باحد مفهومين لازم يكون المفهومين في
+
+376
+00:29:34,490 --> 00:29:37,170
+بالي اذا كان مادة quantitative او تفاعل
+
+377
+00:29:37,170 --> 00:29:41,330
+quantitative فلازم استخدم ال millimole concept
+
+378
+00:29:41,330 --> 00:29:44,950
+والmillimole كان يا اما molarity of volume يا اما
+
+379
+00:29:44,950 --> 00:29:47,970
+milligram على ال formula وانتهينا خلاص الحاجة
+
+380
+00:29:47,970 --> 00:29:51,810
+التانيةإذا كان عندي equilibrium فلازم أستخدم ال
+
+381
+00:29:51,810 --> 00:29:55,690
+equilibrium constant وحسب قيمة ال equilibrium
+
+382
+00:29:55,690 --> 00:30:01,610
+constant بحدد طريقة الحل كل الحل كان بيفترض أنه ال
+
+383
+00:30:01,610 --> 00:30:05,510
+equilibrium constant صغير وبالتالي ال reactants
+
+384
+00:30:05,510 --> 00:30:09,990
+بتقل بمقدار كمية قليلة إلا chapter واحد بس اللي هو
+
+385
+00:30:09,990 --> 00:30:15,210
+ال complex symmetric reactions اللي كان في ال KF
+
+386
+00:30:15,210 --> 00:30:19,200
+كبير وبالتالي بفترض أنهكل المتفاعل يتحول لنواتج
+
+387
+00:30:19,200 --> 00:30:24,440
+إلا جزء قليل بيظلوا متفاعلات هذا كل ال course اللي
+
+388
+00:30:24,440 --> 00:30:29,180
+احنا درسنا لو حطيت هذا في بالك و يعني و حليت
+
+389
+00:30:29,180 --> 00:30:35,760
+الأمثلة اللي أخدناها اطلعت على ال home works و
+
+390
+00:30:35,760 --> 00:30:38,980
+قعدت حلها و حصلت على نفس النتائج و حلها بنفس
+
+391
+00:30:38,980 --> 00:30:46,480
+الطريقةاتطلعت على الاختبارات و برضه عيد حلها و
+
+392
+00:30:46,480 --> 00:30:51,160
+حلها بنفس الطريقة اللي انا حللها فيها يكون في عندك
+
+393
+00:30:51,160 --> 00:30:58,120
+يعني حصيلة ممتازة للنهائي بالاضافة لإن بعض الشباتر
+
+394
+00:30:58,120 --> 00:31:03,740
+أو الأجزاء اللي ماخدناش فيها واجبات ياريت انك يعني
+
+395
+00:31:03,740 --> 00:31:07,040
+اتراجعها و تحاول انك تتطلع على الأمثلة اللي
+
+396
+00:31:07,040 --> 00:31:10,600
+حللناها في الحصة او اللي في الكتاببرضه هذا الكلام
+
+397
+00:31:10,600 --> 00:31:15,200
+بيفيدك بشكل كبير بتمنى ان شاء الله انه يعني الطلاب
+
+398
+00:31:15,200 --> 00:31:18,680
+اللى مستجلين او اللى يعني عندهم تحديد آل الفصل
+
+399
+00:31:18,680 --> 00:31:23,440
+الجاى نشوفهم مستجلين تحديد آل الفصل الجاى وبنتمنى
+
+400
+00:31:23,440 --> 00:31:29,100
+لكم ان شاء الله التوفيق في الاختبارات وكل عام و
+
+401
+00:31:29,100 --> 00:31:35,220
+انتوا بخير؟ ماشي يا شباب بعطيكم الامتحانات الآن
+
+402
+00:31:35,220 --> 00:31:35,660
+يعني
+
diff --git a/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/GdjgOIlbWRM.srt b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/GdjgOIlbWRM.srt
new file mode 100644
index 0000000000000000000000000000000000000000..ca8a433aa7cebe496e61679c4b4f1afa3e2bb144
--- /dev/null
+++ b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/GdjgOIlbWRM.srt
@@ -0,0 +1,1985 @@
+
+1
+00:00:21,460 --> 00:00:25,620
+بسم الله الرحمن الرحيم طيب يا شباب، نكمل في ال
+
+2
+00:00:25,620 --> 00:00:31,420
+acid-base equilibria. شفنا الحصة الماضية النظريات
+
+3
+00:00:31,420 --> 00:00:37,340
+المختلفة التي تفسر ما هي الـ acid والـ base. شفنا
+
+4
+00:00:37,340 --> 00:00:41,780
+أربع نظريات تفسر الـ acids والـ bases. اليوم إن شاء
+
+5
+00:00:41,780 --> 00:00:48,680
+الله نكمل، نتكلم في البداية عن الماء كـ solvent في
+
+6
+00:00:48,680 --> 00:00:52,920
+الـ acid-base equilibria. طبعًا زي ما شفنا، يمكن نظرية
+
+7
+00:00:52,920 --> 00:00:58,740
+Franklin كانت تتكلم عن بعض الـ solvents التي تكون
+
+8
+00:00:58,740 --> 00:01:03,940
+ionizable زي الـ ethanol أو الـ methanol. فهذا يعني
+
+9
+00:01:03,940 --> 00:01:07,300
+لحسن الحظ، في هذا المساق، نحن  لن نتعرض لأي solvent
+
+10
+00:01:08,140 --> 00:01:14,440
+إلا الماء. فهذا سيحدد عملنا بشكل كبير جدًا. الماء يا
+
+11
+00:01:14,440 --> 00:01:19,320
+شباب، يعتبر من الـ weak electrolytes، weak
+
+12
+00:01:19,320 --> 00:01:24,180
+electrolytes. فيحدث عندي تفكك بسيط للماء، يعطيني
+
+13
+00:01:24,180 --> 00:01:29,890
+الـ hydronium ion والـ hydroxide. إذاً، الـ K أقدر أكتبه
+
+14
+00:01:29,890 --> 00:01:34,250
+على أنه hydronium ion في hydroxide مقسومًا على
+
+15
+00:01:34,250 --> 00:01:39,350
+تركيز الماء squared، لأنه عندي two moles of water.
+
+16
+00:01:39,350 --> 00:01:43,770
+الآن، أقدر أقول أن تركيز الماء كـ solvent يعتبر ثابتًا،
+
+17
+00:01:43,770 --> 00:01:48,710
+لأن تفككه ضئيل للغاية، فتركيزه هو تركيز ثابت.
+
+18
+00:01:48,710 --> 00:01:53,210
+فممكن أضرب تركيز الماء في الـ K. في هذه الحالة، أحصل
+
+19
+00:01:53,210 --> 00:01:58,440
+على قيمة أسميها KW أو الـ ionic product of
+
+20
+00:01:58,440 --> 00:02:03,880
+water. KW تساوي الـ H3O plus، اللي هو الهيدرونيوم
+
+21
+00:02:03,880 --> 00:02:12,340
+ايون، مضروبًا في الهيدروكسيد. في الواقع، لماذا
+
+22
+00:02:12,340 --> 00:02:17,960
+لم نكتب الماء على هيئة H2O فقط، وقلنا H Plus زائد
+
+23
+00:02:17,960 --> 00:02:22,620
+Hydroxide؟ نقول إن الـ H Plus، عادةً ما يظهر
+
+24
+00:02:22,620 --> 00:02:29,420
+عندي، هذا عبارة عن أيون حجمه صغير، وعليه شحنة موجبة
+
+25
+00:02:29,420 --> 00:02:34,880
+كاملة. فعادةً كلما صغر حجم الأيون، وزدات الشحنة
+
+26
+00:02:34,880 --> 00:02:40,170
+النسبية عليه، يكون more reactive، يكون نشطًا أكثر،
+
+27
+00:02:40,170 --> 00:02:45,850
+يتفاعل بسرعة. وبالتالي، الـ H plus الموجب، لو طلعنا
+
+28
+00:02:45,850 --> 00:02:49,630
+على جزيء الماء، نجد شحنة جزئية سالبة. دائمًا
+
+29
+00:02:49,630 --> 00:02:54,330
+تنجذب إلى الـ H plus، وبالتالي، يتكون أيون الهيدرونيوم،
+
+30
+00:02:54,330 --> 00:02:59,730
+الـ hydronium ion.  ممكن في الواقع، يعني كشيء، نحن لن نأخذه
+
+31
+00:02:59,730 --> 00:03:03,870
+بالتفصيل الآن، لكن ممكن، ليس فقط أيون الهيدرونيوم يتكون،
+
+32
+00:03:03,870 --> 00:03:07,790
+كثير من العلماء يقولون إنه يتكون على هيئة
+
+33
+00:03:07,790 --> 00:03:14,910
+H9O4 موجب،  أي أربع جزيئات ماء تلتصق بالـ H plus.
+
+34
+00:03:14,910 --> 00:03:20,830
+لكن نحن سنقول إنه أيون الهيدرونيوم فقط. في عندي H3O
+
+35
+00:03:20,830 --> 00:03:26,380
+plus. ومع ذلك، مع هذا التبسيط الذي ذكرناه، نقول
+
+36
+00:03:26,380 --> 00:03:31,740
+وكذلك، نحن سنعبر عن الـ hydronium ion بالـ H plus، مع
+
+37
+00:03:31,740 --> 00:03:37,300
+علمنا أن هذا غير صحيح، لكن لتسهيل، لتسهيل الحل
+
+38
+00:03:37,300 --> 00:03:41,060
+لتسهيل في الحل فقط، ليس لتسهيل في الكتابة فقط،
+
+39
+00:03:41,060 --> 00:03:45,040
+لتسهيل في النطق فقط. لكن في الواقع، هو لا يكون
+
+40
+00:03:45,040 --> 00:03:48,380
+على هيئة H plus، يكون على هيئة hydronium ion على
+
+41
+00:03:48,380 --> 00:03:54,630
+الأقل. الـ KW وجدنا أنه عند 25 درجة، تساوي عشرة أس
+
+42
+00:03:54,630 --> 00:03:59,470
+سالب 14. يعني معنى الكلام، لو لم يوجد إلا ماء،
+
+43
+00:03:59,470 --> 00:04:02,830
+فالـ H plus  سيساوي، الهيدروكسيد سيساوي عشرة
+
+44
+00:04:02,830 --> 00:04:10,400
+أس سالب سبعة. الـ H plus سيساوي الـ hydroxide، سيساوي
+
+45
+00:04:10,400 --> 00:04:14,620
+عشرة أس سالب سبعة. لكن هذا يا شباب، فقط عند 25
+
+46
+00:04:14,620 --> 00:04:19,500
+درجة. لو زادت درجة الحرارة، سألاحظ أن كمية
+
+47
+00:04:19,500 --> 00:04:24,120
+الـ H plus تزيد، كمية الـ hydroxide طبعًا، ثابتة،
+
+48
+00:04:24,120 --> 00:04:28,080
+ثابتة من ناحية أن الـ H plus يجب أن يساوي الـ hydroxide،
+
+49
+00:04:28,080 --> 00:04:33,290
+لكن الكمية تزيد. لماذا؟ لأن التفكك يزيد مع الحرارة.
+
+50
+00:04:33,290 --> 00:04:39,590
+فممكن نلاحظ أنه مثلًا عند الـ 100 درجة، بدلًا ما هي عشرة
+
+51
+00:04:39,590 --> 00:04:43,030
+أس سالب 14، تصبح عشرة أس سالب 13، أو
+
+52
+00:04:43,030 --> 00:04:47,310
+13 وشوية، يعني. فالحرارة تؤثر على الـ
+
+53
+00:04:47,310 --> 00:04:53,760
+equilibrium constant. ننتقل كذلك إلى الـ p Scale. نقول
+
+54
+00:04:53,760 --> 00:04:57,920
+الـ p Scale هنا، نتكلم عن الـ pH، لكن نتكلم بشكل عام
+
+55
+00:04:57,920 --> 00:05:02,400
+عن الـ p. هذا عبارة عن p function، دالة، تعني minus
+
+56
+00:05:02,400 --> 00:05:06,880
+log التركيز، minus log التركيز. يعني مثلًا لما نتكلم
+
+57
+00:05:06,880 --> 00:05:11,020
+عن الـ H plus، نقول الـ pH، minus log تركيز الـ H plus.
+
+58
+00:05:11,020 --> 00:05:16,490
+لما نتكلم عن الـ hydroxide، نقول pOH، يعني minus، الـ
+
+59
+00:05:16,490 --> 00:05:20,530
+minus log تركيز الـ OH. لما أريد أن أتحدث عن مثلًا الـ
+
+60
+00:05:20,530 --> 00:05:26,090
+calcium في المحلول، أقول الـ p للكالسيوم، pCa، يعني
+
+61
+00:05:26,090 --> 00:05:29,850
+minus log تركيز الكالسيوم، وهكذا. يعني الـ p ليست
+
+62
+00:05:29,850 --> 00:05:33,150
+مرتبطة فقط بالـ H والـ OH، لا، هذه عبارة عن دالة،
+
+63
+00:05:33,150 --> 00:05:37,010
+هذه الدالة تعني ماذا؟ minus log تركيز الشيء الذي
+
+64
+00:05:37,010 --> 00:05:42,860
+أريد إيجاده. حسنًا؟ بالنسبة لي، أقول الـ pH تساوي
+
+65
+00:05:42,860 --> 00:05:47,400
+minus log تركيز الـ H. طيب، لو افترضنا أن الـ H
+
+66
+00:05:47,400 --> 00:05:50,480
+plus في الـ hydroxide تساوي عشرة أس سالب أربعة
+
+67
+00:05:50,480 --> 00:05:54,100
+عشر. لو قلنا minus log تركيز الـ H plus، minus log
+
+68
+00:05:54,100 --> 00:06:00,400
+تركيز الـ OH، تساوي سالب أربعة عشر. يعني بمعنى آخر،
+
+69
+00:06:00,400 --> 00:06:05,950
+الـ pH زائد الـ pOH، يجب أن تساوي أربعة عشر، في الحالتين،
+
+70
+00:06:05,950 --> 00:06:09,570
+سواءً قلنا الـ H plus في الـ hydroxide تساوي عشرة
+
+71
+00:06:09,570 --> 00:06:12,910
+أس سالب أربعة عشر، لو عندي الـ H plus، أحصل على الـ hydroxide،
+
+72
+00:06:12,910 --> 00:06:16,310
+لو عندي الـ hydroxide، أحصل على الـ H plus. ولو قلنا الـ pH
+
+73
+00:06:16,310 --> 00:06:19,710
+زائد الـ pOH تساوي أربعة عشر، أيضًا نفس الكلام، لو
+
+74
+00:06:19,710 --> 00:06:25,430
+عندي الـ pH، أحصل على الـ pOH، ولو عندي الـ pOH، أحصل على الـ pH.
+
+75
+00:06:27,500 --> 00:06:30,620
+نحن يا شباب، كما ذكرت سابقًا، في هذا الـ chapter
+
+76
+00:06:30,620 --> 00:06:34,880
+تحديدًا، سندرس عدة أنواع من أنواع المحاليل.
+
+77
+00:06:34,880 --> 00:06:40,800
+سنبدأ دراستنا بالـ strong acids والـ strong bases، و
+
+78
+00:06:40,800 --> 00:06:44,920
+أملاحها. بعد ذلك، سندرس الـ monoprotic acids، و
+
+79
+00:06:44,920 --> 00:06:48,800
+الـ monobasic bases، وكيف نحسب الـ pH لها. بعد ذلك، سنأخذ
+
+80
+00:06:48,800 --> 00:06:53,380
+الأملاح الخاصة بالـ monoprotic acids والـ monobasic
+
+81
+00:06:53,380 --> 00:07:00,350
+bases. بعد ذلك، سندرس خليط من الأحماض، وأملاحها، الـ
+
+82
+00:07:00,350 --> 00:07:04,250
+weak acids والـ monoprotic acids، وأملاحها،
+
+83
+00:07:04,250 --> 00:07:07,810
+والـ monobasic bases، وأملاحها. هذه تُسمى
+
+84
+00:07:07,810 --> 00:07:11,810
+buffer solutions. بعد ذلك، سنتطرق إلى الـ polyprotic
+
+85
+00:07:11,810 --> 00:07:15,390
+acids والـ polybasic bases، سنرى كيف نحسب الـ pH
+
+86
+00:07:15,390 --> 00:07:19,410
+لها، وبعد ذلك سنأخذ أملاحها، كيف نحسب
+
+87
+00:07:19,410 --> 00:07:22,530
+التركيز،
+
+88
+00:07:22,530 --> 00:07:26,690
+أو الـ pH لأملاح الـ polyprotic acids أو الـ polybasic
+
+89
+00:07:26,690 --> 00:07:32,570
+bases. بعد ذلك، سنأخذ mixtures من الأحماض، وmixtures
+
+90
+00:07:32,570 --> 00:07:37,510
+من القواعد. القاعدة قد تكون ملحًا، وقد تكون
+
+91
+00:07:37,510 --> 00:07:43,850
+قاعدة حقيقية. لذا، سنأخذ بعض الـ mixtures، يعني في
+
+92
+00:07:43,850 --> 00:07:49,430
+عندي عدد لا بأس به من الحالات التي سأدرس كيفية
+
+93
+00:07:49,430 --> 00:07:54,250
+حساب الـ pH لها. الآن، في البداية، نتحدث عن الـ strong
+
+94
+00:07:54,250 --> 00:07:58,290
+acids والـ strong bases، وأرجو أننا جميعًا نحاول أن
+
+95
+00:07:58,290 --> 00:08:05,330
+نركز معًا لنفهم كيفية، أو منهجية حساب الـ pH.
+
+96
+00:08:07,500 --> 00:08:10,180
+أقول في البداية، لو أردت أن أعرف ما هو الـ strong acid
+
+97
+00:08:10,180 --> 00:08:14,540
+وما هو الـ strong base، أقول والله الـ strong acid
+
+98
+00:08:14,540 --> 00:08:17,360
+هو الـ acid الذي يتفكك بنسبة مئة في المئة، والـ
+
+99
+00:08:17,360 --> 00:08:20,440
+strong base هو الـ base الذي يتفكك بنسبة مئة في
+
+100
+00:08:20,440 --> 00:08:26,220
+المئة. افهم، نحن، الـ strong acids مثل ماذا؟ ليس من الضروري
+
+101
+00:08:26,220 --> 00:08:28,920
+أن نقول مثل ماذا، نقول ما هي الـ strong acids؟ لماذا؟
+
+102
+00:08:28,920 --> 00:08:34,380
+لأنها محددة، ليست كثيرة، محددة. فأقول في البداية، الـ HX
+
+103
+00:08:34,380 --> 00:08:41,460
+حيث X هو halogen، ما عدا الـ HF، حمض الهيدروفلوريك. هذا
+
+104
+00:08:41,460 --> 00:08:48,880
+حمض ضعيف. لكن الـ HCl، الـ HBr، الـ HI، أحماض قوية، قوية،
+
+105
+00:08:48,880 --> 00:08:54,980
+يعني تتفكك بنسبة 100%. أضيف إلى الـ HX، الـ HF لا، حمض ضعيف.
+
+106
+00:08:54,980 --> 00:09:00,700
+أضيف إلى هؤلاء الـ HX، HNO3، اللي هو حمض النيتريك،
+
+107
+00:09:00,700 --> 00:09:02,680
+والـ HClO4،
+
+108
+00:09:03,980 --> 00:09:08,460
+حمض البيركلوريك.  نضيف الحمض الأخير الذي نقوله حمض الكبريتيك،
+
+109
+00:09:08,460 --> 00:09:12,260
+sulphuric acid. ولماذا هذا له قصة؟ لأنه فقط التفكك الأول له
+
+110
+00:09:12,260 --> 00:09:16,960
+قوي، والثاني ضعيف. لذلك، لن ندرس
+
+111
+00:09:16,960 --> 00:09:22,580
+حساب الـ pH لحمض الكبريتيك، في هذه
+
+112
+00:09:22,580 --> 00:09:26,600
+الجزئية من الـ course، يجب أن نستمر حتى نتعلم كيف نحسب
+
+113
+00:09:26,600 --> 00:09:32,200
+الـ pH للحمض الضعيف، وبعد ذلك نستطيع أن نحسب الـ pH لـ
+
+114
+00:09:32,200 --> 00:09:36,920
+حمض الكبريتيك، لأن أحد التفككات قوي، لكن الثاني
+
+115
+00:09:36,920 --> 00:09:42,160
+ضعيف. فيجب أن نستمر حتى ننهي الأحماض الضعيفة لنستطيع
+
+116
+00:09:42,160 --> 00:09:44,560
+حساب الـ pH لحمض الكبريتيك.
+
+117
+00:09:47,990 --> 00:09:53,830
+HX، يعني HCl، HBr، HI. عندي HNO3، عندي
+
+118
+00:09:53,830 --> 00:09:57,490
+Perchloric Acid. فقط، والتفكك الأول من
+
+119
+00:09:57,490 --> 00:10:00,490
+حمض الكبريتيك. نقول إن حمض الكبريتيك هذا في الوجيزة
+
+120
+00:10:00,490 --> 00:10:02,350
+التي سنراها في المستقبل.
+
+121
+00:10:04,760 --> 00:10:09,440
+طيب، الـ strong bases مثل ماذا؟ نقول… ليس مثل ماذا…
+
+122
+00:10:09,440 --> 00:10:12,480
+ما هي الـ strong bases؟ نقول أي هيدروكسيد
+
+123
+00:10:12,480 --> 00:10:17,460
+قابل للذوبان، أي هيدروكسيد، يعني مثلًا Sodium hydroxide,
+
+124
+00:10:17,800 --> 00:10:21,520
+Potassium hydroxide, Calcium hydroxide, Magnesium
+
+125
+00:10:21,520 --> 00:10:25,720
+hydroxide. أي هيدروكسيد قابل للذوبان، هذا يُعتبر؟ strong
+
+126
+00:10:25,720 --> 00:10:29,700
+base. انتهى. إذًا هذه هي الـ strong acids والـ strong
+
+127
+00:10:29,700 --> 00:10:36,040
+bases. ما عدا ذلك يُعتبر weak… ما عدا ذلك يُعتبر
+
+128
+00:10:36,040 --> 00:10:39,340
+weak. طبعًا، الـ strong acids والـ strong bases لا
+
+129
+00:10:39,340 --> 00:10:43,260
+يمكن كتابة equilibrium constant لها. لماذا؟ لأنه
+
+130
+00:10:43,260 --> 00:10:46,860
+عندما يتفكك الـ strong acid، تفككًا كاملًا، ماذا يتبقى من
+
+131
+00:10:46,860 --> 00:10:51,740
+المتفاعلات؟ لا شيء… ليس شيئًا بسيطًا ولا شيء
+
+132
+00:10:51,740 --> 00:10:56,540
+أبداً. إذًا، لا يوجد شيء في مقام المعادلة. هذا
+
+133
+00:10:56,540 --> 00:11:00,180
+كلام يعطي قيمة غير محددة. لذلك نحن لا
+
+134
+00:11:00,180 --> 00:11:03,880
+نكتب equilibrium constants للـ strong acids ولـ
+
+135
+00:11:03,880 --> 00:11:06,080
+strong bases. لماذا؟ لأنه لا يتبقى أي شيء منها،
+
+136
+00:11:06,080 --> 00:11:10,500
+لا يتبقى أي شيء في المقام، صفر.  لا نستطيع الحصول على قيمة على
+
+137
+00:11:10,500 --> 00:11:15,680
+صفر، قيمة غير محددة، قيمة غير معلومة، غير محددة. طيب،
+
+138
+00:11:15,680 --> 00:11:23,030
+يا شباب، نحاول أن نتعلم كيف نحسب الـ H plus للأحماض، و
+
+139
+00:11:23,030 --> 00:11:26,150
+القواعد. تعالوا نتطلع على المثال، وأنا أرجو أن
+
+140
+00:11:26,150 --> 00:11:31,850
+نركز معًا قليلًا. قد يبدو المثال بسيطًا، لكن نحن
+
+141
+00:11:31,850 --> 00:11:36,370
+سنستخدمه لنطور منهجية في التفكير. المثال قد
+
+142
+00:11:36,370 --> 00:11:39,790
+يبدو بسيطًا، لكن نحن سنحاول أن نطور منهجية في
+
+143
+00:11:39,790 --> 00:11:44,870
+التفكير. أقول في عندي 0.1 molar HCl، أريد أن أحسب
+
+144
+00:11:44,870 --> 00:11:49,730
+الـ pH له. أقول، حسنًا، الـ HCl يتفكك تفككًا كاملًا، يعطي H
+
+145
+00:11:49,730 --> 00:11:54,760
+plus و chloride. طيب، كذلك في المحلول، الماء يتفكك،
+
+146
+00:11:54,760 --> 00:11:57,300
+يعطي H plus و Hydroxide. أنا وضعت الـ HCl في
+
+147
+00:11:57,300 --> 00:12:01,160
+الماء، أيه الـ solvent تبعي؟ إذًا، أتوقع أن في عندي H
+
+148
+00:12:01,160 --> 00:12:06,220
+plus قادم من الـ HCl، وH plus قادم من أين؟ من الماء.
+
+149
+00:12:06,220 --> 00:12:10,480
+إذن، الـ H plus للمحلول هو مجموع الاثنين، مجموع
+
+150
+00:12:10,480 --> 00:12:16,120
+الاثنين. الآن يا شباب، في عندي عدة طرق في التفكير.
+
+151
+00:12:16,120 --> 00:12:20,850
+أقول من أبسط الطرق، من أفضل الطرق، أن أقول، كم الـ H
+
+152
+00:12:20,850 --> 00:12:27,290
+plus الذي جاء من الـ HCl؟ واحد من عشرة؟ لأن
+
+153
+00:12:27,290 --> 00:12:33,290
+التفكك تفكك كامل. طيب، من يقول كم الـ H plus الذي
+
+154
+00:12:33,290 --> 00:12:38,950
+جاء من الماء؟ لا، ليس عشرة أس سالب سبعة، لو كان الماء نقيًا، pure water، لكن عندما يكون
+
+155
+00:12:38,950 --> 00:12:42,390
+فيه حمض، التفكك يعود إلى الخلف. أنا أقول لكم، كم الـ H
+
+156
+00:12:46,960 --> 00:12:49,720
+plus الذي يأتي من الماء؟  الـ H plus الذي يأتي من
+
+157
+00:12:49,720 --> 00:12:54,900
+الماء يساوي تركيز الـ OH. ولماذا؟ وما مصدر الـ OH؟
+
+158
+00:12:54,900 --> 00:13:01,820
+الماء فقط. مصدر الـ OH الماء فقط. إذًا، الـ H plus الذي
+
+159
+00:13:01,820 --> 00:13:05,580
+يأتي من الماء يساوي تركيز الـ hydroxide.  طيب، أنا أعرف
+
+160
+00:13:05,580 --> 00:13:09,800
+أن تركيز الـ H plus في تركيز الـ hydroxide، كم؟
+
+162 --> 168 (Repeated line - removed)
+
+169
+00:13:35,340 --> 00:13:39,940
+OH. طيب، حصل ضرب الـ OH في الـ H plus، عشرة أس سالب
+
+170
+00:13:39,940 --> 00:13:43,480
+أربعة عشر، هذا يعني عشرة أس سالب أربعة عشر. إذاً هذا عشرة
+
+171
+00:13:43,480 --> 00:13:46,520
+أس سالب أربعة عشر، لأنه حصل ضرب عشرة أس سالب أربعة
+
+172
+00:13:46,520 --> 00:13:50,440
+عشر. يبقى، عندما نقول بالـ 0.1 من عشرة،
+
+173
+00:13:50,440 --> 00:13:54,400
+لعشرة أس سالب أربعة عشر،  نجمع العشرة أس سالب
+
+174
+00:13:54,400 --> 
+
+223
+00:17:18,550 --> 00:17:21,850
+يعني برضه منهاش تفكير، بنقول يبقى الـ H plus
+
+224
+00:17:21,850 --> 00:17:25,110
+للمحلول بده يساوي الـ H plus لـ الـ HCA، لكن احنا
+
+225
+00:17:25,110 --> 00:17:28,030
+فرضنا أن الـ point one أكبر كتير من الـ H plus اللي
+
+226
+00:17:28,030 --> 00:17:32,930
+جاية من الميه. طيب لو حاولنا إنه نحقق فرضيتنا بدنا
+
+227
+00:17:32,930 --> 00:17:35,130
+نجيب الـ H plus اللي جاية من الميه، بنعتبر الـ H
+
+228
+00:17:35,130 --> 00:17:39,530
+plus للمحلول 1 من 10، إذا الـ H plus اللي جاية من
+
+229
+00:17:39,530 --> 00:17:43,750
+الميه بتساوي الـ hydroxide بتساوي 10 أس سالب 13
+
+230
+00:17:45,670 --> 00:17:49,370
+عشرة أس سالب ثلاثة عشر. طبعا تعتبر قَدِيلة جدا، ممكن أن
+
+231
+00:17:49,370 --> 00:17:53,350
+نجيب relative error بيطلع يعني حاجة تافهة غير عشرة
+
+232
+00:17:53,350 --> 00:17:56,490
+أس سالب عشرة. يمكن يطلع عشرة أس سالب عشرة في المئة ولا
+
+233
+00:17:56,490 --> 00:18:00,850
+شيء. إذا نظريتنا صحيحة، والـ pH عبارة عن واحد لأن الـ
+
+234
+00:18:00,850 --> 00:18:05,110
+H plus واحد من عشرة. الطريقة الثانية في الحل اللي
+
+235
+00:18:05,110 --> 00:18:11,410
+أنا بفضله، نشتغل فيها إنه أدور على الـ equilibrium
+
+236
+00:18:11,410 --> 00:18:14,430
+لأن أنا الآن بشتغل الـ equilibrium في الشبات
+
+237
+00:18:14,430 --> 00:18:17,230
+الدينية مش هيك، بشتغل الـ equilibrium .. بشتغل على
+
+238
+00:18:17,230 --> 00:18:20,210
+أي equilibrium لما أحط الـ HCl في الميه، ماهي الـ
+
+239
+00:18:20,210 --> 00:18:23,690
+equilibrium اللي عندي؟ مافيش عندي غير الميه لأن الـ
+
+240
+00:18:23,690 --> 00:18:27,970
+HCl بتفكك كده، مش equilibrium، تفكك تام، مش عندي غير
+
+241
+00:18:27,970 --> 00:18:31,550
+الميه. فيقول والله الميه تتفكك تعطيني H plus و
+
+242
+00:18:31,550 --> 00:18:36,470
+hydroxide. قبل الـ equilibrium هان عندي واحد من عشرة
+
+243
+00:18:36,470 --> 00:18:40,250
+جاية من الـ acid، فان عندي صفر. إذا point one بتنزل
+
+244
+00:18:40,250 --> 00:18:44,930
+زائد x جايه هذا من ايه؟ من تفكك المياه. الآن واضح
+
+245
+00:18:44,930 --> 00:18:50,110
+أن الـ Kw بده يساوي واحد من عشرة زائد x في x. بفترض
+
+246
+00:18:50,110 --> 00:18:54,430
+أن الواحد من عشرة أكبر كتير من الـ x، إذا الـ x بتطلع
+
+247
+00:18:54,430 --> 00:18:56,870
+عشرة أس سالب ثلاثة عشر. لحظة أنه عملنا هذا الكلام
+
+248
+00:18:56,870 --> 00:19:02,620
+مجرد نظر قبل شوية. مجرد النظر اللي عملناها. طيب الـ
+
+249
+00:19:02,620 --> 00:19:06,000
+relative error عشرة أس سالب عشرة في المئة. إذا الـ H
+
+250
+00:19:06,000 --> 00:19:09,300
+plus point one زائد x، الـ x هذه ما هي ملغية، قلنا
+
+251
+00:19:09,300 --> 00:19:12,460
+أنها قليلة كتير، يبقى point one، والـ pH عبارة عن
+
+252
+00:19:12,460 --> 00:19:19,760
+واحد. هذه منهجية حل كويس. نيجي طيب نطلع على مسألة
+
+253
+00:19:19,760 --> 00:19:25,690
+ثانية. بقول الـ nitric acid عندي تركيزه واحد في عشرة
+
+254
+00:19:25,690 --> 00:19:28,710
+أس سالب خمسة مولار، بدي أحسب له الـ pH. طبعا الـ
+
+255
+00:19:28,710 --> 00:19:31,390
+nitric acid هو عبارة عن strong acid، مافي مشكلة.
+
+256
+00:19:31,390 --> 00:19:34,330
+يبقى الـ H plus اللي جاي من الـ strong acid عبارة عن
+
+257
+00:19:34,330 --> 00:19:37,190
+عشرة أس سالب خمسة. نفس الكلام، أقول الـ H plus اللي
+
+258
+00:19:37,190 --> 00:19:40,730
+جاي من المحلول. لو بدي أعمل زيك ممكن أعمله بطريقة
+
+259
+00:19:40,730 --> 00:19:43,670
+ثانية. الـ H plus اللي جاي من المحلول في المحلول
+
+260
+00:19:43,670 --> 00:19:46,610
+يعني عبارة عن الـ H plus اللي جاي من الـ nitric acid
+
+261
+00:19:46,610 --> 00:19:49,250
+زائد الـ H plus اللي جاي من الميه. طيب، إذا كان اللي
+
+262
+00:19:49,250 --> 00:19:51,510
+جاي من الـ nitric acid عشرة أس سالب خمسة، كذا الـ H
+
+263
+00:19:51,510 --> 00:19:55,390
+plus اللي جاي من على طول، و مجرد النظر عشرة أس سالب
+
+264
+00:19:55,390 --> 00:19:58,910
+تسعة، العشرة أس سالب خمسة أكبر ألف مرة من
+
+265
+00:19:58,910 --> 00:20:02,230
+عشرة أس سالب تسعة، إذا يمكن إلغاءها، أو أنه أقول
+
+266
+00:20:02,230 --> 00:20:06,190
+بما أنه تركيز الـ acid أكبر من عشرة أس سالب ستة
+
+267
+00:20:06,190 --> 00:20:10,280
+اللي توي شفناها، اللي بتعطي واحد في المئة error. بما أن
+
+268
+00:20:10,280 --> 00:20:12,940
+العشرة أس سالب خمسة هي أكبر من العشرة أس سالب
+
+269
+00:20:12,940 --> 00:20:17,260
+ستة، فالـ H plus اللي جاي من الميه ليس له أي قيمة، ليس
+
+270
+00:20:17,260 --> 00:20:22,660
+له أي قيمة، أو أن اشتغل بالـ equilibrium وأنا بفضل
+
+271
+00:20:22,660 --> 00:20:25,920
+الـ equilibrium. بقول الـ H2O بتعطينا H plus و
+
+272
+00:20:25,920 --> 00:20:29,500
+hydroxide. الـ H plus طبعا جاي من الـ acid عشرة أس سالب
+
+273
+00:20:29,500 --> 00:20:33,400
+خمسة لأنه تفكك تفكك كامل. الـ hydroxide كان
+
+274
+00:20:33,400 --> 00:20:36,360
+صفر قبل الـ equilibrium، بعد الـ equilibrium، وعند الـ
+
+275
+00:20:36,360 --> 00:20:39,480
+equilibrium، الـ H plus عشرة أس سالب خمسة اللي جاء من
+
+276
+00:20:39,480 --> 00:20:42,580
+الـ acid زائد x اللي جاء من الميه. الـ hydroxide x
+
+277
+00:20:42,580 --> 00:20:45,980
+يبقى بده أقول أن الـ Kw بدها تساوي أو عشرة أس سالب
+
+278
+00:20:45,980 --> 00:20:49,900
+أربعة عشر بقى تساوي عشرة أس سالب خمسة زائد x في
+
+279
+00:20:49,900 --> 00:20:54,740
+x. بدي أفترض الآن أن العشرة أس سالب خمسة أكبر كتير
+
+280
+00:20:54,740 --> 00:21:00,500
+من الـ x، كويس؟ إذا الـ x بتطلع عشرة أس سالب تسعة. كم
+
+281
+00:21:00,500 --> 00:21:05,640
+عملت هذا الكلام، مجرد النظر قبل شوية، تقولي بس
+
+282
+00:21:05,640 --> 00:21:14,190
+تفهميني هذا الكلام؟ أه، أه، فاهمني، مافيش مشكلة. إذا الـ
+
+283
+00:21:14,190 --> 00:21:18,690
+H plus عشرة أس سالب خمسة مولار، والـ pH عبارة عن
+
+284
+00:21:18,690 --> 00:21:24,390
+خمسة. طيب، ليش نطلع على مسألة ثانية؟ تفضل.
+
+285
+00:21:32,580 --> 00:21:36,280
+هو أنا بهمني ايش اسمه في الحقيقة؟ هو أنا عندي
+
+286
+00:21:36,280 --> 00:21:40,900
+equilibrium، H2O بتعطيني H plus زائد hydroxide. بتطلع
+
+287
+00:21:40,900 --> 00:21:44,740
+على الـ H plus، بقول H plus جابني الـ equilibrium فيه
+
+288
+00:21:44,740 --> 00:21:47,080
+عندي H plus جايه بس من الـ acid، لأن الميه لسه
+
+289
+00:21:47,080 --> 00:21:50,200
+ما تفككتش، جابتش، الـ H plus جايه من الـ acid هذا
+
+290
+00:21:50,200 --> 00:21:53,340
+strong acid، عشرة أس سالب خمسة. بعمل equilibrium
+
+291
+00:21:53,340 --> 00:21:56,750
+الميه هتعطيني كمان x، فأنا مهمنيش ايش اسمه، لكن هو
+
+292
+00:21:56,750 --> 00:22:02,190
+طبعا أيون مشترك. فبنيجي نطلع على الـ HCl اللي تركيزه
+
+293
+00:22:02,190 --> 00:22:06,250
+عشرة أس سالب سبعة مولار، ونقول كيف بده نوجد الـ H
+
+294
+00:22:06,250 --> 00:22:14,120
+plus له؟ فبقول والله الـ H plus بدها تساوي للمحلول
+
+295
+00:22:14,120 --> 00:22:18,060
+الـ H plus اللي جاي من الـ acid زائد الـ H plus اللي
+
+296
+00:22:18,060 --> 00:22:21,560
+جاي من الميه. أنا ممكن أقول والله يبقى الـ H plus
+
+297
+00:22:21,560 --> 00:22:25,380
+اللي جاي من الميه عشرة أس سالب سبعة. مش ممكن نلغي أي
+
+298
+00:22:25,380 --> 00:22:32,480
+واحد بالنسبة للثاني، إذا لازم أجمع الاثنين. بس أنا
+
+299
+00:22:32,480 --> 00:22:37,400
+مش عارف يعني كده، الـ H plus اللي جاي من الميه كيف
+
+300
+00:22:37,400 --> 00:22:40,160
+بدي أجيبه؟ بقول، عشان هيك بقول الـ equilibrium
+
+301
+00:22:40,160 --> 00:22:43,840
+دائما أسلم. بقول H2O بتعطيني H plus زائد hydroxide.
+
+302
+00:22:43,840 --> 00:22:47,100
+أنا في عندي عشرة أس سالب سبعة جاء من الـ acid، الـ
+
+303
+00:22:47,100 --> 00:22:49,480
+hydroxide صفر. جاب للـ equilibrium، بعد الـ
+
+304
+00:22:49,480 --> 00:22:53,420
+equilibrium، الميه بتعطيني x و x. يبقى عشرة أس سالب
+
+305
+00:22:53,420 --> 00:22:57,420
+سبعة زائد x و x. بدي أقول يبقى العشرة أس سالب
+
+306
+00:22:57,420 --> 00:23:00,760
+أربعة عشر بيساوي عشرة أس سالب سبعة زائد x في x.
+
+307
+00:23:01,430 --> 00:23:04,150
+وبنفترض أن العشرة أس سالب سبعة أكبر كتير من الـ x
+
+308
+00:23:04,150 --> 00:23:07,210
+بتطلع عندي الـ x عشرة أس سالب سبعة. الـ relative
+
+309
+00:23:07,210 --> 00:23:12,450
+error بتطلع عندي مئة في المئة، إذا لا يمكن إلغاء
+
+310
+00:23:12,450 --> 00:23:16,090
+الـ H plus اللي جاء من الميه، طيب هاي إيش بدي أعمل؟
+
+311
+00:23:16,090 --> 00:23:19,930
+جاي حل quadratic equation. طبعا احنا بدنا نقول
+
+312
+00:23:19,930 --> 00:23:24,130
+ساعتها بنحلها الـ equation، لكنها لو حليتها هيطلع
+
+313
+00:23:24,130 --> 00:23:27,770
+سبعة فاصلة اثنين وستين في عشرة أس سالب سبعة، ولو جبت
+
+314
+00:23:27,770 --> 00:23:32,190
+الـ pH هتطلع مش سبعة، لأ ستة فاصلة تسعة وسبعة يعني
+
+315
+00:23:32,190 --> 00:23:36,870
+بالضبط.
+
+316
+00:23:36,870 --> 00:23:40,230
+يعني فبنجي نتطلع على هالمثال اللي ما بتكاش تقول
+
+317
+00:23:40,230 --> 00:23:44,350
+فيه invalid وخلاص. فايد بي اتش أو بي عشرة أس سالب
+
+318
+00:23:44,350 --> 00:23:48,830
+عشرة مولار HCl، بيقول نفس الكلام. الـ H plus لسه الـ
+
+319
+00:23:48,830 --> 00:23:52,090
+usual هو H plus من الـ HCl زائد الـ H plus من الميه.
+
+320
+00:23:52,090 --> 00:23:55,010
+بمجرد النظر بيقول هذه عشرة أس سالب عشرة. إذا هذه
+
+321
+00:23:55,010 --> 00:23:58,690
+عشرة أس سالب أربعة. لأ والله هذه مش هتطلع أكبر
+
+322
+00:23:58,690 --> 00:24:00,850
+كتير منه، بالعكس. الـ H plus اللي جاي من الميه هيطلع
+
+323
+00:24:00,850 --> 00:24:05,040
+أكبر كتير من الـ H plus اللي جاي من الـ acid، لكن احنا
+
+324
+00:24:05,040 --> 00:24:08,420
+اللي هنخلقها نشتغل بالـ equilibrium، بنقول الـ H2O
+
+325
+00:24:08,420 --> 00:24:10,960
+بتعطينا H plus، هيدروكسيد. في عندي عشرة أس سالب
+
+326
+00:24:10,960 --> 00:24:15,460
+عشرة من الـ acid، صفر الـ hydroxide، عشرة أس سالب عشرة.
+
+327
+00:24:15,460 --> 00:24:19,680
+x من الميه، x من الميه. معناه الكلام بقول عشرة أس سالب
+
+328
+00:24:19,680 --> 00:24:26,060
+أربعة عشر بدها تساوي عشرة أس سالب عشرة
+
+329
+00:24:26,060 --> 00:24:30,080
+زائد x في x. نفترض أن عشرة أس سالب عشرة أكبر كتير
+
+330
+00:24:30,080 --> 00:24:33,020
+من الـ x، إذا الـ x بتطلع عندي عشرة أس سالب أربعة.
+
+331
+00:24:33,710 --> 00:24:38,470
+طبعا واضح أن العشرة أس سالب أربعة يعني مش أصغر
+
+332
+00:24:38,470 --> 00:24:41,970
+كتير من العشرة أس سالب عشرة، بالعكس، بالعكس في
+
+333
+00:24:41,970 --> 00:24:45,590
+الواقع الـ x هي اللي much larger than العشرة أس
+
+334
+00:24:45,590 --> 00:24:50,530
+سالب عشرة. إذا في هذه الحالة اللي مبين معاك أن الـ
+
+335
+00:24:50,530 --> 00:24:54,330
+x هي اللي أكبر كتير من الـ value، أتجينا بالحل
+
+336
+00:24:54,330 --> 00:24:59,090
+باستخدام الـ quadratic. لأ، نفترض، نفترض الآن أن الـ x هي
+
+337
+00:24:59,090 --> 00:25:03,570
+اللي أكبر من العشرة أس سالب عشرة، بقول نفترض أه
+
+338
+00:25:03,570 --> 00:25:09,850
+أكبر من الـ value، ليش؟ لأن طلعت عيننا الـ x عشرة أس
+
+339
+00:25:09,850 --> 00:25:13,130
+سالب أربعة، فالعشرة أس سالب أربعة هي اللي أكبر من
+
+340
+00:25:13,130 --> 00:25:15,590
+العشرة أس سالب عشرة، مش العشرة أس سالب عشرة هي اللي
+
+341
+00:25:15,590 --> 00:25:18,270
+أكبر من العشرة أس سالب أربعة، العشرة أس سالب أربعة
+
+342
+00:25:18,270 --> 00:25:22,230
+أكبر مليون مرة من العشرة أس سالب عشرة، فبنفترض
+
+343
+00:25:22,230 --> 00:25:27,250
+العكس. أه، we reverse the assumption. بالضبط، هاي
+
+344
+00:25:27,250 --> 00:25:30,250
+العشرة أس سالب عشرة، واحد، صارت هادي x، تربيعها، بالسبب
+
+345
+00:25:30,250 --> 00:25:34,290
+عشرة أس سالب أربعة،  فالـ x عشرة أس سالب سبعة. طيب بنحقق
+
+346
+00:25:34,290 --> 00:25:38,370
+فرضيتنا، ألا ده كده صح ولا لأ؟ عشرة أس سالب سبعة على
+
+347
+00:25:38,370 --> 00:25:42,450
+عشرة أس سالب عشرة في مئة من مئة، بتطلع واحد من عشرة
+
+348
+00:25:42,450 --> 00:25:47,780
+في المئة. الفرضية صحيحة. إذا الـ x اللي هي الـ H plus
+
+349
+00:25:47,780 --> 00:25:50,780
+بدها تساوي عشرة أس سالب سبعة، يبقى الـ pH بتساوي
+
+350
+00:25:50,780 --> 00:25:56,180
+سبعة. يعني الميه متعادلة إذا كان تركيز الـ HCl فيها
+
+351
+00:25:56,180 --> 00:25:58,560
+عشرة أس سالب عشرة مولار.
+
+352
+00:26:02,690 --> 00:26:08,070
+هو إنت بينفع
+
+353
+00:26:08,070 --> 00:26:12,830
+في حالة واحدة بس. آسف، إن الـ error مش مثلاً 7% ولا 10
+
+354
+00:26:12,830 --> 00:26:19,330
+% ولا 15% ولا 20% ولا 100%. لو تبين أنه بالعكس
+
+355
+00:26:19,330 --> 00:26:23,570
+طالع معاك القيمة الـ x أكبر .. هي اللي أكبر كتير من
+
+356
+00:26:23,570 --> 00:26:26,770
+القيمة زي ما طلع أينها هان، يعني هان واضح أن الـ x
+
+357
+00:26:26,770 --> 00:26:29,610
+أكبر مليون مرة من العشرة أس سالب عشرة، ساعتها
+
+358
+00:26:29,610 --> 00:26:32,670
+واضحة بالنسبالك أنه  تؤكس الفرضية، لكن غير هيك لو
+
+359
+00:26:32,670 --> 00:26:38,010
+كانت لحد مئة ولا يعني ما شابه، يعني عشرة، خمسة،
+
+360
+00:26:38,010 --> 00:26:40,950
+عشرين، ثلاثين، أربعين، خمسين، مش هيظل معاك، هتأكس
+
+361
+00:26:40,950 --> 00:26:45,070
+الفرضية، وبرضه هتطلع معاك الفرضية غلط. لكن فيك تحاول
+
+362
+00:26:45,070 --> 00:26:51,330
+لكن لو كانت واضحة أن الـ x هي اللي أكبر مئة مرة من
+
+363
+00:26:51,330 --> 00:26:57,110
+الـ value، ساعتها تؤكس الفرضية، تطلع معاك تؤكس الفرضية
+
+364
+00:26:57,110 --> 00:27:02,610
+صحيحة. بس لما تكون الـ x أكبر كتير من، يعني أه، إذا كان
+
+365
+00:27:02,610 --> 00:27:09,450
+مئة أو أكثر، بتكون القيمة عندك صحيحة. طيب، نطلع على
+
+366
+00:27:09,450 --> 00:27:10,730
+هالمثالين.
+
+367
+00:27:14,240 --> 00:27:19,500
+المثال الأول منهم إيش بيقول؟ بيقول calculate the pH
+
+368
+00:27:19,500 --> 00:27:24,220
+of the solution resulting from mixing 50 ml of 0.1
+
+369
+00:27:24,220 --> 00:27:30,120
+molar HCl with 50 ml of 0.2 molar sodium hydroxide.
+
+370
+00:27:30,120 --> 00:27:33,700
+ننبه شوية، احنا قلنا الحصة الماضية، وهذا هنواجهه
+
+371
+00:27:33,700 --> 00:27:39,400
+كتير خلال الشبات اللي جايه، هنقول أنه لما نخلط
+
+372
+00:27:39,400 --> 00:27:45,880
+محلولين مع بعض، والله بيحصل أحد حاجتين، يا المحلولين
+
+373
+00:27:45,880 --> 00:27:50,420
+بتتفاعلوا، يا بتتفاعلوش. إذا كانوا ما بتتفاعلوش، هذه مشكلة
+
+374
+00:27:50,420 --> 00:27:57,340
+التخفيف. إذا بتتفاعلوا، إيش قلت؟ بدي أجيب الزيادة،
+
+375
+00:27:57,340 --> 00:28:00,700
+إيش اللي بيزيد منهم؟ بدي أجيب الزيادة، وبدي أجيب
+
+376
+00:28:00,700 --> 00:28:05,030
+إيش اللي تكون فقط. إذا كان اللي تكون هو جزء من
+
+377
+00:28:05,030 --> 00:28:08,590
+equilibrium موجود عندي، إذا كان بيدخل في تحديد أو
+
+378
+00:28:08,590 --> 00:28:13,350
+في حساب الـ equilibrium، بالزمن أجيبه. فهنا عندي HCl
+
+379
+00:28:13,350 --> 00:28:16,890
+و sodium hydroxide، بتتفاعلوا ولا لأ؟ طبعا بتتفاعلوا، مش
+
+380
+00:28:16,890 --> 00:28:21,790
+بس هيك، معروف نسبة واحد لواحد. فبجيب الميلي مول من
+
+381
+00:28:21,790 --> 00:28:25,630
+الأول، الـ acid، point one في خمسين، moderate volume،
+
+382
+00:28:25,630 --> 00:28:28,870
+خمسة ميلي مول. الميلي مول sodium hydroxide
+
+383
+00:28:30,200 --> 00:28:34,160
+Molarity في Volume، 0.2 × 50، عشرة ميلي مول. واضح
+
+384
+00:28:34,160 --> 00:28:38,140
+أن الصوديوم الهيدروكسيد أكثر، يبقى بدي أجيب الملي
+
+385
+00:28:38,140 --> 00:28:41,440
+مول الصوديوم الهيدروكسيد excess، عشرة ناقص
+
+445
+00:33:21,770 --> 00:33:25,210
+بتطلع 2 في 10 أقل سالب 13، ال relative error بتطلع
+
+446
+00:33:25,210 --> 00:33:29,130
+very small، دليل خالص إذا ال hydroxide 5 من 100، و
+
+447
+00:33:29,130 --> 00:33:37,590
+ال pOH 1.3 و ال pH 12.7، ماشي يا شباب؟ طيب نتطلع
+
+448
+00:33:37,590 --> 00:33:42,640
+عليها بالمثال التالي، ممكن المثال يجيك بشكل يعني مختلف
+
+449
+00:33:42,640 --> 00:33:49,180
+بشكل بسيط، يعني بنقول find the pH of a solution
+
+450
+00:33:49,180 --> 00:33:53,200
+prepared by mixing 2 ml of a strong acid at pH 3
+
+451
+00:33:53,200 --> 00:33:57,760
+and 3 ml of a strong base at pH 10، يبدو خلطنا two
+
+452
+00:33:57,760 --> 00:34:03,070
+acids، أتنين مل من الـ strong acid، ما جليش جدّش تركيز
+
+453
+00:34:03,070 --> 00:34:07,330
+ال H بلس، جلّ ال pH تلاتة، و لا فيها سالب منها ال pH
+
+454
+00:34:07,330 --> 00:34:11,210
+بتساوي تلاتة، يعني ال H بلس عشرة أس سالب تلاتة، واحد
+
+455
+00:34:11,210 --> 00:34:11,550
+من ألف
+
+456
+00:34:14,850 --> 00:34:19,610
+جلّي ال base، ال pH بتاعها عشرة، طيب ال pH بتساوي عشرة،
+
+457
+00:34:19,610 --> 00:34:23,510
+إذا ال H بلس عشرة أقل سالب عشرة، يبقى ال hydroxide
+
+458
+00:34:23,510 --> 00:34:26,990
+عشرة أقل سالب أربعة، أو ال pOH بتساوي أربعة، إذا ال
+
+459
+00:34:26,990 --> 00:34:30,890
+pOH بتساوي أربعة، يبقى ال OH بتساوي عشرة أقل سالب
+
+460
+00:34:30,890 --> 00:34:34,690
+أربعة، يبقى جيبنا تركيز ال hydroxide وجيبنا تركيز
+
+461
+00:34:34,690 --> 00:34:39,540
+ال H plus، زي ما احنا عارفين الهيدروكسيد بتفعل مع ال
+
+462
+00:34:39,540 --> 00:34:43,140
+H بلس بنسبة ايه؟ واحد لواحد، بنحسب من
+
+463
+00:34:43,140 --> 00:34:46,440
+millimol H بلس، ال molarity في ال volume، ال
+
+464
+00:34:46,440 --> 00:34:49,220
+millimol الهيدروكسيد، ال molarity في ال volume
+
+465
+00:34:49,220 --> 00:34:52,440
+طيب، صار عندنا millimols، واضح أن العشرة أس سالب
+
+466
+00:34:52,440 --> 00:34:55,500
+تلاتة أكبر من العشرة أس سالب أربعة، يبدو حيزيد عن
+
+467
+00:34:55,500 --> 00:35:00,190
+H بلس، مش هيك؟ يبقى الملي مول H plus excess هتساوى
+
+468
+00:35:00,190 --> 00:35:02,890
+1.7 في عشرة أس سالب تلاتة، متراحوا من بعض
+
+469
+00:35:02,890 --> 00:35:06,830
+يبقى ال H plus 1.7 في عشرة أس سالب تلاتة
+
+470
+00:35:06,830 --> 00:35:10,350
+على ال total volume اللي هو اتنين وتلاتة يعني خمسة
+
+471
+00:35:10,350 --> 00:35:14,310
+بطلع عندي 3.4 في عشرة أس سالب أربعة molar
+
+472
+00:35:14,310 --> 00:35:19,870
+ال pH طبعا minus log لتركيز ال H plus، كويس هذا
+
+473
+00:35:19,870 --> 00:35:26,580
+الكلام يا شباب؟ يعني أنتم مشيتم معايا بشكل سليم
+
+474
+00:35:26,580 --> 00:35:31,700
+الأصل أنه بمجرد النظر، لما تقول والله ال H plus ل
+
+475
+00:35:31,700 --> 00:35:36,000
+المحلول بتساوي ال H plus لل acid، زائد ال H plus
+
+476
+00:35:36,000 --> 00:35:39,160
+اللي جاي من المية، بتقدر على طول تعرف إذا كان ال H
+
+477
+00:35:39,160 --> 00:35:42,080
+plus اللي جاي من المية مهم بالنسبة لك ولا لأ، في
+
+478
+00:35:42,080 --> 00:35:46,380
+البداية، هل هو مهم ولا لأ، هل يمكن إهماله ولا لأ،
+
+479
+00:35:46,380 --> 00:35:51,240
+هذه حاجة تانية، هل هو أكتر من ال acid ولا لأ، في
+
+480
+00:35:51,240 --> 00:35:55,780
+بعض الأحيان، يوجد تلات حالات، بتقول والله ال H plus ده
+
+481
+00:35:55,780 --> 00:35:58,800
+المحلول بيساوي ال H plus اللي جاي من ال acid زائد
+
+482
+00:35:58,800 --> 00:36:02,640
+ال H plus اللي جاي من المية، أنت بتقدر تعرف بناء
+
+483
+00:36:02,640 --> 00:36:07,520
+على قيمة ال H plus اللي جاي من ال acid، هل هل ال H
+
+484
+00:36:07,520 --> 00:36:11,650
+plus اللي جاي من المية يمكن إهماله؟ ولا لا يمكن
+
+485
+00:36:11,650 --> 00:36:15,670
+إهماله، يكونوا قريبين من بعض، ولا ال H بلس اللي جاي
+
+486
+00:36:15,670 --> 00:36:18,430
+من المية هو اللي أكتر كتير من ال H بلس اللي جاي من
+
+487
+00:36:18,430 --> 00:36:21,070
+ال acid، وبالتالي يمكن إهمال ال H بلس اللي جاي من
+
+488
+00:36:21,070 --> 00:36:25,750
+ال acid، هاي التلات أحوال اللي عندك، ونفس الكلام ال
+
+489
+00:36:25,750 --> 00:36:29,150
+base، ال hydroxide، بقدر أقول ال hydroxide في
+
+490
+00:36:29,150 --> 00:36:32,250
+المحلول بيساوي ال hydroxide اللي جاي من ال base
+
+491
+00:36:32,250 --> 00:36:37,140
+زائد ال hydroxide اللي جاي من المية، وهان برضه عندي
+
+492
+00:36:37,140 --> 00:36:40,220
+تلات أحوال، يا إما ال hydroxide اللي جاي من ال base
+
+493
+00:36:40,220 --> 00:36:42,880
+أكبر كتير من ال hydroxide اللي جاي من المية،
+
+494
+00:36:42,880 --> 00:36:47,480
+وبالتالي يمكن إلغاءها، أو إنه ال hydroxide اللي جاي
+
+495
+00:36:47,480 --> 00:36:51,660
+من ال base قريب، يعني عشرة أس سالب سبعة، عشرة أس
+
+496
+00:36:51,660 --> 00:36:58,200
+سالب تمانية، بس قريب من، أو جزء عشرة أس سالب سبعة
+
+497
+00:36:58,200 --> 00:37:00,540
+أو حواليها يعني، خليني أقول لأن عشرة أس سالب
+
+498
+00:37:00,540 --> 00:37:04,900
+تمانية، لأ، مش هتظبط، معناه هل هو قريب منه، وبالتالي لا
+
+499
+00:37:04,900 --> 00:37:09,480
+يمكن إهمال الهيدروكسيد اللي جاي من المية، أو إنه
+
+500
+00:37:09,480 --> 00:37:12,240
+إذا كان كمية الهيدروكسيد اللي جايه من ال base
+
+501
+00:37:12,240 --> 00:37:15,880
+قليلة بالنسبة لكمية الهيدروكسيد اللي جايه من المية،
+
+502
+00:37:15,880 --> 00:37:19,980
+ساعتها من الممكن إلغاء الهيدروكسيد اللي جاي من ال
+
+503
+00:37:19,980 --> 00:37:25,800
+base، هذه هي أحوال ال acid calculations أو ال base
+
+504
+00:37:25,800 --> 00:37:26,480
+calculations
+
+505
+00:37:28,970 --> 00:37:32,250
+التركيز الهيدروجين، التركيز الهيدروكسيد، يبقى يبقى
+
+506
+00:37:32,250 --> 00:37:34,530
+يبقى يبقى يبقى يبقى يبقى يبقى يبقى يبقى يبقى يبقى
+
+507
+00:37:34,530 --> 00:37:36,730
+يبقى يبقى يبقى يبقى يبقى يبقى يبقى يبقى يبقى يبقى
+
+508
+00:37:36,730 --> 00:37:38,530
+يبقى يبقى يبقى يبقى يبقى يبقى يبقى يبقى يبقى يبقى
+
+509
+00:37:38,530 --> 00:37:39,230
+يبقى يبقى يبقى يبقى يبقى يبقى يبقى يبقى يبقى يبقى
+
+510
+00:37:39,230 --> 00:37:44,010
+يبقى يبقى
+
+511
+00:37:44,010 --> 00:37:48,890
+يبقى يبقى يبقى يبقى يبقى يبقى
+
+512
+00:37:48,890 --> 00:37:52,850
+يبعشرة أقصى لتلاتة، وعشرة أقصى لتلاتة، وعشرة أقصى
+
+513
+00:37:52,850 --> 00:37:53,430
+لتلاتة، وعشرة أقصى لتلاتة، وعشرة أقصى لتلاتة، وعشرة
+
+514
+00:37:53,430 --> 00:37:56,550
+أقصى لتلاتة، وعشرة أقصى لتلاتة، وعشرة أقصى لتلاتة
+
+515
+00:37:56,550 --> 00:38:00,090
+وعشرة أقصى لتلاتة، وعشرة أقصى لتلاتة، وعشرة أقصى
+
+516
+00:38:00,090 --> 00:38:00,830
+لتلاتة، وعشرة أقصى لتلاتة، وعشرة أقصى لتلاتة، وعشرة
+
+517
+00:38:00,830 --> 00:38:02,890
+أقصى لتلاتة، وعشرة أقصى لتلاتة، وعشرة أقصى لتلاتة
+
+518
+00:38:02,890 --> 00:38:07,470
+وعشرة أقصى لتلاتة، وعشرة بتبقى عند الاتزان، تلاتة، يعني ال
+
+519
+00:38:07,470 --> 00:38:13,750
+H بلس هالجاب بده يطلع عندك ال hydroxide عشرة أس
+
+520
+00:38:13,750 --> 00:38:17,450
+سالب أربعة، عاشر على هذا، هدول قبل التفاعل كانوا
+
+521
+00:38:17,450 --> 00:38:21,250
+هالجاب، بعد التفاعل طبعا حاجة تانية، طيب يا شباب
+
+522
+00:38:21,250 --> 00:38:26,870
+نيجي نتطلع الآن على ال salts of strong acids وال
+
+523
+00:38:26,870 --> 00:38:34,280
+salts of strong bases، بقول ال strong acids زي إيش
+
+524
+00:38:34,280 --> 00:38:41,400
+غال زي ال HCl، زي ال HCl، بعطينا H plus زائد Cl
+
+525
+00:38:41,400 --> 00:38:46,900
+minus، ال HCl هذا strong ولا weak؟ عارفين؟ طيب ليش
+
+526
+00:38:46,900 --> 00:38:48,740
+هو strong؟
+
+527
+00:38:54,000 --> 00:38:57,860
+لا، مش عشان هيك طبعا، هو صحيح .. صحيح يعني في المية
+
+528
+00:38:57,860 --> 00:39:02,380
+.. في المية يعني بتفكك بشكل كامل، صحيح، لكن مش هذا
+
+529
+00:39:02,380 --> 00:39:05,900
+هو الجواب اللي أنا بديه، يعني عارفين ليش هو قوي؟ ..
+
+530
+00:39:05,900 --> 00:39:14,900
+ليش هو قوي؟ جال لأنه ال conjugate base تبعه ضعيف
+
+531
+00:39:14,900 --> 00:39:19,660
+يبقى هذا weak conjugate base، عارفين إيش معنى أن ال
+
+532
+00:39:19,660 --> 00:39:24,480
+conjugate base تبعه ضعيف؟ هو قوي ماشي، بس إيش
+
+533
+00:39:24,480 --> 00:39:29,540
+معناته يعني ضعيف؟ انتبه عليها شوية، كلمة ضعيف عندي
+
+534
+00:39:29,540 --> 00:39:34,580
+معناها إنه لا يتفاعل مع الماء، هي الضعيف، أي acid
+
+535
+00:39:34,580 --> 00:39:38,580
+ضعيف يعني ما يتفاعلش مع المية، يعني أي .. سواء acid
+
+536
+00:39:38,580 --> 00:39:42,940
+أو base، مدامه weak ما يتفاعلش مع المية، إيش يعني؟
+
+537
+00:39:42,940 --> 00:39:48,060
+يعني لو جيت أنا قلت ال Cl المينوس زائد H2O بتعطينا
+
+538
+00:39:48,060 --> 00:39:52,700
+HCl زائد Hydroxide، بقول هذا التفاعل ما حصلش، لأن ال
+
+539
+00:39:52,700 --> 00:39:57,620
+HCl بتفكك تفكك كامل، لا يمكن يكون موجود على الطرف
+
+540
+00:39:57,620 --> 00:40:02,960
+الأيمن من المعادلة، صح ولا لأ؟ إذا ال HCl هو حمض
+
+541
+00:40:02,960 --> 00:40:08,290
+قوي، ليش هو حمض قوي؟ جال لأنه .. لأن ال conjugate
+
+542
+00:40:08,290 --> 00:40:12,870
+base تبعه ضعيف، إيش يعني ضعيف؟ لا يتفاعل مع الماء،
+
+543
+00:40:12,870 --> 00:40:16,470
+يعني لا يؤثر، لا يغير ال pH، لا بيعطينا hydroxide
+
+544
+00:40:16,470 --> 00:40:20,870
+ولا بيعطينا H plus، ما بيغيّرش ال pH للمية، طيب لو إجينا
+
+545
+00:40:20,870 --> 00:40:27,690
+كمان لل sodium hydroxide، بنقول بيعطينا Sodium زائد
+
+546
+00:40:27,690 --> 00:40:31,230
+Hydroxide، Sodium Hydroxide هذا عبارة عن قاعدة إيه
+
+547
+00:40:31,230 --> 00:40:39,370
+شملها قوية، ليش هي قوية؟ لأنه ال conjugate acid
+
+548
+00:40:39,370 --> 00:40:47,830
+تبعها ضعيف، إيش يعني ضعيف؟ يعني Sodium مع المية
+
+549
+00:40:52,020 --> 00:40:55,660
+ما بيعطيناش H بلس، هذا التفاعل ما بيحصلش، لأن ال sodium hydroxide
+
+550
+00:40:55,660 --> 00:41:00,700
+بيرجع ال sodium hydroxide بتفكك تفككه كامل، طب أنا
+
+551
+00:41:00,700 --> 00:41:05,800
+عندي الملح NaCl، من إيش مشتق؟ مشتق من strong
+
+552
+00:41:05,800 --> 00:41:11,340
+acid و strong base، مش هيك؟ هذا الملح من وين مشتق؟
+
+553
+00:41:11,340 --> 00:41:13,500
+من strong base
+
+554
+00:41:15,800 --> 00:41:18,060
+هو مشتق .. ما بديش أكتب عليه strong base، حتفكر هو
+
+555
+00:41:18,060 --> 00:41:21,900
+strong base، مشتق من strong base و strong acid،
+
+556
+00:41:21,900 --> 00:41:27,580
+يبقى لا ال sodium بتفعل مع المية ولا ال chloride
+
+557
+00:41:27,580 --> 00:41:34,420
+بتفعل مع المية، يبقى هل .. هل ال pH للمية راح
+
+558
+00:41:34,420 --> 00:41:39,640
+تختلف؟ لأ، ال pH للمية مش راح تختلف، عشان هيك دائما
+
+559
+00:41:39,640 --> 00:41:45,510
+الأملاح المشتقة من strong acid و strong base، أملاح
+
+560
+00:41:45,510 --> 00:41:52,950
+لا تؤثر على ال pH للمية، بمعنى أن الماء يبقى
+
+561
+00:41:52,950 --> 00:41:59,410
+متعادل، يعني لو حطينا الأملاح هذه في المية، ال pH
+
+562
+00:41:59,410 --> 00:42:00,710
+هتبقى متعادلة
+
+563
+00:42:09,220 --> 00:42:13,920
+ال NaCl ملح ضعيف؟ لأ، لأ، لأ، ما بتقولش عنه هو
+
+564
+00:42:13,920 --> 00:42:17,700
+بتفكك تفكك كامل، بتفكك تفكك كامل، يعني عندي هاي
+
+565
+00:42:17,700 --> 00:42:23,920
+ال H2O، هاي Na Plus زائد Cl Minus زائد H2O بتعطينا
+
+566
+00:42:23,920 --> 00:42:29,720
+H Plus زائد Hydroxide زائد Na Plus زائد Cl Minus،
+
+567
+00:42:29,720 --> 00:42:32,900
+هاي هذا مع هذا، وهي هذا مع هذا، Spectator Ions
+
+568
+00:42:32,900 --> 00:42:37,530
+كلهم، فهو الملح مشتق من ال strong acid و strong
+
+569
+00:42:37,530 --> 00:42:40,170
+base، إذا كان مشتق من ال strong acid و strong base،
+
+570
+00:42:40,170 --> 00:42:44,230
+فمعنى الكلام أن ال conjugate base very weak، ما لها
+
+571
+00:42:44,230 --> 00:42:47,210
+تفاعل مع الماء، و ال conjugate acid very weak، ما لها
+
+572
+00:42:47,210 --> 00:42:51,490
+تفاعل مع الماء، يبقى ال pH مش راح تتغير، حتبقى
+
+573
+00:42:51,490 --> 00:42:58,040
+ثابتة، هذا الكلام بيخلينا نقول إنه كل الأملاح
+
+574
+00:42:58,040 --> 00:43:01,760
+المشتقة من strong acid و strong bases، مهما كان
+
+575
+00:43:01,760 --> 00:43:07,800
+تركيزها، الأصل إنه لا تغير، أو لا تؤثر على ال pH
+
+576
+00:43:07,800 --> 00:43:13,920
+للمية، وبالتالي ال pH دائما هتبقى 7، مش هيك؟ يعني
+
+577
+00:43:13,920 --> 00:43:20,390
+الأملاح زي مثلا Potassium Perchlorate، Sodium
+
+578
+00:43:20,390 --> 00:43:29,730
+Nitrate، Potassium Iodide، Calcium
+
+579
+00:43:29,730 --> 00:43:34,890
+Chloride، كلها مشتقة من قاعدة قوية و حمض قوي،
+
+580
+00:43:34,890 --> 00:43:42,340
+انتهى، لا تؤثر على ال pH، طبعا هذا كلام بنقوله لعامة
+
+581
+00:43:42,340 --> 00:43:46,160
+الناس، لكن لكم أنتم بالذات بنقول لكم لازم ناخد
+
+582
+00:43:46,160 --> 00:43:51,820
+بالنا من النقطة، إنه لما التركيز ال .. ال .. السلط
+
+583
+00:43:51,820 --> 00:43:58,780
+يكون عالي، طب هو إيش السلط، هاي H2O بتفكك، بيعطينا H
+
+584
+00:43:58,780 --> 00:44:02,280
+Plus زائد Hydroxide، طب إيش بيحصل لما نحط عليها
+
+585
+00:44:02,280 --> 00:44:08,500
+NaCl؟ هل ال Na Plus هو أيون مشترك، عشان الرجوع اللي
+
+586
+00:44:08,500 --> 00:44:12,880
+ورا؟ هل ال NaCl معناه أيون مشترك؟ إيش يعتبر NaCl
+
+587
+00:44:12,880 --> 00:44:20,350
+بالنسبة لل H2O؟ Diverse ions، طب إيش بيحصل فيها؟ ال H
+
+588
+00:44:20,350 --> 00:44:26,130
+بلس بيحوطه والله سفير من ال Cl المينوس، والهيدروكسيد
+
+589
+00:44:26,130 --> 00:44:34,550
+برضه بيحوطه سفير من ال sodium، إذا
+
+590
+00:44:34,550 --> 00:44:40,060
+صار في عندي حجب، يبقى إيش بيحصل للمياه؟ بتتفكك
+
+591
+00:44:40,060 --> 00:44:44,660
+بزيادة، لأن ال diverse ions إيش بتعمل؟ بتزيد التفكك
+
+592
+00:44:44,660 --> 00:44:48,040
+عشان هيك، صح، المحلول بيبقى متعادل بمعنى أن ال H
+
+593
+00:44:48,040 --> 00:44:52,280
+plus بيساوي ال hydroxide، لكن ال pH بتبطل 7.25
+
+594
+00:44:52,280 --> 00:44:57,180
+درجة ال pH بتبعد عن 7، لأن تركيز ال H plus بده يزيد،
+
+595
+00:44:57,180 --> 00:45:00,500
+وتركيز ال hydroxide بده يزيد، ليش زاد؟ نتيجة ال
+
+596
+00:45:00,500 --> 00:45:04,120
+diverse ions؟ نتيجة الحجب اللي قامله ال diverse
+
+597
+00:45:04,120 --> 00:45:07,720
+ions، لكن يا شباب طبعا بإمكاننا نعمل .. نحسب هذا
+
+598
+00:45:07,720 --> 00:45:12,280
+الكلام، كمان بإمكاننا نعمله، لكن احنا هناخد مجازا ..
+
+599
+00:45:12,280 --> 00:45:17,620
+مجازا أن ال pH ل ال strong acid .. ل ال salts of
+
+600
+00:45:17,620 --> 00:45:21,380
+strong acids و ال salts of strong bases دائما
+
+601
+00:45:21,380 --> 00:45:26,560
+هتظلها سبعة، لكن هل هي سبعة؟ يقوموا يقولوا سبعة،
+
+602
+00:45:26,560 --> 00:45:31,030
+لأ، مش سبعة، بنقدر نحسبها في سهولة، بنشوف إيش ال ionic
+
+603
+00:45:31,030 --> 00:45:35,510
+strength، لما تركيز الصوت من طلع ال ionic strength،
+
+604
+00:45:35,510 --> 00:45:41,970
+و من دي باي هيك ال equation، بنحسب ال F ل ال Na
+
+605
+00:45:41,970 --> 00:45:47,390
+plus و ال F ل ال H plus و ال F ل ال hydroxide في
+
+606
+00:45:47,390 --> 00:45:52,450
+وجود ال NaCl، و منهم بنحسب ال Kw الجديدة،
+
+607
+00:45:54,710 --> 00:45:59,690
+خلاص؟ وعلى أساسها بنعود KW الجديدة، بتساوي H plus
+
+608
+00:45:59,690 --> 00:46:03,050
+في ال hydroxide، بنحسب قيمة ال H plus وقيمة ال
+
+609
+00:46:03,050 --> 00:46:08,170
+hydroxide، هنلاقي أن ال pH بتنزل عن سبعة، ال pH أقل
+
+610
+00:46:08,170 --> 00:46:12,350
+من سبعة، لكن المحلول متعادل، لأنه دائما ال H plus
+
+611
+00:46:12,350 --> 00:46:18,010
+بده يساوي ال hydroxide، ماشي يا شباب؟ إذا
\ No newline at end of file
diff --git a/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/GfMveIZXq9A_raw.srt b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/GfMveIZXq9A_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..e2050e386cf689101077656807fd2394d7d0d1c3
--- /dev/null
+++ b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/GfMveIZXq9A_raw.srt
@@ -0,0 +1,2116 @@
+1
+00:00:20,700 --> 00:00:23,260
+بسم الله الرحمن الرحيم والحمد لله والصلاة والسلام
+
+2
+00:00:23,260 --> 00:00:28,580
+على رسول الله طبعا فى البداية بنرحب فىكم جدا يعنى
+
+3
+00:00:28,580 --> 00:00:34,280
+فى هذا المساق مساق كيميا تحليلية فى الأصل أنه لازم
+
+4
+00:00:34,280 --> 00:00:40,080
+نكون ماخدين كيميا عامة ألف وكيميا عامة با ونجحين
+
+5
+00:00:40,080 --> 00:00:47,400
+فيهم لكن يعني الجامعات تشتريت أنه على الأقل تكون
+
+6
+00:00:47,400 --> 00:00:51,590
+ماخد كيميا عامة باو مش ضروري تكون ناجحي و ممكن
+
+7
+00:00:51,590 --> 00:00:54,730
+تكون راسي فيه عشان تسجل المادة هذه بس لازم تكون
+
+8
+00:00:54,730 --> 00:00:58,890
+مرت عليك فانا بعنصح ان كل الطلاب يكونوا ماخدين
+
+9
+00:00:58,890 --> 00:01:04,250
+كيميا عامة ألف و كيميا عامة با في البداية اجمالا
+
+10
+00:01:04,250 --> 00:01:10,210
+عن المساق اللي موجود حاليا مساق كيميا تحليلية اش
+
+11
+00:01:10,210 --> 00:01:15,520
+بيعالج؟مثاق الكيميا التحليلية بيعالج أحد فروع
+
+12
+00:01:15,520 --> 00:01:18,220
+الكيميا التحليلية لأنه لو أتينا نتكلم عن الكيميا
+
+13
+00:01:18,220 --> 00:01:24,320
+التحليلية يمكن تقسيمها لقسمين أساسيين كيميا
+
+14
+00:01:24,320 --> 00:01:30,080
+تحليلية وصفية او qualitative analytical chemistry
+
+15
+00:01:31,160 --> 00:01:38,380
+وهذه بتوعنا بتحديد نوعية العناصر المكونة لعينة
+
+16
+00:01:38,380 --> 00:01:44,060
+معينة أو نوعية المواد المكونة لعينة معينة والفرع
+
+17
+00:01:44,060 --> 00:01:51,360
+الآخر بيتعلق بتحديد كمية مادة أو مواد معينة موجودة
+
+18
+00:01:51,360 --> 00:01:55,470
+في عينةفبالتالي الكيمة التحليلية يمكن تقسيمها
+
+19
+00:01:55,470 --> 00:02:03,450
+لكيمة تحليلية وصفية بمعنى كيمة تحليلية تتعرض
+
+20
+00:02:03,450 --> 00:02:10,570
+لمعرفة نوعية المكونات اللي بتكون عينما وكيمة
+
+21
+00:02:10,570 --> 00:02:15,310
+تحليلية كمية أي تقدير كمية هذه المكونات اللي
+
+22
+00:02:15,310 --> 00:02:18,590
+موجودة في عينما
+
+23
+00:02:20,920 --> 00:02:25,400
+ايضا يمكن تقسيم الكيما التحليلية لقسمين مثلا يمكن
+
+24
+00:02:25,400 --> 00:02:30,550
+نقول والله كيما تحليلية تقليدية بمعنىWet
+
+25
+00:02:30,550 --> 00:02:34,650
+Analytical Chemistry أو بمعنى Classical Analytical
+
+26
+00:02:34,650 --> 00:02:40,290
+Chemistry يعني كيميا تحليلية تستخدم المحاليل
+
+27
+00:02:40,290 --> 00:02:45,130
+والمفاهيم التقليدية اللي تم عرضها ومناقشتها
+
+28
+00:02:45,130 --> 00:02:53,160
+وتفسيرها ويعني استخدامها من عشرات السنينمطلع يعني
+
+29
+00:02:53,160 --> 00:02:57,040
+القرن التاسع عشر وما بعده فهذه classical
+
+30
+00:02:57,040 --> 00:03:00,740
+analytical chemistry مفاهيمها يعني أساسية جدا
+
+31
+00:03:00,740 --> 00:03:05,980
+وموجودة من قديم الزمان والفرع الأخر هو
+
+32
+00:03:05,980 --> 00:03:10,180
+instrumental analytical chemistry بمعنى ال
+
+33
+00:03:10,180 --> 00:03:13,420
+analytical chemistry أو الكيميا التحليلية اللي
+
+34
+00:03:13,420 --> 00:03:20,100
+بتستخدم الأجهزةاحنا خلال شغلنا هذا في الحقيقة خلال
+
+35
+00:03:20,100 --> 00:03:24,140
+الفصل هذا بنتعرض لنوع واحد من أنواع الكيميا
+
+36
+00:03:24,140 --> 00:03:27,940
+التحليلية اللي هو ال quantitative analytical
+
+37
+00:03:27,940 --> 00:03:34,900
+chemistry بمعنى تقدير كمية المواد المكونة لعين ما
+
+38
+00:03:34,900 --> 00:03:40,700
+او تقدير كمية مادة موجودة في عين ما فهذا اسمه
+
+39
+00:03:40,700 --> 00:03:44,940
+quantitative analytical chemistry مش بس هيك لأ
+
+40
+00:03:44,940 --> 00:03:49,020
+احنا بنستخدمالـ Classical Analytical Chemistry
+
+41
+00:03:49,020 --> 00:03:52,560
+بمعنى Wet Chemistry بمعنى المفاهيم الأساسية
+
+42
+00:03:52,560 --> 00:03:55,600
+الأساسية
+
+43
+00:03:55,600 --> 00:04:00,640
+اللى موجودة من قديم الزمان ايه كويس؟ لأ بنستخدمش
+
+44
+00:04:00,640 --> 00:04:05,520
+الكيميا التحليلية الآلية ففقط بنستخدم المفاهيم
+
+45
+00:04:05,520 --> 00:04:09,580
+الأساسية للكيميا التحليلية التقليدية و اللى بتنقسم
+
+46
+00:04:09,580 --> 00:04:16,240
+لقسمين تحليل وزنى وتحليل حجمىهل معنى هذا الكلام
+
+47
+00:04:16,240 --> 00:04:20,400
+أنه احنا بندرس كيمة تحليلية تقليدية يعني تاريخية
+
+48
+00:04:20,400 --> 00:04:25,260
+بمعنى أنه والله عفه عليها الزمن ويعني أصبحت خارج
+
+49
+00:04:25,260 --> 00:04:29,420
+إطار التاريخ مع أن الناس طلت على الجمر الآن؟ اقول
+
+50
+00:04:29,420 --> 00:04:33,940
+لأ أبدا، لكن احنا بنستخدم المفاهيم أو بنتعلم
+
+51
+00:04:33,940 --> 00:04:38,690
+المفاهيم الأساسية للتحليلو هذه المفاهيم الأساسية
+
+52
+00:04:38,690 --> 00:04:43,550
+لابد من معرفتها إذا كان بدنا نحلل المواد بطرق صحية
+
+53
+00:04:43,550 --> 00:04:48,650
+أو حتى لو كنا بدنا نستخدم الأجهزة لابد إلا إن نكون
+
+54
+00:04:48,650 --> 00:04:55,430
+عارفين معرفة تامة كيف بيتمالتحليل أو كيف بتتم
+
+55
+00:04:55,430 --> 00:05:01,330
+عملية التحليل فبالتالي مابدناش يعني نشعر او يكون
+
+56
+00:05:01,330 --> 00:05:04,410
+في مفهومنا انه اه والله احنا بندرس كيميا classical
+
+57
+00:05:04,410 --> 00:05:08,410
+analytical chemistry يعني هذا شيء قديم ويعني بس
+
+58
+00:05:08,410 --> 00:05:11,790
+مجرد يعني بندرس ولا حاجة تاريخية او عشان فقط ندرس
+
+59
+00:05:11,790 --> 00:05:20,190
+ولا ابدا لدرجة انه بعض الموادالان لا يتم تحليلها
+
+60
+00:05:20,190 --> 00:05:24,490
+بطريقة دقيقة للغاية إلا باستخدام الطرق التقليدية
+
+61
+00:05:24,490 --> 00:05:27,650
+اللى أنا بتكلم عنها أو اللى هناخد أمثل على هذا
+
+62
+00:05:27,650 --> 00:05:31,770
+الكلام يعني الطرق التقليدية هي اسما طرق تقليدية
+
+63
+00:05:31,770 --> 00:05:38,670
+لكن من ناحية واقع تعتبرمن الطرق المستخدمة بكثرة
+
+64
+00:05:38,670 --> 00:05:43,410
+إما كطرق أولية للوصول إلى عملية التحليل أو كطرق
+
+65
+00:05:43,410 --> 00:05:51,470
+كاملة قياسية تستخدم بالفعل في عملية التحليل فأرجو
+
+66
+00:05:51,470 --> 00:05:57,490
+أن هذا المفهوم يكون واضح بالنسبة لناماذا ندرس في
+
+67
+00:05:57,490 --> 00:06:02,350
+الكيميا التحليلية حاليا؟ ندرس quantitative
+
+68
+00:06:02,350 --> 00:06:07,010
+analytical chemistry quantitative يعني حاجة كمية
+
+69
+00:06:07,010 --> 00:06:11,110
+أرقام مثلا ممكن أسألك جداش و الله وزنك بتقولي رقم
+
+70
+00:06:11,110 --> 00:06:15,170
+جداش طولك بتقولي رقم ممكن أسألك الساعة اللي في
+
+71
+00:06:15,170 --> 00:06:20,970
+إيدك إيش نسبة الانحاس فيها مثلا بتقولي رقم
+
+72
+00:06:20,970 --> 00:06:26,480
+فبالتالي نتعامل مع أرقام بشكل أساسيبنتعامل مع
+
+73
+00:06:26,480 --> 00:06:32,220
+نتائج، بنتعامل مع بيانات، بنتعامل مع بيانات،
+
+74
+00:06:32,220 --> 00:06:37,780
+وبالتالي مدام إحدى أغلب شغلنا بيتعلق بالبيانات،
+
+75
+00:06:37,780 --> 00:06:45,940
+بالنتائج، إذا لابد من معرفة كيفية معالجة البيانات
+
+76
+00:06:46,600 --> 00:06:51,120
+بشكل دقيق وبشكل صحيح مش كافي انك تعطيني نتيجة
+
+77
+00:06:51,120 --> 00:06:56,040
+تقولي والله الجواب هو عبارة عن مثلا 76 كيلو جرام
+
+78
+00:06:56,040 --> 00:07:01,900
+وزني 76 كيلو جرام انا بفهم على طول كعالم ايش هي
+
+79
+00:07:01,900 --> 00:07:04,920
+اداة القياس اللى انت استخدمتها للوصول الى هذا
+
+80
+00:07:04,920 --> 00:07:09,200
+الوزنمثلا او تقول مثلا ستة و سبعين و واحد من عشرة
+
+81
+00:07:09,200 --> 00:07:15,000
+الها مفهوم اخر الها مفهوم اخر او ستة و سبعين و
+
+82
+00:07:15,000 --> 00:07:19,560
+مثلا تلاتة و عشرين من مية الها مفهوم مختلف
+
+83
+00:07:19,560 --> 00:07:23,520
+فبالتالي معالجة البيانات تفسر الكلام بالنسبة لل
+
+84
+00:07:23,520 --> 00:07:28,780
+experiments احنا بنتعامل مع تجارب معالجة البيانات
+
+85
+00:07:28,780 --> 00:07:35,250
+في هذه التجارب كنتائج الها مدلولاتالعالم لما يقرأ
+
+86
+00:07:35,250 --> 00:07:42,230
+النتيجة بيفهم من هذه النتيجة معلومات موجودة داخل
+
+87
+00:07:42,230 --> 00:07:45,470
+النتيجة هذه انت مش ماخد بالك منها بعض الأحيان لكن
+
+88
+00:07:45,470 --> 00:07:50,210
+مجرد ذكرك للنتيجة برقم او رقمين او تلاتة او اربعة
+
+89
+00:07:50,210 --> 00:07:54,970
+هذا له دلالات علمية مهمة جدا فبما انه احنا بنتعامل
+
+90
+00:07:54,970 --> 00:07:59,150
+مع نتائج رقمية عشان هيك اول chapter عيننا هيكون
+
+91
+00:07:59,150 --> 00:08:03,820
+chapter طويل في الحقيقةشبتر بعد المقدمة اللي هو
+
+92
+00:08:03,820 --> 00:08:08,560
+شبتر طويل اسمه معالجة البيانات او data handling
+
+93
+00:08:08,560 --> 00:08:12,320
+كيف بدي اعالج النتائج اللي انا بحصل عليها كيف بدي
+
+94
+00:08:12,320 --> 00:08:19,000
+اعالج النتائج اللي انا بحصل عليها ايش هندرس فيه
+
+95
+00:08:19,000 --> 00:08:22,580
+هندرس فيه يعني مقدمة صغيرة ايش يعني precision و
+
+96
+00:08:22,580 --> 00:08:25,200
+ايش يعني accuracy هنشوف مفاهيمه ان شاء الله
+
+97
+00:08:25,200 --> 00:08:27,880
+المحاضرة الجاية هندرس ايضا
+
+98
+00:08:30,720 --> 00:08:33,800
+حاجة مرت عليك في السنة الأولى لكن مرت عليك مرور
+
+99
+00:08:33,800 --> 00:08:38,230
+الكرام ليا significant figuresاحنا درسناها في
+
+100
+00:08:38,230 --> 00:08:42,010
+السنة الأولى كمفهوم عام أرقام معنوية بمعنى أرقام
+
+101
+00:08:42,010 --> 00:08:46,790
+لها معنى لها مغزة احنا في هذا الفصل هحنحاول انه
+
+102
+00:08:46,790 --> 00:08:52,410
+نتوسع في دراسة الأرقام المعنوية أو significant
+
+103
+00:08:52,410 --> 00:09:00,770
+figures لدرجة نوصل من خلالها لطريقة نفهم فيها كل
+
+104
+00:09:02,330 --> 00:09:06,130
+نتيجة ليش عدد ال significant figures اللي فيها أو
+
+105
+00:09:06,130 --> 00:09:09,930
+عدد الأرقام أو ال digits اللي فيها هالجد ليش لازم
+
+106
+00:09:09,930 --> 00:09:13,930
+نفهم هذا الكلام بشكل دقيق و بالذات في حالة ما يكون
+
+107
+00:09:13,930 --> 00:09:17,530
+في عندي حاجة بقولها uncertainty لأنه أنا بشتغل
+
+108
+00:09:17,530 --> 00:09:21,430
+تجارب التجارب اللي بشتغلها كل تجرب بكرهها على
+
+109
+00:09:21,430 --> 00:09:25,870
+الأقل تلت لخمس مرات لما نشتغل تجربة تلت لخمس مرات
+
+110
+00:09:25,870 --> 00:09:30,560
+بحصلش دائما على نفس النتيجة بحصل على عدة نتائجطب
+
+111
+00:09:30,560 --> 00:09:35,920
+هذه النتائج اللي انا حصلت عليها يعني في النهاية
+
+112
+00:09:35,920 --> 00:09:41,720
+مدير المختبر او طالب التحليل بده نتيجة بفهمش تقوله
+
+113
+00:09:41,720 --> 00:09:44,400
+والله اه نتيجة الأولى كذا و التانية كذا و التانية
+
+114
+00:09:44,400 --> 00:09:47,480
+.. بظبطش عنده بده نتيجة نهائية طب انت مدام عندك
+
+115
+00:09:47,480 --> 00:09:50,820
+عدة نتائج اذا في عندك حاجة بنقولها uncertain انت
+
+116
+00:09:50,820 --> 00:09:54,720
+بدك عدم تأكد في النتائج فكيف نحسب ال significant
+
+117
+00:09:54,720 --> 00:09:56,620
+figures في وجود
+
+118
+00:09:59,750 --> 00:10:03,970
+uncertainty معينة سواء كانت العملية عملية ضرب او
+
+119
+00:10:03,970 --> 00:10:07,810
+فسمة او جامعة او طرح هنشوف هذا كلها بنوع من
+
+120
+00:10:07,810 --> 00:10:12,230
+التفصيل ايضا كما ذكرت بنعمل العملية اكثر من مرة او
+
+121
+00:10:12,230 --> 00:10:15,530
+التجربة بنعملها اكثر من مرة فبالتالي في عندك
+
+122
+00:10:15,530 --> 00:10:20,310
+uncertainty في عندك حيود عن المتوسط في عندك متوسط
+
+123
+00:10:20,310 --> 00:10:24,450
+للنتائج نعم لكن في عندك نتائج اقل من المتوسط
+
+124
+00:10:24,450 --> 00:10:33,730
+ونتائج اعلى من المتوسطو هذا بيقودنا لدراسة
+
+125
+00:10:33,730 --> 00:10:39,010
+الانحراف المعياري جداش نتائجك فيها spread فيها
+
+126
+00:10:39,010 --> 00:10:44,070
+انتشار هل هي قريبة من المتوسط كتير ولا متباعدة
+
+127
+00:10:44,070 --> 00:10:48,770
+وبعيدة عن المتوسط هذا بنقوله ال standard deviation
+
+128
+00:10:48,770 --> 00:10:52,570
+و هندرس عدة أنواع من أنواع ال standard deviation
+
+129
+00:10:54,560 --> 00:10:59,760
+أيضا شيء مهم جدا انت الآن عملت التجربة و عدتها
+
+130
+00:10:59,760 --> 00:11:06,520
+أكمن مرة عدة مرات فمن ناحية إحصائية مدى او درجة
+
+131
+00:11:06,520 --> 00:11:12,100
+الثقة على انه نتيجتكقريبة او تقع فيه مدى النتيجة
+
+132
+00:11:12,100 --> 00:11:16,620
+الصحيحة جديش انت عملت التجربة عدة مرات صحيح و حصلت
+
+133
+00:11:16,620 --> 00:11:22,020
+على نتائج صحيح لكن هل عندك ثقة ان نتائجك هذه قريبة
+
+134
+00:11:22,020 --> 00:11:26,520
+إلى حد ما من النتيجة الصحيحة ولا لا؟طب جداش درجة
+
+135
+00:11:26,520 --> 00:11:32,480
+الثقة هل نستطيع حساب المدى اللى بنتوقع احنا
+
+136
+00:11:32,480 --> 00:11:35,460
+نتيجتنا صحيحة فيه او قريبة من نتيجة الصحيحة فيه
+
+137
+00:11:35,460 --> 00:11:39,900
+عند درجة ثقة معينة مثلا 90% انا متأكد ان نتيجتي
+
+138
+00:11:39,900 --> 00:11:46,860
+بتقع في هذا ال range او 95% او 99%؟فحنشوف حاجة
+
+139
+00:11:46,860 --> 00:11:52,440
+بنقولك confidence limit و ندرس يعني كيف نحسبها
+
+140
+00:11:52,440 --> 00:12:01,480
+أيضا أثناء عملك في مختبر أو في مؤسسة علمية بحثية
+
+141
+00:12:02,480 --> 00:12:06,800
+وانت بتشتغل دائما على تحليل مواد معينة او مادة
+
+142
+00:12:06,800 --> 00:12:10,640
+معينة عشان تبسط الموضوع فخلال هالخبرة القوية اللي
+
+143
+00:12:10,640 --> 00:12:14,700
+تكونت عندك وانت دائما ابتجري نفس ال procedure عشان
+
+144
+00:12:14,700 --> 00:12:19,450
+تحلل نفس المادةمئات المرات في اليوم أو عشرات
+
+145
+00:12:19,450 --> 00:12:25,030
+المرات في اليوم تكونت عندك قناعة ان في طريقة تانية
+
+146
+00:12:25,030 --> 00:12:31,890
+أسهل لعمل التحليل او أسرع مهم جدا او أرخص انت
+
+147
+00:12:31,890 --> 00:12:35,950
+العملية بتعملها 100 مرة في اليوم لو وفرت دولار في
+
+148
+00:12:35,950 --> 00:12:41,130
+التحليل هي 100 دولار في اليوم حلوين على مستوى
+
+149
+00:12:41,130 --> 00:12:45,670
+العالم ممكن يكون عشرات ألف بل مئات ألف دولاراتممكن
+
+150
+00:12:45,670 --> 00:12:50,650
+تكون الطريقة اللى انت بتعتقد انه يمكن استخدامها
+
+151
+00:12:50,650 --> 00:12:53,810
+الجديدة اللى بتعتقد انه يمكن استخدامها ممكن نقول
+
+152
+00:12:53,810 --> 00:13:00,150
+والله هذه الطريقة يعني
+
+153
+00:13:00,150 --> 00:13:04,450
+لا تستخدم مواد سامة مضرة بالبيئة هذا عنصر مهم جدا
+
+154
+00:13:04,450 --> 00:13:07,360
+إيجابي جداإذا كانت الطريقة القياسية اللي احنا
+
+155
+00:13:07,360 --> 00:13:10,700
+بنستخدمها الآن تستخدم مواد مضرة في البيئة، والله
+
+156
+00:13:10,700 --> 00:13:13,020
+هذه مشكلة، لكن إذا كانت الطريقة الجديدة اللي أنت
+
+157
+00:13:13,020 --> 00:13:17,160
+بتقترحها هي طريقة لا تستخدم مواد مضرة بالبيئة،
+
+158
+00:13:17,160 --> 00:13:22,620
+فهذا يعتبر إنجاز مهم جدا على مستوى البشرية حتىطيب
+
+159
+00:13:22,620 --> 00:13:25,480
+لكن في النهاية بنسأل حالنا السؤال هالطريقة اللى
+
+160
+00:13:25,480 --> 00:13:30,060
+بيطرحنا ممتازة جدا شكلها حلو كتير لكن هل تعطي
+
+161
+00:13:30,060 --> 00:13:34,560
+نتائج مكافئة للطريقة القياسية ولا لأ دائما هل تعطي
+
+162
+00:13:34,560 --> 00:13:38,960
+نتائج مكافئة للطريقة القياسية ولا لأ بدنا نتعلم
+
+163
+00:13:38,960 --> 00:13:45,980
+كيف نحكم على طريقة ما جديدةهل نتائجها تعتبر مكافئة
+
+164
+00:13:45,980 --> 00:13:51,060
+لنتائج طريقة قياسية وبالتالي يمكن استخدامها عيوبا
+
+165
+00:13:51,060 --> 00:13:55,860
+عن الطريقة القياسية ولا لأ فهذا برضه شيء هنتعرضله
+
+166
+00:13:55,860 --> 00:14:01,820
+برضه كمان يعني في كثير من الأحيان احنا بنعمل تجارب
+
+167
+00:14:01,820 --> 00:14:06,140
+و في النهاية بنرسم علاقة خط مستقيم ما بين ال
+
+168
+00:14:06,140 --> 00:14:11,250
+signal اللي هي الإشارة و ما بين التركيزفممكن
+
+169
+00:14:11,250 --> 00:14:15,090
+النقاط يقعوا على الخط المستقيم وممكن يقعوا حواليه
+
+170
+00:14:15,090 --> 00:14:20,170
+ونرسم أحسن خط مستقيم فبدنا نتعلم كيف نرسم الخط
+
+171
+00:14:20,170 --> 00:14:23,930
+المستقيم او بالاخرى يعني انا مش معني كتير برسم
+
+172
+00:14:23,930 --> 00:14:29,510
+الخط المستقيم بقدر ما انا معني بكتابة معادلة الخط
+
+173
+00:14:29,510 --> 00:14:34,670
+المستقيم فكيف بدي اكتب او اصل معادلة الخط المستقيم
+
+174
+00:14:34,670 --> 00:14:39,110
+هنشوف هذا الكلام بالاضافة لبعض التفاصيلات الأخرىكل
+
+175
+00:14:39,110 --> 00:14:43,050
+هذا الكلام هندرسه في chapter طويل شوية هو chapter
+
+176
+00:14:43,050 --> 00:14:49,150
+المقدمة تتعلق بمعالجة البيانات قد يشعر بعضه ان هذا
+
+177
+00:14:49,150 --> 00:14:55,100
+حسابرياضيات مش كيميا صحيح جزء منه كبير هو عبارة عن
+
+178
+00:14:55,100 --> 00:15:00,380
+statistics احصى جزء كبير منه يعني رياضيات مالوش
+
+179
+00:15:00,380 --> 00:15:08,780
+خليني اقول علاقة يعني واضحة او يعني علاقة مباشرة
+
+180
+00:15:08,780 --> 00:15:14,760
+كتير بالرياضيات بالكيميا لكن هو يعتبر في الصميم
+
+181
+00:15:14,760 --> 00:15:20,910
+تطبيقاتتطبيقات مهمة جدا للرياضيات في الكيميا بحيث
+
+182
+00:15:20,910 --> 00:15:24,170
+إنه هي اللي بتفسر النتائج تبعتنا بشكل سليم وهي
+
+183
+00:15:24,170 --> 00:15:27,990
+اللي بتعرفنا إذا كان شغلنا جيد ولا مش جيد صحيح إلى
+
+184
+00:15:27,990 --> 00:15:31,090
+حد ما ولا مش صحيح يمكن استخدامه ولا لا يمكن
+
+185
+00:15:31,090 --> 00:15:34,590
+استخدامه تعبيرنا عن نتائجنا جيد ولا مش جيد لابد من
+
+186
+00:15:34,590 --> 00:15:39,030
+أنه ندرس هذا ال chapter بتمعهم وحتحس إن شاء الله
+
+187
+00:15:39,030 --> 00:15:43,630
+في نهايته إنه صار في عندك قدرة جيدة على الحكم على
+
+188
+00:15:44,290 --> 00:15:51,630
+يعني نتائجك بشكل أفضل كتير بعد هيك يا شباب هندرس
+
+189
+00:15:51,630 --> 00:15:55,450
+طبعا كيميا واحنا راحين نفترض انه معلوماتك في
+
+190
+00:15:55,450 --> 00:16:00,050
+الكيميا ضاحلة فهنبدأ للأمانة يعني ب .. يعني بداية
+
+191
+00:16:00,050 --> 00:16:04,190
+مبسطة كتير chapter مقدمة بنرجع فيه كل الحسابات
+
+192
+00:16:04,190 --> 00:16:08,800
+الكيميائية اللي أخدناهافي سنة أولى لكن بدك تاخد
+
+193
+00:16:08,800 --> 00:16:13,120
+بالك انه هذه اخر سنة او هذه اخر فصل بتاخد فيه
+
+194
+00:16:13,120 --> 00:16:15,900
+مراجعات اخدت مراجعات في أولى ثانوي و في ثانية
+
+195
+00:16:15,900 --> 00:16:20,200
+ثانوي و في ثانوية العامة و في سنة أولى و كله كان
+
+196
+00:16:20,200 --> 00:16:24,020
+اشي يعني دايما بتراجع مفاهيم معينة و بتزيد عليها
+
+197
+00:16:24,020 --> 00:16:29,450
+شوية الان الفصل هذا هيكون اخر فصلقبل العمل يمكن
+
+198
+00:16:29,450 --> 00:16:34,010
+انه اتراجع في شيء و احنا هنراجعه بتوسع و هنطوي
+
+199
+00:16:34,010 --> 00:16:37,970
+صفحة حاجة اسمها حسابات كيميائية انتهى خلاص مافيش
+
+200
+00:16:37,970 --> 00:16:41,590
+بعدين حسابات كيميائية في ما يتعلق بالتحليل فهندرس
+
+201
+00:16:41,590 --> 00:16:45,650
+chapter عن ال stoichiometric calculations الحسابات
+
+202
+00:16:45,650 --> 00:16:51,010
+الكيميائية اللي التفاعلات بتكون فيها a
+
+203
+00:16:51,010 --> 00:16:55,890
+quantitative يعني بتتم بنسبة 100%في نوع اخر من
+
+204
+00:16:55,890 --> 00:17:00,590
+التفاعلات تفاعلات لا تتم بنسبة 100% يعني تفاعلات
+
+205
+00:17:00,590 --> 00:17:04,630
+اتزان هذه هندرسها في chapter اخر اسمه general
+
+206
+00:17:04,630 --> 00:17:09,830
+equilibrium concepts chapter صغير هذول الشابترين
+
+207
+00:17:09,830 --> 00:17:14,570
+انا بعتبرهم مهمين جدا ليش مهمين جدا لان اساس
+
+208
+00:17:14,570 --> 00:17:20,810
+حساباتنا و تقريبا اكتر من 95% من المساق عبارة عن
+
+209
+00:17:20,810 --> 00:17:23,530
+حسابات وبالتالي
+
+210
+00:17:24,630 --> 00:17:31,230
+لابد من دراسة الشبترين هدول دراسة يعني معمقة و
+
+211
+00:17:31,230 --> 00:17:35,530
+نفهمهم فاهم ممتاز لأن لو خلصنا الشبترين هدول ال
+
+212
+00:17:35,530 --> 00:17:38,010
+stoichiometric calculations و ال equilibrium
+
+213
+00:17:38,010 --> 00:17:42,210
+concepts لو خلصناها بشكل جيد الحسابات اللي جاي في
+
+214
+00:17:42,210 --> 00:17:45,950
+الشباتر اللي بعدين الأخرى معينة تقصصية هتكون
+
+215
+00:17:45,950 --> 00:17:50,030
+حساباتباعتبار تحصيل حاصل مش هيكون في عنا أي مشكلة
+
+216
+00:17:50,030 --> 00:17:55,110
+فيها كلها هنقدر نعملها بمجرد معرفتنا لشبترين
+
+217
+00:17:55,110 --> 00:18:01,190
+المقدمة وفي هذا الجانب لابد من الإشارة لإن الكتب
+
+218
+00:18:01,190 --> 00:18:06,810
+بتعتمد أساليب متعددة لإيصال المعلومة للطالب طرق
+
+219
+00:18:06,810 --> 00:18:10,070
+متعددة في الحسابات ومن ضمنهم الكتاب اللي احنا
+
+220
+00:18:10,070 --> 00:18:16,100
+هندرسهبيعتمد طريقة معينة وبتحاول كتب تبسط المعلومة
+
+221
+00:18:16,100 --> 00:18:20,900
+لدرجة انه بتحط القوانين في مربعات او في مستطيلات
+
+222
+00:18:20,900 --> 00:18:24,220
+وبتقولك هذا القوانين المهم يعني احفظها احنا
+
+223
+00:18:24,220 --> 00:18:30,840
+للامانة مش هيكون في عندنا اي داعي لانه نحفظ اي شيء
+
+224
+00:18:30,840 --> 00:18:37,960
+ليه؟ لانه هنستخدم مفاهيم قليلة جدا لا تحتاج لحفظ
+
+225
+00:18:39,220 --> 00:18:42,620
+وهي معروفة لديكم بس مجرد ان انا بدي استثيرها و
+
+226
+00:18:42,620 --> 00:18:46,020
+احاول اقولكم او اضعها في موضوعها الصحيح هي معروفة
+
+227
+00:18:46,020 --> 00:18:50,820
+لديكم اللي هو مفهوم الـ minimalالمول بتعرفوا الملي
+
+228
+00:18:50,820 --> 00:18:54,420
+مول واحد على ألف من المول هذا بحل أي مسألة في ال
+
+229
+00:18:54,420 --> 00:18:58,200
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+230
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+231
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+232
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+233
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+239
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+240
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+241
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+251
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+259
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+264
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+00:23:10,400 --> 00:23:14,520
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+280
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+الكيميا التحليلية اسمه Gary Christian الكتاب يدرس
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+281
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+284
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+285
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+286
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+294
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+299
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+300
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+على المحاضرات اللي أنا بقولها هان ويعني أمثلة
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+304
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+أي مجال لحديث عن إنسان بيغشه إن الواحد يتعاطف معاه
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+بيندرج تحت اسم quantitative analysis او
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+344
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+quantitation الحاجة التانية اللى ممكن نطلع عليها
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+347
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+348
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+هذا برضه analytical chemistry بس تحت ايه؟ تحت ..
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+349
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+لما أسأل هل فمعناته detection ممكن أشوف حاجة
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+350
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+المواد اللى لسه لازالت ماتفعلتش او المواد الجانبية
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+361
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+اسمه chemical separation ويعتبر فرع مهم من فروع
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+362
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+الكيميا التحليليةيمكن حكينا عن هذه الموضوعات في
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+ومعرفتها بالترتيب بالتتابع بال sequence تبعها هل
+
+367
+00:30:18,830 --> 00:30:22,490
+يجب ان احفظها هل جاتب نقول اه نعم يجب ان نحفظها
+
+368
+00:30:22,490 --> 00:30:29,150
+لكن في الحقيقة هي عبارة عن عناصر متتابعة منطقية
+
+369
+00:30:29,150 --> 00:30:34,850
+بمعنى ان انت مش ممكن تلبس الجميسقبل ما تلبس
+
+370
+00:30:34,850 --> 00:30:38,510
+الفانيلا أو بدك تلبس الفانيلا تلبسهاش بعد ما تلبس
+
+371
+00:30:38,510 --> 00:30:41,990
+الجميص هذا حد بيعلمهلك او حد بيقولك والله لأ
+
+372
+00:30:41,990 --> 00:30:44,590
+انتبهي الفانيلا في الأول بعد الجميص هذا الشيء عادي
+
+373
+00:30:44,590 --> 00:30:48,030
+انت بتعمله كل يوم ونفس الكلام لو اشتغلت في التحليل
+
+374
+00:30:48,030 --> 00:30:53,080
+هذه العناصر بتصير عندك ايه؟منطقية بدك تيجي تسيوج
+
+375
+00:30:53,080 --> 00:30:56,500
+السيارة تضرب صلف في الأول او بتطلع تظبط الموري
+
+376
+00:30:56,500 --> 00:31:01,960
+تضرب صلف مثلا بتنزل ال handbrake معايا انت ولا لا؟
+
+377
+00:31:01,960 --> 00:31:05,720
+في شغلات منطقية بالتم هل جيت حلم تتعلمها؟ اه لكن
+
+378
+00:31:05,720 --> 00:31:09,520
+في المستقبل بديش إياك تحفظها لأنها هتصير بالنسبة
+
+379
+00:31:09,520 --> 00:31:13,840
+إلك عادية جدا زي ألف بات زي ما يقولك إيش اسمك؟
+
+380
+00:31:13,840 --> 00:31:16,180
+بتقولليش اسم سيدك في الأول بعدين اسم أبوك بعدين
+
+381
+00:31:16,180 --> 00:31:19,380
+اسم العيلة بعدين اسمك محربطي لأ بتقوللي فلان
+
+382
+00:31:19,380 --> 00:31:24,320
+بنفلان بنفلان بنفلانمش هيك وهذه زي هيك تماما يعني
+
+383
+00:31:24,320 --> 00:31:26,900
+هالجيت صح احنا بنذكرها لكن في المستقبل ايه مش
+
+384
+00:31:26,900 --> 00:31:31,280
+المفروض تكون زي ألف باب بالنسبالنا زي routine
+
+385
+00:31:31,280 --> 00:31:38,200
+information معلومات روتينية بالنسبالنا أول أنصر أو
+
+386
+00:31:38,200 --> 00:31:44,740
+حدث من أو في العملية التحليلية اللي هو بيتكلم عن
+
+387
+00:31:44,740 --> 00:31:52,380
+defining the problem defining the problem تحديدإيش
+
+388
+00:31:52,380 --> 00:31:56,820
+هي المشكلة؟ أنا إجتني عينة والله خد هذه حللها طيب
+
+389
+00:31:56,820 --> 00:32:01,920
+ماشي بده أحللها بس لازم أفهم لازم أفهم يعني إيش
+
+390
+00:32:01,920 --> 00:32:05,300
+المعلومات المطلوبة من التحليل يعني إيش بدك إياه؟
+
+391
+00:32:05,300 --> 00:32:09,460
+إيش بدك إياه بالظبط لازم أفهم مثلا حاجة عن ال
+
+392
+00:32:09,460 --> 00:32:14,940
+precision جدش بدك precision جدش بدك accuracy ليه؟
+
+393
+00:32:14,940 --> 00:32:19,370
+لأن هذا الكلاممش كل الطرق الكيميائية بتعطيك نفس ال
+
+394
+00:32:19,370 --> 00:32:22,010
+precision مش كل الطرق الكيميائية بتعطيك نفس ال
+
+395
+00:32:22,010 --> 00:32:25,790
+accuracy فانت بدك مثلا accuracy معينة بدك
+
+396
+00:32:25,790 --> 00:32:30,490
+precision معينة بدك sensitivity حساسية معينة لابد
+
+397
+00:32:30,490 --> 00:32:34,910
+انك تستخدم طريقة يمكن انها تعطيك هذه المعلومات
+
+398
+00:32:34,910 --> 00:32:38,950
+يبقى انت ضروري تعرف في الأول شوية عن ال precision
+
+399
+00:32:38,950 --> 00:32:43,730
+شوية عن ال accuracy شوية عن ال sensitivity مثلا
+
+400
+00:32:45,260 --> 00:32:49,940
+برضه بدك تعرف جداش كمية العينة المتاحة إليك ليه؟
+
+401
+00:32:49,940 --> 00:32:54,480
+لأن بعض الطرق الكيميائية بحاجة ل مثلا milligram من
+
+402
+00:32:54,480 --> 00:32:59,680
+العينة بحاجة ل volume مثلا 5 mil طب أنت مافيش عندك
+
+403
+00:32:59,680 --> 00:33:03,220
+إلا عشرين تلاتين خمسين micron بنفع تستخدم الطريقة،
+
+404
+00:33:03,220 --> 00:33:09,030
+بينفعش؟في عندك nano gram بنفع تستخدم طريقة تستخدم
+
+405
+00:33:09,030 --> 00:33:12,590
+milligrams؟ بنفعش فانت حسب كمية العينة اللي عندك
+
+406
+00:33:12,590 --> 00:33:16,890
+هذا بيفترض عليك برضه كمان قيود على استخدام الطريقة
+
+407
+00:33:16,890 --> 00:33:23,090
+فانت بتشوف ايش المعلومات المطلوبة كلها وبعدين
+
+408
+00:33:23,090 --> 00:33:29,630
+بتحدد ايش هي الطريقة الكيميائية التحليلية اللي
+
+409
+00:33:29,630 --> 00:33:35,550
+يمكن استخدامها للوصول الى النتائج المطلوبةمش كويس
+
+410
+00:33:35,550 --> 00:33:41,030
+يبقى في البداية تحديد إيش هي المشكلة تاني حاجة يا
+
+411
+00:33:41,030 --> 00:33:45,930
+شباب حددنا المشكلة و عرفناها 100% بنقول والله بدنا
+
+412
+00:33:45,930 --> 00:33:50,190
+نحصل على representative sample obtaining a
+
+413
+00:33:50,190 --> 00:33:53,710
+representative sample إيش يعني representative
+
+414
+00:33:53,710 --> 00:34:00,230
+sample معناتها عينة ممثلة إيش يعني عينة ممثلة يعني
+
+415
+00:34:00,230 --> 00:34:09,330
+عينة بتمثل الكل يعني مثلاانا بدي اشوف والله ايش
+
+416
+00:34:09,330 --> 00:34:15,730
+تركيز خان الحديد في جبل من جبال فلسطين يعني جبل
+
+417
+00:34:15,730 --> 00:34:22,070
+ضخم جدا ممكن انه يستخدم في عملية ال .. يعني كمنجم
+
+418
+00:34:22,070 --> 00:34:29,060
+او شبه لاستخلاص هذا الخان منه تجاريا فاش بسويبدي
+
+419
+00:34:29,060 --> 00:34:31,940
+أخد عينة و أحللها أشوف كدهش والله نسبة المقوية
+
+420
+00:34:31,940 --> 00:34:36,720
+للخام هذا موجود في الجبل أو في المنجم اللي عندي
+
+421
+00:34:36,720 --> 00:34:42,660
+طيب من وين أخد العينة من رأس الجبل ولا من السفح
+
+422
+00:34:42,660 --> 00:34:48,640
+ولا نعمل فتحة جوا و ناخده من الداخل مثلا احنا لو
+
+423
+00:34:48,640 --> 00:34:52,460
+قلنا لكم يا شباب كله يروح على هالجبل و كل واحد
+
+424
+00:34:52,460 --> 00:34:56,440
+يجيب عينة و يحللهاو اين ما بده يروح يروح المهم
+
+425
+00:34:56,440 --> 00:34:59,620
+انها الجبل و حللها كل واحد فيكم هيعطيه انتيجة ايش
+
+426
+00:34:59,620 --> 00:35:04,160
+ما لا اكيد مختلفة ليه؟ لأن كل واحد يعني راح على
+
+427
+00:35:04,160 --> 00:35:09,330
+منطقة و المناطق الجبل مش متجانسعلشان هيك بنقول
+
+428
+00:35:09,330 --> 00:35:14,650
+احنا الاصل في العينة إيش تكون؟ ممثلة يعني بتتاخد
+
+429
+00:35:14,650 --> 00:35:19,150
+من أماكن مختلفة و أيضا من أعماق مختلفة فيما يتعلق
+
+430
+00:35:19,150 --> 00:35:24,270
+بالمنجم مثلا أو جبل من مناطق مختلفة و من أعماق
+
+431
+00:35:24,270 --> 00:35:29,700
+مختلفة كمانبعد هيك بناخد كل هذه العينات و بنحللهاش
+
+432
+00:35:29,700 --> 00:35:34,720
+بنخلطها و بنطحنها منيح و بنجسمها لأربع أقسام و
+
+433
+00:35:34,720 --> 00:35:38,420
+الربع برضه بنطحنه منيح و بنجسمه لأربع أقسام لغاية
+
+434
+00:35:38,420 --> 00:35:42,300
+ما ناخد كمية محترمة بنقول والله أه هذه متجانسة
+
+435
+00:35:42,300 --> 00:35:48,280
+بتمثلالجبل هذا مش هيك و بنحلل العينة اربع خمس مرات
+
+436
+00:35:48,280 --> 00:35:50,320
+و بنقول والله المتوسط هالجد اذا النسبة الماوية
+
+437
+00:35:50,320 --> 00:35:56,520
+هالجد اه بينفع نعمل مشروع استخلاص الخام هذا من
+
+438
+00:35:56,520 --> 00:36:01,060
+المنجم ولا لا بينفع نعمله مصنع و نجيبله و نعمله
+
+439
+00:36:01,060 --> 00:36:05,400
+شركة كهربا لأنه مثلا حديده صلب بده كهربا كتير و
+
+440
+00:36:05,400 --> 00:36:09,540
+بده يعني بنيات و بده مهندسين و بده كذا اه مانعملش
+
+441
+00:36:09,540 --> 00:36:13,050
+كل شيء جبل ما نكتشف واللهالنسبة الموية تبعتنا
+
+442
+00:36:13,050 --> 00:36:15,770
+جداشي و لا هو تجاري و لا مش تجاري و اذا اتمت على
+
+443
+00:36:15,770 --> 00:36:20,550
+انه اخدت اي عينة بتورط ممنفعش فالعينة بدها تكون
+
+444
+00:36:20,550 --> 00:36:24,710
+عينة ايه ممثلة برضه احنا يمكن بنفهم هذا كلام كويسة
+
+445
+00:36:24,710 --> 00:36:28,230
+كتير لو قلناكم والله بدنا نشوف نسبة التلوث في بحر
+
+446
+00:36:28,230 --> 00:36:33,600
+غزةو يلا يا شباب كل واحد ياخد عينة و يحلل و الله
+
+447
+00:36:33,600 --> 00:36:38,660
+اللي ساكن جانب الواد و شماله شوية هيجيبه لإن بحر
+
+448
+00:36:38,660 --> 00:36:43,780
+غزة مينفعش لا لأسماك ولا لسباحة ولا لأي شيء نسبة
+
+449
+00:36:43,780 --> 00:36:48,690
+التلوث فيه أعلى من أي مكان في العالمبينما اللي
+
+450
+00:36:48,690 --> 00:36:53,050
+ساكن بس منه و شرجه ابو .. و جنوب ابو ميت متر ولا
+
+451
+00:36:53,050 --> 00:36:55,770
+متين متر، هيقولنا والله مافي أصفة من هيك، هداش
+
+452
+00:36:55,770 --> 00:36:59,110
+ممتاز، واللي ساكن عند رفح أو خانونس، هيقول ما شاء
+
+453
+00:36:59,110 --> 00:37:02,610
+الله، مافيش أحلى من هيك، لكن احنا في المحاصلة
+
+454
+00:37:02,610 --> 00:37:07,350
+بنقول، الأصل أنه العينة اللي بدنا نحكم عليها، يجب
+
+455
+00:37:07,350 --> 00:37:13,080
+إنها تكون إيه؟عينة ممثلة يعني بتمثل الكل نفس
+
+456
+00:37:13,080 --> 00:37:16,860
+الكلام من عدة مناطق و من أعماق مختلفة ساعتها بيكون
+
+457
+00:37:16,860 --> 00:37:24,480
+النتيجة فيقلها معنى بعد هيك يا شباب بنلجأ ل .. لسه
+
+458
+00:37:24,480 --> 00:37:29,620
+ما خلصناش المنطق التالت اللي هو تحضير العينة
+
+459
+00:37:29,620 --> 00:37:34,120
+للتحليل إيش يعني تحضير العينة للتحليل؟مثلا في حالة
+
+460
+00:37:34,120 --> 00:37:38,300
+والله المنجم اللي حكينا عنه العينة صلبة وانا بتدعم
+
+461
+00:37:38,300 --> 00:37:43,430
+المعاهرةفلازم العينة ندوبها في الأول هذا جزء من
+
+462
+00:37:43,430 --> 00:37:47,530
+تحضير العينة للتحليل طب بدي أدوبها عشان أدوب
+
+463
+00:37:47,530 --> 00:37:52,170
+العينة أنا بحاجة ل solvent لازم أنت به كتير يا
+
+464
+00:37:52,170 --> 00:37:57,970
+شباب من أخطر من أخطر مراحل التحليل اللي هو إضافة
+
+465
+00:37:57,970 --> 00:38:04,430
+solvent لإيه؟ لأن خاصة إذا كان كمية ال analyte
+
+466
+00:38:04,430 --> 00:38:08,350
+اللي أنا بدور عليها أو اللي بدي أقدرها كانت كمية
+
+467
+00:38:08,350 --> 00:38:14,560
+قليلةكويس إذا كان ال solvent بيحتوي على أي كميات
+
+468
+00:38:14,560 --> 00:38:17,420
+لإن أنا بستخدم ال solvent كمية كبيرة من ال solvent
+
+469
+00:38:17,420 --> 00:38:20,840
+فإذا كان بيحتوي على أي كمية من ال analyte ولو كانت
+
+470
+00:38:20,840 --> 00:38:25,600
+قليلة كتير ساعتها هتكون كمية ال analyte اللي جاية
+
+471
+00:38:25,600 --> 00:38:28,940
+من ال solvent أعلى كتير من كمية ال analyte
+
+472
+00:38:28,940 --> 00:38:32,180
+الموجودة في العينة وبالتالي قراءتي كلها هتكون غلط
+
+473
+00:38:33,120 --> 00:38:37,580
+فلازم أنت به دائما لعمليات التخفيف عمليات الإذابة
+
+474
+00:38:37,580 --> 00:38:43,000
+ضروري كتير برضه من تحضير العينة للتحليل بقول انه
+
+475
+00:38:43,000 --> 00:38:47,060
+هدم اتوقف على الطريقة يعني في طريقة مثلا بتجيس من
+
+476
+00:38:47,060 --> 00:38:53,780
+10 مجرام ل 100 مجرام طيب تركيز ال analyte في
+
+477
+00:38:53,780 --> 00:39:00,960
+العينة 5000 مجرامفلازم أخفف برضه من تحضير العينة
+
+478
+00:39:00,960 --> 00:39:05,720
+أني أخلى تركيز الانالايت في ال range للطريقة
+
+479
+00:39:05,720 --> 00:39:11,100
+المستخدمة في ال range فبدي برضه في هذا الجانب بدي
+
+480
+00:39:11,100 --> 00:39:14,760
+أخلى تركيز الانالايت يكون في ال range للطريقة وإلا
+
+481
+00:39:14,760 --> 00:39:19,000
+شغلي برضه هيكون غلط وإذا كان تركيز الانالايت أقل
+
+482
+00:39:19,000 --> 00:39:23,480
+بدي أضطر أني أركزه إما عن طريقة التبخير أو ال
+
+483
+00:39:23,480 --> 00:39:26,900
+extraction أو أي طريقة أخرى هنتكلم عنها برضه في
+
+484
+00:39:26,900 --> 00:39:32,440
+المستقبلالخطوة الرابعة من الخطوات اللي بنعتبرها
+
+485
+00:39:32,440 --> 00:39:37,240
+منطقية أو الحدث الرابع هو عبارة عن ال chemical
+
+486
+00:39:37,240 --> 00:39:42,120
+separations في بعض الأحيان يا شباب انا مضطر ان
+
+487
+00:39:42,120 --> 00:39:45,720
+اعمل chemical separation كيب؟ يعني مثلا والله بدي
+
+488
+00:39:45,720 --> 00:39:51,260
+اشوف تركيز الاسترانشيوم في ماء البحرتركيز
+
+489
+00:39:51,260 --> 00:39:54,960
+السترانشيوم في ماء البحر ايش اعمل؟ جال والله اضيف
+
+490
+00:39:54,960 --> 00:40:00,300
+عليه شوية صلفات على طول السترانشيوم بترسب اخدت
+
+491
+00:40:00,300 --> 00:40:07,140
+شوية مية بحر و حطيت عليها صلفات اترسب راصب طيب انا
+
+492
+00:40:07,140 --> 00:40:11,100
+انسيت ان ال barium برضه موجود في ماء البحر و برضه
+
+493
+00:40:11,100 --> 00:40:15,100
+بترسب بالصلفات و ال calcium موجود في ماء البحر و
+
+494
+00:40:15,100 --> 00:40:18,100
+برضه بترسب بالصلفات اذا الراصب اللي انا حصلت عليه
+
+495
+00:40:19,300 --> 00:40:22,960
+مش راسب خاص فقط بالسترانشيوم وبالتالي لا يمكن
+
+496
+00:40:22,960 --> 00:40:28,160
+استخدام وزنة هذا الراسب لتقدير كمية السترانشيوم صح
+
+497
+00:40:28,160 --> 00:40:33,220
+ولا لأ علشان هيك ابنا اضطر نعمل عملية separation
+
+498
+00:40:33,220 --> 00:40:38,460
+وعملية ال separation يا شباب عملية مضنية و مكلفة
+
+499
+00:40:38,460 --> 00:40:43,590
+عادةعلشان هيك إذا كان في طرق بتستثني عملية ال
+
+500
+00:40:43,590 --> 00:40:47,650
+separation و بتنجح بتكون أفضل، اتروحش لل
+
+501
+00:40:47,650 --> 00:40:51,370
+separation إلا إذا كانت سكرة معاك لأنها طريقة أو
+
+502
+00:40:51,370 --> 00:40:59,410
+technique مجهد مكلف بحاجة لوقت، لكن قد نضطر إنه
+
+503
+00:40:59,410 --> 00:41:05,720
+نعملهبعد ما نعمل عملية separation إذا كان اضطرنا
+
+504
+00:41:05,720 --> 00:41:09,860
+ساعتها بنطبق ال procedure performing the
+
+505
+00:41:09,860 --> 00:41:16,760
+measurementعمل التجربة أو عمل القياس يتطلب تطبيق ل
+
+506
+00:41:16,760 --> 00:41:21,780
+procedure ل procedure هو خطوات التحليل العمل بنطبق
+
+507
+00:41:21,780 --> 00:41:25,920
+ال procedure زي مثلا عملية معايرة اي زي او مثلا
+
+508
+00:41:25,920 --> 00:41:29,940
+عملية وزن الراسب يعني الراسب و نوزان الراسب في
+
+509
+00:41:29,940 --> 00:41:34,370
+النهاية بحصل على ايه؟بحصل على نتائج، النتائج
+
+510
+00:41:34,370 --> 00:41:38,130
+بتقودنا للخطوة الأخيرة من الخطوات أو للحدث الأخير
+
+511
+00:41:38,130 --> 00:41:43,890
+من الأحداث اللي بتتطلبها عملية التحليل وهو ال
+
+512
+00:41:43,890 --> 00:41:47,250
+calculations يبقى ال calculations أو الحسابات هذا
+
+513
+00:41:47,250 --> 00:41:50,830
+اعتبر أخر خطوة و أبسط خطوة في الحقيقةمن الخطوات
+
+514
+00:41:50,830 --> 00:41:58,130
+اللي انا ممكن اني استخدمها في ال .. يعني في نهاية
+
+515
+00:41:58,130 --> 00:42:02,810
+العملية التحليلية فالعملية التحليلية هي عبارة عن
+
+516
+00:42:02,810 --> 00:42:08,150
+سلسلة من الأحداث، سلسلة من الخطوات متتابعة لكنها
+
+517
+00:42:08,150 --> 00:42:14,620
+منطقيةبقدرش أنا مثلا أطبق ال procedure قبل ما أحدد
+
+518
+00:42:14,620 --> 00:42:18,740
+المشكلة، بقدرش أطبق ال procedure قبل ما أستخدم
+
+519
+00:42:18,740 --> 00:42:24,860
+عينة ممثلة، بقدرش أطبق يعني أقول والله أخفف العينة
+
+520
+00:42:24,860 --> 00:42:29,460
+قبل ما مثلا أخد عينة ممثلةإلى آخرها فهي عبارة عن
+
+521
+00:42:29,460 --> 00:42:33,520
+سلسلة من الخطوات المنطقية الكويسة اللي لازم تنعمل
+
+522
+00:42:33,520 --> 00:42:37,140
+بالتتابع وبقولها ال gate نعم احنا ذكرناها ومقلوب
+
+523
+00:42:37,140 --> 00:42:43,420
+من أن نحفظها لكن في المستقبل هذا الكلام يعني مش
+
+524
+00:42:43,420 --> 00:42:47,020
+هيكون فيه درورة لأنه هتكون تحصيل حاصل ومعروف
+
+525
+00:42:47,020 --> 00:42:52,420
+بالضرورة للإنسان اللي بيشتغل في هذا المجالأنا
+
+526
+00:42:52,420 --> 00:42:56,560
+بعتقد أنه هنوقفان و إذا الله راد الحصة اللي جاية
+
+527
+00:42:56,560 --> 00:43:05,120
+بنكمل إذا كان في أي حد عنده سؤال ممكن يسأل طيب
+
+528
+00:43:05,120 --> 00:43:07,780
+معناه الكلام إذا الله راد بنشوفكم الحصة اللي جاية
+
+529
+00:43:07,780 --> 00:43:08,760
+بارك الله فيكم
+
diff --git a/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/IFhUAkHuLbs.srt b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/IFhUAkHuLbs.srt
new file mode 100644
index 0000000000000000000000000000000000000000..03ab3481e8f013cbe7a6b0411b58659be8e448bc
--- /dev/null
+++ b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/IFhUAkHuLbs.srt
@@ -0,0 +1,1825 @@
+1
+00:00:20,940 --> 00:00:23,800
+بسم الله الرحمن الرحيم. طيب يا شباب، الحصة الماضية
+
+2
+00:00:23,800 --> 00:00:28,260
+كنا تحدثنا عن مقدمة عامة في الكيمياء التحليلية.
+
+3
+00:00:28,260 --> 00:00:34,280
+ووصلنا إلى أن الطريقة التحليلية تتضمن خطوات منطقية
+
+4
+00:00:35,570 --> 00:00:40,270
+روتينية؛ الأصل أنه يعني الإنسان يعرفها أو الشخص
+
+5
+00:00:40,270 --> 00:00:44,250
+الذي يعمل في هذا المجال يعرفها معرفة تامة، و
+
+6
+00:00:44,250 --> 00:00:51,830
+تصبح عنده، مع استمرار العمل على الطرق التحليلية،
+
+7
+00:00:51,830 --> 00:00:56,930
+تصبح يعني عنده وكأنها مألوفة، ليست حاجة إلى
+
+8
+00:00:56,930 --> 00:01:01,400
+حفظ؛ وقولنا منها ما هو تحديد المشكلة بدايةً،
+
+9
+00:01:01,400 --> 00:01:08,900
+بعدين تحضير عينة ممثلة، وبعدين ممكن بعد ما نحضر
+
+10
+00:01:08,900 --> 00:01:13,180
+العينة الممثلة، نحضر العينة للتحضير سواء كان في
+
+11
+00:01:13,180 --> 00:01:19,700
+عينتنا تخفيف أو إذابة أو ما شابه؛ ممكن نعمل عملية
+
+12
+00:01:19,700 --> 00:01:24,760
+separation، وممكن بعد ما نخلص كل هذه العمليات
+
+13
+00:01:24,760 --> 00:01:28,160
+نروح لتطبيق الـ procedure أو performing the
+
+14
+00:01:28,160 --> 00:01:33,410
+analytical measurement أو الـ procedure؛ وفي الآخر
+
+15
+00:01:33,410 --> 00:01:37,690
+نخلص العمليات الحسابية. بنقول أن الطرق الكيميائية
+
+16
+00:01:37,690 --> 00:01:44,090
+بشكل عام تتميز بأنها تصلح لكميات
+
+17
+00:01:44,090 --> 00:01:48,490
+مختلفة من الـ solutes؛ فنجد بعض الطرق يحتاج إلى كمية
+
+18
+00:01:48,490 --> 00:01:52,130
+كبيرة من الـ solute، مثلاً أكثر من 100 milligram
+
+19
+00:01:52,130 --> 00:01:56,690
+solute أو analyte (المادة التي أنا أبحث عنها) أكثر
+
+20
+00:01:56,690 --> 00:02:04,230
+من 100 milligram أو أكثر من 100 microliter. في هذه
+
+21
+00:02:04,230 --> 00:02:10,250
+الحالة تسمى الطريقة Meso method. أما إذا كان الـ
+
+22
+00:02:10,250 --> 00:02:16,230
+range الذي تعمل فيه الطريقة من 10 إلى 100 ملي
+
+23
+00:02:16,230 --> 00:02:20,590
+جرام أو من 50 إلى 100 ميكرون، فالطريقة يمكن اعتبارها
+
+24
+00:02:20,590 --> 00:02:25,780
+sub micro method، يعني طريقة أقل حساسية من الأولى.
+
+25
+00:02:25,780 --> 00:02:29,720
+ولا أكثر؟ بالطبع أكثر حساسية من الأولى لأنها
+
+26
+00:02:29,720 --> 00:02:35,280
+تتعامل مع analyte كميته أقل؛ في حين أنه لو كان كمية
+
+27
+00:02:35,280 --> 00:02:41,020
+الـ analyte التي يمكن تحليلها باستخدام الطريقة أقل
+
+28
+00:02:41,020 --> 00:02:49,060
+من ذلك، مثلاً من 1 إلى 10 milligram أو أقل من
+
+29
+00:02:49,060 --> 00:02:51,960
+50 microliter in general، يعني فتعتبر الطريقة
+
+30
+00:02:51,960 --> 00:02:56,620
+micro method، طريقة micro. وفي حالة ما يكون عندي
+
+31
+00:02:57,680 --> 00:03:02,200
+طريقة قادرة على تحليل أقل من 1 مليجرام، فنسميها
+
+32
+00:03:02,200 --> 00:03:06,580
+ultra micro. فهذا تصنيف يعني يعتبر تصنيف عام، ليس
+
+33
+00:03:06,580 --> 00:03:11,540
+شيء ملزم؛ لكن بشكل عام الطرق الكيميائية تختلف
+
+34
+00:03:11,540 --> 00:03:17,700
+في الحساسية باختلاف قدرتها على العمل في مدى معين
+
+35
+00:03:17,700 --> 00:03:24,900
+من تركيزات الـ analyte أو الـ solutes. في نفس الوقت،
+
+36
+00:03:24,900 --> 00:03:28,620
+الذي نتحدث فيه عن الطرق، ممكن نتحدث فيه أيضاً
+
+37
+00:03:28,620 --> 00:03:34,070
+عن الـ Solute نفسه، أو نتحدث عن الـ Analyte نفسه،
+
+38
+00:03:34,070 --> 00:03:37,650
+ووجوده في العينة؛ فإذا كان كمية الـ Analyte
+
+39
+00:03:37,650 --> 00:03:41,590
+الموجودة في العينة كمية كبيرة نسبياً، يعني أكثر من
+
+40
+00:03:41,590 --> 00:03:46,690
+1% من تركيب العينة هو عبارة عن Analyte، في هذه
+
+41
+00:03:46,690 --> 00:03:51,150
+الحالة يُعتبر الـ Analyte Major Constituent، مكون
+
+42
+00:03:51,150 --> 00:03:56,650
+رئيسي من مكونات العينة؛ بينما لو كان من 1/10 إلى
+
+43
+00:03:56,650 --> 00:04:04,110
+1%، نقول عنه Minor constituent، قليل يعني
+
+44
+00:04:04,110 --> 00:04:09,270
+قليل، ليس الكثير الكثير؛ بينما لو كان كمية الـ
+
+45
+00:04:09,270 --> 00:04:12,510
+analyte، النسبة المئوية له تقل عن واحد من عشرة في
+
+46
+00:04:12,510 --> 00:04:16,930
+المئة، فهذا يسمى الـ trace constituent، الـ trace
+
+47
+00:04:16,930 --> 00:04:20,290
+constituent، كمية قليلة للغاية.
+
+48
+00:04:22,670 --> 00:04:27,610
+في الحقيقة أيضاً، في نهاية chapter المقدمة هذا، في
+
+49
+00:04:27,610 --> 00:04:35,230
+عندي مصطلحين لا بد من التفريق بينهما؛ مصطلح نقوله
+
+50
+00:04:35,230 --> 00:04:39,230
+analyze، ومصطلح نقوله determine، أو analysis، و
+
+51
+00:04:39,230 --> 00:04:46,660
+determination؛ فهذان المصطلحان يستخدمان ملتصقين إما
+
+52
+00:04:46,660 --> 00:04:52,460
+بالعينة أو بالـ analyte بحد ذاته؛ فالـ analyte دائماً
+
+53
+00:04:52,460 --> 00:04:57,280
+يلتصق معه أو يستخدم معه كلمة determination.
+
+54
+00:04:58,420 --> 00:05:02,420
+الـ analyte يستخدم معه كلمة determination، أو we
+
+55
+00:05:02,420 --> 00:05:06,680
+determine and analyze; we determine and analyze.
+
+56
+00:05:06,680 --> 00:05:14,260
+بينما العينة نستخدم معها مصطلح analysis; we analyze
+
+57
+00:05:14,260 --> 00:05:21,240
+a sample; we analyze a sample; analysis of a sample. فـ
+
+58
+00:05:21,240 --> 00:05:25,800
+determination مرتبطة مع الـ analyte، بينما analysis
+
+59
+00:05:25,800 --> 00:05:31,060
+مرتبطة مع العينة. أرجو أنه أثناء شغلكم تنتبهوا إلى، أو
+
+60
+00:05:31,060 --> 00:05:36,180
+تعبيركم عن نتائجكم، تنتبهوا للاستخدام الصحيح لهذين
+
+61
+00:05:36,180 --> 00:05:43,340
+المصطلحين. الآن ننتقل إلى أول chapter، نتحدث عن معالجة
+
+62
+00:05:43,340 --> 00:05:46,280
+البيانات، وقلنا لماذا معالجة البيانات مهمة جداً في
+
+63
+00:05:46,280 --> 00:05:52,400
+الكيمياء التحليلية؟ خاصة أنه باختصار معظم نتائجنا
+
+64
+00:05:52,400 --> 00:05:58,200
+عبارة عن نتائج رقمية حسابية، وبالتالي لابد من معرفة
+
+65
+00:05:58,200 --> 00:06:03,600
+كيفية التعامل مع البيانات المختلفة، وكيفية معالجتها
+
+66
+00:06:03,600 --> 00:06:09,660
+حتى نستطيع أن نفهم معنى النتائج التي نحصل عليها.
+
+67
+00:06:10,670 --> 00:06:14,150
+أقول في البداية، قبل ما أطلع على معالجة البيانات،
+
+68
+00:06:14,150 --> 00:06:18,950
+لا بد من التفريق أيضاً بين مصطلحين مهمين جداً، مصطلح
+
+69
+00:06:18,950 --> 00:06:26,210
+أقوله accuracy، ومصطلح أقوله precision؛ هذان المصطلحان
+
+70
+00:06:26,210 --> 00:06:30,330
+مهمّان جداً جداً، خاصة أن نتائجنا التي نحصل عليها
+
+71
+00:06:30,330 --> 00:06:33,690
+نريد أن نعبر عنها، نقول: والله هل هي نتائج دقيقة أم
+
+72
+00:06:33,690 --> 00:06:37,050
+غير دقيقة؟ مدى دقتها وما إلى ذلك؛ فمهم أن نعرف ماذا يعني
+
+73
+00:06:37,050 --> 00:06:42,950
+accuracy. الـ accuracy، أو مصطلح accuracy، يعني مدى
+
+74
+00:06:42,950 --> 00:06:47,710
+قرب النتائج، أو النتيجة التي حصلنا عليها، من النتيجة
+
+75
+00:06:47,710 --> 00:06:54,650
+الحقيقية الصحيحة، أو النتيجة المقبولة؛ دقة بالعربية
+
+76
+00:06:54,650 --> 00:06:58,050
+بنقول عنها دقة، لكن precision نقول عنها دقة
+
+77
+00:06:58,050 --> 00:07:04,640
+بالعربية، لكن عموماً للتفريق بينهما نقول أن الـ
+
+78
+00:07:04,640 --> 00:07:09,360
+accuracy مدى قرب النتيجة أو النتائج التي أحصل
+
+79
+00:07:09,360 --> 00:07:13,680
+عليها من النتيجة الصحيحة أو المقبولة؛ لماذا أقول
+
+80
+00:07:13,680 --> 00:07:18,500
+نتيجة صحيحة أو مقبولة؟ لأن في الحقيقة يا شباب معظم
+
+81
+00:07:18,500 --> 00:07:23,960
+النتائج هي عبارة عن مقارنات بين نتائج نحن حصلنا
+
+82
+00:07:23,960 --> 00:07:29,300
+عليها ونتيجة، خليني أقول أو يعني كمية قياسية نحن
+
+83
+00:07:29,300 --> 00:07:33,420
+قدرنا أنها قياسية، أو نحن قررنا أنها قياسية؛ فمثلاً
+
+84
+00:07:33,420 --> 00:07:41,520
+لما نجي نتحدث عن الكتلة، نتحدث عن مثلاً kilogram.
+
+85
+00:07:42,470 --> 00:07:46,970
+نتحدث عن أن الـ kilogram ألف جرام، طيب ماشي الحال،
+
+86
+00:07:46,970 --> 00:07:50,010
+طيب من الذي قال أن الـ kilogram هو عبارة عن هذه
+
+87
+00:07:50,010 --> 00:07:55,010
+الكمية؟ نحن في الحقيقة الذين قررنا أن هذه الكمية
+
+88
+00:07:55,010 --> 00:08:00,370
+من المادة هي عبارة عن kilogram، يعني وحدة ليست
+
+89
+00:08:00,370 --> 00:08:03,890
+وحدة موجودة من قبل ومعروفة أنها kilogram، لأ؛
+
+90
+00:08:03,890 --> 00:08:07,270
+نحن عملناها وقلنا هذه kilogram، والآن موضوعها في
+
+91
+00:08:07,270 --> 00:08:10,770
+معهد القياسات العالمية؛ الذي يريد عمل kilogram، يريد
+
+92
+00:08:10,770 --> 00:08:13,930
+يعني يجد جدها بالضبط تماماً، ليكون الذي عنده
+
+93
+00:08:13,930 --> 00:08:17,770
+kilogram، ونفس الكلام، المتفق عليه الذي عمل الـ meter،
+
+94
+00:08:17,770 --> 00:08:21,310
+وقلنا والله هذه الكمية أو هذه المسافة عبارة عن
+
+95
+00:08:21,310 --> 00:08:24,490
+meter، وبالتالي قسمناها إلى 100 سنتيمتر، لكن نحن الذين
+
+96
+00:08:24,490 --> 00:08:27,230
+عملناها؛ فهذا arbitrarily، اختياري؛ كان ممكن نعمل الـ
+
+97
+00:08:27,230 --> 00:08:32,090
+meter من يعني الحقيقة نقول هذا meter، لكن لا؛
+
+98
+00:08:32,090 --> 00:08:36,100
+فهذه نتيجة اعتمدناها، هي نتيجة مقبولة. معظم النتائج
+
+99
+00:08:36,100 --> 00:08:38,380
+التي نعتمدها أو معظم النتائج التي نتطلع إليها هي عبارة
+
+100
+00:08:38,380 --> 00:08:45,140
+عن نتائج مقاسة بالنسبة لوحدات مقبولة بالنسبة لنا،
+
+101
+00:08:45,140 --> 00:08:50,440
+وليس وحدات، خليني أقول مطلقة، لا؛ لذلك
+
+102
+00:08:50,440 --> 00:08:54,760
+تعريفنا للـ accuracy هو عبارة عن قرب النتائج التي
+
+103
+00:08:54,760 --> 00:09:01,880
+من النتيجة الصحيحة أو المقبولة. طيب نتطلع على الـ
+
+104
+00:09:01,880 --> 00:09:07,420
+precision. الـ precision تعني، أو يقصد فيها مدى
+
+105
+00:09:07,420 --> 00:09:12,920
+تقارب النتائج التي أحصل عليها من تجارب أو تجربة
+
+106
+00:09:12,920 --> 00:09:18,080
+مكررة، متكررة؛ مدى تقارب هذه النتائج؛ فمثلاً أعمل
+
+107
+00:09:18,080 --> 00:09:24,440
+التحليل لتعيين كمية النحاس في قطعة ذهب، عند أي قطعة
+
+108
+00:09:24,440 --> 00:09:30,460
+ذهب، وأريد معرفة كم فيها نحاس؛ فحللت التجربة مرة، و
+
+109
+00:09:30,460 --> 00:09:33,580
+مرتين، وثلاث، وأربع، وخمس، وعشر؛ كل مرة حصلت
+
+110
+00:09:33,580 --> 00:09:39,080
+على نتيجة؛ مدى تقارب هذه النتائج بعضها عن بعض، هذا
+
+111
+00:09:39,080 --> 00:09:43,340
+معناه precision؛ كل ما تقاربت أكثر، كل ما كانت more
+
+112
+00:09:43,340 --> 00:09:49,490
+precise، لكن ليس شرطاً أنها تكون صحيحة، ليس شرطاً أن تكون
+
+113
+00:09:49,490 --> 00:09:52,870
+قريبة من النتيجة الصحيحة؛ مدى تقارب النتائج بعضها
+
+114
+00:09:52,870 --> 00:09:56,290
+مع بعض، بغض النظر عن قربها من النتيجة الصحيحة أو
+
+115
+00:09:56,290 --> 00:09:59,830
+المقبولة أو لا؛ هذا يسمى الـ precision؛ كل ما اقتربت،
+
+116
+00:09:59,830 --> 00:10:06,870
+كل ما زاد الـ precision. طيب، نتطلع على الشكل
+
+117
+00:10:06,870 --> 00:10:11,630
+الذي أمامي هنا، خلينا نقول أنه على فرض أنه عندنا
+
+118
+00:10:11,630 --> 00:10:15,960
+تجربة ما، والنتيجة الصحيحة التي هي النتيجة
+
+119
+00:10:15,960 --> 00:10:21,340
+الموجودة في الدائرة الصفراء؛ يعني إذا كانت نتيجة
+
+120
+00:10:21,340 --> 00:10:24,700
+واقعه في الدائرة الصفراء، فهي نتيجة صحيحة أو مقبولة،
+
+121
+00:10:24,700 --> 00:10:28,620
+بينما إذا كانت بعيدة، فهي قضية... هنشوف، ممكن تكون
+
+122
+00:10:28,620 --> 00:10:35,760
+قضية أخرى. فنتطلع على أول نوع
+
+123
+00:10:35,760 --> 00:10:40,740
+من أنواع الدوائر، التي إلى اليسار؛ نجد كل النتائج
+
+124
+00:10:40,740 --> 00:10:45,730
+واقعه في الدائرة الصفراء، وأيضاً في نفس الوقت قريبة
+
+125
+00:10:45,730 --> 00:10:48,610
+من بعضها؛ وقعت في الدائرة الصفراء، يعني accurate
+
+126
+00:10:48,610 --> 00:10:52,330
+لأنها
+
+127
+00:10:52,330 --> 00:10:57,590
+قريبة جداً من النتيجة الصحيحة أو المقبولة، ومتقاربة
+
+128
+00:10:57,590 --> 00:11:02,780
+مع بعضها، مع بعضها؛  نقول أنهم precise، النتائج
+
+129
+00:11:02,780 --> 00:11:06,220
+التي حصلت عليها في، أو من خلال الرسم الأول،
+
+130
+00:11:06,220 --> 00:11:10,540
+الدوائر الأولى، التي في أعلى اليسار، هذه عبارة
+
+131
+00:11:10,540 --> 00:11:15,460
+عن نتائج أعبر عنها بقول: accurate and precise. نجي
+
+132
+00:11:15,460 --> 00:11:18,900
+إلى
+
+133
+00:11:18,900 --> 00:11:23,640
+الدائرة التي بجانبها، على يمينها في الأعلى، نقول
+
+134
+00:11:23,640 --> 00:11:27,980
+النتائج ليست واقعة في الدائرة الصفراء، واقعة في دائرة
+
+135
+00:11:27,980 --> 00:11:36,270
+أخرى، لكنها متقاربة؛ فهي أكيد ليست accurate، أكيد non
+
+136
+00:11:36,270 --> 00:11:41,670
+accurate أو inaccurate؛ بينما بما أنها متقاربة، فهي
+
+137
+00:11:41,670 --> 00:11:47,930
+precise؛ لذلك أعبر عن هذه النتائج بـ precise but
+
+138
+00:11:47,930 --> 00:11:54,290
+not accurate. لو جئنا للدائرة السفلى من اليسار،
+
+139
+00:11:54,290 --> 00:11:58,970
+نلاحظ أن بعض النتائج واقعة في الدائرة الصفراء،
+
+140
+00:11:58,970 --> 00:12:06,910
+وبعضها حول الدائرة الصفراء، بحيث أنه لو أخذنا متوسط
+
+141
+00:12:06,910 --> 00:12:10,750
+النقط، أو متوسط النقاط، أو متوسط النقاط، أين
+
+142
+00:12:10,750 --> 00:12:16,100
+يقع المتوسط؟ في الدائرة الصفراء. معنى الكلام، معنى
+
+143
+00:12:16,100 --> 00:12:21,240
+الكلام، نقدر نقول أن النتائج هذه accurate، لكن هل
+
+144
+00:12:21,240 --> 00:12:24,220
+هي متقاربة من بعضها البعض؟ لا، ليست متقاربة من بعضها
+
+145
+00:12:24,220 --> 00:12:29,620
+البعض؛ إذن هي ماذا؟ imprecise، أو accurate but not
+
+146
+00:12:29,620 --> 00:12:34,200
+precise. لكن الحال الأخير الذي قد نواجهه
+
+147
+00:12:34,200 --> 00:12:40,190
+في نتائجنا، أن النتائج scattered، مُشتّتة، لكن مُشتّتة
+
+148
+00:12:40,190 --> 00:12:47,450
+على جانب من جوانب الدائرة، ليست منتشرة حول المركز،
+
+149
+00:12:47,450 --> 00:12:50,870
+يعني لو تأخذ متوسطها، سيكون أيضاً بعيداً عن الأصفر،
+
+150
+00:12:50,870 --> 00:12:55,190
+عن الصحيح؛ فهي scattered، وبعيدة عن الصحيح؛ إذن هي
+
+151
+00:12:55,190 --> 00:13:00,370
+neither accurate nor precise.  فممكن نتائجنا تكون
+
+152
+00:13:00,370 --> 00:13:03,970
+accurate and precise, accurate but not precise,
+
+153
+00:13:04,110 --> 00:13:07,410
+precise but not accurate, neither accurate nor
+
+154
+00:13:07,410 --> 00:13:13,640
+precise؛ كلها ممكن. نجي نمثل هذا الكلام، يعني تمثيل
+
+155
+00:13:13,640 --> 00:13:19,320
+بسيط جداً؛ لو جئنا بميزان وقلنا لأحدهم: لو
+
+156
+00:13:19,320 --> 00:13:23,620
+سمحت، اخرج على الميزان عدة مرات. فخرج، أول وزنة كانت
+
+157
+00:13:23,620 --> 00:13:29,280
+84، ثانية وزنة 83، ثالثة وزنة 84، رابعة وزنة 85، خامسة
+
+158
+00:13:29,280 --> 00:13:34,360
+وزنة 84؛ نتائج متقاربة،
+
+159
+00:13:34,360 --> 00:13:37,860
+فهي precise بحد ذاتها؛ precise، يعني ليس فرق كبير بينها،
+
+160
+00:13:37,860 --> 00:13:42,680
+precise؛ لكن بمجرد ما قلنا هذا الكلام للشاب، قال: لا،
+
+161
+00:13:42,680 --> 00:13:46,120
+وزني يختلف. جبنا ميزان قياسي وقلنا له: لو سمحت، اخرج عليه. طلع وزنه 76 كيلو جرام. إذا ممكن
+
+162
+00:13:46,120 --> 00:13:51,160
+النتائج التي لدينا تكون precise، بأن:  نعم، طبعاً الميزان
+
+163
+00:13:51,160 --> 00:13:55,040
+الذي وزننا عليه فيه مشكلات، وهذا نواجهه كثيراً
+
+164
+00:13:55,040 --> 00:13:58,260
+في المختبر. في بعض الأحيان تعمل تحليلاً ما، تلاحظ
+
+165
+00:13:58,260 --> 00:14:03,100
+أن كل نتائجك أعلى من النتيجة الحقيقية. تقول: لماذا؟
+
+166
+00:14:03,100 --> 00:14:08,630
+طيب أنا الـ procedure يقول لي: خذ نصف جرام، أخذت نصف
+
+167
+00:14:08,630 --> 00:14:11,890
+جرام ووزنته صح 100%، ماذا يعني أن النتيجة التي أحلل
+
+168
+00:14:11,890 --> 00:14:17,670
+التي تظهر دائماً أعلى بكثير من مثلاً النتيجة
+
+169
+00:14:17,670 --> 00:14:21,210
+الحقيقية أو النتيجة المعطاة، النتيجة المقبولة،
+
+170
+00:14:21,210 --> 00:14:24,230
+التي أعرفها مسبقاً؟ إيش هيكون؟ نقول: هاه،
+
+171
+00:14:24,230 --> 00:14:30,260
+هناك عندك مشكلة في الميزان؛ الميزان بدلاً ما يعطيك
+
+172
+00:14:30,260 --> 00:14:33,500
+نصف جرام صحيح، هو يقرأ نصف جرام لكن في الحقيقة هو
+
+173
+00:14:33,500 --> 00:14:36,6
+
+223
+00:18:20,040 --> 00:18:23,840
+أدوات القياس المستخدمة، وناس كانت عارفة دقة أدوات
+
+224
+00:18:23,840 --> 00:18:29,180
+القياس، و بفترض الحرفية طبعًا في اللي عمل التجربة
+
+225
+00:18:29,180 --> 00:18:36,820
+فبتدلني أيضًا على الكفاءة أو على مصداقية النتائج
+
+226
+00:18:36,820 --> 00:18:40,660
+اللي موجودة قدامي، فما نستهين بالـ Significant
+
+227
+00:18:40,660 --> 00:18:46,680
+Figures، زي ما هنشوف أمثلة بعد شوية، أحنا هنتطلع
+
+228
+00:18:46,680 --> 00:18:50,480
+كأمثلة عامة على المسطرة مثلًا، بس عشان نبسط المفهوم
+
+229
+00:18:50,480 --> 00:18:55,200
+و هنتطلع على الـ graduated cylinder، و هنتطلع على
+
+230
+00:18:55,200 --> 00:19:00,680
+الميزان، عشان بس نبين إيش المقصود بمفهوم الـ
+
+231
+00:19:00,680 --> 00:19:02,580
+significant figures
+
+232
+00:19:04,190 --> 00:19:08,730
+أحنا بنقول الـ Significant Figures بتعبر عن أو
+
+233
+00:19:08,730 --> 00:19:14,110
+تستخدم في التعبير عن النتائج المخبرية، لأنه مدامها
+
+234
+00:19:14,110 --> 00:19:18,970
+نتائج مخبرية، يعني اللي بيقوم فيها إنسان، فتحتمل أنه
+
+235
+00:19:18,970 --> 00:19:22,330
+فيها uncertainty، تحتمل أنه فيها نوع من الخطأ، ومش
+
+236
+00:19:22,330 --> 00:19:26,270
+شرط إنسان، ممكن آلة، طب الآلة مين صنعها؟ إذًا برضه
+
+237
+00:19:26,270 --> 00:19:32,920
+تحتمل نوع من أنواع الخطأ، لكن لا تتعامل زي ما ذكرت
+
+238
+00:19:32,920 --> 00:19:37,920
+مع الـ exact numbers، فالقيم المخبرية أو النتائج
+
+239
+00:19:37,920 --> 00:19:44,140
+المخبرية دائمًا إلها، عادة إلها واحدة، بينما زي
+
+240
+00:19:44,140 --> 00:19:51,380
+ما ذكرت، لا نتعامل مع القيم المجردة أو الأرقام اللي
+
+241
+00:19:51,380 --> 00:19:54,160
+فيش إلها واحدة، أو الـ exact numbers
+
+242
+00:19:56,860 --> 00:20:00,760
+مراجعة سريعة، كيف نتعرف أو كيف نعرف نعد الـ
+
+243
+00:20:00,760 --> 00:20:04,240
+Significant Figures؟ بنقول والله فيه قوانين، لابد
+
+244
+00:20:04,240 --> 00:20:09,440
+من معرفتها، القوانين يعني برضه مش بحاجة لشقاء أو
+
+245
+00:20:09,440 --> 00:20:13,040
+يعني معاناة كبيرة في فهمها وتطبيقها، لأنه مرّنا عن
+
+246
+00:20:13,040 --> 00:20:20,380
+الموضوع قبل هيك، فبنقول، بنتطلع على كل ما عدا
+
+247
+00:20:20,380 --> 00:20:25,750
+الصفر، هو Significant، يعني باجي أي رقم أبدأ أشوف كم
+
+248
+00:20:25,750 --> 00:20:30,190
+significant figure فيه، ببدأ من اليسار، و ببدأ من
+
+249
+00:20:30,190 --> 00:20:38,090
+العدد الصحيح، كويس؟ فمثلًا عندي 42.1 من 10 متر،
+
+250
+00:20:38,090 --> 00:20:43,480
+كم significant figure فيها؟ بقول واحد، اثنين،
+
+251
+00:20:43,480 --> 00:20:47,020
+ثلاثة، كويس كتير، ما فيش عندي أصفار، لكن لو عندي أصفار
+
+252
+00:20:47,020 --> 00:20:51,880
+على يمين، ما ليش دعوة، هنيجي للأسفار الآن، بس بقول أنا
+
+253
+00:20:51,880 --> 00:20:57,680
+كل ما عدا، كل الـ digits ما عدا الصفر تعتبر إيه
+
+254
+00:20:57,680 --> 00:21:03,300
+significant، دائمًا بالنسبة للأسفار، ففي بعض الأحيان
+
+255
+00:21:03,300 --> 00:21:07,620
+هي significant، وفي بعض الأحيان insignificant، non-
+
+256
+00:21:07,620 --> 00:21:13,720
+significant، طب إيش الأحيان اللي بتكون فيها الأصفار
+
+257
+00:21:13,720 --> 00:21:16,700
+non-significant أو insignificant؟ قال والله إذا
+
+258
+00:21:16,700 --> 00:21:22,880
+كانت على اليسار، على اليسار، على اليسار دائمًا
+
+259
+00:21:22,880 --> 00:21:27,940
+الأصفار insignificant، حتى لو كان في عندنا علامة
+
+260
+00:21:27,940 --> 00:21:31,950
+عشرية، عندنا علامة عشرية، ما عندناش علامة عشرية،
+
+261
+00:21:31,950 --> 00:21:37,590
+الأصفار غير معنوية، ما لهاش معنى، الأصفار ما لهاش
+
+262
+00:21:37,590 --> 00:21:41,150
+معنى، طيب، هالعلامة العشرية ليش بتكون، والأصفار؟ ده
+
+263
+00:21:41,150 --> 00:21:44,830
+بس بتحدد، يعني موضوع العلامة العشرية مش أكتر،
+
+264
+00:21:44,830 --> 00:21:49,010
+ما لهاش دعوة بالـ .. بالمغزى أو الـ significance، زي
+
+265
+00:21:49,010 --> 00:21:51,870
+إيش؟ زي ما أقول والله عندي خمسة gram، كم
+
+266
+00:21:51,870 --> 00:21:56,250
+significant figure في عندي؟ طب لو قلت خمسة من ألف
+
+267
+00:21:56,250 --> 00:21:59,750
+kilogram، ما هي هي هي خمسة gram، يعني خمسة من ألف
+
+268
+00:21:59,750 --> 00:22:05,210
+kilogram، كويس، برضه واحد، لأ، طب الأصفر إيش عملت؟ هي
+
+269
+00:22:05,210 --> 00:22:10,650
+إحنا غيرنا الوحدة فقط، إحنا غيرنا الوحدة، لكن عدد الـ
+
+270
+00:22:10,650 --> 00:22:13,790
+significant figures لا يتغير، لأنه إذا تغير عدد الـ
+
+271
+00:22:13,790 --> 00:22:17,970
+significant figures، معناته أدات القياس تغيرت، إذا
+
+272
+00:22:17,970 --> 00:22:20,930
+تغير عدد الـ significant figures، معناته أدات القياس
+
+273
+00:22:20,930 --> 00:22:25,360
+تغيرت، وهذا غير صحيح، علشان هيك بنقول الأصفار اللي
+
+274
+00:22:25,360 --> 00:22:32,880
+على اليمين لا تحسب، فمثلًا الرقم 0.025 متر، هذا فيه
+
+275
+00:22:32,880 --> 00:22:38,080
+اثنين، فيه اثنين، لأنه عبارة عن الـ 25 من ألف متر
+
+276
+00:22:38,080 --> 00:22:42,240
+يعبر عن اثنين و نص سنتي، اثنين و نص سنتي، يمكن
+
+277
+00:22:42,240 --> 00:22:46,840
+كتابتها اثنين و نص في عشرة أس سالب اثنين، رقمين، two
+
+278
+00:22:46,840 --> 00:22:50,180
+digits، two significant figures فقط، طيب
+
+279
+00:22:52,700 --> 00:22:56,780
+بنقول إذا كان في عندي أعداد صحيحة، وفي بينهم أصفار
+
+280
+00:22:56,780 --> 00:23:01,520
+كل الأصفار اللي بين الأعداد الصحيحة، خلاص، بنحسبه
+
+281
+00:23:01,520 --> 00:23:05,380
+فعندي مثلًا أربعين و واحد من عشرة، هي عبارة عن ثلاثة
+
+282
+00:23:05,380 --> 00:23:10,360
+significant figures، بنتكلم
+
+283
+00:23:10,360 --> 00:23:14,380
+الآن عن الأصفار اللي على اليسار، الأصفار اللي في
+
+284
+00:23:14,380 --> 00:23:17,860
+المنتصف أو بين الأعداد الصحيحة، بنتكلم عن الأصفار
+
+285
+00:23:17,860 --> 00:23:22,600
+اللي على اليمين، الأصفار اللي على اليمين، بدنا نتذكر
+
+286
+00:23:22,600 --> 00:23:26,280
+أنه مرات بتكون significant، و مرات بتكون
+
+287
+00:23:26,280 --> 00:23:31,540
+insignificant، بسيطة كتير، بتكون significant دائمًا
+
+288
+00:23:31,540 --> 00:23:36,780
+إذا كانت في عندي علامة عشرية، إذا عندي علامة عشرية
+
+289
+00:23:36,780 --> 00:23:39,920
+انتهى الموضوع، كل اللي على اليمين significant، إذا
+
+290
+00:23:39,920 --> 00:23:43,040
+عندي علامة عشرية، إذا كل اللي على اليمين
+
+291
+00:23:43,040 --> 00:23:48,650
+significant، لكن لو ما فيش عندي علامة عشرية، آه في عندي
+
+292
+00:23:48,650 --> 00:23:54,450
+هنا مشكلة، هنتعرف عليها، فمثلًا 140 متر، حلو
+
+293
+00:23:54,450 --> 00:23:58,250
+كتير، هذا عبارة عن، مدام في عندي علامة عشرية، إذا كل
+
+294
+00:23:58,250 --> 00:24:01,450
+الأصفار اللي على اليمين بتحسب، يبقى هذا ثلاثة، واحد،
+
+295
+00:24:01,450 --> 00:24:05,530
+اثنين، ثلاثة، طيب مثلًا
+
+296
+00:24:08,630 --> 00:24:14,730
+441.2 × 0.20، يعني هذا فيه خمسة، الأصفار اللي على
+
+297
+00:24:14,730 --> 00:24:19,110
+اليمين بتحسب، ليه كمان مرة؟ لأنه عندي علامة عشرية، و
+
+298
+00:24:19,110 --> 00:24:22,650
+هنشوف ليه هذا الكلام بعد شوية لما ناخد أمثلة
+
+299
+00:24:22,650 --> 00:24:28,020
+حقيقية، هنشوف ليه هذا الكلام، يمكن كتابة الرقم بالـ
+
+300
+00:24:28,020 --> 00:24:30,760
+Scientific Notation، الـ Scientific Notation لا
+
+301
+00:24:30,760 --> 00:24:36,280
+تحسب، زي ما هنشوف أيضًا بعد شوية، فـ 4.10 × 10 أس
+
+302
+00:24:36,280 --> 00:24:41,040
+واحد، ثلاثة، العشرة أس أي شيء موجب أو أي شيء سالب
+
+303
+00:24:41,040 --> 00:24:44,120
+هذا ما لهوش تعب، هذا عبارة عن كتابة الرقم بالـ
+
+304
+00:24:44,120 --> 00:24:47,940
+Scientific Notation، بالطريقة العلمية، ما لهوش أي دخل
+
+305
+00:24:47,940 --> 00:24:51,660
+في تحديد عدد الـ significant figures، ما له أي دخل في
+
+306
+00:24:51,660 --> 00:24:56,930
+تحديد عدد الرقم اللي جابله، 4.10 هذا ثلاثة، لو كانت 4
+
+307
+00:24:56,930 --> 00:25:02,510
+.1 لحالها يبقى هذا اثنين، لو كانت 4.100 يبقى هذا
+
+308
+00:25:02,510 --> 00:25:06,670
+أربعة، في أيّ مكان مضروبة تكون في عشرة أس أيّ
+
+309
+00:25:06,670 --> 00:25:13,170
+مكان، ما فيش عندي أي مشكلة في هذا الكلام، لكن الأرقام
+
+310
+00:25:13,170 --> 00:25:18,390
+إذا كانت مش موجودة، مش موجودة على اليمين بعد فاصلة
+
+311
+00:25:18,390 --> 00:25:23,630
+عشرية، يعني ما فيش عندي فاصلة عشرية في الرقم نفسه، ففي
+
+312
+00:25:23,630 --> 00:25:26,570
+الحقيقة يعني ممكن تكون significant أو ممكن تكون
+
+313
+00:25:26,570 --> 00:25:30,430
+insignificant، هي بتكون significant إذا أنا كنت
+
+314
+00:25:30,430 --> 00:25:34,660
+عارف أداة القياس، بحدد إذا كانت significant ولا لا،
+
+315
+00:25:34,660 --> 00:25:38,500
+لكن إحنا هنعتبرها خلال الفصل هذا، بما أن إحنا
+
+316
+00:25:38,500 --> 00:25:43,100
+ما بنعطيكمش أداة القياس عادة يعني، و بنكتب و بنشجعكم
+
+317
+00:25:43,100 --> 00:25:45,340
+تكتبوا بالطريقة العلمية، و بنعطيكم رقم بالطريقة
+
+318
+00:25:45,340 --> 00:25:49,960
+العلمية، فهنعتبر أنه كل الأصفار اللي على اليمين، إذا
+
+319
+00:25:49,960 --> 00:25:54,760
+ما فيش decimal point تعتبر insignificant، تماشيًا مع
+
+320
+00:25:54,760 --> 00:25:58,800
+الكتاب اللي موجود معانا، fixed يعني، تماشيًا معاه
+
+321
+00:25:58,800 --> 00:26:02,460
+هنعتبر كل الأصفار اللي على اليمين insignificant، لكن
+
+322
+00:26:02,460 --> 00:26:06,740
+في بعض الأحيان، لو أنا كنت عارف إيش أداة القياس
+
+323
+00:26:06,740 --> 00:26:09,340
+ممكن والله هذه الأصفار أعرف إنها significant أو لا
+
+324
+00:26:09,340 --> 00:26:15,160
+لكن إذا كان أنا مش عارف، فعادة إحنا هنعتبر دائمًا أن
+
+325
+00:26:15,160 --> 00:26:17,540
+الأصفار اللي على اليمين، مدام فيش عندنا الـ decimal
+
+326
+00:26:17,540 --> 00:26:22,760
+point، هتكون insignificant، فمثلًا الكمية
+
+327
+00:26:24,020 --> 00:26:30,940
+أو القياس 52800، كويس، ممكن يكون ثلاثة أو أربعة أو
+
+328
+00:26:30,940 --> 00:26:35,180
+خمسة، لكن أنا هأعتبره جدعش ثلاثة، لأن الأصفار
+
+329
+00:26:35,180 --> 00:26:38,380
+اللي على اليمين لا تحسب، فعشان هيك بكتبه 5.28
+
+330
+00:26:38,380 --> 00:26:44,840
+في عشرة أس أربعة، مثلًا، ممكن وابتدي ممكن يكون
+
+331
+00:26:44,840 --> 00:26:48,320
+فيه أربعة، مش ثلاثة، لو كتبته 5.280
+
+332
+00:26:48,320 --> 00:26:53,280
+في عشرة أس أربعة، وابتدي ممكن يكون خمسة
+
+333
+00:26:56,880 --> 00:27:02,820
+5.2800 × 10 أس 4، هذا خمسة فيه، لكن هذا لو بدي أعبر عنه
+
+334
+00:27:02,820 --> 00:27:05,680
+أنا زي ما هو مكتوب زي هيك، بقول هذا عبارة عن ثلاثة
+
+335
+00:27:05,680 --> 00:27:09,720
+يمكن أعبّر عنه 5.28 × 10 أس 4
+
+336
+00:27:13,300 --> 00:27:18,580
+بدي أحكي شوية عن الـ exact numbers، أنا ذكرت exact
+
+337
+00:27:18,580 --> 00:27:21,980
+numbers، كأن يكون عدد، جدعش، عدد الطلاب في البنك الأول
+
+338
+00:27:21,980 --> 00:27:29,040
+بنقول أربعة، أو أنت عملت التجربة خمس مرات، لما أقول
+
+339
+00:27:29,040 --> 00:27:34,240
+والله عملت التجارب خمس مرات، وأجمع النتائج، و
+
+340
+00:27:34,240 --> 00:27:37,260
+أقسمها على خمسة عشان أجيب الـ average، وأحسب عدد الـ
+
+341
+00:27:37,260 --> 00:27:41,020
+significant figures، بقول الخمسة هذه لا تدخل في
+
+342
+00:27:41,020 --> 00:27:45,820
+تحديد عدد الـ significant figures، ليه؟ لأن الخمسة هذه
+
+343
+00:27:45,820 --> 00:27:49,040
+عدد صحيح، لا يمكن يكون عن التجارب اللي عملتها أنا،
+
+344
+00:27:49,040 --> 00:27:52,200
+خمسة أو تسعة من عشرة، أو أربعة أو تسعة من عشرة، أو
+
+345
+00:27:52,200 --> 00:27:54,260
+خمسة وواحد من عشرة، أو خمسة وتسعة من عشرة، هذه
+
+346
+00:27:54,260 --> 00:27:57,640
+الخمسة هي عبارة عن 5.0000
+
+347
+00:27:57,640 --> 00:28:02,680
+إلى ما لا نهاية، كويس؟ ليه؟ لأنها عدد صحيح، عدد صحيح
+
+348
+00:28:02,680 --> 00:28:07,820
+من التجارب، فهي لا تدخل في حساب أو في تحديد عدد الـ
+
+349
+00:28:07,820 --> 00:28:11,280
+significant figures، لأن إحنا اتفقنا على أنه اللي
+
+350
+00:28:11,280 --> 00:28:15,860
+بيدخل في تحديد عدد الـ significant figures هو فقط
+
+351
+00:28:15,860 --> 00:28:22,450
+النتائج المخبرية، الخمسة هذه مش نتيجة، خمسة يعني
+
+352
+00:28:22,450 --> 00:28:25,470
+تقرير، حق كام تجربة عملت، إجابة على كام تجربة
+
+353
+00:28:25,470 --> 00:28:31,390
+عملت، خمسة، عدد صحيح، فهذا أول شيء لا يُعتبر أو لا
+
+354
+00:28:31,390 --> 00:28:35,950
+يُستخدم في حساب عدد الـ significant figures، الحاجة
+
+355
+00:28:35,950 --> 00:28:42,510
+الثانية اللي أيضًا تعتبر exact number، رقم صحيح اللي
+
+356
+00:28:42,510 --> 00:28:45,610
+هي الـ equivalence، ماهي الـ equivalence يعني أنا
+
+357
+00:28:45,610 --> 00:28:51,730
+عارف مثلًا أنه واحد متر تساوي مائة centimeter، كم
+
+358
+00:28:51,730 --> 00:28:56,280
+significant figure فيه في الواحد متر؟ بقول لأ، مش
+
+359
+00:28:56,280 --> 00:28:59,900
+واحد، فيه عدد لا نهائي، لأن هذا equivalence، هذا
+
+360
+00:28:59,900 --> 00:29:04,400
+تكافؤ، أنا عرفت الواحد متر على أنه مئة سنتيمتر،
+
+361
+00:29:04,400 --> 00:29:08,320
+يعني لو قلت واحد متر واحد، ولا قلت 1.0
+
+362
+00:29:08,320 --> 00:29:13,780
+متر تساوي مئة سنتي، صح ولا لأ؟ طب لو قلت 1.000 متر
+
+363
+00:29:13,780 --> 00:29:19,220
+تساوي مئة سنتي، صح ولا لأ؟ طب لو قلت 1.000 متر
+
+364
+00:29:19,220 --> 00:29:23,300
+تساوي مئة سنتي، صح ولا لأ؟ صحيح، الـ equivalence لا
+
+365
+00:29:23,300 --> 00:29:26,480
+تدخل في تحديد عدد الـ significant figures، يعني لو
+
+366
+00:29:26,480 --> 00:29:30,780
+كانت موجودة في عملية حسابية عندك، تستخدمهاش في
+
+367
+00:29:30,780 --> 00:29:32,960
+تحديد عدد الـ significant figures، ده الجواب لا
+
+368
+00:29:32,960 --> 00:29:36,100
+تستخدمها في تحديد عدد الـ significant figures اللي
+
+369
+00:29:36,100 --> 00:29:36,660
+في الجواب
+
+370
+00:29:43,630 --> 00:29:47,230
+أنا بقول .. أنا بقول إنه إذا كان الـ equivalence
+
+371
+00:29:47,230 --> 00:29:51,510
+factor موجود عندك، تهمله في تحديد عدد الـ
+
+372
+00:29:51,510 --> 00:29:54,310
+significant figures، هاي اللي بقوله، كويس؟ اللي
+
+373
+00:29:54,310 --> 00:29:57,610
+بحدد عدد الـ significant figures هي أرقام النتائج
+
+374
+00:29:57,610 --> 00:30:03,290
+المخبرية، اللي إلها واحدة، نفس الكلام لما نقول والله
+
+375
+00:30:03,290 --> 00:30:09,550
+الـ kilogram ألف gram، أو الـ gram ألف milligram، هذه
+
+376
+00:30:09,550 --> 00:30:14,330
+يا شباب مش .. مش .. مش نتائج مخبرية، مش نتائج
+
+377
+00:30:14,330 --> 00:30:18,430
+مخبرية بالمرة، هذه عبارة عن equivalence factors، هذا
+
+378
+00:30:18,430 --> 00:30:22,070
+عبارة عن معاملات تكافئية، شغلات متكافئة، الألف
+
+379
+00:30:22,070 --> 00:30:25,110
+gram هو عبارة عن كيلو جرام، الواحد gram عبارة عن
+
+380
+00:30:25,110 --> 00:30:29,430
+ألف milligram، فلما تكون هذه موجودة معاك في العملية
+
+381
+00:30:29,430 --> 00:30:32,750
+الحسابية، تطلعش عليها في تحديد عدد الـ significant
+
+382
+00:30:32,750 --> 00:30:36,090
+figures، ماشي؟ هذا اللي بنقوله، الـ equivalence
+
+383
+00:30:36,090 --> 00:30:41,430
+الحاجة الثانية ذكرتها برضه، لو كان الرقم مضروب
+
+384
+00:30:41,430 --> 00:30:46,670
+عندك في عشرة أس كذا، يعني الـ scientific notation
+
+385
+00:30:46,670 --> 00:30:50,190
+فهذا أيضًا ما لهوش دعوة في تحديد عدد الـ significant
+
+386
+00:30:50,190 --> 00:30:55,250
+figures، هي بس بتنقل الإشارة أو بتنقل يعني الـ
+
+387
+00:30:55,250 --> 00:30:58,010
+decimal point من مكان لمكان آخر
+
+388
+00:31:01,800 --> 00:31:09,040
+طيب، نيجي نتعرف أكتر على كيف نحسب أو كيف نعبر عن
+
+389
+00:31:09,040 --> 00:31:13,120
+النتيجة باستخدام الـ significant figures، باستخدام
+
+390
+00:31:13,120 --> 00:31:19,440
+أدوات قياس مختلفة، لو جينا طلعنا على المصطرة في
+
+391
+00:31:19,440 --> 00:31:23,580
+الصفّ، تحت، يعني لو جينا طلعنا على هذه المصطرة، و
+
+392
+00:31:23,580 --> 00:31
+
+445
+00:35:29,730 --> 00:35:32,510
+one digit مقدر تقدير
+
+446
+00:35:34,850 --> 00:35:39,010
+لو حبينا نقرأ الـ master اللي قدامي باجي في الأول
+
+447
+00:35:39,010 --> 00:35:42,790
+مانير ما اقراها بقول والله هذه مقسمة الأقرب أيه؟
+
+448
+00:35:42,790 --> 00:35:46,050
+واحد من عشرة إذا الجواب بدي يكون الأقرب أيه؟ واحد
+
+449
+00:35:46,050 --> 00:35:49,050
+من مية هذا الـ class الأقرب واحد من مية فباجي بقول
+
+450
+00:35:49,050 --> 00:35:53,910
+والله واحد، اتنين ونصف، ستة من عشرة أو أكثر من اتنين
+
+451
+00:35:53,910 --> 00:36:00,410
+وستة من عشرة، اتنين certain، ستة من عشرة certain يبقى
+
+452
+00:36:00,410 --> 00:36:03,990
+بدي رقم واحد بعد ستة من عشرة، جدش ممكن واحد، اتنين
+
+453
+00:36:03,990 --> 00:36:08,950
+تلاتة، أربعة، مش فارق بس ماتحطش تسعة يعني مش جريمة
+
+454
+00:36:08,950 --> 00:36:13,130
+كتير على الاتنين
+
+455
+00:36:13,130 --> 00:36:18,410
+point ستة اتنين مثلا تعتبر شيء جيد يعني ماشي يا
+
+456
+00:36:18,410 --> 00:36:25,370
+شباب، طيب نيجي في البداية تحت لهذا الـ cylinder هذا
+
+457
+00:36:25,370 --> 00:36:29,330
+الـ cylinder الجواب يكون مقرب لأقرب أيه؟ الـ
+
+458
+00:36:29,330 --> 00:36:35,890
+cylinder بتعطينا لأقرب أيه؟ مش صحيح كلامك، هاي
+
+459
+00:36:35,890 --> 00:36:41,880
+خمسين وهاي ستين، هذا بيقرأ الأقرب واحد، إذا التقدير
+
+460
+00:36:41,880 --> 00:36:45,980
+تبع الأقرب إيش بيكون؟ بالظبط، التقدير بيكون الأقرب
+
+461
+00:36:45,980 --> 00:36:49,500
+واحد من عشرة، لو حبينا نقول والله هذا خمسين، لأ
+
+462
+00:36:49,500 --> 00:36:52,300
+أكثر من خمسين، وبنطلع على الـ meniscus، بنطلع على
+
+463
+00:36:52,300 --> 00:36:55,460
+الشرطات،
+
+464
+00:36:55,480 --> 00:37:01,100
+والـ ... الـ ... الـ ... هنا في التقعر، بالظبط التقعر
+
+465
+00:37:01,100 --> 00:37:04,500
+اللي موجود فبقول واحد وخمسين، أكثر من اتنين و
+
+466
+00:37:04,500 --> 00:37:07,520
+خمسين بينما أقل من تلاتة وخمسين، ممكن أقول أبدأ
+
+467
+00:37:07,520 --> 00:37:12,040
+اتنين وخمسين وتسعة وثمانية لكن ما أقولش اتنين و
+
+468
+00:37:12,040 --> 00:37:18,480
+خمسين و مثلاً وخمسة وثمانين من مية، بنرفض بس اه
+
+469
+00:37:18,480 --> 00:37:21,720
+بدام لأقرب واحد إذا النتيجة لأقرب واحد من عشرة
+
+470
+00:37:21,720 --> 00:37:26,580
+اتفجنا، طيب اطلعولي على المصطرة اللي فوق، بتقيس لأقرب
+
+471
+00:37:26,580 --> 00:37:31,140
+أيش في الأول؟ لأقرب واحد، اه واحد، اتنين، تلاتة، لأقرب
+
+472
+00:37:31,140 --> 00:37:35,660
+واحد بتقيس، إذا الجواب لأقرب إيش طيب؟ لأقرب واحد من
+
+473
+00:37:35,660 --> 00:37:39,160
+عشرة، معناه الكلام، الجواب بتطلع على بلاجيه واحد و
+
+474
+00:37:39,160 --> 00:37:43,200
+تلاتين بالظبط، إذا إيش الجواب؟ واحد وتلاتين point
+
+475
+00:37:43,200 --> 00:37:48,030
+zero، واحد وتلاتين point zero، اه يبقى فهمناه في بعض
+
+476
+00:37:48,030 --> 00:37:53,290
+الأحيان لما نجيبلك في الكتاب 31.0، 31.00 مش والله
+
+477
+00:37:53,290 --> 00:37:57,730
+جاي علمال يكتب أصفار أو هيك أجمل، لا هذه إلها معنى
+
+478
+00:37:57,730 --> 00:38:01,010
+هذه بتدلك على أداة القياس، هذه بتقولك إن المصطرة
+
+479
+00:38:01,010 --> 00:38:04,550
+اللي استخدمها بتقيس لأقرب واحد، بينما لو قاعدة
+
+480
+00:38:04,550 --> 00:38:09,090
+المصطرة 0، 5، 10 مافيش هذه الـ ... إيش بيسموها
+
+481
+00:38:09,090 --> 00:38:13,890
+التدرجات بينهم كان اه 31، صح لكن مادام في التدرجات
+
+482
+00:38:13,890 --> 00:38:21,550
+لقى واحد وتلاتين point zero، فضل طبعاً
+
+483
+00:38:21,550 --> 00:38:25,770
+طبعاً significant لأنه دالني على دقة القياس، طيب يا
+
+484
+00:38:25,770 --> 00:38:30,530
+شباب، نتطلع على هذا الشكل اللي قدامي، هذا شكل ميزان
+
+485
+00:38:30,530 --> 00:38:35,780
+بنقوله triple beam، ميزان يُستخدم كتير في الكيميا،
+
+486
+00:38:35,780 --> 00:38:39,840
+حلو، كويس وما بيخربش ورخيص الثمن نسبياً يعني
+
+487
+00:38:39,840 --> 00:38:45,100
+ويستخدم يعني بشكل كبير في المعامل في السنوات
+
+488
+00:38:45,100 --> 00:38:49,540
+الأولى وبرضه اللي عنده مختبر ممكن أنه يستخدمه الـ
+
+489
+00:38:49,540 --> 00:38:52,780
+triple beam لأنه لو شفت بتلاقي تلت تدرجات، كل
+
+490
+00:38:52,780 --> 00:38:57,770
+تدريج بنقوله beam، كويس، نجي نتطلع عليه بشكل يعني
+
+491
+00:38:57,770 --> 00:39:03,150
+أبسط، هاي التلات تدرجات تبعته، في تدريج بيقيس الـ
+
+492
+00:39:03,150 --> 00:39:08,930
+100 gram وفي تدريج بيقيس بالعشرة وفي تدريج بيقيس
+
+493
+00:39:08,930 --> 00:39:13,550
+بالـ gram وبالعشر، كويس؟ طيب، نجي نتطلع على
+
+494
+00:39:13,550 --> 00:39:17,290
+هالوزنة،
+
+495
+00:39:17,290 --> 00:39:25,090
+اجينا وزنّاها، وزنّاها فطلعت الـ ... الـ beams تبعتي بالشكل
+
+496
+00:39:25,090 --> 00:39:31,050
+اللي قدامي بقول هي مية وأربعين، بجي مية وأربعين
+
+497
+00:39:31,050 --> 00:39:36,790
+أربعة أقل من خمسة، هي ... هي ... هي أقل من خمسة، أربعة
+
+498
+00:39:36,790 --> 00:39:42,500
+إذا مية وأربعة وأربعين point واحد من عشرة، اتنين من
+
+499
+00:39:42,500 --> 00:39:46,360
+عشرة، تلاتة من عشرة، أربعة من عشرة، خمسة من عشرة لسه
+
+500
+00:39:46,360 --> 00:39:51,180
+هي هان، هي في النص، إذا one مية وأربعة وأربعين ونص
+
+501
+00:39:51,180 --> 00:39:58,070
+هذه كلها certain، certain، باجي لـ بين الخمسة والستة
+
+502
+00:39:58,070 --> 00:40:03,630
+يعني قراها هو نص خمسة، يعني فمية وأربعة وأربعين وخمسة
+
+503
+00:40:03,630 --> 00:40:08,790
+وخمسين، المية والواحد والأربعة والأربعة point five
+
+504
+00:40:08,790 --> 00:40:12,010
+هذه كلها certain، آخر رقم هو اللي مش certain وهذا
+
+505
+00:40:12,010 --> 00:40:16,790
+طبيعي، لأنه أنا لو ... لو حبيت إني أسأل سؤال من غير لسه
+
+506
+00:40:16,790 --> 00:40:22,090
+ما بعرف جدش الجواب ولا بدي أقرأ، بدي أعرف الـ significant كانت
+
+507
+00:40:22,090 --> 00:40:26,450
+figures اللي بتطلع عندي، في أي خانة، في أي ... في
+
+508
+00:40:26,450 --> 00:40:32,230
+أي خانة، هذا بيقيس لأقرب أيه؟ هذا بيقيس لأقرب واحد
+
+509
+00:40:32,230 --> 00:40:38,280
+من عشرة certain، إذا الجواب يكون لأقرب واحد من مية
+
+510
+00:40:38,280 --> 00:40:43,060
+اتفجنا يا شباب، افهمنا إيش مفهوم significant
+
+511
+00:40:43,060 --> 00:40:47,620
+figures، نيجي نتطلع على هذا الشكل اللي قدامي، آخر
+
+512
+00:40:47,620 --> 00:40:54,860
+حاجة في هذا الموضوع، تلت مية وأربعين وسبعة، لكن هذه
+
+513
+00:40:54,860 --> 00:40:55,980
+ملطبقة تماماً
+
+514
+00:40:58,710 --> 00:41:08,590
+لازم الجواب يكون 347.00 لأن هذا مدرج لأقرب واحد من
+
+515
+00:41:08,590 --> 00:41:11,890
+عشرة، إذا الجواب إيش بده يكون؟ لأقرب واحد من عشرة، طب
+
+516
+00:41:11,890 --> 00:41:14,810
+هذا لما نكون عندي أقول والله تلاتمية وسبعة وأربعين
+
+517
+00:41:14,810 --> 00:41:17,030
+شايف بالظبط تلاتمية وسبعة وأربعين، أقول تلاتمية
+
+518
+00:41:17,030 --> 00:41:20,190
+وسبعة وأربعين من غير zero zero، إيش معناها؟
+
+519
+00:41:20,190 --> 00:41:24,390
+معناها الميزان هذا بيقيس لأقرب عشرة gram، لأقرب
+
+520
+00:41:24,390 --> 00:41:30,600
+عشرة gram، والسبعة هادي تقدير، السابعة هادي
+
+521
+00:41:30,600 --> 00:41:34,400
+إيش مالها؟ تقدير، لأنه دائماً آخر رقم إيش بيكون؟ تقدير
+
+522
+00:41:34,400 --> 00:41:37,680
+لأ، الميزان بيقيسش لأقرب عشر جرام، الميزان بيقيس
+
+523
+00:41:37,680 --> 00:41:42,560
+لأقرب واحد من عشر جرام، ليش تبخس من نتائجك؟ أنت مش
+
+524
+00:41:42,560 --> 00:41:48,340
+بتقرأ على ميزان كويس نسبياً، فليش تقول النتيجة 347؟
+
+525
+00:41:48,340 --> 00:41:52,860
+ليش؟ بنفهم منها إن الميزان المستخدم بيقيس لأقرب عشر
+
+526
+00:41:52,860 --> 00:41:58,140
+جرام، والسبعة هذه اللي في الآخر التقديرية، لكن لأ
+
+527
+00:41:58,140 --> 00:42:01,300
+ميزانك بيقيس لأقرب واحد من عشرة، عشان هيك لما أنت
+
+528
+00:42:01,300 --> 00:42:12,430
+وزن وزن زي هذه، بدك تقول 347.00، طيب يا شباب، نجي
+
+529
+00:42:12,430 --> 00:42:18,410
+الآن نتطلع لكيف نجري عمليات حسابية باستخدام الـ
+
+530
+00:42:18,410 --> 00:42:21,890
+significant figures، فبقول عمليات الحسابية اللي
+
+531
+00:42:21,890 --> 00:42:27,450
+عادة احنا بنجريها هي عمليات بسيطة كتير، إما جمع و
+
+532
+00:42:27,450 --> 00:42:32,770
+طرح، وهذه إلها مفهوم واحد، يعني بتستخدم نفس المفاهيم
+
+533
+00:42:32,770 --> 00:42:39,230
+بتُحل بنفس الطريقة، أو في عندي ضرب وقسمة، وهذه إلها
+
+534
+00:42:39,230 --> 00:42:44,960
+طريقة أخرى، في عندي إما العمليات الحسابية تبعتي إما
+
+535
+00:42:44,960 --> 00:42:49,340
+جمع وطرح، وهذه بتُحل بطريقة معينة، نفس الطريقة
+
+536
+00:42:49,340 --> 00:42:58,080
+بينما ضرب وقسمة بتُحل بطريقة أخرى، عادة الجمع و
+
+537
+00:42:58,080 --> 00:43:04,380
+الطرح بنطلع فيه على الأرقام
+
+538
+00:43:04,380 --> 00:43:09,900
+أو النتائج اللي فيها أعلى uncertainty، أعلى
+
+539
+00:43:09,900 --> 00:43:18,530
+uncertainty، يعني الجواب دائماً بيتوقف على النتيجة
+
+540
+00:43:18,530 --> 00:43:22,190
+اللي فيها أعلى uncertainty، هي اللي بتحكم الجواب يا
+
+541
+00:43:22,190 --> 00:43:29,590
+سيدي، جدش وكأنه يعني عندك سلسلة لكن في حلقة من
+
+542
+00:43:29,590 --> 00:43:33,970
+الحلقات ضعيفة، فقوة السلسلة لا تعتمد على جدش
+
+543
+00:43:33,970 --> 00:43:38,390
+الحلقات الأخرى قوية، لما تجي تشدها تعتمد على أيه؟
+
+544
+00:43:38,390 --> 00:43:43,350
+على الحلقة الضعيفة، بالظبط، زي ما نجيب أربعة، خمسة، عشرة،
+
+545
+00:43:43,350 --> 00:43:46,810
+أتعشر، تنفار، ونقولوا أنتو فريق، بدكم تمسكوا
+
+546
+00:43:46,810 --> 00:43:50,450
+أيدين بعض وتجروا، كويس، لكن واحد فيهم رجله
+
+547
+00:43:50,450 --> 00:43:56,630
+مكسورة، فبدهم يمشوا بإيه؟ بسرعة الإيه؟ البطئ، وهو
+
+548
+00:43:56,630 --> 00:44:02,850
+نفس الكلام، دائماً، دائماً النتيجة النهائية راح
+
+549
+00:44:02,850 --> 00:44:08,530
+تتوقف على النتيجة اللي تحتوي على أعلى uncertainty
+
+550
+00:44:10,080 --> 00:44:18,140
+فمثلاً في عندنا نتيجة بالعدد
+
+551
+00:44:18,140 --> 00:44:23,820
+الصحيح يعني كلها رقم صحيح، بينما في نتيجة بالأعشار
+
+552
+00:44:23,820 --> 00:44:29,780
+وفي نتيجة بواحد من مية، وفي نتيجة بواحد من ألف
+
+553
+00:44:29,780 --> 00:44:33,660
+النتيجة النهائية لازم تكون بالعدد الصحيح، ليه؟ لأن
+
+554
+00:44:33,660 --> 00:44:39,840
+هذه الوحدة الأقل دقة، هذه الوحدة الأقل دقة، الأعلى
+
+555
+00:44:39,840 --> 00:44:43,600
+uncertainty، إحنا إذا الله راضي، الحصة الجاية هنحاول
+
+556
+00:44:43,600 --> 00:44:48,140
+إننا نفصل في هذا الكلام وناخد أمثلة حسابية، إذا الله
+
+557
+00:44:48,140 --> 00:44:52,620
+راضي، أي سؤال يا شباب؟ طيب الله يعطيكم العافية
+
+558
+00:44:52,620 --> 00:44:54,060
+ونشوفكم إن شاء الله الحصة الجاية
diff --git a/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/IFhUAkHuLbs_postprocess.srt b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/IFhUAkHuLbs_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..16919e7636d648cde78d3a1c5b4d91c641156645
--- /dev/null
+++ b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/IFhUAkHuLbs_postprocess.srt
@@ -0,0 +1,2232 @@
+1
+00:00:20,940 --> 00:00:23,800
+بسم الله الرحمن الرحيم طيب يا شباب الحصة الماضية
+
+2
+00:00:23,800 --> 00:00:28,260
+كنا اتحدثنا عن مقدمة عامة في الكيميا التحليلية
+
+3
+00:00:28,260 --> 00:00:34,280
+ووصلنا لإن الطريقة التحليلية تتضمن خطوات منطقية
+
+4
+00:00:35,570 --> 00:00:40,270
+روتينية الاصل أنه يعني الإنسان بيعرفها أو الشخص
+
+5
+00:00:40,270 --> 00:00:44,250
+اللي بيشتغل في هذا المجال بيعرفها معرفة تامة و
+
+6
+00:00:44,250 --> 00:00:51,830
+تصبح عنده مع استمرار العمل على الطرق التحليلية
+
+7
+00:00:51,830 --> 00:00:56,930
+تصبح يعني عنده و كأنها يعني مألوفة ليست حاجة إلى
+
+8
+00:00:56,930 --> 00:01:01,400
+حفظه وقولنا منها اللي هو تحديد المشكلة بدايةو
+
+9
+00:01:01,400 --> 00:01:08,900
+بعدين تحضير عينة ممثلة و بعدين ممكن بعد ما نحضر
+
+10
+00:01:08,900 --> 00:01:13,180
+العينة الممثلة نحضر العينة لتحضير سواء كان في
+
+11
+00:01:13,180 --> 00:01:19,700
+عيننا تخفيف او اذابة او ما شابه ممكن نبطل نعمل
+
+12
+00:01:19,700 --> 00:01:24,760
+عملية separationو ممكن بعد ما نخلص كل هذه العمليات
+
+13
+00:01:24,760 --> 00:01:28,160
+نروح لتطبيق ال procedure أو performing the
+
+14
+00:01:28,160 --> 00:01:33,410
+analytical measurement أو ال procedureوفي الآخر
+
+15
+00:01:33,410 --> 00:01:37,690
+خالص العمليات الحسابية بنقول أنه الطرق الكيميائية
+
+16
+00:01:37,690 --> 00:01:44,090
+بشكل عام تتميز بأنه تصلح لكميات
+
+17
+00:01:44,090 --> 00:01:48,490
+مختلفة من ال solutes فنجد بعض الطرق يحتاج إلى كمية
+
+18
+00:01:48,490 --> 00:01:52,130
+كبيرة من ال solute مثلا أكتر من 100 milligram
+
+19
+00:01:52,130 --> 00:01:56,690
+solute أو analyte المادة اللي أنا بدور عليها أكتر
+
+20
+00:01:56,690 --> 00:02:04,230
+من 100 milligramأو أكتر من 100 Microliter في هذه
+
+21
+00:02:04,230 --> 00:02:10,250
+الحالة تسمى الطريقة Meso method اما اذا كان ال
+
+22
+00:02:10,250 --> 00:02:16,230
+range اللى بتشتغل فيه الطريقة من 10 ل 100 ميلي
+
+23
+00:02:16,230 --> 00:02:20,590
+جرام او من 50 ل 100 مايكرون فالطريقة يمكن اعتبارها
+
+24
+00:02:20,590 --> 00:02:25,780
+sub micro methodيعني طريقة أقل حساسية من الأولى
+
+25
+00:02:25,780 --> 00:02:29,720
+ولا أكتر؟ بالطبع أكتر حساسية من الأولى لأنها
+
+26
+00:02:29,720 --> 00:02:35,280
+تتعامل مع analyte كميته أقل في حين أنه لو كان كمية
+
+27
+00:02:35,280 --> 00:02:41,020
+ال analyte اللى يمكن تحليله باستخدام الطريقة أقل
+
+28
+00:02:41,020 --> 00:02:49,060
+من ذلك مثلا من واحد لعشرة milligram أو منأقل من
+
+29
+00:02:49,060 --> 00:02:51,960
+خمسين microliter in general يعني فتعتبر الطريقة
+
+30
+00:02:51,960 --> 00:02:56,620
+micro method طريقة micro و في حالة ما يكون عندى
+
+31
+00:02:57,680 --> 00:03:02,200
+طريقة قادر على تحليل أقل من واحد ملي جرام فبنسميها
+
+32
+00:03:02,200 --> 00:03:06,580
+ultra micro فهذا تصنيف يعني يعتبر تصنيف عام مش
+
+33
+00:03:06,580 --> 00:03:11,540
+يعني شيء ملزم لكن بشكل عام الطرق الكيميائية تختلف
+
+34
+00:03:11,540 --> 00:03:17,700
+في الحساسية باختلاف قدرتها على العمل في مدى معين
+
+35
+00:03:17,700 --> 00:03:24,900
+من تركيزات ال analyte أو ال solutesفي نفس الوقت
+
+36
+00:03:24,900 --> 00:03:28,620
+اللي احنا بنتكلم فيه عن الطرق ممكن نتكلم فيه ايضا
+
+37
+00:03:28,620 --> 00:03:34,070
+عنالـ Solute نفسه أو نتكلم عن الـ Analyte نفسه
+
+38
+00:03:34,070 --> 00:03:37,650
+ووجوده في العينة فإذا كان كمية الـ Analyte
+
+39
+00:03:37,650 --> 00:03:41,590
+الموجودة في العينة كمية كبيرة نسبيا، يعني أكتر من
+
+40
+00:03:41,590 --> 00:03:46,690
+1% من تركيب العينة هو عبارة عن Analyte في هذه
+
+41
+00:03:46,690 --> 00:03:51,150
+الحالة يُعتبر الـ Analyte Major Constituent مكون
+
+42
+00:03:51,150 --> 00:03:56,650
+رئيسي من مكونات العينة بينما لو كان من 1 من 10 إلى
+
+43
+00:03:56,650 --> 00:04:04,110
+1%، بنقول عنه Minorminor constituent قليل يعني
+
+44
+00:04:04,110 --> 00:04:09,270
+قليل مش يعني مش كتير كتير بينما لو كان كمية ال
+
+45
+00:04:09,270 --> 00:04:12,510
+analyte النسبة المقوية له تقل عن واحد من عشرة في
+
+46
+00:04:12,510 --> 00:04:16,930
+المية فهذا يسمى ال trace constituent ال trace
+
+47
+00:04:16,930 --> 00:04:20,290
+constituent كمية قليلة للغاية
+
+48
+00:04:22,670 --> 00:04:27,610
+في في الحقيقة أيضا في نهاية chapter المقدمة هذا في
+
+49
+00:04:27,610 --> 00:04:35,230
+عندى مصطلحين لابد من التفريق بينهم مصطلح بنقوله
+
+50
+00:04:35,230 --> 00:04:39,230
+analyze و مصطلح بنقوله determine او analysis و
+
+51
+00:04:39,230 --> 00:04:46,660
+determination فهدول المصطلحين استخدمواملتصقين بإما
+
+52
+00:04:46,660 --> 00:04:52,460
+العينة أو الانالايت بحد ذاته فالانالايت دائما
+
+53
+00:04:52,460 --> 00:04:57,280
+يلتصق معاه أو يستخدم معاه كلمة determination
+
+54
+00:04:58,420 --> 00:05:02,420
+الانالايت يستخدم معاه كلمة determination او we
+
+55
+00:05:02,420 --> 00:05:06,680
+determine and analyze we determine and analyze
+
+56
+00:05:06,680 --> 00:05:14,260
+بينما العينة نستخدم معها مصطلح analysis we analyze
+
+57
+00:05:14,260 --> 00:05:21,240
+a samplewe analyze a sample analysis of a sample ف
+
+58
+00:05:21,240 --> 00:05:25,800
+determination مرتبطة مع الانالايت بينما analysis
+
+59
+00:05:25,800 --> 00:05:31,060
+مرتبطة مع العينة أرجو أنه أثناء شغلكم تنتبهوا ل أو
+
+60
+00:05:31,060 --> 00:05:36,180
+تعبيركم عن نتائجكم تنتبهوا للاستخدام الصحيح لهدول
+
+61
+00:05:36,180 --> 00:05:43,340
+المصطلحين الآن ننتقل لأول chapter بتحدث عن معالجة
+
+62
+00:05:43,340 --> 00:05:46,280
+البيانات وقلنا ليش معالجة البيانات مهمة جدا في
+
+63
+00:05:46,280 --> 00:05:52,400
+الكيمة التحليلية خاصة انه باختصار معظم نتائجنا
+
+64
+00:05:52,400 --> 00:05:58,200
+عبارة عن نتائج رقمية حسابية وبالتالي لابد من معرفة
+
+65
+00:05:58,200 --> 00:06:03,600
+كيفية التعامل مع البيانات المختلفة وكيفية معالجتها
+
+66
+00:06:03,600 --> 00:06:09,660
+حتى نستطيع أن نفهم معنى النتائج اللي بنحصل عليها
+
+67
+00:06:10,670 --> 00:06:14,150
+بقول في البداية قبل ما أطلع على معالجة البيانات
+
+68
+00:06:14,150 --> 00:06:18,950
+لابد من التفريق أيضا بين مصطلحين مهمين كتير مصطلح
+
+69
+00:06:18,950 --> 00:06:26,210
+بقوله accuracy ومصطلح بقوله precision هدول مصطلحين
+
+70
+00:06:26,210 --> 00:06:30,330
+مهمين جدا جدا خاصة أنه نتائجنا اللي بنحصل عليها
+
+71
+00:06:30,330 --> 00:06:33,690
+بدنا نعبر عليها نقول والله هل هي نتائج دقيقة أو مش
+
+72
+00:06:33,690 --> 00:06:37,050
+دقيقة مدى دقتها وما إلى ذلك فمهم نعرف إيش يعني
+
+73
+00:06:37,050 --> 00:06:42,950
+accuracyال accuracy أو مصطلح accuracy بيعني مدى
+
+74
+00:06:42,950 --> 00:06:47,710
+قرب النتائج أو النتيجة اللى حصلنا عليها من النتيجة
+
+75
+00:06:47,710 --> 00:06:54,650
+الحقيقية الصحيحة او النتيجة المقبولة دقة بالعربي
+
+76
+00:06:54,650 --> 00:06:58,050
+بنقول عنها دقة لكن برضه precision بنقول عنها دقة
+
+77
+00:06:58,050 --> 00:07:04,640
+بالعربي لكن لكنعموما للتفريق بينهم بنقول إن ال
+
+78
+00:07:04,640 --> 00:07:09,360
+accuracy مدى قرب النتيجة أو النتائج اللي بحصل
+
+79
+00:07:09,360 --> 00:07:13,680
+عليها من النتيجة الصحيحة أو المقبولة، ليش بقول
+
+80
+00:07:13,680 --> 00:07:18,500
+نتيجة صحيحة أو مقبولة؟لأن في الحقيقة يا شباب معظم
+
+81
+00:07:18,500 --> 00:07:23,960
+النتائج هي عبارة عن مقارنات بين نتائج احنا حصلنا
+
+82
+00:07:23,960 --> 00:07:29,300
+عليها ونتيجة خليني اقول او يعني كمية قياسية احنا
+
+83
+00:07:29,300 --> 00:07:33,420
+قدرنا انها قياسية او احنا قررنا انها قياسية فمثلا
+
+84
+00:07:33,420 --> 00:07:41,520
+لما نيجي نتحدث عن الكتلة نتحدث عن مثلا kilogram
+
+85
+00:07:42,470 --> 00:07:46,970
+بنتحدث عن ان ال kilogram ألف جرام، طب ماشي الحال،
+
+86
+00:07:46,970 --> 00:07:50,010
+طب مين اللي قال ان ال kilogram هو عبارة عن هذه
+
+87
+00:07:50,010 --> 00:07:55,010
+الكمية؟ احنا في الحقيقة اللي قررنا ان هذا الكمية
+
+88
+00:07:55,010 --> 00:08:00,370
+من المادة هي عبارة عن kilogramيعني واحدة ماهياش
+
+89
+00:08:00,370 --> 00:08:03,890
+واحدة موجودة من الأذل ومعروفة انها kilogram لأ
+
+90
+00:08:03,890 --> 00:08:07,270
+احنا عملناها وقلنا هادي kilogram والآن موضوعها في
+
+91
+00:08:07,270 --> 00:08:10,770
+معهد القياسات العالمية اللي بده يعمل kilogram بده
+
+92
+00:08:10,770 --> 00:08:13,930
+يعني جيس جدها بالظبط تماما عشان يكون اللي عنده
+
+93
+00:08:13,930 --> 00:08:17,770
+kilogram ونفس الكلام المتراحنا اللي عملنا ال meter
+
+94
+00:08:17,770 --> 00:08:21,310
+وقلنا والله هذه الكمية او هذه المسافة عبارة عن
+
+95
+00:08:21,310 --> 00:08:24,490
+meter وبالتالي قسمناها ل 100 ساطل لكن احنا اللي
+
+96
+00:08:24,490 --> 00:08:27,230
+عملناها فهذا arbitrarily اختياري كان ممكن نعمل ال
+
+97
+00:08:27,230 --> 00:08:32,090
+meter من يعني الحطلة الحقيقة نقول هذا meter لكن لأ
+
+98
+00:08:32,090 --> 00:08:36,100
+فهذه نتيجة طبعتنا هي نتيجة مقبولةمعظم النتائج
+
+99
+00:08:36,100 --> 00:08:38,380
+تبعتنا أو معظم النتائج اللي نتطلع عليها هي عبارة
+
+100
+00:08:38,380 --> 00:08:45,140
+عن نتائج مقاسة بالنسبة لوحدات مقبولة بالنسبة لنا
+
+101
+00:08:45,140 --> 00:08:50,440
+مش وحدات يعني خليني أقول مطلقة لأ علشان هيك
+
+102
+00:08:50,440 --> 00:08:54,760
+تعريفنا لل accuracy هي عبارة عن قرب النتائج تبعتنا
+
+103
+00:08:54,760 --> 00:09:01,880
+من النتيجة الصحيحة أو المقبولة طيب نتطلع علي ال
+
+104
+00:09:01,880 --> 00:09:07,420
+precisionالـ precision بتعني أو يقصد فيها مدى
+
+105
+00:09:07,420 --> 00:09:12,920
+تقارب النتائج اللي بحصل عليها من تجارب أو تجربة
+
+106
+00:09:12,920 --> 00:09:18,080
+مكررة متكررة مدى تقارب هذه النتائج فمثلا اعمل
+
+107
+00:09:18,080 --> 00:09:24,440
+التحليل لتعيين كمية النحاس في الذهب عند اي قطعة
+
+108
+00:09:24,440 --> 00:09:30,460
+الذهب وحبيت اعرف جدش فيها نحاسفحللت التجربة مرة و
+
+109
+00:09:30,460 --> 00:09:33,580
+مرتين و تلاتة و أربعة و خمسة و عشرة كل مرة حصلت
+
+110
+00:09:33,580 --> 00:09:39,080
+على نتيجة مدى تقارب هذه النتائج بعض عن بعض هذا
+
+111
+00:09:39,080 --> 00:09:43,340
+معناته precision كل ما تقاربت أكتر كل ما كانت more
+
+112
+00:09:43,340 --> 00:09:49,490
+precise لكن مش شرط إنها تكون صحيحةمش شرط ان تكون
+
+113
+00:09:49,490 --> 00:09:52,870
+قريبة من النتيجة الصحيحة مدى تقارب النتائج بعضها
+
+114
+00:09:52,870 --> 00:09:56,290
+مع بعض بغض النظر عن قربها من النتيجة الصحيحة أو
+
+115
+00:09:56,290 --> 00:09:59,830
+المقبولة أو لا هذا يسمى ال precision كل ما اقتربت
+
+116
+00:09:59,830 --> 00:10:06,870
+كل ما زاد ل precision تبنيش نتطلع على الشكل
+
+117
+00:10:06,870 --> 00:10:11,630
+اللي قدامي هنا خلينا نقول انه على فرض انه عندنا
+
+118
+00:10:11,630 --> 00:10:15,960
+تجربة ماوالنتيجة الصحيحة تبعتها هي النتيجة
+
+119
+00:10:15,960 --> 00:10:21,340
+الموجودة في الدائرة الصفراء يعني إذا كانت نتيجة
+
+120
+00:10:21,340 --> 00:10:24,700
+مقعد في الدائرة الصفراء فهي نتيجة صحيحة أو مقبولة
+
+121
+00:10:24,700 --> 00:10:28,620
+بينما إذا كانت إبعادات فهي قضية .. هنشوف ممكن تكون
+
+122
+00:10:28,620 --> 00:10:35,760
+قضية أخرى فنتطلع على أول نوع
+
+123
+00:10:35,760 --> 00:10:40,740
+من أنواع الدوائر اللي إلى اليسار بنلاقي كل النتائج
+
+124
+00:10:40,740 --> 00:10:45,730
+واجعة في الدائرة الصفراءو أيضا في نفس الوقت قريبا
+
+125
+00:10:45,730 --> 00:10:48,610
+مع بعض مع بعض وقع في الدائرة الصفراء يعني accurate
+
+126
+00:10:48,610 --> 00:10:52,330
+لأنها
+
+127
+00:10:52,330 --> 00:10:57,590
+قريبة جدا من إتجار الصحيحة أو المقبولة و متقاربة
+
+128
+00:10:57,590 --> 00:11:02,780
+مع بعض مع بعض مانتوا انهم والله preciseالنتائج
+
+129
+00:11:02,780 --> 00:11:06,220
+اللى حصلت عليها فيه او من خلال الرسم الاولى
+
+130
+00:11:06,220 --> 00:11:10,540
+الدوائر الاولى اللى لليسار اعلى اليسار هذه عبارة
+
+131
+00:11:10,540 --> 00:11:15,460
+عن نتائج بعبر عنها بقول ا accurate and precise
+
+132
+00:11:15,460 --> 00:11:18,900
+نيجي
+
+133
+00:11:18,900 --> 00:11:23,640
+للدائرة اللى جانبها على يمينها في الاعلى بنقول
+
+134
+00:11:23,640 --> 00:11:27,980
+النتائج مش واقعة في الدائرة الصفراء واقعة في دائرة
+
+135
+00:11:27,980 --> 00:11:36,270
+اخرى لكنها متقاربةفهي اكيد مش accurate اكيد non
+
+136
+00:11:36,270 --> 00:11:41,670
+accurate او inaccurate بينما بما انها متقاربة فهي
+
+137
+00:11:41,670 --> 00:11:47,930
+precise عشان هيك يعبر عن هذه النتائجprecise but
+
+138
+00:11:47,930 --> 00:11:54,290
+not accurate لو جينا للدائرة السفلة من اليسار
+
+139
+00:11:54,290 --> 00:11:58,970
+بنلاحظ ان بعض النتائج واقع في الدائرة الصفراء
+
+140
+00:11:58,970 --> 00:12:06,910
+وبعضها حول الدائرة الصفراء بحيث انه لو أخدنا متوسط
+
+141
+00:12:06,910 --> 00:12:10,750
+النقطتين او متوسط النقطتين او متوسط النقطتين وين
+
+142
+00:12:10,750 --> 00:12:16,100
+بيجعل متوسط؟ في الدائرة الصفراء معنى الكلاممعنى
+
+143
+00:12:16,100 --> 00:12:21,240
+الكلام بنقدر نقول إنه النتائج هذه accurate لكن هل
+
+144
+00:12:21,240 --> 00:12:24,220
+هي متقاربة من بعضها البعض؟ لأ مش متقاربة من بعضها
+
+145
+00:12:24,220 --> 00:12:29,620
+البعض، إذا هي إيه؟ imprecise أو accurate but not
+
+146
+00:12:29,620 --> 00:12:34,200
+precise لكن الحل الأخير عندنا اللي ممكن يتواجهنا
+
+147
+00:12:34,200 --> 00:12:40,190
+في نتائجنا إنه النتائج scattered مشتتةلكن مشتتة
+
+148
+00:12:40,190 --> 00:12:47,450
+على جانب من جوانب الدوائر، مش منتشر حوالين المركز،
+
+149
+00:12:47,450 --> 00:12:50,870
+يعني لو بتاخده متوسط، هيكون برضه بعيد عن الأصفر،
+
+150
+00:12:50,870 --> 00:12:55,190
+عن الصحيح، فهي scattered و بعيد عن الصحيح، إذا هي
+
+151
+00:12:55,190 --> 00:13:00,370
+neither accurate nor preciseفممكن نتائجنا تكون
+
+152
+00:13:00,370 --> 00:13:03,970
+accurate and precise, accurate but not precise,
+
+153
+00:13:04,110 --> 00:13:07,410
+precise but not accurate, neither accurate nor
+
+154
+00:13:07,410 --> 00:13:13,640
+precise، كله ممكننيجي نمثل هذا الكلام يعني تمثيل
+
+155
+00:13:13,640 --> 00:13:19,320
+بسيط كتير لو جيبنا والله ميزان وقولنا لأ أحدكم لو
+
+156
+00:13:19,320 --> 00:13:23,620
+سمحت اطلع على الميزان عدة مرات فاطلع أول وزنة كانت
+
+157
+00:13:23,620 --> 00:13:29,280
+84 تاني وزنة 83 تالت وزنة 84 رابع وزنة 85 خامس
+
+158
+00:13:29,280 --> 00:13:34,360
+وزنة 84 المتوقع يعني خلينا نقول إنه نتاج متقاربة
+
+159
+00:13:34,360 --> 00:13:37,860
+فهي precise بحد ذاتها precise يعني مش فرق كبير بنا
+
+160
+00:13:37,860 --> 00:13:42,680
+preciseلكن بمجرد ما قلنا هذا الكلام للشاب قال لأ
+
+161
+00:13:42,680 --> 00:13:46,120
+انا وزني بيختلف جبنا ميزان قياسي وقلنا له طب لو
+
+162
+00:13:46,120 --> 00:13:51,160
+سمحت اطلع عليه طلع وزنه 76 كيلو جرام اذا ممكن
+
+163
+00:13:51,160 --> 00:13:55,040
+النتائج تبعتنا تكون precise بان اه طبعا الميزان
+
+164
+00:13:55,040 --> 00:13:58,260
+اللي احنا وزننا عليه فيه مشكلات وهذا بنواجهه كتير
+
+165
+00:13:58,260 --> 00:14:03,100
+في المختبر في بعض الأحيان بتشتغل تحليل ما بتلاحظ
+
+166
+00:14:03,100 --> 00:14:08,630
+انه كل نتائجك أعلى من النتيجة الحقيقيةبتقول ليش؟
+
+167
+00:14:08,630 --> 00:14:11,890
+طب أنا ال procedure بيقوللي خد نص جرام أخدت نص
+
+168
+00:14:11,890 --> 00:14:17,670
+جرام و وزنتي صح 100% إيش معنى النتيجة لما أحلل
+
+169
+00:14:17,670 --> 00:14:21,210
+اللي بيطلع دائما أعلى كتير من مثلا النتيجة
+
+170
+00:14:21,210 --> 00:14:24,230
+الحقيقية أو النتيجة المعطاة، النتيجة المقبولة،
+
+171
+00:14:24,230 --> 00:14:30,260
+اللي أنا عارف مسبقا إيش هيبنقول standard بنقول اه
+
+172
+00:14:30,260 --> 00:14:33,500
+هان في عندك مشكلة في الميزان الميزان بدل ما يعطيك
+
+173
+00:14:33,500 --> 00:14:36,600
+نص جرام صح هو بيقرأ نص جرام لكن في الحقيقة هو
+
+174
+00:14:36,600 --> 00:14:42,420
+بيعطيك واحد جرام مثلا او 75% من الجرام او جرام و
+
+175
+00:14:42,420 --> 00:14:46,840
+نص بيعطيك دائما كمية اكبر لكن ايش اللي بيقرأه نص
+
+176
+00:14:46,840 --> 00:14:50,880
+جرام عشان هيك دائما نتائجك هتكون اعلى نفس المنطق
+
+177
+00:14:50,880 --> 00:14:54,780
+لو استخدمت buret او pipet بدل ما تعطيك عشرة mil
+
+178
+00:14:55,500 --> 00:15:00,140
+قرأت تدريجة عشرة مل لكن إذا كانت بتعطيك مثلا بد
+
+179
+00:15:00,140 --> 00:15:05,760
+العشرة تمانية مل إذا نتائجك باستمرار هتكون أقل من
+
+180
+00:15:05,760 --> 00:15:09,040
+النتيجة الحقيقية لأن انت عامل في حسابك انك ماقد
+
+181
+00:15:09,040 --> 00:15:14,620
+عشرة الاصل انه تعطيك نتيجة قياسية لكن لأنك لما
+
+182
+00:15:14,620 --> 00:15:19,000
+تسحب عشرة انت ماتسحب عشرة انت بتسحب تمانية فقط
+
+183
+00:15:19,000 --> 00:15:23,440
+فنتائجك بالضرورة هتكون أقل من القيمةالمقبولة أو
+
+184
+00:15:23,440 --> 00:15:29,980
+الحقيقية أو الصحيحة لهذا السبب بنقول أنه يعني ممكن
+
+185
+00:15:29,980 --> 00:15:34,140
+نتعرض لمشاكل في ال accuracy ومشاكل في ال precision
+
+186
+00:15:34,140 --> 00:15:38,080
+بشكل كبير وليس شرطا أنت تطابق ال precision مع ال
+
+187
+00:15:38,080 --> 00:15:42,740
+accuracy تلويش دراعي نتائج تبعتك و تحاول تجربهم من
+
+188
+00:15:42,740 --> 00:15:46,330
+بعض على أمل أنه اه والله يقوله شغله كويس يعنيما
+
+189
+00:15:46,330 --> 00:15:50,750
+يدرك إن المتواصل تبعهم يبعد عن النتيجة الحقيقية،
+
+190
+00:15:50,750 --> 00:15:55,050
+لأ خد نتائجك زي ما هي، دائما كون أمين، أخد نتائجك
+
+191
+00:15:55,050 --> 00:15:58,550
+زي ما هي تماما، ما يتغير فيها مطلقا، مش شغلك تتغير
+
+192
+00:15:58,550 --> 00:16:02,110
+فيها، أنت تطبقت النتيجة بأعلى درجة من درجات
+
+193
+00:16:02,110 --> 00:16:06,510
+الحرافية والمهانية، خلاص زي ما تطلع نتائج حطهالكن
+
+194
+00:16:06,510 --> 00:16:10,790
+اكتشف اذا كنت عارف مسبقا النتيجة ولا جيت دائما
+
+195
+00:16:10,790 --> 00:16:14,790
+نتاجك اعلى او نتاجك اقل فاعرف ان في عندك حجم
+
+196
+00:16:14,790 --> 00:16:17,970
+يقولها systematic error هنتكلم عنه في المستقبل او
+
+197
+00:16:17,970 --> 00:16:23,610
+خطأ منهجي ممكن يكون ناتج عن مشاكل في الوزن مشاكل
+
+198
+00:16:23,610 --> 00:16:31,880
+في الحجم او في الجهاز او غيره الآن يا شباببنقدر ان
+
+199
+00:16:31,880 --> 00:16:35,380
+ندخل فعليا في معالجة البيانات وعلشان ندخل في
+
+200
+00:16:35,380 --> 00:16:38,820
+معالجة البيانات لابد من الحديث عن موضوع ال
+
+201
+00:16:38,820 --> 00:16:42,600
+significant figures الأرقام المعنوية أو الأرقام
+
+202
+00:16:42,600 --> 00:16:48,700
+اللي إلها مغزة في البداية لابد من الإشارة لإن
+
+203
+00:16:48,700 --> 00:16:54,900
+الأرقام المعنويةكان تبق على القياسات المخبرية،
+
+204
+00:16:54,900 --> 00:16:58,500
+يعني استخدام مفاهيم الأرقام المعنوية أو ال
+
+205
+00:16:58,500 --> 00:17:02,200
+significant figures فقط، خاص بالإيه؟ بالقياسات
+
+206
+00:17:02,200 --> 00:17:08,300
+المخبرية، وغير خابع أو لا يهتم أو لا يجوز استخدامه
+
+207
+00:17:08,300 --> 00:17:15,420
+أصلا مع الأرقام المجردة أو القيم المجردةغير
+
+208
+00:17:15,420 --> 00:17:20,380
+المخبرية، زي ايش يعني؟ زي مثلا إنه والله أسأل أكم
+
+209
+00:17:20,380 --> 00:17:25,320
+شاب قاعدين عندى في السطر الأول هان، بقول أربعة، لا
+
+210
+00:17:25,320 --> 00:17:27,680
+يقل إنه كونوا أربعة و واحد من عشرة يعني استخدموا
+
+211
+00:17:27,680 --> 00:17:30,320
+اتنين significant figures أو أربعة point zero أو
+
+212
+00:17:30,320 --> 00:17:33,080
+.. يعني هي أربعة point zero zero إلى ما لنهاية، إن
+
+213
+00:17:33,080 --> 00:17:37,380
+هدول أربعة أربعة، لكن لا يندرج أو لا يستخدم مفهوم
+
+214
+00:17:37,380 --> 00:17:41,860
+significant figures مع ..أعداد .. أعداد مجردة احنا
+
+215
+00:17:41,860 --> 00:17:45,100
+بنستخدم مفهوم significant figures مع إيه؟ مع
+
+216
+00:17:45,100 --> 00:17:49,200
+النتائج المخبرية اللي في النهاية إلها وحدة في
+
+217
+00:17:49,200 --> 00:17:54,180
+النهاية إلها إيه؟ وحدة مهم
+
+218
+00:17:54,180 --> 00:17:56,880
+جدا أني أفهم
+
+219
+00:18:00,830 --> 00:18:04,250
+إن استخدام ال significant figures ضروري كتير لأنه
+
+220
+00:18:04,250 --> 00:18:10,330
+بيدلني وبيعرفني على دقة أدوات القياس المستخدمة
+
+221
+00:18:10,330 --> 00:18:15,180
+وبالتالي بيعرفني مدى الثقة في النتيجةالـ
+
+222
+00:18:15,180 --> 00:18:20,040
+Significant Figures راح تعرفني أو بتدلني على دقة
+
+223
+00:18:20,040 --> 00:18:23,840
+أدوات القياس المستخدمة و ناس كانت عارفة دقة أدوات
+
+224
+00:18:23,840 --> 00:18:29,180
+القياس و بفترض الحرفية طبعا في اللي عمل التجربة
+
+225
+00:18:29,180 --> 00:18:36,820
+فبتدلني أيضا على الكفاءة أو على مصداقية النتائج
+
+226
+00:18:36,820 --> 00:18:40,660
+اللي موجودة جدامي فمانستهنش بالـ Significant
+
+227
+00:18:40,660 --> 00:18:46,680
+Figures زي ما هنشوف أمثلة بعد شويةأحنا هنتطلع
+
+228
+00:18:46,680 --> 00:18:50,480
+كأمثلة عامة على المسطرة مثلا بس عشان نبضع المفهوم
+
+229
+00:18:50,480 --> 00:18:55,200
+و هنتطلع على ال graduated cylinder و هنتطلع على
+
+230
+00:18:55,200 --> 00:19:00,680
+الميزان عشان بس نبين إيش المقصود بمفهوم ال
+
+231
+00:19:00,680 --> 00:19:02,580
+significant figures
+
+232
+00:19:04,190 --> 00:19:08,730
+أحنا بنقول الـ Significant Figures بتعبر عن أو
+
+233
+00:19:08,730 --> 00:19:14,110
+تستخدم في التعبير عن النتائج المخبرية لأنه مدامها
+
+234
+00:19:14,110 --> 00:19:18,970
+نتائج مخبرية يعني اللي بيقوم فيها إنسان فتحتمل إنه
+
+235
+00:19:18,970 --> 00:19:22,330
+فيها uncertainty تحتمل إنه فيها نوع من الخطأ ومش
+
+236
+00:19:22,330 --> 00:19:26,270
+شرط إنسان، ممكن آلة، طب الآلة مين صنعها؟ إذاً برضه
+
+237
+00:19:26,270 --> 00:19:32,920
+تحتمل نوع من أنواع الخطألكن لا تتعامل زي ما ذكرت
+
+238
+00:19:32,920 --> 00:19:37,920
+مع ال exact numbers فالقيم المخبرية أو النتاج
+
+239
+00:19:37,920 --> 00:19:44,140
+المخبرية دائما في إلها عادة في إلها واحدة بينما زي
+
+240
+00:19:44,140 --> 00:19:51,380
+ما ذكرت لا نتعامل مع القيم المجردة أو الأرقام اللي
+
+241
+00:19:51,380 --> 00:19:54,160
+فيش إلها واحدة أو ال exact numbers
+
+242
+00:19:56,860 --> 00:20:00,760
+مراجعة سريعة، كيف نتعرف أو كيف نعرف نعد الـ
+
+243
+00:20:00,760 --> 00:20:04,240
+Significant Figures؟ بنقول والله فيه قوانين، لابد
+
+244
+00:20:04,240 --> 00:20:09,440
+من معرفتها القوانين يعني برضه مش بحاجة لشقاء أو
+
+245
+00:20:09,440 --> 00:20:13,040
+يعني معاناة كبيرة في فهمها وتطبيقها، لأنه مرنا عن
+
+246
+00:20:13,040 --> 00:20:20,380
+الموضوع قبل هيك، فبنقول، بنتطلع على كل ما عدا
+
+247
+00:20:20,380 --> 00:20:25,750
+الصفر هو Significantيعني باجي أي رقم بدأ أشوف أكم
+
+248
+00:20:25,750 --> 00:20:30,190
+significant figure فيه، ببدأ من اليسار، و ببدأ من
+
+249
+00:20:30,190 --> 00:20:38,090
+العدد الصحيح، كويس؟ فمثلا عندي 42 و 1 من 10 متر،
+
+250
+00:20:38,090 --> 00:20:43,480
+أكم significant figure فيها؟ بقول بعدواحد اتنين
+
+251
+00:20:43,480 --> 00:20:47,020
+تلاتة كويس كتير مافيش عندي أسفار لكن لو عندي أسفار
+
+252
+00:20:47,020 --> 00:20:51,880
+علي يمين ماليش دعوة هنيجي للأسفار الآن بس بقول أنا
+
+253
+00:20:51,880 --> 00:20:57,680
+كل ما عدا كل ال digits ما عدا الصفر تعتبر ايه
+
+254
+00:20:57,680 --> 00:21:03,300
+significant دائما بالنسبة للأسفار ففي بعض الأحيان
+
+255
+00:21:03,300 --> 00:21:07,620
+هي significant وفي بعض الأحيان insignificant non
+
+256
+00:21:07,620 --> 00:21:13,720
+significantطب إيش الأحيان اللي بتكون فيها الأصفار
+
+257
+00:21:13,720 --> 00:21:16,700
+non-significant أو insignificant؟ قال والله إذا
+
+258
+00:21:16,700 --> 00:21:22,880
+كانت على اليسار، على اليسار، على اليسار دائما
+
+259
+00:21:22,880 --> 00:21:27,940
+الأصفار insignificant حتى لو كان في عيننا علانة
+
+260
+00:21:27,940 --> 00:21:31,950
+عشريةعينا علامة عشرية، ماعيناش علامة عشرية،
+
+261
+00:21:31,950 --> 00:21:37,590
+الأصفار غير معنوية مالهاش معنى، الأصفار مالهاش
+
+262
+00:21:37,590 --> 00:21:41,150
+معنى طيب، هالعلامة العشرية ليش بتكون والأصفار؟ ده
+
+263
+00:21:41,150 --> 00:21:44,830
+بس بتحدد يعني موضوع العلامة العشرية مش أكتر،
+
+264
+00:21:44,830 --> 00:21:49,010
+مالهاش دعوة بال .. بالمغزة أو ال significance زي
+
+265
+00:21:49,010 --> 00:21:51,870
+إيش؟ زي ما أقول والله عندي خمسة gram أكم
+
+266
+00:21:51,870 --> 00:21:56,250
+significant figure في عندي؟طب لو قلت خمسة من الف
+
+267
+00:21:56,250 --> 00:21:59,750
+kilogram ما هي هي هي خمسة gram يعني خمسة من الف
+
+268
+00:21:59,750 --> 00:22:05,210
+kilogram كويس برضه واحد لأ طب الأصفر إيش عملت؟ هي
+
+269
+00:22:05,210 --> 00:22:10,650
+احنا غيرنا الوحدة فقط احنا غيرنا الوحدة لكن عدد ال
+
+270
+00:22:10,650 --> 00:22:13,790
+significant figures لا يتغير لأنه إذا تغير عدد ال
+
+271
+00:22:13,790 --> 00:22:17,970
+significant figures معناته أدات القياس تغيرت إذا
+
+272
+00:22:17,970 --> 00:22:20,930
+تغير عدد ال significant figures معناته أدات القياس
+
+273
+00:22:20,930 --> 00:22:25,360
+تغيرت وهذا غير صحيحعلشان هيك بنقول الأصفار اللي
+
+274
+00:22:25,360 --> 00:22:32,880
+على اليمين لا تحسب فمثلا الرقم 0.025 متر هذا فيه
+
+275
+00:22:32,880 --> 00:22:38,080
+اتنين فيه اتنين لإنه عبارة عن ال 25 من الف متر
+
+276
+00:22:38,080 --> 00:22:42,240
+يعبر عن اتنين و نص سانتي اتنين و نص سانتي يمكن
+
+277
+00:22:42,240 --> 00:22:46,840
+كتابتها اتنين و نص في عشرة أسالي باتنين رقمين two
+
+278
+00:22:46,840 --> 00:22:50,180
+digits two significant figures فقط طيب
+
+279
+00:22:52,700 --> 00:22:56,780
+بنقول إذا كان في عندي أعداد صحيحة وفي بينهم أصفار
+
+280
+00:22:56,780 --> 00:23:01,520
+كل الأصفار اللي بين الأعداد الصحيحة خلاص بينحسبه
+
+281
+00:23:01,520 --> 00:23:05,380
+فعندي مثلا أربعين و واحد من عشرة هي عبارة عن تلاتة
+
+282
+00:23:05,380 --> 00:23:10,360
+significant figures بنتكلم
+
+283
+00:23:10,360 --> 00:23:14,380
+الآن عن الأصفار اللي على اليسار الأصفار اللي في
+
+284
+00:23:14,380 --> 00:23:17,860
+المنتصف أو بين الأعداد الصحيحة بنتكلم عن الأصفار
+
+285
+00:23:17,860 --> 00:23:22,600
+اللي على اليمينالأصفر اللي على اليمين بدنا نتذكر
+
+286
+00:23:22,600 --> 00:23:26,280
+انه مرات بتكون significant و مرات بتكون
+
+287
+00:23:26,280 --> 00:23:31,540
+insignificant بسيطة كتير بتكون significant دائما
+
+288
+00:23:31,540 --> 00:23:36,780
+إذا كانت في عندي علامة عشرية إذا عندي علامة عشرية
+
+289
+00:23:36,780 --> 00:23:39,920
+إنتهى الموضوع كل اللي على اليمين significant إذا
+
+290
+00:23:39,920 --> 00:23:43,040
+عندي علامة عشرية إذا كل اللي على اليمين
+
+291
+00:23:43,040 --> 00:23:48,650
+significant لكن لو فيش عندي علامة عشريةأه في عندي
+
+292
+00:23:48,650 --> 00:23:54,450
+hand مشكلة هنتعرف عليها فمثلا واحد واربعين متر حلو
+
+293
+00:23:54,450 --> 00:23:58,250
+كتير هذا عبارة عن مدان في عندي علامة عشرية اذا كل
+
+294
+00:23:58,250 --> 00:24:01,450
+الأصفر اللي على اليمين تحسب يبقى هذا تلاتة واحد
+
+295
+00:24:01,450 --> 00:24:05,530
+تانين تلاتة طيب مثلا
+
+296
+00:24:08,630 --> 00:24:14,730
+441.2×0.20 يعني هذا فيه خمسة الأصفر اللي على
+
+297
+00:24:14,730 --> 00:24:19,110
+اليمين تحسب ليه كمان مرة؟ لأنه عندي علامة عشرية و
+
+298
+00:24:19,110 --> 00:24:22,650
+هنشوف ليه هذا الكلام بعد شوية لما ناخد أمثلة
+
+299
+00:24:22,650 --> 00:24:28,020
+حقيقية هنشوف ليه هذا الكلاميمكن كتابة الرقم بالـ
+
+300
+00:24:28,020 --> 00:24:30,760
+Scientific Notation الـ Scientific Notation لا
+
+301
+00:24:30,760 --> 00:24:36,280
+تحسب زي ما هنشوف أيضا بعد شوية ف 4.10 في 10 أقص
+
+302
+00:24:36,280 --> 00:24:41,040
+واحد تلاتة العشرة أقص أي شيء موجب أو أي شيء سالب
+
+303
+00:24:41,040 --> 00:24:44,120
+هذا مالوش تعوى هذا عبارة عن كتابة الرقم بال
+
+304
+00:24:44,120 --> 00:24:47,940
+Scientific Notation بالطريقة العلمية مايله أي دخل
+
+305
+00:24:47,940 --> 00:24:51,660
+في تحديد عدد ال significant figures اللييله دخل في
+
+306
+00:24:51,660 --> 00:24:56,930
+تحديد عدد الرقم اللي جابله4.10 هذا تلاتة لو كانت 4
+
+307
+00:24:56,930 --> 00:25:02,510
+.1 لحالها يبقى هذا اتنين لو كانت 4.100 يبقى هذا
+
+308
+00:25:02,510 --> 00:25:06,670
+اربعة في اي اش مكانة مضروبة تكون في عشر أقصر اي اش
+
+309
+00:25:06,670 --> 00:25:13,170
+مكان مافيش عندى اي مشكلة في هذا الكلام لكن الأرقام
+
+310
+00:25:13,170 --> 00:25:18,390
+اذا كانت مش موجودة مش موجودة عاليمين بعد فاصلة
+
+311
+00:25:18,390 --> 00:25:23,630
+عشرية يعني مافيش عندى فاصلة عشرية في الرقم نفسهففي
+
+312
+00:25:23,630 --> 00:25:26,570
+الحقيقة يعني ممكن تكون significant أو ممكن تكون
+
+313
+00:25:26,570 --> 00:25:30,430
+insignificant هي بتكون significant إذا أنا كنت
+
+314
+00:25:30,430 --> 00:25:34,660
+عارف أداة القياسبحدد اذا كانت significant ولا لا،
+
+315
+00:25:34,660 --> 00:25:38,500
+لكن احنا هنعتبرها خلال الفصل هذا بما ان احنا
+
+316
+00:25:38,500 --> 00:25:43,100
+مايعطيكمش أداة القياس عادة يعني و بنكتب و بنشبركم
+
+317
+00:25:43,100 --> 00:25:45,340
+تكتبوا بالطريقة العلمية و بنعطيكم رقم بالطريقة
+
+318
+00:25:45,340 --> 00:25:49,960
+العلمية فهنعتبر انه كل الأصفار اللي على اليمين إذا
+
+319
+00:25:49,960 --> 00:25:54,760
+مافيش decimal point تعتبر insignificant تماشيا مع
+
+320
+00:25:54,760 --> 00:25:58,800
+الكتاب اللي موجود معاناfixed يعني تمشيا معاه
+
+321
+00:25:58,800 --> 00:26:02,460
+هنعتبر كل الأصفر اللي على اليمين insignificant لكن
+
+322
+00:26:02,460 --> 00:26:06,740
+في بعض الأحيان لو أنا كنت عارف ايش أداة القياس
+
+323
+00:26:06,740 --> 00:26:09,340
+ممكن والله هذه الأصفر اعرف انها significant او لا
+
+324
+00:26:09,340 --> 00:26:15,160
+لكن اذا كان انا مش عارف فعادة احنا هنعتبر دائما ان
+
+325
+00:26:15,160 --> 00:26:17,540
+الأصفر اللي على اليمين مادام في الشعين ال decimal
+
+326
+00:26:17,540 --> 00:26:22,760
+point هتكون insignificant فمثلا الكمية
+
+327
+00:26:24,020 --> 00:26:30,940
+أو القياس 52800 كويس ممكن يكون تلاتة أو أربعة أو
+
+328
+00:26:30,940 --> 00:26:35,180
+خمسة لكن انا هاعتبره جديش تلاتة لإن الأصحار
+
+329
+00:26:35,180 --> 00:26:38,380
+العالمين لا تحسبت فعشان هيك بابتبه five point two
+
+330
+00:26:38,380 --> 00:26:44,840
+eight في عشر أقصر أربعة مثلا ممكن وابتش ممكن يكون
+
+331
+00:26:44,840 --> 00:26:48,320
+في أربعة مش تلاتة لو كتبته five point two eight
+
+332
+00:26:48,320 --> 00:26:53,280
+zero في عشر أقصر أربعة وابتش ممكن يكون خمسة
+
+333
+00:26:56,880 --> 00:27:02,820
+5.2800×10 4 هذا خمسة فيه لكن هذا لو بدي اعبر عنه
+
+334
+00:27:02,820 --> 00:27:05,680
+انا زي ما هم مكتوب زي هيك بقول هذا عبارة عن تلاتة
+
+335
+00:27:05,680 --> 00:27:09,720
+يمكن اتعبر عنه 5.28×10 4
+
+336
+00:27:13,300 --> 00:27:18,580
+بدي اتكلم شويه عن ال exact numbers انا ذكرت exact
+
+337
+00:27:18,580 --> 00:27:21,980
+numbers كأن يكون عدد جدش عدد الطلاب في البنك الأول
+
+338
+00:27:21,980 --> 00:27:29,040
+بنقول أربعة او انت عملت التجربة خمس مراتلما أقول
+
+339
+00:27:29,040 --> 00:27:34,240
+والله عملت التجارب خمس مرات و أجمع النتائج و
+
+340
+00:27:34,240 --> 00:27:37,260
+أقسمها على خمس عشان أجيب ال average و أري عدد ال
+
+341
+00:27:37,260 --> 00:27:41,020
+significant figures بقول الخمسة هذه لا تدخل في
+
+342
+00:27:41,020 --> 00:27:45,820
+تحديد عدد ال significant figuresجال لأن الخمسة هذه
+
+343
+00:27:45,820 --> 00:27:49,040
+عدد صحيح لا يمكن يكون عن التجارب اللي عملتها انا
+
+344
+00:27:49,040 --> 00:27:52,200
+خمسة أو تسعة من عشرة او اربع او تسعة من عشرة او
+
+345
+00:27:52,200 --> 00:27:54,260
+خمسة و واحد من عشرة او خمسة و تسعة من عشرة هذه
+
+346
+00:27:54,260 --> 00:27:57,640
+الخمسة هي عبارة عن five point zero zero zero zero
+
+347
+00:27:57,640 --> 00:28:02,680
+إلى مال نهايةبكويس ليه؟ لأنها عدد صحيح، عدد صحيح
+
+348
+00:28:02,680 --> 00:28:07,820
+من التجارب، فهي لا تدخل في حساب أو في تحديد عدد ال
+
+349
+00:28:07,820 --> 00:28:11,280
+significant figures، لأن احنا اتفرجنا على انه اللي
+
+350
+00:28:11,280 --> 00:28:15,860
+بيدخل في تحديد عدد ال significant figures هو فقط
+
+351
+00:28:15,860 --> 00:28:22,450
+النتائج المخبرية، الخامسة هذه مش نتيجةخمسة يعني
+
+352
+00:28:22,450 --> 00:28:25,470
+تقرير حق الأكام تجربة عملت، إجابة على أكام تجربة
+
+353
+00:28:25,470 --> 00:28:31,390
+عملت، خمسة، عدد صحيح، فهذا أول شيء لا يعتبر أو لا
+
+354
+00:28:31,390 --> 00:28:35,950
+يستخدم في حساب عدد ال significant figures الحاجة
+
+355
+00:28:35,950 --> 00:28:42,510
+التانية اللي أيضا تعتبر exact numberرقم صحيح اللي
+
+356
+00:28:42,510 --> 00:28:45,610
+هي ال equivalence ماهي ال equivalence يعني انا
+
+357
+00:28:45,610 --> 00:28:51,730
+عارف مثلا انه واحد متر تساوي مائة centimeter اكم
+
+358
+00:28:51,730 --> 00:28:56,280
+significant figure فيه في الواحد متربقول لأ مش
+
+359
+00:28:56,280 --> 00:28:59,900
+واحد، في عدد لا نهائي، لأن هذا equivalance، هذا
+
+360
+00:28:59,900 --> 00:29:04,400
+تكافؤ، أنا عرفت الواحد متر على أنه ميت صنطيمتر،
+
+361
+00:29:04,400 --> 00:29:08,320
+يعني لو قلت واحد متر واحد، ولا قلت one point zero
+
+362
+00:29:08,320 --> 00:29:13,780
+متر تساوي ميت صنطي، صح ولا لأ؟طب لو قلت 1.000 متر
+
+363
+00:29:13,780 --> 00:29:19,220
+تساوي 100 ساطي صح ولا لأ؟ طب لو قلت 1.000 متر
+
+364
+00:29:19,220 --> 00:29:23,300
+تساوي 100 ساطي صح ولا لأ؟ صحيح ال equivalence لا
+
+365
+00:29:23,300 --> 00:29:26,480
+تدخل في تحديد عدد ال significant figures يعني لو
+
+366
+00:29:26,480 --> 00:29:30,780
+كانت موجودة في عملية حسابية عندك تستخدمهاش في
+
+367
+00:29:30,780 --> 00:29:32,960
+تحديد عدد ال significant figures ده الجواب لا
+
+368
+00:29:32,960 --> 00:29:36,100
+تستخدمها في تحديد عدد ال significant figures اللي
+
+369
+00:29:36,100 --> 00:29:36,660
+في الجواب
+
+370
+00:29:43,630 --> 00:29:47,230
+أنا بقول .. أنا بقول إنه إذا كان ال equivalence
+
+371
+00:29:47,230 --> 00:29:51,510
+factor موجود عندك، تهتملوش في تحديد عدد ال
+
+372
+00:29:51,510 --> 00:29:54,310
+significant figures، هاي اللي بقوله، كويس؟ اللي
+
+373
+00:29:54,310 --> 00:29:57,610
+بحدد عدد ال significant figures هي أبارع النتائج
+
+374
+00:29:57,610 --> 00:30:03,290
+المخبرية، اللي إلها واحدةنفس الكلام لما نقول والله
+
+375
+00:30:03,290 --> 00:30:09,550
+ال kilogram ألف gram أو ال gram ألف milligram، هذه
+
+376
+00:30:09,550 --> 00:30:14,330
+يا شباب مش .. مش .. مش نتائج مخبرية، مش نتائج
+
+377
+00:30:14,330 --> 00:30:18,430
+مخبرية بالمرة، هذه عبارة عن equivalence factorsهذا
+
+378
+00:30:18,430 --> 00:30:22,070
+عبارة عن معاملات تكافئية، شغلات متكافئة، الألف
+
+379
+00:30:22,070 --> 00:30:25,110
+جرام هو عبارة عن كيلو جرام، الواحد جرام عبارة عن
+
+380
+00:30:25,110 --> 00:30:29,430
+ألف ملي جرام، فلما تكون هذه موجودة معاك في العملية
+
+381
+00:30:29,430 --> 00:30:32,750
+الحسابية، تطلعش عليها في تحديد عدد ال significant
+
+382
+00:30:32,750 --> 00:30:36,090
+figures، ماشي؟ هذا اللي بنقوله ال equivalence
+
+383
+00:30:36,090 --> 00:30:41,430
+الحاجة التانية ذكرتها برضه، لو كان الرقم مضروب
+
+384
+00:30:41,430 --> 00:30:46,670
+عندك في عشر أقص كذا،فيعني ال scientific notation
+
+385
+00:30:46,670 --> 00:30:50,190
+فهذا أيضا مالهاش دعوة في تحديد عدد ال significant
+
+386
+00:30:50,190 --> 00:30:55,250
+figures هي بس بتنجل الإشارة أو بتنجل يعني ال
+
+387
+00:30:55,250 --> 00:30:58,010
+decimal point من مكان لمكان آخر
+
+388
+00:31:01,800 --> 00:31:09,040
+طيب نيجي نتعرف أكتر على كيف نحسب أو كيف نعبر عن
+
+389
+00:31:09,040 --> 00:31:13,120
+النتيجة باستخدام ال significant figures باستخدام
+
+390
+00:31:13,120 --> 00:31:19,440
+أدوات قياس مختلفة لو جينا نطلعنا على المصطرة في
+
+391
+00:31:19,440 --> 00:31:23,580
+الصفلة تحت يعني لو جينا نطلعنا على هذه المصطرة و
+
+392
+00:31:23,580 --> 00:31:27,260
+بدنا نجيس object بدنا نجيس object هي من الصفر ماشي
+
+393
+00:31:27,260 --> 00:31:29,320
+ل بعد الإتنين بشوية
+
+394
+00:31:31,850 --> 00:31:36,270
+انا قدرتها انها اتنين و نص فيك تطلع عليها و تقدرها
+
+395
+00:31:36,270 --> 00:31:41,090
+بشكل اخر ممكن
+
+396
+00:31:41,090 --> 00:31:46,590
+نكون اكثر دقة من اتنين و نص لو طلعنا منيح؟ ده دياش
+
+397
+00:31:46,590 --> 00:31:50,350
+ممكن تقترح علينا يعني ممكن واحد و خمسين في حد
+
+398
+00:31:50,350 --> 00:31:54,850
+بقترح حاجة تانية اتنين و خمسين او خمسة و خمسين طيب
+
+399
+00:31:54,850 --> 00:31:59,070
+خلينا ناخد في اعتبارنا حاجة دبل ما نحكي اكتر عن
+
+400
+00:31:59,070 --> 00:32:03,810
+الموضوع او نقول صح او غلطهذه المصطرة مدرجة لأقرب
+
+401
+00:32:03,810 --> 00:32:10,170
+ايه؟ بقول لأقرب عدد صحيح هذه المصطرة مدرجة لأقرب
+
+402
+00:32:10,170 --> 00:32:15,310
+عدد صحيح العقل البشري يا شباب لا يستطيع تقسيم
+
+403
+00:32:15,310 --> 00:32:20,010
+الجزء بكفاءة لأكتر من عشر أجزاء يعني عندي من
+
+404
+00:32:20,010 --> 00:32:24,230
+الواحد والاتنين هذا جزء مش مقسم العقل البشري لو
+
+405
+00:32:24,230 --> 00:32:27,390
+بده يجسمه بقدر يجسمه لعشر أجزاء مش لأكتر من عشر
+
+406
+00:32:27,390 --> 00:32:32,390
+أجزاءنفس الكلام من 2 إلى 3 هذا جزء واحد يعني
+
+407
+00:32:32,390 --> 00:32:35,870
+مابنقدرش نجسمه العقل البشر لاز تقسيمه يعني لاز
+
+408
+00:32:35,870 --> 00:32:42,070
+تقدير القيمة لأكثر من عشر يعني عشرها عشر الكمية
+
+409
+00:32:42,070 --> 00:32:48,110
+علشان هيك بنقول احنا انه بالضرورة هذا ال object
+
+410
+00:32:48,110 --> 00:32:54,270
+أكبر من 2 صحيح؟ أكبر من 2 لكنه أقل من 3 فأكبر يبقى
+
+411
+00:32:54,270 --> 00:32:57,390
+ال 2 هذا certain أنا متأكد أنه أكبر من 2 صح ولا
+
+412
+00:32:57,390 --> 00:33:04,780
+لأ؟بدي أقدر الرقم اللي بعده تقدير مدام أداة القياس
+
+413
+00:33:04,780 --> 00:33:10,200
+بتعطيلي أقرب واحد صحيح إذا التقدير بدي يكون لأقرب
+
+414
+00:33:10,200 --> 00:33:14,940
+واحد من عشرة التقدير بدي يكون لأقرب واحد من عشرة
+
+415
+00:33:14,940 --> 00:33:18,580
+فش واحد من .. الخمسة من عشرة هاد اتنين و نص أنا
+
+416
+00:33:18,580 --> 00:33:21,900
+قدرتها اتنين و نص الخمسة من عشرة هادي تقدير ولا
+
+417
+00:33:21,900 --> 00:33:26,950
+certainتقدير طب إذا كان هذا تقدير يعني فيها شك صح
+
+418
+00:33:26,950 --> 00:33:32,930
+ولا لأ فما بالكم حد يقولي والله 51 او 54 او 52 لأ
+
+419
+00:33:32,930 --> 00:33:37,030
+إذا كان الكبير اللي هو في الأعشار فيه شك فما بالنا
+
+420
+00:33:37,030 --> 00:33:40,930
+في الواحد من 100 كمان مرة بدي أقول إذا كان آدات
+
+421
+00:33:40,930 --> 00:33:44,410
+القياس مقرب لأقرب واحد صحيح إذا الجواب بدي يكون
+
+422
+00:33:44,410 --> 00:33:48,790
+لأقرب أشر الجواب بدي يكون لأقرب أشر لأن التقدير
+
+423
+00:33:48,790 --> 00:33:53,620
+بدي يكون في الأعشار مدام المعروفلأقرب واحد صحيح،
+
+424
+00:33:53,620 --> 00:33:57,540
+إذا التقدير لوين بده يكون؟ للأعشار، لأن العقل
+
+425
+00:33:57,540 --> 00:34:02,540
+البشري لا يستطيع تقسيم الجزء لأكثر من عشر أجزاء طب
+
+426
+00:34:02,540 --> 00:34:05,580
+نيجي للمصطر اللي فوق، نفس المصطر اللي تحت، لكن
+
+427
+00:34:05,580 --> 00:34:07,800
+مقسمة
+
+428
+00:34:08,840 --> 00:34:13,600
+من 1 ل 2 مقسمة ل 10 من 2 ل 3 مقسمة ل 10 فانا لما
+
+429
+00:34:13,600 --> 00:34:18,020
+أجي أقول هي أكبر من 2 صح ولا لأ طب أكبر من 2 و 1
+
+430
+00:34:18,020 --> 00:34:24,340
+من 10 أكبر من 2 و 2 من 10 أكبر من 2 و نص اه اذا ال
+
+431
+00:34:24,340 --> 00:34:29,230
+2 certainوالنص certain، خمسة من عشرة certain، إذا
+
+432
+00:34:29,230 --> 00:34:32,530
+بقدر أقرب لرقم واحد بعدها، يعني بقرب لواحد من مية،
+
+433
+00:34:32,530 --> 00:34:39,590
+ولو لاحظته المصدر مقربة لأقرب واحد من عشر، لأقرب
+
+434
+00:34:39,590 --> 00:34:43,750
+عشر، إذا النتيجة تبعتي بدها تكون إيه؟ التقدير
+
+435
+00:34:43,750 --> 00:34:50,520
+لأقرب واحد من مية، إذا دائما مش أكتر من العشرعشر
+
+436
+00:34:50,520 --> 00:34:54,460
+اللي موجود عشر اللي موجود فهان بقول والله اه
+
+437
+00:34:54,460 --> 00:34:59,520
+الاتنين سيرتين النص السيرتين اه الخمسة هي التقرير
+
+438
+00:34:59,520 --> 00:35:02,880
+ممكن تقدر انت تقول والله two point five four بتمشي
+
+439
+00:35:02,880 --> 00:35:07,780
+معايا two point five six بتمشي معايا مش مشكلة لكن
+
+440
+00:35:07,780 --> 00:35:10,760
+ماتقوليش two point four لأ ال four فيش فيها شك
+
+441
+00:35:10,760 --> 00:35:15,870
+الخمسة فيش فيها شكفالشك بدي يكون في الرقم الأخير
+
+442
+00:35:15,870 --> 00:35:20,030
+ومش مسموح بأكتر من one digit يكون فيه uncertainty
+
+443
+00:35:20,030 --> 00:35:23,810
+يبقى ال uncertainty هو عبارة عن one single digit
+
+444
+00:35:23,810 --> 00:35:29,730
+مش أكتر يبقى عندك المعروف زائد فقط واحد مقدر تقدير
+
+445
+00:35:29,730 --> 00:35:32,510
+one digit مقدر تقدير
+
+446
+00:35:34,850 --> 00:35:39,010
+لو حبينا نقرأ ال master اللي قدامي باجي في الأول
+
+447
+00:35:39,010 --> 00:35:42,790
+مانير ما اقراها بقول والله هذه مقسمة الأقرب ايه؟
+
+448
+00:35:42,790 --> 00:35:46,050
+واحد من عشرة اذا الجواب بدي يكون الأقرب ايه؟ واحد
+
+449
+00:35:46,050 --> 00:35:49,050
+من مية هذا class الأقرب واحد من مية فباجي بقول
+
+450
+00:35:49,050 --> 00:35:53,910
+والله واحد تنين و نص ستة من عشرة او اكتر من اتنين
+
+451
+00:35:53,910 --> 00:36:00,410
+وستة من عشرة اتنينcertain ستة من عشرة certain يبقى
+
+452
+00:36:00,410 --> 00:36:03,990
+بدي رقم واحد بعد ستة من عشرة جدش ممكن واحد اتنين
+
+453
+00:36:03,990 --> 00:36:08,950
+تلاتة اربع مش فارق بس ماتحطش تسعة يعني مش جريمة
+
+454
+00:36:08,950 --> 00:36:13,130
+كتير على ال اتنين
+
+455
+00:36:13,130 --> 00:36:18,410
+point ستة اتنين مثلا تعتبر شئ جيد يعني ماشي يا
+
+456
+00:36:18,410 --> 00:36:25,370
+شباب طيب نيجي في البداية تحت لهذا ال cylinderهذا
+
+457
+00:36:25,370 --> 00:36:29,330
+الـ cylinder الجواب يكون مقرب لأقرب ايه؟ ال
+
+458
+00:36:29,330 --> 00:36:35,890
+cylinder بتعطينا لأقرب ايه؟ مش صحيح كلامك هاي
+
+459
+00:36:35,890 --> 00:36:41,880
+خمسين وهاي ستينهذا بيقرأ الأقرب واحد، إذا التقدير
+
+460
+00:36:41,880 --> 00:36:45,980
+تبع الأقرب إيش بيكون؟ بالظبط التقدير بيكون الأقرب
+
+461
+00:36:45,980 --> 00:36:49,500
+واحد من عشرة، لو حبينا نقول و الله هذا خمسين، لأ
+
+462
+00:36:49,500 --> 00:36:52,300
+أكتر من خمسين، و بنطلع على ال meniscus، بنطلع على
+
+463
+00:36:52,300 --> 00:36:55,460
+الشرطات،
+
+464
+00:36:55,480 --> 00:37:01,100
+وال .. ال .. ال .. هنا في التقعر بالظبط التقعر
+
+465
+00:37:01,100 --> 00:37:04,500
+اللي موجود فبقول واحد و خمسين اكتر من اتنين و
+
+466
+00:37:04,500 --> 00:37:07,520
+خمسين بينما اقل من تلاتة و خمسين ممكن اقول ابدا
+
+467
+00:37:07,520 --> 00:37:12,040
+اتنين و خمسين و تسعة و تمانية لكن ماجولش اتنين و
+
+468
+00:37:12,040 --> 00:37:18,480
+خمسين و مثلا و خمسة و تمانين من ميةبنفهش بس اه
+
+469
+00:37:18,480 --> 00:37:21,720
+بدام لاقرب واحد اذا النتيجة لاقرب واحد من عشرة
+
+470
+00:37:21,720 --> 00:37:26,580
+اتفجنا طيب اطلعولي على المصطر اللي فوق بتجيس لاقرب
+
+471
+00:37:26,580 --> 00:37:31,140
+ايش في الاول لاقرب واحد اه واحد تانين تلاتة لاقرب
+
+472
+00:37:31,140 --> 00:37:35,660
+واحد بتجيس اذا الجواب لاقرب ايش طيب لاقرب واحد من
+
+473
+00:37:35,660 --> 00:37:39,160
+عشرة معناه الكلام الجواب بتطلع على بلاجيه واحد و
+
+474
+00:37:39,160 --> 00:37:43,200
+تلاتين بالظبط اذا ايش الجواب واحد تلاتين point
+
+475
+00:37:43,200 --> 00:37:48,030
+zero واحد تلاتين point zeroاه يبقى فهمناه في بعض
+
+476
+00:37:48,030 --> 00:37:53,290
+الأحيان لما نجيبلك في الكتاب 31.0 31.00 مش والله
+
+477
+00:37:53,290 --> 00:37:57,730
+جاي علمال يكتب أصفار أو هيك أجمل لا هذه إلها معنى
+
+478
+00:37:57,730 --> 00:38:01,010
+هذه بتدلك علي أداة القياس هذه بتقولك إن المصطر
+
+479
+00:38:01,010 --> 00:38:04,550
+اللي استخدمها بتجيس لأقرب واحد بينما لو قاعدة
+
+480
+00:38:04,550 --> 00:38:09,090
+المصطرة 0 5 10 مافيش هذه ال .. إيش بيسموها
+
+481
+00:38:09,090 --> 00:38:13,890
+التدرجات بينهم كان اه 31 صحلكن مادام في التدرجات
+
+482
+00:38:13,890 --> 00:38:21,550
+لقى واحد و تلاتين point zero فضل طبعا
+
+483
+00:38:21,550 --> 00:38:25,770
+طبعا significant لأنه دالني على دات القياس طيب يا
+
+484
+00:38:25,770 --> 00:38:30,530
+شباب نتطلع على هذا الشكل اللي جداني هذا شكل ميزان
+
+485
+00:38:30,530 --> 00:38:35,780
+بنقوله triple beamميزانيك بيستخدم كتير في الكيميا،
+
+486
+00:38:35,780 --> 00:38:39,840
+حلو، كويس وما بيخربش ورخيص الثمن نسبيا يعني
+
+487
+00:38:39,840 --> 00:38:45,100
+ويستخدم يعني بشكل كبير في المعامل في السنوات
+
+488
+00:38:45,100 --> 00:38:49,540
+الأولى وبرضه اللي عنده مختبر ممكن انه يستخدمه ال
+
+489
+00:38:49,540 --> 00:38:52,780
+triple beam لإنه لو شفت بتلاقي تلت تدرجات، كل
+
+490
+00:38:52,780 --> 00:38:57,770
+تدريج بنقوله beam، كويسنجي نتطلع عليه بشكل يعني
+
+491
+00:38:57,770 --> 00:39:03,150
+أبسط، هاي التلات تدرجات تبعته، في تدريج بيجيس ال
+
+492
+00:39:03,150 --> 00:39:08,930
+100 gram وفي تدريج بيجيس بالعشرة وفي تدريج بيجيس
+
+493
+00:39:08,930 --> 00:39:13,550
+بال gram و بالعشر، كويس؟ طيب، نجي نتطلع على
+
+494
+00:39:13,550 --> 00:39:17,290
+هالوزنة،
+
+495
+00:39:17,290 --> 00:39:25,090
+اجيناوزنه وزنه فطلعت ال .. ال beams تبعتي بالشكل
+
+496
+00:39:25,090 --> 00:39:31,050
+اللي جدامي بقول هي مية و أربعين بجه مية و أربعين
+
+497
+00:39:31,050 --> 00:39:36,790
+أربعة أقل من خمسة هي .. هي .. هي أقل من خمسة أربعة
+
+498
+00:39:36,790 --> 00:39:42,500
+إذا مية أربعة و أربعين pointواحد من عشرة اتنين من
+
+499
+00:39:42,500 --> 00:39:46,360
+عشرة تلاتة من عشرة اربع من عشرة خمسة من عشرة لسه
+
+500
+00:39:46,360 --> 00:39:51,180
+هي هان هي في النص اذا one مية و اربع واربعين و نص
+
+501
+00:39:51,180 --> 00:39:58,070
+هذه كلها certaincertain باجي ل بين الخمسة والستة
+
+502
+00:39:58,070 --> 00:40:03,630
+يعني قراها هو نص خمسة يعني فمية أربع واربعين وخمسة
+
+503
+00:40:03,630 --> 00:40:08,790
+وخمسين المية الواحد والاربعة والاربعة point five
+
+504
+00:40:08,790 --> 00:40:12,010
+هذه كلها certain آخر رقم هو اللي مش certain وهذا
+
+505
+00:40:12,010 --> 00:40:16,790
+طبيعي لأنه انا لو لو حبيت اني اسأل سؤال من غير لسه
+
+506
+00:40:16,790 --> 00:40:22,090
+ماعرف جديش الجواب ولا بدي اقرأ بدي اعرفالسجنف كانت
+
+507
+00:40:22,090 --> 00:40:26,450
+figures اللي بتطلع عندي، في أي خانة، في أي .. في
+
+508
+00:40:26,450 --> 00:40:32,230
+أي خانة، هذا بجيس لأقرب إيه؟ هذا بجيس لأقرب واحد
+
+509
+00:40:32,230 --> 00:40:38,280
+من عشرة certainأذا الجواب يكون لأقرب واحد من مية
+
+510
+00:40:38,280 --> 00:40:43,060
+اتفجنا يا شباب افهمنا ايش مفهوم significant
+
+511
+00:40:43,060 --> 00:40:47,620
+figures نيجي نتطلع على هذا الشكل اللي جدامي اخر
+
+512
+00:40:47,620 --> 00:40:54,860
+حاجة في هذا الموضوع تلت مية واربعين وسبعة لكن هذه
+
+513
+00:40:54,860 --> 00:40:55,980
+ملطبقة تماما
+
+514
+00:40:58,710 --> 00:41:08,590
+لازم الجواب يكون 347.00 لأن هذا مدرج لأقرب واحد من
+
+515
+00:41:08,590 --> 00:41:11,890
+عشرة إذا الجواب إيش بده يكون لأقرب واحد من عشرة طب
+
+516
+00:41:11,890 --> 00:41:14,810
+هذا لما نكون عندى اقول والله تلاتمية وسبعة واربعين
+
+517
+00:41:14,810 --> 00:41:17,030
+شايف بالظبط تلاتمية وسبعة واربعين اقول تلاتمية
+
+518
+00:41:17,030 --> 00:41:20,190
+وسبعة واربعين من غير zero zero إيش معناتها؟
+
+519
+00:41:20,190 --> 00:41:24,390
+معناتها الميزان هذا بيجيس لأقرب عشرة gram لأقرب
+
+520
+00:41:24,390 --> 00:41:30,600
+عشرة gramوانا السابعة ها دي تقدير السابعة ها دي
+
+521
+00:41:30,600 --> 00:41:34,400
+ايش مالها تقدير لأنه دائما اخر رقم ايش بيكون تقدير
+
+522
+00:41:34,400 --> 00:41:37,680
+لأ الميزان بيقيصش لأقرب عشر جرام الميزان بيقيص
+
+523
+00:41:37,680 --> 00:41:42,560
+لأقرب واحد من عشر جرام ليش تبخس من نتائجك انت مش
+
+524
+00:41:42,560 --> 00:41:48,340
+تقرا على ميزان كويس نسبيا فليش تقول النتيجة 347؟
+
+525
+00:41:48,340 --> 00:41:52,860
+ليش بنفهم منها ان الميزان المستخدم بيقيص لأقرب عشر
+
+526
+00:41:52,860 --> 00:41:58,140
+جراموالسبعة هذه اللي في الآخر التقديرية لكن لأ
+
+527
+00:41:58,140 --> 00:42:01,300
+مزانك بيجيس لأقرب واحد من عشرة عشان هيك لما انت
+
+528
+00:42:01,300 --> 00:42:12,430
+وزن وزن زي هذه بدك تقول 347.00 طيب يا شباببنجي
+
+529
+00:42:12,430 --> 00:42:18,410
+الآن نتطلع لكيف نجري عمليات حسابية باستخدام ال
+
+530
+00:42:18,410 --> 00:42:21,890
+significant figures فبقول عمليات الحسابية اللي
+
+531
+00:42:21,890 --> 00:42:27,450
+عادة احنا بنجريها هي عمليات بسيطة كتير اما جمع و
+
+532
+00:42:27,450 --> 00:42:32,770
+طرح و هذه لها مفهوم واحد يعني تستخدم نفس المفاهيم
+
+533
+00:42:32,770 --> 00:42:39,230
+تحل بنفس الطريقة او في عندي ضرب و قسمة و هذه لها
+
+534
+00:42:39,230 --> 00:42:44,960
+طريقة أخرىفي عندى اما العمليات الحسابية تبعتي اما
+
+535
+00:42:44,960 --> 00:42:49,340
+جمع و طرح وهذه بتحلق بطريقة معينة نفس الطريقة
+
+536
+00:42:49,340 --> 00:42:58,080
+بينما ضرب و قسمة بتحلق بطريقة اخرى عادة الجمع و
+
+537
+00:42:58,080 --> 00:43:04,380
+الطرح بنطلع فيه على الارقام
+
+538
+00:43:04,380 --> 00:43:09,900
+او النتائج اللى فيها اعلى uncertaintyأعلى
+
+539
+00:43:09,900 --> 00:43:18,530
+uncertainty يعني الجواب دائما بيتوقف علىالنتيجة
+
+540
+00:43:18,530 --> 00:43:22,190
+اللى فيها أعلى uncertainty هي اللى بتحكم الجواب يا
+
+541
+00:43:22,190 --> 00:43:29,590
+سير جديش وكأنه يعني عندك سلسلة لكن في حلقة من
+
+542
+00:43:29,590 --> 00:43:33,970
+الحلقات ضعيفة فقوة السلسلة لا تعتمد على جديش
+
+543
+00:43:33,970 --> 00:43:38,390
+الحلقات الأخرى قوية لما تجيه تشدها تعتمد على ايه؟
+
+544
+00:43:38,390 --> 00:43:43,350
+على الحلقات ضعيفة بالظبطزي ما نجيب اربع، خمس، عشر،
+
+545
+00:43:43,350 --> 00:43:46,810
+اتعشر، تنفار و نقولوا انتوا فريق، بدكم تمسكوا
+
+546
+00:43:46,810 --> 00:43:50,450
+ايدين بعض و تجروا، كويس، لكن واحد فيهم رجله
+
+547
+00:43:50,450 --> 00:43:56,630
+مكسورة، فبدهم يمشوا بإيه؟ بسرعة الإيه؟ البطيق، وهو
+
+548
+00:43:56,630 --> 00:44:02,850
+نفس الكلام، دائما، دائما النتيجة النهائية راح
+
+549
+00:44:02,850 --> 00:44:08,530
+تتوقف على النتيجة اللي تحتوي على أعلى uncertainty
+
+550
+00:44:10,080 --> 00:44:18,140
+فمثلا في عندنا نتيجة بالعدد
+
+551
+00:44:18,140 --> 00:44:23,820
+الصحيح يعني كلها رقم صحيح بينما في نتيجة بالأعشار
+
+552
+00:44:23,820 --> 00:44:29,780
+وفي نتيجة بواحد من مية وفي نتيجة واحد من الف
+
+553
+00:44:29,780 --> 00:44:33,660
+النتيجة النهائية لازم تكون بالعدد الصحيح ليه؟ لأن
+
+554
+00:44:33,660 --> 00:44:39,840
+هذه الوحدة الأقل دقة هذه الوحدة الأقل دقة الأعلى
+
+555
+00:44:39,840 --> 00:44:43,600
+uncertainty احنا إذا الله راضي الحصة الجاية هنحاول
+
+556
+00:44:43,600 --> 00:44:48,140
+أنه نفصل في هذا الكلام وناخد أمثلة حسابية إذا الله
+
+557
+00:44:48,140 --> 00:44:52,620
+راضى أي سؤال يا شباب؟ طيب الله يعطيكم العافية
+
+558
+00:44:52,620 --> 00:44:54,060
+ونشوفكم إن شاء الله الحصة الجاية
+
diff --git a/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/KvHOk6vIgOk.srt b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/KvHOk6vIgOk.srt
new file mode 100644
index 0000000000000000000000000000000000000000..aaff91adf95e0c8b5934b987a1676be8924b780a
--- /dev/null
+++ b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/KvHOk6vIgOk.srt
@@ -0,0 +1,1682 @@
+1
+00:00:22,680 --> 00:00:26,560
+بسم الله الرحمن الرحيم. طيب يا شباب، احنا الحصة
+
+2
+00:00:26,560 --> 00:00:29,380
+الماضية كنا بدأنا نتكلم عن الـ normality
+
+3
+00:00:29,380 --> 00:00:33,420
+calculations أو بالأحرى نستكمل الـ normality
+
+4
+00:00:33,420 --> 00:00:37,800
+calculations اللي شفناها، اخذنا بعض الأمثلة كمقدمة.
+
+5
+00:00:37,800 --> 00:00:43,380
+فأخذنا مثال الحصة الماضية، واليوم بنحاول نكمل في
+
+6
+00:00:43,380 --> 00:00:49,640
+الـ normality calculations. فنطلع على هالمثال اللي
+
+7
+00:00:49,640 --> 00:00:54,920
+كان معناه مثال شبيه لما تكلمنا عن الـ molarity
+
+8
+00:00:54,920 --> 00:00:59,240
+calculations، لكن اليوم بدنا نستخدم الـ normality في
+
+9
+00:00:59,240 --> 00:01:04,260
+الحسابات. فالمثال بيقول: "Use normalities to"
+
+10
+00:01:04,260 --> 00:01:10,240
+calculate how many ml of a 0.1 molar H₂SO₄
+
+11
+00:01:10,240 --> 00:01:17,000
+ستتفاعل مع 20 مل من محلول مولاري صوديوم هيدروكسيد. طبعًا لو
+
+12
+00:01:17,000 --> 00:01:22,720
+كان الغرض من المسألة هو حساب المولارات أو حساب
+
+13
+00:01:22,720 --> 00:01:26,940
+المليلترات من الـ H₂SO₄ كان ممكن استخدم المليمول
+
+14
+00:01:26,940 --> 00:01:30,960
+مباشرة، لأنه أنا بعرف أن الملي مولات من الـ sodium
+
+15
+00:01:30,960 --> 00:01:35,600
+hydroxide بتساوي ضعف الملي مولات من الـ H₂SO₄ لو
+
+16
+00:01:35,600 --> 00:01:37,860
+كتبنا المعادلة، والمعادلة اللي بيكتبها برضه هذا
+
+17
+00:01:37,860 --> 00:01:43,540
+الكلام معلوم، لكن أنا ما بديش أستخدم أو ما بديش أحل
+
+18
+00:01:43,540 --> 00:01:47,400
+باستخدام الـ molarity، أنا بدي أحل باستخدام الـ
+
+19
+00:01:47,400 --> 00:01:51,490
+normality. فيه قدام يعني في الحقيقة خيارات من أبسط
+
+20
+00:01:51,490 --> 00:01:55,670
+الخيارات اللي ممكن أستخدم فيها الـ normalities، إني
+
+21
+00:01:55,670 --> 00:02:01,490
+أطلع الـ normality للـ H₂SO₄ وأطلع الـ normality للـ
+
+22
+00:02:01,490 --> 00:02:06,570
+Sodium Hydroxide، وبعدين أقول: milliequivalent H₂SO₄
+
+23
+00:02:06,570 --> 00:02:12,490
+بيساوي milliequivalent من Sodium Hydroxide. فالـ
+
+24
+00:02:12,490 --> 00:02:19,800
+normality للـ H₂SO₄، والـ N بتساوي 2 ضرب المولارية
+
+25
+00:02:19,800 --> 00:02:24,880
+لأن عندي الـ normality بتساوي N ضرب المولارية. 2
+
+26
+00:02:24,880 --> 00:02:28,000
+في 0.1 بتعطيني 0.2، الـ normality للـ
+
+27
+00:02:28,000 --> 00:02:32,160
+H₂SO₄، والـ normality للصوديوم هيدروكسيد، طبيعي الصوديوم
+
+28
+00:02:32,160 --> 00:02:36,320
+هيدروكسيد ما فيه إلا غير one hydroxide group،
+
+29
+00:02:36,320 --> 00:02:40,860
+وبالتالي هو دائمًا الـ normality له بتساوي المولارية.
+
+30
+00:02:40,860 --> 00:02:44,940
+فالـ N بواحد، معناته الـ normality هتساوي 0.
+
+31
+00:02:44,940 --> 00:02:51,960
+25. الآن مباشرة milliequivalent من الـ H₂SO₄ تساوي
+
+32
+00:02:51,960 --> 00:02:55,120
+milliequivalent من الـ Sodium Hydroxide، ما فيش عنده أي
+
+33
+00:02:55,120 --> 00:02:58,260
+Stoichiometric factors، لأن الملي اكوي فالنت بتساوي
+
+34
+00:02:58,260 --> 00:03:03,360
+الملي اكوي فالنت، فعندي الملي اكوي فالنت بعوض عنها زي
+
+35
+00:03:03,360 --> 00:03:09,800
+ما اتفقنا سابقًا بأحد ثلاث حاجات: يا إما normality بـ
+
+36
+00:03:09,800 --> 00:03:14,650
+volume بالمليلترات، إما milligram على الـ equivalent
+
+37
+00:03:14,650 --> 00:03:18,850
+weight، يا إما N في الملي مول، هي الملي equivalent.
+
+38
+00:03:18,850 --> 00:03:24,690
+ما فيش غير هي، فأنا بطبق عندي normality وعندي volume
+
+39
+00:03:24,690 --> 00:03:28,610
+بالملي، فبقول والله الـ normality للـ H₂SO₄ في الـ
+
+40
+00:03:28,610 --> 00:03:31,510
+volume بالملي مجهولة. الـ normality للـ sodium
+
+41
+00:03:31,510 --> 00:03:36,570
+hydroxide في الـ volume بالملي، 20 مل، بيطلع عندي الـ
+
+42
+00:03:36,570 --> 00:03:40,150
+volume من الـ H₂SO₄ 25 مل.
+
+43
+00:03:43,560 --> 00:03:52,380
+لأ، أنت بدك تطلع كم مل من الـ H₂SO₄؟ لو بدك تطلعها
+
+44
+00:03:52,380 --> 00:03:57,200
+من الـ molarity، بيطلعلك نفس القيمة، يعني بس احنا هنا
+
+45
+00:03:57,200 --> 00:04:02,780
+نستخدم الـ normalities. بالضبط، الـ normalities. نيجي
+
+46
+00:04:02,780 --> 00:04:07,560
+نتطلع على المثال التالي الآن. المثال بيقول: "Find the"
+
+47
+00:04:07,560 --> 00:04:12,720
+normality of sodium carbonate، الـ formula weight 106، in a
+
+48
+00:04:12,720 --> 00:04:18,640
+solution containing 0.212 gram carbonate in 100 ml
+
+49
+00:04:18,640 --> 00:04:24,350
+solution. يعني عندي 0.212 جرام من الـ sodium
+
+50
+00:04:24,350 --> 00:04:28,810
+carbonate مذوبة في 100 مل محلول، عايز أعرف
+
+51
+00:04:28,810 --> 00:04:33,870
+هذا المحلول إيش الـ normality له؟ كويس. فإيش بيقول لي؟
+
+52
+00:04:33,870 --> 00:04:37,990
+بيقول لي: "The carbonate is used as a monobasic base".
+
+53
+00:04:37,990 --> 00:04:41,990
+طبعًا بيقول لي: "If" إذا الـ carbonate كانت monobasic
+
+54
+00:04:41,990 --> 00:04:46,670
+base، بمعنى إنها بتتفاعل بس مع واحد يعني  n=1 HCl،
+
+55
+00:04:46,670 --> 00:04:50,690
+يعني n بتساوي واحد. الحالة الثانية: "The carbonate is"
+
+56
+00:04:50,690 --> 00:04:55,530
+used as a dibasic base"، يعني بتتفاعل مع 2 HCl،
+
+57
+00:04:55,530 --> 00:05:00,010
+بمعنى أن الـ N بتساوي 2. في حالة ما تكون mono
+
+58
+00:05:00,010 --> 00:05:05,310
+basic base، معناته الـ formula weight على 1
+
+59
+00:05:05,310 --> 00:05:09,070
+بتساوي الـ equivalent weight، ليه؟ لأن إن عندنا n
+
+60
+00:05:09,070 --> 00:05:11,850
+بواحد، فالـ equivalent weight بده يساوي الـ formula
+
+61
+00:05:11,850 --> 00:05:16,750
+weight على واحد، أو 106. أنا بنصح بشكل كبير أنه
+
+62
+00:05:16,750 --> 00:05:23,870
+دائمًا نكتب الـ… يعني المعطى، المعطى هو عبارة عن لو
+
+63
+00:05:23,870 --> 00:05:29,250
+اتطلعت فيها كويس، بتقول 0.212 جرام على
+
+64
+00:05:29,250 --> 00:05:38,010
+100 مل. هذه هي نفسها 212 مليجرام على 100
+
+65
+00:05:38,010 --> 00:05:41,470
+مل. يعني حولت جرام وحولتها لمليجرام، ضربت في
+
+66
+00:05:41,470 --> 00:05:45,990
+1000.  المثال لو كتبتها بالشكل هذا واضحة. ليه؟ لأنه أنا
+
+67
+00:05:45,990 --> 00:05:50,690
+بدي normality، بجيب المليجرام هذه بدي أحولها لإيه؟
+
+68
+00:05:50,690 --> 00:05:53,450
+لملي equivalent، لأن الـ normality ملي equivalent
+
+69
+00:05:53,450 --> 00:05:56,610
+على المليلتر. طب كيف ممكن أحول مليجرام لملي
+
+70
+00:05:56,610 --> 00:06:02,760
+equivalent؟ الـ equivalent weight، يعني وكأني بدي
+
+71
+00:06:02,760 --> 00:06:07,340
+أقسم الـ 212 على الـ equivalent weight اللي هي 106
+
+72
+00:06:07,340 --> 00:06:12,620
+على 100، بيعطينا الـ normality. معي يا شباب؟ يعني
+
+73
+00:06:12,620 --> 00:06:18,590
+أركز على المطلوب، ودائمًا حاول توصل لملي إيكوي فالنت على
+
+74
+00:06:18,590 --> 00:06:22,370
+المليلتر إذا كان بدك normality. احنا عندنا الملي
+
+75
+00:06:22,370 --> 00:06:27,370
+إيكوي فالنت، لو حبينا إن نحسبها مثلًا، فالمليجرام على الـ
+
+76
+00:06:27,370 --> 00:06:32,730
+equivalent weight، أنا حسبت 212 مليجرام على الـ 100
+
+77
+00:06:32,730 --> 00:06:37,630
+مل على 106، بيطلع 0.02 ملي إيكوي فالنت على المل، يعني 0.02
+
+78
+00:06:37,630 --> 00:06:43,050
+normal. بنفس الطريقة لما بدي أتكلم عن حساب الـ
+
+79
+00:06:43,050 --> 00:06:47,650
+normality في حالة ما إني أستخدم الـ carbonate as a
+
+80
+00:06:47,650 --> 00:06:54,010
+dibasic base، بيكون عندنا الـ N بتساوي 2، معناته الـ
+
+81
+00:06:54,010 --> 00:06:57,150
+equivalent weight بده يساوي الـ formula weight على 2،
+
+82
+00:06:57,150 --> 00:07:03,020
+بده يساوي 53. نفس المنطق، أنا عندي 212 مليجرام على الـ 100
+
+83
+00:07:03,020 --> 00:07:06,340
+مل، بدي أقسم على الـ equivalent weight عشان
+
+84
+00:07:06,340 --> 00:07:09,620
+أحولها لملي equivalent، بتعطيني normality على طول.
+
+85
+00:07:09,620 --> 00:07:15,020
+طيب إيش هو الـ equivalent weight؟ هو 53. إذا بدي
+
+86
+00:07:15,020 --> 00:07:20,720
+أقسم 212 على 53 على 100، هذا بيعطيني الـ normality،
+
+87
+00:07:20,720 --> 00:07:27,180
+بتطلع الـ normality 0.04. فسهل أن أوصل أيضًا للحل.
+
+88
+00:07:29,090 --> 00:07:35,900
+بيجينا مسألتين، خليني أقول متعاكستين تقريبًا. في مثلًا
+
+89
+00:07:35,900 --> 00:07:41,600
+ما عايز أحضر محلول له normality معينة، كيف بدي
+
+90
+00:07:41,600 --> 00:07:46,040
+أحضر محلول له normality معينة؟ يمكن احنا لما اخذنا
+
+91
+00:07:46,040 --> 00:07:51,380
+الـ normality قبل عدة محاضرات، مرينا بشيء شبيه بهذا
+
+92
+00:07:51,380 --> 00:07:56,940
+الكلام، لكن يعتبر هذا المثال مكرر تقريبًا، لكن بناخذه
+
+93
+00:07:56,940 --> 00:08:01,460
+لأنه موجود في الكتاب بالترتيب. إنك لما تتراجع في
+
+94
+00:08:01,460 --> 00:08:05,980
+الكتاب تحس حالك إنك مسجون مع المادة المكتوبة.
+
+95
+00:08:05,980 --> 00:08:10,480
+فالمثال بيقول التالي: بيقول: "How many milligrams of"
+
+96
+00:08:10,480 --> 00:08:15,480
+I₂ should you weigh to prepare 250 ml of 0.1
+
+97
+00:08:15,480 --> 00:08:20,500
+normal solution in the reaction: I₂ + 2 إلكترون
+
+98
+00:08:20,500 --> 00:08:25,940
+بيعطينا 2 I⁻. عكس هذا الكلام ممكن يعطيني وزنة
+
+99
+00:08:26,400 --> 00:08:30,120
+مادة في حجم معين ويقول لي والله جديش الـ
+
+100
+00:08:30,120 --> 00:08:33,520
+normality؟ زي ما شفنا في حالة الكربونيت، هنشوف مثال
+
+101
+00:08:33,520 --> 00:08:38,800
+مثال من هذا النوع بعد شوية، لكن الآن نرجع لمثالنا
+
+102
+00:08:38,800 --> 00:08:42,480
+بيقول: "How many milligrams of I₂ should you weigh"
+
+103
+00:08:42,480 --> 00:08:47,000
+to prepare 250 ml of 0.1 normal solution؟ طبعًا احنا
+
+104
+00:08:47,000 --> 00:08:51,220
+اتفقنا سابقًا على أن مفتاح الحل: الملي إيكوي فالنت، يعني
+
+105
+00:08:51,220 --> 00:08:55,280
+لأنه مش ملي مول، لأنه Normalities، فالملي إيكوي فالنت
+
+106
+00:08:55,280 --> 00:08:58,920
+بيساوي الـ normality في الـ volume بالملي، فبيعطيني
+
+107
+00:08:58,920 --> 00:09:04,880
+25 ملي إيكوي فالنت. هي عدد الملي إيكوي فالنت 25، أنا ما بدي
+
+108
+00:09:04,880 --> 00:09:08,620
+ملي إيكوي فالنت، أنا بدي مليجرام. المليجرام بيساوي
+
+109
+00:09:08,620 --> 00:09:11,360
+الملي إيكوي فالنت في الـ equivalent weight. الـ
+
+110
+00:09:11,360 --> 00:09:15,300
+equivalent weight إيش بيساوي؟ formula weight على
+
+111
+00:09:15,300 --> 00:09:20,840
+2، لأن عندي 2 electrons للمول. هذا 1 مول I₂،
+
+112
+00:09:22,750 --> 00:09:28,710
+2 إلكترون. إذًا في عندي N بتساوي 2. مع هذا الكلام، الـ
+
+113
+00:09:28,710 --> 00:09:32,550
+milligram I₂ بتساوي الملي إيكوي فالنت اللي هو
+
+114
+00:09:32,550 --> 00:09:36,650
+25 في الـ formula weight 254 على 2،
+
+115
+00:09:36,650 --> 00:09:40,410
+فبيطلع عندي 3175، تقريبًا 3175
+
+116
+00:09:40,410 --> 00:09:46,470
+milligrams. آخر مثال في الـ normalities زي ما… زي
+
+117
+00:09:46,470 --> 00:09:52,260
+ما ذكرت، يعني هو تقريبًا نفس المثال السابق. "Find the"
+
+118
+00:09:52,260 --> 00:09:59,840
+normality of the solution containing 0.25 g H₂C₂O₄
+
+119
+00:09:59,840 --> 00:10:05,600
+Oxalic Acid، الـ formula weight 90. طبعًا الـ Oxalic Acid
+
+120
+00:10:05,600 --> 00:10:11,400
+يا شباب، مر معنا أنه هو Acid، حمض، يعني ما في
+
+121
+00:10:11,400 --> 00:10:17,280
+مشكلة يستخدم كـ حمض، لكن مر معنا كـ reducing agent،
+
+122
+00:10:17,760 --> 00:10:21,920
+أوكزاليك أسيد، مر معنا أيضًا كـ reducing agent، فهو
+
+123
+00:10:21,920 --> 00:10:29,360
+يستخدم كـ reducing agent وأيضًا كـ حمض. في المعادلة
+
+124
+00:10:29,360 --> 00:10:32,680
+اللي عندي هو بيستخدم كـ حمض، وقال لي أنه أوكزاليك
+
+125
+00:10:32,680 --> 00:10:38,720
+أسيد "reacts as a diacidic substance"، بمعنى أن الـ N
+
+126
+00:10:38,720 --> 00:10:44,520
+بتساوي 2. فبقول ببساطة خالص، يعني لو حاولت إن
+
+127
+00:10:44,520 --> 00:10:50,940
+أكتب المعادلة، بقول والله 0.25، أنت عندك
+
+128
+00:10:50,940 --> 00:10:55,960
+مليجرام على المليلتر، بنفع ولا لأ؟ 0.2
+
+129
+00:10:55,960 --> 00:10:57,940
+5 مليجرام على المليلتر، يعني 0.25
+
+130
+00:10:57,940 --> 00:11:01,980
+مليجرام على إيه؟ على المليلتر. طب أنا بدي أحول،
+
+131
+00:11:01,980 --> 00:11:06,130
+بدي… بدي normality، إذا أنا بدي إيه تكون؟ ملي
+
+132
+00:11:06,130 --> 00:11:08,750
+إيكوي فالنت، أنا بدي ملي إيكوي فالنت على المليلتر، لأن
+
+133
+00:11:08,750 --> 00:11:13,550
+هذه الـ normality. إيش بدي أقسم على؟ الـ equivalent
+
+134
+00:11:13,550 --> 00:11:15,930
+weight. بجيب الـ equivalent weight، الـ equivalent
+
+135
+00:11:15,930 --> 00:11:19,850
+weight هو عبارة عن formula weight على 2، 90 على
+
+136
+00:11:19,850 --> 00:11:23,330
+2، 45. يعني بدي أقسم 0.25 على
+
+137
+00:11:23,330 --> 00:11:29,530
+45، بيعطيني الـ normality. الجواب
+
+138
+00:11:29,530 --> 00:11:34,690
+بيطلع عندنا 0.0056 normal. كويس يا
+
+139
+00:11:34,690 --> 00:11:41,230
+شباب، هذه طبيعة الأسئلة اللي ممكن تواجهنا في حسابات
+
+140
+00:11:41,230 --> 00:11:47,150
+الـ normalities. بتمنى كتير أنه تكون أسئلة جيدة و
+
+141
+00:11:47,150 --> 00:11:56,770
+حلها مباشر وسهل كتير. الآن ننتقل لآخر جزئية في هذا
+
+142
+00:11:56,770 --> 00:11:59,670
+الـ chapter، وهي مفهوم الـ titer.
+
+143
+00:12:03,060 --> 00:12:07,620
+تعالوا نشوف بالظبط إيش المقصود بمفهوم التيتر. طبعًا
+
+144
+00:12:07,620 --> 00:12:12,300
+تيتر المعايير، أو يعني مصطلح اسمه التيتر المعايير،
+
+145
+00:12:12,300 --> 00:12:19,080
+بنقوله. فإيش هو بالظبط؟ لو إجينا اتذكرنا معكم في
+
+146
+00:12:19,080 --> 00:12:23,520
+عندي KMnO₄
+
+147
+00:12:23,520 --> 00:12:32,460
+مثلًا، بتتفاعل مع Fe²⁺. التفاعل اللي ممكن شفناه
+
+148
+00:12:32,460 --> 00:12:39,740
+سابقا: MnO₄⁻ + 5 Fe²⁺ +
+
+149
+00:12:39,740 --> 00:12:45,620
+8 H⁺ بيعطيني نواتج. كويس هيك يا شباب؟
+
+150
+00:12:45,620 --> 00:12:50,300
+فبقول: إيش أنا بقول؟ إنه والله لما بدي أحل مسألة
+
+151
+00:12:50,300 --> 00:12:58,380
+زي هذه، بقول: 5 ملي مول من الـ iron، ملي مول iron بيساوي
+
+152
+00:12:58,380 --> 00:13:05,850
+1 ملي مول Permanganate، صحيح؟  هنا الـ iron 5 و
+
+153
+00:13:05,850 --> 00:13:09,110
+الـ permanganate 1. إذًا المليمول iron خمس أمثال
+
+154
+00:13:09,110 --> 00:13:14,690
+الـ permanganate، صحيح؟ طيب، لكن عادة لما أكون بشتغل
+
+155
+00:13:14,690 --> 00:13:21,210
+في مختبر بيختص مثلًا بتحليل خام، فعايز… بدوش يحسب
+
+156
+00:13:21,210 --> 00:13:26,090
+iron، بده يحسب Fe²⁺ و Fe³⁺.
+
+157
+00:13:28,970 --> 00:13:32,570
+يعني بدوش يعوض عن الـ iron بـ iron، بده Fe²⁺ أو
+
+158
+00:13:32,570 --> 00:13:37,110
+Fe³⁺. فبقول: أنا عادة بقول هذا بيعطيني 2 iron، إذا
+
+159
+00:13:37,110 --> 00:13:43,930
+الملي مول iron إيش بيساوي؟ بده
+
+160
+00:13:43,930 --> 00:13:51,930
+يساوي 2 ملي مول Fe²⁺ أو Fe³⁺، هي 2
+
+161
+00:13:51,930 --> 00:13:56,410
+ملي مول Fe²⁺ أو Fe³⁺ محل ملي مول iron.
+
+162
+00:13:57,130 --> 00:14:02,110
+فبتصير 2 ملي مول ايرون اتنين أو تلاتة بدها
+
+163
+00:14:02,110 --> 00:14:09,610
+تساوي 5 ملي مول KMnO₄. الآن بقدر أحسب
+
+164
+00:14:09,610 --> 00:14:15,610
+أنا كم مليجرام Fe²⁺ أو Fe³⁺، صحيح؟ اه، و
+
+165
+00:14:15,610 --> 00:14:18,550
+هذا اللي أنا بدي أحسبه، كم مليجرام Fe²⁺ أو
+
+166
+00:14:18,550 --> 00:14:23,610
+Fe³⁺؟ الفكرة إيش الآن؟ الفكرة إنه لو كان في عندي
+
+167
+00:14:23,610 --> 00:14:24,710
+محلول
+
+168
+00:14:31,870 --> 00:14:37,510
+KMnO₄ وليكن 0.1 مولاري، وليكن 
+
+223
+00:19:09,250 --> 00:19:12,490
+عدد ميلي جرامات الـ Iron 2O3 الموجودة في العينة
+
+224
+00:19:12,490 --> 00:19:16,970
+إذا كان عندي حجم معين من الـ 5.442 جرام على اللتر
+
+225
+00:19:16,970 --> 00:19:21,930
+Potassium Dichromate فبقول الحل كتير كتير بسيط أنا
+
+226
+00:19:21,930 --> 00:19:25,430
+بدي أجيب التايتر يعني بدي أجيب كم ميلي جرام Iron
+
+227
+00:19:25,430 --> 00:19:31,800
+2O3 لكل ملي لتر من الـ Potassium dichromate اللي عندي يعني كل
+
+228
+00:19:31,800 --> 00:19:35,480
+ملي لتر من الـ Potassium dichromate مع كم milligram من الـ
+
+229
+00:19:35,480 --> 00:19:38,580
+iron 2O3 بيتفعل فبنقول بنفس الطريقة اللي حكينا
+
+230
+00:19:38,580 --> 00:19:43,180
+فيها سابقا بنطلع في البداية الـ millimol Iron ستة
+
+231
+00:19:43,180 --> 00:19:45,700
+millimol Potassium dichromate من وين جيبناها؟ من المعادلة
+
+232
+00:19:45,700 --> 00:19:51,360
+المعادلة هي الـ Iron ستة أمثال Potassium dichromate يبقى الـ
+
+233
+00:19:51,360 --> 00:20:00,210
+millimol Iron ستة millimol Potassium dichromate. أنا 5.4 ميلي
+
+234
+00:20:00,210 --> 00:20:03,430
+جرام.  فورا لازم يكون ميلي جرام؟ الجرام قليل  ترهيب
+
+235
+00:20:03,430 --> 00:20:09,450
+فبتحط 5.4 ميلي جرام.  فرميل قعدت بكتوبها زي هيك و
+
+236
+00:20:09,450 --> 00:20:16,610
+كتوبها زي هيك ما فيش مشكلة سواء كتبتها 5.442 جرام
+
+237
+00:20:16,610 --> 00:20:21,350
+على اللتر أو كتبتها 5.442 ميلي جرام على الميلي لتر
+
+238
+00:20:21,350 --> 00:20:26,010
+هي نفسها لأنك لما تحط فوق ميلي وتحط تحت ميلي هي هي
+
+239
+00:20:26,010 --> 00:20:32,000
+نفس الكلام. طيب انتبهوا معايا يا شباب. بقول أنا بدي
+
+240
+00:20:32,000 --> 00:20:35,240
+Iron. أنا بدي Iron 2O3. عشان إيه؟ بيقول كل اتنين Iron
+
+241
+00:20:35,240 --> 00:20:38,620
+بيعطوني Iron 2O3. مش هيك؟ يبقى الـ millimol Iron
+
+242
+00:20:38,620 --> 00:20:42,980
+بيساوي عفوا، اللي بيساوي هذه قبلها يساوي اتنين
+
+243
+00:20:42,980 --> 00:20:48,840
+millimol Iron 2O3. كويس. إذا اتنين millimol Iron
+
+244
+00:20:48,840 --> 00:20:53,080
+2O3 بنعوض محل الـ Iron اللي موجود فيصير اتنين ميلي
+
+245
+00:20:53,080 --> 00:20:56,160
+مول Iron 2O3 بيساوي ستة ميلي مول Potassium dichromate
+
+246
+00:20:56,160 --> 00:20:58,760
+هذه معادلة stoichiometric equation يعني معادلة
+
+247
+00:20:58,760 --> 00:21:07,200
+بنعملها بسهولة. سهلة المفروض وين ستة Iron؟
+
+248
+00:21:07,200 --> 00:21:18,220
+هذه؟ هذه اتنين. كيف هي ستة؟ ستة؟ هذه؟ هذه المعادلة
+
+249
+00:21:23,580 --> 00:21:27,860
+هذه ستة Iron  مع Potassium dichromate. عدد ملي مولات الـ Iron
+
+250
+00:21:27,860 --> 00:21:31,220
+ستة أمثال Potassium dichromate. الملي مولات الـ Iron ستة أمثال
+
+251
+00:21:31,220 --> 00:21:31,920
+Potassium dichromate
+
+252
+00:21:36,160 --> 00:21:41,380
+بنقول الميلي مول Iron بيساوي 2 ميلي مول Iron 2
+
+253
+00:21:41,380 --> 00:21:44,980
+O3 بنعوض عنها 2 ميلي مول Iron 2O3 محل الميلي
+
+254
+00:21:44,980 --> 00:21:48,340
+مول Iron بيساوي 6 ميلي مول Potassium dichromate. الآن السؤال
+
+255
+00:21:48,340 --> 00:21:52,320
+إيش بدنا نعوض عن الميلي مول Iron 2O3؟ ميلي جرام
+
+256
+00:21:52,320 --> 00:21:55,340
+على الـ formula weight. مفهوم؟ ميلي جرام على الـ formula weight.
+
+257
+00:21:55,340 --> 00:21:59,820
+طيب هان الميلي مول = molarity × volume. الـ molarity
+
+258
+00:21:59,820 --> 00:22:05,330
+هي عبارة عن 5.442 جرام على اللتر. بديها مول على اللتر
+
+259
+00:22:05,330 --> 00:22:09,890
+إيش بسوي؟ بجسم على الـ formula weight تتحول لـ مول على اللتر
+
+260
+00:22:09,890 --> 00:22:14,500
+صارت molarity. ضربت في إيه؟ كتبت هلاك بلون مختلف، في
+
+261
+00:22:14,500 --> 00:22:18,180
+واحد، في واحد، إيش واحد؟ الـ volume مل، ليه؟ لأن
+
+262
+00:22:18,180 --> 00:22:21,420
+أنا بدي أطلع الـ milligram من الـ Iron 2O3 اللي
+
+263
+00:22:21,420 --> 00:22:24,760
+بتتفعل مع كم مل؟ مع واحد مل، عشان إيه؟ هذا هو
+
+264
+00:22:24,760 --> 00:22:28,740
+تعريف التايتر، هذا هو تعريف التايتر، إذا الـ volume
+
+265
+00:22:28,740 --> 00:22:32,670
+اللي عندي اللي بتتعود عنه في المعادلة إيه؟ شو؟ واحد
+
+266
+00:22:32,670 --> 00:22:36,890
+ليه واحد؟ لأنه أنا بدي أتايتر، أتايتر عدد ميلي
+
+267
+00:22:36,890 --> 00:22:40,550
+جرامات الـ Iron 2O3 اللي بتتفاعل معاه أو correspond
+
+268
+00:22:40,550 --> 00:22:46,010
+to one ml من الـ Potassium dichromate. يبقى بدك تتذكر أن الـ
+
+269
+00:22:46,010 --> 00:22:49,030
+volume اللي عندك واحد. ما أحد يسألني عن الـ volume في
+
+270
+00:22:49,030 --> 00:22:52,770
+الامتحان. شو؟ الـ volume عندك واحد. بتبدأ بتجيب التايتر
+
+271
+00:22:52,770 --> 00:22:56,010
+الـ volume واحد لأنك بدك تجيب عدد الميلي جرامات
+
+272
+00:22:56,010 --> 00:23:00,970
+اللي بتتفاعل مع كم؟ مع واحد مل من التايتر. فالميلي
+
+273
+00:23:00,970 --> 00:23:06,110
+جرام Iron 2O3 بتطلع 8.86 ميلي جرام. بمعنى إنه لو
+
+274
+00:23:06,110 --> 00:23:10,950
+معايرة ما أخذت عشرة مل من الـ Potassium dichromate هذا معناته
+
+275
+00:23:10,950 --> 00:23:16,750
+كم ميلي جرام Iron 2O3 عندي؟ 88.6 من عشرة. هذا هو
+
+276
+00:23:16,750 --> 00:23:20,090
+مفهوم الـ Titer. كتير بنحب نجيبه في الامتحان مش
+
+277
+00:23:20,090 --> 00:23:25,070
+لأنه يعني موضوع كبير لكن في الحقيقة كمفهوم بيسهل
+
+278
+00:23:25,070 --> 00:23:28,510
+علينا لدرجة كبيرة الحسابات اللي بنعملها وبيوفر
+
+279
+00:23:28,510 --> 00:23:33,150
+وقت. عشان هيك بهمنا نسألك عنه ونتأكد إنك بتعرف إيش
+
+280
+00:23:33,150 --> 00:23:38,790
+مفهوم الـ Titer. الآن يا شباب بننتقل لـ chapter جديد
+
+281
+00:23:38,790 --> 00:23:43,890
+general concepts of chemical equilibrium. الفهم
+
+282
+00:23:43,890 --> 00:23:52,550
+العام لـ الإتزان الكيميائي. إحنا قلنا إنه في عندنا
+
+283
+00:23:52,550 --> 00:23:59,190
+أنواع أسئلة تتمثل فيه بشكل أساسي نوعين من أنواع
+
+284
+00:23:59,190 --> 00:24:07,830
+الحسابات. حسابات stoichiometric كمية، وحسابات اتزان
+
+285
+00:24:07,830 --> 00:24:13,530
+فالحسابات الكمية اتعرفنا كيف نجريها في الـ chapter
+
+286
+00:24:13,530 --> 00:24:17,490
+الماضي. الآن بدنا نطلع على الحسابات اللي تستخدم
+
+287
+00:24:17,490 --> 00:24:23,330
+الاتزان. وعموما لما نتكلم عن الاتزان بنتكلم عن
+
+288
+00:24:23,330 --> 00:24:30,330
+تفاعل كيميائي لا يتم بنسبة 100%. تفاعل كيميائي لا
+
+289
+00:24:30,330 --> 00:24:35,330
+يتم بنسبة 100%. تفاعلات نوعين. وإحنا دائما يمكن بنحط
+
+290
+00:24:35,330 --> 00:24:40,870
+... بنجسم الأشياء لقسمين عشان يكون حفظها أسهل و
+
+291
+00:24:40,870 --> 00:24:43,990
+استيعابها كمان أسهل. شوفنا مثلا الـ errors
+
+292
+00:24:43,990 --> 00:24:50,490
+determined و indeterminate. شوفنا ... حتى كمان طلعت
+
+293
+00:24:50,490 --> 00:24:53,390
+معنا يعني... الميلي مول، ميلي جرام على الـ formula
+
+294
+00:24:53,390 --> 00:24:56,710
+weight أو molar volume. حاجتين. الـ equilibrium
+
+295
+00:24:56,710 --> 00:25:04,630
+بنقول والله تفاعل تم وتفاعل غير تم. تفاعل تم هذا
+
+296
+00:25:04,630 --> 00:25:07,830
+ما لوش دعوة في الـ equilibrium. تفاعل بيتم بنسبة 100%
+
+297
+00:25:07,830 --> 00:25:12,490
+بنقول تفاعل تم. تفاعل غير تم. هذا هو تفاعل الاتزان
+
+298
+00:25:12,490 --> 00:25:18,550
+يعني تفاعل لا يتم بنسبة 100%. زي مثلا a مول من a
+
+299
+00:25:18,550 --> 00:25:24,050
+بيفعل مع b مول من b بيعطينا c مول من c و d مول من d
+
+300
+00:25:24,050 --> 00:25:27,270
+بقول بقدر أكتب الـ equilibrium constant وأطلع عليه
+
+301
+00:25:27,270 --> 00:25:33,020
+الـ concentration للنواتج كل واحد مرفوع له أس
+
+302
+00:25:33,020 --> 00:25:36,280
+بإساوي عدد المولات تبعته على الـ concentrations
+
+303
+00:25:36,280 --> 00:25:41,780
+للمتفاعلات. كل متفاعل مرفوع له أس بإساوي عدد
+
+304
+00:25:41,780 --> 00:25:47,200
+مولاته. فهذا الـ equilibrium constant لأنه بيستخدم
+
+305
+00:25:47,200 --> 00:25:52,540
+الـ concentrations فهو يسمى concentration
+
+306
+00:25:52,540 --> 00:25:56,260
+equilibrium constant لأنه بيستخدم الـ concentrations
+
+307
+00:25:56,260 --> 00:26:01,360
+يسمى إيه؟ concentration equilibrium constant. في
+
+308
+00:26:01,360 --> 00:26:06,500
+الحقيقة التفاعل لما a بتفاعل مع b بيعطينا c و d هنا
+
+309
+00:26:06,500 --> 00:26:11,080
+التفاعل بيمشي. أول حاجة يمشي سريع لأن التركيزات
+
+310
+00:26:11,080 --> 00:26:16,260
+بتكون كبيرة. بعدين لغاية ما يوصل لنقطة معينة بنلاحظ
+
+311
+00:26:16,260 --> 00:26:21,530
+إنه وكأنه متوقف، وكأنه خلص لكن يا شباب هو لأ، ما بيكونش
+
+312
+00:26:21,530 --> 00:26:24,290
+بخلص. الـ equilibrium اللي عندنا هو dynamic
+
+313
+00:26:24,290 --> 00:26:29,670
+equilibrium. يعني اتزان ديناميكي. بمعنى إنه سرعة
+
+314
+00:26:29,670 --> 00:26:34,010
+التفاعل في الاتجاه الأمامي تساوي سرعة التفاعل في
+
+315
+00:26:34,010 --> 00:26:38,570
+الاتجاه الخلفي أو المعاكس، العكسي. يعني التفاعل بيتم
+
+316
+00:26:38,570 --> 00:26:42,930
+بين a و b دائما بيعطينا c و d لكن في نفس الوقت c و
+
+317
+00:26:42,930 --> 00:26:46,800
+d بتفعل مع بعض يعطينا a و b بنفس السرعة. فالسرعتين
+
+318
+00:26:46,800 --> 00:26:51,440
+متساويتين. بنحس وكأنه واجف لكن هو في الحقيقة لأ
+
+319
+00:26:51,440 --> 00:26:58,380
+عندي دائما الـ equilibrium dynamic equilibrium. طيب
+
+320
+00:26:58,380 --> 00:27:04,000
+فعنا إيش اللي بيحصل عادة لما a يتفاعل مع b؟
+
+321
+00:27:04,000 --> 00:27:08,800
+بقول بيحصل عندنا أحد الأشكال اللي قدامي هذه. ممكن
+
+322
+00:27:08,800 --> 00:27:14,370
+نطلع على اللي في النص. بداية هذا المتفاعلات ومع الوجود
+
+323
+00:27:14,370 --> 00:27:18,210
+عامل. إيش بيصير لها؟ بتقل، بتقل، بتقل لغاية ما تقريبا
+
+324
+00:27:18,210 --> 00:27:22,430
+توصل شيء قريب من الصفر. مش صفر. لو وصلت صفر بصير
+
+325
+00:27:22,430 --> 00:27:26,430
+تفاعل تام انتهى، بصير تفاعل تام. لكن لأ هي بتوصلش
+
+326
+00:27:26,430 --> 00:27:31,290
+صفر. قريبة جدا من الصفر. مثلا يعني... يعني جزء صغير من
+
+327
+00:27:31,290 --> 00:27:37,030
+المتفاعلات. جزء يسير جدا جدا لا يكاد يذكر، قليل خالص
+
+328
+00:27:38,140 --> 00:27:41,880
+وفي نفس الوقت النواتج بتزيد، بتزيد لغاية ما تجرب
+
+329
+00:27:41,880 --> 00:27:47,680
+على الـ 100%. تجرب، مش توصل، توصلش لأنه باقي a و b
+
+330
+00:27:47,680 --> 00:27:52,900
+فلازم يكون c و d يعني ما يوصلش 100% من 100% لما
+
+331
+00:27:52,900 --> 00:27:57,860
+المتفاعلات تقل توصل شيء قريب من الصفر والنواتج
+
+332
+00:27:57,860 --> 00:28:02,540
+تزيد. إيش اللي بيحصل؟ لو إجينا بتطلعنا على النواتج
+
+333
+00:28:02,540 --> 00:28:06,760
+فوق في الـ numerator والمتفاعلات وين؟ في المقام. النواتج
+
+334
+00:28:06,760 --> 00:28:10,720
+كبيرة خالص والمتفاعلات قليلة جدا. كيف الـ
+
+335
+00:28:10,720 --> 00:28:16,380
+equilibrium constant؟ عالي كتير. large، large. مش أكبر
+
+336
+00:28:16,380 --> 00:28:21,600
+من واحد. very large. كويس. very large. طيب هذا نوع من
+
+337
+00:28:21,600 --> 00:28:26,100
+أنواع التفاعلات، نوع من أنواع تفاعلات الإتزان إنه
+
+338
+00:28:26,100 --> 00:28:28,960
+الـ equilibrium constant بيكون كبير. ليش بيكون كبير؟
+
+339
+00:28:28,960 --> 00:28:35,540
+لأن a و b بتفعلوا مع بعض وكميتهم بتقل إلى درجة
+
+340
+00:28:35,540 --> 00:28:41,250
+تقترب من الصفر. كويس. بينما النواتج بتزيد درجة تقريب
+
+341
+00:28:41,250 --> 00:28:44,770
+من 100%. هذا نوع. النوع الآخر هو النوع اللي على
+
+342
+00:28:44,770 --> 00:28:52,770
+اليسار،  عيمينك. يعني بيكون أو بيدوب اللي بتفاعله
+
+343
+00:28:52,770 --> 00:28:56,150
+تفاعله قليل ... يعني المتفاعلات قلت بنسبة ضئيلة
+
+344
+00:28:56,150 --> 00:29:00,290
+للغاية. يعني تقريبا كل المتفاعلات باقية زي ما هي
+
+345
+00:29:00,290 --> 00:29:03,610
+إلا جزء يسير. تفاعل الجزء الياسير اللي اتفاعل هذا
+
+346
+00:29:03,610 --> 00:29:09,680
+كون نواتج. النواتج قريبة من الصفر. المتفاعلات قريبة
+
+347
+00:29:09,680 --> 00:29:13,660
+من 100%. لما نيجي نقول والله المتفاعلات قريبة من
+
+348
+00:29:13,660 --> 00:29:16,760
+100% والنواتج قريبة من الصفر. كيف الـ equilibrium
+
+349
+00:29:16,760 --> 00:29:21,480
+constant؟ صغير للغاية. يعني هذا النوع الثاني. أما أن
+
+350
+00:29:21,480 --> 00:29:25,140
+الـ equilibrium constant يكون large أو أما إنه يكون
+
+351
+00:29:25,140 --> 00:29:32,660
+small. في يعني نوع ثالث من التفاعلات. والله a و b
+
+352
+00:29:32,660 --> 00:29:34,160
+بيقلوا
+
+353
+00:29:35,970 --> 00:29:44,310
+بدرجة ملحوظة، و c و d بيزيدوا بدرجة ملحوظة أيضا
+
+354
+00:29:44,310 --> 00:29:48,590
+يعني حوالين بعض. يعني a و b بيصير تقريبا تركيزاتهم
+
+355
+00:29:48,590 --> 00:29:54,260
+زي c و d تقريبا. يعني الاثنين موجودين بدرجة إيه؟
+
+356
+00:29:54,260 --> 00:29:57,560
+ملحوظة. عشان هيك الـ equilibrium constant في هذه
+
+357
+00:29:57,560 --> 00:30:02,860
+الحالة إيش بيكون؟ متوسط. متوسط. إحنا يا شباب معنى
+
+358
+00:30:02,860 --> 00:30:05,440
+الكلام، في عندنا ثلاث أنواع من أنواع الـ equilibrium
+
+359
+00:30:05,440 --> 00:30:10,010
+constant. حسب الـ equilibrium constant اللي عندي بدي
+
+360
+00:30:10,010 --> 00:30:14,990
+أستخدم طريقة الحل. يبقى طريقة الحل هتعتمد على إيه؟
+
+361
+00:30:14,990 --> 00:30:19,590
+على قيمة الـ equilibrium constant. هل هو كبير، صغير
+
+362
+00:30:19,590 --> 00:30:27,130
+ولا متوسط؟ إحنا علشان نسهل الأمور علينا هنقول لأ
+
+363
+00:30:27,130 --> 00:30:30,350
+بدناش ناخد ثلاث حالات، وبدناش ناخد ثلاث حالات في
+
+364
+00:30:30,350 --> 00:30:37,130
+الحل. بدنا ناخد حاجتين فقط زي ما اتعودنا. تفاعل تم أو
+
+365
+00:30:37,130 --> 00:30:40,330
+غير تم. determinant error و indeterminant error.
+
+366
+00:30:40,330 --> 00:30:42,870
+حاجتين. milligram على الـ formula weight أو molar
+
+367
+00:30:42,870 --> 00:30:47,150
+volume. مثلا. فبناخد برضه جسم بس من جسم هدول اثنين
+
+368
+00:30:47,150 --> 00:30:54,070
+فإيش بقول؟ وأسهل ويمكن بدي أقول بدي آخد الحالة أي
+
+369
+00:30:54,070 --> 00:30:57,970
+حالة قدامي بدي أحطها ضمن حالتين. هل الـ equilibrium
+
+370
+00:30:57,970 --> 00:31:05,970
+constant كبير أو أن الـ equilibrium constant إيه؟ مش
+
+371
+00:31:05,970 --> 00:31:13,090
+كبير. يا كبير يا إما مش كبير. يا كبير يا إما،
+
+372
+00:31:13,090 --> 00:31:16,270
+ما ليش دي علاقة هذا الكلام. يا كبير يعني أكبر من
+
+373
+00:31:16,270 --> 00:31:20,130
+عشرة، أقصى اثنين مثلا، أكبر من مئة، يا إما مش كبير،
+
+374
+00:31:20,130 --> 00:31:24,390
+مش كبير يعني أقل من عشرة، أقصى اثنين. معايا أنتو؟ هيك
+
+375
+00:31:24,390 --> 00:31:27,290
+أسهل. ليه؟ فجأة أنا بدي أحل على أساس الـ equilibrium
+
+376
+00:31:27,290 --> 00:31:32,150
+tool. طالع ليه؟ هل هو كبير، إله طريقة حل، مش كبير،
+
+377
+00:31:32,150 --> 00:31:36,350
+إله طريقة أخرى في الحل. فجأة هيك جمعت الصغير و
+
+378
+00:31:36,350 --> 00:31:41,130
+المتوسط مع بعض. بس عندي حالتين يا كبير يا مش
+
+379
+00:31:41,130 --> 00:31:44,250
+كبير. كبير إله طريقة في الحل، مش كبير إيش إله
+
+380
+00:31:44,250 --> 00:31:50,320
+طريقة أخرى في الحل. ماشي يا شباب. إذا حل أي مسألة
+
+381
+00:31:50,320 --> 00:31:53,440
+equilibrium. بمجرد ما أشوف المسألة بدي أطلع الـ
+
+382
+00:31:53,440 --> 00:31:56,960
+equilibrium constant وأقرر هل الـ equilibrium
+
+383
+00:31:56,960 --> 00:32:02,500
+constant كبير ولا مش كبير؟ إيش يعني كبير؟  قال يعني
+
+384
+00:32:02,500 --> 00:32:07,680
+أكبر من عشرة، أقصى اثنين مثلا. وأنا بأرجو أنك في آخر يعني
+
+385
+00:32:07,680 --> 00:32:12,760
+الفصل على الأقل تستوعب ليش الأستاذ قال عشرة أقصى اثنين؟
+
+386
+00:32:12,760 --> 00:32:17,000
+هذا من عندي.  بجد عندي يعني كتير من الكتب ممكن تحدد لك
+
+387
+00:32:17,000 --> 00:32:23,020
+أرقام لـ ... يعني equilibrium constants حسب نوعها
+
+388
+0
+
+445
+00:36:50,570 --> 00:36:54,070
+legend لا يتفاعل مع الـ metal ion بنسبة 100%
+
+446
+00:36:54,070 --> 00:37:00,590
+يتفاعل بدرجة عالية، نعم، ويكون complex، نعم، لكن مش 100%
+
+447
+00:37:00,590 --> 00:37:03,950
+لأ، جزء ضئيل من الـ metal ion، جزء من الـ legend  مش
+
+448
+00:37:03,950 --> 00:37:08,030
+متفاعل، أو أنه لو عندي metal legend complex
+
+449
+00:37:08,030 --> 00:37:14,130
+فبلاحظ أنه يتفكك جزئيًا لبعض الـ metal وبعض الـ
+
+450
+00:37:14,130 --> 00:37:18,950
+legend. فهذا نوع ثالث من أنواع الـ Equilibria، النوع
+
+451
+00:37:18,950 --> 00:37:22,630
+الرابع الذي سندرسه هو Oxidation Reduction
+
+452
+00:37:22,630 --> 00:37:26,010
+Equilibria، فيه مادة Oxidized تتفاعل مع مادة
+
+453
+00:37:26,010 --> 00:37:30,610
+Reduced، الـ Oxidized يحصل لها اختزال، والمختزلة الـ
+
+454
+00:37:30,610 --> 00:37:35,230
+Reduced يحصل لها أكسدة.  برضه هذا تفاعل ممكن أن يكون
+
+455
+00:37:35,230 --> 00:37:40,060
+تفاعل اتزان. النوع الأخير من الاتزانيات التي يعني
+
+456
+00:37:40,060 --> 00:37:42,760
+موجودة عندنا في الـ slide، على الأقل، اللي هو حاجة
+
+457
+00:37:42,760 --> 00:37:47,500
+نقولها phase distribution، لما يكون في عندك organic
+
+458
+00:37:47,500 --> 00:37:52,860
+phase و aqueous phase، وفي عندك مادة راحت  خبيت هذه
+
+459
+00:37:52,860 --> 00:37:58,680
+المادة في الـ organic والـ aqueous phase معًا.
+
+460
+00:37:58,680 --> 00:38:02,680
+بتلاحظ أن هذه المادة تتجزأ حسب حبها للـ organic والـ
+
+461
+00:38:02,680 --> 00:38:06,500
+aqueous phase. فإذا كانت خصائصها قريبة من خصائص الـ
+
+462
+00:38:06,500 --> 00:38:10,980
+organic، بتروح وين؟ على الـ organic phase، على الطبقة
+
+463
+00:38:10,980 --> 00:38:15,040
+الـ organic. إذا كانت خصائصها قريبة من خصائص الـ
+
+464
+00:38:15,040 --> 00:38:20,220
+aqueous phase، معظمها بيكون في الـ aqueous phase،
+
+465
+00:38:20,220 --> 00:38:25,040
+لكن الشاهد أنه مش كلها بتنتقل للـ aqueous، ومش كلها
+
+466
+00:38:25,040 --> 00:38:30,880
+بتنتقل للـ organic، لأ، جزئيًا، ممكن الجزء هذا يكون
+
+467
+00:38:30,880 --> 00:38:35,650
+واحد من ألف في المئة، لكنه موجود. ممكن يكون قليل جدًا،
+
+468
+00:38:35,650 --> 00:38:40,670
+لكنه موجود. لكن هذا النوع الأخير إحنا مش رايحين
+
+469
+00:38:40,670 --> 00:38:45,690
+ندرسه في هذا الـ course، يعني الـ phase distribution
+
+470
+00:38:45,690 --> 00:38:49,990
+مش هيكون ضمن الحاجات التي سندرسها في هذا الـ
+
+471
+00:38:49,990 --> 00:38:56,530
+course. طيب يا شباب، كيف إحنا بنحسب الـ equilibrium
+
+472
+00:38:56,530 --> 00:39:02,210
+constant؟ كيف بنحسبه؟ بنقول والله إحنا توي شفنا الـ
+
+473
+00:39:02,210 --> 00:39:06,190
+equilibrium constant ما هو إلا عبارة عن تركيزات A
+
+474
+00:39:06,190 --> 00:39:10,710
+وB وC وD مجمعة على بعض بشكل معين. Equals.  فممكن لو
+
+475
+00:39:10,710 --> 00:39:14,830
+أنا عارف أو ممكن أقدر أحسب تركيز A وتركيز B و
+
+476
+00:39:14,830 --> 00:39:18,050
+تركيز C وتركيز D عند الاتزان، وباجي بجمعهم على
+
+477
+00:39:18,050 --> 00:39:20,770
+بعض حسب الـ equilibrium constant، بتطلع لقيمة الـ
+
+478
+00:39:20,770 --> 00:39:24,090
+equilibrium constant، اللي هو بسميه concentration
+
+479
+00:39:24,090 --> 00:39:29,800
+equilibrium constant. ممكن ولا مش ممكن؟ ممكن، فش
+
+480
+00:39:29,800 --> 00:39:35,900
+مشكلة. لكن في عندنا equilibrium constant يمكن حسابه
+
+481
+00:39:35,900 --> 00:39:39,680
+مباشرة من الـ thermodynamics، لأنه إحنا بنعرف أنه
+
+482
+00:39:39,680 --> 00:39:43,660
+أخذنا في سنة أولى، وأخذنا أسئلة كمان عليها في
+
+483
+00:39:43,660 --> 00:39:47,100
+الامتحان، جالنا أسئلة عليها أيضًا. أنا عندي الـ Gibbs
+
+484
+00:39:47,100 --> 00:39:51,890
+free energy، بتساوي ΔH - TΔS. لو جاء
+
+485
+00:39:51,890 --> 00:39:54,810
+نتكلم عن Gibbs free energy في الـ standard state،
+
+486
+00:39:54,810 --> 00:39:59,510
+فبنقول ΔG° بدها تساوي ΔH°
+
+487
+00:39:59,510 --> 00:40:04,350
+- TΔS°. حطينا ° هنا، إذا لازم نحط
+
+488
+00:40:04,350 --> 00:40:07,290
+° هنا و° هنا، لأن دول كلهم يعتبروا state
+
+489
+00:40:07,290 --> 00:40:11,710
+functions. فالـ ΔG° بتساوي ΔH°
+
+490
+00:40:11,710 --> 00:40:16,190
+- TΔS°. طب الـ ΔG° مش مر معنا
+
+491
+00:40:16,190 --> 00:40:21,010
+سابقا كمان أن هي بتساوي -RT ln K، حيث الـ K
+
+492
+00:40:21,010 --> 00:40:24,810
+هو الـ equilibrium constant. طبعًا مرات معانا إذا الـ
+
+493
+00:40:24,810 --> 00:40:29,950
+equilibrium constant إيش بيساوي؟ e<sup>-ΔG°/RT</sup>.  ندّقق شوية، إيش K؟ قال هي الـ
+
+494
+00:40:29,950 --> 00:40:33,930
+equilibrium constant. يعني لو كان في عندي تفاعل A
+
+495
+00:40:33,930 --> 00:40:37,230
+وB بيعطوني C وD مثلًا، وأنا حبيت أن أحسب الـ
+
+496
+00:40:37,230 --> 00:40:42,590
+equilibrium constant، هأفعل، وأجيب الـ ΔG°.
+
+497
+00:40:42,590 --> 00:40:45,330
+إذا كان الـ ΔG° معايا، وبقدر أحسبها أنا من
+
+498
+00:40:45,330 --> 00:40:49,830
+الـ ΔH° - TΔS°، بقدر أحسبها. الـ
+
+499
+00:40:49,830 --> 00:40:54,610
+R ثابت، والـ T ثابت، إذا بقدر أحسب الـ K بمعلومية
+
+500
+00:40:54,610 --> 00:40:59,190
+الـ ΔG°، اللي هي تعتبر thermodynamic
+
+501
+00:40:59,190 --> 00:41:02,210
+function، بقدر أجيبها بسهولة. طيب، إذا هذا الـ
+
+502
+00:41:02,210 --> 00:41:06,820
+equilibrium constant، بقدر أقول لكم حاجة عنه، بقدر
+
+503
+00:41:06,820 --> 00:41:10,740
+أقول أن هذا الـ equilibrium constant، إحنا حصلنا
+
+504
+00:41:10,740 --> 00:41:13,340
+عليه من الـ thermodynamic equations، من الـ
+
+505
+00:41:13,340 --> 00:41:17,120
+thermodynamics. عشان هيك اسمه thermodynamic
+
+506
+00:41:17,120 --> 00:41:21,220
+equilibrium constant. اسم الـ equilibrium constant
+
+507
+00:41:21,220 --> 00:41:25,520
+هذا الذي أحصل عليه من الـ thermodynamics، بسميه
+
+508
+00:41:25,520 --> 00:41:28,320
+thermodynamic equilibrium constant. هل يختلف عن الـ
+
+509
+00:41:28,320 --> 00:41:32,580
+concentration equilibrium constant ولا بيساوي؟ هذاك
+
+510
+00:41:32,580 --> 00:41:37,760
+حصلت عليه من الـ concentrations، وهذا حصلت عليه من
+
+511
+00:41:37,760 --> 00:41:40,200
+الـ thermodynamic equations. بقول إنه في بعض الأحيان،
+
+512
+00:41:40,200 --> 00:41:44,560
+أو ضمن شروط معينة، بيساوي، لكن ضمن شروط... إذا اختلت
+
+513
+00:41:44,560 --> 00:41:48,640
+هذه الشروط، لأ، لا يساوي. إذا... إذا بقول ضمن شروط
+
+514
+00:41:48,640 --> 00:41:54,560
+معينة، سندرسها... سندرسها، لكن في آخر الـ chapter، ضمن
+
+515
+00:41:54,560 --> 00:41:58,080
+شروط معينة، الـ thermodynamic equilibrium constant
+
+516
+00:41:58,080 --> 00:42:02,780
+هذا الذي أمامي، يساوي الـ concentration equilibrium
+
+517
+00:42:02,780 --> 00:42:06,340
+constant، لكن ضمن شروط مغايرة. الاثنان مختلفان عن
+
+518
+00:42:06,340 --> 00:42:12,130
+بعض، وبالتالي هذا له انعكاسات مهمة جدًا على دراستنا
+
+519
+00:42:12,130 --> 00:42:18,690
+في الكيمياء التحليلية، لكن سنرى هذا الكلام في آخر
+
+520
+00:42:18,690 --> 00:42:23,070
+الشابتر. إذا، الله يرضى علي، ممكن نتكلم برضه عن موضوع مر
+
+521
+00:42:32,770 --> 00:42:38,670
+معنا سابقًا، Le Chatelier's Principle. هو مبادئ لتشتّـ
+
+522
+00:42:38,670 --> 00:42:44,070
+ليه؟ إيش مبادئ لتشتّـ ليه؟ قال والله هي العوامل التي
+
+523
+00:42:44,070 --> 00:42:50,130
+تؤثر على الـ equilibrium، العوامل التي تؤثر على الـ
+
+524
+00:42:50,130 --> 00:42:53,610
+equilibrium. هناك عوامل تؤثر على الـ equilibrium.
+
+525
+00:42:53,610 --> 00:42:55,650
+أنا عندي equilibrium، أنا عندي تفاعل، مافي
+
+526
+00:42:55,650 --> 00:43:02,090
+equilibrium، كويس. لو أثرت عليه بمؤثر خارجي، لو أثرت
+
+527
+00:43:02,090 --> 00:43:07,070
+عليه بمؤثر خارجي، بلاحظ أن الـ equilibrium هذا يعني
+
+528
+00:43:07,070 --> 00:43:13,230
+يتأثر، بحيث إنه يحاول أن يُلَاَشي تأثير المؤثر
+
+529
+00:43:13,230 --> 00:43:17,710
+الخارجي. يعني يمشي في اتجاه بحيث إنه يحاول يُلَاَشي
+
+530
+00:43:17,710 --> 00:43:22,850
+تأثير المؤثر الخارجي. إذا، الله أراد، الحصة القادمة
+
+531
+00:43:22,850 --> 00:43:26,890
+سنتكلم عن Le Chatelier's Principle.
diff --git a/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/KvHOk6vIgOk_postprocess.srt b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/KvHOk6vIgOk_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..2b323064fe13bac98ba061c073fbcc768e5d2f8d
--- /dev/null
+++ b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/KvHOk6vIgOk_postprocess.srt
@@ -0,0 +1,2128 @@
+1
+00:00:22,680 --> 00:00:26,560
+بسم الله الرحمن الرحيم طيب يا شباب احنا الحصة
+
+2
+00:00:26,560 --> 00:00:29,380
+الماضية كنا بدأنا نتكلم عن ال normality
+
+3
+00:00:29,380 --> 00:00:33,420
+calculations او بالاخره نستكمل ال normality
+
+4
+00:00:33,420 --> 00:00:37,800
+calculations اللي شفناها جاب العدة مخادرات كمقدمة
+
+5
+00:00:37,800 --> 00:00:43,380
+فاخدنا مثال الحصة الماضية و اليوم بنحاول نكمل في
+
+6
+00:00:43,380 --> 00:00:49,640
+ال normality calculationsفنطلع على هالمثال اللي
+
+7
+00:00:49,640 --> 00:00:54,920
+كان معناه مثال شبيه في لما نتكلمنا عن ال molarity
+
+8
+00:00:54,920 --> 00:00:59,240
+calculations لكن اليوم بدنا نستخدم ال normality في
+
+9
+00:00:59,240 --> 00:01:04,260
+الحسابات فالمثال بيقول use normalities to
+
+10
+00:01:04,260 --> 00:01:10,240
+calculate how many ml of a 0.1 molar H2SO4H2SO4
+
+11
+00:01:10,240 --> 00:01:17,000
+ستتفاعل مع 20 مل مولار صوديم هيدروكسيد . طبعا لو
+
+12
+00:01:17,000 --> 00:01:22,720
+كان الغرض من المسألة هو حساب المولارات أو حساب
+
+13
+00:01:22,720 --> 00:01:26,940
+المليليتر من ال H2SO4 كان ممكن استخدم المليمول
+
+14
+00:01:26,940 --> 00:01:30,960
+مباشرةلأنه انا بعرف ان ال millimoles من ال sodium
+
+15
+00:01:30,960 --> 00:01:35,600
+hydroxide بتساوي ضعف ال millimoles من ال H2SO4 لو
+
+16
+00:01:35,600 --> 00:01:37,860
+كتبنا المعادلة و المدير اللي بيكتبها برضه هذا
+
+17
+00:01:37,860 --> 00:01:43,540
+الكلام معلوم لكن انا مابديش استخدم او مابديش احل
+
+18
+00:01:43,540 --> 00:01:47,400
+باستخدام ال molarity انا بدي احل باستخدام ال
+
+19
+00:01:47,400 --> 00:01:51,490
+normalityففيه قدام يعني في الحقيقة خيارات من أبسط
+
+20
+00:01:51,490 --> 00:01:55,670
+الخيارات اللي ممكن استخدم فيها ال normalities اني
+
+21
+00:01:55,670 --> 00:02:01,490
+اطلع ال normality لل H2SO4 واطلع ال normality لل
+
+22
+00:02:01,490 --> 00:02:06,570
+Sodium Hydroxide وبعدين اقول milliequivalent H2SO4
+
+23
+00:02:06,570 --> 00:02:12,490
+بيساوي milliequivalent من Sodium Hydroxide فال
+
+24
+00:02:12,490 --> 00:02:19,800
+normality لل H2SO4 and ال N بتنينمرة الملاريتي
+
+25
+00:02:19,800 --> 00:02:24,880
+لأنه عندي ال normality بتساوي N في الملاريتي اتنين
+
+26
+00:02:24,880 --> 00:02:28,000
+في point one بتعطيني point two ال normality لل
+
+27
+00:02:28,000 --> 00:02:32,160
+H2SO4 والnormality للصودم هيدروكسايد طبيعي الصودم
+
+28
+00:02:32,160 --> 00:02:36,320
+هيدروكسايد فش فيه الا غير one hydroxide group
+
+29
+00:02:36,320 --> 00:02:40,860
+وبالتالي هو دائما ال normality له بتساوي الملاريتي
+
+30
+00:02:40,860 --> 00:02:44,940
+فال N بواحد معناه الكلمة من normality هتساوي point
+
+31
+00:02:44,940 --> 00:02:51,960
+two fiveالان مباشرة ملي اكوفلانت من ال H2SO4 تساوي
+
+32
+00:02:51,960 --> 00:02:55,120
+ملي اكوفلانت من ال Sodium Hydroxide مافيش عنده اي
+
+33
+00:02:55,120 --> 00:02:58,260
+Stoichiometric factors لان الملي اكوفلانت بتساوي
+
+34
+00:02:58,260 --> 00:03:03,360
+الملي اكوفلانت فعندي الملي اكوفلانت بعوض عنها زي
+
+35
+00:03:03,360 --> 00:03:09,800
+ما اتفجنا سابقا بأحد تلت حاجات يا اما normality ب
+
+36
+00:03:09,800 --> 00:03:14,650
+volume بالمليا إما milligram على ال equivalent
+
+37
+00:03:14,650 --> 00:03:18,850
+weight يا إما N في الملي مول هي الملي equivalent
+
+38
+00:03:18,850 --> 00:03:24,690
+فاش غير هي فانا بتطبع عندها normality وعندي volume
+
+39
+00:03:24,690 --> 00:03:28,610
+بالمل فبقول والله ال normality لل H2SO4 في ال
+
+40
+00:03:28,610 --> 00:03:31,510
+volume بالمل مجهولة ال normality لل sodium
+
+41
+00:03:31,510 --> 00:03:36,570
+hydroxide في ال volume بالمل عشرين مل بطلع عند ال
+
+42
+00:03:36,570 --> 00:03:40,150
+volume من ال H2SO4 خمسة وعشرين مل
+
+43
+00:03:43,560 --> 00:03:52,380
+لأ إنت بدك تطلع أكم مل من ال H2SO4 لو بدك تطلعها
+
+44
+00:03:52,380 --> 00:03:57,200
+من ال molarity بيطلعنك نفس القيمة يعني بس احنا ها
+
+45
+00:03:57,200 --> 00:04:02,780
+نستخدم ال normalitiesبالظبط ال normalities نيجي
+
+46
+00:04:02,780 --> 00:04:07,560
+نتطلع على المثال التالي الآن المثال بيقول find the
+
+47
+00:04:07,560 --> 00:04:12,720
+normality of sodium carbonate ال formula 106 in a
+
+48
+00:04:12,720 --> 00:04:18,640
+solution containing 0.212 gram carbonate in 100 ml
+
+49
+00:04:18,640 --> 00:04:24,350
+solution يعني عندي 0.212 gramمن ال sodium
+
+50
+00:04:24,350 --> 00:04:28,810
+carbonate مدوبة في hundred ml solution عايز أعرف
+
+51
+00:04:28,810 --> 00:04:33,870
+هذا المحلول إيش ال normality إله كويس فإيش بيقوللي
+
+52
+00:04:33,870 --> 00:04:37,990
+بيقوللي the carbonate is used as a monobasic base
+
+53
+00:04:37,990 --> 00:04:41,990
+طبعا بيقوللي if إذا ال carbonate كانت monobasic
+
+54
+00:04:41,990 --> 00:04:46,670
+base بمعنى إنها تتفاعل بس مع واحد يعني n واحد hc
+
+55
+00:04:46,670 --> 00:04:50,690
+يعني n بتساوي واحدالحالة التانية the carbonate is
+
+56
+00:04:50,690 --> 00:04:55,530
+used as a by basic base يعني بتتفعل مع اتنين HCl
+
+57
+00:04:55,530 --> 00:05:00,010
+بمعنى ان ال N بتساوي اتنين في حالة ما تكون mono
+
+58
+00:05:00,010 --> 00:05:05,310
+basic base معناته ال formula weight على واحد
+
+59
+00:05:05,310 --> 00:05:09,070
+بتساوي ال equivalent weight ليه؟ لأن ان عندنا F
+
+60
+00:05:09,070 --> 00:05:11,850
+واحد فال equivalent weight بده يساوي ال formula
+
+61
+00:05:11,850 --> 00:05:16,750
+weight على واحد او مية وستةأنا بعنصح بشكل كبير أنه
+
+62
+00:05:16,750 --> 00:05:23,870
+دائما نكتب ال .. يعني المعطى المعطى هو عبارة عن لو
+
+63
+00:05:23,870 --> 00:05:29,250
+اتطلعت فيها كويس بتقول point two one two grams على
+
+64
+00:05:29,250 --> 00:05:38,010
+hundred milهذه هي نفسها 212 ميلي جرام على الميت
+
+65
+00:05:38,010 --> 00:05:41,470
+ميل يعني هانبدل جرام و حولتها لميلي جرام فضربت في
+
+66
+00:05:41,470 --> 00:05:45,990
+الف المثل لو كتبتها بالشكل هذا واضحة ليه؟ لأنه انا
+
+67
+00:05:45,990 --> 00:05:50,690
+بدي normality بجا الميلي جرام هذه بده احولها لإيه؟
+
+68
+00:05:50,690 --> 00:05:53,450
+لميلي equivalent لأن ال normality ميلي equivalent
+
+69
+00:05:53,450 --> 00:05:56,610
+على الميلي لتر طب كيف ممكن احول ميلي جرام لميلي
+
+70
+00:05:56,610 --> 00:06:02,760
+equivalent؟الـ equivalent weight يعني وكأنني بدى
+
+71
+00:06:02,760 --> 00:06:07,340
+أجسم الـ212 على ال equivalent weight اللي هي 106
+
+72
+00:06:07,340 --> 00:06:12,620
+على 100 بيعطينا ال normality معايا يا شباب؟ يعني
+
+73
+00:06:12,620 --> 00:06:18,590
+اقطب المطلوب و دائما حاول توصل لملي اكوفلانت على
+
+74
+00:06:18,590 --> 00:06:22,370
+الملي لتر اذا كان بدك normality احنا عندنا الملي
+
+75
+00:06:22,370 --> 00:06:27,370
+اكوفلانت لو حبنا ان نحسبها مثلا فالملي جرام على ال
+
+76
+00:06:27,370 --> 00:06:32,730
+equivalent weight انا حاسب 2.12 ملي جرام على المل
+
+77
+00:06:32,730 --> 00:06:37,630
+على 106 بطلع 0.02 ملي اكوفلانت على المل يعني 0.02
+
+78
+00:06:37,630 --> 00:06:43,050
+normalبنفس الطريقة لما بدي أتكلم عن حساب ال
+
+79
+00:06:43,050 --> 00:06:47,650
+normality في حالة ما أني أستخدم ال carbonate as a
+
+80
+00:06:47,650 --> 00:06:54,010
+bi-basic base بيكون في عنا ال N بتساوي 2 معناته ال
+
+81
+00:06:54,010 --> 00:06:57,150
+equivalent weight بدي سوى ال formula weight على 2
+
+82
+00:06:57,150 --> 00:07:03,020
+بدي سوى 53نفس المنطق انا عندى 212 ميلي جرام على ال
+
+83
+00:07:03,020 --> 00:07:06,340
+meat meal بدى اجسم على ال equivalent weight عشان
+
+84
+00:07:06,340 --> 00:07:09,620
+احوالها لميلي equivalent بتعطينى normality على طول
+
+85
+00:07:09,620 --> 00:07:15,020
+طيب ايش هو ال equivalent weight؟ هى و 53 اذا بدى
+
+86
+00:07:15,020 --> 00:07:20,720
+اجسم 212 على 53 على 100 هذا بيعطينى ال normality
+
+87
+00:07:20,720 --> 00:07:27,180
+بتطلع ال normality 0.04 فسهل ان اوصل ايضا للحل
+
+88
+00:07:29,090 --> 00:07:35,900
+بيجينا مسألتين خليني أقول متعاكستين تقريباففي مثلة
+
+89
+00:07:35,900 --> 00:07:41,600
+ما عايز أحضر محلول إله normality معينة كيف بدي
+
+90
+00:07:41,600 --> 00:07:46,040
+أحضر محلول إله normality معينة يمكن إحنا لما أخدنا
+
+91
+00:07:46,040 --> 00:07:51,380
+ال normality قبل عدة محاضرات مرنا إشي شبيه بهذا
+
+92
+00:07:51,380 --> 00:07:56,940
+الكلام لكن يعتبر هذا المثال مكرر تقريبا لكن بناخده
+
+93
+00:07:56,940 --> 00:08:01,460
+لإنه موجود في الكتاب بالترتيبإنك لما نتراجع في
+
+94
+00:08:01,460 --> 00:08:05,980
+الكتاب تحس حالك إنك منسجن مع المادة المكتوبة
+
+95
+00:08:05,980 --> 00:08:10,480
+فالمثال بيقول التالي بيقول how many milligram of
+
+96
+00:08:10,480 --> 00:08:15,480
+I2 should you weigh to prepare 250 ml of 0.1
+
+97
+00:08:15,480 --> 00:08:20,500
+normal solution in the reaction I2 زائد 2 إلكترون
+
+98
+00:08:20,500 --> 00:08:25,940
+بيعطينا 2 I minus عكس هذا الكلام ممكن يعطيني وزنة
+
+99
+00:08:26,400 --> 00:08:30,120
+مثابة في حجب معين ويقول اللي والله جديش ال
+
+100
+00:08:30,120 --> 00:08:33,520
+normality زي ما شفنا في حالة الكربونيت هنشوف مثال
+
+101
+00:08:33,520 --> 00:08:38,800
+مثال من هذا النوع بعد شوية لكن الان نرجع لمثالنا
+
+102
+00:08:38,800 --> 00:08:42,480
+بيقول how many milligrams of I2 should you weigh
+
+103
+00:08:42,480 --> 00:08:47,000
+to prepare 250ml of 0.1 normal solution طبعا احنا
+
+104
+00:08:47,000 --> 00:08:51,220
+اتفقنا سابقا على ان مفتاح الحلالملي اكوفلانت يعني
+
+105
+00:08:51,220 --> 00:08:55,280
+لأنه مش ملي مول لأنه Normalities فالملي اكوفلانت
+
+106
+00:08:55,280 --> 00:08:58,920
+بيساوي ال normality فيه ال volume بالمل فبيعطيني
+
+107
+00:08:58,920 --> 00:09:04,880
+25 ملي اكوفلانت هي عدد الملي اكوفلانت 25 انا بديش
+
+108
+00:09:04,880 --> 00:09:08,620
+ملي اكوفلانت انا بدي ملي جرام الملي جرام بيساوي
+
+109
+00:09:08,620 --> 00:09:11,360
+الملي اكوفلانت في ال equivalent weightالـ
+
+110
+00:09:11,360 --> 00:09:15,300
+equivalent weight ايش بيساوي؟ formula weight على
+
+111
+00:09:15,300 --> 00:09:20,840
+اتنين لان عندي two electrons للمول هذا واحد مول I2
+
+112
+00:09:22,750 --> 00:09:28,710
+إتنين إذن في عندي N بتساوي اتنين مع هذا الكلام ال
+
+113
+00:09:28,710 --> 00:09:32,550
+milligram I2 بتساوي ال milliequivalent اللي هو
+
+114
+00:09:32,550 --> 00:09:36,650
+خمسة وعشرين في ال formula weight 254 على اتنين
+
+115
+00:09:36,650 --> 00:09:40,410
+فبيطلع عندي تلاتة و تمانتاش انمية فعشرة أقص تلاتة
+
+116
+00:09:40,410 --> 00:09:46,470
+milligrams أخر مثال في ال normalities زي ما .. زي
+
+117
+00:09:46,470 --> 00:09:52,260
+ما ذكرت يعني هو تقريبا أكس المثال السابقFind the
+
+118
+00:09:52,260 --> 00:09:59,840
+normality of the solution containing 0.25g H2C2O4
+
+119
+00:09:59,840 --> 00:10:05,600
+Oxalic Acid الفورمولة وقت 90 طبعا ال Oxalic Acid
+
+120
+00:10:05,600 --> 00:10:11,400
+يا شباب مر معنى انه هو Acid بي أسدك أسد يعني مافي
+
+121
+00:10:11,400 --> 00:10:17,280
+مشكلة فيستخدم ك أسد لكن مر معنى ك reducing agent
+
+122
+00:10:17,760 --> 00:10:21,920
+أوكزاليك أسد مر معنى أيضا ك reducing agent فهو
+
+123
+00:10:21,920 --> 00:10:29,360
+يستخدم ك reducing agent و أيضا ك acid ففي المعادلة
+
+124
+00:10:29,360 --> 00:10:32,680
+اللي عندي هو يستخدم ك acid و قال لي أنه اوكزاليك
+
+125
+00:10:32,680 --> 00:10:38,720
+أسد reacts as a diacidic substance بمعنى أنهالان
+
+126
+00:10:38,720 --> 00:10:44,520
+بتساوي اتنين فبقول ببساطة خالص يعني لو حاولت ان
+
+127
+00:10:44,520 --> 00:10:50,940
+اكتب المعادلة بقول والله point two five انت عليك
+
+128
+00:10:50,940 --> 00:10:55,960
+ميلي جرام على الميلي لتر بنفع ولا لأ point two
+
+129
+00:10:55,960 --> 00:10:57,940
+five ميلي جرام على الميلي لتر يعني point two five
+
+130
+00:10:57,940 --> 00:11:01,980
+ميلي جرام على ايه؟ على الميلي لتر طب انا بدي حول
+
+131
+00:11:01,980 --> 00:11:06,130
+بدي .. بدي normality اذا انا بدي هاتي تكون ايه؟ملي
+
+132
+00:11:06,130 --> 00:11:08,750
+اكويفلانت انا بدي ملي اكويفلانت على الملي لتر لان
+
+133
+00:11:08,750 --> 00:11:13,550
+هذه ال normality ايش بدي اقسم على ال equivalent
+
+134
+00:11:13,550 --> 00:11:15,930
+weight بجيب ال equivalent weight ال equivalent
+
+135
+00:11:15,930 --> 00:11:19,850
+weight هو عبارة عن formula weight على 2 تسعين على
+
+136
+00:11:19,850 --> 00:11:23,330
+2 خمسة و أربعين يعني بدي اقسم point two five على
+
+137
+00:11:23,330 --> 00:11:29,530
+خمسة و أربعين بعطيني ال normality الجواب
+
+138
+00:11:29,530 --> 00:11:34,690
+بيطلع عندنا point o o five six normalالكويس يا
+
+139
+00:11:34,690 --> 00:11:41,230
+شباب هذه طبيعة الأسئلة اللي ممكن تواجهنا في حسابات
+
+140
+00:11:41,230 --> 00:11:47,150
+ال normalities بتمنى كتير أنه تكون أسئلة جيدة و
+
+141
+00:11:47,150 --> 00:11:56,770
+حالها مباشر وسهل كتير الآن ننتقل لآخر جزئية في هذا
+
+142
+00:11:56,770 --> 00:11:59,670
+ال chapter وهي مفهوم ال title
+
+143
+00:12:03,060 --> 00:12:07,620
+تعالوا نشوف بالظبط إيش المقصود بمفهوم التيتر طبعا
+
+144
+00:12:07,620 --> 00:12:12,300
+تيتر المعايير أو يعني مصطلح اسمه التيتر المعايير
+
+145
+00:12:12,300 --> 00:12:19,080
+بنقوله فإيش هو بالظبط لو إجينا اتذكرنا معاكوا في
+
+146
+00:12:19,080 --> 00:12:23,520
+عندي KMNO4
+
+147
+00:12:23,520 --> 00:12:32,460
+مثلا تتفاعل مع iron 2 plusالتفاعل اللي ممكن شفناه
+
+148
+00:12:32,460 --> 00:12:39,740
+سابقا MnO أربعة زائد خمسة iron اتنين plus زائد
+
+149
+00:12:39,740 --> 00:12:45,620
+تمانية H plus بيعطيني نواتج اكويس هيك يا شباب
+
+150
+00:12:45,620 --> 00:12:50,300
+فبقول ايش انا بقول انه والله لما بدي أشي أحل مسألة
+
+151
+00:12:50,300 --> 00:12:58,380
+زي هذه بقول خمسة ملي او ال iron ملي مول iron بيسوى
+
+152
+00:12:58,380 --> 00:13:05,850
+خمسة ملي مولPermanganate صحيح؟ هيه ال iron خمسة و
+
+153
+00:13:05,850 --> 00:13:09,110
+ال permanganate واحد اذا المليمول iron خمس امثال
+
+154
+00:13:09,110 --> 00:13:14,690
+ال permanganate صحيح؟ طيب لكن عادة لما أكون بشتغل
+
+155
+00:13:14,690 --> 00:13:21,210
+في مختبر بيختص مثلا بتحليل خان فعايز .. بدوش يحسب
+
+156
+00:13:21,210 --> 00:13:26,090
+iron بده يحسب iron اتنين و تلاتة
+
+157
+00:13:28,970 --> 00:13:32,570
+يعني بدوش يعوض عن ال iron ب iron بده iron اتنين او
+
+158
+00:13:32,570 --> 00:13:37,110
+تلاتة فبقول انا عادة بقول هذا بعطيل اتنين iron اذا
+
+159
+00:13:37,110 --> 00:13:43,930
+ال millimol iron ايش بيساوي بده
+
+160
+00:13:43,930 --> 00:13:51,930
+يساوي اتنين millimol iron اتنين او تلاتة هاي اتنين
+
+161
+00:13:51,930 --> 00:13:56,410
+millimol iron اتنين او تلاتة محل ال millimol iron
+
+162
+00:13:57,130 --> 00:14:02,110
+فبتصير اتنين ميلي مول ايرون اتنين او تلاتة بدها
+
+163
+00:14:02,110 --> 00:14:09,610
+تساوي خمسة ميلي مول كي مي ن او فور الان بقدر احسب
+
+164
+00:14:09,610 --> 00:14:15,610
+انا اكم ميلي جرام ايرون اتنين او تلاتة صحيح؟ اه و
+
+165
+00:14:15,610 --> 00:14:18,550
+هذا اللي انا بدي احسب اكم ميلي جرام ايرون اتنين او
+
+166
+00:14:18,550 --> 00:14:23,610
+تلاتة الفكرة ايش الان الفكرة انه لو كان في عندي
+
+167
+00:14:23,610 --> 00:14:24,710
+محلول
+
+168
+00:14:31,870 --> 00:14:37,510
+KMNO4 وليكن point one molar وليكن point one molar
+
+169
+00:14:37,510 --> 00:14:43,270
+انا بديش اعبر عنه او بديش اكتب عليه هي تركيزه واحد
+
+170
+00:14:43,270 --> 00:14:47,850
+من عشرة molar بدي اكتب عليه انه كل واحد mil منه
+
+171
+00:14:47,850 --> 00:14:53,690
+بيتفاعل مع كذا milligram من ال iron 203 يعني بدي
+
+172
+00:14:53,690 --> 00:15:02,890
+اكتب عليه مثلا ال titer تبعه بيساويمثلا 3.425
+
+173
+00:15:02,890 --> 00:15:10,890
+milligram Fe2O3 ايش معنى هذا الكلام؟ معناته انه
+
+174
+00:15:10,890 --> 00:15:14,370
+انا لو استخدمت محلول البرمينجانيت هذا عشان اعير
+
+175
+00:15:14,370 --> 00:15:19,270
+فيه محلول ال iron فكل mil من محلول البرمينجانيت
+
+176
+00:15:20,280 --> 00:15:26,540
+بيعادل 3.425 ميلي جرام iron 203 يعني لو أجيت عملت
+
+177
+00:15:26,540 --> 00:15:31,160
+معايرة المعايرة هذه أخدت عشر مل من البرمجانات
+
+178
+00:15:31,160 --> 00:15:35,820
+معناته أندي اربعة و تلاتين و ربع ميلي جرام من ال
+
+179
+00:15:35,820 --> 00:15:39,980
+iron 203 مباشرة من غير ماعمل الحسبات الطويلة هذه
+
+180
+00:15:39,980 --> 00:15:44,020
+أنا عملت بس مرة واحدة بإن طلعت ال titer للبرمجانات
+
+181
+00:15:44,560 --> 00:15:50,160
+الان لو اجيت اعملت مائة معايرة بشوف فقط جداش الحجم
+
+182
+00:15:50,160 --> 00:15:53,460
+اللي اخدته المعايرة الاولى بضربه في التيتر بطلع
+
+183
+00:15:53,460 --> 00:15:57,040
+لأكم ميلي جرام ايرون 2 او 3 في المعايرة الاولى
+
+184
+00:15:57,040 --> 00:16:03,240
+المعايرة التانية بضرب الحجم بالتيتر
+
+185
+00:16:03,240 --> 00:16:08,680
+فبيعطيني جداش ميلي جرام من الايرون 2 او 3 موجود
+
+186
+00:16:08,680 --> 00:16:13,690
+عندى في المحلول و هكذا يعنياستخدام مفهوم الـ titer
+
+187
+00:16:13,690 --> 00:16:19,510
+بيسهل علي الوصول للنتائج دون المرور بالخطوات
+
+188
+00:16:19,510 --> 00:16:26,870
+الحسابية المتعددة والمتكررة كل مرة بدي اخد مثال
+
+189
+00:16:26,870 --> 00:16:32,730
+على هذا الكلام ويمكن في الحياة العملية يعني عندنا
+
+190
+00:16:32,730 --> 00:16:37,330
+في بلادنا لو اجيت انت اشتغلت في مختبر مية مثلا
+
+191
+00:16:38,930 --> 00:16:42,890
+مختبر الميه عادة يعني بياخدوا عينات من الآبار
+
+192
+00:16:42,890 --> 00:16:47,650
+المختلفة وبيحللوا بيشوفوا ال water hardness عصر
+
+193
+00:16:47,650 --> 00:16:51,090
+الميه بيعملوا report على هيئة calcium carbonate
+
+194
+00:16:51,090 --> 00:16:56,770
+milligram calcium carbonate كويس فال EDTA بعيروا
+
+195
+00:16:56,770 --> 00:17:02,790
+فيها دائماالميه بيقول ال EDTA بتعادل الكالسيوم و
+
+196
+00:17:02,790 --> 00:17:06,410
+المجنيزيوم مثلا يعني لكن في النهاية بيقولك ميلي
+
+197
+00:17:06,410 --> 00:17:09,490
+مول EDTA بيساوي ميلي مول مثلا كالسيوم، بعدين ميلي
+
+198
+00:17:09,490 --> 00:17:12,490
+مول كالسيوم بيساوي ميلي مول كالسيوم كربونيت، بعدين
+
+199
+00:17:12,490 --> 00:17:16,670
+بيحسبوا أكم ميلي جرام من الكالسيوم كربونيت لكل
+
+200
+00:17:16,670 --> 00:17:22,550
+معايرة، لأ بدناش نعمل هيك، احنا ال EDTA هادياللي
+
+201
+00:17:22,550 --> 00:17:25,230
+هي مثلا خمسة letters عندي وبعدين بنبطل بقالها
+
+202
+00:17:25,230 --> 00:17:29,750
+point one molar EDTA لأ بنبطل بقالها ال title
+
+203
+00:17:29,750 --> 00:17:37,470
+تبعها مثلا بي ساوي مثلا six point five three two
+
+204
+00:17:38,110 --> 00:17:43,150
+ملي جرام كالسيوم كربونيت ايش معناته؟ معناته انه كل
+
+205
+00:17:43,150 --> 00:17:47,450
+مل من هذه ال EDTA لما ناجي اعير فيها الميه بعبيرلي
+
+206
+00:17:47,450 --> 00:17:52,790
+عن ايه؟ 6.532 ميلي جرام كالسيوم كربونيت يعني لو
+
+207
+00:17:52,790 --> 00:17:58,860
+عملت معايرة واخدت 10 مل من ال EDTA معناتهخمسة ستين
+
+208
+00:17:58,860 --> 00:18:02,900
+و ثلاثة من عشرة milligram مباشرة فلما نكون عندى
+
+209
+00:18:02,900 --> 00:18:06,540
+معاييرات متعددة مائة معايرة مثلا على طول أددشة و
+
+210
+00:18:06,540 --> 00:18:09,080
+المعاييرة أخدت بضرب في التيتر و أجد أندي calcium
+
+211
+00:18:09,080 --> 00:18:14,300
+carbonate و هكذا علشان هيك استخدام التيتر بيوفر
+
+212
+00:18:14,300 --> 00:18:18,100
+يعني وقت كبير جدا كلنا بنستهلكوا في إيه؟ في
+
+213
+00:18:18,100 --> 00:18:22,020
+الحسابات أنا بدي أخد مثال عملي على هذا الكلام أخد
+
+214
+00:18:22,020 --> 00:18:25,320
+مثال يعني كتير جيد
+
+215
+00:18:28,560 --> 00:18:33,460
+نطلع على المثال التالي، ايش بنقول؟ بيسأل، بيقول،
+
+216
+00:18:33,460 --> 00:18:37,900
+what's the titer of a 5.442 grams per liter
+
+217
+00:18:37,900 --> 00:18:42,720
+potassium dichromate in terms of milligram iron
+
+218
+00:18:42,720 --> 00:18:48,480
+2O3؟ يعني هو بيعير دائما، هدت بيعير الـ iron بإيه؟
+
+219
+00:18:48,480 --> 00:18:52,220
+بالـ dichromate، لكن في المعادلة إيش في عندى؟ في 2
+
+220
+00:18:52,220 --> 00:18:57,060
+plusمعايا انتوا؟ هو بدوش هو بدوها in terms of ايه؟
+
+221
+00:18:57,060 --> 00:19:01,940
+milligram iron 203 يعني بيقول ليه كل mil من هذا
+
+222
+00:19:01,940 --> 00:19:09,250
+المحلول مع اكم milligram iron 203 بيتفعليعني أكم
+
+223
+00:19:09,250 --> 00:19:12,490
+عدد ميلي جرامات الـ Iron 2O3 الموجودة في العينة
+
+224
+00:19:12,490 --> 00:19:16,970
+إذا كان عندي حجم معين من ال 5.442 جرام على اللتر
+
+225
+00:19:16,970 --> 00:19:21,930
+Potassium Dichromate فبقول الحل كتير كتير بسيط أنا
+
+226
+00:19:21,930 --> 00:19:25,430
+بدي أجيب التايتر يعني بدي أجيب أكم ميلي جرام Iron
+
+227
+00:19:25,430 --> 00:19:31,800
+2O3لكل ملي لتر من ال biochromate اللي عندي يعني كل
+
+228
+00:19:31,800 --> 00:19:35,480
+ملي لتر من ال biochromate مع أكم milligram من ال
+
+229
+00:19:35,480 --> 00:19:38,580
+iron 203 بيتفعل فبنقول بنفس الطريقة اللي حكينا
+
+230
+00:19:38,580 --> 00:19:43,180
+فيها سابقا بنطلع في البداية ال millimol iron ستة
+
+231
+00:19:43,180 --> 00:19:45,700
+millimol biochromate من وين جيبناها؟ من المعادلة
+
+232
+00:19:45,700 --> 00:19:51,360
+المعادلة هي ال iron ستة أمثال biochromate يبقى ال
+
+233
+00:19:51,360 --> 00:20:00,210
+millimol iron ستة millimol biochromateأنا 5.4 ميلي
+
+234
+00:20:00,210 --> 00:20:03,430
+جرام فورد لازم يكون ميلي جرام؟ الجرام قليل ترهيب
+
+235
+00:20:03,430 --> 00:20:09,450
+فبتحط 5.4 ميلي جرام فيرميل قعدت بكتوبها زي هيك و
+
+236
+00:20:09,450 --> 00:20:16,610
+كتوبها زي هيك مافيش مشكلةسواء كتبتها 5.442 اجرام
+
+237
+00:20:16,610 --> 00:20:21,350
+على اللتر او كتبتها 5.442 ميلي جرام على الميلي لتر
+
+238
+00:20:21,350 --> 00:20:26,010
+هي نفسها لإنك لما تحط فوق ميلي وتحط تحت ميلي هي هي
+
+239
+00:20:26,010 --> 00:20:32,000
+نفس الكلام طيب انتبهوا معايا يا شباببقول انا بديش
+
+240
+00:20:32,000 --> 00:20:35,240
+iron انا بدي iron 2O3 عشان ايه بيقول كل اتنين iron
+
+241
+00:20:35,240 --> 00:20:38,620
+بيعطوني iron 2O3 مش هيك يبقى ال millimole iron
+
+242
+00:20:38,620 --> 00:20:42,980
+بيساوي عفوا اللي بيساوي هذه قبلها يساوي اتنين
+
+243
+00:20:42,980 --> 00:20:48,840
+millimole iron 2O3 كويس اذا اتنين millimole iron
+
+244
+00:20:48,840 --> 00:20:53,080
+2O3 بنعوض محل ال ironاللي موجود فيصير اتنين ميلي
+
+245
+00:20:53,080 --> 00:20:56,160
+مول ايرون تو او ثري بساوي ستة ميلي مول باي كرو ميت
+
+246
+00:20:56,160 --> 00:20:58,760
+هذه معادلة stoichiometric equation يعني معادلة
+
+247
+00:20:58,760 --> 00:21:07,200
+بنعملها بسهولة سهلة المفروض وين ستة ايرون؟
+
+248
+00:21:07,200 --> 00:21:18,220
+هذه؟ هذه اتنين كيف هي ستة ستة؟ هذه؟ هذه المعادلة
+
+249
+00:21:23,580 --> 00:21:27,860
+هذه ستة ايرون ذات دايكرومات عدد ملي مولات الايرون
+
+250
+00:21:27,860 --> 00:21:31,220
+ستة امثال دايكرومات الملي مولات الايرون ستة امثال
+
+251
+00:21:31,220 --> 00:21:31,920
+دايكرومات
+
+252
+00:21:36,160 --> 00:21:41,380
+بنقول الميلي مول ايرون بيساوي 2 ميلي مول ايرون 2
+
+253
+00:21:41,380 --> 00:21:44,980
+او 3 بنعوض عنها 2 ميلي مول ايرون 2 او 3 محل الميلي
+
+254
+00:21:44,980 --> 00:21:48,340
+مول ايرون بيساوي 6 ميلي مول بيجروميت الان السؤال
+
+255
+00:21:48,340 --> 00:21:52,320
+ايش بدنا نعوض عن الميلي مول ايرون 2 او 3 ميلي جرام
+
+256
+00:21:52,320 --> 00:21:55,340
+على الفورمولا 8 مفهوم ميلي جرام على الفورمولا 8
+
+257
+00:21:55,340 --> 00:21:59,820
+طيب هان الميلي مول molarity ب volume ال molarity
+
+258
+00:21:59,820 --> 00:22:05,330
+هي عبارة عن5.442 اجرام ع اللتر بديها مول ع اللتر
+
+259
+00:22:05,330 --> 00:22:09,890
+ايش بسوي بجسم على الفورمولات تتحول ل مول ع اللتر
+
+260
+00:22:09,890 --> 00:22:14,500
+صارت molarityدربت في ايه؟ كتب هلاك بلون مختلف، في
+
+261
+00:22:14,500 --> 00:22:18,180
+واحد، في واحد، ايش واحد؟ ال volume مل، ليه؟ لأن
+
+262
+00:22:18,180 --> 00:22:21,420
+انا بيده أطلع ال milligram من ال iron 2 O3 اللي
+
+263
+00:22:21,420 --> 00:22:24,760
+بتتفعل مع كم مل؟ مع واحد مل، عشان ايه، هذا هو
+
+264
+00:22:24,760 --> 00:22:28,740
+تعريف التايتر، هذا هو تعريف التايتر، اذا ال volume
+
+265
+00:22:28,740 --> 00:22:32,670
+اللي عندي اللي بتتعود عنه في المعادلة ايه؟ شو؟واحد
+
+266
+00:22:32,670 --> 00:22:36,890
+ليش واحد؟ لأنه انا بدي اتتيتر اتتيتر عدد ميلي
+
+267
+00:22:36,890 --> 00:22:40,550
+جرامات ال iron 203 اللى بتتفاعل معاه او correspond
+
+268
+00:22:40,550 --> 00:22:46,010
+to one mil من ال diachromate يبقى بدك تتذكر ان ال
+
+269
+00:22:46,010 --> 00:22:49,030
+volume اللى عندك واحد ماحدش يسألني عن ال volume في
+
+270
+00:22:49,030 --> 00:22:52,770
+الامتحان شو؟ ال volume عندك واحدبتبدأ بتجيب التيتر
+
+271
+00:22:52,770 --> 00:22:56,010
+ال volume واحد لإنك بدك تجيب عدد الميلي جرامات
+
+272
+00:22:56,010 --> 00:23:00,970
+اللى بتتفاعل مع أكمل مع واحد مل من التيتر فالميلي
+
+273
+00:23:00,970 --> 00:23:06,110
+جرام iron 203 بتطلع 8.86 ميلي جرام بمعنى إنه لو
+
+274
+00:23:06,110 --> 00:23:10,950
+معايرة ماأخدت عشرة مل من الـ Bicromate هذا معناته
+
+275
+00:23:10,950 --> 00:23:16,750
+أكم ميلي جرام Iron 2 أو 3 عندي 88.6 من عشرة هذا هو
+
+276
+00:23:16,750 --> 00:23:20,090
+مفهوم الـ Titer كتير بنحب نجيبه في الامتحان مش
+
+277
+00:23:20,090 --> 00:23:25,070
+لأنه يعني موضوع كبير لكن في الحقيقة كمفهوم بيسهل
+
+278
+00:23:25,070 --> 00:23:28,510
+علينا لدرجة كبيرة الحسابات اللي بنعملها وبيوفر
+
+279
+00:23:28,510 --> 00:23:33,150
+وجهة عشان هيك بهمنا نسألك عنه ونتأكد إنك بتعرف إيش
+
+280
+00:23:33,150 --> 00:23:38,790
+مفهوم الـ Titerالان يا شباب بننتقل ل chapter جديد
+
+281
+00:23:38,790 --> 00:23:43,890
+general concepts of chemical equilibrium الفهم
+
+282
+00:23:43,890 --> 00:23:52,550
+العام له الإتزان الكيميائي احنا قلنا انه في عندنا
+
+283
+00:23:52,550 --> 00:23:59,190
+أنواع أسئلة تتمثل فيه بشكل أساسي نوعين من أنواع
+
+284
+00:23:59,190 --> 00:24:07,830
+الحسابات حسابات stoichiometricكمية و حسابات اتزان
+
+285
+00:24:07,830 --> 00:24:13,530
+فالحسابات الكمية اتعرفنا كيف نجريها في الشقر
+
+286
+00:24:13,530 --> 00:24:17,490
+الماضي الان بدنا نطلع على الحسابات اللي تستخدم
+
+287
+00:24:17,490 --> 00:24:23,330
+الاتزان و عموما لما نتكلم عن الاتزان بنتكلم عن
+
+288
+00:24:23,330 --> 00:24:30,330
+تفاعل كيميائي لا يتم بنسبة 100% تفاعل كيميائي لا
+
+289
+00:24:30,330 --> 00:24:35,330
+يتم بنسبة 100% تفاعلات نوعينو احنا دائما يمكن بنحط
+
+290
+00:24:35,330 --> 00:24:40,870
+.. بنجسم الأشياء لقسمين عشان يكون حفظها أسهل و
+
+291
+00:24:40,870 --> 00:24:43,990
+استيعابها كمان أسهل شوفنا مثلا ال errors
+
+292
+00:24:43,990 --> 00:24:50,490
+determined و indeterminate شوفنا .. حتى كمان طلعت
+
+293
+00:24:50,490 --> 00:24:53,390
+معانا يعنيالملي مول ميلي جرام على ال formula
+
+294
+00:24:53,390 --> 00:24:56,710
+weight او moderative volume حاجتين ال equilibrium
+
+295
+00:24:56,710 --> 00:25:04,630
+بنقول والله تفاعل تم وتفاعل غير تم تفاعل تم هذا
+
+296
+00:25:04,630 --> 00:25:07,830
+مالوش تعوى في ال equilibrium تفاعل بيتم بنسبة 100%
+
+297
+00:25:07,830 --> 00:25:12,490
+بنقول تفاعل تم تفاعل غير تم هذا هو تفاعل الاتزان
+
+298
+00:25:12,490 --> 00:25:18,550
+يعني تفاعل لا يتم بنسبة 100% زي مثلاا مول من ا
+
+299
+00:25:18,550 --> 00:25:24,050
+بتفعل مع ب مول من ب بيعطينا c مول من c وd مول من d
+
+300
+00:25:24,050 --> 00:25:27,270
+بقول بقدر اكتب ال equilibrium constant واطلع عليه
+
+301
+00:25:27,270 --> 00:25:33,020
+ال concentration ل النواتج كل واحد مرفوع لهEOS
+
+302
+00:25:33,020 --> 00:25:36,280
+بساوية عدد المولات تبعته على ال concentrations
+
+303
+00:25:36,280 --> 00:25:41,780
+للمتفاعلات كل متفاعل مرفوع له EOS بساوية عدد
+
+304
+00:25:41,780 --> 00:25:47,200
+مولاته فهذا ال equilibrium constant لأنه بيستخدم
+
+305
+00:25:47,200 --> 00:25:52,540
+ال concentrations فهو يسمى concentration
+
+306
+00:25:52,540 --> 00:25:56,260
+equilibrium constantلأنه بيستخدم ال concentrations
+
+307
+00:25:56,260 --> 00:26:01,360
+يسمى ايه؟ concentration equilibrium constant في
+
+308
+00:26:01,360 --> 00:26:06,500
+الحقيقة التفاعل لما A بتفاعل مع B بيعطينا C وD هنا
+
+309
+00:26:06,500 --> 00:26:11,080
+التفاعل بيمشي أول حاجة يمشي سريع لإن التركيزات
+
+310
+00:26:11,080 --> 00:26:16,260
+بتكون كبيرة بعدين لغاية ما يوصل لنقطة معينة بنلاحظ
+
+311
+00:26:16,260 --> 00:26:21,530
+إنه وكأنه متوقفو كأنه خلص لكن يا شباب هو لأ بكونش
+
+312
+00:26:21,530 --> 00:26:24,290
+بخلص ال equilibrium اللي عندنا هو dynamic
+
+313
+00:26:24,290 --> 00:26:29,670
+equilibrium يعني اتزان ديناميكي بمعنى أنه سرعة
+
+314
+00:26:29,670 --> 00:26:34,010
+التفاعل في الاتجاه الأمامي تساوي سرعة التفاعل في
+
+315
+00:26:34,010 --> 00:26:38,570
+الاتجاه الخلفي أو المعاكس العكسي يعني التفاعل بيتم
+
+316
+00:26:38,570 --> 00:26:42,930
+بين a و b دائما بيعطينا c و d لكن في نفس الوقت c و
+
+317
+00:26:42,930 --> 00:26:46,800
+d بتفعل معاقطنا a و b بنفس السرعةفالسرعتين
+
+318
+00:26:46,800 --> 00:26:51,440
+متساويتين بنحسوا كأنه واجف لكن هو في الحقيقة لأ
+
+319
+00:26:51,440 --> 00:26:58,380
+عندي دائما ال equilibrium dynamic equilibrium طيب
+
+320
+00:26:58,380 --> 00:27:04,000
+فعنا إيش اللي بيحصل عادة لما إيه يتفاعل مع بيه
+
+321
+00:27:04,000 --> 00:27:08,800
+بقول بيحصل عنا أحد الأشكال اللي جدامي هذه ممكن
+
+322
+00:27:08,800 --> 00:27:14,370
+نطلع على اللي في النص بدايةهذا المتفاعلات مع الوجد
+
+323
+00:27:14,370 --> 00:27:18,210
+عامل إش بجرالها بتجل بتجل بتجل لغاية ما تقريبا
+
+324
+00:27:18,210 --> 00:27:22,430
+توصل إش قريب من الصفر مش صفر لو وصلت صفر بصير
+
+325
+00:27:22,430 --> 00:27:26,430
+تفاعل تام انتهى بصير تفاعل تام لكن لأ هي بتوصلش
+
+326
+00:27:26,430 --> 00:27:31,290
+صفر قريبة جدا من الصفر مثلا يعني يعني جدش طويل من
+
+327
+00:27:31,290 --> 00:27:37,030
+المتفاعلات جزء يسير جدا جدا لا يكاد يذكر قليل خالص
+
+328
+00:27:38,140 --> 00:27:41,880
+وفي نفس الوقت النواتج بتنمت بتنمت لغاية ما تجرب
+
+329
+00:27:41,880 --> 00:27:47,680
+على المية من ميةتجرب مش توصل، توصلش لأنه ضايل A وB
+
+330
+00:27:47,680 --> 00:27:52,900
+فلازم يكون C وD يعني مايوصلش 100 من 100 لما
+
+331
+00:27:52,900 --> 00:27:57,860
+المتفاعلات تجل توصل إش قريب من الصفر والنواتج
+
+332
+00:27:57,860 --> 00:28:02,540
+تزيد، إيش اللي بيحصل؟ لو إجينا بتطلعنا على النواتج
+
+333
+00:28:02,540 --> 00:28:06,760
+فوق في ال bus و المتفاعلات وين؟ في المقام النواتج
+
+334
+00:28:06,760 --> 00:28:10,720
+كبيرة خالص و المتفاعلات قليلة جدا كيف ال
+
+335
+00:28:10,720 --> 00:28:16,380
+equilibrium constant؟عالي كتير large large مش أكبر
+
+336
+00:28:16,380 --> 00:28:21,600
+واحد very large كويس very large طيب هذا نوع من
+
+337
+00:28:21,600 --> 00:28:26,100
+أنواع التفاعلات نوع من أنواع تفاعلات الإتزان انه
+
+338
+00:28:26,100 --> 00:28:28,960
+ال equilibrium constant بيكون كبير ليش بيكون كبير
+
+339
+00:28:28,960 --> 00:28:35,540
+لأن a و b بتفعلوا مع بعض وكميتهم بتقل إلى درجة
+
+340
+00:28:35,540 --> 00:28:41,250
+تقترب من الصفركويس بينما النواتج بتزيد درجة تقريب
+
+341
+00:28:41,250 --> 00:28:44,770
+من 100% هذا نوع النوع الآخر هو النوع اللي على
+
+342
+00:28:44,770 --> 00:28:52,770
+اليسار عيمينك يعني بيكون او بيدوب اللي بتفاعله
+
+343
+00:28:52,770 --> 00:28:56,150
+تفاعله جل .. يعني المتفاعله اتقلت بالنسبة ضائلة
+
+344
+00:28:56,150 --> 00:29:00,290
+للغاية يعني تقريبا كل المتفاعله اتبايلة زي ما هي
+
+345
+00:29:00,290 --> 00:29:03,610
+إلا جزء ياسير تفاعل الجزء الياسير اللي اتفاعل هذا
+
+346
+00:29:03,610 --> 00:29:09,680
+كون نواتج النواتج قريبة من الصفرالمتفاعلات قريبة
+
+347
+00:29:09,680 --> 00:29:13,660
+من 100% لما نيجي نقول والله المتفاعلات قريبة من
+
+348
+00:29:13,660 --> 00:29:16,760
+100% والنوتش قريبة من الصفر كيف ال equilibrium
+
+349
+00:29:16,760 --> 00:29:21,480
+constant صغير للغاية يعني هذا النوع التاني اما ان
+
+350
+00:29:21,480 --> 00:29:25,140
+ال equilibrium constant يكون large او اما انه يكون
+
+351
+00:29:25,140 --> 00:29:32,660
+small في يعني نوع تالت من التفاعلات والله a و b
+
+352
+00:29:32,660 --> 00:29:34,160
+بيجلوا
+
+353
+00:29:35,970 --> 00:29:44,310
+بدرجة ملحوظة و C و D بيزيدوا بدرجة ملحوظة أيضا
+
+354
+00:29:44,310 --> 00:29:48,590
+يعني حوالين بعض يعني A و B بيصير تجريبا تركيزاتهم
+
+355
+00:29:48,590 --> 00:29:54,260
+زي C و D تجريبا يعنيالاتنين موجودين بدرجة ايه؟
+
+356
+00:29:54,260 --> 00:29:57,560
+ملحوظة عشان هيك ال equilibrium constant في هذه
+
+357
+00:29:57,560 --> 00:30:02,860
+الحالة ايش بيكون؟ متوسط متوسط احنا يا شباب معنى
+
+358
+00:30:02,860 --> 00:30:05,440
+الكلام في عندنا تلت انواع من انواع ال equilibrium
+
+359
+00:30:05,440 --> 00:30:10,010
+constantحسب ال equilibrium constant اللي عندي بدي
+
+360
+00:30:10,010 --> 00:30:14,990
+استخدم طريقة الحل يبقى طريقة الحل هتعتمد على ايه؟
+
+361
+00:30:14,990 --> 00:30:19,590
+على قيمة ال equilibrium constant هل هو كبير صغير
+
+362
+00:30:19,590 --> 00:30:27,130
+ولا متوسط احنا علشان نسهل الأمور علينا هنقول لأ
+
+363
+00:30:27,130 --> 00:30:30,350
+بدناش ناخد تلت حالات و بدناش ناخد تلت حالات في
+
+364
+00:30:30,350 --> 00:30:37,130
+الحل بدنا ناخد حاجتين فقط زيما اتعودنا تفاعل تم او
+
+365
+00:30:37,130 --> 00:30:40,330
+غير تم determinant error و indeterminant error
+
+366
+00:30:40,330 --> 00:30:42,870
+حاجتين milligram ع ال formula wet or moderative
+
+367
+00:30:42,870 --> 00:30:47,150
+volume مثلا فبناخد برضه جسم بس من جسم هدول اتنين
+
+368
+00:30:47,150 --> 00:30:54,070
+فاش بقول و اسهل بيمكن بدي اقول بدي اخد الحالة اي
+
+369
+00:30:54,070 --> 00:30:57,970
+حالة جدامي بدي احطها ضمن حالتين هل ال equilibrium
+
+370
+00:30:57,970 --> 00:31:05,970
+constant كبير او ان ال equilibrium constant ايهمش
+
+371
+00:31:05,970 --> 00:31:13,090
+كبير، يا كبير، يا إما مش كبير، يا كبير، يا إما،
+
+372
+00:31:13,090 --> 00:31:16,270
+ماليش دي علاقة هدا الكلام، يا كبير يعني أكبر من
+
+373
+00:31:16,270 --> 00:31:20,130
+عشر أقصى اتنين مثلا، أكبر من مية، يا إما مش كبير،
+
+374
+00:31:20,130 --> 00:31:24,390
+مش كبير يعني أقل من عشر أقصى اتنينمعايا انتوا؟ هيك
+
+375
+00:31:24,390 --> 00:31:27,290
+أسهل ليه؟ يفجأة أنا بدي حل على أساس ال equilibrium
+
+376
+00:31:27,290 --> 00:31:32,150
+tool طالع ليه؟ هل هو كبير، إله طريقة حل، مش كبير،
+
+377
+00:31:32,150 --> 00:31:36,350
+إله طريقة أخرى في الحل، يفجأة هيك جمعت الصغير و
+
+378
+00:31:36,350 --> 00:31:41,130
+المتوسط مع بعض، بس عندي حالتين، يا كبير يا مش
+
+379
+00:31:41,130 --> 00:31:44,250
+كبير، كبير إله طريقة في الحل، مش كبير إيش إله
+
+380
+00:31:44,250 --> 00:31:50,320
+طريقة أخرى في الحلماشي يا شباب اذا حل اي مسألة
+
+381
+00:31:50,320 --> 00:31:53,440
+equilibrium بمجرد مشوف المسألة بدي اطلع ال
+
+382
+00:31:53,440 --> 00:31:56,960
+equilibrium constant و اقرر هل ال equilibrium
+
+383
+00:31:56,960 --> 00:32:02,500
+constant كبير ولا مش كبير؟ ايش يعني كبير؟ جال يعني
+
+384
+00:32:02,500 --> 00:32:07,680
+اكبر من 10 أقصى 2 مثلا و انا بأرجو انك في اخر يعني
+
+385
+00:32:07,680 --> 00:32:12,760
+الفصل على الأقل تستوعب ليش الأستاذ جال 10 أقصى 2؟
+
+386
+00:32:12,760 --> 00:32:17,000
+هذا من عنديبنعندي يعني كتير من الكتب ممكن تحددك
+
+387
+00:32:17,000 --> 00:32:23,020
+أرقام ل .. يعني equilibrium constants حسب نوعها
+
+388
+00:32:23,020 --> 00:32:26,740
+مثلا اللي هو acid base اللي هو وغيره بتحدد أرقام
+
+389
+00:32:26,740 --> 00:32:30,020
+معينة بتلاقي مرة عشر أقص أربعة مرة عشر أقص تلاتة
+
+390
+00:32:30,020 --> 00:32:34,780
+عشر مرة عشر أقص يعني حاجات مختلفة لكن لأ احنا انا
+
+391
+00:32:34,780 --> 00:32:37,760
+بالنسبالي بقول عشر أقص اتنين هذا يعتبر عندي كبير
+
+392
+00:32:39,690 --> 00:32:44,630
+أقل منه، والله هذا مش كبير، يبقى بتطلع على ال
+
+393
+00:32:44,630 --> 00:32:47,730
+equilibrium constant وبحدد طريقة الحل بناء على
+
+394
+00:32:47,730 --> 00:32:52,670
+قيمة ال equilibrium constantإيش أنواع الـ
+
+395
+00:32:52,670 --> 00:32:55,490
+Equilibrium اللي هنتطلع عليها؟ بقول فيها إن عدة
+
+396
+00:32:55,490 --> 00:33:00,230
+أنواع من أنواع الـ Equilibrium اللي هنواجهها خلال
+
+397
+00:33:00,230 --> 00:33:05,470
+دراستنا في هذا الفصل فمن أهم الأنواع و أبسطها يعني
+
+398
+00:33:05,470 --> 00:33:08,690
+هي كلها إيه لها نفس طريقة الحل يعني يعني أنا
+
+399
+00:33:08,690 --> 00:33:13,850
+بهمنيش إيش النوع يكون عشان أحل وهي الاشي الجوهري
+
+400
+00:33:13,850 --> 00:33:19,150
+اللي إحنا بدنا نحاول نتعلمه بهمنيش إيش هو التفاعل
+
+401
+00:33:19,150 --> 00:33:24,100
+إيش هو ال equilibriumهل هو acid base و لا
+
+402
+00:33:24,100 --> 00:33:26,800
+solubility و لا complex formation و لا oxidation
+
+403
+00:33:26,800 --> 00:33:30,260
+reduction و لا غيره بهمنيش اللي بيهمني هل ال
+
+404
+00:33:30,260 --> 00:33:35,060
+equilibrium constant كبير و لا مش كبير بس لكن ايش
+
+405
+00:33:35,060 --> 00:33:39,840
+طبيعة التفاعل ما بيهمني مش فارق كلها واحد علشان
+
+406
+00:33:39,840 --> 00:33:42,300
+هيك زي ما كنا بنقول في ال stoichiometric
+
+407
+00:33:42,300 --> 00:33:45,140
+calculations مجرد انه اخدنا ال chapter هذا
+
+408
+00:33:45,140 --> 00:33:52,130
+القادرين على حل اي سؤالQuantitative فإحنا لازم
+
+409
+00:33:52,130 --> 00:33:55,410
+نكون قادرين على حل أي سؤال في ال equilibrium بعد
+
+410
+00:33:55,410 --> 00:33:58,430
+ما نخلص ال chapter هذي اللي هو قصير يعني محاضرتين
+
+411
+00:33:58,430 --> 00:34:03,190
+إذا كان الله راد قصير جدا في الحقيقة فبقول أنواع
+
+412
+00:34:03,190 --> 00:34:06,130
+ال equilibrium اللي هندرسها هندرس ال acid base
+
+413
+00:34:06,130 --> 00:34:10,870
+equilibrium إيش يعني؟ يعني ال acids الضعيفة
+
+414
+00:34:13,150 --> 00:34:17,510
+أه هذه بتتفكك و ال bases الضعيفة أيضا في الميه
+
+415
+00:34:17,510 --> 00:34:22,350
+بتتفكك فبتعطينا نواتج و لل acid ضعيف و ال base
+
+416
+00:34:22,350 --> 00:34:28,480
+ضعيف لكل واحد له ايه ثابت اتزان حسب ضعفهكل مكان
+
+417
+00:34:28,480 --> 00:34:36,240
+أقوى كل مكان ثابت الإتزان له أعلى لدرجة
+
+418
+00:34:36,240 --> 00:34:40,360
+أنه لما نصبح قوى لا نكتب ثابت الإتزان لأن ثابت
+
+419
+00:34:40,360 --> 00:34:44,100
+الإتزان يساوي النواتج على المتفاعلات لما نكون قوى
+
+420
+00:34:44,100 --> 00:34:48,380
+نتفكك نسبة 100% لا نقدر نبقى من المتفاعلات سفر
+
+421
+00:34:48,380 --> 00:34:52,540
+يعني نكتب infinity نواتج على سفر عشان لا نكتبها
+
+422
+00:34:52,540 --> 00:34:59,680
+فكل مزاد ال equilibrium constant كل مكان أقوىممكن
+
+423
+00:34:59,680 --> 00:35:04,140
+اول شي بنقول ال acids و ال bases هذه شغلات معروفة
+
+424
+00:35:04,140 --> 00:35:08,940
+حاجة تانية Solubility Equilibria كتير من المواد
+
+425
+00:35:08,940 --> 00:35:12,780
+اللي احنا بتعامل معهالا تذوب دوبان كامل في الميّه
+
+426
+00:35:12,780 --> 00:35:18,960
+يعني ممكن بعض هيذوب يعني دوبان بسيط زي مثلا الصخور
+
+427
+00:35:18,960 --> 00:35:25,920
+وكلنا بنعرف مجاري الأنهار تكونت عبر آلاف السنين من
+
+428
+00:35:25,920 --> 00:35:29,720
+جريان الأنهار في هذه الصخور لما تيجي تجيب صخرة و
+
+429
+00:35:29,720 --> 00:35:33,240
+تحطها في الميه بتدوبش، بتدوب على هذه بتدوبش لكن هل
+
+430
+00:35:33,240 --> 00:35:37,260
+هي بالفعل بتدوبش؟ لأ، هي بتدوب جزءيا لغاية ما يصير
+
+431
+00:35:37,260 --> 00:35:42,070
+فيه نوع من الإتزانلكن ثابت الاتزان ايش ماله؟ قليل
+
+432
+00:35:42,070 --> 00:35:49,050
+يعني بده وقت طويل جدا جدا جدا علشان الصخر هذا يدوب
+
+433
+00:35:49,050 --> 00:35:54,270
+لأنه الميه الجارية بتحمل الايونات والميه الجديدة
+
+434
+00:35:54,270 --> 00:35:58,510
+بتخلي الصخر يذوب بنسبة ال equilibrium constant او
+
+435
+00:35:58,510 --> 00:36:02,570
+بدرجة ال equilibrium constant فالدوبان مستمرعبر
+
+436
+00:36:02,570 --> 00:36:07,010
+آلاف السنين بنلاحظ أنه بتتكون مجرد أنهار في الصخور
+
+437
+00:36:07,010 --> 00:36:12,710
+بعض الأنهار اللي بتعد من مثلا الجبال بتلاحظ فيها
+
+438
+00:36:12,710 --> 00:36:17,890
+صار زي الكهوف شغلة جميلة للغاية يعني ممكن نطلع
+
+439
+00:36:17,890 --> 00:36:24,950
+عليها النوع التالت من ال equilibriumبنطلع على الـ
+
+440
+00:36:24,950 --> 00:36:28,950
+Complex Formation Equilibria وفي هذه الحالة بنتطلع
+
+441
+00:36:28,950 --> 00:36:35,510
+على Metal Ions بتتفاعل مع Ligands الـ Ligand هو
+
+442
+00:36:35,510 --> 00:36:39,470
+عبارة عن مادة بتتفاعل مع Metal Ions، هناخد Chapter
+
+443
+00:36:39,470 --> 00:36:41,250
+كامل على هذا الكلام
+
+444
+00:36:44,790 --> 00:36:50,570
+فثابت التكوين بيكونش يعني بدرجة 100% يعني ال
+
+445
+00:36:50,570 --> 00:36:54,070
+legend لا تفاعل مع ال metal ion بنسبة 100% لأ
+
+446
+00:36:54,070 --> 00:37:00,590
+بتفاعل بدرجة عالية نعمبكون complex نعم لكن مش 100%
+
+447
+00:37:00,590 --> 00:37:03,950
+لأ بضال جزء من ال metal iron جزء من ال legend مش
+
+448
+00:37:03,950 --> 00:37:08,030
+متفاعل او انه لو عند ال metal legend complex
+
+449
+00:37:08,030 --> 00:37:14,130
+فبلاحظ انه بيتفكك جزئيا لبعض ال metal و بعض ال
+
+450
+00:37:14,130 --> 00:37:18,950
+legendفهذا نوع تالت من أنواع الـ Equilibria النوع
+
+451
+00:37:18,950 --> 00:37:22,630
+الرابع اللي هندرسه ال Oxidation Reduction
+
+452
+00:37:22,630 --> 00:37:26,010
+Equilibria فيه مادة Oxidized اتفاعل مع مادة
+
+453
+00:37:26,010 --> 00:37:30,610
+Reduced ال Oxidized بحصلها اختزال والمختزلة ال
+
+454
+00:37:30,610 --> 00:37:35,230
+Reduced بحصلها اكسدة برضه هذا تفاعل ممكن انه يكون
+
+455
+00:37:35,230 --> 00:37:40,060
+تفاعل اتزانالنوع الأخير من الإتزانات اللي يعني
+
+456
+00:37:40,060 --> 00:37:42,760
+موجودة عندنا في ال slide على الأقل اللي هو حاجة
+
+457
+00:37:42,760 --> 00:37:47,500
+نقولها phase distribution لما يكون في عندك organic
+
+458
+00:37:47,500 --> 00:37:52,860
+phase و aqueous phase و في عندك مادة روحت خبيت هذه
+
+459
+00:37:52,860 --> 00:37:58,680
+المادة في ال organic و ال aqueous phase مع بعض
+
+460
+00:37:58,680 --> 00:38:02,680
+بتلاحظ ان هذه المادة بتتجزأحسب حبها لل organic وال
+
+461
+00:38:02,680 --> 00:38:06,500
+aqueous phase فإذا كان خصائصها قريبة من خصائص ال
+
+462
+00:38:06,500 --> 00:38:10,980
+organic بتروح وين؟ على ال organic phase على الطبقة
+
+463
+00:38:10,980 --> 00:38:15,040
+ال organic إذا كان خصائصها قريبة من خصائص ال
+
+464
+00:38:15,040 --> 00:38:20,220
+aqueous phaseمعظمها بيكون في الـ aqueous phase،
+
+465
+00:38:20,220 --> 00:38:25,040
+لكن الشاهد أنه مش كلها بتنتقل للـ aqueous ومش كلها
+
+466
+00:38:25,040 --> 00:38:30,880
+بتنتقل لل organic، لأ جزئيا، ممكن الجزء هذا يكون
+
+467
+00:38:30,880 --> 00:38:35,650
+واحد من الف في المية، لكنه موجودممكن يكون قليل جدا
+
+468
+00:38:35,650 --> 00:38:40,670
+لكنه موجود لكن هذا النوع الأخير احنا مش رايحين
+
+469
+00:38:40,670 --> 00:38:45,690
+ندرسه في هذا ال course يعني ال phase distribution
+
+470
+00:38:45,690 --> 00:38:49,990
+مش هيكون معنى ضمن الحاجات اللي هندرسها في هذا ال
+
+471
+00:38:49,990 --> 00:38:56,530
+course طيب يا شباب كيف احنا بنحسب ال equilibrium
+
+472
+00:38:56,530 --> 00:39:02,210
+constant؟ كيف بنحسبه؟بنقول والله احنا توي شفنا ال
+
+473
+00:39:02,210 --> 00:39:06,190
+equilibrium constant ما هو الا عبارة عن تركيزات A
+
+474
+00:39:06,190 --> 00:39:10,710
+وB وC وD مجسمين على بعض بشكل معين Equals فممكن لو
+
+475
+00:39:10,710 --> 00:39:14,830
+انا عارف او ممكن اقدر احسب تركيز A و تركيز B و
+
+476
+00:39:14,830 --> 00:39:18,050
+تركيز C و تركيز D عند الاتزان وباجي باجسمهم على
+
+477
+00:39:18,050 --> 00:39:20,770
+بعض حسب ال equilibrium constant بتطلع لقيمة ال
+
+478
+00:39:20,770 --> 00:39:24,090
+equilibrium constant اللي هو بسميه concentration
+
+479
+00:39:24,090 --> 00:39:29,800
+equilibrium constant ممكن ولا مش ممكن؟ممكن فش
+
+480
+00:39:29,800 --> 00:39:35,900
+مشكلة لكن في عندنا equilibrium constant يمكن حسابه
+
+481
+00:39:35,900 --> 00:39:39,680
+مباشرة من ال thermodynamics لأنه احنا بنعرف انه
+
+482
+00:39:39,680 --> 00:39:43,660
+أخدنا في سنة أولى و أخدنا أسئلة كمان عليها في
+
+483
+00:39:43,660 --> 00:39:47,100
+الامتحان جالنا أسئلة عليها أيضا انا عند ال gypsy
+
+484
+00:39:47,100 --> 00:39:51,890
+free energy بتساوية delta H minus T delta Sلو جاء
+
+485
+00:39:51,890 --> 00:39:54,810
+نتكلم عن gives free energy في ال standard state
+
+486
+00:39:54,810 --> 00:39:59,510
+فبنقول delta g note بدها تساوي ال delta h note
+
+487
+00:39:59,510 --> 00:40:04,350
+minus T delta s note حطينا note هنا إذا لازم نحط
+
+488
+00:40:04,350 --> 00:40:07,290
+note هنا و note هنا لأن دول كلهم يعتبروا state
+
+489
+00:40:07,290 --> 00:40:11,710
+functions فال delta g note بتساوي ال delta h note
+
+490
+00:40:11,710 --> 00:40:16,190
+minus T delta s noteطب الـ delta G not مش مر معنا
+
+491
+00:40:16,190 --> 00:40:21,010
+سابقا كمان ان هي بتساوي minus RT لن ال K حيث ال K
+
+492
+00:40:21,010 --> 00:40:24,810
+هو ال equilibrium constant طبعا مرات معانا اذا ال
+
+493
+00:40:24,810 --> 00:40:29,950
+equilibrium constant ايش بيساوي E أُس سالب delta G
+
+494
+00:40:29,950 --> 00:40:33,930
+not على ال RT ندبه شوية ايش K قال هي ال
+
+495
+00:40:33,930 --> 00:40:37,230
+equilibrium constant يعني لو كان في عندي تفاعل A
+
+496
+00:40:37,230 --> 00:40:42,590
+وB بيعطوني C وD مثلاوانا حبيت ان احسب ال
+
+497
+00:40:42,590 --> 00:40:45,330
+equilibrium constant هتفعل و أجيب ال delta G not
+
+498
+00:40:45,330 --> 00:40:49,830
+إذا كان ال delta G not معايا و بقدر أحسبها انا من
+
+499
+00:40:49,830 --> 00:40:54,610
+ال delta H not minus T delta S not بقدر أحسبها ال
+
+500
+00:40:54,610 --> 00:40:59,190
+R ثابت والT ثابت إذا بقدر أحسب ال A ال K بمعلومية
+
+501
+00:40:59,190 --> 00:41:02,210
+ال delta G not اللي هي تعتبر thermodynamic
+
+502
+00:41:02,210 --> 00:41:06,820
+function بقدر أجيبها بسهولةطيب اذا هذا ال
+
+503
+00:41:06,820 --> 00:41:10,740
+equilibrium constant بقدر اقولكم حاجة عنه بقدر
+
+504
+00:41:10,740 --> 00:41:13,340
+اقول ان هذا ال equilibrium constant احنا حصلنا
+
+505
+00:41:13,340 --> 00:41:17,120
+عليه من ال thermodynamic equations من ال
+
+506
+00:41:17,120 --> 00:41:21,220
+thermodynamics عشان هيك اسمه thermodynamic
+
+507
+00:41:21,220 --> 00:41:25,520
+equilibrium constantاسم ال equilibrium constant
+
+508
+00:41:25,520 --> 00:41:28,320
+هذا اللي بحصل عليه من ال thermodynamics بسميه
+
+509
+00:41:28,320 --> 00:41:32,580
+thermodynamic equilibrium constant هل يختلف عن ال
+
+510
+00:41:32,580 --> 00:41:37,760
+concentration equilibrium constant ولا بيسوي؟ هداك
+
+511
+00:41:37,760 --> 00:41:40,200
+حصلت عليه من ال concentrations وهذا حصلت عليه من
+
+512
+00:41:40,200 --> 00:41:44,560
+ال thermodynamic equations بقول إنه في بعض الأحيان
+
+513
+00:41:44,560 --> 00:41:48,640
+أو ضمن شروط معينة بيسوي لكن ضمن شروط .. إذا اختلت
+
+514
+00:41:48,640 --> 00:41:54,560
+هذه الشروط لأ بيسويغوشإذا .. إذا بقول ضمن شروط
+
+515
+00:41:54,560 --> 00:41:58,080
+معينة هندوسها .. هندوسها لكن في آخر ال chapter ضمن
+
+516
+00:41:58,080 --> 00:42:02,780
+شروط معينة ال thermodynamic equilibrium constant
+
+517
+00:42:02,780 --> 00:42:06,340
+هذا اللي جدامي يساوي ال concentration equilibrium
+
+518
+00:42:06,340 --> 00:42:12,130
+constantلكن ضمن شروط مغايرة، الإثنين مختلفين عن
+
+519
+00:42:12,130 --> 00:42:18,690
+بعض وبالتالي هذا إله إعكاسات مهمة جدا على دراستنا
+
+520
+00:42:18,690 --> 00:42:23,070
+في الكيميا التحليلية لكن هنشوف هذا الكلام في آخر
+
+521
+00:42:23,070 --> 00:42:32,770
+الشابتر إذا الله راني ممكن نتكلم برضه عن موضوع مر
+
+522
+00:42:32,770 --> 00:42:38,670
+معنى سابقا let Chatelet Principlesهو مبادئ لتشت
+
+523
+00:42:38,670 --> 00:42:44,070
+ليه؟ ايش مبادئ لتشت ليه؟ قال والله هي العوامل اللي
+
+524
+00:42:44,070 --> 00:42:50,130
+بتأثر على ال equilibrium العوامل اللي بتأثر على ال
+
+525
+00:42:50,130 --> 00:42:53,610
+equilibrium هناك عوامل بتأثر على ال equilibrium
+
+526
+00:42:53,610 --> 00:42:55,650
+انا عندي equilibrium، انا عندي تفاعل مافي
+
+527
+00:42:55,650 --> 00:43:02,090
+equilibrium، كويس، لو أثرت عليه بمؤثر خارجيلو أثرت
+
+528
+00:43:02,090 --> 00:43:07,070
+عليه مؤثر خارجي بلاحظ إن ال equilibrium هذا يعني
+
+529
+00:43:07,070 --> 00:43:13,230
+بيتأثر بحيث إنه يحاول أن يلاشي تأثير المؤثر
+
+530
+00:43:13,230 --> 00:43:17,710
+الخارجي يعني بيمشي في اتجاه بحيث إنه يحاول يلاشي
+
+531
+00:43:17,710 --> 00:43:22,850
+تأثير المؤثر الخارجي إذا الله أراد الحصة الجاية
+
+532
+00:43:22,850 --> 00:43:26,890
+هنتكلم عن Le Chatelet Principle
+
diff --git a/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/Lm8jGs0R1aI_raw.srt b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/Lm8jGs0R1aI_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..4aff2659fa52c82f300fcfa14aff3848cc4c17a1
--- /dev/null
+++ b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/Lm8jGs0R1aI_raw.srt
@@ -0,0 +1,2336 @@
+1
+00:00:20,770 --> 00:00:23,410
+بسم الله الرحمن الرحيم الحمد لله و الصلاة والسلام
+
+2
+00:00:23,410 --> 00:00:28,510
+على رسول الله الحصة الماضية شباب بدنا نتكلم عن ال
+
+3
+00:00:28,510 --> 00:00:32,010
+propagation of error و اتكلمنا عن ال addition و ال
+
+4
+00:00:32,010 --> 00:00:35,590
+subtraction في حالة ما يكون في عندىفي النتيجة
+
+5
+00:00:35,590 --> 00:00:41,350
+uncertainty فلو في واندي uncertainty في نتائج ما
+
+6
+00:00:41,350 --> 00:00:45,610
+هو حبيت ان اجمع او اطرح قولنا ال absolute numbers
+
+7
+00:00:45,610 --> 00:00:52,690
+النتائج ال absolute تجمع و تطرح بشكل طبيعي فحسب
+
+8
+00:00:52,690 --> 00:00:56,170
+القوانين اللي اتعلمناها نتطلع ايش فيها على يمين ال
+
+9
+00:00:56,170 --> 00:00:59,830
+decimal point في الأعشار او في جزء من مية او جزء
+
+10
+00:00:59,830 --> 00:01:06,820
+من الف والاقلعدد من ال digits بيكون الجواب مبني
+
+11
+00:01:06,820 --> 00:01:10,680
+عليه أو ممكن والأقل precision أو الأعلى
+
+12
+00:01:10,680 --> 00:01:13,860
+uncertainty هو اللي بيحكم عدد ال significant
+
+13
+00:01:13,860 --> 00:01:17,260
+figures اللي في الجواب فيما يتعلق بال absolute
+
+14
+00:01:17,260 --> 00:01:22,340
+number لكن فيما يتعلق بال uncertainty اتفاجنا على
+
+15
+00:01:22,340 --> 00:01:26,040
+ان ال uncertainty في ال answer as a بتساوي الجزر
+
+16
+00:01:26,040 --> 00:01:29,400
+التربيعيالـ uncertainty تربيع في الأول زائد ال
+
+17
+00:01:29,400 --> 00:01:31,800
+uncertainty تربيع في التاني زائد ال uncertainty
+
+18
+00:01:31,800 --> 00:01:36,620
+تربيع في التالت إلى آخرها فإيها طريقة في الحساب و
+
+19
+00:01:36,620 --> 00:01:40,600
+أخدنا مثال على هذا النوع من الحسابات اليوم نتكلم
+
+20
+00:01:40,600 --> 00:01:44,900
+عن ال multiplication و ال divisionبنقول إنه في
+
+21
+00:01:44,900 --> 00:01:47,200
+حالة ال multiplication و ال division و اللي هي
+
+22
+00:01:47,200 --> 00:01:50,720
+حالة تقريبا يعني بتمر معنى بشكل كبير في الكيما
+
+23
+00:01:50,720 --> 00:01:55,200
+التحليلية زي ما هنشوف برضه بعض الأمثلة بعد شوية
+
+24
+00:01:55,200 --> 00:02:01,080
+بنقول إنه للأسف بقدرش أحسب ال S A مباشرة لأ بقدرش
+
+25
+00:02:01,080 --> 00:02:05,540
+أحسب ال absolute uncertainty مباشرة كما كنت أفعل
+
+26
+00:02:05,540 --> 00:02:09,500
+ذلك يعني في حالة ال addition و ال subtraction هكذا
+
+27
+00:02:09,500 --> 00:02:15,000
+جال في البداية بحسب حاجة بقولها S A relativeاس اي
+
+28
+00:02:15,000 --> 00:02:19,120
+relative ايش الاس اي relative؟ الاس اي relative هي
+
+29
+00:02:19,120 --> 00:02:24,900
+ال relative uncertainty في ال answer ايش بتساوي؟
+
+30
+00:02:24,900 --> 00:02:30,240
+بتساوي ال uncertainty المحسوبة الاس اي ال absolute
+
+31
+00:02:30,240 --> 00:02:34,540
+uncertainty على ال answerعلى ال answer فأي
+
+32
+00:02:34,540 --> 00:02:38,120
+relative uncertainty إيش هي؟ هي عبارة عن ال
+
+33
+00:02:38,120 --> 00:02:41,620
+uncertainty في القيمة على القيمة هذه اسمها
+
+34
+00:02:41,620 --> 00:02:45,920
+relative uncertainty ففي البداية بحسب ال relative
+
+35
+00:02:45,920 --> 00:02:50,440
+uncertainty في ال answer بعدين بدرب هذه القيمة
+
+36
+00:02:50,440 --> 00:02:53,540
+اللي حصلت عليها في قيمة ال answer بتعطيني ال
+
+37
+00:02:53,540 --> 00:02:58,660
+absolute uncertainty الكلام كتير سهل لما نتطلع على
+
+38
+00:02:58,660 --> 00:03:07,020
+مثلا المسألة التاليةبقول find the result of the
+
+39
+00:03:07,020 --> 00:03:10,340
+following calculation using the correct number of
+
+40
+00:03:10,340 --> 00:03:13,840
+significant figures عندك ال calculation المطلوبة 2
+
+41
+00:03:13,840 --> 00:03:18,220
+.23 plus or minus 0.01 طبعا ال 0.01 هي ال
+
+42
+00:03:18,220 --> 00:03:26,780
+uncertainty في ال 2.23 ولاحظ أنه عندك رقمين عشرين
+
+43
+00:03:26,780 --> 00:03:33,940
+ال uncertainty برضه رقمين عشرينTimes 3.508 plus or
+
+44
+00:03:33,940 --> 00:03:41,260
+minus 0.007 طبعا هدول نتيجتين مضروبين في بعض بقول
+
+45
+00:03:41,260 --> 00:03:45,440
+الأرقام ال absolute absolute numbers اللي هو ال 2
+
+46
+00:03:45,440 --> 00:03:50,840
+.23 و ال 3.508 هدول يعني نفس المفاهيم اللي
+
+47
+00:03:50,840 --> 00:03:56,080
+اتعلمتها سابقا فاطبقها عليهم مضرب عادي فالنتيجة 7
+
+48
+00:03:56,080 --> 00:04:01,530
+.82الـ Uncertainty بقول والله S A اللي هي ال
+
+49
+00:04:01,530 --> 00:04:05,090
+absolute uncertainty في ال answer لكن للأسف كما
+
+50
+00:04:05,090 --> 00:04:08,910
+ذكرت لا نستطيع حساب ال absolute uncertainty بشكل
+
+51
+00:04:08,910 --> 00:04:12,790
+مباشر بحسب في البداية ال relative uncertainty ال
+
+52
+00:04:12,790 --> 00:04:17,510
+relative uncertainty بتساوي ال uncertainty في
+
+53
+00:04:17,510 --> 00:04:24,030
+الأول على الأول تربيع زائد ال uncertainty في
+
+54
+00:04:24,030 --> 00:04:30,380
+التاني على التانيتربية كله تحت الجزر بيعطينا ال
+
+55
+00:04:30,380 --> 00:04:35,280
+relative uncertainty بتطلع 4.91 في عشرة أسالب
+
+56
+00:04:35,280 --> 00:04:40,700
+تلاتة، هذه relative uncertainty، بنفعش أحطها في
+
+57
+00:04:40,700 --> 00:04:45,310
+الجوابما بينفع احطها في الجواب، لا هذه relative مش
+
+58
+00:04:45,310 --> 00:04:49,250
+absolute عشان احولها ل absolute بدي اضربها في ال
+
+59
+00:04:49,250 --> 00:04:52,430
+answer هي relative uncertainty في ال answer فانا
+
+60
+00:04:52,430 --> 00:04:54,790
+عند ال answer هذا هو 7.82
+
+61
+00:04:58,500 --> 00:05:04,680
+4.91×10⁻³ 4
+
+62
+00:05:04,680 --> 00:05:10,860
+.9×10⁻³
+
+63
+00:05:10,860 --> 00:05:21,940
+4.9×10⁻³ 4.9×10⁻³
+
+64
+00:05:21,940 --> 00:05:26,700
+4.9×10⁻³ 4.9×10⁻³ 4.9×10⁻³ 4.9×10⁻³ 4.9×10⁻³ 4
+
+65
+00:05:26,700 --> 00:05:26,840
+.9×10⁻³ 4.9×10⁻³ 4.9×10⁻³ 4.9×10⁻³ 4.9×10⁻³ 4
+
+66
+00:05:26,840 --> 00:05:26,840
+.9×10⁻³ 4.9×10⁻³ 4.9×10⁻³ 4.9×10⁻³ 4.9×10⁻³ 4
+
+67
+00:05:26,840 --> 00:05:26,860
+.9×10⁻³ 4.9×10⁻³ 4.9×10⁻³ 4.9×10⁻³ 4.9×10⁻³ 4
+
+68
+00:05:26,860 --> 00:05:34,120
+.9×10⁻�كويس فبنقول انه كانت هي 7.823 ماشي لكن انا
+
+69
+00:05:34,120 --> 00:05:37,000
+رفعت التلاتة لأنه هان عندى تلاتة significant
+
+70
+00:05:37,000 --> 00:05:41,320
+figures هان حطيتها ليه؟ عشان اقلل من ال error لإنه
+
+71
+00:05:41,320 --> 00:05:44,760
+مابديش اقربت فوق و بدي اقرب كمان هان؟ لأ فبدي
+
+72
+00:05:44,760 --> 00:05:50,600
+اضربها في ال 4.91 علشان احصل على نتيجة صحيحة مش
+
+73
+00:05:50,600 --> 00:05:56,370
+مقربةفبيطلع عندى 0.0384 هدى هى ال S A او ال
+
+74
+00:05:56,370 --> 00:06:01,170
+absolute uncertainty الجوابب بدى يكون 7.82 هانقى
+
+75
+00:06:01,170 --> 00:06:07,650
+كام رقم يا شباب فى عندى اتنين زادة ونقص 0.04 لأنه
+
+76
+00:06:07,650 --> 00:06:11,470
+لو لاحظنا احنا ال uncertainty اللى عندى موجودة فى
+
+77
+00:06:11,470 --> 00:06:14,490
+الواحد من مية اذا فال uncertainty اللى فى الواحد
+
+78
+00:06:14,490 --> 00:06:17,970
+من الف واللى فى الواحد من عشر تلافلا قيمة طبعا
+
+79
+00:06:17,970 --> 00:06:21,410
+اكيد هي very uncertain مالهاش معنى اذا كان الواحد
+
+80
+00:06:21,410 --> 00:06:25,670
+من مية estimated uncertain فانا بقالكوا في الواحد
+
+81
+00:06:25,670 --> 00:06:29,970
+من الف والواحد من عشر تلات لا يجوز فعشان هيك بقول
+
+82
+00:06:29,970 --> 00:06:34,070
+مدام عندي هان رقمين اول رقم في عندي هان في الواحد
+
+83
+00:06:34,070 --> 00:06:36,930
+من مية اذا هذا الكلام يقرب التمانية تقرب بتصير
+
+84
+00:06:36,930 --> 00:06:40,450
+point oh four والجواب بالتالي بيكون seven point
+
+85
+00:06:40,450 --> 00:06:47,370
+eight to plus or minus point oh fourطيب ناخد مثال
+
+86
+00:06:47,370 --> 00:06:54,170
+كينيا فى الحقيقة فى عندى عينة chloride أخدت منها
+
+87
+00:06:54,170 --> 00:06:59,310
+خمسة وعشرين mil فروحت اعيرته بال silver نايتريت
+
+88
+00:06:59,310 --> 00:07:03,910
+معروف ان ال chloride بتفاعل مع ال silver بنسبة
+
+89
+00:07:03,910 --> 00:07:08,780
+واحد لواحد وبيعطيني ال silver ال chlorideفالكلوريد
+
+90
+00:07:08,780 --> 00:07:11,760
+حطيت عليه silver nitrate، ال silver nitrate اللي
+
+91
+00:07:11,760 --> 00:07:15,560
+حطيتها إيش تركيزها؟ جال point one one six seven
+
+92
+00:07:15,560 --> 00:07:21,770
+plus or minus point O O O twoمن وين جبت هذا
+
+93
+00:07:21,770 --> 00:07:24,430
+الكلام؟ كانوا يقدروا يعطينا المسألة بشكل آخر يقول
+
+94
+00:07:24,430 --> 00:07:28,370
+ال chloride تمت معيارته بال silver و ال silver هذا
+
+95
+00:07:28,370 --> 00:07:33,890
+يعني تمت معيارته بمحلول قياسي فكان تركيز ال silver
+
+96
+00:07:33,890 --> 00:07:37,550
+point one one six eight point one one six nine
+
+97
+00:07:37,550 --> 00:07:41,650
+point one one six seven point six point one one
+
+98
+00:07:41,650 --> 00:07:48,250
+six مثلا six كويس فانا بوجد ال average بلاقي point
+
+99
+00:07:48,250 --> 00:07:52,120
+one one six seven مثلامن الأربع قيم بحسب ال
+
+100
+00:07:52,120 --> 00:07:54,640
+standard deviation اللي هي ال absolute uncertainty
+
+101
+00:07:54,640 --> 00:08:00,060
+بتعطيني point 0002 يفجأه لكن هو ماجليش هيك اعطاني
+
+102
+00:08:00,060 --> 00:08:04,120
+الاشي جاهز لكن كان بإمكانه انه يقولي والله هيك تمت
+
+103
+00:08:04,120 --> 00:08:08,600
+او تم الوصول لتركيز ال silver عن طريق اربع
+
+104
+00:08:08,600 --> 00:08:13,260
+معاييرات مثلا بمادة قياسية كل معايرة أعطتني نتيجة
+
+105
+00:08:13,260 --> 00:08:16,720
+من النتائج هذه حصلت على ال average اللي هو point
+
+106
+00:08:16,720 --> 00:08:17,660
+1167
+
+107
+00:08:20,630 --> 00:08:25,690
+الـ Standard Deviation اللي هو 0.0002 مثلا مالهاش
+
+108
+00:08:25,690 --> 00:08:29,110
+دعوة في المثال، لكن أنا بحب إنك تفهم من وين جاء
+
+109
+00:08:29,110 --> 00:08:33,150
+بالأرقام هذه طيب بيقول إنه عيارنا بتركيزها الجد
+
+110
+00:08:33,150 --> 00:08:40,970
+جديش أخدت المعايرة أخدت 36.78% من ال millكويس لكن
+
+111
+00:08:40,970 --> 00:08:44,230
+برضه بيكمل بيقول the standard deviation in the
+
+112
+00:08:44,230 --> 00:08:50,210
+volume was 0.04 يعني هذه 36 و 78 زائد او ناقص 0.04
+
+113
+00:08:50,210 --> 00:08:54,210
+من وين جابها هو لما عير ال chloride بال silver
+
+114
+00:08:54,210 --> 00:09:04,190
+عيرها خمس مرات اول مرة طلعت 36 مثلا و 75 36 و 70
+
+115
+00:09:04,190 --> 00:09:14,890
+36 و 80 36 و 85 مثلا36.78 راح جاب المتوسط لجهة 36
+
+116
+00:09:14,890 --> 00:09:20,730
+.78 جاب ال standard deviation مثلا لجهة 0.04 يبقى
+
+117
+00:09:20,730 --> 00:09:23,730
+اعرف من وين ايجي ال uncertainty في ال volume عيرنا
+
+118
+00:09:23,730 --> 00:09:27,290
+عدة مرات وهذا الكلام بيقدر ان يكون في عندى عدة
+
+119
+00:09:27,290 --> 00:09:30,130
+نتائج بحسب ال standard deviation و ال average
+
+120
+00:09:30,130 --> 00:09:35,010
+بيطلع عندى القيام الآن يا شباب هو طالب ايش بقول
+
+121
+00:09:35,010 --> 00:09:37,710
+find the uncertainty in the number of millimoles
+
+122
+00:09:37,710 --> 00:09:40,640
+of the chlorideبدوا ال answer تنتهي في ال number
+
+123
+00:09:40,640 --> 00:09:45,340
+of millimoles من ال chloride الموجودة في 250 mil
+
+124
+00:09:45,340 --> 00:09:49,180
+من ال chloride sample انا بعير بس 25 اذا كان عرفت
+
+125
+00:09:49,180 --> 00:09:53,860
+ال millimoles في 25 بضربها في 10 بتطلع millimoles
+
+126
+00:09:53,860 --> 00:09:59,040
+في 250 هو طالب ال millimoles في 250 انا بعير بس 25
+
+127
+00:09:59,040 --> 00:10:02,020
+لو عرفت ال millimoles و ال answer تنتهي فيها
+
+128
+00:10:02,020 --> 00:10:04,860
+بضربها في 10 بتعطيني ال millimoles و ال answer
+
+129
+00:10:04,860 --> 00:10:11,470
+تنتهي في 250بس بدي اذكركم بدي اقولكم ان ايش يعني
+
+130
+00:10:11,470 --> 00:10:15,230
+millimol millimol يعني molarity في volume انا عندي
+
+131
+00:10:15,230 --> 00:10:19,390
+ال molarity وعندي ال volume نضربهم في بعض ال
+
+132
+00:10:19,390 --> 00:10:22,570
+molarity في ال volumeبيعطوني ملي مول الـ silver
+
+133
+00:10:22,570 --> 00:10:25,730
+nitrate والملي مول الـ silver nitrate هي الملي مول
+
+134
+00:10:25,730 --> 00:10:28,610
+الكلوريد لأنه بتفعله بنسبة واحد لو واحد عدد ملي
+
+135
+00:10:28,610 --> 00:10:31,450
+مولات ال silver nitrate يساوي عدد ملي مولات
+
+136
+00:10:31,450 --> 00:10:35,430
+الكلوريد وبالتالي الملي مول ال silver nitrate اللي
+
+137
+00:10:35,430 --> 00:10:38,410
+بتساوي ملي مول الكلوريد عبارة عن حصل ضرب ال
+
+138
+00:10:38,410 --> 00:10:44,100
+molarity اللي هي point one one six seven timesأو
+
+139
+00:10:44,100 --> 00:10:49,000
+زاد أو ناقص اللي هي ال uncertainty 0.0002 times ال
+
+140
+00:10:49,000 --> 00:10:54,200
+volume 36.78 plus or minus 0.04 لو طلعنا عليها هذه
+
+141
+00:10:54,200 --> 00:10:58,600
+مسألة ضرب و مسألة الضرب بقدر أضرب الأرقام ال
+
+142
+00:10:58,600 --> 00:11:05,900
+absolute وضع طبيعي 0.1167 times 36.78 وضع طبيعي
+
+143
+00:11:05,900 --> 00:11:13,240
+هذه أرقام مجردة بقدر أضرب 4.292طيب الـ plus or
+
+144
+00:11:13,240 --> 00:11:15,440
+minus بدي ال uncertainty بقول اه هذه ال
+
+145
+00:11:15,440 --> 00:11:19,940
+uncertainty يجب حسابها من ال relative uncertainty
+
+146
+00:11:19,940 --> 00:11:23,940
+ففي البداية بدي اجيب ال relative uncertainty بقول
+
+147
+00:11:23,940 --> 00:11:26,980
+والله ال relative uncertainty ال uncertainty في ال
+
+148
+00:11:26,980 --> 00:11:30,380
+molarity على ال molarity تربيع ال uncertainty في
+
+149
+00:11:30,380 --> 00:11:34,400
+ال volume على ال volume تربيع ايش بيعطيني تحت
+
+150
+00:11:34,400 --> 00:11:38,180
+الجزير هذه بيعطينا ال relative uncertaintyطيب ال
+
+151
+00:11:38,180 --> 00:11:40,240
+relative uncertainty كي بده أحولها ل absolute
+
+152
+00:11:40,240 --> 00:11:43,780
+uncertainty نضبها في ال answer في هاي ال S A
+
+153
+00:11:43,780 --> 00:11:46,800
+بيساوي ال answer في ال relative uncertainty
+
+154
+00:11:46,800 --> 00:11:52,060
+بتعطيني 8.71 في عشرة أس سالب تلاتة هذا في الخمسة و
+
+155
+00:11:52,060 --> 00:11:55,700
+عشرين ميل يبقى في ال 250 ميل كل خمسة و عشرين ميل
+
+156
+00:11:55,700 --> 00:11:59,180
+في هذه ال uncertainty طب في ال 250 ميل أضربها في
+
+157
+00:11:59,180 --> 00:12:06,590
+عشرة فبيطلع عندى 0.0871 و بده الكل يفتح عينههذه هي
+
+158
+00:12:06,590 --> 00:12:10,110
+الـ Absolute Uncertainty باجي بمشي من اليسار في
+
+159
+00:12:10,110 --> 00:12:13,990
+عندي Uncertainty في ال إيش؟ في ال 1 من 100 إذا في
+
+160
+00:12:13,990 --> 00:12:16,450
+قيمة ال Uncertainty في ال 1 من الف و ال واحد إذا
+
+161
+00:12:16,450 --> 00:12:20,630
+هذه و كأنه بس بتدخلي رقم واحد باجي بقول إذا
+
+162
+00:12:20,630 --> 00:12:25,670
+للنتيجة النتيجة هل لما أضرب في 10 عشان أحول هل لما
+
+163
+00:12:25,670 --> 00:12:30,690
+أضرب في 50 من 42.92 plus or minus 0.0871 لكن قلنا
+
+164
+00:12:30,690 --> 00:12:36,480
+إنه فقطعند ال uncertainty في المية هذا هو المهم
+
+165
+00:12:36,480 --> 00:12:38,900
+اللي باجي مافيش إله أي معنى، معنى الكلام السابعة
+
+166
+00:12:38,900 --> 00:12:41,700
+بدها تصير .. آه التمانية بدها تصير تسعة، السابعة
+
+167
+00:12:41,700 --> 00:12:45,840
+تقرب، بدها تصير تسعة، يبقى 42.92 plus or minus 0
+
+168
+00:12:45,840 --> 00:12:51,400
+.09 يبقى ال uncertainty في ال 250 mil يجب إنه
+
+169
+00:12:51,400 --> 00:12:58,410
+نعملها report على إنها plus or minus 0.09.09
+
+170
+00:12:58,410 --> 00:13:02,450
+millimole يبقى ال answer تنتهي عبارة عن point 09
+
+171
+00:13:02,450 --> 00:13:03,830
+millimole
+
+172
+00:13:05,950 --> 00:13:11,070
+الان برضه بدنا نحاول يعني ننهي موضوع ال
+
+173
+00:13:11,070 --> 00:13:15,270
+significant figures الان فرصتنا ننهي موضوع ال
+
+174
+00:13:15,270 --> 00:13:18,170
+significant figures و احنا لسه مصحي انه يعني بنقدر
+
+175
+00:13:18,170 --> 00:13:25,850
+نقول أخدنا كل الأدوات اللازمة لإنه اتساعدنا نستنتج
+
+176
+00:13:25,850 --> 00:13:29,230
+القوانين الأساسية اللي بتحكم عدد ال significant
+
+177
+00:13:29,230 --> 00:13:32,590
+figures بالذات إذا كان في عندي uncertainty في
+
+178
+00:13:32,590 --> 00:13:36,530
+البداية بده اقولفيش عندي uncertainty؟ اه باجي
+
+179
+00:13:36,530 --> 00:13:40,130
+بتطلع مثلا على ال .. في الجامعة والطريح بتطلع على
+
+180
+00:13:40,130 --> 00:13:44,070
+النتيجة الأقل دقة أو الأعلى uncertainty يعني بتشوف
+
+181
+00:13:44,070 --> 00:13:46,890
+إيش فيه على يسار على يمين العلامة العشرية مثلا
+
+182
+00:13:46,890 --> 00:13:50,050
+يعني في الواحد من مية ولا في الواحد من عشرة ولا في
+
+183
+00:13:50,050 --> 00:13:52,970
+الواحد من ألف ولا في الواحد من عشرة تلاني بدي أخد
+
+184
+00:13:52,970 --> 00:14:00,770
+الأقل دقةبالنسبة لها الدرج والقسمة بطل على ال key
+
+185
+00:14:00,770 --> 00:14:05,670
+number والجواب يجب أن يكون نفس عدد ال significant
+
+186
+00:14:05,670 --> 00:14:08,570
+figures الموجودة في ال key number إلا إذا كان
+
+187
+00:14:08,570 --> 00:14:13,330
+الجواب أقل من ال key number فبد أضيف one
+
+188
+00:14:13,330 --> 00:14:15,750
+additional significant figure على هيئة subscript
+
+189
+00:14:15,750 --> 00:14:20,870
+فش مشكلة هذا الجزء إذا كان العمليات الحسابية اللي
+
+190
+00:14:20,870 --> 00:14:26,960
+عندي فش فيها uncertaintiesطيب إذا كان العمليات
+
+191
+00:14:26,960 --> 00:14:30,900
+الحسابية اللي عندي فيها uncertainties شوفنا احنا
+
+192
+00:14:30,900 --> 00:14:34,200
+بعض الأمثلة كيف نعمل الجمهور الطريح بس كيف نعمله
+
+193
+00:14:34,200 --> 00:14:38,200
+لكن الآن بدنا نشوف كيف بنحدد عدد ال significant
+
+194
+00:14:38,200 --> 00:14:43,660
+figures خلينا ناخد مسألة صغيرة كتير يبقى جسمنا
+
+195
+00:14:43,660 --> 00:14:47,880
+الموضوع لجسمين جسمعمليات حسابيا فيش فيها
+
+196
+00:14:47,880 --> 00:14:51,620
+uncertainties القوانين الماضية مبروك عليك 100%
+
+197
+00:14:51,620 --> 00:14:55,400
+استخدمها و علامتك صحيحة إذا جوابت صح علامتك 100%
+
+198
+00:14:55,400 --> 00:14:59,120
+إذا فيش عندي uncertainties في عندي uncertainties
+
+199
+00:14:59,120 --> 00:15:04,720
+فتح عينك كيف بدنا نشتغل نطلع على المسألة الأولى 73
+
+200
+00:15:04,720 --> 00:15:15,290
+.1 ± 0.2 x 2.245 ± 0.008لو بدأ أقول إذا كان في
+
+201
+00:15:15,290 --> 00:15:18,230
+عندي uncertainties، ما تطلعش لا على key number ولا
+
+202
+00:15:18,230 --> 00:15:22,330
+غيره، سواء كانت جمع أو طريح أو جسم أو ضرب، ما
+
+203
+00:15:22,330 --> 00:15:24,990
+تطلعش لا على key number ولا إيش فيه علمين ولا على
+
+204
+00:15:24,990 --> 00:15:30,790
+اليسار، مش شغلك، مش شغلك، بقول مثلا الجواب بطلع
+
+205
+00:15:30,790 --> 00:15:34,890
+164.1، لو طلعتها، لو بدك تعتبر ال key number، بدي
+
+206
+00:15:34,890 --> 00:15:40,150
+تقول والله الجواب 164، مش هيك؟زاد أو ناقص SA لأن
+
+207
+00:15:40,150 --> 00:15:43,190
+ال key number ثلاثة مثلا يعني و بدك يعني إذا كانت
+
+208
+00:15:43,190 --> 00:15:45,570
+قولت والله هذا أقل بدنا نحط واحد من عشرة لأنه أقل
+
+209
+00:15:45,570 --> 00:15:50,110
+ممكن واحد من عشرة تحت يعني ممكن لكن على الأقل يعني
+
+210
+00:15:50,110 --> 00:15:53,350
+احنا بنقول مش هنعتبر شيء اسمه key number مدام فيه
+
+211
+00:15:53,350 --> 00:15:55,650
+in the uncertainties انسى موضوع ال key number
+
+212
+00:15:55,650 --> 00:15:58,830
+وانسى موضوع إيش فيه على يمين العلامة العشرية وإيش
+
+213
+00:15:58,830 --> 00:16:02,790
+الأقل دقة وغيره مش شغلك بقول هذا كلام one six four
+
+214
+00:16:02,790 --> 00:16:06,900
+point one plus or minus SAبدنا نجيب ال S A بنقول
+
+215
+00:16:06,900 --> 00:16:09,080
+فش مشكلة ال S A relative في البداية لإن هذا
+
+216
+00:16:09,080 --> 00:16:13,320
+الموضوع ايه ضرب فبقول ال S A relative ساوي point
+
+217
+00:16:13,320 --> 00:16:17,180
+two على تلات سبعين واحد من عشرة تربيع زائد point
+
+218
+00:16:17,180 --> 00:16:21,780
+eight على two point two four five تربيع تحت الجزير
+
+219
+00:16:21,780 --> 00:16:27,820
+ماشي طلعنا ال S A إيش relative بنضربها فيه one six
+
+220
+00:16:27,820 --> 00:16:31,140
+four point one بطلع عننا الجواب point seven يبقى
+
+221
+00:16:31,140 --> 00:16:35,870
+ال S A إيش مال يا شبابpoint seven يبقى ال S A
+
+222
+00:16:35,870 --> 00:16:41,550
+الهقيمة محسوبة مقدارها point seven او بمعنى اخر ال
+
+223
+00:16:41,550 --> 00:16:45,070
+absolute uncertainty معروفة لأقرب واحد من عشرة
+
+224
+00:16:45,070 --> 00:16:49,210
+صحيح ولا لأ بما ان ال uncertainty معروفة لأقرب
+
+225
+00:16:49,210 --> 00:16:54,650
+واحد من عشرة اذا الجواب لابد ان يكون معلومة لأقرب
+
+226
+00:16:54,650 --> 00:16:59,210
+واحد من عشرةكمان مرة بقول احنا حسبنا ال
+
+227
+00:16:59,210 --> 00:17:03,790
+uncertainty لجينا ال uncertainty سبعة من عشرة، ايش
+
+228
+00:17:03,790 --> 00:17:07,470
+معنى هذا الكلام؟ معناته ان ال uncertainty معلومة
+
+229
+00:17:07,470 --> 00:17:12,320
+لأقرب واحد من عشرةبنقول مدام ال uncertainty مش ال
+
+230
+00:17:12,320 --> 00:17:15,540
+key number ولا اللي على اليمين ولا .. لأ مدام ال
+
+231
+00:17:15,540 --> 00:17:19,940
+uncertainty معلومة لأقرب واحد من عشرة إذا الجواب
+
+232
+00:17:19,940 --> 00:17:23,640
+يجب أن يكون معلوما لأقرب واحد من عشرة انتهى
+
+233
+00:17:23,640 --> 00:17:30,540
+الموضوع عشان هيك مش 164 زاد أو نقص إسئلة 164 و
+
+234
+00:17:30,540 --> 00:17:34,520
+واحد من عشرة اللي كانت موجودة أربع أرقام مش تلاتة
+
+235
+00:17:35,780 --> 00:17:40,120
+مش عشان ال key number ولا عشان أقل أو أكتر لأ عشان
+
+236
+00:17:40,120 --> 00:17:43,600
+ال uncertainty معلومة لأقرب واحد من عشرة الجواب
+
+237
+00:17:43,600 --> 00:17:46,420
+لازم يكون معلوم لأقرب واحد من عشرة إذا الجواب
+
+238
+00:17:46,420 --> 00:17:51,140
+الصحيح 164 و واحد من عشرة زائد أو ناقص سبعة من
+
+239
+00:17:51,140 --> 00:17:52,980
+عشرة اللي هي ال absolute uncertainty
+
+240
+00:17:56,990 --> 00:18:03,430
+0 بالظبط صحيح هذا الكلام طيب نطلع على بعض الأسئلة
+
+241
+00:18:03,430 --> 00:18:07,050
+الأخرى يعني مثلا نطلع على نفس المثال اللي فات
+
+242
+00:18:07,050 --> 00:18:14,490
+شكلها 73.1 ± 0.7 أنا كبرت ال answer تنتي لسبب
+
+243
+00:18:14,490 --> 00:18:20,930
+هالجتها تشوفه times 2.245 ± 0.08 ضربنا الأتنين في
+
+244
+00:18:20,930 --> 00:18:27,580
+بعض طلع 164.1 من عشرةطلعنا الـ SA relative اللي هي
+
+245
+00:18:27,580 --> 00:18:30,620
+عبارة عن point seven على تلات سبعين و واحد تربيع
+
+246
+00:18:30,620 --> 00:18:35,440
+زائد point eight على two point two four five تربيع
+
+247
+00:18:35,440 --> 00:18:39,600
+كويس الكل تحت الجزير طلعت قيمة ضلبناها في المية
+
+248
+00:18:39,600 --> 00:18:43,320
+أربع ستين و واحد من عشرة إيش طلع عندي؟ one point
+
+249
+00:18:43,320 --> 00:18:48,780
+six seven seven باجي بقول إذا الأنصر تنتفي العدد
+
+250
+00:18:48,780 --> 00:18:53,380
+الصحيح الأنصر تنتفي إيه؟في الآية الصحيحة، إذا لا
+
+251
+00:18:53,380 --> 00:18:57,520
+يمكن الجواب يحتوي عليها عشر، لا يمكن الجواب يحتوي
+
+252
+00:18:57,520 --> 00:19:01,420
+عليها عشر، معايا؟ عشان هيك الجواب بدي يكون مية
+
+253
+00:19:01,420 --> 00:19:05,780
+أربعة و ستين صحيح، زائد أو ناقص، طبعا الستة تقرب
+
+254
+00:19:05,780 --> 00:19:17,130
+اتنين، كمان مرةحسابة ال SA طلعت 1.677 بطلع عليها
+
+255
+00:19:17,130 --> 00:19:23,690
+بقول يبقى ال uncertainty في العدد الصحيح، بقولك ال
+
+256
+00:19:23,690 --> 00:19:29,590
+uncertainty في العدد الصحيحهيها one point one هي
+
+257
+00:19:29,590 --> 00:19:33,310
+واحد، إيش كيف عرفنا؟ هي جدامنا، one point six
+
+258
+00:19:33,310 --> 00:19:35,670
+seven seven، هذه ال uncertainty، إذا وين ال
+
+259
+00:19:35,670 --> 00:19:40,190
+uncertainty؟ في العدد الصحيح، إذا الجواب لا يمكن
+
+260
+00:19:40,190 --> 00:19:44,750
+يكون فيه عشر أو واحد من مية أو واحد من ألف، كتبتلي
+
+261
+00:19:44,750 --> 00:19:50,880
+هيك في الامتحان؟ غلطمدام ال answer تنتهي في العدد
+
+262
+00:19:50,880 --> 00:19:54,680
+الصحيح، إذا الجواب عدد صحيح، مانفعش يكون فيه عندي
+
+263
+00:19:54,680 --> 00:20:02,300
+عشاء أو جزء من 100 أو غيره، طيب، لا لا لا، هيوه
+
+264
+00:20:02,300 --> 00:20:05,320
+هيوه يا عناي، هتطلع له طلعتان، one six four plus
+
+265
+00:20:05,320 --> 00:20:08,920
+or minus اتنين، الواحد ستة صارت اتنين، طيب، نتطلع
+
+266
+00:20:08,920 --> 00:20:13,040
+على المسألة مرت معانا سابقا، لكن برضه غيرت شوية في
+
+267
+00:20:13,040 --> 00:20:19,080
+الأرقام علشان يطلع الاشي اللي أنا بدي يعنى2 2.3
+
+268
+00:20:19,080 --> 00:20:23,880
+plus or minus 0.1 times 35.08 plus or minus 0.07
+
+269
+00:20:23,880 --> 00:20:28,260
+بقول هدول الرقمين يضربوا عادي بيطلعوا سبعمية اتنين
+
+270
+00:20:28,260 --> 00:20:32,280
+و تمانين و تلاتة من عشرة سبعمية اتنين و تمانين و
+
+271
+00:20:32,280 --> 00:20:35,700
+تلاتة من عشرة زائد او نقص ال S A طبعا ماقدرش اقسم
+
+272
+00:20:35,700 --> 00:20:39,780
+ال S A مباشرة لان هذه عملية ضرب فبجيب ال S A
+
+273
+00:20:39,780 --> 00:20:44,930
+relativeبتطلع عندنا 4.9 1 في 10 أقصى سالب ثلاثة،
+
+274
+00:20:44,930 --> 00:20:49,370
+إذا الـ S إيه ال answer فيه؟ الـ S إيه ال
+
+275
+00:20:49,370 --> 00:20:53,030
+relative؟ بتطلع عندنا تلاتة و أربعة و تمانين، كمان
+
+276
+00:20:53,030 --> 00:20:57,230
+مرة، ال answer تنتهي في إيهش؟ إذا الجواب لا يمكن
+
+277
+00:20:57,230 --> 00:21:01,770
+يحتوي على عشار، مالفعليش، الجواب يجب أن يكون في
+
+278
+00:21:01,770 --> 00:21:05,090
+العدد الصحيح، عشان هيك بنجوز سبعمية اتنين و تمانين
+
+279
+00:21:05,090 --> 00:21:09,650
+حيث زائدة وناقص أربعة، زائدة وناقص أربعة، التهيأ
+
+280
+00:21:09,650 --> 00:21:10,090
+الموضوع
+
+281
+00:21:14,430 --> 00:21:19,990
+محاضرة اللي كنا ناخدها ماتتش عملية جماعة؟ معرفش
+
+282
+00:21:19,990 --> 00:21:21,770
+أيش اللي كنا ناخدها في المحاضرة الماضية، ماعرفش
+
+283
+00:21:21,770 --> 00:21:24,390
+عليش اللي بتسأل، لكن أنا بقولك إنه إذا كان في عندك
+
+284
+00:21:24,390 --> 00:21:29,310
+uncertainty، اطلع فقط، أه طبعا، يعني عملية الجماعة
+
+285
+00:21:29,310 --> 00:21:33,770
+مبينة، تحسب ال uncertainty، و ال uncertainty هي
+
+286
+00:21:33,770 --> 00:21:36,730
+اللي بدها تحدد عدد ال significant figures اللي في
+
+287
+00:21:36,730 --> 00:21:48,790
+الجوابطيب أخر مثال 101.1 ± 0.9 x 1.562 ± 0.008 لو
+
+288
+00:21:48,790 --> 00:21:55,210
+جيت ضربت طول ربعدي الأرقام 101.1 x 1.562 بطلع 157
+
+289
+00:21:55,210 --> 00:22:00,590
+.9 طب حسبت ال S A relative و ضربتها في ال answer
+
+290
+00:22:00,590 --> 00:22:07,350
+طلع عندك 1.62إذا ال answer تنتهي في إيش موجودة؟ في
+
+291
+00:22:07,350 --> 00:22:10,470
+العادل الصحيح إذا انتهى الموضوع أن الجواب لا يمكن
+
+292
+00:22:10,470 --> 00:22:14,770
+يحتوي على أعشارعشان هيك الجواب بدي يكون 158 plus
+
+293
+00:22:14,770 --> 00:22:18,110
+or minus 2 لو انت بدك تحسب هال key number كان هادي
+
+294
+00:22:18,110 --> 00:22:22,090
+أربعة و هادي أربعة الجواب إيش بدي يكون أربعة لأ
+
+295
+00:22:22,090 --> 00:22:26,530
+بنحسبش هيك مدام أنت ب .. مدام أننا uncertainty
+
+296
+00:22:26,530 --> 00:22:32,270
+طريقة الحساب هي حساب ال uncertainty و حسب ال
+
+297
+00:22:32,270 --> 00:22:36,110
+uncertainty عدد ال significant figure في الجواب
+
+298
+00:22:36,110 --> 00:22:39,400
+بدي يعتمد على ال uncertainty تبعتك اللي حسبتهايبقى
+
+299
+00:22:39,400 --> 00:22:44,640
+ال answer تنتهي يا شباب إن وجدات هي التي تحدد عدد
+
+300
+00:22:44,640 --> 00:22:48,000
+the significant figures اللي في الجواب وهيك بنكون
+
+301
+00:22:48,000 --> 00:22:51,140
+طوينا صفحة significant figures وارجو أنها تكون
+
+302
+00:22:51,140 --> 00:22:55,340
+يعني كانت واضحة وكويسة بالنسبالكم ونستخدمها بشكل
+
+303
+00:22:55,340 --> 00:22:56,440
+صحيح
+
+304
+00:23:01,300 --> 00:23:06,660
+لا يقرب انتهى الموضوع يعني مثلا one point four
+
+305
+00:23:06,660 --> 00:23:12,040
+زائد او ناقص واحد طبعا طبعا لإن مافيش إلها معنى
+
+306
+00:23:12,040 --> 00:23:15,360
+لإن إذا كان العدد صحيح في uncertainty فانا قالك في
+
+307
+00:23:15,360 --> 00:23:18,600
+الأربعة من عشرة إذا كانت الأربعة من عشرة أكبر طب
+
+308
+00:23:18,600 --> 00:23:26,900
+يعني تقرب أقل لا تقرب معايا التقريب هذا يعني ايش
+
+309
+00:23:26,900 --> 00:23:31,810
+مكان يكون مدام أكتر من خمسة تقربلو خمسة بتختار
+
+310
+00:23:31,810 --> 00:23:34,930
+القانون الخامسة يعني إيش؟ بدنا نعيد نفس الكلام
+
+311
+00:23:34,930 --> 00:23:39,770
+اللي كنا بنحكي فيه دائما طيب يا شباب، يا طيبين، يا
+
+312
+00:23:39,770 --> 00:23:45,390
+محترمين، نتطلع على الموضوع الحلو كتير بدنا
+
+313
+00:23:45,390 --> 00:23:49,030
+نتطلع على حاجة بيقولك confidence limit حدود الثقة
+
+314
+00:23:49,030 --> 00:23:55,490
+يعني مثلا، بقدركم مثال كتير بصير في عندنا مثلا
+
+315
+00:23:55,490 --> 00:24:01,190
+ميزان جديد اخترعناهطبعا مش في الجامعة لأنه لو في
+
+316
+00:24:01,190 --> 00:24:03,970
+الجامعة كان يختار على ميزاني كويس فيختار على ميزان
+
+317
+00:24:03,970 --> 00:24:08,970
+جديد وقلنا لزميكم لو سمحت اطلع جهز وزنك فجهز وزنه
+
+318
+00:24:08,970 --> 00:24:13,330
+80 81 81 81 81 81 81 81 81 81 81 81 81 81 81 81 81
+
+319
+00:24:13,330 --> 00:24:13,330
+81 81 81 81 81 81 81 81 81 81 81 81 81 81 81 81 81
+
+320
+00:24:13,330 --> 00:24:13,330
+81 81 81 81 81 81 81 81 81 81 81 81 81 81 81 81 81
+
+321
+00:24:13,330 --> 00:24:13,330
+81 81 81 81 81 81 81 81 81 81 81 81 81 81 81 81 81
+
+322
+00:24:13,330 --> 00:24:13,350
+81 81 81 81 81 81 81 81 81 81 81 81 81 81 81 81 81
+
+323
+00:24:13,350 --> 00:24:13,750
+81 81 81 81 81 81 81 81 81 81 81 81 81 81 81 81 81
+
+324
+00:24:13,750 --> 00:24:13,930
+81 81 81 81 81 81 81 81 81 81 81 81 81 81 81 81 81
+
+325
+00:24:13,930 --> 00:24:15,530
+81 81 81 81 81 81 81 81 81 81 81 81 81 81 81 81 81
+
+326
+00:24:15,530 --> 00:24:16,190
+81 81 81 81 81 81 81 81 81 81 81 81 81 81 81
+
+327
+00:24:27,110 --> 00:24:31,590
+إيش رأيكم في ال precision تبعت الميزان القياسي؟ زي
+
+328
+00:24:31,590 --> 00:24:34,470
+ال precision هداك تقريبا، صح ولا لأ؟ يعني الإتنين
+
+329
+00:24:34,470 --> 00:24:40,870
+ال precision تبعتهم كويسة، لكن ال accuracy ممكن
+
+330
+00:24:40,870 --> 00:24:42,610
+إنها تختلف
+
+331
+00:24:47,500 --> 00:24:51,260
+الان احنا مابنحكيش في هذا الكلام يعني في ما يتعلق
+
+332
+00:24:51,260 --> 00:24:56,180
+بال confidence limit احنا بنقول تعالوا نستخدم
+
+333
+00:24:56,180 --> 00:25:00,980
+أدوات صحيحة بديش استخدم أدوات يعني فيها مشكلة فيها
+
+334
+00:25:00,980 --> 00:25:08,000
+مشكلة بدي استخدم موازين ممتازة للقياس أدوات قياسية
+
+335
+00:25:08,000 --> 00:25:12,100
+لقياس الحجم والمعاييرات وغيره بدي استخدم أجهزة
+
+336
+00:25:12,100 --> 00:25:17,460
+قياسية معايرة بشكل دقيق 100%كويس يعني كل شغل صح
+
+337
+00:25:17,460 --> 00:25:22,240
+بدى استخدم ال procedure وطبقه بشكل سليم يعني
+
+338
+00:25:22,240 --> 00:25:27,260
+كنتيجة الاصل اللى هتكون نتيجة ايه شمالها؟ صحيحة
+
+339
+00:25:27,260 --> 00:25:30,120
+الاصل هتكون نتيجة صحيحة طيب السؤال
+
+340
+00:25:33,410 --> 00:25:37,790
+أنا بعملش يعني بحللش التجربة يعني آلاف المرات و لا
+
+341
+00:25:37,790 --> 00:25:42,170
+مئات المرات و لا بحللها فقط عدد قليل من المرات صح
+
+342
+00:25:42,170 --> 00:25:47,250
+ولا لأ طيب إيش مدى الثقة اللي عندي إنه النتيجة
+
+343
+00:25:47,250 --> 00:25:52,370
+الصحيحة بتوجع في range معين أنا من ال confidence
+
+344
+00:25:52,370 --> 00:25:57,310
+limit ممكن أحسب ال range ال rangeRange للنتائج
+
+345
+00:25:57,310 --> 00:26:00,590
+تبعتي طب إيش مدى الثقة اللي عندي إنه النتيجة
+
+346
+00:26:00,590 --> 00:26:05,990
+الصحيحة بالفعل بتوجع في ال range هذا أو بمعنى آخر
+
+347
+00:26:05,990 --> 00:26:15,350
+لو بدي يعني أستخدم ال confidence limit و أقول إنه
+
+348
+00:26:15,350 --> 00:26:18,550
+ال confidence limit اللي بتعبر عن النتيجة الصحيحة
+
+349
+00:26:18,550 --> 00:26:21,550
+يعني و كإنها ال confidence limit ممكن أحط مدالها
+
+350
+00:26:21,550 --> 00:26:28,490
+Muميو اللي هي عبارة عن ال true mean وين بوجع ال
+
+351
+00:26:28,490 --> 00:26:32,290
+true mean جال X bar اللي هو ال experimental mean
+
+352
+00:26:32,290 --> 00:26:40,110
+زائد او ناقص TS على جزر ال N حيث ال X bar اللي
+
+353
+00:26:40,110 --> 00:26:44,050
+بنعرفها هي ال average ال S مرة اتنانة هي ال
+
+354
+00:26:44,050 --> 00:26:49,850
+standard deviation ال L عدد التجاربطب وال T جال
+
+355
+00:26:49,850 --> 00:26:54,070
+هاد ال T عبارة عن statistical factor معامل إحصائي
+
+356
+00:26:54,070 --> 00:27:00,890
+بنقولها student T معامل إيه؟ معامل إحصائي بيتوقف
+
+357
+00:27:00,890 --> 00:27:05,540
+على حاجتينبتوقف على ال degrees of freedom اللي هي
+
+358
+00:27:05,540 --> 00:27:09,740
+عدد التجارب ناقص واحد، بتوقف على حاجتين، بتوقف على
+
+359
+00:27:09,740 --> 00:27:13,020
+عدد التجارب اللي أنا بعملها، يعني او بمعنى أدق،
+
+360
+00:27:13,020 --> 00:27:14,900
+بتوقف على ال degrees of freedom اللي هو عدد
+
+361
+00:27:14,900 --> 00:27:19,660
+التجارب ناقص واحد، وبتوقف أيضا على حاجة بنقولها
+
+362
+00:27:19,660 --> 00:27:25,060
+confidence level، مدى الثقةاللي انا بطلب ان نتائجي
+
+363
+00:27:25,060 --> 00:27:31,140
+تكون موجودة فيه يعني فبدي مدى ثقة معين فممكن اشتغل
+
+364
+00:27:31,140 --> 00:27:38,660
+عند مستوى .. مستوى ثقة 90% او مستوى ثقة 95% او
+
+365
+00:27:38,660 --> 00:27:46,960
+مستوى ثقة 99% او مستوى ثقة 99.9% طب عند مستوى
+
+366
+00:27:46,960 --> 00:27:51,940
+الثقة هذا اللتيجة الصحيحة تبعتي في أي range بتوجع
+
+367
+00:27:52,830 --> 00:27:56,430
+معايا عند مستوى الثقة هذا النتيجة تبعتي في أي
+
+368
+00:27:56,430 --> 00:28:00,270
+range بتوجع هذا الكلام اللي بنقوله confidence
+
+369
+00:28:00,270 --> 00:28:06,730
+limit فلو اجينا اطلعنا على الجدول اللي قدامنا عشان
+
+370
+00:28:06,730 --> 00:28:10,410
+نعرف عن ايش بنحكي ايش هي ال T فبنقول هان ال
+
+371
+00:28:10,410 --> 00:28:16,010
+degrees of freedom انا عملت مثلا ست تجارب6 تجارب،
+
+372
+00:28:16,010 --> 00:28:25,590
+5 تجارب، 5 تجارب، 5 تجارب، 5 تجارب،
+
+373
+00:28:26,350 --> 00:28:30,710
+معايا انا اشتغلت عشر تجارب اذا ال degree of
+
+374
+00:28:30,710 --> 00:28:36,750
+freedom جد ايش تسعة بدي اشتغل لعين 95% اذا ال T
+
+375
+00:28:36,750 --> 00:28:43,110
+value 2.262 و هكذا احنا في الكيمة التحليلية بنعتمد
+
+376
+00:28:43,110 --> 00:28:47,770
+الشغل لعين 95% حتى لو ما قلت الكاش انا في الامتحان
+
+377
+00:28:47,770 --> 00:28:52,970
+او غيره خلاص قلت لك 95 ماشيماقلت ال cash اعتبر انه
+
+378
+00:28:52,970 --> 00:28:56,090
+ال confidence level اللى بنشتغل عنده هو مستوى ايه
+
+379
+00:28:56,090 --> 00:29:01,490
+95% فهيك بنجيب ال T value لاحظ انه في عندنا عند كل
+
+380
+00:29:01,490 --> 00:29:06,470
+مستوى ثقة في عندنا T values مختلفة حسب مستوى الثقة
+
+381
+00:29:06,470 --> 00:29:09,270
+اللى احنا بدنا نشتغل عنده وقولنا ان احنا هنشتغل
+
+382
+00:29:09,270 --> 00:29:18,900
+غالبا عند 95% انتبه معايا شوية صغيرةطبعا كما ذكرت
+
+383
+00:29:18,900 --> 00:29:24,320
+سابقا على فرض أنه احنا مشتغلين التجربة صح يعني فيش
+
+384
+00:29:24,320 --> 00:29:28,940
+عندنا اي systematic error شغلنا مظموط كله أدواتنا
+
+385
+00:29:28,940 --> 00:29:33,390
+مظموطة ال procedure مظموط الجهاز معايرساعتها اقبل
+
+386
+00:29:33,390 --> 00:29:36,290
+نفهم حاجة من ال confidence limit تعالوا نطلع على
+
+387
+00:29:36,290 --> 00:29:40,110
+هالمسألة عشان توضحلنا ايش المفهوم ال confidence
+
+388
+00:29:40,110 --> 00:29:45,130
+limit اللي بتكلم عنه بقول the standard deviation
+
+389
+00:29:45,130 --> 00:29:50,010
+for the analysis of a carbonate sample was 0.075
+
+390
+00:29:50,010 --> 00:29:53,070
+يعني حللت الكربونيت و حسبت ال standard deviation
+
+391
+00:29:53,070 --> 00:30:02,990
+فطلع 75 من الفfor the results 93.50 93.58 93.43
+
+392
+00:30:02,990 --> 00:30:06,750
+طبعا هو كان ممكن ما يعطيليش ال S لو اعطاني لو
+
+393
+00:30:06,750 --> 00:30:10,870
+اعطاني هذه القيم ما انا ببدأ احسب ال S منها لكن هو
+
+394
+00:30:10,870 --> 00:30:15,350
+يعني مش الغرض هان حساب ال S الغرض انه يحسب ال
+
+395
+00:30:15,350 --> 00:30:18,310
+confidence limit و ال range فهو اعطاه اللي عشان
+
+396
+00:30:18,310 --> 00:30:25,760
+يخفف عني بيقول find the confidence limitو Range 95
+
+397
+00:30:25,760 --> 00:30:32,120
+% confidence levelقال ايه وجد حدود الثقة وايضا
+
+398
+00:30:32,120 --> 00:30:39,160
+المدى عند 95% درجة ثقة او مستوى ثقة 95% وماعطيني
+
+399
+00:30:39,160 --> 00:30:46,240
+بقول ال T عند 95% 4.303 يعني ال T عند مستوى ثقة 95
+
+400
+00:30:46,240 --> 00:30:50,900
+% 4.303 لو حبينا احنا نجيب هذا الكلام من الجدول
+
+401
+00:30:50,900 --> 00:30:53,720
+ممكن مايعطيه ليش ممكن يعطيني الجدول لو اعطاني
+
+402
+00:30:53,720 --> 00:30:58,790
+الجدول بقول انا تلت تجارب اذاأتنين باجه عين الخالص
+
+403
+00:30:58,790 --> 00:31:03,010
+لان ماقلش بلاجة four point three او three هاي اللي
+
+404
+00:31:03,010 --> 00:31:07,050
+طلعت عندى في ال ايه اللى اعطاه اللى هو في السؤال
+
+405
+00:31:07,050 --> 00:31:10,790
+فبده ال confidence limit بقول والله ال confidence
+
+406
+00:31:10,790 --> 00:31:13,670
+limit سوى ال X bar plus or minus TS على جزر ال L
+
+407
+00:31:13,670 --> 00:31:17,950
+ال X bar بدي اجيبها بجمع التلاتة و باقسم على تلاتة
+
+408
+00:31:17,950 --> 00:31:27,880
+بطلع 93.50 اذا تطبيق مباشر في القانون93.50x±t4
+
+409
+00:31:27,880 --> 00:31:38,460
+.303.075 93.50±0
+
+410
+00:31:38,460 --> 00:31:43,000
+.19 93.50±0.19 93
+
+411
+00:31:43,000 --> 00:31:48,180
+.50±0.19 93.50±0
+
+412
+00:31:48,180 --> 00:31:55,450
+.19 93.50±0.19 93.50±0.19فلو طرحتها بطلع عندي 93
+
+413
+00:31:55,450 --> 00:32:00,910
+.31 إلى 93.69 إيش معنى هذا الكلام؟ معناته أنا
+
+414
+00:32:00,910 --> 00:32:08,670
+متأكد بمستوى ثقة، بدرجة ثقة 95% إنه النتيجة
+
+415
+00:32:08,670 --> 00:32:11,190
+الصحيحة للتحليل، لأن مافيش عندي systematic error
+
+416
+00:32:11,190 --> 00:32:17,930
+ها، النتيجة الصحيحة للتحليل تقع في المدى من 93 و
+
+417
+00:32:17,930 --> 00:32:22,910
+31 إلى 93 و 69أنا متأكد، هذه معناته، أنا متأكد
+
+418
+00:32:22,910 --> 00:32:28,470
+بنسبة 95% إنه النتيجة الصحيحة بتوجع في هذا ال
+
+419
+00:32:28,470 --> 00:32:35,230
+range من 93 و 31 إلى 93 و 69 افهمني يا شباب إيش
+
+420
+00:32:35,230 --> 00:32:39,290
+مدلول ومفهوم ال confidence limit و ال range؟ هذا
+
+421
+00:32:39,290 --> 00:32:42,570
+هو، هيجيله تطبيق إذا الله رد المحاضرة اللي جاية،
+
+422
+00:32:42,570 --> 00:32:48,180
+كمان تطبيق آخر، اتفضل لأن احنا بنحلل نسبةجالك
+
+423
+00:32:48,180 --> 00:32:55,120
+بنحلل نسبة، نسبة الكربونات في العينات، اه هي نسبة،
+
+424
+00:32:55,120 --> 00:32:59,200
+انت افترض انه من غير نسبة، نفس الكلام، فهي ال 19%
+
+425
+00:32:59,200 --> 00:33:06,560
+هذه كله 93.5% زادة ونقص، 19%، uncertainty اه صحيح
+
+426
+00:33:08,140 --> 00:33:11,900
+لو اه اه ممكن يعني بتقربها صحيح فش مشكلة بس احنا
+
+427
+00:33:11,900 --> 00:33:14,680
+مابنحكيش عن .. احنا مابنحكيش عن هذا الكلام انا
+
+428
+00:33:14,680 --> 00:33:19,820
+مقرت .. مقرتهاش هان لأنه انا بدي اقلع ال range بدي
+
+429
+00:33:19,820 --> 00:33:22,840
+اقلع ال range فال range هو من تلاتة سعين و واحد و
+
+430
+00:33:22,840 --> 00:33:25,820
+تلاتين الى تلاتة سعين و تسعة و ستين فش مشكلة هذا
+
+431
+00:33:25,820 --> 00:33:29,500
+هو ال range تبعي طيب لحظة شوية تفضل
+
+432
+00:33:36,890 --> 00:33:40,910
+من القيم التلاتة اللى عندك هذى بتجيب ال average X
+
+433
+00:33:40,910 --> 00:33:45,490
+bar بقى بتقول X I minus X bar اللى هو ال seven
+
+434
+00:33:45,490 --> 00:33:49,570
+division اتفضل الاربعة فاصلة تلاتة اجت منها ده كام
+
+435
+00:33:49,570 --> 00:33:54,250
+تجربة عملنا احنا تلاتة اذا في عندنا two degrees of
+
+436
+00:33:54,250 --> 00:34:00,170
+freedom هدى عندك 95% هي الرقم عرفت جرابه ولا لأ 4
+
+437
+00:34:00,170 --> 00:34:01,390
+.303 هو
+
+438
+00:34:04,830 --> 00:34:09,230
+معطف السؤال صحيح و الفاصل سبعة ماهو الفاصل السابع؟
+
+439
+00:34:09,230 --> 00:34:12,830
+point 9
+
+440
+00:34:12,830 --> 00:34:17,430
+هذا في السؤال هى هذا ال deviation في السؤال موجود
+
+441
+00:34:17,430 --> 00:34:22,410
+طيب يا شباب نتكلم الآن عن ال tests of significance
+
+442
+00:34:22,410 --> 00:34:26,890
+ونرجع لموضوعنا أزميلكم اللى طلع على الميزان
+
+443
+00:34:26,890 --> 00:34:32,800
+التجريبيوعلى الميزان القياسي، كويس، اللي قولناها
+
+444
+00:34:32,800 --> 00:34:36,540
+او اللي لاحظناها احنا انه ممكن جدا ان الميزان
+
+445
+00:34:36,540 --> 00:34:41,340
+التجريبي تكون ال precision تبعته مكافئة لل
+
+446
+00:34:41,340 --> 00:34:48,180
+precision للميزان القياسي، لكن هليعني ذلك ان
+
+447
+00:34:48,180 --> 00:34:52,280
+النتائج اللى حصلت عليها بالتجريب مكافئة للنتائج
+
+448
+00:34:52,280 --> 00:34:56,580
+اللى حصلت عليها بالقياسي لا يعني ذلك مطلقا .. يعني
+
+449
+00:34:56,580 --> 00:35:02,740
+هذا كلام مطلقا مش .. مش صحيح بمعنى أخر في عندى
+
+450
+00:35:02,740 --> 00:35:07,560
+اختبارات لازم اجريها انا او اختبارين بالاخرى لازم
+
+451
+00:35:07,560 --> 00:35:11,520
+اجريهم على اي طريقة جديدة او ميزان جديد او غيره
+
+452
+00:35:13,080 --> 00:35:18,780
+عشان أحكم إذا كانت طريقتين متكافئات أو ليس هناك
+
+453
+00:35:18,780 --> 00:35:23,920
+فرق إحصائي مهم بينهمكويس لكن هذا كلام بتوقف على
+
+454
+00:35:23,920 --> 00:35:29,200
+عنصرين بتوقف على انه ال precision تكون متكافئة
+
+455
+00:35:29,200 --> 00:35:33,520
+وكمان بتوقف على انه النتيجة او ال value تكون
+
+456
+00:35:33,520 --> 00:35:38,280
+مكافئة او متكافئة معايا عشان احكم على انه طريقتين
+
+457
+00:35:38,280 --> 00:35:43,420
+مثلا متكافئات بحكم عليهم عن طريق اختبارين اول
+
+458
+00:35:43,420 --> 00:35:48,210
+اختبار بيقول لي ال precisionللطريقتين لازم تكون
+
+459
+00:35:48,210 --> 00:35:52,470
+متكافئة يعني الطريقتين بيعطوني نفس ال precision
+
+460
+00:35:52,470 --> 00:35:57,210
+تقريبا او انه فيش فرق احصائي في ال precision ما
+
+461
+00:35:57,210 --> 00:36:01,530
+بين الطريقتين لكن هذا لا يعني انه فيش فرق احصائي
+
+462
+00:36:02,170 --> 00:36:06,570
+بين نتائج الطريقتين عشان هيك في اختبار تاني لازم
+
+463
+00:36:06,570 --> 00:36:11,930
+اعمله يوضحلي اذا كان في هناك فرق احصائي جوهري بين
+
+464
+00:36:11,930 --> 00:36:14,930
+نتائج الطريقة الاولى والنتائج اللى بحصل عليها
+
+465
+00:36:14,930 --> 00:36:18,050
+باستخدام الطريقة الاولى والنتائج اللى بحصل عليها
+
+466
+00:36:18,050 --> 00:36:21,210
+باستخدامالطريقة التانية يبقى لازم أطبق اختبارين
+
+467
+00:36:21,210 --> 00:36:26,130
+عشان أقول والله طريقة ما مكافئة أو ليس هناك فرق
+
+468
+00:36:26,130 --> 00:36:30,950
+جوهري بينها و بين طريقة أخرى لازم أطبق اختبارين
+
+469
+00:36:30,950 --> 00:36:37,510
+الاختبار الأول بنقوله F test ال F test يعني بيه؟
+
+470
+00:36:39,260 --> 00:36:44,340
+بالإجابة عن السؤال هل هناك فرق جوهري إحصائي جوهري
+
+471
+00:36:44,340 --> 00:36:48,580
+بين ال precision لطريقتين مختلفتين، إيش ال
+
+472
+00:36:48,580 --> 00:36:50,780
+precision؟ ال precision يعني ال standard
+
+473
+00:36:50,780 --> 00:36:54,220
+deviation، هل هناك فرق جوهري في ال standard
+
+474
+00:36:54,220 --> 00:36:59,390
+deviation لطريقتين؟وبرضه كمان حاجة ممكن نقول هل
+
+475
+00:36:59,390 --> 00:37:04,310
+هناك فرق جوهري بين ال variances للطريقتين ايش ال
+
+476
+00:37:04,310 --> 00:37:07,850
+variance ال variance هو ال standard deviation لكن
+
+477
+00:37:07,850 --> 00:37:12,670
+تربيع ال variance هو ال standard deviation لكن ال
+
+478
+00:37:12,670 --> 00:37:15,570
+standard deviation مربع مربع ال standard deviation
+
+479
+00:37:15,570 --> 00:37:21,590
+اسمه variance فال if test تجيب عن السؤال هل هناك
+
+480
+00:37:21,590 --> 00:37:27,790
+فرق جوهري بينالـ Precision لطريقتين أو الـ
+
+481
+00:37:27,790 --> 00:37:31,470
+Variances لطريقتين أو الـ Standard Deviations
+
+482
+00:37:31,470 --> 00:37:35,670
+لطريقتين لكن لا تجيب مطلقا عن السؤال اللي بيقول هل
+
+483
+00:37:35,670 --> 00:37:38,150
+هناك فرق بين النتائج
+
+484
+00:37:39,800 --> 00:37:43,580
+نتيجة هذه المتوسط هذه المتوسط هذه لأ مالهاش دعوة
+
+485
+00:37:43,580 --> 00:37:46,000
+بتجيبش عن هذا السؤال هاه ايش اللي بيجيب عن هذا
+
+486
+00:37:46,000 --> 00:37:50,860
+السؤال مش ال F test حاجة بنقولها ال T test ال T
+
+487
+00:37:50,860 --> 00:37:55,900
+test بيجيب عن السؤال هل هناك فرق جوهر بين النتائج
+
+488
+00:37:55,900 --> 00:37:59,260
+اللي بحصل عليها من الطريقتين ولا لأ يبقى عشان
+
+489
+00:37:59,260 --> 00:38:05,230
+طريقة تنجح طريقة ما تكون مكافئة لطريقة أخرىمعتبرة
+
+490
+00:38:05,230 --> 00:38:10,490
+بقول يجب انه انطبق ال F test اللي بيعطيني فكرة عن
+
+491
+00:38:10,490 --> 00:38:14,050
+ال precision وال T test اللي بيعطيني فكرة عن ال
+
+492
+00:38:14,050 --> 00:38:17,750
+results او ال value و لازم الاتنين ينجحوا لو واحد
+
+493
+00:38:17,750 --> 00:38:20,970
+من الاختبارين فشل معناته لا لا يمكن استخدام
+
+494
+00:38:20,970 --> 00:38:25,410
+الطريقة الجديدة او ان الطريقتين غير متكافئات يبقى
+
+495
+00:38:25,410 --> 00:38:29,110
+لازم الاتنين ينجحوا ممنوع واحد ينجح والتاني لأ طيب
+
+496
+00:38:29,110 --> 00:38:34,490
+نطلع ايش ال F test؟الـ F test هو عبارة عن ال ratio
+
+497
+00:38:34,490 --> 00:38:39,450
+ل ال two variances ايش ال variances اللي هي مربع
+
+498
+00:38:39,450 --> 00:38:43,910
+ال standard deviation فال F بتساوي ال S1 تربية على
+
+499
+00:38:43,910 --> 00:38:48,770
+ال S2 تربية لكن يجب الا اخذ بعين الاعتبار ان قيمة
+
+500
+00:38:48,770 --> 00:38:55,150
+ال F دائما يجب ان تكون اكبر من 1 عشان هيك ايش اللي
+
+501
+00:38:55,150 --> 00:39:01,370
+نحط فوق دائما التجريبي ولا القياسي القياسي
+
+502
+00:39:07,460 --> 00:39:10,920
+أه في راجل طيب هاد طبعا الأكبر بهمنيش لإن مرات
+
+503
+00:39:10,920 --> 00:39:13,460
+التجريب يكون أكبر و مرات الكياس يبقى الله يعلم
+
+504
+00:39:13,460 --> 00:39:18,500
+يعني حسب النوع الطريقة يعني فلأ احنا بنحط دائما
+
+505
+00:39:18,500 --> 00:39:22,940
+الكبير فوق الكبير هو اللي بنحطه فوق و الصغير تحت
+
+506
+00:39:22,940 --> 00:39:28,690
+عشان النتيجة تكون ايه؟طيب بنقول يا شباب هان بنحسب
+
+507
+00:39:28,690 --> 00:39:32,030
+ال F حطينا الكبير فوق والصغير تحت وكان النتيجة
+
+508
+00:39:32,030 --> 00:39:36,470
+أكتر من واحد حسبنا ال F بنقول بنقارن ال calculated
+
+509
+00:39:36,470 --> 00:39:41,890
+F أو ال F calculated مع F في الجدول زي ما في جدول
+
+510
+00:39:41,890 --> 00:39:46,890
+لل T في جدول لل Fيبقى بنقارن ال F اللي هي
+
+511
+00:39:46,890 --> 00:39:50,850
+calculated مع ال F اللي هي وين موجودة في الجدول،
+
+512
+00:39:50,850 --> 00:39:55,830
+إذا كان ال F calculated أقل من ال F tabulated، إذا
+
+513
+00:39:55,830 --> 00:39:59,890
+ليس هناك فرق إحصائي جوهري بين ال standard
+
+514
+00:39:59,890 --> 00:40:04,490
+deviations للطريقتينبقول إذا كان ال F calculated
+
+515
+00:40:04,490 --> 00:40:08,910
+اللي بحسبه من هذه المعادلة أقل من ال F tabulated
+
+516
+00:40:08,910 --> 00:40:13,650
+المجدول بقول إذا ليس هناك فرق إحصائي جوهري بين
+
+517
+00:40:13,650 --> 00:40:18,550
+الطريقتين فيما يتعلق بال إيه بال precision أو فيما
+
+518
+00:40:18,550 --> 00:40:22,410
+يتعلق بال إيه بال standard deviation أو فيما يتعلق
+
+519
+00:40:22,410 --> 00:40:26,390
+بال إيه بال variances فش فرق طب يعني يا سيدي كل
+
+520
+00:40:26,390 --> 00:40:32,350
+الإجابة تبعت من التجربة دقيقة أو لا إيه؟أه، الدقة
+
+521
+00:40:32,350 --> 00:40:38,090
+طبعتها مش مقبولة كإجابة، الدقة مقبولة مثلها مثل
+
+522
+00:40:38,090 --> 00:40:41,450
+القياسية، لكن مالهاش دعوة في النتيجة لسه، النتيجة
+
+523
+00:40:41,450 --> 00:40:52,750
+بما تطبق ال T-test فوق،
+
+524
+00:40:52,750 --> 00:41:01,390
+صحيح، بعد ما تربع، هو .. أه اسواح التربيهمش مشكلة
+
+525
+00:41:01,390 --> 00:41:06,970
+مش مشكلة خلاص مش مشكلة طيب يا شباب نيجي نفرجيكم بس
+
+526
+00:41:06,970 --> 00:41:12,270
+اللي هو الجدول تبع ال F ال T كان عندي مستوية ثقة
+
+527
+00:41:12,270 --> 00:41:16,570
+مختلفة كلها في جدول واحد لكن هان ال F كل مستوى ثقة
+
+528
+00:41:16,570 --> 00:41:20,890
+له جدول و لاحظوا في عندي هان ال degrees of freedom
+
+529
+00:41:20,890 --> 00:41:26,510
+لل S1 ايش ال S1 اتفاجنا لكبير يبقى الكبير هيه
+
+530
+00:41:26,510 --> 00:41:32,510
+horizontal هيك بمشي و لصغيراللي تحت اللي تحت هين
+
+531
+00:41:32,510 --> 00:41:36,210
+ماشي لتحت يعني لما بدي اجيب ال F بتعتمد على جداش
+
+532
+00:41:36,210 --> 00:41:40,050
+ال S واحد و ال S اتنين بتعتمد على ميو واحد و ميو
+
+533
+00:41:40,050 --> 00:41:43,690
+اتنين مش زي ال T بس قيمة واحدة لأ بتعتمد هذا على
+
+534
+00:41:43,690 --> 00:41:48,690
+الاتنين هاي الجدول هفرجيكم يعني مثال تطبيق عليه
+
+535
+00:41:48,690 --> 00:41:55,610
+هفرجيكيا هفرجيكيا لأ هاد ال degrees of freedomفي
+
+536
+00:41:55,610 --> 00:41:59,990
+عندي مثال، المثال إيش بيقول؟ بيقول حللنا ال
+
+537
+00:41:59,990 --> 00:42:03,650
+glucose باستخدام طريقة جديدة وباستخدام طريقة
+
+538
+00:42:03,650 --> 00:42:07,390
+قياسية ال variances ل ال two procedures لجناهم
+
+539
+00:42:07,390 --> 00:42:12,150
+أربعة و تمانية و تمانية و تلاتةأه بيقول if the
+
+540
+00:42:12,150 --> 00:42:15,930
+tabulated if value at 95 percent confidence level
+
+541
+00:42:15,930 --> 00:42:19,910
+at the number of degrees of freedom used was أربعة
+
+542
+00:42:19,910 --> 00:42:23,850
+و خمسة و تسعين يعني ال if value جداش أربعة و خمسة
+
+543
+00:42:23,850 --> 00:42:27,730
+و تسعين بيقول determine whether the variance of
+
+544
+00:42:27,730 --> 00:42:31,170
+the new procedure ال variance لل new procedure
+
+545
+00:42:31,770 --> 00:42:36,310
+differs significantly بيختلف اختلاف جوهري from
+
+546
+00:42:36,310 --> 00:42:39,430
+that of the standard method، يعني هل الطريقة
+
+547
+00:42:39,430 --> 00:42:44,950
+الجديدة تختلف ولا مكافئة للطريقة القياسية فيما
+
+548
+00:42:44,950 --> 00:42:50,410
+يتعلق بالـ Variances، فإيش بتطبق؟الـ F test بدي
+
+549
+00:42:50,410 --> 00:42:53,910
+أجيب ال F calculated S1 تربيع على S2 تربيع، إيش
+
+550
+00:42:53,910 --> 00:42:57,170
+نحط فوق؟ الأربعة و تمانية ولا التمانية و تلاتة؟
+
+551
+00:42:57,170 --> 00:42:59,310
+فأبقى على التمانية و تلاتة، بيطلع أن ال F واحد و
+
+552
+00:42:59,310 --> 00:43:05,530
+تلاتة و سبعين، لكن ال F ال calculated جد إيش؟أعطاه
+
+553
+00:43:05,530 --> 00:43:09,410
+اللي في السؤال كداش ال F اربعة و خمسة وتسعين اعطاه
+
+554
+00:43:09,410 --> 00:43:14,770
+اللي ماشي اذا ال F calculated اقل من ال F
+
+555
+00:43:14,770 --> 00:43:18,830
+tabulated هذا يعني انه ليس هناك فرق جوهر بين
+
+556
+00:43:18,830 --> 00:43:22,410
+الطريقتين يعني الطريقتين اللي هم precision متقاربة
+
+557
+00:43:22,410 --> 00:43:26,710
+متكافئة precision متكافئة standard deviation
+
+558
+00:43:26,710 --> 00:43:33,230
+متكافئة variances متكافئة كويس؟هك بتكون النتيجة
+
+559
+00:43:33,230 --> 00:43:38,270
+اللى حصلنا عليها، ثوانى، بدأ أقول جداش هو جل ال F
+
+560
+00:43:38,270 --> 00:43:43,730
+value ال tabulated؟ 495 هل نستطيع نستدل على أكم
+
+561
+00:43:43,730 --> 00:43:46,330
+تجربة عمل بالطريقة الأولى أو أكم تجربة عمل
+
+562
+00:43:46,330 --> 00:43:49,050
+بالطريقة التانية؟ بقول نعم، تعالوا نتطلع
+
+563
+00:43:52,700 --> 00:43:55,220
+هو جالي أربعة و خمسة و تسعين هي قيمة اللي طلعت في
+
+564
+00:43:55,220 --> 00:43:57,840
+الجدول كله هي الأربعة و خمسة و تسعين مش هيك؟
+
+565
+00:43:57,840 --> 00:44:02,360
+معناته عمل بال S1 عمل سبع تجارب فهي ستة اللي هي
+
+566
+00:44:02,360 --> 00:44:06,980
+degrees of freedom وعمل ستة تجارب بال .. بالتاني
+
+567
+00:44:06,980 --> 00:44:11,560
+معايا يعني بس يعني حاجة إضافية مش أكتر بس أنا من
+
+568
+00:44:11,560 --> 00:44:12,420
+قيمة ال F
+
+569
+00:44:31,120 --> 00:44:37,880
+مش لإن، ماشي يا شباب، نعم، ماشي
+
+570
+00:44:42,290 --> 00:44:47,050
+استاذ احنا مش قلت انت ال variance هو مربع ال
+
+571
+00:44:47,050 --> 00:44:50,330
+standard variation صحيح طيب هنا جالنا ال variance
+
+572
+00:44:50,330 --> 00:44:54,370
+دغري يعني هي مربع مش هي مربعة طبعا طبعا لان اعطاك
+
+573
+00:44:54,370 --> 00:44:59,070
+ال variance صحيح صحيح هذا كلام و مرات كتير انا في
+
+574
+00:44:59,070 --> 00:45:02,570
+الامتحان بجيبكم ال variance و شباب كتير بيربعوه
+
+575
+00:45:02,570 --> 00:45:05,570
+فال variance لأ يعني ال variance هو مربع already
+
+576
+00:45:05,570 --> 00:45:13,780
+يعنيطيب يا شباب يعني هو اللي جالنا في السؤال هى و
+
+577
+00:45:13,780 --> 00:45:18,040
+جالنا if the tabulated if هى هى مجدولة أربعة و
+
+578
+00:45:18,040 --> 00:45:18,680
+خمسة و تسعين
+
+579
+00:45:25,410 --> 00:45:29,190
+أه أه بيقول أنه ال variance هي عبارة عن S تربية
+
+580
+00:45:29,190 --> 00:45:33,630
+فلما نقولك variance هي مربعة جاهزة اتربعهاش كمان
+
+581
+00:45:33,630 --> 00:45:39,230
+مرة بس هي مربعة و جاهزة طيب يا شباب بتمنى ان شاء
+
+582
+00:45:39,230 --> 00:45:43,030
+الله انه يعني تكونوا استفدتوا من المعلومات اللي
+
+583
+00:45:43,030 --> 00:45:46,250
+أخدناها اكفايا الحصة هذه وإذا الله راضي الحصة
+
+584
+00:45:46,250 --> 00:45:49,010
+الجاية بنستكمل ال data handling
+
diff --git a/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/MYMWKyuV7H0_raw.srt b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/MYMWKyuV7H0_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..70be720659bff850090f2ea4d350b3df0b573a8a
--- /dev/null
+++ b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/MYMWKyuV7H0_raw.srt
@@ -0,0 +1,2348 @@
+1
+00:00:21,450 --> 00:00:24,010
+بسم الله الرحمن الرحيم طيب يا شباب اليوم ان شاء
+
+2
+00:00:24,010 --> 00:00:26,850
+الله بنتكلم عن او بنستكمل الحديث عن ال
+
+3
+00:00:26,850 --> 00:00:30,310
+stoichiometric calculations و بعدين هنتكلم عن
+
+4
+00:00:30,310 --> 00:00:33,230
+موضوع رئيسي اللي هو ال back titrations لكن في
+
+5
+00:00:33,230 --> 00:00:35,710
+البداية خلينا نراجع بس مع بعض ايش الكلام اللي كنا
+
+6
+00:00:35,710 --> 00:00:40,010
+درسناه في الحصة الماضية كنا بنقول انه عشان نحل اي
+
+7
+00:00:40,010 --> 00:00:43,730
+مسألة في
+
+8
+00:00:43,730 --> 00:00:47,490
+ال stoichiometric calculations الاصل انه بداية
+
+9
+00:00:47,490 --> 00:00:53,880
+نكتب المعادلة صحنكتب المعادلة موزونة بعدين بنشوف
+
+10
+00:00:53,880 --> 00:00:59,350
+أكم عدد من لمولات Aوأكم عدد ملي مولات P و بنقول
+
+11
+00:00:59,350 --> 00:01:03,550
+أكم ملي مول من A بساوي أكم ملي مول من B أو عدد ملي
+
+12
+00:01:03,550 --> 00:01:07,090
+مولات A بالنسبة لعدد ملي مولات B يعني بنعمل برضه
+
+13
+00:01:07,090 --> 00:01:11,510
+معادلة تانية وبعدين بنعوض عن الملي مول بأحد حاجتين
+
+14
+00:01:11,510 --> 00:01:16,530
+يا إما molarity ال volume يا إما milligram على
+
+15
+00:01:16,530 --> 00:01:21,570
+الفورمولويت ناخد بعض الأمثلة الآناللي بتستخدم
+
+16
+00:01:21,570 --> 00:01:25,310
+Stoichiometries مختلفة عن الـ Stoichiometries اللي
+
+17
+00:01:25,310 --> 00:01:31,190
+خدناها الحصة الماضية بس زيادة في التأكيد على طريقة
+
+18
+00:01:31,190 --> 00:01:35,390
+الحل باستخدام الـ minimal concept فحين نطلع على
+
+19
+00:01:35,390 --> 00:01:39,270
+المسألة التالية المسألة التالية بتقول find the
+
+20
+00:01:39,270 --> 00:01:43,720
+volume of 0.1 molar potassium permanganatethat
+
+21
+00:01:43,720 --> 00:01:48,620
+will react with 50 ml of 0.2 molar H2O2 يعني عندنا
+
+22
+00:01:48,620 --> 00:01:53,440
+البرمجانات فعل مع ال H2O2 وبالمناسبة يعني هذه
+
+23
+00:01:53,440 --> 00:01:59,360
+طريقة قياسية لتقدير او لتحديد تركيز ال H2O2 بفعل
+
+24
+00:01:59,360 --> 00:02:05,050
+ال H2O2 عادة مع standard permanganate solutionعشان
+
+25
+00:02:05,050 --> 00:02:10,250
+احصل على تركيز ال H2O2 فالمعادلة عندي خمسة H2O2 مع
+
+26
+00:02:10,250 --> 00:02:13,250
+اتنين permanganate في acidic solution بتعطيني
+
+27
+00:02:13,250 --> 00:02:18,490
+النواتج المعادلة موزونة بقول من المعادلة مباشرة
+
+28
+00:02:18,490 --> 00:02:22,690
+دائما مفتاح الحل عندي الميلي مولز بقول والله
+
+29
+00:02:22,690 --> 00:02:29,890
+الميلي مول H2O2 بده يساوي خمسة على اتنين ميلي مولز
+
+30
+00:02:29,890 --> 00:02:34,520
+permanganate لان ميلي مولز H2O2 أكبرمش هيك او اني
+
+31
+00:02:34,520 --> 00:02:38,980
+اقول millimol H2O2 على خمسة تساوي millimol
+
+32
+00:02:38,980 --> 00:02:43,620
+permanganate على اتنين والان بدي اعوض عن ال
+
+33
+00:02:43,620 --> 00:02:46,140
+millimol اذا بدي اقول millimol هو milligram على
+
+34
+00:02:46,140 --> 00:02:48,780
+الفورمولوية او molarity of volume طبعا اللي مافيش
+
+35
+00:02:48,780 --> 00:02:53,510
+عندنا غير molarities of volumeبالنسبة للبرمجانات
+
+36
+00:02:53,510 --> 00:02:57,750
+ال molarity لها point one ال volume مجهول بالنسبة
+
+37
+00:02:57,750 --> 00:03:03,010
+ل ال H2O2 عند ال molarity point two ال volume
+
+38
+00:03:03,010 --> 00:03:06,850
+fifty mil طبعا ال stoichiometric factor اللي عندى
+
+39
+00:03:06,850 --> 00:03:12,430
+اتنين على خمسة فال volume بال mil للبرمجانات بيطلع
+
+40
+00:03:12,430 --> 00:03:20,260
+اربعين milمسألة تانية نتطلع على تفاعل المنجاني
+
+41
+00:03:20,260 --> 00:03:24,360
+السلفات مع ال potassium permanganate فبيقول find
+
+42
+00:03:24,360 --> 00:03:28,800
+the volume of 0.1 molar permanganate solution that
+
+43
+00:03:28,800 --> 00:03:33,400
+will react with 50 ml of 0.2 molar منجاني السلفات
+
+44
+00:03:33,900 --> 00:03:37,340
+According to the following equation نعطينا تلاتة
+
+45
+00:03:37,340 --> 00:03:42,020
+منجاني الصلفية زي اتنين per منجانية بقول ببساطة
+
+46
+00:03:42,020 --> 00:03:44,040
+خلاص هو بده ال mill per منجانية عشان يخل ال per
+
+47
+00:03:44,040 --> 00:03:47,100
+منجانية على اليسار فبقول والله ال mill mole per
+
+48
+00:03:47,100 --> 00:03:51,680
+منجانية على ايش على اتنين بتساوي ال mill mole
+
+49
+00:03:51,680 --> 00:03:55,430
+منجانية الصلفية علىتلاتة فبتطلع الميلي مول
+
+50
+00:03:55,430 --> 00:03:59,770
+بيرمينجانيت هي اتنين على تلاتة لأنه البرمينجانيت
+
+51
+00:03:59,770 --> 00:04:03,490
+اقل من الصلفيت وضع طبيعي اللي هتكون كسر
+
+52
+00:04:03,490 --> 00:04:07,950
+البرمينجانيت اتنين والصلفيت تلاتة فبتكون الميلي
+
+53
+00:04:07,950 --> 00:04:13,910
+مول بيرمينجانيت اتنين على تلاتة ميلي مولالان
+
+54
+00:04:13,910 --> 00:04:17,690
+الخطوة البديهية انه بدنا نعوض من الملي مول
+
+55
+00:04:17,690 --> 00:04:21,050
+مولاراتيف volume او ملي جرام على الفورمولوهات
+
+56
+00:04:21,050 --> 00:04:24,550
+ومافيش اي حاجة تلتقلهم طبعا التعويض مولاراتيف
+
+57
+00:04:24,550 --> 00:04:27,630
+volume لان عندي انا molarities of volumes بطلع ال
+
+58
+00:04:27,630 --> 00:04:35,310
+volume بالمل بساوي 66.7 مل من البرمجاناتنطلع على
+
+59
+00:04:35,310 --> 00:04:40,030
+اخر مثال انا ممكن يمور معانا حاله والمثال كمان من
+
+60
+00:04:40,030 --> 00:04:43,990
+ناحية عملية كتير مهم بالنسبة ليه المثال بتحدث عن
+
+61
+00:04:43,990 --> 00:04:48,990
+معايرة ال permanganate بال oxalic acid عادة يا
+
+62
+00:04:48,990 --> 00:04:54,090
+شباب ال permanganate لما نبدأ أجي أحضرها من solid
+
+63
+00:04:54,090 --> 00:04:58,870
+فبتكون مش standard solid مش primary standardلأن
+
+64
+00:04:58,870 --> 00:05:03,070
+فيها جزء من الشوائب عادة بيكون وبعض ال catalyst
+
+65
+00:05:03,070 --> 00:05:08,030
+اللي يعني ممكن تعمل مشاكل فعادة يعني ال
+
+66
+00:05:08,030 --> 00:05:11,370
+permanganate اللي انا بحضرها من وزن كمية معينة من
+
+67
+00:05:11,370 --> 00:05:14,590
+ال permanganate في حجم معين مش standard solution
+
+68
+00:05:14,590 --> 00:05:19,330
+طب ها كيف بدي اعملها standardization او ان اعيرها
+
+69
+00:05:19,330 --> 00:05:25,010
+اطلع يعني تركيزها بشكل دقيق جال والله باعيرها مع
+
+70
+00:05:25,010 --> 00:05:29,990
+ال oxalic acidهذا standard procedure على أي حال
+
+71
+00:05:29,990 --> 00:05:32,870
+احنا مابهمناش هذا كلب حيمور معانا في المستقبل لكن
+
+72
+00:05:32,870 --> 00:05:37,010
+الآن بنقول find the volume of 0.1 molar potassium
+
+73
+00:05:37,010 --> 00:05:40,810
+permanganate that will react with 500 milligrams
+
+74
+00:05:40,810 --> 00:05:46,780
+of oxalic acid H2C2O4حسب المعادلة اللى معانا وحسب
+
+75
+00:05:46,780 --> 00:05:50,460
+المعادلة في عندى خمسة oxalic acid مع اتنين
+
+76
+00:05:50,460 --> 00:05:54,560
+permanganate في acidic solution بيعطينى النواتج
+
+77
+00:05:54,560 --> 00:05:58,580
+فبقول والله ال permanganate الملي مول permanganate
+
+78
+00:05:58,580 --> 00:06:02,480
+على اتنين بتساوى الملي مول oxalic acid على خمسة
+
+79
+00:06:02,480 --> 00:06:06,900
+يعنى الملي مول permanganate بتساوى اتنين على خمسة
+
+80
+00:06:06,900 --> 00:06:12,040
+من ال oxalic acid الان ال permanganate molarity of
+
+81
+00:06:12,040 --> 00:06:15,800
+volume لأنه معطينى اصلاالمدارة تبعتها فبد
+
+82
+00:06:15,800 --> 00:06:19,200
+البرمجانات بقول مدارة ال volume بد ال millimole of
+
+83
+00:06:19,200 --> 00:06:22,620
+oxalic acid معطيني milligram اذا ال milligram على
+
+84
+00:06:22,620 --> 00:06:27,340
+ال formula weight فبيطلع عند ال volume بالمل اتنين
+
+85
+00:06:27,340 --> 00:06:30,500
+و عشرين و اتنين من عشرة مل من ال potassium
+
+86
+00:06:30,500 --> 00:06:34,740
+برمجانات بعتقد انا انه يعني انواع الاسئلة اللي
+
+87
+00:06:34,740 --> 00:06:40,480
+درسناها و التفاعلات اللي شوفناها في الأمثلة يعني
+
+88
+00:06:41,490 --> 00:06:45,750
+بتمثل تقريبا معظم أنواع الأسئلة اللي هتمر عليك في
+
+89
+00:06:45,750 --> 00:06:48,710
+.. في ما يتعلق بال Stoichiometric Calculations
+
+90
+00:06:48,710 --> 00:06:52,950
+يعني أنواع الأسئلة كأنواع أسئلة و كمعادلات معظم
+
+91
+00:06:52,950 --> 00:06:56,750
+الحاجات يعني شبيهة جدا بهذا الكلام لك كل مفهومها
+
+92
+00:06:56,750 --> 00:07:00,810
+كل مفهوم الحل يتوقف على إنك والله عندك معادلةمنها
+
+93
+00:07:00,810 --> 00:07:04,250
+بتجيب عدد مولات A، إيش بتساوي من عدد مولات B،
+
+94
+00:07:04,250 --> 00:07:09,730
+وبعدين بتعوض عن عدد ال millimoles بإما moderative
+
+95
+00:07:09,730 --> 00:07:13,150
+volume أو milligram على ال formula و إيه.الأن
+
+96
+00:07:13,150 --> 00:07:17,670
+خلينا نتطلع على موضوعنا الرئيسي اللي هو ال back
+
+97
+00:07:17,670 --> 00:07:22,080
+titrationsالـ Back titrations تعتبر معايرة غير
+
+98
+00:07:22,080 --> 00:07:29,440
+مباشرة، معايرة غير مباشرة، كويس، يتم خلالها إضافة
+
+99
+00:07:29,440 --> 00:07:36,780
+زيادة من مادة معينة على الانالايت فبتتفاعل معاه،
+
+100
+00:07:36,780 --> 00:07:40,780
+وبما إنها زيادة بزيد جزء منها، فأنا بعير الجزء
+
+101
+00:07:40,780 --> 00:07:47,440
+الزيادة مع titrant معين بتفاعل معاهطيب، هنشوف برضه
+
+102
+00:07:47,440 --> 00:07:50,740
+تفاصيل هذا الكلام الآن، لكن في البداية خلينا نقول
+
+103
+00:07:50,740 --> 00:07:55,160
+إيش حاجتنا إحنا لل back titration؟ ليش يعني نروح
+
+104
+00:07:55,160 --> 00:07:57,840
+لل back titration؟ طب ما نعاير معينة مباشرة، و
+
+105
+00:07:57,840 --> 00:08:02,560
+نريح راسنا، ليش نضيف excess على ال analyte، و
+
+106
+00:08:02,560 --> 00:08:05,540
+الزيادة بعد التفاعل، بعد ما يتفاعل هذه المادة
+
+107
+00:08:05,540 --> 00:08:08,200
+التفاعل مع ال analyte، الزيادة منها هي اللي
+
+108
+00:08:08,200 --> 00:08:13,930
+نعايرها مع مادة تالتة، ليش؟بنقول يعني طب نروح
+
+109
+00:08:13,930 --> 00:08:17,510
+لمعايرة مباشرة، بنقول لأ في أسباب بتجبرنا أن نروح
+
+110
+00:08:17,510 --> 00:08:25,190
+لل back titration من هذه الأسباب مثلا أنه يعني
+
+111
+00:08:25,190 --> 00:08:29,950
+التفاعل المعايرة معروف، لازم يكون تفاعل سريع، طب
+
+112
+00:08:29,950 --> 00:08:34,130
+على فرض التفاعل عندي مش سريع، على فرض أنه التفاعل
+
+113
+00:08:34,130 --> 00:08:39,530
+عندي مش تفاعل سريع، تفاعل بطيء زي إيش؟ زي مثلا ما
+
+114
+00:08:39,530 --> 00:08:41,450
+يكون في عندي cobalt
+
+115
+00:08:45,810 --> 00:08:53,570
+الـ Cobalt لو بده عيره بالـ EDTA مباشرةً هذا
+
+116
+00:08:53,570 --> 00:08:59,210
+تفاعل بطيء أو حتى يعني .. يعني بشكل هناخده بعد
+
+117
+00:08:59,210 --> 00:09:06,190
+شوية لو كان في عيننا Acromion تفاعل بطيءكويس مع ال
+
+118
+00:09:06,190 --> 00:09:11,730
+EDTA فلو حطيتى .. مدى حط نقطة نقطة معنا الكلام مش
+
+119
+00:09:11,730 --> 00:09:17,790
+.. يعني فقدت معيار مهم من معايير ال .. ال
+
+120
+00:09:17,790 --> 00:09:20,990
+titration reaction انه التفاعل لازم يكون سريع طب
+
+121
+00:09:20,990 --> 00:09:26,250
+ايش ممكن اعمل؟ جال والله بسهولة جدا ممكن احنا ناخد
+
+122
+00:09:26,250 --> 00:09:30,050
+EDTA زيادة ونضيفها على
+
+123
+00:09:33,510 --> 00:09:38,710
+بنضيفها على الكوبرت او الكروميان فبحصل على التفاعل
+
+124
+00:09:38,710 --> 00:09:42,850
+تم كل التفاعل فورا لان انا اضافت كمية كبيرة من ال
+
+125
+00:09:42,850 --> 00:09:51,370
+EDTA و زاد عندي EDTA الان ال EDTA اللي زادت بقى
+
+126
+00:09:51,370 --> 00:09:55,590
+عيرها مع metal ions زي مثلا المجنيزيوم
+
+127
+00:09:57,830 --> 00:10:02,050
+كويس فانا اتغلبت على ان التفاعل EDTA مع الكوبالد
+
+128
+00:10:02,050 --> 00:10:08,470
+تفاعل اشماله بطيء يعني هذا احد الأحوال اللي انا
+
+129
+00:10:08,470 --> 00:10:11,910
+بضطر ان اعمل فيها back titration وإلا لو كانت
+
+130
+00:10:11,910 --> 00:10:15,370
+المعايير المباشرة جيدة لقاش اروح لل back titration
+
+131
+00:10:15,370 --> 00:10:20,930
+بعير مباشرة مثلا هذا احد الأحوال في بعض الأحيان حل
+
+132
+00:10:20,930 --> 00:10:26,410
+او يعني مشكلة تانية انا على فرض ناخد برضه الكوبالد
+
+133
+00:10:28,200 --> 00:10:36,720
+الكوبلت لو بده اعيره بال EDTA مباشرة او الكمر لو
+
+134
+00:10:36,720 --> 00:10:42,360
+بده اعيره بال EDTA مباشرة فاش indicator مناسب يعني
+
+135
+00:10:42,360 --> 00:10:47,680
+مافيش عندي indicator دقيق طب ايش بده اعمل؟ بقول
+
+136
+00:10:47,680 --> 00:10:51,360
+والله التفاعل منفعش يكون تفاعل معايرة لكن ايش بحصل
+
+137
+00:10:51,360 --> 00:10:57,440
+لو انا ايضا اضفت ال excess EDTA
+
+138
+00:11:00,520 --> 00:11:05,320
+بحيث انه اتفاعل وزادله شوية EDTA ال EDTA لان
+
+139
+00:11:05,320 --> 00:11:09,840
+بعيارها مع اشي اللي له indicator مناسب زي ال zinc
+
+140
+00:11:09,840 --> 00:11:14,120
+ال zinc مع ال EDTA ال indicator تبقى ممتاز يفجأة
+
+141
+00:11:14,120 --> 00:11:21,000
+انا اتغلبت على عدم وجود indicator مناسب ماشي يا
+
+142
+00:11:21,000 --> 00:11:25,120
+شباب اذا برضه ال back titrations تعتبر ممتازة اذا
+
+143
+00:11:25,120 --> 00:11:31,480
+مافيش عندي indicator مناسب ناخد حالة تالتةأفرض إن
+
+144
+00:11:31,480 --> 00:11:38,320
+في عندى مادة A بتتعير مع مادة B، بتتعيرها مع مادة
+
+145
+00:11:38,320 --> 00:11:45,180
+B، لكن للأسف، للأسف، المادة A، حتى لو ما أضفتش
+
+146
+00:11:45,180 --> 00:11:48,620
+عليها أي بي، مع الوجه التعمالت، تتكسر، يعني هي
+
+147
+00:11:48,620 --> 00:11:52,820
+مادة مش ثابتةهي مادة مش ثابتة لو بدى اعير اثناء
+
+148
+00:11:52,820 --> 00:11:56,640
+انا باعير اه بتتفعل a مع b لكن ايضا اثناء المعايرة
+
+149
+00:11:56,640 --> 00:12:00,820
+a بتتفكك لحاجات تانية يبقى انا بفقدها يبقى معنا
+
+150
+00:12:00,820 --> 00:12:04,540
+الكلام ال volume اللي راح اضيفه من b لا يتناسب مع
+
+151
+00:12:04,540 --> 00:12:11,060
+كمية a اللي اتفعلت لأن جزء منها بالفعل اتكسر او مع
+
+152
+00:12:11,060 --> 00:12:15,220
+كمية a الموجودة اصلا لأن جزء منها اتكسر طب هيش
+
+153
+00:12:15,220 --> 00:12:23,810
+ممكن اعمل جال ممكن اضيف انا فورابعلى a excess ب
+
+154
+00:12:23,810 --> 00:12:29,170
+بمجرد ماحط a مستبهاش تتكسر فورا بمجرد ماضيف اضيف
+
+155
+00:12:29,170 --> 00:12:33,610
+عليها ب فروحت اتفاعل كلها اتفاعلت زاد هنا ب ممكن
+
+156
+00:12:33,610 --> 00:12:39,640
+افعله مع مادة cأه C يعني B ثابتة ففعلا مع مادة
+
+157
+00:12:39,640 --> 00:12:43,220
+ثابتة C إذا أنا اتغلبت على كون المادة اللي بدي
+
+158
+00:12:43,220 --> 00:12:47,580
+أعيرها هي مادة غير ثابتة فيعني واضح من هذا الكلام
+
+159
+00:12:47,580 --> 00:12:53,640
+يا شباب أنه في عندنا أحوال بضطر أنا أنه أستخدم ال
+
+160
+00:12:53,640 --> 00:12:56,900
+back titrationهذه الأحوال قلنا في حالة ما يكون
+
+161
+00:12:56,900 --> 00:13:00,440
+التفاعل بطيق سهل جدا استخدام ال back titration في
+
+162
+00:13:00,440 --> 00:13:05,740
+حالة ما انه ماعندي كاشف مناسب برضه ممكن استخدم ال
+
+163
+00:13:05,740 --> 00:13:08,940
+back titration بسهولة يعني في حالة ما يكون عندي
+
+164
+00:13:08,940 --> 00:13:13,350
+مادة غير مستقرةبقدرش والله اعيل على مهل لأن المادة
+
+165
+00:13:13,350 --> 00:13:17,310
+بتتكسر جاعدة غير مستقرة تتحول لحاجات تانية فلازم
+
+166
+00:13:17,310 --> 00:13:21,590
+برضه استخدم ال back titrations فيعني معنى الكلام
+
+167
+00:13:21,590 --> 00:13:28,010
+في عندى أحوال يجب فيها استخدام ال back titrations
+
+168
+00:13:28,010 --> 00:13:33,690
+فكرة ال back titrations الحسابات تبعاتها فكرتها
+
+169
+00:13:33,690 --> 00:13:39,700
+كتير بسيطةاحنا بنقول بنضيف excess من المادة يعني
+
+170
+00:13:39,700 --> 00:13:46,100
+مثلا في عندنا metal ion انا حط كروميان وانا اضافت
+
+171
+00:13:46,100 --> 00:13:50,420
+عليه excess EDTA
+
+172
+00:13:50,420 --> 00:13:57,280
+فاتفاعلت مع الكروميان وصار في عندي hand شوية EDTA
+
+173
+00:13:57,280 --> 00:14:00,860
+بعاير
+
+174
+00:14:00,860 --> 00:14:07,250
+ال EDTA لزيادة مثلا الزنكخدوا بالكم بقول ال excess
+
+175
+00:14:07,250 --> 00:14:10,430
+EDTA هذي اللي انا اضفتها معروف جداش كمية معلومة
+
+176
+00:14:10,430 --> 00:14:14,510
+والتكن مثلا عشرة millimoles اذا كان فيه اتنين
+
+177
+00:14:14,510 --> 00:14:18,470
+اتفعلوا مع الكروميا مجدش زاد تمانية تمانية هم اللي
+
+178
+00:14:18,470 --> 00:14:22,210
+بدهم اتعيروا اذا كان فيه سبعة اتفعلوا مع الكروميا
+
+179
+00:14:22,210 --> 00:14:27,830
+مجدش زاد تلتة هم اللي بدهم اتعيروا بمعنى اخر ال
+
+180
+00:14:27,830 --> 00:14:31,550
+millimoles من ال reagent اللي هو في هذه الحالة
+
+181
+00:14:31,550 --> 00:14:35,950
+EDTA taken اللي احنا اضفناه ال excessبدي يساوي
+
+182
+00:14:35,950 --> 00:14:42,290
+حاجتين او انقسم لقسمين جزء تفاعل وجزء تعير الكل
+
+183
+00:14:42,290 --> 00:14:46,570
+يساوي مجموعة الجزءين اللي تفاعل زائد اللي تعير او
+
+184
+00:14:46,570 --> 00:14:52,190
+بمعنى اخر اللي اتفاعل
+
+185
+00:14:52,190 --> 00:14:56,250
+بساوي الكل ناقص اللي تعير اذا كان الكل بساوي اللي
+
+186
+00:14:56,250 --> 00:15:02,160
+اتفاعل زائد اللي تعيرالاتفاعل بدي ساوي الكلي اللي
+
+187
+00:15:02,160 --> 00:15:06,540
+هو ال reagent taken minus ال millimole reagent
+
+188
+00:15:06,540 --> 00:15:13,060
+titrated، ماشي يا شباب؟ هذا هو أساس الحل، قلنا
+
+189
+00:15:13,060 --> 00:15:16,600
+عشان نستكمل صورة الحل، ال millimole reagent
+
+190
+00:15:16,600 --> 00:15:20,460
+reacted، بقول طب هو اتفعل مع إيش؟أتفاعل مع
+
+191
+00:15:20,460 --> 00:15:24,280
+الانالايت، مع المادة المجهولة تبعتي، إذا بدي أحوله
+
+192
+00:15:24,280 --> 00:15:28,040
+لملي مول انالايت، كيف بدي أحوله لملي مول انالايت؟
+
+193
+00:15:28,040 --> 00:15:32,100
+بدي أستخدم معادلة التفاعل، لأن هو أتفاعل مع
+
+194
+00:15:32,100 --> 00:15:35,060
+الانالايت، كيف بدي أحول الملي مول reaction زي ال
+
+195
+00:15:35,060 --> 00:15:39,980
+EDTA مثلا؟ كيف بدي أحوله لملي مول انالايت؟جال بدّي
+
+196
+00:15:39,980 --> 00:15:44,720
+معادلة التفاعل، طيب ال minimum taken معروف، أنا
+
+197
+00:15:44,720 --> 00:15:48,940
+أضافت كمية معينة، بزيادة، أضافت كمية معينة، طب ال
+
+198
+00:15:48,940 --> 00:15:52,320
+minimum reagent titrated، طب مع إيش هو اتعير؟
+
+199
+00:15:52,320 --> 00:15:57,010
+اتعير مع ال titrantإذا بدي استخدم معادلة المعايرة
+
+200
+00:15:57,010 --> 00:16:00,810
+عشان أعوض عن الـ millimole reaction titrated
+
+201
+00:16:00,810 --> 00:16:06,070
+بالmillimole titrant، يبقى في حاجتين، بدي أعوض عن
+
+202
+00:16:06,070 --> 00:16:10,070
+ال millimole reaction reacted بالmillimole analyte
+
+203
+00:16:16,630 --> 00:16:20,490
+هذا الشغل تبعي بكون هيك خلاص بعدين يعني التعوض عن
+
+204
+00:16:20,490 --> 00:16:23,510
+الميلي مول يا اما molar volume يا اما ميلي جرام
+
+205
+00:16:23,510 --> 00:16:25,470
+على ال form على ال form
+
+206
+00:16:29,320 --> 00:16:35,060
+نجي نطلع على مثال كتير بسيط بدنا ناخد الحالة اللي
+
+207
+00:16:35,060 --> 00:16:39,240
+حاجتين بتفعلوا فيها بنسبة واحد لواحد اللي هي ال
+
+208
+00:16:39,240 --> 00:16:43,460
+EDTA أحلى حاجة ممكن نتعامل معاها ال EDTA فخلينا
+
+209
+00:16:43,460 --> 00:16:47,640
+نشوف المثال التالي بيقول ايه two point sixty three
+
+210
+00:16:47,640 --> 00:16:51,200
+grams of chromium sample was dissolved and
+
+211
+00:16:51,200 --> 00:16:56,140
+analyzed by addition of five mil of 0.0103 molar
+
+212
+00:16:56,140 --> 00:16:58,100
+EDTA يعني انا في عندى
+
+213
+00:17:01,390 --> 00:17:08,250
+الـ Chromium تلاتة حطيت عليه خمسمل
+
+214
+00:17:08,250 --> 00:17:17,970
+of 0.0103 molar EDTA فاتفاعلت مع ال Chromium و زاد
+
+215
+00:17:17,970 --> 00:17:23,870
+عندي EDTA لأ ماعرفش جدش زاد يا شباب لما عيارت ال
+
+216
+00:17:23,870 --> 00:17:35,050
+EDTA هذا مع ال zincأخدت من الزنك 1.32 ميل أو 0
+
+217
+00:17:35,050 --> 00:17:43,910
+.0112 مولار كمان مرة انا حطيت هذه الكمية على ايه؟
+
+218
+00:17:43,910 --> 00:17:48,530
+على الكروميام فاتفاعلت مع الكروميام خلص الكروميام
+
+219
+00:17:48,530 --> 00:17:54,990
+زاد شوية EDTA كيف بده اعرف اللي زاد؟ بعايره من
+
+220
+00:17:54,990 --> 00:17:58,770
+نتيجة المعايا باعرف اللي زاد صح ولا لأ؟طيب، إيش
+
+221
+00:17:58,770 --> 00:18:03,030
+بقول عشان أحل المسألة؟ بقول الملي مول EDTA reacted
+
+222
+00:18:03,030 --> 00:18:12,690
+اللي اتفعل بساوي الكلي ناقص اللي اتعاير، هيو ولاحظ
+
+223
+00:18:12,690 --> 00:18:17,790
+معايا المعادلة إيش بتقول؟ ملي مول EDTA reactedملي
+
+224
+00:18:17,790 --> 00:18:24,890
+مول EDTA taken يعني كلها دالة في ايه؟ في ال EDTA
+
+225
+00:18:24,890 --> 00:18:29,590
+لازم المعادلة اللي بتكونها كلها تكون دالة في نفس
+
+226
+00:18:29,590 --> 00:18:34,730
+المادة اللي هي ال excess بعدين بتحول ال reacted
+
+227
+00:18:34,730 --> 00:18:37,870
+تشوف والله reacted مع إيش ال titrated تشوف والله
+
+228
+00:18:37,870 --> 00:18:41,290
+ال titrated مع إيش لكن لازم المعادلة هي تكون ايه؟
+
+229
+00:18:41,290 --> 00:18:45,780
+دالة في مادة واحدة وإلا لو حصل أن ده غلطبالفعش
+
+230
+00:18:45,780 --> 00:18:49,820
+تقولي والله minimal reacted بساوي مثلا minimal et
+
+231
+00:18:49,820 --> 00:18:52,800
+نقص minimal مثلا zincake على طول لأ أول حاجة
+
+232
+00:18:52,800 --> 00:18:57,820
+اكتبها دالة في ال EDTA في ال agent ال excess بعدين
+
+233
+00:18:57,820 --> 00:19:04,830
+بدنا نحول ال reacted طب اتفعل مع ايه؟تعير مع ايه؟
+
+234
+00:19:04,830 --> 00:19:07,930
+كويس؟ يبقى السطر كله اللي انت شايفه هو عبارة عن
+
+235
+00:19:07,930 --> 00:19:11,590
+دالة في ايه؟ في مادة واحدة اللي هي ايه؟ الزيادة،
+
+236
+00:19:11,590 --> 00:19:15,590
+الآن بنقول والله احنا بنعرف خصاص ال EDTA الـ
+
+237
+00:19:15,590 --> 00:19:19,010
+millimole EDTA reacted اتفاعل مع الكروميوم مليمول
+
+238
+00:19:19,010 --> 00:19:22,410
+كروميوم كلورايد تلاتة، مادام هذه الكروميوم واحدة،
+
+239
+00:19:22,410 --> 00:19:27,270
+اه اذا مليمول بيساوي مليمولأيضا الملي مول EDTA
+
+240
+00:19:27,270 --> 00:19:31,230
+تيتريتد بساوة الملي مول زنك لأنه برضه EDTA تتفاعل
+
+241
+00:19:31,230 --> 00:19:36,290
+مع الزنك بنسبة 1 ل 1 اذا الان باجي بعود بقول الملي
+
+242
+00:19:36,290 --> 00:19:41,270
+مول EDTA تيتريتد ايش حطيت بداله ايه reacted عفوا
+
+243
+00:19:41,270 --> 00:19:46,670
+ايش حطيت بداله ملي مول اكروميوم اكلورايدأه انه نفس
+
+244
+00:19:46,670 --> 00:19:52,410
+العدد هنا شيبناها من هنا و ال millimol edta tight
+
+245
+00:19:52,410 --> 00:19:58,670
+rated حطينا بدلها millimol zinc لأنه بتسوي الان يا
+
+246
+00:19:58,670 --> 00:20:03,610
+شباب انا عندي ال taken خمسة في point O one O three
+
+247
+00:20:03,610 --> 00:20:07,350
+ال millimol zinc one point three two في point O
+
+248
+00:20:07,350 --> 00:20:10,810
+one one two اذا بجيب ال millimol chromium اكلورايد
+
+249
+00:20:10,810 --> 00:20:15,520
+بضربها في ال formula و يتقش بتعطينيميلي جرام
+
+250
+00:20:15,520 --> 00:20:18,900
+اكروميا ميكلورايد او انه على طول ممكن اقول هان
+
+251
+00:20:18,900 --> 00:20:24,580
+والله ميلي جرام اكروميا ميكلورايد على one fifty
+
+252
+00:20:24,580 --> 00:20:28,000
+eight point four اللي هو ال formula weight هي ميلي
+
+253
+00:20:28,000 --> 00:20:33,340
+جرام على ال formula هي الميلي مول بتساوي point O
+
+254
+00:20:33,340 --> 00:20:41,620
+one O three في خمسة minus one اللي هي point O one
+
+255
+00:20:41,620 --> 00:20:48,420
+one twoفي 1.32 خطوة واحدة بتطلع منها الميلي جرام
+
+256
+00:20:48,420 --> 00:20:51,100
+اكراميوم اكلورايد بتفرح هدول من بعض في الأوقت روم
+
+257
+00:20:51,100 --> 00:20:55,880
+158.4 الفورمولاوية بتطلع عندك الميلي جرام اكراميوم
+
+258
+00:20:55,880 --> 00:20:59,160
+اكلورايد بتجسمها على وزن العينا بالميلي جرام في
+
+259
+00:20:59,160 --> 00:21:04,940
+100 من 100 بتطلع عندك ال percentage ماشي يا شباب
+
+260
+00:21:04,940 --> 00:21:12,280
+فهي الحل يعني كيف انا حليتها طلعت الميلي مول
+
+261
+00:21:12,280 --> 00:21:17,550
+اكراميوم اكلورايد الفرقفجبت قيمته ضربته في ال
+
+262
+00:21:17,550 --> 00:21:22,290
+formula weight حولته لميلي جرام جسمته على وزدة
+
+263
+00:21:22,290 --> 00:21:25,870
+العينة بالميلي جرام في مية من مية بيطلع ان النسبة
+
+264
+00:21:25,870 --> 00:21:28,850
+المئوية لل chromium chloride في العينة اتنين من
+
+265
+00:21:28,850 --> 00:21:33,270
+عشرة في المية طبعا هذا أبسط أنواع ال back
+
+266
+00:21:33,270 --> 00:21:37,190
+titrations لما نتكون اندي النسبة عبارة عن واحد
+
+267
+00:21:37,190 --> 00:21:41,310
+لواحد لكن لو كانت النسبة مش واحد لواحد بدي يكون
+
+268
+00:21:41,310 --> 00:21:44,510
+عندنا جثة تانية انشوف انشوف
+
+269
+00:21:47,840 --> 00:21:53,700
+نشوف المعادلة او المثال التالي اللى جدامى بيقول فى
+
+270
+00:21:53,700 --> 00:21:58,080
+عندى نص جرام sample فى عندى عينة مقدرها نص جرام
+
+271
+00:21:58,080 --> 00:22:02,640
+طبعا مدام جالى عينة اذا النص هذه لا تستخدم الا
+
+272
+00:22:02,640 --> 00:22:06,980
+حساب ال percentagecontaining sodium carbonate فيها
+
+273
+00:22:06,980 --> 00:22:11,060
+العينة sodium carbonate حلو was dissolved دودناها
+
+274
+00:22:11,060 --> 00:22:15,440
+وحللناها عن طريق إضافة خمسين mil من ال point one
+
+275
+00:22:15,440 --> 00:22:22,240
+molar HCl يعني هاي في عندى sodium carbonate كويس
+
+276
+00:22:22,240 --> 00:22:30,000
+حطينا عليها خمسين mil of point one molar HCl هذا
+
+277
+00:22:30,000 --> 00:22:36,510
+هوو بعدين اتفعل معاها كلها و زاد عندى hcl اللى زاد
+
+278
+00:22:36,510 --> 00:22:44,490
+ال hcl اللى زاد عيرناه مع ال sodium hydroxide ال
+
+279
+00:22:44,490 --> 00:22:46,910
+sodium hydroxide جديش أخد من ال sodium hydroxide
+
+280
+00:22:46,910 --> 00:22:52,070
+بيقول the excess hcl ال hcl الزيادة the excess hcl
+
+281
+00:22:52,070 --> 00:22:59,530
+required خمسة وستة من عشرة mil of 0.05 molar
+
+282
+00:22:59,530 --> 00:23:09,650
+solutionتساوي يعني؟ احنا
+
+283
+00:23:09,650 --> 00:23:12,430
+لسه ماقلناش، احنا بنشرح المثلة، يعني لسه مابدلاش
+
+284
+00:23:12,430 --> 00:23:19,550
+نحل، احنا .. اسمع مني، من أول وقت هاي
+
+285
+00:23:19,550 --> 00:23:25,190
+بقولك ال .. ال excess hc اللي زاد هانجديش أخد من
+
+286
+00:23:25,190 --> 00:23:29,070
+المعايرة خمسة لستة من عشرة مل من point oh five
+
+287
+00:23:29,070 --> 00:23:32,770
+molar sodium hydroxide اتفاعل معاه بالظبط يعني او
+
+288
+00:23:32,770 --> 00:23:37,410
+يعني نتيجة المعايرة هالجد فانا عندى sodium
+
+289
+00:23:37,410 --> 00:23:42,970
+carbonate نص جرام دوّبته وحطيت عليه خمسين مل من ال
+
+290
+00:23:42,970 --> 00:23:47,030
+HCl تركيزه point one molar اتفاعل معاه كله زاد HCl
+
+291
+00:23:47,030 --> 00:23:53,150
+ال HCl اللي زادعيرته مع ال sodium hydroxide فاخد
+
+292
+00:23:53,150 --> 00:23:55,970
+خمسة وستة من عشرة مل من ال sodium hydroxide اللي
+
+293
+00:23:55,970 --> 00:24:01,130
+تركيزه خمسة من مية molar عايز يحسب ال percentage
+
+294
+00:24:01,130 --> 00:24:06,800
+لل sodium carbonate in the sampleكمان مرة كل أسئلة
+
+295
+00:24:06,800 --> 00:24:10,180
+ال back titration لازم يكون فيها معادلتين انتوا
+
+296
+00:24:10,180 --> 00:24:12,820
+لاحظته يمكن ال EDTA مكتبنهم مش لأنه كلنا في ال
+
+297
+00:24:12,820 --> 00:24:17,660
+EDTA مش ضرور نقطب واحد لواحد أي معادل .. أي مسألة
+
+298
+00:24:17,660 --> 00:24:20,760
+back titration يكون فيها .. فيها معادلتين معادل
+
+299
+00:24:20,760 --> 00:24:26,200
+التفاعل و معادل ال titrationreaction و titration
+
+300
+00:24:26,200 --> 00:24:29,780
+تانية فهي بيقوللي صديم كربونيت مع اتنين HCl
+
+301
+00:24:29,780 --> 00:24:34,940
+بيعطينا صديم اكلورايد او H2CO3 هذه معادلة ايه؟ال
+
+302
+00:24:34,940 --> 00:24:37,860
+reaction التفاعل مع ال sodium carbonate معادلة ال
+
+303
+00:24:37,860 --> 00:24:40,520
+titration هده هي طبعا ممكن مابتبهاش لإن ال sodium
+
+304
+00:24:40,520 --> 00:24:44,160
+hydroxide دائما مع ال HCl واحد لو واحد لكن الأصل
+
+305
+00:24:44,160 --> 00:24:47,360
+ان الكورفانه معادلتين بقول اطلعوا على السطر اللي
+
+306
+00:24:47,360 --> 00:24:52,440
+قدامي هان بقول دائما مفتاح الحل بإيه بال millimole
+
+307
+00:24:52,440 --> 00:24:57,080
+من المادة المبعفة من المادة ال excessبتكلم عن
+
+308
+00:24:57,080 --> 00:25:00,200
+الـHCl هو اللي اضافته زي كله ملي مول الـHCl
+
+309
+00:25:00,200 --> 00:25:03,360
+reacted اللي اتفاعل بساوي ال total number of
+
+310
+00:25:03,360 --> 00:25:06,980
+millimoles اللي هو ال millimoles HCl taken ناقص ال
+
+311
+00:25:06,980 --> 00:25:12,980
+millimoles كمان HCl بس ايه titrated المعاير ماشي؟
+
+312
+00:25:12,980 --> 00:25:16,260
+الآن المهمة تبعتي اني بدي اقول ال millimoles HCl
+
+313
+00:25:16,260 --> 00:25:21,310
+reacted طب هو اتفاعل معايش ال HCl اتفاعل معايشماذا
+
+314
+00:25:21,310 --> 00:25:23,550
+يجب أن يساوي؟ يجب أن يتعود عن ملي مول الـHCl
+
+315
+00:25:23,550 --> 00:25:26,910
+بالملي مول الكربونات، ماذا؟ كم ملي مول الكربونات؟
+
+316
+00:25:26,910 --> 00:25:35,090
+الـHCl 2 ملي مول صوديوم كربونات، الـHCl ضعف
+
+317
+00:25:35,090 --> 00:25:39,290
+الكربونات، الـHCl 2 بينما الكربونات 1، يبقى 2 ملي
+
+318
+00:25:39,290 --> 00:25:42,950
+مول صوديوم كربونات، نقول هنا أندي نفس الكلام الملي
+
+319
+00:25:42,950 --> 00:25:46,770
+مول HCl taken هي هي
+
+320
+00:25:55,910 --> 00:26:00,550
+الان يا شباب المسألة واضحة ممكن ان احلها بالشكل
+
+321
+00:26:00,550 --> 00:26:07,060
+التالي اتنين في الميلي جرام صوديوم كربونيدعلى مية
+
+322
+00:26:07,060 --> 00:26:14,120
+وستة بدها تساوي ال millimol HCl point one في خمسين
+
+323
+00:26:14,120 --> 00:26:21,220
+minus الميليمول Sodium hydroxide point oh five في
+
+324
+00:26:21,220 --> 00:26:25,180
+خمسة وستة المثال انحلت لأن هين هيك بنطلع ال
+
+325
+00:26:25,180 --> 00:26:31,300
+milligram Sodium carbonate ايش رأيكم يا شباب كتير
+
+326
+00:26:31,300 --> 00:26:35,840
+كتير كتير الموضوع بسيطالموضوع بسيط بس مجرد انك
+
+327
+00:26:35,840 --> 00:26:39,900
+تشوف اين ال excess تقول والله ال reacted بساوي
+
+328
+00:26:39,900 --> 00:26:44,490
+الكلينقص اللي اتعير ال reactant بده يحول ل
+
+329
+00:26:44,490 --> 00:26:47,690
+millimole analyte هو اتفاعل مع ايه؟ ماهو اتفاعل مع
+
+330
+00:26:47,690 --> 00:26:50,950
+ايه؟ اتحول ل millimole من المتفاعل اتعير طب هو
+
+331
+00:26:50,950 --> 00:26:55,050
+اتعير مع ايه؟ بده يحول ل millimole من ال titrant
+
+332
+00:26:55,050 --> 00:26:59,330
+ال millimole taken ماهو millimole taken معروف احنا
+
+333
+00:26:59,330 --> 00:27:03,090
+عضفناه كميته معروفة عندنا يعني ماتحولش لحاجة
+
+334
+00:27:03,090 --> 00:27:08,030
+فالمسألة هيك بتكون انحلة تشوف كيف نطلع على حل
+
+335
+00:27:08,030 --> 00:27:08,630
+المسألة
+
+336
+00:27:12,940 --> 00:27:16,820
+خطوة خطوة يعني بقول ملي مول HCl بسوء اتنين ملي مول
+
+337
+00:27:16,820 --> 00:27:20,380
+كربونيت، من وين؟ من المعادلة، معادلة التفاعل، طب
+
+338
+00:27:20,380 --> 00:27:23,860
+ملي مول HCl بسوء ملي مول Sodium Hydroxide، من وين؟
+
+339
+00:27:23,860 --> 00:27:27,660
+من معادلة المعايرة، الآن بنعوض، بنطلع الملي مول
+
+340
+00:27:27,660 --> 00:27:29,700
+Sodium Carbonate، طلعنا الملي مول Sodium
+
+341
+00:27:29,700 --> 00:27:32,620
+Carbonate، ضربنا فيه مية وستة الفورمولا ويتطلع
+
+342
+00:27:32,620 --> 00:27:36,380
+لملي جرام Sodium Carbonate، جسمت على وزنة العينة
+
+343
+00:27:36,380 --> 00:27:39,280
+بالملي جرام، في مية من مية بيعطينا ال percentage
+
+344
+00:27:39,280 --> 00:27:44,010
+لل Sodium Carbonate خمسين في الميةطيب نيجي ناخد
+
+345
+00:27:44,010 --> 00:27:47,690
+اخر مثال بس بدنا ناخد stoichiometry يعني كبيرة
+
+346
+00:27:47,690 --> 00:27:54,790
+شوية كتيرة شوية يعني مش يعني مباشرة نتطلع على
+
+347
+00:27:54,790 --> 00:28:03,430
+المثال التاليمهما بدت المسألة صعبة انت ابدأ دائما
+
+348
+00:28:03,430 --> 00:28:11,530
+بال excess ال excess اللى انت عرفته جزء منه اتفاعل
+
+349
+00:28:11,530 --> 00:28:15,030
+جزء منه تعير اللى اتفاعل بساوي لكل ناقص اللى اتعير
+
+350
+00:28:15,030 --> 00:28:18,930
+انتهى الموضوع بعدين بتتعود عن اللى اتفاعل تشوف
+
+351
+00:28:18,930 --> 00:28:21,910
+اتفاعل معاه يتحول ل ملي ملي متفاعل و اللى اتعير
+
+352
+00:28:21,910 --> 00:28:24,450
+اتعير معاه يتحول ل ملي ملي multi trend وانتهى
+
+353
+00:28:24,450 --> 00:28:28,200
+الموضوعلأن الملي مول بعد هيك هو molarity of volume
+
+354
+00:28:28,200 --> 00:28:31,180
+أو ملي جرام على الفورمولويت فنتطلع عليها المسألة
+
+355
+00:28:31,180 --> 00:28:36,600
+اللي قد تبدو معقدة لكن هي فيش أبسط من هيك بنقول a
+
+356
+00:28:36,600 --> 00:28:40,840
+point two gram sample containing manganese dioxide
+
+357
+00:28:40,840 --> 00:28:44,900
+was dissolved and analyzed by addition of fifty
+
+358
+00:28:44,900 --> 00:28:49,200
+mil of point one molar iron يعني في عندي manganese
+
+359
+00:28:49,200 --> 00:28:53,480
+dioxide حطينا
+
+360
+00:28:53,480 --> 00:29:03,060
+عليهخمسين ميل of point one molar F E2 طيب يبقى
+
+361
+00:29:03,060 --> 00:29:08,160
+اتفاعل معاه و بيقولك ايش حسب التفاعل اتفاعل معاه
+
+362
+00:29:08,160 --> 00:29:11,720
+بيقولك دي excess iron اتنين يعني زاد عنا كمان iron
+
+363
+00:29:11,720 --> 00:29:16,300
+اتنين يعني ال iron اتنين اتفاعل هيو لكن زاد عنا
+
+364
+00:29:16,300 --> 00:29:22,460
+كمية كبيرة فزاد جال اللي زاد عيارنا مع ايه عيارنا
+
+365
+00:29:22,460 --> 00:29:32,700
+معالـ KMnO4 ايش اخد؟ اخد 15 مل of 0.02 molar
+
+366
+00:29:32,700 --> 00:29:38,660
+solution يعني هذا اللي زاد اتعاير مع مين؟ مع الـ
+
+367
+00:29:38,660 --> 00:29:43,380
+KMnO4 كمان مرة يا شباب يعني مفتاح الحل كتير بسيط
+
+368
+00:29:43,380 --> 00:29:47,080
+هو عايز يحسب اه .. دبل ما ننتقل عايز يحسب مش
+
+369
+00:29:47,080 --> 00:29:50,460
+مانجانيز اكسايد .. دايكسايد لأ بدي يحسب مانجانيز
+
+370
+00:29:50,460 --> 00:29:55,950
+تلاتة واربعةمش مانجانيز دا يوكسايد عايز يحسب ايه؟
+
+371
+00:29:55,950 --> 00:29:58,230
+مانجانيز تلاتة و أربع أقول ايش هو اللي بده يحسب
+
+372
+00:29:58,230 --> 00:30:02,510
+انسوه انت جيبه المتفاعل و بعدين في الآخر بتحوله لل
+
+373
+00:30:02,510 --> 00:30:06,130
+.. للشكل اللي بدهيا فانتوا انسوه ايش اللي بدهيا في
+
+374
+00:30:06,130 --> 00:30:09,470
+الأول اول حاجة جيبه المتفاعل ايش المتفاعل حسب
+
+375
+00:30:09,470 --> 00:30:14,110
+المعادلة بعدين بتحول ال MnO2 للMn تلاتة و أربعة
+
+376
+00:30:14,110 --> 00:30:18,370
+كيف؟ هنشوف شفنا طبعا سابقا لكن برضه هان هنشوف في
+
+377
+00:30:18,370 --> 00:30:18,910
+البداية
+
+378
+00:30:21,840 --> 00:30:29,100
+في البداية يا شباب بنقول ايش الملي مول ايرن
+
+379
+00:30:29,100 --> 00:30:32,720
+reacted بيساوي الملي مول ايرن هيها الملي مول ايرن
+
+380
+00:30:32,720 --> 00:30:35,840
+هي ال axis يبقى الملي مول ايرن reacted بيساوي
+
+381
+00:30:35,840 --> 00:30:42,740
+الملي مول ايرن taken minus الملي مول ايرنTitrated
+
+382
+00:30:42,740 --> 00:30:46,480
+فبقول هذا اتفاعل طب هو اتفاعل مع ايه؟ اتفاعل مع
+
+383
+00:30:46,480 --> 00:30:50,580
+الميلي مول مانجانيز بيوكسايت باجي بقول والله
+
+384
+00:30:50,580 --> 00:30:54,000
+الميلي مول ايرون ايش بيساوي الميلي مول المجزرسة؟
+
+385
+00:30:54,000 --> 00:30:58,540
+اتنين ميلي مول مية المية طيب اتعاير ال iron مع ال
+
+386
+00:30:58,540 --> 00:31:01,270
+permanganate ايش بيساوي الميلي مول ال iron؟خمسة
+
+387
+00:31:01,270 --> 00:31:09,050
+ملي مول ايرون
+
+388
+00:31:09,050 --> 00:31:12,630
+بيساوي خمسة ملي مول البرمجانات الان بنعود في
+
+389
+00:31:12,630 --> 00:31:18,310
+المعادلة اللى فوق ايه بتعطينى اتنين ملي مول MnO2
+
+390
+00:31:18,310 --> 00:31:22,010
+لان محطتها بدل ملي مول ايرون هي بيساوي اتنين ملي
+
+391
+00:31:22,010 --> 00:31:26,350
+مول MnO2 بتساوي ملي مول ايرون minus خمسة ملي مول
+
+392
+00:31:26,350 --> 00:31:32,600
+برمجاناتكويس؟ الآن المسألة خلصت مجرد أنه بدنا نعوض
+
+393
+00:31:32,600 --> 00:31:36,280
+عن هدول، بعوضش عن هذا لإنه مش مطلوب، بخليه زي ما
+
+394
+00:31:36,280 --> 00:31:40,060
+هو، لكن ممكن أعوض عنه بال Mn3 و Mn4، كيف بدي أعمل
+
+395
+00:31:40,060 --> 00:31:49,340
+هذا الكلام؟ بقول، لو لاحظنا، لو لاحظنا، ال MnO2،
+
+396
+00:31:49,340 --> 00:31:53,500
+تلاتة منه بيعطون Mn3 و Mn4، صح ولا لأ؟أنا في
+
+397
+00:31:53,500 --> 00:31:58,460
+الخطوة الأولى حسبت الميلي مول MnO2 جديش اك ميلي
+
+398
+00:31:58,460 --> 00:32:03,540
+مول اكم ميلي مول الان طلع الميلي مول MnO2 وحده
+
+399
+00:32:03,540 --> 00:32:07,920
+خمسة وسبعين الان بقول تلاته ميلي .. تلاته مانجانيز
+
+400
+00:32:07,920 --> 00:32:12,580
+الديوكسايت بتساوي مانجانيز تلاته او اربعة اذا
+
+401
+00:32:12,580 --> 00:32:19,530
+الميلي مول Mn3O4 ايش بساويتلت ال MnO2 لأ انا حط هد
+
+402
+00:32:19,530 --> 00:32:23,390
+على تلت و هد على واحد تلت ال MnO2 انا عند ال MnO2
+
+403
+00:32:23,390 --> 00:32:28,430
+هل جد تلته ايش بده يساوي ال Mn3 و Mn4 اذا مباشرة
+
+404
+00:32:28,430 --> 00:32:33,630
+نطلع ال Mn3 و Mn4 او انك يعني ملي مول MnO2 خليها
+
+405
+00:32:33,630 --> 00:32:37,970
+زي ما هي وبعدين بتيجي من هنا بتقول الملي مول MnO2
+
+406
+00:32:37,970 --> 00:32:42,590
+ايش بيساوي ايش
+
+407
+00:32:42,590 --> 00:32:49,440
+بيساوي من ال Mn3 و Mn4الـ Millimole MnO2 تلت أمثال
+
+408
+00:32:49,440 --> 00:32:52,740
+Mn3
+
+409
+00:32:52,740 --> 00:32:57,960
+أو Mn4 هاي المليمول MnO2 وهي المليمول MnO2 ايش
+
+410
+00:32:57,960 --> 00:33:01,840
+بتحط بدالها بالظبط تحط تلتها نفس الكلام هي التلت
+
+411
+00:33:01,840 --> 00:33:09,160
+يعني تطلع تلت المليمول MnO2 ماشي فبطلعها مدام طلعت
+
+412
+00:33:09,160 --> 00:33:12,060
+المليمول مالجانيز تلت أو أربعة بتضربه في
+
+413
+00:33:12,060 --> 00:33:15,720
+الفورمولويتمتين و تمانية و عشرين و تمانية من عشرة
+
+414
+00:33:15,720 --> 00:33:19,800
+صار عندك milligram مانجانيز تلاتة و أربعة بنجسمه
+
+415
+00:33:19,800 --> 00:33:24,500
+على وزنة العينة في مية من مية بيعطينا ستة و ستين و
+
+416
+00:33:24,500 --> 00:33:29,420
+سبعة من عشرة في المية هدى
+
+417
+00:33:29,420 --> 00:33:33,460
+.. هى هى .. هدى .. هدى المانجانيز .. اذا كان
+
+418
+00:33:33,460 --> 00:33:37,330
+مانجانيز في عندك هدىهى فى الأول اكام مانجانيزا
+
+419
+00:33:37,330 --> 00:33:41,030
+واحدة هان اكام واحدة كام تتكلموا زى بعض بس حط هان
+
+420
+00:33:41,030 --> 00:33:45,110
+تلاتة انسى
+
+421
+00:33:45,110 --> 00:33:48,370
+المعادلة الأصلية فيها هذا المعادلة الأصلية فيها
+
+422
+00:33:48,370 --> 00:33:53,270
+هذاكانت بتحوله لمنجنيز تلاتة واربعة، بتقول والله
+
+423
+00:33:53,270 --> 00:33:56,130
+تلاتة منه، تلاتة منجنيز، هي تلاتة منجنيز، تلاتة
+
+424
+00:33:56,130 --> 00:34:01,530
+ظروف، تلاتة، فبتصير عندك ال .. المنجنيز O2 بيساوي
+
+425
+00:34:01,530 --> 00:34:06,710
+تلت أمثال، تلت عدد ملات يعني، تلت عدد ملات، نعم؟
+
+426
+00:34:06,710 --> 00:34:10,230
+ان هم عدل، ان هم عدل، ان هم عدل، ان هم عدل، ان هم
+
+427
+00:34:10,230 --> 00:34:13,010
+عدل، عدل واحدة، اه اه، بدك توزنهم، تخلي عدد
+
+428
+00:34:13,010 --> 00:34:16,620
+المنجنيز في الاتنين واحدةبصير معادلة موزونة فبسبب
+
+429
+00:34:16,620 --> 00:34:19,980
+دك الملي مول مانجانيز دا يوكسايد بساوي تلاتة الملي
+
+430
+00:34:19,980 --> 00:34:25,440
+مول مانجانيز تلاتة او اربعة كويس؟ هيك يا شباب يعني
+
+431
+00:34:25,440 --> 00:34:30,960
+بنكون اتعرفنا على ايش يعني back titration ليش
+
+432
+00:34:30,960 --> 00:34:36,140
+بنضطر نستخدمها؟ ايش مزاياها؟ ايش يعني .. يعني
+
+433
+00:34:36,140 --> 00:34:40,670
+وابتديش بنستخدمها بشكل كويس؟ كيف نعمل حساباتها؟كيف
+
+434
+00:34:40,670 --> 00:34:44,330
+نعمل حسابات؟ مدخل الحسابات هي ال excess اللى
+
+435
+00:34:44,330 --> 00:34:48,350
+بتضيفه لأنه بنجسم لجسمين جزء بيتفاعل وجزء بيتعير
+
+436
+00:34:48,350 --> 00:34:52,830
+وبعد هيك بدك تعود عن اللى بيتفاعل بالمتفاعل عن
+
+437
+00:34:52,830 --> 00:34:55,170
+اللى بيتعير بالشيء اللى تعير معاه اللى هو ال
+
+438
+00:34:55,170 --> 00:34:58,910
+titrant وبعد هيك اللى بدك تعود عن ال millimoles
+
+439
+00:34:58,910 --> 00:35:02,690
+ملي مولاراتيب volume او ملي جرام على ال formula
+
+440
+00:35:02,690 --> 00:35:03,130
+weight
+
+441
+00:35:09,100 --> 00:35:14,780
+المشكلة دا هي تحط خطة فوق و تبقى أطول من 2000 و ..
+
+442
+00:35:14,780 --> 00:35:18,200
+بحطهاش يعني أنا عاملها إلك عشان تشوفها أنت أنا مش
+
+443
+00:35:18,200 --> 00:35:20,660
+بشتغلش هان يعني أنا مشتغل هذه المسألة significant
+
+444
+00:35:20,660 --> 00:35:24,060
+figures بس إلك أنت عشان تطلع عليها لو حبيت تتبعها
+
+445
+00:35:24,060 --> 00:35:30,920
+ايه كويس إلا إذا كان قلتلك استخدمهاطيب يا شباب
+
+446
+00:35:30,920 --> 00:35:34,380
+الآن خلينا ننتقل لموضوع تاني بنقوله normality
+
+447
+00:35:34,380 --> 00:35:37,960
+calculations احنا شوفنا ال molarity calculations
+
+448
+00:35:37,960 --> 00:35:42,440
+شوفنا في ال molarity calculations الحل عندي بديهي
+
+449
+00:35:42,440 --> 00:35:47,560
+millimol من a أكم millimol من b بتساوي وبعدين بعوض
+
+450
+00:35:47,560 --> 00:35:51,240
+عن ال millimol بحد حاجتين يا اما milligram على ال
+
+451
+00:35:51,240 --> 00:35:54,820
+formulate يا اما molarity ال volume لما نتكلم عن
+
+452
+00:35:54,820 --> 00:35:57,340
+ال normality calculations نتكلم عن اشي أبسط كتير
+
+453
+00:35:57,340 --> 00:36:02,590
+من ايهبنقول دائما إذا كان عندي a بتفعل مع b ف
+
+454
+00:36:02,590 --> 00:36:06,010
+milliequivalent من a يساوي milliequivalent من b
+
+455
+00:36:06,010 --> 00:36:11,770
+بدون أي stoichiometric factors بدون أي عدد دائما
+
+456
+00:36:11,770 --> 00:36:16,550
+ال millimole واحد millimole من a بيساوي عدد عفوا
+
+457
+00:36:16,550 --> 00:36:19,650
+واحد milliequivalent من a يساوي واحد
+
+458
+00:36:19,650 --> 00:36:23,960
+milliequivalent من bدائما، طب وين راح عدد الملات؟
+
+459
+00:36:23,960 --> 00:36:27,760
+هنشوف هل جت وين راح عدد الملات، لكن الآن بقول ملي
+
+460
+00:36:27,760 --> 00:36:30,440
+equivalent من a تساوي ملي equivalent من b فقط،
+
+461
+00:36:30,440 --> 00:36:34,740
+ماعندي أي شيء آخر، ملي equivalent من a تساوي ملي
+
+462
+00:36:34,740 --> 00:36:39,380
+equivalent من b، و بعدين الحل، بدي أكمل، بقول بدي
+
+463
+00:36:39,380 --> 00:36:41,600
+أعوض عن الملي equivalent، إيش أعوض عن الملي
+
+464
+00:36:41,600 --> 00:36:46,050
+equivalent؟أه واحد من مجموعة حاجات الملي اكوفلانت
+
+465
+00:36:46,050 --> 00:36:48,810
+عبارة عن ال normality في ال volume بالملي الملي
+
+466
+00:36:48,810 --> 00:36:52,050
+اكوفلانت هي عبارة عن milligram على ال equivalent
+
+467
+00:36:52,050 --> 00:36:55,450
+weight انا بدي اختار الملي اكوفلانت هي عبارة عن in
+
+468
+00:36:55,450 --> 00:37:00,250
+في الملي مول وهنا بنرجع بنقول ليش احنا مانحطش اي
+
+469
+00:37:00,250 --> 00:37:04,150
+stoichiometric factors قبل الملي اكوفلانت دائما
+
+470
+00:37:04,150 --> 00:37:07,790
+واحد ملي اكوفلانت من a بيساوي واحد ملي اكوفلانت من
+
+471
+00:37:07,790 --> 00:37:11,540
+bليش؟ قال لأن الـ Millie Equivalent إيش بحتوي
+
+472
+00:37:11,540 --> 00:37:16,340
+جواته؟ على ال N أنا عندي هاي ال Millie Mole مثلا
+
+473
+00:37:16,340 --> 00:37:20,860
+عندي Millie Equivalent من إيه؟ بساوي NAفي الـ
+
+474
+00:37:20,860 --> 00:37:23,640
+millimolar ايه؟ هذا بيساوي milliequivalent من B
+
+475
+00:37:23,640 --> 00:37:30,260
+يعني بيساوي N ل B في millimolar B يعني ال N موجودة
+
+476
+00:37:30,260 --> 00:37:33,620
+أصلا انت صح مش شايفها لكن هي وين؟ موجودة في
+
+477
+00:37:33,620 --> 00:37:38,100
+الحسابات موجودة في تحديد مثلا ال equivalent weight
+
+478
+00:37:38,100 --> 00:37:40,520
+بشكل أساسي لأن ال milliequivalent بيساوي ال
+
+479
+00:37:40,520 --> 00:37:43,200
+milligram على ال equivalent weight ال N موجودة
+
+480
+00:37:43,200 --> 00:37:46,800
+داخل ال equivalent weightفما تتداجش يعني انه والله
+
+481
+00:37:46,800 --> 00:37:49,440
+فاش عندك Stoichiometry لأ ال Stoichiometry موجودة
+
+482
+00:37:49,440 --> 00:37:53,400
+ليه؟ لأنه هيه الميلي equivalent ايش بيساوي N في
+
+483
+00:37:53,400 --> 00:37:57,660
+الميلي مول فالميلي equivalent من A بيساوي N ل A في
+
+484
+00:37:57,660 --> 00:38:01,400
+الميلي مول ل A والميلي equivalent من E بيساوي N ل
+
+485
+00:38:01,400 --> 00:38:05,840
+B في الميلي equivalent في الميلي مول ل B فال N ايش
+
+486
+00:38:05,840 --> 00:38:08,940
+مالها موجودة لكن كحسابات دايما بنقول ميلي
+
+487
+00:38:08,940 --> 00:38:11,950
+equivalent من Aبتساوي الملي اكوبلت من بي والان
+
+488
+00:38:11,950 --> 00:38:16,430
+embedded او يعني مدفونة جوات المعادلة هدول التلت
+
+489
+00:38:16,430 --> 00:38:20,350
+معادلات منهم ايش بنجيب؟ الملي اكوبلت، بنعوض عن
+
+490
+00:38:20,350 --> 00:38:24,550
+الملي اكوبلت في واحد منهم وبرضه معادلة رابعة كتير
+
+491
+00:38:24,550 --> 00:38:28,130
+مهمة في الحسابات اللي هو ال normality بتساوي ال
+
+492
+00:38:28,130 --> 00:38:32,130
+familiarity هدول المعادلات اللي عادة بنستخدمهم في
+
+493
+00:38:32,130 --> 00:38:35,690
+الحسابات اللي بتتعلق بال normality
+
+494
+00:38:38,050 --> 00:38:46,670
+طيب خلّينا ناخد مثال بسيط المثال يعني و نعرف كيف
+
+495
+00:38:46,670 --> 00:38:51,250
+احنا بنستخدم هذه المفاهيم في حله يعني هذا المثال
+
+496
+00:38:51,250 --> 00:38:54,070
+ممكن بسهولة أحله باستخدام ال modality و مر معنا
+
+497
+00:38:54,070 --> 00:38:57,970
+يعني طرق حله قبل هيك و حتى الأرقام اللي موجودة مرت
+
+498
+00:38:57,970 --> 00:39:00,510
+معنا سابقالكن احنا مابدناش نحله باستخدام
+
+499
+00:39:00,510 --> 00:39:04,650
+الـMolarity، بدنا نحله باستخدام الـNormality، نقرأ
+
+500
+00:39:04,650 --> 00:39:07,930
+المثال و نفهمه في البداية، بيقول فيها أندي عينة
+
+501
+00:39:07,930 --> 00:39:15,330
+وزنتها 0.4671 جرام تحتوي على صوديم بيكربونيت، was
+
+502
+00:39:15,330 --> 00:39:21,030
+titrated with HCl requiring 40.72% مل، ماجليش جداش
+
+503
+00:39:21,030 --> 00:39:26,700
+تركيز الـHClكويس؟ لكن اعطاني خطوة تانية بيقول the
+
+504
+00:39:26,700 --> 00:39:30,300
+acid اللي هو ال HCl هذا اللي مش عارفين تركيزه اللي
+
+505
+00:39:30,300 --> 00:39:33,560
+عيرنا فيه و احنا مش عارفين تركيزه بيقول the acid
+
+506
+00:39:33,560 --> 00:39:38,700
+was standardized by titrating 0.1876 gram of
+
+507
+00:39:38,700 --> 00:39:44,580
+sodium carbonate عيرنا sodium carbonate 0.1876
+
+508
+00:39:44,580 --> 00:39:50,250
+gram من ال sodium carbonateقداش أخدت من ال HCL
+
+509
+00:39:50,250 --> 00:39:55,850
+requiring 37.86 ml of the acid، إذا من هذه الخطوة
+
+510
+00:39:55,850 --> 00:40:03,970
+بقدر أجيب تركيز ال HCL، طيب، بقول find percentage
+
+511
+00:40:03,970 --> 00:40:08,380
+of sodium bicarbonate in this sampleFind
+
+512
+00:40:08,380 --> 00:40:11,060
+percentage of sodium b-carbonate in this sample
+
+513
+00:40:11,060 --> 00:40:14,140
+بقول أنا ببساطة خالص يعني أنا من الخطوة التانية
+
+514
+00:40:14,140 --> 00:40:17,700
+ممكن أبدأ اللي هو في الأول أجيب إيش تركيز ال acid
+
+515
+00:40:17,700 --> 00:40:20,760
+و بعدين أستخدم التركيز اللي حصلت عليه في الخطوة
+
+516
+00:40:20,760 --> 00:40:24,500
+الأولىمش هيك؟ لأنه أنا المعايير اللي بديها هي
+
+517
+00:40:24,500 --> 00:40:26,960
+المعايير الأساسية، هي اللي بديها أنا ال sodium
+
+518
+00:40:26,960 --> 00:40:31,460
+bicarbonate، لكن للأسف مش عادي تركيز ال acid فبجيب
+
+519
+00:40:31,460 --> 00:40:36,300
+تركيز ال acid بالخطوة الإضافية هذه، و بعدين بستخدم
+
+520
+00:40:36,300 --> 00:40:39,540
+الخطوة الأولى لحل المسألة، فكيف بدي أجيب تركيز ال
+
+521
+00:40:39,540 --> 00:40:44,710
+acid؟ بقول ناخد بالنا شويةبقول انا الميلي
+
+522
+00:40:44,710 --> 00:40:47,510
+equivalent من ال HCl بتساوي الميلي equivalent من
+
+523
+00:40:47,510 --> 00:40:50,490
+ال Sodium Carbonate هي كلام مفهوم لازم واحد ميلي
+
+524
+00:40:50,490 --> 00:40:52,390
+equivalent من ايه يساوي واحد ميلي equivalent منه
+
+525
+00:40:52,390 --> 00:40:55,970
+بس مافيش جاملة لا واحد ولا اتنين ولا تلاتة ولا
+
+526
+00:40:55,970 --> 00:40:58,790
+اربعة ولا اتنين على خمسة ولا اتنين على تلاتة ولا
+
+527
+00:40:58,790 --> 00:41:00,730
+غيره دايما عندي واحد واحد
+
+528
+00:41:03,650 --> 00:41:06,350
+في البداية انا بكون طلعت ال equivalent weight
+
+529
+00:41:06,350 --> 00:41:10,430
+للصوديوم carbonate طبعا لما اتفاعل مع ال HCl كاملا
+
+530
+00:41:10,430 --> 00:41:14,650
+فبتكون يعني formula weight على اتنين مية و ستة على
+
+531
+00:41:14,650 --> 00:41:17,690
+اتنين يعني تلاتة و خمسين بينما ال equivalent
+
+532
+00:41:17,690 --> 00:41:21,440
+weight للصوديوم بيه carbonateهذه مونو بيزيك
+
+533
+00:41:21,440 --> 00:41:24,740
+الصوديوم بيكربونيت مونو بيزيك تتفعل بس دائما مع
+
+534
+00:41:24,740 --> 00:41:29,640
+اكم HCl مع واحد يعني لو حتى انت كتبت المعادلة حتى
+
+535
+00:41:29,640 --> 00:41:33,880
+ماعطكاش لأن المعادلة معروفة الصوديوم بيكربونيت
+
+536
+00:41:33,880 --> 00:41:38,260
+ماتتفعل مع اكتر من واحد HCl بينما الصوديوم كربونيت
+
+537
+00:41:38,260 --> 00:41:43,080
+تتفعل مع ايه؟ مع اتنين HCl فماعطكاش المعادلة على
+
+538
+00:41:43,080 --> 00:41:46,780
+اساس ان هذا اشي يعني معروف لطالب في مستواك العلمي
+
+539
+00:41:48,330 --> 00:41:50,730
+على أي حال ميلي إيكوفلانت HCl بتساوي ميلي
+
+540
+00:41:50,730 --> 00:41:55,750
+إيكوفلانت صوديوم كربونيت هان الـHCl normality في
+
+541
+00:41:55,750 --> 00:41:58,530
+volume لإن هو ميعطيك ال volume تبعه بده ال
+
+542
+00:41:58,530 --> 00:42:02,190
+normality بده التركيز طيب الميلي إيكوفلانت
+
+543
+00:42:02,190 --> 00:42:05,030
+للصوديوم بيكربونيت عبارة عن ال weight الميلي جرام
+
+544
+00:42:05,030 --> 00:42:08,670
+على ال equivalent weight الميلي جرام يعطيهولي 187
+
+545
+00:42:08,670 --> 00:42:14,090
+.6 هو يعطيهولي بالجرام 0.1876 بالميلي جرام بده
+
+546
+00:42:14,090 --> 00:42:19,330
+يكون187.6 ميلي جرامs على ال equivalent weight اللي
+
+547
+00:42:19,330 --> 00:42:24,370
+هو جد ايه 53 حسبناه في الخطوة الأولى formula
+
+548
+00:42:24,370 --> 00:42:29,290
+weight على N ال N ب 2 اذا 106 على 2 53 يبقى ال
+
+549
+00:42:29,290 --> 00:42:35,150
+normally لل HCL تطلع 0.0935 يعني كان بإمكانه من
+
+550
+00:42:35,150 --> 00:42:41,770
+الأول يقولي والله 40.72 mil of
+
+551
+00:42:46,770 --> 00:42:53,910
+.0935 Normal HCl كان بيبقى يقول زهقه ومايعطينيشي
+
+552
+00:42:53,910 --> 00:43:00,470
+بجيت ال ايه بجيت المثلة لهذا كان بيبقى بس يقوللي
+
+553
+00:43:00,470 --> 00:43:04,190
+هذا بس انا استخدمت الخطوة التانية عشان اعرف ايش
+
+554
+00:43:04,190 --> 00:43:09,430
+تركيز ال HCl اللي عندي ال normality ل ال HCl اللي
+
+555
+00:43:09,430 --> 00:43:15,430
+عنديطيب الآن مدام عرفت إيش التركيز بقدر أكمل
+
+556
+00:43:15,430 --> 00:43:18,970
+المسألة بقدر أقول من أول و جديد ملي إيكوفلانت
+
+557
+00:43:18,970 --> 00:43:23,770
+صوديوم بيكربونيت تساوي ملي إيكوفلانت HCl مش هيك
+
+558
+00:43:23,770 --> 00:43:27,230
+لأنه دائما الملي إيكوفلانت من المادة A بتساوي
+
+559
+00:43:27,230 --> 00:43:29,050
+الملي إيكوفلانت من المادة B اللي بتتفاعل معاها
+
+560
+00:43:29,050 --> 00:43:32,410
+فبقول والله بتدعوض عن الملي إيكوفلانت جال والله
+
+561
+00:43:32,410 --> 00:43:35,210
+ملي جرام صوديوم بيكربونيت على ال equivalent weight
+
+562
+00:43:36,420 --> 00:43:38,580
+أحنا اتفاجن على ان اتعود على الـ Milliequivalent
+
+563
+00:43:38,580 --> 00:43:42,340
+يا إما Normality بـ Volume، يا إما Milligram على
+
+564
+00:43:42,340 --> 00:43:45,260
+ال equivalent weight، يا إما N في الملي مول، هذه
+
+565
+00:43:45,260 --> 00:43:48,280
+التلت حاجات اللي بعوض فيهم عن إيه؟ مش فيها
+
+566
+00:43:48,280 --> 00:43:51,980
+اختراعات، الـ Milliequivalent بعوض عنه بأحد تلت
+
+567
+00:43:51,980 --> 00:43:59,480
+أشياء، يا إما .. يا إما ..Normality في volume يا
+
+568
+00:43:59,480 --> 00:44:02,620
+ما milligram على ال equivalent weight يا ما in في
+
+569
+00:44:02,620 --> 00:44:05,900
+ال millimole مافي حاجة غير هيك زي ما كنا بنقول ال
+
+570
+00:44:05,900 --> 00:44:09,500
+millimole تعويض بس أحد حاجتين يا ما milligram على
+
+571
+00:44:09,500 --> 00:44:11,860
+ال formula weight يا moderate في volume ال
+
+572
+00:44:11,860 --> 00:44:15,560
+milliequivalent تلت حاجات شفناهم فهل انا بدي
+
+573
+00:44:15,560 --> 00:44:17,900
+milligram بقول milligram على ال equivalent weight
+
+574
+00:44:18,080 --> 00:44:21,520
+بتساوي ال HCl عند ال normality و ال volume له إذا
+
+575
+00:44:21,520 --> 00:44:26,080
+ال normality ب volume الميلي جرام لصوديم بيكربونيت
+
+576
+00:44:26,080 --> 00:44:33,280
+بيطلع 84 times 0.0935 times 40.72 بطلع قيمةها إذا
+
+577
+00:44:33,280 --> 00:44:36,500
+كان حبيت و لو ماحبيتش خليها زي ما هي اجسبها على
+
+578
+00:44:36,500 --> 00:44:40,020
+وزنة العينة بالميلي جرام أيضا لإن طلعت ميلي جرام
+
+579
+00:44:40,020 --> 00:44:44,790
+صوديمبكربونيت فاكسبها على وزن العينا بالملي جرام
+
+580
+00:44:44,790 --> 00:44:48,270
+وزن العينا بالملي جرام four seven six point one
+
+581
+00:44:48,270 --> 00:44:52,570
+times مية في المية طبعا بيعطيك سبعة و ستين و اتنين
+
+582
+00:44:52,570 --> 00:44:56,690
+من عشرة في المية يبدأ طلعنا على طريقة حل المثال
+
+583
+00:44:56,690 --> 00:45:00,990
+اللي معانا باستخدام ال normalities هل كان بإمكاننا
+
+584
+00:45:00,990 --> 00:45:03,870
+نحله باستخدام ال normalities طبعا حل مباشر و سهل
+
+585
+00:45:03,870 --> 00:45:07,670
+مافيش فيها مشكلة لكن المقلوب مننا في هذا المثال و
+
+586
+00:45:07,670 --> 00:45:12,270
+الأمثلة القادمةان نستخدم ال normalites عشان نتعلم
+
+587
+00:45:12,270 --> 00:45:16,310
+كيف نحل باستخدام ال normalites ماشي يا شباب
+
diff --git a/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/P1ca0YrAX7k.srt b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/P1ca0YrAX7k.srt
new file mode 100644
index 0000000000000000000000000000000000000000..939e68cf6ad47f481b4f882a9852ab80aa563bf2
--- /dev/null
+++ b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/P1ca0YrAX7k.srt
@@ -0,0 +1,1356 @@
+1
+00:00:20,960 --> 00:00:23,640
+بسم الله الرحمن الرحيم، فقولنا يا شباب أن ال
+
+2
+00:00:23,640 --> 00:00:29,740
+carbonic acids كلها ضعيفة
+
+3
+00:00:29,740 --> 00:00:34,440
+الـ carbonic acid حمض ضعيف مثلاً، لكنه polyprotic
+
+4
+00:00:34,440 --> 00:00:38,420
+acid، يعني يحتوي على two protons. التفكك الأول
+
+5
+00:00:38,420 --> 00:00:42,500
+يعطيني H⁺  زائد bicarbonate. التفكك الثاني
+
+6
+00:00:42,500 --> 00:00:49,100
+يعطيني H⁺ زائد carbonate. على أي حال، إذا كان
+
+7
+00:00:49,100 --> 00:00:54,250
+بدنا نعاير حمضاً مثل هذا، نقول إن معايرته يجب أن تتم
+
+8
+00:00:54,250 --> 00:00:59,810
+باستخدام strong base. ليه؟ لأن أحد طرفي المعايرة
+
+9
+00:00:59,810 --> 00:01:03,810
+يجب أن يكون strong. على أساس أنه لا يمكن معايرة
+
+10
+00:01:03,810 --> 00:01:07,990
+weak acid بـ weak base visually. يعني المعايرات
+
+11
+00:01:07,990 --> 00:01:12,450
+التي نعرفها، المعايرات البصرية أو المعايرات
+
+12
+00:01:12,450 --> 00:01:16,190
+التي نطلع فيها على تغير لون الـ pH
+
+13
+00:01:16,190 --> 00:01:21,790
+indicator. فيجب أن أحد طرفي التفاعل يكون strong.
+
+14
+00:01:21,790 --> 00:01:26,530
+فيتفاعل الـ carbonic acid مع شيء مثل الـ sodium
+
+15
+00:01:26,530 --> 00:01:31,190
+hydroxide. لكن السؤال: هل نحصل على one inflection
+
+16
+00:01:31,190 --> 00:01:37,010
+point، one end point، أم two end points؟ أقول أنا في
+
+17
+00:01:37,010 --> 00:01:39,930
+عندي two protons في الـ carbonic acid، فمتوقع أن
+
+18
+00:01:39,930 --> 00:01:46,070
+أحصل من كل proton على one equivalence point أو one
+
+19
+00:01:46,070 --> 00:01:52,510
+end point. طبيعى في أحماض أخرى أيضاً polyprotic
+
+20
+00:01:52,510 --> 00:01:57,970
+ونتوقع أن نحصل منها على عدد من الـ equivalence
+
+21
+00:01:57,970 --> 00:02:02,210
+points يساوي عدد الـ protons الموجودة في الـ acid.
+
+22
+00:02:02,210 --> 00:02:06,330
+لكن في الحقيقة، ليس دائماً نحصل على نفس العدد من الـ
+
+23
+00:02:06,330 --> 00:02:10,510
+equivalence points مساوياً لعدد الـ protons التي
+
+24
+00:02:10,510 --> 00:02:17,190
+موجودة في الـ polyprotic acid.  لأَن أحصل على أن أحصل
+
+25
+00:02:17,190 --> 00:02:23,630
+على equivalence point مميزة لكل proton، يجب أن يكون
+
+26
+00:02:23,630 --> 00:02:32,060
+Kₐ₁ على Kₐ₂ أكبر من 10⁴. في حالة ما يقترب
+
+27
+00:02:32,060 --> 00:02:37,060
+الـ Kₐ₁ من الـ Kₐ₂، يحصل Merge للـ two equivalence
+
+28
+00:02:37,060 --> 00:02:40,580
+points في واحدة، يعني إحداهما تختفي على حساب
+
+29
+00:02:40,580 --> 00:02:46,020
+الأخرى، عادةً الأقل، يحصل لها Merge في الـ... في
+
+30
+00:02:46,020 --> 00:02:54,660
+الـ... يعني الـ... الـ equivalence point الثانية يحصل لها
+
+31
+00:02:54,660 --> 00:02:57,060
+Merge في الـ equivalence point الأولى، وتعطيني
+
+32
+00:02:57,060 --> 00:03:03,220
+one equivalence point ظاهرة.  بعدُ في بعض
+
+33
+00:03:03,220 --> 00:03:07,530
+يعني  Merge. بعدُ في بعض. اختلاف.  يجب أن يكون عندي
+
+34
+00:03:07,530 --> 00:03:11,710
+الـ Kₐ₁ أكبر كثيراً من الـ Kₐ₂ إذا أردت أن أحصل على
+
+35
+00:03:11,710 --> 00:03:22,950
+one distinct، one observable equivalence point لكل
+
+36
+00:03:22,950 --> 00:03:27,210
+proton موجودة عندي. هذه نقطة. النقطة الثانية التي
+
+37
+00:03:27,210 --> 00:03:31,250
+يجب أن نأخذ بالنا منها أيضاً، أنه في بعض الأحيان يكون
+
+38
+00:03:31,250 --> 00:03:36,900
+عندي polyprotic acid، لكن بعض قيم الـ Kₐ، خاصة المتأخرة
+
+39
+00:03:36,900 --> 00:03:42,360
+يعني Kₐ₃ أو Kₐ₄، صغيرة جداً، يعني 10⁻¹⁵، 10⁻¹⁶، 10⁻¹³، صعب جداً أن أحصل أو أقدر
+
+40
+00:03:42,360 --> 00:03:48,040
+أرى الـ equivalence point لها، لأنها ضعيفة جداً. فليس فقط
+
+41
+00:03:48,040 --> 00:03:53,770
+Kₐ₁ على Kₐ₂، بل يجب أن تكون كبيرة، ولكن أيضاً الـ
+
+42
+00:03:53,770 --> 00:04:03,590
+... الـ acid dissociation constant نفسه للـ proton التي
+
+43
+00:04:03,590 --> 00:04:07,090
+أريد أن أراه، يجب أن يكون أيضاً، يعني إلى حد ما
+
+44
+00:04:07,090 --> 00:04:12,570
+معقولاً، وإلا لن أقدر أن أرى equivalence point لهذا
+
+45
+00:04:12,570 --> 00:04:20,690
+الـ proton.  بشكل عام، نحن خلينا نتكلم عن أنه في
+
+46
+00:04:20,690 --> 00:04:24,930
+عندنا الـ polyprotic acids، وكثير منها يعطيني
+
+47
+00:04:24,930 --> 00:04:35,090
+distinct equivalence point لكل proton. فنقول كل
+
+48
+00:04:35,090 --> 00:04:38,670
+proton موجود أو كل equivalence point نحصل عليها
+
+49
+00:04:38,670 --> 00:04:43,680
+تحتاج إلى indicator معين. ليه؟ لأننا نعرف أن
+
+50
+00:04:43,680 --> 00:04:47,360
+الـ indicator يشتغل في range معين. فهنا بالتالي كل
+
+51
+00:04:47,360 --> 00:04:53,540
+observable proton، كل observable equivalence point
+
+52
+00:04:53,540 --> 00:04:59,980
+تحتاج إلى indicator معين. فبالتالي، إذا كان في عندي
+
+53
+00:04:59,980 --> 00:05:03,880
+two observable equivalence points، أنا بحاجة أن أجد
+
+54
+00:05:03,880 --> 00:05:08,440
+two different indicators. لأنه لو في النهاية أردت
+
+55
+00:05:08,440 --> 00:05:11,690
+استخدام one indicator، سيقول لي والله آه one
+
+56
+00:05:11,690 --> 00:05:13,790
+equivalence point. كل indicator سيعطيني equivalence
+
+57
+00:05:13,790 --> 00:05:18,090
+point. ليه؟ لأن اللون يتغير من a إلى b، أو من color one
+
+58
+00:05:18,090 --> 00:05:23,730
+إلى color two.  طيب، خلينا ننظر إلى معايرة الـ carbonic
+
+59
+00:05:23,730 --> 00:05:29,710
+acid مع sodium hydroxide. فلو عندي مثلاً خمسين ml
+
+60
+00:05:29,710 --> 00:05:33,770
+من 0.1 molar carbonic acid، وأعيرهم بالـ
+
+61
+00:05:33,770 --> 00:05:37,870
+sodium hydroxide، أقول في عندي عدة مراحل للمعايرة.
+
+62
+00:05:38,900 --> 00:05:42,920
+المرحلة الأولى، إذا رسمت الـ titration curve، أرى
+
+63
+00:05:42,920 --> 00:05:47,680
+هذا الكلام بوضوح. المرحلة الأولى، قبل إضافة أي sodium
+
+64
+00:05:47,680 --> 00:05:51,720
+hydroxide، أو after addition of 0 ml من الـ sodium
+
+65
+00:05:51,720 --> 00:05:54,460
+hydroxide، يجب أن أطلع، ما في عندي أي sodium
+
+66
+00:05:54,460 --> 00:05:57,240
+hydroxide.  ماذا موجود عندي في المحلول؟
+
+67
+00:06:02,890 --> 00:06:09,270
+لحظة بدأ من low pH، لأنه حمض له low pH، يجب أن
+
+68
+00:06:09,270 --> 00:06:14,610
+أعرف كيف أحسب في البداية، ما هي قيمة الـ pH، أو كيفية حساب الـ
+
+69
+00:06:14,610 --> 00:06:19,930
+pH لـ pure carbonic acid؟ أقول الحساب سهل جداً عادةً
+
+70
+00:06:19,930 --> 00:06:24,330
+ماذا أفعل؟ أقول والله الـ carbonic acid يتفكك، يعطيني
+
+71
+00:06:24,330 --> 00:06:28,610
+بيكربونات وبروتون، والـ بيكربونات يتفكك، يعطيني
+
+72
+00:06:28,610 --> 00:06:34,360
+كربونات وبروتون. أقول Kₐ₁ على Kₐ₂ أكبر من عشرة، أقصى
+
+73
+00:06:34,360 --> 00:06:39,600
+اثنين. إذن، يبقى فقط التفكك الأول. التفكك الأول
+
+74
+00:06:39,600 --> 00:06:45,580
+carbonic acid تركيزه C، أي تركيز البروتون قبل
+
+75
+00:06:45,580 --> 00:06:50,500
+التفكك صفر، الـ bicarbonate صفر. إذن C - X، X، X.
+
+76
+00:06:50,500 --> 00:06:55,380
+ونقول Kₐ₁ تساوي X² على C - X. الـ C
+
+77
+00:06:55,380 --> 00:07:01,340
+معلومة، وهكذا نحسب الـ X، التي هي الـ H⁺، أو
+
+78
+00:07:01,340 --> 00:07:05,040
+التركيز للـ protons، ومنها نجيب الـ pH. هذا كلام
+
+79
+00:07:05,040 --> 00:07:09,960
+شفناه سابقاً، وسنأخذ مثالاً حسابياً بعد قليل. يبقى هذه
+
+80
+00:07:09,960 --> 00:07:16,120
+المرحلة الأولى. المرحلة الثانية هي المرحلة التي أبدأ
+
+81
+00:07:16,120 --> 00:07:22,620
+أضيف فيها، أبدأ أضيف فيها Sodium Hydroxide. أنا عندي
+
+82
+00:07:22,620 --> 00:07:26,490
+carbonic acid. لما نبدأ نضيف عليها Sodium
+
+83
+00:07:26,490 --> 00:07:31,230
+Hydroxide، ماذا يحدث له؟ يقل، أنت معي. لما
+
+84
+00:07:31,230 --> 00:07:33,690
+نبدأ نضيف Sodium Hydroxide على Carbonic Acid، ماذا
+
+85
+00:07:33,690 --> 00:07:40,730
+يفعل؟ يقل، وماذا يبدأ في التكون؟ الـ بيكربونات، إذن
+
+86
+00:07:40,730 --> 00:07:45,310
+الـ بيكربونات عاملة تتكون أو تزيد، والـ Carbonic
+
+87
+00:07:45,310 --> 00:07:49,070
+Acid عاملة يقل، لكن مجرد وجود بيكربونات مع
+
+88
+00:07:49,070 --> 00:07:55,260
+Carbonic Acid، هذا عبارة عن buffer. كيف نعمل
+
+89
+00:07:55,260 --> 00:07:59,540
+العملية الحسابية؟ أقول أنا في البداية، الكربونيك أسيد
+
+90
+00:07:59,540 --> 00:08:04,460
+مع الهيدروكسيد، لو أخذنا X ميلي مول من الكربونيك
+
+91
+00:08:04,460 --> 00:08:08,120
+أسيد الذي موجود عندي، وأضفنا عليه Y ميلي مول من
+
+92
+00:08:08,120 --> 00:08:12,440
+الهيدروكسيد، حيث X أكبر من Y، لسه الـ Y شوية
+
+93
+00:08:12,440 --> 00:08:17,760
+شوية.  نريد أن نضيف، X أكبر من Y، فعندي قبل التفاعل
+
+94
+00:08:17,760 --> 00:08:23,430
+عند الـ bicarbonate صفر. بعد التفاعل، عند الـ millimoles
+
+95
+00:08:23,430 --> 00:08:28,910
+من الكربونيك أسيد المتبقية X - Y. عند الهيدروكسيد
+
+96
+00:08:28,910 --> 00:08:33,550
+انتهى، لأنه كمية قليلة هيدروكسيد. عند الـ بيكربونات
+
+97
+00:08:33,550 --> 00:08:40,250
+التي تكونت Y. دائماً مجموع الـ
+
+98
+00:08:40,250 --> 00:08:46,220
+بيكربونات والكربونيك أسيد، مجموعهم يجب أن يساوي
+
+99
+00:08:46,220 --> 00:08:51,540
+الكربونيك أسيد الأصلي. فأنا عندي هنا X ميلي مول، هدي
+
+100
+00:08:51,540 --> 00:08:55,880
+X - Y، هدي Y. طبعاً X - Y + Y يجب أن تساوي
+
+101
+00:08:55,880 --> 00:08:59,460
+الكربونيك أسيد الأصلي، لأن الكربونيك أسيد ينقسم
+
+102
+00:08:59,460 --> 00:09:03,860
+لجزئين، جزء يبقى كما هو، وجزء يتحول إلى ماذا؟ إلى الـ بي
+
+103
+00:09:03,860 --> 00:09:07,840
+كربونات. فمجموع الاثنين يجب أن يساوي الكمية
+
+104
+00:09:07,840 --> 00:09:13,840
+الأصلية التي عندي. وهكذا تتم عملية الحسابات. نحسب من
+
+105
+00:09:13,840 --> 00:09:16,220
+هنا هذه المولات، لو قسمناها على الـ total
+
+106
+00:09:16,220 --> 00:09:20,700
+volume، الذي هو حجم الـ hydroxide زائد حجم الكربونيك
+
+107
+00:09:20,700 --> 00:09:23,860
+أسيد، يعطيني التركيز. أيضاً، هذه على الـ total volume
+
+108
+00:09:23,860 --> 00:09:27,480
+يعطيني التركيز. فصار عندي تركيز الـ بيكربونات، تركيز
+
+109
+00:09:27,480 --> 00:09:32,280
+الكربونيك أسيد، على طول أقدر أجيب الـ pH. ليه؟ لأن هذا
+
+110
+00:09:32,280 --> 00:09:37,680
+عبارة عن buffer solution. يبقى هذا قبل نقطة النهاية
+
+111
+00:09:37,680 --> 00:09:42,640
+الأولى. طيب، ماذا يحدث؟ لما أستمر في إضافة هيدروكسيد لغاية
+
+112
+00:09:42,640 --> 00:09:51,000
+ما X تساوي Y، at the first equivalence point، الـ
+
+113
+00:09:51,000 --> 00:09:55,300
+X وهي الـ Y. عند الـ X تساوي الـ Y، يعني هنا يصبح
+
+114
+00:09:55,300 --> 00:10:00,150
+صفر، انتهى الـ carbonic acid، الهيدروكسيد انتهى، الـ
+
+115
+00:10:00,150 --> 00:10:05,090
+بيكربونيت صارت X، لأنه كل الكربونيك أسيد تحول إلى الـ
+
+116
+00:10:05,090 --> 00:10:12,250
+بيكربونات. طيب الآن السؤال: كيف أحسب الـ pH لمحلول
+
+117
+00:10:12,250 --> 00:10:18,030
+بيكربونات؟  ليس
+
+118
+00:10:18,030 --> 00:10:25,210
+صحيح. هذا بروتونيتد سولت. البروتونيتد سولت، مادام
+
+119
+00:10:25,210 --> 00:10:28,810
+البروتونيتد is an H⁺، بتساوي الجذر التربيعي
+
+120
+00:10:28,810 --> 00:10:34,590
+ننظر إلى الشحنة، الشحنة واحدة. is a Kₐ₁ Kʷ + Kₐ₁
+
+121
+00:10:34,590 --> 00:10:44,530
+Kₐ₂ HCO₃⁻ على Kₐ₁ + HCO₃⁻. هكذا
+
+122
+00:10:44,530 --> 00:10:52,190
+نحسب الـ pH أو الـ H⁺ للبروتونيتد سولت. إذا قدرنا
+
+123
+00:10:52,190 --> 00:11:01,170
+نحسبها هنا بالضبط، هنا في عندي فقط بيكربونات. لاحظ
+
+124
+00:11:01,170 --> 00:11:04,470
+معي، لو أردت أن ترى الـ carbonic acid عامة، الـ Beagle
+
+125
+00:11:04,470 --> 00:11:07,910
+Beagle، لما تحول إلى ماذا؟ إلى الـ Beagle لما انتهى كل الـ
+
+126
+00:11:07,910 --> 00:11:11,290
+carbonic acid. هذه نقطة التكافؤ الأولى. كل ما
+
+127
+00:11:11,290 --> 00:11:16,430
+عندي فقط بيكربونات. ماشي يا شباب؟ طيب، لو حاولنا
+
+128
+00:11:16,430 --> 00:11:21,600
+أن نستمر في الإضافة، بين نقطة التكافؤ الأولى
+
+129
+00:11:21,600 --> 00:11:25,240
+والثانية، صار عندي... لحظة انتهى الـ carbonic acid.
+
+130
+00:11:25,240 --> 00:11:27,880
+ما في عندي carbonic acid. الآن أريد أن أمضي قدماً في
+
+131
+00:11:27,880 --> 00:11:34,660
+عندي بيكربونات، هي و
+
+132
+00:11:34,660 --> 00:11:39,380
+لما نحط عليها الـ hydroxide، ماذا يحدث لها؟ تتفاعل، آه،
+
+133
+00:11:39,380 --> 00:11:43,680
+تتحول إلى ماذا؟ إلى الكربونات. الكربونات عاملة تتكون أو
+
+134
+00:11:43,680 --> 00:11:47,600
+تزيد. يبقى صار في عندي كربونات وبيكربونات، وهذا
+
+135
+00:11:47,600 --> 00:11:53,560
+buffer. لاحظ الـ pH تقريباً ثابتة. هذا ماذا؟ buffer. يبقى
+
+136
+00:11:53,560 --> 00:11:57,540
+مستمر مع الإضافة. X ميلي مول أحط عليها Y ميلي مول
+
+137
+00:11:57,540 --> 00:12:04,040
+حيث X أكبر من Y. فأقول X - Y سيبقى أو سيتبقى. Y
+
+138
+00:12:04,040 --> 00:12:10,250
+سيتكون من الكربونات. على الـ total volume، على الـ
+
+139
+00:12:10,250 --> 00:12:14,350
+total volume بتاع التركيزات، وعلى طول أقدر أجيب الـ
+
+140
+00:12:14,350 --> 00:12:23,390
+pH من الـ Kₐ₂. سنرى هذا الكلام حسابياً بعد قليل. طيب،
+
+141
+00:12:23,390 --> 00:12:28,490
+استمرت بإضافة الـ sodium hydroxide، أنا استمرت
+
+142
+00:12:28,490 --> 00:12:30,090
+بإضافة الـ sodium hydroxide، أنا انتهيت من كل الـ
+
+143
+00:12:30,090 --> 00:12:35,670
+بيكربونات، تحولت كلها إلى ماذا؟ إلى الكربونات. إذن هذه
+
+144
+00:12:35,670 --> 00:12:46,410
+نقطة التكافؤ الثانية. X صارت تساوي Y. صفر، صفر، صفر
+
+145
+00:12:46,410 --> 00:12:48,830
+صفر، صفر، صفر، صفر، صفر، صفر، صفر، صفر، صفر، صفر، صفر
+
+146
+00:12:48,830 --> 00:12:49,150
+صفر، صفر، صفر، صفر، صفر، صفر، صفر، صفر، صفر، صفر، صفر
+
+147
+00:12:49,150 --> 00:12:50,030
+صفر، صفر، صفر، صفر، صفر، صفر، صفر، صفر، صفر، صفر، صفر
+
+148
+00:12:50,030 --> 00:12:52,550
+صفر، صفر، صفر، صفر، صفر، صفر، صفر، صفر، صفر، صفر، صفر
+
+149
+00:12:52,550 --> 00:12:56,910
+صفر، صفر، صفر، صفر، صفر، صفر، صفر، صفر، صفر، صفر، صفر
+
+150
+00:12:56,910 --> 00:13:02,660
+صفر، صفر، صفر، صفر، صفر، صفر، صفر.  على كربونات فقط.
+
+151
+00:13:02,660 --> 00:13:06,080
+كربونات. انتهى الـ بيكربونات. ما في طبعاً عندي hydroxide.
+
+152
+00:13:06,080 --> 00:13:09,280
+equivalence point. يعني، بس عندي كربونات. كيف الآن
+
+153
+00:13:09,280 --> 00:13:16,700
+أجيب الـ pH لمحلول كربونات؟ هذا السؤال كيف؟
+
+154
+00:13:19,380 --> 00:13:24,100
+ماشي، ماشي. نقول الكربونات هي unprotonated salt.
+
+155
+00:13:24,100 --> 00:13:30,520
+كيف أوجد الـ pH لها؟ آه، هذه هي كربونات زائد ماء
+
+156
+00:13:30,520 --> 00:13:36,020
+تعطيني HCO₃⁻ زائد hydroxide. أجيب الـ Kᵦ Kʷ
+
+157
+00:13:36,020 --> 00:13:39,880
+على Kₐ₂. وأنا عندي تركيز الكربونات X على الـ total
+
+158
+00:13:39,880 --> 00:13:45,140
+volume. إذن X على الـ total volume ناقص قيمة صغيرة.
+
+159
+00:13:46,420 --> 00:13:50,340
+تعطيني قيمة صغيرة، نفس قيمة الهيدروكسيد، و
+
+160
+00:13:50,340 --> 00:13:57,740
+من الـ Kᵦ أقدر أوجد الهيدروكسيد، وأجيب منه الـ pOH، و
+
+161
+00:13:57,740 --> 00:14:02,440
+من الـ pOH أحسب الـ pH. يبقى هذا الـ second
+
+162
+00:14:02,440 --> 00:14:09,420
+equivalence point. طيب، ماذا يحدث بعد ذلك؟ هي صار
+
+163
+00:14:09,420 --> 00:14:13,460
+عندها كربونات. طيب، لو حطيت عليها كمان هيدروكسيد، ماذا
+
+164
+00:14:13,460 --> 00:14:19,660
+يحدث؟ كربونات زائد هيدروكسيد، يتفاعلان مع بعض؟ طبعاً
+
+165
+00:14:19,660 --> 00:14:23,540
+لا، two bases. لو أنه فيه H، آه، الهيدروكسيد يتفاعل
+
+166
+00:14:23,540 --> 00:14:26,480
+معه، بس ما في عندي أي H، هذا عليه شحنتين سالبتين، و
+
+167
+00:14:26,480 --> 00:14:29,680
+هذا عليه شحنة سالبة، وما في عندي أي protons، معناه
+
+168
+00:14:29,680 --> 00:14:35,410
+الكلام، يبقى لا يتفاعلان مع بعض. طيب، كيف أحسب الـ pH؟
+
+1
+
+223
+00:19:02,360 --> 00:19:06,540
+خمسين مل من Sodium Hydroxide بقول والله أنا عندي
+
+224
+00:19:06,540 --> 00:19:09,640
+الملي مول من Carbonic Acid خمسة ملي مول من Sodium
+
+225
+00:19:09,640 --> 00:19:12,600
+Hydroxide أدت برضه كمان خمسة، إذا الملي مول من
+
+226
+00:19:12,600 --> 00:19:17,520
+Carbonic Acid المتبقي left خمسة نقص خمسة صفر، مدين
+
+227
+00:19:17,520 --> 00:19:20,960
+طلع صفر، إذا هذا بيقول في عندنا equivalence point
+
+228
+00:19:20,960 --> 00:19:24,560
+في عندنا equivalence point، هذا هي الـ first
+
+229
+00:19:24,560 --> 00:19:28,480
+equivalence point، كل الـ Carbonic Acid اتحول لإيه؟
+
+230
+00:19:29,710 --> 00:19:33,110
+للبيكربونيت، إذا الـ minimum للبيكربونيت بتساوي
+
+231
+00:19:33,110 --> 00:19:37,610
+خمسة، تركيز البيكربونيت خمسة على مية، يعني خمسة من
+
+232
+00:19:37,610 --> 00:19:42,150
+مئه، والآن السؤال كيف نحسب الـ pH للبيكربونيت جال
+
+233
+00:19:42,150 --> 00:19:45,310
+من القانون لأنها أدا protonated salt
+
+234
+00:19:48,230 --> 00:19:51,450
+بتطلع عنه قانون، أستخدم، بطلع الشحنة اللي على الـ
+
+235
+00:19:51,450 --> 00:19:54,910
+بيكربونيت، شحنة واحدة، إذا القانون اللي بستخدمه K<sub>A</sub>
+
+236
+00:19:54,910 --> 00:19:59,570
+one في البداية، فباجي أقول والله هذا القانون بعوض
+
+237
+00:19:59,570 --> 00:20:02,990
+عنه، بتطلع إن الـ H<sup>+</sup> أربعة و نص في عشرة أس سالب
+
+238
+00:20:02,990 --> 00:20:08,640
+تسعة، والـ pH تمانية وأربعة وتلاتين، هذه هي نقطة
+
+239
+00:20:08,640 --> 00:20:13,720
+التكافؤ الأولى، الآن في المحلول أُضيفت خمسين مل من
+
+240
+00:20:13,720 --> 00:20:16,860
+الـ sodium hydroxide، بقبل في عندي أي Carbonic
+
+241
+00:20:16,860 --> 00:20:21,600
+acid، كل اللي عندي إيه؟ بيكربونيت، طيب، نيجي
+
+242
+00:20:21,600 --> 00:20:27,560
+نضيف كمية أكبر من الـ sodium hydroxide، بقول أنا الـ
+
+243
+00:20:27,560 --> 00:20:30,980
+initial millimole بيكربونيت خمسة، كل الكربونيك أسيد
+
+244
+00:20:30,980 --> 00:20:33,920
+اتحول للبيكربونيت، فالـ initial millimole بيكربونيت
+
+245
+00:20:33,920 --> 00:20:38,800
+خمسة، أنا أضفت خمسة وسبعين مل، لكن لاحظوا إنه أول
+
+246
+00:20:38,800 --> 00:20:42,960
+خمسين هدول اتفعلوا مع الكربونيك أسيد علشان يحولوا
+
+247
+00:20:42,960 --> 00:20:47,860
+للبيكربونيت، فأول خمسين اتفاعلوا، إذا جديش أنا
+
+248
+00:20:47,860 --> 00:20:52,080
+أضفت على البيكربونيت؟ بس خمسة وعشرين، أول خمسين
+
+249
+00:20:52,080 --> 00:20:55,020
+اتفاعلوا مع الـ carbonic acid علشان يحولوا للـ
+
+250
+00:20:55,020 --> 00:20:58,100
+بيكربونيت، إذا أنا جديش أضفت على البيكربونيت؟
+
+251
+00:20:58,100 --> 00:21:01,740
+خمسة وعشرين، يعني اتنين ونص millimol، الملي مول
+
+252
+00:21:01,740 --> 00:21:05,340
+بيكربونيت left خمسة ناقص اتنين ونص، اتنين ونص،
+
+253
+00:21:05,340 --> 00:21:09,780
+تركيز البيكربونيت اتنين ونص على خمسة وسبعين وخمسين، 125
+
+254
+00:21:09,780 --> 00:21:15,660
+مولي، اتنين ونص على 125 مولار، الآن لما
+
+255
+00:21:15,660 --> 00:21:19,620
+أضفت أنا الـ sodium hydroxide اتنين ونص ميلي مول
+
+256
+00:21:19,620 --> 00:21:24,940
+من الـ sodium hydroxide على البيكربونيت، طبعاً
+
+257
+00:21:24,940 --> 00:21:30,620
+اتحولت لكربونيت كمية مناظرة، فالميلي مول كربونيت
+
+258
+00:21:30,620 --> 00:21:37,370
+formed اتنين ونص، تركيز الكربونيت، الملي مول من
+
+259
+00:21:37,370 --> 00:21:39,730
+الكربونيت اللي هو اتنين ونص على total volume مية
+
+260
+00:21:39,730 --> 00:21:44,350
+خمسة وسبعين، ولو أطلعت معايا بتلاقي إن عندك
+
+261
+00:21:44,350 --> 00:21:49,550
+كربونيت وبيكربونيت، هذا أيضاً buffer solution، هذا
+
+262
+00:21:49,550 --> 00:21:53,250
+أيضاً buffer solution، هي الـ acid وهي its conjugate
+
+263
+00:21:53,250 --> 00:21:57,570
+base، كيف بدي أحسبه؟ أي معادلة فيها البيكربونيت و
+
+264
+00:21:57,570 --> 00:22:03,360
+الكربونيت هي معادلة التفكك الثانية، فباجي بقول من
+
+265
+00:22:03,360 --> 00:22:07,540
+بعمل الجدول اللي إذا كان حبيت، فبقول هذا الـ B
+
+266
+00:22:07,540 --> 00:22:11,800
+carbonate 2.5 على 125، الـ carbonate 2.5 على 125، هذا
+
+267
+00:22:11,800 --> 00:22:16,720
+ناقص X، زائد X، لو حبينا إنه نلغي الـ X ده و
+
+268
+00:22:16,720 --> 00:22:21,060
+مانحطهاش من الأصل مافيش أي مشكلة، لأنه بالفعل هذا
+
+269
+00:22:21,060 --> 00:22:24,320
+buffer، ولما نكون عندنا buffer الـ X مافيش لها قيمة،
+
+270
+00:22:24,320 --> 00:22:29,670
+قيمتها مهملة، فبطبق الـ K<sub>A</sub>2 بتساوي الـ X، 2.5 على 125
+
+271
+00:22:29,670 --> 00:22:35,770
+على 2.5 على 125، بيروحوا مع بعض هدول القيمتين، بتصير
+
+272
+00:22:35,770 --> 00:22:44,530
+الـ X إيش بتساوي؟ يبقى عندنا نص، لو قلنا هنا الـ end
+
+273
+00:22:44,530 --> 00:22:50,730
+point الثانية، يبقى عند نص الحجم اللازم للوصول لها
+
+274
+00:22:50,730 --> 00:22:54,850
+من نقطة التكافؤ الأولى لنقطة التكافؤ الثانية، عند
+
+275
+00:22:54,850 --> 00:23:01,580
+الـ pH بتساوي الـ pK<sub>A</sub>2، أو عند تلت أرباع الحجم
+
+276
+00:23:01,580 --> 00:23:06,060
+اللازم للوصول لنقطة التكافؤ الثانية، في عند الـ pH
+
+277
+00:23:06,060 --> 00:23:10,260
+بتساوي الـ pK<sub>A</sub>2، وهذا شيء ممتاز كتير لأنه أنا
+
+278
+00:23:10,260 --> 00:23:15,820
+لو عندي acid مجهول، الـ K<sub>A</sub>s بقدر من عملية المعايرة و
+
+279
+00:23:15,820 --> 00:23:21,300
+تتبع عملية المعايرة ومعرفة موضع الـ equivalence
+
+280
+00:23:21,300 --> 00:23:29,030
+point الأولى والثانية، بقدر أحسب جديش بالضبط الـ K<sub>A</sub>1
+
+281
+00:23:29,030 --> 00:23:34,690
+والـ K<sub>A</sub>2، بمعرفتي لموضع الـ equivalence point الأولى
+
+282
+00:23:34,690 --> 00:23:39,910
+والثانية، بقدر أحدد الحجوم اللي عندها بالضبط بتكون
+
+283
+00:23:39,910 --> 00:23:46,330
+الـ pH بتساوي pK<sub>A</sub>1 والـ pH بتساوي pK<sub>A</sub>2
+
+284
+00:23:46,330 --> 00:23:51,230
+مع هذا الكلام، الـ X بتطلع أربعة أو ثمانية أو عشرة أو أحد عشر، والـ pH
+
+285
+00:23:51,230 --> 00:23:57,230
+إن هذا هو عبارة عن الـ H<sup>+</sup>، والـ pH عشرة واثنين وثلاثين وثلاثين
+
+286
+00:23:59,820 --> 00:24:07,280
+طيب، إيش بيحصل بعد إضافة 100 مل من الـ sodium
+
+287
+00:24:07,280 --> 00:24:12,260
+hydroxide؟ إيش بيحصل بعد إضافة 100 مل من الـ sodium
+
+288
+00:24:12,260 --> 00:24:18,740
+hydroxide؟ لاحظ معايا إنه المية هذه، أول خمسين منها
+
+289
+00:24:18,740 --> 00:24:25,630
+راحوا لمعاملة الـ carbonic acid، حولوا لإيه؟ للـ
+
+290
+00:24:25,630 --> 00:24:30,810
+بيكربونيت، يعني وكأني أنا أضفت خمسين مل على الـ
+
+291
+00:24:30,810 --> 00:24:36,290
+بيكربونيت، كمان مرة بقول أنا أضفت مئة مل هنا، أول
+
+292
+00:24:36,290 --> 00:24:42,390
+خمسين حولوا هذا للبيكربونيت، إذا وكأني أنا أضفت
+
+293
+00:24:42,390 --> 00:24:47,860
+خمسين مل على البيكربونيت، بنفس الطريقة بنقول الملي
+
+294
+00:24:47,860 --> 00:24:51,500
+مول بيكربونيت أصلاً خمسة، الملي مول هيدروكسايد
+
+295
+00:24:51,500 --> 00:24:55,180
+added point one في خمسين، خمسة، إذا الملي مول
+
+296
+00:24:55,180 --> 00:25:02,560
+بيكربونيت left خمسة ناقص خمسة، صفر، معناته this is
+
+297
+00:25:02,560 --> 00:25:06,980
+the second equivalence point، هذه هي الـ second
+
+298
+00:25:06,980 --> 00:25:13,320
+equivalence point، نقطة التكافؤ الثانية، طيب معنى
+
+299
+00:25:13,320 --> 00:25:17,480
+الكلام، كل البيكربونات خلصت، هاي الـ left عندنا صفر،
+
+300
+00:25:17,480 --> 00:25:21,160
+مافيش عندي بيكربونات، معنى الكلام كلها اتحولت
+
+301
+00:25:21,160 --> 00:25:25,660
+إليه؟ للكربونات، يبقى الميلي مول الكربونات بتساوي
+
+302
+00:25:25,660 --> 00:25:28,980
+خمسة، الـ carbonic acid خمسة ميلي مول اتحول كله
+
+303
+00:25:28,980 --> 00:25:32,380
+لبيكربونات، خمسة ميلي مول اتحولت كلها للكربونات،
+
+304
+00:25:32,380 --> 00:25:37,080
+طبعاً خمسة ميلي مول ما بتتغير، إذا تركيز الكربونات
+
+305
+00:25:37,080 --> 00:25:42,650
+خمسة على مئة وخمسين، يبقى الآن في عندي محلول
+
+306
+00:25:42,650 --> 00:25:49,450
+carbonate، تركيزها خمسة على مئة وخمسين، الآن كيف بدي
+
+307
+00:25:49,450 --> 00:25:55,870
+أحسب الـ pH لمحلول carbonate، unprotonated salt، طبعاً
+
+308
+00:25:55,870 --> 00:26:03,690
+بقول حساب الـ pH له مباشر، ممكن أقول والله الكربونيت
+
+309
+00:26:03,690 --> 00:26:08,330
+في المي بتعطيني بيكربونيت زائد هيدروكسايد، طبعاً هذا
+
+310
+00:26:08,330 --> 00:26:13,290
+طالع عندي هيدروكسايد، K<sub>b</sub> بتساوي K<sub>w</sub> على K<sub>a</sub>، أنهي K<sub>a</sub>؟
+
+311
+00:26:13,290 --> 00:26:17,510
+فباجي بطلع، بلاقي عندي هنا سالب اثنين، يعني شحنة
+
+312
+00:26:17,510 --> 00:26:22,640
+سالبة اثنين، معناته K<sub>a</sub>2، فبكتب الـ K<sub>w</sub> اللي هو عشرة أس سالب
+
+313
+00:26:22,640 --> 00:26:26,460
+أربعة عشر، على K<sub>a</sub>2، أربعة وثمانية في عشرة
+
+314
+00:26:26,460 --> 00:26:31,280
+أس سالب أحد عشر، بيطلع لنا اتنين وواحد في عشرة أس سالب
+
+315
+00:26:31,280 --> 00:26:35,860
+أربعة، هذه أحد عشر مش ثلاث عشرة، اتنين وواحد في
+
+316
+00:26:35,860 --> 00:26:41,520
+عشرة أس سالب أربعة، الآن يا شباب عندي بس كربونات خمسة
+
+317
+00:26:41,520 --> 00:26:46,480
+على 150، 0 0، 5 على 150، ناقص X، زائد X، زي ما إحنا
+
+318
+00:26:46,480 --> 00:26:53,560
+متعودين نوجد الـ pH للـ unprotonated salt، فبنرجع في
+
+319
+00:26:53,560 --> 00:26:57,760
+الـ K<sub>b</sub> بتساوي الـ X<sup>2</sup> على 5 على 150 ناقص X، و
+
+320
+00:26:57,760 --> 00:27:02,460
+بنعمل الفرضية تبعتنا، 5 على 150 أكبر كتير من الـ X،
+
+321
+00:27:02,680 --> 00:27:07,760
+معناته الـ X هتساوي اتنين وستة في عشرة أس سالب ثلاثة، لو
+
+322
+00:27:07,760 --> 00:27:11,820
+أجينا حسبنا الـ relative error، هل هذا يعني، هل معقول
+
+323
+00:27:11,820 --> 00:27:15,780
+أنه نلغي الـ X جنب هذا الرقم ولا لا؟ فبنحسب الـ
+
+324
+00:27:15,780 --> 00:27:18,340
+relative error، بيطلع سبعة وتسعة من عشرة في المئة،
+
+325
+00:27:18,340 --> 00:27:23,240
+حوالي ثمانية في المئة، هذا بيخالف الـ margin أو
+
+326
+00:27:23,240 --> 00:27:27,180
+الهامش اللي إحنا حاطينه إلينا، إحنا حاطين هامش
+
+327
+00:27:27,180 --> 00:27:32,160
+مقداره خمسة في المئة، فهذا سبعة وتسعة وعشرة، معناته
+
+328
+00:27:32,160 --> 00:27:36,000
+the assumption is invalid and therefore we should
+
+329
+00:27:36,000 --> 00:27:40,700
+use the quadratic equation، لكن أنا جايلكم إنه يعني
+
+330
+00:27:40,700 --> 00:27:44,320
+بس عشان الحسابات، أنا راح أقبله، بس أما أنت في
+
+331
+00:27:44,320 --> 00:27:48,580
+الامتحان لا، في الامتحان ما تقبلهش، قول لي إنه حل الـ
+
+332
+00:27:48,580 --> 00:27:51,740
+quadratic equation، لكن أنا هنجيبه بس علشان أطلع
+
+333
+00:27:51,740 --> 00:27:58,400
+النتيجة، طيب خلينا نضيف 150 مل من الـ sodium
+
+334
+00:27:58,400 --> 00:28:06,780
+hydroxide، نضيف 150 مل من الـ sodium hydroxide، بقول
+
+335
+00:28:06,780 --> 00:28:12,960
+150 مل، هدول في الحقيقة لو أجيت بدي أفصلهم، بقول هذه
+
+336
+00:28:12,960 --> 00:28:17,500
+الخمسين لتحويل الـ carbonic acid للبيكربونات،
+
+337
+00:28:17,500 --> 00:28:24,490
+وهذه الخمسين الثانية لتحويل البيكربونات للكربونات،
+
+338
+00:28:24,490 --> 00:28:30,050
+ومعنى الكلام أنا أضفت بس خمسين على الكربونات،
+
+339
+00:28:30,050 --> 00:28:33,550
+أضفت بس خمسين على الكربونات، يبقى عندي الآن
+
+340
+00:28:33,550 --> 00:28:37,450
+المحلول محلول الكربونات، ومحطوط عليه كمان خمسين مل
+
+341
+00:28:37,450 --> 00:28:40,490
+من الهيدروكسايد، لكن الهيدروكسايد ما تفاعلش مع
+
+342
+00:28:40,490 --> 00:28:45,750
+الكربونات، لكن الهيدروكسيد ما بيتفاعل مع الكربونيت،
+
+343
+00:28:45,750 --> 00:28:51,470
+فكيف بنحسب الـ pH؟ بنقول في معظم الأحيان، لو جينا
+
+344
+00:28:51,470 --> 00:28:58,310
+إحنا طلعنا مثلاً في الـ slide الماضية، لو جينا طلعنا
+
+345
+00:28:58,310 --> 00:29:00,550
+على الـ equilibrium للكربونيت بنلاحظ إنه فيه
+
+346
+00:29:00,550 --> 00:29:05,910
+هيدروكسيد، يعني الكربونيت بتعطيني هيدروكسيد، لكن
+
+347
+00:29:05,910 --> 00:29:08,810
+عندما يكون هناك أنديانا هيدروكسايد إكسيث من
+
+348
+00:29:08,810 --> 00:29:11,950
+الصوديوم هيدروكسايد، هذا الـ equilibrium له
+
+349
+00:29:11,950 --> 00:29:16,910
+equilibrium constant اتنين وواحد في عشرة أس سالب أربعة، يعتبر
+
+350
+00:29:16,910 --> 00:29:23,410
+قليل، مش قريب على عشرة أس سالب اثنين أو عشرة أس سالب واحد،
+
+351
+00:29:24,630 --> 00:29:28,650
+ماشي، يعتبر إيه؟ قليل، عشرة أس سالب أربعة قليل نسبياً،
+
+352
+00:29:28,650 --> 00:29:32,410
+فيعني إيش يعني قليل؟ يعني كمية الـ hydroxide اللي
+
+353
+00:29:32,410 --> 00:29:36,270
+جاية من الكربونيت قليلة، ليه؟ لأنه الـ equilibrium
+
+354
+00:29:36,270 --> 00:29:42,160
+constant إيش ماله؟ قليل، طيب إيش بيحصل لما يكون في
+
+355
+00:29:42,160 --> 00:29:46,180
+عندي هيدروكسيد أيضاً جاي من الـ sodium hydroxide
+
+356
+00:29:46,180 --> 00:29:51,120
+excess، في عندي خمسين مل من الـ sodium hydroxide، آه،
+
+357
+00:29:51,120 --> 00:29:56,580
+هو أصلاً قليل، و بده يرجع لورا كمان لتشاتليه، حسب
+
+358
+00:29:56,580 --> 00:30:01,660
+لتشاتليه، هو في الأصل قليل، وبده يرجع لورا أيضاً،
+
+359
+00:30:01,660 --> 00:30:08,440
+فمعنى الكلام، آه، بده يجيء تأثير كبير خالص، عشان هيك أنا
+
+360
+00:30:08,440 --> 00:30:17,740
+بقول، يعني كشيء عام، في معظم الأحيان رح يكون مبرر عندنا
+
+361
+00:30:17,740 --> 00:30:21,120
+إن نقول والله الملي مول Sodium hydroxide
+
+362
+00:30:21,120 --> 00:30:24,100
+excess point one في خمسين، خمسة ملي مول، إذا
+
+363
+00:30:24,100 --> 00:30:27,500
+تركيز Sodium hydroxide الـ excess خمسة على مئتين،
+
+364
+00:30:27,500 --> 00:30:31,340
+وبما إنه ما فيش مصدر hydroxide إلا هذا الـ hydroxide،
+
+365
+00:30:31,340 --> 00:30:35,120
+والـ hydroxide اللي جاي من الكربونات، وبما إن الـ
+
+366
+00:30:35,120 --> 00:30:37,440
+hydroxide اللي جاي من الكربونات قليل جداً، إذا هذا
+
+367
+00:30:37,440 --> 00:30:40,400
+هو الـ hydroxide اللي في المحلول، ممكن نحكي زي هيك،
+
+368
+00:30:40,710 --> 00:30:43,950
+لكن في الحقيقة، وبنحسب الـ pOH ومنها بنجيب الـ pH،
+
+369
+00:30:43,950 --> 00:30:49,950
+لكن يا شباب في الحقيقة يعني مش دائماً هذا الكلام صحيح،
+
+370
+00:30:49,950 --> 00:30:55,200
+مش دائماً، وهذا الكلام بيتوقف عليه حاجتين، بيتوقف على الـ
+
+371
+00:30:55,200 --> 00:31:00,320
+K، حاجة، جديش الـ equilibrium constant، الـ K، بيكون كويس،
+
+372
+00:31:00,320 --> 00:31:06,620
+وبيتوقف على كمان تركيز الـ salt، فلما يكون تركيز الـ salt
+
+373
+00:31:06,620 --> 00:31:13,760
+كمان قليل كتير، معناته والله يعني مشكلة، ولما يكون
+
+374
+00:31:13,760 --> 00:31:17,840
+عالي، معناته آه، في احتمال إنه يعطيني hydroxide أكثر،
+
+375
+00:31:18,980 --> 00:31:23,520
+فهذا بيتوقف عليه تركيز الـ salt حاجة، وأيضاً الـ K<sub>b</sub>
+
+376
+00:31:23,520 --> 00:31:27,820
+حاجة ثانية، فأنا بقول إنه نفترض إن الـ hydroxide هو
+
+377
+00:31:27,820 --> 00:31:30,600
+عبارة عن فقط الـ hydroxide اللي جاي من الـ sodium
+
+378
+00:31:30,600 --> 00:31:34,880
+hydroxide، وإن كان منطقي يعني في هذه الحالة تحديداً،
+
+379
+00:31:34,880 --> 00:31:39,300
+لأنه الـ K<sub>b</sub> قليل، وإن كان منطقي إلا أنه الأفضل أن
+
+380
+00:31:39,300 --> 00:31:43,530
+نحسبه، الأفضل إنه نحسب الـ hydroxide اللي جاي من
+
+381
+00:31:43,530 --> 00:31:48,030
+الكربونيت، ونجمع الاتنين، أو إنه نقول والله آه اللي
+
+382
+00:31:48,030 --> 00:31:52,770
+جاي من الكربونيت قليل جداً، وبالتالي الـ hydroxide
+
+383
+00:31:52,770 --> 00:31:57,350
+اللي عندي خمسة على مئتين، كيف بنعمل هذا الكلام طبعاً
+
+384
+00:31:
+
+445
+00:37:07,090 --> 00:37:09,790
+أو ثلاثة، بيانة الـ H Plus اللي جاي منه هيكون قليل
+
+446
+00:37:09,790 --> 00:37:17,010
+كتير، فما بالكم في وجود H Plus جاية من الـ Excess
+
+447
+00:37:17,010 --> 00:37:21,010
+HCL هيرجع يبقى حاطين الكمية، أي زيادة  مهمة للغاية
+
+448
+00:37:21,010 --> 00:37:24,950
+عشان كده الـ H Plus غالبا هتكون هي الـ H Plus الناشئة
+
+449
+00:37:24,950 --> 00:37:30,780
+عن الزيادة في الـ HCL. طيب يا شباب، إذا الله راض
+
+450
+00:37:30,780 --> 00:37:36,900
+الحصة الجاية هناخد مثال بيعالج الـ poly basic bases
+
+451
+00:37:36,900 --> 00:37:41,140
+و ما بديش أخد الكربونيت لإنه هيكون كلام مكرر، هاخد
+
+452
+00:37:41,140 --> 00:37:48,860
+الفوسفيت، إيش بيحصل لما نُعَير الفوسفيت بالـ HCl؟  فإذا
+
+453
+00:37:48,860 --> 00:37:50,580
+الله راض، بنشوفكم الحصة الجاية
diff --git a/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/P1ca0YrAX7k_postprocess.srt b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/P1ca0YrAX7k_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..8ba3005e323077f8f890d4ab1e4d50e584420caa
--- /dev/null
+++ b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/P1ca0YrAX7k_postprocess.srt
@@ -0,0 +1,1812 @@
+1
+00:00:20,960 --> 00:00:23,640
+بسم الله الرحمن الرحيم فقولنا يا شباب ان ال
+
+2
+00:00:23,640 --> 00:00:29,740
+carbonic acids كلها ضعيفة
+
+3
+00:00:29,740 --> 00:00:34,440
+ال carbonic acid حمض ضعيف مثلا لكنه polyprotic
+
+4
+00:00:34,440 --> 00:00:38,420
+acid يعني بيحتوي على two protons التفكك الأول
+
+5
+00:00:38,420 --> 00:00:42,500
+بيعطيني H plus زائد B carbonate التفكك التاني
+
+6
+00:00:42,500 --> 00:00:49,100
+بيعطيني H plus زائد carbonateعلى أي حال إذا كان
+
+7
+00:00:49,100 --> 00:00:54,250
+بدنا نعاير حمض زي هذابنقول إن معاييرته يجب أن تتم
+
+8
+00:00:54,250 --> 00:00:59,810
+باستخدام strong base ليه؟ لأن أحد طرفي المعايرة
+
+9
+00:00:59,810 --> 00:01:03,810
+يجب إنه يكون strong على أساس إنه لا يمكن معايرة
+
+10
+00:01:03,810 --> 00:01:07,990
+weak acid ب weak base visually يعني المعاييرات
+
+11
+00:01:07,990 --> 00:01:12,450
+اللي احنا بنعرفها المعاييرات البصرية أو المعاييرات
+
+12
+00:01:12,450 --> 00:01:16,190
+اللي احنا بنطلع فيها على تغير اللون لل pH
+
+13
+00:01:16,190 --> 00:01:21,790
+indicatorفيجب أحد طرفي التفاعل يكون strong
+
+14
+00:01:21,790 --> 00:01:26,530
+فبيتفاعل ال carbonic acid مع حاجة زي ال sodium
+
+15
+00:01:26,530 --> 00:01:31,190
+hydroxide لكن السؤال هل بحصل على one inflection
+
+16
+00:01:31,190 --> 00:01:37,010
+point one end point ولا two end points بقول أنا في
+
+17
+00:01:37,010 --> 00:01:39,930
+عندي two protons في ال carbonic acid فمتوقع أن
+
+18
+00:01:39,930 --> 00:01:46,070
+أحصل من كل proton على one equivalence point او one
+
+19
+00:01:46,070 --> 00:01:52,510
+end pointطبيعي في أحماض أخرى برضه polyprotic
+
+20
+00:01:52,510 --> 00:01:57,970
+وبتوقع أنه أحصل منها على عدد من ال equivalence
+
+21
+00:01:57,970 --> 00:02:02,210
+points يساوي عدد ال protons الموجودة في ال acid
+
+22
+00:02:02,210 --> 00:02:06,330
+لكن في الحقيقة مش دائما بحصل على نفس العدد من ال
+
+23
+00:02:06,330 --> 00:02:10,510
+equivalence points مساوي لعدد ال protons اللي
+
+24
+00:02:10,510 --> 00:02:17,190
+موجودة في ال polyprotic acid علشان أحصل علىان احصل
+
+25
+00:02:17,190 --> 00:02:23,630
+على equivalent point مميزة لكل proton يجب ان يكون
+
+26
+00:02:23,630 --> 00:02:32,060
+kA1 على kA2 اكبر من 10 اقصى 4في حالة ما يقترب
+
+27
+00:02:32,060 --> 00:02:37,060
+الـKA1 من الـKA2، بيحصل Merge للـTwo Equivalence
+
+28
+00:02:37,060 --> 00:02:40,580
+Points في واحدة، يعني واحدة منهم بتبينش على حساب،
+
+29
+00:02:40,580 --> 00:02:46,020
+التانية عادة من الأقل، بيحصلها Merge في ال .. في
+
+30
+00:02:46,020 --> 00:02:54,660
+ال .. يعني ال ..ال equivalence point التاني بحصلها
+
+31
+00:02:54,660 --> 00:02:57,060
+marriage في ال equivalence point الأولى و بتعطيني
+
+32
+00:02:57,060 --> 00:03:03,220
+best when equivalence point ظاهرة اه بعدوا في بعض
+
+33
+00:03:03,220 --> 00:03:07,530
+يعني marriage بعدوا في بعض اختلاطفلازم يكون عندى
+
+34
+00:03:07,530 --> 00:03:11,710
+ال K a1 اكبر كتير من ال K a2 اذا كان بدي احصل على
+
+35
+00:03:11,710 --> 00:03:22,950
+one distinct one observable equivalence point لكل
+
+36
+00:03:22,950 --> 00:03:27,210
+proton موجودة عندى هذه حاجة الحاجة التانية اللى
+
+37
+00:03:27,210 --> 00:03:31,250
+لازم اخد بالي منها ايضا انه في بعض الأحيان بيكون
+
+38
+00:03:31,250 --> 00:03:36,900
+عندى صحبوليبروتيك أسد لكن بعض الـKa خاصة المتأخر
+
+39
+00:03:36,900 --> 00:03:42,360
+يعني Ka3 أو Ka4 صغير كتير يعني 10 أقل سالب 15 10
+
+40
+00:03:42,360 --> 00:03:48,040
+أقل سالب 16 10 أقل سالب 13 صعب جدا أن أحصل أو أقدر
+
+41
+00:03:48,040 --> 00:03:53,770
+أشوف ال equivalence point له لأنه ضعيف كتيرفمش بس
+
+42
+00:03:53,770 --> 00:03:58,490
+كأ واحد على كأ اتنين بدها تكون كبيرة لأ وكمان ال
+
+43
+00:03:58,490 --> 00:04:03,590
+.. ال acid dissociation constant نفسه للبروتن اللي
+
+44
+00:04:03,590 --> 00:04:07,090
+أنا بده أشوفه يجب أنه يكون برضه يعني إلى حد ما
+
+45
+00:04:07,090 --> 00:04:12,570
+معقول وإلا مش راح أقدر أشوف equivalence point لهذا
+
+46
+00:04:12,570 --> 00:04:20,690
+البروتن الحد بشكل عام احنا خلينا نتكلم عنإنه في
+
+47
+00:04:20,690 --> 00:04:24,930
+عندنا ال polyprotic acids و كتير منها بيعطيني
+
+48
+00:04:24,930 --> 00:04:35,090
+distinct equivalence point لكل proton فبنقول كل
+
+49
+00:04:35,090 --> 00:04:38,670
+proton موجود أو كل equivalence point بحصل عليها
+
+50
+00:04:38,670 --> 00:04:43,680
+تحتاج إلى indicator معينليه؟ لأنه احنا عارفين ان
+
+51
+00:04:43,680 --> 00:04:47,360
+ال indicator بيشتغل في range معين فهنا بالتالي كل
+
+52
+00:04:47,360 --> 00:04:53,540
+observable براطون كل observable equivalence point
+
+53
+00:04:53,540 --> 00:04:59,980
+تحتاج الى indicator معين فبالتالي اذا كان في عندي
+
+54
+00:04:59,980 --> 00:05:03,880
+two observable equivalence points انا بحاجة ألاقي
+
+55
+00:05:03,880 --> 00:05:08,440
+two different indicators لأنه لو في النهاية بدي
+
+56
+00:05:08,440 --> 00:05:11,690
+استخدم one indicatorهيقول لي والله اه one
+
+57
+00:05:11,690 --> 00:05:13,790
+equivalence point كل indicator هتعطيني equivalence
+
+58
+00:05:13,790 --> 00:05:18,090
+point ليه؟ لأن اللون بتغير من a لb او من color one
+
+59
+00:05:18,090 --> 00:05:23,730
+ل color two طيب خلينا نتطلع على معاييرة carbonic
+
+60
+00:05:23,730 --> 00:05:29,710
+acid مع sodium hydroxide فلو عندي مثلا خمسين mil
+
+61
+00:05:29,710 --> 00:05:33,770
+من point one molar carbonic acid و بعيّرهم بال
+
+62
+00:05:33,770 --> 00:05:37,870
+sodium hydroxide بقول في عندي عدة مراحل للمعايرة
+
+63
+00:05:38,900 --> 00:05:42,920
+أول مرحلة اذا كان رسمتي ال titration curve بشوف
+
+64
+00:05:42,920 --> 00:05:47,680
+هذا الكلام بوضوح اول مرحلة قبل اضافة اي sodium
+
+65
+00:05:47,680 --> 00:05:51,720
+hydroxide او after addition of 0 ml من ال sodium
+
+66
+00:05:51,720 --> 00:05:54,460
+hydroxide تاجب ابطلع مافيش عندى اي sodium
+
+67
+00:05:54,460 --> 00:05:57,240
+hydroxide ايش الموجود عندى في المحلول؟
+
+68
+00:06:02,890 --> 00:06:09,270
+لحظة بدأ من low pH لأنه اسد له low pH يبقى لازم
+
+69
+00:06:09,270 --> 00:06:14,610
+أعرف أحسب في البدايةما هي ال pH أو كيفية حساب ال
+
+70
+00:06:14,610 --> 00:06:19,930
+pH لـPure Carbonic Acid؟ بقول الحساب سهل كثير عادة
+
+71
+00:06:19,930 --> 00:06:24,330
+ايش بسوي؟ بقول والله ال carbonic acid بتفكك بعطيني
+
+72
+00:06:24,330 --> 00:06:28,610
+بيكربونيت وبروتون وال بيكربونيت بتتفكك تعطيني
+
+73
+00:06:28,610 --> 00:06:34,360
+كربونيت وبروتونبقول kA1 على kA2 أكبر من عشرة أقصى
+
+74
+00:06:34,360 --> 00:06:39,600
+اتنين إذاً بيتبقى فقط التفاكك الأول التفاكك الأول
+
+75
+00:06:39,600 --> 00:06:45,580
+carbonic acid تركيزه C أي تركيز لبروتون قبل
+
+76
+00:06:45,580 --> 00:06:50,500
+التفاكك الصفر ال B carbon الصفر إذا C minus X X X
+
+77
+00:06:50,500 --> 00:06:55,380
+وبتقول kA1 بتساوي X تربيه على C minus X ال C
+
+78
+00:06:55,380 --> 00:07:01,340
+معلومةو هيك بنحسب ال C ال X اللي هي ال H plus أو
+
+79
+00:07:01,340 --> 00:07:05,040
+التركيز ل ال protons و منها بنجيب ال pH فهذا كلام
+
+80
+00:07:05,040 --> 00:07:09,960
+شفناه سابقا و هناخد مثال حسابي بعد شوية يبقى هذه
+
+81
+00:07:09,960 --> 00:07:16,120
+اول مرحلة المرحلة التانية هي المرحلة اللي انا ببدأ
+
+82
+00:07:16,120 --> 00:07:22,620
+اضيف فيها ببدأ اضيف فيها Sodium Hydroxide انا عندي
+
+83
+00:07:22,620 --> 00:07:26,490
+hand carbonic acidلما نبدأ أضيف عليها Sodium
+
+84
+00:07:26,490 --> 00:07:31,230
+Hydroxide، أيش بيحصل له؟ بيقل، انت باهي معايا، لما
+
+85
+00:07:31,230 --> 00:07:33,690
+نبدأ أضيف Sodium Hydroxide على Carbonic Acid، أيش
+
+86
+00:07:33,690 --> 00:07:40,730
+بيسويه؟ بيقل، وإيش بيبدأ يتكون؟ ال بيكربونيت، إذا
+
+87
+00:07:40,730 --> 00:07:45,310
+ال بيكربونيت عامال بتتكون أو بتزيد، وال Carbonic
+
+88
+00:07:45,310 --> 00:07:49,070
+Acid عامال بيقل، لكن مجرد وجود بيكربونيت مع
+
+89
+00:07:49,070 --> 00:07:55,260
+Carbonic Acid، هذا عبارة عن bufferكيف بنعمل
+
+90
+00:07:55,260 --> 00:07:59,540
+العملية الحسابية بقول انا في البداية الكربونيك أسد
+
+91
+00:07:59,540 --> 00:08:04,460
+مع الهيدروكسيد لو أخدنا X ميلي مول من الكربونيك
+
+92
+00:08:04,460 --> 00:08:08,120
+أسد اللي موجود عندى اضافنا عليه Y ميلي مول من
+
+93
+00:08:08,120 --> 00:08:12,440
+الهيدروكسيد حيث ال X أكبر من ال Y لسه ال Y شوية
+
+94
+00:08:12,440 --> 00:08:17,760
+شوية بدنا ضييف ال X أكبر من ال Y فعندى قبل التفاعل
+
+95
+00:08:17,760 --> 00:08:23,430
+عند ال B كربونية صفر بعد التفاعلعند الـ millimoles
+
+96
+00:08:23,430 --> 00:08:28,910
+من الكربونيكاسة المتبقية X minus Y عند الهيدروكسيد
+
+97
+00:08:28,910 --> 00:08:33,550
+خلص لأنه كمية قليلة هيدروكسيد عند ال بيكربونيات
+
+98
+00:08:33,550 --> 00:08:40,250
+اللي تكونت Y دائما مجموع ال
+
+99
+00:08:40,250 --> 00:08:46,220
+بيكربونيات والكربونيك أسد مجموعهم لازم يساوي
+
+100
+00:08:46,220 --> 00:08:51,540
+الكربونيك أسد الأصلي فانا عندي هان X ميلي مول هدي
+
+101
+00:08:51,540 --> 00:08:55,880
+X minus Y هدي Y طبعا X minus Y زائد Y لازم تساوي
+
+102
+00:08:55,880 --> 00:08:59,460
+الكربونيك أسد الأصلي لأن الكربونيك أسد ينقسم
+
+103
+00:08:59,460 --> 00:09:03,860
+لجزءين جزء بيبقى زي ما هو وجزء بتحول لإيه لل بي
+
+104
+00:09:03,860 --> 00:09:07,840
+كربونيت فمجموع الأتنين بدي ساوي الأصل الكمية
+
+105
+00:09:07,840 --> 00:09:13,840
+الأصلية اللي عنديفهيك بتتم عملية الحسابات بنحسب من
+
+106
+00:09:13,840 --> 00:09:16,220
+هنا هذه من ال limones لو قسمناها على ال total
+
+107
+00:09:16,220 --> 00:09:20,700
+volume اللي هو حجم ال hydroxide زائد حجم الكربونك
+
+108
+00:09:20,700 --> 00:09:23,860
+أسد بتعطيني التركيز برضه هذه على ال total volume
+
+109
+00:09:23,860 --> 00:09:27,480
+بتعطيني التركيز فصار عندي تركيز ال بيكربونيت تركيز
+
+110
+00:09:27,480 --> 00:09:32,280
+الكربونك أسد على طول بقدر أجيب ال pH ليه؟ لأن هذا
+
+111
+00:09:32,280 --> 00:09:37,680
+عبارة عن buffer solution يبقى هذا قبل نقطة النهاية
+
+112
+00:09:37,680 --> 00:09:42,640
+الأولىطب إيش بيحصل؟ لما قتمني أضيف هيدروكسيد لغاية
+
+113
+00:09:42,640 --> 00:09:51,000
+ما ال X تساوي ال Y، at first equivalence point، ال
+
+114
+00:09:51,000 --> 00:09:55,300
+X وهي ال Y عند ال X بتساوي ال Y، يعني هان بده يضال
+
+115
+00:09:55,300 --> 00:10:00,150
+صفر، خلص ال carbonic acidالهيدروكسايت خلص ال
+
+116
+00:10:00,150 --> 00:10:05,090
+بيكربونيت صارت X لأنه كل الكربونيك أسد اتحول ل ال
+
+117
+00:10:05,090 --> 00:10:12,250
+بيكربونيت طب الآن السؤال كيف بده احسب ال pH لمحلول
+
+118
+00:10:12,250 --> 00:10:18,030
+بيكربونيت مش
+
+119
+00:10:18,030 --> 00:10:25,210
+صحيحهذا البروتونيتد سولت البروتونيتد سولت مادام
+
+120
+00:10:25,210 --> 00:10:28,810
+البروتونيتد is an H بلس بتساوي الجزر التربيهي
+
+121
+00:10:28,810 --> 00:10:34,590
+بنطلع على الشحنة الشحنة واحدة is a K A1 KW زائد K
+
+122
+00:10:34,590 --> 00:10:44,530
+A1 K A2 HCO3 سالب على K A1 زائد HCO3 سالب هيك
+
+123
+00:10:44,530 --> 00:10:52,190
+بنحسب ال pH أو ال H بلس للبروتونيتد سولتإذا اقدرنا
+
+124
+00:10:52,190 --> 00:11:01,170
+نحسب هى هان بالظبط هان في عندى فقط بيكربونيت ولاحظ
+
+125
+00:11:01,170 --> 00:11:04,470
+معايا لو حبيت تطلع ال carbonic acid عامة ال beagle
+
+126
+00:11:04,470 --> 00:11:07,910
+بيجل بيجل لما اتحول ليه ل ال beagle لما خرس كل ال
+
+127
+00:11:07,910 --> 00:11:11,290
+carbonic acid هذه نقطة التكافئة الأولى كل اللى
+
+128
+00:11:11,290 --> 00:11:16,430
+عندى فقط بس بيكربونيت ماشي يا شباب طب لو حاولنا
+
+129
+00:11:16,430 --> 00:11:21,600
+انه نستمر في الإضافةبين نقطة التكافئة الأولى
+
+130
+00:11:21,600 --> 00:11:25,240
+والتانية صار عندى .. لحظة انتهى ال carbonic acid
+
+131
+00:11:25,240 --> 00:11:27,880
+مافيش عندى carbonic acid الان بدى امشي لقدام فى
+
+132
+00:11:27,880 --> 00:11:34,660
+عندى بيكربونيت هي و
+
+133
+00:11:34,660 --> 00:11:39,380
+لما نحط عليها ال hydroxide ايش بحصلها؟ بتجل اه
+
+134
+00:11:39,380 --> 00:11:43,680
+تتحول لإيه؟ للكربونيت الكربونيت عامال تتكون او
+
+135
+00:11:43,680 --> 00:11:47,600
+بتزيد يبقى صار فى عندى كربونيت و بيكربونيت وهذا
+
+136
+00:11:47,600 --> 00:11:53,560
+bufferلحظ ال PH تقريبا ثاتة هذا ايه بافر يبقى
+
+137
+00:11:53,560 --> 00:11:57,540
+مستمرار مع الإضافة X ملي مول احط عليها Y ملي مول
+
+138
+00:11:57,540 --> 00:12:04,040
+حيث X أكبر من Y فبقول X minus Y هيفضل او هيتبقى Y
+
+139
+00:12:04,040 --> 00:12:10,250
+هيتكون من الكربونينعلى ال total volume على ال
+
+140
+00:12:10,250 --> 00:12:14,350
+total volume بتاع التركيزات وعلى طول بقدر اجيب ال
+
+141
+00:12:14,350 --> 00:12:23,390
+PH من ال KA2 هنشوف هذا الكلام حسابيا بعد شوية طب
+
+142
+00:12:23,390 --> 00:12:28,490
+استمرت بإيباف الصوديوم الهيدروكسايد انا استمرت
+
+143
+00:12:28,490 --> 00:12:30,090
+بإيباف الصوديوم الهيدروكسايد انا خلصت كل ال
+
+144
+00:12:30,090 --> 00:12:35,670
+بيكربونيات اتحولت كلها لإيه للكربونيات إذا هذه
+
+145
+00:12:35,670 --> 00:12:46,410
+نقطة التكافؤالتانية X صارت تساوي ال Y صفر صفر صفر
+
+146
+00:12:46,410 --> 00:12:48,830
+صفر صفر صفر صفر صفر صفر صفر صفر صفر صفر صفر صفر
+
+147
+00:12:48,830 --> 00:12:49,150
+صفر صفر صفر صفر صفر صفر صفر صفر صفر صفر صفر صفر
+
+148
+00:12:49,150 --> 00:12:50,030
+صفر صفر صفر صفر صفر صفر صفر صفر صفر صفر صفر صفر
+
+149
+00:12:50,030 --> 00:12:52,550
+صفر صفر صفر صفر صفر صفر صفر صفر صفر صفر صفر صفر
+
+150
+00:12:52,550 --> 00:12:56,910
+صفر صفر صفر صفر صفر صفر صفر صفر صفر صفر صفر صفر
+
+151
+00:12:56,910 --> 00:13:02,660
+صفر صفر صفر صفر صفر صفر صفرعلى كربونات فقط بس
+
+152
+00:13:02,660 --> 00:13:06,080
+كربونات خلص ال بيكربونات مافيش طبعا عندي hydroxide
+
+153
+00:13:06,080 --> 00:13:09,280
+equivalence point يعني بس عندي كربونات كيف بقى
+
+154
+00:13:09,280 --> 00:13:16,700
+أجيب ال pH لمحلول كربونات هذا السؤال كيف؟
+
+155
+00:13:19,380 --> 00:13:24,100
+ماشي ماشي بنقول الكربونيت هدى unprotonated salt
+
+156
+00:13:24,100 --> 00:13:30,520
+كيف بوجد ال PH لها؟ اه هدا هي كربونيت زائد مية
+
+157
+00:13:30,520 --> 00:13:36,020
+بتعطينى HCO3 minus زائد hydroxide بجيب ال Kb Kw
+
+158
+00:13:36,020 --> 00:13:39,880
+على K A2 وانا عندي تركيز الكربونيت X على ال total
+
+159
+00:13:39,880 --> 00:13:45,140
+volume اذا X على ال total volume minus قيمة صغيرة
+
+160
+00:13:46,420 --> 00:13:50,340
+بتعطيني اقهان قيمة صغيرة نفس القيمة الهيدروكسيد و
+
+161
+00:13:50,340 --> 00:13:57,740
+من ال Kب بقدر اوجد الهيدروكسيد و بجيب منه ال POH و
+
+162
+00:13:57,740 --> 00:14:02,440
+من ال POH بحسب ال PH يبقى هذا ال second
+
+163
+00:14:02,440 --> 00:14:09,420
+equivalence point طب ايش بيحصل بعد هيك؟ هى صار
+
+164
+00:14:09,420 --> 00:14:13,460
+عندها كربونية طب لو حطيت عليها كمان هيدروكسيد ايش
+
+165
+00:14:13,460 --> 00:14:19,660
+بيحصل؟كربونيت زائد هيدروكسيد بتفعلوا مع بعض؟ طبعا
+
+166
+00:14:19,660 --> 00:14:23,540
+لأ two bases، لو أنه فيه H، أه الهيدروكسيد بتفعل
+
+167
+00:14:23,540 --> 00:14:26,480
+معاه، بس فيش عند أي H، هذا عليا شحنتين سالبتين، و
+
+168
+00:14:26,480 --> 00:14:29,680
+هذا عليا شحنة سالبة، وفيش عند أي protons، معناه
+
+169
+00:14:29,680 --> 00:14:35,410
+كلام بيظلهم بتفعلوش مع بعضطب كيف بده احسب ال pH؟
+
+170
+00:14:35,410 --> 00:14:40,130
+آخر الحصة هنشوف كيف بنحسب ال pH فده هو ال
+
+171
+00:14:40,130 --> 00:14:43,590
+titration curve اللي احنا رسمناه بس فرجناكم كيف
+
+172
+00:14:43,590 --> 00:14:48,470
+نرسمه خطوة خطوة الآن خلينا ناخد مثال حسابي تطبيقي
+
+173
+00:14:48,470 --> 00:14:54,030
+على الكلام هذا ونشوف كيف بنقدر نحسب ال pH بعد كل
+
+174
+00:14:54,030 --> 00:14:58,710
+إضافةفبقول في البداية نقرأ المثال بقول find the pH
+
+175
+00:14:58,710 --> 00:15:04,210
+of a 50 ml solution of a 0.1 molar carbonic acid
+
+176
+00:15:05,140 --> 00:15:12,680
+بعد اضافة من 0، 25، 50، 75، 100 و 150 اكسيد و اضيف
+
+177
+00:15:12,680 --> 00:15:15,300
+عليهم سوديوم هيدروكسيد شوية شوية فعلى طول باجي
+
+178
+00:15:15,300 --> 00:15:17,800
+بقول و الله بعد اضافة من 0 مل سوديوم هيدروكسيد
+
+179
+00:15:17,800 --> 00:15:21,480
+يعني قبل اضافة اي اي سوديوم هيدروكسيد انا عندي بس
+
+180
+00:15:21,480 --> 00:15:26,700
+كربونيك اسد هي ال K A1 له و ال K A2 ايضا باقسم K
+
+181
+00:15:26,700 --> 00:15:33,720
+A1 على K A2 بيعقيني اكتر من عشر أقصى اتنينأه إذا
+
+182
+00:15:33,720 --> 00:15:39,580
+التاني بيلتغي بيبقى لعندي one equilibrium H2CO3
+
+183
+00:15:39,580 --> 00:15:44,280
+بتعطينا H plus زاد HCO3 minus هاي ال equation بقول
+
+184
+00:15:44,280 --> 00:15:47,140
+و الله هي تركيزه point one صفر صفر point one minus
+
+185
+00:15:47,140 --> 00:15:51,900
+X X X من ال K a one X تربيع على point one minus X
+
+186
+00:15:51,900 --> 00:15:55,200
+و بفترض أن ال point one أكبر كتير من ال X زي ما
+
+187
+00:15:55,200 --> 00:15:59,880
+احنا متعودين إذا ال X بتطلع عندنا اتنين و واحد في
+
+188
+00:15:59,880 --> 00:16:05,060
+عشر أقل سالب أربعةالـ Relative Error والله 2
+
+189
+00:16:05,060 --> 00:16:11,360
+.1×10⁻⁴ على الـ 0.1 في 100 من 100 0.21% قليل كتير،
+
+190
+00:16:11,360 --> 00:16:15,260
+معناه كلام بالفعل الـ X أقل كتير من الـ 0.1 يبجى
+
+191
+00:16:15,260 --> 00:16:20,220
+الـ X هي الـ H بلس، الـ H بلس بتساوي 2.1×10⁻⁴
+
+192
+00:16:20,220 --> 00:16:27,040
+ومنها الـ pH 3.68 يبجى هذه أول نقطة هنا لما كان بس
+
+193
+00:16:27,040 --> 00:16:32,930
+Carbonic Acid لواحدهماشي يا جماعة طيب الآن خلّينا
+
+194
+00:16:32,930 --> 00:16:38,050
+نشتغل بعد إضافة جزء من أو كمية من ال sodium
+
+195
+00:16:38,050 --> 00:16:41,930
+hydroxide بقول مجرد إضافة ال sodium hydroxide بدي
+
+196
+00:16:41,930 --> 00:16:48,030
+إيش تكون عنده buffer من ال carbonic acid و ال HCO3
+
+197
+00:16:48,030 --> 00:16:52,600
+سالب اللي تكونعلى أي حال بنقول initial millimole
+
+198
+00:16:52,600 --> 00:16:57,160
+carbonic acid 0.1 في 50 الملي مول Sodium hydroxide
+
+199
+00:16:57,160 --> 00:17:02,900
+0.1 في 25 اذا الملي مول carbonic acid left 5 ناقص
+
+200
+00:17:02,900 --> 00:17:09,690
+2.5 2.5معنى الكلام تركيز الكربونيك أسد 2.5 على 50
+
+201
+00:17:09,690 --> 00:17:16,330
+و 25 و 75 مولار في نفس الوقت تكون عندى بيكربونيت
+
+202
+00:17:16,330 --> 00:17:22,030
+ميلي مول بيكربونيت 2.5 لازم ال بيكربونيت و
+
+203
+00:17:22,030 --> 00:17:27,650
+الكربونيك أسد يكونوا 5 لازم كل species تكون 5 ميلي
+
+204
+00:17:27,650 --> 00:17:34,200
+مولأذا تركيز الكربونات 2.5 على 75 باش بقول هذا
+
+205
+00:17:34,200 --> 00:17:40,120
+عبارة عن buffer بيكربونات carbonic acid هاي معادلة
+
+206
+00:17:40,120 --> 00:17:48,070
+تربط بينهم ال KA1 فبقول والله ال KA1 بدها تساويال
+
+207
+00:17:48,070 --> 00:17:52,950
+X في 2.5 على 75 ممكن ما تحطش ال X هذه لأن هذا
+
+208
+00:17:52,950 --> 00:17:57,890
+buffer على 2.5 على 75 minus X ممكن ما تحطش ال X
+
+209
+00:17:57,890 --> 00:18:00,730
+التانية لأنه buffer وقلنا في حالة ال buffer ال X
+
+210
+00:18:00,730 --> 00:18:05,950
+بتكون يعني قيمتها مهملة قليلة جدا وشوفنا ليش زمان
+
+211
+00:18:05,950 --> 00:18:10,550
+فال X لما نقول هذا بيروح لو ال X راحت و ال X راحت
+
+212
+00:18:10,550 --> 00:18:16,730
+2.5 على 75 مع 2.5 على 75 ال X بتسوي ايه؟يبقى عند
+
+213
+00:18:16,730 --> 00:18:21,050
+نص الحجم، هاي الحجم اللازم لل equivalence point
+
+214
+00:18:21,050 --> 00:18:25,090
+عند نص الحجم، عند 25 mil اللي هو نص الحجم اللازم
+
+215
+00:18:25,090 --> 00:18:29,770
+لل equivalence point، عندنا هنا ال pH بتساوي ال
+
+216
+00:18:29,770 --> 00:18:31,470
+PK1
+
+217
+00:18:32,790 --> 00:18:37,350
+يبقى عن نص الحجم اللازم ل ال first equivalence
+
+218
+00:18:37,350 --> 00:18:43,690
+point أن ال PH بتساوي ال PKA1 يبقى ال H plus بدها
+
+219
+00:18:43,690 --> 00:18:47,690
+تساوي طبعا ال relative error بتطلع قليل كتير لأن
+
+220
+00:18:47,690 --> 00:18:50,510
+احنا قولنا ال X أصلا بمكانك بتحطهاش من الأول مش
+
+221
+00:18:50,510 --> 00:18:56,650
+مشكلة فال H plus تطلع هي KA 4 3 10 أو 7 أو ال PH 6
+
+222
+00:18:56,650 --> 00:19:02,360
+و7 و 30نضيف كمية أكبر من الـ Sodium Hydroxide نضيف
+
+223
+00:19:02,360 --> 00:19:06,540
+خمسين مل Sodium Hydroxide بقول والله أنا عندي
+
+224
+00:19:06,540 --> 00:19:09,640
+الملي مول Carbonic Acid خمسة الملي مول Sodium
+
+225
+00:19:09,640 --> 00:19:12,600
+Hydroxide أدت برضه كمان خمسة إذا الملي مول
+
+226
+00:19:12,600 --> 00:19:17,520
+Carbonic Acid المتبقي left خمسة نقص خمسة صفر مدين
+
+227
+00:19:17,520 --> 00:19:20,960
+طلع صفر إذا هذا بيقول في عندنا equivalence point
+
+228
+00:19:20,960 --> 00:19:24,560
+في عندنا equivalence point هذا هي ال first
+
+229
+00:19:24,560 --> 00:19:28,480
+equivalence point كل ال Carbonic Acid اتحول لإيه؟
+
+230
+00:19:29,710 --> 00:19:33,110
+لل بيكربونيت اذا ال minimum لل بيكربونيت بتساوي
+
+231
+00:19:33,110 --> 00:19:37,610
+خمسة تركيز ال بيكربونيت خمسة على مية يعني خمسة من
+
+232
+00:19:37,610 --> 00:19:42,150
+مية والان السؤال كيف نحسب ال pH لل بيكربونيت جال
+
+233
+00:19:42,150 --> 00:19:45,310
+من القانون لأنها ادى protonated salt
+
+234
+00:19:48,230 --> 00:19:51,450
+بتطلع عنه قانون استخدم بطلع الشحنة اللي على ال
+
+235
+00:19:51,450 --> 00:19:54,910
+بيكربونيت شحنة واحدة اذا القانون اللي بستخدم K A
+
+236
+00:19:54,910 --> 00:19:59,570
+one في البداية فباجب اقول والله هاي القانون بعوض
+
+237
+00:19:59,570 --> 00:20:02,990
+عنه بتطلع ان ال H plus اربعة و نص في عشرة او سالب
+
+238
+00:20:02,990 --> 00:20:08,640
+تسعة وال P H تمانية واربعة و تلاتينهذه هي نقطة
+
+239
+00:20:08,640 --> 00:20:13,720
+التكافؤ الأولى، الآن في المحلول أضافت خمسين مل من
+
+240
+00:20:13,720 --> 00:20:16,860
+ال sodium hydroxide، بقبل في عندي أي carbonic
+
+241
+00:20:16,860 --> 00:20:21,600
+acid، كل اللي عندي ايه بيه carbonate، طيب، نيجي
+
+242
+00:20:21,600 --> 00:20:27,560
+نضيف كمية أكبر من ال sodium hydroxideبقول انا ال
+
+243
+00:20:27,560 --> 00:20:30,980
+initial millimole بيكربونيت خمسة كل الكربونيك أسد
+
+244
+00:20:30,980 --> 00:20:33,920
+اتحول لل بيكربونيت فال initial millimole بيكربونيت
+
+245
+00:20:33,920 --> 00:20:38,800
+خمسة انا اضافت خمسة و سبعين مل لكن لاحظوا انه اول
+
+246
+00:20:38,800 --> 00:20:42,960
+خمسين هدول اتفعلوا مع الكربونيك أسد علشان يحولوا
+
+247
+00:20:42,960 --> 00:20:47,860
+لل بيكربونيتفأول خمسين اتفاعلوا، اذا جديش انا
+
+248
+00:20:47,860 --> 00:20:52,080
+اضافت على ال بيكربونيت؟ بس خمسة و عشرين، اول خمسين
+
+249
+00:20:52,080 --> 00:20:55,020
+اتفاعلوا مع ال carbonic acid علشان يحولوا لل
+
+250
+00:20:55,020 --> 00:20:58,100
+بيكربونيت، اذا انا جديش اضافت على ال بيكربونيت؟
+
+251
+00:20:58,100 --> 00:21:01,740
+خمسة و عشرين، يعني اتنين و نص millimol الملي مول
+
+252
+00:21:01,740 --> 00:21:05,340
+بيكربونيت left خمسة ناقص اتنين و نص اتنين و نص،
+
+253
+00:21:05,340 --> 00:21:09,780
+تركيز ال بيكربونيت اتنين و نص على خمسة و سبعين و
+
+254
+00:21:09,780 --> 00:21:15,660
+خمسين125 مولار اتنين و نص على 125 مولار.الان لما
+
+255
+00:21:15,660 --> 00:21:19,620
+اضافت انا ال sodium hydroxide اتنين و نص ميلي مول
+
+256
+00:21:19,620 --> 00:21:24,940
+من ال sodium hydroxide على ال بي كربونايت طبعا
+
+257
+00:21:24,940 --> 00:21:30,620
+اتحولت لكربونايت كمية مناظرة فالميلي مول كربونايت
+
+258
+00:21:30,620 --> 00:21:37,370
+formed اتنين و نصتركيز الكربونيت الملي مول من
+
+259
+00:21:37,370 --> 00:21:39,730
+الكربونيت اللي هو اتنين و نص على total volume مية
+
+260
+00:21:39,730 --> 00:21:44,350
+خمسة و عشرين و لو اتطلعت معايا بتلاقي ان عندك
+
+261
+00:21:44,350 --> 00:21:49,550
+كربونيت و بيكربونيت هذا ايضا buffer solution هذا
+
+262
+00:21:49,550 --> 00:21:53,250
+ايضا buffer solution هي ال acid و هي its conjugate
+
+263
+00:21:53,250 --> 00:21:57,570
+base كيف بدي احسبه اي معادلة فيها ال بيكربونيت و
+
+264
+00:21:57,570 --> 00:22:03,360
+الكربونيت هي معادلة التفكك التاني فباجي بقولمن
+
+265
+00:22:03,360 --> 00:22:07,540
+بعمل الجدوة اللي إذا كان حبيت فبقول هاي ال B
+
+266
+00:22:07,540 --> 00:22:11,800
+carbonate 2.5 على 125 ال carbonate 2.5 على 125 هذا
+
+267
+00:22:11,800 --> 00:22:16,720
+minus X X زائد X لو حبينا إنه نلغي ال X ده و
+
+268
+00:22:16,720 --> 00:22:21,060
+مانحطهاش من الأصل مافيش أي مشكلة لأنه بالفعل هذا
+
+269
+00:22:21,060 --> 00:22:24,320
+buffer و لما نكون عنده buffer ال X مافيش إلها قيمة
+
+270
+00:22:24,320 --> 00:22:29,670
+قيمتها مهملةفبطبق ال K A2 بتساوي ال X 2.5 على 125
+
+271
+00:22:29,670 --> 00:22:35,770
+على 2.5 على 125 بيروحوا مع بعض هدول القيمتين بتصير
+
+272
+00:22:35,770 --> 00:22:44,530
+ال X إيش بتساوي؟ يبقى عند نص لو جولنا هنا ال end
+
+273
+00:22:44,530 --> 00:22:50,730
+point التانية يبقى عند نص الحجم اللازم للوصول له
+
+274
+00:22:50,730 --> 00:22:54,850
+من نقطة التكافؤ الأولى لنقطة التكافؤ التانية عند
+
+275
+00:22:54,850 --> 00:23:01,580
+ال P Hبتساوي ال PKAتنين او عند تلت ارباع الحجم
+
+276
+00:23:01,580 --> 00:23:06,060
+اللازم للوصول لنقطة التكافؤ التانية في عند ال pH
+
+277
+00:23:06,060 --> 00:23:10,260
+بتساوي ال PKA اتنين وهذا اشي ممتاز كتير لانه انا
+
+278
+00:23:10,260 --> 00:23:15,820
+لو عندي acid مجهول ال KAs بقدر من عملية المعايرة و
+
+279
+00:23:15,820 --> 00:23:21,300
+تتبع عملية المعايرة و معرفة موضع ال equivalence
+
+280
+00:23:21,300 --> 00:23:29,030
+point الاولى و التانية بقدر احسب جداش بالظبطالـKA1
+
+281
+00:23:29,030 --> 00:23:34,690
+والـKA2 بمعرفتي لموضع الـEquivalence Point الأولى
+
+282
+00:23:34,690 --> 00:23:39,910
+والتانية بقدر أحدد الحجوم اللى عندها بالظبط بتكون
+
+283
+00:23:39,910 --> 00:23:46,330
+الـPH بتساوي PKA1 والـPH بتساوي PKA2
+
+284
+00:23:46,330 --> 00:23:51,230
+مع هذا الكلام ال X بتطلع 4 او 8 او 10 او 11 والـPH
+
+285
+00:23:51,230 --> 00:23:57,230
+ان هذا هو عبارة عن الـH Plus والـPH 10 و32 و30
+
+286
+00:23:59,820 --> 00:24:07,280
+طيب إيش بيحصل بعد إضافة 100 مل من ال sodium
+
+287
+00:24:07,280 --> 00:24:12,260
+hydroxide؟ إيش بيحصل بعد إضافة 100 مل من ال sodium
+
+288
+00:24:12,260 --> 00:24:18,740
+hydroxide؟ لاحظ معايا إنه المية هذه أول خمسين منها
+
+289
+00:24:18,740 --> 00:24:25,630
+راحوا لمعاملة ال carbonic acid حوّلوا لإيه؟لل
+
+290
+00:24:25,630 --> 00:24:30,810
+بيكربونيت يعني وكأني انا مستقيف خمسين مل على ال
+
+291
+00:24:30,810 --> 00:24:36,290
+بيكربونيت كمان مرة بقول انا اضافت ميت مل هنا اول
+
+292
+00:24:36,290 --> 00:24:42,390
+خمسين حولوا هذا للبيكربونيت اذا وكأني انا اضافت
+
+293
+00:24:42,390 --> 00:24:47,860
+خمسين مل على ال بيكربونيتبنفس الطريقة بنقول الملي
+
+294
+00:24:47,860 --> 00:24:51,500
+مول بيكربونيت أصلا خمسة الملي مول صدر مهادركسايد
+
+295
+00:24:51,500 --> 00:24:55,180
+added point one في خمسين خمسة إذا الملي مول
+
+296
+00:24:55,180 --> 00:25:02,560
+بيكربونيت left خمسة ناقص خمسة صفر معناته this is
+
+297
+00:25:02,560 --> 00:25:06,980
+the second equivalence point هذه هي ال second
+
+298
+00:25:06,980 --> 00:25:13,320
+equivalence point نقطة التكافؤالتانية طيب معنى
+
+299
+00:25:13,320 --> 00:25:17,480
+الكلام كل ال بيكربونيات خلصت هاي ال lift عندنا صفر
+
+300
+00:25:17,480 --> 00:25:21,160
+مافيش عندي بيكربونيات معنى الكلام كلها اتحولت
+
+301
+00:25:21,160 --> 00:25:25,660
+لإيه؟ للكربونيات يبقى الميلي مول الكربونيات بتساوي
+
+302
+00:25:25,660 --> 00:25:28,980
+خمسة ال carbonic acid خمسة ميلي مول اتحول كله
+
+303
+00:25:28,980 --> 00:25:32,380
+لبيكربونيات خمسة ميلي مول اتحولت كلها للكربونيات
+
+304
+00:25:32,380 --> 00:25:37,080
+طبعا خمسة ميلي مول مابتتغير اذا تركيز الكربونيات
+
+305
+00:25:37,080 --> 00:25:42,650
+خمسة على مية وخمسينيبقى الأن في عندي محلول
+
+306
+00:25:42,650 --> 00:25:49,450
+carbonate تركيزها خمسة على مية وخمسين الآن كيف بدي
+
+307
+00:25:49,450 --> 00:25:55,870
+أحسب ال pH لمحلول carbonate unprotonated salt طبعا
+
+308
+00:25:55,870 --> 00:26:03,690
+بقول حساب ال pH له مباشر ممكن أقول واللهالكربونيت
+
+309
+00:26:03,690 --> 00:26:08,330
+في المي بتعطيني بيكربونيت زائد هيدروكسايد طبعا هذا
+
+310
+00:26:08,330 --> 00:26:13,290
+طالع عندي هيدروكسايد كب بيساوي kw على ka انهي ka
+
+311
+00:26:13,290 --> 00:26:17,510
+فماجي بتطلع بلاجة عندي هنا سالب اتنين يعني شحن
+
+312
+00:26:17,510 --> 00:26:22,640
+التأ اتنين معناته ka2فمكسيم ال KW اللي هو عشرة أقل
+
+313
+00:26:22,640 --> 00:26:26,460
+سالب أربعة تعاشر على KA2 أربعة و تمانية في عشرة
+
+314
+00:26:26,460 --> 00:26:31,280
+أقل سالب أحداشر بيطلع لنا اتنين و واحد في عشرة أقل
+
+315
+00:26:31,280 --> 00:26:35,860
+سالب أربعة هذي أحداشر مش تلاتاشر اتنين و واحد في
+
+316
+00:26:35,860 --> 00:26:41,520
+عشرة أقل سالب أربعةالان يا شباب عندى بس كربونية 5
+
+317
+00:26:41,520 --> 00:26:46,480
+على 150 0 0 5 على 150 minus x x x زى ما احنا
+
+318
+00:26:46,480 --> 00:26:53,560
+متعودين نوجد ال ph لل un protonated salt فبنعود فى
+
+319
+00:26:53,560 --> 00:26:57,760
+ال kb بتساوي ال x تربيع على 5 على 150 minus x و
+
+320
+00:26:57,760 --> 00:27:02,460
+بنعمل الفرضية تبعتنا 5 على 150 أكبر كتير من ال x
+
+321
+00:27:02,680 --> 00:27:07,760
+معناته ال X هتساوي 2 و 6 في 10 أقل سالب ثلاثة لو
+
+322
+00:27:07,760 --> 00:27:11,820
+أجينا حسبنا ال relative error هل هذا يعني هل معقول
+
+323
+00:27:11,820 --> 00:27:15,780
+أنه نلغي ال X جنب هذا الرقم ولا لا فبنحسب ال
+
+324
+00:27:15,780 --> 00:27:18,340
+relative error بطلع سبعة و تسعة من عشرة في المية
+
+325
+00:27:18,340 --> 00:27:23,240
+حوالى تمانية في المية هذا بيخالف ال margin أو
+
+326
+00:27:23,240 --> 00:27:27,180
+الهامش اللي احنا حاطينه إلينااحنا حاطين هامش
+
+327
+00:27:27,180 --> 00:27:32,160
+مقداره خمسة في المية فهذا سبعة وتسعة و عشر معناته
+
+328
+00:27:32,160 --> 00:27:36,000
+the assumption is invalid and therefore we should
+
+329
+00:27:36,000 --> 00:27:40,700
+use the quadratic equation لكن أنا جايلكم انه يعني
+
+330
+00:27:40,700 --> 00:27:44,320
+بس عشان الحسابات انا راح اقبله بس اما انت في
+
+331
+00:27:44,320 --> 00:27:48,580
+الامتحان لأ في الامتحان تقبلهش قوللي انه حل ال
+
+332
+00:27:48,580 --> 00:27:51,740
+quadratic equation لكن انا هنجبلانه بس علشان اطلع
+
+333
+00:27:51,740 --> 00:27:58,400
+النتيجةطيب خلّينا نضيف 150 مل من ال sodium
+
+334
+00:27:58,400 --> 00:28:06,780
+hydroxide نضيف 150 مل من ال sodium hydroxide بقول
+
+335
+00:28:06,780 --> 00:28:12,960
+150 مل هدول في الحقيقة لو اجت بدي افصلهم بقول هذه
+
+336
+00:28:12,960 --> 00:28:17,500
+الخمسين لتحويل ال carbonic acid ل ال b carbonate
+
+337
+00:28:17,500 --> 00:28:24,490
+وهذه الخمسين التانيةلتحويل ال بي كربونات للكربونات
+
+338
+00:28:24,490 --> 00:28:30,050
+ومعنى الكلام انا اضافت بس خمسين على الكربونات
+
+339
+00:28:30,050 --> 00:28:33,550
+اضافت بس خمسين على الكربونات يبقى عندى الان
+
+340
+00:28:33,550 --> 00:28:37,450
+المحلول محلول الكربونات ومحطوط عليه كمان خمسين مل
+
+341
+00:28:37,450 --> 00:28:40,490
+من الهيدروكسايد لكن الهيدروكسايد متفاعلش مع
+
+342
+00:28:40,490 --> 00:28:45,750
+الكربوناتلكن الهيدروكسيد ما بيتفاعل مع الكربونيت
+
+343
+00:28:45,750 --> 00:28:51,470
+فكيف بنحسب ال pH؟ بنقول في معظم الأحيان لو جينا
+
+344
+00:28:51,470 --> 00:28:58,310
+احنا طلعنا مثلا في ال slide الماضية لو جينا طلعنا
+
+345
+00:28:58,310 --> 00:29:00,550
+على ال equilibrium للكربونيت بنلاحظ أنه فيه
+
+346
+00:29:00,550 --> 00:29:05,910
+هيدروكسيد يعني الكربونيت بتعطيني هيدروكسيدولكن
+
+347
+00:29:05,910 --> 00:29:08,810
+عندما يكون هناك انديانا هيدروكسايد اكسيث من
+
+348
+00:29:08,810 --> 00:29:11,950
+السوديوم هيدروكسايد هذا ال equilibrium له
+
+349
+00:29:11,950 --> 00:29:16,910
+equilibrium constant 2 و 1 في 10 أقل سالب 4 يعتبر
+
+350
+00:29:16,910 --> 00:29:23,410
+قليل مش قريب على 10 أقل سالب 2 أو 10 أقل سالب 1
+
+351
+00:29:24,630 --> 00:29:28,650
+ماشي يعتبر ايه قليل عشرة او سالب اربعة قليل نسبيا
+
+352
+00:29:28,650 --> 00:29:32,410
+فيعني ايش يعني قليل يعني كمية ال hydroxide اللي
+
+353
+00:29:32,410 --> 00:29:36,270
+جاية من الكربونيت قليلة ليه لأنه ال equilibrium
+
+354
+00:29:36,270 --> 00:29:42,160
+constant ايش ماله قليلطب إيش بيحصل لما يكون في
+
+355
+00:29:42,160 --> 00:29:46,180
+عندي هيدروكسيد أيضا جاي من ال sodium hydroxide
+
+356
+00:29:46,180 --> 00:29:51,120
+excess في عندي خمسين مل من ال sodium hydroxide اه
+
+357
+00:29:51,120 --> 00:29:56,580
+هو أصلا قليل و بده يرجع لورا كمان لتشاتليه حسب
+
+358
+00:29:56,580 --> 00:30:01,660
+لتشاتليه هو في الأصل قليل و بده يرجع لورا أيضا
+
+359
+00:30:01,660 --> 00:30:08,440
+فمعنى الكلاماه بده يجلب شكل كبير خالص عشان هيك انا
+
+360
+00:30:08,440 --> 00:30:17,740
+بقول يعني كشيع عامفي معظم الأحيان رح يكون مبرر عنا
+
+361
+00:30:17,740 --> 00:30:21,120
+انه نقول والله ال milli mole Sodium hydroxide
+
+362
+00:30:21,120 --> 00:30:24,100
+excess point one في خمسين خمسة milli mole اذا
+
+363
+00:30:24,100 --> 00:30:27,500
+تركيز Sodium hydroxide ال excess خمسة على متين
+
+364
+00:30:27,500 --> 00:30:31,340
+وبما انه مافيش مصدر hydroxide الا هذا ال hydroxide
+
+365
+00:30:31,340 --> 00:30:35,120
+وال hydroxide اللي جاى من الكربونيات وبما ان ال
+
+366
+00:30:35,120 --> 00:30:37,440
+hydroxide اللي جاى من الكربونيات قليل جدا اذا هذا
+
+367
+00:30:37,440 --> 00:30:40,400
+هو ال hydroxide اللي في المقلول ممكن نحكي زي هيك
+
+368
+00:30:40,710 --> 00:30:43,950
+لكن في الحقيقة و بنحسب ال POH و منها بنجيب ال pH
+
+369
+00:30:43,950 --> 00:30:49,950
+لكن يا شباب في الحقيقة يعني مش دائما هذا كلام صحيح
+
+370
+00:30:49,950 --> 00:30:55,200
+مش دائما و هذا كلام بتوقف عليهحاجتين بتوقف على ال
+
+371
+00:30:55,200 --> 00:31:00,320
+K حاجة جدّاش ال equilibrium constant ال K بيه كويس
+
+372
+00:31:00,320 --> 00:31:06,620
+و بتوقف على كمان تركيز السلط فلما يكون تركيز السلط
+
+373
+00:31:06,620 --> 00:31:13,760
+كمان قليل كتير معناته والله يعني مشكلة و لما يكون
+
+374
+00:31:13,760 --> 00:31:17,840
+عالي معناته اه في احتمال انه يعطيني hydroxide اكتر
+
+375
+00:31:18,980 --> 00:31:23,520
+فهذا بتوقف عليه تركيز ال salt حاجة وأيضا ال Kb
+
+376
+00:31:23,520 --> 00:31:27,820
+حاجة تانية فانا بقول انه نفترض ان ال hydroxide هو
+
+377
+00:31:27,820 --> 00:31:30,600
+عبارة عن فقط ال hydroxide اللي جاي من ال sodium
+
+378
+00:31:30,600 --> 00:31:34,880
+hydroxide وإن كان منطقي يعني في هذه الحالة تحديدا
+
+379
+00:31:34,880 --> 00:31:39,300
+لأنه ال Kb قليل وإن كان منطقي إلا أنه الأفضل أن
+
+380
+00:31:39,300 --> 00:31:43,530
+نحسبهالافضل انه نحسب ال hydroxide اللى جاي من
+
+381
+00:31:43,530 --> 00:31:48,030
+الكربونيت و نجمع الاتنين او انه نقول والله اه اللى
+
+382
+00:31:48,030 --> 00:31:52,770
+جاي من الكربونيت قليل جدا وبالتالي ال hydroxide
+
+383
+00:31:52,770 --> 00:31:57,350
+اللى عندى خمسة على متين كيف بنعمل هذا الكلام طبعا
+
+384
+00:31:57,350 --> 00:32:03,010
+زى ما احنا متعودين بنقول هي عندى الكربونيت في
+
+385
+00:32:03,010 --> 00:32:06,820
+الميه بتعطينى بيه كربونيت و hydroxideالـ carbonate
+
+386
+00:32:06,820 --> 00:32:10,860
+خمسة ملي مول الان تركيزها بطل خمسة على مية و خمسين
+
+387
+00:32:10,860 --> 00:32:14,160
+لأنه عنده مية و خمسين مل هيدروكسايد و خمسين مل
+
+388
+00:32:14,160 --> 00:32:18,520
+acid carbonic acid هيصار متين مل اذا تركيز ال
+
+389
+00:32:18,520 --> 00:32:21,720
+carbonate خمسة على متين ال b carbonate صفر
+
+390
+00:32:21,720 --> 00:32:26,580
+الهيدروكسايد اللى هو الزيادة خمسة على متينهذا
+
+391
+00:32:26,580 --> 00:32:31,120
+الهيدروكسايد اللى موجود مش من تفكك الكربونيات لأ
+
+392
+00:32:31,120 --> 00:32:35,700
+من الزيادة من ال sodium hydroxide اذا خمس عالمتين
+
+393
+00:32:35,700 --> 00:32:43,000
+minus X X خمس عالمتين زائد X الان لو استخدمنا ال
+
+394
+00:32:43,000 --> 00:32:46,820
+equilibrium constant تطلع ان ال X اتنين واحد فعشر
+
+395
+00:32:46,820 --> 00:32:51,510
+أقل سالم أربعة لأنه عندى ال Xفي 5 على 200 زائد x
+
+396
+00:32:51,510 --> 00:32:55,290
+على 5 على 200 نقص x تفترض أن 5 على 200 أكبر من ال
+
+397
+00:32:55,290 --> 00:32:58,990
+x فبتروح ال x و بتروح ال x و ال 5 على 200 بتروح مع
+
+398
+00:32:58,990 --> 00:33:03,810
+ال 5 على 200 بتتم ال x بتساوي ال KD يعني 2 و 1 في
+
+399
+00:33:03,810 --> 00:33:09,050
+10 أقل سالب 4 ال relative error بطلع قليل كتير
+
+400
+00:33:09,050 --> 00:33:16,010
+قليل كتير في الحقيقة يعني point eight four point
+
+401
+00:33:16,010 --> 00:33:21,260
+eight four percentأقل من 1% بالفعل إذا كنتوا
+
+402
+00:33:21,260 --> 00:33:26,060
+ماخدين بالكم بالفعل إيش هي ال X؟ ال X هي عبارة عن
+
+403
+00:33:26,060 --> 00:33:30,300
+ال hydroxide اللي جاي من الكربونيت هيها ال X هي
+
+404
+00:33:30,300 --> 00:33:33,020
+عبارة عن ال hydroxide اللي جاي من الكربونيت طب ال
+
+405
+00:33:33,020 --> 00:33:35,180
+hydroxide اللي جاي من الكربونيت إيه؟ الغاءوا جنب
+
+406
+00:33:35,180 --> 00:33:39,620
+الخمس علامتين؟لأنه جداش قيمته اتنين و واحد فعشر
+
+407
+00:33:39,620 --> 00:33:43,620
+عشر سالب اربعة بالمقارنة مع الخمسة على متين صغير
+
+408
+00:33:43,620 --> 00:33:49,820
+جدا معناته بالفعل كمية ال hydroxide اللي في
+
+409
+00:33:49,820 --> 00:33:55,900
+المحلول عند إضافة زيادة من ال hydroxideهى عبارة عن
+
+410
+00:33:55,900 --> 00:34:00,180
+الكمية القادمة من الزيادة من ال hydroxide وليس من
+
+411
+00:34:00,180 --> 00:34:05,220
+تفكك الكربونيد قولنا انه هذا كلام صحيح في هذه
+
+412
+00:34:05,220 --> 00:34:09,580
+الحالة لكن مش شرط يكون صحيح في كل الحالات ليه؟
+
+413
+00:34:09,580 --> 00:34:14,340
+لأنه بتوقف على قيمة ال Kb بتوقف على تركيز ال salt
+
+414
+00:34:14,340 --> 00:34:22,600
+أيضا طيب يا شباب عكس هذا الكلام تماما عكس هذا
+
+415
+00:34:22,600 --> 00:34:28,340
+الكلام تمامافيما لو كان عندى حاجة زى مثلا ال
+
+416
+00:34:28,340 --> 00:34:40,240
+carbonate وبدى اعيرها بال HCl بلاحظ انه
+
+417
+00:34:40,240 --> 00:34:44,960
+بحصل
+
+418
+00:34:44,960 --> 00:34:51,840
+على الشكل التالى بقول هى
+
+419
+00:34:54,680 --> 00:35:00,900
+الـ Mil من الـ HCl وهي الـ pH كربونيت هلاحظ انها
+
+420
+00:35:00,900 --> 00:35:05,520
+بيز بيزي بجاية ال pH تبعية هي شمالها عالية كتير
+
+421
+00:35:05,520 --> 00:35:11,260
+عند Zero من الـ HCl هيكون في واندي هان بس كربونيت
+
+422
+00:35:13,410 --> 00:35:19,930
+هذه الكربونات تبدأ تقل وال بي كربونات تبدأ تزيد
+
+423
+00:35:19,930 --> 00:35:24,910
+ليه؟ لأن أنا مضيف عليه H بلس طيب بنتمنا نضيف لغاية
+
+424
+00:35:24,910 --> 00:35:31,690
+ما كل الكربونات اتخلص يبقى كلها صارت بي كربونات
+
+425
+00:35:31,690 --> 00:35:37,350
+طبعا الكلام حطينا عليها كمان H بلس اه بتبدأ ال بي
+
+426
+00:35:37,350 --> 00:35:44,030
+كربونات تقل وال carbonic acid ببدأ يزيدطب حطينا
+
+427
+00:35:44,030 --> 00:35:49,990
+كمان H بلس جال اه كل ال B كربوني اتخلصت و اتحولت
+
+428
+00:35:49,990 --> 00:35:56,250
+لإيه؟ لل carbonic acid بعدين جال والله ال carbonic
+
+429
+00:35:56,250 --> 00:35:59,890
+acid حطينا عليه كمان H بلس هل بتفعلوا مع بعض ولا
+
+430
+00:35:59,890 --> 00:36:06,790
+لأ؟ two acids بتفعلوش يفجأ بهمني اعرففي الحالة
+
+431
+00:36:06,790 --> 00:36:10,550
+العكسية لكربونيك أسد اللي هي في هذه الحالة
+
+432
+00:36:10,550 --> 00:36:14,930
+carbonate يعني هذا بولي basic base في البداية ال
+
+433
+00:36:14,930 --> 00:36:17,970
+carbonate بتهمني أعرف كيف أحسب ال pH للcarbonate
+
+434
+00:36:17,970 --> 00:36:23,750
+لوحدها قبل إضافة أي HCl بعدين بتكون عندي buffer
+
+435
+00:36:23,750 --> 00:36:27,750
+نفس الطريقة نفس طريقة الحسابات تماما لو أنا عندي
+
+436
+00:36:27,750 --> 00:36:30,370
+buffer بتكون عندي first equivalence point
+
+437
+00:36:30,370 --> 00:36:35,670
+بcarbonate case بحلهاعن طريق القانون بمشي لقدام
+
+438
+00:36:35,670 --> 00:36:40,730
+بفر تاني سهل كتير بمشي لقدام free carbonic acid
+
+439
+00:36:40,730 --> 00:36:44,230
+النقطة الأولى اللى حسبناها فى المثال الماضى free
+
+440
+00:36:44,230 --> 00:36:49,070
+carbonic acid بعدين carbonic acid مع ال H بلس وهان
+
+441
+00:36:49,070 --> 00:36:54,030
+برضه لازم اخد بعين الاعتبار انه لما نكون في عندى
+
+442
+00:36:54,030 --> 00:36:59,450
+زيادة من ال H بلسو في عندي كمان carbonic acid طب
+
+443
+00:36:59,450 --> 00:37:02,750
+ما ال carbonic acid برضه بعطيني H بلس لكن ال KA
+
+444
+00:37:02,750 --> 00:37:07,090
+اللي وجداش عشر أقل سالب سبعةأربعة أو تلاتة في عشرة
+
+445
+00:37:07,090 --> 00:37:09,790
+أو ثلاثة بيانة الـ H Plus اللي جاي منه هيكون قليل
+
+446
+00:37:09,790 --> 00:37:17,010
+كتير فما بالكم في وجود H Plus جاية من الـ Excess
+
+447
+00:37:17,010 --> 00:37:21,010
+HCL هيرجع يبقى حاطين الكمية أي شمالها مهمة للغاية
+
+448
+00:37:21,010 --> 00:37:24,950
+عشانك الـ H Plus غالبا هتكون هي الـ H Plus الناشعة
+
+449
+00:37:24,950 --> 00:37:30,780
+عن الزيادة في الـ HCLطيب يا شباب إذا الله راض
+
+450
+00:37:30,780 --> 00:37:36,900
+الحصة الجاية هناخد مثال بيعالج ال poly basic bases
+
+451
+00:37:36,900 --> 00:37:41,140
+و بديش أخد الكربونيت لإنه هيكون كلام مكرر هاخد
+
+452
+00:37:41,140 --> 00:37:48,860
+الفوسفيت إيش بيحصل لما ينعير الفوسفيت بال HCl فإذا
+
+453
+00:37:48,860 --> 00:37:50,580
+الله راض بنشوفكم الحصة الجاية
+
diff --git a/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/P2ufM_zJW7c.srt b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/P2ufM_zJW7c.srt
new file mode 100644
index 0000000000000000000000000000000000000000..3721f71e49f965b40f66e25e253fc66ff6c2a6d0
--- /dev/null
+++ b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/P2ufM_zJW7c.srt
@@ -0,0 +1,1583 @@
+1
+00:00:21,110 --> 00:00:25,230
+بسم الله الرحمن الرحيم اليوم إن شاء الله سنتكلم
+
+2
+00:00:25,230 --> 00:00:29,930
+عن المحاضرة الأولى في الـ chapter الأخير الذي معنا
+
+3
+00:00:29,930 --> 00:00:33,330
+الذي يتكلم عن الـ oxidation reduction equilibria و
+
+4
+00:00:33,330 --> 00:00:36,870
+titrations. في البداية سنتكلم عن الـ oxidation
+
+5
+00:00:36,870 --> 00:00:43,820
+reduction equilibria، ونقول إن التفاعلات أنواع،
+
+6
+00:00:43,820 --> 00:00:49,440
+منها تفاعلات الـ acids مع الـ bases، تفاعلات الـ ligands
+
+7
+00:00:49,440 --> 00:00:55,040
+مع الـ metal ions، تفاعلات الـ precipitation، ونوع آخر هو
+
+8
+00:00:55,040 --> 00:00:58,640
+تفاعلات الأكسدة والاختزال. تفاعلات الأكسدة
+
+9
+00:00:58,640 --> 00:01:06,900
+والاختزال تتضمن عمليتين متلازمتين: عملية أكسدة يتم
+
+10
+00:01:06,900 --> 00:01:14,200
+خلالها فقد إلكترونات، وعملية اختزال يتم خلالها
+
+11
+00:01:14,200 --> 00:01:19,640
+اكتساب هذه الإلكترونات التي فقدت من جانب الـ half
+
+12
+00:01:19,640 --> 00:01:24,230
+reaction الأول. فعلى سبيل المثال، لو طلعنا على
+
+13
+00:01:24,230 --> 00:01:30,070
+التفاعل الذي أمامي: Ce⁴⁺ مع Fe²⁺
+
+14
+00:01:30,070 --> 00:01:35,890
+يعطينا Ce³⁺ مع Fe³⁺. لو طلعنا على
+
+15
+00:01:35,890 --> 00:01:41,830
+Ce⁴⁺ تحول إلى Ce³⁺، يعني معنى الكلام اكتسب
+
+16
+00:01:41,830 --> 00:01:47,270
+إلكترونًا. اكتسب إلكترونًا يعني حصلت له عملية اختزال، بينما
+
+17
+00:01:47,270 --> 00:01:53,520
+Fe²⁺ تحول إلى Fe³⁺، معنى الكلام أن Fe²⁺
+
+18
+00:01:53,520 --> 00:02:00,060
+فقد إلكترونًا، يبقى معنى الكلام حصل له أكسدة، أو ممكن
+
+19
+00:02:00,060 --> 00:02:03,060
+نتطلع على الموضوع بشكل آخر: الـ oxidation number
+
+20
+00:02:03,060 --> 00:02:07,740
+للسيريوم 4⁺، 4⁺ تحول إلى سيريوم 3⁺،
+
+21
+00:02:07,740 --> 00:02:14,300
+إذا الـ oxidation number للسيريوم قل، وهذا عملية
+
+22
+00:02:14,300 --> 00:02:18,840
+reduction، بينما الـ iron تحول من 2⁺ إلى 3⁺،
+
+23
+00:02:18,840 --> 00:02:22,620
+يبقى الـ oxidation number تحول من 2⁺ إلى 3⁺، إذا
+
+24
+00:02:22,620 --> 00:02:27,400
+الـ oxidation number زاد، وبالتالي هذه عملية أكسدة.
+
+25
+00:02:27,400 --> 00:02:32,540
+فعملية الأكسدة وعملية الاختزال عمليتان متلازمتان
+
+26
+00:02:32,540 --> 00:02:38,130
+يحصلان مع بعض، بحيث أن الإلكترونات التي يمنحها نصف
+
+27
+00:02:38,130 --> 00:02:44,770
+التفاعل الأول يستهلكها نصف التفاعل الآخر. المحصلة
+
+28
+00:02:44,770 --> 00:02:49,450
+في المعادلة النهائية لا يوجد فيها ظهور لأي إلكترون.
+
+29
+00:02:51,740 --> 00:02:54,780
+ممكن المعادلة الماضية نجسمها لنصفين كما نحن
+
+30
+00:02:54,780 --> 00:02:58,060
+شايفين، السيريوم 4⁺ يأخذ إلكترونًا، هذه عملية
+
+31
+00:02:58,060 --> 00:03:02,100
+reduction.  الحديد 2⁺ يعطيني إلكترونًا، هذه عملية
+
+32
+00:03:02,100 --> 00:03:06,120
+oxidation. الآن، كيف نتعرف على تفاعلات الأكسدة
+
+33
+00:03:06,120 --> 00:03:13,540
+والاختزال؟ نقول: تفاعل الأكسدة والاختزال يتم خلاله
+
+34
+00:03:13,540 --> 00:03:19,930
+تغير في الـ oxidation number لبعض الذرات. بعض الذرات
+
+35
+00:03:19,930 --> 00:03:25,150
+في المتفاعلات ليست هي نفسها في النواتج. نلاحظ، لو شفنا
+
+36
+00:03:25,150 --> 00:03:28,730
+الـ oxidation number للأولى نلاحظ أنه يتغير عن الـ
+
+37
+00:03:28,730 --> 00:03:33,450
+oxidation number في الثانية أو في النواتج. فمثلاً، لو
+
+38
+00:03:33,450 --> 00:03:40,170
+طلعنا على الـ KMnO₄: K⁺ واحد موجب، O²⁻ اثنان سالب في أربعة، يعني ثمانية سالبة، منهم واحد موجب، إذا
+
+39
+00:03:40,170 --> 00:03:44,570
+المنجنيز 7⁺.  الـ Oxalic Acid: H⁺ واحد موجب،
+
+40
+00:03:44,570 --> 00:03:53,450
+O²⁻ اثنان سالب في أربعة، سالب ثمانية، موجب اثنين، إذا الكربون 6⁺.
+
+41
+00:03:53,450 --> 00:04:00,330
+الـ Oxygen اثنان سالب في أربعة، سالب ثمانية، موجب
+
+42
+00:04:00,330 --> 00:04:06,090
+اثنين، إذا الكربون 6⁺، يبقى الواحدة 3⁺.
+
+43
+00:04:06,090 --> 00:04:11,790
+موجب، الاثنان كربون 6⁺، يبقى الواحدة 3⁺.
+
+44
+00:04:11,790 --> 00:04:18,910
+الـ HCl: H⁺ واحد موجب، Cl⁻ واحد سالب، في
+
+45
+00:04:18,910 --> 00:04:22,910
+اثنين، اثنين سالب، إذا المنجنيز 2⁺، الـ K⁺
+
+46
+00:04:22,910 --> 00:04:25,930
+واحد موجب، الـ Cl⁻ واحد سالب.
+
+47
+00:04:29,050 --> 00:04:32,850
+أو ممكن نقول: نبدأ بالـ O₂: اثنان سالب في اثنين، يبقى
+
+48
+00:04:32,850 --> 00:04:38,350
+أربعة سالب، يبقى الكربون 4⁺، الـ H⁺ واحد موجب،
+
+49
+00:04:38,350 --> 00:04:43,210
+الاكسجين 2⁻. لو جئنا واطلعنا على المنجنيز،
+
+50
+00:04:43,210 --> 00:04:49,690
+بنلاحظ أن الـ oxidation number تبعه تغير من موجب
+
+51
+00:04:49,690 --> 00:04:58,200
+سبعة إلى موجب اثنين، إذا اختزل. أما الكربون،
+
+52
+00:04:58,200 --> 00:05:05,100
+فبنلاحظ أنه تغير من موجب ثلاثة إلى موجب أربعة، زاد،
+
+53
+00:05:05,100 --> 00:05:10,280
+عملية أكسدة. عملية أكسدة، فأكيد هذا التفاعل الذي
+
+54
+00:05:10,280 --> 00:05:15,800
+أمامي هو تفاعل أكسدة واختزال، لأنه تم خلال التفاعل
+
+55
+00:05:15,800 --> 00:05:19,760
+تغير في الـ oxidation numbers.
+
+56
+00:05:21,890 --> 00:05:26,690
+شيء يزيد وشيء يقل، لازم شيء يزيد وشيء يقل،
+
+57
+00:05:26,690 --> 00:05:32,010
+لأنه لازم عملية الأكسدة تحصل بالتلازم مع عملية
+
+58
+00:05:32,010 --> 00:05:35,560
+الاختزال، الذي تطلعنا عليه. مثال آخر، مثلاً Sodium
+
+59
+00:05:35,560 --> 00:05:40,480
+Carbonate مع 2HCl يعطينا Sodium Chloride، CO₂، H₂O.
+
+60
+00:05:40,480 --> 00:05:44,580
+الـ Sodium موجب واحد، الكربون موجب أربعة، الـ Oxygen
+
+61
+00:05:44,580 --> 00:05:49,200
+سالب اثنين، الـ H موجب واحد، الـ Cl سالب واحد، الآخرى.
+
+62
+00:05:49,200 --> 00:05:53,500
+لو جئنا وتطلعنا، هل حصل أي تغير في الـ oxidation
+
+63
+00:05:53,500 --> 00:05:58,490
+number لأي عنصر من العناصر، لأي ذرة من الذرات؟
+
+64
+00:05:58,490 --> 00:06:02,830
+نلاحظ أن نفس الـ oxidation numbers الموجودة على
+
+65
+00:06:02,830 --> 00:06:06,590
+اليسار هي نفسها، نفس الـ oxidation numbers لنفس
+
+66
+00:06:06,590 --> 00:06:09,470
+الذرات الموجودة على اليمين، ومع ذلك لم يحصل أي
+
+67
+00:06:09,470 --> 00:06:13,230
+تغير في الـ oxidation number، وبالتالي هذا معادلة، أو
+
+68
+00:06:13,230 --> 00:06:17,370
+هذا تفاعل ليس تفاعل أكسدة أو اختزال، بالطبع هو تفاعل
+
+69
+00:06:17,370 --> 00:06:24,270
+acid base reaction. الآن، فقط نريد مراجعة كيف نوزن
+
+70
+00:06:24,270 --> 00:06:28,110
+المعادلات الـ... الـ Redox reaction، المعادلة الـ
+
+71
+00:06:28,110 --> 00:06:31,890
+Redox، المعادلة الأكسدة والاختزال، كيف نوزنها؟  لا
+
+72
+00:06:31,890 --> 00:06:35,170
+معناها هذا كلام سنة أولى، لكن يعني كلام سريع كثير.
+
+73
+00:06:35,170 --> 00:06:43,990
+نقو: أساس وزن المعادلة هو عبارة عن ثلاث خطوات، يعني
+
+74
+00:06:43,990 --> 00:06:47,930
+بسيطة جداً ومفهومة بالنسبة لنا. أول خطوة: نفصل
+
+75
+00:06:47,930 --> 00:06:52,210
+المعادلة إلى نصفين، وهذه  مهمة سهلة جداً، نفصل المعادلة
+
+76
+00:06:52,210 --> 00:06:56,830
+إلى نصفين. ثاني خطوة: كل نصف نأخذه على حدّة، نعمله mass
+
+77
+00:06:56,830 --> 00:07:02,670
+balance. وثالث خطوة: الـ charge balance، نخلي عدد
+
+78
+00:07:02,670 --> 00:07:06,410
+الذرات على اليمين يساوي عدد الذرات على اليسار، و
+
+79
+00:07:06,410 --> 00:07:10,950
+بعدين الشحنات تكون أيضاً على اليمين تساوي الشحنات
+
+80
+00:07:10,950 --> 00:07:14,770
+على اليسار، وهكذا نكون وزنّا المعادلة. بالذات، لما
+
+81
+00:07:14,770 --> 00:07:19,330
+نجي في الآخر خالص نجمع النصفين، التفاعل نلاحظ أن
+
+82
+00:07:19,330 --> 00:07:22,660
+المعادلة التي عندنا معادلة موزونة. نشوف مثلاً
+
+83
+00:07:22,660 --> 00:07:26,640
+المعادلة التالية:  الـ Dichromate مع الـ Iron يعطينا كروم
+
+84
+00:07:26,640 --> 00:07:30,380
+و Iron ثلاثي. بدك نوزن المعادلة، بدك تسميها
+
+85
+00:07:30,380 --> 00:07:34,740
+نصفين في البداية، فأقول: الـ Iron  2⁺ يتحول إلى Iron
+
+86
+00:07:34,740 --> 00:07:38,340
+3⁺، و Dichromate يتحول إلى Chromium 3⁺. فناخد
+
+87
+00:07:38,340 --> 00:07:42,060
+النص الأول: Iron 2⁺ يتحول إلى Iron 3⁺. ماذا؟
+
+88
+00:07:42,060 --> 00:07:45,520
+بقول: أنا عملت الخطوة الأولى، فصلتهما إلى نصفين، الخطوة
+
+89
+00:07:45,520 --> 00:07:49,690
+الثانية mass balance، لازم بالترتيب. الخطوة الثالثة
+
+90
+00:07:49,690 --> 00:07:52,410
+charge balance. فخليني في الـ mass balance للنصف
+
+91
+00:07:52,410 --> 00:07:57,810
+الأول: كم ذرة حديد هنا؟ كم ذرة حديد هنا؟ إذا  mass
+
+92
+00:07:57,810 --> 00:08:01,870
+balance. نجي للخطوة الأخيرة، التي هي الـ charge
+
+93
+00:08:01,870 --> 00:08:06,410
+balance: كم الشحنة هنا؟ اثنان موجب، الشحنة هنا
+
+94
+00:08:06,410 --> 00:08:10,720
+ثلاثة موجب، كم هذا؟ خليهم متساويين، أضع إلكترونًا
+
+95
+00:08:10,720 --> 00:08:14,440
+على اليمين، إذا Iron 2⁺ يعطيني Iron
+
+96
+00:08:14,440 --> 00:08:16,660
+3⁺ زائد إلكترون. طبعاً هذه صارت mass
+
+97
+00:08:16,660 --> 00:08:20,700
+balanced و charge balanced. يبقى خلاص من النصف
+
+98
+00:08:20,700 --> 00:08:25,560
+الأول، آجي للنصف الثاني، الـ Dichromate يعطيني
+
+99
+00:08:25,560 --> 00:08:30,380
+Chromium. كم كروم هنا؟ كم كروم هنا؟ إذا
+
+100
+00:08:30,380 --> 00:08:33,910
+أضرب هنا باثنين، أخليها اثنين كروم. ماشي يا
+
+101
+00:08:33,910 --> 00:08:37,430
+شباب، صارت ذرات الكروم 2، 2. آجي للأكسجين،
+
+102
+00:08:37,430 --> 00:08:41,730
+هنا عندي سبعة أكسجين، هنا كم أكسجين؟  أضع سبعة
+
+103
+00:08:41,730 --> 00:08:45,790
+ماء، سبعة ماء. طيب ماشي، صار عندي سبعة أكسجين، لكن صار
+
+104
+00:08:45,790 --> 00:08:50,450
+عندي هنا 14 H، فأخذه أين؟ على اليسار، على
+
+105
+00:08:50,450 --> 00:08:54,510
+هيئة H⁺، يبقى الـ H الذي وضعته على هيئة H₂O
+
+106
+00:08:55,340 --> 00:08:59,720
+أخذه على اليسار على هيئة ماذا؟ H⁺، 14 H⁺.
+
+107
+00:08:59,720 --> 00:09:04,340
+الآن، لو جئت وتطلع، أجد أن 14 H،
+
+108
+00:09:04,340 --> 00:09:07,760
+14 H، 2 كروم، 2 كروم، 7 أكسجين،
+
+109
+00:09:07,760 --> 00:09:11,740
+7 أكسجين، موزونة، فهذه الـ mass balanced، موزونة من
+
+110
+00:09:11,740 --> 00:09:16,660
+ناحية الـ mass، فنجي نتطلع على charge balance، فنقول
+
+111
+00:09:16,660 --> 00:09:21,600
+والله نعد هذه: 14 موجب، اثنان سالب،
+
+112
+00:09:21,600 --> 00:09:26,610
+يبقى 12 موجب. طيب، هنا في عندي 6 موجب، إذا
+
+113
+00:09:26,610 --> 00:09:30,650
+كيف أجعل الستة تساويها؟ أزيد 6 موجب؟ أضع
+
+114
+00:09:30,650 --> 00:09:34,210
+ستة إلكترونات على هذه الناحية. وضعنا ستة إلكترونات
+
+115
+00:09:34,210 --> 00:09:37,430
+على هذه الناحية، يبقى صار عندي mass balanced
+
+116
+00:09:37,430 --> 00:09:42,190
+equation وأيضاً charge balanced equation. هذا النص
+
+117
+00:09:42,190 --> 00:09:47,250
+أجمعه مع نص الـ Iron الذي رأيته قبل قليل، لكن الـ Iron
+
+118
+00:09:47,250 --> 00:09:49,930
+كان فيه فقط إلكترون واحد، وأنا أعرف أن المعادلة
+
+119
+00:09:49,930 --> 00:09:53,410
+النهائية لا بد ألا يكون فيها أي إلكترون، فيجب ضرب
+
+120
+00:09:53,410 --> 00:09:56,690
+المعادلة الأولى بـ 6، لكي تذهب الإلكترونات، هذه
+
+121
+00:09:56,690 --> 00:10:01,230
+ممنوع ظهور أي إلكترون في المعادلة النهائية، فتكون
+
+122
+00:10:01,230 --> 00:10:05,730
+هذه المعادلة المحصلة، أو هذا هو وزن المعادلة الذي
+
+123
+00:10:05,730 --> 00:10:09,390
+عندي. لو جئت وتطلع على المعادلة هذه المكتوبة
+
+124
+00:10:09,390 --> 00:10:14,590
+باللون الأحمر، أقول: هذه المعادلة تحصل في الـ acid
+
+125
+00:10:14,590 --> 00:10:18,590
+medium. في ماذا؟ في الـ acid medium. مرات أقول: لماذا
+
+126
+00:10:18,590 --> 00:10:22,610
+أوزن المعادلة في الـ basic medium، في الوسط القاعدي؟
+
+127
+00:10:22,610 --> 00:10:26,490
+أقول: كيف أفعل هذا؟ كلام بعد ما أخلص أو قبل ما أخلص،
+
+128
+00:10:26,490 --> 00:10:30,070
+خليني أقول: بعد ما أخلص هنا، وآخذ مثال بعد قليل، قبل
+
+129
+00:10:30,070 --> 00:10:33,270
+ما أخلص، ماذا أفعل؟ أقول: في هنا 14 H⁺،
+
+130
+00:10:33,270 --> 00:10:35,630
+لا يعقل أن يكون هنا 14 H⁺ في الـ basic
+
+131
+00:10:35,630 --> 00:10:41,590
+medium، هذا acid، فـ أضع بدلاً منهم، فقط أضع الـ OH⁻
+
+132
+00:10:41,590 --> 00:10:46,920
+على الناحيتين. لماذا؟ لكي أحافظ على الـ mass balance
+
+133
+00:10:46,920 --> 00:10:49,980
+تبعي والـ charge balance تبعي أيضاً. أضع الـ
+
+134
+00:10:49,980 --> 00:10:54,100
+hydroxide على ماذا؟ على الـ 14 H⁺، أصبح 14
+
+135
+00:10:54,100 --> 00:10:59,580
+hydroxide، هذان يعطيانِ: 14 ماء. طيب، هي في
+
+136
+00:10:59,580 --> 00:11:03,940
+عندي سبعة ماء هنا، هي راحت، وهنا أزيد سبعة، إذا
+
+137
+00:11:03,940 --> 00:11:07,660
+تكون المعادلة موزونة. هذان راحوا خلاص، يعطوني
+
+138
+00:11:07,660 --> 00:11:11,740
+الـ 14 ماء، منهم سبعة، إذا 6 Iron زائد
+
+139
+00:11:11,740 --> 00:11:15,980
+7 ماء زائد Dichromate يعطينا 6 Iron، 2
+
+140
+00:11:15,980 --> 00:11:19,380
+Chromium، زائد 14 Hydroxide. هذا وزن المعادلة
+
+141
+00:11:19,380 --> 00:11:21,460
+في الـ basic solution.
+
+142
+00:11:24,140 --> 00:11:29,460
+طيب يا شباب، أقول: نأخذ مثال آخر، لكن لا ننسى
+
+143
+00:11:29,460 --> 00:11:33,620
+التذكير: Oxalate زائد Permanganate يعطينا
+
+144
+00:11:33,620 --> 00:11:38,980
+Manganese ⁴⁺ زائد CO₂. أول خطوة: نفصلهما إلى نصفين، فصلناها
+
+145
+00:11:38,980 --> 00:11:43,620
+إلى نصفين: Oxalate يعطي CO₂، Permanganate يعطي Manganese
+
+146
+00:11:43,620 --> 00:11:48,590
+طبعاً، ليس معقول Oxalate يعطي Manganese، ليس هكذا! طبيعي
+
+147
+00:11:48,590 --> 00:11:51,950
+يعني، في النصف الجديد تبع المنجنيز، الـ Oxalate
+
+148
+00:11:51,950 --> 00:11:57,090
+تبع الـ CO₂. نريد أن نقول: مادام فصلناها، نأخذ أول نصف،
+
+149
+00:11:57,090 --> 00:12:02,130
+هي الـ Oxalate، هذا اثنان، ما كان هذا اثنان، هذا هذا
+
+150
+00:12:02,130 --> 00:12:05,250
+اثنان كربون، أضع قدره بعيد في اثنين. الـ Oxygen
+
+151
+00:12:05,250 --> 00:12:08,070
+أربعة، والله يوم أربعة، يبقى هذا موزونة من ناحية
+
+152
+00:12:08,070 --> 00:12:12,950
+mass، mass balanced، نجي للشحنات: هذا شحنتان سالبتان،
+
+153
+00:12:12,950 --> 00:12:16,130
+إذا أضع هنا اثنين إلكترون على اليمين.
+
+154
+00:12:18,890 --> 00:12:23,950
+طيب، نجي لنصف التفاعل الآخر، الذي هو الـ
+
+155
+00:12:23,950 --> 00:12:27,710
+Permanganate. أقول: المنجنيز كم ذرة؟ واحدة، وهنا
+
+156
+00:12:27,710 --> 00:12:31,630
+واحدة، إذا موزونة. الأكسجين أربعة، فش ولا واحدة، إذا
+
+157
+00:12:31,630 --> 00:12:35,850
+أربعة ماء، أربعة ماء، يبقى صار في عندي ثمانية H⁺،
+
+158
+00:12:35,850 --> 00:12:40,810
+ثمانية H⁺ على اليسار، ثمانية H⁺ على اليسار،
+
+159
+00:12:40,810 --> 00:12:43,630
+يبقى ثمانية H⁺ زائد Permanganate يعطيني
+
+160
+00:12:43,630 --> 00:12:46,610
+Manganese ⁴⁺ زائد 4 H₂O. نتطلع عليها، نجدها
+
+161
+00:12:46,610 --> 00:12:52,860
+mass balanced، موزونة بالنسبة للـ mass.  أريد
+
+162
+00:12:52,860 --> 00:12:58,600
+أن أوزن الشحنات: هنا ثمانية موجب وواحد سالب، صار سبعة
+
+163
+00:12:58,600 --> 00:13:04,780
+موجب. هنا أربعة موجب، إذا أضع ثلاث إلكترونات على
+
+164
+00:13:04,780 --> 00:13:10,320
+الجهة اليسار. مضبوط يا شباب! طيب، ثلاث إلكترونات على
+
+165
+00:13:10,320 --> 00:13:15,180
+الجهة اليسار. لو أردت أن أشتغل in basic medium، ممكن أني
+
+166
+00:13:15,180 --> 00:13:18,080
+أجمع المعادلتين، وفي الآخر أفعل أعمالي التي فعلتها
+
+167
+00:13:18,080 --> 00:13:23,340
+سابقاً، لكن فيها أنه عند هذه الخطوة أضع ثمانية OH⁻
+
+168
+00:1
+
+223
+00:17:46,640 --> 00:17:50,540
+وحطينا voltmeter ووصلناها للطرفين، بال voltmeter بنلاحظ
+
+224
+00:17:50,540 --> 00:17:54,680
+ال voltmeter بيقيس بيعطينا فرق جهد، وليكن مثلاً
+
+225
+00:17:54,680 --> 00:17:59,870
+0.521 volt. هذا الـ 0.521
+
+226
+00:17:59,870 --> 00:18:03,930
+volt عبارة عن ايه؟ عبارة عن فرق الجهد بين القطبين
+
+227
+00:18:03,930 --> 00:18:10,570
+فرق الجهد بين القطبين يعني فرق الجهد ما بين الـ
+
+228
+00:18:10,570 --> 00:18:13,950
+electrode هذا و الـ electrode هذا، فرق الجهد بينهم
+
+229
+00:18:13,950 --> 00:18:19,450
+عادة فرق الجهد يعني بقدر أقيسه بسهولة بواسطة الـ
+
+230
+00:18:19,450 --> 00:18:25,880
+voltmeter، بقدر أقيسه بسهولة بواسطة الـ voltmeter لكن
+
+231
+00:18:25,880 --> 00:18:30,040
+لو سألنا أنفسنا سؤال: طب ايش فرق جهد الـ electrode هذا
+
+232
+00:18:30,040 --> 00:18:38,000
+لوحده؟ وايه جهد الـ electrode هذا لوحده؟ فالفرق بينهم
+
+233
+00:18:38,000 --> 00:18:44,600
+معروف، لكن يمكن يكون هذا واحد 0.521
+
+234
+00:18:44,600 --> 00:18:49,780
+والتاني مثلاً واحد، الفرق بينهم 0.521 أو
+
+235
+00:18:49,780 --> 00:18:53,100
+يمكن يكون واحد 0.521، والتاني صفر معايا.
+
+236
+00:18:53,100 --> 00:18:57,960
+يعني الفرق بينهم اه سهل قياسه لكن جهد الـ
+
+237
+00:18:57,960 --> 00:19:01,540
+electrode هذا لوحده وجهد الـ electrode هذا لوحده، هل
+
+238
+00:19:01,540 --> 00:19:06,680
+بقدر أعيّنه؟ بنقول بدنا طريقة نقدر نعين جهد الـ
+
+239
+00:19:06,680 --> 00:19:13,280
+electrode، علشان هيك لابد من استخدام حاجة بنقولها
+
+240
+00:19:13,280 --> 00:19:19,430
+standard hydrogen electrode، قطب الهيدروجين القياسي
+
+241
+00:19:19,430 --> 00:19:24,370
+أو برضه بنقوله normal hydrogen electrode، SHE يعني
+
+242
+00:19:24,370 --> 00:19:28,130
+standard hydrogen electrode أو NHE يعني normal
+
+243
+00:19:28,130 --> 00:19:32,810
+hydrogen electrode، لازم نستخدمه، ليش لازم نستخدمه؟
+
+244
+00:19:32,810 --> 00:19:37,010
+لأن هذا الـ electrode اللي أنا بتكلم عنه
+
+245
+00:19:37,010 --> 00:19:39,970
+هذا الـ electrode، أعطيناه
+
+246
+00:19:42,690 --> 00:19:46,890
+بإختيار من عندنا، هذا الـ potential هو عبارة عن
+
+247
+00:19:46,890 --> 00:19:50,990
+صفر at standard state، صفر at standard state، وعند
+
+248
+00:19:50,990 --> 00:19:57,310
+الحالة القياسية بنعطيه potential مقداره صفر، يعني
+
+249
+00:19:57,310 --> 00:20:03,930
+مثلاً لو كان هذا هو الـ SHE، وهان أعطاني 0.3
+
+250
+00:20:03,930 --> 00:20:08,410
+42، اللي هو فرق الجهود بينهم، مادام هذا SHE
+
+251
+00:20:08,410 --> 00:20:14,430
+هذا الـ E note تبعته صفر، لأنه احنا اصلا بنعرفه، و
+
+252
+00:20:14,430 --> 00:20:23,430
+بنقول أنه جهد الـ electrode صفر للـ SHE، إذاً واضح أن
+
+253
+00:20:23,430 --> 00:20:26,570
+اللي بحصل عليه أنا هان هو عبارة عن جهد الـ other
+
+254
+00:20:26,570 --> 00:20:32,090
+electrode، لأن الفرق هذا هو عبارة عن هذا بصفر، إذاً
+
+255
+00:20:32,090 --> 00:20:37,310
+هذا الفرق هو عبارة عن جهد الـ electrode الآخر، مش هيك؟
+
+256
+00:20:37,310 --> 00:20:43,130
+طيب، إذا كان هذا الكلام بهذه السهولة، إذاً والله ممكن
+
+257
+00:20:43,130 --> 00:20:47,570
+أنا أجي أحط الـ SHE
+
+258
+00:20:50,440 --> 00:20:55,540
+أستخدمه كقطب، وأستخدم أيّ electrode أنا بدي أعرف الـ
+
+259
+00:20:55,540 --> 00:20:59,680
+potential تبعه، أيش ما كان يكون، فأحطه أتمله في
+
+260
+00:20:59,680 --> 00:21:02,500
+الخلية، لأن الخلية قطبين، فواحد منهم الـ SHE
+
+261
+00:21:02,500 --> 00:21:05,640
+والتاني هو الـ other electrode، فرق الجهد؟ راح
+
+262
+00:21:05,640 --> 00:21:08,340
+يقول لي والله هذا هو عبارة عن جهد الـ other
+
+263
+00:21:08,340 --> 00:21:12,710
+electrode، يبقى هذه شغلة سهلة كثير في البداية، لكن
+
+264
+00:21:12,710 --> 00:21:17,950
+قبل ما أروح لهذا الكلام، بدي أقول ايش هو الـ S.H.E؟
+
+265
+00:21:17,950 --> 00:21:21,930
+ايش هو الـ S.H.E؟ ايش هو الـ standard hydrogen
+
+266
+00:21:21,930 --> 00:21:27,850
+electrode؟ جال هو والله الشكل اللي قدامي هذا، فيه
+
+267
+00:21:27,850 --> 00:21:32,250
+عندي inverted tube، هذا glass tube فيها فتحة، بعدين
+
+268
+00:21:32,250 --> 00:21:37,110
+منها الـ hydrogen، الـ hydrogen بيدخل منها، عند واحد
+
+269
+00:21:37,110 --> 00:21:41,130
+أتموسفير، هذه الـ standard state تبعتي، واحد أتموسفير
+
+270
+00:21:41,130 --> 00:21:45,110
+يعني الـ pressure للهيدروجين اللي داخل جواها واحد
+
+271
+00:21:45,110 --> 00:21:52,330
+أتموسفير، طيب عندي هذا الكلام موجود في محلول HCl
+
+272
+00:21:52,330 --> 00:21:58,760
+جواها، الـ H plus له واحد مولار، الحرارة مظبوطة عند 25
+
+273
+00:21:58,760 --> 00:22:04,800
+درجة أو 298 كيلفن، إذا هذه هي الشروط القياسية اللي
+
+274
+00:22:04,800 --> 00:22:08,300
+أنا بستخدمها في الـ standard hydrogen electrode عندها
+
+275
+00:22:08,300 --> 00:22:17,720
+عندي واحد أتموسفير للـ H2، الـ H plus واحد مولار، الحرارة 298
+
+276
+00:22:17,720 --> 00:22:25,620
+كيلفن، وفي عند القطب هو عبارة عن platinum wire من
+
+277
+00:22:25,620 --> 00:22:29,620
+البلاتين، فيه في آخره platinum electrode، platinized
+
+278
+00:22:29,620 --> 00:22:32,560
+platinum electrode، platinized platinum electrode
+
+279
+00:22:32,560 --> 00:22:35,500
+هذا عبارة عن قطب البلاتين، الـ surface area تبعته
+
+280
+00:22:35,500 --> 00:22:39,560
+عالية، الـ surface area تبعته عالية، لإيه؟ لأن التفاعل
+
+281
+00:22:39,560 --> 00:22:44,860
+اللي قدامي هذا أو عكسه، بدي يحصل بسرعة، وأكتشف أحصل
+
+282
+00:22:44,860 --> 00:22:49,960
+بسرعة، إذا كان الـ surface area عندي كبيرة، فـ
+
+283
+00:22:49,960 --> 00:22:53,840
+platinumized platinum electrode، هذا الجزء اللي هو
+
+284
+00:22:53,840 --> 00:23:00,840
+مربع تقريباً، هذا عبارة عن platinum electrode، يعني هو
+
+285
+00:23:00,840 --> 00:23:07,120
+عبارة عن plate أو foil من الـ platinum، لكن فيه عليه
+
+286
+00:23:07,120 --> 00:23:10,700
+particles من الـ platinum، بحيث أن الـ surface area
+
+287
+00:23:10,700 --> 00:23:15,040
+تبعته ايش بتكون؟ كبيرة، يعني هاي الـ surface، وفي عندي
+
+288
+00:23:15,040 --> 00:23:18,540
+بدل الـ surface، معروف قد ايش المساحة، يعني، لكن لو حطيت
+
+289
+00:23:19,590 --> 00:23:23,330
+زي الكرة، اللي هي حبة بلاتين، شوفوا كده الـ surface
+
+290
+00:23:23,330 --> 00:23:28,440
+area زادت، طب وكمان حبّتها، الـ surface area اه صارت زي
+
+291
+00:23:28,440 --> 00:23:32,360
+هيك معايا، إلى آخره، هيك، فالـ surface area زادت كثير.
+
+292
+00:23:32,360 --> 00:23:35,540
+ليش الـ surface area بدي إياها تكون كبيرة؟ جال عشان هذا
+
+293
+00:23:35,540 --> 00:23:38,940
+التفاعل اللي يحصل بسرعة، لأن هذا التفاعل عادة بطيء
+
+294
+00:23:38,940 --> 00:23:42,500
+وبده catalyst، يعني بطيء، بده catalyst، فأنا بدي الـ
+
+295
+00:23:42,500 --> 00:23:46,780
+surface area تكون كبيرة، فعندي platinum wire، في
+
+296
+00:23:46,780 --> 00:23:50,200
+آخره platinumized platinum electrode، بعدين منها
+
+297
+00:23:50,200 --> 00:23:54,360
+الـ hydrogen، واحد atmosphere pressure تبعه، على محلول
+
+298
+00:23:54,360 --> 00:24:00,020
+HCl، الـ H plus فيه واحد molar، وعند حرارة 25 درجة، لو
+
+299
+00:24:00,020 --> 00:24:06,580
+استخدمت هذا الشكل، قد ايش بيكون الـ E note له صفر، ليش
+
+300
+00:24:06,580 --> 00:24:10,920
+قلت note؟ note يعني standard، standard، ايش يعني
+
+301
+00:24:10,920 --> 00:24:14,180
+standard؟ يعني تحت standard state، الـ standard state
+
+302
+00:24:14,180 --> 00:24:20,250
+هي اللي ذكرتها، حرارة 25 درجة مئوية أو Celsius، اه
+
+303
+00:24:20,250 --> 00:24:25,210
+واحد atmosphere، واحد molar، أي شيء لو في عندي أكثر
+
+304
+00:24:25,210 --> 00:24:28,930
+... لأيّ... لأيّ electrode، أكثر من نوع من المحاليل
+
+305
+00:24:28,930 --> 00:24:32,230
+دائماً كل المحاليل واحد molar، بدها تكون كلها
+
+306
+00:24:32,230 --> 00:24:36,390
+الحرارة دائماً 25، إذا كان في عندي غاز، دائماً واحد
+
+307
+00:24:36,390 --> 00:24:43,460
+atmosphere، طيب يا شباب، لو اجينا نطلع على تعيين
+
+308
+00:24:43,460 --> 00:24:48,540
+شيء عملي، نطلع عليه، تعيين الـ potential لتفاعل اللي
+
+309
+00:24:48,540 --> 00:24:52,160
+قدامك، Cu2+ زائد 2 electron بيعطيني Cu
+
+310
+00:24:52,160 --> 00:24:56,940
+solid، بدي أعين الـ potential تبعه، بقول والله بحطه
+
+311
+00:24:56,940 --> 00:25:04,340
+في مكان، وبحط الـ SHE في المكان الآخر في الخلية
+
+312
+00:25:04,340 --> 00:25:07,920
+وبعدين بوصل الاثنين، وبشوف فرق الجهد معايا ولا لأ.
+
+313
+00:25:08,790 --> 00:25:13,590
+طيب نيجي نتطلع في البداية، هاي الـ Cu هذا solid
+
+314
+00:25:13,590 --> 00:25:17,930
+وهو جزء من ايه؟ من الـ reaction هذا، هو الـ
+
+315
+00:25:17,930 --> 00:25:22,470
+electrode، Cu solid، مغمور في محلول Cu2+
+
+316
+00:25:22,470 --> 00:25:25,830
+وليكون مثلاً كبريتات نحاس، مدوب في المي، لكن قد ايش
+
+317
+00:25:25,830 --> 00:25:30,650
+تركيز الـ Cu2+؟ لازم يكون واحد molar، لازم
+
+318
+00:25:30,650 --> 00:25:35,730
+يكون واحد molar، كويس؟ والحرارة 25 درجة، salt
+
+319
+00:25:35,730 --> 00:25:42,480
+bridge من الـ KCl مثلاً، Salt Bridge موجود فيها KCl
+
+320
+00:25:42,480 --> 00:25:49,900
+هاي الـ SHE، هاي الـ SHE، ايش التفاعل اللي بيحصل هان في
+
+321
+00:25:49,900 --> 00:25:56,140
+البداية؟ بدي أقول لكم، هالشغلة، الـ E note للخلية بتساوي
+
+322
+00:25:56,140 --> 00:26:05,140
+E note للكاثود ناقص الـ E note للانود، أو الـ E note
+
+323
+00:26:05,140 --> 00:26:09,720
+لخلية بتساوي E note right
+
+324
+00:26:15,170 --> 00:26:17,410
+الخلية، فرق الجهود، ايش اللي بيقيسه؟ الـ cathode
+
+325
+00:26:17,410 --> 00:26:22,520
+ناقص الانود، كويس؟ لكن في عندي convention، إستلاح
+
+326
+00:26:22,520 --> 00:26:27,460
+أنه دائماً الكاثود على اليمين، ودائماً الانود على اليسار
+
+327
+00:26:27,460 --> 00:26:31,900
+عشان هيك بقول القطب الايمن، الجهد طبعاً ناقص جهد
+
+328
+00:26:31,900 --> 00:26:35,560
+القطب الايسر، هي فرق الجهود، يبقى القطب الايمن دائماً
+
+329
+00:26:35,560 --> 00:26:40,820
+ايه؟ كاثود، القطب الايسر دائماً ايه؟ انود، طيب بنجي
+
+330
+00:26:40,820 --> 00:26:45,160
+بنقول هاي الـ SHE، ايش اللي بيحصل فيه؟ اللي بيحصل
+
+331
+00:26:45,160 --> 00:26:50,750
+أنه الـ H2 بتتحول لـ 2H+ زائد 2 إلكترون، يعني هنا
+
+332
+00:26:50,750 --> 00:26:56,370
+هي الـ H، عدة هنا بالظبط، الـ H2  بيفقد إلكترونين
+
+333
+00:26:56,370 --> 00:27:05,970
+وتحول لـ H+ أو 2H+ زائد 2 إلكترون
+
+334
+00:27:05,970 --> 00:27:11,230
+الإلكترونات بتعدي في المحلول، الإلكترونات بتنتقل
+
+335
+00:27:11,230 --> 00:27:15,810
+في السلك، لـ 2 إلكترون، الاثنين إلكترون بتتوجه
+
+336
+00:27:15,810 --> 00:27:20,970
+ناحية القطب الموجب، وبهيك صار في عندي فرق جهود، عامة
+
+337
+00:27:20,970 --> 00:27:25,390
+اللي هيحرّك الـ ايه؟ المؤشر تبع الـ voltmeter، الاثنين
+
+338
+00:27:25,390 --> 00:27:28,390
+إلكترون بتنزل هي في الـ Cu، الـ Cu solid ما
+
+339
+00:27:28,390 --> 00:27:35,370
+هو مش هيك، في عندي Cu2+ على السطح، هي
+
+340
+00:27:35,370 --> 00:27:40,130
+بياخد الـ two electrons، واش بتحول لـ Cu solid
+
+341
+00:27:40,130 --> 00:27:45,550
+معايا، الـ Cu2+ اللي في المحلول أخد الاثنين
+
+342
+00:27:45,550 --> 00:27:51,650
+إلكترون هدول، وين اترسب على سطح الـ electrode، هاي
+
+343
+00:27:51,650 --> 00:27:56,510
+التفاعل اللي بيتم، لكن يا شباب طول ما الـ H+
+
+344
+00:27:56,510 --> 00:28:01,710
+بيتكون هنا، يبقى هذا المحلول عمال بيصير فيه H+
+
+345
+00:28:01,710 --> 00:28:07,830
+زيادة، عمال الـ H+ بيزيد، مش هيك ولا لأ؟ ما بينفعش
+
+346
+00:28:07,830 --> 00:28:12,960
+الـ H+ يزداد هيك، يصير المحلول موجب، فهنا بيتطر الـ
+
+347
+00:28:12,960 --> 00:28:18,040
+Cl- ييجي من الـ salt bridge، وهي فائدتها بحيث
+
+348
+00:28:18,040 --> 00:28:23,700
+أنه يعادل، يعادل الـ H+ اللي طلعت، عشان دائماً
+
+349
+00:28:23,700 --> 00:28:29,740
+الشحنات الموجبة بتساوي الشحنات السالبة، بقى نهاية ونفس
+
+350
+00:28:29,740 --> 00:28:34,500
+الكلام هنا، هنا عامل الـ Cu2+ بترسب،
+
+351
+00:28:34,500 --> 00:28:39,340
+ايش بيسيب؟ أيونات كبريتات، سالبة، عشان هيك الـ
+
+352
+00:28:39,340 --> 00:28:45,200
+potassium بينزل في هذا الاتجاه، علشان برضه يعادل
+
+353
+00:28:45,200 --> 00:28:52,440
+الشحنات السالبة اللي تكونت، ماشي، المهم أنه الآن هي
+
+354
+00:28:52,440 --> 00:28:56,500
+اللي بيحصل حقيقة في الـ cell، الآن الـ voltmeter ايش
+
+355
+00:28:56,500 --> 00:29:00,860
+بيعطيني؟ فرق جهد الـ cathode ناقص الـ anode، يعطاني
+
+356
+00:29:00,860 --> 00:29:04,720
+0.342، بما أن الـ cathode صفر، الـ anode
+
+357
+00:29:04,720 --> 00:29:11,560
+صفر، وهدا 0.342 بتساوي الـ E naught
+
+358
+00:29:12,150 --> 00:29:17,170
+للكاثود ماينص صفر، صفر طبعاً راحت، يبقى الـ E note
+
+359
+00:29:17,170 --> 00:29:21,290
+للكاثود اللي هو هذا يعني، هذا التفاعل، ايش الـ E note
+
+360
+00:29:21,290 --> 00:29:27,770
+تبعته؟ بدها تساوي 0.342 volts، هي القراءة
+
+361
+00:29:27,770 --> 00:29:31,630
+اللي أعطاه لي الـ voltmeter، هي القراءة اللي أعطاه
+
+362
+00:29:31,630 --> 00:29:34,250
+لي الـ voltmeter، ماشي يا شباب.
+
+363
+00:29:37,570 --> 00:29:44,830
+لاحظ أنه...لاحظ أنه الـ convention تبعي هيو، الـ
+
+364
+00:29:44,830 --> 00:29:48,910
+cathode موجب، والانود سالب، والخلية galvanic...
+
+365
+00:29:48,910 --> 00:29:55,930
+والخلية galvanic، لو
+
+366
+00:29:55,930 --> 00:30:05,400
+اجينا...لو اجينا ل...مثلاً تفاعل الـ zinc، زنك half
+
+367
+00:30:05,400 --> 00:30:09,220
+reaction، فبقول زنك زائد 2 إلكترون بيعطينا زنك
+
+368
+00:30:09,220 --> 00:30:16,720
+solid، الـ E نوت ناقص 0.762، نشوف الخلية كيف جبناها
+
+369
+00:30:16,720 --> 00:30:25,760
+هذا الكلام، لو اجينا حطينا ال...لو استخدمنا
+
+370
+00:30:25,760 --> 00:30:31,240
+voltmeter بمؤشر، وقولنا هذه هي الصفر، وهذه هي الموجب
+
+371
+00:30:31,240 --> 00:30:38,240
+وهذه هي السالب، بنلاحظ أنه...بنلاحظ أن تفاعل الزنك
+
+372
+00:30:38,240 --> 00:30:41,580
+حاطني ناقص 0.76، احنا خلينا ناخد
+
+373
+00:30:41,580 --> 00:30:47,260
+التفاعل اللي قدامي هنا، هاي الـ SHE وين حطيناها؟ وين
+
+374
+00:30:47,260 --> 00:30:52,380
+حطيناها؟ على اليمين، إذا هو ايش؟ الكاثود، فأنا حطيتها
+
+375
+00:30:52,380 --> 00:30:56,000
+على اليسار، إذا هو الانود، اجينا طلعنا، وجينا هذه
+
+376
+00:30:56,000 --> 00:31:00,620
+0.76 موجب، 0.76 موجب، ايش يعني
+
+377
+00:31:00,620 --> 00:31:05,060
+0.76؟ هي 0.76 موجب بتساوي E note
+
+378
+00:31:05,060 --> 00:31:10,600
+للـ cathode اللي هي بتساوي صفر ناقص E note للانود
+
+379
+00:31:11,600 --> 00:31:15,660
+اللي هو ايش؟ الزنك، لأنه الـ cathode هنا هو الـ SHE
+
+380
+00:31:15,660 --> 00:31:22,060
+هو الـ cathode اللي بيساوي الصفر، فمعنى...نعم...مش
+
+381
+00:31:22,060 --> 00:31:25,540
+احنا فرضنا صفر دائماً، لأنه standard...يعني
+
+382
+00:31:25,540 --> 00:31:29,140
+standard hydrogen electrode، إعتبرنا إنه احنا إختيارياً
+
+383
+00:31:29,140 --> 00:31:35,120
+اتفقنا، كل العالم اتفق على إنه الـ electrode
+
+384
+00:31:35,120 --> 00:31:40,040
+potential للـ SHE potential، كويس؟ صفر at standard
+
+385
+00:31:40,040 --> 00:31:50,660
+state، يبقى الـ E note للانود ناقص 0.76، سالبة
+
+386
+00:31:50,660 --> 00:31:59,380
+لأن الـ potential
+
+387
+00:31:59,380 --> 00:32:06,410
+بالسالب، لاحظ أنه لو حطينا...لو جلبنا ال...ايش
+
+388
+00:32:06,410 --> 00:32:09,690
+بيسموه؟ لو جلبنا الخلية، حطينا هذا هنا وهذا هنا
+
+389
+00:32:09,690 --> 00:32:15,030
+هتلاحظ أن هذا صار بالسالب، اه، فانت بدك تجيب
+
+445
+00:37:19,240 --> 00:37:24,020
+الأعلى للأقل للأقل للأقل للأقل للصفر للسالب أقل
+
+446
+00:37:24,020 --> 00:37:28,780
+أقل أقل وهكذا، هذه بنقولها ordered standard
+
+447
+00:37:28,780 --> 00:37:33,500
+standard reduction potentials  كويس لما عملناها زي
+
+448
+00:37:33,500 --> 00:37:37,300
+هيك بنستفيد منها كتير بنعرف أنه كل ما طلعنا فوق
+
+449
+00:37:37,300 --> 00:37:41,700
+بتزيد ال oxidizing power يعني هذا better oxidizing
+
+450
+00:37:41,700 --> 00:37:45,520
+agent than هذا وهذا أكثر من هذا oxidizing وهذا
+
+451
+00:37:45,520 --> 00:37:49,480
+أكثر من هذا oxidizing يبقى ال oxidizing power كل
+
+452
+00:37:49,480 --> 00:37:54,120
+ما زادت ال E0 positively كل ما كان ال oxidizing
+
+453
+00:37:54,120 --> 00:38:00,850
+power أعلى طيب، لو نزلنا لتحت، كل ما نزلنا لتحت، ال
+
+454
+00:38:00,850 --> 00:38:05,970
+reducing power بتزيد، يعني ال lithium better
+
+455
+00:38:05,970 --> 00:38:08,690
+reducing power than potassium، وال potassium
+
+456
+00:38:08,690 --> 00:38:15,790
+better reducing power than cadmium، وهكذا، مفهوم؟
+
+457
+00:38:15,790 --> 00:38:18,350
+بقالنا؟ يبقى ال reducing power بتزيد واحنا نزلنا
+
+458
+00:38:18,350 --> 00:38:24,710
+لتحت، وفوق oxidizing كمان ممكن نستفيد حاجة ثانية
+
+459
+00:38:24,710 --> 00:38:30,370
+ممكن نقول أنه هي ال E note لاحظوا دائما
+
+460
+00:38:30,370 --> 00:38:37,330
+الإلكترونات وين موجودة؟ وين موجودة؟ على أي جهة؟
+
+461
+00:38:37,330 --> 00:38:40,890
+على الجهة اليسار يعني دائما ال standard electrode
+
+462
+00:38:40,890 --> 00:38:44,690
+potential اللي هي ال E note تكتب تكتب على هيئة
+
+463
+00:38:44,690 --> 00:38:49,740
+إيه؟ reduction يعني لما نعطيك قيمة ال E note ما
+
+464
+00:38:49,740 --> 00:38:56,040
+تفكرش هل هي مثلا Iron 3 زائد إلكترون تعطينا Iron 2
+
+465
+00:38:56,040 --> 00:39:02,800
+أو Iron 2 بتعطينا Iron 3 زائد إلكترون، لأ، هذه
+
+466
+00:39:02,800 --> 00:39:08,080
+غلط ال E note بتكون موجودة لإيه؟ لل reduction فقط
+
+467
+00:39:08,080 --> 00:39:11,880
+يعني ال E note بنكتبها على هيئة إيه؟ reduction
+
+468
+00:39:11,880 --> 00:39:16,920
+دائما، يبقى كتابة ال E note دائما reduction يعني
+
+469
+00:39:16,920 --> 00:39:20,320
+هذه القيمة محسوبة لل reduction مش لل oxidation
+
+470
+00:39:20,320 --> 00:39:23,800
+لل reduction هذه حاجة، الحاجة الثانية كمان اللي
+
+471
+00:39:23,800 --> 00:39:27,400
+بنستفيدها من الجدول أو الجداول اللي معانا، والله
+
+472
+00:39:27,400 --> 00:39:34,440
+احنا حابين نعرف احنا حابين نعرف هل مثلا لو جينا
+
+473
+00:39:34,440 --> 00:39:40,620
+طلعنا على هدول اتنين، احنا حابين نعرف هل ال silver
+
+474
+00:39:40,620 --> 00:39:45,320
+plus بيتفاعل مع ال copper واحد منهم لازم ناقصه عشان
+
+475
+00:39:45,320 --> 00:39:49,300
+يتفاعلوا، مش هيك؟ عشان ال electron هذا يكون في هذه
+
+476
+00:39:49,300 --> 00:39:51,840
+الناحية، ولما بده يتفاعل ال electron الثاني بده يكون
+
+477
+00:39:51,840 --> 00:39:55,320
+في النواتج علشان يروحوا مع بعض لأن المحصلة
+
+478
+00:39:55,320 --> 00:40:00,240
+النهائية مافيش فيها إلكترونات، فبقول هل ال AG plus
+
+479
+00:40:00,240 --> 00:40:05,900
+بيتفاعل مع ال copper solid ولا ال copper 2 plus هو
+
+480
+00:40:05,900 --> 00:40:09,080
+اللي بيتفاعل مع ال AG solid؟ يعني ال copper 2 plus
+
+481
+00:40:09,080 --> 00:40:14,700
+بيتفاعل مع هذا ولا هذا هو اللي بيتفاعل مع هذا؟ بنقول
+
+482
+00:40:14,700 --> 00:40:18,800
+سهل جدا نوصل لحل إذا كان رتبناهم بالترتيب الأعلى
+
+483
+00:40:18,800 --> 00:40:23,460
+فوق، الأعلى E note فوق والأقل تحت، هي هم رتبينها point
+
+484
+00:40:23,460 --> 00:40:26,880
+seven nine nine point three three nine يعني الأعلى
+
+485
+00:40:26,880 --> 00:40:30,480
+فوق والأقل تحت، إذا كان رتبناهم على هيئة reduction
+
+486
+00:40:30,480 --> 00:40:37,710
+اه، بعدين بيجي بنعمل خط بشكل هذا diagonal  
+
+487
+00:40:37,710 --> 00:40:41,830
+بنقول اه هذا هو اللي بيحصل فقط، يفجأ ال a g plus
+
+488
+00:40:41,830 --> 00:40:47,530
+زائد copper solid هو اللي راح يعطيني copper اتنين
+
+489
+00:40:47,530 --> 00:40:54,970
+plus زائد a g solid، لو بدنا نقرنها يعني، يفجأ هذا
+
+490
+00:40:54,970 --> 00:41:01,410
+اللي بيحصل، بينما هذا يعطيني a g plus زائد copper
+
+491
+00:41:01,410 --> 00:41:06,860
+solid هذا الكلام ما بيحصلش يبقى بقدر أعرف ايش التفاعل
+
+492
+00:41:06,860 --> 00:41:12,040
+اللي بيحصل و ايش التفاعل اللي ما بيحصلش، مجرد أني
+
+493
+00:41:12,040 --> 00:41:16,500
+فقط ارتب ال two half reactions اللي له E note أعلى
+
+494
+00:41:16,500 --> 00:41:21,400
+فوق واللي له E note أقل تحت، واعمل ال diagonal و
+
+495
+00:41:21,400 --> 00:41:25,600
+أرتبهم كقيمة E note، معناه كلام الاتنين يجب كتابتهم
+
+496
+00:41:25,600 --> 00:41:30,160
+على هيئة reduction، ما تكتبش أي ايش على هيئة oxidation
+
+497
+00:41:30,160 --> 00:41:34,500
+نهائيًا دائمًا شغلنا reduction عشان هيك ايش اسمها
+
+498
+00:41:34,500 --> 00:41:40,880
+ordered standard reduction potentials reduction
+
+499
+00:41:40,880 --> 00:41:46,880
+دائما تكتب على إنها reduction، خد اللي جابله، لاحظ
+
+500
+00:41:46,880 --> 00:41:50,980
+وين الإلكترونات؟ ده الإلكترونات على اليسار، ما فيش
+
+501
+00:41:50,980 --> 00:41:53,260
+ولا إلكترون على اليمين، دائما تكتب reduction
+
+502
+00:41:54,310 --> 00:41:56,950
+Standard Potentials يعني هو ممكن نقول Standard
+
+503
+00:41:56,950 --> 00:42:00,430
+Reduction Potentials لكن اختصارها، لأنه معروف أن
+
+504
+00:42:00,430 --> 00:42:04,710
+احنا بنكتبها دائما على هيئة reduction، طيب يا شباب
+
+505
+00:42:04,710 --> 00:42:09,690
+بنجف هان اليوم وإذا الله راد الحصة الجاية بنكمل
+
diff --git a/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/P2ufM_zJW7c_postprocess.srt b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/P2ufM_zJW7c_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..28e1d93937bf77e3abbae94092a9478532901bf8
--- /dev/null
+++ b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/P2ufM_zJW7c_postprocess.srt
@@ -0,0 +1,2020 @@
+1
+00:00:21,110 --> 00:00:25,230
+بسم الله الرحمن الرحيم اليوم إذا الله راضي بنتكلم
+
+2
+00:00:25,230 --> 00:00:29,930
+عن المحاضرة الأولى في ال chapter الأخير اللي معانا
+
+3
+00:00:29,930 --> 00:00:33,330
+اللي بتكلم عن ال oxidation reduction equilibria و
+
+4
+00:00:33,330 --> 00:00:36,870
+titrations في البداية بنتكلم عن ال oxidation
+
+5
+00:00:36,870 --> 00:00:43,820
+reduction equilibria وبنقول أنهالتفاعلات أنواع،
+
+6
+00:00:43,820 --> 00:00:49,440
+منها تفاعلات acid، acids مع bases، تفاعلات ligands
+
+7
+00:00:49,440 --> 00:00:55,040
+مع metal ions، تفاعلات precipitation ونوع آخر هو
+
+8
+00:00:55,040 --> 00:00:58,640
+تفاعلات الأكسدة والاختزال، تفاعلات الأكسدة
+
+9
+00:00:58,640 --> 00:01:06,900
+والاختزال تتضمنعمليتين متلازمتين عملية أكسدة يتم
+
+10
+00:01:06,900 --> 00:01:14,200
+خلالها فقد إلكترونات وعملية اختزال يتم خلالها
+
+11
+00:01:14,200 --> 00:01:19,640
+اكتساب هذه الإلكترونات اللى فقدت من جانب ال half
+
+12
+00:01:19,640 --> 00:01:24,230
+reaction الأولفعلى سبيل المثال لو طلعنا على
+
+13
+00:01:24,230 --> 00:01:30,070
+التفاعل اللي قدامي Serum 4 موجب مع Iron 2 موجب
+
+14
+00:01:30,070 --> 00:01:35,890
+يعطينا Serum 3 موجب مع Iron 3 موجب لو طلعنا على
+
+15
+00:01:35,890 --> 00:01:41,830
+Serum 4 اتحول لل Serum 3 يعني معنى الكلام اكتسب
+
+16
+00:01:41,830 --> 00:01:47,270
+إلكترون اكتسب إلكترون يعني حصله عملية اختزال بينما
+
+17
+00:01:47,270 --> 00:01:53,520
+ال Iron 2اتحول لل iron تلاتة معنى الكلام ال iron 2
+
+18
+00:01:53,520 --> 00:02:00,060
+فقد إلكترون يبقى معنى الكلام حصل له أكسدا أو ممكن
+
+19
+00:02:00,060 --> 00:02:03,060
+نتطلع على الموضوع بشكل آخر ال oxidation number
+
+20
+00:02:03,060 --> 00:02:07,740
+للثيريوم أربعة موجب أربعة موجب اتحول لثيريوم تلاتة
+
+21
+00:02:07,740 --> 00:02:14,300
+موجب إذا ال oxidation numberلسيريام جال هذا عملية
+
+22
+00:02:14,300 --> 00:02:18,840
+reduction بينما ال iron اتنين اتحول لل iron تلاتة
+
+23
+00:02:18,840 --> 00:02:22,620
+يبقى ال oxidation number اتحول من اتنين لتلاتة اذا
+
+24
+00:02:22,620 --> 00:02:27,400
+ال oxidation number زاد وبالتالي هذا عملية اكسدة
+
+25
+00:02:27,400 --> 00:02:32,540
+فعملية الاكسدة وعملية الاختزال عمليتين متلازمتين
+
+26
+00:02:32,540 --> 00:02:38,130
+بيحصل مع بعض بحيث انهالإلكترونات اللي بيمنحها نصف
+
+27
+00:02:38,130 --> 00:02:44,770
+التفاعل الأول بيستهلكها نصف التفاعل الآخر المحصلة
+
+28
+00:02:44,770 --> 00:02:49,450
+المعادلة النهائية لا يوجد فيها ظهور لأي إلكترون
+
+29
+00:02:51,740 --> 00:02:54,780
+ممكن المعادلة الماضية نجسمها لنصين زي ما احنا
+
+30
+00:02:54,780 --> 00:02:58,060
+شايفين السيريام أربعة بياخد إلكترون هذه عملية
+
+31
+00:02:58,060 --> 00:03:02,100
+reduction الايرون اتنين بيعطيني إلكترون هذه عملية
+
+32
+00:03:02,100 --> 00:03:06,120
+oxidation الآن كيف نتعرف على تفاعلات الأكسدة
+
+33
+00:03:06,120 --> 00:03:13,540
+والاختزال بنقول تفاعل الأكسدة والاختزال يتم خلاله
+
+34
+00:03:13,540 --> 00:03:19,930
+تغير في ال oxidation number لبعض الذراتبعض الذرات
+
+35
+00:03:19,930 --> 00:03:25,150
+في المتفاعلات هي نفسها في النواتج بنلاحظ لو شوفنا
+
+36
+00:03:25,150 --> 00:03:28,730
+ال oxygen number للأولى بنلاحظ انه بيتغير عن ال
+
+37
+00:03:28,730 --> 00:03:33,450
+oxygen number في الثانية او في النواتج فمثلا لو
+
+38
+00:03:33,450 --> 00:03:40,170
+طلعنا على ال potassium واحد موجب ال oxygen اتنين
+
+39
+00:03:40,170 --> 00:03:44,570
+سالب في اربعة يعني تمانية سالب منهم واحد موجب اذا
+
+40
+00:03:44,570 --> 00:03:53,450
+المنجانيز سبعة موجبالـ Oxalic Acid الـ H واحد موجب
+
+41
+00:03:53,450 --> 00:04:00,330
+الـ Oxygen اتنين سالم في اربعة سالم تمانية موجب
+
+42
+00:04:00,330 --> 00:04:06,090
+اتنين اذا الكربون تان ستة موجب يبقى الواحدة تلاتة
+
+43
+00:04:06,090 --> 00:04:11,790
+موجب الاتنين كربون6 موجب يبقى الواحدة تلاتة موجب
+
+44
+00:04:11,790 --> 00:04:18,910
+ال HCl واحد موجب واحد سالب الكلور واحد سالب في
+
+45
+00:04:18,910 --> 00:04:22,910
+اتنين اتنين سالب اذا المنجانيز اتنين موجب ال K
+
+46
+00:04:22,910 --> 00:04:25,930
+واحد موجب ال CL واحد سالب
+
+47
+00:04:29,050 --> 00:04:32,850
+أو ممكن نقول نبدأ بال O2 اتنين سالب في اتنين يبقى
+
+48
+00:04:32,850 --> 00:04:38,350
+اربعة سالب يبقى الكربون اربعة موجب ال H واحد موجب
+
+49
+00:04:38,350 --> 00:04:43,210
+الاكسجين اتنين سالب لو جينا واطلعنا على المانجانيز
+
+50
+00:04:43,210 --> 00:04:49,690
+بنلاحظ انه ال oxidation number تبعه اتغير من موجب
+
+51
+00:04:49,690 --> 00:04:58,200
+سبعة لموجب اتنين اذا اختزل اختزلأما الكربون
+
+52
+00:04:58,200 --> 00:05:05,100
+فبنلاحظ أنه اتغير من نوجة بتلاتة لموجة باربع زاد
+
+53
+00:05:05,100 --> 00:05:10,280
+عملية أكسدة عملية أكسدة فأكيد هذا التفاعل اللي
+
+54
+00:05:10,280 --> 00:05:15,800
+جدامي هو تفاعل أكسدة واختزال لأنه تم خلال التفاعل
+
+55
+00:05:15,800 --> 00:05:19,760
+تغير في ال oxidation numbers
+
+56
+00:05:21,890 --> 00:05:26,690
+واحد او اش يزاد و اش يجل لازم اش يزيد و اش يجل
+
+57
+00:05:26,690 --> 00:05:32,010
+لانه لازم عملية الاكسدة تحصل بالتلازم مع عملية
+
+58
+00:05:32,010 --> 00:05:35,560
+الاختزالاللي هم اتطلعنا عليه مثال اخر مثلا Sodium
+
+59
+00:05:35,560 --> 00:05:40,480
+Carbonate مع 2HCl بيعطينا Sodium Chloride CO2H2O
+
+60
+00:05:40,480 --> 00:05:44,580
+ال Sodium موجب واحد الكربون موجب اربعة ال Oxygen
+
+61
+00:05:44,580 --> 00:05:49,200
+سالب اتنين ال H موجب واحد ال Cl سالب واحد الاخره
+
+62
+00:05:49,200 --> 00:05:53,500
+لو جينا اتطلعنا هل حصل اي تغير في ال oxidation
+
+63
+00:05:53,500 --> 00:05:58,490
+numberلأي عنصر من العناصر لأي ذرّة من الذرّات
+
+64
+00:05:58,490 --> 00:06:02,830
+بنلاحظ لأ نفس ال oxidation numbers اللي موجودة على
+
+65
+00:06:02,830 --> 00:06:06,590
+اليسار هي نفسها نفس ال oxidation numbers لنفس
+
+66
+00:06:06,590 --> 00:06:09,470
+الذرّات اللي موجودة على اليمين مع ذلك لا حصلش أي
+
+67
+00:06:09,470 --> 00:06:13,230
+تغير في ال oxidation number وبالتالي هذا معادل أو
+
+68
+00:06:13,230 --> 00:06:17,370
+هذا تفاعل مش تفاعل أكسيد أو اختزال بالطبع هو تفاعل
+
+69
+00:06:17,370 --> 00:06:24,270
+acid base reactionالان بس بدنا نراجع كيف نوزن
+
+70
+00:06:24,270 --> 00:06:28,110
+المعادلات ال .. ال Redox reaction المعادلة ال
+
+71
+00:06:28,110 --> 00:06:31,890
+Redox المعادلة الأكسدة والاختزال كيف نوزنها؟ لأ
+
+72
+00:06:31,890 --> 00:06:35,170
+معناها ده كلام سنة أولى لكن يعني كلام سريع كتير
+
+73
+00:06:35,170 --> 00:06:43,990
+بنقول أساس وزن المعادلة هو عبارة عن تلت خطواتيعني
+
+74
+00:06:43,990 --> 00:06:47,930
+بسيطة جدا ومفهومة بالنسبالنا أول خطوة نفصل
+
+75
+00:06:47,930 --> 00:06:52,210
+المعادلة لنصين وهذه محاجة سائلة كتير نفصل المعادلة
+
+76
+00:06:52,210 --> 00:06:56,830
+لنصين تاني خطوة كل نص ناخده على حده نعمله mass
+
+77
+00:06:56,830 --> 00:07:02,670
+balanceأه و تالت خطوة ال charge balance خلي عدد
+
+78
+00:07:02,670 --> 00:07:06,410
+الذرات علي اليمين يصيب عدد الذرات علي اليسار و
+
+79
+00:07:06,410 --> 00:07:10,950
+بعدين الشحنات تكون أيضا علي اليمين بتساوي الشحنات
+
+80
+00:07:10,950 --> 00:07:14,770
+علي اليسار و هيك بنكون وزن المعادلة بالذات لما
+
+81
+00:07:14,770 --> 00:07:19,330
+نيجي في الآخر خالص نجمع نصين التفاعل بنلاحظ ان
+
+82
+00:07:19,330 --> 00:07:22,660
+المعادلة اللي عندنا معادلة موزونةفنشوف مثلا
+
+83
+00:07:22,660 --> 00:07:26,640
+المعادلة التالية باي كروميت مع ايرون بيعطينا كروم
+
+84
+00:07:26,640 --> 00:07:30,380
+و ايرون تلاتة بدك سم المعادلة بتدوزنها بدك سمها
+
+85
+00:07:30,380 --> 00:07:34,740
+نصين في البداية فبقول ال ايرون اتنين بتحول ل ايرون
+
+86
+00:07:34,740 --> 00:07:38,340
+تلاتة و باي كروميت بتحول ل كروميام تلاتة فناخد
+
+87
+00:07:38,340 --> 00:07:42,060
+النص الأول ايرون اتنين بتحول ل ايرون تلاتة ايش
+
+88
+00:07:42,060 --> 00:07:45,520
+بقول انا عملت الخطوة لولا فصلتهم لنصين الخطوة
+
+89
+00:07:45,520 --> 00:07:49,690
+التانية mass balanceلازم بالترتيب الخطوة التالتة
+
+90
+00:07:49,690 --> 00:07:52,410
+charge balance فخليني في ال mass balance للنص
+
+91
+00:07:52,410 --> 00:07:57,810
+الأول اكم ذرة iron هان اكم ذرة هان اذا واندي mass
+
+92
+00:07:57,810 --> 00:08:01,870
+balance ابنجي للخطوة الأخيرة اللي هي ال charge
+
+93
+00:08:01,870 --> 00:08:06,410
+balance اكم الشحن اللي هان اتنين موجب الشحن اللي
+
+94
+00:08:06,410 --> 00:08:10,720
+هان ثلاثة موجب كم ده خليهم زي بعضبدي أضع إلكترون
+
+95
+00:08:10,720 --> 00:08:14,440
+على اليمين إذا ايرون اتنين موجة بتعطيني ايرون
+
+96
+00:08:14,440 --> 00:08:16,660
+تلاتة موجة زي الإلكترون طبعا هذه صارت mass
+
+97
+00:08:16,660 --> 00:08:20,700
+balanced with charge balanced يبقى خلاص من النص
+
+98
+00:08:20,700 --> 00:08:25,560
+الأول باجي للنص التاني الداي كروميت بتعطيني
+
+99
+00:08:25,560 --> 00:08:30,380
+كروميام اكم كروميام عندي هان اكم كروميام هان إذا
+
+100
+00:08:30,380 --> 00:08:33,910
+بدي أضرب هان باتنين أخليها اتنين كروميامماشي يا
+
+101
+00:08:33,910 --> 00:08:37,430
+شباب صارت ذرات لي كروم اتنين اتنين باجري ال oxygen
+
+102
+00:08:37,430 --> 00:08:41,730
+هان عندي سبعة oxygen هان اكم oxygen اه؟ بحط سبعة
+
+103
+00:08:41,730 --> 00:08:45,790
+مية سبعة مية طب ماشي صار عندي سبعة oxygen لك صار
+
+104
+00:08:45,790 --> 00:08:50,450
+عندي هان اربع تاشر H فباخدهم وين؟ على اليسار على
+
+105
+00:08:50,450 --> 00:08:54,510
+هيئة H plus يبجى ال H اللي هو حاطيته على هيئة H2O
+
+106
+00:08:55,340 --> 00:08:59,720
+باخده على اليسار على هيئة ايه اتش بلس اربعتاشر اتش
+
+107
+00:08:59,720 --> 00:09:04,340
+بلس الان لو اتيت اتطلعت بلاقي انه اربعتاشر اتش
+
+108
+00:09:04,340 --> 00:09:07,760
+اربعتاشر اتش اتنين كروم اتنين كروم سبعة اكسجين
+
+109
+00:09:07,760 --> 00:09:11,740
+سبعة اكسجين موزونة فهذه الmass balanced موزونة من
+
+110
+00:09:11,740 --> 00:09:16,660
+ناحية ال mass فبنجي نتطلع على charge balance فنقول
+
+111
+00:09:16,660 --> 00:09:21,600
+والله بدنا نعد هاي اربعة عيش موجب اتس اتنين سالب
+
+112
+00:09:21,600 --> 00:09:26,610
+يبقى اتنين عيش موجبطب هان في عندي ستة موجب، إذا
+
+113
+00:09:26,610 --> 00:09:30,650
+كيف بدي أخلي الستة تساوي ليه أطلع عش موجب؟ بدي أحط
+
+114
+00:09:30,650 --> 00:09:34,210
+ستة إلكترونات على هذه الناحية، حطينا ستة إلكترونات
+
+115
+00:09:34,210 --> 00:09:37,430
+على هذه الناحية، يبقى سعر عندي mass balanced
+
+116
+00:09:37,430 --> 00:09:42,190
+equation و أيضا charge balanced equation، هذا النص
+
+117
+00:09:42,190 --> 00:09:47,250
+بجمعه لنص ال iron اللي شفته قبل شوية، لكنالـ Iron
+
+118
+00:09:47,250 --> 00:09:49,930
+كان فيه بس إلكترون واحد و أنا بعرف إن المعادلة
+
+119
+00:09:49,930 --> 00:09:53,410
+النهائية لازم مايكونش فيها أي إلكترون فيجب ضرب
+
+120
+00:09:53,410 --> 00:09:56,690
+المعادلة الأولى ب 6 علشان الإلكترونات هذه تروح
+
+121
+00:09:56,690 --> 00:10:01,230
+ممنوع يظهر أي إلكترون في المعادلة النهائية فبتكون
+
+122
+00:10:01,230 --> 00:10:05,730
+هذه المعادلة المحصلة أو هذا هو وزن المعادلة اللي
+
+123
+00:10:05,730 --> 00:10:09,390
+عندي لو جيت قلعت على المعادلة هذه اللي مكتوبة
+
+124
+00:10:09,390 --> 00:10:14,590
+باللون الأحمر بقول هذه المعادلةبتحصل في ال acid
+
+125
+00:10:14,590 --> 00:10:18,590
+medium في ايه؟ في ال acid medium مرات بقول ليه
+
+126
+00:10:18,590 --> 00:10:22,610
+اوزن المعادلة في ال basic medium في الوسط القاعدى
+
+127
+00:10:22,610 --> 00:10:26,490
+بقول كيف بعمل هذا كلام بعد ما اخلص او قبل ما اخلص
+
+128
+00:10:26,490 --> 00:10:30,070
+خليني اقول بعد ما اخلص هان و اخد مثال بعد شوية قبل
+
+129
+00:10:30,070 --> 00:10:33,270
+ما اخلص ايش بعمل بقول في انديهان اربعة عشر H بلس
+
+130
+00:10:33,270 --> 00:10:35,630
+لا يعقل ان يكون في انديهان H بلس في ال basic
+
+131
+00:10:35,630 --> 00:10:41,590
+medium هذا acid فبدي احط جدهم بالظبط بس بحط ال OH
+
+132
+00:10:41,590 --> 00:10:46,920
+على الناحيتينليه؟ علشان احافظ على ال mass balance
+
+133
+00:10:46,920 --> 00:10:49,980
+تبعي و ال charge balance تبعي ايضا بحط ال
+
+134
+00:10:49,980 --> 00:10:54,100
+hydroxide على ايه؟ على الترفين 14 H plus بقى 14
+
+135
+00:10:54,100 --> 00:10:59,580
+hydroxide هدول ايش بيعطوني؟أربعة عاش مية طب هي في
+
+136
+00:10:59,580 --> 00:11:03,940
+عندي سبعة مية هان هيها راحت وهان بزيد سبعة إذا
+
+137
+00:11:03,940 --> 00:11:07,660
+بتكون المعادلة موزونة هدول راحوا خلاص تعطوني
+
+138
+00:11:07,660 --> 00:11:11,740
+الأربعة عاش مية تم منهم سبعة إذا ستة iron زائد
+
+139
+00:11:11,740 --> 00:11:15,980
+سبعة مية زائد diachromate بيعطينا ستة iron اتنين
+
+140
+00:11:15,980 --> 00:11:19,380
+chromium زائد أربعة عاش hydroxide هذا وزن المعادلة
+
+141
+00:11:19,380 --> 00:11:21,460
+في ال basic solution
+
+142
+00:11:24,140 --> 00:11:29,460
+طيب يا شباب انا بقول ناخد كمان مثال بس لا ايه
+
+143
+00:11:29,460 --> 00:11:33,620
+التذكير بصحى أجزالات زائد بيرمانجانات بتعطينا
+
+144
+00:11:33,620 --> 00:11:38,980
+مانجانيز 4 زائد CO2 أول خطوة نجسبهم لنصين جسلناها
+
+145
+00:11:38,980 --> 00:11:43,620
+لنصين أجزالات بتعطي CO2 بيرمانجانات بتعطي مانجانيز
+
+146
+00:11:43,620 --> 00:11:48,590
+طبعا مش معقول أجزالات بتعطي مانجانيزمش هيك؟ طبيعي
+
+147
+00:11:48,590 --> 00:11:51,950
+يعني فالفيلم الجديد بتاعة المنجانيز ال Oxalية
+
+148
+00:11:51,950 --> 00:11:57,090
+بتاعة ال CO2 بدنا نقول مادام قصلناهم ناخد أول نص
+
+149
+00:11:57,090 --> 00:12:02,130
+هي ال Oxalية هاد اتنين ماكانش هاد اتنين هاد هاد
+
+150
+00:12:02,130 --> 00:12:05,250
+اتنين كربون بده أحط قدره بعيد في اتنين ال Oxygen
+
+151
+00:12:05,250 --> 00:12:08,070
+أربعة و الله يوم أربعة يبقى هاد موزونة من ناحية
+
+152
+00:12:08,070 --> 00:12:12,950
+mass mass balanced بد recharge هاد شحنتين سالبتين
+
+153
+00:12:12,950 --> 00:12:16,130
+اذا بدي أحط هنا اتنين electron على اليمين
+
+154
+00:12:18,890 --> 00:12:23,950
+طيب بنيجي لنص التفاعل الآخر اللي هو ال
+
+155
+00:12:23,950 --> 00:12:27,710
+permanganate بقول مانجانيز أكم ذره واحدة و هان
+
+156
+00:12:27,710 --> 00:12:31,630
+واحدة اذا موزونة الاكسجين اربعة فش ولا واحدة اذا
+
+157
+00:12:31,630 --> 00:12:35,850
+اربعة مية اربعة مية يبقى صار في عندي تمانية H بلس
+
+158
+00:12:35,850 --> 00:12:40,810
+تمانية H بلس على اليسار تمانية H بلس على اليسار
+
+159
+00:12:40,810 --> 00:12:43,630
+يبقى تمانية H بلس زائد permanganate تعطيني
+
+160
+00:12:43,630 --> 00:12:46,610
+مانجانيز اربعة زي اربعة H2O بتطلع عليها بيلاجيها
+
+161
+00:12:46,610 --> 00:12:52,860
+mass balancedموزورة بالنسبة للماس بدي
+
+162
+00:12:52,860 --> 00:12:58,600
+اضمط الشحنات هان تمانية موجب و واحد سالب صار سبعة
+
+163
+00:12:58,600 --> 00:13:04,780
+موجب هان أربعة موجب اذا بدي احط تلت إلكترونات على
+
+164
+00:13:04,780 --> 00:13:10,320
+الجهة اليسار مظبوط يا شبابطيب تلت إلكترونات على
+
+165
+00:13:10,320 --> 00:13:15,180
+الجهة اليسار لو بدي أشتغل in basic medium ممكن أني
+
+166
+00:13:15,180 --> 00:13:18,080
+أجمع المعادلتين و في الآخر أعمل أعمالي اللي عملتها
+
+167
+00:13:18,080 --> 00:13:23,340
+سابقا لكن فيها أنه عند هذه الخطوة أحط تمانية OH
+
+168
+00:13:23,340 --> 00:13:28,840
+سالمعلى الطرفين فبتصير تمانية واتش سالب و تمانية H
+
+169
+00:13:28,840 --> 00:13:34,140
+plus هدول بيعطونا تمانية H2O و بزيد عنا تمانية
+
+170
+00:13:34,140 --> 00:13:36,640
+Hydroxide عن ناحية التانية لاحظ ان في عن ناحية
+
+171
+00:13:36,640 --> 00:13:41,320
+أربعة مية و في عن ناحية تمانية مية طبعا الاربعة
+
+172
+00:13:41,320 --> 00:13:44,320
+بيروحوا مع اربعة منها ان بيبقى عندى اربعة مية على
+
+173
+00:13:44,320 --> 00:13:49,380
+ناحية اليسار باجي
+
+174
+00:13:49,380 --> 00:13:55,260
+باجمعهك حصلت على المعادلاتين بجيب أشبعهم عشان أضيع
+
+175
+00:13:55,260 --> 00:13:58,460
+الإلكترونات هل في عندي two electrons و هل في عندي
+
+176
+00:13:58,460 --> 00:14:01,960
+three electrons كيف الأثنين بيروح مع التلاتة لازم
+
+177
+00:14:01,960 --> 00:14:04,760
+أضرب الأثنين في التلاتة و التلاتة في اتنين فبضرب
+
+178
+00:14:04,760 --> 00:14:06,740
+المعادلة الأولى في تلاتة و المعادلة التانية في
+
+179
+00:14:06,740 --> 00:14:11,380
+اتنين اللي بيعطيني المعادلة المحصلة هك بوزن
+
+180
+00:14:11,380 --> 00:14:17,580
+المعادلات في ال Redox reactionsماشي يا شباب طبعا
+
+181
+00:14:17,580 --> 00:14:24,840
+الكلام مر معنا في سنة أولى بس مجرد تذكير الان نجي
+
+182
+00:14:24,840 --> 00:14:29,300
+نتطلع على ال electrochemical cells هذا الموضوع
+
+183
+00:14:29,300 --> 00:14:33,320
+الأساسي تبعنا ال electrochemical cells الخلايا
+
+184
+00:14:33,320 --> 00:14:38,780
+الكهرو كيميائية أو الكهربية الكهرو كيميائية بنقول
+
+185
+00:14:38,780 --> 00:14:44,970
+ال electrochemical cells نوعينيا اما خلايا بتولد
+
+186
+00:14:44,970 --> 00:14:50,770
+كهربا تعطيني كهربا يعني ايه؟ يعني التفاعل نصين
+
+187
+00:14:50,770 --> 00:14:55,850
+التفاعل بيتفاعلوا مع بعض المتفاعل تتفاعل مع بعض
+
+188
+00:14:55,850 --> 00:15:01,190
+بتعطيني نواتج بشكل تلقاء spontaneous كويس وهك بحصل
+
+189
+00:15:01,190 --> 00:15:05,550
+على فرق جهودبحصل نتيجة فعل بحصل على فرق جهود،
+
+190
+00:15:05,550 --> 00:15:11,310
+نتيجة انتقال الإلكترونات بحصل على تيار، كويس، لما
+
+191
+00:15:11,310 --> 00:15:16,850
+تكون الخلية بتعطيني جهود، بسميها Galvanic cell أو
+
+192
+00:15:16,850 --> 00:15:23,530
+في نوع آخر من الخلايا، المتفاعلات بتعطينيش نواتج،
+
+193
+00:15:23,530 --> 00:15:28,750
+بالعكس النواتج هي اللي بتعطي متفاعلاتفالمتفاعلات
+
+194
+00:15:28,750 --> 00:15:34,750
+مايعطيش نواتج، بنقول هذه الخلية لا يعني ينشأ عنها
+
+195
+00:15:34,750 --> 00:15:39,570
+جهد، بالعكس هي بحاجة إلى جهد علشان التفاعل يحصل،
+
+196
+00:15:39,570 --> 00:15:42,990
+بحاجة إلى جهد علشان التفاعل يحصل، فهذه الخلية
+
+197
+00:15:42,990 --> 00:15:47,060
+بنقولها electrolytic cellsElectrolytic احنا بدنا
+
+198
+00:15:47,060 --> 00:15:50,820
+نحاول نطلع على او ندرس بالتفصيل اللي هو ال
+
+199
+00:15:50,820 --> 00:15:55,100
+Galvanic cells الخلايا الإلكتروليتية طبعا عكسها
+
+200
+00:15:55,100 --> 00:16:01,560
+تماما بنقول اي خلية كهربية تتكون من قطبينقطبين،
+
+201
+00:16:01,560 --> 00:16:07,020
+قطب بنقوله cathode و قطب بنقوله anode إيش هي
+
+202
+00:16:07,020 --> 00:16:09,920
+الشحنة اللي على ال cathode أو ال sign اللي بنعتهله
+
+203
+00:16:09,920 --> 00:16:14,300
+هل هي موجبة أو سالبة؟ بنقول هذا الكلام بتوقف على
+
+204
+00:16:14,300 --> 00:16:19,920
+نوع الخلية، هل هي galvanic أو electrolytic فهذا
+
+205
+00:16:19,920 --> 00:16:23,620
+عبارة عن sign إله convention معين، إله يعني إصطلاح
+
+206
+00:16:23,620 --> 00:16:27,080
+معين، لكن إحنا في ال galvanic cells بنعتبر ال
+
+207
+00:16:27,080 --> 00:16:32,060
+cathode موجب والanode سالبنعتبر الكاثود موجب
+
+208
+00:16:32,060 --> 00:16:38,080
+والأنود سالب في الـ electrolytic cells عكس هذا
+
+209
+00:16:38,080 --> 00:16:43,940
+الكلام تماما لما جينا اتطلعنا ايش الخلية ال
+
+210
+00:16:43,940 --> 00:16:47,960
+electrochemical cell بنقول هي اظهر عن وعى بيحتوي
+
+211
+00:16:47,960 --> 00:16:51,560
+على two electrodes كل electrode مأمور في المحلول
+
+212
+00:16:51,560 --> 00:16:55,260
+تبعه او في محلول في half reaction معين وهذا في
+
+213
+00:16:55,260 --> 00:17:00,440
+half reaction معينوفي بينهم حاجز الحاجز هذا عبارة
+
+214
+00:17:00,440 --> 00:17:06,880
+عن semi permeable membrane يعني غشاء شبه منفذ او
+
+215
+00:17:06,880 --> 00:17:12,000
+اذا كانوا موجودين فيه محلولين منفصلين فبيكون فيه
+
+216
+00:17:12,000 --> 00:17:18,690
+قنطرة ملحية salt bridge بتوصل بينهملأنه مابينفعش
+
+217
+00:17:18,690 --> 00:17:23,010
+مايكونش فيه عندى حركة للأيونات في هذا الاتجاه و
+
+218
+00:17:23,010 --> 00:17:29,670
+هذا الاتجاه عادة هذا الاتجاه الايود السالب مثلا زى
+
+219
+00:17:29,670 --> 00:17:33,250
+الـC المينوس فهذا الاتجاه الايود الموجب زى
+
+220
+00:17:33,250 --> 00:17:37,070
+البوتاسيوم على سبيل المثال هنشوف ليش هذا الكلام
+
+221
+00:17:37,070 --> 00:17:43,000
+المهم انههذه الخلية لو جئنا وكانت Galvanic لو جئنا
+
+222
+00:17:43,000 --> 00:17:46,640
+وصلنا ال two electrodes اللي هو ال cathode بالأنود
+
+223
+00:17:46,640 --> 00:17:50,540
+وحطينا voltmeter ووصلناها الطرفيا voltmeter بنلاحظ
+
+224
+00:17:50,540 --> 00:17:54,680
+ال voltmeter بيقشر بيعطينا فرق جهد وليكن مثلا ال
+
+225
+00:17:54,680 --> 00:17:59,870
+volt بيسوا point five to one voltهذا ال point 521
+
+226
+00:17:59,870 --> 00:18:03,930
+volt عبارة عن ايه؟ عبارة عن فرق الجهد بين القطبين
+
+227
+00:18:03,930 --> 00:18:10,570
+فرق الجهد بين القطبين يعني فرق الجهد ما بين ال
+
+228
+00:18:10,570 --> 00:18:13,950
+electrode هذا و ال electrode هذا فرق الجهد بينهم
+
+229
+00:18:13,950 --> 00:18:19,450
+عادة فرق الجهد يعني بقدر أجيسه بسهولة بواسطة ال
+
+230
+00:18:19,450 --> 00:18:25,880
+voltmeter بقدر أجيسه بسهولة بواسطة ال voltmeterلكن
+
+231
+00:18:25,880 --> 00:18:30,040
+لو سألنا حالنا سؤال طب إيش فرق جهد الإلكترود هذا
+
+232
+00:18:30,040 --> 00:18:38,000
+لوحده؟ وإيش جهد الإلكترود هذا لوحده؟ فالفرق بينهم
+
+233
+00:18:38,000 --> 00:18:44,600
+معروفلكن يمكن يكون هذا واحده point five to one
+
+234
+00:18:44,600 --> 00:18:49,780
+والتاني مثلا واحد الفرق منهم point five to one او
+
+235
+00:18:49,780 --> 00:18:53,100
+يمكن يكون واحد point five to one والتاني صفر معايا
+
+236
+00:18:53,100 --> 00:18:57,960
+يعني الفرق بينهم اه سهولة بينجاز لكن جهد ال
+
+237
+00:18:57,960 --> 00:19:01,540
+electrode هذا لوحده وجهد ال electrode هذا لوحده هل
+
+238
+00:19:01,540 --> 00:19:06,680
+بقدر اعينهبنقول بدنا طريقة نقدر نعين جهد ال
+
+239
+00:19:06,680 --> 00:19:13,280
+electrode علشان هيك لابد من استخدام حاجة بنقولها
+
+240
+00:19:13,280 --> 00:19:19,430
+standard hydrogen electrodeقطب الهيدروجين القياسي
+
+241
+00:19:19,430 --> 00:19:24,370
+أو برضه بنقوله normal hydrogen electrode SHE يعني
+
+242
+00:19:24,370 --> 00:19:28,130
+standard hydrogen electrode أو NHE يعني normal
+
+243
+00:19:28,130 --> 00:19:32,810
+hydrogen electrode لازم نستخدمه ليش لازم نستخدمه
+
+244
+00:19:32,810 --> 00:19:37,010
+جان لأنه هذا ال electrode اللي أنا بتتكلم عنه
+
+245
+00:19:37,010 --> 00:19:39,970
+هالجيت هذا ال electrode اعطناله
+
+246
+00:19:42,690 --> 00:19:46,890
+بتنشيل اختياري من عنا هذا ال potential هو عبارة عن
+
+247
+00:19:46,890 --> 00:19:50,990
+صفر at standard state صفر at standard state وعند
+
+248
+00:19:50,990 --> 00:19:57,310
+الحالة القياسية بنعطيله potential مقدارها صفر يعني
+
+249
+00:19:57,310 --> 00:20:03,930
+مثلا لو كان هذا هو ال SHEو هان اعطاني point three
+
+250
+00:20:03,930 --> 00:20:08,410
+four two اللي هو فرق الجهود بينهم مادام هذا SHE
+
+251
+00:20:08,410 --> 00:20:14,430
+هذا ال E note تبعته صفر لأنه احنا عاملا بنعرفه و
+
+252
+00:20:14,430 --> 00:20:23,430
+بنقول انه جهد ال electrode صفر لل SHE اذا واضح ان
+
+253
+00:20:23,430 --> 00:20:26,570
+اللي بحصل عليه انا هان هو عبارة عن جهد ال other
+
+254
+00:20:26,570 --> 00:20:32,090
+electrodeلأن الفرق هذا هو عبارة عن هذا بصفر، إذا
+
+255
+00:20:32,090 --> 00:20:37,310
+هذا الفرق هو عبارة عن ال electrode الآخر، مش هيك؟
+
+256
+00:20:37,310 --> 00:20:43,130
+طيب، إذا كان هذا الكلام هالسهولة، إذا والله ممكن
+
+257
+00:20:43,130 --> 00:20:47,570
+أنا أجي أحط ال SHE
+
+258
+00:20:50,440 --> 00:20:55,540
+أستخدمه كقطم واستخدم أي إلكترود أنا بدي أعرف ال
+
+259
+00:20:55,540 --> 00:20:59,680
+potential تبعه، أيش ما كان يكون، فاحطه أتمل فيه
+
+260
+00:20:59,680 --> 00:21:02,500
+الخلية، لأن الخلية قطمين، فواحد منهم ال SHA
+
+261
+00:21:02,500 --> 00:21:05,640
+والتاني هو ال other electrode، فرق الجهد؟ راح
+
+262
+00:21:05,640 --> 00:21:08,340
+يقولي والله يا هدا هو عبارة عن جهد ال other
+
+263
+00:21:08,340 --> 00:21:12,710
+electrodeيبقى هذه شغلة سهلة كثير في البداية لكن
+
+264
+00:21:12,710 --> 00:21:17,950
+قبل ما اروح لهذا الكلام بدأ اقول ايش هو ال S.H.E
+
+265
+00:21:17,950 --> 00:21:21,930
+ايش هو ال S.H.E ايش هو ال standard hydrogen
+
+266
+00:21:21,930 --> 00:21:27,850
+electrode جال هو والله الشكل اللي قدامي هذا فيه
+
+267
+00:21:27,850 --> 00:21:32,250
+عندي inverted tube هذا glass tube فيها فتحة بعدي
+
+268
+00:21:32,250 --> 00:21:37,110
+منها ال hydrogen ال hydrogen بيدخل منهاعند واحد
+
+269
+00:21:37,110 --> 00:21:41,130
+أتمسفير هذه ال standard state تبعتي واحد أتمسفير
+
+270
+00:21:41,130 --> 00:21:45,110
+يعني ال pressure للهيدروجين اللي داخل جداش واحد
+
+271
+00:21:45,110 --> 00:21:52,330
+أتمسفير طيب عندي هذا الكلام موجود في محلول HCl
+
+272
+00:21:52,330 --> 00:21:58,760
+جداش ال H plus لهو 1 مولار الحرارة مظبوطة عند 25
+
+273
+00:21:58,760 --> 00:22:04,800
+درجة او 298 كيلوفر اذا هذه هي الشروط القياسية اللى
+
+274
+00:22:04,800 --> 00:22:08,300
+انا بستخدم ال standard hydrogen electrode عندها
+
+275
+00:22:08,300 --> 00:22:17,720
+عندى 1 اتمسفير لل H2 ال H plus 1 مولار الحرارة 298
+
+276
+00:22:17,720 --> 00:22:25,620
+كيلوفرفي عنده القطب هو عبارة عن platinum wire من
+
+277
+00:22:25,620 --> 00:22:29,620
+البلاتين فيه في آخره platinum electrode Platinized
+
+278
+00:22:29,620 --> 00:22:32,560
+platinum electrode Platinized platinum electrode
+
+279
+00:22:32,560 --> 00:22:35,500
+هذا عبارة عن قطب البلاتين ال surface area تبعته
+
+280
+00:22:35,500 --> 00:22:39,560
+عاليةال surface area تبعته عالية لإيه؟ لأن التفاعل
+
+281
+00:22:39,560 --> 00:22:44,860
+اللي قدامي هذا أو عكسه بدي يحصل بسرعة و أكتشف أحصل
+
+282
+00:22:44,860 --> 00:22:49,960
+بسرعة إذا كان ال surface area عندي كبيرة ف
+
+283
+00:22:49,960 --> 00:22:53,840
+platinumized platinum electrode هذا الجزء اللي هو
+
+284
+00:22:53,840 --> 00:23:00,840
+مربع تقريباهذا عبارة عن platinum electrode يعني هو
+
+285
+00:23:00,840 --> 00:23:07,120
+عبارة عن plate او foil من ال platinum لكن في عليه
+
+286
+00:23:07,120 --> 00:23:10,700
+particles من ال platinum بحيث انه ال surface area
+
+287
+00:23:10,700 --> 00:23:15,040
+تبعته اش تكون كبيرة يعني هاي ال surface وفي عندي
+
+288
+00:23:15,040 --> 00:23:18,540
+بدل ال surface معروف جدش المساحة يعني لكن لو حطيت
+
+289
+00:23:19,590 --> 00:23:23,330
+زي الكورة اللي هي حبة بلاتين شوفوا كده ال surface
+
+290
+00:23:23,330 --> 00:23:28,440
+area زادت طب وكمان حبهاال surface area اه صارت زي
+
+291
+00:23:28,440 --> 00:23:32,360
+هيك معايا الى اخر هيك فال surface area زالت كتير
+
+292
+00:23:32,360 --> 00:23:35,540
+ليش ال surface area بدي هتكون كبيرة؟ جال عشان هذا
+
+293
+00:23:35,540 --> 00:23:38,940
+التفاعل اللي يحصل بسرعة لأن هذا التفاعل عادة بطيئ
+
+294
+00:23:38,940 --> 00:23:42,500
+و بده catalyst يعني بطيئ بده catalyst فانا بد ال
+
+295
+00:23:42,500 --> 00:23:46,780
+surface area تكون اكبيرة فعند platinum wire في
+
+296
+00:23:46,780 --> 00:23:50,200
+اخره platinumized platinum electrode بعدي منها
+
+297
+00:23:50,200 --> 00:23:54,360
+انhydrogenواحد atmosphere pressure تبعه على محلول
+
+298
+00:23:54,360 --> 00:24:00,020
+HCl الـH plus في واحد molar وعند حرارة 25 درجة لو
+
+299
+00:24:00,020 --> 00:24:06,580
+استخدمت هذا الشكل جداش بيكون ال E note له سفر ليش
+
+300
+00:24:06,580 --> 00:24:10,920
+قولت note؟ note يعني standard standard ايش يعني
+
+301
+00:24:10,920 --> 00:24:14,180
+standard؟ يعني قد standard state ال standard state
+
+302
+00:24:14,180 --> 00:24:20,250
+هي اللي ذكرتهاحرارة 25 درجة مئوية او Celsius اه
+
+303
+00:24:20,250 --> 00:24:25,210
+واحد atmosphere واحد molar اي شيء لو في عندي اكتر
+
+304
+00:24:25,210 --> 00:24:28,930
+.. لأي .. لأي electrode اكتر من نوع من المحاليل
+
+305
+00:24:28,930 --> 00:24:32,230
+دائما كل المحاليل واحد molar بدها تكون كلها
+
+306
+00:24:32,230 --> 00:24:36,390
+الحرارة دائما 25 اذا كان في عندي غاز دائما واحد
+
+307
+00:24:36,390 --> 00:24:43,460
+atmosphereطيب يا شباب لو إجينا نطلعنا على تعيين
+
+308
+00:24:43,460 --> 00:24:48,540
+كشي عملي نطلع عليه تعيين ال potential لاتفاعل اللي
+
+309
+00:24:48,540 --> 00:24:52,160
+جدامك cover 2 plus زائد 2 electron بيعطيني cover
+
+310
+00:24:52,160 --> 00:24:56,940
+solid بدي أعين ال potential تبعه بقول والله بحط هو
+
+311
+00:24:56,940 --> 00:25:04,340
+في مكان و بحط ال ال SHE في المكان الآخر في الخلية
+
+312
+00:25:04,340 --> 00:25:07,920
+و بعدين بوصل الاتنين و بشوف فرق الجهد معايا ولا لا
+
+313
+00:25:08,790 --> 00:25:13,590
+طيب نيجي نتطلع في البداية هاي ال cover هذا solid
+
+314
+00:25:13,590 --> 00:25:17,930
+وهيه جزء من ايه؟ من ال reaction هذا هو ال
+
+315
+00:25:17,930 --> 00:25:22,470
+electrode cover solid مغموط المخلوق cover 2 plus
+
+316
+00:25:22,470 --> 00:25:25,830
+وليه يكون مثلا cover صلفية مدوب في الميه لكن قداش
+
+317
+00:25:25,830 --> 00:25:30,650
+تركيز ال cover 2 plus؟ لازم يكون واحد molar لازم
+
+318
+00:25:30,650 --> 00:25:35,730
+يكون واحد molar كويس؟ و الحرارة 25 درجة salt
+
+319
+00:25:35,730 --> 00:25:42,480
+bridge من ال KCL مثلاSalt Bridge موجود فيها KCL
+
+320
+00:25:42,480 --> 00:25:49,900
+هاي ال SHE هاي ال SHE ايش اتفاعل اللي بيحصل هان في
+
+321
+00:25:49,900 --> 00:25:56,140
+البداية بدي اقولكم هالشغلها ال E note للسل بتساوي
+
+322
+00:25:56,140 --> 00:26:05,140
+E note للكثود minus ال E note للانود او ال E note
+
+323
+00:26:05,140 --> 00:26:09,720
+للسل بتساوي E note right
+
+324
+00:26:15,170 --> 00:26:17,410
+الخلية فرق الجوهات ايش اللي بيجيسه ال cathode
+
+325
+00:26:17,410 --> 00:26:22,520
+minus الانونكويس؟ لكن في عندي convention استلاح
+
+326
+00:26:22,520 --> 00:26:27,460
+انه دائما الكثود عاليمين و دائما القانود عاليسار
+
+327
+00:26:27,460 --> 00:26:31,900
+عشان هيك بقول القطب الأيمن الجهد طبعا ناقص جهد
+
+328
+00:26:31,900 --> 00:26:35,560
+القطب الأيسر هي فرق الجهود يبقى القطب الأيمن دائما
+
+329
+00:26:35,560 --> 00:26:40,820
+ايه؟ كثود القطب الأيسر دائما ايه؟ قانود طيب بنجي
+
+330
+00:26:40,820 --> 00:26:45,160
+بنقول هاي ال SHA ايش اللي بيحصل فيه؟ اللي بيحصل
+
+331
+00:26:45,160 --> 00:26:50,750
+انهالـ H2 بتتحول لـ 2H بلس زائد 2 إلكترون يعني هن
+
+332
+00:26:50,750 --> 00:26:56,370
+هي الـ H عدة هن بالظبط الـ H2 لزج في هذا الإلكترون
+
+333
+00:26:56,370 --> 00:27:05,970
+و اتحول لـ H بلس أو 2H بلس زائد 2 إلكترون
+
+334
+00:27:05,970 --> 00:27:11,230
+الإلكترونيات بتعديش في المحلول الإلكترونيات بتنتقل
+
+335
+00:27:11,230 --> 00:27:15,810
+في السيليكاي لـ 2 إلكترونالاتنين الالكترون بتتوجه
+
+336
+00:27:15,810 --> 00:27:20,970
+ناحية القطب الموجب وبهيك صار في عندي فرق جهود عامة
+
+337
+00:27:20,970 --> 00:27:25,390
+اللي هيتحرك ال ايه المؤشر تبع ال voltmeter الاتنين
+
+338
+00:27:25,390 --> 00:27:28,390
+الالكترون بتنزل هي في ال cover ال cover solid ما
+
+339
+00:27:28,390 --> 00:27:35,370
+هو مش هيك في عندي cover two plus على السطح هيه
+
+340
+00:27:35,370 --> 00:27:40,130
+بياخد ال two electrons واش بتتحول ل cover solid
+
+341
+00:27:40,130 --> 00:27:45,550
+معاياالـ Cover 2 Plus اللي في المحلول أخد الاتنين
+
+342
+00:27:45,550 --> 00:27:51,650
+الالكترون هدول و وين اترسم على سطح الالكترون هاي
+
+343
+00:27:51,650 --> 00:27:56,510
+التفاعل اللي بيتم لكن يا شباب طول ما الـ H Plus
+
+344
+00:27:56,510 --> 00:28:01,710
+بيتكون هان يبجى هذا المحلول عمال بيصير فيه H Plus
+
+345
+00:28:01,710 --> 00:28:07,830
+زيادة عمال الـ H Plus بزيد مش هيك ولا لأ؟ بينفعش
+
+346
+00:28:07,830 --> 00:28:12,960
+الـ H Plus يزداد هدم يصير محلول موجبفهان بيتطر الـ
+
+347
+00:28:12,960 --> 00:28:18,040
+C الـ minus ييجي من ال salt bridge وهي فيدتها بحيث
+
+348
+00:28:18,040 --> 00:28:23,700
+انه يعادل يعادل ال H plus اللي طلعت عشان دائما
+
+349
+00:28:23,700 --> 00:28:29,740
+الشحنات الموجة بتساوي الشحنات السالية بقى نهاية و
+
+350
+00:28:29,740 --> 00:28:34,500
+نفس الكلام هان هان عامل ال cover two plus بترسم
+
+351
+00:28:34,500 --> 00:28:39,340
+ايش بيسيب نحله صلفات لحالها minus عشان هيك ال
+
+352
+00:28:39,340 --> 00:28:45,200
+potassiumبينزل في هذا الاتجاه علشان برضه يعادل
+
+353
+00:28:45,200 --> 00:28:52,440
+الشحنات السالبة اللي تكونت ماشي المهم انه الان هي
+
+354
+00:28:52,440 --> 00:28:56,500
+اللي بيحصل حقيقة في ال cell الان ال voltmeter ايش
+
+355
+00:28:56,500 --> 00:29:00,860
+بيعطيني فرق جهد ال cathode minus ال anode يعطاني
+
+356
+00:29:00,860 --> 00:29:04,720
+point three four بما ان ال cathode صفر ال anode
+
+357
+00:29:04,720 --> 00:29:11,560
+صفر وهد point three four two بتساوي ال E naught
+
+358
+00:29:12,150 --> 00:29:17,170
+للكاثود ماينس صفر صفر طبعا راحت يبقى ال E note
+
+359
+00:29:17,170 --> 00:29:21,290
+للكاثود اللي هو هيه يعني هذا التفاعل ايش ال E note
+
+360
+00:29:21,290 --> 00:29:27,770
+تبعته بدها تساوي point three four volts هي القراءة
+
+361
+00:29:27,770 --> 00:29:31,630
+اللي اعطاه لي ال voltmeter هي القراءة اللي اعطاه
+
+362
+00:29:31,630 --> 00:29:34,250
+لي ال voltmeter ماشي يا شباب
+
+363
+00:29:37,570 --> 00:29:44,830
+لاحظ انه .. لاحظ انه ال convention تبعي هيو ال
+
+364
+00:29:44,830 --> 00:29:48,910
+cathode موجب والانود سالب والخلية galvanic ..
+
+365
+00:29:48,910 --> 00:29:55,930
+والخلية galvanic لو
+
+366
+00:29:55,930 --> 00:30:05,400
+اجينا .. لو اجينا ل .. مثلا تفاعل ال zincزنك half
+
+367
+00:30:05,400 --> 00:30:09,220
+reaction فبقول زنك زائد 2 إلكترون بيعطينا زنك
+
+368
+00:30:09,220 --> 00:30:16,720
+solid ال a نوت minus 0.762 نشوف الخلية كيف جبناها
+
+369
+00:30:16,720 --> 00:30:25,760
+هذا الكلاملو اجينا حطينا ال .. لو استخدمنا
+
+370
+00:30:25,760 --> 00:30:31,240
+voltmeter بمؤشر وقولنا هذه هي الصفر وهذا هي موجب
+
+371
+00:30:31,240 --> 00:30:38,240
+وهذا هي سالم بنلاحظ انه .. بنلاحظ انه تفاعل الذنكر
+
+372
+00:30:38,240 --> 00:30:41,580
+حاطيني minus point seven six احنا خلينا ناخد
+
+373
+00:30:41,580 --> 00:30:47,260
+التفاعل اللي قدامي هان هاي ال SHE وين حطيناها؟وين
+
+374
+00:30:47,260 --> 00:30:52,380
+حطناها؟ عاليمين إذا هو إيش؟ ال cathode فانا حطناها
+
+375
+00:30:52,380 --> 00:30:56,000
+ع اليسار إذا هو القنود إجينا اطلعنا وجينا هذه
+
+376
+00:30:56,000 --> 00:31:00,620
+point seven six موجب point seven six موجب إيش يعني
+
+377
+00:31:00,620 --> 00:31:05,060
+point six؟ هي point seven six موجب بتساوي E note
+
+378
+00:31:05,060 --> 00:31:10,600
+لل cathode اللي هي بتساوي صفر minus E note للقنود
+
+379
+00:31:11,600 --> 00:31:15,660
+اللي هو إيش ال zinc لإنه ال cathode هيه هو ال SHE
+
+380
+00:31:15,660 --> 00:31:22,060
+هو ال cathode اللي بيساوي الصفر فمعنى .. نعم .. مش
+
+381
+00:31:22,060 --> 00:31:25,540
+احنا فرضنا صفر دائما لإنه standard .. يعني
+
+382
+00:31:25,540 --> 00:31:29,140
+standard hydraulic load اعتبرنا إنه احنا اختياريا
+
+383
+00:31:29,140 --> 00:31:35,120
+اتفقنا كل العالم اتفق على إنه ال electrode
+
+384
+00:31:35,120 --> 00:31:40,040
+potential ال SHE potential كويس صفر at standard
+
+385
+00:31:40,040 --> 00:31:50,660
+stateيبقى ال E note للقنوط minus 0.76 سالبة
+
+386
+00:31:50,660 --> 00:31:59,380
+لأن ال potential
+
+387
+00:31:59,380 --> 00:32:06,410
+بالسالملاحظ انه لو حطينا .. لو جلبنا ال .. اش
+
+388
+00:32:06,410 --> 00:32:09,690
+بيسموه؟ لو جلبنا الخلية حطينا هاد هان و هاد هان
+
+389
+00:32:09,690 --> 00:32:15,030
+هتلاحظ ان هاد صارت بالسالب اه فانت بدك كجلب انكسل
+
+390
+00:32:15,030 --> 00:32:20,890
+نشتغل دائما بدنا ايه هنوجة بقى معناته الكثود بدكون
+
+391
+00:32:20,890 --> 00:32:25,030
+ال potential تبعه اكبر من الانود معايا؟ قلت لو
+
+392
+00:32:25,030 --> 00:32:29,520
+جلبتي هتلاقي هاد صارت سالبماشي لكن بالشكل هذا طبعا
+
+393
+00:32:29,520 --> 00:32:34,860
+هتكون موجبة لأنه ال ال cathode هو عبارة عن ال SHE
+
+394
+00:32:34,860 --> 00:32:42,280
+هتشوف كلام التفصيل اكتر بعد شوية لو اجينا يا شباب
+
+395
+00:32:42,280 --> 00:32:49,250
+لو اجيناجبنا كل ال half reactions اللي بنعرفها كل
+
+396
+00:32:49,250 --> 00:32:53,750
+ال half reactions اللي بنعرفها و إجينا مثلا حطينا
+
+397
+00:32:53,750 --> 00:32:59,130
+ال SHE و معاه ال half reaction تبعي اللي أنا بدي
+
+398
+00:32:59,130 --> 00:33:03,870
+أحسبله ال potential كويس بقدر أحسب ال potential أو
+
+399
+00:33:03,870 --> 00:33:06,490
+ال standard electrode potential لكل ال half
+
+400
+00:33:06,490 --> 00:33:13,050
+reactions لكل ال half reactions و راح ألاحظراح
+
+401
+00:33:13,050 --> 00:33:20,670
+ألاحظ أنه يمكن بناء جدول كالتالي مثلا H2O2, 2H+, 2
+
+402
+00:33:20,670 --> 00:33:25,650
+إلكترون بيعطينا ميه هذا له potential 1.77 يعني لما
+
+403
+00:33:25,650 --> 00:33:31,290
+أجي أحطه مع ال SHE رح يعطيني 1.77
+
+404
+00:33:39,090 --> 00:33:45,310
+هذا platinum electrode وهذا H2O2 وH plus كل واحدة
+
+405
+00:33:45,310 --> 00:33:52,650
+منهم واحد molar كويس؟ ليش حطيت platinum electrode؟
+
+406
+00:33:52,650 --> 00:33:57,470
+لأنه انا بدي معدن عشان يوصل لو كان فيه معدن زي ال
+
+407
+00:33:57,470 --> 00:34:00,830
+zinc او لو كان فيه معدن زي ال copper كان حطيته هو
+
+408
+00:34:01,620 --> 00:34:05,960
+معايا لكن في ال reactions دي كتير مافيش معدن زي
+
+409
+00:34:05,960 --> 00:34:10,200
+مثلا ال Sirium 4 وSirium 3 هدول salts زي ال H2O2
+
+410
+00:34:10,200 --> 00:34:14,440
+وH Plus هدول عبارة عن chemicals يعني ماهياش معدن
+
+411
+00:34:14,440 --> 00:34:19,140
+ال permanganate salt ال H Plus chemical المنجانيز
+
+412
+00:34:19,140 --> 00:34:23,520
+ال dioxide ال salts كلها salts فلما نكون في عند ال
+
+413
+00:34:23,520 --> 00:34:29,500
+half reaction مافيش في solid metalبستخدم ايه حاجة
+
+414
+00:34:29,500 --> 00:34:34,400
+موصلة و خاملة في نفس الوقت زي البلاتين وهي ال SHE
+
+415
+00:34:34,400 --> 00:34:38,160
+باجي
+
+416
+00:34:38,160 --> 00:34:45,560
+بشوف فرق الجهود فلما حطيت اول اول half reaction
+
+417
+00:34:45,560 --> 00:34:48,640
+اعطاني one point seven seven جبت ال permanganate
+
+418
+00:34:48,640 --> 00:34:52,380
+واحد molar و ال H plus واحد molar و ال MnO2 برضه
+
+419
+00:34:52,380 --> 00:34:59,680
+واحد molarكويس لجت ال potential 1.695 طب جبت
+
+420
+00:34:59,680 --> 00:35:06,060
+سيريام 4 واحد مولر و سيريام 3 واحد مولر معايا و
+
+421
+00:35:06,060 --> 00:35:10,200
+حطيتهم على ال SHE اعطاني 1.61 مااخد بالك ولا لأ
+
+422
+00:35:10,200 --> 00:35:15,180
+جبت ترمينجانات واحد مولر H plus واحد مولر مانجانيز
+
+423
+00:35:15,180 --> 00:35:22,880
+اتنين واحد مولرجبت ال note لجيتها 1.51 وها كانت
+
+424
+00:35:22,880 --> 00:35:29,360
+لما نعملت كل الجدول طيب جبت ال 2H2 و جبت ال H2 و
+
+425
+00:35:29,360 --> 00:35:33,520
+ال hydroxide ال H2 واحد أتمسفير و ال hydroxide
+
+426
+00:35:33,520 --> 00:35:39,140
+جداش واحد مولار حطيتهم هال في قبلتين راح طاني ..
+
+427
+00:35:39,140 --> 00:35:45,300
+لاحظ انت بالثالثيبقى بالثالث بإيش يعني؟ معناته
+
+428
+00:35:45,300 --> 00:35:49,680
+الـSHE لازم يكون هو الـCathode والتالد الأنوات
+
+429
+00:35:49,680 --> 00:35:58,200
+وكأنه في عندنا حاجتين، في عندنا حاجة فوق
+
+430
+00:35:59,000 --> 00:36:03,860
+الـ SHE فيه يعني standard reception cells أعلى من
+
+431
+00:36:03,860 --> 00:36:08,840
+الـ SHE وفي حاجة أقل من الـ SHE الأعلى من الـ SHE
+
+432
+00:36:08,840 --> 00:36:13,860
+دايما هي الكثود بينما الـ SHE هو الأنود الأقل لازم
+
+433
+00:36:13,860 --> 00:36:21,300
+يكون في شغلنا يعني الـ SHE هو الكثود والأقل منه هو
+
+434
+00:36:21,300 --> 00:36:28,650
+الأنودفبنقدر نبني حاجة زي هيك يعني طلعوا في الكتب
+
+435
+00:36:28,650 --> 00:36:34,330
+بتلاحظوا في عندنا جداول كبيرة جدا لل standard
+
+436
+00:36:34,330 --> 00:36:39,450
+electrode potentials ليش هي standard؟ لأنها مقاسة
+
+437
+00:36:39,450 --> 00:36:44,370
+عند ال standard أو يعني مقاسة عند ال standard
+
+438
+00:36:44,370 --> 00:36:48,290
+state اللي هي واحد molar واحد atmosphere إذا كان
+
+439
+00:36:48,290 --> 00:36:54,420
+في عندنا غاز 25 درجة او 298 Kelvinماشي يا شباب
+
+440
+00:36:54,420 --> 00:37:00,880
+فبنحصل على الشكل اللي قدامي هذالو جينا استخدمنا
+
+441
+00:37:00,880 --> 00:37:04,460
+الشكل المرتب، هدول مرتبين أصلا، لكن هنا في عندي
+
+442
+00:37:04,460 --> 00:37:08,700
+صورة أفضل، لو جينا استخدمنا الشكل المرتب، كيف يعني
+
+443
+00:37:08,700 --> 00:37:14,000
+مرتب؟ يعني حطينا ال standard electrode potential
+
+444
+00:37:14,000 --> 00:37:19,240
+الأعلى فوق والأقل تحت، يعني مرتبين من فوق من
+
+445
+00:37:19,240 --> 00:37:24,020
+الأعلى للأقل للأقل للأقل للأقل للصفر للسالب أقل
+
+446
+00:37:24,020 --> 00:37:28,780
+أقل أقل و هكذا، هذه بنقولها orderedordered
+
+447
+00:37:28,780 --> 00:37:33,500
+standard reduction potentials كويس لما عملناها زي
+
+448
+00:37:33,500 --> 00:37:37,300
+هيك بنستفيد منها كتير بنعرف أنه كل ما طلعنا فوق
+
+449
+00:37:37,300 --> 00:37:41,700
+بتزيد ال oxidizing power يعني هذا better oxidizing
+
+450
+00:37:41,700 --> 00:37:45,520
+agent than هذا و هذا أكتر من هذا oxidizing و هذا
+
+451
+00:37:45,520 --> 00:37:49,480
+أكتر من هذا oxidizing يبقى ال oxidizing power كل
+
+452
+00:37:49,480 --> 00:37:54,120
+ما زادت ال E0 positively كل ما كان ال oxidizing
+
+453
+00:37:54,120 --> 00:38:00,850
+power أعلىطيب، لو نزلنا لتحت، كل ما نزلنا لتحت، ال
+
+454
+00:38:00,850 --> 00:38:05,970
+reducing power بتزيد، يعني ال lithium better
+
+455
+00:38:05,970 --> 00:38:08,690
+reducing power than potassium، و ال potassium
+
+456
+00:38:08,690 --> 00:38:15,790
+better reducing power than cadmium، و هكذا، ماختين
+
+457
+00:38:15,790 --> 00:38:18,350
+بقالنا؟ يبقى ال reducing power بتزيد و احنا نزلنا
+
+458
+00:38:18,350 --> 00:38:24,710
+لتحت، و فوق oxidizingكمان ممكن نستفيد حاجة تانية
+
+459
+00:38:24,710 --> 00:38:30,370
+ممكن نقول انه هي ال E note لاحظوا دائما
+
+460
+00:38:30,370 --> 00:38:37,330
+الإلكترونات وين موجودة؟ وين موجودة؟ على أي جهة؟
+
+461
+00:38:37,330 --> 00:38:40,890
+على الجهة اليسار يعني دائما ال standard electrode
+
+462
+00:38:40,890 --> 00:38:44,690
+potential اللي هي ال E note تكتب تكتب على هيئة
+
+463
+00:38:44,690 --> 00:38:49,740
+ايه؟ reductionيعني لما نعطيك قيمة ال E note ما
+
+464
+00:38:49,740 --> 00:38:56,040
+تفكرش هل هي مثلا Iron 3 زائد إلكترون تعطينا Iron 2
+
+465
+00:38:56,040 --> 00:39:02,800
+أو Iron 2 بتعطيلنا Iron 3 زائد إلكترون، لأ، هذه
+
+466
+00:39:02,800 --> 00:39:08,080
+غلط ال E note بتكون موجودة لإيه؟ لل reduction فقط
+
+467
+00:39:08,080 --> 00:39:11,880
+يعني ال E note بنكتبها على هيئة إيه؟ reduction
+
+468
+00:39:11,880 --> 00:39:16,920
+دائما، يبقى كتابة ال E note دائماreduction يعني
+
+469
+00:39:16,920 --> 00:39:20,320
+هذه القيمة محسوبة للـreduction مش لل oxidation
+
+470
+00:39:20,320 --> 00:39:23,800
+للreduction هذه حاجة الحاجة التانية كمان اللي
+
+471
+00:39:23,800 --> 00:39:27,400
+بنستفيدها من الجدول أو الجداول اللي معانا والله
+
+472
+00:39:27,400 --> 00:39:34,440
+احنا حابين نعرف احنا حابين نعرف هل مثلا لو جينا
+
+473
+00:39:34,440 --> 00:39:40,620
+طلعنا على هدول اتنين احنا حابين نعرف هل ال silver
+
+474
+00:39:40,620 --> 00:39:45,320
+plusبيتفاعل مع ال cover واحد منهم لازم ناقصه عشان
+
+475
+00:39:45,320 --> 00:39:49,300
+يتفاعلوا مش هيك عشان ال electron هذا يكون في هذه
+
+476
+00:39:49,300 --> 00:39:51,840
+الناحية ولما بده يتفاعل ال electron تاني بده يكون
+
+477
+00:39:51,840 --> 00:39:55,320
+في النواتج علشان يروحوا مع بعض لإن المحاصلة
+
+478
+00:39:55,320 --> 00:40:00,240
+النهائية مافيش فيها إلكترونات فبقول هل ال AG plus
+
+479
+00:40:00,240 --> 00:40:05,900
+بتفاعل مع ال cover solid ولا ال cover 2 plus هو
+
+480
+00:40:05,900 --> 00:40:09,080
+اللي بتفاعل مع ال AG solid يعني ال cover 2 plus
+
+481
+00:40:09,080 --> 00:40:14,700
+بتفاعل مع هذا ولا هذا هو اللي بتفاعل مع هذابنقول
+
+482
+00:40:14,700 --> 00:40:18,800
+سهل جدا نوصل لحل إذا كان رتبناهم بالترتيب الأعلى
+
+483
+00:40:18,800 --> 00:40:23,460
+فوق الأعلى E note فوق والأقل تحت هي هم رتبين point
+
+484
+00:40:23,460 --> 00:40:26,880
+seven nine nine point three three nine يعني الأعلى
+
+485
+00:40:26,880 --> 00:40:30,480
+فوق والأقل تحت إذا كان رتبناهم على هيئة reduction
+
+486
+00:40:30,480 --> 00:40:37,710
+اه بعدين بيجي بنعمل خط بشكل هذا diagonalباياجونال
+
+487
+00:40:37,710 --> 00:40:41,830
+بنقول آه هذا هو اللي بيحصل فقط يفجأ ال a g plus
+
+488
+00:40:41,830 --> 00:40:47,530
+زائد cover solid هو اللي راح يعطيني cover اتنين
+
+489
+00:40:47,530 --> 00:40:54,970
+plus زائد a g solid لو بدنا نقزنها يعني يفجأ هذا
+
+490
+00:40:54,970 --> 00:41:01,410
+اللي بيحصل بينما هذا يعطيني a g plus زائد cover
+
+491
+00:41:01,410 --> 00:41:06,860
+solid هذا الكلام بيحصلشيبقى بقدر اعرف ايش التفاعل
+
+492
+00:41:06,860 --> 00:41:12,040
+اللي بيحصل و ايش التفاعل اللي مابيحصلش مجرد اني
+
+493
+00:41:12,040 --> 00:41:16,500
+فقط ارتب ال two half reactions اللي له E note اعلى
+
+494
+00:41:16,500 --> 00:41:21,400
+فوق و اللي له E note اقل تحت و اعمل ال diagonal و
+
+495
+00:41:21,400 --> 00:41:25,600
+برتبهم كقيمة E note معناه كلام التنين يجب كتابتهم
+
+496
+00:41:25,600 --> 00:41:30,160
+على هيئة reductionتكتبش أي إيش على هاية oxidation
+
+497
+00:41:30,160 --> 00:41:34,500
+نهائيًا دائمًا شغلنا reduction عشان هيك إيش اسمها
+
+498
+00:41:34,500 --> 00:41:40,880
+ordered standard reduction potentials reduction
+
+499
+00:41:40,880 --> 00:41:46,880
+دائمًا تكتب على إنها reduction خد اللي جابله لاحظ
+
+500
+00:41:46,880 --> 00:41:50,980
+وين الإلكترونات ده الإلكترونات على اليسار مافيش
+
+501
+00:41:50,980 --> 00:41:53,260
+ولا إلكترون على اليمين دائمًا تكتب reduction
+
+502
+00:41:54,310 --> 00:41:56,950
+Standard Potentials يعني هو ممكن نقول Standard
+
+503
+00:41:56,950 --> 00:42:00,430
+Reduction Potentials لكن اختصارها لأنه معروف ان
+
+504
+00:42:00,430 --> 00:42:04,710
+احنا بنكتبها دائما على هيئة reduction طيب يا شباب
+
+505
+00:42:04,710 --> 00:42:09,690
+بنجف هان اليوم وإذا الله راد الحصة الجاية بنكمل
+
diff --git a/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/P2ufM_zJW7c_raw.srt b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/P2ufM_zJW7c_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..28e1d93937bf77e3abbae94092a9478532901bf8
--- /dev/null
+++ b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/P2ufM_zJW7c_raw.srt
@@ -0,0 +1,2020 @@
+1
+00:00:21,110 --> 00:00:25,230
+بسم الله الرحمن الرحيم اليوم إذا الله راضي بنتكلم
+
+2
+00:00:25,230 --> 00:00:29,930
+عن المحاضرة الأولى في ال chapter الأخير اللي معانا
+
+3
+00:00:29,930 --> 00:00:33,330
+اللي بتكلم عن ال oxidation reduction equilibria و
+
+4
+00:00:33,330 --> 00:00:36,870
+titrations في البداية بنتكلم عن ال oxidation
+
+5
+00:00:36,870 --> 00:00:43,820
+reduction equilibria وبنقول أنهالتفاعلات أنواع،
+
+6
+00:00:43,820 --> 00:00:49,440
+منها تفاعلات acid، acids مع bases، تفاعلات ligands
+
+7
+00:00:49,440 --> 00:00:55,040
+مع metal ions، تفاعلات precipitation ونوع آخر هو
+
+8
+00:00:55,040 --> 00:00:58,640
+تفاعلات الأكسدة والاختزال، تفاعلات الأكسدة
+
+9
+00:00:58,640 --> 00:01:06,900
+والاختزال تتضمنعمليتين متلازمتين عملية أكسدة يتم
+
+10
+00:01:06,900 --> 00:01:14,200
+خلالها فقد إلكترونات وعملية اختزال يتم خلالها
+
+11
+00:01:14,200 --> 00:01:19,640
+اكتساب هذه الإلكترونات اللى فقدت من جانب ال half
+
+12
+00:01:19,640 --> 00:01:24,230
+reaction الأولفعلى سبيل المثال لو طلعنا على
+
+13
+00:01:24,230 --> 00:01:30,070
+التفاعل اللي قدامي Serum 4 موجب مع Iron 2 موجب
+
+14
+00:01:30,070 --> 00:01:35,890
+يعطينا Serum 3 موجب مع Iron 3 موجب لو طلعنا على
+
+15
+00:01:35,890 --> 00:01:41,830
+Serum 4 اتحول لل Serum 3 يعني معنى الكلام اكتسب
+
+16
+00:01:41,830 --> 00:01:47,270
+إلكترون اكتسب إلكترون يعني حصله عملية اختزال بينما
+
+17
+00:01:47,270 --> 00:01:53,520
+ال Iron 2اتحول لل iron تلاتة معنى الكلام ال iron 2
+
+18
+00:01:53,520 --> 00:02:00,060
+فقد إلكترون يبقى معنى الكلام حصل له أكسدا أو ممكن
+
+19
+00:02:00,060 --> 00:02:03,060
+نتطلع على الموضوع بشكل آخر ال oxidation number
+
+20
+00:02:03,060 --> 00:02:07,740
+للثيريوم أربعة موجب أربعة موجب اتحول لثيريوم تلاتة
+
+21
+00:02:07,740 --> 00:02:14,300
+موجب إذا ال oxidation numberلسيريام جال هذا عملية
+
+22
+00:02:14,300 --> 00:02:18,840
+reduction بينما ال iron اتنين اتحول لل iron تلاتة
+
+23
+00:02:18,840 --> 00:02:22,620
+يبقى ال oxidation number اتحول من اتنين لتلاتة اذا
+
+24
+00:02:22,620 --> 00:02:27,400
+ال oxidation number زاد وبالتالي هذا عملية اكسدة
+
+25
+00:02:27,400 --> 00:02:32,540
+فعملية الاكسدة وعملية الاختزال عمليتين متلازمتين
+
+26
+00:02:32,540 --> 00:02:38,130
+بيحصل مع بعض بحيث انهالإلكترونات اللي بيمنحها نصف
+
+27
+00:02:38,130 --> 00:02:44,770
+التفاعل الأول بيستهلكها نصف التفاعل الآخر المحصلة
+
+28
+00:02:44,770 --> 00:02:49,450
+المعادلة النهائية لا يوجد فيها ظهور لأي إلكترون
+
+29
+00:02:51,740 --> 00:02:54,780
+ممكن المعادلة الماضية نجسمها لنصين زي ما احنا
+
+30
+00:02:54,780 --> 00:02:58,060
+شايفين السيريام أربعة بياخد إلكترون هذه عملية
+
+31
+00:02:58,060 --> 00:03:02,100
+reduction الايرون اتنين بيعطيني إلكترون هذه عملية
+
+32
+00:03:02,100 --> 00:03:06,120
+oxidation الآن كيف نتعرف على تفاعلات الأكسدة
+
+33
+00:03:06,120 --> 00:03:13,540
+والاختزال بنقول تفاعل الأكسدة والاختزال يتم خلاله
+
+34
+00:03:13,540 --> 00:03:19,930
+تغير في ال oxidation number لبعض الذراتبعض الذرات
+
+35
+00:03:19,930 --> 00:03:25,150
+في المتفاعلات هي نفسها في النواتج بنلاحظ لو شوفنا
+
+36
+00:03:25,150 --> 00:03:28,730
+ال oxygen number للأولى بنلاحظ انه بيتغير عن ال
+
+37
+00:03:28,730 --> 00:03:33,450
+oxygen number في الثانية او في النواتج فمثلا لو
+
+38
+00:03:33,450 --> 00:03:40,170
+طلعنا على ال potassium واحد موجب ال oxygen اتنين
+
+39
+00:03:40,170 --> 00:03:44,570
+سالب في اربعة يعني تمانية سالب منهم واحد موجب اذا
+
+40
+00:03:44,570 --> 00:03:53,450
+المنجانيز سبعة موجبالـ Oxalic Acid الـ H واحد موجب
+
+41
+00:03:53,450 --> 00:04:00,330
+الـ Oxygen اتنين سالم في اربعة سالم تمانية موجب
+
+42
+00:04:00,330 --> 00:04:06,090
+اتنين اذا الكربون تان ستة موجب يبقى الواحدة تلاتة
+
+43
+00:04:06,090 --> 00:04:11,790
+موجب الاتنين كربون6 موجب يبقى الواحدة تلاتة موجب
+
+44
+00:04:11,790 --> 00:04:18,910
+ال HCl واحد موجب واحد سالب الكلور واحد سالب في
+
+45
+00:04:18,910 --> 00:04:22,910
+اتنين اتنين سالب اذا المنجانيز اتنين موجب ال K
+
+46
+00:04:22,910 --> 00:04:25,930
+واحد موجب ال CL واحد سالب
+
+47
+00:04:29,050 --> 00:04:32,850
+أو ممكن نقول نبدأ بال O2 اتنين سالب في اتنين يبقى
+
+48
+00:04:32,850 --> 00:04:38,350
+اربعة سالب يبقى الكربون اربعة موجب ال H واحد موجب
+
+49
+00:04:38,350 --> 00:04:43,210
+الاكسجين اتنين سالب لو جينا واطلعنا على المانجانيز
+
+50
+00:04:43,210 --> 00:04:49,690
+بنلاحظ انه ال oxidation number تبعه اتغير من موجب
+
+51
+00:04:49,690 --> 00:04:58,200
+سبعة لموجب اتنين اذا اختزل اختزلأما الكربون
+
+52
+00:04:58,200 --> 00:05:05,100
+فبنلاحظ أنه اتغير من نوجة بتلاتة لموجة باربع زاد
+
+53
+00:05:05,100 --> 00:05:10,280
+عملية أكسدة عملية أكسدة فأكيد هذا التفاعل اللي
+
+54
+00:05:10,280 --> 00:05:15,800
+جدامي هو تفاعل أكسدة واختزال لأنه تم خلال التفاعل
+
+55
+00:05:15,800 --> 00:05:19,760
+تغير في ال oxidation numbers
+
+56
+00:05:21,890 --> 00:05:26,690
+واحد او اش يزاد و اش يجل لازم اش يزيد و اش يجل
+
+57
+00:05:26,690 --> 00:05:32,010
+لانه لازم عملية الاكسدة تحصل بالتلازم مع عملية
+
+58
+00:05:32,010 --> 00:05:35,560
+الاختزالاللي هم اتطلعنا عليه مثال اخر مثلا Sodium
+
+59
+00:05:35,560 --> 00:05:40,480
+Carbonate مع 2HCl بيعطينا Sodium Chloride CO2H2O
+
+60
+00:05:40,480 --> 00:05:44,580
+ال Sodium موجب واحد الكربون موجب اربعة ال Oxygen
+
+61
+00:05:44,580 --> 00:05:49,200
+سالب اتنين ال H موجب واحد ال Cl سالب واحد الاخره
+
+62
+00:05:49,200 --> 00:05:53,500
+لو جينا اتطلعنا هل حصل اي تغير في ال oxidation
+
+63
+00:05:53,500 --> 00:05:58,490
+numberلأي عنصر من العناصر لأي ذرّة من الذرّات
+
+64
+00:05:58,490 --> 00:06:02,830
+بنلاحظ لأ نفس ال oxidation numbers اللي موجودة على
+
+65
+00:06:02,830 --> 00:06:06,590
+اليسار هي نفسها نفس ال oxidation numbers لنفس
+
+66
+00:06:06,590 --> 00:06:09,470
+الذرّات اللي موجودة على اليمين مع ذلك لا حصلش أي
+
+67
+00:06:09,470 --> 00:06:13,230
+تغير في ال oxidation number وبالتالي هذا معادل أو
+
+68
+00:06:13,230 --> 00:06:17,370
+هذا تفاعل مش تفاعل أكسيد أو اختزال بالطبع هو تفاعل
+
+69
+00:06:17,370 --> 00:06:24,270
+acid base reactionالان بس بدنا نراجع كيف نوزن
+
+70
+00:06:24,270 --> 00:06:28,110
+المعادلات ال .. ال Redox reaction المعادلة ال
+
+71
+00:06:28,110 --> 00:06:31,890
+Redox المعادلة الأكسدة والاختزال كيف نوزنها؟ لأ
+
+72
+00:06:31,890 --> 00:06:35,170
+معناها ده كلام سنة أولى لكن يعني كلام سريع كتير
+
+73
+00:06:35,170 --> 00:06:43,990
+بنقول أساس وزن المعادلة هو عبارة عن تلت خطواتيعني
+
+74
+00:06:43,990 --> 00:06:47,930
+بسيطة جدا ومفهومة بالنسبالنا أول خطوة نفصل
+
+75
+00:06:47,930 --> 00:06:52,210
+المعادلة لنصين وهذه محاجة سائلة كتير نفصل المعادلة
+
+76
+00:06:52,210 --> 00:06:56,830
+لنصين تاني خطوة كل نص ناخده على حده نعمله mass
+
+77
+00:06:56,830 --> 00:07:02,670
+balanceأه و تالت خطوة ال charge balance خلي عدد
+
+78
+00:07:02,670 --> 00:07:06,410
+الذرات علي اليمين يصيب عدد الذرات علي اليسار و
+
+79
+00:07:06,410 --> 00:07:10,950
+بعدين الشحنات تكون أيضا علي اليمين بتساوي الشحنات
+
+80
+00:07:10,950 --> 00:07:14,770
+علي اليسار و هيك بنكون وزن المعادلة بالذات لما
+
+81
+00:07:14,770 --> 00:07:19,330
+نيجي في الآخر خالص نجمع نصين التفاعل بنلاحظ ان
+
+82
+00:07:19,330 --> 00:07:22,660
+المعادلة اللي عندنا معادلة موزونةفنشوف مثلا
+
+83
+00:07:22,660 --> 00:07:26,640
+المعادلة التالية باي كروميت مع ايرون بيعطينا كروم
+
+84
+00:07:26,640 --> 00:07:30,380
+و ايرون تلاتة بدك سم المعادلة بتدوزنها بدك سمها
+
+85
+00:07:30,380 --> 00:07:34,740
+نصين في البداية فبقول ال ايرون اتنين بتحول ل ايرون
+
+86
+00:07:34,740 --> 00:07:38,340
+تلاتة و باي كروميت بتحول ل كروميام تلاتة فناخد
+
+87
+00:07:38,340 --> 00:07:42,060
+النص الأول ايرون اتنين بتحول ل ايرون تلاتة ايش
+
+88
+00:07:42,060 --> 00:07:45,520
+بقول انا عملت الخطوة لولا فصلتهم لنصين الخطوة
+
+89
+00:07:45,520 --> 00:07:49,690
+التانية mass balanceلازم بالترتيب الخطوة التالتة
+
+90
+00:07:49,690 --> 00:07:52,410
+charge balance فخليني في ال mass balance للنص
+
+91
+00:07:52,410 --> 00:07:57,810
+الأول اكم ذرة iron هان اكم ذرة هان اذا واندي mass
+
+92
+00:07:57,810 --> 00:08:01,870
+balance ابنجي للخطوة الأخيرة اللي هي ال charge
+
+93
+00:08:01,870 --> 00:08:06,410
+balance اكم الشحن اللي هان اتنين موجب الشحن اللي
+
+94
+00:08:06,410 --> 00:08:10,720
+هان ثلاثة موجب كم ده خليهم زي بعضبدي أضع إلكترون
+
+95
+00:08:10,720 --> 00:08:14,440
+على اليمين إذا ايرون اتنين موجة بتعطيني ايرون
+
+96
+00:08:14,440 --> 00:08:16,660
+تلاتة موجة زي الإلكترون طبعا هذه صارت mass
+
+97
+00:08:16,660 --> 00:08:20,700
+balanced with charge balanced يبقى خلاص من النص
+
+98
+00:08:20,700 --> 00:08:25,560
+الأول باجي للنص التاني الداي كروميت بتعطيني
+
+99
+00:08:25,560 --> 00:08:30,380
+كروميام اكم كروميام عندي هان اكم كروميام هان إذا
+
+100
+00:08:30,380 --> 00:08:33,910
+بدي أضرب هان باتنين أخليها اتنين كروميامماشي يا
+
+101
+00:08:33,910 --> 00:08:37,430
+شباب صارت ذرات لي كروم اتنين اتنين باجري ال oxygen
+
+102
+00:08:37,430 --> 00:08:41,730
+هان عندي سبعة oxygen هان اكم oxygen اه؟ بحط سبعة
+
+103
+00:08:41,730 --> 00:08:45,790
+مية سبعة مية طب ماشي صار عندي سبعة oxygen لك صار
+
+104
+00:08:45,790 --> 00:08:50,450
+عندي هان اربع تاشر H فباخدهم وين؟ على اليسار على
+
+105
+00:08:50,450 --> 00:08:54,510
+هيئة H plus يبجى ال H اللي هو حاطيته على هيئة H2O
+
+106
+00:08:55,340 --> 00:08:59,720
+باخده على اليسار على هيئة ايه اتش بلس اربعتاشر اتش
+
+107
+00:08:59,720 --> 00:09:04,340
+بلس الان لو اتيت اتطلعت بلاقي انه اربعتاشر اتش
+
+108
+00:09:04,340 --> 00:09:07,760
+اربعتاشر اتش اتنين كروم اتنين كروم سبعة اكسجين
+
+109
+00:09:07,760 --> 00:09:11,740
+سبعة اكسجين موزونة فهذه الmass balanced موزونة من
+
+110
+00:09:11,740 --> 00:09:16,660
+ناحية ال mass فبنجي نتطلع على charge balance فنقول
+
+111
+00:09:16,660 --> 00:09:21,600
+والله بدنا نعد هاي اربعة عيش موجب اتس اتنين سالب
+
+112
+00:09:21,600 --> 00:09:26,610
+يبقى اتنين عيش موجبطب هان في عندي ستة موجب، إذا
+
+113
+00:09:26,610 --> 00:09:30,650
+كيف بدي أخلي الستة تساوي ليه أطلع عش موجب؟ بدي أحط
+
+114
+00:09:30,650 --> 00:09:34,210
+ستة إلكترونات على هذه الناحية، حطينا ستة إلكترونات
+
+115
+00:09:34,210 --> 00:09:37,430
+على هذه الناحية، يبقى سعر عندي mass balanced
+
+116
+00:09:37,430 --> 00:09:42,190
+equation و أيضا charge balanced equation، هذا النص
+
+117
+00:09:42,190 --> 00:09:47,250
+بجمعه لنص ال iron اللي شفته قبل شوية، لكنالـ Iron
+
+118
+00:09:47,250 --> 00:09:49,930
+كان فيه بس إلكترون واحد و أنا بعرف إن المعادلة
+
+119
+00:09:49,930 --> 00:09:53,410
+النهائية لازم مايكونش فيها أي إلكترون فيجب ضرب
+
+120
+00:09:53,410 --> 00:09:56,690
+المعادلة الأولى ب 6 علشان الإلكترونات هذه تروح
+
+121
+00:09:56,690 --> 00:10:01,230
+ممنوع يظهر أي إلكترون في المعادلة النهائية فبتكون
+
+122
+00:10:01,230 --> 00:10:05,730
+هذه المعادلة المحصلة أو هذا هو وزن المعادلة اللي
+
+123
+00:10:05,730 --> 00:10:09,390
+عندي لو جيت قلعت على المعادلة هذه اللي مكتوبة
+
+124
+00:10:09,390 --> 00:10:14,590
+باللون الأحمر بقول هذه المعادلةبتحصل في ال acid
+
+125
+00:10:14,590 --> 00:10:18,590
+medium في ايه؟ في ال acid medium مرات بقول ليه
+
+126
+00:10:18,590 --> 00:10:22,610
+اوزن المعادلة في ال basic medium في الوسط القاعدى
+
+127
+00:10:22,610 --> 00:10:26,490
+بقول كيف بعمل هذا كلام بعد ما اخلص او قبل ما اخلص
+
+128
+00:10:26,490 --> 00:10:30,070
+خليني اقول بعد ما اخلص هان و اخد مثال بعد شوية قبل
+
+129
+00:10:30,070 --> 00:10:33,270
+ما اخلص ايش بعمل بقول في انديهان اربعة عشر H بلس
+
+130
+00:10:33,270 --> 00:10:35,630
+لا يعقل ان يكون في انديهان H بلس في ال basic
+
+131
+00:10:35,630 --> 00:10:41,590
+medium هذا acid فبدي احط جدهم بالظبط بس بحط ال OH
+
+132
+00:10:41,590 --> 00:10:46,920
+على الناحيتينليه؟ علشان احافظ على ال mass balance
+
+133
+00:10:46,920 --> 00:10:49,980
+تبعي و ال charge balance تبعي ايضا بحط ال
+
+134
+00:10:49,980 --> 00:10:54,100
+hydroxide على ايه؟ على الترفين 14 H plus بقى 14
+
+135
+00:10:54,100 --> 00:10:59,580
+hydroxide هدول ايش بيعطوني؟أربعة عاش مية طب هي في
+
+136
+00:10:59,580 --> 00:11:03,940
+عندي سبعة مية هان هيها راحت وهان بزيد سبعة إذا
+
+137
+00:11:03,940 --> 00:11:07,660
+بتكون المعادلة موزونة هدول راحوا خلاص تعطوني
+
+138
+00:11:07,660 --> 00:11:11,740
+الأربعة عاش مية تم منهم سبعة إذا ستة iron زائد
+
+139
+00:11:11,740 --> 00:11:15,980
+سبعة مية زائد diachromate بيعطينا ستة iron اتنين
+
+140
+00:11:15,980 --> 00:11:19,380
+chromium زائد أربعة عاش hydroxide هذا وزن المعادلة
+
+141
+00:11:19,380 --> 00:11:21,460
+في ال basic solution
+
+142
+00:11:24,140 --> 00:11:29,460
+طيب يا شباب انا بقول ناخد كمان مثال بس لا ايه
+
+143
+00:11:29,460 --> 00:11:33,620
+التذكير بصحى أجزالات زائد بيرمانجانات بتعطينا
+
+144
+00:11:33,620 --> 00:11:38,980
+مانجانيز 4 زائد CO2 أول خطوة نجسبهم لنصين جسلناها
+
+145
+00:11:38,980 --> 00:11:43,620
+لنصين أجزالات بتعطي CO2 بيرمانجانات بتعطي مانجانيز
+
+146
+00:11:43,620 --> 00:11:48,590
+طبعا مش معقول أجزالات بتعطي مانجانيزمش هيك؟ طبيعي
+
+147
+00:11:48,590 --> 00:11:51,950
+يعني فالفيلم الجديد بتاعة المنجانيز ال Oxalية
+
+148
+00:11:51,950 --> 00:11:57,090
+بتاعة ال CO2 بدنا نقول مادام قصلناهم ناخد أول نص
+
+149
+00:11:57,090 --> 00:12:02,130
+هي ال Oxalية هاد اتنين ماكانش هاد اتنين هاد هاد
+
+150
+00:12:02,130 --> 00:12:05,250
+اتنين كربون بده أحط قدره بعيد في اتنين ال Oxygen
+
+151
+00:12:05,250 --> 00:12:08,070
+أربعة و الله يوم أربعة يبقى هاد موزونة من ناحية
+
+152
+00:12:08,070 --> 00:12:12,950
+mass mass balanced بد recharge هاد شحنتين سالبتين
+
+153
+00:12:12,950 --> 00:12:16,130
+اذا بدي أحط هنا اتنين electron على اليمين
+
+154
+00:12:18,890 --> 00:12:23,950
+طيب بنيجي لنص التفاعل الآخر اللي هو ال
+
+155
+00:12:23,950 --> 00:12:27,710
+permanganate بقول مانجانيز أكم ذره واحدة و هان
+
+156
+00:12:27,710 --> 00:12:31,630
+واحدة اذا موزونة الاكسجين اربعة فش ولا واحدة اذا
+
+157
+00:12:31,630 --> 00:12:35,850
+اربعة مية اربعة مية يبقى صار في عندي تمانية H بلس
+
+158
+00:12:35,850 --> 00:12:40,810
+تمانية H بلس على اليسار تمانية H بلس على اليسار
+
+159
+00:12:40,810 --> 00:12:43,630
+يبقى تمانية H بلس زائد permanganate تعطيني
+
+160
+00:12:43,630 --> 00:12:46,610
+مانجانيز اربعة زي اربعة H2O بتطلع عليها بيلاجيها
+
+161
+00:12:46,610 --> 00:12:52,860
+mass balancedموزورة بالنسبة للماس بدي
+
+162
+00:12:52,860 --> 00:12:58,600
+اضمط الشحنات هان تمانية موجب و واحد سالب صار سبعة
+
+163
+00:12:58,600 --> 00:13:04,780
+موجب هان أربعة موجب اذا بدي احط تلت إلكترونات على
+
+164
+00:13:04,780 --> 00:13:10,320
+الجهة اليسار مظبوط يا شبابطيب تلت إلكترونات على
+
+165
+00:13:10,320 --> 00:13:15,180
+الجهة اليسار لو بدي أشتغل in basic medium ممكن أني
+
+166
+00:13:15,180 --> 00:13:18,080
+أجمع المعادلتين و في الآخر أعمل أعمالي اللي عملتها
+
+167
+00:13:18,080 --> 00:13:23,340
+سابقا لكن فيها أنه عند هذه الخطوة أحط تمانية OH
+
+168
+00:13:23,340 --> 00:13:28,840
+سالمعلى الطرفين فبتصير تمانية واتش سالب و تمانية H
+
+169
+00:13:28,840 --> 00:13:34,140
+plus هدول بيعطونا تمانية H2O و بزيد عنا تمانية
+
+170
+00:13:34,140 --> 00:13:36,640
+Hydroxide عن ناحية التانية لاحظ ان في عن ناحية
+
+171
+00:13:36,640 --> 00:13:41,320
+أربعة مية و في عن ناحية تمانية مية طبعا الاربعة
+
+172
+00:13:41,320 --> 00:13:44,320
+بيروحوا مع اربعة منها ان بيبقى عندى اربعة مية على
+
+173
+00:13:44,320 --> 00:13:49,380
+ناحية اليسار باجي
+
+174
+00:13:49,380 --> 00:13:55,260
+باجمعهك حصلت على المعادلاتين بجيب أشبعهم عشان أضيع
+
+175
+00:13:55,260 --> 00:13:58,460
+الإلكترونات هل في عندي two electrons و هل في عندي
+
+176
+00:13:58,460 --> 00:14:01,960
+three electrons كيف الأثنين بيروح مع التلاتة لازم
+
+177
+00:14:01,960 --> 00:14:04,760
+أضرب الأثنين في التلاتة و التلاتة في اتنين فبضرب
+
+178
+00:14:04,760 --> 00:14:06,740
+المعادلة الأولى في تلاتة و المعادلة التانية في
+
+179
+00:14:06,740 --> 00:14:11,380
+اتنين اللي بيعطيني المعادلة المحصلة هك بوزن
+
+180
+00:14:11,380 --> 00:14:17,580
+المعادلات في ال Redox reactionsماشي يا شباب طبعا
+
+181
+00:14:17,580 --> 00:14:24,840
+الكلام مر معنا في سنة أولى بس مجرد تذكير الان نجي
+
+182
+00:14:24,840 --> 00:14:29,300
+نتطلع على ال electrochemical cells هذا الموضوع
+
+183
+00:14:29,300 --> 00:14:33,320
+الأساسي تبعنا ال electrochemical cells الخلايا
+
+184
+00:14:33,320 --> 00:14:38,780
+الكهرو كيميائية أو الكهربية الكهرو كيميائية بنقول
+
+185
+00:14:38,780 --> 00:14:44,970
+ال electrochemical cells نوعينيا اما خلايا بتولد
+
+186
+00:14:44,970 --> 00:14:50,770
+كهربا تعطيني كهربا يعني ايه؟ يعني التفاعل نصين
+
+187
+00:14:50,770 --> 00:14:55,850
+التفاعل بيتفاعلوا مع بعض المتفاعل تتفاعل مع بعض
+
+188
+00:14:55,850 --> 00:15:01,190
+بتعطيني نواتج بشكل تلقاء spontaneous كويس وهك بحصل
+
+189
+00:15:01,190 --> 00:15:05,550
+على فرق جهودبحصل نتيجة فعل بحصل على فرق جهود،
+
+190
+00:15:05,550 --> 00:15:11,310
+نتيجة انتقال الإلكترونات بحصل على تيار، كويس، لما
+
+191
+00:15:11,310 --> 00:15:16,850
+تكون الخلية بتعطيني جهود، بسميها Galvanic cell أو
+
+192
+00:15:16,850 --> 00:15:23,530
+في نوع آخر من الخلايا، المتفاعلات بتعطينيش نواتج،
+
+193
+00:15:23,530 --> 00:15:28,750
+بالعكس النواتج هي اللي بتعطي متفاعلاتفالمتفاعلات
+
+194
+00:15:28,750 --> 00:15:34,750
+مايعطيش نواتج، بنقول هذه الخلية لا يعني ينشأ عنها
+
+195
+00:15:34,750 --> 00:15:39,570
+جهد، بالعكس هي بحاجة إلى جهد علشان التفاعل يحصل،
+
+196
+00:15:39,570 --> 00:15:42,990
+بحاجة إلى جهد علشان التفاعل يحصل، فهذه الخلية
+
+197
+00:15:42,990 --> 00:15:47,060
+بنقولها electrolytic cellsElectrolytic احنا بدنا
+
+198
+00:15:47,060 --> 00:15:50,820
+نحاول نطلع على او ندرس بالتفصيل اللي هو ال
+
+199
+00:15:50,820 --> 00:15:55,100
+Galvanic cells الخلايا الإلكتروليتية طبعا عكسها
+
+200
+00:15:55,100 --> 00:16:01,560
+تماما بنقول اي خلية كهربية تتكون من قطبينقطبين،
+
+201
+00:16:01,560 --> 00:16:07,020
+قطب بنقوله cathode و قطب بنقوله anode إيش هي
+
+202
+00:16:07,020 --> 00:16:09,920
+الشحنة اللي على ال cathode أو ال sign اللي بنعتهله
+
+203
+00:16:09,920 --> 00:16:14,300
+هل هي موجبة أو سالبة؟ بنقول هذا الكلام بتوقف على
+
+204
+00:16:14,300 --> 00:16:19,920
+نوع الخلية، هل هي galvanic أو electrolytic فهذا
+
+205
+00:16:19,920 --> 00:16:23,620
+عبارة عن sign إله convention معين، إله يعني إصطلاح
+
+206
+00:16:23,620 --> 00:16:27,080
+معين، لكن إحنا في ال galvanic cells بنعتبر ال
+
+207
+00:16:27,080 --> 00:16:32,060
+cathode موجب والanode سالبنعتبر الكاثود موجب
+
+208
+00:16:32,060 --> 00:16:38,080
+والأنود سالب في الـ electrolytic cells عكس هذا
+
+209
+00:16:38,080 --> 00:16:43,940
+الكلام تماما لما جينا اتطلعنا ايش الخلية ال
+
+210
+00:16:43,940 --> 00:16:47,960
+electrochemical cell بنقول هي اظهر عن وعى بيحتوي
+
+211
+00:16:47,960 --> 00:16:51,560
+على two electrodes كل electrode مأمور في المحلول
+
+212
+00:16:51,560 --> 00:16:55,260
+تبعه او في محلول في half reaction معين وهذا في
+
+213
+00:16:55,260 --> 00:17:00,440
+half reaction معينوفي بينهم حاجز الحاجز هذا عبارة
+
+214
+00:17:00,440 --> 00:17:06,880
+عن semi permeable membrane يعني غشاء شبه منفذ او
+
+215
+00:17:06,880 --> 00:17:12,000
+اذا كانوا موجودين فيه محلولين منفصلين فبيكون فيه
+
+216
+00:17:12,000 --> 00:17:18,690
+قنطرة ملحية salt bridge بتوصل بينهملأنه مابينفعش
+
+217
+00:17:18,690 --> 00:17:23,010
+مايكونش فيه عندى حركة للأيونات في هذا الاتجاه و
+
+218
+00:17:23,010 --> 00:17:29,670
+هذا الاتجاه عادة هذا الاتجاه الايود السالب مثلا زى
+
+219
+00:17:29,670 --> 00:17:33,250
+الـC المينوس فهذا الاتجاه الايود الموجب زى
+
+220
+00:17:33,250 --> 00:17:37,070
+البوتاسيوم على سبيل المثال هنشوف ليش هذا الكلام
+
+221
+00:17:37,070 --> 00:17:43,000
+المهم انههذه الخلية لو جئنا وكانت Galvanic لو جئنا
+
+222
+00:17:43,000 --> 00:17:46,640
+وصلنا ال two electrodes اللي هو ال cathode بالأنود
+
+223
+00:17:46,640 --> 00:17:50,540
+وحطينا voltmeter ووصلناها الطرفيا voltmeter بنلاحظ
+
+224
+00:17:50,540 --> 00:17:54,680
+ال voltmeter بيقشر بيعطينا فرق جهد وليكن مثلا ال
+
+225
+00:17:54,680 --> 00:17:59,870
+volt بيسوا point five to one voltهذا ال point 521
+
+226
+00:17:59,870 --> 00:18:03,930
+volt عبارة عن ايه؟ عبارة عن فرق الجهد بين القطبين
+
+227
+00:18:03,930 --> 00:18:10,570
+فرق الجهد بين القطبين يعني فرق الجهد ما بين ال
+
+228
+00:18:10,570 --> 00:18:13,950
+electrode هذا و ال electrode هذا فرق الجهد بينهم
+
+229
+00:18:13,950 --> 00:18:19,450
+عادة فرق الجهد يعني بقدر أجيسه بسهولة بواسطة ال
+
+230
+00:18:19,450 --> 00:18:25,880
+voltmeter بقدر أجيسه بسهولة بواسطة ال voltmeterلكن
+
+231
+00:18:25,880 --> 00:18:30,040
+لو سألنا حالنا سؤال طب إيش فرق جهد الإلكترود هذا
+
+232
+00:18:30,040 --> 00:18:38,000
+لوحده؟ وإيش جهد الإلكترود هذا لوحده؟ فالفرق بينهم
+
+233
+00:18:38,000 --> 00:18:44,600
+معروفلكن يمكن يكون هذا واحده point five to one
+
+234
+00:18:44,600 --> 00:18:49,780
+والتاني مثلا واحد الفرق منهم point five to one او
+
+235
+00:18:49,780 --> 00:18:53,100
+يمكن يكون واحد point five to one والتاني صفر معايا
+
+236
+00:18:53,100 --> 00:18:57,960
+يعني الفرق بينهم اه سهولة بينجاز لكن جهد ال
+
+237
+00:18:57,960 --> 00:19:01,540
+electrode هذا لوحده وجهد ال electrode هذا لوحده هل
+
+238
+00:19:01,540 --> 00:19:06,680
+بقدر اعينهبنقول بدنا طريقة نقدر نعين جهد ال
+
+239
+00:19:06,680 --> 00:19:13,280
+electrode علشان هيك لابد من استخدام حاجة بنقولها
+
+240
+00:19:13,280 --> 00:19:19,430
+standard hydrogen electrodeقطب الهيدروجين القياسي
+
+241
+00:19:19,430 --> 00:19:24,370
+أو برضه بنقوله normal hydrogen electrode SHE يعني
+
+242
+00:19:24,370 --> 00:19:28,130
+standard hydrogen electrode أو NHE يعني normal
+
+243
+00:19:28,130 --> 00:19:32,810
+hydrogen electrode لازم نستخدمه ليش لازم نستخدمه
+
+244
+00:19:32,810 --> 00:19:37,010
+جان لأنه هذا ال electrode اللي أنا بتتكلم عنه
+
+245
+00:19:37,010 --> 00:19:39,970
+هالجيت هذا ال electrode اعطناله
+
+246
+00:19:42,690 --> 00:19:46,890
+بتنشيل اختياري من عنا هذا ال potential هو عبارة عن
+
+247
+00:19:46,890 --> 00:19:50,990
+صفر at standard state صفر at standard state وعند
+
+248
+00:19:50,990 --> 00:19:57,310
+الحالة القياسية بنعطيله potential مقدارها صفر يعني
+
+249
+00:19:57,310 --> 00:20:03,930
+مثلا لو كان هذا هو ال SHEو هان اعطاني point three
+
+250
+00:20:03,930 --> 00:20:08,410
+four two اللي هو فرق الجهود بينهم مادام هذا SHE
+
+251
+00:20:08,410 --> 00:20:14,430
+هذا ال E note تبعته صفر لأنه احنا عاملا بنعرفه و
+
+252
+00:20:14,430 --> 00:20:23,430
+بنقول انه جهد ال electrode صفر لل SHE اذا واضح ان
+
+253
+00:20:23,430 --> 00:20:26,570
+اللي بحصل عليه انا هان هو عبارة عن جهد ال other
+
+254
+00:20:26,570 --> 00:20:32,090
+electrodeلأن الفرق هذا هو عبارة عن هذا بصفر، إذا
+
+255
+00:20:32,090 --> 00:20:37,310
+هذا الفرق هو عبارة عن ال electrode الآخر، مش هيك؟
+
+256
+00:20:37,310 --> 00:20:43,130
+طيب، إذا كان هذا الكلام هالسهولة، إذا والله ممكن
+
+257
+00:20:43,130 --> 00:20:47,570
+أنا أجي أحط ال SHE
+
+258
+00:20:50,440 --> 00:20:55,540
+أستخدمه كقطم واستخدم أي إلكترود أنا بدي أعرف ال
+
+259
+00:20:55,540 --> 00:20:59,680
+potential تبعه، أيش ما كان يكون، فاحطه أتمل فيه
+
+260
+00:20:59,680 --> 00:21:02,500
+الخلية، لأن الخلية قطمين، فواحد منهم ال SHA
+
+261
+00:21:02,500 --> 00:21:05,640
+والتاني هو ال other electrode، فرق الجهد؟ راح
+
+262
+00:21:05,640 --> 00:21:08,340
+يقولي والله يا هدا هو عبارة عن جهد ال other
+
+263
+00:21:08,340 --> 00:21:12,710
+electrodeيبقى هذه شغلة سهلة كثير في البداية لكن
+
+264
+00:21:12,710 --> 00:21:17,950
+قبل ما اروح لهذا الكلام بدأ اقول ايش هو ال S.H.E
+
+265
+00:21:17,950 --> 00:21:21,930
+ايش هو ال S.H.E ايش هو ال standard hydrogen
+
+266
+00:21:21,930 --> 00:21:27,850
+electrode جال هو والله الشكل اللي قدامي هذا فيه
+
+267
+00:21:27,850 --> 00:21:32,250
+عندي inverted tube هذا glass tube فيها فتحة بعدي
+
+268
+00:21:32,250 --> 00:21:37,110
+منها ال hydrogen ال hydrogen بيدخل منهاعند واحد
+
+269
+00:21:37,110 --> 00:21:41,130
+أتمسفير هذه ال standard state تبعتي واحد أتمسفير
+
+270
+00:21:41,130 --> 00:21:45,110
+يعني ال pressure للهيدروجين اللي داخل جداش واحد
+
+271
+00:21:45,110 --> 00:21:52,330
+أتمسفير طيب عندي هذا الكلام موجود في محلول HCl
+
+272
+00:21:52,330 --> 00:21:58,760
+جداش ال H plus لهو 1 مولار الحرارة مظبوطة عند 25
+
+273
+00:21:58,760 --> 00:22:04,800
+درجة او 298 كيلوفر اذا هذه هي الشروط القياسية اللى
+
+274
+00:22:04,800 --> 00:22:08,300
+انا بستخدم ال standard hydrogen electrode عندها
+
+275
+00:22:08,300 --> 00:22:17,720
+عندى 1 اتمسفير لل H2 ال H plus 1 مولار الحرارة 298
+
+276
+00:22:17,720 --> 00:22:25,620
+كيلوفرفي عنده القطب هو عبارة عن platinum wire من
+
+277
+00:22:25,620 --> 00:22:29,620
+البلاتين فيه في آخره platinum electrode Platinized
+
+278
+00:22:29,620 --> 00:22:32,560
+platinum electrode Platinized platinum electrode
+
+279
+00:22:32,560 --> 00:22:35,500
+هذا عبارة عن قطب البلاتين ال surface area تبعته
+
+280
+00:22:35,500 --> 00:22:39,560
+عاليةال surface area تبعته عالية لإيه؟ لأن التفاعل
+
+281
+00:22:39,560 --> 00:22:44,860
+اللي قدامي هذا أو عكسه بدي يحصل بسرعة و أكتشف أحصل
+
+282
+00:22:44,860 --> 00:22:49,960
+بسرعة إذا كان ال surface area عندي كبيرة ف
+
+283
+00:22:49,960 --> 00:22:53,840
+platinumized platinum electrode هذا الجزء اللي هو
+
+284
+00:22:53,840 --> 00:23:00,840
+مربع تقريباهذا عبارة عن platinum electrode يعني هو
+
+285
+00:23:00,840 --> 00:23:07,120
+عبارة عن plate او foil من ال platinum لكن في عليه
+
+286
+00:23:07,120 --> 00:23:10,700
+particles من ال platinum بحيث انه ال surface area
+
+287
+00:23:10,700 --> 00:23:15,040
+تبعته اش تكون كبيرة يعني هاي ال surface وفي عندي
+
+288
+00:23:15,040 --> 00:23:18,540
+بدل ال surface معروف جدش المساحة يعني لكن لو حطيت
+
+289
+00:23:19,590 --> 00:23:23,330
+زي الكورة اللي هي حبة بلاتين شوفوا كده ال surface
+
+290
+00:23:23,330 --> 00:23:28,440
+area زادت طب وكمان حبهاال surface area اه صارت زي
+
+291
+00:23:28,440 --> 00:23:32,360
+هيك معايا الى اخر هيك فال surface area زالت كتير
+
+292
+00:23:32,360 --> 00:23:35,540
+ليش ال surface area بدي هتكون كبيرة؟ جال عشان هذا
+
+293
+00:23:35,540 --> 00:23:38,940
+التفاعل اللي يحصل بسرعة لأن هذا التفاعل عادة بطيئ
+
+294
+00:23:38,940 --> 00:23:42,500
+و بده catalyst يعني بطيئ بده catalyst فانا بد ال
+
+295
+00:23:42,500 --> 00:23:46,780
+surface area تكون اكبيرة فعند platinum wire في
+
+296
+00:23:46,780 --> 00:23:50,200
+اخره platinumized platinum electrode بعدي منها
+
+297
+00:23:50,200 --> 00:23:54,360
+انhydrogenواحد atmosphere pressure تبعه على محلول
+
+298
+00:23:54,360 --> 00:24:00,020
+HCl الـH plus في واحد molar وعند حرارة 25 درجة لو
+
+299
+00:24:00,020 --> 00:24:06,580
+استخدمت هذا الشكل جداش بيكون ال E note له سفر ليش
+
+300
+00:24:06,580 --> 00:24:10,920
+قولت note؟ note يعني standard standard ايش يعني
+
+301
+00:24:10,920 --> 00:24:14,180
+standard؟ يعني قد standard state ال standard state
+
+302
+00:24:14,180 --> 00:24:20,250
+هي اللي ذكرتهاحرارة 25 درجة مئوية او Celsius اه
+
+303
+00:24:20,250 --> 00:24:25,210
+واحد atmosphere واحد molar اي شيء لو في عندي اكتر
+
+304
+00:24:25,210 --> 00:24:28,930
+.. لأي .. لأي electrode اكتر من نوع من المحاليل
+
+305
+00:24:28,930 --> 00:24:32,230
+دائما كل المحاليل واحد molar بدها تكون كلها
+
+306
+00:24:32,230 --> 00:24:36,390
+الحرارة دائما 25 اذا كان في عندي غاز دائما واحد
+
+307
+00:24:36,390 --> 00:24:43,460
+atmosphereطيب يا شباب لو إجينا نطلعنا على تعيين
+
+308
+00:24:43,460 --> 00:24:48,540
+كشي عملي نطلع عليه تعيين ال potential لاتفاعل اللي
+
+309
+00:24:48,540 --> 00:24:52,160
+جدامك cover 2 plus زائد 2 electron بيعطيني cover
+
+310
+00:24:52,160 --> 00:24:56,940
+solid بدي أعين ال potential تبعه بقول والله بحط هو
+
+311
+00:24:56,940 --> 00:25:04,340
+في مكان و بحط ال ال SHE في المكان الآخر في الخلية
+
+312
+00:25:04,340 --> 00:25:07,920
+و بعدين بوصل الاتنين و بشوف فرق الجهد معايا ولا لا
+
+313
+00:25:08,790 --> 00:25:13,590
+طيب نيجي نتطلع في البداية هاي ال cover هذا solid
+
+314
+00:25:13,590 --> 00:25:17,930
+وهيه جزء من ايه؟ من ال reaction هذا هو ال
+
+315
+00:25:17,930 --> 00:25:22,470
+electrode cover solid مغموط المخلوق cover 2 plus
+
+316
+00:25:22,470 --> 00:25:25,830
+وليه يكون مثلا cover صلفية مدوب في الميه لكن قداش
+
+317
+00:25:25,830 --> 00:25:30,650
+تركيز ال cover 2 plus؟ لازم يكون واحد molar لازم
+
+318
+00:25:30,650 --> 00:25:35,730
+يكون واحد molar كويس؟ و الحرارة 25 درجة salt
+
+319
+00:25:35,730 --> 00:25:42,480
+bridge من ال KCL مثلاSalt Bridge موجود فيها KCL
+
+320
+00:25:42,480 --> 00:25:49,900
+هاي ال SHE هاي ال SHE ايش اتفاعل اللي بيحصل هان في
+
+321
+00:25:49,900 --> 00:25:56,140
+البداية بدي اقولكم هالشغلها ال E note للسل بتساوي
+
+322
+00:25:56,140 --> 00:26:05,140
+E note للكثود minus ال E note للانود او ال E note
+
+323
+00:26:05,140 --> 00:26:09,720
+للسل بتساوي E note right
+
+324
+00:26:15,170 --> 00:26:17,410
+الخلية فرق الجوهات ايش اللي بيجيسه ال cathode
+
+325
+00:26:17,410 --> 00:26:22,520
+minus الانونكويس؟ لكن في عندي convention استلاح
+
+326
+00:26:22,520 --> 00:26:27,460
+انه دائما الكثود عاليمين و دائما القانود عاليسار
+
+327
+00:26:27,460 --> 00:26:31,900
+عشان هيك بقول القطب الأيمن الجهد طبعا ناقص جهد
+
+328
+00:26:31,900 --> 00:26:35,560
+القطب الأيسر هي فرق الجهود يبقى القطب الأيمن دائما
+
+329
+00:26:35,560 --> 00:26:40,820
+ايه؟ كثود القطب الأيسر دائما ايه؟ قانود طيب بنجي
+
+330
+00:26:40,820 --> 00:26:45,160
+بنقول هاي ال SHA ايش اللي بيحصل فيه؟ اللي بيحصل
+
+331
+00:26:45,160 --> 00:26:50,750
+انهالـ H2 بتتحول لـ 2H بلس زائد 2 إلكترون يعني هن
+
+332
+00:26:50,750 --> 00:26:56,370
+هي الـ H عدة هن بالظبط الـ H2 لزج في هذا الإلكترون
+
+333
+00:26:56,370 --> 00:27:05,970
+و اتحول لـ H بلس أو 2H بلس زائد 2 إلكترون
+
+334
+00:27:05,970 --> 00:27:11,230
+الإلكترونيات بتعديش في المحلول الإلكترونيات بتنتقل
+
+335
+00:27:11,230 --> 00:27:15,810
+في السيليكاي لـ 2 إلكترونالاتنين الالكترون بتتوجه
+
+336
+00:27:15,810 --> 00:27:20,970
+ناحية القطب الموجب وبهيك صار في عندي فرق جهود عامة
+
+337
+00:27:20,970 --> 00:27:25,390
+اللي هيتحرك ال ايه المؤشر تبع ال voltmeter الاتنين
+
+338
+00:27:25,390 --> 00:27:28,390
+الالكترون بتنزل هي في ال cover ال cover solid ما
+
+339
+00:27:28,390 --> 00:27:35,370
+هو مش هيك في عندي cover two plus على السطح هيه
+
+340
+00:27:35,370 --> 00:27:40,130
+بياخد ال two electrons واش بتتحول ل cover solid
+
+341
+00:27:40,130 --> 00:27:45,550
+معاياالـ Cover 2 Plus اللي في المحلول أخد الاتنين
+
+342
+00:27:45,550 --> 00:27:51,650
+الالكترون هدول و وين اترسم على سطح الالكترون هاي
+
+343
+00:27:51,650 --> 00:27:56,510
+التفاعل اللي بيتم لكن يا شباب طول ما الـ H Plus
+
+344
+00:27:56,510 --> 00:28:01,710
+بيتكون هان يبجى هذا المحلول عمال بيصير فيه H Plus
+
+345
+00:28:01,710 --> 00:28:07,830
+زيادة عمال الـ H Plus بزيد مش هيك ولا لأ؟ بينفعش
+
+346
+00:28:07,830 --> 00:28:12,960
+الـ H Plus يزداد هدم يصير محلول موجبفهان بيتطر الـ
+
+347
+00:28:12,960 --> 00:28:18,040
+C الـ minus ييجي من ال salt bridge وهي فيدتها بحيث
+
+348
+00:28:18,040 --> 00:28:23,700
+انه يعادل يعادل ال H plus اللي طلعت عشان دائما
+
+349
+00:28:23,700 --> 00:28:29,740
+الشحنات الموجة بتساوي الشحنات السالية بقى نهاية و
+
+350
+00:28:29,740 --> 00:28:34,500
+نفس الكلام هان هان عامل ال cover two plus بترسم
+
+351
+00:28:34,500 --> 00:28:39,340
+ايش بيسيب نحله صلفات لحالها minus عشان هيك ال
+
+352
+00:28:39,340 --> 00:28:45,200
+potassiumبينزل في هذا الاتجاه علشان برضه يعادل
+
+353
+00:28:45,200 --> 00:28:52,440
+الشحنات السالبة اللي تكونت ماشي المهم انه الان هي
+
+354
+00:28:52,440 --> 00:28:56,500
+اللي بيحصل حقيقة في ال cell الان ال voltmeter ايش
+
+355
+00:28:56,500 --> 00:29:00,860
+بيعطيني فرق جهد ال cathode minus ال anode يعطاني
+
+356
+00:29:00,860 --> 00:29:04,720
+point three four بما ان ال cathode صفر ال anode
+
+357
+00:29:04,720 --> 00:29:11,560
+صفر وهد point three four two بتساوي ال E naught
+
+358
+00:29:12,150 --> 00:29:17,170
+للكاثود ماينس صفر صفر طبعا راحت يبقى ال E note
+
+359
+00:29:17,170 --> 00:29:21,290
+للكاثود اللي هو هيه يعني هذا التفاعل ايش ال E note
+
+360
+00:29:21,290 --> 00:29:27,770
+تبعته بدها تساوي point three four volts هي القراءة
+
+361
+00:29:27,770 --> 00:29:31,630
+اللي اعطاه لي ال voltmeter هي القراءة اللي اعطاه
+
+362
+00:29:31,630 --> 00:29:34,250
+لي ال voltmeter ماشي يا شباب
+
+363
+00:29:37,570 --> 00:29:44,830
+لاحظ انه .. لاحظ انه ال convention تبعي هيو ال
+
+364
+00:29:44,830 --> 00:29:48,910
+cathode موجب والانود سالب والخلية galvanic ..
+
+365
+00:29:48,910 --> 00:29:55,930
+والخلية galvanic لو
+
+366
+00:29:55,930 --> 00:30:05,400
+اجينا .. لو اجينا ل .. مثلا تفاعل ال zincزنك half
+
+367
+00:30:05,400 --> 00:30:09,220
+reaction فبقول زنك زائد 2 إلكترون بيعطينا زنك
+
+368
+00:30:09,220 --> 00:30:16,720
+solid ال a نوت minus 0.762 نشوف الخلية كيف جبناها
+
+369
+00:30:16,720 --> 00:30:25,760
+هذا الكلاملو اجينا حطينا ال .. لو استخدمنا
+
+370
+00:30:25,760 --> 00:30:31,240
+voltmeter بمؤشر وقولنا هذه هي الصفر وهذا هي موجب
+
+371
+00:30:31,240 --> 00:30:38,240
+وهذا هي سالم بنلاحظ انه .. بنلاحظ انه تفاعل الذنكر
+
+372
+00:30:38,240 --> 00:30:41,580
+حاطيني minus point seven six احنا خلينا ناخد
+
+373
+00:30:41,580 --> 00:30:47,260
+التفاعل اللي قدامي هان هاي ال SHE وين حطيناها؟وين
+
+374
+00:30:47,260 --> 00:30:52,380
+حطناها؟ عاليمين إذا هو إيش؟ ال cathode فانا حطناها
+
+375
+00:30:52,380 --> 00:30:56,000
+ع اليسار إذا هو القنود إجينا اطلعنا وجينا هذه
+
+376
+00:30:56,000 --> 00:31:00,620
+point seven six موجب point seven six موجب إيش يعني
+
+377
+00:31:00,620 --> 00:31:05,060
+point six؟ هي point seven six موجب بتساوي E note
+
+378
+00:31:05,060 --> 00:31:10,600
+لل cathode اللي هي بتساوي صفر minus E note للقنود
+
+379
+00:31:11,600 --> 00:31:15,660
+اللي هو إيش ال zinc لإنه ال cathode هيه هو ال SHE
+
+380
+00:31:15,660 --> 00:31:22,060
+هو ال cathode اللي بيساوي الصفر فمعنى .. نعم .. مش
+
+381
+00:31:22,060 --> 00:31:25,540
+احنا فرضنا صفر دائما لإنه standard .. يعني
+
+382
+00:31:25,540 --> 00:31:29,140
+standard hydraulic load اعتبرنا إنه احنا اختياريا
+
+383
+00:31:29,140 --> 00:31:35,120
+اتفقنا كل العالم اتفق على إنه ال electrode
+
+384
+00:31:35,120 --> 00:31:40,040
+potential ال SHE potential كويس صفر at standard
+
+385
+00:31:40,040 --> 00:31:50,660
+stateيبقى ال E note للقنوط minus 0.76 سالبة
+
+386
+00:31:50,660 --> 00:31:59,380
+لأن ال potential
+
+387
+00:31:59,380 --> 00:32:06,410
+بالسالملاحظ انه لو حطينا .. لو جلبنا ال .. اش
+
+388
+00:32:06,410 --> 00:32:09,690
+بيسموه؟ لو جلبنا الخلية حطينا هاد هان و هاد هان
+
+389
+00:32:09,690 --> 00:32:15,030
+هتلاحظ ان هاد صارت بالسالب اه فانت بدك كجلب انكسل
+
+390
+00:32:15,030 --> 00:32:20,890
+نشتغل دائما بدنا ايه هنوجة بقى معناته الكثود بدكون
+
+391
+00:32:20,890 --> 00:32:25,030
+ال potential تبعه اكبر من الانود معايا؟ قلت لو
+
+392
+00:32:25,030 --> 00:32:29,520
+جلبتي هتلاقي هاد صارت سالبماشي لكن بالشكل هذا طبعا
+
+393
+00:32:29,520 --> 00:32:34,860
+هتكون موجبة لأنه ال ال cathode هو عبارة عن ال SHE
+
+394
+00:32:34,860 --> 00:32:42,280
+هتشوف كلام التفصيل اكتر بعد شوية لو اجينا يا شباب
+
+395
+00:32:42,280 --> 00:32:49,250
+لو اجيناجبنا كل ال half reactions اللي بنعرفها كل
+
+396
+00:32:49,250 --> 00:32:53,750
+ال half reactions اللي بنعرفها و إجينا مثلا حطينا
+
+397
+00:32:53,750 --> 00:32:59,130
+ال SHE و معاه ال half reaction تبعي اللي أنا بدي
+
+398
+00:32:59,130 --> 00:33:03,870
+أحسبله ال potential كويس بقدر أحسب ال potential أو
+
+399
+00:33:03,870 --> 00:33:06,490
+ال standard electrode potential لكل ال half
+
+400
+00:33:06,490 --> 00:33:13,050
+reactions لكل ال half reactions و راح ألاحظراح
+
+401
+00:33:13,050 --> 00:33:20,670
+ألاحظ أنه يمكن بناء جدول كالتالي مثلا H2O2, 2H+, 2
+
+402
+00:33:20,670 --> 00:33:25,650
+إلكترون بيعطينا ميه هذا له potential 1.77 يعني لما
+
+403
+00:33:25,650 --> 00:33:31,290
+أجي أحطه مع ال SHE رح يعطيني 1.77
+
+404
+00:33:39,090 --> 00:33:45,310
+هذا platinum electrode وهذا H2O2 وH plus كل واحدة
+
+405
+00:33:45,310 --> 00:33:52,650
+منهم واحد molar كويس؟ ليش حطيت platinum electrode؟
+
+406
+00:33:52,650 --> 00:33:57,470
+لأنه انا بدي معدن عشان يوصل لو كان فيه معدن زي ال
+
+407
+00:33:57,470 --> 00:34:00,830
+zinc او لو كان فيه معدن زي ال copper كان حطيته هو
+
+408
+00:34:01,620 --> 00:34:05,960
+معايا لكن في ال reactions دي كتير مافيش معدن زي
+
+409
+00:34:05,960 --> 00:34:10,200
+مثلا ال Sirium 4 وSirium 3 هدول salts زي ال H2O2
+
+410
+00:34:10,200 --> 00:34:14,440
+وH Plus هدول عبارة عن chemicals يعني ماهياش معدن
+
+411
+00:34:14,440 --> 00:34:19,140
+ال permanganate salt ال H Plus chemical المنجانيز
+
+412
+00:34:19,140 --> 00:34:23,520
+ال dioxide ال salts كلها salts فلما نكون في عند ال
+
+413
+00:34:23,520 --> 00:34:29,500
+half reaction مافيش في solid metalبستخدم ايه حاجة
+
+414
+00:34:29,500 --> 00:34:34,400
+موصلة و خاملة في نفس الوقت زي البلاتين وهي ال SHE
+
+415
+00:34:34,400 --> 00:34:38,160
+باجي
+
+416
+00:34:38,160 --> 00:34:45,560
+بشوف فرق الجهود فلما حطيت اول اول half reaction
+
+417
+00:34:45,560 --> 00:34:48,640
+اعطاني one point seven seven جبت ال permanganate
+
+418
+00:34:48,640 --> 00:34:52,380
+واحد molar و ال H plus واحد molar و ال MnO2 برضه
+
+419
+00:34:52,380 --> 00:34:59,680
+واحد molarكويس لجت ال potential 1.695 طب جبت
+
+420
+00:34:59,680 --> 00:35:06,060
+سيريام 4 واحد مولر و سيريام 3 واحد مولر معايا و
+
+421
+00:35:06,060 --> 00:35:10,200
+حطيتهم على ال SHE اعطاني 1.61 مااخد بالك ولا لأ
+
+422
+00:35:10,200 --> 00:35:15,180
+جبت ترمينجانات واحد مولر H plus واحد مولر مانجانيز
+
+423
+00:35:15,180 --> 00:35:22,880
+اتنين واحد مولرجبت ال note لجيتها 1.51 وها كانت
+
+424
+00:35:22,880 --> 00:35:29,360
+لما نعملت كل الجدول طيب جبت ال 2H2 و جبت ال H2 و
+
+425
+00:35:29,360 --> 00:35:33,520
+ال hydroxide ال H2 واحد أتمسفير و ال hydroxide
+
+426
+00:35:33,520 --> 00:35:39,140
+جداش واحد مولار حطيتهم هال في قبلتين راح طاني ..
+
+427
+00:35:39,140 --> 00:35:45,300
+لاحظ انت بالثالثيبقى بالثالث بإيش يعني؟ معناته
+
+428
+00:35:45,300 --> 00:35:49,680
+الـSHE لازم يكون هو الـCathode والتالد الأنوات
+
+429
+00:35:49,680 --> 00:35:58,200
+وكأنه في عندنا حاجتين، في عندنا حاجة فوق
+
+430
+00:35:59,000 --> 00:36:03,860
+الـ SHE فيه يعني standard reception cells أعلى من
+
+431
+00:36:03,860 --> 00:36:08,840
+الـ SHE وفي حاجة أقل من الـ SHE الأعلى من الـ SHE
+
+432
+00:36:08,840 --> 00:36:13,860
+دايما هي الكثود بينما الـ SHE هو الأنود الأقل لازم
+
+433
+00:36:13,860 --> 00:36:21,300
+يكون في شغلنا يعني الـ SHE هو الكثود والأقل منه هو
+
+434
+00:36:21,300 --> 00:36:28,650
+الأنودفبنقدر نبني حاجة زي هيك يعني طلعوا في الكتب
+
+435
+00:36:28,650 --> 00:36:34,330
+بتلاحظوا في عندنا جداول كبيرة جدا لل standard
+
+436
+00:36:34,330 --> 00:36:39,450
+electrode potentials ليش هي standard؟ لأنها مقاسة
+
+437
+00:36:39,450 --> 00:36:44,370
+عند ال standard أو يعني مقاسة عند ال standard
+
+438
+00:36:44,370 --> 00:36:48,290
+state اللي هي واحد molar واحد atmosphere إذا كان
+
+439
+00:36:48,290 --> 00:36:54,420
+في عندنا غاز 25 درجة او 298 Kelvinماشي يا شباب
+
+440
+00:36:54,420 --> 00:37:00,880
+فبنحصل على الشكل اللي قدامي هذالو جينا استخدمنا
+
+441
+00:37:00,880 --> 00:37:04,460
+الشكل المرتب، هدول مرتبين أصلا، لكن هنا في عندي
+
+442
+00:37:04,460 --> 00:37:08,700
+صورة أفضل، لو جينا استخدمنا الشكل المرتب، كيف يعني
+
+443
+00:37:08,700 --> 00:37:14,000
+مرتب؟ يعني حطينا ال standard electrode potential
+
+444
+00:37:14,000 --> 00:37:19,240
+الأعلى فوق والأقل تحت، يعني مرتبين من فوق من
+
+445
+00:37:19,240 --> 00:37:24,020
+الأعلى للأقل للأقل للأقل للأقل للصفر للسالب أقل
+
+446
+00:37:24,020 --> 00:37:28,780
+أقل أقل و هكذا، هذه بنقولها orderedordered
+
+447
+00:37:28,780 --> 00:37:33,500
+standard reduction potentials كويس لما عملناها زي
+
+448
+00:37:33,500 --> 00:37:37,300
+هيك بنستفيد منها كتير بنعرف أنه كل ما طلعنا فوق
+
+449
+00:37:37,300 --> 00:37:41,700
+بتزيد ال oxidizing power يعني هذا better oxidizing
+
+450
+00:37:41,700 --> 00:37:45,520
+agent than هذا و هذا أكتر من هذا oxidizing و هذا
+
+451
+00:37:45,520 --> 00:37:49,480
+أكتر من هذا oxidizing يبقى ال oxidizing power كل
+
+452
+00:37:49,480 --> 00:37:54,120
+ما زادت ال E0 positively كل ما كان ال oxidizing
+
+453
+00:37:54,120 --> 00:38:00,850
+power أعلىطيب، لو نزلنا لتحت، كل ما نزلنا لتحت، ال
+
+454
+00:38:00,850 --> 00:38:05,970
+reducing power بتزيد، يعني ال lithium better
+
+455
+00:38:05,970 --> 00:38:08,690
+reducing power than potassium، و ال potassium
+
+456
+00:38:08,690 --> 00:38:15,790
+better reducing power than cadmium، و هكذا، ماختين
+
+457
+00:38:15,790 --> 00:38:18,350
+بقالنا؟ يبقى ال reducing power بتزيد و احنا نزلنا
+
+458
+00:38:18,350 --> 00:38:24,710
+لتحت، و فوق oxidizingكمان ممكن نستفيد حاجة تانية
+
+459
+00:38:24,710 --> 00:38:30,370
+ممكن نقول انه هي ال E note لاحظوا دائما
+
+460
+00:38:30,370 --> 00:38:37,330
+الإلكترونات وين موجودة؟ وين موجودة؟ على أي جهة؟
+
+461
+00:38:37,330 --> 00:38:40,890
+على الجهة اليسار يعني دائما ال standard electrode
+
+462
+00:38:40,890 --> 00:38:44,690
+potential اللي هي ال E note تكتب تكتب على هيئة
+
+463
+00:38:44,690 --> 00:38:49,740
+ايه؟ reductionيعني لما نعطيك قيمة ال E note ما
+
+464
+00:38:49,740 --> 00:38:56,040
+تفكرش هل هي مثلا Iron 3 زائد إلكترون تعطينا Iron 2
+
+465
+00:38:56,040 --> 00:39:02,800
+أو Iron 2 بتعطيلنا Iron 3 زائد إلكترون، لأ، هذه
+
+466
+00:39:02,800 --> 00:39:08,080
+غلط ال E note بتكون موجودة لإيه؟ لل reduction فقط
+
+467
+00:39:08,080 --> 00:39:11,880
+يعني ال E note بنكتبها على هيئة إيه؟ reduction
+
+468
+00:39:11,880 --> 00:39:16,920
+دائما، يبقى كتابة ال E note دائماreduction يعني
+
+469
+00:39:16,920 --> 00:39:20,320
+هذه القيمة محسوبة للـreduction مش لل oxidation
+
+470
+00:39:20,320 --> 00:39:23,800
+للreduction هذه حاجة الحاجة التانية كمان اللي
+
+471
+00:39:23,800 --> 00:39:27,400
+بنستفيدها من الجدول أو الجداول اللي معانا والله
+
+472
+00:39:27,400 --> 00:39:34,440
+احنا حابين نعرف احنا حابين نعرف هل مثلا لو جينا
+
+473
+00:39:34,440 --> 00:39:40,620
+طلعنا على هدول اتنين احنا حابين نعرف هل ال silver
+
+474
+00:39:40,620 --> 00:39:45,320
+plusبيتفاعل مع ال cover واحد منهم لازم ناقصه عشان
+
+475
+00:39:45,320 --> 00:39:49,300
+يتفاعلوا مش هيك عشان ال electron هذا يكون في هذه
+
+476
+00:39:49,300 --> 00:39:51,840
+الناحية ولما بده يتفاعل ال electron تاني بده يكون
+
+477
+00:39:51,840 --> 00:39:55,320
+في النواتج علشان يروحوا مع بعض لإن المحاصلة
+
+478
+00:39:55,320 --> 00:40:00,240
+النهائية مافيش فيها إلكترونات فبقول هل ال AG plus
+
+479
+00:40:00,240 --> 00:40:05,900
+بتفاعل مع ال cover solid ولا ال cover 2 plus هو
+
+480
+00:40:05,900 --> 00:40:09,080
+اللي بتفاعل مع ال AG solid يعني ال cover 2 plus
+
+481
+00:40:09,080 --> 00:40:14,700
+بتفاعل مع هذا ولا هذا هو اللي بتفاعل مع هذابنقول
+
+482
+00:40:14,700 --> 00:40:18,800
+سهل جدا نوصل لحل إذا كان رتبناهم بالترتيب الأعلى
+
+483
+00:40:18,800 --> 00:40:23,460
+فوق الأعلى E note فوق والأقل تحت هي هم رتبين point
+
+484
+00:40:23,460 --> 00:40:26,880
+seven nine nine point three three nine يعني الأعلى
+
+485
+00:40:26,880 --> 00:40:30,480
+فوق والأقل تحت إذا كان رتبناهم على هيئة reduction
+
+486
+00:40:30,480 --> 00:40:37,710
+اه بعدين بيجي بنعمل خط بشكل هذا diagonalباياجونال
+
+487
+00:40:37,710 --> 00:40:41,830
+بنقول آه هذا هو اللي بيحصل فقط يفجأ ال a g plus
+
+488
+00:40:41,830 --> 00:40:47,530
+زائد cover solid هو اللي راح يعطيني cover اتنين
+
+489
+00:40:47,530 --> 00:40:54,970
+plus زائد a g solid لو بدنا نقزنها يعني يفجأ هذا
+
+490
+00:40:54,970 --> 00:41:01,410
+اللي بيحصل بينما هذا يعطيني a g plus زائد cover
+
+491
+00:41:01,410 --> 00:41:06,860
+solid هذا الكلام بيحصلشيبقى بقدر اعرف ايش التفاعل
+
+492
+00:41:06,860 --> 00:41:12,040
+اللي بيحصل و ايش التفاعل اللي مابيحصلش مجرد اني
+
+493
+00:41:12,040 --> 00:41:16,500
+فقط ارتب ال two half reactions اللي له E note اعلى
+
+494
+00:41:16,500 --> 00:41:21,400
+فوق و اللي له E note اقل تحت و اعمل ال diagonal و
+
+495
+00:41:21,400 --> 00:41:25,600
+برتبهم كقيمة E note معناه كلام التنين يجب كتابتهم
+
+496
+00:41:25,600 --> 00:41:30,160
+على هيئة reductionتكتبش أي إيش على هاية oxidation
+
+497
+00:41:30,160 --> 00:41:34,500
+نهائيًا دائمًا شغلنا reduction عشان هيك إيش اسمها
+
+498
+00:41:34,500 --> 00:41:40,880
+ordered standard reduction potentials reduction
+
+499
+00:41:40,880 --> 00:41:46,880
+دائمًا تكتب على إنها reduction خد اللي جابله لاحظ
+
+500
+00:41:46,880 --> 00:41:50,980
+وين الإلكترونات ده الإلكترونات على اليسار مافيش
+
+501
+00:41:50,980 --> 00:41:53,260
+ولا إلكترون على اليمين دائمًا تكتب reduction
+
+502
+00:41:54,310 --> 00:41:56,950
+Standard Potentials يعني هو ممكن نقول Standard
+
+503
+00:41:56,950 --> 00:42:00,430
+Reduction Potentials لكن اختصارها لأنه معروف ان
+
+504
+00:42:00,430 --> 00:42:04,710
+احنا بنكتبها دائما على هيئة reduction طيب يا شباب
+
+505
+00:42:04,710 --> 00:42:09,690
+بنجف هان اليوم وإذا الله راد الحصة الجاية بنكمل
+
diff --git a/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/T0tFyL2b7X0_raw.json b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/T0tFyL2b7X0_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..045951226faf0dd330dd8d89aa700cce17126b42
--- /dev/null
+++ b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/T0tFyL2b7X0_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 4818, "start": 21.02, "end": 48.18, "text": "بسم الله الرحمن الرحيم اليوم ان شاء الله بنكمل في ال complexometric reactions و titrations بنتكلم شكل أساسي عن ال complexometric indicators و بعدين بناخد بعض الأمثلة الحسابية تطبيق على الكلام اللي كنا درسنا في الحصة الماضية ال complexometric indicators في الحقيقة يعني يمكن تكون من مشاكل ال complexometric titrations", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640, 45595, 20498, 16472, 13412, 16606, 21984, 44945, 24793, 1211, 8978, 2423, 3997, 29470, 12215, 4032, 3459, 12154, 44945, 2655, 4117, 19528, 13412, 28820, 5551, 3794, 32277, 1829, 18871, 2423, 3997, 29470, 22176, 4032, 39182, 9957, 44945, 47283, 3215, 45030, 11242, 16247, 2304, 12984, 37977, 21542, 3794, 16758, 10632, 6055, 9566, 21292, 4587, 15844, 2423, 28820, 10943, 13672, 1829, 9122, 8315, 11778, 2288, 3794, 8315, 8978, 21542, 9381, 3660, 9673, 46958, 10632, 2423, 3997, 29470, 22176, 8978, 21542, 38436, 28671, 37495, 22653, 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"word": " إذا", "probability": 0.823974609375}, {"start": 673.09, "end": 673.55, "word": " التفاعل", "probability": 0.8702392578125}, {"start": 673.55, "end": 673.93, "word": " slow", "probability": 0.86962890625}, {"start": 673.93, "end": 674.93, "word": " الحل", "probability": 0.947265625}, {"start": 674.93, "end": 675.65, "word": " الأقرب", "probability": 0.9734700520833334}, {"start": 675.65, "end": 677.49, "word": " إلي", "probability": 0.78271484375}, {"start": 677.49, "end": 678.05, "word": " إن", "probability": 0.38330078125}, {"start": 678.05, "end": 678.61, "word": " أشتغل", "probability": 0.91279296875}, {"start": 678.61, "end": 678.83, "word": " back", "probability": 0.86669921875}, {"start": 678.83, "end": 679.47, "word": " titration", "probability": 0.817138671875}], "temperature": 1.0}, {"id": 31, "seek": 70095, "start": 680.55, "end": 700.95, "text": "ليه؟ لأن ال slow reaction في معظم الأحيان بيكون السبب اللي بيأد لإنه التفاعل بطيق هو تركيز المتفاعلات أنا بضيف نقطة من ال EDTA على ال metal ion النقطة هذه لما تتوزع على الحجم كيف بيكون تركيزها؟", "tokens": [20292, 3224, 22807, 5296, 33456, 2423, 2964, 5480, 8978, 20449, 19913, 2304, 16247, 5016, 1829, 7649, 4724, 1829, 30544, 21136, 3555, 3555, 13672, 1829, 4724, 1829, 10721, 3215, 5296, 28814, 1863, 3224, 16712, 5172, 995, 30241, 4724, 9566, 1829, 4587, 31439, 6055, 31747, 1829, 11622, 9673, 2655, 5172, 995, 30241, 9307, 41850, 4724, 11242, 33911, 8717, 47432, 3660, 9154, 2423, 18050, 8241, 15844, 2423, 5760, 17437, 28239, 47432, 3660, 29538, 5296, 15042, 6055, 2655, 2407, 11622, 3615, 15844, 21542, 7435, 2304, 9122, 33911, 4724, 1829, 30544, 6055, 31747, 1829, 11622, 11296, 22807], "avg_logprob": -0.1533938165633909, "compression_ratio": 1.5673076923076923, "no_speech_prob": 1.1920928955078125e-07, "words": [{"start": 680.55, "end": 681.11, "word": "ليه؟", "probability": 0.8310546875}, {"start": 681.11, "end": 681.55, "word": " لأن", "probability": 0.882080078125}, {"start": 681.55, "end": 682.47, 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metal EDTA complex و بزيد EDTA ال EDTA لزيادة ببدأ اعيرها", "tokens": [3555, 16254, 1975, 11242, 33911, 9310, 18050, 8241, 2423, 9310, 18050, 8241, 13672, 1829, 1975, 8315, 4724, 11242, 33911, 11296, 8032, 2655, 2655, 5172, 995, 30241, 20449, 28242, 2423, 5760, 17437, 13672, 1829, 3714, 29245, 23328, 4032, 39896, 11622, 25708, 18050, 8241, 8032, 2655, 2655, 5172, 995, 30241, 20449, 28242, 2423, 5760, 17437, 37037, 1829, 3224, 4724, 9566, 1211, 3615, 18871, 16254, 5760, 18050, 8241, 3997, 4032, 4724, 11622, 25708, 18050, 8241, 2423, 18050, 8241, 5296, 11622, 1829, 18513, 3660, 4724, 44510, 10721, 1975, 3615, 13546, 11296], "avg_logprob": -0.190696023743261, "compression_ratio": 1.7241379310344827, "no_speech_prob": 0.0, "words": [{"start": 726.35, "end": 726.71, "word": "بدي", "probability": 0.38446044921875}, {"start": 726.71, "end": 727.25, "word": " اضيف", "probability": 0.86572265625}, {"start": 727.25, "end": 728.31, "word": " excess", "probability": 0.66796875}, {"start": 728.31, 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فالمجنيزيام", "probability": 0.8281947544642857}, {"start": 761.52, "end": 762.26, "word": " عادة", "probability": 0.9801432291666666}, {"start": 762.26, "end": 763.34, "word": " نستخدمه", "probability": 0.93037109375}, {"start": 763.34, "end": 763.64, "word": " بشكل", "probability": 0.9431966145833334}, {"start": 763.64, "end": 764.08, "word": " كبير", "probability": 0.9959309895833334}, {"start": 764.08, "end": 764.96, "word": " المجنيزيام", "probability": 0.9603678385416666}, {"start": 764.96, "end": 765.48, "word": " بيبدأ", "probability": 0.8984375}, {"start": 765.48, "end": 766.1, "word": " يعاير", "probability": 0.7814127604166666}, {"start": 766.1, "end": 766.86, "word": " الزيادة", "probability": 0.944140625}, {"start": 766.86, "end": 767.0, "word": " من", "probability": 0.984375}, {"start": 767.0, "end": 767.18, "word": " الـ", "probability": 0.815185546875}, {"start": 767.18, "end": 767.84, "word": " EDTA", "probability": 0.82275390625}, {"start": 767.84, "end": 768.82, "word": " خلصت", "probability": 0.965576171875}, {"start": 768.82, "end": 769.28, "word": " الزيادة", "probability": 0.97734375}, {"start": 769.28, "end": 769.42, "word": " من", "probability": 0.99267578125}, {"start": 769.42, "end": 769.58, "word": " الـ", "probability": 0.782958984375}, {"start": 769.58, "end": 770.32, "word": " EDTA", "probability": 0.917724609375}, {"start": 770.32, "end": 772.1, "word": " أول", "probability": 0.903564453125}, {"start": 772.1, "end": 772.58, "word": " نقطة", "probability": 0.99365234375}, {"start": 772.58, "end": 772.76, "word": " من", "probability": 0.9873046875}, {"start": 772.76, "end": 773.68, "word": " المجنيزيام", "probability": 0.9838053385416666}, {"start": 773.68, "end": 774.94, "word": " بتتفاعل", "probability": 0.93974609375}, {"start": 774.94, "end": 775.3, "word": " مع", "probability": 0.99169921875}], "temperature": 1.0}, {"id": 35, "seek": 80770, "start": 784.82, "end": 807.7, "text": "بتعطينا magnesium I N سالب هذا طبعا كان color one هذا صار color two ماشي يا شباب هذا بسهولة و هيك بكون اتغلبت على ال slow reaction", "tokens": [3555, 2655, 3615, 9566, 1829, 8315, 32950, 286, 426, 8608, 6027, 3555, 23758, 23032, 3555, 3615, 995, 25961, 2017, 472, 23758, 20328, 9640, 2017, 732, 3714, 33599, 1829, 35186, 13412, 3555, 16758, 23758, 4724, 3794, 3224, 12610, 3660, 4032, 39896, 4117, 4724, 30544, 1975, 2655, 17082, 46152, 2655, 15844, 2423, 2964, 5480], "avg_logprob": -0.262234683306712, "compression_ratio": 1.308724832214765, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 784.82, "end": 785.6, "word": "بتعطينا", "probability": 0.8014322916666666}, {"start": 785.6, "end": 786.18, "word": " magnesium", "probability": 0.329345703125}, {"start": 786.18, "end": 788.76, "word": " I", "probability": 0.210693359375}, {"start": 788.76, "end": 789.1, "word": " N", "probability": 0.44189453125}, {"start": 789.1, "end": 789.68, "word": " سالب", "probability": 0.8575846354166666}, {"start": 789.68, "end": 790.0, 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سالب color 2 كمان مرة بقول edta بتتفعل مع ال metal ion خلص ال metal ion", "tokens": [3224, 15730, 25961, 43242, 7578, 2017, 502, 7251, 3555, 7435, 7578, 8032, 7649, 8032, 36081, 5016, 12610, 43242, 7578, 294, 6055, 1211, 9307, 3660, 8608, 6027, 3555, 2017, 568, 9122, 2304, 7649, 3714, 25720, 4724, 39648, 1257, 1328, 39894, 2655, 5172, 30241, 20449, 2423, 5760, 17437, 16490, 1211, 9381, 2423, 5760, 17437], "avg_logprob": -0.28847288860465, "compression_ratio": 1.373134328358209, "no_speech_prob": 0.0, "words": [{"start": 1005.78, "end": 1006.16, "word": "هذا", "probability": 0.77294921875}, {"start": 1006.16, "end": 1006.38, "word": " كان", "probability": 0.94921875}, {"start": 1006.38, "end": 1006.76, "word": " عندى", "probability": 0.4964599609375}, {"start": 1006.76, "end": 1007.02, "word": " color", "probability": 0.77099609375}, {"start": 1007.02, "end": 1007.48, "word": " 1", "probability": 0.45703125}, {"start": 1007.48, "end": 1008.72, "word": " يبجى", "probability": 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{"start": 2199.66, "end": 2199.98, "word": " اتفاعل", "probability": 0.76552734375}, {"start": 2199.98, "end": 2200.12, "word": " مع", "probability": 0.98876953125}, {"start": 2200.12, "end": 2200.44, "word": " خمسة", "probability": 0.911376953125}, {"start": 2200.44, "end": 2200.58, "word": " هى", "probability": 0.4176025390625}, {"start": 2200.58, "end": 2200.88, "word": " بيزيد", "probability": 0.958984375}, {"start": 2200.88, "end": 2201.46, "word": " خمسة", "probability": 0.9876708984375}, {"start": 2201.46, "end": 2201.94, "word": " هى", "probability": 0.79443359375}, {"start": 2201.94, "end": 2202.52, "word": " صفر", "probability": 0.9599609375}, {"start": 2202.52, "end": 2203.22, "word": " هى", "probability": 0.925537109375}, {"start": 2203.22, "end": 2203.82, "word": " خمسة", "probability": 0.9947509765625}], "temperature": 1.0}, {"id": 92, "seek": 222571, "start": 2204.77, "end": 2225.71, "text": "ماشي يا شباب اذا هذه millimoles التركيزات ال calcium ال excess خمسة millimoles على خمسين و خمسين مية يعني point O5 ال calcium Y2 minus formed خمسة اذا تركيز ال complex خمسة على برضه خمسين زي خمسين مية يعني point O5", "tokens": [2304, 33599, 1829, 35186, 13412, 3555, 16758, 1975, 15730, 29538, 1728, 332, 7456, 16712, 31747, 1829, 11622, 9307, 2423, 20918, 2423, 9310, 16490, 2304, 3794, 3660, 1728, 332, 7456, 15844, 16490, 2304, 3794, 9957, 4032, 16490, 2304, 3794, 9957, 3714, 10632, 37495, 22653, 935, 422, 20, 2423, 20918, 398, 17, 3175, 8693, 16490, 2304, 3794, 3660, 1975, 15730, 6055, 31747, 1829, 11622, 2423, 3997, 16490, 2304, 3794, 3660, 15844, 4724, 43042, 3224, 16490, 2304, 3794, 9957, 30767, 1829, 16490, 2304, 3794, 9957, 3714, 10632, 37495, 22653, 935, 422, 20], "avg_logprob": -0.19722221940755844, "compression_ratio": 1.7740112994350283, "no_speech_prob": 1.0132789611816406e-06, "words": [{"start": 2204.77, "end": 2205.21, "word": "ماشي", "probability": 0.7394205729166666}, {"start": 2205.21, "end": 2205.33, "word": " يا", "probability": 0.90380859375}, 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"probability": 0.86279296875}, {"start": 2467.27, "end": 2467.63, "word": " total", "probability": 0.84521484375}, {"start": 2467.63, "end": 2468.83, "word": " concentration", "probability": 0.923828125}], "temperature": 1.0}, {"id": 104, "seek": 249955, "start": 2469.81, "end": 2499.55, "text": "كمان مسألة نفس الطريقة بقول calculate PCA PCA يعني minus log التركيز الكالسيوم لان احنا اتفجنا على ان ال P function هي عبارة عن minus log التركيز فبقول calculate the PCA of a solution at pH 10 after addition of 100 ml of 0.1 molar calcium to 100 ml of 0.1 molar EDTA", "tokens": [24793, 7649, 47524, 10721, 37977, 8717, 36178, 41950, 16572, 28671, 4724, 39648, 8873, 430, 15515, 430, 15515, 37495, 22653, 3175, 3565, 16712, 31747, 1829, 11622, 33251, 6027, 3794, 1829, 20498, 5296, 7649, 1975, 5016, 8315, 1975, 2655, 5172, 7435, 8315, 15844, 16472, 2423, 430, 2445, 39896, 6225, 3555, 9640, 3660, 18871, 3175, 3565, 16712, 31747, 1829, 11622, 6156, 3555, 39648, 8873, 264, 6465, 32, 295, 257, 3827, 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احسب الـ millimole من الأول و millimole من التاني حسب ال stoichiometric طبعا واحد لواحد ايش اللي بيتبقى و ايش اللي بيتكون فان عندي هان ال millimole calcium point one في مية عشرة EDTA point one في مية عشرة اذا هذه عشرة هذه عشرة هذه صفر هذه صفر هذه صفر", "tokens": [3555, 16254, 1975, 5016, 35457, 2423, 39184, 1728, 332, 4812, 9154, 16247, 12610, 4032, 1728, 332, 4812, 9154, 16712, 7649, 1829, 11331, 35457, 2423, 22784, 18543, 29470, 23032, 3555, 3615, 995, 36764, 24401, 5296, 14407, 24401, 1975, 1829, 8592, 13672, 1829, 4724, 36081, 3555, 4587, 7578, 4032, 1975, 1829, 8592, 13672, 1829, 4724, 36081, 30544, 6156, 7649, 18871, 16254, 8032, 7649, 2423, 1728, 332, 4812, 20918, 935, 472, 8978, 3714, 10632, 6225, 8592, 25720, 18050, 8241, 935, 472, 8978, 3714, 10632, 6225, 8592, 25720, 1975, 15730, 29538, 6225, 8592, 25720, 29538, 6225, 8592, 25720, 29538, 20328, 5172, 2288, 29538, 20328, 5172, 2288, 29538, 20328, 5172, 2288], "avg_logprob": -0.2755549176831112, "compression_ratio": 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2575.59, "end": 2575.85, "word": " في", "probability": 0.67138671875}, {"start": 2575.85, "end": 2576.19, "word": " عندي", "probability": 0.71044921875}, {"start": 2576.19, "end": 2576.71, "word": " المحلول", "probability": 0.988037109375}, {"start": 2576.71, "end": 2577.01, "word": " فيه", "probability": 0.6485595703125}, {"start": 2577.01, "end": 2577.39, "word": " فقط", "probability": 0.987548828125}, {"start": 2577.39, "end": 2577.99, "word": " calcium", "probability": 0.771484375}, {"start": 2577.99, "end": 2578.67, "word": " y2", "probability": 0.741943359375}, {"start": 2578.67, "end": 2578.97, "word": "-", "probability": 0.426025390625}, {"start": 2578.97, "end": 2579.21, "word": " لكن", "probability": 0.6767578125}, {"start": 2579.21, "end": 2579.45, "word": " انا", "probability": 0.7197265625}, {"start": 2579.45, "end": 2579.69, "word": " بدي", "probability": 0.843994140625}, {"start": 2579.69, "end": 2580.15, "word": " احسب", "probability": 0.9347330729166666}, {"start": 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0.90712890625}, {"start": 2722.34, "end": 2722.5, "word": " قبل", "probability": 0.881103515625}, {"start": 2722.5, "end": 2722.86, "word": " هيك", "probability": 0.94970703125}, {"start": 2722.86, "end": 2723.24, "word": " لكن", "probability": 0.8173828125}, {"start": 2723.24, "end": 2724.1, "word": " موضوع", "probability": 0.95166015625}, {"start": 2724.1, "end": 2724.42, "word": " مهم", "probability": 0.989990234375}, {"start": 2724.42, "end": 2724.64, "word": " فيما", "probability": 0.858154296875}, {"start": 2724.64, "end": 2725.06, "word": " يتعلق", "probability": 0.9769287109375}, {"start": 2725.06, "end": 2725.24, "word": " بال", "probability": 0.7578125}, {"start": 2725.24, "end": 2725.92, "word": " EDTA", "probability": 0.773681640625}, {"start": 2725.92, "end": 2726.7, "word": " و", "probability": 0.47314453125}, {"start": 2726.7, "end": 2727.36, "word": " بعده", "probability": 0.91015625}, {"start": 2727.36, "end": 2728.82, "word": " هناخد", "probability": 0.9730224609375}, {"start": 2728.82, "end": 2729.92, "word": " مثال", "probability": 0.991943359375}, {"start": 2729.92, "end": 2730.38, "word": " آخر", "probability": 0.83837890625}], "temperature": 1.0}, {"id": 115, "seek": 275334, "start": 2731.42, "end": 2753.34, "text": "ناخد مثال تالت على إيش بحصل أثناء ال complexometric titration يعني بدنا نحسب ال P للmetal ion after addition of zero before equivalence point at equivalence point و after equivalence point فهذا الكلام إذا الله راضي الحصة الجاية بنشوفه و بنشوفكم ان شاء الله يوم الأربعة", "tokens": [1863, 47283, 3215, 50113, 6027, 6055, 6027, 2655, 15844, 11933, 1829, 8592, 4724, 5016, 36520, 5551, 12984, 1863, 16606, 2423, 3997, 29470, 3459, 2405, 37495, 22653, 47525, 8315, 8717, 5016, 35457, 2423, 430, 24976, 39857, 17437, 934, 4500, 295, 4018, 949, 9052, 655, 935, 412, 9052, 655, 935, 4032, 934, 9052, 655, 935, 6156, 3224, 15730, 2423, 28820, 10943, 11933, 15730, 21984, 12602, 46958, 1829, 21542, 9381, 3660, 25724, 995, 10632, 44945, 8592, 38688, 3224, 4032, 44945, 8592, 38688, 24793, 16472, 13412, 16606, 21984, 7251, 20498, 16247, 25513, 27884], "avg_logprob": -0.1579861102832688, "compression_ratio": 1.5924369747899159, "no_speech_prob": 4.76837158203125e-07, "words": [{"start": 2731.42, "end": 2732.14, "word": "ناخد", "probability": 0.8279622395833334}, {"start": 2732.14, "end": 2732.56, "word": " مثال", "probability": 0.982421875}, {"start": 2732.56, "end": 2733.1, "word": " تالت", "probability": 0.9596354166666666}, {"start": 2733.1, "end": 2733.44, "word": " على", "probability": 0.60693359375}, {"start": 2733.44, "end": 2734.26, "word": " إيش", "probability": 0.8062337239583334}, {"start": 2734.26, "end": 2734.82, "word": " بحصل", "probability": 0.859375}, {"start": 2734.82, "end": 2735.58, "word": " أثناء", "probability": 0.947998046875}, {"start": 2735.58, "end": 2735.74, "word": " ال", "probability": 0.95556640625}, {"start": 2735.74, "end": 2736.82, "word": " complexometric", "probability": 0.5755615234375}, {"start": 2736.82, "end": 2737.74, "word": " titration", "probability": 0.98046875}, {"start": 2737.74, "end": 2738.04, "word": " يعني", "probability": 0.699462890625}, {"start": 2738.04, "end": 2738.26, "word": " بدنا", "probability": 0.8984375}, {"start": 2738.26, "end": 2738.68, "word": " نحسب", "probability": 0.9957682291666666}, {"start": 2738.68, "end": 2739.32, "word": " ال", "probability": 0.8642578125}, {"start": 2739.32, "end": 2739.66, "word": " P", "probability": 0.740234375}, {"start": 2739.66, "end": 2740.48, "word": " للmetal", "probability": 0.4974365234375}, {"start": 2740.48, "end": 2740.92, "word": " ion", "probability": 0.798828125}, {"start": 2740.92, "end": 2741.24, "word": " after", "probability": 0.7939453125}, {"start": 2741.24, "end": 2741.54, "word": " addition", "probability": 0.97314453125}, {"start": 2741.54, "end": 2741.8, "word": " of", "probability": 0.974609375}, {"start": 2741.8, "end": 2742.2, "word": " zero", "probability": 0.40185546875}, {"start": 2742.2, "end": 2742.94, "word": " before", "probability": 0.552734375}, {"start": 2742.94, "end": 2743.56, "word": " equivalence", "probability": 0.933837890625}, {"start": 2743.56, "end": 2743.98, "word": " point", "probability": 0.9775390625}, {"start": 2743.98, "end": 2744.34, "word": " at", "probability": 0.70654296875}, {"start": 2744.34, "end": 2745.22, "word": " equivalence", "probability": 0.971435546875}, {"start": 2745.22, "end": 2745.54, "word": " point", "probability": 0.982421875}, {"start": 2745.54, "end": 2745.74, "word": " و", "probability": 0.86767578125}, {"start": 2745.74, "end": 2746.12, "word": " after", "probability": 0.7275390625}, {"start": 2746.12, "end": 2746.8, "word": " equivalence", "probability": 0.983154296875}, {"start": 2746.8, "end": 2747.18, "word": " point", "probability": 0.986328125}, {"start": 2747.18, "end": 2747.7, "word": " فهذا", "probability": 0.9300130208333334}, {"start": 2747.7, "end": 2748.04, "word": " الكلام", "probability": 0.9539388020833334}, {"start": 2748.04, "end": 2748.24, "word": " إذا", "probability": 0.954833984375}, {"start": 2748.24, "end": 2748.44, "word": " الله", "probability": 0.87939453125}, {"start": 2748.44, "end": 2748.68, "word": " راضي", "probability": 0.8658854166666666}, {"start": 2748.68, "end": 2749.02, "word": " الحصة", "probability": 0.9747721354166666}, {"start": 2749.02, "end": 2749.52, "word": " الجاية", "probability": 0.9503580729166666}, {"start": 2749.52, "end": 2750.28, "word": " بنشوفه", "probability": 0.9173583984375}, {"start": 2750.28, "end": 2750.36, "word": " و", "probability": 0.358154296875}, {"start": 2750.36, "end": 2750.8, "word": " بنشوفكم", "probability": 0.888427734375}, {"start": 2750.8, "end": 2750.94, "word": " ان", "probability": 0.57763671875}, {"start": 2750.94, "end": 2751.14, "word": " شاء", "probability": 0.982421875}, {"start": 2751.14, "end": 2751.36, "word": " الله", "probability": 0.96484375}, {"start": 2751.36, "end": 2752.84, "word": " يوم", "probability": 0.990966796875}, {"start": 2752.84, "end": 2753.34, "word": " الأربعة", "probability": 0.9459635416666666}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2754.676, "duration_after_vad": 2626.5824999999904}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/T0tFyL2b7X0_raw.srt b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/T0tFyL2b7X0_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..2a8c72fd6a2a39d74e1484cad0fc9c3fbd97bd60
--- /dev/null
+++ b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/T0tFyL2b7X0_raw.srt
@@ -0,0 +1,2132 @@
+1
+00:00:21,020 --> 00:00:25,120
+بسم الله الرحمن الرحيم اليوم ان شاء الله بنكمل في
+
+2
+00:00:25,120 --> 00:00:28,180
+ال complexometric reactions و titrations بنتكلم
+
+3
+00:00:28,180 --> 00:00:32,640
+شكل أساسي عن ال complexometric indicators و بعدين
+
+4
+00:00:32,640 --> 00:00:35,880
+بناخد بعض الأمثلة الحسابية تطبيق على الكلام اللي
+
+5
+00:00:35,880 --> 00:00:41,200
+كنا درسنا في الحصة الماضية ال complexometric
+
+6
+00:00:41,200 --> 00:00:46,680
+indicators في الحقيقة يعني يمكن تكون من مشاكل ال
+
+7
+00:00:46,680 --> 00:00:51,620
+complexometric titrationsليه؟ لأنه في كثير من
+
+8
+00:00:51,620 --> 00:00:56,180
+الأحيان مافيش indicators مناسبة لمعاييرات كثيرة
+
+9
+00:00:56,180 --> 00:01:03,020
+لهذا السبب يمكن نضطر أنه نتكلم شوية بالتفصيل عن
+
+10
+00:01:03,020 --> 00:01:07,220
+إيش ممكن نعمل علشان نتغلب على عدم وجود indicator
+
+11
+00:01:07,220 --> 00:01:12,740
+مناسب لكن في البداية خلينا نراجع مع بعض إيش يعني؟
+
+12
+00:01:12,850 --> 00:01:16,150
+complexometric indicator ايش طبيعة ال indicator
+
+13
+00:01:16,150 --> 00:01:18,810
+هذا اللي يمكن استخدام في ال complexometric
+
+14
+00:01:18,810 --> 00:01:24,270
+titrations فبنقول انه ال complexometric indicator
+
+15
+00:01:24,270 --> 00:01:30,660
+هو عبارة عن legend legendوالـ legend هاد هو عبارة
+
+16
+00:01:30,660 --> 00:01:34,260
+عن collating agent عادة، collating agent يعني
+
+17
+00:01:34,260 --> 00:01:38,120
+organic legend، collating agent يعني موجود فيه
+
+18
+00:01:38,120 --> 00:01:43,360
+أكتر من donating group يعني يُعتبر polydentate
+
+19
+00:01:43,360 --> 00:01:51,410
+عادة، لكن ما يميزه أنه بيكون very weakكليتس مع ال
+
+20
+00:01:51,410 --> 00:01:56,070
+metal ions بيكون very weak كليتس مع ال metal ions
+
+21
+00:01:56,070 --> 00:02:00,330
+اللي بتفاعل معاها يعني مش مع كل ال metal ions طبعا
+
+22
+00:02:00,330 --> 00:02:03,330
+اتفاعل مع بعض ال metal ions عادة ال few metal ions
+
+23
+00:02:03,330 --> 00:02:10,510
+يعني مثلا اتنين تلاتة اربعة خمسة فبيكون مع هذه ال
+
+24
+00:02:10,510 --> 00:02:15,450
+metal ions كليتس لكن الكليتس هذه ال formation
+
+25
+00:02:15,450 --> 00:02:22,290
+constant تبعها very smallمش مستالب معناه كلام،
+
+26
+00:02:22,290 --> 00:02:27,390
+لكنه قليل نسبيا إذا ما قورن مثلا بال EDTA metal
+
+27
+00:02:27,390 --> 00:02:32,790
+complex أو كلية، فهو يعتبر قليل، قويس، صغير، قيمته
+
+28
+00:02:32,790 --> 00:02:39,330
+قليلةفهذه حاجة الحاجة التانية أيضا لما بنتكلم عن
+
+29
+00:02:39,330 --> 00:02:45,950
+ال complexometric indicators بنتكلم عن indicators
+
+30
+00:02:45,950 --> 00:02:51,130
+بتعمل complexes مع بعض ال metal ions at specific
+
+31
+00:02:51,130 --> 00:02:56,990
+أو at some pH range يعني لو كان خارج هذا ال pH
+
+32
+00:02:56,990 --> 00:03:02,700
+range ممكن ال indicator هذا مايعملشكمبليكس او انه
+
+33
+00:03:02,700 --> 00:03:08,600
+ممكن الكمبليكس تبعه يكون ال KF له مش صغير كتير
+
+34
+00:03:08,600 --> 00:03:12,600
+نسبيا طبعا يعني مثلا عشر أقص اتنين عشر أقص تلاتة
+
+35
+00:03:12,600 --> 00:03:16,120
+عشر أقص أربعة هذا يعتبر صغير عشر أقص خمسة صغير
+
+36
+00:03:16,120 --> 00:03:22,580
+نسبيا يعني بالنسبة ل ال EDTA complexes هو يعتبر
+
+37
+00:03:22,580 --> 00:03:28,300
+صغير فبنقول انهالـ pH برضه بتعطينا نوع من القيود
+
+38
+00:03:28,300 --> 00:03:35,620
+على اختيار ال indicator ال
+
+39
+00:03:35,620 --> 00:03:39,560
+indicator زي ما احنا شايفين في المعادلة ال complex
+
+40
+00:03:39,560 --> 00:03:42,420
+indicator و ليه يكون مثلا مع حاجة زي ال magnesium
+
+41
+00:03:42,420 --> 00:03:49,420
+ال complex indicator هذا عبارة عن color one يعني
+
+42
+00:03:49,420 --> 00:03:57,210
+في لون لل complexوال Indicator لـ Free له لون تاني
+
+43
+00:03:57,210 --> 00:04:02,870
+وهذا عبارة عن لـ Free Indicator Color أو Color 2
+
+44
+00:04:02,870 --> 00:04:07,330
+فعند نقطة النهاية في عندي انتقال من Color 1 لColor
+
+45
+00:04:07,330 --> 00:04:11,950
+2 أو من Color 2 لColor 1من color 1 ل color 2 او من
+
+46
+00:04:11,950 --> 00:04:15,790
+color 2 ل color 1 حسب طبيعة الاشياء المعايرة هل
+
+47
+00:04:15,790 --> 00:04:22,370
+بعاير metal ion بال EDTA او EDTA بالmetal ion لاحظ
+
+48
+00:04:22,370 --> 00:04:28,130
+معايا ان ال EDTA اول لقطة زيادة من ال EDTA تتفاعل
+
+49
+00:04:28,130 --> 00:04:32,460
+مع ال magnesium indicator complexوبتطرد ال
+
+50
+00:04:32,460 --> 00:04:37,900
+indicator بتحرره ليه جال لأنه بالضرورة المجنيزيوم
+
+51
+00:04:37,900 --> 00:04:43,280
+EDTA complex او ال metal EDTA complex اقوى الكائف
+
+52
+00:04:43,280 --> 00:04:49,000
+له اكبر من الكائف ل المجنيزيوم او ال metal
+
+53
+00:04:49,000 --> 00:04:55,200
+indicator complex اه اثبت فبالتالي فورا تطرد ال
+
+54
+00:04:55,200 --> 00:04:59,040
+indicator at equivalence point وبيعطيني ال color
+
+55
+00:04:59,800 --> 00:05:04,620
+ماشي يا جماعة من ال indicators اللي انت متعود
+
+56
+00:05:04,620 --> 00:05:09,860
+عليها و اللي شفتها قبل هيك حاجة بنقولها EBT او
+
+57
+00:05:09,860 --> 00:05:14,780
+الاريكروم بلاك تي فهذا طبعا استخدمته انت لتعيين ال
+
+58
+00:05:14,780 --> 00:05:18,590
+water hardness الكالسيوم والمجنيزيوملو طلعت على
+
+59
+00:05:18,590 --> 00:05:23,390
+شكله تلاحظ انه في two نيتروجين كل نيتروجين في
+
+60
+00:05:23,390 --> 00:05:28,550
+عليها lone pair of electrons فهي two donating
+
+61
+00:05:28,550 --> 00:05:32,070
+groups و ال OH هذي و ال OH هذي في الحقيقة لما
+
+62
+00:05:32,070 --> 00:05:36,780
+تشتغل عند pH عشرة هذي عبارة عن phenolicهيدروكسيل
+
+63
+00:05:36,780 --> 00:05:41,720
+فنولج فهذه عادة تكون أسد فعند ph عشرة ال h هذه
+
+64
+00:05:41,720 --> 00:05:44,860
+بتكون راحت و صار عليها هان سالب و ال h هذه بتكون
+
+65
+00:05:44,860 --> 00:05:47,980
+راحت و صار عليها سالب فصار فعندي كمان two donating
+
+66
+00:05:47,980 --> 00:05:52,700
+groups الميتل بقعد هان في النص و هان بجيله رابطة
+
+67
+00:05:52,700 --> 00:05:55,140
+من هان و رابطة من هان و رابطة من هان و رابطة من
+
+68
+00:05:55,140 --> 00:06:00,730
+هان معايافبتعطينا ال complex لكن هذا ال complex
+
+69
+00:06:00,730 --> 00:06:07,170
+بيتم عند TH معينة هذه الحاجة و ايضا دائما ال KF
+
+70
+00:06:07,170 --> 00:06:12,510
+تبعه ايش ماله قليل يعني ال stability له قليلة
+
+71
+00:06:12,510 --> 00:06:18,310
+بسهولة ممكن انه يعني ال ED تتحل محله وتاخد ال
+
+72
+00:06:18,310 --> 00:06:21,990
+metal iron منه لو شفنا هاي ال metal indicator مثلا
+
+73
+00:06:21,990 --> 00:06:26,210
+في هذه الحالة wine red كانكلكم متذكرين التجربة
+
+74
+00:06:26,210 --> 00:06:31,290
+اللي عملتوها wine red لكن ال free indicator طبعا
+
+75
+00:06:31,290 --> 00:06:36,410
+هو blue وهذه ال blue بدها تكون تحت ال hin2 سالب
+
+76
+00:06:36,410 --> 00:06:43,720
+اللي هو ال blueمش ال مثل EDTA، ماهواش color، مش
+
+77
+00:06:43,720 --> 00:06:48,220
+blue، ال blue هو عبارة عن ال free indicator فاللون
+
+78
+00:06:48,220 --> 00:06:54,520
+بتحول من wine red ل blue، لون واضح، لون حلو بشكل
+
+79
+00:06:54,520 --> 00:07:01,820
+كبيرلو طلعنا على أمثلة، على بعض ال indicators،
+
+80
+00:07:01,820 --> 00:07:06,940
+بنشوف مثلا الـ Calmagite من 9 إلى 11 بيشتغل، هي ال
+
+81
+00:07:06,940 --> 00:07:11,420
+pH range تبعته، من 9 إلى 11، لإيش بينفع؟ جالب
+
+82
+00:07:11,420 --> 00:07:15,770
+بينفع للباريوم، للكالسيوم، للمجنيزيم، للزينكبناخد
+
+83
+00:07:15,770 --> 00:07:20,350
+حاجة تانية إيريكرون بلاك R في طبعا قدة فصائل من
+
+84
+00:07:20,350 --> 00:07:26,890
+فصائل ال EBT كويس فبيشتغل من سبعة و نص لعشرة و نص
+
+85
+00:07:26,890 --> 00:07:30,450
+بينفع للباريوم الكالسيوم الماجنيزيوم الزينك زي
+
+86
+00:07:30,450 --> 00:07:34,550
+اللي فوق بالظبط ملاحظين ولا لأ؟ يعني مافيش .. طيب
+
+87
+00:07:34,550 --> 00:07:38,730
+شوف ال .. إيريكرون بلو R من تمانية لاطمعاش بينفع
+
+88
+00:07:38,730 --> 00:07:41,170
+للكالسيوم ماجنيزيوم زينك كبر
+
+89
+00:07:45,390 --> 00:07:51,770
+المينوكسايد بينفع من 6 ل 13 OBG's أو بيعمل Complex
+
+90
+00:07:51,770 --> 00:07:55,790
+مع الكالسيوم والنكل والكبر لو اطلعت على بجيهة ال
+
+91
+00:07:55,790 --> 00:08:00,910
+.. ال .. لجن أو ال indicators الموجودة واطلعت على
+
+92
+00:08:01,940 --> 00:08:04,940
+الـmetal ions اللى بتقدر تعيينها، لاحظ انه عدد
+
+93
+00:08:04,940 --> 00:08:08,080
+الـmetal ions ايه اشماله؟ قليله محدود كتير، وفي
+
+94
+00:08:08,080 --> 00:08:11,420
+الحقيقة دائما، كمان ملاحظة تانية، ان ال calcium و
+
+95
+00:08:11,420 --> 00:08:14,620
+ال magnesium يعني حلوين كتير، يعني ال calcium هان
+
+96
+00:08:14,620 --> 00:08:19,160
+و هان و هان و هان، في أول أربع ال calcium، كويس؟
+
+97
+00:08:19,160 --> 00:08:23,280
+يعني ال calcium، و ال magnesium في أول تلاتةتمام ف
+
+98
+00:08:23,280 --> 00:08:27,740
+.. هذه العناصر ال calcium و ال magnesium لها
+
+99
+00:08:27,740 --> 00:08:33,620
+indicators كتيرة هذه حاجة و جيدة في نفس الوقت و ال
+
+100
+00:08:33,620 --> 00:08:36,620
+end point تبعتها واضحة كتير بس بدنا ناخد هذه
+
+101
+00:08:36,620 --> 00:08:40,980
+الملاحظة ال calcium و ال magnesium لهم و ال zinc
+
+102
+00:08:40,980 --> 00:08:47,440
+كمان يعني اه لهم indicators متعددة لكن طب بجيت
+
+103
+00:08:47,440 --> 00:08:51,940
+العناصر وين راحت؟ليش مش كاتبين list أكبر من هيك
+
+104
+00:08:51,940 --> 00:08:59,240
+كتير؟ بنقول في كثير من الأحيان صعب نلاقي indicator
+
+105
+00:08:59,240 --> 00:09:06,360
+مناسب لmetal ion معين احنا بنرغب فيه صعب طب ايش
+
+106
+00:09:06,360 --> 00:09:09,400
+بدنا نعمل دعالوا نناقش
+
+107
+00:09:11,170 --> 00:09:17,550
+المشاكل المصاحبة لاستخدام أو تحديد الـ
+
+108
+00:09:17,550 --> 00:09:21,750
+Complexometric Indicators بنقول في البداية خالص و
+
+109
+00:09:21,750 --> 00:09:30,380
+كشيء عام في كثير من الأحيان ممكن ال indicatorاللي
+
+110
+00:09:30,380 --> 00:09:35,660
+أنا بستخدمه يكون مش مناسب و ممكن أجيله حلول زي ما
+
+111
+00:09:35,660 --> 00:09:38,560
+هنشوف حنعرض حلول كتيرة يعني بعض الحلول مش كتيرة
+
+112
+00:09:38,560 --> 00:09:42,880
+لكن بعض حلول جيدة جدا لكن قبل ما نتطلع على هذه
+
+113
+00:09:42,880 --> 00:09:47,640
+الحلول إيش هي بنقول إنه قد تكون المشكلة في إنه
+
+114
+00:09:47,640 --> 00:09:51,620
+التفاعل بطيء قد تكون المشكلة في إنه إيه التفاعل
+
+115
+00:09:51,620 --> 00:09:56,960
+بطيء يعني لما يكون التفاعل بطيء لو جلنا هنا ال
+
+116
+00:09:56,960 --> 00:10:06,340
+millوهي ال P للميطال ايون لما يكون التفاعل بطيء ال
+
+117
+00:10:06,340 --> 00:10:11,300
+inflection بتكون ايش؟ sharp بتكون ايش عاملة؟
+
+118
+00:10:11,300 --> 00:10:12,120
+سيجمويدل
+
+119
+00:10:16,430 --> 00:10:22,470
+ال indicator تبعي هان بيبدأ اللون يظهر هان بيتغير
+
+120
+00:10:22,470 --> 00:10:27,730
+اللون طب جداش أخد volume من ال EDTA مش نقطة أخد
+
+121
+00:10:27,730 --> 00:10:34,010
+كمية هذا كلام ماضبطش لأنه هيأدي إلى خطأ جسيم انا
+
+122
+00:10:34,010 --> 00:10:37,630
+بد ال inflection تكون sharp عشان اقول والله هاي
+
+123
+00:10:37,630 --> 00:10:43,710
+مثلا هان اللون بيبدأ يتغير هان اللون بيخلص يتغير
+
+124
+00:10:43,710 --> 00:10:49,710
+نقطة واحدةنقطة واحدة فقط فال slow reaction بعمللي
+
+125
+00:10:49,710 --> 00:10:53,390
+مشكلة لكل أنواع ال indicators في الحكاية slow
+
+126
+00:10:53,390 --> 00:10:56,950
+reaction يعني مشكلة طب إيش ممكن أعمل أنا عشان
+
+127
+00:10:56,950 --> 00:11:02,670
+أتغلب على التفاعل إذا كانه slow؟ كيف ممكن أتغلب
+
+128
+00:11:02,670 --> 00:11:08,650
+على التفاعل إذا كان التفاعل عندي slow؟جال مش بس في
+
+129
+00:11:08,650 --> 00:11:12,290
+ال complexometric titrations لأ في جميع أنواع ال
+
+130
+00:11:12,290 --> 00:11:18,050
+titrations إذا التفاعل slow الحل الأقرب إلي إن
+
+131
+00:11:18,050 --> 00:11:23,750
+أشتغل back titrationليه؟ لأن ال slow reaction في
+
+132
+00:11:23,750 --> 00:11:28,750
+معظم الأحيان بيكون السبب اللي بيأد لإنه التفاعل
+
+133
+00:11:28,750 --> 00:11:35,950
+بطيق هو تركيز المتفاعلات أنا بضيف نقطة من ال EDTA
+
+134
+00:11:35,950 --> 00:11:39,350
+على ال metal ion النقطة هذه لما تتوزع على الحجم
+
+135
+00:11:39,350 --> 00:11:45,410
+كيف بيكون تركيزها؟قليل قليل معناته طب ال rate of
+
+136
+00:11:45,410 --> 00:11:49,850
+reaction يتناسب مع التركيز إذا المعدل التفاعل إيش
+
+137
+00:11:49,850 --> 00:11:55,330
+هيكون بطيء لأنه التركيز قليل يبقى أنا لما بدي
+
+138
+00:11:55,330 --> 00:11:59,870
+أتغلب على هذه المشكلة أفضل حل ليه و أقرب حل للعقل
+
+139
+00:11:59,870 --> 00:12:03,650
+أنه والله أستخدم back titration بحيث أني أضيف
+
+140
+00:12:03,650 --> 00:12:11,050
+excess EDTAبدي اضيف excess EDTA ال excess EDTA
+
+141
+00:12:11,050 --> 00:12:15,470
+اللي انا بضيفها هتتفاعل
+
+142
+00:12:15,470 --> 00:12:20,730
+مع كل ال metal ion اللي موجود و هيزيد EDTA هتتفاعل
+
+143
+00:12:20,730 --> 00:12:24,350
+مع كل ال metal ion وهيه بطلع عندي metal EDTA
+
+144
+00:12:24,350 --> 00:12:32,660
+complex و بزيد EDTA ال EDTA لزيادة ببدأ اعيرهاالـ
+
+145
+00:12:32,660 --> 00:12:36,160
+Metal-Ion له Indicator مناسب Indicator حلو زي ما
+
+146
+00:12:36,160 --> 00:12:39,460
+شوفنا الـ EBT أو الـ Meroxide أو الكالماجايت كله
+
+147
+00:12:39,460 --> 00:12:44,080
+بينفع فالمجنيزيام عادة نستخدمه بشكل كبير
+
+148
+00:12:44,080 --> 00:12:48,820
+المجنيزيام بيبدأ يعاير الزيادة من الـ EDTA خلصت
+
+149
+00:12:48,820 --> 00:12:54,940
+الزيادة من الـ EDTA أول نقطة من المجنيزيام بتتفاعل
+
+150
+00:12:54,940 --> 00:12:55,300
+مع
+
+151
+00:13:04,820 --> 00:13:11,900
+بتعطينا magnesium I N سالب هذا طبعا كان color one
+
+152
+00:13:11,900 --> 00:13:21,660
+هذا صار color two ماشي يا شباب هذا بسهولة و هيك
+
+153
+00:13:21,660 --> 00:13:29,790
+بكون اتغلبت على ال slow reactionو مش .. زي ما قلت
+
+154
+00:13:29,790 --> 00:13:33,770
+مش بس في ال complexometric titrations لأ في جميع
+
+155
+00:13:33,770 --> 00:13:38,150
+أنواع ال titrations إذا كان عندي slow reaction
+
+156
+00:13:38,150 --> 00:13:42,570
+أفضل حالة ليه أن أستخدم ال back titration واضح يا
+
+157
+00:13:42,570 --> 00:13:47,570
+شباب يبقى ال back titration حاجة ممتازة جدا طب
+
+158
+00:13:47,570 --> 00:13:51,570
+نيجي نتطلع على الحالة اللي بيكون فيها أصلا ال
+
+159
+00:13:51,570 --> 00:13:55,350
+indicator مش مناسب فيش indicator مناسب lack of
+
+160
+00:13:55,350 --> 00:13:57,230
+suitable indicator
+
+161
+00:13:59,380 --> 00:14:04,160
+في الحقيقة في هذه الحالة انا ممكن اطلع على الحلول
+
+162
+00:14:04,160 --> 00:14:07,800
+كالتالي اول حل و طبعا هذا الشي اللى بدنا نقول احنا
+
+163
+00:14:07,800 --> 00:14:14,380
+نفصل فيه شوية اول حل يتضمن اضافة standard
+
+164
+00:14:14,380 --> 00:14:18,680
+magnesium solution كمية معروفة انا عندي هاي ال
+
+165
+00:14:18,680 --> 00:14:26,780
+metal ion وهاي عندي كمان ال
+
+166
+00:14:26,780 --> 00:14:33,280
+indicator وهي ال EDTAلكن للأسف الـ metal مع ال
+
+167
+00:14:33,280 --> 00:14:37,560
+indicator بيتفعلوش بيحطوليش complex فبالتالي لو
+
+168
+00:14:37,560 --> 00:14:46,340
+بدي اعير انا لما انا اعير طب خلص ال metal ion طب
+
+169
+00:14:46,340 --> 00:14:49,260
+وبعدين ال indicator بضال زي ما هو مابيتفعل مع ال
+
+170
+00:14:49,260 --> 00:14:55,600
+intelligence اذا مش راح يتغير اللون جال لأ ضيف هان
+
+171
+00:14:55,600 --> 00:14:58,640
+مثلا
+
+172
+00:14:58,640 --> 00:15:06,410
+اتنين من الof 0.01 molar magnesium مجنيزم كلورايد
+
+173
+00:15:06,410 --> 00:15:14,010
+عادة مجنيزم يعني طب ايش بيحصل لما اضيف انا ال ال
+
+174
+00:15:14,010 --> 00:15:17,590
+point one مولار مجنيزم اتنين منه بالظبط لازم يكون
+
+175
+00:15:17,590 --> 00:15:20,950
+الكمية معروفة ايش بيحصل جالي والله على طول
+
+176
+00:15:20,950 --> 00:15:26,310
+المجنيزم بيتفاعل مع ال I N تلاتة سالب وبيعطيني
+
+177
+00:15:26,310 --> 00:15:33,870
+مجنيزم I N سالب وهذا colorone صح مجرد ان اضافت
+
+178
+00:15:33,870 --> 00:15:37,970
+المجنيزيام وانهارتها اندكاتور مناسب للمجنيزيام مش
+
+179
+00:15:37,970 --> 00:15:41,190
+للميتال ايون لانه فش اندكاتور للميتال ايون مناسب
+
+180
+00:15:41,190 --> 00:15:47,290
+فالمجنيزيام هيتفاعل مع ال indicator و هيعطيني
+
+181
+00:15:47,290 --> 00:15:51,770
+magnesium indicator complex طبعا
+
+182
+00:15:53,690 --> 00:15:58,550
+هيزيد كمية من المجنيزيام ما اختلفتش معاك لأن ال
+
+183
+00:15:58,550 --> 00:16:01,130
+indicator كمية قليلة هياخد كمية قليلة من
+
+184
+00:16:01,130 --> 00:16:05,190
+المجنيزيام المضاف و هيزيد شوية مجنيزيام الان ببدأ
+
+185
+00:16:05,190 --> 00:16:14,050
+اغاير انا ال EDTA هاتتفاعل مع ال metal ion لغاية
+
+186
+00:16:14,050 --> 00:16:18,270
+ما يخلص كل ال metal ionخلص الـ metal ion تبعي ال
+
+187
+00:16:18,270 --> 00:16:23,110
+EDTA هتتفاعل مع ال magnesium لزيادة خلص المضعف
+
+188
+00:16:23,110 --> 00:16:28,970
+يعني خلص ال magnesium لزيادة اول نقطة تنزل من ال
+
+189
+00:16:28,970 --> 00:16:34,330
+EDTA هنلاحظ ان ال EDTA بتتفاعل مع ال magnesium
+
+190
+00:16:34,330 --> 00:16:44,110
+indicator و بتعطيلنا magnesium EDTA زائد هذا color
+
+191
+00:16:44,110 --> 00:16:51,600
+2هذا كان عندى color 1 يبجى هان هيتحول عندى in
+
+192
+00:16:51,600 --> 00:16:57,200
+تلاتة سالب color 2 كمان مرة بقول edta بتتفعل مع ال
+
+193
+00:16:57,200 --> 00:17:00,890
+metal ion خلص ال metal ionالـ EDTA تتفاعل مع
+
+194
+00:17:00,890 --> 00:17:04,910
+المجنيزيوم خلص المجنيزيوم أول نقطة زيادة من الـ
+
+195
+00:17:04,910 --> 00:17:10,490
+EDTA هتتفاعل مع المجنيزيوم I N سالب و بما أنه
+
+196
+00:17:10,490 --> 00:17:16,830
+المجنيزيوم EDTA أثبت أقوى الـ KF إليها أكبر من
+
+197
+00:17:16,830 --> 00:17:20,410
+المجنيزيوم indicator إذا هتطرد ال indicator و
+
+198
+00:17:20,410 --> 00:17:24,070
+هتاخد هي المجنيزيوم عشان تكون مجنيزيوم EDTA فالـ
+
+199
+00:17:24,070 --> 00:17:29,080
+EDTA هتطرد ال indicator هيوهي اللي هتاخد
+
+200
+00:17:29,080 --> 00:17:33,840
+المجنيزيام لإنه الـKf للمجنيزيام EDTA أكبر من
+
+201
+00:17:33,840 --> 00:17:39,280
+الـKf للإنديكاتور المجنيزيام complex إذن الآن
+
+202
+00:17:39,280 --> 00:17:42,980
+اتحول كل المجنيزيام indicator ل free indicator هذا
+
+203
+00:17:42,980 --> 00:17:47,760
+عبارة عن color 2 أو هذه ال end point لكن بتواجهنا
+
+204
+00:17:47,760 --> 00:17:52,240
+مشكلة هنا بتواجهنا مشكلة أنه ال volume لل EDTA
+
+205
+00:17:52,240 --> 00:17:57,780
+المضعف أو المستخدم بكافئ ال metal ion زائد
+
+206
+00:17:58,700 --> 00:18:03,160
+المجنيزيوم المضعف هيو مشان اضافت مجنيزيوم اذا ال
+
+207
+00:18:03,160 --> 00:18:10,060
+EDTA المضعفة تساوي او تكافئ ال metal ion زائد كمان
+
+208
+00:18:10,060 --> 00:18:14,840
+المجنيزيوم وهذا بيقدي طبعا يعني هذا خطأ ماينفعش
+
+209
+00:18:14,840 --> 00:18:19,880
+يكون زي هيك لهذا السبب بنعمل حاجة بنقولها blank
+
+210
+00:18:19,880 --> 00:18:25,800
+experiment او
+
+211
+00:18:25,800 --> 00:18:31,740
+titration هينبحطبس اتنين mil of point one molar
+
+212
+00:18:31,740 --> 00:18:35,080
+magnesium
+
+213
+00:18:35,080 --> 00:18:42,320
+وهي عندى نفس الكمية من ال indicator ففورا بتكون
+
+214
+00:18:42,320 --> 00:18:46,260
+عندنا magnesium indicator سالب اللى هو ال complex
+
+215
+00:18:46,260 --> 00:18:52,100
+يعنى وبعدين بعاير بال EDTA بعاير هذه الكمية بال
+
+216
+00:18:52,100 --> 00:18:59,330
+EDTA فالمعايرة التانية هذهبتعطيني فقط حجم ال EDTA
+
+217
+00:18:59,330 --> 00:19:04,490
+المكافئ لإيه للمجنيزيوم اللي أنا أضافته نفس الكمية
+
+218
+00:19:04,490 --> 00:19:09,170
+لأنها فهنا عندي حجم ال EDTA بكافئ ال metal ion
+
+219
+00:19:09,170 --> 00:19:13,670
+زائد المجنيزيوم هن حجم ال EDTA بكافئ بس المجنيزيوم
+
+220
+00:19:13,670 --> 00:19:17,850
+لو طرحنا الاتنين من بعض بحصل على حجم ال EDTA
+
+221
+00:19:17,850 --> 00:19:22,510
+المكافئ فقط للمetal ion اللي أصلا موجود عندى كمان
+
+222
+00:19:22,510 --> 00:19:24,350
+مرة أول titration
+
+223
+00:19:27,650 --> 00:19:32,450
+أول titration بتعطيني
+
+224
+00:19:32,450 --> 00:19:38,490
+ال metal ion زائد المجنيزيوم المضاعف الاتنين ليه؟
+
+225
+00:19:38,490 --> 00:19:41,710
+لأن المجنيزيوم بتعير بال EDTA والmetal ion بتعير
+
+226
+00:19:41,710 --> 00:19:45,430
+بال EDTA يبقى ال EDTA المضاعف فهي مجموعة الأتنين
+
+227
+00:19:45,430 --> 00:19:50,130
+لبلاك experiment بستخدم نفس الكمية من المجنيزيوم
+
+228
+00:19:50,130 --> 00:19:53,790
+اللى استخدمتها في ال ايه؟ في ال original titration
+
+229
+00:19:54,580 --> 00:19:59,980
+وبعييرها بال EDTA إذا حجم ال EDTA P كافة اللي هو
+
+230
+00:19:59,980 --> 00:20:03,680
+المجنيزم اللي موجود أنا عندي المجنيزم زائد ال
+
+231
+00:20:03,680 --> 00:20:07,960
+metal ion وعندي المجنيزم لوحده لو طرحتهم من بعض
+
+232
+00:20:07,960 --> 00:20:12,440
+بعطيني بس ال metal ion هذه أول شغلة ممكن أعملها
+
+233
+00:20:12,440 --> 00:20:19,920
+لكن للأسف يعني خلينا نقول انا
+
+234
+00:20:19,920 --> 00:20:25,590
+بحاجة ل two experiments في عندي originalexperiment
+
+235
+00:20:25,590 --> 00:20:31,710
+وفي عندى black experiment السؤال هل يمكن هل يمكن
+
+236
+00:20:31,710 --> 00:20:35,030
+عمل
+
+237
+00:20:35,030 --> 00:20:39,730
+ال titration بدون black experiment هل ممكن نوفر
+
+238
+00:20:39,730 --> 00:20:44,570
+خطوة ل black ممكن نوفر خطوة ل black يعني نشتغل
+
+239
+00:20:44,570 --> 00:20:48,950
+بدون black بنقول ممكن نشتغل بدون black إذا كان
+
+240
+00:20:48,950 --> 00:20:54,510
+استخدمناحاجة بنقولها magnesium EDTA هي عندها ال
+
+241
+00:20:54,510 --> 00:21:03,270
+metal ion و عند ال indicator بتفعلش معاه وهي عندها
+
+242
+00:21:03,270 --> 00:21:14,090
+EDTA ده ال ايش بيحصل لو احنا اضافلها مش magnesium
+
+243
+00:21:14,090 --> 00:21:15,690
+magnesium EDTA
+
+244
+00:21:19,820 --> 00:21:23,860
+إيش بيحصل لو أضفنا مجنيزيوم EDTA جال والله لما أنا
+
+245
+00:21:23,860 --> 00:21:30,960
+أضيف مجنيزيوم EDTA هاي مجنيزيوم EDTA عند ال metal
+
+246
+00:21:30,960 --> 00:21:47,060
+ion تعطيني مجنيزيوم free زائد metal EDTA ليه؟
+
+247
+00:21:47,060 --> 00:21:52,820
+ليش هذا الكلام؟أنا أضفت لاحظوا معي مش magnesium
+
+248
+00:21:52,820 --> 00:21:58,040
+انا أضفت complex اسمه magnesium EDTA طيب لما أضفته
+
+249
+00:21:58,040 --> 00:22:01,420
+انا عندها ال metal ion بمجرد ما أضفت ال magnesium
+
+250
+00:22:01,420 --> 00:22:06,800
+EDTA ال metal طرد ال magnesium و أخد ال EDTA ليش
+
+251
+00:22:06,800 --> 00:22:12,400
+هذا الكلام؟ جال لأنه قلنا في الحصة الماضية ان هاي
+
+252
+00:22:12,400 --> 00:22:19,550
+ال pH و هاي ال logللـ KF و لجينا ان المجنيزيوم هان
+
+253
+00:22:19,550 --> 00:22:22,750
+في ذهن القائمة و ال metal ions التانية ال KF
+
+254
+00:22:22,750 --> 00:22:27,970
+تباعها اكبر كتير من ال KF للمجنيزيومفبسهولة اي
+
+255
+00:22:27,970 --> 00:22:32,470
+metal ion بيحل محل المجنيزم ويطلعه لضارة ليه؟ لأن
+
+256
+00:22:32,470 --> 00:22:38,890
+الـKf له أكبر من الـKf للمجنيزم EDTA فبطرد
+
+257
+00:22:38,890 --> 00:22:42,770
+المجنيزم وبياخد ال EDTA منه لهذا السبب المجنيزم
+
+258
+00:22:42,770 --> 00:22:46,150
+على طول ايش بيسوي؟ بيطلع free ايش بيلاجي في
+
+259
+00:22:46,150 --> 00:22:53,370
+المحلول؟ الIN تلاتة سالب فبتحول فورا لمجنيزم IN
+
+260
+00:22:53,370 --> 00:23:01,490
+سالب وهذا colorone ماشي يا شباب بمجرد إضافة ال
+
+261
+00:23:01,490 --> 00:23:06,810
+magnesium edta بيحصل
+
+262
+00:23:06,810 --> 00:23:11,370
+التفاعل هذا ال free magnesium بيتفاعل مع ال in
+
+263
+00:23:11,370 --> 00:23:16,520
+تلاتة سالم وبيعطينا magnesium in سالملسه ماضفناش
+
+264
+00:23:16,520 --> 00:23:22,360
+ال EDTA نهائيا جويس الان بدأ اضيف ال EDTA ال EDTA
+
+265
+00:23:22,360 --> 00:23:29,820
+هتخلص كل ال metal ion فعل معاه طيب اول لقطة زيادة
+
+266
+00:23:29,820 --> 00:23:30,780
+من ال EDTA
+
+267
+00:23:51,050 --> 00:23:56,630
+صار ind i in تلقى تسالب هذا عبارة عن ايه color 2
+
+268
+00:23:56,630 --> 00:24:02,510
+ليش طيب ال EDTA بتحل محل ال indicator؟ جان لأن ال
+
+269
+00:24:02,510 --> 00:24:06,750
+magnesium EDTA أقوى ال KFLو أكبر، ليه؟ لإحنا قولنا
+
+270
+00:24:06,750 --> 00:24:11,600
+إن ال indicator very weak collating agentبعيف جدا
+
+271
+00:24:11,600 --> 00:24:18,560
+جدا وبالتالي بسهولة اي metal ion ممكن يحل .. اي
+
+272
+00:24:18,560 --> 00:24:21,420
+legend ممكن يحل محل ال indicator وبالذات ال EDTA
+
+273
+00:24:21,420 --> 00:24:26,710
+تعتبر legend قوي legend كتير كويسفهذا عبارة عن
+
+274
+00:24:26,710 --> 00:24:29,470
+color 1 و color 2 و طبعا في هذه الحالة انا مش
+
+275
+00:24:29,470 --> 00:24:34,650
+بحاجة لتصحيح ليه؟ لأنه انا هان ما اضافت مجنيزيام
+
+276
+00:24:34,650 --> 00:24:39,490
+لوحده اضافت مجنيزيام EDTA وهذا مابيتعير يعني مثلا
+
+277
+00:24:39,490 --> 00:24:48,470
+مثلا لو كان عندي كمية كبيرة هي EDTA وهي مجنيزيام
+
+278
+00:24:48,470 --> 00:24:57,400
+EDTA لو بدي اعير بدي اقول EDTAزائد مجنيزيام EDTA
+
+279
+00:24:57,400 --> 00:25:06,360
+بتعطي مجنيزيام EDTA زائد EDTA نفس الحاجة بتتفعليش
+
+280
+00:25:06,360 --> 00:25:09,420
+معاها لإن هي مااخد اصلا EDTA كفاية معايا
+
+281
+00:25:09,420 --> 00:25:14,880
+المجنيزيام أصلا complex وبالتاليوبالتالي بتعيرش
+
+282
+00:25:14,880 --> 00:25:19,120
+بال EDTA ماعيره خالص معنى الكلام حجم ال EDTA
+
+283
+00:25:19,120 --> 00:25:23,900
+المضعف في هذه الحالة فقط بيعبر عن ايه او بيكافئ بس
+
+284
+00:25:23,900 --> 00:25:27,080
+ال metal ion لأن ال magnesium EDTA المضعف مهما
+
+285
+00:25:27,080 --> 00:25:31,440
+كانت كميتها بتأثرش على ال equilibrium ما بتأثر على
+
+286
+00:25:31,440 --> 00:25:36,520
+ال equilibrium يبقى هذه خلصتني من مشكلة انه والله
+
+287
+00:25:36,520 --> 00:25:40,760
+اعمل blank titration هيك بضطرش اعمل blank
+
+288
+00:25:40,760 --> 00:25:45,240
+titration لكن للأسفلو قلنا لأفندي المختبر لو سمحت
+
+289
+00:25:45,240 --> 00:25:50,680
+عوزين شوية magnesium EDTA Complex بقولك والله
+
+290
+00:25:50,680 --> 00:25:55,420
+مافيش عيناك ولو روحت تشتري من أي شركة ممكن يعني
+
+291
+00:25:55,420 --> 00:25:58,020
+يتساءلوا لإيش بدك إياه وممكن ماتلاجهوش
+
+292
+00:26:01,290 --> 00:26:06,470
+طب ها إيش الحل؟ كيف بدنا نسوي؟ قال هذا الكلام صحيح
+
+293
+00:26:06,470 --> 00:26:14,970
+لأنه عملية يعني عملية بسيطة جدا بتأدي لاستعاضتنا
+
+294
+00:26:14,970 --> 00:26:23,710
+عن شراء أو استخدام magnesium EDTA complex كيف؟ إيش
+
+295
+00:26:23,710 --> 00:26:32,790
+بنعمل عشان نستغني عن شراء أواستخدام ال complex بحد
+
+296
+00:26:32,790 --> 00:26:40,270
+ذاته، بنقول احنا يمكن لو جينا اطلعنا على ال EDTA
+
+297
+00:26:41,170 --> 00:26:45,930
+أنا بدى أحضر EDTA فبقول EDTA تقريبا يعني واحد من
+
+298
+00:26:45,930 --> 00:26:52,410
+عشرة مولار EDTA ليش تقريبا؟ جان لأن EDTA ماهياش
+
+299
+00:26:52,410 --> 00:26:56,470
+primary standard لازم نعملها standardization بنقول
+
+300
+00:26:56,470 --> 00:27:01,250
+قبل ما نكمل الحجم لألف mil خلينا نضيف عليها شوية
+
+301
+00:27:01,250 --> 00:27:05,470
+magnesium جبتاش نضيف يعني اتنين تلاتة mil واحد من
+
+302
+00:27:05,470 --> 00:27:10,060
+عشرة مولار اتنين تلاتة milجداش بالظبط مش مهم ان
+
+303
+00:27:10,060 --> 00:27:14,960
+اعرف جداش بالظبط بهمنيش مابيهمنيش بهمنيش اعرف جداش
+
+304
+00:27:14,960 --> 00:27:18,280
+بالظبط يبجى هالجيت ايش صار مجرد مضيف المجنيزيام
+
+305
+00:27:18,280 --> 00:27:23,700
+ايش حصل جزء من ال EDTA اتفاعل مع المجنيزيام وصار
+
+306
+00:27:23,700 --> 00:27:29,720
+مجنيزيام EDTA وجزء من ال EDTA ايش ضايل زي ما هو طب
+
+307
+00:27:29,720 --> 00:27:34,280
+باجي انا بعاير هذا عشان اعرف جداش بكمل للألف ميل
+
+308
+00:27:34,280 --> 00:27:40,700
+مثلا اجيت استخدمت هي عند هنا EDTAواندي مجنيزيوم
+
+309
+00:27:40,700 --> 00:27:46,700
+EDTA بعيرها مثلا بالمجنيزيوم او بالزينك عشان يعني
+
+310
+00:27:46,700 --> 00:27:53,960
+بس نغير شوية بعيرها الزينك هيعير ال EDTA
+
+311
+00:27:59,520 --> 00:28:05,680
+يعني هيعير المجنيزم ممكن يحل محل المجنيزم وياخد ال
+
+312
+00:28:05,680 --> 00:28:12,920
+EDTM انه علشان هيك احنا بنقول يعني بنقول بشكل عام
+
+313
+00:28:12,920 --> 00:28:20,950
+لو استخدمنا مجنيزمعشان مايقدرش يحل محل المجنيزم او
+
+314
+00:28:20,950 --> 00:28:24,410
+لو حل محله و يطلع نفس الكمية على سبيل المثال هي هي
+
+315
+00:28:24,410 --> 00:28:29,670
+نفس الكلام فبنقول انه المجنيزم هيكافئ ال EDTA وهان
+
+316
+00:28:29,670 --> 00:28:33,910
+مش هيتفاعل مع المجنيزم EDTA مافيش عندى تفاعل مع
+
+317
+00:28:33,910 --> 00:28:39,930
+المجنيزم EDTA طيب معنى الكلام اجدرت اعين تركيز ال
+
+318
+00:28:39,930 --> 00:28:45,550
+EDTA لوحدها ال EDTA ولا تلاقوا مثلا 0.0888 molar
+
+319
+00:28:45,990 --> 00:28:50,610
+EDTA كويسة
+
+320
+00:28:50,610 --> 00:28:55,730
+بجه اول خطوة حطيت شوية مجنيزيام و بعدين اتحول طبعا
+
+321
+00:28:55,730 --> 00:29:00,690
+لجزء من ال EDTA لمجنيزيام EDTA بعدين عيرت ال EDTA
+
+322
+00:29:00,690 --> 00:29:04,830
+باستخدام standard magnesium عرفت جداش تركيز ال
+
+323
+00:29:04,830 --> 00:29:10,030
+EDTA بالظبط ماشي لكن ال EDTA المحلول اش فيه فيه
+
+324
+00:29:10,030 --> 00:29:14,270
+شوية مجنيزيام EDTA ماشي يا شبابلسه ماعملناش حاجة
+
+325
+00:29:14,270 --> 00:29:18,790
+احنا مجرد حضرنا محلول ال EDTA كويس لكن محلول ال
+
+326
+00:29:18,790 --> 00:29:22,790
+EDTA إيش كان فيه؟ شوية مجنزة من مجنزة من EDTA احنا
+
+327
+00:29:22,790 --> 00:29:26,090
+بعد ما عملناها مجنزة من EDTA شوية منها عيرنا
+
+328
+00:29:26,090 --> 00:29:30,850
+فعرفنا كده إيش تركيز ال EDTA في هذا المحلول طيب
+
+329
+00:29:30,850 --> 00:29:36,730
+حلو كتير الآن خلينا لو عندى .. بدك تتبه شوية الآن
+
+330
+00:29:36,730 --> 00:29:45,130
+لو عندى metal ionهو عنده IN تلاتة ثالث بتفعلوش مع
+
+331
+00:29:45,130 --> 00:29:50,310
+بعض وعندي هنا ال EDTA اللي موجود فيها مجنيزيوم
+
+332
+00:29:50,310 --> 00:29:55,650
+EDTA معايا انت اللي هو هذا المحلول تعالوا نضيف
+
+333
+00:29:55,650 --> 00:30:00,730
+نقطة واحدة من هذا المحلول هان ونشوف ايش اللي بيحصل
+
+334
+00:30:00,730 --> 00:30:07,230
+بقول ال EDTA النقطة
+
+335
+00:30:07,230 --> 00:30:13,720
+بتتفاعل مع الmetal بتحول لmetalEDTA فش مشكلة في
+
+336
+00:30:13,720 --> 00:30:19,640
+هذا الكلام كويس لكن كمان فى عندي حاجة خطيرة انه ال
+
+337
+00:30:19,640 --> 00:30:22,860
+metal هذا اللى موجود هان كمان لأنه كمية كبيرة منه
+
+338
+00:30:22,860 --> 00:30:26,020
+لسه اول نقطة حطينا من ال EDTA كمية كبيرة من ال
+
+339
+00:30:26,020 --> 00:30:31,880
+metalion فالمetal مع ال magnesium I ال magnesium
+
+340
+00:30:31,880 --> 00:30:37,960
+EDTAاللي أنا استخدمته هذا النقطة بتحتوي على EDTA
+
+341
+00:30:37,960 --> 00:30:41,320
+ومش تحتويه كمان على مجنيزيوم EDTA لكن المجنيزيوم
+
+342
+00:30:41,320 --> 00:30:52,160
+متكمية قليلة جدا فورا الميتل بيطلع مجنيزيوم
+
+343
+00:30:52,160 --> 00:30:58,130
+افري المجنيزيوم افري هذا اول نقطة عايش هيعطينيأه
+
+344
+00:30:58,130 --> 00:31:03,130
+ميجنيزيام I N سالب هاي color one يبقى أول مضيف أول
+
+345
+00:31:03,130 --> 00:31:07,570
+نقطة بتعطيني color one أول نقطة بتعطيني color one
+
+346
+00:31:07,570 --> 00:31:10,910
+ليش ال metal ion بيحل محل الميجنيزيام كمان مرة
+
+347
+00:31:10,910 --> 00:31:14,170
+لأنه الميجنيزيام ال K أفقله قليل بالنسبة ل ال
+
+348
+00:31:14,170 --> 00:31:18,130
+metals التانية فبسهولة بيحل محله و بيطلعه ال free
+
+349
+00:31:18,130 --> 00:31:21,570
+metal ion بتفاعل مع ال I N أو ال free magnesium
+
+350
+00:31:21,570 --> 00:31:25,150
+ion بتفاعل مع ال I N تلاتة سالب يعطينا ميجنيزيام I
+
+351
+00:31:25,150 --> 00:31:31,810
+N سالب كويسطبعا يعني يبدأ color one طب خلينا نطلع
+
+352
+00:31:31,810 --> 00:31:36,370
+ايش بيحصل عند نقطة النهاية يعنى انا عاملا بضيف ال
+
+353
+00:31:36,370 --> 00:31:41,090
+EDTA خلص كل ال كل ال MN plus لأنه انا بضيف EDTA
+
+354
+00:31:41,090 --> 00:31:49,510
+خلص كل ال MN plus الان باشي بقول ال EDTA اللى
+
+355
+00:31:49,510 --> 00:31:54,730
+بتنزل اول نقطة EDTA هتلاقي magnesium in سالب
+
+356
+00:31:57,690 --> 00:32:05,610
+حقل مجنيزيا EDTA زائد IN تلاتة سالب إذا هذه هي ال
+
+357
+00:32:05,610 --> 00:32:11,160
+color 2ماشي يا شباب بهادي الحالة يعني انا ماضطرتش
+
+358
+00:32:11,160 --> 00:32:15,240
+ان انا استخدم .. ماضطرتش
+
+359
+00:32:15,240 --> 00:32:18,840
+ان انا استخدم magnesium EDTA complex من برا لأ انا
+
+360
+00:32:18,840 --> 00:32:21,880
+مجرد ان انا قضيت اللي بس يعني شوية magnesium
+
+361
+00:32:21,880 --> 00:32:28,280
+chloride كمية بسيطة جدا ممكن تكون يعني واحد من مية
+
+362
+00:32:28,280 --> 00:32:32,560
+و لا واحد من او خمسة من الف من ال EDTA يعني حاجة
+
+363
+00:32:32,560 --> 00:32:36,660
+بسيطة كتير او اتنين من الف من ال EDTA بينفع كمية
+
+364
+00:32:36,660 --> 00:32:42,560
+بسيطة كتيرفإن اللي بيحصل إنه بنعير ال EDTA عرفنا
+
+365
+00:32:42,560 --> 00:32:46,340
+كده عيارية أو تركيز ال EDTA، بعير في هذا المحول
+
+366
+00:32:46,340 --> 00:32:49,780
+اللي بحتوى على ال EDTA والمجنيزم EDTA أول نقطة
+
+367
+00:32:49,780 --> 00:32:53,600
+بتنزل تتفاعل مع ال metal ion، فيش مشكلة في هذا
+
+368
+00:32:53,600 --> 00:32:59,200
+الكلام، لكن ال metal ion اللي موجود هنالما ينضعف
+
+369
+00:32:59,200 --> 00:33:02,660
+عليه ميجنيزيام EDTA بيطلع لـ Free Magnesium لـ
+
+370
+00:33:02,660 --> 00:33:04,960
+Free Magnesium مع الـ I N تلاتة سالب يعطينا
+
+371
+00:33:04,960 --> 00:33:08,940
+ميجنيزيام I N سالب فورا وهذا Color 1 لما تستمر
+
+372
+00:33:08,940 --> 00:33:13,220
+المعايرة بيخلص ال M N Plus ال EDTA خلص فعلت معاها
+
+373
+00:33:13,220 --> 00:33:19,540
+كله طيب أول نقطة زيادة أه أول نقطة زيادة ال EDTA
+
+374
+00:33:19,540 --> 00:33:23,140
+تفعل مع الميجنيزيام Indicator تاخد الميجنيزيام من
+
+375
+00:33:23,140 --> 00:33:26,140
+ال Indicator و بتطلع ال I N تلاتة سالب اللي هو
+
+376
+00:33:26,140 --> 00:33:32,850
+عبارة عن Color 2تمام فهذه طريقة ممتازة للمعايرة
+
+377
+00:33:32,850 --> 00:33:37,190
+انا بنصحك انك تجربها في المختبر جربها يعنيكتير
+
+378
+00:33:37,190 --> 00:33:41,090
+كتير مفيدة و كتير يعني دائما ال indicator اللي أنا
+
+379
+00:33:41,090 --> 00:33:44,170
+بتطلع عليه لأي معايرة في الحقيقة هو عبارة عن
+
+380
+00:33:44,170 --> 00:33:50,650
+magnesium indicator complex ل free indicator و زي
+
+381
+00:33:50,650 --> 00:33:57,070
+ما شوفنا يعني مثلا إذا كان استخدمنا calcium أو بدل
+
+382
+00:33:57,070 --> 00:34:00,290
+ال magnesium برضه بينفع لإن برضه ال KF تبعه عشرة
+
+383
+00:34:00,290 --> 00:34:02,990
+أقص عشرة قريب من العشرة أقص تمانية تبعت ال
+
+384
+00:34:02,990 --> 00:34:07,790
+magnesium مش هالمشكلة الكبيرةلكن هيك عملية
+
+385
+00:34:07,790 --> 00:34:10,650
+المعايرة لأي نوع من أنواع الـmetal ions بتكون
+
+386
+00:34:10,650 --> 00:34:15,350
+عملية مباشرة وسهلة وال indicator مبمون لأنه هو
+
+387
+00:34:15,350 --> 00:34:19,890
+حاجة غير مباشرة بشكل يعني بسيط يعني مش كتير صعب
+
+388
+00:34:19,890 --> 00:34:25,770
+أنه الواحد يطبقه يتخيله ويطبقه على أي معايرة مافيش
+
+389
+00:34:25,770 --> 00:34:35,870
+إلها indicator مناسب طيب خلينا الآن نتطلع علىبعض
+
+390
+00:34:35,870 --> 00:34:40,590
+الأمثلة الحسابية كتطبيق
+
+391
+00:34:40,590 --> 00:34:46,060
+على الكلام اللي درسناه في الحصة الماضيةنتقل على
+
+392
+00:34:46,060 --> 00:34:50,880
+المثال التالي، find the concentrations of all
+
+393
+00:34:50,880 --> 00:34:56,060
+species in solution at equilibrium resulting from
+
+394
+00:34:56,060 --> 00:35:02,060
+mixing 50 ml من 0.2 molar calcium with 50 ml of 0
+
+395
+00:35:02,060 --> 00:35:06,760
+.1 molar EDTA adjusted to pH 10، لازم في ال
+
+396
+00:35:06,760 --> 00:35:10,160
+complexometric reactions و titrations يقول ال pH
+
+397
+00:35:10,990 --> 00:35:14,330
+لأن هال pH مهمة كتير بالذات في ال titrations لأنه
+
+398
+00:35:14,330 --> 00:35:18,970
+انا لما بدي اجي احسب بدي اضطر احسب قيمة ال Y4-
+
+399
+00:35:18,970 --> 00:35:22,850
+وقيمة ال Y4- اتوقف على ال pH زي ما شوفنا الحصة
+
+400
+00:35:22,850 --> 00:35:27,790
+الماضية هان بيعطيني بيقول ال alpha 4 at pH 10 is 0
+
+401
+00:35:27,790 --> 00:35:34,610
+.35 اعطاني قيمة ال alpha 4طبعا في اي امتحان يعني
+
+402
+00:35:34,610 --> 00:35:38,450
+بعطيه قيمة ال alpha 4 و اي alpha اكتر من alpha 2
+
+403
+00:35:38,450 --> 00:35:40,730
+انا بعطيه قيمتها يعني المفروض انك تقدر تحسن في
+
+404
+00:35:40,730 --> 00:35:44,570
+الامتحان بس لغاية alpha 2 ليه؟ لأنه ممكنش هيك تضيع
+
+405
+00:35:44,570 --> 00:35:47,590
+وجت في alpha 3 او alpha 4 بتاخد شوية وجت الزيادة
+
+406
+00:35:48,240 --> 00:35:51,440
+فبيقول الفا فور ات بي اتش تين is point three five
+
+407
+00:35:51,440 --> 00:35:55,500
+والكف خمسة في عشرة اقص عشرة طيب يا شباب انا عندي
+
+408
+00:35:55,500 --> 00:35:59,540
+محلولين محلول كالسيوم محلول EDTA انا بعرف انهم
+
+409
+00:35:59,540 --> 00:36:03,420
+بيتفاعلوا مع بعض تفاعل ممتاز وهي الكف عندي جداش
+
+410
+00:36:03,420 --> 00:36:07,920
+عشرة اقص عشرة ففي مادتين خلطناهم مع بعض و هم
+
+411
+00:36:07,920 --> 00:36:16,000
+بيتفاعلوا اذا مدام بيتفاعلوا بدى احسبجديش عندى من
+
+412
+00:36:16,000 --> 00:36:20,340
+الأول جديش عندى من التانى ايش اللى بيزيد و ايش
+
+413
+00:36:20,340 --> 00:36:25,440
+اللى بيتكون ايش اللى بيزيد و ايش اللى بيتكون فبقول
+
+414
+00:36:25,440 --> 00:36:30,660
+والله ال millimol calcium عشرة millimol point two
+
+415
+00:36:30,660 --> 00:36:37,260
+في خمسين millimol EDTA خمسة ال millimol هى عشرة و
+
+416
+00:36:37,260 --> 00:36:40,880
+هى خمسة هى كانت صفر الخمسة اتفاعل مع خمسة هى بيزيد
+
+417
+00:36:40,880 --> 00:36:47,550
+خمسة هى صفر هى خمسةماشي يا شباب اذا هذه millimoles
+
+418
+00:36:47,550 --> 00:36:51,470
+التركيزات ال calcium ال excess خمسة millimoles على
+
+419
+00:36:51,470 --> 00:36:57,130
+خمسين و خمسين مية يعني point O5 ال calcium Y2
+
+420
+00:36:57,130 --> 00:37:01,850
+minus formed خمسة اذا تركيز ال complex خمسة على
+
+421
+00:37:01,850 --> 00:37:09,390
+برضه خمسين زي خمسين مية يعني point O5طيب الآن مدام
+
+422
+00:37:09,390 --> 00:37:15,430
+حسبت تركيز المتبقي وتركيز المتكون تعالوا نحسب جداش
+
+423
+00:37:15,430 --> 00:37:20,810
+التركيزات at equilibrium الناواتج
+
+424
+00:37:20,810 --> 00:37:25,670
+بدها تقل بمقدار X والمتفاعلات بدها تزيد بمقدار X
+
+425
+00:37:28,640 --> 00:37:33,760
+At equilibrium لأن الـ KF كبير فالنواتج بتقل
+
+426
+00:37:33,760 --> 00:37:38,900
+المقدار X والمتفاعلات هي اللي بتزيد المقدار X نشوف
+
+427
+00:37:38,900 --> 00:37:39,960
+هذا الكلام
+
+428
+00:37:43,370 --> 00:37:46,930
+مع ال EDT بيعطينا calcium EDT هذي تركيزها point O5
+
+429
+00:37:46,930 --> 00:37:51,090
+هذي تركيزها الصفر هذي تركيزها point O5 اذا point
+
+430
+00:37:51,090 --> 00:37:55,470
+O5 minus X النواتج فهي تقل المقدار X المتفاعلات
+
+431
+00:37:55,470 --> 00:38:00,970
+point O5 زائد X اه ها لازم ناخد بالنا ال Y for
+
+432
+00:38:00,970 --> 00:38:06,990
+minus مش Xكل ال Y هي عبارة عن X يعني لما انتيجي
+
+433
+00:38:06,990 --> 00:38:11,670
+هذا ال calcium Y2- بتعطي Y4- لكن ال Y4- بتتحول
+
+434
+00:38:11,670 --> 00:38:15,890
+لهذا و لهذا و لهذا و لهذا و جزء منها بيظل Y4-
+
+435
+00:38:15,890 --> 00:38:20,330
+معايا انت؟ لكن ال equilibrium بيحتوي على إيه؟ على
+
+436
+00:38:20,330 --> 00:38:23,870
+ال Y4- لوحده زي ما شوفنا الحصة الماضية إذا مجددش
+
+437
+00:38:23,870 --> 00:38:29,390
+موجود على هيئة Y4- Alpha 4 من التركيز الكلي اللي
+
+438
+00:38:29,390 --> 00:38:35,110
+هو ال Xالـ X هي كل التركيز هذا CT أو الـ X هي كل
+
+439
+00:38:35,110 --> 00:38:38,610
+التركيز هذا فإن جداش موجود على هيئة Y for minus
+
+440
+00:38:38,610 --> 00:38:41,850
+Alpha 4 منه لازم تاخد بالك من هذه النقطة عشان
+
+441
+00:38:41,850 --> 00:38:46,250
+تشتغل صح أنا ال equilibrium بحتويش على كل ال Y
+
+442
+00:38:46,250 --> 00:38:50,150
+عشان أقول أه كل ال Y هي عبارة عن X أه كل ال Y هي
+
+443
+00:38:50,150 --> 00:38:53,310
+عبارة عن X لكن جداش موجود على هيئة Y for minus
+
+444
+00:38:53,310 --> 00:38:56,930
+اللي هي حاوظة في ال equilibrium Alpha 4 من ال X
+
+445
+00:38:58,720 --> 00:39:03,360
+تمام؟ هذه النقطة اللي لازم تاخد بالك منها طب الآن
+
+446
+00:39:03,360 --> 00:39:09,480
+لو قلنابدنا نطبق ال formation constant expression
+
+447
+00:39:09,480 --> 00:39:14,860
+بقدر أقول ال KF بدي يساوي النواتج على المتفاعلات 5
+
+448
+00:39:14,860 --> 00:39:18,400
+ف 10 أقصى 10 هذا ال KF 0.05 minus X اللي هي
+
+449
+00:39:18,400 --> 00:39:23,100
+النواتج 0.05 زائد X في ال alpha 4 X لو قلنا أن ال
+
+450
+00:39:23,100 --> 00:39:26,560
+0.05 أكبر كتير من ال X و لو عوضنا عن ال alpha 4
+
+451
+00:39:26,560 --> 00:39:31,340
+بقيمتها في المسألة اللي هي 0.35 بتطلع ال X عيننا 5
+
+452
+00:39:31,340 --> 00:39:36,630
+و 6 ف 10 أقصى ال 11خمسة أو ستة في عشر أقل سالب
+
+453
+00:39:36,630 --> 00:39:42,570
+إحدى عشر هل بالفعل ال X أقل كتير من ال point O5
+
+454
+00:39:42,570 --> 00:39:46,890
+العشر أقل سالب إحدى عشر هل بالفعل هي أقل كتير من
+
+455
+00:39:46,890 --> 00:39:50,510
+ال point O5 طبعا أقل كتير من ال point O5 مش بحاجة
+
+456
+00:39:50,510 --> 00:39:53,130
+لإن نحصل بال relative error لأن بالفعل أقل كتير من
+
+457
+00:39:53,130 --> 00:39:56,770
+ال point O5 إذا ال calcium اللي كان بيساوي point
+
+458
+00:39:56,770 --> 00:40:03,420
+O5 زائد X ال X لا تجمع يعني point O5والكلّة
+
+459
+00:40:03,420 --> 00:40:07,940
+concentration point O5 minus X ال X لا تترح من ال
+
+460
+00:40:07,940 --> 00:40:12,040
+point O5 لأنه كمية 10 أقص سالب 11 فبتبقى point O5
+
+461
+00:40:12,040 --> 00:40:15,440
+طب ال Y for minus هي اللي موجودة في ال equilibrium
+
+462
+00:40:15,440 --> 00:40:22,120
+Alpha 4 من X point 3 5 في قيمة ال X بتطلع أنه 1 9
+
+463
+00:40:22,120 --> 00:40:30,570
+في 10 أقص سالب 11 ماشي يا شبابإذن بدنا ناخد بالنا
+
+464
+00:40:30,570 --> 00:40:38,830
+من طريقة حساب التركيزات و ناخد بالنا أن ال Y4-
+
+465
+00:40:38,830 --> 00:40:43,470
+اللي عندى في ال equilibrium مش هي كل ال Y ال Y4-
+
+466
+00:40:43,470 --> 00:40:48,130
+اللي طلعت بتتجزق فورا بحسب ال pH لما نكون ال pH
+
+467
+00:40:48,130 --> 00:40:54,610
+عالية ال Y4- بتزيدلما تكون ال pH منخفضة ال Y4-
+
+468
+00:40:54,610 --> 00:41:00,610
+بتجل فال Y4- قيمتها بحسب ال pH وهذه اللي موجودة
+
+469
+00:41:00,610 --> 00:41:04,230
+وعشان هيك بنقول Alpha 4 من ال total concentration
+
+470
+00:41:04,230 --> 00:41:08,830
+لل Y Alpha 4 من ال CT أو ال total concentration
+
+471
+00:41:09,810 --> 00:41:16,610
+كمان مسألة نفس الطريقة بقول calculate PCA PCA يعني
+
+472
+00:41:16,610 --> 00:41:20,550
+minus log التركيز الكالسيوم لان احنا اتفجنا على ان
+
+473
+00:41:20,550 --> 00:41:26,190
+ال P function هي عبارة عن minus log التركيز فبقول
+
+474
+00:41:26,190 --> 00:41:32,450
+calculate the PCA of a solution at pH 10 after
+
+475
+00:41:32,450 --> 00:41:37,730
+addition of 100 ml of 0.1 molar calcium to 100 ml
+
+476
+00:41:37,730 --> 00:41:43,200
+of 0.1 molar EDTAخلطنا 100 مل من الكالسيوم لتركيز
+
+477
+00:41:43,200 --> 00:41:48,120
+1 من 10 مع 100 مل من ال EDTA لتركيز 1 من 10 عند pH
+
+478
+00:41:48,120 --> 00:41:53,080
+10 بقول لي alpha 4 at pH 10 لازم يعطيها لي لازم
+
+479
+00:41:53,080 --> 00:41:55,800
+يعطينا ال alpha 4 و عند ال pH اللي أنا بشتغل عندها
+
+480
+00:41:55,800 --> 00:42:01,420
+alpha 4 at pH 10 is 0.35 و ال KF 5 في 10 أقصى 10
+
+481
+00:42:01,420 --> 00:42:06,400
+كمان مرة بقول في عندي حاجتين بتفاعلوا كالسيوم و
+
+482
+00:42:06,400 --> 00:42:10,070
+EDTAبدي احسب الـ millimole من الأول و millimole من
+
+483
+00:42:10,070 --> 00:42:13,110
+التاني حسب ال stoichiometric طبعا واحد لواحد ايش
+
+484
+00:42:13,110 --> 00:42:18,030
+اللي بيتبقى و ايش اللي بيتكون فان عندي هان ال
+
+485
+00:42:18,030 --> 00:42:21,610
+millimole calcium point one في مية عشرة EDTA point
+
+486
+00:42:21,610 --> 00:42:25,550
+one في مية عشرة اذا هذه عشرة هذه عشرة هذه صفر هذه
+
+487
+00:42:25,550 --> 00:42:30,790
+صفر هذه صفرهذه عشرة millimoles إذاً هذه وكأنها هي
+
+488
+00:42:30,790 --> 00:42:33,370
+عبارة عن equivalence point لو كانت في titration
+
+489
+00:42:33,370 --> 00:42:37,030
+هذه عبارة عن equivalence point لو كانت في
+
+490
+00:42:37,030 --> 00:42:40,790
+titration فبقول والله مافيش عندنا غير calcium y2
+
+491
+00:42:40,790 --> 00:42:46,270
+minus طب إيش تركيزها جال calcium y2 minus اللي هو
+
+492
+00:42:46,270 --> 00:42:49,630
+عشرة millimoles على ال total volume 100 و100 200
+
+493
+00:42:49,630 --> 00:42:52,450
+بتصير عندنا point or five
+
+494
+00:42:54,950 --> 00:42:59,450
+يبقى في عندي المحلول فيه فقط calcium y2- لكن انا
+
+495
+00:42:59,450 --> 00:43:05,530
+بدي احسب ال P لل-CA هي صفر بس at equilibrium لأ مش
+
+496
+00:43:05,530 --> 00:43:10,480
+صفر ماينفعش تكون صفرفبقول والله من المعادلة من
+
+497
+00:43:10,480 --> 00:43:14,600
+المعادلة calcium زائد y4 minus calcium y2 minus ال
+
+498
+00:43:14,600 --> 00:43:18,420
+kf بتساوي ال calcium y2 minus على ال calcium في ال
+
+499
+00:43:18,420 --> 00:43:22,940
+y4 minus لكن ال y4 minus بتساوي alpha four من ال
+
+500
+00:43:22,940 --> 00:43:26,340
+ct ال ct هو عبارة عن تركيز ال calcium لأن ال
+
+501
+00:43:26,340 --> 00:43:32,080
+calcium y2 minus لما تتفكك بتعطيY و بتعطي كالسيوم
+
+502
+00:43:32,080 --> 00:43:36,180
+لكن هذه يا شباب اتجزأت صارت هذه و هذه و هذه و
+
+503
+00:43:36,180 --> 00:43:40,640
+الاخره فإيش ال Y4-؟ هي عبارة عن Alpha 4 من ال CT
+
+504
+00:43:40,640 --> 00:43:46,680
+يعني هذا ال Y4- ال Y كلها عبارة عن ال CT ال CT
+
+505
+00:43:46,680 --> 00:43:51,960
+بتسوي الكالسيوم لأن ال calcium Y2- بتعطي Y و بتعطي
+
+506
+00:43:51,960 --> 00:43:58,080
+كالسيوم لكن ال Y اتجزأتالـ Y4- هي عبارة عن Alpha 4
+
+507
+00:43:58,080 --> 00:44:02,980
+من قيمة الـ Y كلها يعني من الـ CT فبالتالي بقول
+
+508
+00:44:02,980 --> 00:44:05,940
+والله خمسة في عشرة أقصى عشرة point oh five على ال
+
+509
+00:44:05,940 --> 00:44:10,400
+calcium square في point three five أو ال calcium
+
+510
+00:44:10,400 --> 00:44:13,360
+one point seven في عشرة أقصى سالب ستة موادر أو ال
+
+511
+00:44:13,360 --> 00:44:17,200
+P للكالسيوم خمسة وسبعة وسبعين لكن أنا بفضل أنه
+
+512
+00:44:17,200 --> 00:44:22,120
+اتحل بالشكل هذا بفضل اتحل بالشكل هذا اتقول والله
+
+513
+00:44:22,120 --> 00:44:24,920
+المعادلة تبعتي
+
+514
+00:44:27,500 --> 00:44:32,000
+كالسيوم زائد Y4-كالسيوم Y2- وهذه صفر وهذه صفر وهذه
+
+515
+00:44:32,000 --> 00:44:36,760
+point of I وهذه ستتقل المقدار X وهذه عبارة عن X
+
+516
+00:44:36,760 --> 00:44:42,880
+وهذه عبارة عن Alpha 4 من X إذا كان كل اللي .. كل
+
+517
+00:44:42,880 --> 00:44:46,540
+اللي إجا X فهذه ال Y4 منه عبارة عن Alpha 4 منهالفا
+
+518
+00:44:46,540 --> 00:44:51,760
+فور من ال X وبتعود في المعادلة ال KF بده يساوي
+
+519
+00:44:51,760 --> 00:44:56,580
+point of five minus X على ال X الفا فور X معنى
+
+520
+00:44:56,580 --> 00:44:59,320
+الكلام نفترض ان ال point of five أكبر كتير من ال X
+
+521
+00:44:59,320 --> 00:45:02,540
+ال X بتطلع القيمة اللي احنا شوفناها واحد وسبعة في
+
+522
+00:45:02,540 --> 00:45:06,200
+عشر أقل سالب ستة ال relative error طبعا قليل جدا
+
+523
+00:45:06,200 --> 00:45:09,020
+جدا يبقى ال calcium بده يساوي واحد وسبعة في عشر
+
+524
+00:45:09,020 --> 00:45:14,040
+أقل سالب ستة molar او ال P للكالسيوم خمسة وسبعة
+
+525
+00:45:14,040 --> 00:45:19,820
+وسبعينإذا الله راد الحصة الجاية هناخد مثال على ال
+
+526
+00:45:19,820 --> 00:45:24,100
+titer مع أنه يعني احنا درسناه قبل هيك لكن موضوع
+
+527
+00:45:24,100 --> 00:45:32,140
+مهم فيما يتعلق بال EDTA و بعده هناخد مثال آخرناخد
+
+528
+00:45:32,140 --> 00:45:36,820
+مثال تالت على إيش بحصل أثناء ال complexometric
+
+529
+00:45:36,820 --> 00:45:41,240
+titration يعني بدنا نحسب ال P للmetal ion after
+
+530
+00:45:41,240 --> 00:45:44,340
+addition of zero before equivalence point at
+
+531
+00:45:44,340 --> 00:45:47,700
+equivalence point و after equivalence point فهذا
+
+532
+00:45:47,700 --> 00:45:50,800
+الكلام إذا الله راضي الحصة الجاية بنشوفه و بنشوفكم
+
+533
+00:45:50,800 --> 00:45:53,340
+ان شاء الله يوم الأربعة
+
diff --git a/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/TI0SnTXAa-s_raw.json b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/TI0SnTXAa-s_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..f79d0368976fbf13bed353c5462da7ac9b922484
--- /dev/null
+++ b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/TI0SnTXAa-s_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 3173, "start": 22.19, "end": 31.73, "text": "بسم الله الرحمن الرحيم اليوم ان شاء الله بنحاول نتكلم عن ال titration of mixtures of acids", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640, 45595, 20498, 16472, 13412, 16606, 21984, 44945, 5016, 995, 12610, 8717, 2655, 4117, 19528, 18871, 2423, 3459, 2405, 295, 2752, 37610, 295, 21667], "avg_logprob": -0.12843276515151514, "compression_ratio": 1.3269230769230769, "no_speech_prob": 1.1920928955078125e-07, "words": [{"start": 22.19, "end": 22.49, "word": "بسم", "probability": 0.8388671875}, {"start": 22.49, "end": 22.67, "word": " الله", "probability": 0.96826171875}, {"start": 22.67, "end": 22.95, "word": " الرحمن", "probability": 0.962890625}, {"start": 22.95, "end": 23.67, "word": " الرحيم", "probability": 0.994140625}, {"start": 23.67, "end": 24.65, "word": " اليوم", "probability": 0.79931640625}, {"start": 24.65, "end": 24.83, "word": " ان", "probability": 0.62451171875}, {"start": 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161101, "start": 1594.45, "end": 1611.01, "text": "على أي حال تعالوا نتطلع على هذا المثال و نحاول نمشي في خطوة خطوة بقول find the pH of a 50 ml solution containing 0.1 molar sodium hydroxide and 0.1 molar sodium carbonate", "tokens": [3615, 23942, 36632, 11331, 6027, 37279, 6027, 14407, 8717, 2655, 9566, 1211, 3615, 15844, 23758, 9673, 12984, 6027, 4032, 8717, 5016, 995, 12610, 8717, 2304, 8592, 1829, 8978, 16490, 9566, 2407, 3660, 16490, 9566, 2407, 3660, 4724, 39648, 915, 264, 21677, 295, 257, 2625, 23271, 3827, 19273, 1958, 13, 16, 45712, 20265, 15435, 34454, 293, 1958, 13, 16, 45712, 20265, 5954, 473], "avg_logprob": -0.14409722411443318, "compression_ratio": 1.331360946745562, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 1594.45, "end": 1594.83, "word": "على", "probability": 0.90771484375}, {"start": 1594.83, "end": 1595.01, "word": " أي", "probability": 0.5810546875}, {"start": 1595.01, "end": 1595.31, "word": " حال", "probability": 0.998046875}, {"start": 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"probability": 0.9111328125}, {"start": 2293.57, "end": 2293.81, "word": " 5", "probability": 0.89697265625}, {"start": 2293.81, "end": 2293.99, "word": " و", "probability": 0.67578125}, {"start": 2293.99, "end": 2294.29, "word": " رحوا", "probability": 0.685791015625}, {"start": 2294.29, "end": 2294.39, "word": " ال", "probability": 0.67626953125}, {"start": 2294.39, "end": 2294.47, "word": " 2", "probability": 0.62548828125}, {"start": 2294.47, "end": 2294.67, "word": ".5", "probability": 0.995849609375}, {"start": 2294.67, "end": 2294.79, "word": " اللي", "probability": 0.960205078125}, {"start": 2294.79, "end": 2295.19, "word": " ضايقين", "probability": 0.65545654296875}], "temperature": 1.0}, {"id": 100, "seek": 231537, "start": 2295.71, "end": 2315.37, "text": "تحولوا للـ B-Carbonate لأن دائما الـ Carbonate و الـ B-Carbonate و الـ Carbonic Acid مجموعة كلهم خمسة فالفئة اللي عندى دلوقت بس Carbonate و أخدت H بلس صارت B-Carbonate فالـ B-Carbonate 2.5 إذا تركيز الـ B-Carbonate برضه 2.5 على 125", "tokens": [2655, 5016, 12610, 14407, 24976, 39184, 363, 12, 24437, 4351, 473, 5296, 33456, 11778, 16373, 15042, 2423, 39184, 2741, 65, 266, 473, 4032, 2423, 39184, 363, 12, 24437, 4351, 473, 4032, 2423, 39184, 31453, 299, 5097, 327, 3714, 7435, 2304, 2407, 27884, 28242, 16095, 16490, 2304, 3794, 3660, 6156, 6027, 5172, 19986, 3660, 13672, 1829, 43242, 7578, 11778, 1211, 30543, 2655, 4724, 3794, 31453, 473, 4032, 5551, 9778, 3215, 2655, 389, 4724, 1211, 3794, 20328, 9640, 2655, 363, 12, 24437, 4351, 473, 6156, 6027, 39184, 363, 12, 24437, 4351, 473, 568, 13, 20, 11933, 15730, 6055, 31747, 1829, 11622, 2423, 39184, 363, 12, 24437, 4351, 473, 4724, 43042, 3224, 568, 13, 20, 15844, 25276], "avg_logprob": -0.32146740581678307, "compression_ratio": 1.6994818652849741, "no_speech_prob": 4.76837158203125e-07, "words": [{"start": 2295.71, "end": 2296.39, "word": "تحولوا", "probability": 0.7343597412109375}, {"start": 2296.39, "end": 2297.03, "word": " للـ", "probability": 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{"start": 2327.17, "end": 2327.79, "word": " المعادلة", "probability": 0.9876708984375}, {"start": 2327.79, "end": 2329.19, "word": " الكربونات", "probability": 0.89521484375}, {"start": 2329.19, "end": 2329.57, "word": " تعطيني", "probability": 0.7572021484375}, {"start": 2329.57, "end": 2330.15, "word": " hydroxide", "probability": 0.6890869140625}, {"start": 2330.15, "end": 2330.39, "word": " او", "probability": 0.6639404296875}, {"start": 2330.39, "end": 2331.99, "word": " بيكربونات", "probability": 0.9227818080357143}, {"start": 2331.99, "end": 2332.73, "word": " لكن", "probability": 0.701171875}, {"start": 2332.73, "end": 2333.41, "word": " الاسهل", "probability": 0.84307861328125}, {"start": 2333.41, "end": 2333.59, "word": " ان", "probability": 0.8330078125}, {"start": 2333.59, "end": 2333.93, "word": " اقول", "probability": 0.95703125}, {"start": 2333.93, "end": 2334.27, "word": " والله", "probability": 0.7275390625}, {"start": 2334.27, "end": 2334.43, "word": " ال", "probability": 0.884765625}, {"start": 2334.43, "end": 2335.43, "word": " HCO3", "probability": 0.8238932291666666}, {"start": 2335.43, "end": 2335.95, "word": " minus", "probability": 0.2113037109375}, {"start": 2335.95, "end": 2336.77, "word": " تعطيني", "probability": 0.9560546875}, {"start": 2336.77, "end": 2336.95, "word": " H", "probability": 0.86181640625}, {"start": 2336.95, "end": 2337.39, "word": " plus", "probability": 0.267578125}, {"start": 2337.39, "end": 2338.49, "word": " زائد", "probability": 0.8059895833333334}, {"start": 2338.49, "end": 2340.43, "word": " كربونات", "probability": 0.92568359375}], "temperature": 1.0}, {"id": 102, "seek": 235548, "start": 2341.0, "end": 2355.48, "text": "أستخدم هذه المعادلة أحسن من هذه لماذا؟ لأن هذه المعادلة بتعطيني الـ H Plus على طول لكن المعادلة التانية صح 100% يمكن أن استخدمتها لأنه خلاص صار عند الـ KB موجود و يعني المعادلة موجودة", "tokens": [10721, 14851, 9778, 40448, 29538, 9673, 3615, 18513, 37977, 5551, 5016, 3794, 1863, 9154, 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"word": " الكربونيت", "probability": 0.65118408203125}, {"start": 2439.66, "end": 2439.88, "word": " عشان", "probability": 0.82568359375}, {"start": 2439.88, "end": 2440.3, "word": " يتحولها", "probability": 0.88564453125}, {"start": 2440.3, "end": 2440.44, "word": " لـ", "probability": 0.467041015625}, {"start": 2440.44, "end": 2440.56, "word": " B", "probability": 0.465087890625}, {"start": 2440.56, "end": 2441.14, "word": "-Carbonate", "probability": 0.731689453125}], "temperature": 1.0}, {"id": 107, "seek": 246712, "start": 2441.88, "end": 2467.12, "text": "أنا اضفت 50 مل على الكربونات بقول ملي مول كربونات left point one في خمسين هذا الكربونات اللى موجودة ايش اضفت عليها خمسين مل من point one molar hcl اذا انجدشت علي الكربونات صفر this is the second equivalence point او ال first equivalence point الخاصة بالكربونات طيب الآن كل الكربونات خلصت لإيش اتحولت؟", "tokens": [10721, 8315, 1975, 11242, 5172, 2655, 2625, 3714, 1211, 15844, 33251, 25513, 11536, 9307, 4724, 39648, 3714, 20292, 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" equivalence", "probability": 0.829345703125}, {"start": 2459.8, "end": 2460.08, "word": " point", "probability": 0.98583984375}, {"start": 2460.08, "end": 2460.3, "word": " او", "probability": 0.904052734375}, {"start": 2460.3, "end": 2460.42, "word": " ال", "probability": 0.83349609375}, {"start": 2460.42, "end": 2460.82, "word": " first", "probability": 0.84423828125}, {"start": 2460.82, "end": 2461.68, "word": " equivalence", "probability": 0.94921875}, {"start": 2461.68, "end": 2461.98, "word": " point", "probability": 0.98681640625}, {"start": 2461.98, "end": 2462.44, "word": " الخاصة", "probability": 0.8798828125}, {"start": 2462.44, "end": 2463.22, "word": " بالكربونات", "probability": 0.9478515625}, {"start": 2463.22, "end": 2464.48, "word": " طيب", "probability": 0.955078125}, {"start": 2464.48, "end": 2464.74, "word": " الآن", "probability": 0.6082763671875}, {"start": 2464.74, "end": 2464.98, "word": " كل", "probability": 0.97900390625}, {"start": 2464.98, "end": 2465.46, 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{"start": 2794.11, "end": 2794.41, "word": " تكون", "probability": 0.99169921875}, {"start": 2794.41, "end": 2794.87, "word": " قادر", "probability": 0.9905598958333334}, {"start": 2794.87, "end": 2795.05, "word": " على", "probability": 0.9345703125}, {"start": 2795.05, "end": 2795.69, "word": " تحقيقها", "probability": 0.9447265625}], "temperature": 1.0}, {"id": 123, "seek": 281897, "start": 2796.71, "end": 2818.97, "text": "لكن بالنسبة لنا هان واضح انه لو حكيت حتى ماكملتش الحل لو قلت ان ال H2CO3 بتفكك بشكل هذا و الكائن و قليل و في وجود ال common ion هيرجع اكتر يعني ال H plus اللى جاية منه لاتكن تذكر بجبل منك هذا الكلام لكن الأحسن انك تقدر تخسمها و تحسب relative error و تقولي والله ان هذه مهملة", "tokens": [1211, 19452, 20666, 1863, 35457, 3660, 5296, 8315, 8032, 7649, 4032, 46958, 5016, 16472, 3224, 45164, 11331, 4117, 36081, 11331, 49975, 19446, 24793, 1211, 2655, 8592, 21542, 1211, 45164, 12174, 1211, 2655, 16472, 2423, 389, 17, 12322, 18, 39894, 5172, 4117, 4117, 4724, 8592, 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{"start": 2798.41, "end": 2799.05, "word": " واضح", "probability": 0.8824869791666666}, {"start": 2799.05, "end": 2799.87, "word": " انه", "probability": 0.4266357421875}, {"start": 2799.87, "end": 2800.11, "word": " لو", "probability": 0.9541015625}, {"start": 2800.11, "end": 2800.67, "word": " حكيت", "probability": 0.9671223958333334}, {"start": 2800.67, "end": 2800.97, "word": " حتى", "probability": 0.86767578125}, {"start": 2800.97, "end": 2801.59, "word": " ماكملتش", "probability": 0.88935546875}, {"start": 2801.59, "end": 2801.93, "word": " الحل", "probability": 0.98828125}, {"start": 2801.93, "end": 2802.31, "word": " لو", "probability": 0.583984375}, {"start": 2802.31, "end": 2802.61, "word": " قلت", "probability": 0.8546549479166666}, {"start": 2802.61, "end": 2802.75, "word": " ان", "probability": 0.845703125}, {"start": 2802.75, "end": 2802.91, "word": " ال", "probability": 0.9052734375}, {"start": 2802.91, "end": 2803.81, "word": " H2CO3", "probability": 0.85205078125}, {"start": 2803.81, "end": 2804.37, "word": " بتفكك", "probability": 0.935302734375}, {"start": 2804.37, "end": 2804.77, "word": " بشكل", "probability": 0.87353515625}, {"start": 2804.77, "end": 2805.07, "word": " هذا", "probability": 0.6259765625}, {"start": 2805.07, "end": 2805.47, "word": " و", "probability": 0.8349609375}, {"start": 2805.47, "end": 2805.95, "word": " الكائن", "probability": 0.7180989583333334}, {"start": 2805.95, "end": 2806.05, "word": " و", "probability": 0.79638671875}, {"start": 2806.05, "end": 2806.47, "word": " قليل", "probability": 0.9005533854166666}, {"start": 2806.47, "end": 2806.71, "word": " و", "probability": 0.9404296875}, {"start": 2806.71, "end": 2806.79, "word": " في", "probability": 0.7392578125}, {"start": 2806.79, "end": 2807.07, "word": " وجود", "probability": 0.964111328125}, {"start": 2807.07, "end": 2807.19, "word": " ال", "probability": 0.89697265625}, {"start": 2807.19, "end": 2807.37, "word": " common", "probability": 0.865234375}, {"start": 2807.37, "end": 2807.61, "word": " ion", "probability": 0.7529296875}, {"start": 2807.61, "end": 2808.03, "word": " هيرجع", "probability": 0.8294270833333334}, {"start": 2808.03, "end": 2808.33, "word": " اكتر", "probability": 0.91357421875}, {"start": 2808.33, "end": 2808.59, "word": " يعني", "probability": 0.852294921875}, {"start": 2808.59, "end": 2808.71, "word": " ال", "probability": 0.95068359375}, {"start": 2808.71, "end": 2808.87, "word": " H", "probability": 0.91259765625}, {"start": 2808.87, "end": 2809.27, "word": " plus", "probability": 0.1412353515625}, {"start": 2809.27, "end": 2809.69, "word": " اللى", "probability": 0.765625}, {"start": 2809.69, "end": 2809.89, "word": " جاية", "probability": 0.7877604166666666}, {"start": 2809.89, "end": 2810.09, "word": " منه", "probability": 0.974853515625}, {"start": 2810.09, "end": 2810.49, "word": " لاتكن", "probability": 0.5846354166666666}, {"start": 2810.49, "end": 2810.93, "word": " تذكر", "probability": 0.8836263020833334}, {"start": 2810.93, "end": 2811.57, "word": " بجبل", "probability": 0.7119954427083334}, {"start": 2811.57, "end": 2812.11, "word": " منك", "probability": 0.9580078125}, {"start": 2812.11, "end": 2813.11, "word": " هذا", "probability": 0.9404296875}, {"start": 2813.11, "end": 2813.51, "word": " الكلام", "probability": 0.97412109375}, {"start": 2813.51, "end": 2813.73, "word": " لكن", "probability": 0.5556640625}, {"start": 2813.73, "end": 2814.39, "word": " الأحسن", "probability": 0.87188720703125}, {"start": 2814.39, "end": 2814.99, "word": " انك", "probability": 0.824462890625}, {"start": 2814.99, "end": 2815.27, "word": " تقدر", "probability": 0.9798177083333334}, {"start": 2815.27, "end": 2815.85, "word": " تخسمها", "probability": 0.7103515625}, {"start": 2815.85, "end": 2816.19, "word": " و", "probability": 0.441162109375}, {"start": 2816.19, "end": 2816.51, "word": " تحسب", "probability": 0.83056640625}, {"start": 2816.51, "end": 2816.81, "word": " relative", "probability": 0.91552734375}, {"start": 2816.81, "end": 2817.21, "word": " error", "probability": 0.94189453125}, {"start": 2817.21, "end": 2817.55, "word": " و", "probability": 0.72900390625}, {"start": 2817.55, "end": 2817.87, "word": " تقولي", "probability": 0.7264404296875}, {"start": 2817.87, "end": 2818.13, "word": " والله", "probability": 0.783447265625}, {"start": 2818.13, "end": 2818.31, "word": " ان", "probability": 0.7353515625}, {"start": 2818.31, "end": 2818.55, "word": " هذه", "probability": 0.170166015625}, {"start": 2818.55, "end": 2818.97, "word": " مهملة", "probability": 0.8995768229166666}], "temperature": 1.0}, {"id": 124, "seek": 283752, "start": 2819.56, "end": 2837.52, "text": "هذا هو الحل الصحيح بضل علينا يا شباب نقطة صغيرة في هذا ال chapter إذا الله راد الحصة الجاية بتتكلم عنها النقطة بتتكلم عن تطبيقات على ال acid-base titrations و هناخد كل دال nitrogen analysis فالحصة الجاية إذا الله راد بنشوفكم", "tokens": [3224, 15730, 31439, 21542, 1211, 31767, 5016, 1829, 5016, 4724, 11242, 1211, 25894, 8315, 35186, 13412, 3555, 16758, 8717, 47432, 3660, 20328, 17082, 48923, 8978, 23758, 2423, 7187, 11933, 15730, 21984, 12602, 18513, 21542, 9381, 3660, 25724, 995, 10632, 39894, 2655, 4117, 19528, 18871, 11296, 28239, 47432, 3660, 39894, 2655, 4117, 19528, 18871, 6055, 9566, 21292, 4587, 9307, 15844, 2423, 8258, 12, 17429, 3459, 12154, 4032, 8032, 1863, 47283, 3215, 28242, 11778, 6027, 17903, 5215, 6156, 6027, 5016, 9381, 3660, 25724, 995, 10632, 11933, 15730, 21984, 12602, 18513, 44945, 8592, 38688, 24793], "avg_logprob": -0.16910281681245373, "compression_ratio": 1.7264150943396226, "no_speech_prob": 3.641843795776367e-05, "words": [{"start": 2819.56, "end": 2819.9, "word": "هذا", "probability": 0.891357421875}, {"start": 2819.9, "end": 2820.0, "word": " هو", "probability": 0.95556640625}, {"start": 2820.0, "end": 2820.32, "word": " الحل", "probability": 0.985595703125}, {"start": 2820.32, "end": 2820.9, "word": " الصحيح", "probability": 0.9871826171875}, {"start": 2820.9, "end": 2821.58, "word": " بضل", "probability": 0.4558919270833333}, {"start": 2821.58, "end": 2821.9, "word": " علينا", "probability": 0.928955078125}, {"start": 2821.9, "end": 2822.02, "word": " يا", "probability": 0.91748046875}, {"start": 2822.02, "end": 2822.52, "word": " شباب", "probability": 0.9899088541666666}, {"start": 2822.52, "end": 2823.22, "word": " نقطة", "probability": 0.95849609375}, {"start": 2823.22, "end": 2823.56, "word": " صغيرة", "probability": 0.9899088541666666}, {"start": 2823.56, "end": 2823.72, "word": " في", "probability": 0.91259765625}, {"start": 2823.72, "end": 2823.96, "word": " هذا", "probability": 0.93505859375}, {"start": 2823.96, "end": 2824.04, "word": " ال", "probability": 0.53076171875}, {"start": 2824.04, "end": 2824.38, "word": " chapter", "probability": 0.51953125}, {"start": 2824.38, "end": 2824.78, "word": " إذا", "probability": 0.84130859375}, {"start": 2824.78, "end": 2824.98, "word": " الله", "probability": 0.86376953125}, {"start": 2824.98, "end": 2825.38, "word": " راد", "probability": 0.72998046875}, {"start": 2825.38, "end": 2826.32, "word": " الحصة", "probability": 0.9412434895833334}, {"start": 2826.32, "end": 2826.8, "word": " الجاية", "probability": 0.9388020833333334}, {"start": 2826.8, "end": 2827.42, "word": " بتتكلم", "probability": 0.80645751953125}, {"start": 2827.42, "end": 2827.76, "word": " عنها", "probability": 0.964599609375}, {"start": 2827.76, "end": 2828.64, "word": " النقطة", "probability": 0.81689453125}, {"start": 2828.64, "end": 2829.12, "word": " بتتكلم", "probability": 0.9010009765625}, {"start": 2829.12, "end": 2829.4, "word": " عن", "probability": 0.9912109375}, {"start": 2829.4, "end": 2830.42, "word": " تطبيقات", "probability": 0.92744140625}, {"start": 2830.42, "end": 2830.6, "word": " على", "probability": 0.87158203125}, {"start": 2830.6, "end": 2830.72, "word": " ال", "probability": 0.98046875}, {"start": 2830.72, "end": 2830.9, "word": " acid", "probability": 0.90380859375}, {"start": 2830.9, "end": 2831.16, "word": "-base", "probability": 0.62744140625}, {"start": 2831.16, "end": 2831.78, "word": " titrations", "probability": 0.81689453125}, {"start": 2831.78, "end": 2832.2, "word": " و", "probability": 0.73681640625}, {"start": 2832.2, "end": 2832.74, "word": " هناخد", "probability": 0.8878173828125}, {"start": 2832.74, "end": 2833.0, "word": " كل", "probability": 0.380615234375}, {"start": 2833.0, "end": 2833.44, "word": " دال", "probability": 0.794189453125}, {"start": 2833.44, "end": 2834.26, "word": " nitrogen", "probability": 0.7333984375}, {"start": 2834.26, "end": 2835.16, "word": " analysis", "probability": 0.78125}, {"start": 2835.16, "end": 2835.94, "word": " فالحصة", "probability": 0.9400390625}, {"start": 2835.94, "end": 2836.24, "word": " الجاية", "probability": 0.97021484375}, {"start": 2836.24, "end": 2836.46, "word": " إذا", "probability": 0.978515625}, {"start": 2836.46, "end": 2836.62, "word": " الله", "probability": 0.94970703125}, {"start": 2836.62, "end": 2836.9, "word": " راد", "probability": 0.983154296875}, {"start": 2836.9, "end": 2837.52, "word": " بنشوفكم", "probability": 0.8082275390625}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2838.36075, "duration_after_vad": 2739.978749999992}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/UYz7-7JfQps_raw.srt b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/UYz7-7JfQps_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..22938214948afc9150e6f17d0c602d18466bc23b
--- /dev/null
+++ b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/UYz7-7JfQps_raw.srt
@@ -0,0 +1,2016 @@
+1
+00:00:20,890 --> 00:00:25,310
+بسم الله الرحمن الرحيم الحصة الماضية يا شباب شوفنا
+
+2
+00:00:25,310 --> 00:00:31,290
+كيف نحسب ال pH لل salts of polyprotic acids فشوفنا
+
+3
+00:00:31,290 --> 00:00:36,090
+انه فيها نوعين من ال salts في salts قولنا بنسميها
+
+4
+00:00:36,090 --> 00:00:40,210
+unprotonated salts يعني مش فيها proton زي
+
+5
+00:00:40,210 --> 00:00:45,950
+الكربونيت او الفوسفيت او الأجزاليت مثلا وفي انا
+
+6
+00:00:45,950 --> 00:00:51,560
+salts ال protonatedفقلنا الـ Unprotonated salts
+
+7
+00:00:51,560 --> 00:00:56,200
+هدى بنعملها معاملة ال salts of monoprotic acids
+
+8
+00:00:56,200 --> 00:01:04,380
+فقط بنعوز نستخدم معها ال appropriate
+
+9
+00:01:06,010 --> 00:01:11,690
+عشان اوجد ال KB لل equilibrium لأن ال unprotonated
+
+10
+00:01:11,690 --> 00:01:16,330
+salt في الميه بتعطينا hydroxide يعني إلها KB KB
+
+11
+00:01:16,330 --> 00:01:20,590
+بيساوي KW على KA قلنا أنهي KA نستخدم لأن هذا salt
+
+12
+00:01:20,590 --> 00:01:28,750
+of polyprotic acid فبستخدم ال final equilibrium
+
+13
+00:01:28,750 --> 00:01:34,220
+constantأو بطلع على الشحنات اللي في المعادلة و
+
+14
+00:01:34,220 --> 00:01:38,700
+بستخدم أعلى شحنة فمثلا إذا كان المعادلة فيها أعلى
+
+15
+00:01:38,700 --> 00:01:42,360
+شحنة فيها 2 بستخدم ال KE2 إذا كان أعلى شحنة 3
+
+16
+00:01:42,360 --> 00:01:48,650
+بستخدم ال KE3 على سبيل المثالبينما الـ protonated
+
+17
+00:01:48,650 --> 00:01:53,950
+salts قلنا بنستخدم المعادلة اللى بتتوقف على هل ال
+
+18
+00:01:53,950 --> 00:01:59,090
+protonated salt single charged ولا bubbly charged
+
+19
+00:01:59,090 --> 00:02:02,470
+ولا triple charged ولا غير هيك إذا كان single
+
+20
+00:02:02,470 --> 00:02:07,290
+charged فالمعادلة H plus بتساوي الجزر التربيع ده K
+
+21
+00:02:07,290 --> 00:02:13,030
+A1 K W زائد K A1 K A2 تركيز ال saltعلى k a one
+
+22
+00:02:13,030 --> 00:02:16,850
+زائد تركيز ال salt بينما إذا كانت double charge
+
+23
+00:02:16,850 --> 00:02:20,530
+فمابدعش بال k a one مبدع طول k a two مافيش عندى k
+
+24
+00:02:20,530 --> 00:02:26,730
+a one k a two k w زائد k a two k a three تركيز ال
+
+25
+00:02:26,730 --> 00:02:31,330
+salt على k a two زائد تركيز ال salt كله تحت الجزر
+
+26
+00:02:31,330 --> 00:02:37,750
+و هكذا اليوم بس بذكركم انه دائما لازم نستخدم
+
+27
+00:02:37,750 --> 00:02:38,750
+النموذج
+
+28
+00:02:43,160 --> 00:02:47,580
+الأصلي للمعادلة يعني مش لازم أستخدم ال shortcut
+
+29
+00:02:47,580 --> 00:02:52,420
+إلا إذا كانت الشروط عندى تتحقق لإستخدام ال
+
+30
+00:02:52,420 --> 00:02:57,280
+shortcut لحساب ال pH فلو عندى point one molar
+
+31
+00:02:57,280 --> 00:03:02,040
+sodium b carbonate وعندي ال KAs لل carbonic acid
+
+32
+00:03:02,350 --> 00:03:05,890
+بقول و استخدمت القانون فبيطلع عند ال H plus أربعة
+
+33
+00:03:05,890 --> 00:03:09,390
+نص في عشرة أقل سالب تسعة في هذه الحالة لو استخدمت
+
+34
+00:03:09,390 --> 00:03:12,470
+أيضا ال shortcut هلاجي نفس النتيجة ليه؟ لأن
+
+35
+00:03:12,470 --> 00:03:16,110
+الشرطين اللي حكيت عنهم الحصة الماضية بيتحققوا
+
+36
+00:03:16,110 --> 00:03:20,010
+بينما لما استخدمنا عشرة أقل سالب أربعة مولار
+
+37
+00:03:20,010 --> 00:03:24,140
+Sodium B Carbonateفوجدنا إن استخدام القانون كان
+
+38
+00:03:24,140 --> 00:03:30,160
+بعطيني pH 8.1 بينما استخدام ال shortcut كان بعطيني
+
+39
+00:03:30,160 --> 00:03:36,820
+pH 38.4 يبقى في عندي خطأ أو في عندي عدم دقة في
+
+40
+00:03:36,820 --> 00:03:40,600
+الحساب فعشان هيك بنقول دائما الاصل إن استخدم
+
+41
+00:03:40,600 --> 00:03:46,520
+القانون بصيغته الصحيحة ما استخدمش ال shortcut إلا
+
+42
+00:03:46,520 --> 00:03:53,050
+إذا كان في عندي تحقيق للشرطين اللي ذكرتهمفي حالة
+
+43
+00:03:53,050 --> 00:03:56,570
+ما يكون في عند ال salt double charged بقولنا
+
+44
+00:03:56,570 --> 00:04:03,990
+بنتكلم عن H بلس بتساوي KA2KW زائد KA2 KA3 تركيز ال
+
+45
+00:04:03,990 --> 00:04:10,370
+salt على KA2 زائد تركيز ال salt كله تحت الجزر في
+
+46
+00:04:10,370 --> 00:04:14,350
+هذه الحالة مثلا في حالة point two molar sodium او
+
+47
+00:04:14,350 --> 00:04:17,570
+di sodium hydrogen phosphate بلاحظ ان ال pH بالصفر
+
+48
+00:04:17,570 --> 00:04:23,260
+عندنا تسعة وسبعة من عشرةالحسابات مباشرة كتير ممنوع
+
+49
+00:04:23,260 --> 00:04:29,100
+انك تروح ت .. اتفككلي مثلا في Sodium Dihydrogen
+
+50
+00:04:29,100 --> 00:04:33,180
+Phosphate او Dihydrogen Sodium Phosphate اتفككلي
+
+51
+00:04:33,180 --> 00:04:37,360
+على طول في الميه تقول بتعطي H Plus و مثلا PO4
+
+52
+00:04:37,360 --> 00:04:41,200
+تلاتة سالمبظبطش هذا الكلام، و تيجي تقولي و الله
+
+53
+00:04:41,200 --> 00:04:44,520
+هدى point two minus X هدى X هدى، بظبطش هذا الكلام،
+
+54
+00:04:44,520 --> 00:04:48,160
+ليه؟ لأنك بأي حق أنت فككت على أنها acid، ما هي
+
+55
+00:04:48,160 --> 00:04:53,000
+ممكن ال HPO42 سالب تاخد البروتون من الميه، وتعطينا
+
+56
+00:04:53,000 --> 00:04:59,350
+hydroxideفبالتالي إذا كان عندك protonated salt
+
+57
+00:04:59,350 --> 00:05:03,530
+ممنوع منع انبعاد تنقل انك اتفكك ال salt بصيغة
+
+58
+00:05:03,530 --> 00:05:08,330
+واحدة فقط ال salt مرة بيتصرف ك acid و مرة بيتصرف ك
+
+59
+00:05:08,330 --> 00:05:13,890
+base يعني في نوع من ال amphotericity وبالتالي يجب
+
+60
+00:05:13,890 --> 00:05:18,130
+اخذ ايضا تفكك الماء بعين الاعتبار وبالتالي ايضا
+
+61
+00:05:18,130 --> 00:05:20,110
+يجب استخدام المعادلة في الحل
+
+62
+00:05:25,530 --> 00:05:29,590
+الـ mixtures of acids كيف بدي اوجد ال pH ل
+
+63
+00:05:29,590 --> 00:05:34,110
+mixtures of acids طبعا احنا بس بنذكركم انه شفنا ال
+
+64
+00:05:34,110 --> 00:05:37,670
+strong acids و ال strong bases و كيف بنجيب ال pH
+
+65
+00:05:37,670 --> 00:05:41,110
+لها بعدين اتطلعنا لل salts المشتقة من ال strong
+
+66
+00:05:41,110 --> 00:05:44,890
+acids و ال strong bases و برضه شفنا كيف بنجيب ال
+
+67
+00:05:44,890 --> 00:05:48,930
+pH لها و بعد هيك اتطلعنا على ال monoprotic acids و
+
+68
+00:05:48,930 --> 00:05:52,930
+ال monomersic bases و شفنا ايضا كيفية حساب ال pH
+
+69
+00:05:53,800 --> 00:05:57,060
+اتطلعنا على ال salts للمونو بروتيك أسد و ال salts
+
+70
+00:05:57,060 --> 00:06:00,760
+للمونو بيزيك بيزيز و شوفنا كيف نحسب ال pH لهذه ال
+
+71
+00:06:00,760 --> 00:06:05,960
+salts بعدين شوفنا ال weak acid و its conjugate
+
+72
+00:06:05,960 --> 00:06:08,500
+base او ال weak base و its conjugate acid و
+
+73
+00:06:08,500 --> 00:06:11,980
+اتكلمنا عن ال buffer solutions بعدين مشينا خطولة
+
+74
+00:06:11,980 --> 00:06:16,470
+جدا اتطلعنا على ال polyprotic acidsوشوفنا كيف
+
+75
+00:06:16,470 --> 00:06:20,850
+بنحصل ال PhD لها وقلنا إنه بنقسم K1 على K2 وبنشوف
+
+76
+00:06:20,850 --> 00:06:25,190
+إذا كان هذه القيمة أكبر من 100 إذن ال K2 تقريبا
+
+77
+00:06:25,190 --> 00:06:30,610
+بيشاركش بأي كمية محترمة من ال H Plus أو بيشارك
+
+78
+00:06:30,610 --> 00:06:35,790
+بكمية مهملة من ال H Plus في المحلولفاتكلمنا عن ال
+
+79
+00:06:35,790 --> 00:06:39,690
+polyprotic acids و بعدين اتكلمنا عن ال salts لل
+
+80
+00:06:39,690 --> 00:06:43,390
+polyprotic acids اتكلمنا عن ال unprotonated salts
+
+81
+00:06:43,390 --> 00:06:46,390
+و اتكلمنا عن ال protonated salts الآن انا بيتكلم
+
+82
+00:06:46,390 --> 00:06:50,290
+عن طب ايش بيحصل لو كان عندي mixtures of acids كيف
+
+83
+00:06:50,290 --> 00:06:54,730
+بدي اوجد ال pH ل mixtures of acids؟في البداية
+
+84
+00:06:54,730 --> 00:07:00,070
+بنقول والله هذا ال mixture ممكن يكون عبارة عن
+
+85
+00:07:00,070 --> 00:07:04,130
+strong acids مع بعض two strong acids زي مثلا
+
+86
+00:07:04,130 --> 00:07:07,870
+المثال اللي قدامي بيقول find the pH of a solution
+
+87
+00:07:07,870 --> 00:07:13,610
+containing 0.1 molar HCl و 0.1 molar nitric acid
+
+88
+00:07:15,140 --> 00:07:19,380
+بقول هدول two strong acids معنى الكلام ال H بلس
+
+89
+00:07:19,380 --> 00:07:22,220
+بالسواء ال H بلس اللي جاه من ال HCl زادي ال H بلس
+
+90
+00:07:22,220 --> 00:07:24,900
+اللي جاه من ال nitric acid هذا جاه منه واحد من
+
+91
+00:07:24,900 --> 00:07:28,960
+عشرة وهذا جاه منه واحد من عشرة لأنه بتفكك و تفكك
+
+92
+00:07:28,960 --> 00:07:33,140
+كامل بنسبة مية في المية في المية إذا ال H بلس
+
+93
+00:07:33,140 --> 00:07:35,780
+هتكون مجموعة ال H بلس اللي جاه من الإتنين يعني
+
+94
+00:07:35,780 --> 00:07:40,300
+اتنين من عشرة molar ال pH بتطلع سبعة من عشرةيبقى
+
+95
+00:07:40,300 --> 00:07:44,740
+لو كانوا three strong acids بجمع ال H بلس ماعندي
+
+96
+00:07:44,740 --> 00:07:51,080
+مشكلة ماشي يا شباب إذا عندي strong acids فال H بلس
+
+97
+00:07:51,080 --> 00:07:54,760
+في المحلول مجموعة ال H بلس اللي جاية من ال strong
+
+98
+00:07:54,760 --> 00:08:00,060
+acids جميعها ماشي يبقى هان ماعندي مشكلة قصاب ال pH
+
+99
+00:08:00,060 --> 00:08:02,680
+في ال mixture من ال strong acids على الإطلاق
+
+100
+00:08:02,680 --> 00:08:08,410
+مباشرة كتيرالان نيجي نتطلع على نوع تاني من المسائل
+
+101
+00:08:08,410 --> 00:08:13,410
+نيجي نتطلع على حساب ال pH ال mixture من strong
+
+102
+00:08:13,410 --> 00:08:19,830
+acid مع weak monoprotic acid زي مثلا المثال اللي
+
+103
+00:08:19,830 --> 00:08:24,090
+قدامي بيقول find the pH of a solution containing 0
+
+104
+00:08:24,090 --> 00:08:28,610
+.1 molar HCl and 0.1 molar acetic acid وماعطينا ال
+
+105
+00:08:28,610 --> 00:08:29,770
+Ka للacetic acid
+
+106
+00:08:32,510 --> 00:08:36,430
+ممنوع منع عنبتا ولا يجوز وانا بتضايق كتير اذا كان
+
+107
+00:08:36,430 --> 00:08:41,610
+بتعمل الحاجة هذه اذا كان قلت والله اه ال H plus هو
+
+108
+00:08:41,610 --> 00:08:44,370
+عبارة عن ال H plus اللي جاي من ال HC الواحد من
+
+109
+00:08:44,370 --> 00:08:48,390
+عشرة و ال H plus اللي جاي من ال acetic acid لكن ال
+
+110
+00:08:48,390 --> 00:08:52,090
+acetic acid روح تقول it point one صفر صفر point
+
+111
+00:08:52,090 --> 00:08:57,130
+one minus X X X بينفعش ليه؟ لأن ال acetic acid مش
+
+112
+00:08:57,130 --> 00:09:01,560
+موجود لوحده ال acetic acid ايش معاها؟الـ H is N
+
+113
+00:09:01,560 --> 00:09:04,940
+بدت تشتغل زي معناه مش تشتغل هنا بتقول الـ Acetic
+
+114
+00:09:04,940 --> 00:09:08,140
+acid بتفكك الـ H plus و Acetate الـ Acetic acid
+
+115
+00:09:08,140 --> 00:09:11,840
+كان تركيز واحد من عشرة الـ H plus واحد من عشرة
+
+116
+00:09:11,840 --> 00:09:16,720
+جاية من الـ HCl معايا هيك بتحل مش والله بتاخد الـ
+
+117
+00:09:16,720 --> 00:09:20,940
+Acetic acid لوحده بتقول وكأنه مش موجود معايا HCl
+
+118
+00:09:20,940 --> 00:09:24,760
+لأ غلط طيب بتقول point one minus X الـ Acetic acid
+
+119
+00:09:24,760 --> 00:09:27,620
+فكك عطاني X يبقى هدف point one اللي جاية من الـ
+
+120
+00:09:27,620 --> 00:09:32,080
+HClزائد X اللي جاء من الاستيك أسد X بستخدم ال
+
+121
+00:09:32,080 --> 00:09:34,500
+equilibrium constant طبعا في الحالة مافيش قدامي
+
+122
+00:09:34,500 --> 00:09:38,400
+غير أن أستخدم ال equilibrium constant فبعود بقول K
+
+123
+00:09:38,400 --> 00:09:41,400
+بسبب point one زائد X في X ع ال point one minus X
+
+124
+00:09:41,400 --> 00:09:47,230
+و بفترض أن ال point one أكبر كتير من ال Xفال X
+
+125
+00:09:47,230 --> 00:09:51,350
+بتطلع عندى 1.8×10⁻⁵ relative error بتطلع حقيقي اه
+
+126
+00:09:51,350 --> 00:09:57,410
+مافيش عندى مشكلة حوالى 18000 في المية 18000 اذا
+
+127
+00:09:57,410 --> 00:10:03,710
+بالفعل ال X قليلة جدا طب ايش هي ال X ال X هي كمية
+
+128
+00:10:03,710 --> 00:10:07,850
+ال H plus اللى جاي من ايه من ال acetic acid اذا
+
+129
+00:10:07,850 --> 00:10:12,250
+لما انا بدى أرى ال X هذه بقول اذا ال H plus يعبر
+
+130
+00:10:12,250 --> 00:10:16,560
+عن point one فقط point oneمعناته ال Astic Acid لا
+
+131
+00:10:16,560 --> 00:10:21,820
+يشارك بأي H Plus في المحلول، لا يشارك، كل ال H
+
+132
+00:10:21,820 --> 00:10:26,380
+Plus تقريبا اللي في المحلول جاء من ال HCl أما ال
+
+133
+00:10:26,380 --> 00:10:31,040
+Astic Acid فمشاركته مهملة، قليلة جدا، واحد و
+
+134
+00:10:31,040 --> 00:10:35,920
+تمانية فعشرة أس سالب خمسة، قليلة جدا، إذا ما كورنت
+
+135
+00:10:35,920 --> 00:10:38,840
+بال H Plus اللي جاء من ال Astic Acid، إذا يا شباب
+
+136
+00:10:39,410 --> 00:10:43,390
+واضح بالنسبة لنا لما نكون عندنا أستك أستك أسد وHCl
+
+137
+00:10:43,390 --> 00:10:48,270
+معظم ال H Plus جاية من وين؟ من ال HCl وفي الحقيقة
+
+138
+00:10:48,270 --> 00:10:52,250
+بقدر أقول كل ال H Plus جاية من ال HCl لأن كمية ال
+
+139
+00:10:52,250 --> 00:10:57,810
+H Plus اللي جاية من الأستك أسد كمية مهملة لكن هذا
+
+140
+00:10:57,810 --> 00:11:04,260
+فقط لما كانتركيز ال HCl واحد من عشرة طب افرض انه
+
+141
+00:11:04,260 --> 00:11:08,520
+تركيز ال HCl عشرة أو سالب خمسة مولار او عشرة أو
+
+142
+00:11:08,520 --> 00:11:15,220
+سالب اربعة مولار بتشغل بنفس الطريقةلكن هتلاقي ال X
+
+143
+00:11:15,220 --> 00:11:20,300
+أشمالها لا تهمل كمية محترمة ليه؟ لأن ال H plus
+
+144
+00:11:20,300 --> 00:11:24,320
+اللي جاي من ال acetic acid صار كمية معتمرة بالنسبة
+
+145
+00:11:24,320 --> 00:11:28,820
+ل 10 أقل سالب 4 أو 10 أقل سالب 5 molar H plus جاي
+
+146
+00:11:28,820 --> 00:11:33,520
+من ال HCl فبدك تاخد بالك، يعني مش على طول تشوف حمض
+
+147
+00:11:33,520 --> 00:11:36,420
+قوة و حمض ضعيف، تقول أه باخد القوة بالسائق من
+
+148
+00:11:36,420 --> 00:11:41,340
+الضعيف مش دائما، لازم تاخد اتحلي المعادلة بالشكل
+
+149
+00:11:41,340 --> 00:11:48,560
+اللي أنا حلتهطيب ننتقل الآن ل strong acid مع
+
+150
+00:11:48,560 --> 00:11:53,060
+polyprotic acid أخد strong acid مع weak acid بس
+
+151
+00:11:53,060 --> 00:11:57,020
+كان monoprotic، الآن strong acid مع ايه؟ مع
+
+152
+00:11:57,020 --> 00:12:02,390
+polyprotic acid زي ال phosphoric acid مثلافهنطلع
+
+153
+00:12:02,390 --> 00:12:05,590
+على المثال التالي المثال ايش بيقول؟ بيقول find the
+
+154
+00:12:05,590 --> 00:12:11,370
+pH of a solution containing 0.1 molar HCl and 0.1
+
+155
+00:12:11,370 --> 00:12:15,670
+molar phosphoric acid ومعطينا ال Ks للphosphoric
+
+156
+00:12:15,670 --> 00:12:21,080
+acidأنا .. يعني بسرعة لازم .. أنت بيه؟ عندي
+
+157
+00:12:21,080 --> 00:12:25,180
+polyprotic acid بعرف كيف بدي أشتغله، بدي أقسم kA1
+
+158
+00:12:25,180 --> 00:12:30,240
+على kA2، هذا بداية من حد بشوف polyprotic acid، بدي
+
+159
+00:12:30,240 --> 00:12:34,520
+أقسم kA1 على kA2، kA1 عشرة أقل سالب اتنين، kA2
+
+160
+00:12:34,520 --> 00:12:38,140
+عشرة أقل سالب تمانية، اه يبجى فيه فرق عشرة أقل
+
+161
+00:12:38,140 --> 00:12:44,570
+ستة، معناه كلام kA1 أكبر كتير من kA2Ka1 أكبر
+
+162
+00:12:44,570 --> 00:12:48,990
+كئيزان بألغي التفكك التاني والتالت شوفني هذا كلام
+
+163
+00:12:48,990 --> 00:12:53,050
+سابقا بضل عندى بس ايه معادلة ال phosphoric acid
+
+164
+00:12:53,050 --> 00:12:58,390
+الأولى التفكك الأول ساعتها بنتقل للحل على طول بقول
+
+165
+00:12:58,390 --> 00:13:03,550
+ال phosphoric acid بعطيني H plus وH2PO4 سالم الآن
+
+166
+00:13:03,550 --> 00:13:06,250
+التفكك قبل ال equilibrium او التركيز قبل ال
+
+167
+00:13:06,250 --> 00:13:09,270
+equilibrium واحد من عشرة التركيز قبل ال
+
+168
+00:13:09,270 --> 00:13:13,990
+equilibrium لل H plusواحد من وين جاية؟ من ال HCl
+
+169
+00:13:13,990 --> 00:13:19,130
+آه زائد صفر مش عندى H2PO4 قبل ال equilibrium هان
+
+170
+00:13:19,130 --> 00:13:22,370
+point one minus X بتيجي X من ال phosphoric acid
+
+171
+00:13:22,370 --> 00:13:25,630
+point one زائد X ال point one اللي من ال HCl زائد
+
+172
+00:13:25,630 --> 00:13:30,690
+ال X من ال phosphoric acid وال H2PO4 سالب X بتطبق
+
+173
+00:13:30,690 --> 00:13:32,390
+ال equilibrium constant equation
+
+174
+00:13:36,860 --> 00:13:41,540
+هل ال X بالفعل مهملة بالنسبة لل point 1؟ بجيب ال
+
+175
+00:13:41,540 --> 00:13:47,320
+relative error بطلع عند 11 من 100إذاً، يجب الحل
+
+176
+00:13:47,320 --> 00:13:51,020
+باستخدام الـ Quadratic Equation، بس إيش معناتها؟
+
+177
+00:13:51,020 --> 00:13:54,720
+معنات أنه لا يمكن إلغاء الـ X جنب الـ Point 1،
+
+178
+00:13:54,720 --> 00:13:57,980
+يعني كمية الـ H Plus اللي جاية من الـ Phosphoric
+
+179
+00:13:57,980 --> 00:14:02,120
+Acid مُعتبرة إذا ما قُرنت بكمية الـ H Plus اللي
+
+180
+00:14:02,120 --> 00:14:06,460
+جاية من الـ HClماشي كمية ال H Plus اللي جاية من ال
+
+181
+00:14:06,460 --> 00:14:11,560
+Phosphoric Acid تعتبر ايه؟ كمية مهمة، كمية معتبرة
+
+182
+00:14:11,560 --> 00:14:16,260
+إذا ما قرنت بكمية ال H Plus اللي جاية من ال HCl
+
+183
+00:14:16,260 --> 00:14:19,820
+انت لو حلتلي quadratic equation تطلع ال X تسعة و
+
+184
+00:14:19,820 --> 00:14:23,840
+اتنين في عشرة أس سالب تلاتةلو جمعتها مع ال H بلس
+
+185
+00:14:23,840 --> 00:14:27,520
+عشان اطلع قيمة ال H بلس واحد من عشرة زائد ال X
+
+186
+00:14:27,520 --> 00:14:34,180
+فبتطلع ال H بلس حوالي point one one molar و ال pH
+
+187
+00:14:34,180 --> 00:14:39,340
+point nine six طيب
+
+188
+00:14:39,340 --> 00:14:43,980
+السؤال الآن هل ممكن يعني اجيب ال pH ل
+
+189
+00:14:48,230 --> 00:14:52,750
+mixture من two weak acids اقول والله ليش لأ ممكن
+
+190
+00:14:52,750 --> 00:14:58,350
+اجيب ال pH ل mixture of two weak acids في البداية
+
+191
+00:14:58,350 --> 00:15:03,410
+يعني انا بدي اشتغل ال weak acids اللي عندى ممكن
+
+192
+00:15:03,410 --> 00:15:13,890
+يكونوا monoprotic يعني مثلا زي ما يقول find the pH
+
+193
+00:15:13,890 --> 00:15:25,290
+of a mixtureof point one molar acetic acid ال K A
+
+194
+00:15:25,290 --> 00:15:31,910
+واحد و تمانية في عشرة أس سالب خمسة and point one
+
+195
+00:15:31,910 --> 00:15:39,670
+molar HCN ال K A له ستة و اتنين في عشرة أس سالب
+
+196
+00:15:39,670 --> 00:15:46,710
+عشرة ففي عندي two monoprotic acids
+
+197
+00:15:48,440 --> 00:15:51,760
+كيف بدي اوجد ال H Plus؟ بقول الله هاي ال Acetic
+
+198
+00:15:51,760 --> 00:15:58,400
+Acid مثلا فكك بعطي H Plus زائد Acetate ال K له
+
+199
+00:15:58,400 --> 00:16:03,840
+واحد و تمانية في عشرة أقل سالب خمسة وهي ال HCin
+
+200
+00:16:03,840 --> 00:16:11,880
+بيعطيلنا H Plus زائد CN minus ال K له ستة و اتنين
+
+201
+00:16:11,880 --> 00:16:18,430
+في عشرة أقل سالب عشرةفهيش بيطلع K A لل Acetic Acid
+
+202
+00:16:18,430 --> 00:16:24,670
+الكبير على K A لل HCN أكبر من 10 أقصى 2 في الحقيقة
+
+203
+00:16:24,670 --> 00:16:29,530
+حوالي 10 أقصى 5 100 ألف يعني بمعنى أنه لما التفكك
+
+204
+00:16:29,530 --> 00:16:33,390
+الأول يعطيني 100 ألف بروتون التفكك التاني يعطيني
+
+205
+00:16:33,390 --> 00:16:37,370
+بروتون فإيش هذا بيقولي؟ بيقولي أنه التفكك التاني
+
+206
+00:16:37,370 --> 00:16:44,570
+هذامهمل، ليس له قيمة، مش راح يعطيني H بشكل ملحوظ،
+
+207
+00:16:44,570 --> 00:16:51,210
+مش هيك يا شباب؟ اذا، بقى عندي فقط تفكك واحد، اللي
+
+208
+00:16:51,210 --> 00:16:57,610
+هو لو نحيت هذا، معناته بقى اللي عندي بس أستك أسد،
+
+209
+00:16:57,610 --> 00:17:03,070
+هذه point one صفر صفر point one minus x x x،
+
+210
+00:17:03,070 --> 00:17:07,180
+شفناها قبل هيكشوفنا هذه المثالة قبلك هذا في حالة
+
+211
+00:17:07,180 --> 00:17:13,640
+ما يكون عندي two monopotic acids مباشرة كتير
+
+212
+00:17:13,640 --> 00:17:20,520
+مباشرة لكن بدنا نقارن بين الـKa ونلغي الـKa الجليل
+
+213
+00:17:20,520 --> 00:17:26,980
+إذا كان الآخر أكبر منه بمية مرة فأكثر ماشي يا شباب
+
+214
+00:17:26,980 --> 00:17:32,820
+طيب نيجي نتطلع على المثال اللي جدامي نتطلع على
+
+215
+00:17:34,530 --> 00:17:38,990
+Polyprotic Acid مع Monoprotic Acid الحالة التانية
+
+216
+00:17:38,990 --> 00:17:45,550
+نتطلع على Monoprotic Acid مع Polyprotic Acid زي
+
+217
+00:17:45,550 --> 00:17:49,210
+المثال اللي بيقول Find the pH of a solution
+
+218
+00:17:49,210 --> 00:17:53,050
+containing 0.1 molar Phosphoric Acid ومعطينا ال K
+
+219
+00:17:53,050 --> 00:17:59,450
+is الوو 0.1 مولار أسيتك أسد ليس الاتنين مونوبروتيك
+
+220
+00:17:59,450 --> 00:18:02,050
+لأ واحد منهم مونوبروتيك والتاني مونوبروتيك
+
+221
+00:18:02,050 --> 00:18:05,510
+بوليبروتيك تعرف انا على طول ال polyperotic acid
+
+222
+00:18:05,510 --> 00:18:10,290
+بقسم K1 على K2 بطلع اكتر من عشر عقل ستين اذا بضل
+
+223
+00:18:10,290 --> 00:18:14,820
+المعادلة الأولى بسمعايا يا شباب هاي المعادلة و
+
+224
+00:18:14,820 --> 00:18:20,620
+الastic acid هاي معادلته طيب هذا ال K A1 الو 1 و 1
+
+225
+00:18:20,620 --> 00:18:26,400
+في 10 أقص سالب 2 و هذا ال K A الو 1 و 8 في 10 أقص
+
+226
+00:18:26,400 --> 00:18:32,580
+سالب 5 لما انا اقسم لكبير على لصغير بيطلع عندى
+
+227
+00:18:32,580 --> 00:18:36,800
+حوالي 1000 يعني اكتر من 10 أقص 2 اذا بقدر اقول
+
+228
+00:18:36,800 --> 00:18:42,540
+والله هذا مافيش له اي قيمةبين طموح ما اللي هتكون،
+
+229
+00:18:42,540 --> 00:18:47,940
+إيش رأيكم؟ علشان هيك بنقول بضلش عندي إلا معادلة
+
+230
+00:18:47,940 --> 00:18:53,680
+واحدة، هي معادلة الـ Phosphoric Acid، والباجي راح،
+
+231
+00:18:53,680 --> 00:18:57,860
+إذا بضل عندي هاي Phosphoric Acid بيعطيني H Plus
+
+232
+00:18:57,860 --> 00:19:03,480
+وDihydrogen Phosphate 0.100.1-XXX ومن ال
+
+233
+00:19:03,480 --> 00:19:07,240
+equilibrium constantبعد ما أقول ال point one أكبر
+
+234
+00:19:07,240 --> 00:19:10,280
+كتير من ال X ال X بتطلع عندي تلاتة و تلاتين من الف
+
+235
+00:19:10,280 --> 00:19:14,260
+لو جبت ال relative error تلاتة و تلاتين في المية
+
+236
+00:19:14,260 --> 00:19:20,680
+اه اذا ال assumption is invalid and we must use او
+
+237
+00:19:20,680 --> 00:19:24,120
+solve the quadratic equation لو حلناها بتطلع
+
+238
+00:19:24,120 --> 00:19:28,240
+تمانية و عشرين من الف بتطلع ال X اللي هي قاش ال X
+
+239
+00:19:28,950 --> 00:19:33,890
+هذه ال X ال H بلس للمحلول طيب هل في حد مقدر يقول
+
+240
+00:19:33,890 --> 00:19:37,290
+لي جديش جاي او يعني انا لغيت ال H بلس اللي جاي من
+
+241
+00:19:37,290 --> 00:19:41,430
+ال acetic acid فبقدر احسبها بقدر اعرف جديش H بلس
+
+242
+00:19:41,430 --> 00:19:45,030
+كان جاي من ال acetic acid اللي انا لغيته يعني و هل
+
+243
+00:19:45,030 --> 00:19:49,790
+بالفعل الغاء كان منطقي تعالوا نحسب جديش ال H بلس
+
+244
+00:19:49,790 --> 00:19:55,590
+اللي كان ال acetic acid بده يعطيه ليه انا حسبت هذه
+
+245
+00:19:55,590 --> 00:19:59,640
+كانت point oneالـ H Plus اللي جاي من الـ
+
+246
+00:19:59,640 --> 00:20:04,940
+Phosphoric Acid اللي أنا حسبته و قلت 0.028 السافر
+
+247
+00:20:05,180 --> 00:20:10,060
+إذا point one minus X point O two eight زائد X
+
+248
+00:20:10,060 --> 00:20:14,440
+وهذه X لو إجينا أعملنا هذا الكلام و حسبنا قيمة ال
+
+249
+00:20:14,440 --> 00:20:18,200
+X اللي هي ال H plus اللي جاي من ال acetic acid
+
+250
+00:20:18,200 --> 00:20:21,640
+بلاحظ من ستة وأربعة في عشر أقل سالب خمسة وهذه كمية
+
+251
+00:20:21,640 --> 00:20:25,100
+قليلة جدا لأنه لو إجينا طلعنا ال relative error
+
+252
+00:20:25,100 --> 00:20:29,460
+بتطلع أو بيطلع عند point two three percent كمية
+
+253
+00:20:29,460 --> 00:20:30,700
+قليلة للغاية
+
+254
+00:20:33,390 --> 00:20:38,010
+تعالوا لآخر مثال ايش بيحصل لو كان في عندي mixture
+
+255
+00:20:38,010 --> 00:20:43,510
+من two polyprotic acids زي مثلا ال carbonic acid و
+
+256
+00:20:43,510 --> 00:20:46,890
+ال phosphoric acid انشوف المثال التالي بيقول find
+
+257
+00:20:46,890 --> 00:20:49,850
+the pH of a mixture containing 0.1 molar
+
+258
+00:20:49,850 --> 00:20:54,470
+phosphoric acid and 0.1 molar carbonic acid بقول
+
+259
+00:20:54,470 --> 00:20:57,250
+والله ال phosphoric acid بتفكك هي التفككات وهي ال
+
+260
+00:20:57,250 --> 00:21:03,900
+Ka سبعته باجي بقسم Ka1 على Ka2بقدر ألغي هدول، مش
+
+261
+00:21:03,900 --> 00:21:08,900
+هيك؟ طب هي ال carbonic acid باجي بقول K1 على K2
+
+262
+00:21:08,900 --> 00:21:14,320
+برضه أكبر من عشر أقصى اتنين، بلغي التاني، اه، اذا
+
+263
+00:21:14,320 --> 00:21:21,670
+خلصنا من هدول، باجي بكمل شغليبتم عندي معادلتين فقط
+
+264
+00:21:21,670 --> 00:21:26,630
+المعادلتين هم ال phosphoric acid التفكك الأول وال
+
+265
+00:21:26,630 --> 00:21:30,250
+carbonic acid التفكك الأول طب ماجي بطلع التفكك
+
+266
+00:21:30,250 --> 00:21:33,330
+الأول لل phosphoric عشر عقل ثاني باتنين التفكك
+
+267
+00:21:33,330 --> 00:21:38,390
+الأول لل carbonic عشر عقل خمسة معنى الكلام k a one
+
+268
+00:21:38,390 --> 00:21:42,670
+على k a one عشر عقل خمسة معنى الكلام هذا راحأيش
+
+269
+00:21:42,670 --> 00:21:45,690
+طال عندى؟ طال عندى الـ Phosphoric Acid التفكك
+
+270
+00:21:45,690 --> 00:21:49,890
+الأول وانتهى الموضوع طب هذا انا ماعرف أجيبله ال P
+
+271
+00:21:49,890 --> 00:21:55,570
+-H لأنه مر معايا سابقا هدهو بس للتذكير بس بتحط
+
+272
+00:21:55,570 --> 00:22:01,710
+لجوا عندكم هاي ال Phosphoric Acid 0.100.1-XXX
+
+273
+00:22:01,710 --> 00:22:07,590
+وبالتالي عندنا ال X بتطلع 0.0333 تقري جولناها اذا
+
+274
+00:22:07,590 --> 00:22:12,710
+33% في الجلازمإن حل باستخدام ال equation بتطلع ال
+
+275
+00:22:12,710 --> 00:22:17,150
+X عنا 28 من 1000 لو جبنا ال pH بتطلع 51 وعنا ال
+
+276
+00:22:17,150 --> 00:22:21,210
+carbonic acid بيشارك بكمية محترمة من ال H plus في
+
+277
+00:22:21,210 --> 00:22:25,730
+المحلول طبعا لا طبعا لا ما بيشارك لأنه زي ما شفنا
+
+278
+00:22:25,730 --> 00:22:30,010
+سابقا انه المعادلة تبعته كانت قليلة جدا بمعنى انه
+
+279
+00:22:30,010 --> 00:22:33,610
+كل 100 ألف بروتون بحصل عليها من التفكك الأول بحصل
+
+280
+00:22:33,610 --> 00:22:38,030
+على بروتون واحد فقط من التفكك التانيماشي يا شباب
+
+281
+00:22:38,030 --> 00:22:45,370
+بعتقد انا انه هيك اكفايا على يعني
+
+282
+00:22:45,370 --> 00:22:48,710
+ال acid base equilibria وانا تجريبا اتعرضنا لانواع
+
+283
+00:22:48,710 --> 00:22:56,040
+مختلفة من المحاليلأنواع مختلفة من المحاليل ومتعددة
+
+284
+00:22:56,040 --> 00:23:00,440
+في الحقيقة ومتنوعة كتيرة خالص وأنا بعتقد أنها
+
+285
+00:23:00,440 --> 00:23:05,960
+بتغطي جميع أنواع المحاليل اللي ممكن يعني اتواجهنا
+
+286
+00:23:05,960 --> 00:23:10,820
+في الحياة العملية طبعا كان بإمكاننا برضه ناخد في
+
+287
+00:23:10,820 --> 00:23:14,860
+هذا الجانب إيش بحصل لو كان فينا mixtures من bases
+
+288
+00:23:14,860 --> 00:23:22,640
+يعني مثلا لو أنا قلتلك فوسفات وكربوناتفوسفات و
+
+289
+00:23:22,640 --> 00:23:29,960
+carbonate يعني مثلا point one molar صادم فوسفات
+
+290
+00:23:29,960 --> 00:23:40,660
+بقتنق به and point one molar صادم carbonate بقول
+
+291
+00:23:40,660 --> 00:23:45,080
+انا هاي الفوسفات في
+
+292
+00:23:45,080 --> 00:23:50,860
+الميه بتتفكك و بتعطيHPO4 اتنين سالب زائد
+
+293
+00:23:50,860 --> 00:23:54,800
+هيدروكسايت وهذا KP بيساوي عشر أقل سالب أربعة عاشر
+
+294
+00:23:54,800 --> 00:24:01,060
+على KA تلاتة يعني اربعة و تمانية في عشر أقل سالب
+
+295
+00:24:01,060 --> 00:24:07,680
+تلتاشر point O two أما الكربونيت في هاي ال H2O
+
+296
+00:24:13,230 --> 00:24:18,830
+بتعطيني HCO3 زائد هيدروكسايد وال Kb بده يساوي عشرة
+
+297
+00:24:18,830 --> 00:24:25,170
+أقل سالف أربع تاشر على ال KA2 KA2
+
+298
+00:24:25,170 --> 00:24:30,030
+اللي هو أربعة و تمانية عشرة أقل سالف أحداشر ساوي
+
+299
+00:24:30,030 --> 00:24:32,710
+اتنين و واحد عشرة أقل سالف أربعة
+
+300
+00:24:35,530 --> 00:24:40,510
+نفس الكلام لو إجيت بقول الأول ماشي أو التاني ماشي
+
+301
+00:24:40,510 --> 00:24:46,310
+تقريبا مائة مرة أكتر من الأول ممكن يكون يعني أقل
+
+302
+00:24:46,310 --> 00:24:52,270
+لكن مافيش قدام طريقة إلا أني أعتبر أن الأول Kb هذا
+
+303
+00:24:52,270 --> 00:24:57,170
+أكبر كتير من Kb التاني وبالتالي بألغي الكربونيت
+
+304
+00:24:57,170 --> 00:25:01,690
+هذا بداية وبعدين بشتغل عليه أنه بس عندي فوسفاتبعد
+
+305
+00:25:01,690 --> 00:25:05,290
+ما طلع قيمة الفوسفات لان هان في شك لانه اقل من 100
+
+306
+00:25:05,290 --> 00:25:09,170
+تقريبا الفرق في شك فليش بسوي اه بقول هاي ال
+
+307
+00:25:09,170 --> 00:25:12,990
+carbonate H2O بقول point one بجيب ال hydroxide
+
+308
+00:25:12,990 --> 00:25:16,590
+اللي طلعته من الأول و بحطه هان و بطلع قيمة
+
+309
+00:25:17,350 --> 00:25:20,190
+الهيدروكسايد اللى جاى من الخطوة التانية و بشوف هل
+
+310
+00:25:20,190 --> 00:25:25,990
+بالفعل كان يمكن إلغاءه ولا لأ يعني بنفس الوقت سهل
+
+311
+00:25:25,990 --> 00:25:29,830
+أو بنفس الطريقة يمكن لو كان عنده mixture of bases
+
+312
+00:25:29,830 --> 00:25:35,150
+برضه ان يعملها بنفس الطريقة طيب يا شباب الآن ننتقل
+
+313
+00:25:35,150 --> 00:25:41,650
+لشطر جديد شطر هذا بتحدث عن ال acid base titrations
+
+314
+00:25:43,340 --> 00:25:47,880
+في ال acid-base titrations يا شباب احنا بنتعرض
+
+315
+00:25:47,880 --> 00:25:53,840
+لكيفية حساب ال pH عند إضافة أي كمية من ال titrant
+
+316
+00:25:53,840 --> 00:25:57,140
+لل analyte فانا في عندي analyte في ال flask و في
+
+317
+00:25:57,140 --> 00:26:00,960
+عندي titrant في ال burette و بنزل شوية شوية طب عند
+
+318
+00:26:00,960 --> 00:26:06,770
+أي إضافة بدي أحسب جداشالـ pH بقول هذا كلام سهل
+
+319
+00:26:06,770 --> 00:26:12,290
+كتير لإنه مش راح أجي أتطرق لكيفية حساب ال pH بدي
+
+320
+00:26:12,290 --> 00:26:16,690
+أحسب ال pH باستخدام المعلومات اللي أنا اتعلمتها في
+
+321
+00:26:16,690 --> 00:26:21,390
+ال chapter الماضي ماشي انا اتعلمت أحسب ال pH لجميع
+
+322
+00:26:21,390 --> 00:26:27,670
+أنواع المحليل الآن بدي أستخدمالـ Titration عند أي
+
+323
+00:26:27,670 --> 00:26:33,530
+إضافة بعرف كيف أحسب ال pH بعد هذه الإضافة فهنستخدم
+
+324
+00:26:33,530 --> 00:26:36,110
+نفس المعلومات اللي اتعلمناها في ال chapter اللي
+
+325
+00:26:36,110 --> 00:26:39,910
+فات لعملية الحساب ايش اللي راح ندرسه احنا في ال
+
+326
+00:26:39,910 --> 00:26:44,150
+acid-base titration هندرس معايرة ال strong acid مع
+
+327
+00:26:44,150 --> 00:26:47,370
+ال strong base او طبعا يعني strong base مع strong
+
+328
+00:26:47,370 --> 00:26:52,670
+acid هي نفسهاهندرس معارض strong acid مع weak base
+
+329
+00:26:52,670 --> 00:26:57,030
+او strong acid مع weak acid او strong acid مع poly
+
+330
+00:26:57,030 --> 00:27:02,690
+basic base او strong acid مع polyprotic acid او
+
+331
+00:27:02,690 --> 00:27:07,270
+strong acid مع mixture من two bases او strong acid
+
+332
+00:27:07,270 --> 00:27:12,410
+مع mixture من two acids لو اطلعت معايا ايش اول
+
+333
+00:27:12,410 --> 00:27:17,230
+كلمة هان؟اه اذا دايما في عندي حاجة strong من غير
+
+334
+00:27:17,230 --> 00:27:19,110
+ما يكون عندي حاجة strong مانديش اعمل titration
+
+335
+00:27:19,110 --> 00:27:23,130
+يبقى ال titration تتطلب ان واحد المتفاعلات ايش
+
+336
+00:27:23,130 --> 00:27:27,150
+يكون strong و هذا السؤال ليش لازم يكون strong بعد
+
+337
+00:27:27,150 --> 00:27:31,470
+شوية هنفهمه تمام فلازم واحد منهم يكون strong
+
+338
+00:27:31,470 --> 00:27:34,970
+والتاني ممكن يكون strong هذا أحسن لو كان weak
+
+339
+00:27:34,970 --> 00:27:39,860
+مافيش مشكلةقبل ما اتكلم عن ال titrations بدي اتكلم
+
+340
+00:27:39,860 --> 00:27:43,040
+عن موضوع مرتبط بال titrations بشكل كبير اللي هو ال
+
+341
+00:27:43,040 --> 00:27:46,600
+indicator من غير indicator مافيش visual titration
+
+342
+00:27:46,600 --> 00:27:51,960
+ليه؟ لأنه ال indicator بيخبرني هل ال end point اجت
+
+343
+00:27:51,960 --> 00:27:55,680
+ولا لأ بدي اشوفها عن طريق تغير لون ال indicator
+
+344
+00:27:55,680 --> 00:27:59,640
+ايش هو ال indicator ال acid base indicator عبارة
+
+345
+00:27:59,640 --> 00:28:03,720
+عن weaker acid او weaker base انا فيه عندي ممكن
+
+346
+00:28:03,720 --> 00:28:08,700
+يكون في المحلول weak acidاو weak base، ال
+
+347
+00:28:08,700 --> 00:28:11,960
+indicator بدي يكون يا اما weak acid يا اما weak
+
+348
+00:28:11,960 --> 00:28:14,860
+base، بس weaker than ال analyte اللي عندى، اول
+
+349
+00:28:14,860 --> 00:28:18,000
+الشيء اللي انا احد مكونات ال titration، ال
+
+350
+00:28:18,000 --> 00:28:22,780
+titration هي مكونين analyte و titrant، طب ال
+
+351
+00:28:22,780 --> 00:28:26,860
+indicator بدي يكون weaker than هدول اتنينفهو very
+
+352
+00:28:26,860 --> 00:28:29,520
+weak خلّيني أقول، very weak acid أو very weak
+
+353
+00:28:29,520 --> 00:28:33,720
+base، لكن very weak organic acid أو very weak
+
+354
+00:28:33,720 --> 00:28:37,860
+organic base، organic، يعني في أكم من حلجة بنزين
+
+355
+00:28:37,860 --> 00:28:41,700
+مشبكين في بعض، ليه؟ لأن حلجات البنزين هذه، لما
+
+356
+00:28:41,700 --> 00:28:44,560
+نكون مشبكة في بعض، لو فيها شوية functional groups،
+
+357
+00:28:44,560 --> 00:28:48,980
+بيكون في الهالون عادةلون فال indicator فيه له لون
+
+358
+00:28:48,980 --> 00:28:54,300
+او يعني له لون في الوسط الحمضي و لون اخر في الوسط
+
+359
+00:28:54,300 --> 00:29:00,420
+القاعدي تمام طبعا لما انا اعاير انا تحصل تغير في
+
+360
+00:29:00,420 --> 00:29:07,340
+هذا اللون طيب نيجي نتطلع على هذه القيمة انا قلت
+
+361
+00:29:07,340 --> 00:29:10,840
+انه ال indicator له لونين لون في الوسط الحمضي و
+
+362
+00:29:10,840 --> 00:29:13,960
+لون في الوسط القاعدي طب ايه لما يكون في عندي لون
+
+363
+00:29:13,960 --> 00:29:18,890
+أحمر و لون مثلا أزرجوخلطتهم ايش اللون اللي بحصل
+
+364
+00:29:18,890 --> 00:29:29,710
+عليه مثلا ممكن تحصل على يعني لون اخضر مثلا مثلا او
+
+365
+00:29:29,710 --> 00:29:35,350
+اي لون اخر بس انا بقول بده اشوف اللون الأحمر وقت
+
+366
+00:29:35,350 --> 00:29:38,790
+اش مقدر اشوف اللون الأحمر جال والله اذا كان تركيز
+
+367
+00:29:38,790 --> 00:29:44,200
+اللون الأحمر عشر امثال تركيز اللون الأزرقوبتش ببدأ
+
+368
+00:29:44,200 --> 00:29:48,500
+أشوف اللون أزرق و أحمر مخلطين بشوف ألوان متعددة
+
+369
+00:29:48,500 --> 00:29:53,180
+حسب درجة الألوان تبعتي أو حسب النسبة بينهم لكن لو
+
+370
+00:29:53,180 --> 00:29:56,700
+كان الأحمر عشر أمثال الأزرق بشوفش الأزرق بشوف بس
+
+371
+00:29:56,700 --> 00:30:01,040
+لون أحمر طب لو كان الأزرق عشر أمثال الأحمر بشوف بس
+
+372
+00:30:01,040 --> 00:30:04,520
+الأزرق شاشة الأحمر هذا كله بنستفيد منه كتير لأنه
+
+373
+00:30:04,520 --> 00:30:08,500
+مثلا تركيز ال I N سالب كان عشر أمثال ال H I N يبقى
+
+374
+00:30:08,500 --> 00:30:11,900
+عشر على واحد log العشرة بواحديبقى الـPK
+
+375
+00:30:11,900 --> 00:30:17,960
+للإنديكاتور زائد واحد طب لو كان لون ال ion سالب
+
+376
+00:30:17,960 --> 00:30:21,620
+أقل من ال H، ال H ion هو العشر أمثال ال ion سالب،
+
+377
+00:30:21,620 --> 00:30:25,080
+بيكون log الواحد على عشر إذا سالب واحد، يبقى ال pH
+
+378
+00:30:25,080 --> 00:30:30,000
+ال line دي بتثور PK للإنديكاتور زائد أو ناقص واحد،
+
+379
+00:30:30,000 --> 00:30:33,280
+إيش معناه هذا الكلام؟ معناته كلام خطير كتير في
+
+380
+00:30:33,280 --> 00:30:38,180
+الحقيقة يعنيايش بيقولنا؟ بيقولنا انه مش أي
+
+381
+00:30:38,180 --> 00:30:42,680
+indicator يمكن استخدامه لأي acid-base titration،
+
+382
+00:30:42,680 --> 00:30:48,380
+مش أي acid-base indicator يمكن استخدامه لأي acid
+
+383
+00:30:48,380 --> 00:30:52,780
+-base titration، ها كيف؟ قال لا، كل indicator
+
+384
+00:30:52,780 --> 00:30:56,140
+بيشتغل في range معير من ال pH، هذا ال range لا
+
+385
+00:30:56,140 --> 00:31:01,340
+يتجاوز two pH unitsهذا ال range لا يتجاوز two pH
+
+386
+00:31:01,340 --> 00:31:04,200
+يعني مثلا ممكن نلاقي asset based indicator بيشتغل
+
+387
+00:31:04,200 --> 00:31:07,780
+من تلاتة لخمسة ممكن نلاقي واحد تاني بيشتغل من اربع
+
+388
+00:31:07,780 --> 00:31:10,100
+على ستة ممكن نلاقي واحد تالت بيشتغل من تمانية
+
+389
+00:31:10,100 --> 00:31:13,680
+لعشرة بس two pH units مافيش واحد بيشتغل من مثلا
+
+390
+00:31:13,680 --> 00:31:18,240
+اربع على اتناش او اربع على تسعة او اربع على تمانية
+
+391
+00:31:18,240 --> 00:31:24,230
+لا بس اكم pH unitتو pH units هذه حاجة الحاجة
+
+392
+00:31:24,230 --> 00:31:28,330
+التانية اللي هذه المعادلة بتقولها ليه بتقول انه مش
+
+393
+00:31:28,330 --> 00:31:33,890
+اي indicator بنفعل اي معايرة هكذا جال لازم لو انا
+
+394
+00:31:33,890 --> 00:31:43,610
+حبيت اقول هاي ال volume titrant وهي ال pH هذا اسمه
+
+395
+00:31:43,610 --> 00:31:50,000
+titration curve هاي نقطة ايه التكافؤفبقول هاي ال
+
+396
+00:31:50,000 --> 00:31:55,940
+PH at equivalence point جال
+
+397
+00:31:55,940 --> 00:32:02,860
+انه ال indicator المناسب هو اللي ال PKله بساوي ال
+
+398
+00:32:02,860 --> 00:32:06,420
+PH at equivalence point يعني أنا مثلا ال PH at
+
+399
+00:32:06,420 --> 00:32:10,340
+equivalence point كانت عند 6 بقول ال indicator
+
+400
+00:32:10,340 --> 00:32:18,940
+المناسب هو اللي ال PKله في 6الـ PK بدي يسوى ال pH
+
+401
+00:32:18,940 --> 00:32:23,760
+at equivalence point ليه؟ بل لأنهالـ Range بده
+
+402
+00:32:23,760 --> 00:32:28,020
+يكون زائد أو ناقص واحد فالـ Range بيكون حوالين ال
+
+403
+00:32:28,020 --> 00:32:30,540
+equivalence point يعني ال equivalence point توجع
+
+404
+00:32:30,540 --> 00:32:36,000
+في ال range تبعه، معايا؟ إذا لازم في الحقيقة تكون
+
+405
+00:32:36,000 --> 00:32:40,560
+ال pH تقريبا مساوية ال PK لل Indicator، منفعش ما
+
+406
+00:32:40,560 --> 00:32:43,820
+تسويش ال PK لل Indicator، ما تكونش قريبة كتير منه،
+
+407
+00:32:43,820 --> 00:32:47,440
+لأنه لو كانت بعيدة كتير عنه، ممكن أتواجه بمشكلة
+
+408
+00:32:47,440 --> 00:32:52,490
+عويصةممكن اتواجه المشكلة عويصة اذا المنهجية في
+
+409
+00:32:52,490 --> 00:32:56,770
+اختيار ال indicator هو اني اتطلع في البداية وين ال
+
+410
+00:32:56,770 --> 00:33:01,730
+PH at equivalence point اذا عرفتها بقول اه يبقى
+
+411
+00:33:01,730 --> 00:33:05,550
+بدأ اتطلع على indicator من ال list ال PK تبعته
+
+412
+00:33:05,550 --> 00:33:10,170
+قريبة جدا من ال PH at equivalence point وإذا كان
+
+413
+00:33:10,170 --> 00:33:14,980
+محظوظ براجعindicator يعني ال pH تبعته قريبة جدا من
+
+414
+00:33:14,980 --> 00:33:19,460
+ال PK لل indicator ال PK لل indicator قريبة جدا من
+
+415
+00:33:19,460 --> 00:33:23,460
+ال pH at equivalence point إذا كان محظوظ طبعا يعني
+
+416
+00:33:23,460 --> 00:33:27,840
+للأسف مش دائما هذا الكلام ممكن بشكل دقيق
+
+417
+00:33:30,630 --> 00:33:33,910
+بعض ال indicators مثلا ال crystal violet من 0 ل 2
+
+418
+00:33:33,910 --> 00:33:38,230
+برمو فينو ل blue من 3 ل 5 مثل ال orange من 3 و 1 ل
+
+419
+00:33:38,230 --> 00:33:43,730
+4 و 4 هذا بيعتمد على الألوان يعني عشرة ل واحد او
+
+420
+00:33:43,730 --> 00:33:47,990
+واحد ل عشرة هذا يعني بشكل عام لكن من ناحية عملية
+
+421
+00:33:47,990 --> 00:33:51,210
+ممكن يصير فيها نشوية اختلافات لكن مانلاقيش
+
+422
+00:33:51,210 --> 00:33:56,620
+مانلاقيش مثلا indicator بيشتغل عند 4 و 5أو ضمن
+
+423
+00:33:56,620 --> 00:33:59,760
+أربعة أو خمسة pH units لأ ما باللاجئ هذا الكلام
+
+424
+00:33:59,760 --> 00:34:05,920
+هذه ال list مختصرة جدا فيها عشرات
+
+425
+00:34:05,920 --> 00:34:09,980
+و يمكن مئات ال acid base indicators اللي موجودة
+
+426
+00:34:09,980 --> 00:34:16,020
+تحت إيدينا فاحنا بنختار الشيء المناسب لو جينا
+
+427
+00:34:16,020 --> 00:34:20,080
+اطلعنا ال titration curve هذه يا شباب لو جينا
+
+428
+00:34:20,080 --> 00:34:26,500
+اطلعنا بقول يعني هذا indicator وهذا indicatorهذا
+
+429
+00:34:26,500 --> 00:34:31,920
+Indicator وهذا Indicator انا عادة بختار Indicator
+
+430
+00:34:31,920 --> 00:34:33,180
+الأقرب
+
+431
+00:34:35,240 --> 00:34:38,000
+للـ equivalence point عادة بتختار ال indicator
+
+432
+00:34:38,000 --> 00:34:42,740
+الأيه الأقرب لل equivalence point فبدي يعني أنت
+
+433
+00:34:42,740 --> 00:34:46,080
+ماهلاقاش ال indicator اللي بده اختاره لأنه اختيار
+
+434
+00:34:46,080 --> 00:34:50,180
+ال indicator قد يؤدي إلى خطأ جسم جدا أو قد يؤدي
+
+435
+00:34:50,180 --> 00:34:54,120
+إلى دقة عالية جدا فانت بدك تختار ال indicator الصح
+
+436
+00:34:54,120 --> 00:35:00,600
+لأنه هذا من ناحية فعلية بينعكس على دقة نتائجكلو
+
+437
+00:35:00,600 --> 00:35:05,920
+جينا اطلعنا بقول والله هذا الأخضر هو أنسب من
+
+438
+00:35:05,920 --> 00:35:12,520
+الأصفر أو البني يعني لكن الأزرق اللي فوق هذا غير
+
+439
+00:35:12,520 --> 00:35:16,840
+مناسب نهائيا هذا لو استخدمنا مهما أضافنا أسد أو
+
+440
+00:35:16,840 --> 00:35:21,280
+بيز مش راح يتغير لونه خلاص هو هيك ليه؟ لأنه خارج
+
+441
+00:35:21,280 --> 00:35:25,520
+إطار ال titration curve مالوش دعوة فيه فمابيتغير
+
+442
+00:35:25,520 --> 00:35:31,760
+لونهطبعاً هان لو إجينا طلعنا على الأخضر بقول هو
+
+443
+00:35:31,760 --> 00:35:40,720
+أنسب شكله أنسب ليه؟ لأنه هان لو إجينا قولنا لاحظ
+
+444
+00:35:40,720 --> 00:35:46,810
+هذا بيشي على المنطقة اللي إيهالمائلة يعني هيعطيك
+
+445
+00:35:46,810 --> 00:35:52,450
+خطأ ما بينما هان لأ لسه يعني هي من هان لهان ما
+
+446
+00:35:52,450 --> 00:35:56,130
+قداش على المنطقة المائلة على سبيل المثال المنطقة
+
+447
+00:35:56,130 --> 00:36:01,710
+المائلة هذه هالجت هنشوف قصتها هى اللى بتحكم هل
+
+448
+00:36:01,710 --> 00:36:05,030
+يكون في عندي خطأ او مايكنش في عندي خطأ و جداش
+
+449
+00:36:05,030 --> 00:36:09,390
+مقدار ايه الخطأ؟ خدوا بالكم هالجت لما يكون في عندي
+
+450
+00:36:09,390 --> 00:36:14,300
+indicator اناالاندكاتور الارنج two pH units ايش
+
+451
+00:36:14,300 --> 00:36:18,580
+معنى هذا الكلام؟ ايش معناته؟ معناته انه ال lower
+
+452
+00:36:18,580 --> 00:36:21,520
+range انا لما اجي اوصل ال titration curve يعني عند
+
+453
+00:36:21,520 --> 00:36:27,820
+هذه النقطة بالظبط بيبدأ اللون يتغير يعني عند السهم
+
+454
+00:36:27,820 --> 00:36:32,270
+الأحمراللون اللون ال indicator بيبدأ يتغير لكن
+
+455
+00:36:32,270 --> 00:36:36,050
+مبدأ يتغير بشوف انا تغير في اللون لكن لأ مش هو
+
+456
+00:36:36,050 --> 00:36:39,630
+اللون اللي انا بديه يعني مثلا يتحول من أحمر لأزرج
+
+457
+00:36:39,630 --> 00:36:43,510
+يعني اللون يتغير من أحمر لحاجة تانية لكن ماصارش
+
+458
+00:36:43,510 --> 00:36:47,550
+الأزرج اللي انا بعرفه لون هالستارة مثلا لأ ماصارش
+
+459
+00:36:47,550 --> 00:36:55,310
+لسه بتن أضيف لغاية آخر ال rangeهذا أخر ال range
+
+460
+00:36:55,310 --> 00:36:59,650
+يعني ان كله اتحول لل base مثلا عند الخط الأخضر
+
+461
+00:36:59,650 --> 00:37:05,270
+انتهى التغير اللون اتحول كله للأزرق مثلامعايا يبقى
+
+462
+00:37:05,270 --> 00:37:08,970
+في أول ال range ببدأ التحول في اللون في آخر ال
+
+463
+00:37:08,970 --> 00:37:13,630
+range أشماله اللون بيصير واضح انتهى بقدر أشوفه صح
+
+464
+00:37:13,630 --> 00:37:18,170
+100% مش مستعد أن أسأل أزميلي أو أسأل حد تاني أقوله
+
+465
+00:37:18,170 --> 00:37:23,490
+والله إجا اللون ولا لأ واضح 100% هذا المسافة هي
+
+466
+00:37:23,490 --> 00:37:28,590
+عبارة عن الحجم اللازم أضيفه علشان أقدر أشوف اللون
+
+467
+00:37:28,590 --> 00:37:40,530
+بشكل جيدطبعا لو كان .. لو كان ..
+
+468
+00:37:40,530 --> 00:37:44,910
+لو أخدنا بالنا من هذا الشكل، لاحظوا أنه مايل أكتر،
+
+469
+00:37:44,910 --> 00:37:52,090
+هان ببدأ اللون يتغير، مش هيك؟ و هان اللون بخلص
+
+470
+00:37:52,090 --> 00:37:55,790
+يتغير، لاحظوا الحجب اللي أخدته إيش ماله؟ زاد، لأنه
+
+471
+00:37:55,790 --> 00:38:04,080
+عمال، ال curve مش sharpالـ curve مال بزيادة و لو
+
+472
+00:38:04,080 --> 00:38:09,060
+مال اكتر من هيك ..
+
+473
+00:38:09,060 --> 00:38:14,840
+كويس اه بقى انا كلام فيه عند زيادة كمان اكبر لمن
+
+474
+00:38:14,840 --> 00:38:19,560
+اجي اعاير .. لمن اجي اعاير week مع week بحصل على
+
+475
+00:38:19,560 --> 00:38:22,780
+هذا النوع من الميلان اللي كتير خالص diffuse بيكون
+
+476
+00:38:22,780 --> 00:38:27,500
+.. بيكون الشرببكون diffuse لما نكون diffuse بدي
+
+477
+00:38:27,500 --> 00:38:32,780
+اضطر اضيف كمية كبيرة من الحجم حجم ال titrant علشان
+
+478
+00:38:32,780 --> 00:38:37,140
+احصل على تغير في اللون وهذا كله طبعا بخرب كل عملية
+
+479
+00:38:37,140 --> 00:38:40,300
+ال titration ليه اللي ببفل اشرين تلاتين ميلي زيادة
+
+480
+00:38:40,300 --> 00:38:45,340
+عشان اقدر اشوف ال end point طبعا هذا الكلام مش
+
+481
+00:38:45,340 --> 00:38:46,600
+معطقي لايجوز
+
+482
+00:38:50,570 --> 00:38:57,620
+والتاش بتكون بتكون ال titration curve sharpإذا الـ
+
+483
+00:38:57,620 --> 00:39:01,040
+titration curve شارب في الحقيقة بسمحلي أن أستخدم
+
+484
+00:39:01,040 --> 00:39:04,640
+هذا ال indicator أو أن أستخدم مثلا هذا ال
+
+485
+00:39:04,640 --> 00:39:09,480
+indicator أو أستخدم هذا ال indicator أو أستخدم هذا
+
+486
+00:39:09,480 --> 00:39:12,980
+ال indicator معاها انتوا كل واحد من هدول فيه ال
+
+487
+00:39:12,980 --> 00:39:18,300
+range معين لكن لما نكون ال break شارب بسمحلي أن
+
+488
+00:39:18,300 --> 00:39:22,360
+أستخدم أي indicator و انهم مش هيحصل عندي مشكلة ما
+
+489
+00:39:22,360 --> 00:39:26,650
+هيحصل عندي مشكلةفبالتالي انا بحب كتير ال titration
+
+490
+00:39:26,650 --> 00:39:30,450
+curve يكون sharp بحب كتير ال titration curve يكون
+
+491
+00:39:30,450 --> 00:39:35,490
+sharp و اكتشف ال titration curve يكون sharp جال في
+
+492
+00:39:35,490 --> 00:39:42,450
+حالتين لما التركيز المتفاعلات يكون عالي كويس هذي
+
+493
+00:39:42,450 --> 00:39:45,610
+اول حالة يعني ال titrant و ال analyte يكون تركيزهم
+
+494
+00:39:45,610 --> 00:39:49,730
+معقول حوالين ال point one molar point oh five ماشي
+
+495
+00:39:49,730 --> 00:39:52,990
+الحال لكن مش عشرة أس سالب أربعة ولا عشرة أس سالب
+
+496
+00:39:52,990 --> 00:39:56,760
+خمسة لأيبقى لما نكون التركيزات عالية هذه حاجة،
+
+497
+00:39:56,760 --> 00:40:04,460
+والحاجة التانية لما نكون عند الـKa كبير أو الـKb
+
+498
+00:40:04,460 --> 00:40:07,780
+كبير، كل ما كان كبير كل ما كان أحسن، ولو كان
+
+499
+00:40:07,780 --> 00:40:12,660
+الـacid strong أحسن وأحسن، الـKa عالي جدا، فكل ما
+
+500
+00:40:12,660 --> 00:40:17,350
+زاد الـKa أو الـKbالـ titration curve بيكون
+
+501
+00:40:17,350 --> 00:40:21,810
+sharper كل ما كان تركيزات المتفاعلات عالية كل ما
+
+502
+00:40:21,810 --> 00:40:27,210
+كان الـ titration curve الـ brick تبعت وقه شمالها
+
+503
+00:40:27,210 --> 00:40:31,230
+sharper طيب يا شباب بنقو جافان وإذا الله راض الحصة
+
+504
+00:40:31,230 --> 00:40:32,090
+الجاية بنكمل
+
diff --git a/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/Uetvqs2Dbgo.srt b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/Uetvqs2Dbgo.srt
new file mode 100644
index 0000000000000000000000000000000000000000..87cae894c16c3e65c48f50d753ea4aa93914d89c
--- /dev/null
+++ b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/Uetvqs2Dbgo.srt
@@ -0,0 +1,1706 @@
+
+1
+00:00:21,110 --> 00:00:25,490
+بسم الله الرحمن الرحيم طيب يا شباب نكمل في موضوع
+
+2
+00:00:25,490 --> 00:00:27,970
+اللي بدأنا فيه الحصة الماضية كنا نتكلم عن
+
+3
+00:00:27,970 --> 00:00:33,860
+expressing concentrations، وتكلمنا عن الـMolarity
+
+4
+00:00:33,860 --> 00:00:38,060
+وتكلمنا عن الـNormality Calculations، و
+
+5
+00:00:38,060 --> 00:00:42,940
+الـDensity أيضا Calculations كيف ممكن نحسب التركيز
+
+6
+00:00:42,940 --> 00:00:46,320
+بمعلومية الـDensity والـPercentage والـFormula Weight اليوم، إن شاء الله، نكمل في نفس الموضوع
+
+7
+00:00:46,320 --> 00:00:50,220
+
+8
+00:00:50,220 --> 00:00:55,020
+لكن قبل ما نبدأ في طرق جديدة للتعبير عن التركيز
+
+9
+00:00:55,020 --> 00:01:00,550
+نطلع على مراجعة الـDilution Problems، فنطلع
+
+10
+00:01:00,550 --> 00:01:06,810
+على الـdilution problems، نقول إنه بشكل أساسي أي
+
+11
+00:01:06,810 --> 00:01:12,370
+عملية dilution المفروض نتطلع عليها من منطلق أن
+
+12
+00:01:12,370 --> 00:01:17,710
+عدد الـmillimoles قبل التخفيف يساوي عدد الـ
+
+13
+00:01:17,710 --> 00:01:22,110
+millimoles بعد التخفيف، يعني في معظم الأحيان بتكون
+
+14
+00:01:22,110 --> 00:01:26,650
+مسألة الـdilution مباشرة، بمعنى أن في عندي محلول
+
+15
+00:01:26,650 --> 00:01:34,350
+مركز، عايزين ناخد منه حجم معين عشان نحضر حجم نهائي
+
+16
+00:01:34,350 --> 00:01:40,510
+له تركيز معين، فالمجهول في معظم الأحيان هو الحجم من
+
+17
+00:01:40,510 --> 00:01:48,640
+المحلول المركز، طبعا احنا بنقول MIVI=MFVF، أو
+
+18
+00:01:48,640 --> 00:01:53,500
+الملي مولز قبل التخفيف تساوي الملي مولز بعد
+
+19
+00:01:53,500 --> 00:01:57,880
+التخفيف، طبعا شفنا احنا مسائل حتى على هذا الكلام
+
+20
+00:01:57,880 --> 00:02:02,840
+لما نتكلمنا عن الـdensity calculations، لكن الآن
+
+21
+00:02:02,840 --> 00:02:07,100
+برضه بنراجع مثالين أو ثلاثة أمثلة في نفس الموضوع
+
+22
+00:02:07,100 --> 00:02:13,620
+فنقول مثلا المثال التالي بيقول: prepare 200 ml of
+
+23
+00:02:13,620 --> 00:02:19,690
+0.12 molar potassium nitrate solution from 0.48
+
+24
+00:02:19,690 --> 00:02:24,270
+molar solution، يعني أنا في عندي 0.48 molar
+
+25
+00:02:24,270 --> 00:02:30,310
+potassium nitrate solution، عايز أحضر 200 ml من 0
+
+26
+00:02:30,310 --> 00:02:34,430
+.12 molar solution، طبعا هذه مسألة مباشرة بتقول لي
+
+27
+00:02:34,430 --> 00:02:37,110
+والله الـmillimoles قبل التخفيف تساوي الـ
+
+28
+00:02:37,110 --> 00:02:40,490
+millimoles بعد التخفيف، فالـmillimoles بعد التخفيف
+
+29
+00:02:40,490 --> 00:02:44,760
+عبارة عن 0.12 × 200، قبل التخفيف قدر عن الـmolarity
+
+30
+00:02:44,760 --> 00:02:49,700
+في الـvolume، يعني 0.48 × الـvolume بالـml بتساوي 0
+
+31
+00:02:49,700 --> 00:02:54,500
+.12 × 200، إذا الـvolume بالـml 50 ml
+
+32
+00:02:56,560 --> 00:03:01,820
+هذا الكلام أن بدي آخذ خمسين مل من الـpotassium
+
+33
+00:03:01,820 --> 00:03:05,440
+nitrate المركز اللي تركيزه 0.48 molar
+
+34
+00:03:05,440 --> 00:03:10,480
+وأضيف عليهم أو أضيفهم على ماء لغاية ما الحجم
+
+35
+00:03:10,480 --> 00:03:13,860
+النهائي يكون 200 مل، ساعتها الـ200 مل هتكون
+
+36
+00:03:13,860 --> 00:03:17,120
+تركيز الـpotassium nitrate فيها 0.12
+
+37
+00:03:17,120 --> 00:03:23,990
+molar، في عندي الآن مثال، يعني هو عبارة عن ترجمة
+
+38
+00:03:23,990 --> 00:03:30,150
+عملية، في بعض الأحيان ممكن يكون فيه مشكلة، في عندي عينة
+
+39
+00:03:30,150 --> 00:03:36,350
+منغنيز، أخذت منها خمسة جرام منغنيز ووضعتهم في
+
+40
+00:03:36,350 --> 00:03:41,510
+100 من الماء، لكن لما نقول عينة معناته شيء غير نقي
+
+41
+00:03:42,190 --> 00:03:46,050
+فهو بيقول لي: If the percentage of manganese in the
+
+42
+00:03:46,050 --> 00:03:49,890
+sample is about 5%، يعني الخمسة جرام هدول اللي أنا
+
+43
+00:03:49,890 --> 00:03:54,010
+أخذتهم مش كلهم منغنيز، 5% فقط منهم
+
+44
+00:03:54,010 --> 00:03:58,030
+منغنيز، والباقي يعني contaminants، باقي الأجرام
+
+45
+00:03:58,030 --> 00:04:03,910
+مواد أخرى مختلفة، كويس، فبيقول إيه: What volume is needed
+
+46
+00:04:03,910 --> 00:04:09,190
+to prepare 100 ml of approximately 3
+
+47
+00:04:09,190 --> 00:04:14,540
+millimolar solution، ننتبه شوية، ليش هو يعني ضروري
+
+48
+00:04:14,540 --> 00:04:19,120
+أنه بده يحضر 3 millimolar solution؟ نقول زي
+
+49
+00:04:19,120 --> 00:04:24,100
+ما ذكرنا سابقا، في كثير من الأحيان الطريقة بتفرض...
+
+50
+00:04:24,100 --> 00:04:29,040
+طريقة التحليل بتفرض عليها قيود في الـrange من الـ
+
+51
+00:04:29,040 --> 00:04:33,360
+concentrations اللي ممكن أستخدمها، يعني كل طريقة في
+
+52
+00:04:33,360 --> 00:04:38,000
+لها مدى من الـconcentration اللي بتشتغل فيه، فمثلا
+
+53
+00:04:38,000 --> 00:04:43,700
+طريقة التحليل اللي أنا بدي أستخدمها يعني تستدعي
+
+54
+00:04:43,700 --> 00:04:47,480
+أن أنا أستخدم حاجة قريبة من 3 × 10⁻³
+
+55
+00:04:47,480 --> 00:04:52,500
+molar، فأنا عايز أحضر محلول 3 × 10⁻³
+
+56
+00:04:52,500 --> 00:04:57,400
+molar solution، بقول في البداية ممكن
+
+57
+00:04:57,400 --> 00:05:02,740
+نجيب number of moles من المنجنيز لما نذوب
+
+58
+00:05:02,740 --> 00:05:06,660
+5 g، 5 g طبعا زي ما قلت مش كلهم
+
+59
+00:05:06,660 --> 00:05:09,820
+منغنيز، 5% منهم منغنيز، 5% من
+
+60
+00:05:09,820 --> 00:05:14,000
+الخمسة من المئة هي تقريبا المنجنيز، 5% × 5
+
+61
+00:05:14,000 --> 00:05:16,160
+من المئة هي الجرام من المنجنيز، لو قسمتها على الـ
+
+62
+00:05:16,160 --> 00:05:18,700
+atomic weight من المنجنيز، بيعطيني مول منجنيز
+
+63
+00:05:19,440 --> 00:05:26,220
+طبعا لما أقسم الـmol على الـvolume بحصل
+
+64
+00:05:26,220 --> 00:05:29,480
+على الـmolarity، فأنا ضربت 4.5 × 10⁻² مول في 10³صار مل مول، قسمته على
+
+65
+00:05:29,480 --> 00:05:34,580
+الـ1000 ml، صار مل مول، قسمته على
+
+66
+00:05:34,580 --> 00:05:37,960
+الـ1000 ml، مل مول على الـml معناته molarity
+
+67
+00:05:37,960 --> 00:05:41,580
+فأعطاني 4.5 × 10⁻² molar
+
+68
+00:05:41,580 --> 00:05:47,360
+يعني لما أذوب 5 جرام من المنجنيز في 1000 ml
+
+69
+00:05:47,360 --> 00:05:51,720
+معناته تركيز المنجنيز في الـ1000 ml  4.5
+
+70
+00:05:51,720 --> 00:05:57,460
+× 10⁻² molar تقريبا، أنا ما بديش هذا
+
+71
+00:05:57,460 --> 00:06:01,980
+التركيز، أنا بدي تقريبا 3 × 10⁻³
+
+72
+00:06:01,980 --> 00:06:06,760
+molar، فإيش بدي أعمل؟ بدي أخفف الـ4.5 × 10⁻²
+
+73
+00:06:06,760 --> 00:06:10,940
+علشان يعطيني 3 × 10⁻³
+
+74
+00:06:10,940 --> 00:06:17,060
+molar، فبقول MIVI=MFVF، أو الملي مولز قبل
+
+75
+00:06:17,060 --> 00:06:22,260
+التخفيف بتساوي الملي مولز بعد التخفيف، فـ4.5×10² ×
+
+76
+00:06:22,260 --> 00:06:25,360
+الـvolume بالـml اللي بتاخده من المركز يساوي
+
+77
+00:06:25,360 --> 00:06:30,980
+التركيز النهائي 3×10⁻³، عايز أحضر منه 100 ml
+
+78
+00:06:30,980 --> 00:06:35,960
+فبيطلع الـvolume بالـml 6.7 ml، هدول الـ6.7
+
+79
+00:06:35,960 --> 00:06:39,640
+ml لو ذوبتهم، أو لو لم أذوبهم، لو أن
+
+80
+00:06:39,640 --> 00:06:45,640
+نقلتهم إلى 100 ml، حجم نهائي 100 ml solution، معناته
+
+81
+00:06:45,640 --> 00:06:51,160
+أنا حصلت على تركيز مقداره تقريبا 3 × 10⁻³
+
+82
+00:06:51,160 --> 00:06:58,900
+molar manganese solution، ننتقل إلى
+
+83
+00:06:58,900 --> 00:07:04,420
+مسألة أخرى، مسألة ثالثة، وهذه المسألة جيدة لأن
+
+84
+00:07:04,420 --> 00:07:10,780
+بتفهمنا أكثر إيش يعني تخفيف وإيش مفهوم التخفيف في
+
+85
+00:07:10,780 --> 00:07:16,750
+هذه المسألة، في عندي محلولين، محلول barium hydroxide
+
+86
+00:07:16,750 --> 00:07:21,730
+تركيزه 0.4، ومحلول sodium hydroxide
+
+87
+00:07:21,730 --> 00:07:26,110
+تركيزه 0.3، عايز أخلط المحلولين هذين، أو
+
+88
+00:07:26,110 --> 00:07:29,350
+جزء من الـbarium hydroxide مع محلول الـsodium
+
+89
+00:07:29,350 --> 00:07:34,030
+hydroxide، علشان أحصل في النهاية على تركيز الـ
+
+90
+00:07:34,030 --> 00:07:39,430
+hydroxide 0.5 molar، فإيش بدي أعمل؟ نفس
+
+91
+00:07:39,430 --> 00:07:43,390
+الكلام، بدي أنتبه لنقطة جوهرية جدا، أن والله أنا
+
+92
+00:07:43,390 --> 00:07:47,630
+مدور على تركيز الهيدروكسيد، إذا بدي أقول الملي
+
+93
+00:07:47,630 --> 00:07:52,190
+مول للهيدروكسيد من المحلول الأول، واللي هو barium
+
+94
+00:07:52,190 --> 00:07:55,950
+hydroxide، زائد الملي مول من المحلول الثاني اللي
+
+95
+00:07:55,950 --> 00:07:59,350
+هو الصوديوم هيدروكسيد، بدي يساوي الملي مول من
+
+96
+00:07:59,350 --> 00:08:01,630
+الهيدروكسيد في المحلول النهائي، لأن أنا بدخل إثنين
+
+97
+00:08:01,630 --> 00:08:05,230
+محلولين علشان أحصل على المحلول النهائي، إذا الملي
+
+98
+00:08:05,230 --> 00:08:09,150
+مول من الأول زائد الملي مول من الثاني يساوي الملي
+
+99
+00:08:09,150 --> 00:08:13,550
+مول من النهائي، لأن كمان مرة الملي مول قبل التخفيف
+
+100
+00:08:13,570 --> 00:08:17,550
+بتساوي الملي مول في أي قانون تخفيف اللي عندي، فهو
+
+101
+00:08:17,550 --> 00:08:20,890
+الملي مول الهيدروكسيد من الباريوم هيدروكسيد زائد
+
+102
+00:08:20,890 --> 00:08:23,330
+الملي مول الهيدروكسيد من الصوديوم هيدروكسيد
+
+103
+00:08:23,330 --> 00:08:26,150
+بتساوي الملي مول الهيدروكسيد في الـfinal solution
+
+104
+00:08:26,150 --> 00:08:29,810
+لأن أنا خلطت المحلولين، فالهيدروكسيد جاي من
+
+105
+00:08:29,810 --> 00:08:34,070
+المحلولين، بس بدي أذكركم أن الـmilli-mol هيدروكسيد
+
+106
+00:08:34,070 --> 00:08:38,870
+من الباريوم هيدروكسيد أو بداية تركيز الهيدروكسيد في
+
+107
+00:08:38,870 --> 00:08:42,770
+الباريوم هيدروكسيد يساوي ضعف تركيز الباريوم
+
+108
+00:08:42,770 --> 00:08:47,110
+هيدروكسيد، لأن كل مول من الباريوم هيدروكسيد فيه
+
+109
+00:08:47,110 --> 00:08:50,870
+إثنين مول هيدروكسيد، إذا تركيز الهيدروكسيد ضعف
+
+110
+00:08:50,870 --> 00:08:53,250
+تركيز الباريوم هيدروكسيد، فإذا كان الباريوم
+
+111
+00:08:53,250 --> 00:08:59,720
+هيدروكسيد 0.4 molar، هيجي أن الباقي
+
+112
+00:08:59,720 --> 00:09:04,700
+الهيدروكسيد 0.8 molar، 0.8 بتاخد منه حجم
+
+113
+00:09:04,700 --> 00:09:09,760
+معين مقداره X، مش عارف قد إيش هو X، هيصبح ملي مول
+
+114
+00:09:09,760 --> 00:09:14,860
+هيدروكسيد جاي من الباريوم هيدروكسيد زائد الملي مول
+
+115
+00:09:14,860 --> 00:09:17,720
+هيدروكسيد اللي جاي من الصوديوم هيدروكسيد، فأنا عندي
+
+116
+00:09:17,720 --> 00:09:21,630
+50 ml صوديوم هيدروكسيد،  قد إيش تركيز الهيدروكسيد
+
+117
+00:09:21,630 --> 00:09:25,790
+0.3، 0.3 × 50 هي الـ
+
+118
+00:09:25,790 --> 00:09:29,390
+millimoles من الهيدروكسيد اللي جايه من الـsodium
+
+119
+00:09:29,390 --> 00:09:32,950
+hydroxide، المجموع هم بدي أساويه الـmillimoles من
+
+120
+00:09:32,950 --> 00:09:35,890
+الهيدروكسيد في المحلول النهائي، الـmolarity
+
+121
+00:09:35,890 --> 00:09:40,130
+للهيدروكسيد في المحلول النهائي 0.5 في الحجم
+
+122
+00:09:40,130 --> 00:09:45,170
+النهائي، الـ50 زائد الـX اللي أضفناها عليه، يبقى
+
+123
+00:09:45,170 --> 00:09:49,950
+50 + X، ألاحظ أن الـX قيمتها 33
+
+124
+00:09:49,950 --> 00:09:54,190
+ml، معنى الكلام لو أنا أخذت الـ50 ml من الـsodium
+
+125
+00:09:54,190 --> 00:10:01,070
+hydroxide اللي تركيزه 0.3 وحطيت عليه 33 ml من
+
+126
+00:10:01,070 --> 00:10:05,770
+الباريوم هيدروكسيد اللي تركيزه 0.4 راح أحصل على
+
+127
+00:10:05,770 --> 00:10:13,570
+محلول هيدروكسيد نهائي حجمه 50 + 33، وتركيزه 0.5 من
+
+128
+00:10:13,570 --> 00:10:19,380
+10، هذا هو يعني التخفيف بشكل عام، تخفيف يعني ممكن
+
+129
+00:10:19,380 --> 00:10:23,740
+نقول علاقات مباشرة جدا، إذا كان بدي أتغلب فيها
+
+130
+00:10:23,740 --> 00:10:27,100
+فأتذكر أن الـmillimoles قبل التخفيف تساوي الـ
+
+131
+00:10:27,100 --> 00:10:29,840
+millimoles بعد التخفيف، وخلاص أحاول أشتغل بهذا
+
+132
+00:10:29,840 --> 00:10:37,860
+المفهوم بحل أي مسألة dilution، الآن يا شباب، عودة إلى
+
+133
+00:10:37,860 --> 00:10:42,980
+expressing concentrations، زي ما ذكرت، احنا طلعنا
+
+134
+00:10:42,980 --> 00:10:48,870
+على الـmolarity والـnormality calculations وطلعنا
+
+135
+00:10:48,870 --> 00:10:51,910
+على الـdensity وكيف ممكن نحولها إلى molarity؟
+
+136
+00:10:51,910 --> 00:10:57,410
+كويس، الآن ننتقل إلى أساليب أخرى للتعبير عن
+
+137
+00:10:57,410 --> 00:11:04,690
+التركيز، فبقول هذه الأساليب تعتمد على نوع الـsolute
+
+138
+00:11:04,690 --> 00:11:12,720
+ونوع الـsample، فممكن الـsolute يكون صلب، ممكن
+
+139
+00:11:12,720 --> 00:11:17,720
+العينة نفسها تكون صلبة، زي إيه؟ زي مثلا الـcoin،
+
+140
+00:11:17,720 --> 00:11:22,900
+القطعة النقدية اللي في جيبك مثلا، كويس؟
+
+141
+00:11:22,900 --> 00:11:28,220
+هذا الشكل بيتكون من زنك ونحاس غالبا، ويمكن شوية
+
+142
+00:11:28,220 --> 00:11:33,640
+نيكل مثلا، لكن لاحظوا أن النحاس مثلا صلب
+
+143
+00:11:33,640 --> 00:11:38,940
+والزنك صلب والنيكل صلب، كلهم مذابين في بعض،
+
+144
+00:11:38,940 --> 00:11:43,210
+فهذا عبارة عن إيه؟ صلب في صلب، نفس الكلام لو حبيت
+
+145
+00:11:43,210 --> 00:11:49,330
+تأخذ مثلا قطعة ذهب، خاتم ذهب مثلا أو سبيكة ذهب،
+
+146
+00:11:49,330 --> 00:11:53,910
+هذه فيها شوية نحاس وشوية إيه؟ وذهب طبعا كثير
+
+147
+00:11:53,910 --> 00:11:58,410
+بشكل أساسي، ذهب لكن شوية نحاس، فبرضه النحاس مذاب
+
+148
+00:11:58,410 --> 00:12:04,940
+تماما في إيه؟ في الذهب، فهذا صلب في صلب، عامل محلول
+
+149
+00:12:04,940 --> 00:12:11,060
+solid، لكن solid مش محلول يعني سائل، فهذا عبارة عن
+
+150
+00:12:11,060 --> 00:12:16,460
+إيه؟ solid، نقوله alloy، alloy سبيكة، صحيح alloy، فهذا
+
+151
+00:12:16,460 --> 00:12:21,300
+صلب في صلب، هذا نوع من أنواع العينات في، يعني زي ما
+
+152
+00:12:21,300 --> 00:12:27,260
+تقول مثلا برضه قد إيش في عندك كالسيوم في حجر، برضه الـ
+
+153
+00:12:27,260 --> 00:12:31,820
+كالسيوم صلب والحجر أيضا، أو كالسيوم كربونات في
+
+154
+00:12:31,820 --> 00:12:35,920
+حجر والحجر أيضا صلب، فهذا صلب في صلب، هذا نوع من
+
+155
+00:12:35,920 --> 00:12:40,680
+أنواع العينات، الفولاذ، الحديد وغيره، والألمنيوم
+
+156
+00:12:40,680 --> 00:12:48,170
+أي شيء سبائك، نقول هذا يعتبر صلب في صلب، طيب يا شباب
+
+157
+00:12:48,170 --> 00:12:52,270
+النوع الثاني واللي هنستخدمه بشكل كبير في الكيمياء
+
+158
+00:12:52,270 --> 00:12:56,470
+التحليلية، النوع الثاني هو النوع المستخدم بشكل كبير
+
+159
+00:12:56,470 --> 00:13:01,450
+جدا في الكيمياء التحليلية، اللي هو لما نقول الـsolute
+
+160
+00:13:01,450 --> 00:13:07,610
+صلب لكن العينة solution، بمعنى إيه؟ بمعنى أنا آخذ
+
+161
+00:13:07,610 --> 00:13:11,410
+مادة صلبة، أذوبها في الماء مثلا عشان أحصل على عينة
+
+162
+00:13:11,410 --> 00:13:15,010
+سائلة، هذا النوع من أنواع المحاليل، هذا النوع
+
+163
+00:13:15,010 --> 00:13:19,590
+المستخدم بشكل كبير جدا جدا في الكيمياء التحليلية
+
+164
+00:13:19,590 --> 00:13:28,010
+وسنركز عليه، النوع الثالث، إذا كان الـsolute سائل و
+
+165
+00:13:28,010 --> 00:13:34,150
+العينة أيضا solution، الـsolute سائل liquid والعينة
+
+166
+00:13:34,150 --> 00:13:39,010
+solution، زي إيه؟ زي مثلا والله بدنا نحضر محلول
+
+167
+00:13:39,010 --> 00:13:44,950
+مخفف من الإيثانول، فنحط شوية إيثانول عليها ماء
+
+168
+00:13:45,980 --> 00:13:51,780
+الإيثانول سائل وأيضا الماء سائل، فسائل في سائل، هذا
+
+169
+00:13:51,780 --> 
+
+223
+00:18:30,220 --> 00:18:34,580
+في عشرة أس ستة بدنا part per billion في عشرة أس
+
+224
+00:18:34,580 --> 00:18:38,360
+تسعة معايا شبكة نفس الكلام المفهوم تماما وكل شيء جاي
+
+225
+00:18:38,360 --> 00:18:41,820
+من وين جاي؟ من الـ percentage لكن لأن حجم العينة
+
+226
+00:18:41,820 --> 00:18:46,520
+بالمللي، فأنا بقول: إيش في تحكم؟ مش gram sample، لأ.
+
+227
+00:18:46,520 --> 00:18:51,880
+العينة هي حجم volume sample بالمللي، لِأنه الـ
+
+228
+00:18:51,880 --> 00:18:56,940
+solute مذاب في حجم معين. برضه، هل في عندي shortcuts؟ و
+
+229
+00:18:56,940 --> 00:19:04,040
+short cuts مهمة جداً أن تتذكرها. فـ milligram ممكن
+
+230
+00:19:04,040 --> 00:19:08,980
+نقول الـ PPM بدها
+
+231
+00:19:08,980 --> 00:19:15,000
+تساوي الـ milligram على الـ liter أو ممكن نقول يعني
+
+232
+00:19:15,000 --> 00:19:24,040
+milligram على الـ ألف مللي. هي جرام مع المللي لأن هيها
+
+233
+00:19:24,040 --> 00:19:28,780
+جرام على إيش؟ على المللي. هدول واحدة، هيروحوا. إذاً، الأن
+
+234
+00:19:28,780 --> 00:19:32,900
+إيش ودي زي دايم دي؟ المللي عشرة أس سالب ثلاثة، والألف
+
+235
+00:19:32,900 --> 00:19:36,760
+عشرة أس سالب ستة. يعني PPM، هذا short cut هذا
+
+236
+00:19:36,760 --> 00:19:41,080
+تحديداً ملي جرام على اللتر، أو ملي جرام على الألف مللي.
+
+237
+00:19:41,080 --> 00:19:49,560
+هذا هنستخدمه بشكل كبير جداً، بشكل كبير جداً، هي
+
+238
+00:19:49,560 --> 00:19:54,000
+الوحدات جرام ومللي. إيش بيزيد إذا كنت استخدمت نفس
+
+239
+00:19:54,000 --> 00:19:59,720
+الوحدات؟ إيش بيزيد عندك؟ بيزيد عندك مللي فوق، وبيزيد عندك
+
+240
+00:19:59,720 --> 00:20:04,240
+ألف تحت. الملي prefix معناته عشرة أس سالب ثلاثة.
+
+241
+00:20:04,240 --> 00:20:09,340
+والألف عشرة أس ثلاثة. عشرة أس سالب ثلاثة على
+
+242
+00:20:09,340 --> 00:20:13,420
+العشرة أس ثلاثة، إيش بيصير عندك؟ يعني PPM part per
+
+243
+00:20:13,420 --> 00:20:18,460
+million مثلاً. فهذا هنستخدمه بشكل كبير جداً.
+
+244
+00:20:21,400 --> 00:20:25,420
+احنا مش كل شغلنا يعني، بس معظم شغلنا آه، ليش؟
+
+245
+00:20:25,420 --> 00:20:28,980
+لأنك لو رحت على المختبر، بدك تعمل معايرة، تعمل
+
+246
+00:20:28,980 --> 00:20:32,120
+معايرة، أكم من مللي بياخد منك؟ لو بدك تاخد في البيبت،
+
+247
+00:20:32,120 --> 00:20:35,900
+بتاخد أكم من مللي؟ لو بدك تعمل برضه، خلينا نقول
+
+248
+00:20:35,900 --> 00:20:40,120
+gravimetry، بتاخد أكم من مللي؟ فأكثر شغلنا من المللي،
+
+249
+00:20:40,120 --> 00:20:42,780
+بتاخدش لتر مثلاً، ولا إثنين لتر، ولا عشرة لترات،
+
+250
+00:20:47,730 --> 00:20:53,690
+ممكن تقول PPM
+
+251
+00:20:53,690 --> 00:21:00,650
+مثلاً micro gram على الـ milliliter. ليش؟ لأن الـ gram
+
+252
+00:21:00,650 --> 00:21:03,910
+والـ milliliter، هذه وحدة السوليوت وهذه وحدة
+
+253
+00:21:03,910 --> 00:21:09,330
+العينة. إيش بيزيد عدا ذلك؟ micro هي PPM لو بدك تقول
+
+254
+00:21:09,330 --> 00:21:10,170
+ppb
+
+255
+00:21:12,640 --> 00:21:17,960
+ممكن ساعتها تطلع على nano gram على الـ milli. هي الـ
+
+256
+00:21:17,960 --> 00:21:22,000
+gram والـ milli. الـ gram وحدة الـ solute، والـ milli
+
+257
+00:21:22,000 --> 00:21:28,140
+وحدة الـ sample. إذا نزلت nano، الـ nano عشرة أس سالب
+
+258
+00:21:28,140 --> 00:21:33,600
+تسعة. فهذه short cuts جيدة، يعني جيدة لأنه أنا بقدر
+
+259
+00:21:33,600 --> 00:21:39,620
+أحلّ المسألة بسرعة، لكن يجب أن تكون
+
+260
+00:21:39,620 --> 00:21:43,480
+متأكداً منها 100%، والتأكد منها مش صعب، يعني مش صعب
+
+261
+00:21:43,480 --> 00:21:47,040
+أن تعرف أن الملي عشرة أس سالب ثلاثة، والكلو
+
+262
+00:21:47,040 --> 00:21:52,380
+عشرة أس سالب ثلاثة مثلاً. الـ micro عشرة أس سالب ستة. الـ
+
+263
+00:21:52,380 --> 00:21:55,760
+nano عشرة أس سالب تسعة. الـ pico عشرة أس سالب
+
+264
+00:21:55,760 --> 00:21:59,000
+إثني عشر. يعني هذه الشغلات اللي بنستخدمها بشكل كبير، و
+
+265
+00:21:59,000 --> 00:22:03,660
+الـ prefixes معروفة. الـ DC عشرة أس سالب واحد، الصنتي
+
+266
+00:22:03,660 --> 00:22:07,580
+عشرة أس سالب إثنين. ماشي. هذه الشغلات لازم تكون في
+
+267
+00:22:07,580 --> 00:22:12,020
+بالنا دائماً. النوع الأخير يا شباب من أنواع المحاليل
+
+268
+00:22:12,020 --> 00:22:18,680
+إذا كان في عندي الـ solute liquid، والـ sample
+
+269
+00:22:18,680 --> 00:22:23,940
+solution، فبتصير volume to volume. نفس المنطق، بس عند
+
+270
+00:22:23,940 --> 00:22:27,520
+هذه الـ volume للسوليوت بالمللي، والـ volume للـ sample
+
+271
+00:22:27,520 --> 00:22:32,420
+أيضاً بالمللي. فـ 10 أس 2 hundred part per hundred. فـ 10
+
+272
+00:22:32,420 --> 00:22:36,920
+أس 3 thousand part per thousand. فـ 10 أس 6  part per million. فـ 10
+
+273
+00:22:36,920 --> 00:22:40,680
+أس 9 part per billion. نفس
+
+274
+00:22:40,680 --> 00:22:46,860
+الكلام تماماً. فالـ... مثلاً الـ PPM micro liter على الـ
+
+275
+00:22:46,860 --> 00:22:50,600
+liter. لأن خد أنتَ الـ liter مع الـ liter، إيش بيضل؟
+
+276
+00:22:50,600 --> 00:22:54,580
+بيضل الـ micron. الـ micron هي PPM. فأنتَ ممكن تستخدم
+
+277
+00:22:54,580 --> 00:22:58,800
+الـ shortcut أو تستخدم لو حبيت القانون، واحنا
+
+278
+00:22:58,800 --> 00:23:06,120
+هنحاول أن نُفرجيك الإثنين. طيب يا شباب، إذا هذه طرق
+
+279
+00:23:06,120 --> 00:23:10,200
+مختلفة للتعبير عن التركيز، تتوقف على إيش؟ طبيعة
+
+280
+00:23:10,200 --> 00:23:15,940
+السوليوت، إيش طبيعة الـ sample، لكن كمفهوم حسابي،
+
+281
+00:23:15,940 --> 00:23:23,440
+كلهم واحد، كلهم واحد، بتشتق الأنواع المختلفة من الـ
+
+282
+00:23:23,440 --> 00:23:26,550
+part per hundred أو من الـ percentage. والـ percentage
+
+283
+00:23:26,550 --> 00:23:31,230
+شيء احنا متعودين عليه من زمان. كيف نطلعه؟ بس مجرد
+
+284
+00:23:31,230 --> 00:23:35,730
+أنه بدل ما تحط 100 في الـ percentage بتحط ألف أو
+
+285
+00:23:35,730 --> 00:23:41,430
+مليون أو ألف مليون في الـ thousand أو المليون أو الـ
+
+286
+00:23:41,430 --> 00:23:46,660
+billion. فنتطلع على المثال التالي الآن. بنقول: في عندي
+
+287
+00:23:46,660 --> 00:23:56,020
+عينة من عينة ما، حللناها، فوجدنا أن فيها ثلاثة وستة
+
+288
+00:23:56,020 --> 00:24:00,500
+من عشرة micro gram زنك. إيش بيقول لي؟ بيقول لي: find
+
+289
+00:24:00,500 --> 00:24:04,940
+the concentration of zinc in ppm and ppb. خلينا
+
+290
+00:24:04,940 --> 00:24:08,820
+ناخد واحدة واحدة. خلينا نعبر عن التركيز باستخدام
+
+291
+00:24:08,820 --> 00:24:14,020
+الـ ppm في البداية، وبعدين بروح للـ ppb. أنا عندي
+
+292
+00:24:14,020 --> 00:24:20,140
+وزن العينة 62 جرام، ووزن الـ solute ثلاثة وستة. وقتها
+
+293
+00:24:20,140 --> 00:24:25,420
+بتبقى شوية. أنا بقول والله الـ PPM على طول micro gram
+
+294
+00:24:25,420 --> 00:24:28,800
+على gram. micro gram solute على gram sample يعني
+
+295
+00:24:28,800 --> 00:24:33,920
+بتساوي ثلاثة وستة على اثنين وستين، بتساوي واحد وأربعة
+
+296
+00:24:33,920 --> 00:24:39,990
+على طول. هيقلّ. هذا حل مباشر. ليش؟ لأن الـ PPM micro
+
+297
+00:24:39,990 --> 00:24:43,190
+جرام على جرام. هي جرام على جرام. micro هي PPM. ما فيش
+
+298
+00:24:43,190 --> 00:24:46,790
+عندي مشكلة. فالمقطعين تماماً كما
+
+299
+00:24:46,790 --> 00:24:52,550
+احتاجهم، فبحطهم على طول. لكن بإمكاني، أنا الكل ينتبه،
+
+300
+00:24:52,550 --> 00:24:57,870
+بإمكاني أقول: والله الـ PPM بتساوي الـ weight solute
+
+301
+00:24:57,870 --> 00:25:03,450
+بالجرام، يبقى ثلاثة وستة في عشرة أس سالب ستة هي جرام
+
+302
+00:25:03,450 --> 00:25:09,600
+على الـ weight sample بالجرام، اثنين وستين جرام، جاي في
+
+303
+00:25:09,600 --> 00:25:14,060
+عشرة أس ستة هي الـ PPM. استخدم القانون، هي القانون
+
+304
+00:25:14,060 --> 00:25:17,240
+فـ العشرة أس سالب ستة مع العشرة أس سالب ستة
+
+305
+00:25:17,240 --> 00:25:20,960
+بيطلع عندك واحد وأربعة. سيّان، أنا عملت هيك أو هيك، هي
+
+306
+00:25:20,960 --> 00:25:24,400
+هيّ: يا تستخدم الـ shortcut، يا تستخدم القانون، وفي
+
+307
+00:25:24,400 --> 00:25:28,320
+الحالتين ما فيش مجال للخطأ، يعني الموضوع مباشر كتير.
+
+308
+00:25:29,600 --> 00:25:33,760
+نفس الكلام يا شباب، لما بدنا نيجي نحسب الـ ppb. قال لي:
+
+309
+00:25:33,760 --> 00:25:39,160
+احسب كمان أو عبّر عن التركيز بالـ ppb. بقول: والله الـ
+
+310
+00:25:39,160 --> 00:25:47,840
+ppb هو عبارة عن إيه؟ الـ ppb nano gram على الجرام.
+
+311
+00:25:47,840 --> 00:25:51,620
+أنا عندي ثلاثة وستة من عشرة micro يعني عشرة أس
+
+312
+00:25:51,620 --> 00:25:56,500
+ثلاثة nano gram على اثنين وستين جرام، العينة. الـ
+
+313
+00:25:56,500 --> 00:26:02,250
+micro،  الألف nano. معايا الـ micro، العشرة أس سالب ستة،
+
+314
+00:26:02,250 --> 00:26:07,970
+ألف في عشرة أس سالب تسعة. مثلاً. أو لو ما حبيتش، ما فيش
+
+315
+00:26:07,970 --> 00:26:14,750
+مشكلة. لو ما حبيتش، ممكن نقول: والله الـ ppb بده يساوي
+
+316
+00:26:14,750 --> 00:26:20,150
+وزن الـ solute اللي هو ثلاثة وستة في عشرة أس سالب ستة
+
+317
+00:26:20,150 --> 00:26:23,550
+جرام، بالـ milligram. وزن الـ solute بالـ milligram، على وزن
+
+318
+00:26:23,550 --> 00:26:29,150
+العينة بالـ milligram. في عشرة أس 9 هي الـ ppb. سواء اشتغلت
+
+319
+00:26:29,150 --> 00:26:33,890
+هيك أو هيك، نفس الكلام يا شباب. يا إما تستخدم
+
+320
+00:26:33,890 --> 00:26:46,790
+القانون. طيب يا شباب، نتطلع على مسألة ثانية. صاحبنا
+
+321
+00:26:46,790 --> 00:26:51,330
+عينة الدم 25 microliter. عينة الدم 25 microliter.
+
+322
+00:26:51,330 --> 00:26:56,820
+فحلّلنا، وجدنا فيها glucose، طلع عندي ستة وعشرين و
+
+323
+00:26:56,820 --> 00:27:01,540
+سبعة من عشرة microgram. يعني الجلوكوز صلب هي، وعطاني
+
+324
+00:27:01,540 --> 00:27:07,120
+وزنه بالإيه؟ بالجرام. والعينة solution، عطاني
+
+325
+00:27:07,120 --> 00:27:11,520
+حجمها بالـ microliter. فهي solution. فإيش بيقوله؟
+
+326
+00:27:11,520 --> 00:27:16,600
+بيقول: express the concentration as PPM في البداية.
+
+327
+00:27:16,600 --> 00:27:21,440
+PPM. فبقول: والله الـ PPM يعني إيش بيساوي؟ بيساوي الـ
+
+328
+00:27:21,440 --> 00:27:28,100
+microgram على المللي. microgram هي الـ PPM. ساوي micro
+
+329
+00:27:28,100 --> 00:27:32,700
+جرام على المللي لتر، لأن قلنا هي الجرام وحدة
+
+330
+00:27:32,700 --> 00:27:38,230
+السوليوت الصلب، وهي المللي وحدة العينة الـ volume. فبقول:
+
+331
+00:27:38,230 --> 00:27:44,310
+أنا عندي ثلاثة وستة microgram على المللي. عندي خمسة
+
+332
+00:27:44,310 --> 00:27:47,010
+وعشرين. ثلاثة لأ، مش ثلاثة وستة. ستة وعشرين وسبعة من
+
+333
+00:27:47,010 --> 00:27:52,570
+عشرة، أنا آسف طبعاً، لسة المثل الماضي معلّق. ستة و
+
+334
+00:27:52,570 --> 00:27:57,050
+عشرين وسبعة من عشرة هي microgram على المللي. خمسة و
+
+335
+00:27:57,050 --> 00:28:01,590
+عشرين microliter يعني في عشرة أس سالب ثلاثة
+
+336
+00:28:01,590 --> 00:28:03,510
+milliliter. أنا بدي
+
+337
+00:28:07,350 --> 00:28:12,650
+تاخدوا بالكم. أنا بدي milli تحت، هيها. فهنا في عندي 25
+
+338
+00:28:12,650 --> 00:28:19,270
+micro. الـ micro أقل من الـ milli بإيه؟ بألف مرة. فعندي
+
+339
+00:28:19,270 --> 00:28:23,450
+هذا الـ shortcut تبعي، بيعطينا على طول ألف وسبعين.
+
+340
+00:28:23,450 --> 00:28:27,970
+بقول: ماشي. أنا بقول الـ ppm عبارة عن micro gram على
+
+341
+00:28:27,970 --> 00:28:31,190
+الـ milli. فوق. الـ micro gram ستة وعشرين وسبعة من عشرة.
+
+342
+00:28:31,190 --> 00:28:35,710
+الـ 25 microliter. أكمل ده. الـ 25 في عشرة أس سالب
+
+343
+00:28:35,710 --> 00:28:42,860
+ثلاثة من الـ milli عشان تصير micro صحيح.
+
+344
+00:28:42,860 --> 00:28:49,780
+صحيح. الـ micro هنا في عشرة أس سالب ثلاثة، وعشرة
+
+345
+00:28:49,780 --> 00:28:53,540
+أس سالب ثلاثة هي عشرة أس سالب ستة تبعتك لأن الـ
+
+346
+00:28:53,540 --> 00:28:56,600
+micro عشرة أس سالب ستة زي ما اتفضلت. طب هي عشرة
+
+347
+00:28:56,600 --> 00:29:00,540
+أس سالب ثلاثة وهي الملي عشرة أس سالب ثلاثة، هي عشرة
+
+348
+00:29:00,540 --> 00:29:08,960
+أس سالب ستة. لو حبيت، بلاش. قول: والله الـ PPM بتساوي
+
+349
+00:29:08,960 --> 00:29:12,840
+الـ weight solute بالـ milligram، يعني ستة وعشرين وسبعة من
+
+350
+00:29:12,840 --> 00:29:17,520
+عشرة في عشرة أس سالب ستة gram، على الـ volume sample
+
+351
+00:29:17,520 --> 00:29:23,640
+بالـ milli يعني خمسة وعشرين في عشرة أس سالب ثلاثة milli
+
+352
+00:29:23,640 --> 00:29:28,620
+في عشرة أس ستة. هذا بيعطيك على طول الـ PPM. هي طبعاً
+
+353
+00:29:28,620 --> 00:29:33,160
+عشرة أس ستة مع عشرة أس ستة بتلاقي نفس الـ factor
+
+354
+00:29:33,160 --> 00:29:38,670
+اللي موجود. المقام؟ ماشي. زميلكم بيقولوا أن هو مش
+
+355
+00:29:38,670 --> 00:29:44,330
+فاهم المقام. احنا بنقول خمسة وعشرين microliter. إيش
+
+356
+00:29:44,330 --> 00:29:51,110
+الـ micro؟ عشرة
+
+357
+00:29:51,110 --> 00:29:53,490
+أس سالب ستة. يعني عشرة أس سالب ستة. تاخد عشرة أس سالب
+
+358
+00:29:53,490 --> 00:29:57,670
+ثلاثة. هذه العشرة أس سالب ثلاثة، حطينا بدالها milli
+
+359
+00:29:57,670 --> 00:30:02,640
+عشان أنا بدي المقام يكون milliliter. ماشي. فالملي هذا
+
+360
+00:30:02,640 --> 00:30:05,300
+هي عبارة عن عشرة أس سالب ثلاثة. هذا يبقى سالب خمسة
+
+361
+00:30:05,300 --> 00:30:10,540
+وعشرين في عشرة أس سالب ثلاثة مللي لتر. أخدت بالك؟ هذا
+
+362
+00:30:10,540 --> 00:30:17,440
+هيّ. طيب نجي نتطلع على المطلوب الثاني. عايز يحسب
+
+363
+00:30:17,440 --> 00:30:21,760
+milligram
+
+364
+00:30:21,760 --> 00:30:23,280
+per deciliter
+
+365
+00:30:30,800 --> 00:30:35,600
+الحل مباشر كتير بالنسبة لنا. الحل مباشر كتير. أنا
+
+366
+00:30:35,600 --> 00:30:41,740
+بدي مثلاً ملي جرام على الديسيلتر. بقول: حلو. أنا عندي
+
+367
+00:30:41,740 --> 00:30:47,320
+ستة وعشرين وسبعة من عشرة ميكرو جرام، يعني في عشرة أس سالب ثلاثة
+
+368
+00:30:47,320 --> 00:30:56,840
+ملي جرام، مش هيك؟ على الـ dl لتر. الـ dl يعني عشر. الـ dl
+
+369
+00:30:56,840 --> 00:31:01,040
+يعني عشر واحد من عشرة الصنتي، يعني عشرة أس سالب
+
+370
+00:31:01,040 --> 00:31:06,620
+اثنين. الملي يعني عشرة أس سالب ثلاثة. فهي عندي الـ
+
+371
+00:31:06,620 --> 00:31:10,780
+milligram. هاي milligram، بده هو الـ dl. ليه ارتاحت؟
+
+372
+00:31:10,780 --> 00:31:15,960
+أنا عندي خمسة وعشرين في عشرة أس سالب ستة liter. كل
+
+373
+00:31:15,960 --> 00:31:19,800
+liter عشرة deciliter. على الـ liter، أو خليها الـ dl
+
+374
+00:31:19,800 --> 00:31:23,990
+صغير، عشان اللي فوق. هذه الـ liter مع الـ liter. فهذا هي هذا
+
+375
+00:31:23,990 --> 00:31:30,110
+بيعطيني ملي جرام على الـ dl لتر. يبقى اللي فوق سبعة
+
+376
+00:31:30,110 --> 00:31:35,510
+وستة وعشرين وسبعة من عشرة مايكرو جرام، يعني ستة
+
+377
+00:31:35,510 --> 00:31:38,950
+وعشرين وسبعة من عشرة، وعشرة سالب ثلاثة ملي جرام. فهي
+
+378
+00:31:38,950 --> 00:31:42,190
+اللي بديها فوق، ملي تحت، بديها dl لتر. خمسة وعشرين
+
+379
+00:31:42,190 --> 00:31:46,090
+مايكرو لتر. خمسة وعشرين في عشرة أس سالب ستة لتر. لكن كل
+
+380
+00:31:46,090 --> 00:31:52,000
+لتر عشرة dl لتر. فبيطلع عندي 107. طبعاً الـ milligram
+
+381
+00:31:52,000 --> 00:31:58,000
+على الـ deciliter هي الوحدة المعتادة للتعبير عن
+
+382
+00:31:58,000 --> 00:32:01,880
+تركيز السكر في الدم. milligram على الـ deciliter هي
+
+383
+00:32:01,880 --> 00:32:07,280
+الوحدة المعتادة للتعبير عن تركيز السكر في الدم. طيب
+
+384
+00:32:07,280 --> 00:32:07,820
+يا شباب
+
+385
+00:32:10,820 --> 00:32:16,220
+نتكلم برضه عن شيء مهم جداً. احنا تعلمنا في السابق
+
+386
+00:32:16,220 --> 00:32:21,060
+كيف ممكن نحول من molarity لـ normality، يعني بمعنى
+
+387
+00:32:21,060 --> 00:32:24,980
+آخر، من وحدة تركيز لوحدة تركيز أخرى
+
+445
+00:37:05,510 --> 00:37:09,150
+milligram ل millimole، كيف بدي أحول ل millimole؟
+
+446
+00:37:09,150 --> 00:37:12,870
+الكتلة المولية، ما فيش غير هيك، ماشي يا شباب، إذا
+
+447
+00:37:12,870 --> 00:37:17,520
+مجرد ماشي في شكل المسألة، الحل كتير بسيط، مرتبط بهذا
+
+448
+00:37:17,520 --> 00:37:28,500
+الكلام، شيء جوهر مهم جدا جدا، كيف ممكن أحضر محلول له
+
+449
+00:37:28,500 --> 00:37:33,900
+PPM معين؟ محلول تركيز و PPM معين، فنطلع على
+
+450
+00:37:33,900 --> 00:37:37,440
+هالمسألة، بيقول find the number of milligrams
+
+451
+00:37:37,440 --> 00:37:42,200
+sodium carbonate، يبقى بده كم milligram من؟ من
+
+452
+00:37:42,200 --> 00:37:46,880
+الـ sodium carbonate required to prepare 500 ml of
+
+453
+00:37:46,880 --> 00:37:54,450
+9.2 PPM sodium solution. عايز يحضر 500 مل من 9.2 PPM
+
+454
+00:37:54,450 --> 00:38:00,730
+صوديوم، مش صوديوم كربونيت، بده صوديوم، و
+
+455
+00:38:00,730 --> 00:38:04,270
+بقول لكم في هذا الجانب، يعني كتير من الناس اللي
+
+456
+00:38:04,270 --> 00:38:09,870
+بتعاملوا مع الـ ... الـ ... يعني التحاليل المختلفة
+
+457
+00:38:09,870 --> 00:38:15,490
+فيما يتعلق بالمعادن، كتير منهم بيشتري المحاليل
+
+458
+00:38:15,490 --> 00:38:20,110
+القياسية، شراء، يعني بده مثلا محلول صوديوم قياسي
+
+459
+00:38:20,110 --> 00:38:24,630
+بروحيش بحضره، هيك بروح بشتريه، هذا كلام مش كتير يعني
+
+460
+00:38:24,630 --> 00:38:27,930
+منطقي للناس اللي بتعرف في الكيميا، ليش؟ لأنه
+
+461
+00:38:27,930 --> 00:38:31,310
+المحلول اللي بروح تشتريه مش محلول نقي، يعني أنتَ
+
+462
+00:38:31,310 --> 00:38:34,270
+بتقدر تنقيه، ليش تشتريه وتحط عليه فلوس كتير، ما أنتَ
+
+463
+00:38:34,270 --> 00:38:39,350
+بتعرف تعمله، اتعلم كيف تحسب وزن الـ sodium
+
+464
+00:38:39,350 --> 00:38:47,630
+carbonate اللازمة لتحضير 500 مل من 9.2 PPM Sodium
+
+465
+00:38:47,630 --> 00:38:51,470
+تعرف، كده في الأول بدي أقول لك إيش منهجية التفكير في
+
+466
+00:38:51,470 --> 00:39:00,150
+الموضوع، بقول لك، ببساطة، 9.2 ppm sodium، إيش يعني؟ إيش
+
+467
+00:39:00,150 --> 00:39:05,770
+يعني؟ يعني 9.2 milligram sodium في الـ 1000 ml
+
+468
+00:39:05,770 --> 00:39:11,990
+مش هي، يعني ppm يعني 9.2 milligram sodium في إيه؟
+
+469
+00:39:11,990 --> 00:39:15,330
+في الـ 1000 ml، أنا في الأول ما بديش 1000 ml، بدي 500
+
+470
+00:39:15,330 --> 00:39:21,020
+نصهم، يعني قديش لازم آخذ وزن؟ نص التسعة و
+
+471
+00:39:21,020 --> 00:39:23,600
+الاثنين، يعني أربعة وستة من عشرة، المفهوم هذا أول
+
+472
+00:39:23,600 --> 00:39:27,960
+خطوة، بنقول milligram sodium، لسّه milligram sodium
+
+473
+00:39:27,960 --> 00:39:31,420
+nine point two milligram على الـ liter، في نص liter
+
+474
+00:39:31,420 --> 00:39:34,200
+يعني خمسمائة ml، بيطلع أربعة وستة من عشرة
+
+475
+00:39:34,200 --> 00:39:37,460
+milligram، إذا الـ sodium اللي أنا بدي إياها لخمسمائة
+
+476
+00:39:37,460 --> 00:39:42,150
+ml هو مجرد أربعة وستة من عشرة milligram sodium، ده
+
+477
+00:39:42,150 --> 00:39:48,250
+الموضوع، بقول أنا بالـ milligrams ما بفهمش، أنا اتعلمت
+
+478
+00:39:48,250 --> 00:39:52,450
+أحسب دائما الـ millimoles، يعني إيش الـ millimoles
+
+479
+00:39:52,450 --> 00:39:57,830
+sodium، بتقسمها على الـ atomic weight له، بيطلع اثنين
+
+480
+00:39:57,830 --> 00:40:04,910
+من عشرة، بيطلع أربعة وستة على ثلاثة وعشرين صحيح
+
+481
+00:40:04,910 --> 00:40:09,470
+بيطلع اثنين من عشرة، يبقى عدد ملي مولات الصوديوم قديش؟
+
+482
+00:40:09,470 --> 00:40:14,450
+اثنين من عشرة، لكن للأسف ما فيش عندي صوديوم أيونات
+
+483
+00:40:14,450 --> 00:40:17,010
+اللي أروح أوزنها، standard solution اللي أوزنه أنا
+
+484
+00:40:17,010 --> 00:40:21,470
+بدي أحضر من الصوديوم كربونيت، فبدي أحول من ملي مول
+
+485
+00:40:21,470 --> 00:40:25,190
+صوديوم لـ ملي مول صوديوم كربونيت، كيف بدي أحول؟ قال
+
+486
+00:40:25,190 --> 00:40:28,870
+والله الصوديوم كربونيت إيش بتعطي؟ اثنين ملي مول
+
+487
+00:40:28,870 --> 00:40:32,710
+صوديوم، لو قلنا عدد ملي مولات الصوديوم كربونيت قديش؟
+
+488
+00:40:32,710 --> 00:40:37,330
+اللي في المعادلة، عدد ملي مولات الصوديوم كربونيت قد إيش؟
+
+489
+00:40:37,330 --> 00:40:42,950
+إيش؟ واحد، عدد ملي مولات الصوديوم قد إيش؟ اثنين، إذا
+
+490
+00:40:42,950 --> 00:40:48,070
+عدد ملي مولات الصوديوم كربونيت نص عدد ملي مولات
+
+491
+00:40:48,070 --> 00:40:52,510
+الصوديوم، الواحد نص الاثنين، فمعنى الكلام، معنى الكلام
+
+492
+00:40:52,510 --> 00:40:56,070
+الملي مول صوديوم كربونيت بيساوي نص الملي مول صوديوم
+
+493
+00:40:56,070 --> 00:41:01,170
+أو بيساوي بالأخرى نص ضرب اثنين من عشرة، يعني واحد من
+
+494
+00:41:01,170 --> 00:41:07,470
+عشرة، إذا الآن طلعت ملي مولات الصوديوم كربونيت، مدام
+
+495
+00:41:07,470 --> 00:41:10,730
+عندي ملي مولات الصوديوم كربونيت، بسهولة بقدر أجيب
+
+496
+00:41:10,730 --> 00:41:13,990
+الملي جرام الصوديوم كربونيت، بس مجرد أن أضرب في الـ
+
+497
+00:41:13,990 --> 00:41:17,620
+formula weight، بتعطيني الـ milligrams، فلو ضربت في الـ
+
+498
+00:41:17,620 --> 00:41:21,460
+formula weight اللي هي 106، بيطلع عندي 10.6 من
+
+499
+00:41:21,460 --> 00:41:26,540
+10 milligram، بمعنى آخر، بمعنى آخر، لو أنا حبيت أحضر
+
+500
+00:41:26,540 --> 00:41:34,900
+500 ml من 9.2 ppm sodium، يجب أن  أضع 10.6 من
+
+501
+00:41:34,900 --> 00:41:40,700
+10 milligram sodium carbonate، وأذوبها في 500 ml، لما
+
+502
+00:41:40,700 --> 00:41:49,100
+تدوب بتعطيني 9.2 ppm sodium، كمان مرة، الحل بقول كتير
+
+503
+00:41:49,100 --> 00:41:53,700
+جدا بسيط، بجيب في البداية عدد ميلي جرامات الأنالايت،
+
+504
+00:41:53,700 --> 00:42:00,580
+عدد ميلي جرامات الأنالايت، كويس، حسب الحجم اللي بده
+
+505
+00:42:00,580 --> 00:42:04,180
+أحضره، حسب الحجم، ليش؟ عدد الميلي جرامات بقسمها على
+
+506
+00:42:04,180 --> 00:42:07,120
+الكتلة المولية، اللي هو أو الـ atomic weight، if كان
+
+507
+00:42:07,120 --> 00:42:12,370
+أيون، بيعطيني عدد الـ millimoles تبعته، الـ millimoles
+
+508
+00:42:12,370 --> 00:42:18,010
+تبعته، عادة ما بتكونش موجودة عندي بالصيغة المطلوبة
+
+509
+00:42:18,010 --> 00:42:21,190
+علشان أحضر منها الـ PPM، فبدي أعمل relation ما بينها
+
+510
+00:42:21,190 --> 00:42:25,610
+و بين الـ compound اللي موجودة فيه، فبشوف، بكتب زي
+
+511
+00:42:25,610 --> 00:42:28,590
+هيك، زي معادلة صغيرة، بقول والله قديش عدد
+
+512
+00:42:28,590 --> 00:42:31,790
+millimoles الـ compound بالنسبة لعدد millimoles الـ
+
+513
+00:42:31,790 --> 00:42:34,430
+analyte، الـ analyte صار معروف عندي عدد millimoles
+
+514
+00:42:34,430 --> 00:42:40,250
+بجيب عدد millimoles الـ compound، نص الـ millimoles
+
+515
+00:42:40,250 --> 00:42:44,810
+sodium، بعدين مدام جبت عدد ملي مولات الـ compound
+
+516
+00:42:44,810 --> 00:42:48,390
+مفهوم، كيف أحول من ملي مول لـ ملي جرام؟ بده أضرب في
+
+517
+00:42:48,390 --> 00:42:54,700
+الـ formula weight، بهذه الطريقة ممكن أن نحسب عدد ملي
+
+518
+00:42:54,700 --> 00:43:00,520
+جرامات الـ Sodium Carbonate اللي لازمة لتحضير 9.2
+
+519
+00:43:00,520 --> 00:43:06,760
+PPM Sodium، 500 مل، طبعا بإمكاني أحل المسألة بخطوة
+
+520
+00:43:06,760 --> 00:43:10,140
+واحدة، وإن كنت أنا يعني ما بديش إياك تشتغل هيك، لكن
+
+521
+00:43:10,140 --> 00:43:13,860
+نطلع بنقول أنا بدي كم ملي جرام، أو بدي أعرف عدد
+
+522
+00:43:13,860 --> 00:43:18,200
+ملي جرامات الـ Sodium Carbonate، فبقول 9.2 ميلي جرام
+
+523
+00:43:18,200 --> 00:43:23,520
+صوديوم على ألف مل، هذا عبارة عن 9.2 ppm صوديوم، هذا
+
+524
+00:43:23,520 --> 00:43:27,460
+مقطع، أنا بدي بس 500 مل، أضرب في 500 مل، بتروح
+
+525
+00:43:27,460 --> 00:43:31,980
+المل مع المل، بيبقى 9.2 ميلي جرام صوديوم، بقسمها
+
+526
+00:43:31,980 --> 00:43:37,340
+على 23، بتصير ميلي مول صوديوم، بقول كل ملي مول صوديوم
+
+527
+00:43:37,340 --> 00:43:41,000
+فيه اثنين ملي مول... كل ملي مول صوديوم كربونيت فيه
+
+528
+00:43:41,000 --> 00:43:45,240
+اثنين ملي مول صوديوم، صحيح، بعدين بقول كل مئة وستة
+
+529
+00:43:45,240 --> 00:43:48,020
+ملي جرام صوديوم كربونيت موجودة في one milli mole
+
+530
+00:43:48,020 --> 00:43:52,720
+صوديوم كربونيت، إذا النتيجة عشرة وستة من عشرة، نفس
+
+531
+00:43:52,720 --> 00:43:56,540
+الكلام، فسواء اشتغلنا خطوة واحدة أو بالخطوات، نفس
+
+532
+00:43:56,540 --> 00:44:00,520
+النتيجة، لكن أنا بفضل أنك تشتغل خطوة خطوة، بيكون
+
+533
+00:44:00,520 --> 00:44:01,200
+أفضل
+
+534
+00:44:05,370 --> 00:44:09,350
+عادي حط هنا على ألف مل، وحط هنا خمسمائة مل، هي هي
+
+535
+00:44:09,350 --> 00:44:14,190
+الشيء، يعني يعني ده برجع لك أنتَ، ماشي يا شباب؟ طيب
+
+536
+00:44:14,190 --> 00:44:21,050
+خلينا نوقف هنا، إذا كان في أي أسئلة ممكن نجاوب
+
+537
+00:44:21,050 --> 00:44:21,470
+عليها
diff --git a/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/WgyAhGE2NYo_postprocess.srt b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/WgyAhGE2NYo_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..1b08d3a1f640692f65ed5060bbc5370dc55e6089
--- /dev/null
+++ b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/WgyAhGE2NYo_postprocess.srt
@@ -0,0 +1,2328 @@
+1
+00:00:20,960 --> 00:00:24,660
+بسم الله الرحمن الرحيم الحصة الماضية شباب كنا بدنا
+
+2
+00:00:24,660 --> 00:00:28,020
+نتكلم عن ال buffer solutions اليوم ان شاء الله
+
+3
+00:00:28,020 --> 00:00:31,020
+بنكمل شوية في ال buffer solutions و بعدين بننتقل
+
+4
+00:00:31,020 --> 00:00:36,500
+لموضوع تاني هو ال polyprotic acid solutions و
+
+5
+00:00:36,500 --> 00:00:43,660
+تعيين ال PH لها فمر معنا الحصة الماضية بعض الأمثلة
+
+6
+00:00:43,660 --> 00:00:49,800
+فى أمثلة مباشرة كانتيعني باخد كمية من أو تركيز من
+
+7
+00:00:49,800 --> 00:00:54,480
+ال acid ال weak acid وتركيز من ال conjugate base
+
+8
+00:00:54,480 --> 00:01:00,840
+وهذا المحلول بقدر بسهولة أعينه ال pH مش مشكلة فيه
+
+9
+00:01:00,840 --> 00:01:07,120
+لكن في بعض المحلول كانتفيش عندى مثلا conjugate
+
+10
+00:01:07,120 --> 00:01:10,640
+base زى مثلا السؤال او المثال اللى أخدناه على ال
+
+11
+00:01:10,640 --> 00:01:14,080
+acetic acid عندى acetic acid نعم لكن فيش عندى
+
+12
+00:01:14,080 --> 00:01:18,560
+sodium acetate مثلا فكيف بدى احضر buffer من ال
+
+13
+00:01:18,560 --> 00:01:22,600
+acetic acid لوحده؟ بنقول ببساطة خالص بنضيف عليه
+
+14
+00:01:22,600 --> 00:01:27,040
+شوية sodium hydroxide بيتحول جزء من ال acetic acid
+
+15
+00:01:27,040 --> 00:01:30,540
+ل ال sodium acetate وبالدالى بيصير فيه عندى acetic
+
+16
+00:01:30,540 --> 00:01:34,260
+acid وacetate يعني اتكون عندى buffer
+
+17
+00:01:37,810 --> 00:01:42,270
+برضه شوفنا كيف نحسب ال buffer capacity وكيف ممكن
+
+18
+00:01:42,270 --> 00:01:48,050
+ال pH تتغير عند إضافة كمية من ال acid شوفنا مثال
+
+19
+00:01:48,050 --> 00:01:51,590
+عليه وبرضه انا بقترح عليك انك بدل ما تضيف point
+
+20
+00:01:51,590 --> 00:01:55,570
+one millimole من ال HCl على المثال اللى شوفناه اخر
+
+21
+00:01:55,570 --> 00:01:59,610
+مثال لأ ضيف عليه point one millimole Sodium
+
+22
+00:01:59,610 --> 00:02:04,420
+Hydroxide وشوف كيف ال pH بتتغيرفكويس أنك تعرف تحل
+
+23
+00:02:04,420 --> 00:02:10,120
+الأسئلة من هذا النوع اليوم راح نتطلع على مثالين
+
+24
+00:02:10,120 --> 00:02:15,580
+بسيطات كتير ومهمات في نفس الوجد فنتطلع على المثال
+
+25
+00:02:15,580 --> 00:02:20,600
+الأول مسألة مباشرة إلى حد كبير لكن تعتبر مسألة
+
+26
+00:02:20,600 --> 00:02:24,900
+عملية لأنه بنواجهها كتير في المختبر فبنقول
+
+27
+00:02:24,900 --> 00:02:31,910
+calculate the volume of 14.8 molarأمونيا ووضع
+
+28
+00:02:31,910 --> 00:02:38,010
+أمونيا ميكلورايد يجب أن تأخذ لتحضير 100 مل من بفر
+
+29
+00:02:38,010 --> 00:02:41,470
+بيه 10إذا كانت تركيز الحصول على الحصول على الحصول
+
+30
+00:02:41,470 --> 00:02:42,790
+على الحصول على الحصول على الحصول على الحصول على
+
+31
+00:02:42,790 --> 00:02:43,950
+الحصول على الحصول على الحصول على الحصول على الحصول
+
+32
+00:02:43,950 --> 00:02:45,230
+على الحصول على الحصول على الحصول على الحصول على
+
+33
+00:02:45,230 --> 00:02:47,630
+الحصول على الحصول على الحصول على الحصول على الحصول
+
+34
+00:02:47,630 --> 00:02:48,630
+على الحصول على الحصول على الحصول على الحصول على
+
+35
+00:02:48,630 --> 00:02:49,610
+الحصول على الحصول على الحصول على الحصول على الحصول
+
+36
+00:02:49,610 --> 00:02:49,730
+على الحصول على الحصول على الحصول على الحصول على
+
+37
+00:02:49,730 --> 00:02:50,770
+الحصول على الحصول على الحصول على الحصول على الحصول
+
+38
+00:02:50,770 --> 00:02:53,370
+على الحصول على الحصول على الحصول على الحصول على
+
+39
+00:02:53,370 --> 00:02:54,070
+الحصول على الحصول على الحصول على الحصول على الحصول
+
+40
+00:02:54,070 --> 00:02:59,030
+على الحصول على الحصول على الحصول على الحصول على
+
+41
+00:02:59,030 --> 00:03:03,350
+الحصول على الحصول علىهذا الكلام أنا بواجهته في
+
+42
+00:03:03,350 --> 00:03:07,870
+المختبر لأنه زي ما شفنا كيف نحسب مثلا الـMolarity
+
+43
+00:03:07,870 --> 00:03:14,730
+لـConcentrated H2SO4 أو HCl أو Acetic Acid أو
+
+44
+00:03:14,730 --> 00:03:18,390
+Nitric Acid، كمان الأمونيا ابتيجيش معلومة
+
+45
+00:03:18,390 --> 00:03:24,360
+الـMolarityبتيجي عادة امونيا percentage و density
+
+46
+00:03:24,360 --> 00:03:28,300
+و انا لازم بنفس الطريقة اعين ال ايه ال molarity
+
+47
+00:03:28,300 --> 00:03:32,060
+لها لكن هو هنعطينا ال molarity فانا بدي اخد وزن
+
+48
+00:03:32,060 --> 00:03:36,800
+معين من ال امونيا ميكلورايد و اضيف عليها قليل من
+
+49
+00:03:36,800 --> 00:03:42,680
+ال امونيا علشان احضر 100 مل ال pH ل ال buffer هذا
+
+50
+00:03:42,680 --> 00:03:49,510
+10 و تركيز ال salt 0.2 مولار ايش هو ال salt؟ال
+
+51
+00:03:49,510 --> 00:03:53,910
+salt دائما هو ال conjugate ال salt دائما هو ال
+
+52
+00:03:53,910 --> 00:03:57,830
+conjugate يعني مثلا هان عين دي ال ammonia طبعا هي
+
+53
+00:03:57,830 --> 00:04:02,290
+ال base ال conjugate تبعها ال conjugate acid ايش
+
+54
+00:04:02,290 --> 00:04:07,170
+بده يكون ال ammonium هو ال salt يبقى تركيز ال
+
+55
+00:04:07,170 --> 00:04:12,550
+ammonium اتنين من عشرة طيب لو جيت طبعك على المسألة
+
+56
+00:04:12,550 --> 00:04:16,630
+بقول من وين بده ابدأ أحل المسألة؟ من وين بده أبدأ
+
+57
+00:04:16,630 --> 00:04:23,300
+أحل المسألة؟بقول انا شفنا سابقا و هنشوف في باقية
+
+58
+00:04:23,300 --> 00:04:29,280
+ال course انه حل اي مسألة بيعتمد على نوع المسألة
+
+59
+00:04:29,280 --> 00:04:32,360
+اذا كانها مثلا Stoichiometric calculation يعني
+
+60
+00:04:32,360 --> 00:04:38,760
+بمعنى اخر quantitative calculation معناته بدي
+
+61
+00:04:38,760 --> 00:04:41,560
+استخدم ال millimoles طب لو كانت مسألة فيها
+
+62
+00:04:41,560 --> 00:04:45,610
+equilibriumمافيش إلا إن أطلع على ال equilibrium
+
+63
+00:04:45,610 --> 00:04:51,310
+constant مباشرة بدي أستخدم يعني توجهي في الحل بدي
+
+64
+00:04:51,310 --> 00:04:55,090
+يكون نحو إيه ال equilibrium constant ومنه بدي
+
+65
+00:04:55,090 --> 00:04:59,170
+أنطلق للحل فعندي هان أمونيا أمونيام ممكن أقول
+
+66
+00:04:59,170 --> 00:05:03,310
+والله المعادلة أمونيا في الميه بتعطيني أمونيام
+
+67
+00:05:03,310 --> 00:05:07,290
+وهيدروكسيد إذا ال Kb أمونيام في الهيدروكسيد على ال
+
+68
+00:05:07,290 --> 00:05:12,920
+NH اثري انا بقولبدي اشوف ايش في عندي معقب و ايش
+
+69
+00:05:12,920 --> 00:05:16,960
+مجهول عادة لازم الاقي مجهول واحد بس و هو اللي بدي
+
+70
+00:05:16,960 --> 00:05:22,460
+يوجهني للحل عادة بدي الاقي مجهول واحد فقط و هو
+
+71
+00:05:22,460 --> 00:05:26,890
+اللي بدي يوجهني للحل زي ما كنت مجهول من لمولبتساوي
+
+72
+00:05:26,890 --> 00:05:30,150
+كذا millimole يعني milligram مثلا على الفورمولات
+
+73
+00:05:30,150 --> 00:05:32,790
+بتساوي مدارة ال volume لازم يكون في عنده مجهول
+
+74
+00:05:32,790 --> 00:05:37,370
+واحد بس هو اللي بده يقودني لاستكمال الحل وهي نفس
+
+75
+00:05:37,370 --> 00:05:41,110
+الكلام هان بقول هي ال equilibrium constant بده
+
+76
+00:05:41,110 --> 00:05:43,530
+اشوف ايش الموجود و ايش المجهول لازم الاجي مجهول
+
+77
+00:05:43,530 --> 00:05:48,370
+واحد فقطبنفعش اكتر من المجهول فبقول ال Kb اه معايا
+
+78
+00:05:48,370 --> 00:05:52,930
+ال Kb واحد و خمسة و سبعين في عشرة أس سالب خمسة ال
+
+79
+00:05:52,930 --> 00:05:56,330
+ammonium اللي هو ال salt معايا جل اتنين من عشرة ال
+
+80
+00:05:56,330 --> 00:06:01,930
+hydroxide معايا جل ال pH عشرةالأمونيا معايا اربعة
+
+81
+00:06:01,930 --> 00:06:05,070
+عشر تمانية؟ لأ، هذا المحلول المركز، أنا بتطلع على
+
+82
+00:06:05,070 --> 00:06:09,590
+المحليل at equilibrium، ال meat meal جداش ال pH
+
+83
+00:06:09,590 --> 00:06:13,530
+تبعتها، جداش تركيز ال salt فيها، جداش تركيز
+
+84
+00:06:13,530 --> 00:06:19,520
+الأمونيا فيهاكويس فالأمونيا مش معايا اذا بعوض انا
+
+85
+00:06:19,520 --> 00:06:24,700
+بقول والله ال .. في البداية ال POH بتساوي 14 نقص
+
+86
+00:06:24,700 --> 00:06:30,100
+ال pH يعني ال POH 4 يعني ال hydroxide بتساوي 10 أس
+
+87
+00:06:30,100 --> 00:06:35,320
+سالب 4 هذه ال hydroxide باجي انا بعوض الآن عن ال
+
+88
+00:06:35,320 --> 00:06:39,560
+Kb عن الأمونيا عن ال hydroxide و بجيب الأمونيا
+
+89
+00:06:39,560 --> 00:06:44,900
+الأمونيا بتطلع 1 و 14 من 100 اذا جيب التركيز
+
+90
+00:06:45,170 --> 00:06:50,750
+الأمونيا طيب يا شباب أنا عندي التركيز ال .. تركيز
+
+91
+00:06:50,750 --> 00:06:56,370
+الأمونيا الأصلي المركز 14.8 أكمل بدي أخد منه عشان
+
+92
+00:06:56,370 --> 00:07:00,830
+أخبر meat meal اللي هو ال buffer تركيز الأمونيا
+
+93
+00:07:00,830 --> 00:07:08,000
+فيه 1.14 يعني M I V I بتسوي M F V Fقبل التخفيف و
+
+94
+00:07:08,000 --> 00:07:11,720
+بعد التخفيف قبل التخفيف كانت 14.8 أنا حضرت 100 مل
+
+95
+00:07:11,720 --> 00:07:15,860
+تركيز الأمونيا لازم تكون فيه 1.14 اذا بقول والله
+
+96
+00:07:15,860 --> 00:07:21,600
+MIVI بتساوي MFVF فبنقول 14.8 في ال volume بالمل
+
+97
+00:07:21,600 --> 00:07:28,740
+بتساوي 1.14100 يعني ال volume بالمل بتطلع 7.10%7 و
+
+98
+00:07:28,740 --> 00:07:33,820
+7 من 10 مل فبقول ايه بقول اذا انا لازم اخد ال 7 و
+
+99
+00:07:33,820 --> 00:07:36,780
+7 من 10 مل هذا و احطها على كمية من ال ammonia
+
+100
+00:07:36,780 --> 00:07:40,980
+mycloride علشان و اخفف لمية مل عشان احصل على ال
+
+101
+00:07:40,980 --> 00:07:44,240
+buffer فابجداش كمية ال ammonia mycloride بقول
+
+102
+00:07:44,240 --> 00:07:48,380
+والله تركيز ال ammonia mycloride معايا 2 من 10 و
+
+103
+00:07:48,380 --> 00:07:52,440
+ال volume معايا ما هو بفهم يا milli mole يا اما
+
+104
+00:07:54,070 --> 00:08:00,430
+Equilibrium فش غير هيك فعندي انا هان ال ال
+
+105
+00:08:00,430 --> 00:08:03,290
+molarity عندي و ال volume عندي و اجيب ال
+
+106
+00:08:03,290 --> 00:08:05,310
+millimoles كيه بده احول ال millimoles ل
+
+107
+00:08:05,310 --> 00:08:09,680
+milligrams؟بدي اضرب في ال formula ويبقى اذا بضرب
+
+108
+00:08:09,680 --> 00:08:13,600
+في ال formula ويعطيني الف وسبعين milligram معنى
+
+109
+00:08:13,600 --> 00:08:16,520
+الكلام هذا انه لازم اخد الف وسبعين milligram من ال
+
+110
+00:08:16,520 --> 00:08:19,860
+ammonia مكلورايد احط عليهم سبعة وسبعة من عشرة mil
+
+111
+00:08:19,860 --> 00:08:23,700
+من ال ammonia المركزة اربعتاش و تمانية من عشرة
+
+112
+00:08:23,700 --> 00:08:28,480
+molar و بعدين اخفف لمية mil بحصل على buffer
+
+113
+00:08:28,480 --> 00:08:33,620
+solution ال pH له عشرة و تركيز السلط في اتنين من
+
+114
+00:08:33,620 --> 00:08:39,410
+عشرة molarماشي يا شباب لو لاحظت معايا مفتاح الحل
+
+115
+00:08:39,410 --> 00:08:44,110
+كان عندي ايه؟ مفتاح الحل هو عبارة عن ال
+
+116
+00:08:44,110 --> 00:08:47,970
+equilibrium constant أثناء الحل مافيش قدامي إلا
+
+117
+00:08:47,970 --> 00:08:51,350
+أني أطلع على ال millimoles millimoles إذا كان في
+
+118
+00:08:51,350 --> 00:08:53,850
+حاجة stoichiometric بدي أحسبها بطلع على ال
+
+119
+00:08:53,850 --> 00:08:57,290
+millimoles يبقى مافيش عندي إلا millimoles أو
+
+120
+00:08:57,290 --> 00:09:01,870
+equilibrium constant نطلع على المثال التالي أيضا
+
+121
+00:09:03,590 --> 00:09:07,990
+هذا مثالي كويس كتير لأنه يعني بيستخدم فقط الأمونيا
+
+122
+00:09:07,990 --> 00:09:10,870
+ميكلورايد عشان يحضر buffer طبعا الأمونيا ميكلورايد
+
+123
+00:09:10,870 --> 00:09:15,730
+بيعطيناش buffer لأنه conjugate acid فبده base بده
+
+124
+00:09:15,730 --> 00:09:18,870
+أمونيا لكن أنا ممكن أضيف عليه شوية sodium
+
+125
+00:09:18,870 --> 00:09:23,570
+hydroxide فال sodium hydroxide بيحول جزء من
+
+126
+00:09:23,570 --> 00:09:28,390
+الأمونيا ميكلورايد لإيه؟ للأمونيا أي الأمونيا مع
+
+127
+00:09:28,390 --> 00:09:33,440
+ال hydroxide تعطيني أمونياكويس فإذا كانت ال
+
+128
+00:09:33,440 --> 00:09:37,640
+millimoles لل أمونيام X حطيت عليها Y millimole
+
+129
+00:09:37,640 --> 00:09:44,140
+hydroxide فهتعطيني Y millimole من الأمونيا فجزء من
+
+130
+00:09:44,140 --> 00:09:50,740
+الأمونيام بتحول للأمونيا بمعنى آخر الأمونيام الكلي
+
+131
+00:09:52,430 --> 00:09:56,710
+اللي عندى الامونيام الكلي هو عبارة عن الامونيام
+
+132
+00:09:56,710 --> 00:10:00,170
+اللى بايل زى ما هو ماتحولش زائد الامونيام اللى
+
+133
+00:10:00,170 --> 00:10:02,810
+اتحول للامونيا اللى بيساوى الملي مول الامونيا
+
+134
+00:10:02,810 --> 00:10:07,190
+فالملي مول الكلي بيساوى الملي مول من الامونيا زائد
+
+135
+00:10:07,190 --> 00:10:13,690
+الملي مول من الامونيا الناتجة على أي حال كمان مرة
+
+136
+00:10:14,840 --> 00:10:19,120
+خلّينا نتطلع على المسألة بداية و نشوف كيف بدنا
+
+137
+00:10:19,120 --> 00:10:22,920
+نيجي للحل بقول how many grams ammonia mycloride
+
+138
+00:10:22,920 --> 00:10:29,400
+and how many ml of 3 molar sodium hydroxide،
+
+139
+00:10:29,400 --> 00:10:32,800
+Sodium hydroxide ضروري عشان يحول جزء من الأمونيام
+
+140
+00:10:32,800 --> 00:10:37,520
+للأمونيا وإلا ماعندي buffershould be added to
+
+141
+00:10:37,520 --> 00:10:41,460
+200ml water and diluted to 500ml يعني هذه جملة
+
+142
+00:10:41,460 --> 00:10:45,240
+اعتراضية يعني جزده ان الحجم النهائي 500ml لما
+
+143
+00:10:45,240 --> 00:10:48,560
+نقولك والله diluted ل 100 واتخففت ل 500 او diluted
+
+144
+00:10:48,560 --> 00:10:51,620
+ل 300 واتخففت ل 500 نفس الكلية يعني ال final
+
+145
+00:10:51,620 --> 00:10:56,600
+volume ماهي اللي جديش 500mlto prepare a buffer at
+
+146
+00:10:56,600 --> 00:11:01,260
+pH 9.5 and a salt concentration of 0.1 molar يبقى
+
+147
+00:11:01,260 --> 00:11:06,640
+ال pH 9.5، ال salt concentration 0.1 molar، إيش هو
+
+148
+00:11:06,640 --> 00:11:11,180
+ال salt؟ ال ammonium طبعا، لو عندي acetic acid،
+
+149
+00:11:11,180 --> 00:11:17,140
+إيش هو ال salt؟ ال acetate دائما ال conjugate هو
+
+150
+00:11:17,140 --> 00:11:23,940
+ال إيه؟ ال saltطيب كمان مرة كيف بدي أحل مسألة زي
+
+151
+00:11:23,940 --> 00:11:29,440
+هذه؟ يعني إيش بدي أعمل؟ بقول يا شباب مدام مسألة
+
+152
+00:11:29,440 --> 00:11:32,460
+equilibrium خينا نعدي على equilibrium على طول و
+
+153
+00:11:32,460 --> 00:11:37,400
+نشوفأيش متطلبات ال equilibrium هذا؟ أيش الحاجات
+
+154
+00:11:37,400 --> 00:11:42,140
+اللي بتستلزم عشان أحل ال equilibrium constant؟ أيش
+
+155
+00:11:42,140 --> 00:11:45,920
+متطلباته؟ فبقول والله أنا عندي أمونيا أمونيام،
+
+156
+00:11:45,920 --> 00:11:48,880
+يعني بقول أمونيا في الميه، فاعطينا أمونيام و
+
+157
+00:11:48,880 --> 00:11:52,040
+hydroxide، يبدأ ال Kb أمونيام في ال hydroxide على
+
+158
+00:11:52,040 --> 00:11:54,560
+الأمونيا، فهذا كلام مفهوم من المعادلة على طول، من
+
+159
+00:11:54,560 --> 00:11:58,190
+ال equilibriumماشي بقول كي بي معايا ولا مش معايا؟
+
+160
+00:11:58,190 --> 00:12:02,290
+معايا ال ammonium جل السولت واحد من عشرة، إذا
+
+161
+00:12:02,290 --> 00:12:07,790
+معايا ال hydroxide جل ال pH تسعة و نص، إذا ال POH
+
+162
+00:12:07,790 --> 00:12:11,850
+أربعة و نص، إذا ال H plus عشرة أسالب أربعة و نص
+
+163
+00:12:11,850 --> 00:12:17,050
+عشرة أسالب أربعة و نص، يبجى ضايل فقط الأمونيا هي
+
+164
+00:12:17,050 --> 00:12:20,390
+اللي مجهولة، جداش تركيز الأمونيا اللي في المحلول،
+
+165
+00:12:20,390 --> 00:12:25,970
+هذا مجهوليبقى عمال ال equilibrium constant بيوجهني
+
+166
+00:12:25,970 --> 00:12:30,570
+وين اروح علشان احل المسألة ويقول اوجد تركيز ال
+
+167
+00:12:30,570 --> 00:12:33,270
+ammonia اللي في المحلول اذا اوجد تركيز ال ammonia
+
+168
+00:12:33,270 --> 00:12:37,890
+و تركيز ال ammonium خلص ال buffer صار معروف اذا
+
+169
+00:12:37,890 --> 00:12:41,110
+صار عندي تركيز ال ammonia و ال ammonium ال buffer
+
+170
+00:12:41,110 --> 00:12:45,070
+خلص خلصت المسألة صارت كلها معروفة الشغل اللي باقي
+
+171
+00:12:45,070 --> 00:12:51,860
+هو عبارة عن كاشطبات بسيطة كتير فباجي بعوضالـ Kb
+
+172
+00:12:51,860 --> 00:12:57,720
+تركيز السلط الهيدروكسايد العشرة أقل سالب أربعة و
+
+173
+00:12:57,720 --> 00:13:00,900
+نص يعني تلاتة و اتنين فعشرة أقل سالب خمسة على
+
+174
+00:13:00,900 --> 00:13:05,560
+الأمونيا الأمونيا تطلع تمانتعش من مية تمانتعش من
+
+175
+00:13:05,560 --> 00:13:10,340
+مية يبقى الأن أنا في عندي يا شباب خمس ميت ميل
+
+176
+00:13:10,340 --> 00:13:18,440
+موجود فيها polarity لا الأمونيا تمانتعش من ميةو
+
+177
+00:13:18,440 --> 00:13:24,120
+موجود فيها polarity للأمونيام 1 من 10 طيب مدام أنا
+
+178
+00:13:24,120 --> 00:13:27,120
+عارف ال polarity و ال volume بقدر أجيب ال
+
+179
+00:13:27,120 --> 00:13:29,880
+millimole للأمونيام و بقدر أجيب ال millimole
+
+180
+00:13:29,880 --> 00:13:34,980
+للأمونيام مجموعة ال two millimoles هو ال millimole
+
+181
+00:13:34,980 --> 00:13:39,280
+للأمونيام الاصليلأن الامونيا مكلورايد الأصلي حطيت
+
+182
+00:13:39,280 --> 00:13:43,120
+عليه صدم هيدروكسايد فاتجزأ جزء منه ضال زي ما هو
+
+183
+00:13:43,120 --> 00:13:48,400
+أمونيام وجزء اتحول لإيه؟ لأمونيا فال millimoles من
+
+184
+00:13:48,400 --> 00:13:52,140
+الأمونيا مكلورايد الكل بتساوي ال millimoles من
+
+185
+00:13:52,140 --> 00:13:55,600
+الأمونيام اللي ضايلة موجودة زائد ال millimoles من
+
+186
+00:13:55,600 --> 00:14:02,310
+الأمونيا اللي اتكونتطيب، لكن قبل ما أجيب الـ
+
+187
+00:14:02,310 --> 00:14:05,510
+Millimoles الكلية، إيه لخاطر أنا أقولكم الـ
+
+188
+00:14:05,510 --> 00:14:07,890
+Millimoles الأمونيا، الـMolarity في الـ Volume، 90
+
+189
+00:14:07,890 --> 00:14:11,190
+Millimoles؟ طب عارفين إنتوا إيش الـMolarity أو الـ
+
+190
+00:14:11,190 --> 00:14:16,160
+Millimoles للأمونيا بيساوي، لو رجعنا خطوةالملي مول
+
+191
+00:14:16,160 --> 00:14:20,080
+الأمونيا بدي ساوي الملي مول الهيدروكسيد لأنه كل ما
+
+192
+00:14:20,080 --> 00:14:22,700
+حطيت واحد ملي مول الهيدروكسيد باعطيني واحد ملي مول
+
+193
+00:14:22,700 --> 00:14:27,460
+الأمونيا اذا الملي مول الهيدروكسيد هي عبارة عن
+
+194
+00:14:27,460 --> 00:14:30,720
+تسعين الملي مول الهيدروكسيد عبارة عن تسعين طب
+
+195
+00:14:30,720 --> 00:14:33,460
+الملي مول الهيدروكسيد عبارة عن ايه ملارة
+
+196
+00:14:33,460 --> 00:14:37,940
+للهيدروكسيد تلاتة في ال volume بالمل بتساوي تسعين
+
+197
+00:14:37,940 --> 00:14:41,400
+يعني ال volume بالمل بيساوي تسعين على تلاتة يعني
+
+198
+00:14:41,400 --> 00:14:47,120
+تلاتين مل يبقى كمية او حجمالسوديوم هيدروكسيد
+
+199
+00:14:47,120 --> 00:14:51,640
+المضاف هو عبارة عن تلاتين مل يبقى لازم انا اضيف
+
+200
+00:14:51,640 --> 00:14:56,360
+على الامونيا ميكلورايد الكل تلاتين مل من السوديوم
+
+201
+00:14:56,360 --> 00:15:00,540
+هيدروكسيد اللي تركيزه تلاتة مولار عندها بحصل على
+
+202
+00:15:00,540 --> 00:15:05,260
+تسعين ملي مول من ايه؟ من الامونيا وبيكون تركيز
+
+203
+00:15:05,260 --> 00:15:05,960
+الامونيا
+
+204
+00:15:10,970 --> 00:15:16,890
+تركيز الأمونيام يعمر عن تركيز الأمونيام في الحجم
+
+205
+00:15:16,890 --> 00:15:17,730
+550
+
+206
+00:15:24,090 --> 00:15:26,350
+الـ Total Millimole من الـ Salt اللي هو الأمونيا
+
+207
+00:15:26,350 --> 00:15:29,230
+ميكلورايد يساوي الملي مول أمونيا زائد الملي مول
+
+208
+00:15:29,230 --> 00:15:34,110
+أمونيا تسعين زائد خمسين مية و أربعين ملي مول الأن
+
+209
+00:15:34,110 --> 00:15:39,070
+بدي أجيب أنا أكم إجرام أمونيا ميكلورايد لازم
+
+210
+00:15:39,070 --> 00:15:42,350
+أستخدم بدي أضرب فيه الفورمولويت
+
+211
+00:15:54,080 --> 00:16:00,340
+يعني ممكن تتصرف في المسألة بالظبط في عندى ممكن
+
+212
+00:16:00,340 --> 00:16:06,680
+تقول how many mill ammonia how many mill ammonia
+
+213
+00:16:06,680 --> 00:16:13,540
+مثلا تركيزها 14.8 مولار and how many mill 3 مولار
+
+214
+00:16:13,540 --> 00:16:18,890
+مثلا hclيبقى ال ammonia بتحط عليها HCl ليه؟ عشان
+
+215
+00:16:18,890 --> 00:16:22,190
+يتكون عنده شوية ammonium عشان هي ammonia و
+
+216
+00:16:22,190 --> 00:16:26,610
+ammonium نفس الكلام حاول تغير فيها حاول تغير في
+
+217
+00:16:26,610 --> 00:16:31,410
+المسألة و تحصل .. استخدم نفس ال .. نفس ال .. نفس
+
+218
+00:16:31,410 --> 00:16:36,130
+البيانات الموجودة لكن جول هاومانيميل من ال ammonia
+
+219
+00:16:36,130 --> 00:16:41,210
+اللي تركيزها 14.8 مثلا و هاومانيميل من ال HCl اللي
+
+220
+00:16:41,210 --> 00:16:46,460
+تركيزه مثلا 3 مولارماشي وشوف ايش النتائج اللي تطلع
+
+221
+00:16:46,460 --> 00:16:49,860
+معاك حلوة كتير المسألة هي دي ممكن انك تستفيد منها
+
+222
+00:16:49,860 --> 00:16:59,050
+خالصالان يا شباب بدنا ننتقل لموضوع يعني بيستكمل
+
+223
+00:16:59,050 --> 00:17:02,810
+الجزء اللى كنا بدأناه سابقا احنا فى هذا ال chapter
+
+224
+00:17:02,810 --> 00:17:07,630
+بدأنا نتعرف على كيفية حساب ال page لأنواع مختلفة
+
+225
+00:17:07,630 --> 00:17:11,870
+من المحاليل فاتكلمنا عن ال strong acids و ال
+
+226
+00:17:11,870 --> 00:17:16,650
+strong bases و ال salts تبعتها و بعدين اتكلمنا عن
+
+227
+00:17:17,590 --> 00:17:21,770
+الـ monoprotic acids و الـ monobasic bases و أيضًا
+
+228
+00:17:21,770 --> 00:17:25,530
+الـ salts بتاعتها و بعدين قلنا طيب ال mixture من
+
+229
+00:17:25,530 --> 00:17:27,810
+ال acid و ال conjugate base أو ال base و ال
+
+230
+00:17:27,810 --> 00:17:30,850
+conjugate acid بتعطينا buffer solution فاتكلمنا عن
+
+231
+00:17:30,850 --> 00:17:35,200
+ال buffer solutions اللي بتتكون منالـ weak acids و
+
+232
+00:17:35,200 --> 00:17:38,500
+ال conjugate bases تبعتها أو ال weak bases و ال
+
+233
+00:17:38,500 --> 00:17:41,840
+conjugate acids تبعتها لكن كنا بنستخدم أو بنخل
+
+234
+00:17:41,840 --> 00:17:45,480
+مسائل على ال monoprotic acids و ال salts تبعتها و
+
+235
+00:17:45,480 --> 00:17:48,060
+ال monobasic bases و ال salts أو ال conjugate
+
+236
+00:17:48,060 --> 00:17:52,580
+acids تبعتها فأخذنا برضه هذا الموضوع، الآن بدنا
+
+237
+00:17:52,580 --> 00:18:00,220
+ننتقل لكيفية حساب ال pH ل ال polyprotic acids إيش
+
+238
+00:18:00,220 --> 00:18:04,590
+هي ال polyprotic acids؟هي ال acids اللي بتحتوي على
+
+239
+00:18:04,590 --> 00:18:09,070
+أكتر من ال proton يعني التفكك تبعها أكتر من تفكك
+
+240
+00:18:09,070 --> 00:18:16,590
+بالظبط كل ال polyprotic acids بعيفة ما عدا ال
+
+241
+00:18:16,590 --> 00:18:20,850
+sulfuric acid التفكك الأول اللي قوي زي ما شفنا في
+
+242
+00:18:20,850 --> 00:18:24,450
+المحاضرات الماضية يبقى لما أتكلم عن ال polyprotic
+
+243
+00:18:24,450 --> 00:18:32,330
+acids بتكلم عن تفكك متعددوبتكلم عن أحماض ضعيفة
+
+244
+00:18:32,330 --> 00:18:37,890
+فكلها أحماض إيه ضعيفة ويلها طبعا تفكك متعدد طيب
+
+245
+00:18:37,890 --> 00:18:42,210
+الأحماض الضعيفة هذه مادام إلها تفكك متعدد يبقى
+
+246
+00:18:42,210 --> 00:18:49,710
+مشكلة الحساب ال PH هتكون معقدة ليه؟ لأن في عندي
+
+247
+00:18:49,710 --> 00:18:54,950
+أكتر من مصدر ل ال H plus فمثلا لو طلعنا على ال
+
+248
+00:18:54,950 --> 00:18:59,830
+phosphoric acidبقول والله الفوسفوريك أسد بتفكك و
+
+249
+00:18:59,830 --> 00:19:04,750
+بعطيني H بلس و H2PO4 سالب هذا K A1 بقوله التفكك
+
+250
+00:19:04,750 --> 00:19:10,290
+الأول او first acid dissociation constant وكمان ال
+
+251
+00:19:10,290 --> 00:19:15,350
+H2PO4 سالب بتفكر بتعطي H بلس و HPO4 اتنين سالب
+
+252
+00:19:15,350 --> 00:19:19,850
+وهذا التفكك التاني second acid dissociation
+
+253
+00:19:19,850 --> 00:19:25,900
+constantو أيضًا ال HPO4 2 سالب تتفكر تعطي H بلس
+
+254
+00:19:25,900 --> 00:19:33,440
+زائد PO4 تلاتة سالب وهان أيضًا في عندى third acid
+
+255
+00:19:33,440 --> 00:19:38,420
+dissociation constant معنى الكلام ال H بلس للمحلول
+
+256
+00:19:38,420 --> 00:19:42,460
+بتساوي ال H بلس اللى جاى من التفكك الأول زاد ال H
+
+257
+00:19:42,460 --> 00:19:45,440
+بلس اللى جاى من التفكك التانى زاد ال H بلس اللى
+
+258
+00:19:45,440 --> 00:19:49,160
+جاى من التفكك التالتوبنفترض إنه طبعا تفكك الميه لا
+
+259
+00:19:49,160 --> 00:19:53,080
+يكاد يذكر لإن هو محلول الاسد و ال H plus اللي جاي
+
+260
+00:19:53,080 --> 00:19:55,960
+من الميه هو عبارة عن ال hydroxide و لا يمكن يكون
+
+261
+00:19:55,960 --> 00:20:00,980
+في عندي hydroxide كتير في محلول acidic فبنعتبر ان
+
+262
+00:20:00,980 --> 00:20:04,260
+تفكك الميه لا يكاد يذكر و ال H plus اللي جاي منها
+
+263
+00:20:04,260 --> 00:20:08,780
+مهمل لكن تعالوا نقلع على ال H plus لازم أحسب ال H
+
+264
+00:20:08,780 --> 00:20:12,040
+plus اللي جاى من الأولى من التفكك الأول و التاني و
+
+265
+00:20:12,040 --> 00:20:16,460
+التالت علشان أقدر أجيب ال H plus ده المحلولإلا إذا
+
+266
+00:20:16,460 --> 00:20:21,740
+اعتمدنا طريقة تبسيط للمسألة طريقة التبسيط كتير
+
+267
+00:20:21,740 --> 00:20:27,940
+كتير يعني معقولة إيش هي قال تعالوا نتطلع على ال
+
+268
+00:20:27,940 --> 00:20:30,920
+equilibrium constants هذي بنلاحظ إن الأول دائما
+
+269
+00:20:30,920 --> 00:20:36,280
+أكبر من التاني والتاني أكبر من التالتيعني دائما
+
+270
+00:20:36,280 --> 00:20:40,960
+التفكك الأول كبير و اللي بعده ايش ماله اقل هذا كلب
+
+271
+00:20:40,960 --> 00:20:44,560
+ممكن احنا نتخيله بأنه اه والله هذه التفاككات كلها
+
+272
+00:20:44,560 --> 00:20:48,520
+موجودة لكن بمجرد ما يحصل التفاكك الأول ايش بيحصل
+
+273
+00:20:48,520 --> 00:20:52,320
+للتفاككات اللي بعده بترجع لورا لأن هي برضه نطلع H
+
+274
+00:20:52,320 --> 00:20:56,690
+plus فالتفاكك الأول بيعطينا H plus كتيرالتاني راح
+
+275
+00:20:56,690 --> 00:21:00,310
+يجل، التالت راح يجل خالص، معايا؟ ممكن تطلع عليه
+
+276
+00:21:00,310 --> 00:21:04,810
+بهذا الشكل، لكن لو إجينا احنا جسمنا k a1 على k a2
+
+277
+00:21:04,810 --> 00:21:10,390
+ال k a1 عشر أقص ثالث اتنين مثلا، و ال k a2 عشر أقص
+
+278
+00:21:10,390 --> 00:21:15,590
+ثالث تمانية، إذا k a1 على k a2 بتساوي عشر أقص ستة،
+
+279
+00:21:15,590 --> 00:21:19,470
+مليون، إيش معنى هذا الكلام؟ و هذا كلام rough،
+
+280
+00:21:19,470 --> 00:21:24,230
+هنشوف ليش في المستقبلبنقول ليش يعني مليون ايش معنى
+
+281
+00:21:24,230 --> 00:21:27,150
+هذه الكلام معناته كل ما احصل على مليون بروتون من
+
+282
+00:21:27,150 --> 00:21:31,720
+التفكك الأولبحصل على بروتن واحد بس من التفكك
+
+283
+00:21:31,720 --> 00:21:35,280
+التاني لأن الأول أكبر من التاني مليون مرة فكل ما
+
+284
+00:21:35,280 --> 00:21:40,140
+أحصل على مليون بروتن من التفكك الأول بحصل على
+
+285
+00:21:40,140 --> 00:21:44,620
+تقريون بروتن من التفكك التاني تمام يا شباب فلما
+
+286
+00:21:44,620 --> 00:21:50,100
+أقول واحد مقابل مليون مش كتير يعني أنا يعني خمسة
+
+287
+00:21:50,100 --> 00:21:55,220
+في المية عند نسبة أو نسبة قبول للخطأ خمسة مش واحد
+
+288
+00:21:55,220 --> 00:21:59,440
+في المليونفبقول عشان هيك هذا الواحد بديش إياه طبعا
+
+289
+00:21:59,440 --> 00:22:02,980
+واللي جاي من التفكك التالت أقل كتير من هيك فمعنى
+
+290
+00:22:02,980 --> 00:22:05,920
+كلام التفكك التاني والتالت لايا كان يذكره ال H
+
+291
+00:22:05,920 --> 00:22:08,920
+plus اللي جاي من التفكك التاني تكاد تكون صفر ال H
+
+292
+00:22:08,920 --> 00:22:12,460
+plus اللي جاي من التفكك التالت تكاد تكون أيضا صفر
+
+293
+00:22:13,310 --> 00:22:18,270
+عشان هيك بيبقى عندي تفكك واحد فقط اللي هو التفكك
+
+294
+00:22:18,270 --> 00:22:22,150
+الأول وهيك بشتغل زي الـ monoproteic acids بالظبط
+
+295
+00:22:22,150 --> 00:22:26,770
+يبقى عندي تفكك إيه شماله؟ واحد إذا أنا بقدر أتوصل
+
+296
+00:22:26,770 --> 00:22:31,330
+لحساب ال pH لل polyproteic acids بعملية تبسيط
+
+297
+00:22:31,330 --> 00:22:35,870
+عملية التبسيط عملية معقولة بدل ما عندي تلت معادلة
+
+298
+00:22:35,870 --> 00:22:43,270
+أصلا عندي إيه؟ إيش عملت؟ جسمة KA1 على KA2مدام
+
+299
+00:22:43,270 --> 00:22:50,290
+النسبة كبيرة، إذا بعرف إن الأول أكبر من التاني
+
+300
+00:22:50,290 --> 00:22:54,330
+بالنسبة معقولة، إذا يمكن إلغاء التاني، واللي بعده،
+
+301
+00:22:54,330 --> 00:22:58,490
+إذا كان فيه تالت أو رابع أو خامس، يمكن إلغاهممعظم
+
+302
+00:22:58,490 --> 00:23:01,990
+الكتب بتقول كأ واحد على كأ اتنين يعني لازم تكون
+
+303
+00:23:01,990 --> 00:23:06,370
+اكبر من عشرة اقص اربعة لكن هذا الكلام مش صحيح من
+
+304
+00:23:06,370 --> 00:23:10,530
+ناحية عملية و هنشوف هذا الكلام احنا في المستقبل
+
+305
+00:23:10,530 --> 00:23:14,510
+احنا هنعتمد ان كأ واحد اكبر من كأ اتنين بمائة مرة
+
+306
+00:23:14,510 --> 00:23:19,590
+بس اذا كان كأ واحد اكبر من كأ اتنين بمائة مرة
+
+307
+00:23:19,590 --> 00:23:27,170
+هنقول والله خلاص كأ اتنين هذا بيشاركش بالبقيمة الـ
+
+308
+00:23:27,170 --> 00:23:32,170
+H plus للبحلول و كأنه بتفككش و هنحاول احنا في
+
+309
+00:23:32,170 --> 00:23:36,610
+المحاضرات خلال شغلنا هنحاول نثبت هذا الكلام و
+
+310
+00:23:36,610 --> 00:23:40,390
+هنلاحظ انه مش ميت مرة حتى لو كان اقل سبعين مرة
+
+311
+00:23:40,390 --> 00:23:45,470
+بصيدليه؟ لأنه مش قيمة ال equilibrium constant
+
+312
+00:23:45,470 --> 00:23:49,970
+المطلقة هي اللي بتعطين الفرق، لأ الأول لما يتفكك
+
+313
+00:23:49,970 --> 00:23:53,570
+مليون مرة أكتر من التاني، نظريا، لما المليون
+
+314
+00:23:53,570 --> 00:23:56,830
+يبروتون ييجوهان، إيش بحصل التفكك التاني؟ بيرجع
+
+315
+00:23:56,830 --> 00:24:00,310
+الأول، إذا الفرق بينهم بقبل مليون، صار مليار ولا
+
+316
+00:24:00,310 --> 00:24:06,560
+تريليون؟معايا؟ فلما نكون مائة مرة الفريق مش هي في
+
+317
+00:24:06,560 --> 00:24:10,120
+الحقيقة مش مائة مرة لأ مائات المرات بيكون هنشوف
+
+318
+00:24:10,120 --> 00:24:14,060
+هذا الكلام في المستقبل لكن ك guideline كشيء إرشادي
+
+319
+00:24:14,060 --> 00:24:17,640
+أو استرشادي هنقول والله إذا كان ال KA واحد أكبر من
+
+320
+00:24:17,640 --> 00:24:21,320
+ال KA اتنين بمائة مرة إذا مافيش ضرورة لل إيه ده ال
+
+321
+00:24:21,320 --> 00:24:27,800
+KA اتنين واللي بعده ماشي يا شباب طيب الآن خلينا
+
+322
+00:24:27,800 --> 00:24:32,100
+ناخدلنا بعض الأمثلةناخد بعض الأمثلة نتطلع في
+
+323
+00:24:32,100 --> 00:24:35,360
+البداية على الـ sulphuric acid لأنه وعدناكم أنه
+
+324
+00:24:35,360 --> 00:24:39,600
+نرجعله لما ناخد ال polyprotic acids بنقول find the
+
+325
+00:24:39,600 --> 00:24:46,880
+pH of a 0.1 molar H2SO4 sulphuric acid الـKa2 له 1
+
+326
+00:24:46,880 --> 00:24:52,240
+و 7 في 10 أقل سالب 2 طب ماعطانيش الـKa1 قال طبعا
+
+327
+00:24:52,240 --> 00:24:56,960
+ماعطانيش الـKa1 لأن هذا الـKa1 مالوش Ka1 لأن هذا
+
+328
+00:24:56,960 --> 00:25:01,670
+التفكك الأول له قويماذا يعني تفكك الأول لقوي؟ يعني
+
+329
+00:25:01,670 --> 00:25:05,570
+ليس لديه equilibrium constant لتفكك الأول، لماذا؟
+
+330
+00:25:05,570 --> 00:25:07,490
+لأنه لو أرد أن يكون ال equilibrium constant، يجب
+
+331
+00:25:07,490 --> 00:25:11,970
+أن نكسب على المتفاعلات اللي هو ال H2SO4 وهذا صفر،
+
+332
+00:25:11,970 --> 00:25:15,510
+يبقى كمية غير محددة، لذلك ليس لديه إلا بس تفكك
+
+333
+00:25:15,510 --> 00:25:24,310
+تاني، لذلك هذا اسمه KA2، ليس KA1،بقول ببساطة خالص
+
+334
+00:25:24,310 --> 00:25:29,050
+عند ال sulfuric acid طبعا بتفكك بشكل مية في المية
+
+335
+00:25:29,050 --> 00:25:33,190
+و بعدين ال HSO4 هذه اللي حصلت عليها من التفكك
+
+336
+00:25:33,190 --> 00:25:38,730
+الأول بتتفكك جزئيا لل H بلس وال SO4 اتنين سالب
+
+337
+00:25:38,730 --> 00:25:44,930
+فيها انه ابني الجدول كالعادة بقول ال HSO4 كانت
+
+338
+00:25:44,930 --> 00:25:51,460
+واحد من عشرةالـ H Plus أيضًا 1 من عشرة الـ SO4
+
+339
+00:25:51,460 --> 00:25:58,060
+كانت صفر فالـ HSO4 بدها تجلب مقدار X والـ H Plus
+
+340
+00:25:58,060 --> 00:26:03,120
+بدها تزيد بمقدار X من تفكك الـ HSO4 الـ 1 من عشرة
+
+341
+00:26:03,120 --> 00:26:07,280
+هذه هي اللي جاية من التفكك الأول من الـ H2SO4 1 من
+
+342
+00:26:07,280 --> 00:26:12,980
+عشرة كاملة ليه؟ لأنه التفكك الأول قويفبطبق ال
+
+343
+00:26:12,980 --> 00:26:15,520
+equilibrium constant واحد وسبعة في عشر أقل سالب
+
+344
+00:26:15,520 --> 00:26:19,620
+اتنين ساوي ال X في ال point one زاد X ع ال point
+
+345
+00:26:19,620 --> 00:26:23,040
+one minus X وبعمل الفرضية تبعتي point one أكبر
+
+346
+00:26:23,040 --> 00:26:28,510
+كتير من ال Xهذا الكلام بيعطيني x بتساوي واحد وسبعة
+
+347
+00:26:28,510 --> 00:26:32,430
+في عشر أقل سالب اتنين ال relative error بيطلع 17%
+
+348
+00:26:32,430 --> 00:26:37,870
+إذا إيش بيقوليا ده؟ بيقوليا لا يمكن إلغاء x و طبعا
+
+349
+00:26:37,870 --> 00:26:41,490
+هذا موضوع طبيعي أنا بالنسبالي ليش موضوع طبيعي؟ لأن
+
+350
+00:26:41,490 --> 00:26:45,510
+ال equilibrium constant مش صغير كتير عشر أقل سالب
+
+351
+00:26:45,510 --> 00:26:49,880
+اتنين مش صغير كتيرعشرة أساليب اتنين يا شباب مش
+
+352
+00:26:49,880 --> 00:26:52,700
+صغير كتير عشان هيك دائما لما نكون ال equilibrium
+
+353
+00:26:52,700 --> 00:26:58,260
+constant يعني مش صغير خالص بحصل عندى مشكلة في
+
+354
+00:26:58,260 --> 00:27:02,240
+إلغاء ال X وغالبا بضطر ان احل باستخدام ال
+
+355
+00:27:02,240 --> 00:27:06,160
+quadratic equation هنشوف برضه هذا المثال تصديق
+
+356
+00:27:06,160 --> 00:27:11,260
+لهذا الكلاممثال كالتالي مثال اخر ايش بيقول بيقول
+
+357
+00:27:11,260 --> 00:27:14,740
+find the pH of a 0.1 molar phosphoric acid
+
+358
+00:27:14,740 --> 00:27:19,380
+solution عندى phosphoric acid بدى اوجدله ال pH
+
+359
+00:27:19,380 --> 00:27:24,480
+بقول phosphoric acid هدا triprotic acidبتفكك تفكك
+
+360
+00:27:24,480 --> 00:27:30,140
+أول و تاني و تالت بقول بما أنه polyprotic acid على
+
+361
+00:27:30,140 --> 00:27:35,060
+طول بجسم KA1 على KA2 و بشوف هل يمكن إلغاء التفكك
+
+362
+00:27:35,060 --> 00:27:39,380
+التاني وما يليه ولا لأ KA1 على KA2 بتعطينا حوالي
+
+363
+00:27:39,380 --> 00:27:43,930
+مليون مثلاإذا أكبر من 10 رقص 2 إذا خلاص مش عندي
+
+364
+00:27:43,930 --> 00:27:49,230
+مشكلة ابنلغ هدول الاتنين مش علهم أي قيمة والان فضل
+
+365
+00:27:49,230 --> 00:27:53,530
+عندى فقط معادلة واحدة فوسفوريك أسد فاكر بغطينا H
+
+366
+00:27:53,530 --> 00:27:59,270
+plus وH2PO4 سالم إذا بقول والله هذه المعادلة point
+
+367
+00:27:59,270 --> 00:28:04,050
+one صفر صفر point one minus X X X يبقى بعوض في ال
+
+368
+00:28:04,050 --> 00:28:09,300
+equilibrium constant بقولالـ K A1 بدها تساوي X
+
+369
+00:28:09,300 --> 00:28:12,880
+تربية على الـ 0.1 minus X و افترض ان الـ 0.1 أكبر
+
+370
+00:28:12,880 --> 00:28:18,180
+كتير من ال X ال X بتطلع 0.033 لو جبت relative
+
+371
+00:28:18,180 --> 00:28:26,660
+error بطلع عندي 33% اذا ايضا .. ايضا الفرضية غير
+
+372
+00:28:26,660 --> 00:28:32,040
+صحيحة و يجب حل ال quadratic equation يجب حل ..
+
+373
+00:28:32,040 --> 00:28:37,340
+ليش؟ كمان مرة لو جينا تطلعنا علىالـ equilibrium مش
+
+374
+00:28:37,340 --> 00:28:40,260
+صغير كتير مش عشرة أقل سالب خمسة و لا عشرة أقل سالب
+
+375
+00:28:40,260 --> 00:28:43,460
+ستة و لا عشرة أقل سالب عشرة عشان نقول والله ال X
+
+376
+00:28:43,460 --> 00:28:48,640
+هذه لا مهمة لا تكت تذكرها لأ مش هالجد فهذه رسميا
+
+377
+00:28:48,640 --> 00:28:52,620
+يعني هيعتبر مش صغير مش صغير كتير يعني يعتبر إله
+
+378
+00:28:52,620 --> 00:28:56,460
+قيمة إلى حد ما يعني لو حلينا المثلة باستخدام ال
+
+379
+00:28:56,460 --> 00:29:00,020
+color equation تطلع ال X اللي هي ال H plus point O
+
+380
+00:29:00,020 --> 00:29:05,410
+two eight و ال pH واحد وخمسة وخمسينطيب الآن خلينا
+
+381
+00:29:05,410 --> 00:29:10,190
+نتطلع على أسد الـKA1 الو بالفعل قليل فنتطلع على ال
+
+382
+00:29:10,190 --> 00:29:16,990
+carbonic acid مثلا مثال بيقول find the pH of a 0.1
+
+383
+00:29:16,990 --> 00:29:21,490
+molar carbonic acid solution حلو كتير بكتب
+
+384
+00:29:21,490 --> 00:29:27,070
+المعادلات المعادلة التفكك الأول والتفكك التاني و
+
+385
+00:29:27,070 --> 00:29:32,070
+باجي بقارن ال KA's بقول KA1 على KA2 بطلع حوالي 10
+
+386
+00:29:32,070 --> 00:29:37,860
+,000 مثلااه والله التفكير الأول أكبر كتير أنا سامح
+
+387
+00:29:37,860 --> 00:29:42,800
+لحالي ب 100، كويس؟ وحتى لو كان أقل من 100، راح
+
+388
+00:29:42,800 --> 00:29:46,000
+أسمح لحالي فيها و بعدين أحقق فرضيتي، بس أكتر من
+
+389
+00:29:46,000 --> 00:29:50,160
+100 مش بحاجة أحقق فرضيتنا، لكن إذا كان يعني .. كان
+
+390
+00:29:50,160 --> 00:29:55,380
+أقل .. مثلا واحد أكبر مثلا بس ب 50، ب60، ب40، راح
+
+391
+00:29:55,380 --> 00:29:59,100
+أفترض أنه كمان أكبر منه كتير، راح أفترض، لإن مافيش
+
+392
+00:29:59,100 --> 00:30:04,050
+حالجه قداميطيب على اي حال كتبناهم شفنا ان ال K1
+
+393
+00:30:04,050 --> 00:30:08,570
+اكبر كتير من ال K2 اذا لغاية التفكك التاني معناه
+
+394
+00:30:08,570 --> 00:30:11,770
+الكلام صار عندى معادلة واحدة و بتنحل بالظبط زي ال
+
+395
+00:30:11,770 --> 00:30:16,520
+monoproticعندي الكربونيك أسد بيعطينا H بلس و B
+
+396
+00:30:16,520 --> 00:30:20,640
+كربونيت قبل ال equilibrium point one صفر صفر بعد
+
+397
+00:30:20,640 --> 00:30:24,500
+ال equilibrium point one minus X X X فمجرغوا ال X
+
+398
+00:30:24,500 --> 00:30:28,600
+تربيع على point one minus X بتساوي ال K a one بعوض
+
+399
+00:30:28,600 --> 00:30:32,430
+عن ال K a one و لاحظوا K a one جديشعشرة أو سالب
+
+400
+00:30:32,430 --> 00:30:37,710
+سبعة يبدأ متوقع عندي بالفعل متوقع عندي ان ال X
+
+401
+00:30:37,710 --> 00:30:42,490
+تنجح ان ال X تكون قليلة جدا يبدأ ال X اتنين واحد
+
+402
+00:30:42,490 --> 00:30:45,150
+فعشرة أو سالب اربعة يجيب ال relative error بطلع
+
+403
+00:30:45,150 --> 00:30:50,830
+point one percent point one percent واحد و عشرين
+
+404
+00:30:50,830 --> 00:30:52,950
+من مية في المية كمية قليلة خالص
+
+405
+00:30:56,610 --> 00:31:00,290
+الـ Assumption valid والـ H plus 2 و 1 فعشرة أقل
+
+406
+00:31:00,290 --> 00:31:05,830
+سالب أربعة أو ال pH تلاتة و تمانية و ستين فضل مثل
+
+407
+00:31:05,830 --> 00:31:09,350
+ال .. اللي جابت ال .. ال .. ال X ما جدناش نلاقيها
+
+408
+00:31:09,350 --> 00:31:12,390
+اه ليش؟ لأنه يعني ال .. الفكرة كانت التانية فيه
+
+409
+00:31:12,390 --> 00:31:18,350
+لها يعني اسم كبير ولا كبير؟ لو جيت تطلع اتهان
+
+410
+00:31:18,350 --> 00:31:22,110
+بتلاقي إيش قيمة ال equilibrium constant عشرة أقل
+
+411
+00:31:22,110 --> 00:31:27,490
+سالب اتنين مش صغير كتيريعني ال equilibrium بيتم
+
+412
+00:31:27,490 --> 00:31:33,430
+لدرجة معقولة لأ لأ لأ بحكيش عن التاني التاني خلص
+
+413
+00:31:33,430 --> 00:31:36,730
+مافيش حاجة تاني اسمها التاني التغى نهائيا انا
+
+414
+00:31:36,730 --> 00:31:41,970
+بتكلم عن إلغاء ال X هنا انا اخترت خلاص انا اخترت
+
+415
+00:31:41,970 --> 00:31:45,390
+هذا هو ال equilibrium اللي انا ايه بشتغل عليه ال
+
+416
+00:31:45,390 --> 00:31:48,770
+equilibrium الأول خلاص لما بديها جاحل باستخدام ال
+
+417
+00:31:48,770 --> 00:31:52,510
+equilibrium الأول بستخدم طبعا ال K ايه طبعته مش
+
+418
+00:31:52,510 --> 00:31:58,290
+هيكلما استخدم الـ QA تبعته بقول الـ X.033 طلعت الـ
+
+419
+00:31:58,290 --> 00:32:00,650
+rate of error تلاتة و تلاتين في المية معناه الكلام
+
+420
+00:32:00,650 --> 00:32:05,750
+هذا خطأيعني ال assumption invalid ال assumption
+
+421
+00:32:05,750 --> 00:32:10,830
+فرضية غير .. غير صحيحة وبتالي بقول لازم أحلم
+
+422
+00:32:10,830 --> 00:32:13,790
+استخدام ال quadratic equation بس هذا الكلام أنا
+
+423
+00:32:13,790 --> 00:32:17,850
+بقولك إيه؟ ليش؟ ليش حصل معنى هيك؟ قال لأن ال
+
+424
+00:32:17,850 --> 00:32:21,570
+equilibrium constant مش صغير كتير بينما لو جينا
+
+425
+00:32:21,570 --> 00:32:24,830
+carbonic acid مثلا ال equilibrium constant عشرة
+
+426
+00:32:24,830 --> 00:32:29,260
+أقل سالب سبعة مش عشرة أقل سالب اتنينمش هيك؟ لما
+
+427
+00:32:29,260 --> 00:32:32,860
+يكون عشرة أو سالب سبعة يبقى ال X هتكون كمية قليلة
+
+428
+00:32:32,860 --> 00:32:37,340
+جدا، بتوقع هيك أنا و بالفعل لما حسبنا ال X و جبنا
+
+429
+00:32:37,340 --> 00:32:40,080
+ال relative error لجنا relative error قليل كتير
+
+430
+00:32:40,080 --> 00:32:44,140
+كمان مرة، ليش هذا الكلام؟ بتوقع أن هذا الكلام يحصل
+
+431
+00:32:44,140 --> 00:32:48,100
+بالفعل زيك، ليه؟ لأن ال equilibrium constant صغير
+
+432
+00:32:48,100 --> 00:32:52,200
+إيش يعني ال equilibrium constant صغير؟ يعني بمشيش
+
+433
+00:32:52,200 --> 00:32:56,560
+ناحية النواتجإيش يعني ال equilibrium constant في
+
+434
+00:32:56,560 --> 00:33:02,040
+المثال اللي جابله كبير نسبيا يعني أو مش صغير كتير
+
+435
+00:33:02,040 --> 00:33:05,680
+معناته بيمشي لحيط النواتج بشكل ملحوظ يبقى ال X
+
+436
+00:33:05,680 --> 00:33:09,720
+اللي هي قيمة هاي الكلام اللي بنقوله طب السؤال اللي
+
+437
+00:33:09,720 --> 00:33:16,520
+هو يمكن المهم هان انه احنا لغينا التفكك التاني طب
+
+438
+00:33:16,520 --> 00:33:20,000
+ليش لغينا التفكك التاني؟ قلنا هان في البداية ان
+
+439
+00:33:20,000 --> 00:33:26,080
+والله التفكك الأول أكبر من التاني بحوالي إيش؟حوالي
+
+440
+00:33:26,080 --> 00:33:29,980
+يعني عشر تلاف مرة هو أقل يعنى، حوالي عشر تلاف مرة
+
+441
+00:33:29,980 --> 00:33:33,980
+خيا نقول، كويس، عشان هيقولنا كل ما الأول يعطينا
+
+442
+00:33:33,980 --> 00:33:36,580
+عشر تلاف بروتون، التاني بعطينا بروتون واحد، إذا
+
+443
+00:33:36,580 --> 00:33:40,300
+بدي ألغيه، طب إيش رأيكم نحسب جداش ال H plus اللي
+
+444
+00:33:40,300 --> 00:33:45,260
+جاية من التفكك التاني؟معايا؟ انا عندس كان بتلاحظوا
+
+445
+00:33:45,260 --> 00:33:51,280
+انتوا هذا ال carbonic acid اتفكك وعطانى 2 و 1 ف 10
+
+446
+00:33:51,280 --> 00:33:56,540
+أقل سالب 4 و 2 و 1 ف 10 أقل سالب 4 اللى X و X X
+
+447
+00:33:56,540 --> 00:34:00,820
+حسبناها 2 و 1 ف 10 أقل سالب 4 2 و 1 ف 10 أقل سالب
+
+448
+00:34:00,820 --> 00:34:06,940
+4 طيب ممكن يجي كده واحد اقل من كده لا دفعشده من
+
+449
+00:34:06,940 --> 00:34:11,340
+الـ Ke1 أكبر من الـ Ke2 تعالوا نشوف، بدنا نحاول
+
+450
+00:34:11,340 --> 00:34:13,600
+إحنا نحسب الـ H بلس اللي جاي من التفكك التاني
+
+451
+00:34:13,600 --> 00:34:17,300
+أخدنا ال equilibrium لتفكك التاني فهي الـ Ke2
+
+452
+00:34:17,300 --> 00:34:20,840
+بتساوي الـ H بلس في الكربونيت على ال B كربونيت لكن
+
+453
+00:34:20,840 --> 00:34:24,760
+الـ H بلس بتساوي ال B كربونيت بتساوي 2 و 1 في 10
+
+454
+00:34:24,760 --> 00:34:28,900
+أقل سالم 4 من التفكك اللي شفناها سابقة، من النتيجة
+
+455
+00:34:28,900 --> 00:34:34,330
+السابقة، إذا الـ Ke2 بتساوي الكربونيتبتساوى اربعة
+
+456
+00:34:34,330 --> 00:34:37,550
+و تمانية فى عشر اقل سالب احداشر لكن ال carbonate
+
+457
+00:34:37,550 --> 00:34:41,210
+بتساوى ال H plus اللى جاى من ال second step هي ال
+
+458
+00:34:41,210 --> 00:34:43,850
+carbonate بتساوى ال H plus اللى جاى من ايه من
+
+459
+00:34:43,850 --> 00:34:47,170
+الخطوة التانية طيب جداش طلع يبجى ال H plus اللى
+
+460
+00:34:47,170 --> 00:34:49,890
+جاى من الخطوة التانية اربعة و تمانية فى عشر اقل
+
+461
+00:34:49,890 --> 00:34:55,270
+سالب احداشر لما بدي اجى اقارنه بال H plus اللى جاى
+
+462
+00:34:55,270 --> 00:34:57,070
+من الخطوة الاولى جداش كان ال H plus اللى جاى من
+
+463
+00:34:57,070 --> 00:35:00,530
+الخطوة الاولى اتنين واحد فى عشر اقل سالب اربعة طب
+
+464
+00:35:00,530 --> 00:35:05,810
+شوف لأ مش هيك انتشوف قداش هذا اصغر من هداك او قداش
+
+465
+00:35:05,810 --> 00:35:09,610
+الاول اكبر من التاني عشر اقل سالب اربع الاول وهذا
+
+466
+00:35:09,610 --> 00:35:14,350
+عشر اقل سالب احداشر عشر مليون مرة مش عشر تلاف مرة
+
+467
+00:35:14,350 --> 00:35:19,630
+زي ما اتوقعنا احنا من مش عشر تلاف مرة زي ما
+
+468
+00:35:19,630 --> 00:35:23,050
+اتوقعنا من ال KS ليه؟ لأن مجرد ان ال H plus هذا
+
+469
+00:35:23,920 --> 00:35:27,680
+يحصل يكون موجود التفكك التاني ايش بيحصل له بيرجع
+
+470
+00:35:27,680 --> 00:35:30,260
+لورا فاحنا من ناحية نظرية اه لو كان هذا موجود
+
+471
+00:35:30,260 --> 00:35:33,760
+لحاله و هذا موجود لحاله اه الاول يعني بيمشي عشر
+
+472
+00:35:33,760 --> 00:35:36,360
+تلاف مرة اكتر من التاني لكن لما نكون الاتنين مع
+
+473
+00:35:36,360 --> 00:35:42,480
+بعض لأ مش عشر تلاف لجينا هال عشر رليون يعني مبرر
+
+474
+00:35:42,480 --> 00:35:47,280
+لنا كتير ان نلغي التفككات اللي بعد التفكك الاول
+
+475
+00:35:47,280 --> 00:35:57,700
+طيب الآن انحاول نتقلع علىطبقات لل polyprotic acids
+
+476
+00:35:57,700 --> 00:36:00,900
+وبدنا نتكلم فيما يتعلق بال buffer buffer solutions
+
+477
+00:36:00,900 --> 00:36:06,000
+بقول في الحقيقة ال polyprotic acids يعني ممتازة
+
+478
+00:36:06,000 --> 00:36:10,680
+جدا لتحضير ال buffer solutions ليه؟ لأن كل
+
+479
+00:36:10,680 --> 00:36:16,700
+polyprotic acid موجود فيه أكتر من تفكك كل تفكك من
+
+480
+00:36:16,700 --> 00:36:22,490
+التفككات يمكن اعتباره buffer يعني مثلالو جينا
+
+481
+00:36:22,490 --> 00:36:27,430
+اطلعنا على ال phosphoric acid هاي عندى phosphoric
+
+482
+00:36:27,430 --> 00:36:31,490
+acid و ال by hydrogen phosphate مع بعض هدول buffer
+
+483
+00:36:31,490 --> 00:36:37,390
+و هاي ال by hydrogen phosphate هدى acid و هى ال
+
+484
+00:36:37,390 --> 00:36:41,070
+conjugate base تبعها هدى buffer تانى و ال hydrogen
+
+485
+00:36:41,070 --> 00:36:45,210
+phosphate مع ال phosphate هدى buffer تالت بدك
+
+486
+00:36:45,210 --> 00:36:49,230
+تلاحظ انه مثلا phosphoric acid مع ال phosphate هدى
+
+487
+00:36:49,230 --> 00:36:54,590
+مش bufferليش؟ لأن الفوسفات مش conjugate base
+
+488
+00:36:54,590 --> 00:36:58,350
+للفوسفوريك أسد الفرق بين ال acid و ال conjugate
+
+489
+00:36:58,350 --> 00:37:03,290
+base لازم يكون دائما one proton معايا يبجى
+
+490
+00:37:03,290 --> 00:37:08,310
+الفوسفات و الفوسفوريك أسد فهذا مايعملش buffer ليه؟
+
+491
+00:37:08,310 --> 00:37:11,710
+لأن الفوسفات مش conjugate base للفوسفوريك أسد
+
+492
+00:37:11,710 --> 00:37:18,140
+الفوسفات conjugate base للهيدروجين فوسفاتكمان مرة
+
+493
+00:37:18,140 --> 00:37:24,300
+ال HPO4 مش conjugate
+
+494
+00:37:24,300 --> 00:37:28,880
+base لـ H3PO4 للفسوفوريكات ليه؟ لأن الفرق بينهم
+
+495
+00:37:28,880 --> 00:37:33,320
+اتنين بروتون لازم الفرق بينهم ايش يكون بروتون واحد
+
+496
+00:37:33,320 --> 00:37:36,340
+دائما يبقى ال acid base conjugate معناته ايش الفرق
+
+497
+00:37:36,340 --> 00:37:41,730
+بينهم بروتون مش اكتر من بروتون لكن ايش جمال؟الـ
+
+498
+00:37:41,730 --> 00:37:45,030
+Polyprotic Acids فيما يتعلق بالبفر Solutions بقول
+
+499
+00:37:45,030 --> 00:37:48,550
+كل تفكك من التفككات يعني هي عندي Acid Base
+
+500
+00:37:48,550 --> 00:37:51,830
+Conjugate, Acid Base Conjugate تاني, Acid Base
+
+501
+00:37:51,830 --> 00:37:57,410
+Conjugate تالت، كل واحد له Ka مختلفمش هيك؟ طب انا
+
+502
+00:37:57,410 --> 00:38:03,610
+بعرف ان ال pH بتساوي PKA زائد او ناقص واحد، اذا لو
+
+503
+00:38:03,610 --> 00:38:07,010
+جينا طلعنا احنا على ال buffer solutions هذه بقول
+
+504
+00:38:07,010 --> 00:38:10,590
+التفاكك الاول KA واحد واحد فعشرة اقل ثالث اتنين
+
+505
+00:38:10,590 --> 00:38:18,730
+يعني ال PKA واحد وستة وتسعينبكا 1 و 1.96 إذا بينفع
+
+506
+00:38:18,730 --> 00:38:27,410
+يكون buffer من 0.69 ل 2.96 ل 2.96
+
+507
+00:38:27,410 --> 00:38:32,050
+هذا الفوسفوريك أسد مع ال by hydrogen phosphate طب
+
+508
+00:38:32,050 --> 00:38:34,750
+نيجي ناخد التفكك اللي بعده في الفوسفوريك أسد
+
+509
+00:38:36,240 --> 00:38:39,180
+الـBihydrogen Phosphate مع الـHydrogen Phosphate
+
+510
+00:38:39,180 --> 00:38:47,600
+الـKa 7.5×10⁸ لو شفنا الـPKa 2 7.1 من 10 إذن هدول
+
+511
+00:38:47,600 --> 00:38:52,740
+اتنين يمكن استخدامهم كبفر بيشتغل من 6 و 1 لـ8 و 1
+
+512
+00:38:52,740 --> 00:38:57,840
+PKA plus or minus one minus one صارت 6 و 1 plus
+
+513
+00:38:57,840 --> 00:39:01,580
+one صارت 8 و 1 طب لو جينا لها الـHydrogen
+
+514
+00:39:01,580 --> 00:39:03,900
+Phosphate مع الـPhosphate هذا برضه acid base
+
+515
+00:39:03,900 --> 00:39:09,180
+conjugateالـ Ka أربعة و تمانية في عشرة أقل سالب
+
+516
+00:39:09,180 --> 00:39:14,280
+تلاتة أقل واخدنا ال Pka بطلع عنده اتناشر و تلاتة
+
+517
+00:39:14,280 --> 00:39:18,460
+من عشرة اذا بنفع من احداشر و تلاتة لتلاتاشر و
+
+518
+00:39:18,460 --> 00:39:21,540
+تلاتة لحظة الفوسفوري كاسيد و مشتقاته عملت لنا
+
+519
+00:39:21,540 --> 00:39:26,280
+تلاتة buffers وقبل هيك طبعا هدول تلاتة متفرقين لكن
+
+520
+00:39:26,280 --> 00:39:31,000
+قبل هيك شوفنا ال citric acid من اتنين و واحد لسبعة
+
+521
+00:39:31,000 --> 00:39:36,310
+و أربعةمتداخلين يعني بنفع مرة واحدة استخدمه من
+
+522
+00:39:36,310 --> 00:39:40,530
+اتنين و واحد لسبعة و اربعة ليه لأنه برضه تلاتة
+
+523
+00:39:40,530 --> 00:39:45,590
+protons تلت تفككات كل تفكك بعطيني PK لكن ال PK
+
+524
+00:39:45,590 --> 00:39:49,630
+استبعات ال citric acid اشمالها متداخلة فبيعطيني من
+
+525
+00:39:49,630 --> 00:39:56,410
+اتنين و واحد لسبعة و واحد نفس الكلاملو اتكلمنا عن
+
+526
+00:39:56,410 --> 00:40:01,070
+الكربونيك أسد بنقول برضه عندي تفككين كربونيك أسد
+
+527
+00:40:01,070 --> 00:40:07,590
+مع بيكربونيت ال KA 4 3 X 10 أقل سالب 7 لو جبت ال
+
+528
+00:40:07,590 --> 00:40:12,990
+PKA 1 بقوله 6 4 من 10 إذا يمكن استخدام الكربونيك
+
+529
+00:40:12,990 --> 00:40:16,510
+أسد مع ال بيكربونيت لتحضير buffer من 5 4 إلى 7 4
+
+530
+00:40:16,510 --> 00:40:19,930
+لو جينا طلعنا على الكربونيت بيكربونيت هذا مشكل
+
+531
+00:40:19,930 --> 00:40:24,560
+كتيركربونيت بي كربونيت بفر الكي اتنين اربعة تمانية
+
+532
+00:40:24,560 --> 00:40:28,680
+في عشرة او سالب احداشر يعني ال PK عشرة و تلاتة من
+
+533
+00:40:28,680 --> 00:40:33,400
+عشرة اذا يمكن استخدامه من تسعة و تلاتة الى احداشر
+
+534
+00:40:33,400 --> 00:40:38,030
+و تلاتةاللي شاهد في الكلام أو يعني بقدر اقول انا
+
+535
+00:40:38,030 --> 00:40:44,850
+انه ال polyprotic acids بتعطي مرونة flexibility في
+
+536
+00:40:44,850 --> 00:40:50,930
+تحضير ال buffer solutions يعني هي عبارة عن أحماض
+
+537
+00:40:51,500 --> 00:40:56,700
+لو يعني اقترنت بمشتقاتها الحمض مع ال conjugate
+
+538
+00:40:56,700 --> 00:40:59,420
+base تبعه و ادي اكتر من حمض و اكتر من conjugate
+
+539
+00:40:59,420 --> 00:41:05,520
+base لما ادي polyprotic acid الاصل فبقدر احضر يعني
+
+540
+00:41:05,520 --> 00:41:09,860
+انواع مختلفة من ال buffer solutions اللي لها
+
+541
+00:41:09,860 --> 00:41:14,180
+ranges مختلفة خالص فهذا بيعطيني مرونة كبيرة جدا
+
+542
+00:41:14,180 --> 00:41:17,310
+غير عن ال monoprotic acidsمونوبروتيك أسد والله هي
+
+543
+00:41:17,310 --> 00:41:21,330
+مثلا أستيك أسد اه من تلاتة و سبتة و سبعين لخمسة و
+
+544
+00:41:21,330 --> 00:41:24,870
+سبتة و سبعين غير هيك خلاص انسى مافيش يعني .. لأن
+
+545
+00:41:24,870 --> 00:41:27,710
+هو هالبفر الوحيد مافيش اللي غير acid base
+
+546
+00:41:27,710 --> 00:41:30,450
+conjugate واحد و خلاص و انتهى الموضوع غير عن ال
+
+547
+00:41:30,450 --> 00:41:33,510
+polyprotic acid بعطيك نوع من المرونة يعني لو عندك
+
+548
+00:41:33,510 --> 00:41:36,950
+فوسفوريك أسد و عندك sodium hydroxide ممكن تتحكم
+
+549
+00:41:36,950 --> 00:41:40,210
+فيه اتحول جزء منه لل dihydrogen phosphate صار عندك
+
+550
+00:41:40,210 --> 00:41:43,530
+bufferممكن تضيف صدوم هيدروكسيد اكتر تحول
+
+551
+00:41:43,530 --> 00:41:49,050
+الفوسفوركاسد كله لديهيدرونفوسفات وهيدروجينفوسفات
+
+552
+00:41:49,050 --> 00:41:52,550
+صار عندك بفر تاني ممكن تضيف صدوم هيدروكسيد اكتر
+
+553
+00:41:52,550 --> 00:41:57,110
+تحول كل الديهيدرونفوسفات تحولها لهيدروجينفوسفات
+
+554
+00:41:57,110 --> 00:42:02,690
+وفوسفات صار عندك بفر تالت فتعطينا نوع من المرونة
+
+555
+00:42:02,690 --> 00:42:04,210
+الممتازة
+
+556
+00:42:07,550 --> 00:42:12,790
+بقى بس مثال بسيط على ال buffer solutions لما نكون
+
+557
+00:42:12,790 --> 00:42:18,390
+عندى polyprotic acids لو طلعنا هان H2PO4 وHPO4
+
+558
+00:42:18,390 --> 00:42:22,170
+طبعا هذه بنعتبرها هي ال acid وهذه هي ال conjugate
+
+559
+00:42:22,170 --> 00:42:26,310
+base هان فهذا buffer مدام الفرق بينهم H plus هذا
+
+560
+00:42:26,310 --> 00:42:30,490
+bufferماشي يا شباب هو طالب يقول find the ratio of
+
+561
+00:42:30,490 --> 00:42:37,090
+H2PO4 سالب على ال HPO4 اتنين سالب if the pH of the
+
+562
+00:42:37,090 --> 00:42:40,190
+solution containing a mixture of both substances
+
+563
+00:42:40,190 --> 00:42:42,910
+is سبعة وأربعة من عشرة ال pH عندي معروفة سبعة
+
+564
+00:42:42,910 --> 00:42:47,720
+وأربعة من عشرة بدي أعرف اللسبة بينهمبقول كمان مرة
+
+565
+00:42:47,720 --> 00:42:50,060
+يعني هذا عبارة عن equilibrium و أنا مشتغلش لغاية
+
+566
+00:42:50,060 --> 00:42:54,660
+equilibrium في هذه الشباتر يعني فبقول كيف بدي أحل
+
+567
+00:42:54,660 --> 00:42:57,640
+المسألة قال اكتب ال equilibrium constant طبعا هو
+
+568
+00:42:57,640 --> 00:43:01,020
+equilibrium constant طبعا ال equilibrium constant
+
+569
+00:43:01,020 --> 00:43:06,100
+اللي بحتوي على هدول اتنينعلى هذا الاتنين ال H2PO4
+
+570
+00:43:06,100 --> 00:43:10,480
+تعطيني H بلس زائد HPO4 وهي ال K موجودة ال
+
+571
+00:43:10,480 --> 00:43:14,000
+equilibrium constant K أتنين مستوي ال H بلس معروفة
+
+572
+00:43:14,000 --> 00:43:18,960
+عندى عشرة أقل سالب سبعة وأربعة من عشرة ال K أتنين
+
+573
+00:43:18,960 --> 00:43:24,190
+معروفة إذا بتبتدلش إلا النسبة هو بده النسبةمعايا؟
+
+574
+00:43:24,190 --> 00:43:29,570
+هو بده ال H2PO4 على ال HPO4 هو بدهياها طب هيدا
+
+575
+00:43:29,570 --> 00:43:33,250
+عوّط عن ال KE2 وعوّط عن ال H بلصب عشرة أس سالب
+
+576
+00:43:33,250 --> 00:43:37,670
+سبعة وأربعة من عشرة إذا إيش بدل؟ النسبة اللي
+
+577
+00:43:37,670 --> 00:43:40,750
+بدهياها بس هو النسبة اللي بدهياها معكوسة يعني هو
+
+578
+00:43:40,750 --> 00:43:45,850
+بده H2PO4 على ال HPO4 فانت مجرد أنه بتطلع القيامة
+
+579
+00:43:45,850 --> 00:43:54,250
+تكسب واحد على Xفبتعطيك ال HPO4 على ال H2PO4
+
+580
+00:43:54,250 --> 00:43:58,830
+تطلع عندك واحد وتسعة من عشرة لو حبيت انك يعني
+
+581
+00:43:58,830 --> 00:44:04,870
+تعكسها بتعكسها ماشي يا شباب اذا الله راد الحصة
+
+582
+00:44:04,870 --> 00:44:07,910
+الجاية بنكمل ان شاء الله كل عام و انتوا بخير
+
diff --git a/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/a2PZpAILMkI_raw.json b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/a2PZpAILMkI_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..474b0579bdba3dfb4679385a6fdec626060bf815
--- /dev/null
+++ b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/a2PZpAILMkI_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 3570, "start": 21.16, "end": 35.7, "text": "بسم الله الرحمن الرحيم اليوم إذا الله راضى بنتكلم عن آخر جزئية في ال acid-base titrations بنتكلم عن كلدال أناليسيس كلدال أناليسس في الحقيقة بيعالج", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640, 45595, 20498, 11933, 15730, 21984, 12602, 46958, 7578, 4724, 29399, 4117, 19528, 18871, 19753, 34740, 10874, 11622, 19986, 10632, 8978, 2423, 8258, 12, 17429, 3459, 12154, 4724, 29399, 4117, 19528, 18871, 28242, 3215, 6027, 14739, 6027, 1829, 3794, 1829, 3794, 28242, 3215, 6027, 14739, 6027, 1829, 3794, 3794, 8978, 21542, 38436, 28671, 4724, 40228, 6027, 7435], "avg_logprob": -0.22952177533597656, "compression_ratio": 1.638157894736842, "no_speech_prob": 8.404254913330078e-06, "words": [{"start": 21.16, "end": 21.48, "word": "بسم", "probability": 0.69482421875}, {"start": 21.48, "end": 21.64, "word": " الله", "probability": 0.96484375}, {"start": 21.64, "end": 21.94, "word": " الرحمن", 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nitrogen في العينات المختلفة عشان هيك ممكن أنه نسمي كل ده ال analysis بكل ده ال nitrogen analysis ليه؟ لأنه فقط يختص بتقدير كمية ال nitrogen في العينات المختلفة في الحقيقة تقدير ال nitrogen شيء مهم جدا", "tokens": [2655, 28543, 13546, 9122, 2304, 10632, 2423, 17903, 8978, 18863, 1829, 8315, 2655, 9673, 46456, 46538, 3660, 6225, 8592, 7649, 39896, 4117, 3714, 43020, 14739, 3224, 8717, 38251, 1829, 28242, 11778, 3224, 2423, 5215, 4724, 28820, 11778, 3224, 2423, 17903, 5215, 32239, 3224, 22807, 5296, 33456, 3224, 6156, 47432, 7251, 46456, 9381, 39894, 28543, 13546, 9122, 2304, 10632, 2423, 17903, 8978, 18863, 1829, 8315, 2655, 9673, 46456, 46538, 3660, 8978, 21542, 38436, 28671, 6055, 28543, 13546, 2423, 17903, 44049, 38207, 3714, 16095, 10874, 28259], "avg_logprob": -0.11360294222831727, "compression_ratio": 1.9826589595375723, "no_speech_prob": 1.1920928955078125e-07, "words": [{"start": 36.43, "end": 37.29, "word": "تقدير", "probability": 0.9007161458333334}, {"start": 37.29, "end": 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85.26, "word": " عينة", "probability": 0.8972981770833334}, {"start": 85.26, "end": 86.4, "word": " معناته", "probability": 0.8841145833333334}, {"start": 86.4, "end": 87.14, "word": " عينة", "probability": 0.9241536458333334}, {"start": 87.14, "end": 87.66, "word": " البروتين", "probability": 0.9056396484375}, {"start": 87.66, "end": 88.08, "word": " معناته", "probability": 0.9220377604166666}, {"start": 88.08, "end": 88.4, "word": " ممكن", "probability": 0.96435546875}, {"start": 88.4, "end": 88.7, "word": " والله", "probability": 0.83203125}, {"start": 88.7, "end": 89.06, "word": " نعمل", "probability": 0.9739583333333334}, {"start": 89.06, "end": 89.6, "word": " relation", "probability": 0.98486328125}, {"start": 89.6, "end": 90.16, "word": " ما", "probability": 0.89404296875}, {"start": 90.16, "end": 90.42, "word": " بين", "probability": 0.9326171875}, {"start": 90.42, "end": 90.86, "word": " كمية", "probability": 0.9939778645833334}, {"start": 90.86, "end": 91.02, "word": " ال", "probability": 0.95654296875}, {"start": 91.02, "end": 91.56, "word": " nitrogen", "probability": 0.95654296875}, {"start": 91.56, "end": 91.88, "word": " و", "probability": 0.74951171875}, {"start": 91.88, "end": 92.46, "word": " البروتين", "probability": 0.8984375}, {"start": 92.46, "end": 92.64, "word": " اللى", "probability": 0.7880859375}, {"start": 92.64, "end": 93.06, "word": " موجود", "probability": 0.9903971354166666}, {"start": 93.06, "end": 93.22, "word": " على", "probability": 0.86669921875}, {"start": 93.22, "end": 93.5, "word": " اساس", "probability": 0.814697265625}, {"start": 93.5, "end": 93.64, "word": " ان", "probability": 0.87841796875}, {"start": 93.64, "end": 94.22, "word": " البروتين", "probability": 0.9764404296875}, {"start": 94.22, "end": 94.94, "word": " جزء", "probability": 0.9967447916666666}, {"start": 94.94, "end": 95.52, "word": " منه", "probability": 0.9873046875}, {"start": 95.52, "end": 96.42, "word": " عبارة", "probability": 0.994384765625}, {"start": 96.42, "end": 96.56, "word": " عن", "probability": 0.99658203125}, {"start": 96.56, "end": 97.14, "word": " نيتروجين", "probability": 0.8828125}], "temperature": 1.0}, {"id": 5, "seek": 12077, "start": 98.11, "end": 120.77, "text": "ايش اللي بيحصل في طريقة كلدال لتعيين ال nitrogen؟ ايش اللي بيحصل بالظبط؟ بنقول عادة ال nitrogen في العينات المختلفة ممكن على هيئة ال protein او ما شابه هذا عبارة عن organic nitrogen هذا عبارة عن organic nitrogen ال nitrogen موجود ضمن مركب عضوي", "tokens": [47302, 8592, 13672, 1829, 4724, 1829, 5016, 36520, 8978, 23032, 16572, 28671, 28242, 3215, 6027, 5296, 2655, 3615, 1829, 9957, 2423, 17903, 22807, 1975, 1829, 8592, 13672, 1829, 4724, 1829, 5016, 36520, 20666, 19913, 3555, 9566, 22807, 44945, 39648, 6225, 18513, 3660, 2423, 17903, 8978, 18863, 1829, 8315, 2655, 9673, 46456, 46538, 3660, 3714, 43020, 15844, 39896, 19986, 3660, 2423, 7944, 1975, 2407, 19446, 13412, 16758, 3224, 23758, 6225, 3555, 9640, 3660, 18871, 10220, 17903, 23758, 6225, 3555, 9640, 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"word": " على", "probability": 0.89306640625}, {"start": 111.43, "end": 111.77, "word": " هيئة", "probability": 0.9254557291666666}, {"start": 111.77, "end": 111.87, "word": " ال", "probability": 0.59814453125}, {"start": 111.87, "end": 112.19, "word": " protein", "probability": 0.8544921875}, {"start": 112.19, "end": 112.49, "word": " او", "probability": 0.844970703125}, {"start": 112.49, "end": 112.59, "word": " ما", "probability": 0.88818359375}, {"start": 112.59, "end": 113.15, "word": " شابه", "probability": 0.87646484375}, {"start": 113.15, "end": 113.69, "word": " هذا", "probability": 0.48193359375}, {"start": 113.69, "end": 114.03, "word": " عبارة", "probability": 0.99609375}, {"start": 114.03, "end": 114.21, "word": " عن", "probability": 0.9970703125}, {"start": 114.21, "end": 114.63, "word": " organic", "probability": 0.9228515625}, {"start": 114.63, "end": 115.75, "word": " nitrogen", "probability": 0.9853515625}, {"start": 115.75, "end": 116.01, "word": " هذا", "probability": 0.289794921875}, {"start": 116.01, "end": 116.51, "word": " عبارة", "probability": 0.9962158203125}, {"start": 116.51, "end": 116.81, "word": " عن", "probability": 0.99658203125}, {"start": 116.81, "end": 117.61, "word": " organic", "probability": 0.94775390625}, {"start": 117.61, "end": 118.29, "word": " nitrogen", "probability": 0.9912109375}, {"start": 118.29, "end": 118.63, "word": " ال", "probability": 0.37255859375}, {"start": 118.63, "end": 119.05, "word": " nitrogen", "probability": 0.98876953125}, {"start": 119.05, "end": 119.57, "word": " موجود", "probability": 0.9837239583333334}, {"start": 119.57, "end": 119.83, "word": " ضمن", "probability": 0.943359375}, {"start": 119.83, "end": 120.35, "word": " مركب", "probability": 0.7906901041666666}, {"start": 120.35, "end": 120.77, "word": " عضوي", "probability": 0.92724609375}], "temperature": 1.0}, {"id": 6, "seek": 13959, "start": 122.31, "end": 139.59, "text": "كيف بدنا نقدره؟ بنقول في البداية حسب طريقة كل بال بنعمل digestion للعينة هضم للعينة كيف هذا الكلام بيتم؟ بيتم عن طريق إضافة concentrated sulfuric acid والتسخين", "tokens": [4117, 33911, 47525, 8315, 8717, 28543, 2288, 3224, 22807, 44945, 39648, 8978, 29739, 28259, 10632, 11331, 35457, 23032, 16572, 28671, 28242, 20666, 44945, 25957, 1211, 40560, 24976, 3615, 9957, 3660, 8032, 11242, 2304, 24976, 3615, 9957, 3660, 9122, 33911, 23758, 2423, 28820, 10943, 4724, 36081, 2304, 22807, 4724, 36081, 2304, 18871, 23032, 16572, 4587, 11933, 11242, 31845, 3660, 21321, 33831, 299, 8258, 16070, 2655, 3794, 9778, 9957], "avg_logprob": -0.16567095895023906, "compression_ratio": 1.446927374301676, "no_speech_prob": 0.0, "words": [{"start": 122.31, "end": 122.75, "word": "كيف", "probability": 0.8623046875}, {"start": 122.75, "end": 123.27, "word": " بدنا", "probability": 0.900146484375}, {"start": 123.27, "end": 125.87, "word": " نقدره؟", "probability": 0.8259765625}, {"start": 125.87, "end": 126.27, "word": " بنقول", "probability": 0.6767578125}, 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"text": "وجود الـ Sulphuric Acid المركز مع التسخين هذا كله بيكسر العينة و بيحولها لحجم نقولها Ammonium Hydrogen Sulphate او Inorganic Nitrogen Ammonium Hydrogen Sulphate او الميتروجين الآن صار Inorganic Nitrogen يبقى من الخطوة الأولى واضح انه", "tokens": [29245, 23328, 2423, 39184, 35897, 950, 374, 299, 5097, 327, 9673, 31747, 11622, 20449, 16712, 3794, 9778, 9957, 23758, 28242, 3224, 4724, 1829, 4117, 3794, 2288, 18863, 9957, 3660, 4032, 4724, 1829, 5016, 12610, 11296, 5296, 5016, 7435, 2304, 8717, 39648, 11296, 2012, 3317, 2197, 24231, 7747, 35897, 950, 473, 1975, 2407, 682, 12372, 299, 37942, 7747, 2012, 3317, 2197, 24231, 7747, 35897, 950, 473, 1975, 2407, 9673, 36081, 2288, 29245, 9957, 6024, 48506, 20328, 9640, 682, 12372, 299, 37942, 7747, 7251, 3555, 4587, 7578, 9154, 33962, 9566, 2407, 3660, 16247, 12610, 7578, 4032, 46958, 5016, 16472, 3224], "avg_logprob": -0.20249368987902247, "compression_ratio": 1.6310679611650485, "no_speech_prob": 1.1920928955078125e-07, "words": [{"start": 140.5, "end": 141.24, "word": "وجود", "probability": 0.6580810546875}, {"start": 141.24, "end": 141.62, "word": " الـ", "probability": 0.68310546875}, {"start": 141.62, "end": 142.02, "word": " Sulphuric", "probability": 0.760009765625}, {"start": 142.02, "end": 142.26, "word": " Acid", "probability": 0.821044921875}, {"start": 142.26, "end": 142.8, "word": " المركز", "probability": 0.9757486979166666}, {"start": 142.8, "end": 143.0, "word": " مع", "probability": 0.9853515625}, {"start": 143.0, "end": 143.76, "word": " التسخين", "probability": 0.9881591796875}, {"start": 143.76, "end": 144.52, "word": " هذا", "probability": 0.63134765625}, {"start": 144.52, "end": 144.8, "word": " كله", "probability": 0.752685546875}, {"start": 144.8, "end": 146.04, "word": " بيكسر", "probability": 0.91904296875}, {"start": 146.04, "end": 146.7, "word": " العينة", "probability": 0.89892578125}, {"start": 146.7, "end": 146.76, "word": " و", "probability": 0.81640625}, {"start": 146.76, "end": 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"temperature": 1.0}, {"id": 8, "seek": 17383, "start": 166.23, "end": 173.83, "text": "إضافة كمية من الـ H2SO4 المركز والتسخين راح تكسر العينة واتحولها للأمونيوم هيدروجين صلفيت", "tokens": [28814, 11242, 31845, 3660, 9122, 2304, 10632, 9154, 2423, 39184, 389, 17, 17188, 19, 9673, 31747, 11622, 16070, 2655, 3794, 9778, 9957, 12602, 39319, 6055, 4117, 3794, 2288, 18863, 9957, 3660, 4032, 9307, 5016, 12610, 11296, 24976, 10721, 2304, 11536, 1829, 20498, 8032, 25708, 2288, 29245, 9957, 20328, 46538, 36081], "avg_logprob": -0.16789215744710437, "compression_ratio": 1.2903225806451613, "no_speech_prob": 0.0, "words": [{"start": 166.23, "end": 166.89, "word": "إضافة", "probability": 0.8978271484375}, {"start": 166.89, "end": 167.35, "word": " كمية", "probability": 0.9931640625}, {"start": 167.35, "end": 167.49, "word": " من", "probability": 0.92529296875}, {"start": 167.49, "end": 167.65, "word": " الـ", "probability": 0.896484375}, {"start": 167.65, "end": 168.77, "word": " H2SO4", 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يساوي ملي مول HCl وانتهت المسألة اذا حتى من ناحية حسابات اسهل كتير من ايه من الكلبال method الأصلي حتى من ناحية حسابات اسهل كتير من كلبال method الأصلي نيجي طيب نطلع", "tokens": [4117, 45865, 3794, 6156, 3555, 2655, 5016, 12610, 10874, 11622, 38207, 9154, 3224, 11331, 35457, 9122, 2304, 10632, 16247, 2304, 11536, 3660, 39894, 5016, 12610, 24976, 3555, 13063, 36081, 29739, 13063, 36081, 37279, 1829, 13546, 11296, 20666, 389, 9966, 9673, 20292, 3714, 12610, 3714, 36081, 2288, 29245, 9957, 7251, 3794, 995, 45865, 3714, 20292, 3714, 12610, 389, 9966, 4032, 7649, 47395, 2655, 9673, 3794, 10721, 37977, 1975, 15730, 11331, 49975, 9154, 8717, 39319, 10632, 11331, 3794, 16758, 9307, 24525, 3224, 1211, 9122, 2655, 13546, 9154, 1975, 1829, 3224, 9154, 2423, 28820, 3555, 6027, 3170, 16247, 9381, 20292, 11331, 49975, 9154, 8717, 39319, 10632, 11331, 3794, 16758, 9307, 24525, 3224, 1211, 9122, 2655, 13546, 9154, 28242, 3555, 6027, 3170, 16247, 9381, 20292, 8717, 1829, 7435, 1829, 23032, 1829, 3555, 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"word": " method", "probability": 0.701171875}, {"start": 1184.43, "end": 1185.09, "word": " الأصلي", "probability": 0.6188151041666666}, {"start": 1185.09, "end": 1186.09, "word": " حتى", "probability": 0.758544921875}, {"start": 1186.09, "end": 1186.25, "word": " من", "probability": 0.97998046875}, {"start": 1186.25, "end": 1186.49, "word": " ناحية", "probability": 0.9850260416666666}, {"start": 1186.49, "end": 1187.07, "word": " حسابات", "probability": 0.9403076171875}, {"start": 1187.07, "end": 1187.77, "word": " اسهل", "probability": 0.8551432291666666}, {"start": 1187.77, "end": 1188.13, "word": " كتير", "probability": 0.9816080729166666}, {"start": 1188.13, "end": 1188.31, "word": " من", "probability": 0.9853515625}, {"start": 1188.31, "end": 1188.81, "word": " كلبال", "probability": 0.84521484375}, {"start": 1188.81, "end": 1189.19, "word": " method", "probability": 0.97119140625}, {"start": 1189.19, "end": 1189.81, "word": " الأصلي", "probability": 0.9187825520833334}, {"start": 1189.81, "end": 1190.73, "word": " نيجي", "probability": 0.8707275390625}, {"start": 1190.73, "end": 1191.03, "word": " طيب", "probability": 0.9054361979166666}, {"start": 1191.03, "end": 1191.67, "word": " نطلع", "probability": 0.91943359375}], "temperature": 1.0}, {"id": 53, "seek": 121585, "start": 1193.42, "end": 1215.86, "text": "على هذا المثال ونشوف كيف بنطبق هذا الكلام من ناحية عملية بنقول a 0.3 gram feed sample feed sample يعني علف أكل الإنسان بنقوله food أكل الحيوان بنقوله feed يبقى a 0.3 gram feed sample is analyzed for its protein content", "tokens": [3615, 23942, 23758, 9673, 12984, 6027, 4032, 1863, 8592, 38688, 9122, 33911, 44945, 9566, 3555, 4587, 23758, 2423, 28820, 10943, 9154, 8717, 39319, 10632, 6225, 42213, 10632, 44945, 39648, 257, 1958, 13, 18, 21353, 3154, 6889, 3154, 6889, 37495, 22653, 6225, 46538, 5551, 28820, 33688, 1863, 3794, 7649, 44945, 39648, 3224, 1755, 5551, 28820, 21542, 1829, 2407, 7649, 44945, 39648, 3224, 3154, 7251, 3555, 4587, 7578, 257, 1958, 13, 18, 21353, 3154, 6889, 307, 28181, 337, 1080, 7944, 2701], "avg_logprob": -0.14999999273568393, "compression_ratio": 1.6595744680851063, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 1193.42, "end": 1193.86, "word": "على", "probability": 0.7783203125}, {"start": 1193.86, "end": 1194.1, "word": " هذا", "probability": 0.383544921875}, {"start": 1194.1, "end": 1195.38, "word": " المثال", "probability": 0.970703125}, {"start": 1195.38, "end": 1195.8, "word": " ونشوف", "probability": 0.7498779296875}, {"start": 1195.8, "end": 1196.08, "word": " كيف", "probability": 0.96923828125}, {"start": 1196.08, "end": 1196.78, "word": " بنطبق", "probability": 0.9500732421875}, {"start": 1196.78, "end": 1197.08, "word": " هذا", "probability": 0.9384765625}, {"start": 1197.08, "end": 1197.56, "word": " الكلام", "probability": 0.9324544270833334}, {"start": 1197.56, "end": 1197.7, "word": " من", "probability": 0.9716796875}, {"start": 1197.7, "end": 1197.98, "word": " ناحية", "probability": 0.9739583333333334}, {"start": 1197.98, "end": 1198.52, "word": " عملية", "probability": 0.9303385416666666}, {"start": 1198.52, "end": 1199.66, "word": " بنقول", "probability": 0.79541015625}, {"start": 1199.66, "end": 1200.12, "word": " a", "probability": 0.53857421875}, {"start": 1200.12, "end": 1200.4, "word": " 0", "probability": 0.333251953125}, {"start": 1200.4, "end": 1200.84, "word": ".3", "probability": 0.990966796875}, {"start": 1200.84, "end": 1201.3, "word": " gram", "probability": 0.7314453125}, {"start": 1201.3, "end": 1201.78, "word": " feed", "probability": 0.9423828125}, {"start": 1201.78, "end": 1202.6, "word": " sample", "probability": 0.86865234375}, {"start": 1202.6, "end": 1203.1, "word": " feed", "probability": 0.360595703125}, {"start": 1203.1, "end": 1203.52, "word": " sample", "probability": 0.87158203125}, {"start": 1203.52, "end": 1203.86, "word": " يعني", "probability": 0.969482421875}, {"start": 1203.86, "end": 1204.26, "word": " علف", "probability": 0.744384765625}, {"start": 1204.26, "end": 1205.22, "word": " أكل", "probability": 0.81640625}, {"start": 1205.22, "end": 1205.74, "word": " الإنسان", "probability": 0.9931640625}, {"start": 1205.74, "end": 1206.18, "word": " بنقوله", "probability": 0.87255859375}, {"start": 1206.18, "end": 1206.6, "word": " food", "probability": 0.9638671875}, {"start": 1206.6, "end": 1207.48, "word": " أكل", "probability": 0.866455078125}, {"start": 1207.48, "end": 1207.94, "word": " الحيوان", "probability": 0.9716796875}, {"start": 1207.94, "end": 1208.66, "word": " بنقوله", "probability": 0.7898763020833334}, {"start": 1208.66, "end": 1209.42, "word": " feed", "probability": 0.96484375}, {"start": 1209.42, "end": 1210.46, "word": " يبقى", "probability": 0.9349365234375}, {"start": 1210.46, "end": 1210.68, "word": " a", "probability": 0.9267578125}, {"start": 1210.68, "end": 1210.9, "word": " 0", "probability": 0.8779296875}, {"start": 1210.9, "end": 1211.26, "word": ".3", "probability": 0.998046875}, {"start": 1211.26, "end": 1211.62, "word": " gram", "probability": 0.93896484375}, {"start": 1211.62, "end": 1211.96, "word": " feed", "probability": 0.89111328125}, {"start": 1211.96, "end": 1212.58, "word": " sample", "probability": 0.86572265625}, {"start": 1212.58, "end": 1213.24, "word": " is", "probability": 0.96826171875}, {"start": 1213.24, "end": 1214.0, "word": " analyzed", "probability": 0.77392578125}, {"start": 1214.0, "end": 1214.34, "word": " for", "probability": 0.97216796875}, {"start": 1214.34, "end": 1214.64, "word": " its", "probability": 0.80712890625}, {"start": 1214.64, "end": 1215.08, "word": " protein", "probability": 0.94384765625}, {"start": 1215.08, "end": 1215.86, "word": " content", "probability": 0.96484375}], "temperature": 1.0}, {"id": 54, "seek": 124041, "start": 1216.35, "end": 1240.41, "text": "by the modified Keldal method ماشرحليش عنها حاجة قاللي بس إيه ال modified Keldal method لازم تعرف أنت أنه في ال modified Keldal method هذه الخطوات اللي بتحصل و ال millimol نيتروجين يساوي و millimol HCl لازم تكون فاهم هذا الكلام فإيش بيقول؟ بيقول if 25 ml of 0.1 molar HCl is required for the titration", "tokens": [2322, 264, 15873, 591, 5957, 304, 3170, 19446, 46309, 5016, 20292, 8592, 18871, 11296, 11331, 26108, 3660, 50239, 20292, 4724, 3794, 11933, 1829, 3224, 2423, 15873, 591, 5957, 304, 3170, 5296, 31377, 2304, 37279, 28480, 14739, 2655, 14739, 3224, 8978, 2423, 15873, 591, 5957, 304, 3170, 29538, 33962, 9566, 2407, 9307, 13672, 1829, 39894, 5016, 36520, 4032, 2423, 1728, 332, 401, 8717, 36081, 2288, 29245, 9957, 7251, 3794, 995, 45865, 4032, 1728, 332, 401, 389, 9966, 5296, 31377, 2304, 6055, 30544, 6156, 995, 16095, 23758, 2423, 28820, 10943, 6156, 28814, 1829, 8592, 4724, 1829, 39648, 22807, 4724, 1829, 39648, 498, 3552, 23271, 295, 1958, 13, 16, 45712, 389, 9966, 307, 4739, 337, 264, 3459, 2405], "avg_logprob": -0.24259159534141936, "compression_ratio": 1.6303501945525292, "no_speech_prob": 4.172325134277344e-07, "words": [{"start": 1216.35, "end": 1216.63, "word": "by", "probability": 0.041778564453125}, {"start": 1216.63, "end": 1216.99, "word": " the", "probability": 0.71875}, {"start": 1216.99, "end": 1217.73, "word": " modified", "probability": 0.68310546875}, {"start": 1217.73, "end": 1218.29, "word": " Keldal", "probability": 0.4205729166666667}, {"start": 1218.29, "end": 1218.71, "word": " method", "probability": 0.8408203125}, {"start": 1218.71, "end": 1219.97, "word": " ماشرحليش", "probability": 0.771044921875}, {"start": 1219.97, "end": 1220.21, "word": " عنها", "probability": 0.9541015625}, {"start": 1220.21, "end": 1220.63, "word": " حاجة", "probability": 0.9943033854166666}, {"start": 1220.63, "end": 1221.37, "word": " قاللي", "probability": 0.689697265625}, {"start": 1221.37, "end": 1221.61, "word": " بس", "probability": 0.971923828125}, {"start": 1221.61, "end": 1221.97, "word": " إيه", "probability": 0.784912109375}, {"start": 1221.97, "end": 1222.33, "word": " ال", "probability": 0.6025390625}, {"start": 1222.33, "end": 1222.79, "word": " modified", "probability": 0.6650390625}, {"start": 1222.79, "end": 1223.23, "word": " Keldal", "probability": 0.8776041666666666}, {"start": 1223.23, "end": 1223.39, "word": " method", "probability": 0.97607421875}, {"start": 1223.39, "end": 1223.65, "word": " لازم", "probability": 0.96923828125}, {"start": 1223.65, "end": 1224.03, "word": " تعرف", "probability": 0.945068359375}, {"start": 1224.03, "end": 1224.33, "word": " أنت", "probability": 0.6962890625}, {"start": 1224.33, "end": 1224.53, "word": " أنه", "probability": 0.580078125}, {"start": 1224.53, "end": 1224.57, "word": " في", "probability": 0.86279296875}, {"start": 1224.57, "end": 1224.67, "word": " ال", "probability": 0.5908203125}, {"start": 1224.67, "end": 1224.95, "word": " modified", "probability": 0.88134765625}, {"start": 1224.95, "end": 1225.47, "word": " Keldal", "probability": 0.94677734375}, {"start": 1225.47, "end": 1225.79, "word": " method", "probability": 0.9892578125}, {"start": 1225.79, "end": 1226.39, "word": " هذه", "probability": 0.3466796875}, {"start": 1226.39, "end": 1226.85, "word": " الخطوات", "probability": 0.979248046875}, {"start": 1226.85, "end": 1226.97, "word": " اللي", "probability": 0.96533203125}, {"start": 1226.97, "end": 1227.49, "word": " بتحصل", "probability": 0.9739583333333334}, {"start": 1227.49, "end": 1227.83, "word": " و", "probability": 0.6083984375}, {"start": 1227.83, "end": 1227.93, "word": " ال", "probability": 0.611328125}, {"start": 1227.93, "end": 1228.37, "word": " millimol", "probability": 0.6442057291666666}, {"start": 1228.37, "end": 1228.91, "word": " نيتروجين", "probability": 0.81162109375}, {"start": 1228.91, "end": 1229.17, "word": " يساوي", "probability": 0.822021484375}, {"start": 1229.17, "end": 1229.35, "word": " و", "probability": 0.470458984375}, {"start": 1229.35, "end": 1229.59, "word": " millimol", "probability": 0.9435221354166666}, {"start": 1229.59, "end": 1230.17, "word": " HCl", "probability": 0.698486328125}, {"start": 1230.17, "end": 1230.71, "word": " لازم", "probability": 0.9825846354166666}, {"start": 1230.71, "end": 1230.97, "word": " تكون", "probability": 0.98779296875}, {"start": 1230.97, "end": 1231.27, "word": " فاهم", "probability": 0.9757486979166666}, {"start": 1231.27, "end": 1231.47, "word": " هذا", "probability": 0.94775390625}, {"start": 1231.47, "end": 1232.27, "word": " الكلام", "probability": 0.9602864583333334}, {"start": 1232.27, "end": 1234.45, "word": " فإيش", "probability": 0.8204345703125}, {"start": 1234.45, "end": 1234.83, "word": " بيقول؟", "probability": 0.808349609375}, {"start": 1234.83, "end": 1235.09, "word": " بيقول", "probability": 0.9637044270833334}, {"start": 1235.09, "end": 1235.45, "word": " if", "probability": 0.60986328125}, {"start": 1235.45, "end": 1236.41, "word": " 25", "probability": 0.84228515625}, {"start": 1236.41, "end": 1236.79, "word": " ml", "probability": 0.302978515625}, {"start": 1236.79, "end": 1237.01, "word": " of", "probability": 0.955078125}, {"start": 1237.01, "end": 1237.21, "word": " 0", "probability": 0.86328125}, {"start": 1237.21, "end": 1237.49, "word": ".1", "probability": 0.9931640625}, {"start": 1237.49, "end": 1237.81, "word": " molar", "probability": 0.8828125}, {"start": 1237.81, "end": 1238.57, "word": " HCl", "probability": 0.904052734375}, {"start": 1238.57, "end": 1238.85, "word": " is", "probability": 0.966796875}, {"start": 1238.85, "end": 1239.27, "word": " required", "probability": 0.85693359375}, {"start": 1239.27, "end": 1239.63, "word": " for", "probability": 0.97216796875}, {"start": 1239.63, "end": 1239.79, "word": " the", "probability": 0.75146484375}, {"start": 1239.79, "end": 1240.41, "word": " titration", "probability": 0.98486328125}], "temperature": 1.0}, {"id": 55, "seek": 125428, "start": 1241.26, "end": 1254.28, "text": "لو ان احنا بنحتاج 25 مل من 0.1 مولر HCL للـ titration للمعايرة بسأل what is the percent protein content of the sample؟ جداش نسبة البروتين في العالم؟", "tokens": [1211, 2407, 16472, 1975, 5016, 8315, 44945, 33753, 26108, 3552, 3714, 1211, 9154, 1958, 13, 16, 3714, 12610, 2288, 389, 22458, 24976, 39184, 3459, 2405, 5296, 19528, 3615, 995, 48923, 4724, 3794, 10721, 1211, 437, 307, 264, 3043, 7944, 2701, 295, 264, 6889, 22807, 10874, 3215, 33599, 8717, 35457, 3660, 2423, 26890, 35473, 9957, 8978, 18863, 45340, 22807], "avg_logprob": -0.29475635795269983, "compression_ratio": 1.2126436781609196, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 1241.26, "end": 1241.66, "word": "لو", "probability": 0.6881103515625}, {"start": 1241.66, "end": 1241.84, "word": " ان", "probability": 0.382568359375}, {"start": 1241.84, "end": 1242.12, "word": " احنا", "probability": 0.8427734375}, {"start": 1242.12, "end": 1242.7, "word": " بنحتاج", "probability": 0.8390299479166666}, {"start": 1242.7, "end": 1243.38, "word": " 25", "probability": 0.8642578125}, {"start": 1243.38, "end": 1243.84, "word": " مل", "probability": 0.5966796875}, {"start": 1243.84, "end": 1243.96, "word": " من", "probability": 0.9755859375}, {"start": 1243.96, "end": 1244.18, "word": " 0", "probability": 0.434814453125}, {"start": 1244.18, "end": 1244.48, "word": ".1", "probability": 0.98876953125}, {"start": 1244.48, "end": 1244.98, "word": " مولر", "probability": 0.76611328125}, {"start": 1244.98, "end": 1246.32, "word": " HCL", "probability": 0.494384765625}, {"start": 1246.32, "end": 1246.68, "word": " للـ", "probability": 0.37176513671875}, {"start": 1246.68, "end": 1247.16, "word": " titration", "probability": 0.775390625}, {"start": 1247.16, "end": 1247.88, "word": " للمعايرة", "probability": 0.780908203125}, {"start": 1247.88, "end": 1248.7, "word": " بسأل", "probability": 0.818603515625}, {"start": 1248.7, "end": 1249.16, "word": " what", "probability": 0.58056640625}, {"start": 1249.16, "end": 1249.36, "word": " is", "probability": 0.9326171875}, {"start": 1249.36, "end": 1249.54, "word": " the", "probability": 0.81103515625}, {"start": 1249.54, "end": 1249.9, "word": " percent", "probability": 0.67822265625}, {"start": 1249.9, "end": 1250.38, "word": " protein", "probability": 0.57861328125}, {"start": 1250.38, "end": 1251.2, "word": " content", "probability": 0.970703125}, {"start": 1251.2, "end": 1251.5, "word": " of", "probability": 0.96337890625}, {"start": 1251.5, "end": 1251.7, "word": " the", "probability": 0.82958984375}, {"start": 1251.7, "end": 1252.44, "word": " sample؟", "probability": 0.737060546875}, {"start": 1252.44, "end": 1252.74, "word": " جداش", "probability": 0.6580403645833334}, {"start": 1252.74, "end": 1253.12, "word": " نسبة", "probability": 0.9850260416666666}, {"start": 1253.12, "end": 1253.6, "word": " البروتين", "probability": 0.9254150390625}, {"start": 1253.6, "end": 1253.74, "word": " في", "probability": 0.8857421875}, {"start": 1253.74, "end": 1254.28, "word": " العالم؟", "probability": 0.9850260416666666}], "temperature": 1.0}, {"id": 56, "seek": 127457, "start": 1255.45, "end": 1274.57, "text": "مع العلم بيعطيك جوس بيقولك ال milligram protein إذا كان لك تحسبه بساوي ستة وربع في ال milligram نيتروجين، يعني لو حسبت ال milligram نيتروجين أضربه في ستة وربع بيعطيك إيه؟ milligram protein، الستة وربع هادي factor ل .. ل proteins عامة اللي موجودة في العلاف", "tokens": [2304, 3615, 18863, 19528, 4724, 40228, 9566, 1829, 4117, 10874, 41779, 4724, 1829, 39648, 4117, 2423, 38298, 7944, 11933, 15730, 25961, 5296, 4117, 6055, 5016, 35457, 3224, 4724, 3794, 995, 45865, 8608, 2655, 3660, 4032, 25513, 3615, 8978, 2423, 38298, 8717, 36081, 2288, 29245, 9957, 12399, 37495, 22653, 45164, 11331, 35457, 2655, 2423, 38298, 8717, 36081, 2288, 29245, 9957, 5551, 11242, 25513, 3224, 8978, 8608, 2655, 3660, 4032, 25513, 3615, 4724, 40228, 9566, 1829, 4117, 11933, 1829, 3224, 22807, 38298, 7944, 12399, 21136, 2655, 3660, 4032, 25513, 3615, 8032, 995, 16254, 5952, 5296, 4386, 5296, 15577, 6225, 10943, 3660, 13672, 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"word": " steric", "probability": 0.6611328125}, {"start": 2643.1, "end": 2643.52, "word": " effects", "probability": 0.931640625}, {"start": 2643.52, "end": 2643.74, "word": " اللي", "probability": 0.909912109375}, {"start": 2643.74, "end": 2644.1, "word": " هي", "probability": 0.86328125}, {"start": 2644.1, "end": 2644.76, "word": " يعني", "probability": 0.921630859375}, {"start": 2644.76, "end": 2645.08, "word": " هل", "probability": 0.98291015625}, {"start": 2645.08, "end": 2645.2, "word": " في", "probability": 0.96875}, {"start": 2645.2, "end": 2646.0, "word": " ممانعة", "probability": 0.9521484375}, {"start": 2646.0, "end": 2646.4, "word": " في", "probability": 0.96435546875}, {"start": 2646.4, "end": 2646.94, "word": " تكوين", "probability": 0.971435546875}, {"start": 2646.94, "end": 2647.46, "word": " الرابط", "probability": 0.9435221354166666}, {"start": 2647.46, "end": 2647.78, "word": " ولا", "probability": 0.88525390625}, {"start": 2647.78, "end": 2648.1, "word": " لأ", "probability": 0.935302734375}], "temperature": 1.0}, {"id": 114, "seek": 266773, "start": 2650.63, "end": 2667.73, "text": "ممانعة فراغية هل في ممانعة ولا لأ يعني ال metal ion حوالي groups بتمنع ال legal من إنه يكون رابطة يعني أو بيكونها بصعوبة مش مناجي وسع كافي يكون الرابطة هذا الكلام برضه بيأثر على", "tokens": [2304, 2304, 7649, 27884, 6156, 2288, 5718, 118, 10632, 8032, 1211, 8978, 3714, 2304, 7649, 27884, 49429, 5296, 10721, 37495, 22653, 2423, 5760, 17437, 11331, 2407, 6027, 1829, 3935, 39894, 27842, 3615, 2423, 5089, 9154, 36145, 3224, 7251, 30544, 12602, 16758, 9566, 3660, 37495, 22653, 34051, 4724, 1829, 30544, 11296, 4724, 9381, 3615, 37746, 3660, 37893, 3714, 8315, 7435, 1829, 46952, 3615, 9122, 31845, 1829, 7251, 30544, 34892, 16758, 9566, 3660, 23758, 2423, 28820, 10943, 4724, 43042, 3224, 4724, 1829, 10721, 49115, 15844], "avg_logprob": -0.2585565529408909, "compression_ratio": 1.618279569892473, "no_speech_prob": 1.8537044525146484e-05, "words": [{"start": 2650.6299999999997, "end": 2651.43, "word": "ممانعة", "probability": 0.63134765625}, {"start": 2651.43, "end": 2652.09, "word": " فراغية", "probability": 0.989453125}, {"start": 2652.09, "end": 2653.03, "word": " هل", "probability": 0.5712890625}, {"start": 2653.03, "end": 2653.15, "word": " في", "probability": 0.8701171875}, {"start": 2653.15, "end": 2653.77, "word": " ممانعة", "probability": 0.9434814453125}, {"start": 2653.77, "end": 2654.07, "word": " ولا", "probability": 0.79541015625}, {"start": 2654.07, "end": 2654.33, "word": " لأ", "probability": 0.83349609375}, {"start": 2654.33, "end": 2654.97, "word": " يعني", "probability": 0.568603515625}, {"start": 2654.97, "end": 2655.63, "word": " ال", "probability": 0.6689453125}, {"start": 2655.63, "end": 2655.91, "word": " metal", "probability": 0.54833984375}, {"start": 2655.91, "end": 2656.45, "word": " ion", "probability": 0.65771484375}, {"start": 2656.45, "end": 2657.47, "word": " حوالي", "probability": 0.935302734375}, {"start": 2657.47, "end": 2657.87, "word": " groups", "probability": 0.53955078125}, {"start": 2657.87, "end": 2658.81, "word": " بتمنع", "probability": 0.9254557291666666}, {"start": 2658.81, "end": 2659.57, "word": " ال", "probability": 0.79443359375}, {"start": 2659.57, "end": 2659.89, "word": " legal", "probability": 0.7998046875}, {"start": 2659.89, "end": 2660.09, "word": " من", "probability": 0.943359375}, {"start": 2660.09, "end": 2660.41, "word": " إنه", "probability": 0.6202392578125}, {"start": 2660.41, "end": 2660.65, "word": " يكون", "probability": 0.91064453125}, {"start": 2660.65, "end": 2661.49, "word": " رابطة", "probability": 0.8974609375}, {"start": 2661.49, "end": 2661.83, "word": " يعني", "probability": 0.57421875}, {"start": 2661.83, "end": 2662.37, "word": " أو", "probability": 0.63330078125}, {"start": 2662.37, "end": 2662.87, "word": " بيكونها", "probability": 0.9193115234375}, {"start": 2662.87, "end": 2663.59, "word": " بصعوبة", "probability": 0.826904296875}, {"start": 2663.59, "end": 2663.91, "word": " مش", "probability": 0.9130859375}, {"start": 2663.91, "end": 2664.29, "word": " مناجي", "probability": 0.4898681640625}, {"start": 2664.29, "end": 2664.61, "word": " وسع", "probability": 0.616943359375}, {"start": 2664.61, "end": 2665.01, "word": " كافي", "probability": 0.927734375}, {"start": 2665.01, "end": 2665.27, "word": " يكون", "probability": 0.942626953125}, {"start": 2665.27, "end": 2665.93, "word": " الرابطة", "probability": 0.8626708984375}, {"start": 2665.93, "end": 2666.39, "word": " هذا", "probability": 0.845703125}, {"start": 2666.39, "end": 2666.73, "word": " الكلام", "probability": 0.8738606770833334}, {"start": 2666.73, "end": 2666.97, "word": " برضه", "probability": 0.9781901041666666}, {"start": 2666.97, "end": 2667.45, "word": " بيأثر", "probability": 0.900634765625}, {"start": 2667.45, "end": 2667.73, "word": " على", "probability": 0.908203125}], "temperature": 1.0}, {"id": 115, "seek": 268265, "start": 2671.41, "end": 2682.65, "text": "هذه هي العوامل الأساسية اللى بتأثر على ثبات ال complex طيب يا شباب احنا اذا الله راضي بنوبة في هذا اليوم والحصة الجاية بنكملها", "tokens": [3224, 24192, 39896, 18863, 2407, 10943, 1211, 16247, 3794, 32277, 10632, 13672, 7578, 39894, 10721, 49115, 15844, 38637, 3555, 9307, 2423, 3997, 23032, 1829, 3555, 35186, 13412, 3555, 16758, 1975, 5016, 8315, 1975, 15730, 21984, 12602, 46958, 1829, 44945, 37746, 3660, 8978, 23758, 45595, 20498, 16070, 5016, 9381, 3660, 25724, 995, 10632, 44945, 24793, 1211, 11296], "avg_logprob": -0.2206688596491228, "compression_ratio": 1.5, "no_speech_prob": 3.55839729309082e-05, "words": [{"start": 2671.41, "end": 2672.27, "word": "هذه", "probability": 0.425567626953125}, {"start": 2672.27, "end": 2672.43, "word": " هي", "probability": 0.33837890625}, {"start": 2672.43, "end": 2672.87, "word": " العوامل", "probability": 0.9217529296875}, {"start": 2672.87, "end": 2673.59, "word": " الأساسية", "probability": 0.951904296875}, {"start": 2673.59, "end": 2674.13, "word": " اللى", "probability": 0.775634765625}, {"start": 2674.13, "end": 2674.69, "word": " بتأثر", "probability": 0.9415690104166666}, {"start": 2674.69, "end": 2675.07, "word": " على", "probability": 0.916015625}, {"start": 2675.07, "end": 2675.93, "word": " ثبات", "probability": 0.9557291666666666}, {"start": 2675.93, "end": 2676.11, "word": " ال", "probability": 0.92626953125}, {"start": 2676.11, "end": 2676.65, "word": " complex", "probability": 0.72705078125}, {"start": 2676.65, "end": 2677.29, "word": " طيب", "probability": 0.8553059895833334}, {"start": 2677.29, "end": 2677.43, "word": " يا", "probability": 0.89111328125}, {"start": 2677.43, "end": 2677.85, "word": " شباب", "probability": 0.9918619791666666}, {"start": 2677.85, "end": 2678.67, "word": " احنا", "probability": 0.9176432291666666}, {"start": 2678.67, "end": 2679.09, "word": " اذا", "probability": 0.796875}, {"start": 2679.09, "end": 2679.29, "word": " الله", "probability": 0.93896484375}, {"start": 2679.29, "end": 2679.57, "word": " راضي", "probability": 0.7275390625}, {"start": 2679.57, "end": 2679.87, "word": " بنوبة", "probability": 0.7379557291666666}, {"start": 2679.87, "end": 2679.99, "word": " في", "probability": 0.80712890625}, {"start": 2679.99, "end": 2680.11, "word": " هذا", "probability": 0.36376953125}, {"start": 2680.11, "end": 2680.47, "word": " اليوم", "probability": 0.9296875}, {"start": 2680.47, "end": 2680.91, "word": " والحصة", "probability": 0.83929443359375}, {"start": 2680.91, "end": 2681.43, "word": " الجاية", "probability": 0.9202473958333334}, {"start": 2681.43, "end": 2682.65, "word": " بنكملها", "probability": 0.9219970703125}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2683.298, "duration_after_vad": 2600.49312499999}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/a2PZpAILMkI_raw.srt b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/a2PZpAILMkI_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..f0bf93cac8de6b4967da19b42bb22addcd0da936
--- /dev/null
+++ b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/a2PZpAILMkI_raw.srt
@@ -0,0 +1,2148 @@
+1
+00:00:21,160 --> 00:00:24,760
+بسم الله الرحمن الرحيم اليوم إذا الله راضى بنتكلم
+
+2
+00:00:24,760 --> 00:00:29,960
+عن آخر جزئية في ال acid-base titrations بنتكلم عن
+
+3
+00:00:29,960 --> 00:00:35,700
+كلدال أناليسيس كلدال أناليسس في الحقيقة بيعالج
+
+4
+00:00:36,430 --> 00:00:40,650
+تقدير كمية ال nitrogen في العينات المختلفة عشان
+
+5
+00:00:40,650 --> 00:00:46,570
+هيك ممكن أنه نسمي كل ده ال analysis بكل ده ال
+
+6
+00:00:46,570 --> 00:00:52,490
+nitrogen analysis ليه؟ لأنه فقط يختص بتقدير كمية
+
+7
+00:00:52,490 --> 00:01:00,510
+ال nitrogen في العينات المختلفة في الحقيقة تقدير
+
+8
+00:01:00,510 --> 00:01:05,990
+ال nitrogen شيء مهم جداليه؟ لأنه كتير من المراكبات
+
+9
+00:01:05,990 --> 00:01:09,950
+المهمة في الحياة العامة بتحتوي على ال nitrogen من
+
+10
+00:01:09,950 --> 00:01:13,940
+أهم هذه المراكبات اللي هو ال proteinالبروتينات
+
+11
+00:01:13,940 --> 00:01:18,240
+طبعا عبارة عن amino acids و ال amino acids بتحتوي
+
+12
+00:01:18,240 --> 00:01:22,140
+على ال amino group او نيتروجين معناه الكلام اذا
+
+13
+00:01:22,140 --> 00:01:26,400
+احنا قدرنا نعين كمية ال nitrogen في اي عينة معناته
+
+14
+00:01:26,400 --> 00:01:30,160
+عينة البروتين معناته ممكن والله نعمل relation ما
+
+15
+00:01:30,160 --> 00:01:33,220
+بين كمية ال nitrogen و البروتين اللى موجود على
+
+16
+00:01:33,220 --> 00:01:39,150
+اساس ان البروتين جزء منه عبارة عن نيتروجينايش اللي
+
+17
+00:01:39,150 --> 00:01:43,390
+بيحصل في طريقة كلدال لتعيين ال nitrogen؟ ايش اللي
+
+18
+00:01:43,390 --> 00:01:48,110
+بيحصل بالظبط؟ بنقول عادة ال nitrogen في العينات
+
+19
+00:01:48,110 --> 00:01:53,690
+المختلفة ممكن على هيئة ال protein او ما شابه هذا
+
+20
+00:01:53,690 --> 00:01:57,610
+عبارة عن organic nitrogen هذا عبارة عن organic
+
+21
+00:01:57,610 --> 00:02:03,270
+nitrogen ال nitrogen موجود ضمن مركب عضويكيف بدنا
+
+22
+00:02:03,270 --> 00:02:09,670
+نقدره؟ بنقول في البداية حسب طريقة كل بال بنعمل
+
+23
+00:02:09,670 --> 00:02:14,410
+digestion للعينة هضم للعينة كيف هذا الكلام بيتم؟
+
+24
+00:02:14,410 --> 00:02:18,770
+بيتم عن طريق إضافة concentrated sulfuric acid
+
+25
+00:02:18,770 --> 00:02:23,760
+والتسخينوجود الـ Sulphuric Acid المركز مع التسخين
+
+26
+00:02:23,760 --> 00:02:29,320
+هذا كله بيكسر العينة و بيحولها لحجم نقولها
+
+27
+00:02:29,320 --> 00:02:34,700
+Ammonium Hydrogen Sulphate او Inorganic Nitrogen
+
+28
+00:02:34,700 --> 00:02:39,920
+Ammonium Hydrogen Sulphate او الميتروجين الآن صار
+
+29
+00:02:39,920 --> 00:02:45,740
+Inorganic Nitrogen يبقى من الخطوة الأولى واضح انه
+
+30
+00:02:46,230 --> 00:02:50,870
+إضافة كمية من الـ H2SO4 المركز والتسخين راح تكسر
+
+31
+00:02:50,870 --> 00:02:55,940
+العينة واتحولها للأمونيوم هيدروجين صلفيتالان موجود
+
+32
+00:02:55,940 --> 00:02:59,300
+عندى زيادة من الـ Sulphuric Acid اللى ما اتفعلش
+
+33
+00:02:59,300 --> 00:03:03,260
+Dial Sulphuric Acid زي ما هو لم يتفعل والأمونيوم
+
+34
+00:03:03,260 --> 00:03:07,340
+هيدرين سالفيت أيضا موجودة فى المحلول فالخطوة
+
+35
+00:03:07,340 --> 00:03:13,080
+التانية تتطلب إضافة Concentrated Sodium Hydroxide
+
+36
+00:03:13,080 --> 00:03:16,300
+عشان يعادل ال acid اللى موجود فى الخطوة الأولى أو
+
+37
+00:03:16,300 --> 00:03:21,400
+الزيادة فى الخطوة الأولى مش بس هيك لأ وكمان يحول
+
+38
+00:03:21,400 --> 00:03:27,280
+الأمونيوم إلى أمونياوجود Hydroxide بيحول ال
+
+39
+00:03:27,280 --> 00:03:34,840
+ammonium إلى أمونيا فهي ال ammonium مع Hydroxide
+
+40
+00:03:34,840 --> 00:03:41,380
+بيعطينا أمونيا وميه فالأمونيا هذه هي عبارة عن ايه؟
+
+41
+00:03:41,380 --> 00:03:46,540
+عبارة عن غاز اذا الخطوة الأولى اعمل advisation
+
+42
+00:03:49,440 --> 00:03:54,260
+أضافنا concentrated sulfuric acid بعد تسخين اتكسرت
+
+43
+00:03:54,260 --> 00:03:59,300
+العينة اتحولت ل ammonium hydrogen sulfate بعد هيك
+
+44
+00:03:59,300 --> 00:04:02,820
+بضيف sodium hydroxide مركز اتفعل مع ال acid
+
+45
+00:04:02,820 --> 00:04:06,660
+الزيادة و اتفعل كمان مع ال ammonium و حولها ل
+
+46
+00:04:06,660 --> 00:04:11,780
+gaseous ammonia الآن الخطوة اللي بعد هيك تيجي هي
+
+47
+00:04:11,780 --> 00:04:18,220
+عملية distillation بدي اسخن هذا المحلول علشانأخلى
+
+48
+00:04:18,220 --> 00:04:23,820
+الأمونيا اللى اتكونت تطلع على هيئة غاز فهذه عملية
+
+49
+00:04:23,820 --> 00:04:29,680
+distillation طيب سخنت علشان أخلى الأمونيا اللى
+
+50
+00:04:29,680 --> 00:04:34,380
+اتكونت في الخطوة التانية تطلع على هيئة غاز طلعت
+
+51
+00:04:34,380 --> 00:04:38,620
+على هيئة غاز وين بقى استقبلها؟ الآن الأمونيا طالعة
+
+52
+00:04:38,620 --> 00:04:45,900
+على هيئة غاز باستقبلها فيمحلول حمض كبريتيك مخفف
+
+53
+00:04:45,900 --> 00:04:52,200
+standard معروف يعني مثلا بستقبلها في خمسين ميل من
+
+54
+00:04:52,200 --> 00:04:58,760
+point one molar H2SO4 الآن الأمونيا عدت لجت في
+
+55
+00:04:58,760 --> 00:05:04,700
+المحلول H2SO4 طبعا اتفاعل معه acid and base فتركيز
+
+56
+00:05:04,700 --> 00:05:11,750
+ال H2SO4 رح يقل لأن جزء منه اتفاعل معالأمونيا أنا
+
+57
+00:05:11,750 --> 00:05:16,190
+باجي الخطوة الأخيرة بعمل معايرة لل H2SO4 هذا ال
+
+58
+00:05:16,190 --> 00:05:19,450
+standard بعمله معايرة بال sodium hydroxide
+
+59
+00:05:19,450 --> 00:05:22,810
+standard sodium hydroxide نتيجة المعايرة بعرف ولا
+
+60
+00:05:22,810 --> 00:05:28,710
+قداش تبقى من ال H2SO4إذا أنا عارف الكمية الكلية
+
+61
+00:05:28,710 --> 00:05:34,590
+عارف كمية التبقى منه إذا كمية الاتفاعل مع الأمونيا
+
+62
+00:05:34,590 --> 00:05:39,210
+بقدر أحسبه وبالتالي بعرف أكمل لمول أمونيا عندي
+
+63
+00:05:39,210 --> 00:05:45,150
+وبالتالي أكمل لمول نيتروجين موجود وكمية النيتروجين
+
+64
+00:05:45,150 --> 00:05:48,850
+ممكن أعمل relation ما بينها وما بين ال protein
+
+65
+00:05:48,850 --> 00:05:51,890
+اللي عندي على سبيل المثال هنشوف هذا كلام بعد شوية
+
+66
+00:05:51,890 --> 00:05:56,900
+إذا الخطوات كتير كتير بسيطةومت السلسلة بشكل منطقي
+
+67
+00:05:56,900 --> 00:06:01,620
+اول خطوة عملية digestion بكسر العينة باستخدام
+
+68
+00:06:01,620 --> 00:06:07,100
+concentrated sulfuric acid مع التسخين بعدين بضيف
+
+69
+00:06:07,100 --> 00:06:11,520
+Sodium hydroxide مركزبعادل السلفوريك أسد الذي
+
+70
+00:06:11,520 --> 00:06:14,600
+زيادة و كمان في عندي كمية كبيرة من ال Sodium
+
+71
+00:06:14,600 --> 00:06:17,820
+Hydroxide الذي زيادة بتتفاعل معاه الأمونيا بتحولها
+
+72
+00:06:17,820 --> 00:06:21,540
+لأمونيا بعمل عملية distillation to drive the
+
+73
+00:06:21,540 --> 00:06:24,900
+ammonia out of the solution باستقبلها في محلول
+
+74
+00:06:24,900 --> 00:06:30,440
+قياسي من السلفوريك أسد كويس تتفاعل معاه جزئيا
+
+75
+00:06:30,440 --> 00:06:33,980
+بعاير السلفوريك أسد الذي زيادة هذا
+
+76
+00:06:37,390 --> 00:06:41,350
+وانا عارف الكمية الكلية اللى موجودة وانا مقدر اعرف
+
+77
+00:06:41,350 --> 00:06:46,430
+جداش اللى اتفاعل مع الامونيا هذه هي فكرة Keldal
+
+78
+00:06:46,430 --> 00:06:47,350
+Analysis
+
+79
+00:06:50,800 --> 00:06:55,240
+انترجم هذا الكلام اللي احنا قولناها لجهة على صيغة
+
+80
+00:06:55,240 --> 00:06:59,760
+مثال و نشوف كيف ممكن نتطلع على حل هذا المثال
+
+81
+00:06:59,760 --> 00:07:05,140
+المثال بيقول a point two gram of a urea sample فيه
+
+82
+00:07:05,140 --> 00:07:08,500
+عندي urea ال urea الفرمولة ويتقلها ستين والرمز
+
+83
+00:07:08,500 --> 00:07:14,380
+تبعها NH2CO
+
+84
+00:07:19,930 --> 00:07:24,090
+التحليل تم عن طريق كيلدال ميثود اللي ذكرناها
+
+85
+00:07:24,090 --> 00:07:28,210
+ايوريا سامبل ايوريا سامبل ايوريا سامبل ايوريا
+
+86
+00:07:28,210 --> 00:07:28,810
+سامبل ايوريا سامبل ايوريا سامبل ايوريا سامبل
+
+87
+00:07:28,810 --> 00:07:28,810
+ايوريا سامبل ايوريا سامبل ايوريا سامبل ايوريا
+
+88
+00:07:28,810 --> 00:07:30,930
+سامبل ايوريا سامبل ايوريا سامبل ايوريا سامبل
+
+89
+00:07:30,930 --> 00:07:36,270
+ايوريا سامبل ايوريا سامبل ايوريا سامبل ايوريا
+
+90
+00:07:36,270 --> 00:07:36,270
+سامبل ايوريا سامبل ايوريا سامبل ايوريا سامبل
+
+91
+00:07:36,270 --> 00:07:36,270
+ايوريا سامبل ايوريا سامبل ايوريا سامبل ايوريا
+
+92
+00:07:36,270 --> 00:07:39,650
+سامبل ايوريا سامبل ايوريا سامبل ايوريا سامبل
+
+93
+00:07:39,650 --> 00:07:43,250
+ايوريا
+
+94
+00:07:43,930 --> 00:07:48,570
+طيب بقول the excess acid ال H2SO4 هذا زاد the
+
+95
+00:07:48,570 --> 00:07:52,950
+excess acid required تلاتة وأربعة من عشرة mil of 0
+
+96
+00:07:52,950 --> 00:07:55,730
+.05 molar sodium hydroxide عيارته بال Sodium
+
+97
+00:07:55,730 --> 00:07:59,490
+Hydroxide فأخد تلاتة وأربعة من عشرة mil الآن
+
+98
+00:07:59,490 --> 00:08:03,130
+السؤال بيقول find the percentage of the compound
+
+99
+00:08:03,130 --> 00:08:09,640
+اللي هو urea in the sampleبقول بس يعني بشكل عام
+
+100
+00:08:09,640 --> 00:08:13,480
+نمشي على الحل بقول انا عندى ال ammonia بتتفاعل مع
+
+101
+00:08:13,480 --> 00:08:16,600
+ال sulfuric acid بتعطينى ammonium hydrogen sulfate
+
+102
+00:08:16,600 --> 00:08:22,600
+طيب ال millimole بتكلم عن ال ammonia اللى تعايرة
+
+103
+00:08:22,600 --> 00:08:27,020
+او اللى اتفاعلت مع ال H2SO4 بقول ال sulfuric acid
+
+104
+00:08:27,020 --> 00:08:32,330
+بتفاعل مع اتنين ammoniaالملي مول سيلفوريك أسد
+
+105
+00:08:32,330 --> 00:08:35,850
+بساوي نص الملي مول أمونيا
+
+106
+00:08:40,710 --> 00:08:44,390
+الـUrea فيها تنتين نيتروجين، اذا بتعطي اتنين
+
+107
+00:08:44,390 --> 00:08:50,510
+أمونيا، صح ولا لأ؟ اذا الـMolUrea نص الملي مول
+
+108
+00:08:50,510 --> 00:08:54,970
+أمونيا، لكن النص الملي مول أمونيا إيش بتساوي؟
+
+109
+00:08:54,970 --> 00:08:58,650
+الملي مول H2SO4، يعني عشان هيك بنقول إحنا الملي
+
+110
+00:08:58,650 --> 00:09:04,170
+مول H2SO4، كويس، القصد إنه بساوي الملي مول يوريا
+
+111
+00:09:05,250 --> 00:09:09,310
+معايا نص ميلي مول أمونيا بتساوي الميلي مول H2SO4
+
+112
+00:09:09,310 --> 00:09:12,950
+وكمان النص ميلي مول يوريا بتساوي الميلي مول أمونيا
+
+113
+00:09:12,950 --> 00:09:15,630
+بتساوي الميلي مول يوريا اذا الميلي مول يوريا
+
+114
+00:09:15,630 --> 00:09:20,390
+بتساوي الميلي مول H2SO4 reacted بنفس الطريقة
+
+115
+00:09:20,390 --> 00:09:23,890
+الميلي مول H2SO4 titrated مع ال sodium hydroxide
+
+116
+00:09:23,890 --> 00:09:28,810
+بساوي نص الميلي مول sodium hydroxide لأن H2SO4
+
+117
+00:09:28,810 --> 00:09:33,090
+زائد اتنين sodium hydroxide يبقى الميلي مول H2SO4
+
+118
+00:09:34,290 --> 00:09:39,030
+بساوي نص الميلي مول صوديوم هيدروكسايد بمعنى اخر
+
+119
+00:09:39,030 --> 00:09:42,550
+ممكن انا اشوف هذا ال scheme اللي قدامي الميلي مول
+
+120
+00:09:42,550 --> 00:09:47,630
+H2SO4 reacted بساوي نص الميلي مول أمونيا والنص
+
+121
+00:09:47,630 --> 00:09:51,530
+الميلي مول أمونيا بساوي الميلي مول يورياالملي مول
+
+122
+00:09:51,530 --> 00:09:54,850
+H2SO4 تيتريت بيساوي نص الملي مول صوديوم هيدروكسايد
+
+123
+00:09:54,850 --> 00:09:58,430
+لو اجيت اعملت هذا الشغل هذا بيقول الملي مول يوريا
+
+124
+00:09:58,430 --> 00:10:02,590
+اذا عوّبت عن هذا بيساوي الملي مول H2SO4 taken
+
+125
+00:10:02,590 --> 00:10:07,170
+عوّبت عنه minus الملي مول H2SO4 تيتريت نص الملي
+
+126
+00:10:07,170 --> 00:10:11,170
+مول صوديوم هيدروكسايد الان بدنا نعوّب بقول الملي
+
+127
+00:10:11,170 --> 00:10:14,470
+مول يوريا point oh five في خمسين هذا هو الملي مول
+
+128
+00:10:14,470 --> 00:10:20,390
+taken- نص في 0.05 في 3 أو 4 من 10 اللي هو ال
+
+129
+00:10:20,390 --> 00:10:23,370
+sodium hydroxide بطلع عندى 2.415
+
+130
+00:10:25,990 --> 00:10:29,390
+إذا الملي جرام يوريا هذا الملي مول يوريا بدي
+
+131
+00:10:29,390 --> 00:10:32,250
+أحولها لملي جرام بدي أضرب في ال formula weight
+
+132
+00:10:32,250 --> 00:10:36,670
+بيطلع عند الملي جرام يوريا مية أربعة وأربعين وتسعة
+
+133
+00:10:36,670 --> 00:10:41,390
+من عشرة إذا ال percentage يوريا في العينة وزن ال
+
+134
+00:10:41,390 --> 00:10:45,910
+يوريا على وزن العينة في مية من مية بتطلع اتنين
+
+135
+00:10:45,910 --> 00:10:52,450
+وسبعين ونص كويس يا شبابيبقى هيك اقدرنا نعين كمية
+
+136
+00:10:52,450 --> 00:10:57,230
+ال nitrogen في عينا ما كمان مرة اللي عملناه لو
+
+137
+00:10:57,230 --> 00:11:02,490
+اطلعنا على المثال اللي عملناه انه عملنا في البداية
+
+138
+00:11:06,460 --> 00:11:11,180
+اتحولت لـ Inorganic Nitrogen أمونيا حطينا عليها
+
+139
+00:11:11,180 --> 00:11:13,920
+Sodium .. ماحكيناش هذا الكلام لأنه معروف هذه كل ده
+
+140
+00:11:13,920 --> 00:11:16,380
+ال method حطينا عليها Sodium Hydroxide يزيد و
+
+141
+00:11:16,380 --> 00:11:20,580
+حولناها لأمونيا الأمونيا اللي طلعت جمعناها في
+
+142
+00:11:20,580 --> 00:11:27,520
+محلول standard H2SO4 50 ml في 0.05 molar كويس ال
+
+143
+00:11:27,520 --> 00:11:31,440
+excess من ال acid أخد تلك و 4 من 10 ml من Sodium
+
+144
+00:11:31,440 --> 00:11:35,760
+Hydroxide لل standard علشان يتعيرمعنى الكلام هذا
+
+145
+00:11:35,760 --> 00:11:40,200
+تطبيق مباشر على الكلام اللي ذكرناه اللي هي طريقة
+
+146
+00:11:40,200 --> 00:11:47,500
+Keldal في التحليل ماشي يا شبابهذه الطريقة كتير
+
+147
+00:11:47,500 --> 00:11:52,700
+مهمة لأنه يعني بشكل أساسي إذا كان بدنا نعين ل
+
+148
+00:11:52,700 --> 00:11:56,540
+proteins اللي موجودة مثلا في الأعلاف في المواد
+
+149
+00:11:56,540 --> 00:11:59,560
+الغذائية المختلفة اللي الإنسان بيتناولها أو
+
+150
+00:11:59,560 --> 00:12:05,260
+الحيوان برضه بيتناولها في الحبوب مثلا بالذات القمح
+
+151
+00:12:05,260 --> 00:12:12,490
+لأنه يعتبر مصدر مهم للتغذية في العالمفلازم احنا
+
+152
+00:12:12,490 --> 00:12:16,610
+بالنسبة لنا نقدر نحلل هذه العينات و نعرف جداش فيها
+
+153
+00:12:16,610 --> 00:12:21,230
+proteins كل دا ال method بتعتبر طريقة ممتازة جدا و
+
+154
+00:12:21,230 --> 00:12:25,990
+مستخدمة عالميا بحيث انه يمكن مئات ألف التحاليل
+
+155
+00:12:25,990 --> 00:12:33,140
+بتتم يوميا بما في ذلك عندنا في غزة مثلافلو في يعني
+
+156
+00:12:33,140 --> 00:12:40,060
+رقابة جيدة على المنتوجات الغذائية كل المنتوجات
+
+157
+00:12:40,060 --> 00:12:46,060
+لازم يتم تحليلها لكمية ال protein اللي فيها لمعرفة
+
+158
+00:12:46,060 --> 00:12:51,500
+مدى يعني الفائدة منها وهل تستحق انه تقدم كغذاء ولا
+
+159
+00:12:51,500 --> 00:12:56,140
+لابرضه الأعلاف اللى بتستخدم في التسمين مثلا و
+
+160
+00:12:56,140 --> 00:13:00,300
+خلافه لو بدنا نستورد أعلاف مثلا فهل هي أعلاف جيدة
+
+161
+00:13:00,300 --> 00:13:04,490
+و لا غير جيدة، نسبة البروتين فيها كتير مهمةأيضا زي
+
+162
+00:13:04,490 --> 00:13:11,370
+ما ذكرت القمح برضه لو مثلا البلد مستور بقى قمح فهل
+
+163
+00:13:11,370 --> 00:13:15,470
+ناخده على عناه خلاص شكله قمح يبجهه مناسب قمح ده هو
+
+164
+00:13:15,470 --> 00:13:20,430
+قمح على طول يؤخذ و يطحن و يستخدم كدقيق ولا يجب
+
+165
+00:13:20,430 --> 00:13:26,270
+دراسته من ناحية يعني القيمة الغذائية له بداية طبعا
+
+166
+00:13:26,270 --> 00:13:29,410
+في بلاد العالم كلها القيمة الغذائية جامل ما ينزل
+
+167
+00:13:29,410 --> 00:13:34,160
+الجمح من الباخرةهو كلكم تسمعوا في مثلا بعض الدول
+
+168
+00:13:34,160 --> 00:13:38,760
+اللي حوالينا كيف عندهم مشاكل في القمح في حاجة غير
+
+169
+00:13:38,760 --> 00:13:41,840
+مغذية نهائيا القمح لا يستخدم .. يعني الأصل أنه لا
+
+170
+00:13:41,840 --> 00:13:47,880
+يستخدم ل .. يعني تغذية الإنسان بعض أنواعه يعني
+
+171
+00:13:47,880 --> 00:13:53,160
+لكنه يباع في دول مثلا من دول العالم الثالث لإنه مش
+
+172
+00:13:53,160 --> 00:13:56,880
+كتير بيهتموا بالتحليل أو في فساد في التحليل يعني
+
+173
+00:13:56,880 --> 00:14:01,380
+على سبيل مثال ممكن إن المختبرات اللي بتحلل ماتكونش
+
+174
+00:14:01,740 --> 00:14:07,360
+مختبرات أمينة وبالتالي بتكون هذه البلاد سوجلة مثل
+
+175
+00:14:07,360 --> 00:14:13,040
+هذه المنتجات فشاهد في الكلام أنه مئات ألاف التحليل
+
+176
+00:14:13,040 --> 00:14:17,580
+يتم إجراءها يوميا على هذا .. باستخدام هذا النوع من
+
+177
+00:14:17,580 --> 00:14:22,900
+أنواع الطرق اللي هي Keldal method لهذا السبب يا
+
+178
+00:14:22,900 --> 00:14:26,560
+شباب كتير من الناس اشتغلت على أنها تبسط طريقة
+
+179
+00:14:26,560 --> 00:14:32,200
+Keldalأما إنها يعني بدها توفر في الوقت أو الجهد أو
+
+180
+00:14:32,200 --> 00:14:36,340
+الفلوس، ليه؟ لأن إذا كان وفرنا في الوقت عشر دقايق
+
+181
+00:14:36,340 --> 00:14:39,520
+من كل تجربة في جول في مئات آلاف التجارب، معنا
+
+182
+00:14:39,520 --> 00:14:42,440
+الكلام وفرنا وقت كتير، إذا كان وفرنا دولار في كل
+
+183
+00:14:42,440 --> 00:14:46,320
+تحليل، في مئات آلاف التحليل يوميا معنا الكلام،
+
+184
+00:14:46,320 --> 00:14:54,100
+وفرنا مبالغ يعني مهمة جدا، إلى آخرهافلاجئنا إنه في
+
+185
+00:14:54,100 --> 00:14:58,960
+ناس كتير اتحدثت عن ال modified كلدال method طريقة
+
+186
+00:14:58,960 --> 00:15:06,040
+كلدال المعدلة إيش هي طريقة كلدال المعدلة؟ قالوا
+
+187
+00:15:06,040 --> 00:15:09,400
+الله في طريقة كلدال العادية إحنا بنستخدم two
+
+188
+00:15:09,400 --> 00:15:13,750
+standard solutionsتو standard solutions واحد اللي
+
+189
+00:15:13,750 --> 00:15:18,170
+هو ال standard H2SO4 اللي بنجمع فيه الأمونيا
+
+190
+00:15:18,170 --> 00:15:21,090
+والتاني ال sodium hydroxide اللي بنعاير فيه
+
+191
+00:15:21,090 --> 00:15:27,510
+الزيادة من ال H2SO4 مش هيك؟ ف ال modified Keldahl
+
+192
+00:15:27,510 --> 00:15:32,330
+method بتتقلق على الموضوع و بتحاول انه تستخدم one
+
+193
+00:15:32,330 --> 00:15:37,620
+standard solutionليه؟ لأنه انا كل ما استخدمت محليل
+
+194
+00:15:37,620 --> 00:15:41,540
+اكتر برضه بكون عندي نسبة خطأ اكبر فهان بالنسبة لي
+
+195
+00:15:41,540 --> 00:15:44,900
+الموديفايد kill dial method تستخدم one standard
+
+196
+00:15:44,900 --> 00:15:47,800
+solution و بنشوف الآن ايش هي الموديفايد kill dial
+
+197
+00:15:47,800 --> 00:15:52,220
+method و كيف بتفرج او بتختلف عن ال kill dial
+
+198
+00:15:52,220 --> 00:15:58,160
+method الأصلية بقول في البدايةأول خطوتين هما نفسهم
+
+199
+00:15:58,160 --> 00:16:02,400
+في الطريقتين يعني مثلا عندي عينة organic nitrogen
+
+200
+00:16:02,400 --> 00:16:06,640
+موجود فيها بدي أعملها digestion فش جدال بدي أعملها
+
+201
+00:16:06,640 --> 00:16:10,360
+digestion فبضيف عليها concentrated sulfuric acid و
+
+202
+00:16:10,360 --> 00:16:14,080
+بدي أسخن لفترة لغاية ما يتم التفاعل و تتكسر كل
+
+203
+00:16:14,080 --> 00:16:18,040
+العينة تتحول من organic nitrogen ل inorganic
+
+204
+00:16:18,040 --> 00:16:22,270
+nitrogen تتحول لل ammoniumوبعدين بدي أضيف excess
+
+205
+00:16:22,270 --> 00:16:25,790
+sodium hydroxide في الطريقتين نفس الكلام وبعدين
+
+206
+00:16:25,790 --> 00:16:28,690
+بدي أعمل distillation to drive the ammonia out of
+
+207
+00:16:28,690 --> 00:16:32,610
+the solution في التنتين لكن ال modified إيش بتسوي
+
+208
+00:16:32,610 --> 00:16:38,170
+قال بدل من جمع ال evolved ammonia بدل من جمعها في
+
+209
+00:16:38,170 --> 00:16:42,690
+standard sulfuric acid solution قال لأ بدنا نجمعها
+
+210
+00:16:42,690 --> 00:16:48,190
+في dilute boric acid solution dilute boric acid
+
+211
+00:16:48,190 --> 00:16:53,190
+solutionجدّاش تركيزه؟ قال مش مهم جدّاش تركيزه
+
+212
+00:16:53,190 --> 00:16:56,350
+المهم انه بايليوت هل هو standard؟ لأ مش standard
+
+213
+00:16:56,350 --> 00:17:01,370
+إذا جمعناها في أسد إيه شماله؟ مش standard أسد طب
+
+214
+00:17:01,370 --> 00:17:04,990
+إيش اللي بيحصل لما نجمع الأمونيا في ال boric acid؟
+
+215
+00:17:04,990 --> 00:17:09,410
+قال الأمونيا بتحول لأمونيا بتاخد H plus من ال
+
+216
+00:17:09,410 --> 00:17:13,510
+boric acid و ال boric acid بتحول لإيه؟ لل borate
+
+217
+00:17:13,510 --> 00:17:17,650
+الفكرة وين يا شباب؟ الفكرة أنه ال boric acid هيبقى
+
+218
+00:17:17,650 --> 00:17:21,410
+حامل ضعيف جدايبجى ال conjugate base تبعته ايش
+
+219
+00:17:21,410 --> 00:17:27,030
+مالها قاعدة قوية اه strong conjugate base هذه
+
+220
+00:17:27,030 --> 00:17:31,650
+القاعدة القوية يمكن معاييرتها مع ال HCL standard
+
+221
+00:17:31,650 --> 00:17:37,910
+HCL اذا البوريت المتكونة يمكن معاييرتها مع
+
+222
+00:17:37,910 --> 00:17:41,130
+standard HCL هاي ال standard الوحيد اللي عندى طب
+
+223
+00:17:41,130 --> 00:17:45,350
+لو اجينا هنا احنا بقول البوريت minimal بوريت
+
+224
+00:17:50,450 --> 00:17:56,690
+ملي مول أمونيا هي الأمونيا بتعطيني بوريت واحد
+
+225
+00:17:56,690 --> 00:18:00,850
+لواحد ملي مول بوريت بتساوي ملي مول أمونيا وكمان
+
+226
+00:18:00,850 --> 00:18:09,890
+عندي أنا الملي مول بوريت بتساوي ملي مول HCl
+
+227
+00:18:10,610 --> 00:18:13,910
+المعاهرة البريت فيش عليا جرشوحنة واحدة بتاخد بس H
+
+228
+00:18:13,910 --> 00:18:17,870
+plus واحدة واحد لواحد مع ال HCl اذا الميلي مول
+
+229
+00:18:17,870 --> 00:18:22,790
+بريت بتسوى الميلي مول HCl او بمعنى اخر الميلي مول
+
+230
+00:18:22,790 --> 00:18:29,490
+HCl بتسوى الميلي مول امونيا
+
+231
+00:18:29,490 --> 00:18:34,850
+او الميلي مول امونيا هو ميلي مول نيتروجين اذا
+
+232
+00:18:34,850 --> 00:18:39,430
+الميلي مول نيتروجين في النهاية بتسوى الميلي مول
+
+233
+00:18:40,300 --> 00:18:45,020
+الـHCl ولاحظوا معايا الـHCl الملي مول استبعت اللي
+
+234
+00:18:45,020 --> 00:18:49,620
+بحتاجها انه معروف 100% ليه؟ لأنه انا عيرت البريت
+
+235
+00:18:49,620 --> 00:18:54,440
+بالـHCl فاخدت حجب معين من الـHCl تركيزه معروف
+
+236
+00:18:54,440 --> 00:18:59,100
+فالملي مول زي اندي من الـHCl معروفة اذا ان على طول
+
+237
+00:18:59,100 --> 00:19:03,040
+بكون عارفة ايه؟ الملي مول نيترجن وممكن هدي احولها
+
+238
+00:19:03,040 --> 00:19:07,860
+لملي مول بروتين او ملي جرام بروتين زي ما بدييبقى
+
+239
+00:19:07,860 --> 00:19:13,060
+الفكرة كمان مرة، أول خطوات هي نفسها، لكن بعدين،
+
+240
+00:19:13,060 --> 00:19:18,040
+بعد ما يعمل distillation للأمونيا، الامونيا is
+
+241
+00:19:18,040 --> 00:19:23,500
+driven into a bilute boric acid solution، جداشترك
+
+242
+00:19:23,500 --> 00:19:27,210
+مش standard، بس bilute boric acid solutionكويس
+
+243
+00:19:27,210 --> 00:19:30,670
+فبتحول جزء منه حسب كمية الأمونة بتحول للبوريت
+
+244
+00:19:30,670 --> 00:19:35,010
+البوريت تعييرها بال HCl الملي مول ميتروجين يساوي
+
+245
+00:19:35,010 --> 00:19:39,790
+ملي مول HCl وانتهت المسألة اذا حتى من ناحية حسابات
+
+246
+00:19:39,790 --> 00:19:46,250
+اسهل كتير من ايه من الكلبال method الأصلي حتى من
+
+247
+00:19:46,250 --> 00:19:50,730
+ناحية حسابات اسهل كتير من كلبال method الأصلي نيجي
+
+248
+00:19:50,730 --> 00:19:57,560
+طيب نطلععلى هذا المثال ونشوف كيف بنطبق هذا الكلام
+
+249
+00:19:57,560 --> 00:20:03,100
+من ناحية عملية بنقول a 0.3 gram feed sample feed
+
+250
+00:20:03,100 --> 00:20:07,480
+sample يعني علف أكل الإنسان بنقوله food أكل
+
+251
+00:20:07,480 --> 00:20:13,240
+الحيوان بنقوله feed يبقى a 0.3 gram feed sample is
+
+252
+00:20:13,240 --> 00:20:17,730
+analyzed for its protein contentby the modified
+
+253
+00:20:17,730 --> 00:20:22,330
+Keldal method ماشرحليش عنها حاجة قاللي بس إيه ال
+
+254
+00:20:22,330 --> 00:20:24,670
+modified Keldal method لازم تعرف أنت أنه في ال
+
+255
+00:20:24,670 --> 00:20:27,930
+modified Keldal method هذه الخطوات اللي بتحصل و ال
+
+256
+00:20:27,930 --> 00:20:30,970
+millimol نيتروجين يساوي و millimol HCl لازم تكون
+
+257
+00:20:30,970 --> 00:20:37,490
+فاهم هذا الكلام فإيش بيقول؟ بيقول if 25 ml of 0.1
+
+258
+00:20:37,490 --> 00:20:42,120
+molar HCl is required for the titrationلو ان احنا
+
+259
+00:20:42,120 --> 00:20:47,160
+بنحتاج 25 مل من 0.1 مولر HCL للـ titration
+
+260
+00:20:47,160 --> 00:20:51,200
+للمعايرة بسأل what is the percent protein content
+
+261
+00:20:51,200 --> 00:20:55,730
+of the sample؟ جداش نسبة البروتين في العالم؟مع
+
+262
+00:20:55,730 --> 00:20:59,950
+العلم بيعطيك جوس بيقولك ال milligram protein إذا
+
+263
+00:20:59,950 --> 00:21:03,290
+كان لك تحسبه بساوي ستة وربع في ال milligram
+
+264
+00:21:03,290 --> 00:21:06,730
+نيتروجين، يعني لو حسبت ال milligram نيتروجين أضربه
+
+265
+00:21:06,730 --> 00:21:09,530
+في ستة وربع بيعطيك إيه؟ milligram protein، الستة
+
+266
+00:21:09,530 --> 00:21:13,930
+وربع هادي factor ل .. ل proteins عامة اللي موجودة
+
+267
+00:21:13,930 --> 00:21:18,490
+في العلافممكن تطلع مثلا هذا مش ثابت لكل أنواع ال
+
+268
+00:21:18,490 --> 00:21:21,050
+proteins اللي في الدنيا لأ حسب نوع ال protein يعني
+
+269
+00:21:21,050 --> 00:21:26,210
+لو تحسب ال proteins اللي موجودة مثلا في الحبوب
+
+270
+00:21:26,210 --> 00:21:33,790
+القمح تحديدا تضرب في 5.57بعض ال proteins الأخرى
+
+271
+00:21:33,790 --> 00:21:38,570
+ممكن تدرب في 6.28 أما للأعلاف وال proteins بشكل
+
+272
+00:21:38,570 --> 00:21:42,250
+عام حوالين ال 6.25 لكن لو ال proteins في حبوب أو
+
+273
+00:21:42,250 --> 00:21:49,470
+ما شابه الرقم ممكن يختلف بشكل يعني واضح شوية زي ما
+
+274
+00:21:49,470 --> 00:21:53,710
+قلت القمح حوالي 5.57 فهذا عبارة عن فاتر ومدة ربوع
+
+275
+00:21:53,710 --> 00:21:57,150
+عشان يتحول من milligram nitrogen ل milligram
+
+276
+00:21:57,150 --> 00:22:02,560
+proteinيبقى انا عملت التحليل هذا اخدت تلاتة تمان
+
+277
+00:22:02,560 --> 00:22:06,620
+مرة اخدت تلاتة من عشرة جرام من العلاق حطيت عليهم
+
+278
+00:22:06,620 --> 00:22:11,120
+concentrated sulphuric acid وعملت دايزشين سخنت
+
+279
+00:22:11,120 --> 00:22:15,420
+بعدين حطيت excess sodium hydroxide القمونية اللي
+
+280
+00:22:15,420 --> 00:22:16,220
+تكونت
+
+281
+00:22:21,010 --> 00:22:25,750
+جمعتها في محلول بوريك أسد مخفف بعدين أخدت المحلول
+
+282
+00:22:25,750 --> 00:22:30,890
+المخفف هذا و عيرته باستخدام ال HCl فأخد المعايير
+
+283
+00:22:30,890 --> 00:22:35,030
+أخدت 25 مل من 0.1 مولر HCl بده يحسب ال percentage
+
+284
+00:22:35,030 --> 00:22:39,250
+ال protein في العينة بقول أنا مدام هذه ال modified
+
+285
+00:22:39,250 --> 00:22:42,270
+Keldal method يزن ال millimole نيتروجين تسوى
+
+286
+00:22:42,270 --> 00:22:47,100
+millimole HClالملي مول نيتروجين سبعة point one في
+
+287
+00:22:47,100 --> 00:22:50,120
+خمسة و عشرين يعني اتنين و نص ملي مول الملي مول
+
+288
+00:22:50,120 --> 00:22:53,900
+نيتروجين اتنين و نص صحيح الملي جرام نيتروجين اتنين
+
+289
+00:22:53,900 --> 00:22:56,580
+و نص في اربعة عشر اللي هي ال atomic weight
+
+290
+00:22:56,580 --> 00:23:00,320
+للنيتروجين خمسة و تلاتين اه طب الملي جرام البروتين
+
+291
+00:23:00,320 --> 00:23:05,880
+الملي جرام نيتروجين في ستة و رباعمتين و تمانتاش و
+
+292
+00:23:05,880 --> 00:23:10,140
+تمانية من عشرة ال percentage وزنة ال protein على
+
+293
+00:23:10,140 --> 00:23:13,980
+وزنة العيناه في مية من مية بطلع حوالي تلاتة و
+
+294
+00:23:13,980 --> 00:23:19,720
+سبعين في المية ماشي يا شباب بالرغم من ان كل ده ال
+
+295
+00:23:19,720 --> 00:23:24,280
+analysis يعني بسيط و ماخدش معنى واجت كتير بالعكس
+
+296
+00:23:24,280 --> 00:23:29,520
+جزء من محاضرة الا انه بتتوقع يجيك حاجة زي هيك في
+
+297
+00:23:29,520 --> 00:23:34,860
+الامتحان ليه؟ لأن الموضوع مهمبمعنى آخر وين ما بدك
+
+298
+00:23:34,860 --> 00:23:41,120
+تشتغل وين ما بدك تشتغل كإنسان درس كيميا و بده
+
+299
+00:23:41,120 --> 00:23:44,520
+يشتغل في التحليل لازم تنسقل عن كل ده ال analysis
+
+300
+00:23:44,520 --> 00:23:47,360
+فمش معقول تكون جايب علامة جيدة في الكيميا
+
+301
+00:23:47,360 --> 00:23:50,440
+التحليلية و أنت بتعرفش إيش يعني كل ده ال analysis
+
+302
+00:23:50,440 --> 00:23:55,120
+لازم تعرفه علشان هيك احنا بنحب دائما نوضحه في
+
+303
+00:23:55,120 --> 00:23:59,920
+المحاضرات و بنحب أيضا أنه نسألك عنه في الامتحان بس
+
+304
+00:23:59,920 --> 00:24:05,970
+علشان تتأكدمن معلوماتك حول إيش هو كلدال nitrogen
+
+305
+00:24:05,970 --> 00:24:09,310
+analysis كيف بيتم إيش الطريقة الأصلية و إيش
+
+306
+00:24:09,310 --> 00:24:12,150
+الطريقة المعدلة ليه؟ لأنه تطبيقاته في الحياة
+
+307
+00:24:12,150 --> 00:24:15,490
+العملية كتيرة خالص و إنت إذا كانت اشتغلة راح تشتغل
+
+308
+00:24:15,490 --> 00:24:21,530
+جزء .. جزء من شغلك هيكون كلدال analysis هيك يا
+
+309
+00:24:21,530 --> 00:24:27,420
+شباب بنكون خلصنا ال acid based titrationsوالان
+
+310
+00:24:27,420 --> 00:24:31,260
+بدنا ننتقل للشكتر الخاص بال complexometric
+
+311
+00:24:31,260 --> 00:24:33,560
+reactions و titrations
+
+312
+00:24:37,290 --> 00:24:41,850
+بنقول بفضل علينا بس chapterين نسبيا صغار بعد هذا
+
+313
+00:24:41,850 --> 00:24:45,130
+chapter وهذا chapter برضه كمان صغير زي ما هنشوف
+
+314
+00:24:45,130 --> 00:24:50,090
+تلت محاضرات واشي بسيط يعنى او تلت محاضرات تقريبا
+
+315
+00:24:50,090 --> 00:24:55,070
+فتقريبا احنا ماشيين كويس كتير في ال course على اي
+
+316
+00:24:55,070 --> 00:24:58,650
+حال فبقول ال complexometric reactions وtitrations
+
+317
+00:24:58,650 --> 00:25:03,440
+برضه تطبيقاتها كتير مهمة في الحياة العمليةلأنه
+
+318
+00:25:03,440 --> 00:25:08,640
+هنشوف مثلا تعيين عصر الماء جداش الميه ماهي الحال
+
+319
+00:25:08,640 --> 00:25:12,900
+ملوحة لعصر الماء ليش الميه بترغيش هذا بيتم
+
+320
+00:25:12,900 --> 00:25:17,720
+باستخدام ال complexometric titrations لال metal
+
+321
+00:25:17,720 --> 00:25:21,480
+ions اللي هي الكالسم والماننيزيا مع ال ligand
+
+322
+00:25:21,480 --> 00:25:27,060
+بنستخدم دائما ال EDTA على أي حال علشان نفهم إيش
+
+323
+00:25:27,060 --> 00:25:29,860
+يعني complexometric reactions و titrations خلّيني
+
+324
+00:25:29,860 --> 00:25:34,440
+نفهم في الأول إيش يعني complexبقول ال complex هو
+
+325
+00:25:34,440 --> 00:25:40,540
+عبارة عن مُركّب مُركّب كيميائي يتكوّن من metal ion
+
+326
+00:25:40,540 --> 00:25:47,100
+oligand ال metal ion هو عبارة عن Lewis acid ليه؟
+
+327
+00:25:47,100 --> 00:25:50,420
+لأنه electron deficient بحب الإلكترونات يستقبل
+
+328
+00:25:50,420 --> 00:25:57,980
+إلكترونات فهو Lewis acidElectron deficient بينما
+
+329
+00:25:57,980 --> 00:26:03,740
+ال legend هذا Lewis Bayes Electron rich Electron
+
+330
+00:26:03,740 --> 00:26:10,810
+rich يعني فيه إلكترونات كتيربحب يعطي electron
+
+331
+00:26:10,810 --> 00:26:17,650
+donor هداك ال acid electron acceptor كويس فبيتكون
+
+332
+00:26:17,650 --> 00:26:22,930
+روابط ما بين ال ligand و ال metal ion الروابط هذه
+
+333
+00:26:22,930 --> 00:26:28,850
+الإلكترونات المكونة إليها عادة بتيجي كلها من ال
+
+334
+00:26:28,850 --> 00:26:32,890
+ligand مش من ال metal ion ليه؟ لأنه فقد الشيء لا
+
+335
+00:26:32,890 --> 00:26:35,930
+يعطيه عمال بنقول ال metal electron deficient
+
+336
+00:26:39,120 --> 00:26:44,580
+الليجانز يا شباب ممكن نقسمها لقسمين يا اما simple
+
+337
+00:26:44,580 --> 00:26:49,840
+legends يا اما حاجة بنقولها
+
+338
+00:26:52,590 --> 00:26:56,470
+يعني collating agents، collating agents،
+
+339
+00:26:56,470 --> 00:26:59,090
+فالـligands نوعين، simple ligand هو عبارة عن ال
+
+340
+00:26:59,090 --> 00:27:03,710
+ligands اللي بتعطي أو بتشارك بزوج إلكترونات واحد،
+
+341
+00:27:03,710 --> 00:27:08,470
+زي مثلا الأمونيا، زي ال chloride، زي الميه، وهذا
+
+342
+00:27:08,470 --> 00:27:15,930
+عبارة عن عادة، عادةهي عبارة عن inorganic ligands
+
+343
+00:27:15,930 --> 00:27:20,550
+أو ممكن تكون ions أو ممكن تكون compounds ممكن ions
+
+344
+00:27:20,550 --> 00:27:23,270
+و ممكن compounds عادة هي عبارة عن inorganic
+
+345
+00:27:23,270 --> 00:27:28,410
+materials small in size small in size يعني صغيرة
+
+346
+00:27:28,410 --> 00:27:33,190
+في الحجم إذا كان ال ligand بيعطي one single pair
+
+347
+00:27:33,190 --> 00:27:38,780
+of electrons بيكون اسمه monodentateمونو دنتات
+
+348
+00:27:38,780 --> 00:27:44,740
+أحادي العطاء لكن في ليجانز يا شباب ممكن تعطي تكون
+
+349
+00:27:44,740 --> 00:27:49,220
+بايدنتات تعطي two pairs of electrons زي مثلا
+
+350
+00:27:49,220 --> 00:27:55,180
+الاثرين دايمين او تعطي تلاتة او اكتر فممكن تكون
+
+351
+00:27:55,180 --> 00:27:59,320
+polydentate يا اما مونو دنتات يا اما polydentate
+
+352
+00:27:59,320 --> 00:28:02,180
+poly ممكن تكون اتنين او تلاتة او اربعة او خمسة او
+
+353
+00:28:02,180 --> 00:28:06,700
+ستة او اكتر كويس multidentate polydentate نفس
+
+354
+00:28:06,700 --> 00:28:15,920
+الكلامفي حالة ما يكون في حالة ما يكون ال legend
+
+355
+00:28:15,920 --> 00:28:20,620
+كبير by dentate زي ما احنا قلنا او tridentate زي
+
+356
+00:28:20,620 --> 00:28:24,540
+اللي قدامي هان او tetradentate او pentadentate
+
+357
+00:28:24,540 --> 00:28:29,720
+شايفين او hexadentate هذا عبارة عن organic
+
+358
+00:28:29,720 --> 00:28:34,520
+molecule بيحتوي على اكتر من donating groupأكتر من
+
+359
+00:28:34,520 --> 00:28:39,920
+donating group أكتر من donor group في هذه الحالة
+
+360
+00:28:39,920 --> 00:28:45,940
+ال legend يسمىulating agent ال legend يسمىulating
+
+361
+00:28:45,940 --> 00:28:51,130
+agentفي هذه الحالة إذا كان الـLigand عبارة عن
+
+362
+00:28:51,130 --> 00:28:56,370
+Large Organic Molecule بيعطي أكتر من زوج من
+
+363
+00:28:56,370 --> 00:28:59,310
+الإلكترونات أكتر من زوج من الإلكترونات يسمى
+
+364
+00:28:59,310 --> 00:29:03,530
+Killating Agent طيب ال complex اللي بتكون منه زائد
+
+365
+00:29:03,530 --> 00:29:10,310
+ال metal ion إيش يسمى؟ يسمى Killate ال complex
+
+366
+00:29:10,310 --> 00:29:16,460
+اللي بتكون يسمى Killate إذاالكمبليكس قد يكون أو قد
+
+367
+00:29:16,460 --> 00:29:23,620
+يتكون من simple ligand زي الأمونيا والميه والميتال
+
+368
+00:29:23,620 --> 00:29:29,380
+ايون هذا اسمه كمبليكس بينما إذا كان الكمبليكس تكون
+
+369
+00:29:29,380 --> 00:29:35,520
+من ميتال ايون وulating agentبكون اسمه كليت هو
+
+370
+00:29:35,520 --> 00:29:40,420
+complex لكن برضه كمان اسمه ايه كليت فكل كليت هو
+
+371
+00:29:40,420 --> 00:29:45,380
+complex لكن مش كل complex ممكن نقول عنه كليت ماشي
+
+372
+00:29:45,380 --> 00:29:51,200
+يا شباب طبعا ال EDTA زي ما احنا شايفين هي عبارة عن
+
+373
+00:29:51,200 --> 00:29:57,380
+hexadentate ليجاند في عندنا هاي إيثيليين دايامين
+
+374
+00:29:57,380 --> 00:30:02,740
+في عندنا two ليجاند هاي واحد هاي اتنينتترا أسيتك
+
+375
+00:30:02,740 --> 00:30:09,200
+أسيد هي كل شحنة سالبة هي عبارة عن donating group
+
+376
+00:30:09,200 --> 00:30:14,880
+عندي فهي أنواع ال legends المختلفة واضحة بتهيألي
+
+377
+00:30:14,880 --> 00:30:22,440
+هذه الخريطة لاحظوا أنه اللون اللي عندي هذا هو
+
+378
+00:30:22,440 --> 00:30:25,540
+عبارة عن لون ال legend كل ال legends هذه عبارة عن
+
+379
+00:30:25,540 --> 00:30:34,570
+أمونياكوبلت أمونيا ليجانز لكن لحظه هان عندي انا
+
+380
+00:30:34,570 --> 00:30:42,890
+كوبلت تلاتة هكسامين كويس كوبلت تلاتة طلع لونه هو
+
+381
+00:30:42,890 --> 00:30:46,050
+اللون اللي موجود على اللوح هو عبارة عن اللون
+
+382
+00:30:46,050 --> 00:30:49,600
+الحقيقيطيب، اذا هذا كل الـlegends اللي حواليه
+
+383
+00:30:49,600 --> 00:30:54,380
+يشملها هي عبارة عن أمونيا، وال cobalt اللي عندنا،
+
+384
+00:30:54,380 --> 00:30:59,460
+cobalt 3 لو طلعنا على ال cobalt 3 أيضا، لكن واحدة
+
+385
+00:30:59,460 --> 00:31:04,140
+من الأمونيا تم استبدالها بالchlor، chloride فاطلع
+
+386
+00:31:04,140 --> 00:31:07,860
+اللون كيف بتغير، اطلع اللون كيف بتغير، اذا كان
+
+387
+00:31:07,860 --> 00:31:13,000
+واحدة من الأمونيا تم استبدالها بالمية، اطلع اللون
+
+388
+00:31:13,000 --> 00:31:18,200
+كيف بتغير، بس هذا cobalt 2، لو كان عندناأكسيال
+
+389
+00:31:18,200 --> 00:31:24,180
+أكلورايد أكلورايد فعنا في الحقيقة فيه تغير كبير في
+
+390
+00:31:24,180 --> 00:31:28,520
+اللون وهذا بيعتمد على نوع الـligands المرتبطة
+
+391
+00:31:28,520 --> 00:31:32,100
+بالـmetal ion نوع الـligands المرتبطة بالـmetal
+
+392
+00:31:32,100 --> 00:31:37,170
+ion شبه بالـالكيميا هيمر معاهم في المستقبل إيش
+
+393
+00:31:37,170 --> 00:31:40,390
+يعني crystal field theory وإيش منشأة هذه الألوان
+
+394
+00:31:40,390 --> 00:31:44,550
+هيدرسوها بالتفصيل لكن بجيه الشباب بيهمناش هذا
+
+395
+00:31:44,550 --> 00:31:49,650
+الكلام الآن لكن بنقول إنه ممكن يعني legends مختلفة
+
+396
+00:31:49,650 --> 00:31:56,430
+ترتبط بmetal ion معين قابلية
+
+397
+00:31:59,210 --> 00:32:04,450
+تكوين Complex هذا شيء مهم كتير هذا شيء مهم كتير و
+
+398
+00:32:04,450 --> 00:32:09,390
+بتوقف على نوع ال legend و نوع ال metal ion و هنشوف
+
+399
+00:32:09,390 --> 00:32:14,590
+بعض خصائصه بعد شوية لكن بنقول على سبيل المثال على
+
+400
+00:32:14,590 --> 00:32:24,890
+سبيل المثال لو عندي لو عندي مثلا silver و أبقعت
+
+401
+00:32:24,890 --> 00:32:29,720
+عليه ammoniaفبقول ممكن أول خطوة ال silver ياخد
+
+402
+00:32:29,720 --> 00:32:34,740
+واحد أمونيا و يعطيني silver ammonia complex هذا له
+
+403
+00:32:34,740 --> 00:32:40,600
+KF1 ايش KF1 يعني first formation constant
+
+404
+00:32:40,600 --> 00:32:44,380
+formation constant يعني stability constant يعني
+
+405
+00:32:44,380 --> 00:32:51,210
+ثابت تكوينأو ثابت الثبات لل Complex ثابت التكوين
+
+406
+00:32:51,210 --> 00:32:54,730
+كل ما زاد كل مكان المُركّب اللي اتكون أو ال
+
+407
+00:32:54,730 --> 00:32:59,490
+Complex اللي اتكون أكثر ثباتاً كل ما زاد ال KF كل
+
+408
+00:32:59,490 --> 00:33:03,170
+مكان المُركّب اللي اتكون أو ال Complex اللي اتكون
+
+409
+00:33:03,170 --> 00:33:08,090
+أكثر ثباتاً بقول ال silver ammonia كمان إذا كان في
+
+410
+00:33:08,090 --> 00:33:12,050
+واندي أمونيا زيادة بياخد كمان أمونيا وبعطين ال
+
+411
+00:33:12,050 --> 00:33:18,650
+silver bi ammonia Complexاللي هو KF2 ثابت التكوين
+
+412
+00:33:18,650 --> 00:33:25,470
+التاني الخطوة التانية طيب إيش بيحصل لو أنا كتبت
+
+413
+00:33:25,470 --> 00:33:32,910
+التكوين على هيئة خطوة واحدة one step formation
+
+414
+00:33:32,910 --> 00:33:37,570
+فبقول ال silver زاد اتنين امونيا بتعطي ال silver
+
+415
+00:33:37,570 --> 00:33:42,910
+بي امونيا complex هذا لو قولنا اللي هو KFلو حسبت
+
+416
+00:33:42,910 --> 00:33:47,430
+انا الـ KF1 و الـ KF2 و الـ KF .. بلاحظ انه الـ KF
+
+417
+00:33:47,430 --> 00:33:52,370
+للخطوة المحصلة يساوي حص البرد الـ KF values
+
+418
+00:33:52,370 --> 00:33:58,230
+للخطوات المتعددة للخطوات المتعددة طبعا مش شرط ان
+
+419
+00:33:58,230 --> 00:34:01,830
+يكون فاندي بس خطوطين يعني مثلا الكبر بتفاعل مع
+
+420
+00:34:01,830 --> 00:34:05,270
+الامونيا بيكون كبر امونيا و كبر بيامونيا و كبر ترا
+
+421
+00:34:05,270 --> 00:34:12,150
+امونيا و كبر تترا امونيا Complex كويس؟فإله KF1 و
+
+422
+00:34:12,150 --> 00:34:16,970
+KF2 و KF3 و KF4 لو أنا قولت cover زائد أربع أمونيا
+
+423
+00:34:16,970 --> 00:34:20,630
+مرة واحدة بيعطيني cover تترا أمونيا complex بقول
+
+424
+00:34:20,630 --> 00:34:25,550
+يبقى ال KF للخطوة المحصلة هذه بساوي KF1 في KF2 في
+
+425
+00:34:25,550 --> 00:34:30,330
+KF3 في KF4 فبدأ ناخد بالنا من هذه النقطة لإنه هيجي
+
+426
+00:34:30,330 --> 00:34:36,870
+لنا تطبيقها بعد يعني خلال الفصل هذا إذا الله رح
+
+427
+00:34:39,070 --> 00:34:45,650
+أيضًا يا شباب، أيضًا، بنقول إن الـKF، الـKF، هذا
+
+428
+00:34:45,650 --> 00:34:50,110
+هو الـFormation Constant أو قولنا عنه برضه كمان،
+
+429
+00:34:50,110 --> 00:34:54,810
+الـStability Constant، بمعنى آخر إن لو كتبنا، لو
+
+430
+00:34:54,810 --> 00:34:59,570
+كتبنا المعادلة
+
+431
+00:34:59,570 --> 00:35:03,530
+على هيئة التفككهي ال complex اتفكك اعطاني ال
+
+432
+00:35:03,530 --> 00:35:07,570
+silver زائد اتنين امونيا بقول هذا ثابت تفكك لكن
+
+433
+00:35:07,570 --> 00:35:12,830
+بسميه لأن هو اتكون عكس التكوين او عكس الثبات K
+
+434
+00:35:12,830 --> 00:35:17,690
+-instability عكسه فبقول انا ال K-instability
+
+435
+00:35:17,690 --> 00:35:22,340
+النواتج على المتفاعلاتمش هيك؟ لو قرنتوا بالـKf
+
+436
+00:35:22,340 --> 00:35:26,260
+بلاحظ ان الـK instability بتسوء واحد على الـKf
+
+437
+00:35:26,260 --> 00:35:30,800
+وبرضه كمان لو حبيته الـKf بسوء واحد على الـK
+
+438
+00:35:30,800 --> 00:35:36,160
+instability الاتنين عكس بعض لإن واحد بتتكلم عن
+
+439
+00:35:36,160 --> 00:35:41,580
+تكوين والتاني بتتكلم عن تفكك فالاتنين عكس بعض
+
+440
+00:35:41,580 --> 00:35:45,740
+تماما طيب يا شباب
+
+441
+00:35:50,580 --> 00:35:56,460
+لو جينا قولنا إيش العوامل اللي بتأثر على ثبات ال
+
+442
+00:35:56,460 --> 00:36:01,880
+complex؟
+
+443
+00:36:01,880 --> 00:36:05,740
+إيش يعني ثبات ال complex؟ يعني بمعنى آخر إيش
+
+444
+00:36:05,740 --> 00:36:14,540
+العوامل اللي بتخلي ال KF يكون
+
+445
+00:36:14,540 --> 00:36:21,810
+كبير؟بقول في البداية خالص بتحدث عن ال nature of
+
+446
+00:36:21,810 --> 00:36:29,630
+the metal ion ال metal ion مهم كتير بحيث انه كل ما
+
+447
+00:36:29,630 --> 00:36:35,930
+كان ال metal ion better او stronger Lewis acid كل
+
+448
+00:36:35,930 --> 00:36:42,110
+ما كان افضل كيف يعني؟ يعني كل ما زغر حجم ال ion و
+
+449
+00:36:42,110 --> 00:36:47,900
+زادت شحنته الموجة بقىكويس؟ كل مكان بيقدر يكون
+
+450
+00:36:47,900 --> 00:36:53,440
+Complex مع الـLegand أقوى يبقى الـKf بيكون ايه؟
+
+451
+00:36:53,440 --> 00:37:01,260
+أعلى يبقى أول عامل من العوامل بيتعلق بالـMetal-Ion
+
+452
+00:37:01,260 --> 00:37:06,520
+بدي Metal-Ion صغير في الحجم كبير في الشحنة كويس؟
+
+453
+00:37:06,520 --> 00:37:10,420
+تاني عامل بنقول مدام حكينا عن الـMetal-Ion نتكلم
+
+454
+00:37:10,420 --> 00:37:17,830
+عن الـLegand بقول إذا كان الـMetalبيعطيني كلّات،
+
+455
+00:37:17,830 --> 00:37:23,550
+يعني كان ال legend عبارة عن kellating agent جيد،
+
+456
+00:37:23,550 --> 00:37:27,870
+بيعطي يعني كلّات، complex اسمه كلّات، كويس، فهذا
+
+457
+00:37:27,870 --> 00:37:34,010
+بيعطينيlarger value للـ KF او بيعطيني more stable
+
+458
+00:37:34,010 --> 00:37:38,210
+complex more stable كلّات more stable يعني ال
+
+459
+00:37:38,210 --> 00:37:43,090
+stability بتزيد اذا كان عندي كلّات يعني مثلا لو
+
+460
+00:37:43,090 --> 00:37:48,590
+جينا تطلعنا على ال cover EDTA او ال cover tetra
+
+461
+00:37:48,590 --> 00:37:52,570
+ammonia complex هذا complex وهذا complex لو جينا
+
+462
+00:37:52,570 --> 00:38:01,060
+تطلعنا على الاتنين بلاحظ انه ال KFلا ال .. ال ..
+
+463
+00:38:01,060 --> 00:38:06,860
+الكلية ال cover E D T A كلية أكبر ثبات ال cover E
+
+464
+00:38:06,860 --> 00:38:11,160
+D T A أكبر من ثبات ال cover tetra amine complex أو
+
+465
+00:38:11,160 --> 00:38:15,260
+tetra ammonia complex هذا الظاهرة بنقولها كلون
+
+466
+00:38:15,260 --> 00:38:22,060
+effect كلون effect الكلون effect هي يعني ثبات زائد
+
+467
+00:38:24,330 --> 00:38:31,390
+للكليات اكتر كتير من ثبات ال complex اللي ال metal
+
+468
+00:38:31,390 --> 00:38:36,390
+ion نفسه بيكونه مع simple legend ال cover EDTA
+
+469
+00:38:36,390 --> 00:38:43,090
+اقوى more stable than ال cover ammonia او ال cover
+
+470
+00:38:43,090 --> 00:38:49,550
+H2O complex هذا بنقوله كلون effect ايش منشأه؟ من
+
+471
+00:38:49,550 --> 00:38:54,650
+وين بيجي؟منشأوه بشكل أساسي من ال thermodynamics
+
+472
+00:38:54,650 --> 00:39:06,690
+لأنه يعني مثلا لو أخدنا ال cover أمونيا ال
+
+473
+00:39:06,690 --> 00:39:11,870
+cover هذا
+
+474
+00:39:11,870 --> 00:39:18,230
+ممكن يعطيلنا cover two plus دقيقة أربعة أمونيا
+
+475
+00:39:18,230 --> 00:39:30,090
+بينما ال coverEDTA بيعطي cover زائد EDTA لو أجينا
+
+476
+00:39:30,090 --> 00:39:36,130
+قولنا أنه تفاعل أو أنه تفكك بيحصل بشكل أكبر الأول
+
+477
+00:39:36,130 --> 00:39:40,830
+ولا التانيبنقول احنا التفكك الأول بحصل بشكل أكبر
+
+478
+00:39:40,830 --> 00:39:46,090
+ليه؟ من ال thermodynamics لأنه بعطيني خمس خمسة
+
+479
+00:39:46,090 --> 00:39:50,350
+species five species التفكك التاني بعطيني ايه؟
+
+480
+00:39:50,350 --> 00:39:57,640
+اتنينالانتروبي للخمسة species أكبر من الانتروبي
+
+481
+00:39:57,640 --> 00:40:02,160
+للتو species يعني ال disorder لما أحصل على خمسة
+
+482
+00:40:02,160 --> 00:40:06,640
+أعلى من ال disorder لما أحصل على اتنين هو واضح
+
+483
+00:40:06,640 --> 00:40:09,740
+طبعا بالنسبة لنا من ال thermodynamics أنه كل ما
+
+484
+00:40:09,740 --> 00:40:15,180
+زادت الفوضى كل ما زاد ال disorder كل ما كان هذا
+
+485
+00:40:15,180 --> 00:40:22,920
+داعي لإنه يحصل التفاعل بشكل أكبرفالتفاعل يعني
+
+486
+00:40:22,920 --> 00:40:27,520
+بيتناسب مع ال disorder ال disorder هي دالة على ان
+
+487
+00:40:27,520 --> 00:40:30,660
+التفاعل بيحصل ولا لا اذا كان ال disorder بيزيد
+
+488
+00:40:30,660 --> 00:40:35,240
+التفاعل اه بيحصل بيزدش يعني ها بدنا ندور على حاجات
+
+489
+00:40:35,240 --> 00:40:39,300
+تانية فعندي هان ال entropy اعلى من ال entropy هان
+
+490
+00:40:39,300 --> 00:40:43,800
+وبالتالي هذا التفكك بيحصل كتير هذا لأ والله اقل
+
+491
+00:40:43,800 --> 00:40:48,160
+منه ايش يعني التفكك كبير وهذا التفكك اقل يعني ال
+
+492
+00:40:48,160 --> 00:40:53,980
+KF هان اكبروالـ KFOD أقل، هذا بنقوله الكلون
+
+493
+00:40:53,980 --> 00:41:00,080
+effect، نتيجة إنه عندي بس legend واحد هو اللي
+
+494
+00:41:00,080 --> 00:41:05,140
+بيعطي أكتر من donating group، أكتر من donor group،
+
+495
+00:41:05,140 --> 00:41:09,460
+معناته هذا بيعطيني more stability، هذا المقصود بال
+
+496
+00:41:09,460 --> 00:41:15,740
+nature of the legendأيضا ما يتعلق بال legend ممكن
+
+497
+00:41:15,740 --> 00:41:20,160
+يتحدث عن ال basicity لل legend ال basicity يعني
+
+498
+00:41:20,160 --> 00:41:23,900
+قدرته على إعطاء إلكترونات احنا شفنا ال metal ion
+
+499
+00:41:23,900 --> 00:41:28,340
+وتحدثنا عن ال charge اللي عليهالـLegand تحدث عن
+
+500
+00:41:28,340 --> 00:41:31,900
+الشحن اللي على الـLegand أو يعني جداش هو Base،
+
+501
+00:41:31,900 --> 00:41:35,840
+جداش بيقدر يعطي Electrons فكل ما زادت الـBasicity
+
+502
+00:41:35,840 --> 00:41:40,920
+للـLegand كل ما كان ال Complex أقوى، كل ما زادت
+
+503
+00:41:40,920 --> 00:41:44,900
+الـBasicity للـLegand كل ما كان ال Complex أقوى،
+
+504
+00:41:44,900 --> 00:41:50,260
+يعني الـKf له أعلى بنتحدث أيضًا عن الـSize
+
+505
+00:41:50,260 --> 00:41:54,320
+للـChelating Ring يعني مثلًا، عند الـEthylene
+
+506
+00:41:54,320 --> 00:42:00,900
+-Diamineهي NH2 وهي NH2 بقول لو لو عندي متل ايون
+
+507
+00:42:00,900 --> 00:42:08,720
+خليني اكتب الرابط خطوط مجطرة هذه
+
+508
+00:42:08,720 --> 00:42:18,960
+الاثيليين ديامين كويس الاثيليين ديامين اتكون زي ما
+
+509
+00:42:18,960 --> 00:42:23,780
+احنا شايفين حلقةكوّن حلقة مع الـmetal ion الحلقة
+
+510
+00:42:23,780 --> 00:42:28,760
+هذه واحد اتنين تلاتة اربعة خمسة خماسية بنقول إذا
+
+511
+00:42:28,760 --> 00:42:35,360
+كان الحلقة اللي تكونت خمسة أو ستة خمس أو ست روابط
+
+512
+00:42:35,360 --> 00:42:40,100
+حلقة خمسية أو سداسية إذا كانت تكونت حلقة خمسية أو
+
+513
+00:42:40,100 --> 00:42:45,380
+سداسية فهذا بيعطي stability أكبر لل complexيعني
+
+514
+00:42:45,380 --> 00:42:49,860
+الحلقة الخمسية والثلاثية دائما more stable لو كانت
+
+515
+00:42:49,860 --> 00:42:53,860
+أربعة لأ، لو كانت سبعة أقل، لو كانت تمانية زي ما
+
+516
+00:42:53,860 --> 00:42:59,180
+هنشوف في بعض ال indicators المستخدمة في ال
+
+517
+00:42:59,180 --> 00:43:03,620
+complexometric reactions ده بعيفة، بعيفة، بينما
+
+518
+00:43:03,620 --> 00:43:09,500
+هان أقوى، ال complex إيش بيكون؟ أقوى، يبقى حسب عدد
+
+519
+00:43:09,500 --> 00:43:15,060
+الحلقة، حسب عدد الروابطفي الحلقة إذا كان الروابط
+
+520
+00:43:15,060 --> 00:43:19,300
+خمسة كونت حلقة خمسية أو سادسية فهذا أدعى لإنه يكون
+
+521
+00:43:19,300 --> 00:43:25,200
+عنده more stable complex أيضا في كمان حاجة واحد أو
+
+522
+00:43:25,200 --> 00:43:34,740
+اتنين حلقة
+
+523
+00:43:34,740 --> 00:43:38,540
+أو تنتين كل ما زاد عدد الحلقات كل ما كان ال
+
+524
+00:43:38,540 --> 00:43:41,860
+complex أقوىيعني هاي اتنين اتنين لو كان في واحد
+
+525
+00:43:41,860 --> 00:43:45,800
+واحد بياخد تلاتة احسن لو كان واحد بياخد اربعة احسن
+
+526
+00:43:45,800 --> 00:43:50,220
+كل ما زادت عدد الحلقات كل ما كان ال complex more
+
+527
+00:43:50,220 --> 00:43:55,620
+stable كويس يبقى مش بس ال ring size لأ و عدد
+
+528
+00:43:55,620 --> 00:44:00,860
+الحلقات كمان بنقول كمان يعني في حاجة بيقولها
+
+529
+00:44:00,860 --> 00:44:05,200
+steric effects steric effects اللي هي يعني هل في
+
+530
+00:44:05,200 --> 00:44:13,150
+ممانعة في تكوين الرابط ولا لأممانعة فراغية هل في
+
+531
+00:44:13,150 --> 00:44:18,810
+ممانعة ولا لأ يعني ال metal ion حوالي groups بتمنع
+
+532
+00:44:18,810 --> 00:44:23,590
+ال legal من إنه يكون رابطة يعني أو بيكونها بصعوبة
+
+533
+00:44:23,590 --> 00:44:26,970
+مش مناجي وسع كافي يكون الرابطة هذا الكلام برضه
+
+534
+00:44:26,970 --> 00:44:27,730
+بيأثر على
+
+535
+00:44:31,410 --> 00:44:36,110
+هذه هي العوامل الأساسية اللى بتأثر على ثبات ال
+
+536
+00:44:36,110 --> 00:44:39,990
+complex طيب يا شباب احنا اذا الله راضي بنوبة في
+
+537
+00:44:39,990 --> 00:44:42,650
+هذا اليوم والحصة الجاية بنكملها
+
diff --git a/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/bgeZXRxTolE.srt b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/bgeZXRxTolE.srt
new file mode 100644
index 0000000000000000000000000000000000000000..c3ea8b031f92729b6a3a24a29c5efcb11de2ded2
--- /dev/null
+++ b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/bgeZXRxTolE.srt
@@ -0,0 +1,1663 @@
+1
+00:00:20,920 --> 00:00:24,820
+بسم الله الرحمن الرحيم اليوم إذا أردنا بنكمل في ال
+
+2
+00:00:24,820 --> 00:00:28,700
+precipitation reactions أو ال titrations سنتكلم
+
+3
+00:00:28,700 --> 00:00:32,160
+بشكل أساسي عن ال precipitation titrations لكن قبل
+
+4
+00:00:32,160 --> 00:00:35,720
+ما نبدأ، بس في نقطة كانت ضائعة من الحصة
+
+5
+00:00:35,720 --> 00:00:41,060
+الماضية، الحصة الماضية كنا نتكلم عن ال solubility
+
+6
+00:00:41,060 --> 00:00:46,310
+في وجود acid solution، وشفنا أن ال solubility تزيد
+
+7
+00:00:46,310 --> 00:00:52,490
+في وجود acid solution لأن ال conjugate base، الجزء
+
+8
+00:00:52,490 --> 00:00:56,050
+من ال salt، اللي على هيئة conjugate base، في وجود
+
+9
+00:00:56,050 --> 00:00:59,150
+acid، إذا كان هذا ال conjugate base ضعيف طبعا، يعني
+
+10
+00:00:59,150 --> 00:01:05,730
+جاي من weak acid، فبيتجزأ في وجود acid، نظرا لأنه
+
+11
+00:01:05,730 --> 00:01:09,890
+بيكون species مختلفة، فبنستخدم ال alpha values
+
+12
+00:01:09,890 --> 00:01:17,620
+لِحَلّ ال solubility problems، قلنا أيضا أنه في
+
+13
+00:01:17,620 --> 00:01:23,140
+وجود complexing agent، أيضا ال metal ion يتجزأ و
+
+14
+00:01:23,140 --> 00:01:29,740
+بيكون جزء منه يبقى free، جزء منه يكون complex مع
+
+15
+00:01:29,740 --> 00:01:33,820
+one ligand أو complex مع two ligands أو complex مع
+
+16
+00:01:33,820 --> 00:01:38,400
+three ligands أو four ligands حسب نوع ال metal ion
+
+17
+00:01:38,400 --> 00:01:49,190
+و حسب نوع ال ligand، أيضا قلنا أن ال Ksp ستساوي ال
+
+18
+00:01:49,190 --> 00:01:57,370
+metal ion مضروب في ال conjugate base، ال Conjugate
+
+19
+00:01:57,370 --> 00:02:00,790
+Base لا يحصل أي تفاعل في وجود الـ Ligand، لأنه الـ
+
+20
+00:02:00,790 --> 00:02:04,290
+Ligand أصلا هو الـ Base، لكن  المثل،  عيِّن، يتجزأ
+
+21
+00:02:04,290 --> 00:02:09,150
+مثلا في الـ Ag Plus، لو حطناه في أمونيا على سبيل
+
+22
+00:02:09,150 --> 00:02:14,570
+المثال، الـ Ag Plus اللي متفكك من الـ AgCl، الجزء
+
+23
+00:02:14,570 --> 00:02:17,150
+منه يبقى على هيئة Ag Plus، الجزء منه يتحول إلى Ag
+
+24
+00:02:17,150 --> 00:02:20,610
+Plus أو الـ Ag Ammonia Plus، الجزء منه يتحول إلى Ag
+
+25
+00:02:20,610 --> 00:02:26,500
+Di Ammonia Plus، فالـ silver سيكون مكافئ أو كل ال
+
+26
+00:02:26,500 --> 00:02:31,300
+silver اللي متفكك من ال AgCl، اللي هو بيساوي ال
+
+27
+00:02:31,300 --> 00:02:35,840
+chloride، ال silver هذه الكمية هي عبارة عن ال
+
+28
+00:02:35,840 --> 00:02:38,040
+silver اللي ما تفككش، زائد ال silver اللي كوّن
+
+29
+00:02:38,040 --> 00:02:41,860
+complex مع ligand واحد، زائد ال silver اللي كوّن
+
+30
+00:02:41,860 --> 00:02:47,440
+complex مع ال two ligands، فجداً موجود عندي من ال
+
+31
+00:02:47,440 --> 00:02:53,840
+silver free، بقول والله beta zero من ال S، إذا كان
+
+32
+00:02:53,840 --> 00:03:01,020
+الكلوريد S، فكل ال silver هو عبارة عن S، Silver بجميع
+
+33
+00:03:01,020 --> 00:03:04,220
+أنواع ال species اللي كوّنها، هو عبارة عن S، طب
+
+34
+00:03:04,220 --> 00:03:07,480
+جداً منه على هيئة AG plus؟ قال والله Beta Zero من
+
+35
+00:03:07,480 --> 00:03:11,840
+ال S، وبالتالي ال S بتساوي جذر ال Ksp على ال Beta
+
+36
+00:03:11,840 --> 00:03:18,720
+Zero، خلينا نطلع على مثال بسيط جداً، بنقول find the
+
+37
+00:03:18,720 --> 00:03:23,520
+solubility of AgBr، ال Ksp له 4×10⁻¹³، طالب ال solubility in a pure water and in 0.1
+
+38
+00:03:23,520 --> 00:03:28,960
+molar ammonia، أعطينا ال beta 0 in 0.1 molar
+
+39
+00:03:28,960 --> 00:03:34,680
+ammonia بتساوي 4×10⁻⁶، طبعا ممكن نعطيها
+
+40
+00:03:34,680 --> 00:03:38,480
+القيمة في الامتحان، نعطيك KF1 و KF2، وأنت بتحسب ال
+
+41
+00:03:38,480 --> 00:03:41,860
+beta 0، يعني هنا ما أعطينا هو ال beta 0، ماشي؟ لكن كان
+
+42
+00:03:41,860 --> 00:03:46,860
+ممكن ما يعطيكش ال beta 0، يعطيك KF1 و KF2، خلاص ال
+
+43
+00:03:46,860 --> 00:03:51,480
+beta 0 طبعا بده تساوي 1 على 1 + KF1 أمونيا
+
+44
+00:03:51,480 --> 00:03:56,100
++ KF1 KF2 أمونيا تربيع، على أي حال، فخلينا الآن
+
+45
+00:03:56,100 --> 00:04:01,610
+نحسب ال solubility في ال pure water في البداية، و
+
+46
+00:04:01,610 --> 00:04:04,310
+بعدين نحسب ال solubility في وجود ال ammonia، ف in a
+
+47
+00:04:09,430 --> 00:04:13,590
+pure water ما فيش عندي أي مشكلة، ال AgBr Ag+ Br-
+
+48
+00:04:13,590 --> 00:04:18,870
+صفر، صفر، S S،  تهيأ الموضوع، إذا ال Ksp بيساوي S
+
+49
+00:04:18,870 --> 00:04:22,870
+تربيعه، وال S بتساوي جذر ال Ksp، يعني بيساوي 6.3×10⁻⁷، ما فيش أي مشكلة في حساب ال
+
+50
+00:04:22,870 --> 00:04:27,030
+solubility in a pure water، ما فيش أي مشكلة، على طول حسب
+
+51
+00:04:27,030 --> 00:04:30,480
+الستوكيومتري، واحد لواحد، يعني S، واحد لواحد، يعني S، يبقى
+
+52
+00:04:34,340 --> 00:04:38,040
+ال Ksp S تربيع، جذر ال Ksp بيساوي ال solubility
+
+53
+00:04:38,040 --> 00:04:41,840
+بتساوي ال 6.3 ×10⁻⁷،  هدفنا إيه في المية
+
+54
+00:04:41,840 --> 00:04:47,000
+المجترة، ال pure النقية؟ إيه كويس، خلينا
+
+55
+00:04:47,000 --> 00:04:50,580
+ناخد بالنا من هذا الرقم اللي احنا توّ حسبناه، نحفظه
+
+56
+00:04:50,580 --> 00:04:56,850
+شوية بس، ثواني، ماذا يحصل في الـ A؟ في الـ Ammonia، في
+
+57
+00:04:56,850 --> 00:05:01,190
+الـ Ammonia، يا شباب؟ واضح أن الـ AgBr تعطينا Ag
+
+58
+00:05:01,190 --> 00:05:05,750
+Plus و Br-، صفر، صفر، طب في الـ Ammonia، إيش
+
+59
+00:05:05,750 --> 00:05:12,130
+بيحصل؟ اه، هذا الـ AgBr، الـ Ag+، بيكون منه
+
+60
+00:05:12,130 --> 00:05:17,890
+بيبقى Ag+، و منه بيكون Ag Ammonia Plus، و
+
+61
+00:05:17,890 --> 00:05:28,590
+منه بيكون Ag Diammonia Plus، كل هدول بيساوي
+
+62
+00:05:28,590 --> 00:05:32,710
+ال S، ال Br- طبعا بتساوي ال S، لكن أنا ما بدّيش كل هدول
+
+63
+00:05:32,710 --> 00:05:37,070
+أنا بدّي بس ال silver plus، إيش بيساوي؟ جزء من هذا
+
+64
+00:05:37,070 --> 00:05:42,210
+الكل، إيش هذا الجزء؟ بيتّخذ من ال S، صحيح؟
+
+65
+00:05:43,910 --> 00:05:46,910
+واضح بالنسبة أن الـ Ksp يساوي الـ Beta Zero من الـ S
+
+66
+00:05:46,910 --> 00:05:50,850
+في الـ S، يعني الـ S بتساوي الجذر التربيعي للـ Ksp
+
+67
+00:05:50,850 --> 00:05:54,990
+على الـ Beta Zero، يعني الـ S بتساوي 3.2 ×10⁻⁴ مولر
+
+68
+00:05:54,990 --> 00:05:59,210
+لما نيجي نقارن هذا الرقم بالرقم اللي حسبنا لل
+
+69
+00:05:59,210 --> 00:06:03,890
+solubility in pure water اللي هو 6.3 ×10⁻⁷، بنلاحظ
+
+70
+00:06:03,890 --> 00:06:07,850
+أنه فرق كبير، لكن احنا قلنا برضه كمان ما بدناش نحسب
+
+71
+00:06:08,410 --> 00:06:12,390
+أرقام مجردة، أو يعني نقارن بين أرقام مجردة، خليني
+
+72
+00:06:12,390 --> 00:06:15,990
+أحسب ال percent increase in solubility، بيساوي ال
+
+73
+00:06:15,990 --> 00:06:19,470
+solubility الجديدة ناقص الأصلية على الأصلية × 100
+
+74
+00:06:19,470 --> 00:06:26,210
+%، بيعطيني 5.1 ×10⁴ %، 51 ألف مرة في المئة
+
+75
+00:06:26,210 --> 00:06:32,050
+كمية زيادة في ال solubility تعتبر يعني كبيرة جداً
+
+76
+00:06:32,050 --> 00:06:36,670
+جداً، كمية الزيادة في ال solubility تعتبر كمية كبيرة
+
+77
+00:06:36,670 --> 00:06:44,250
+جداً جداً، طبعا من هذا الكلام ممكن نستنتج، نقول أن ال
+
+78
+00:06:44,250 --> 00:06:47,110
+solubility في وجود acid أو ال solubility في وجود
+
+79
+00:06:47,110 --> 00:06:52,790
+complexing agent بتكون كبيرة للغاية، كبيرة للغاية
+
+80
+00:06:52,790 --> 00:06:56,070
+يعني الزيادة في ال solubility بالنسبة للمية بتكون
+
+81
+00:06:56,070 --> 00:07:01,590
+زيادة محسوسة بشكل كبير جداً، عشان ما ناخدش يعني
+
+82
+00:07:01,590 --> 00:07:05,930
+تكرار في الأمثلة، بنقول مثلا إننا ناخد حاجة زي ال
+
+83
+00:07:05,930 --> 00:07:09,650
+cadmium sulfide أو copper sulfide على سبيل المثال
+
+84
+00:07:09,650 --> 00:07:14,990
+لأنك أخذته قبل هيك، ال copper sulfide هذا بيتفكك، بيعطينا
+
+85
+00:07:14,990 --> 00:07:21,110
+Cu²+ زائد sulfide، لو حطينا هذا الكلام في أمونيا، هذا
+
+86
+00:07:21,110 --> 00:07:29,050
+ال copper بيكون Cu Ammonia، Cu Di Ammonia
+
+87
+00:07:33,190 --> 00:07:43,730
+Cu Tri Ammonia، Cu Tetra Ammonia، بيهمنّيش كل هذا، كل
+
+88
+00:07:43,730 --> 00:07:50,010
+هدول، إذا كان هذا S، فكل هدول بيساووا إيش؟ S، إذا
+
+89
+00:07:50,010 --> 00:07:52,970
+ال S، كان هذا S، أنا اللي بيهمني بس حاجة واحدة، هذا
+
+90
+00:07:52,970 --> 00:07:57,090
+beta zero من ال S فقط، هو اللي بيهمني، إيش beta
+
+91
+00:07:57,090 --> 00:08:02,470
+zero؟ beta zero بتساوي 1 على 1 + KF1 أمونيا
+
+92
+00:08:02,470 --> 00:08:05,690
++ KF1 KF2 أمونيا تربيع + KF1
+
+93
+00:08:05,690 --> 00:08:09,490
+KF2 KF3 أمونيا تكعيب + KF1 KF2 KF3
+
+94
+00:08:09,490 --> 00:08:13,410
+KF4 أمونيا أس 4، عرفنا كيف بنجيب ال beta 0 و ال
+
+95
+00:08:13,410 --> 00:08:16,690
+beta 1 و ال beta 2 by inspection، بمجرد النظر
+
+96
+00:08:16,690 --> 00:08:21,450
+عرفنا كيف نعمل هذا الكلام بمجرد النظر، لكن أنا قلت
+
+97
+00:08:21,450 --> 00:08:24,750
+أن ال alpha أكثر من ال alpha 2، أنا بعطيه قيمتها
+
+98
+00:08:25,400 --> 00:08:29,500
+وال beta 0، إذا كان عندك أكثر من two formation
+
+99
+00:08:29,500 --> 00:08:33,020
+constants، أنا برضه بعطيك قيمتها، يعني مش راح أخليك
+
+100
+00:08:33,020 --> 00:08:36,520
+تستخدم أربعة formation constants، بس اثنين، زي ال
+
+101
+00:08:36,520 --> 00:08:39,400
+silver مع ال ammonia، اثنين، تقدر تحسبها أنت
+
+102
+00:08:39,400 --> 00:08:44,100
+لكن أربعة مش هخليك تحسبها، إذا على طول ال Ksp إيش
+
+103
+00:08:44,100 --> 00:08:52,980
+بده يساوي برضه beta 0 × S، مش هيك؟ طيب، كمان حاجة
+
+104
+00:08:52,980 --> 00:08:57,460
+أنا حابب أنك تأخذ بالك منها، لو عندي silver
+
+105
+00:08:57,460 --> 00:09:02,320
+sulfide، هذا عبارة عن راسب sparingly soluble salt
+
+106
+00:09:02,320 --> 00:09:07,820
+بقى أنا 2Ag⁺ + sulfide، بقول هذا طبعا
+
+107
+00:09:07,820 --> 00:09:11,960
+بيتجزأ، مش هيك ولا لأ؟ في وجود ال ammonia، إذا هذا إيش
+
+108
+00:09:11,960 --> 00:09:16,940
+بده يكون؟ إذا كان هذا S، هذا إيش بده يكون في الأصل؟
+
+109
+00:09:16,940 --> 00:09:22,440
+2S، لكن هو بس بيتّخذ من ال 2S، beta zero من
+
+110
+00:09:22,440 --> 00:09:27,080
+إيه؟ عشان هيك لما نقول Ksp، بده نقول ال silver إيش؟
+
+111
+00:09:27,080 --> 00:09:33,260
+ال silver بيساوي؟ beta zero من ال 2S الكل تربيع
+
+112
+00:09:33,260 --> 00:09:37,080
+لأن هذا ال silver 2، 2 silver، تاخد بالك
+
+113
+00:09:37,080 --> 00:09:41,340
+مش بس ال 2S تربيع، لأ، لأنه تركيز ال silver beta
+
+114
+00:09:41,340 --> 00:09:46,190
+zero من ال 2S، التركيز تربيع، هاي ال Ksp هي التركيز
+
+115
+00:09:46,190 --> 00:09:49,290
+تربيع ال silver تربيع، يعني تركيز ال silver تربيع
+
+116
+00:09:49,290 --> 00:09:56,130
+فال Ksp ده (2S) الكل تربيع × S، تاخد بالك، يعني مش
+
+117
+00:09:56,130 --> 00:09:59,890
+ضروري ناخد مسألة حسابية على هذا الكلام، هو بس تطبيق
+
+118
+00:09:59,890 --> 00:10:07,890
+مباشر على الكلام اللي درسناه قبل شوية، طيب
+
+119
+00:10:07,890 --> 00:10:14,700
+يا شباب، خلينا الآن ننتقل إلى ال precipitation
+
+120
+00:10:14,700 --> 00:10:18,980
+titrations، اللي هو الموضوع الأساسي في ال chapter
+
+121
+00:10:18,980 --> 00:10:24,560
+هذا، بنقول
+
+122
+00:10:24,560 --> 00:10:28,000
+ال precipitation titrations من الموضوعات المهمة
+
+123
+00:10:28,000 --> 00:10:33,600
+جداً، و البسيطة جداً في نفس الوقت، بسيطة جداً لأنه
+
+124
+00:10:35,050 --> 00:10:38,750
+يعني عدد المواد اللي يمكن تعيينها باستخدام ال
+
+125
+00:10:38,750 --> 00:10:43,390
+precipitation titrations، عدد قليل، عدد محدود، عدد
+
+126
+00:10:43,390 --> 00:10:49,560
+محدود، أكثر من هيك، يعني كان ممكن الكثير من الناس يسموا
+
+127
+00:10:49,560 --> 00:10:55,280
+هذا الجزء من العلم أو ال precipitation، ممكن يسموها
+
+128
+00:10:55,280 --> 00:10:59,280
+argentometric precipitation، يعني معايرات الفضة،
+
+129
+00:10:59,280 --> 00:11:02,360
+إيش معناه بيسموها معايرات الفضة؟ ليش ال
+
+130
+00:11:02,360 --> 00:11:06,210
+precipitation titrations  كثير من الناس؟ في الكتب
+
+131
+00:11:06,210 --> 00:11:10,670
+المختلفة، ممكن تسميها argentometric titrations، لأن
+
+132
+00:11:10,670 --> 00:11:16,370
+لأنها من أنجح ال precipitation titrations، معايرات
+
+133
+00:11:16,370 --> 00:11:21,950
+الفضة مع أربعة من الأيونات: الكلورايد، البروميد،
+
+134
+00:11:21,950 --> 00:11:26,710
+الايودايد، عارفينهم هدول، بالإضافة لهم التيوسيانيت،
+
+135
+00:11:26,710 --> 00:11:31,290
+يبقى هاي أربعة أشياء كانت بتُعاير، بتُعاير بشكل ممتاز
+
+136
+00:11:31,290 --> 00:11:35,620
+مع ال silver، هل معنى الكلام إنه ما فيش precipitation
+
+137
+00:11:35,620 --> 00:11:40,260
+titrations ثانية؟ لأ، موجود، لكن للأسف قليل جداً
+
+138
+00:11:40,260 --> 00:11:45,900
+جداً، طب إيش اللي بيخلي عدد التفاعلات اللي يمكن
+
+139
+00:11:45,900 --> 00:11:49,340
+استخدامها ك precipitation و titration reactions
+
+140
+00:11:49,340 --> 00:11:57,120
+قليل، مع إنه هناك كم هائل من التفاعلات اللي تعتبر
+
+141
+00:11:57,120 --> 00:12:01,820
+quantitative، تعتبر no side reactions، تعتبر very
+
+142
+00:12:01,820 --> 00:12:07,890
+fast، يعني كل تفاعلات المعايرة تنطبق عليها ال
+
+143
+00:12:07,890 --> 00:12:12,230
+conditions، والظروف والشروط لتفاعل المعايرة تنطبق
+
+144
+00:12:12,230 --> 00:12:16,870
+عليها، انطباق ممتاز، طب إيش معناه؟ إيش معناه لا
+
+145
+00:12:16,870 --> 00:12:21,570
+تُستخدم كتفاعلات معايرة؟ لأن المشكلة مش فيها، المشكلة
+
+146
+00:12:21,570 --> 00:12:25,330
+مش في خصائصها، المشكلة في إن احنا ما فيش عندنا
+
+147
+00:12:25,330 --> 00:12:31,620
+indicators مناسبة لها، والسبب إنه تفاعلات معايرات
+
+148
+00:12:31,620 --> 00:12:34,580
+الفضة مع الأربع أيونات: الكلورايد، البروميد،
+
+149
+00:12:34,580 --> 00:12:38,640
+الايودايد، والثلاث أيونات ناجحة، لأنه موجود لها
+
+150
+00:12:38,640 --> 00:12:44,900
+indicators مناسبة، أخذنا بالنا، موجود لمعايرات الفضة
+
+151
+00:12:44,900 --> 00:12:48,960
+indicators مناسبة، بينما مش موجود للمعاييرات الأخرى
+
+152
+00:12:48,960 --> 00:12:53,660
+بشكل عام، indicators مناسبة إلا عدد قليل من ال
+
+153
+00:12:53,660 --> 00:12:58,460
+precipitation reactions، لهذا السبب يمكن احنا من
+
+154
+00:12:58,460 --> 00:13:04,380
+خلال دراستنا لل precipitation reactions أو ال
+
+155
+00:13:04,380 --> 00:13:09,550
+argentometric reactions، معايرات الفضة، بنلاحظ، في
+
+156
+00:13:09,550 --> 00:13:15,030
+عندنا ثلاث طرق رئيسية: طريقة Mohr، وطريقة Fajans،
+
+157
+00:13:15,030 --> 00:13:19,110
+وطريقة Volhard، لو قلنا إيش هالطرق هذه؟ بنلاحظ أن هي
+
+158
+00:13:19,110 --> 00:13:25,230
+في الحقيقة مش طرق يعني غريبة، ولا هي طرق يعني خاصة،
+
+159
+00:13:25,230 --> 00:13:30,930
+هي عبارة عن طرق تستخدم indicators معينة، يعني سمينا
+
+160
+00:13:30,930 --> 00:13:36,310
+الطريقة باسم الشخص اللي اكتشف ال indicator المناسب،
+
+161
+00:13:37,390 --> 00:13:41,670
+فمثلا Mohr method بيستخدم potassium chromate، هي معايرة
+
+162
+00:13:41,670 --> 00:13:45,650
+مباشرة، بيستخدم chromate ك indicator، فـ Fajans method
+
+163
+00:13:45,650 --> 00:13:48,650
+بيستخدم fluorescein مثلا، أو  adsorption
+
+164
+00:13:48,650 --> 00:13:54,070
+indicators زي fluorescein و مشتقاته، فسميت يعني هو
+
+165
+00:13:54,070 --> 00:13:59,070
+اكتشف بس ال indicator، لكن سميت الآن طريقة باسمه،
+
+166
+00:13:59,070 --> 00:14:02,910
+ال Volhard method، نفس الكلام، اكتشف ال indicator
+
+167
+00:14:02,910 --> 00:14:10,670
+اللي هو ال iron(III) على سبيل المثال، فهذه الطرق
+
+168
+00:14:10,670 --> 00:14:16,390
+كلها تستخدم لتعيين بشكل أساسي كمية الكلورايد في
+
+169
+00:14:16,390 --> 00:14:20,630
+المحاليل المختلفة، طيب
+
+170
+00:14:21,230 --> 00:14:25,290
+برضه وإحنا بنتكلم عن ال titration curves، إيه كويس
+
+171
+00:14:25,290 --> 00:14:31,710
+نتكلم عن شكل ال titration curve، شكل ال titration
+
+172
+00:14:31,710 --> 00:14:34,650
+curve، ال titration curve اللي بيهمنّا
+
+223
+00:18:41,740 --> 00:18:49,320
+لاحظ الـ curve A اللي هو أكبر jump، التركيز كان واحد
+
+224
+00:18:49,320 --> 00:18:52,560
+من عشرة molar silver nitrate وواحد من عشرة molar
+
+225
+00:18:52,560 --> 00:18:57,520
+chloride، يعني التركيز واحد من عشرة molar، للـ curve B
+
+226
+00:18:57,520 --> 00:19:03,700
+الـ jump أقل، من hand ل hand، هذه مثلاً من هان لهان
+
+227
+00:19:03,700 --> 00:19:10,100
+هذا من هان لهان أقل
+
+228
+00:19:10,100 --> 00:19:19,780
+هذا واحد من عشرة، هذا واحد من مية، طيب نيجي لهذا واحد
+
+229
+00:19:19,780 --> 00:19:26,680
+من الألف، فلاحظ أنت واحد من ألف molar silver nitrate
+
+230
+00:19:26,680 --> 00:19:30,780
+مع واحد من ألف molar chloride، أعطاني jump صغيرة
+
+231
+00:19:31,710 --> 00:19:37,530
+بينما لما زوّدت التركيز، استخدمت واحد من مية وواحد
+
+232
+00:19:37,530 --> 00:19:41,890
+من عشر، الـ jump زادت لما زوّدت التركيز أكثر، واحد من
+
+233
+00:19:41,890 --> 00:19:45,570
+عشرة وواحد من عشر، الـ jump ايش مالها؟ زادت بشكل كبير
+
+234
+00:19:45,570 --> 00:19:53,730
+علشان هيك بقدر أقول، يعني بدون أي تردد أن والله لما
+
+235
+00:19:53,730 --> 00:20:00,960
+تزيد التركيزات المتفاعلات، ايش بيحصل للـ jump؟ بتزيد
+
+236
+00:20:00,960 --> 00:20:04,940
+الـ jump، وهذا متوافق مع ما درسناه سابقاً، يعني نفس
+
+237
+00:20:04,940 --> 00:20:08,800
+الكلام شفناه في الـ acid base titrations، وشفناه
+
+238
+00:20:08,800 --> 00:20:14,200
+أيضاً في الـ complexometric titrations، في كمان
+
+239
+00:20:14,200 --> 00:20:18,840
+ملاحظة عندي، بقدر أقول أنه في حالة الـ precipitation
+
+240
+00:20:18,840 --> 00:20:26,070
+titrations، أنا بقدر أعاير mixtures، بقدر أعير
+
+241
+00:20:26,070 --> 00:20:33,490
+mixtures وأحصل منها على، نقول
+
+242
+00:20:33,490 --> 00:20:39,910
+يعني two equivalence points، يعني واحدة للأيون
+
+243
+00:20:39,910 --> 00:20:44,450
+الأول وواحدة ثانية للأيون الثاني، إذا كان شرط إذا
+
+244
+00:20:44,450 --> 00:20:45,750
+كان الـ KSP
+
+245
+00:20:49,690 --> 00:20:57,490
+ألف مرة أو أكثر، يعني مثلاً الـ Ksp للكلوريد على
+
+246
+00:20:57,490 --> 00:21:02,120
+الـ iodide عشرة أس سالب ستة، بلاحظ أنه أه ممكن بسهولة
+
+247
+00:21:02,120 --> 00:21:05,780
+أحصل على end point، two equivalence point للكلوريد و
+
+248
+00:21:05,780 --> 00:21:09,160
+equivalence point للـ iodide، إذا كان عشرة أس
+
+249
+00:21:09,160 --> 00:21:13,080
+ثلاثة فأكثر، نعم يمكن الحصول على equivalence point
+
+250
+00:21:13,080 --> 00:21:19,620
+لكل واحد منهم، متميزة عن الأخرى تماماً، يعني بقدر
+
+251
+00:21:19,620 --> 00:21:25,180
+أعين كل واحد، لو كان الفرق بين الـ KSPs أقل من عشرة
+
+252
+00:21:25,180 --> 00:21:28,800
+أس ثلاثة، بلاحظ أنه الـ end point الثاني بتكونش
+
+253
+00:21:30,580 --> 00:21:34,500
+واضحة، ممكن ما تكونش موجودة أو أنها ما تكونش واضحة،
+
+254
+00:21:34,500 --> 00:21:41,800
+كويس؟  ل Ksp واحد، Ksp اثنين، لو كانت أقل من
+
+255
+00:21:41,800 --> 00:21:45,560
+الألف، ممكن يعني كل ما قلت كل ما كانت مش واضحة، لو
+
+256
+00:21:45,560 --> 00:21:48,680
+كان عشرة أس ثلاثة مثلاً، ممكن نلاقيها والله صارت
+
+257
+00:21:48,680 --> 00:21:52,870
+حاجة زي هيك، مش مبينة هذه الـ equivalence point
+
+258
+00:21:52,870 --> 00:21:57,330
+الثانية، مبينة كأنها نفس الـ titration curve ممتدة
+
+259
+00:21:57,330 --> 00:22:02,430
+على أي حال، فعلشان أحصل على distinct equivalence
+
+260
+00:22:02,430 --> 00:22:08,410
+points، لازم Ksp1 على Ksp2 تكون عشرة أس ثلاثة فأكثر
+
+261
+00:22:08,410 --> 00:22:15,330
+الآن يا شباب، خلينا نأخذ مثال على الـ titration
+
+262
+00:22:15,330 --> 00:22:21,910
+curve وطريقة بنائه، يعني عملية معايرة، من خلالها نقدر
+
+263
+00:22:21,910 --> 00:22:27,150
+نبني الـ titration curve، فنتطلع على معايرة 20 مل
+
+264
+00:22:27,150 --> 00:22:35,990
+من 0.1 مولر كلوريد مع
+
+265
+00:22:35,990 --> 00:22:43,710
+0.1 مولر سلفر، علشان أقدر أبني الـ titration curve
+
+266
+00:22:43,710 --> 00:22:51,580
+هذه مل AgNO3، وهي هنا pX، طبعاً بإمكاني أقول
+
+267
+00:22:51,580 --> 00:22:56,540
+والله pAg، لكن في هذه الحالة الـ curve يبدأ من فوق
+
+268
+00:22:56,540 --> 00:23:00,420
+لأ، أنا بدي أشتغل pX مثلاً، أي واحدة بتختارها صحيحة
+
+269
+00:23:00,420 --> 00:23:06,200
+مافيش مشكلة، فإيش المثال بيقول؟ find the pCl، عشان
+
+270
+00:23:06,200 --> 00:23:13,260
+هيك أنا كتبت الـ pX أو الـ pCl، هي pCl = minus log
+
+271
+00:23:13,260 --> 00:23:18,890
+تركيز الـ chloride، In a 20 ml of a 0.1 molar
+
+272
+00:23:18,890 --> 00:23:22,470
+chloride solution after addition of 0, 10, 20 and
+
+273
+00:23:22,470 --> 00:23:26,450
+30 ml of 0.1 molar silver nitrate، فأنا بضيف silver
+
+274
+00:23:26,450 --> 00:23:30,550
+nitrate، صفر، عشرة، عشرين، وثلاثين مل، وكل مرة بدي
+
+275
+00:23:30,550 --> 00:23:35,830
+أحسب الـ pCl، بقول ببساطة خالص، أول إضافة، after
+
+276
+00:23:35,830 --> 00:23:40,290
+addition of 0 ml، طبعاً الكلوريد موجودة في المحلول، واحد من
+
+277
+00:23:40,290 --> 00:23:43,850
+عشرة مولار زي ما هو، إذا تركيز واحد من عشرة مولار، والـ p
+
+278
+00:23:43,850 --> 00:23:47,550
+للـ كلوريد = minus log واحد من عشرة، يعني واحد، يبقى هذه أول
+
+279
+00:23:47,550 --> 00:23:56,290
+نقطة، هذه أول نقطة عند 0 مل من الـ Ag+، طيب تعالوا
+
+280
+00:23:56,290 --> 00:24:00,770
+نضيف 10 مل، بقول والله لما نضيف 10 مل من الـ Ag+
+
+281
+00:24:00,770 --> 00:24:05,050
+أنا عندي الكلوريد 0.1 في 20، يعني 2 ميلي مول، أضفت
+
+282
+00:24:05,050 --> 00:24:10,130
+عليهم 10 مل من السلفر، يعني 0.1 في 10، يعني 1 ميلي
+
+283
+00:24:10,130 --> 00:24:15,660
+مول كلوريد left، بدي أساوي 2 ناقص 1، يعني 1
+
+284
+00:24:15,660 --> 00:24:22,260
+الكلوريد left، واحد على عشرين وعشرة، ثلاثين، لكن أنا
+
+285
+00:24:22,260 --> 00:24:24,840
+بدي تركيز الكلوريد في المحلول، تركيز الكلوريد في
+
+286
+00:24:24,840 --> 00:24:28,640
+المحلول بيساوي واحد على ثلاثين، اللي هو الزايد
+
+287
+00:24:28,640 --> 00:24:34,240
+المتبقي من الكلوريد، لكن أنا لما حطيت silver على
+
+288
+00:24:34,240 --> 00:24:38,180
+الكلوريد، اتكون silver chloride، وبالتالي جزء من
+
+289
+00:24:38,180 --> 00:24:42,220
+الـ silver chloride بيتفكك، جزء من الـ silver chloride
+
+290
+00:24:42,220 --> 00:24:47,420
+بيعطيني كلوريد جديد، بيعطيني من الكلوريد S، ومن
+
+291
+00:24:47,420 --> 00:24:51,500
+السلفر طبعاً S، فأنا بقول كيف بده أحسب كل كلوريد
+
+292
+00:24:51,500 --> 00:24:53,740
+اللي في المحلول؟ قال والله واحد على ثلاثين، اللي هو
+
+293
+00:24:53,740 --> 00:24:58,520
+المتبقي زائد اللي جاي من الـ silver chloride، يعني S
+
+294
+00:24:58,520 --> 00:25:05,580
+لكن أنا بقول لكم من هالجهة، أنه جداش الـ KSP لهذا الـ
+
+295
+00:25:05,580 --> 00:25:10,050
+equilibrium، قال الـ Ksp بده يساوي عشرة أس سالب عشرة
+
+296
+00:25:10,050 --> 00:25:16,070
+صح، فجداش متوقع تكون تفكك، وجداش الـ S بده تكون كمية
+
+297
+00:25:16,070 --> 00:25:21,090
+مهملة، كمية ايش مالها؟ مهملة، طيب أنا بقول مش بس هيك
+
+298
+00:25:21,090 --> 00:25:26,370
+مش بس هيك، لما يكون في عندي زيادة من الكلوريد، آه
+
+299
+00:25:26,370 --> 00:25:29,890
+يبدأ التفاعل ايش ماله؟ بده يرجع كمان لورا كتير
+
+300
+00:25:29,890 --> 00:25:33,840
+معنى الكلام، الـ S دي إلها قيمة؟ هتكون ما إلها قيمة
+
+301
+00:25:33,840 --> 00:25:39,800
+ومع ذلك احنا هنحسبها، فبنقول الـ Ksp بتساوي الـ S في
+
+302
+00:25:39,800 --> 00:25:44,880
+واحد على 30 زائد S، نفترض الـ 31 أكبر كتير من الـ S، إذا
+
+303
+00:25:44,880 --> 00:25:49,980
+الـ S بتطلع أنه 3 في 10 أس سالب 9، هل الفرضية صحيحة؟
+
+304
+00:25:49,980 --> 00:25:55,450
+العشرة أس سالب 9 أقل كتير من الواحد على 30؟ طبعاً، يعني هذا
+
+305
+00:25:55,450 --> 00:25:58,290
+كلام مش أكيد، عشان هيك حتى نرجع نقول إنهم مش
+
+306
+00:25:58,290 --> 00:26:03,630
+حاسبينه، إذا الكلوريد اللي هنحسبها بدنا نساوي واحد على 30
+
+307
+00:26:03,630 --> 00:26:07,490
+زائد الـ S، يعني الـ S هذه ولا حاجة، يعني واحد على 30 أو
+
+308
+00:26:07,490 --> 00:26:17,470
+الـ pCl 1.48، يبقى هيو 1.48، ماشي يا شباب، يبقى عند
+
+309
+00:26:17,470 --> 00:26:26,350
+إضافة 10 مل من الـ silver كان الـ pCl 1.48، طيب نيجي
+
+310
+00:26:26,350 --> 00:26:29,610
+يا شباب، هذا قبل نقطة النهاية، أي رقم قبل نقطة
+
+311
+00:26:29,610 --> 00:26:33,770
+النهائية، بنفس الطريقة، بينشغل أي رقم، دائماً الـ Ksp
+
+312
+00:26:33,770 --> 00:26:37,130
+صغير جداً، يعني الـ S قليلة، ودائماً قبل نقطة النهاية
+
+313
+00:26:37,130 --> 00:26:39,590
+عندك كلوريد زيادة، معناه كل ما تفكر يرجع لورا
+
+314
+00:26:39,590 --> 00:26:44,000
+يبقى الـ S أكيد قليلة كتير، شبق يعني ملغية دائماً، طيب
+
+315
+00:26:44,000 --> 00:26:47,580
+نيجي نشتغل عند عشرين مل من الـ silver، بقول يعني أنا
+
+316
+00:26:47,580 --> 00:26:50,040
+عندي 2 millimole chloride، حطيت عليهم 2
+
+317
+00:26:50,040 --> 00:26:53,660
+millimole silver، معناه كده millimole chloride left
+
+318
+00:26:53,660 --> 00:26:57,660
+صفر، يبقى هذه هي الـ equivalence point، لا عندي
+
+319
+00:26:57,660 --> 00:27:01,140
+كلوريد ولا عندي silver خلص، طيب أنا بدي أحسب
+
+320
+00:27:01,140 --> 00:27:06,860
+جداشه؟ عندي chloride، مفيش حساب إلا عن طريق الـ Ksp أو
+
+321
+00:27:06,860 --> 00:27:11,560
+جاي الكلوريد فقط من تفكك الـ silver chloride
+
+322
+00:27:11,560 --> 00:27:18,220
+فهنا عندي، 0، قبل الإتزان، بعد الإتزان، S، S، يبقى الـ
+
+323
+00:27:18,220 --> 00:27:22,440
+Ksp بتساوي الـ S تربيع، أو الـ S بتساوي عشرة أس سالب
+
+324
+00:27:22,440 --> 00:27:27,500
+خمسة، يعني الـ p للـ Cl، طبعاً الـ S هي الكلوريد، الـ p
+
+325
+00:27:27,500 --> 00:27:35,070
+للـ Cl بتساوي 5،  minus log 10 أس سالب 5، يعني خمسة، طيب نيجي
+
+326
+00:27:35,070 --> 00:27:39,850
+نضيف حجم بعد الـ equivalence point، وأي حجم بعد الـ
+
+327
+00:27:39,850 --> 00:27:44,090
+equivalence point برضه بنفس الطريقة، فبقول أنا عند
+
+328
+00:27:44,090 --> 00:27:49,090
+2 ملي مول كلوريد، أنا عندي 2 ملي مول كلوريد
+
+329
+00:27:49,090 --> 00:27:50,490
+أنا عندي 2 ملي مول كلوريد، أنا عندي 2 ملي مول
+
+330
+00:27:50,490 --> 00:27:53,150
+كلوريد، أنا عندي 2 ملي مول كلوريد، أنا عندي 2
+
+331
+00:27:53,150 --> 00:27:56,950
+ملي مول كلوريد، أنا عندي 2 ملي مول كلوريد، أنا
+
+332
+00:27:56,950 --> 00:27:59,870
+عندي 2 ملي مول كلوريد، أنا عندي 2 ملي مول
+
+333
+00:27:59,870 --> 00:28:00,430
+كلوريد، أنا عندي 2 ملي مول كلوريد، أنا عندي 2
+
+334
+00:28:00,430 --> 00:28:02,260
+ملي مول كلوريد، أنا عندي 2 ملي، طيب أنا ما بدي، أنا
+
+335
+00:28:02,260 --> 00:28:06,180
+بدي كلوريد كمية، بدي أحسب الكلوريد، لأن المطلوب
+
+336
+00:28:06,180 --> 00:28:09,460
+مني أحسب الكلوريد، طيب ايش مصدر الكلوريد؟ ما هو
+
+337
+00:28:09,460 --> 00:28:12,240
+ما فيش عندي أي مصدر للكلوريد إلا الـ silver chloride
+
+338
+00:28:12,240 --> 00:28:15,320
+فباجي بقول، انتبهوا عليها، هذه الـ silver اللي فيه
+
+339
+00:28:15,320 --> 00:28:18,380
+وقت الـ silver والـ chloride، الـ silver الزيادة
+
+340
+00:28:18,380 --> 00:28:25,630
+0.02 هنا، 0.02 زائد S، S، لكن بدي أذكركم هذا
+
+341
+00:28:25,630 --> 00:28:30,050
+الـ Ksp له عشرة أس سالب عشرة، مع الكلام الـ S هذه ايش
+
+342
+00:28:30,050 --> 00:28:34,010
+مالها؟ مهملة، مش بس هيك لما نكون في عندنا common ion
+
+343
+00:28:34,010 --> 00:28:39,310
+هنا، بخلي التفاعل ايش ماله؟ يرجع لورا خالص، يعني الـ S
+
+344
+00:28:39,310 --> 00:28:44,750
+مهملة جداً جداً جداً، لا تكاد تذكر بالنسبة للـ 0.02
+
+345
+00:28:44,750 --> 00:28:48,890
+فهل الـ Ksp يساوي 0.02 زائد S في S، افترض أن الـ
+
+346
+00:28:48,890 --> 00:28:52,530
+0.02 أكبر كتير من الـ S، إذا الـ S بتطلع خمسة في
+
+347
+00:28:52,530 --> 00:28:56,290
+عشرة أس سالب تسعة، كمان مرة، هل العشرة أس سالب تسعة
+
+348
+00:28:56,290 --> 00:29:00,290
+بالفعل أقل كتير من الـ 0.02، طبعاً أقل كتير من الـ
+
+349
+00:29:00,290 --> 00:29:04,130
+... هذا بوضع طبيعي، ودائماً بعد نقطة النهاية هذا هو
+
+350
+00:29:04,130 --> 00:29:09,290
+الحال يا شباب، لأن الـ Ksp دائماً صغير جداً جداً، إذا
+
+351
+00:29:09,290 --> 00:29:17,970
+ايش هي الـ S؟ الـ S هي الكلوريد، معنى الكلام الـ
+
+352
+00:29:17,970 --> 00:29:22,250
+p للـ Cl 8.3، يبقى هذه 8.3
+
+353
+00:29:22,250 --> 00:29:23,250
+ما أقدر أقول
+
+354
+00:29:26,030 --> 00:29:30,990
+هذا هو الـ titration curve اللي عندي، ماشي يا شباب؟
+
+355
+00:29:30,990 --> 00:29:35,490
+إذا أنا بقدر أقول حاجة، بقدر أقول أنه يعني بناء الـ
+
+356
+00:29:35,490 --> 00:29:37,470
+titration curve في حالة الـ precipitation
+
+357
+00:29:37,470 --> 00:29:42,310
+titrations، يعني من أبسط أنواع الـ titration curves
+
+358
+00:29:42,310 --> 00:29:46,070
+اللي ممكن نطلع عليها، حتى أسهل من الـ strong acid والـ
+
+359
+00:29:46,070 --> 00:29:51,090
+strong bases، مباشرة للغاية، مباشرة للغاية، ما فيش
+
+360
+00:29:51,090 --> 00:29:56,720
+فيها أي مشاكل، قبل نقطة النهاية في عندي زيادة من الـ
+
+361
+00:29:56,720 --> 00:30:03,660
+كلوريد، مثلاً عند نقطة النهاية من تفكك الـ AgCl، بعد
+
+362
+00:30:03,660 --> 00:30:06,930
+نقطة النهاية في عندي زيادة من الـ silver، ولما نحسب
+
+363
+00:30:06,930 --> 00:30:10,630
+الـ S في الحالتين، سنجدها مهملة، لأن الـ Ksp أصلاً
+
+364
+00:30:10,630 --> 00:30:13,930
+صغير كتير، في وجود الـ common ion، قبل نقطة النهاية
+
+365
+00:30:13,930 --> 00:30:17,170
+الكلوريد، وبعد نقطة النهاية الـ silver، التفاعل بيرجع
+
+366
+00:30:17,170 --> 00:30:23,050
+لورا بشكل كبير، معنى الكلام ما فيش أي قيمة للـ S
+
+367
+00:30:23,050 --> 00:30:28,490
+وبالتالي يمكن استخدام الكلوريد left أو الـ Ag
+
+368
+00:30:28,490 --> 00:30:34,790
+plus excess كأساس لحساب الكلوريد في المحلول
+
+369
+00:30:37,370 --> 00:30:41,770
+طيب يا شباب، هذا هو شكل الـ titration curve، اللي لو
+
+370
+00:30:41,770 --> 00:30:45,470
+اشتغلنا عدة نقاط، هيطلع معنا نفس الـ titration curve
+
+371
+00:30:45,470 --> 00:30:51,250
+اللي احنا شايفينه، وهذا تقريباً 25 نقطة لنفس المسألة
+
+372
+00:30:51,250 --> 00:30:55,790
+لكن يعني طيب
+
+373
+00:30:55,790 --> 00:31:00,690
+نتطلع الآن على الطرق المختلفة لتعيين الكلوريد
+
+374
+00:31:00,690 --> 00:31:07,240
+وبنتكلم فيها عن، طبعاً معايرة الفضة، فبنتكلم عن معايرة
+
+375
+00:31:07,240 --> 00:31:12,400
+الفضة مع الكلوريد، فبقول في عندي ثلاث طرق رئيسية
+
+376
+00:31:12,400 --> 00:31:17,260
+فبقول أول طريقة هي طريقة Mohr، طريقة السيد Mohr
+
+377
+00:31:17,260 --> 00:31:23,120
+بتستخدم الكرومات أو الـ potassium chromate كـ
+
+378
+00:31:23,120 --> 00:31:31,170
+indicator، الـ potassium chromate مع الـ silver بتكون
+
+379
+00:31:31,170 --> 00:31:35,350
+راسب اسمه الـ silver chromate، الـ potassium chromate
+
+380
+00:31:35,350 --> 00:31:43,350
+لونها أصفر، الـ silver chromate راسب أحمر، راسب أحمر
+
+381
+00:31:43,350 --> 00:31:50,850
+فلو أجينا مثلاً شفنا هنا، هذه الكلوريد، وهذه الـ
+
+382
+00:31:50,850 --> 00:31:53,610
+chromate، وهذه الـ silver
+
+383
+00:31:57,300 --> 00:32:08,560
+بس للمعلومات، الـ Ksp للـ Ag2CrO4 بيساوي 1.3 × 10
+
+384
+00:32:08,560 --> 00:32:17,260
+أس سالب 12، والـ Ksp للـ AgCl بدنا نساوي 10 أس سالب عشرة
+
+385
+00:32:17,260 --> 00:32:21,920
+فلما نيجي نضيف silver، مع ايش هيتفاعل؟ هيتفاعل مع
+
+386
+00:32:21,920 --> 00:32:28,950
+الكلوريد ولا
+
+445
+00:36:54,670 --> 00:36:59,390
+عند إيه؟ عند الـ equivalence point يبقى هنـا عندي
+
+446
+00:36:59,390 --> 00:37:05,670
+عند الـ equivalence point الـ silver تركيزه واحد
+
+447
+00:37:05,670 --> 00:37:09,770
+وخمسة وثلاثين في عشرة أس سالب خمسة molar طيب أنا
+
+448
+00:37:09,770 --> 00:37:13,550
+بقول بده يعطيني لون إذا بده يكون إيه؟ بده يكون
+
+449
+00:37:13,550 --> 00:37:17,780
+راسب مع الكرومات عشان يكون راسب مع الـ dichromate أنا
+
+450
+00:37:17,780 --> 00:37:21,320
+بعرف أن اثنين silver مع dichromate بيعطوني silver
+
+451
+00:37:21,320 --> 00:37:25,320
+dichromate طيب الـ KSP بده يساوي الـ silver تربيع في
+
+452
+00:37:25,320 --> 00:37:28,380
+dichromate أنا الـ silver معايا هيو عند الـ
+
+453
+00:37:28,380 --> 00:37:30,920
+equivalence point واحد وخمسة وثلاثين في عشرة أس
+
+454
+00:37:30,920 --> 00:37:34,400
+سالب خمسة بدي إيه يكون راسب يعني الـ KSP بدها
+
+455
+00:37:34,400 --> 00:37:38,740
+تساوي just precipitate الـ silver dichromate silver
+
+456
+00:37:38,740 --> 00:37:43,360
+تربيع في dichromate طيب جدعش بده يكون تركيز dichromate
+
+457
+00:37:43,360 --> 00:37:52,780
+بلاحظ أنـه تركيز الكروميت تركيز الكروميت تركيز الكروميت
+
+458
+00:37:52,780 --> 00:37:55,840
+تركيز الكروميت تركيز الكروميت تركيز الكروميت تركيز
+
+459
+00:37:55,840 --> 00:37:57,400
+الكروميت تركيز الكروميت تركيز الكروميت تركيز الكروميت
+
+460
+00:37:57,400 --> 00:38:00,520
+تركيز الكروميت تركيز الكروميت تركيز الكروميت تركيز
+
+461
+00:38:00,520 --> 00:38:01,380
+الكروميت تركيز الكروميت تركيز الكروميت تركيز الكروميت
+
+462
+00:38:01,380 --> 00:38:01,680
+تركيز الكروميت تركيز الكروميت تركيز الكروميت تركيز
+
+463
+00:38:01,680 --> 00:38:07,600
+الكروميت تركيز الكروميت تركيز الكروميت تركيز
+
+464
+00:38:07,600 --> 00:38:16,400
+الكروم كمية من الـ chloride وكمية مكافئة من الـ silver
+
+465
+00:38:16,400 --> 00:38:22,380
+فالحجم تضاعف يعني الأصل أنه عند بداية الـ
+
+466
+00:38:22,380 --> 00:38:27,300
+titration تركيز الكرومات يكون ضعف هذا يعني هي تركيز
+
+467
+00:38:27,300 --> 00:38:30,420
+الكروميت لما كان الحجم هو عبارة عن حجم الـ chloride
+
+468
+00:38:30,420 --> 00:38:34,180
+زائد حجم الـ silver، حجم كبير، طب في الأصل جدعش كان
+
+469
+00:38:34,180 --> 00:38:37,580
+تركيز الكروميت عشان يوصل لهذا، أي نقطة النهاية،
+
+470
+00:38:37,580 --> 00:38:41,220
+آه، ضعفه، اثنين في سبعة، واحد من عشرة في عشرة أس
+
+471
+00:38:41,220 --> 00:38:45,490
+سالب ثلاثة، يعني بده يكون 0.0142 molar هذا
+
+472
+00:38:45,490 --> 00:38:49,030
+التركيز الـ dichromate الأصلي اللي بده يكون ساعة ما
+
+473
+00:38:49,030 --> 00:38:53,690
+أحطه في المحلول
+
+474
+00:38:53,690 --> 00:38:57,150
+قبل ما أبدأ عملية المعايرة لازم يكون تركيز
+
+475
+00:38:57,150 --> 00:39:01,130
+الـ dichromate هالجد على أي حال بغض النظر بغض النظر
+
+476
+00:39:01,130 --> 00:39:05,310
+بقول معنى الكلام at equivalence point جدعش بده
+
+477
+00:39:05,310 --> 00:39:09,550
+يكون تركيز الـ dichromate  7×10 أس سالب 3 هذا عندي الـ
+
+478
+00:39:09,550 --> 00:39:14,910
+equivalence point ليه؟ علشان يقدر يعطينا الراسب طيب
+
+479
+00:39:14,910 --> 00:39:18,990
+في الحقيقة 7 في 10 أس سالب ثلاثة هذا تركيز عالي
+
+480
+00:39:18,990 --> 00:39:24,210
+جداً ليش عالي جداً؟ لأنه لون dichromate لون أصفر
+
+481
+00:39:24,210 --> 00:39:29,650
+أصفر غامق واللون الأصفر يا شباب لما يبدأ يدوب
+
+482
+00:39:29,650 --> 00:39:32,150
+يتكون أول نقطة تكون لون أحمر مع الـ silver
+
+483
+00:39:32,150 --> 00:39:37,670
+dichromate اللون الأصفر للـ dichromate بيكون غالب كتير
+
+484
+00:39:37,670 --> 00:39:42,910
+على اللون الأحمر بقدرش أشوف اللون الأحمر منه عشان
+
+485
+00:39:42,910 --> 00:39:46,530
+هيك من ناحية عملية أنا ما بستخدمش 7 في 10 أس سالب 3
+
+486
+00:39:46,530 --> 00:39:51,330
+بستخدم بالكثير 2.5 في 10 أس سالب 3 يعني ثلث
+
+487
+00:39:51,330 --> 00:39:56,070
+التركيز يعني أنا بستخدم ثلث تركيز الكرومات طب لما
+
+488
+00:39:56,070 --> 00:40:00,090
+نستخدم ثلث تركيز الكرومات إذا لازم هذا الـ silver
+
+489
+00:40:00,090 --> 00:40:07,350
+ما بكفيش يعطيني أنا لازم أحط كمان silver من البيرويت
+
+490
+00:40:07,350 --> 00:40:12,470
+علشان أحصل على الراسب لأن الكرومات تركيزه واطي أنا
+
+491
+00:40:12,470 --> 00:40:19,890
+عند الـ KSP بتساوي الـ silver تربيع في الكرومات إذا
+
+492
+00:40:19,890 --> 00:40:22,830
+كان هذا التركيز واطي إذا إيش تركيز الـ silver؟ لازم
+
+493
+00:40:22,830 --> 00:40:28,420
+أزيد كيف بدي أزوده؟ بدي أضيف شوية silver إذاً هذا
+
+494
+00:40:28,420 --> 00:40:32,660
+بيؤدي لخطأ لأن أنا أضفت silver زيادة صح ولا لأ؟
+
+495
+00:40:32,660 --> 00:40:34,980
+أنا أضفت silver زيادة عشان أحصل على الـ equivalence
+
+496
+00:40:34,980 --> 00:40:38,620
+point ليش؟ لأن استخدمت تركيزي... تركيزي chromate
+
+497
+00:40:38,620 --> 00:40:42,460
+أقل من اللازم طب ليش أنا أستخدم تركيزي chromate
+
+498
+00:40:42,460 --> 00:40:47,440
+أقل من اللازم؟ لأنه اللون ما بشوفوش منيح إلا أستخدم
+
+499
+00:40:47,440 --> 00:40:51,700
+تركيز أخف طب إيش بتعمل؟ كيف تتغلب على هذا الخطأ؟
+
+500
+00:40:51,700 --> 00:40:57,060
+معظم الناس للأسف ما بتعملش حاجة لكن بقول إنه يمكن
+
+501
+00:40:58,100 --> 00:41:01,540
+التغلب على هذا الخطأ بإنه نعمل a blank experiment
+
+502
+00:41:01,540 --> 00:41:08,980
+a blank titration إيش
+
+503
+00:41:08,980 --> 00:41:13,180
+هي؟ هذا الحجم at equivalence point وعليه الكرومات
+
+504
+00:41:13,180 --> 00:41:17,680
+أو فيه الكرومات؟ بنفس التركيز at equivalence point
+
+505
+00:41:17,680 --> 00:41:21,500
+اللي استخدمناها يعني هذا الحجم at equivalence
+
+506
+00:41:21,500 --> 00:41:24,240
+point موجود فيه الكرومات بنفس التركيز اثنين ونصف
+
+507
+00:41:24,240 --> 00:41:28,660
+في عشرة أس سالب ثلاثة الآن بدنا نعيرها بإيه؟ بالـ
+
+508
+00:41:28,660 --> 00:41:34,540
+silver أول ما أشوف اللون بكون عرفت جدعش أخدت من الـ
+
+509
+00:41:34,540 --> 00:41:39,520
+silver عشان أطفرّج اللون لو طرحت هذه القيمة من
+
+510
+00:41:39,520 --> 00:41:43,460
+التجربة الأولى اللي هي معايرة الـ chloride في وجود
+
+511
+00:41:43,460 --> 00:41:48,340
+الـ dichromate بتخلص من الخطأ إذا التخلص من الخطأ شغلة
+
+512
+00:41:48,340 --> 00:41:51,880
+بسيطة استخدام blank لكن بدي آخذ بالي في الـ blank
+
+513
+00:41:51,880 --> 00:41:58,220
+أنه بدي أستخدم نفس الـ volume at equivalence point
+
+514
+00:41:58,220 --> 00:42:03,560
+نفس تركيز الكرومات المستخدم في تجربة Mohr اللي هو
+
+515
+00:42:03,560 --> 00:42:08,640
+2.5×10 أس سالب ثلاثة
+
+516
+00:42:08,640 --> 00:42:13,620
+تقريباً اللي هو ثلث التركيز النظري اللي المفروض أن
+
+517
+00:42:13,620 --> 00:42:18,500
+أنا أستخدمه فبحصل على جدعش أخدت حجم طبعاً few drops
+
+518
+00:42:18,500 --> 00:42:22,180
+يعني نصف مل حاجة زي هيك مش أنها ثلاثة من عشرة مل
+
+519
+00:42:22,180 --> 00:42:25,940
+حاجة قليلة يعني مش كتير لكن بأخذ هذا الحجم بطرحه من
+
+520
+00:42:25,940 --> 00:42:31,700
+الحجم الأول بيعطيني الحجم المكافئ للـ chloride
+
+521
+00:42:31,700 --> 00:42:39,740
+لوحده ماشي يا شباب طيب أنا بدي أوقف هنا الحصة
+
+522
+00:42:39,740 --> 00:42:44,060
+الجاية هنشوف الطريقتين اللي فاضلين لتعيين الـ
+
+523
+00:42:44,060 --> 00:42:48,180
+chloride طريقة Fajans وطريقة Volhard فبنشوفكم إن شاء
+
+524
+00:42:48,180 --> 00:42:49,460
+الله راد يوم الأربعاء
diff --git a/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/bgeZXRxTolE_raw.srt b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/bgeZXRxTolE_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..a4dbd38c7336549128a130dc8c2cb161dfdc8436
--- /dev/null
+++ b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/bgeZXRxTolE_raw.srt
@@ -0,0 +1,2100 @@
+1
+00:00:20,920 --> 00:00:24,820
+بسم الله الرحمن الرحيم اليوم إذا أرادت بنكمل في ال
+
+2
+00:00:24,820 --> 00:00:28,700
+precipitation reactions أو ال titrations بنتكلم
+
+3
+00:00:28,700 --> 00:00:32,160
+شكل أساسي عن ال precipitation titrations لكن قبل
+
+4
+00:00:32,160 --> 00:00:35,720
+ما نبدأ بس في نقطة كانت ضايلة معنى من الحصة
+
+5
+00:00:35,720 --> 00:00:41,060
+الماضية الحصة الماضية كنا بنتكلم عن ال solubility
+
+6
+00:00:41,060 --> 00:00:46,310
+في وجود acid solutionوشوفنا ان ال solubility بتزيد
+
+7
+00:00:46,310 --> 00:00:52,490
+في وجود acid solution لأن ال conjugate base الجزء
+
+8
+00:00:52,490 --> 00:00:56,050
+من ال salt اللي على هيئة conjugate base في وجود
+
+9
+00:00:56,050 --> 00:00:59,150
+acid إذا كان هذا ال conjugate base قوي طبعا يعني
+
+10
+00:00:59,150 --> 00:01:05,730
+جاي من weak acid فبيتجزق في وجود acid نظرا لأنه
+
+11
+00:01:05,730 --> 00:01:09,890
+بيكون species مختلفة فبنستخدم ال alpha values
+
+12
+00:01:09,890 --> 00:01:17,620
+علشان انحل ال solubility problemsقلنا ايضا انه في
+
+13
+00:01:17,620 --> 00:01:23,140
+وجود complexing agent ايضا ال metal ion بيتجزأ و
+
+14
+00:01:23,140 --> 00:01:29,740
+بيكون جزء منه بيبقى free جزء منه بيكون complex مع
+
+15
+00:01:29,740 --> 00:01:33,820
+one ligand او complex مع two ligands او complex مع
+
+16
+00:01:33,820 --> 00:01:38,400
+three ligands او four ligands حسب نوع ال metal ion
+
+17
+00:01:38,400 --> 00:01:49,190
+و حسب نوع ال ligand ايضافقولنا إن ال Ksp هتساوي ال
+
+18
+00:01:49,190 --> 00:01:57,370
+metal ion مضروب في ال conjugate baseالـ Conjugate
+
+19
+00:01:57,370 --> 00:02:00,790
+Base لا يحصل أي تفاعل في وجود الـ Ligand لأنه الـ
+
+20
+00:02:00,790 --> 00:02:04,290
+Ligand أصلاً هو الـ Base لكن المثل عيوني يتجزأ
+
+21
+00:02:04,290 --> 00:02:09,150
+مثلاً في الـ Ag Plus لو حطناه في أمونيا على سبيل
+
+22
+00:02:09,150 --> 00:02:14,570
+المثال الـ Ag Plus اللي متفكك من الـ AgCl الجزء
+
+23
+00:02:14,570 --> 00:02:17,150
+منه يبقى على هيئة Ag Plus الجزء منه يتحول إلى Ag
+
+24
+00:02:17,150 --> 00:02:20,610
+Plus أو الـ Ag Ammonia Plus الجزء منه يتحول إلى Ag
+
+25
+00:02:20,610 --> 00:02:26,500
+Di Ammonia Plusفالـ silver هيكون مكافئ أو كل ال
+
+26
+00:02:26,500 --> 00:02:31,300
+silver اللي متفكك من ال agcl اللي هو بيساوي ال
+
+27
+00:02:31,300 --> 00:02:35,840
+chloride ال silver هذه الكمية هي عبارة عن ال
+
+28
+00:02:35,840 --> 00:02:38,040
+silver اللي ماتفككش زائد ال silver اللي كوّن
+
+29
+00:02:38,040 --> 00:02:41,860
+complex مع legend واحد زائد ال silver اللي كوّن
+
+30
+00:02:41,860 --> 00:02:47,440
+complex مع ال two legends فجداش موجود عندي من ال
+
+31
+00:02:47,440 --> 00:02:53,840
+silver ل free بقول والله beta zero من ال Sإذا كان
+
+32
+00:02:53,840 --> 00:03:01,020
+الكلوريد S فكل السلفر هو عبارة عن SSilver بجميع
+
+33
+00:03:01,020 --> 00:03:04,220
+أنواع ال species اللي كوّنها هو عبارة عن S طب
+
+34
+00:03:04,220 --> 00:03:07,480
+جدّاش منه على هيئة AG plus قال والله Beta Zero من
+
+35
+00:03:07,480 --> 00:03:11,840
+ال S وبالتالي ال S بتساوي جزر ال Ksp على ال Beta
+
+36
+00:03:11,840 --> 00:03:18,720
+Zero خلينا نطلع على مثال بسيط كتير بنقول find the
+
+37
+00:03:18,720 --> 00:03:23,520
+solubility of AgBr ال Ksp له أربعة عشر أقل سالب
+
+38
+00:03:23,520 --> 00:03:28,960
+تلتاش طالب ال solubility in a pure waterand in 0.1
+
+39
+00:03:28,960 --> 00:03:34,680
+molar ammonia نعطينا ال beta 0 in 0.1 molar
+
+40
+00:03:34,680 --> 00:03:38,480
+ammonia بتسوى 4 في 10 أقل سالب 6 طبعا ممكن نعطيها
+
+41
+00:03:38,480 --> 00:03:41,860
+ال cash في الامتحان نعطيك KF1 و KF2 و أنت بتحسب ال
+
+42
+00:03:41,860 --> 00:03:46,860
+beta 0يعني هن ما أعطينا هو ال beta 0 ماشي لكن كان
+
+43
+00:03:46,860 --> 00:03:51,480
+ممكن مايعطيكاش ال beta 0 يعطيك KF1 و KF2 خلاص ال
+
+44
+00:03:51,480 --> 00:03:56,100
+beta 0 طبعا بدها تساوي 1 على 1 زائد KF1 أمونيا
+
+45
+00:03:56,100 --> 00:04:01,610
+زائد KF1 KF2 أمونيا تربيةعلى أي حال فخلّينا الآن
+
+46
+00:04:01,610 --> 00:04:04,310
+نحسب ال solubility في ال pure water في البداية و
+
+47
+00:04:04,310 --> 00:04:09,430
+بعدين نحسب ال solubility في وجود ال ammonia ف in a
+
+48
+00:04:09,430 --> 00:04:13,590
+pure water مافيش عندى اي مشكلة ال AGBR AGB plus PR
+
+49
+00:04:13,590 --> 00:04:18,870
+سالب صفر صفر SS تهيأ الموضوع اذا ال KSP بيساوي S
+
+50
+00:04:18,870 --> 00:04:22,870
+تربعه و ال S بتساوي جزر ال KSP يعني بيساوي ستة و
+
+51
+00:04:22,870 --> 00:04:27,030
+تلاتة عشر اقل سالب سبعة مافيش اي مشكلة في حساب ال
+
+52
+00:04:27,030 --> 00:04:30,480
+solubility in a pure waterفيش اي مشكلة على طول حسب
+
+53
+00:04:30,480 --> 00:04:34,340
+الستوكيومتري فان واحد يعني S فان واحد يعني S يبقى
+
+54
+00:04:34,340 --> 00:04:38,040
+ال KSP S تربيع جزر ال KSP بيساوي ال solubility
+
+55
+00:04:38,040 --> 00:04:41,840
+بتساوي الست و تلاتة في عشرة السالب سبعة هدف ال ايه
+
+56
+00:04:41,840 --> 00:04:47,000
+في الميه المجترة ال pure النقية ايه كويس خلينا
+
+57
+00:04:47,000 --> 00:04:50,580
+ناخد بالنا من هذا الرقم اللي احنا توح حسبناه نحفظه
+
+58
+00:04:50,580 --> 00:04:56,850
+شوية بس ثوانىماذا يحصل في الـ A؟ في الـ Ammonia في
+
+59
+00:04:56,850 --> 00:05:01,190
+الـ Ammonia يا شباب واضح ان الـ AGBR تعطينا A G
+
+60
+00:05:01,190 --> 00:05:05,750
+Plus و B R سالب صفر صفر طب في الـ Ammonia ايش
+
+61
+00:05:05,750 --> 00:05:12,130
+بيحصل؟ اه هذا الـ AGBA الـ A G Plus بيكون اش منه
+
+62
+00:05:12,130 --> 00:05:17,890
+بيبقى A G Plus و اش منه بيكون A G Ammonia Plus و
+
+63
+00:05:17,890 --> 00:05:28,590
+اش منه بيكون A G Diammoniaبلاس كل هدول بيساوي
+
+64
+00:05:28,590 --> 00:05:32,710
+ال S ال PR طبعا بتساوي ال S لكن انا مابديش كل هدول
+
+65
+00:05:32,710 --> 00:05:37,070
+انا بدي بس ال silver plus ايش بيساوي جزء من هذا
+
+66
+00:05:37,070 --> 00:05:42,210
+الكل ايش هذا الجزء بيتزير من ال S صحيح؟
+
+67
+00:05:43,910 --> 00:05:46,910
+واضح بالنسبة ان الـ Ksp سوى الـ Beta Zero من الـ S
+
+68
+00:05:46,910 --> 00:05:50,850
+في الـ S يعني الـ S بسوا الجزر التربيه على الـ Ksp
+
+69
+00:05:50,850 --> 00:05:54,990
+على الـ Beta Zero يعني الـ S بسوا 3.2×10⁻⁴ مولر
+
+70
+00:05:54,990 --> 00:05:59,210
+لما نيجي نقارن هذا الرقم بالرقم اللي حسبنا لل
+
+71
+00:05:59,210 --> 00:06:03,890
+solubility in pure water اللي هو 6.3×10⁻⁷ بنلاحظ
+
+72
+00:06:03,890 --> 00:06:07,850
+أنه فرق كبير لكن احنا قلنا برضه كمان بداش نحسب
+
+73
+00:06:08,410 --> 00:06:12,390
+أرقام مجردة أو يعني انقار بين أرقام مجردة خلّيني
+
+74
+00:06:12,390 --> 00:06:15,990
+أحسب ال percent increase in solubility بيساوي ال
+
+75
+00:06:15,990 --> 00:06:19,470
+solubility الجديدة ناقص الأصلية على الأصلية في 100
+
+76
+00:06:19,470 --> 00:06:26,210
+% بيعطيني 5 1 في 10 أقص 4% 51 ألف مرة في المية
+
+77
+00:06:26,210 --> 00:06:32,050
+كمية زيادة في ال solubility تعتبر يعني كبيرة جدا
+
+78
+00:06:32,050 --> 00:06:36,670
+جدا كمية الزيادة في ال solubility تعتبر كمية كبيرة
+
+79
+00:06:36,670 --> 00:06:44,250
+جدا جداطبعا من هذا الكلام ممكن نستنتج نقول ان ال
+
+80
+00:06:44,250 --> 00:06:47,110
+solubility في وجود acid او ال solubility في وجود
+
+81
+00:06:47,110 --> 00:06:52,790
+complexing agent بتكون كبيرة للغاية كبيرة للغاية
+
+82
+00:06:52,790 --> 00:06:56,070
+يعني الزيادة في ال solubility بالنسبة للميه بتكون
+
+83
+00:06:56,070 --> 00:07:01,590
+زيادة محسوسة بشكل كبير كتيرعشان ما ناخدش يعني
+
+84
+00:07:01,590 --> 00:07:05,930
+تكرار في الأمثلة بنقول مثلا إننا حاجة زي ال
+
+85
+00:07:05,930 --> 00:07:09,650
+cadmium sulfide أو القبر sulfide على سبيل المثال
+
+86
+00:07:09,650 --> 00:07:14,990
+لأنك أخدته قبل هيك القبر sulfide هذا بتفكك بعطينا
+
+87
+00:07:14,990 --> 00:07:21,110
+قبر زائد sulfide لو حطينا هذا الكلام في أمونيا هذا
+
+88
+00:07:21,110 --> 00:07:29,050
+القبر بيكون قبر قبر أمونيا قبر داي أمونيا
+
+89
+00:07:33,190 --> 00:07:43,730
+كبر تري أمونيا وكبر تيترا أمونيا بيهمنيش كل هذا كل
+
+90
+00:07:43,730 --> 00:07:50,010
+هدول اذا كان هاد اس فكل هدول بيسوا ايه اس اذا
+
+91
+00:07:50,010 --> 00:07:52,970
+الاسكان هاد اس انا اللي بيهمني بس حاجة واحدة هذا
+
+92
+00:07:52,970 --> 00:07:57,090
+بيتا زيرو من الاس فقط فهو اللي بيهمني ايش بيتا
+
+93
+00:07:57,090 --> 00:08:02,470
+زيرو بيتا زيرو بتسوا واحد على واحد زائدكيف 1
+
+94
+00:08:02,470 --> 00:08:05,690
+أمونيا زائد كيف 1 كيف 2 أمونيا تربية زائد كيف 1
+
+95
+00:08:05,690 --> 00:08:09,490
+كيف 2 كيف 3 أمونيا تكعيب زائد كيف 1 كيف 2 كيف 3
+
+96
+00:08:09,490 --> 00:08:13,410
+كيف 4 أمونيا أُس 4 أعرفنا كيف بنجيب ال beta 0 و ال
+
+97
+00:08:13,410 --> 00:08:16,690
+beta 1 و ال beta 2 by inspection بمجرد النظر
+
+98
+00:08:16,690 --> 00:08:21,450
+أعرفنا كيف نعمل هذا الكلام بمجرد النظر لكن أنا قلت
+
+99
+00:08:21,450 --> 00:08:24,750
+إنه ال alpha أكتر من ال alpha 2 أنا بعطيه قيمتها
+
+100
+00:08:25,400 --> 00:08:29,500
+وال beta 0 اذا كان عندك اكتر من two formation
+
+101
+00:08:29,500 --> 00:08:33,020
+constants انا برضه بعطيك قيمتها يعني مش راح اخليك
+
+102
+00:08:33,020 --> 00:08:36,520
+تستخدم اربعة formation constants بس اتنين زي ال
+
+103
+00:08:36,520 --> 00:08:39,400
+silver مع ال ammonia اتنين اقعد تقدر تحسبها انت
+
+104
+00:08:39,400 --> 00:08:44,100
+لكن اربعة مش هخليك تحسبها اذا على طول ال Ksp ايش
+
+105
+00:08:44,100 --> 00:08:52,980
+بده يساوي برضه beta 0 is في S مش هيك؟ طيبكمان حاجة
+
+106
+00:08:52,980 --> 00:08:57,460
+انا حابب انك تاخد بالك منها لو عندي silver
+
+107
+00:08:57,460 --> 00:09:02,320
+sulphide هذا عبارة عن راسب sparingly soluble salt
+
+108
+00:09:02,320 --> 00:09:07,820
+بقى انا اتنين silver زائد sulphide بقول هذا طبعا
+
+109
+00:09:07,820 --> 00:09:11,960
+بتجزأ مش هيك ولا لأ في وجود ال ammonia اذا هذا ايش
+
+110
+00:09:11,960 --> 00:09:16,940
+بده يكون اذا كان هذا S هذا ايش بده يكون في الاصل
+
+111
+00:09:16,940 --> 00:09:22,440
+اتنين S لكن هو بس بيتزير من الاتنين Sبيتا زيرو من
+
+112
+00:09:22,440 --> 00:09:27,080
+ايه؟ عشان هيك لما نقول KSP بده اقول ال silver ايش
+
+113
+00:09:27,080 --> 00:09:33,260
+ال silver بيساوي؟ بيتا زيرو من ال 2S الكل تربيع
+
+114
+00:09:33,260 --> 00:09:37,080
+لأن هذا ال silver اتنين اتنين silver ماياخد بالك
+
+115
+00:09:37,080 --> 00:09:41,340
+مش بس ال 2S تربيع لأ لأنه تركيز ال silver بيتا
+
+116
+00:09:41,340 --> 00:09:46,190
+زيرو من ال 2Sالتركيز تربيع هاي ال KSP هي التركيز
+
+117
+00:09:46,190 --> 00:09:49,290
+تربيع ال silver تربيع يعني تركيز ال silver تربيع
+
+118
+00:09:49,290 --> 00:09:56,130
+فال P ده 02S كلها تربيع في S مااخد بالك يعني مش
+
+119
+00:09:56,130 --> 00:09:59,890
+ضروري ناخد مسألة حسابية على هذا الكلام هو بس تطبيق
+
+120
+00:09:59,890 --> 00:10:07,890
+مباشر على الكلام اللي درسناه قبل شوية طيب
+
+121
+00:10:07,890 --> 00:10:14,700
+يا شباب خلينا الآنننتقل ل ال precipitation
+
+122
+00:10:14,700 --> 00:10:18,980
+titrations اللي هو الموضوع الأساسي في ال chapter
+
+123
+00:10:18,980 --> 00:10:24,560
+هذا بنقول
+
+124
+00:10:24,560 --> 00:10:28,000
+ال precipitation titrations من الموضوعات المهمة
+
+125
+00:10:28,000 --> 00:10:33,600
+كتير والبسيطة كتير في نفس الوقت بسيطة كتير لأنه
+
+126
+00:10:35,050 --> 00:10:38,750
+يعني عدد المواد اللي يمكن تعيينها باستخدام ل
+
+127
+00:10:38,750 --> 00:10:43,390
+precipitation and titration عدد قليل عدد محدود عدد
+
+128
+00:10:43,390 --> 00:10:49,560
+محدودأكتر من هيك يعني كان ممكن كتير من الناس يسموا
+
+129
+00:10:49,560 --> 00:10:55,280
+هذا الجزء من العلم او ال precipitation ممكن يسموها
+
+130
+00:10:55,280 --> 00:10:59,280
+argentometric precipitation يعني معاييرات الفضة
+
+131
+00:10:59,280 --> 00:11:02,360
+ايش معناه بيسموها معاييرات الفضة؟ ليش ال
+
+132
+00:11:02,360 --> 00:11:06,210
+precipitation titrations كتير من الناس؟في الكتب
+
+133
+00:11:06,210 --> 00:11:10,670
+المختلفة ممكن تسميها argentometric titrations جال
+
+134
+00:11:10,670 --> 00:11:16,370
+لأنه من أنجح ل precipitation titrations معاييرات
+
+135
+00:11:16,370 --> 00:11:21,950
+الفضة مع أربعة من الأيونات الكلورايد لبروميد
+
+136
+00:11:21,950 --> 00:11:26,710
+الايودايد عارفين هم هدول بالإضافة لهم التيوسيانيت
+
+137
+00:11:26,710 --> 00:11:31,290
+يبجى هاي أربعة أشياء كانت بتعاير بتعاير بشكل ممتاز
+
+138
+00:11:31,290 --> 00:11:35,620
+مع ال silverهل معنى الكلام إنه فيش precipitation
+
+139
+00:11:35,620 --> 00:11:40,260
+and titration تانية؟ لأ موجود لكن للأسف قليل جدا
+
+140
+00:11:40,260 --> 00:11:45,900
+جدا طب إيهش اللي بيخلي عدد التفاعلات اللي يمكن
+
+141
+00:11:45,900 --> 00:11:49,340
+استخدامها ك precipitation و titration reactions
+
+142
+00:11:49,340 --> 00:11:57,120
+قليل مع إنه هناك كام هائل من التفاعلات اللي تعتبر
+
+143
+00:11:57,120 --> 00:12:01,820
+quantitative تعتبر no side reactions تعتبر very
+
+144
+00:12:01,820 --> 00:12:07,890
+fastيعني كل تفاعلات المعايرة تنطبق عليها ال
+
+145
+00:12:07,890 --> 00:12:12,230
+conditions والظروف والشروط لتفاعل المعايرة تنطبق
+
+146
+00:12:12,230 --> 00:12:16,870
+عليها انطباق ممتاز طب ايش معناه ايش معناه لا
+
+147
+00:12:16,870 --> 00:12:21,570
+تستخدم كتفاعلات معايرة جال المشكلة مش فيها المشكلة
+
+148
+00:12:21,570 --> 00:12:25,330
+مش في خصائصها المشكلة في ان احنا مافيش عندنا
+
+149
+00:12:25,330 --> 00:12:31,620
+indicators مناسبة لهاوالسبب انه تفاقط معاييرات
+
+150
+00:12:31,620 --> 00:12:34,580
+الفبّة مع الاربع عيونات لكلورايد لبرومايد
+
+151
+00:12:34,580 --> 00:12:38,640
+الايودايد والثالث عيونات ناجحة لأنه موجود لها
+
+152
+00:12:38,640 --> 00:12:44,900
+indicators مناسبةأخدنا بالنا موجود لمعاييرات الفضة
+
+153
+00:12:44,900 --> 00:12:48,960
+indicators مناسبة بينما مش موجود للمعاييرات الأخرى
+
+154
+00:12:48,960 --> 00:12:53,660
+بشكل عام indicators مناسبة إلا عدد قليل من ال
+
+155
+00:12:53,660 --> 00:12:58,460
+precipitation reactions لهذا السبب يمكن احنا من
+
+156
+00:12:58,460 --> 00:13:04,380
+خلال دراستنا لل precipitation reactions أو ال
+
+157
+00:13:04,380 --> 00:13:09,550
+argentometric reactions معاييرات الفضة بنلاحظفي
+
+158
+00:13:09,550 --> 00:13:15,030
+عندنا تلت طرق رئيسية طريقة more وطريقة fashions
+
+159
+00:13:15,030 --> 00:13:19,110
+وطريقة volard لو قلنا ايش هالطرق هذه بنلاحظ ان هي
+
+160
+00:13:19,110 --> 00:13:25,230
+في الحقيقة مش طرق يعني غريبة ولا هي طرق يعني خاصة
+
+161
+00:13:25,230 --> 00:13:30,930
+هي عبارة عن طرق تستخدم indicators معينة يعني سمينا
+
+162
+00:13:30,930 --> 00:13:36,310
+الطريقة باسم الشخص اللي اكتشف ال indicator المناسب
+
+163
+00:13:37,390 --> 00:13:41,670
+فمثلا more method بيستخدم more ليكروميت هي معايرة
+
+164
+00:13:41,670 --> 00:13:45,650
+مباشرة بيستخدم ليكروميت ك indicator فجاز method
+
+165
+00:13:45,650 --> 00:13:48,650
+بيستخدم الفلورسين مثلا لو أول absorption
+
+166
+00:13:48,650 --> 00:13:54,070
+indicators زي الفلورسين ومش تقاتهفسميت يعني هو
+
+167
+00:13:54,070 --> 00:13:59,070
+اكتشف بس ال indicator لكن صميت الآن طريقة باسمه
+
+168
+00:13:59,070 --> 00:14:02,910
+الvalhard method نفس الكلام اكتشف ال indicator
+
+169
+00:14:02,910 --> 00:14:10,670
+اللي هو ال iron تلاتة على سبيل المثال فهذه الطرق
+
+170
+00:14:10,670 --> 00:14:16,390
+كلها تستخدم لتعيين بشكل أساسي كمية الكلورايد في
+
+171
+00:14:16,390 --> 00:14:20,630
+المحليل المختلفة طيب
+
+172
+00:14:21,230 --> 00:14:25,290
+برضه و احنا بنتكلم عن ال titration curves ايه كويس
+
+173
+00:14:25,290 --> 00:14:31,710
+نتكلم عن شكل ال titration curve شكل ال titration
+
+174
+00:14:31,710 --> 00:14:34,650
+curve ال titration curve اللي بيهمنا فيه حاجتين
+
+175
+00:14:34,650 --> 00:14:39,930
+بيهمنا فيه جداش هو sharp جداش sharp بدناش هيكون
+
+176
+00:14:39,930 --> 00:14:43,950
+ميل سيجمويدل لأ بدنا يكون sharp at the end point
+
+177
+00:14:43,950 --> 00:14:47,970
+او the equivalence point بدنا يكون ايه الخط عمودي
+
+178
+00:14:48,600 --> 00:14:53,520
+ليه؟ علشان minimum amount من ال .. ال titrant
+
+179
+00:14:53,520 --> 00:14:57,200
+تعطيني ال end point على قول أقدر أشوف ال end point
+
+180
+00:14:57,200 --> 00:15:00,180
+نقطة واحدة تخليني أشوف ال end point فبديها يكون
+
+181
+00:15:00,180 --> 00:15:05,860
+sharp هذه حاجة والحاجة التانية بد الجمبأو ال break
+
+182
+00:15:05,860 --> 00:15:10,700
+تكون كبيرة القفزة تكون إيه؟ كبيرة مش صغيرة اللي
+
+183
+00:15:10,700 --> 00:15:14,880
+يعني مالجلهاش indicator مناسب أو يعني مجال الخطأ
+
+184
+00:15:14,880 --> 00:15:19,240
+يكون واسع لأ بديها تكون قفزة كبيرة فهدول الحاجتين
+
+185
+00:15:19,240 --> 00:15:24,680
+اللي أنا مهتم فيهم في أي titration curve بقول ال
+
+186
+00:15:24,680 --> 00:15:30,560
+sharpness و ال jump بيتوقفوا على عاملين أول عامل
+
+187
+00:15:30,560 --> 00:15:38,830
+هو قيمة ال KSPقيمة الـ KSP للـ Silver Salt قيمة
+
+188
+00:15:38,830 --> 00:15:45,210
+الـ KSP و العامل التاني هو تركيز المتفاعلات يعني
+
+189
+00:15:45,210 --> 00:15:48,610
+تركيز الـ Silver و تركيز الchloride فتعالوا نشوف
+
+190
+00:15:48,610 --> 00:15:54,610
+كيف الـ KSP للـ Silver Salt بيأثر على ال sharpness
+
+191
+00:15:54,610 --> 00:16:02,220
+و بيأثر على ال jump لو جينا و طلعناهذا ال curve
+
+192
+00:16:02,220 --> 00:16:07,780
+لمعايرة الكلورايد مع ال silver هاي ال silver طبعا
+
+193
+00:16:07,780 --> 00:16:14,000
+دائما الخط هذا عبارة عن silver volume
+
+194
+00:16:14,000 --> 00:16:18,800
+of silver nitrate titrant وهذا الخط انها احد
+
+195
+00:16:18,800 --> 00:16:26,620
+حاجتين يا اماPag يا اما Pcl هذا Pag لو كان Pcl كان
+
+196
+00:16:26,620 --> 00:16:34,280
+شكل ال curve كالتالي هي من ال AgNO3 وهي PX حيث X
+
+197
+00:16:34,280 --> 00:16:37,980
+هي الكلورايد او البرومايد او الايودايد او
+
+198
+00:16:37,980 --> 00:16:45,440
+الثيوسينيد بلاحظ انه عكس الشكل اللي قدامي فانا في
+
+199
+00:16:45,440 --> 00:16:52,560
+ال titration curve فيهأرسم يا إما ال PAG أو أرسم
+
+200
+00:16:52,560 --> 00:16:59,120
+ال PX مع ال Multitrant فإذا كان رسمت ال PAG بطلع
+
+201
+00:16:59,120 --> 00:17:02,740
+هيك شكل الكارو، إذا كان رسمت ال PX بطلع الشكل
+
+202
+00:17:02,740 --> 00:17:07,680
+معاكسماشي يا شباب الاتنين مظبوطين اي شكل بتختاره
+
+203
+00:17:07,680 --> 00:17:12,380
+فاش عندى مشكلة حسب ايش اللى بدك ترسمه هل هو ال PX
+
+204
+00:17:12,380 --> 00:17:17,460
+ولا ال PAG لكن انت فاهمه انا احنا هاي ال chloride
+
+205
+00:17:17,460 --> 00:17:22,460
+لاحظ جداش ال Ksp لل silver chloride عشرة أس سالب
+
+206
+00:17:22,460 --> 00:17:27,940
+عشرة طيب لو عيرنا ال bromide بنلاحظ ان ال jump ايش
+
+207
+00:17:27,940 --> 00:17:30,460
+مالها بتكبر
+
+208
+00:17:32,340 --> 00:17:36,420
+الكي اس بي عشرة أس سالب تلتاش طب لو عيرنا ال ايو
+
+209
+00:17:36,420 --> 00:17:40,280
+دايد ال كي اس بي عشرة أس سالب ست عاش لاحظ ال jump
+
+210
+00:17:40,280 --> 00:17:48,680
+جداش كبيرة خالص هاي هال jump من هان لهان هاد ال
+
+211
+00:17:48,680 --> 00:17:54,240
+jump من هان لهان هاد ال jump من هان لهان هاي هاد
+
+212
+00:17:54,240 --> 00:17:57,840
+ال chloride وهاي هاد ال bromide وهاي هاد ال ايو
+
+213
+00:17:57,840 --> 00:18:02,880
+دايد فكل ما قلي ال كي اس بي ايش محصل لل jumpبتزيد
+
+214
+00:18:02,880 --> 00:18:08,060
+ال sharpness بتزيد و ال jump أيضا بتزيد كويسك؟ اذا
+
+215
+00:18:08,060 --> 00:18:12,680
+هذا يمكن لو احنا قارنناه مع ال equilibrium
+
+216
+00:18:12,680 --> 00:18:17,460
+constants لل acid و ال base او حتى ال Kf كنا بنقول
+
+217
+00:18:17,460 --> 00:18:20,080
+في حالة ال acids و ال bases و ايضا ال
+
+218
+00:18:20,080 --> 00:18:23,900
+complexometric titrations كل ما زاد ال equilibrium
+
+219
+00:18:23,900 --> 00:18:29,660
+constant بتزيد ال jump هنعكسه كل ما قل ال Ksp
+
+220
+00:18:29,660 --> 00:18:35,140
+بتزيد ال jumpماشي يا شباب هذا اول عامل بيأثر على
+
+221
+00:18:35,140 --> 00:18:38,240
+ال titration curve العامل التاني طبعا اللي هو ال
+
+222
+00:18:38,240 --> 00:18:41,740
+concentration لل reactants انشوف ايش اللي بيحصل
+
+223
+00:18:41,740 --> 00:18:49,320
+لاحظ ال curve A اللي هو اكبر jump التركيز كان واحد
+
+224
+00:18:49,320 --> 00:18:52,560
+من عشرة molar silver nitrate وواحد من عشرة molar
+
+225
+00:18:52,560 --> 00:18:57,520
+chloride يعني التركيز واحد من عشرة molar لاتنين B
+
+226
+00:18:57,520 --> 00:19:03,700
+ال jump اقل من hand ل hand هذاهي مثلا من هان لهان
+
+227
+00:19:03,700 --> 00:19:10,100
+هذا من هان لهان أقل
+
+228
+00:19:10,100 --> 00:19:19,780
+هذا واحد من عشرة هذا واحد من مية طب نيجي لهذا واحد
+
+229
+00:19:19,780 --> 00:19:26,680
+من الف فلاحظ انت واحد من الف molar silver nitrate
+
+230
+00:19:26,680 --> 00:19:30,780
+مع واحد من الف molar chloride اعطاني جمب صغيرة
+
+231
+00:19:31,710 --> 00:19:37,530
+بينما لما زوّت التركيز استخدمت واحد من مية و واحد
+
+232
+00:19:37,530 --> 00:19:41,890
+من مية ال jump زادت لما زوّت التركيز اكتر واحد من
+
+233
+00:19:41,890 --> 00:19:45,570
+عشر و واحد من عشر ال jump ايش ما لا زادت بشكل كبير
+
+234
+00:19:45,570 --> 00:19:53,730
+علشان هيك بقدر اقول يعني بدون اي تردد ان والله لما
+
+235
+00:19:53,730 --> 00:20:00,960
+تزيد التركيزات المتفاعلات ايش بيحصل لل jumpبتزيد
+
+236
+00:20:00,960 --> 00:20:04,940
+ال jump وهذا متوافق مع ما درسناه سابقا يعني نفس
+
+237
+00:20:04,940 --> 00:20:08,800
+الكلام شفناه في ال acid base titrations وشفناه
+
+238
+00:20:08,800 --> 00:20:14,200
+أيضا في ال complexometric titrations في كمان
+
+239
+00:20:14,200 --> 00:20:18,840
+ملاحظة عندى بقدر اقول انه في حالة ال precipitation
+
+240
+00:20:18,840 --> 00:20:26,070
+titrations انا بقدر اعايرmixtures بقدر اعير
+
+241
+00:20:26,070 --> 00:20:33,490
+mixtures و احصل منها على نقول
+
+242
+00:20:33,490 --> 00:20:39,910
+يعني two equivalence points يعني واحدة للأيون
+
+243
+00:20:39,910 --> 00:20:44,450
+الأول و واحدة تانية للأيون التانية إذا كان شرط إذا
+
+244
+00:20:44,450 --> 00:20:45,750
+كان ال KSP
+
+245
+00:20:49,690 --> 00:20:57,490
+أو ألف مرة أو أكتر يعني مثلا ال Ksp لالكلورايد على
+
+246
+00:20:57,490 --> 00:21:02,120
+ال Iodide عشرة أقل ستةبلاحظ أنه أه ممكن بسهولة
+
+247
+00:21:02,120 --> 00:21:05,780
+أحصل على end point two equivalence point للكلوريدو
+
+248
+00:21:05,780 --> 00:21:09,160
+equivalence point للإيه لل Iodide إذا كان عشرة أس
+
+249
+00:21:09,160 --> 00:21:13,080
+تلاتة فأكثر نعم يمكن الحصول على equivalence point
+
+250
+00:21:13,080 --> 00:21:19,620
+لكل واحد منهم متميزة عن الأخرى تماما يعني بقدر
+
+251
+00:21:19,620 --> 00:21:25,180
+أعين كل واحد لو كان الفرق بين ال KSPs أقل من عشرة
+
+252
+00:21:25,180 --> 00:21:28,800
+أس تلاتة بلاحظ أنه ال end point التاني بتكونش
+
+253
+00:21:30,580 --> 00:21:34,500
+واضحة، ممكن ما تكونش موجودة أو انها ماتكونش واضحة،
+
+254
+00:21:34,500 --> 00:21:41,800
+كويس؟ لأ كاس بي واحد أكاس بي اتنين، لو كانت أقل من
+
+255
+00:21:41,800 --> 00:21:45,560
+الف ممكن يعني كل ما قال كل ما كانت مش واضحة، لو
+
+256
+00:21:45,560 --> 00:21:48,680
+كان عشر أقصى واحد مثلا ممكن نلاقيها والله صارت
+
+257
+00:21:48,680 --> 00:21:52,870
+حاجة زي هيكمش مبينة هذه الـ equivalence point
+
+258
+00:21:52,870 --> 00:21:57,330
+تانية مبينها كأنها نفس ال titration curve ممتدة
+
+259
+00:21:57,330 --> 00:22:02,430
+على أي حال فعلشان أحصل على distinct equivalence
+
+260
+00:22:02,430 --> 00:22:08,410
+points لازم Ksp1 ع Ksp2 تكون عشرة أس تلاتة فأكتر
+
+261
+00:22:08,410 --> 00:22:15,330
+الآن يا شباب خلّينا ناخد مثال على ال titration
+
+262
+00:22:15,330 --> 00:22:21,910
+curve وطريقة بنائه يعني عملية معايرةمن خلالها نقدر
+
+263
+00:22:21,910 --> 00:22:27,150
+نبني الـ titration curve فنتطلع على معايرة 20 مل
+
+264
+00:22:27,150 --> 00:22:35,990
+من 0.1 مولر إكلورايد مع
+
+265
+00:22:35,990 --> 00:22:43,710
+0.1 مولر سلفر علشان أقدر أبني ال titration curve
+
+266
+00:22:43,710 --> 00:22:51,580
+هاي مل A G N O تلاتة وهي هنا P Xطبعا بإمكاني أقول
+
+267
+00:22:51,580 --> 00:22:56,540
+والله PAG لكن في هذه الحالة ال curve يبدأ من فوق
+
+268
+00:22:56,540 --> 00:23:00,420
+لأ أنا بدي أشتغل PX مثلا أي واحدة بتختارها صحيحة
+
+269
+00:23:00,420 --> 00:23:06,200
+مافيش مشكلة فإيش المثال بيقول find the PCL عشان
+
+270
+00:23:06,200 --> 00:23:13,260
+هيك أنا كتبت ال PX أو ال PCL هي PCL minus log
+
+271
+00:23:13,260 --> 00:23:18,890
+تركيز دي chlorideIn a 20 ml of a 0.1 molar
+
+272
+00:23:18,890 --> 00:23:22,470
+chloride solution after addition of 0, 10, 20 and
+
+273
+00:23:22,470 --> 00:23:26,450
+30 ml of 0.1 molar silver nitrate فانا بضيف silver
+
+274
+00:23:26,450 --> 00:23:30,550
+nitrate صفر عشرة عشرين و تلاتين مل و كل مرة بدي
+
+275
+00:23:30,550 --> 00:23:35,830
+أحسب ال PCL بقول ببساطة خالص أول إضافة after
+
+276
+00:23:35,830 --> 00:23:40,290
+addition of 0 mlطبعا الكلوريد جاعت في المحلول 1 من
+
+277
+00:23:40,290 --> 00:23:43,850
+10 مولار زي ما هو إذا تركيز 1 من 10 مولار و ال P
+
+278
+00:23:43,850 --> 00:23:47,550
+للكلوريد minus log 1 من 10 يعني 1 يبقى هاي أول
+
+279
+00:23:47,550 --> 00:23:56,290
+نقطةهذه اول نقطة عند 0 مل من الاج بلس طب تعالوا
+
+280
+00:23:56,290 --> 00:24:00,770
+نضيف 10 مل بقول و الله لما نضيف 10 مل من الاج بلس
+
+281
+00:24:00,770 --> 00:24:05,050
+انا عندي الاخلرايد 0.1 في 20 يعني 2 ميلي مول اضافت
+
+282
+00:24:05,050 --> 00:24:10,130
+عليهم 10 مل من السلفر يعني 0.1 في 10 يعني 1 ميلي
+
+283
+00:24:10,130 --> 00:24:15,660
+مول اخلرايد leftبدي ساوة اتنين ناقص واحد يعني واحد
+
+284
+00:24:15,660 --> 00:24:22,260
+الكلورايد lift واحد على عشرين وعشرة تلاتين لكن انا
+
+285
+00:24:22,260 --> 00:24:24,840
+بدي تركيز الكلورايد في المحلول تركيز الكلورايد في
+
+286
+00:24:24,840 --> 00:24:28,640
+المحلول بيساوي واحد على تلاتين اللي هو الزايد
+
+287
+00:24:28,640 --> 00:24:34,240
+المتبقي من الكلورايد لكن انا لما حطيت silver على
+
+288
+00:24:34,240 --> 00:24:38,180
+الكلورايد اتكون silver كلورايد وبالتاليجزء من
+
+289
+00:24:38,180 --> 00:24:42,220
+السلفر اكلورايد بيتفكك جزء من السلفر اكلورايد
+
+290
+00:24:42,220 --> 00:24:47,420
+بيعطيني اكلورايد جداش بيعطيني من الاكلورايد S ومن
+
+291
+00:24:47,420 --> 00:24:51,500
+السلفر طبعا S فانا بقول كيف بده احسب كل اكلورايد
+
+292
+00:24:51,500 --> 00:24:53,740
+اللي في المحلول قال والله واحد على تلاتين اللي هو
+
+293
+00:24:53,740 --> 00:24:58,520
+المتبقى زائد اللي جاي من السلفر اكلورايد يعني S
+
+294
+00:24:58,520 --> 00:25:05,580
+لكن انا بقولكم من هالجهة انه جداش ال KSP لهذا ال
+
+295
+00:25:05,580 --> 00:25:10,050
+equilibriumجال ال Ksp بده يساوي عشرة اقل سالب عشرة
+
+296
+00:25:10,050 --> 00:25:16,070
+صح فجداش متوقع تكون تفكك وجداش الاسبد هتكون كمية
+
+297
+00:25:16,070 --> 00:25:21,090
+مهملة كمية ايش مالها مهملة طب انا بقول مش بس هيك
+
+298
+00:25:21,090 --> 00:25:26,370
+مش بس هيك لما يكون في عند زيادة من ال chloride اه
+
+299
+00:25:26,370 --> 00:25:29,890
+يبدأ التفاعل ايش ماله؟ بدي يرجع كمان لورا كتير
+
+300
+00:25:29,890 --> 00:25:33,840
+معنى الكلام ال S دي إيها قيمة؟هتكون فش إلها قيمة
+
+301
+00:25:33,840 --> 00:25:39,800
+ومع ذلك احنا هنحسبها فبنقول ال Ksp بتساوي ال S في
+
+302
+00:25:39,800 --> 00:25:44,880
+1 على 30 زائد S نفترض ال 31 أكبر كتير من ال S إذا
+
+303
+00:25:44,880 --> 00:25:49,980
+ال S بتطلع أنه 3 في 10 أقل 9 هل الفرضية صحيحة؟
+
+304
+00:25:49,980 --> 00:25:55,450
+العشرة أقل 9 أقل كتير من ال 1 على 30؟طبعا يعني هذا
+
+305
+00:25:55,450 --> 00:25:58,290
+كلام مش اكيد عشان هيك حتى الرينا تبقى انهم مش
+
+306
+00:25:58,290 --> 00:26:03,630
+حاسبينه اذا ال chloride اللي هيو بدي سواء 1 على 30
+
+307
+00:26:03,630 --> 00:26:07,490
+زائد ال S يعني ال S هذه ولا حاجة يعني 1 على 30 او
+
+308
+00:26:07,490 --> 00:26:17,470
+ال PCL 1.48 يبجى هيو 1.48 ماشي يا شبابيبقى عند
+
+309
+00:26:17,470 --> 00:26:26,350
+إضافة 10 مل من الـ silver كان الـ PCL 1.48 طب نيجي
+
+310
+00:26:26,350 --> 00:26:29,610
+يا شباب هذا قبل نقطة نهاية اي رقم جاب النقطة
+
+311
+00:26:29,610 --> 00:26:33,770
+النهائية بنفس الطريقة بينشغل اي رقم دائما ال Ksp
+
+312
+00:26:33,770 --> 00:26:37,130
+صغير جدا يعني ال S قليلة و دائما قبل نقطة نهاية
+
+313
+00:26:37,130 --> 00:26:39,590
+عندك chloride زيادة معناه كلما تفكر حيرجي على ورا
+
+314
+00:26:39,590 --> 00:26:44,000
+يبقى ال S اكيد قليلة كتيرشبق يعني ملغية دائما طب
+
+315
+00:26:44,000 --> 00:26:47,580
+نيجي نشتغل عند اشرين مل من ال silver بقول يعني انا
+
+316
+00:26:47,580 --> 00:26:50,040
+عندى اتنين millimole chloride حطيت عليهم اتنين
+
+317
+00:26:50,040 --> 00:26:53,660
+millimole silver معناه كده millimole chloride left
+
+318
+00:26:53,660 --> 00:26:57,660
+صفر يبجى هدى هي ال equivalence point لا عندى
+
+319
+00:26:57,660 --> 00:27:01,140
+chloride ولا عندى silver خلصه طب انا بدى احسب
+
+320
+00:27:01,140 --> 00:27:06,860
+جداشه عندى chlorideفيش حساب إلا عن طريق ال Ksp أو
+
+321
+00:27:06,860 --> 00:27:11,560
+جايس الإكلورايد فقط من تفكك ال silver إكلورايد
+
+322
+00:27:11,560 --> 00:27:18,220
+فهنا عندي 00 قبل الإتزان بعد الإتزان SS يبقى ال
+
+323
+00:27:18,220 --> 00:27:22,440
+Ksp يتساوي ال S تربيع أو ال S يتساوي عشرة السالب
+
+324
+00:27:22,440 --> 00:27:27,500
+خمسة يعني ال P لل CL طبعا ال S هي ال إكلورايد ال P
+
+325
+00:27:27,500 --> 00:27:35,070
+لل CL بيتساوي خمسة- log 10² 5 يعني خمسة طب نيجي
+
+326
+00:27:35,070 --> 00:27:39,850
+نضيف حجم بعد ال equivalence point و أي حجم بعد ال
+
+327
+00:27:39,850 --> 00:27:44,090
+equivalence point برضه بنفس الطريقة فبقول انا عند
+
+328
+00:27:44,090 --> 00:27:49,090
+اتنين ملي مول كلوريد انا عند اتنين ملي مول كلوريد
+
+329
+00:27:49,090 --> 00:27:50,490
+انا عند اتنين ملي مول كلوريد انا عند اتنين ملي مول
+
+330
+00:27:50,490 --> 00:27:53,150
+كلوريد انا عند اتنين ملي مول كلوريد انا عند اتنين
+
+331
+00:27:53,150 --> 00:27:56,950
+ملي مول كلوريد انا عند اتنين ملي مول كلوريد انا
+
+332
+00:27:56,950 --> 00:27:59,870
+عند اتنين ملي مول كلوريد انا عند اتنين ملي مول
+
+333
+00:27:59,870 --> 00:28:00,430
+كلوريد انا عند اتنين ملي مول كلوريد انا عند اتنين
+
+334
+00:28:00,430 --> 00:28:02,260
+ملي مول كلوريد انا عند اتنين ملي مطب انا مابدي انا
+
+335
+00:28:02,260 --> 00:28:06,180
+بدي chloride كيه بدي احسب ال chloride لان المطلوب
+
+336
+00:28:06,180 --> 00:28:09,460
+مني احسب ال chloride طب ايش مصدر ال chloride ماهو
+
+337
+00:28:09,460 --> 00:28:12,240
+فيش عندي اي مصدر للكلوريد الا ال silver chloride
+
+338
+00:28:12,240 --> 00:28:15,320
+فباجي بقول انتبهوا عليها هاي ال silver اللي فيه
+
+339
+00:28:15,320 --> 00:28:18,380
+وقت ال silver و ال chloride ال silver الزيادة
+
+340
+00:28:18,380 --> 00:28:25,630
+point O20 هنا point O2 زائد S S لكن بدأ اذكركم هذا
+
+341
+00:28:25,630 --> 00:28:30,050
+ال Ksp له عشرة او سالب عشرة مع الكلام ال S هذه ايش
+
+342
+00:28:30,050 --> 00:28:34,010
+مالها مهملة مش بس هيك لما نكون في عند common ion
+
+343
+00:28:34,010 --> 00:28:39,310
+هنابخلّي التفاعل اشماله يرجع لوره خالص يعني ال S
+
+344
+00:28:39,310 --> 00:28:44,750
+مهملة جدا جدا جدا لا تكاد تذكر بالنسبة لل point O2
+
+345
+00:28:44,750 --> 00:28:48,890
+فهل ال KS يساوي point O2 زائد S في S افترض ان ال
+
+346
+00:28:48,890 --> 00:28:52,530
+point O2 اكبر كتير من ال S اذا ال S بتطلع خمسة في
+
+347
+00:28:52,530 --> 00:28:56,290
+عشر أقل سالب تسعة كمان مرة هل العشر أقل سالب تسعة
+
+348
+00:28:56,290 --> 00:29:00,290
+بالفعل اقل كتير من ال point O2 طبعا اقل كتير من ال
+
+349
+00:29:00,290 --> 00:29:04,130
+.. هذا بوضع طبيعيودائما بعد نقطة النهاية هذا هو
+
+350
+00:29:04,130 --> 00:29:09,290
+الحال يا شباب لأن ال Ksp دائما صغير جدا جدا اذا
+
+351
+00:29:09,290 --> 00:29:17,970
+ايش هي ال S ال S هي ال chloride معنى الكلام ال
+
+352
+00:29:17,970 --> 00:29:22,250
+P لل CL تمانية و تلاتة يبجه هاي تمانية و تلاتة
+
+353
+00:29:22,250 --> 00:29:23,250
+ماقدر اقول
+
+354
+00:29:26,030 --> 00:29:30,990
+هذا هو ال titration curve اللي عندي ماشي يا شباب
+
+355
+00:29:30,990 --> 00:29:35,490
+اذا انا بقدر اقول حاجة بقدر اقول انه يعني بناء ال
+
+356
+00:29:35,490 --> 00:29:37,470
+titration curve في حالة ال precipitation
+
+357
+00:29:37,470 --> 00:29:42,310
+titrations يعني من أبسط أنواع ال titration curves
+
+358
+00:29:42,310 --> 00:29:46,070
+اللي ممكن نطلع عليها حتى أسهل من ال strong acid و
+
+359
+00:29:46,070 --> 00:29:51,090
+ال strong bases مباشرة للغاية مباشرة للغاية مافيش
+
+360
+00:29:51,090 --> 00:29:56,720
+فيها اي مشاكلقبل نقطة النهاية في عندي زيادة من ال
+
+361
+00:29:56,720 --> 00:30:03,660
+chloride مثلا عند نقطة النهاية من تفكك ال AgCl بعد
+
+362
+00:30:03,660 --> 00:30:06,930
+نقطة النهاية في عندي زيادة من ال silverولما نحسب
+
+363
+00:30:06,930 --> 00:30:10,630
+الـ S في الحالتين سنجدها مهملة لأن الـ Ksp أصلا
+
+364
+00:30:10,630 --> 00:30:13,930
+صغير كثير في وجود ال common ion قبل نقطة النهاية
+
+365
+00:30:13,930 --> 00:30:17,170
+الكلورايد وبعد نقطة النهاية ال silver التفاعل برجع
+
+366
+00:30:17,170 --> 00:30:23,050
+لورا بشكل كبير معنى الكلام مافيش أي قيمة لل S
+
+367
+00:30:23,050 --> 00:30:28,490
+وبالتالي يمكن استخدام ال chloride lift أو ال A G
+
+368
+00:30:28,490 --> 00:30:34,790
+plus excess كأساس لحساب الكلورايد في المحلول
+
+369
+00:30:37,370 --> 00:30:41,770
+طيب يا شباب هذا هو شكل ال titration curve اللي لو
+
+370
+00:30:41,770 --> 00:30:45,470
+اشتغلنا عدة نقاط هيطلع معنا نفس ال titration curve
+
+371
+00:30:45,470 --> 00:30:51,250
+اللي احنا شايفينه وهذا تقريبا 25 مش لنفس المسألة
+
+372
+00:30:51,250 --> 00:30:55,790
+لكن يعني طيب
+
+373
+00:30:55,790 --> 00:31:00,690
+نتطلع الآن على الطرق المختلفة لتعيين ال chloride
+
+374
+00:31:00,690 --> 00:31:07,240
+وبنتكلم فيها عنطبعا معايرة الفضة فبنتكلم عن معايرة
+
+375
+00:31:07,240 --> 00:31:12,400
+الفضة مع ال chloride فبقول في عندي تلت طرق رئيسية
+
+376
+00:31:12,400 --> 00:31:17,260
+فبقول أول طريقة هي طريقة Moore طريقة السيد Moore
+
+377
+00:31:17,260 --> 00:31:23,120
+بتستخدم الكروميت أو ال potassium chromate ك
+
+378
+00:31:23,120 --> 00:31:31,170
+indicator ال potassium chromate مع ال silverبتكون
+
+379
+00:31:31,170 --> 00:31:35,350
+راسب اسمه ال silver chromate ال potassium chromate
+
+380
+00:31:35,350 --> 00:31:43,350
+لونها أصفر ال silver chromate راسب أحمر راسب أحمر
+
+381
+00:31:43,350 --> 00:31:50,850
+فلو أجينا مثلا شفنا هان هي ال chloride وهي ال
+
+382
+00:31:50,850 --> 00:31:53,610
+chromate وهي ال silver
+
+383
+00:31:57,300 --> 00:32:08,560
+بس للمعلومات ال Ksp لل Ag2-Chromate بيساوي 1.3×10
+
+384
+00:32:08,560 --> 00:32:17,260
+-12 و ال Ksp لل AgCl بدي ساوي 10 أقل سالب عشرة
+
+385
+00:32:17,260 --> 00:32:21,920
+فلمّا نقاش أضيف Silver مع أيش هيتفاعل؟ هيتفاعل مع
+
+386
+00:32:21,920 --> 00:32:28,950
+الكلوريد ولا مع الكروميت؟ بديوا يتفاعل مع إيه؟بدي
+
+387
+00:32:28,950 --> 00:32:38,910
+اتفاعل مع الأقل ذوبانية انه الأقل ذوبانية؟ اه،
+
+388
+00:32:38,910 --> 00:32:43,270
+بنقدرش نقارن ال KSPs مع بعض هنا، ليه؟ لأن هذا
+
+389
+00:32:43,270 --> 00:32:47,930
+اتنين لواحد، هذا واحد لواحد، السلفر بقى على
+
+390
+00:32:47,930 --> 00:32:51,070
+الكورية، لكن إيش اللي بنقدر نعمله؟ أنا بقول مع
+
+391
+00:32:51,070 --> 00:32:54,550
+الأقل solubility، لما نحسب ال solubility هنا،
+
+392
+00:32:54,550 --> 00:32:59,080
+حوالي تقريبا عشرة أو سالب أربعةبتساوي ال S هان
+
+393
+00:32:59,080 --> 00:33:02,780
+عشرة أس سالب خمسة بتساوي ال S إذا ال solubility لل
+
+394
+00:33:02,780 --> 00:33:08,640
+AGCL أقل عشرة أس سالب خمسة بينما ال solubility لل
+
+395
+00:33:08,640 --> 00:33:14,380
+AG2-chromate تقريبا عشرة أس سالب أربعة إذا يا شباب
+
+396
+00:33:14,380 --> 00:33:17,340
+إيش اللي هيحصل عندي؟ حصل تفاعل لل silver مع ال
+
+397
+00:33:17,340 --> 00:33:22,380
+chloride ليه؟ لأن ال AGCL أقل ذوبانيا من ال AG2
+
+398
+00:33:22,380 --> 00:33:26,580
+-chromateأخدنا بالنا إيش اللي بتكون دائما في
+
+399
+00:33:26,580 --> 00:33:30,220
+المحلول مش اللي إله Ksp أقل، بتقدر نقارن ال Ksp
+
+400
+00:33:30,220 --> 00:33:34,440
+فقط إذا كان كلها الهلستيستوكيومتري، لكن إذا كان مش
+
+401
+00:33:34,440 --> 00:33:37,040
+كلها الهلستيستوكيومتري، بنطلع على طول، على ال
+
+402
+00:33:37,040 --> 00:33:39,880
+solubility، بحسب ال solubility، ف ال solubility لل
+
+403
+00:33:39,880 --> 00:33:44,000
+AGCl أقل من ال solubility للإكروميت، فبنقول ال
+
+404
+00:33:44,000 --> 00:33:48,970
+AGPlus بتفاعل مع ال chloride لما نخلصبعدين أول
+
+405
+00:33:48,970 --> 00:33:52,590
+نقطة من الجي بلس بتنزل تفعل مع الكرومات بتعطينا
+
+406
+00:33:52,590 --> 00:34:00,990
+اللون الأحمر طيب يا شباب الوسط
+
+407
+00:34:00,990 --> 00:34:05,370
+هنيجي بهالجتلة تفصيل شوية عن ال indicator بس بدي
+
+408
+00:34:05,370 --> 00:34:10,710
+أقول أن الوسط عادة الوسط المستخدم في ال
+
+409
+00:34:10,710 --> 00:34:13,330
+precipitation titrations خاصة ال argentometric
+
+410
+00:34:13,330 --> 00:34:18,690
+titrations تحديداممنوع منع نباتا يكون وسط قاعدى،
+
+411
+00:34:18,690 --> 00:34:23,310
+ممنوع، ليه؟ لأنه مش بس في مورفو، كل الطرق، مدام
+
+412
+00:34:23,310 --> 00:34:26,290
+Argentometric Titrations ممنوع الوسط يكون قاعدى،
+
+413
+00:34:26,290 --> 00:34:29,690
+ليه؟ لأنه إذا كان الوسط قاعدى، الـSilver بدل ما
+
+414
+00:34:29,690 --> 00:34:32,730
+يتفاعل مع الـChloride، بتفاعل مع الـHydroxide،
+
+415
+00:34:32,730 --> 00:34:35,650
+وبيعطينا الـSilver الـHydroxide، إذا خربت المعايرة
+
+416
+00:34:36,720 --> 00:34:41,100
+الممنوع أن السلفر يتفاعل مع الكلوريد لكي يكون ملي
+
+417
+00:34:41,100 --> 00:34:44,060
+مول سلفر يساوي ملي مول الكلوريد، لا يريد السلفر أن
+
+418
+00:34:44,060 --> 00:34:49,420
+يتفاعل مع الهيدروكسيد، لذلك في كل الطرق ممنوع تفكر
+
+419
+00:34:49,420 --> 00:34:53,640
+أنه يمكن أن يكون الوسط قاعدة، ممنوع، يبقى الوسط
+
+420
+00:34:53,640 --> 00:34:58,680
+متعادل أو أسدك، هنا في هذه الحالة، يجب أن يكون
+
+421
+00:34:58,680 --> 00:35:05,000
+الوسط متعادلليه؟ لأنه الوسط الحمضي بيخلي الكرومات
+
+422
+00:35:05,000 --> 00:35:14,180
+تتحول إلى ال di-chromate هاي الكرومات في
+
+423
+00:35:14,180 --> 00:35:24,280
+وجود H بلاس بتتحول ل ال di-chromateو die chromate
+
+424
+00:35:24,280 --> 00:35:27,020
+طبعا بقى ال indicator انا ال indicator تبقى ايش هو
+
+425
+00:35:27,020 --> 00:35:30,440
+ال chromate فانا فقدت ال indicator في هذه الحالة
+
+426
+00:35:30,440 --> 00:35:34,740
+علشان هيك بنقول ان الوسط لازم يكون متعدل يعني
+
+427
+00:35:34,740 --> 00:35:41,180
+حوالين السبعة طيب السؤال الآن جداش تركيز ال
+
+428
+00:35:41,180 --> 00:35:44,340
+indicator المستخدم جداش لازم يكون تركيز ال
+
+429
+00:35:44,340 --> 00:35:49,400
+indicator المستخدم ليه لأنه ال indicator بده يكون
+
+430
+00:35:50,650 --> 00:35:55,710
+راصب مش انه لونه هو بده يتغير للي استخدم اي تركيز
+
+431
+00:35:55,710 --> 00:36:00,570
+لأ هذا بده يكوّن راصب فانا لازم اعرف جداش تركيز ال
+
+432
+00:36:00,570 --> 00:36:04,170
+indicator لازم استخدمه بحيث انه نسبة الخطأ تكون
+
+433
+00:36:04,170 --> 00:36:10,710
+عندى صفر قليلة جدا او يعني صفر من ناحية عملية فاش
+
+434
+00:36:10,710 --> 00:36:17,010
+بده اعمل بقول تعالوا نفترض انه عندى0.1 مولار
+
+435
+00:36:17,010 --> 00:36:21,010
+كلورايد بدعايره مع 0.1 مولار سلفر، طبعا التانين
+
+436
+00:36:21,010 --> 00:36:25,350
+بتعايروا بحصل على ال end point لما نحط حجم معين من
+
+437
+00:36:25,350 --> 00:36:30,190
+الكلورايد أحط عليه نفس الحجم من السلفر لأنه
+
+438
+00:36:30,190 --> 00:36:34,430
+الاتنين تركيزهم واحد، فإذا كان نفس الحجم حطيته،
+
+439
+00:36:34,430 --> 00:36:37,210
+معنى الكلام بحصل على ال end point أو ال
+
+440
+00:36:37,210 --> 00:36:40,630
+equivalence pointطب عند ال equivalence point ال ag
+
+441
+00:36:40,630 --> 00:36:44,330
+plus بدي ساوي ال chloride إذا كان ال Ksp كان واحد
+
+442
+00:36:44,330 --> 00:36:48,950
+و تمانية في عشرة أقل سالب عشرة إذا ال silver بدي
+
+443
+00:36:48,950 --> 00:36:51,330
+ساوي ال chloride ساوي جزر ال Ksp ساوي واحد و خمسة
+
+444
+00:36:51,330 --> 00:36:54,670
+و تلاتين في عشرة أقل سالب خمسة هذا تركيز ال silver
+
+445
+00:36:54,670 --> 00:36:59,390
+عند إيه؟ عند ال equivalence point يبقى هن في عندي
+
+446
+00:36:59,390 --> 00:37:05,670
+عند ال equivalence point ال silverتركيزه واحد
+
+447
+00:37:05,670 --> 00:37:09,770
+وخمسة و تلاتين في عشر أقل سالب خمسة molar طيب أنا
+
+448
+00:37:09,770 --> 00:37:13,550
+بقول بده يعطيني لون إذا بده يكون إيه؟ بده يكون
+
+449
+00:37:13,550 --> 00:37:17,780
+راصب مع الكروميتعشان يكون راسب مع ليكرومات انا
+
+450
+00:37:17,780 --> 00:37:21,320
+بعرف انه اتنين silver مع ليكرومات بيعطوني silver
+
+451
+00:37:21,320 --> 00:37:25,320
+ليكرومات طيب ال KSP بده يساوي ال silver تربيع في
+
+452
+00:37:25,320 --> 00:37:28,380
+ليكرومات انا ال silver معايا هيو عند ال
+
+453
+00:37:28,380 --> 00:37:30,920
+equivalence point واحد وخمسة و تلاتين في عشر او
+
+454
+00:37:30,920 --> 00:37:34,400
+السلم خمسة بدي ايه يكون راسب يعني ال KSP بدها
+
+455
+00:37:34,400 --> 00:37:38,740
+تساوي just precipitate ال silver ليكرومات silver
+
+456
+00:37:38,740 --> 00:37:43,360
+تربيع في ليكرومات طيب جداش بده يكون تركيز ليكرومات
+
+457
+00:37:43,360 --> 00:37:52,780
+بلاحظ انهتركيز لكروميت تركيز لكروميت تركيز لكروميت
+
+458
+00:37:52,780 --> 00:37:55,840
+تركيز لكروميت تركيز لكروميت تركيز لكروميت تركيز
+
+459
+00:37:55,840 --> 00:37:57,400
+لكروميت تركيز لكروميت تركيز لكروميت تركيز لكروميت
+
+460
+00:37:57,400 --> 00:38:00,520
+تركيز لكروميت تركيز لكروميت تركيز لكروميت تركيز
+
+461
+00:38:00,520 --> 00:38:01,380
+لكروميت تركيز لكروميت تركيز لكروميت تركيز لكروميت
+
+462
+00:38:01,380 --> 00:38:01,680
+تركيز لكروميت تركيز لكروميت تركيز لكروميت تركيز
+
+463
+00:38:01,680 --> 00:38:01,680
+لكروميت تركيز لكروميت تركيز لكروميت تركيز لكروميت
+
+464
+00:38:01,680 --> 00:38:07,600
+تركيز لكروميت تركيز لكروميت تركيز لكروميت تركيز
+
+465
+00:38:07,600 --> 00:38:16,400
+لكرومكمية من ال chloride وكمية مكافئة من ال silver
+
+466
+00:38:16,400 --> 00:38:22,380
+فالحجم اتضاعف يعني الاصل انه عند بداية ال
+
+467
+00:38:22,380 --> 00:38:27,300
+titration تركيز الكرومة يكون ضعف هذايعني هي تركيز
+
+468
+00:38:27,300 --> 00:38:30,420
+الكروميت لما كان الحجم هو عبارة عن حجم الكلورايد
+
+469
+00:38:30,420 --> 00:38:34,180
+زائد حجم السلفر، حجم كبير، طب في الاصل جردش كان
+
+470
+00:38:34,180 --> 00:38:37,580
+تركيز الكروميت عشان يوصل لهذا، اي نقطة النهاية،
+
+471
+00:38:37,580 --> 00:38:41,220
+اه، ضعفه، اتنين في سبعة، واحد من عشرة في عشرة أقل
+
+472
+00:38:41,220 --> 00:38:45,490
+سالب تلاتة، يعني بده يكون point O142 molarهذا
+
+473
+00:38:45,490 --> 00:38:49,030
+التركيز الليكروميت الأصلي اللي بده يكون ساعة ما
+
+474
+00:38:49,030 --> 00:38:53,690
+أحطه في المحلول
+
+475
+00:38:53,690 --> 00:38:57,150
+قبل ما أبدأ عملية المعايرة لازم يكون تركيز
+
+476
+00:38:57,150 --> 00:39:01,130
+الليكروميت هالجد على أي حال بغض النظر بغض النظر
+
+477
+00:39:01,130 --> 00:39:05,310
+بقول معنى الكلام at equivalence point جداش بده
+
+478
+00:39:05,310 --> 00:39:09,550
+يكون تركيز الليكروميت جال 7×10 أسالب 3 هذا عندي ال
+
+479
+00:39:09,550 --> 00:39:14,910
+equivalence point ليه؟ علشان يقدر يعطينا الراسبطيب
+
+480
+00:39:14,910 --> 00:39:18,990
+فى الحقيقة 7 فى 10 أقل ثالث تلاتة هذا تركيز عالى
+
+481
+00:39:18,990 --> 00:39:24,210
+جدا ليش عالى جدا جال لأنه لون ليكروميت لون أصفر
+
+482
+00:39:24,210 --> 00:39:29,650
+أصفر غابج و اللون الأصفر يا شباب لما يبدأ يدوب
+
+483
+00:39:29,650 --> 00:39:32,150
+يتكون أول نقطة تكون لون أحمر مع ال silver
+
+484
+00:39:32,150 --> 00:39:37,670
+lycromate اللون الأصفر لليكروميت بيكون غالب كتير
+
+485
+00:39:37,670 --> 00:39:42,910
+على اللون الأحمر بقدرش أشوف اللون الأحمر منهعشان
+
+486
+00:39:42,910 --> 00:39:46,530
+هيك من ناحية عملية أنا بستخدمش 7 في 10 أقل سالب 3
+
+487
+00:39:46,530 --> 00:39:51,330
+بستخدم بالكتير 2.5 في 10 أقل سالب 3 يعني تلت
+
+488
+00:39:51,330 --> 00:39:56,070
+التركيز يعني أنا بستخدم تلت تركيز لكروميت طب لما
+
+489
+00:39:56,070 --> 00:40:00,090
+نستخدم تلت تركيز لكروميت إذا لازم هذا ال silver
+
+490
+00:40:00,090 --> 00:40:07,350
+بكفيش يعطينيأنا لازم أحط كمان silver من الصحاحة
+
+491
+00:40:07,350 --> 00:40:12,470
+علشان أحصل على الراسب لأن الكروميد تركيز و جل أنا
+
+492
+00:40:12,470 --> 00:40:19,890
+عند ال KSP بتساوي ال silver تربيع في الكروميد إذا
+
+493
+00:40:19,890 --> 00:40:22,830
+كان هذا تركيز و جل إذا إيش تركيز ال silver؟ لازم
+
+494
+00:40:22,830 --> 00:40:28,420
+أزيد كيف بدي أزوده؟ بدي أضيف شوية silverإذاً هذا
+
+495
+00:40:28,420 --> 00:40:32,660
+بيقدّي لخطأ لأنه أنا أضفت silver زيادة صح ولا لأ؟
+
+496
+00:40:32,660 --> 00:40:34,980
+أنا أضفت silver زيادة عشان أحصل على ال equivalence
+
+497
+00:40:34,980 --> 00:40:38,620
+point ليش؟ لأنه استخدمت تركيزي .. تركيزي chromate
+
+498
+00:40:38,620 --> 00:40:42,460
+أقل من اللازم طب ليش أنا أستخدم تركيزي chromate
+
+499
+00:40:42,460 --> 00:40:47,440
+أقل من اللازم؟ لأنه اللون بشوفوش منيح إلا أستخدم
+
+500
+00:40:47,440 --> 00:40:51,700
+تركيز أخف طب إيش بتعمل؟ كيف تتغلب على هذا الخطأ؟
+
+501
+00:40:51,700 --> 00:40:57,060
+معظم الناس للأسف بتعمليش حاجة لكن بقول إنه يمكن
+
+502
+00:40:58,100 --> 00:41:01,540
+التغلب على هذا الخطأ بإنه نعمل a blank experiment
+
+503
+00:41:01,540 --> 00:41:08,980
+a blank titration إيش
+
+504
+00:41:08,980 --> 00:41:13,180
+هي هذا الحجم at equivalence point وعليه الكرومات
+
+505
+00:41:13,180 --> 00:41:17,680
+أو فيه الكرومات؟بنفس التركيز at equivalence point
+
+506
+00:41:17,680 --> 00:41:21,500
+اللي استخدمناها يعني هذا الحجم at equivalence
+
+507
+00:41:21,500 --> 00:41:24,240
+point موجود في الكروميت بنفس التركيز اتنين و نص
+
+508
+00:41:24,240 --> 00:41:28,660
+فعشرة أس سالم تلاتة الان بدنا نعييرها بال إيه بال
+
+509
+00:41:28,660 --> 00:41:34,540
+silver أول ما أشوف اللون بكون عرفت جداش أخدت من ال
+
+510
+00:41:34,540 --> 00:41:39,520
+silver عشان اتفرجين اللون لو طرحت هذه القيمةمن
+
+511
+00:41:39,520 --> 00:41:43,460
+التجربة الأولى اللى هي معايرة الليكلوريد في وجود
+
+512
+00:41:43,460 --> 00:41:48,340
+الليكروميل بتخلص من الخطأ اذا التخلص من الخطأ شغلة
+
+513
+00:41:48,340 --> 00:41:51,880
+بسيطة استخدام blank لكن بدي اخد بالي في ال blank
+
+514
+00:41:51,880 --> 00:41:58,220
+انه بدي استخدم نفسالـ volume at equivalence point
+
+515
+00:41:58,220 --> 00:42:03,560
+نفس تركيز لكروميت المستخدم في تجربة Moore اللي هو
+
+516
+00:42:03,560 --> 00:42:08,640
+2.5×10 أو سالب تلاتة
+
+517
+00:42:08,640 --> 00:42:13,620
+تقريبا اللي هو تلت التركيز النظري اللي المفروض ان
+
+518
+00:42:13,620 --> 00:42:18,500
+انا استخدمه فبحصل على جداش اخدت حجم طبعا few drops
+
+519
+00:42:18,500 --> 00:42:22,180
+يعني نص مل حاجة زي هيك مش انها تلاتة من عشرة مل
+
+520
+00:42:22,180 --> 00:42:25,940
+حاجة قليلة يعني مش كتيرلكن باخد هذا الحجم بطرحه من
+
+521
+00:42:25,940 --> 00:42:31,700
+الحجم الأول بيعطيني الحجم المكافئ ل ال chloride
+
+522
+00:42:31,700 --> 00:42:39,740
+لوحده ماشي يا شباب طيب انا بدي اوجف هان الحصة
+
+523
+00:42:39,740 --> 00:42:44,060
+الجاية هنشوف الطريقتين اللي فضلين لتعيين ال
+
+524
+00:42:44,060 --> 00:42:48,180
+chloride طريقة Fagens وطريقة Walhart فبنشوفكم إذا
+
+525
+00:42:48,180 --> 00:42:49,460
+الله راد يوم الأربعة
+
diff --git a/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/eMrPav-gqxE_raw.json b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/eMrPav-gqxE_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..7cf3ed1b25d4e749124b117d45d417f28e22b3a9
--- /dev/null
+++ b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/eMrPav-gqxE_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 2786, "start": 21.58, "end": 27.86, "text": "بسم الله الرحمن الرحيم اليوم ان شاء الله بنستكمل الموضوع اللي بدأنا فيه الحصة الماضية", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640, 45595, 20498, 16472, 13412, 16606, 21984, 44945, 14851, 24793, 1211, 9673, 2407, 11242, 45367, 13672, 1829, 47525, 10721, 8315, 8978, 3224, 21542, 9381, 3660, 9673, 46958, 10632], "avg_logprob": -0.07675253458925195, "compression_ratio": 1.56, "no_speech_prob": 1.7881393432617188e-07, "words": [{"start": 21.58, "end": 21.94, "word": "بسم", "probability": 0.891357421875}, {"start": 21.94, "end": 22.1, "word": " الله", "probability": 0.958984375}, {"start": 22.1, "end": 22.38, "word": " الرحمن", "probability": 0.974609375}, {"start": 22.38, "end": 22.82, "word": " الرحيم", "probability": 0.9921875}, {"start": 22.82, "end": 23.16, "word": " اليوم", "probability": 0.97021484375}, {"start": 23.16, "end": 23.28, "word": " ان", "probability": 0.6396484375}, {"start": 23.28, "end": 23.52, "word": " شاء", "probability": 0.9658203125}, {"start": 23.52, "end": 23.66, "word": " الله", "probability": 0.94384765625}, {"start": 23.66, "end": 25.2, "word": " بنستكمل", "probability": 0.9530029296875}, {"start": 25.2, "end": 25.82, "word": " الموضوع", "probability": 0.9945068359375}, {"start": 25.82, "end": 26.04, "word": " اللي", "probability": 0.791748046875}, {"start": 26.04, "end": 26.72, "word": " بدأنا", "probability": 0.87939453125}, {"start": 26.72, "end": 26.98, "word": " فيه", "probability": 0.782958984375}, {"start": 26.98, "end": 27.36, "word": " الحصة", "probability": 0.9825846354166666}, {"start": 27.36, "end": 27.86, "word": " الماضية", "probability": 0.9934895833333334}], "temperature": 1.0}, {"id": 2, "seek": 5625, "start": 28.53, "end": 56.25, "text": "كنا بدأنا نتكلم عن ال standard deviation وشوفنا انه ال standard deviation بيعبر عن ال spread لل results حوالين ال mean ال spread لل results حوالين ال mean فشوفنا نوعين من أنواع ال standard deviation شوفنا حاجة سمنها population standard deviation وذكرنا انه ال population standard deviation بنستخدمه", "tokens": [4117, 8315, 47525, 10721, 8315, 8717, 2655, 4117, 19528, 18871, 2423, 3832, 25163, 4032, 8592, 38688, 8315, 16472, 3224, 2423, 3832, 25163, 4724, 40228, 26890, 18871, 2423, 3974, 24976, 3542, 11331, 2407, 6027, 9957, 2423, 914, 2423, 3974, 24976, 3542, 11331, 2407, 6027, 9957, 2423, 914, 6156, 8592, 38688, 8315, 8717, 45367, 9957, 9154, 14739, 14407, 3615, 2423, 3832, 25163, 13412, 38688, 8315, 11331, 26108, 3660, 8608, 27842, 11296, 4415, 3832, 25163, 4032, 8848, 37983, 8315, 16472, 3224, 2423, 4415, 3832, 25163, 44945, 14851, 9778, 40448, 3224], "avg_logprob": -0.11274857895279472, "compression_ratio": 2.2162162162162162, "no_speech_prob": 0.0, "words": [{"start": 28.53, "end": 29.15, "word": "كنا", "probability": 0.704833984375}, {"start": 29.15, "end": 29.55, "word": " بدأنا", "probability": 0.9850260416666666}, {"start": 29.55, "end": 30.07, "word": " 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{"start": 50.61, "end": 51.33, "word": " deviation", "probability": 0.96044921875}, {"start": 51.33, "end": 52.59, "word": " وذكرنا", "probability": 0.85845947265625}, {"start": 52.59, "end": 52.89, "word": " انه", "probability": 0.712646484375}, {"start": 52.89, "end": 52.95, "word": " ال", "probability": 0.84814453125}, {"start": 52.95, "end": 53.51, "word": " population", "probability": 0.97900390625}, {"start": 53.51, "end": 54.11, "word": " standard", "probability": 0.96484375}, {"start": 54.11, "end": 54.83, "word": " deviation", "probability": 0.9638671875}, {"start": 54.83, "end": 56.25, "word": " بنستخدمه", "probability": 0.95615234375}], "temperature": 1.0}, {"id": 3, "seek": 8519, "start": 57.79, "end": 85.19, "text": "مع عدد كبير من ال data points أو النتائج لكن احنا في الكيميا بالذات في الكيميا التحليلية عدد النتائج اللي بنتعامل معاها عدد قليل نسبيا يعني من تلت لخمس تجارب بنكررها عادة فقولنا انه بنستخدم حاجة سمناها sample standard deviation او سمناها برضه estimated", 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"word": " population", "probability": 0.9599609375}, {"start": 97.74, "end": 98.8, "word": " standard", "probability": 0.8818359375}, {"start": 98.8, "end": 99.36, "word": " deviation", "probability": 0.951171875}, {"start": 99.36, "end": 99.58, "word": " كنا", "probability": 0.96630859375}, {"start": 99.58, "end": 100.02, "word": " بنستخدم", "probability": 0.8758544921875}, {"start": 100.02, "end": 100.16, "word": " ال", "probability": 0.36376953125}, {"start": 100.16, "end": 100.56, "word": " true", "probability": 0.91748046875}, {"start": 100.56, "end": 101.04, "word": " mean", "probability": 0.9267578125}], "temperature": 1.0}, {"id": 5, "seek": 11753, "start": 101.77, "end": 117.53, "text": "أو الـ true average، لكن بالطبع لما نتكلم عن عدد تجارب محدود فاحنا بنتكلم عن experimental mean ولا شك أنه في عندي اختلاف بين الاتنين، ايضا ال degrees of freedom في ال sample standard deviation", "tokens": [10721, 2407, 2423, 39184, 2074, 4274, 12399, 44381, 20666, 9566, 3555, 3615, 5296, 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"end": 238.39, "word": " نفس", "probability": 0.98095703125}, {"start": 238.39, "end": 239.35, "word": " الشيء", "probability": 0.9602864583333334}, {"start": 239.35, "end": 239.55, "word": " مش", "probability": 0.841796875}, {"start": 239.55, "end": 240.29, "word": " هيك", "probability": 0.972900390625}, {"start": 240.29, "end": 240.83, "word": " علشان", "probability": 0.9241536458333334}, {"start": 240.83, "end": 241.01, "word": " هيك", "probability": 0.984619140625}, {"start": 241.01, "end": 241.29, "word": " بنقول", "probability": 0.94482421875}, {"start": 241.29, "end": 241.83, "word": " أنه", "probability": 0.6094970703125}, {"start": 241.83, "end": 242.45, "word": " قيمة", "probability": 0.9964192708333334}, {"start": 242.45, "end": 242.85, "word": " الخطأ", "probability": 0.9954427083333334}, {"start": 242.85, "end": 243.41, "word": " المطلق", "probability": 0.994873046875}, {"start": 243.41, "end": 243.83, "word": " بحد", "probability": 0.89013671875}, {"start": 243.83, "end": 244.19, "word": " ذاته", "probability": 0.9931640625}, {"start": 244.19, "end": 244.39, "word": " مش", "probability": 0.97705078125}, {"start": 244.39, "end": 244.69, "word": " كتير", "probability": 0.9640299479166666}, {"start": 244.69, "end": 244.91, "word": " مهم", "probability": 0.99462890625}, {"start": 244.91, "end": 245.41, "word": " بالنسبة", "probability": 0.9503173828125}, {"start": 245.41, "end": 245.59, "word": " لي", "probability": 0.92431640625}], "temperature": 1.0}, {"id": 12, "seek": 26912, "start": 245.9, "end": 269.12, "text": "لازم يعرف هذا الخطأ المطلق في أي كمية موجود علشان هيك في أسلوب أخر للتعبير عن ال standard deviation بياخد هذا الكلام بعين الاعتبار بنسميه relative standard deviation ال relative standard deviation بياخده بعين الاعتبار الكمية أو ال average", "tokens": [1211, 31377, 2304, 37495, 28480, 23758, 33962, 9566, 10721, 9673, 9566, 1211, 4587, 8978, 36632, 9122, 2304, 10632, 3714, 29245, 23328, 11203, 8592, 7649, 39896, 4117, 8978, 5551, 3794, 1211, 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تربيع هاي النتيجة تبعتها هذا اللي بتعطينا ال S A اللي انا بده احطها هنا", "tokens": [3555, 2655, 3794, 995, 45865, 25724, 11622, 2288, 16712, 2288, 21292, 3615, 1829, 1804, 420, 3175, 935, 1451, 935, 1451, 6055, 2288, 21292, 3615, 30767, 16373, 3215, 1804, 420, 3175, 935, 732, 6055, 2288, 21292, 3615, 8032, 47302, 28239, 31371, 7435, 3660, 6055, 3555, 34268, 11296, 23758, 13672, 1829, 39894, 3615, 9566, 1829, 8315, 2423, 318, 316, 13672, 1829, 1975, 8315, 47525, 3224, 1975, 5016, 9566, 11296, 34105], "avg_logprob": -0.3122735438139542, "compression_ratio": 1.6689189189189189, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 2441.81, "end": 2442.47, "word": "بتساوي", "probability": 0.7193359375}, {"start": 2442.47, "end": 2442.93, "word": " الجزر", "probability": 0.8816731770833334}, {"start": 2442.93, "end": 2443.93, "word": " التربيعي", "probability": 0.83212890625}, {"start": 2443.93, "end": 2444.55, "word": " plus", "probability": 0.51953125}, {"start": 2444.55, "end": 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حللناها خمس مرات كل مرة أعطينا نتيجة ال average إيه لهم لو طلع مثلا خمستاشر تمانية و سبعين هيك ال average طلع طيب مش احنا حللناها خمس مرات بنقدر نحسب ال standard deviation لو حسبناها", "tokens": [2304, 12984, 15040, 45164, 6225, 42213, 8315, 16712, 7435, 25513, 3660, 9673, 20292, 3714, 12610, 11622, 9154, 1975, 1829, 3224, 6225, 8592, 7649, 8717, 3615, 28480, 10874, 16254, 8592, 11331, 1211, 1211, 8315, 11296, 16490, 2304, 3794, 3714, 2288, 9307, 28242, 3714, 25720, 5551, 3615, 9566, 1829, 8315, 8717, 31371, 7435, 3660, 2423, 4274, 11933, 1829, 3224, 5296, 16095, 45164, 23032, 1211, 3615, 50113, 15040, 16490, 2304, 14851, 33599, 2288, 46811, 7649, 10632, 4032, 8608, 3555, 3615, 9957, 39896, 4117, 2423, 4274, 23032, 1211, 3615, 23032, 1829, 3555, 37893, 1975, 5016, 8315, 11331, 1211, 1211, 8315, 11296, 16490, 2304, 3794, 3714, 2288, 9307, 44945, 28543, 2288, 8717, 5016, 35457, 2423, 3832, 25163, 45164, 11331, 35457, 8315, 11296], "avg_logprob": -0.1950476698703685, "compression_ratio": 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"word": " فنيجي", "probability": 0.79697265625}, {"start": 2580.22, "end": 2580.78, "word": " نتطلع", "probability": 0.888037109375}, {"start": 2580.78, "end": 2581.2, "word": " على", "probability": 0.9384765625}, {"start": 2581.2, "end": 2583.62, "word": " هالمثال", "probability": 0.8192138671875}, {"start": 2583.62, "end": 2584.18, "word": " التالي", "probability": 0.9607747395833334}, {"start": 2584.18, "end": 2585.62, "word": " المثال", "probability": 0.9225260416666666}, {"start": 2585.62, "end": 2585.82, "word": " إيش", "probability": 0.7978515625}, {"start": 2585.82, "end": 2586.54, "word": " بيقول؟", "probability": 0.8775634765625}, {"start": 2586.54, "end": 2587.04, "word": " بيقول", "probability": 0.9495442708333334}, {"start": 2587.04, "end": 2587.3, "word": " ال", "probability": 0.78076171875}, {"start": 2587.3, "end": 2587.5, "word": " three", "probability": 0.40185546875}, {"start": 2587.5, "end": 2588.18, "word": " samples", "probability": 0.884765625}, {"start": 2588.18, "end": 2588.44, "word": " were", "probability": 0.8671875}, {"start": 2588.44, "end": 2588.96, "word": " analyzed", "probability": 0.74169921875}, {"start": 2588.96, "end": 2589.3, "word": " for", "probability": 0.974609375}, {"start": 2589.3, "end": 2589.76, "word": " iron", "probability": 0.88916015625}, {"start": 2589.76, "end": 2590.58, "word": " content", "probability": 0.91796875}], "temperature": 1.0}, {"id": 112, "seek": 261189, "start": 2591.31, "end": 2611.89, "text": "في تلت عينات حللناهم لل iron content كل عينة حللناها عدة مرات مثلا نقول حللناها سبعة مرات التانية تمان مرات التالتة تسعة مرات بقول the average percentage of iron in the first sample was 65.06 يعني أول عينة أخدناها حللناها خمس ست مرات", "tokens": [41185, 6055, 1211, 2655, 6225, 1829, 8315, 2655, 11331, 1211, 1211, 8315, 16095, 24976, 6497, 2701, 28242, 6225, 9957, 3660, 11331, 1211, 1211, 8315, 11296, 6225, 41891, 3714, 2288, 9307, 50113, 15040, 8717, 39648, 11331, 1211, 1211, 8315, 11296, 8608, 3555, 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2611.13, "word": " خمس", "probability": 0.98095703125}, {"start": 2611.13, "end": 2611.35, "word": " ست", "probability": 0.795166015625}, {"start": 2611.35, "end": 2611.89, "word": " مرات", "probability": 0.9645182291666666}], "temperature": 1.0}, {"id": 113, "seek": 263941, "start": 2612.97, "end": 2639.41, "text": "فكل مرة اعطتني قيمة نتيجة مرة 66 مرة 65 مرة 64 مرة 67 لما حسبنا المتوسط كده شطلع 65.6% لحظه انه ممكن احسب كمان ايش ال standard deviation هى اللى جت بعد شوية هيعطوه اللى ممكن احسب ال standard بما اندي نتائج واندي ال average بقدر احسب ال standard deviation طب هذه العينة و العينة التانية اعطتنى 56.13", "tokens": [5172, 28820, 3714, 25720, 1975, 3615, 9566, 2655, 22653, 12174, 32640, 3660, 8717, 31371, 7435, 3660, 3714, 25720, 21126, 3714, 25720, 11624, 3714, 25720, 12145, 3714, 25720, 23879, 5296, 15042, 11331, 35457, 8315, 9673, 2655, 41779, 9566, 9122, 3215, 3224, 13412, 9566, 1211, 3615, 11624, 13, 21, 4, 5296, 5016, 19913, 3224, 16472, 3224, 3714, 43020, 1975, 5016, 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3035.35, "word": " إذا", "probability": 0.78564453125}, {"start": 3035.35, "end": 3035.57, "word": " قال", "probability": 0.70703125}, {"start": 3035.57, "end": 3035.95, "word": " رد", "probability": 0.6396484375}, {"start": 3035.95, "end": 3036.49, "word": " الحصة", "probability": 0.9913736979166666}, {"start": 3036.49, "end": 3036.91, "word": " الجاية", "probability": 0.9296875}, {"start": 3036.91, "end": 3037.61, "word": " هنتكلم", "probability": 0.926025390625}, {"start": 3037.61, "end": 3037.95, "word": " عن", "probability": 0.98876953125}, {"start": 3037.95, "end": 3038.83, "word": " الدرب", "probability": 0.740966796875}, {"start": 3038.83, "end": 3039.85, "word": " والجسمة", "probability": 0.877197265625}, {"start": 3039.85, "end": 3040.01, "word": " و", "probability": 0.845703125}, {"start": 3040.01, "end": 3041.29, "word": " هنثبتلكم", "probability": 0.7929338727678571}, {"start": 3041.29, "end": 3041.67, "word": " أو", "probability": 0.736328125}, {"start": 3041.67, "end": 3042.27, "word": " هنحاول", "probability": 0.9716796875}, {"start": 3042.27, "end": 3043.09, "word": " نستنتج", "probability": 0.9886474609375}, {"start": 3043.09, "end": 3043.77, "word": " أن", "probability": 0.50390625}, {"start": 3043.77, "end": 3044.93, "word": " ال", "probability": 0.8642578125}, {"start": 3044.93, "end": 3045.39, "word": " uncertainty", "probability": 0.49609375}, {"start": 3045.39, "end": 3045.93, "word": " هذه", "probability": 0.60986328125}, {"start": 3045.93, "end": 3046.07, "word": " اللي", "probability": 0.936279296875}, {"start": 3046.07, "end": 3046.25, "word": " احنا", "probability": 0.7686360677083334}, {"start": 3046.25, "end": 3046.47, "word": " الآن", "probability": 0.564208984375}, {"start": 3046.47, "end": 3047.33, "word": " بنتعلمها", "probability": 0.89736328125}, {"start": 3047.33, "end": 3048.11, "word": " هي", "probability": 0.9228515625}, {"start": 3048.11, "end": 3048.59, "word": " التي", "probability": 0.65869140625}, {"start": 3048.59, "end": 3049.77, "word": " تحدد", "probability": 0.9886067708333334}, {"start": 3049.77, "end": 3050.31, "word": " عدد", "probability": 0.9928385416666666}, {"start": 3050.31, "end": 3050.45, "word": " ال", "probability": 0.79736328125}, {"start": 3050.45, "end": 3050.81, "word": " significant", "probability": 0.52099609375}, {"start": 3050.81, "end": 3051.21, "word": " figures", "probability": 0.91845703125}, {"start": 3051.21, "end": 3051.35, "word": " في", "probability": 0.92822265625}, {"start": 3051.35, "end": 3052.07, "word": " الجواب", "probability": 0.97998046875}, {"start": 3052.07, "end": 3052.59, "word": " مش", "probability": 0.78955078125}, {"start": 3052.59, "end": 3052.77, "word": " ال", "probability": 0.94091796875}, {"start": 3052.77, "end": 3052.93, "word": " key", "probability": 0.802734375}, {"start": 3052.93, "end": 3053.33, "word": " number", "probability": 0.9814453125}, {"start": 3053.33, "end": 3054.09, "word": " ولا", "probability": 0.8876953125}], "temperature": 1.0}, {"id": 132, "seek": 307717, "start": 3054.57, "end": 3077.17, "text": "أكم digit على يمين العلامة العشرية اللي بيحدد ال answer تنتهي في الجواب او عدد ال significant figures اللي في الجواب هي ال answer تنتهي المصاحبة للجواب وليس اي شيء اخر هذا اذا كان في في الجواب answer تنتهي معلومة هنشوف هذا الكلام اذا الله راد الحصة الجاية في اي سؤال يا شباب", "tokens": [10721, 24793, 14293, 15844, 7251, 2304, 9957, 18863, 37440, 3660, 18863, 8592, 2288, 10632, 13672, 1829, 4724, 1829, 24401, 3215, 2423, 1867, 6055, 29399, 3224, 1829, 8978, 25724, 14407, 3555, 1975, 2407, 6225, 3215, 3215, 2423, 4776, 9624, 13672, 1829, 8978, 25724, 14407, 3555, 39896, 2423, 1867, 6055, 29399, 3224, 1829, 9673, 9381, 39319, 49401, 24976, 7435, 14407, 3555, 4032, 20292, 3794, 1975, 1829, 44049, 38207, 1975, 34740, 23758, 1975, 15730, 25961, 8978, 8978, 25724, 14407, 3555, 1867, 6055, 29399, 3224, 1829, 20449, 1211, 20498, 3660, 8032, 1863, 8592, 38688, 23758, 2423, 28820, 10943, 1975, 15730, 21984, 12602, 18513, 21542, 9381, 3660, 25724, 995, 10632, 8978, 1975, 1829, 8608, 33604, 6027, 35186, 13412, 3555, 16758], "avg_logprob": -0.1402209005479155, "compression_ratio": 1.9956140350877194, "no_speech_prob": 3.6954879760742188e-06, "words": [{"start": 3054.57, "end": 3055.09, "word": "أكم", "probability": 0.793212890625}, {"start": 3055.09, "end": 3055.67, "word": " digit", "probability": 0.60791015625}, {"start": 3055.67, "end": 3056.05, "word": " على", "probability": 0.8046875}, {"start": 3056.05, "end": 3056.55, "word": " يمين", "probability": 0.9728190104166666}, {"start": 3056.55, "end": 3057.05, "word": " العلامة", "probability": 0.95947265625}, {"start": 3057.05, "end": 3057.69, "word": " العشرية", "probability": 0.8359375}, {"start": 3057.69, "end": 3058.35, "word": " اللي", "probability": 0.698974609375}, {"start": 3058.35, "end": 3059.29, "word": " بيحدد", "probability": 0.9849853515625}, {"start": 3059.29, "end": 3059.75, "word": " ال", "probability": 0.9189453125}, {"start": 3059.75, "end": 3060.11, "word": " answer", "probability": 0.388427734375}, {"start": 3060.11, "end": 3060.57, "word": " تنتهي", "probability": 0.75115966796875}, {"start": 3060.57, "end": 3060.67, "word": " في", "probability": 0.8916015625}, {"start": 3060.67, "end": 3061.27, "word": " الجواب", "probability": 0.97998046875}, {"start": 3061.27, "end": 3062.87, "word": " او", "probability": 0.6676025390625}, {"start": 3062.87, "end": 3063.25, "word": " عدد", "probability": 0.97900390625}, {"start": 3063.25, "end": 3063.35, "word": " ال", "probability": 0.83984375}, {"start": 3063.35, "end": 3063.79, "word": " significant", "probability": 0.6669921875}, {"start": 3063.79, "end": 3064.23, "word": " figures", "probability": 0.81494140625}, {"start": 3064.23, "end": 3064.39, "word": " اللي", "probability": 0.959228515625}, {"start": 3064.39, "end": 3064.49, "word": " في", "probability": 0.92822265625}, {"start": 3064.49, "end": 3064.99, "word": " الجواب", "probability": 0.9847005208333334}, {"start": 3064.99, "end": 3065.37, "word": " هي", "probability": 0.8212890625}, {"start": 3065.37, "end": 3065.61, "word": " ال", "probability": 0.93359375}, {"start": 3065.61, "end": 3065.95, "word": " answer", "probability": 0.732421875}, {"start": 3065.95, "end": 3066.41, "word": " تنتهي", "probability": 0.9639892578125}, {"start": 3066.41, "end": 3067.03, "word": " المصاحبة", "probability": 0.984375}, {"start": 3067.03, "end": 3067.85, "word": " للجواب", "probability": 0.9674072265625}, {"start": 3067.85, "end": 3068.37, "word": " وليس", "probability": 0.8453776041666666}, {"start": 3068.37, "end": 3068.91, "word": " اي", "probability": 0.76220703125}, {"start": 3068.91, "end": 3069.17, "word": " شيء", "probability": 0.830078125}, {"start": 3069.17, "end": 3069.45, "word": " اخر", "probability": 0.916015625}, {"start": 3069.45, "end": 3069.65, "word": " هذا", "probability": 0.8408203125}, {"start": 3069.65, "end": 3069.89, "word": " اذا", "probability": 0.865478515625}, {"start": 3069.89, "end": 3070.27, "word": " كان", "probability": 0.99609375}, {"start": 3070.27, "end": 3070.71, "word": " في", "probability": 0.89013671875}, {"start": 3070.71, "end": 3070.89, "word": " في", "probability": 0.662109375}, {"start": 3070.89, "end": 3071.33, "word": " الجواب", "probability": 0.978515625}, {"start": 3071.33, "end": 3071.67, "word": " answer", "probability": 0.96630859375}, {"start": 3071.67, "end": 3072.07, "word": " تنتهي", "probability": 0.9813232421875}, {"start": 3072.07, "end": 3072.69, "word": " معلومة", "probability": 0.9852294921875}, {"start": 3072.69, "end": 3073.25, "word": " هنشوف", "probability": 0.84112548828125}, {"start": 3073.25, "end": 3073.43, "word": " هذا", "probability": 0.94189453125}, {"start": 3073.43, "end": 3073.75, "word": " الكلام", "probability": 0.9650065104166666}, {"start": 3073.75, "end": 3073.93, "word": " اذا", "probability": 0.79736328125}, {"start": 3073.93, "end": 3074.11, "word": " الله", "probability": 0.92138671875}, {"start": 3074.11, "end": 3074.41, "word": " راد", "probability": 0.6199951171875}, {"start": 3074.41, "end": 3075.09, "word": " الحصة", "probability": 0.9816080729166666}, {"start": 3075.09, "end": 3075.49, "word": " الجاية", "probability": 0.91943359375}, {"start": 3075.49, "end": 3076.01, "word": " في", "probability": 0.6162109375}, {"start": 3076.01, "end": 3076.23, "word": " اي", "probability": 0.920166015625}, {"start": 3076.23, "end": 3076.59, "word": " سؤال", "probability": 0.9913736979166666}, {"start": 3076.59, "end": 3076.73, "word": " يا", "probability": 0.982421875}, {"start": 3076.73, "end": 3077.17, "word": " شباب", "probability": 0.9923502604166666}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 3077.94425, "duration_after_vad": 2995.9624999999896}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/eMrPav-gqxE_raw.srt b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/eMrPav-gqxE_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..96535d465021d11dc371acd113c7e75601f051d2
--- /dev/null
+++ b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/eMrPav-gqxE_raw.srt
@@ -0,0 +1,2644 @@
+1
+00:00:21,580 --> 00:00:25,200
+بسم الله الرحمن الرحيم اليوم ان شاء الله بنستكمل
+
+2
+00:00:25,200 --> 00:00:29,550
+الموضوع اللي بدأنا فيه الحصة الماضيةكنا بدأنا
+
+3
+00:00:29,550 --> 00:00:32,830
+نتكلم عن ال standard deviation وشوفنا انه ال
+
+4
+00:00:32,830 --> 00:00:37,010
+standard deviation بيعبر عن ال spread لل results
+
+5
+00:00:37,010 --> 00:00:44,250
+حوالين ال mean ال spread لل results حوالين ال mean
+
+6
+00:00:44,250 --> 00:00:48,090
+فشوفنا نوعين من أنواع ال standard deviation شوفنا
+
+7
+00:00:48,090 --> 00:00:52,590
+حاجة سمنها population standard deviation وذكرنا
+
+8
+00:00:52,590 --> 00:00:58,950
+انه ال population standard deviation بنستخدمهمع
+
+9
+00:00:58,950 --> 00:01:05,110
+عدد كبير من ال data points أو النتائج لكن احنا في
+
+10
+00:01:05,110 --> 00:01:09,250
+الكيميا بالذات في الكيميا التحليلية عدد النتائج
+
+11
+00:01:09,250 --> 00:01:14,130
+اللي بنتعامل معاها عدد قليل نسبيا يعني من تلت لخمس
+
+12
+00:01:14,130 --> 00:01:20,430
+تجارب بنكررها عادة فقولنا انه بنستخدم حاجة سمناها
+
+13
+00:01:20,430 --> 00:01:25,190
+sample standard deviation او سمناها برضه estimated
+
+14
+00:01:30,800 --> 00:01:35,760
+القانون اللى كنا بنستخدمه في ال population
+
+15
+00:01:35,760 --> 00:01:38,800
+standard deviation لأنه في ال population standard
+
+16
+00:01:38,800 --> 00:01:42,410
+deviation كنا بنستخدم ال true meanأو الـ true
+
+17
+00:01:42,410 --> 00:01:46,710
+average، لكن بالطبع لما نتكلم عن عدد تجارب محدود
+
+18
+00:01:46,710 --> 00:01:50,890
+فاحنا بنتكلم عن experimental mean ولا شك أنه في
+
+19
+00:01:50,890 --> 00:01:54,830
+عندي اختلاف بين الاتنين، ايضا ال degrees of
+
+20
+00:01:54,830 --> 00:01:59,430
+freedom في ال sample standard deviationبيكون N-1
+
+21
+00:01:59,430 --> 00:02:04,410
+مش N زي ما شفناه في ال population standard
+
+22
+00:02:04,410 --> 00:02:07,170
+deviation على اي حال احنا مش هنتكلم عن ال
+
+23
+00:02:07,170 --> 00:02:10,230
+population standard deviation تاني خلاص لأنه مش
+
+24
+00:02:10,230 --> 00:02:14,150
+هنستخدمه فهيظل ان ال sample standard deviation
+
+25
+00:02:14,150 --> 00:02:18,250
+وانواع اخرى ايضا من ال standard deviation هنتكلم
+
+26
+00:02:18,250 --> 00:02:22,650
+عنها اذا الله راضي الحصة هذهلكن قبل ما نتكلم اكتر
+
+27
+00:02:22,650 --> 00:02:26,290
+عن ال standard deviation ال sample standard
+
+28
+00:02:26,290 --> 00:02:30,550
+deviation بنقول ان في بعض الحسابات اللى يمكن
+
+29
+00:02:30,550 --> 00:02:35,070
+اشتقاقها من ال standard deviation فبنتكلم عن ال
+
+30
+00:02:35,070 --> 00:02:39,730
+standard deviation للمين ال standard deviation
+
+31
+00:02:39,730 --> 00:02:42,970
+للمين او ال S للمين بتساوي ال standard deviation
+
+32
+00:02:42,970 --> 00:02:47,580
+على جزر ال Nالـ N اللي هي عدد التجارب يبقى لو
+
+33
+00:02:47,580 --> 00:02:51,220
+جسمنا ال standard deviation على جزر ال N هذا
+
+34
+00:02:51,220 --> 00:02:54,200
+بيعطينا ال S ل المين أو ال standard deviation ل
+
+35
+00:02:54,200 --> 00:02:57,720
+المينالـ standard deviation بيعطيني قيمة مطلقة
+
+36
+00:02:57,720 --> 00:03:02,340
+عادة قيمة مطلقة و احنا قلنا انه قيمة مطلقة او خطأ
+
+37
+00:03:02,340 --> 00:03:07,220
+مطلق الخطأ المطلق او ال absolute error بحد ذاته مش
+
+38
+00:03:07,220 --> 00:03:13,180
+كتير يعني بيعطيني معلومات ليه؟ لأنه قد يكون خطأ
+
+39
+00:03:13,180 --> 00:03:20,490
+مثلا واحد من عشرة إجرام في واحد إجرامالخطأ هذا
+
+40
+00:03:20,490 --> 00:03:23,770
+واحد من عشرة اجرام موجود في تعيين او في تقدير
+
+41
+00:03:23,770 --> 00:03:27,890
+الواحد اجرام او انه مثلا ممكن يكون برضه خطأ مقدار
+
+42
+00:03:27,890 --> 00:03:32,070
+واحد من عشرة اجرام لكن موجود في تقدير مائة الف
+
+43
+00:03:32,070 --> 00:03:38,530
+اجرام فهل الخطأ في تقديرأو في تقدير الخطأ في
+
+44
+00:03:38,530 --> 00:03:42,870
+الحاجة الأولى زي تقدير الخطأ في الحالة التانية
+
+45
+00:03:42,870 --> 00:03:46,150
+أكيد لأ لما يكون عندي خطأ واحد من عشرة gram في ال
+
+46
+00:03:46,150 --> 00:03:50,410
+gram معناته هذا خطأ كبير بينما واحد من عشرة gram
+
+47
+00:03:50,410 --> 00:03:55,150
+في المية ألف gram خطأ أشمله قليل لكن قيمة الخطأ
+
+48
+00:03:55,150 --> 00:04:00,290
+المطلق واحد من عشرة وواحد من عشرة نفس الشيء مش هيك
+
+49
+00:04:00,290 --> 00:04:04,390
+علشان هيك بنقول أنه قيمة الخطأ المطلق بحد ذاته مش
+
+50
+00:04:04,390 --> 00:04:09,660
+كتير مهم بالنسبة ليلازم يعرف هذا الخطأ المطلق في
+
+51
+00:04:09,660 --> 00:04:16,960
+أي كمية موجود علشان هيك في أسلوب أخر للتعبير عن ال
+
+52
+00:04:16,960 --> 00:04:20,540
+standard deviation بياخد هذا الكلام بعين الاعتبار
+
+53
+00:04:20,540 --> 00:04:24,800
+بنسميه relative standard deviation ال relative
+
+54
+00:04:24,800 --> 00:04:28,580
+standard deviation بياخده بعين الاعتبار الكمية أو
+
+55
+00:04:28,580 --> 00:04:31,930
+ال averageفال relative standard deviation أو
+
+56
+00:04:31,930 --> 00:04:35,990
+بنسميه RSD في بعض الأحيان يسمى أيضًا coefficient
+
+57
+00:04:35,990 --> 00:04:41,530
+of variation أو CV، إيش بيساوي؟ ال RSD بتساوي ال
+
+58
+00:04:41,530 --> 00:04:45,480
+standard deviation مقسومة على ال averageالـ
+
+59
+00:04:45,480 --> 00:04:49,100
+Standard Deviation مقسومة على الـ Average في 100
+
+60
+00:04:49,100 --> 00:04:53,340
+من 100 هذا اه لما نقول واحد من عشرة على واحد في
+
+61
+00:04:53,340 --> 00:04:57,360
+100 من 100 معناته 10% لما نقول واحد من عشرة على
+
+62
+00:04:57,360 --> 00:05:03,380
+ميت ألف في 100 من 100 معناته RSD قليل جدا RSD
+
+63
+00:05:03,380 --> 00:05:10,140
+اشمله اه ال RSD بتعبر بشكل افضل عن مدى ال
+
+64
+00:05:10,140 --> 00:05:13,720
+precision تبعتنا احسن من ال Standard Deviation
+
+65
+00:05:13,720 --> 00:05:18,870
+المطلقبنفس الطريقة اللى جيبنا اللى جيبنا فيها ال
+
+66
+00:05:18,870 --> 00:05:22,710
+RSD أو ال relative standard deviation ممكن نتكلم
+
+67
+00:05:22,710 --> 00:05:26,110
+عن ال relative standard deviation للمين في هذه
+
+68
+00:05:26,110 --> 00:05:30,180
+الحالةبساوي الـ S للمين على ال X bar اللي هي ال
+
+69
+00:05:30,180 --> 00:05:34,860
+average أيضا في 100 من 100 نرجع على المثال اللي
+
+70
+00:05:34,860 --> 00:05:40,520
+ذكرناه بالامس أو الحصة الماضية و بنحاول أنه نستكمل
+
+71
+00:05:40,520 --> 00:05:46,180
+حلو و نستكمل الحسابات اللي ذكرناها قبل قليل كيف
+
+72
+00:05:46,180 --> 00:05:49,660
+ممكن نشتقها من ال stand up deviation فقلنا في
+
+73
+00:05:49,660 --> 00:05:53,240
+الحصة الماضية أو في اللقاء الماضي أنه في عندنا
+
+74
+00:05:53,240 --> 00:06:01,450
+replicate weightsكانت بتساوية 29.8 30.2 28.6 29.7
+
+75
+00:06:01,450 --> 00:06:05,930
+ميلي جرام فعايز يحسب ال S و أيضا ال S للمين و ال
+
+76
+00:06:05,930 --> 00:06:13,630
+RSD و ال RSD للمين قولنا إنه في البداية بنحسب ال X
+
+77
+00:06:13,630 --> 00:06:16,130
+bar أو ال average وضعه طبيعي لإنه أنا مدهن بده
+
+78
+00:06:16,130 --> 00:06:19,450
+أحسب ال sudden deviation أول خطوة أو الشيء الأساسي
+
+79
+00:06:19,450 --> 00:06:23,400
+عندنا نحسب ال X barفبطلع بقول X bar بتساوي مجموع
+
+80
+00:06:23,400 --> 00:06:27,440
+القيام أو مجموع النتائج على عددها بالطبع النتيجة
+
+81
+00:06:27,440 --> 00:06:30,600
+النهائية اذا كما نتكلم significant figures كل
+
+82
+00:06:30,600 --> 00:06:34,500
+النتائج تحتوي على one digit على يمين ال decimal
+
+83
+00:06:34,500 --> 00:06:38,180
+point اذا الجواب بده يحتوي على one digit على يمين
+
+84
+00:06:38,180 --> 00:06:41,200
+ال decimal point طيب و الأربعة اللي جسمنا عليها
+
+85
+00:06:41,200 --> 00:06:45,080
+بنقول لأ هذي exact number مائلها دخل في تحديد عدد
+
+86
+00:06:45,080 --> 00:06:50,400
+ال significant figures فال average بيطلع 29.6الان
+
+87
+00:06:50,400 --> 00:06:54,420
+..الان بنقدر نعمل جدول زي هيك و بس الجدول اللي
+
+88
+00:06:54,420 --> 00:06:59,020
+هنقوله يعني المرة هذه لإنه تضيع وسع الفاضي الجدول
+
+89
+00:06:59,020 --> 00:07:03,440
+مش هنستخدمه بس بيضيع وسع الفاضي في الحل فهناخد
+
+90
+00:07:03,440 --> 00:07:09,020
+الحل بسطر واحد لكن هالجهة بس عشان توضح معانا 29.8
+
+91
+00:07:09,020 --> 00:07:16,210
+-29.6 اللي هي ال average بتسوي 0.2 xi-x barx i
+
+92
+00:07:16,210 --> 00:07:19,310
+minus x bar تربيع point two تربيع تطلع point four
+
+93
+00:07:20,690 --> 00:07:28,170
+30.2 minus 29.6 تطلع 0.6 0.6 times 0.6 أو 0.6
+
+94
+00:07:28,170 --> 00:07:34,890
+squared 0.36 28.6 minus 29.6 المفروض minus one ما
+
+95
+00:07:34,890 --> 00:07:37,890
+بنكتبش الإشارة في ال sample ال deviation لأنه بعد
+
+96
+00:07:37,890 --> 00:07:42,770
+شوية هنربعها يبقى الإشارة يعني إبها وابجلتها مش
+
+97
+00:07:42,770 --> 00:07:47,370
+همالها قيمة يعني وهكذا بتطلع ال average أو
+
+98
+00:07:47,370 --> 00:07:51,940
+المجموعة one point four oneالان بتطبيق القانون one
+
+99
+00:07:51,940 --> 00:07:56,520
+point four one على أربعة ناقص واحد اللي هو تلاتة
+
+100
+00:07:56,520 --> 00:08:01,740
+تحت الجزر بطلع ال S عندنا point six nine ال S
+
+101
+00:08:01,740 --> 00:08:05,480
+للمين قال والله ال S على جزر ال N يعني point six
+
+102
+00:08:05,480 --> 00:08:09,720
+nine على جزر الأربعة اللي هو اتنين بتساوي point
+
+103
+00:08:09,720 --> 00:08:17,090
+three four five بتساوي point three four a fiveلكن
+
+104
+00:08:17,090 --> 00:08:23,070
+الخامسة لا تقرب لأنه اللي جابلها إيه اش ماله؟ عدد
+
+105
+00:08:23,070 --> 00:08:27,090
+زوجي فبتمها point three four لإن احنا عايزين نحسب
+
+106
+00:08:27,090 --> 00:08:31,170
+ال S للمين طيب ال RSD قال والله ال S على ال X bar
+
+107
+00:08:31,170 --> 00:08:34,350
+ال S اللي هي point six nine على twenty nine point
+
+108
+00:08:34,350 --> 00:08:37,410
+six في مية من مية بيطلع اتنين او تلاتة من عشرة في
+
+109
+00:08:37,410 --> 00:08:42,470
+المية ال RSD للمين؟هي ال S للمين اللي المفروض 0.34
+
+110
+00:08:42,470 --> 00:08:46,330
+لكن ايش انا حاطط كمان؟ five لان في عندي عملية
+
+111
+00:08:46,330 --> 00:08:51,010
+حسابية اخرى اي عمل بدي اعملها فبديش اتخلص منها لان
+
+112
+00:08:51,010 --> 00:08:54,850
+الجواب عايز بس S للمين يقولي اه 0.34 لكن هاي بده
+
+113
+00:08:54,850 --> 00:09:00,810
+ال RSD للمين فبكتبها زي ما هي 0.345 لكن الخمسة هذه
+
+114
+00:09:00,810 --> 00:09:04,330
+ماهياش significantبس احنا خلّينها عشان الخطأ
+
+115
+00:09:04,330 --> 00:09:07,970
+مايزيدش على ال X بقى في 100 من 100 تطلع عند واحد و
+
+116
+00:09:07,970 --> 00:09:15,770
+واحد من عشرة في الميلاد حاضر التلاتة اربعة
+
+117
+00:09:15,770 --> 00:09:20,310
+ناقص واحد عدد التجارب ناقص واحد تطبيق للقانون هاي
+
+118
+00:09:20,310 --> 00:09:25,310
+القانون القانون بيقول N ناقص واحد هاي ال N اربعة
+
+119
+00:09:25,310 --> 00:09:27,090
+ناقص واحد بيضل تلاتة
+
+120
+00:09:32,610 --> 00:09:36,280
+و هذا نفس اللي خلعناه من جابتناهو هو ال S بالظبط
+
+121
+00:09:36,280 --> 00:09:41,900
+المكتوب بالأحمر بينه هذا هو نفسه هو نفسه هذا هو
+
+122
+00:09:41,900 --> 00:09:50,200
+هذا لأ انت طلعت هي حسبناها هي احنا حسبنا ال S ال S
+
+123
+00:09:50,200 --> 00:09:54,260
+للمين هي عضارة عن ال S على جزر ال N جزر ال N عننا
+
+124
+00:09:54,260 --> 00:09:58,540
+أربعة ال N عننا باربعة اذا جزر الأربعة و ال S عننا
+
+125
+00:09:58,540 --> 00:10:01,120
+point six nine point six nine على جزر الأربعة
+
+126
+00:10:02,600 --> 00:10:07,000
+الخامسة لو إجهت حسبة point six nine هذا هي ال S
+
+127
+00:10:07,000 --> 00:10:10,700
+للمين point six nine على اربع يعني على اتنين بتطلع
+
+128
+00:10:10,700 --> 00:10:16,160
+point three four five لكن ماكتبناش الخمسة لأنه
+
+129
+00:10:16,160 --> 00:10:19,360
+جابلها عدد زوجي هان كتبناها لأنه في عندي عملية
+
+130
+00:10:19,360 --> 00:10:25,800
+حسابية أخرى مابديش أقرر بمرتين طيب طيب بنتكلم الآن
+
+131
+00:10:25,800 --> 00:10:31,310
+على حاجة بنقولها pooled standard deviationوهيجي
+
+132
+00:10:31,310 --> 00:10:34,550
+لنوع اخر ايضا من ال standard deviation يبقى
+
+133
+00:10:34,550 --> 00:10:37,230
+اتكلمنا عن ال population و قولنا مش هنستخدمه
+
+134
+00:10:37,230 --> 00:10:41,550
+اتكلمنا عن ال sample و ال sample كان بتعلق ب one
+
+135
+00:10:41,550 --> 00:10:45,790
+set of data عندي عينة ما بحللها عدة مرات نفس
+
+136
+00:10:45,790 --> 00:10:51,070
+العينة بحللها عدة مرات فبحث ممكن زي ايه مثلا زي
+
+137
+00:10:51,070 --> 00:10:55,510
+مثلا ما والله بدي اعمل معايرة خمس مرات اعملت
+
+138
+00:10:55,510 --> 00:10:59,900
+معايرة خمس مراتالخمس مرات اقول ايش بطلع لهم
+
+139
+00:10:59,900 --> 00:11:03,760
+average صح والخمس مرات اقول بقدر احسب ال standard
+
+140
+00:11:03,760 --> 00:11:06,940
+deviation لهم صح ولا لأ هذا sample standard
+
+141
+00:11:06,940 --> 00:11:09,540
+deviation اكثر نوع من انواع ال standard deviation
+
+142
+00:11:09,540 --> 00:11:13,280
+اللي انا باستخدمه sample standard deviation لنفس
+
+143
+00:11:13,280 --> 00:11:16,440
+العينة اذا كنتوا ملاحظين هي عينة بكرر replicate
+
+144
+00:11:16,440 --> 00:11:22,930
+samples ال pooled standard deviationبنستخدمه إذا
+
+145
+00:11:22,930 --> 00:11:27,230
+كان عندى two sets of data يعني ايه؟ يعني مثلا انا
+
+146
+00:11:27,230 --> 00:11:33,190
+في عندى عينة واحدة أيضا replicate samples بحللها
+
+147
+00:11:33,190 --> 00:11:38,910
+بطريقة ما و نفس العينة هذه بحللها بطريقة أخرى عدة
+
+148
+00:11:38,910 --> 00:11:42,030
+مرات بالطريقة الأولى و عدة مرات بالطريقة التانية
+
+149
+00:11:42,030 --> 00:11:45,950
+مثلا عشر مرات بالطريقة الأولى و سبعة مرات بالطريقة
+
+150
+00:11:45,950 --> 00:11:48,970
+التانية مثلا في عندى
+
+151
+00:11:52,070 --> 00:11:57,740
+هذه المساحة عايز احسب وزنهابستخدم ميزان قياسي
+
+152
+00:11:57,740 --> 00:12:02,700
+وبستخدم ميزان مثلا تجريبي يعني جديد انا ماخترعه او
+
+153
+00:12:02,700 --> 00:12:06,480
+الناس اخترعته يعني تشوفي كويس ولا مش كويس فهذه
+
+154
+00:12:06,480 --> 00:12:10,760
+المساحة وزنتها عشر مرات على الميزان القياسي وكل
+
+155
+00:12:10,760 --> 00:12:14,280
+مرة أسجلت جديش أعطتني وزن أوي نفسها حطيتها على
+
+156
+00:12:14,280 --> 00:12:19,760
+التجريب مثلا وزنتها سبع مرات متتالية ممكن أوزنها
+
+157
+00:12:19,760 --> 00:12:24,550
+نفس العشر مرات خمسة عشر مرات تلت مرات انا حرمش
+
+158
+00:12:24,550 --> 00:12:28,950
+مشكلة، فصار في عندى نتائج حصلت عليها بطريقة ما،
+
+159
+00:12:28,950 --> 00:12:33,390
+بطريقة قياسية مثلا و نتائج أخرى حصلت عليها بالإيه؟
+
+160
+00:12:33,390 --> 00:12:39,610
+بالطريقة الجديدة، مش هيك؟ الآن هال two sets of
+
+161
+00:12:39,610 --> 00:12:42,010
+data اللي صاروا موجودين عندى، هل بستطيع أن
+
+162
+00:12:42,010 --> 00:12:46,360
+أوجدلهم؟الـStandard Deviation الـStandard
+
+163
+00:12:46,360 --> 00:12:50,860
+Deviation للـTwo sets of data مع بعض اسمه Pulled
+
+164
+00:12:50,860 --> 00:12:53,320
+Standard Deviation يعني الـStandard Deviation
+
+165
+00:12:53,320 --> 00:12:58,160
+للخلطة لكل النتائج بعضها مع بعض لكل النتائج اسمه
+
+166
+00:12:58,160 --> 00:13:03,580
+Pulled Standard Deviation ايش القانون اللي بيحكمه
+
+167
+00:13:03,580 --> 00:13:06,940
+القانون اللي بيحكمه والله نفس القانون اللي انا
+
+168
+00:13:06,940 --> 00:13:10,320
+بستخدمه للـSample Standard Deviation تقريبا هي انا
+
+169
+00:13:10,320 --> 00:13:15,790
+كنت بقول الـS بتساوي الجزر التربي يعنيSummation x
+
+170
+00:13:15,790 --> 00:13:22,670
+i minus x bar تربيع على الناقص واحد هذا لما كان
+
+171
+00:13:22,670 --> 00:13:27,350
+عندي one set of data طب لو عندي two sets of data
+
+172
+00:13:27,350 --> 00:13:32,660
+هتصير ايه؟ هتصير summationx i للست الأول ناقص x
+
+173
+00:13:32,660 --> 00:13:37,640
+bar للست الأول تربيع طب الست التاني زائد summation
+
+174
+00:13:37,640 --> 00:13:42,440
+x i للست التاني minus x bar للست التاني تربيع على
+
+175
+00:13:42,440 --> 00:13:49,540
+n واحد ناقص واحد طبعة الست الأول زائد n اتنين ناقص
+
+176
+00:13:49,540 --> 00:13:52,840
+واحد طبعة الست التاني بيصير n واحد زائد n اتنين
+
+177
+00:13:52,840 --> 00:13:57,600
+ناقص اتنين فلما تطلع على قانون ماتحسش ان هذا اش
+
+178
+00:13:57,600 --> 00:14:01,700
+جديد هذا هو نفس هذالكن هذا اللي بيكون عندك بس one
+
+179
+00:14:01,700 --> 00:14:05,180
+set of data عندك two sets بيكون xi واحد x bar واحد
+
+180
+00:14:05,180 --> 00:14:09,700
+xi اتنين x bar اتنين n واحد زاد n اتنين ناقص اتنين
+
+181
+00:14:09,700 --> 00:14:13,280
+ال n واحد زاد n اتنين ناقص اتنين تسمى طبعا ال
+
+182
+00:14:13,280 --> 00:14:18,560
+degrees of freedomفال S P هذا هو ال pooled
+
+183
+00:14:18,560 --> 00:14:22,860
+standard deviation ال X bar واحد متوسط النتائج
+
+184
+00:14:22,860 --> 00:14:26,680
+اللى حصلت عليها بالطريقة الأولى او يعني ال
+
+185
+00:14:26,680 --> 00:14:30,940
+procedure الأول ال X bar اتنين متوسط النتائج اللى
+
+186
+00:14:30,940 --> 00:14:35,000
+حصلت عليها في ال 6 التانى او الطريقة التانية او ال
+
+187
+00:14:35,000 --> 00:14:38,100
+procedure التانى و ال N واحد و ال N اتنين عدد
+
+188
+00:14:38,100 --> 00:14:42,000
+تجارب في ال 6 الأول و ال 6 التانى نيجي نطلع على
+
+189
+00:14:42,000 --> 00:14:47,580
+مثالمثال بيوضح حاجة كلها بشكل كتير ممتاز بنقول إيش
+
+190
+00:14:47,580 --> 00:14:52,060
+المثال؟ بنقول mercury in a sample في عند زئبق في
+
+191
+00:14:52,060 --> 00:14:58,220
+عين ما was determined using a standard method and
+
+192
+00:14:58,220 --> 00:15:01,600
+a new suggested method تم تعيين ال mercury
+
+193
+00:15:01,600 --> 00:15:06,340
+باستخدام طريقتين طريقة standard قياسية و طريقة
+
+194
+00:15:06,340 --> 00:15:12,160
+جديدةبقول ايش؟ five replicate experiments
+
+195
+00:15:12,160 --> 00:15:16,720
+replicate يعني هي نفسها بس بنكررها يعني عندي عينة
+
+196
+00:15:16,720 --> 00:15:22,280
+كبيرة أخدت منها أول مرة، تاني مرة، تالت مرة، رابع
+
+197
+00:15:22,280 --> 00:15:24,980
+مرة، خامس مرة، five replicates ثانث مرة، نفس
+
+198
+00:15:24,980 --> 00:15:28,680
+النتيجة أو نتيجة متقاربة لكن هي نفس العينة نفس
+
+199
+00:15:28,680 --> 00:15:32,200
+العينة five replicate experiments were conducted
+
+200
+00:15:32,200 --> 00:15:35,680
+using يعني عملناهم أجريناهم using the two
+
+201
+00:15:35,680 --> 00:15:39,550
+proceduresGiving the following results in PPM
+
+202
+00:15:39,550 --> 00:15:43,050
+اعتقد النتائج التالية بالمناسبة قبل ما اقول نتائج
+
+203
+00:15:43,050 --> 00:15:48,270
+ممكن والله نعمل التجربة او التحليل مش خمسة و خمسة
+
+204
+00:15:48,270 --> 00:15:53,330
+ممكن نعمله عشر و خمسة سبعة و تمانية اربعة و ستة مش
+
+205
+00:15:53,330 --> 00:15:57,010
+فارق يعني مش لازم عدد التحليل بالطريقة الأولى
+
+206
+00:15:57,010 --> 00:16:01,790
+يساوي عدد مرات التحليل بالطريقة الثانية لاالمهم
+
+207
+00:16:01,790 --> 00:16:09,210
+انه عندى two sets of data في عندى one sample انا
+
+208
+00:16:09,210 --> 00:16:13,810
+باخد منها عينات و بحلل هذه العينات اكتر من مرة
+
+209
+00:16:13,810 --> 00:16:18,210
+بالطريقة القياسية و اكتر من مرة بالطريقة الجديدة
+
+210
+00:16:18,210 --> 00:16:22,610
+فحصلت على النتائج التالية ال new method هي نتائجها
+
+211
+00:16:22,610 --> 00:16:27,550
+و ال standard method هي نتائجها ايش طالب يحسب؟
+
+212
+00:16:27,550 --> 00:16:30,530
+طالب يحسب ال pooled standard deviation
+
+213
+00:16:33,500 --> 00:16:36,560
+بقول والله عشان أحسب ال pooled 7 deviation أنا
+
+214
+00:16:36,560 --> 00:16:40,700
+بعرف ال S P بتساوي الجزر التربيعي summation X I 1
+
+215
+00:16:40,700 --> 00:16:45,940
+minus X bar 1 squared زائد summation X I 2 minus X
+
+216
+00:16:45,940 --> 00:16:52,250
+bar 2 squared على N 1 زائد N 2 ناقص 2مش هيك؟ إذا
+
+217
+00:16:52,250 --> 00:16:58,270
+أول خطوة في أي procedure لحساب ال standard
+
+218
+00:16:58,270 --> 00:17:02,170
+deviation مهما كان بدي أحسب ال average ففي عندي
+
+219
+00:17:02,170 --> 00:17:05,310
+two sets of data بدي أحسب ال average للأول وال
+
+220
+00:17:05,310 --> 00:17:10,550
+average لك تاني فبنقول والله بنجمع الأولعلى خمسة
+
+221
+00:17:10,550 --> 00:17:14,550
+ونجمع التاني التصادف انه اتنين اللهم نفس العدد
+
+222
+00:17:14,550 --> 00:17:18,950
+التجارب على خمسة نطلع ال X bar واحد عشرة ونص وال X
+
+223
+00:17:18,950 --> 00:17:25,150
+bar اتنين عشرة وتلاتة الان سطر واحد بس بجيب ال
+
+224
+00:17:25,150 --> 00:17:29,820
+summation X I واحد minus X bar واحد يعنيلحظة معايا
+
+225
+00:17:29,820 --> 00:17:34,080
+ال X bar واحد عشرة و نص باشي بقول عشرة و نص ناقص
+
+226
+00:17:34,080 --> 00:17:37,740
+عشرة و نص تربية زائد تسعة و تسعة ناقص عشرة و نص
+
+227
+00:17:37,740 --> 00:17:42,040
+تربية زائد عشرة و أربعة ناقص عشرة و نص تربية زائد
+
+228
+00:17:42,040 --> 00:17:45,160
+أحداشر و اتنين ناقص عشرة و نص تربية زائد عشرة و نص
+
+229
+00:17:45,160 --> 00:17:49,760
+ناقص عشرة و نص تربية بيطلع عنا النتيجة الأولى
+
+230
+00:17:49,760 --> 00:17:56,960
+point 86 يعني اذا ماعطاني point 86باجلاء العمود
+
+231
+00:17:56,960 --> 00:18:01,460
+التاني أو الست التاني من ال data من النتائج x I2
+
+232
+00:18:01,460 --> 00:18:06,620
+ناقص x bar 2 تربيع ال summation لهذا التربيع فبقول
+
+233
+00:18:06,620 --> 00:18:09,660
+النتيجة الأولى ناقص المتوسط
+
+234
+00:18:11,560 --> 00:18:14,660
+عشرة و واحد ناقص عشرة و تلاتة تربية عشرة و تلاتة
+
+235
+00:18:14,660 --> 00:18:17,920
+ناقص عشرة و تلاتة تربية عشرة و اتنين ناقص عشرة و
+
+236
+00:18:17,920 --> 00:18:20,960
+تلاتة تربية عشرة و تلاتة ناقص عشرة و تلاتة تربية
+
+237
+00:18:20,960 --> 00:18:24,920
+عشرة و اربعة ناقص عشرة و اربعة تربية ناقص عشرة و
+
+238
+00:18:24,920 --> 00:18:29,420
+تلاتة تربية النتيجة تطلع point o six الان انا جاهز
+
+239
+00:18:29,420 --> 00:18:34,740
+بده اطبق القانون point o eight six point o six ان
+
+240
+00:18:34,740 --> 00:18:39,240
+واحد خمسة ان اتنين خمسة minus اتنين اللي بيطلع عند
+
+241
+00:18:39,240 --> 00:18:46,080
+ال SP point three fourطيب إيش معناه ال SP لا إيش
+
+242
+00:18:46,080 --> 00:18:51,940
+بستخدمه؟ اه احنا اليوم بس بنعرف كيف نحسبهفي
+
+243
+00:18:51,940 --> 00:18:55,420
+المحاضرات الجاية هنعرف في إيش نستخدمه، يعني
+
+244
+00:18:55,420 --> 00:18:59,420
+التطبيقات تبعته مش هتجيلنا اليوم، اليوم تتداجش من
+
+245
+00:18:59,420 --> 00:19:02,800
+إن احنا مش هنقولك التطبيقات، لإنها جاية بشرح وافع
+
+246
+00:19:02,800 --> 00:19:06,780
+و بالتفصيل، لكن بعد .. آخر المحاضرة الجاية هنبدأ
+
+247
+00:19:06,780 --> 00:19:10,760
+أو المحاضرة بعد اللي جاية، فبالتالي احنا بس بنقولك
+
+248
+00:19:10,760 --> 00:19:16,550
+الآن كيف إيه نحسبه، لكن إيش تطبيقاته؟هذه هتجيه لنا
+
+249
+00:19:16,550 --> 00:19:21,150
+بعد شوية يبقى النوع التاني اللي هنستخدمه من أنواع
+
+250
+00:19:21,150 --> 00:19:24,590
+ال standard deviation منقوله pooled standard
+
+251
+00:19:24,590 --> 00:19:30,410
+deviation وهذا كمان مرة يستخدم عند ما يكون في عنده
+
+252
+00:19:30,410 --> 00:19:35,420
+replicate samples معمولةالـ two different
+
+253
+00:19:35,420 --> 00:19:40,120
+procedures، two different methods، ماشي؟ مش شرط
+
+254
+00:19:40,120 --> 00:19:44,940
+أنه عدد التجارب المعمولة باستخدام طريقة ما تساوي
+
+255
+00:19:44,940 --> 00:19:47,580
+عدد التجارب اللي عملت سويا بطريقة أخرى، لأ مش شرط،
+
+256
+00:19:47,580 --> 00:19:51,400
+ممكن بالطريقة القياسية نعمله ستة، بالطريقة الجديدة
+
+257
+00:19:51,400 --> 00:19:55,140
+نعمله عشرة أو تمانية، ليه؟ لأنه الحسابات بتفرضش
+
+258
+00:19:55,140 --> 00:20:01,860
+عليها مثل هذا القيدالان حسب ما .. حسب ما تعملها مش
+
+259
+00:20:01,860 --> 00:20:05,760
+مشكلة يعني N واحد ليس شرطا أن تسوي N اتنين لكن
+
+260
+00:20:05,760 --> 00:20:11,480
+ممكن تسويها زي ما شوفنا ال S فيه تطبيق مباشر بنعوض
+
+261
+00:20:11,480 --> 00:20:15,540
+تعويض يعني ايش اخر سطرية ايش اللي عوضتها ايه ال X
+
+262
+00:20:15,540 --> 00:20:21,280
+X I واحد minus X bar واحد تربيع point eight six
+
+263
+00:20:21,280 --> 00:20:26,160
+حطناها محلها و X I اتنين minus X bar اتنين point
+
+264
+00:20:26,160 --> 00:20:30,540
+oh six حطناها محلهاو ال n واحد و ال اتنين خمسة و
+
+265
+00:20:30,540 --> 00:20:34,060
+خمسة سالب اتنين هي هي يعني حطينا النتائج تبعاتنا
+
+266
+00:20:34,060 --> 00:20:40,060
+حطيناها في القانون طيب يا شباب الان بنتكلم عن اخر
+
+267
+00:20:40,060 --> 00:20:43,100
+نوع من انواع ال standard deviations اللي احنا
+
+268
+00:20:43,100 --> 00:20:47,700
+هنواجهها في هذا ال course في هذا الفصل فبنقول في
+
+269
+00:20:47,700 --> 00:20:51,860
+عندي حاجة بقولها standard deviation of the
+
+270
+00:20:51,860 --> 00:20:58,040
+difference الحرف اللي معناه هي للفرق للفرقاتفي
+
+271
+00:20:58,040 --> 00:21:02,060
+الحقيقة هذا النوع من أنواع ال standard deviation
+
+272
+00:21:03,140 --> 00:21:10,320
+بيطبق فقط إذا كان عندى multiple samples عند عينات
+
+273
+00:21:10,320 --> 00:21:14,220
+مختلفة متعددة مش نفس العينة باخد شوية منها و
+
+274
+00:21:14,220 --> 00:21:18,260
+بحللها عدة مرات بطرق القياسية و عدة مرات لأ عند
+
+275
+00:21:18,260 --> 00:21:22,180
+عينات مختلفة زى ايش زى مثلا لو أقولكم هذا قلم بدي
+
+276
+00:21:22,180 --> 00:21:26,680
+أشوف كده وزنه بيجب أحطه على ميزان قياسي و على
+
+277
+00:21:26,680 --> 00:21:36,700
+ميزان جديد تجريبي مثلا هذه أول عينةهذه مساحة او
+
+278
+00:21:36,700 --> 00:21:41,260
+خلّيني بقى ناخد اقلام ناخد قلم من زميلكم كويس اي
+
+279
+00:21:41,260 --> 00:21:45,940
+قلم هذا القلم اكيد مختلف عنه مش شرط يكون نسخة طبق
+
+280
+00:21:45,940 --> 00:21:51,160
+الأصل عنه مش مهم هذا قلم حطيته على الميزان القياسي
+
+281
+00:21:51,160 --> 00:21:55,220
+وبعدين حطيته على الميزان التجريبي يبقى كل عينة
+
+282
+00:21:55,220 --> 00:21:59,240
+بحللها باستخدام الطريقة القياسية والطريقة ال
+
+283
+00:21:59,520 --> 00:22:03,880
+التجربية لكن بس قياس واحد مش أكتر لإنه بقدرش أعمل
+
+284
+00:22:03,880 --> 00:22:07,460
+أكتر في أحيان كتيرة بقدرش أعمل أكتر من قياس فعملت
+
+285
+00:22:07,460 --> 00:22:10,260
+هذه العينات مختلفة أخدت جلم من سبيلكم التالت
+
+286
+00:22:10,260 --> 00:22:14,280
+والرابع والخامس والسادس وهكذا هل هذه الأقلام كلها
+
+287
+00:22:14,280 --> 00:22:18,360
+متكافئة كل واحد شكل هتعطينا أوزان مختلفة مش مشكلة
+
+288
+00:22:18,360 --> 00:22:24,780
+المهم انه multiple samples عيناتي
+
+289
+00:22:24,780 --> 00:22:30,410
+أشمالهامختلفة متنوعة هذه النقطة علشان هيك بنقدر
+
+290
+00:22:30,410 --> 00:22:35,030
+نقول أنه دائما عدد البيانات اللي بحصل عليها
+
+291
+00:22:35,030 --> 00:22:38,810
+باستخدام الطريقة الجديدة يجب أن يساوي عرض البيانات
+
+292
+00:22:38,810 --> 00:22:43,690
+اللي بحصل عليها بالطريقة القياسية ليه؟ لأن كل عينة
+
+293
+00:22:43,690 --> 00:22:47,130
+بحللها بالطريقة الجديدة هي نفسها بحللها بالإيه
+
+294
+00:22:47,130 --> 00:22:50,990
+يبقى لازم لازم يكون متساوي يعني ماينفعش عمود يكون
+
+295
+00:22:50,990 --> 00:22:56,450
+أكبر من عمودطيب، لو جينا القانون، القانون بيقول
+
+296
+00:22:56,450 --> 00:23:00,830
+والله SD أو ال standard deviation لل difference
+
+297
+00:23:00,830 --> 00:23:06,030
+بدي سوى ال summation di minus d bar squared على n
+
+298
+00:23:06,030 --> 00:23:09,950
+ناقص واحد، الكل تحت الجزيرطيب ايش بيفرج عن
+
+299
+00:23:09,950 --> 00:23:14,230
+summation xi minus x bar squared على ال n ايش
+
+300
+00:23:14,230 --> 00:23:19,630
+بيفرج بدّل ال x حطينا d اذا بدي اقولكم ان كل انواع
+
+301
+00:23:19,630 --> 00:23:21,430
+ال assignment deviation اللي احنا حكينا عنها هي
+
+302
+00:23:21,430 --> 00:23:24,590
+هذا القانون هي ال sample assignment deviation لكن
+
+303
+00:23:24,590 --> 00:23:29,620
+يعني تحويرات بسيطة كلها مشتقة منه مش بحاجة لحفظمش
+
+304
+00:23:29,620 --> 00:23:31,900
+بحاجة لإنا نحفظها، إذا كان إحنا عارفين هذا
+
+305
+00:23:31,900 --> 00:23:35,600
+القانون، انتهى، لا بدي أحفظ pooled standard
+
+306
+00:23:35,600 --> 00:23:38,920
+deviation ولا حتى difference standard deviation
+
+307
+00:23:38,920 --> 00:23:47,980
+طيب، بنقول إيش ال DI؟ ال DI هي عبارة عنالفروقات
+
+308
+00:23:47,980 --> 00:23:52,780
+انا حللت او وزنت هذا القلم بالميزان القياسي و
+
+309
+00:23:52,780 --> 00:23:56,360
+بالميزان التجريبي النتيجة التجريبية ناقص القياسية
+
+310
+00:23:56,360 --> 00:24:01,440
+هي D1 DI جالب زميلكم حللت بالقياسي و بالتجريبي
+
+311
+00:24:01,440 --> 00:24:06,340
+التجريبي لزميلكم ناقص القياسي D2 يبقى ايش ال D
+
+312
+00:24:06,340 --> 00:24:13,280
+الفرق بين القياسي و النتيجة التجريبية دائما نتيجتك
+
+313
+00:24:13,280 --> 00:24:19,650
+minus القياسيطيب ال D bar بجيب ال D واحد و ال D
+
+314
+00:24:19,650 --> 00:24:23,810
+اتنين و ال D تلاتة و ال D اربعة الى اخرها و بجمعهم
+
+315
+00:24:23,810 --> 00:24:27,450
+و بجسمهم على عددهم هذه عبارة عن ال average
+
+316
+00:24:27,450 --> 00:24:34,250
+difference انشوف مثال مثال مهم انك تبقى معاه علشان
+
+317
+00:24:34,250 --> 00:24:39,930
+نقدر يعني نوصل للنتيجة مع بعض بقول برضه Mercury
+
+318
+00:24:39,930 --> 00:24:46,330
+لكن ان ايش؟multiple samples يعني عينات مش
+
+319
+00:24:46,330 --> 00:24:49,170
+replicate، replicate يعني نفس العينة، replicate
+
+320
+00:24:49,170 --> 00:24:53,270
+يعني pooled standard deviation، بيعني هذه مش
+
+321
+00:24:53,270 --> 00:24:57,570
+replicate، هذه multiple طيب was determined using a
+
+322
+00:24:57,570 --> 00:25:01,740
+standard method and a new suggested method؟تم
+
+323
+00:25:01,740 --> 00:25:07,860
+تحليله باستخدام طريقة قياسية وطريقة أخرى يعني
+
+324
+00:25:07,860 --> 00:25:12,100
+جديدة بيقول six different samples were analyzed
+
+325
+00:25:13,160 --> 00:25:19,820
+حللنا ست عينات مختلفة مثلا ميركوري موجود على ورق
+
+326
+00:25:19,820 --> 00:25:24,060
+الشجر أو في ورق الشجر ميركوري في دم إنسان ميركوري
+
+327
+00:25:24,060 --> 00:25:31,040
+في في أي حاجة مش مشكلة أو أنه ناخد مثلا أوراق شجر
+
+328
+00:25:31,040 --> 00:25:37,750
+في عدة أماكن أوراق شجر مثلا جنب الطريق العامأوراق
+
+329
+00:25:37,750 --> 00:25:40,250
+شجرة بعيدة كيلو، أوراق شجرة بعيدة اتنين كيلو على
+
+330
+00:25:40,250 --> 00:25:43,310
+الطريق العام، أوراق شجرة بعيدة تلاتة كيلو، وها
+
+331
+00:25:43,310 --> 00:25:49,550
+كذا، نخدنا عدة عينات أو إنه أخدنا بنا أدمين أول
+
+332
+00:25:49,550 --> 00:25:52,370
+واحد شوف نجداش ال mercury موجود في الدم عنده،
+
+333
+00:25:52,370 --> 00:25:55,230
+التاني جداش ال mercury موجود في الدم عنده، التالت،
+
+334
+00:25:55,230 --> 00:26:00,660
+الرابع، الخامس، السادس مثلا، برضه ممكنكانوا
+
+335
+00:26:00,660 --> 00:26:02,660
+يتعاملون باستخدام الانتجارات التي كانت تدعم
+
+336
+00:26:02,660 --> 00:26:03,520
+الانتجارات التي كانت تدعم الانتجارات التي كانت
+
+337
+00:26:03,520 --> 00:26:04,700
+تدعم الانتجارات التي كانت تدعم الانتجارات التي
+
+338
+00:26:04,700 --> 00:26:09,740
+كانت تدعم الانتجارات
+
+339
+00:26:09,740 --> 00:26:11,300
+التي كانت تدعم الانتجارات التي كانت تدعم
+
+340
+00:26:11,300 --> 00:26:14,720
+الانتجارات التي كانت تدعم الانتجارات التي كانت
+
+341
+00:26:14,720 --> 00:26:16,080
+تدعم الانتجارات التي كانت تدعم الانتجارات التي
+
+342
+00:26:16,080 --> 00:26:17,300
+كانت تدعم الانتجارات التي كانت تدعم الانتجارات
+
+343
+00:26:17,300 --> 00:26:17,400
+التي كانت تدعم الانتجارات التي كانت تدعم
+
+344
+00:26:17,400 --> 00:26:22,400
+الانتجارات التي كانت تدعم الانتجارات التي كانت
+
+345
+00:26:22,400 --> 00:26:27,820
+تدعم الانتجارات التي كانت تدعم الانتجارات
+
+346
+00:26:28,170 --> 00:26:30,650
+العينة التالتة تمانية و ستة تمانية و سبعة العينة
+
+347
+00:26:30,650 --> 00:26:35,670
+الرابعة سبعتاشر و نص ضعف العينة ال .. مالاش ده ..
+
+348
+00:26:35,670 --> 00:26:40,230
+يعني unrelated إلها، مافيش أي relation ما بينهم،
+
+349
+00:26:40,230 --> 00:26:45,900
+مش مشكلةالمهم عندي مجموعة من النتائج باستخدام
+
+350
+00:26:45,900 --> 00:26:47,800
+الطريقة القياسية ومجموعة من النتائج باستخدام
+
+351
+00:26:47,800 --> 00:26:51,880
+الطريقة الجديدة الشرط ان يكون عدد النتائج باستخدام
+
+352
+00:26:51,880 --> 00:26:54,640
+الطريقة القياسية بيساوي عدد النتائج باستخدام
+
+353
+00:26:54,640 --> 00:26:57,380
+الطريقة الجديدة لأنه انا بحلل كل تجربة حللة
+
+354
+00:26:57,380 --> 00:27:01,520
+باستخدام الطريقة هذه وهذه ولازم هدول عبارة عن عينة
+
+355
+00:27:01,520 --> 00:27:06,320
+واحدة كل رقمين اجبال بعض عبارة عن ايه؟ عن عينة
+
+356
+00:27:06,320 --> 00:27:11,180
+واحدةطيب كيف بدنا نحسب ال standard deviation of
+
+357
+00:27:11,180 --> 00:27:14,640
+the difference لازم او بفضل انا انه نشتغل بالشكل
+
+358
+00:27:14,640 --> 00:27:20,660
+التالي نعمل الجدول نعمل الجدول فبقول العينة الأولى
+
+359
+00:27:20,660 --> 00:27:23,380
+حللتها انا باستخدام الطريقة الجديدة اعطتنى عشرة و
+
+360
+00:27:23,380 --> 00:27:26,480
+تلاتة باستخدام الطريقة الخاصية اعطتنى عشرة و نص
+
+361
+00:27:26,480 --> 00:27:31,760
+بقول الفرق عشرة و تلاتة نقص عشرة و نص minus point
+
+362
+00:27:31,760 --> 00:27:39,190
+two ولاحظ الإشارة هان بدك تحفظ الإشارةلأنه اه لأ
+
+363
+00:27:39,190 --> 00:27:44,670
+بدك تحفظ الإشارة لأنه هنستخدمها بعد شوية في الجمع
+
+364
+00:27:44,670 --> 00:27:48,330
+و الطرح و لما تجمع و تطرح الإشارة مهمة و بعدين بدك
+
+365
+00:27:48,330 --> 00:27:50,310
+تجيب ال average كمان بعد شوية و لما تجيب ال
+
+366
+00:27:50,310 --> 00:27:56,830
+average برضه الإشارة مهمة فبتحافظ على الإشارةموجة
+
+367
+00:27:56,830 --> 00:27:59,710
+بقول السلام مش فارق لإنه بالربع هان لأ هان بدك
+
+368
+00:27:59,710 --> 00:28:03,570
+تحفظ الإشارة اتناشر سبعة ناقص احداشر تسعة موجة ب
+
+369
+00:28:03,570 --> 00:28:07,010
+تمانية من عشرة تمانية و ستة minus eight point
+
+370
+00:28:07,010 --> 00:28:11,630
+seven minus point one seventeen point five minus
+
+371
+00:28:11,630 --> 00:28:16,760
+sixteen point nine plus point six الاخرينطيب هاي
+
+372
+00:28:16,760 --> 00:28:21,220
+الـDi's دي واحد minus point two دي اتنين plus
+
+373
+00:28:21,220 --> 00:28:25,640
+point eight دي تلاتة minus point one دي اربعة plus
+
+374
+00:28:25,640 --> 00:28:30,860
+point six دي خمسة plus point three دي ستة plus
+
+375
+00:28:30,860 --> 00:28:36,740
+plus point four كويس؟ طب مجموعهم summation Di
+
+376
+00:28:36,740 --> 00:28:40,500
+بيعطينا one point eight طب بد ال average دي بار
+
+377
+00:28:40,500 --> 00:28:45,360
+جالس summation على ستة بيعطيني point three اذا
+
+378
+00:28:47,500 --> 00:28:51,980
+الـDI تعرفناها الـDI's تعرفناها الـD bar تعرفناها
+
+379
+00:28:51,980 --> 00:28:57,800
+الآن مجرد أنه نوجد summation DI minus D bar الـDI
+
+380
+00:28:57,800 --> 00:29:04,360
+الأولى سالب 2 من 10 سالب minus ال average D bar
+
+381
+00:29:04,360 --> 00:29:09,860
+اللي هي سالب 3 من 10 فبيطلع minus 0.2 minus 0.3
+
+382
+00:29:09,860 --> 00:29:15,430
+يعني minus 0.5 squared معناته 0.25لكن لو ما
+
+383
+00:29:15,430 --> 00:29:19,170
+اعتبرناش الإشارة النتيجة خاطئة لإنها point two لو
+
+384
+00:29:19,170 --> 00:29:22,470
+ولد point two minus point three فهذه صارت minus
+
+385
+00:29:22,470 --> 00:29:25,250
+point one يبقى صارت point oh one بدل ما هي point
+
+386
+00:29:25,250 --> 00:29:30,450
+two five خطأ جسيم نفس الكلام ال D two plus point
+
+387
+00:29:30,450 --> 00:29:35,010
+eight minus ال average point three تربيع إلى آخره
+
+388
+00:29:35,010 --> 00:29:39,870
+فبيطلع أن summation ال D I minus ال D bar point
+
+389
+00:29:39,870 --> 00:29:45,960
+seven sixواضح يا شباب؟ الآن طبعا المسألة خلصت مجرد
+
+390
+00:29:45,960 --> 00:29:48,760
+أنه أطبق في القانون summation di minus d bar
+
+391
+00:29:48,760 --> 00:29:52,960
+squared على ال n minus 1 الكل تحت الجزر التربيعي
+
+392
+00:29:52,960 --> 00:29:59,160
+عند 0.76 على 6 ناقص 1 يعني 5 تحت الجزر يطلع عند 0
+
+393
+00:29:59,160 --> 00:30:04,840
+.39 كمان مرة كمان مرة ال standard deviation of the
+
+394
+00:30:04,840 --> 00:30:07,280
+difference إيش تطبيقاته؟ إيش بدنا نعمل فيه؟ هين
+
+395
+00:30:07,280 --> 00:30:07,960
+حسبناه
+
+396
+00:30:18,250 --> 00:30:22,330
+ممكن هذا النوع يجيبنا لعينة واحدة أكتر من تجربته؟
+
+397
+00:30:22,550 --> 00:30:27,930
+لأ فش هي .. يعني هذا النوع يخضع multiple samples،
+
+398
+00:30:27,930 --> 00:30:31,630
+عينات مختلفة، عينات مختلفة، إذا كان عينة واحدة
+
+399
+00:30:31,630 --> 00:30:35,450
+حللتها بعدة طرق، بطريقتين يعني، حللتها عدة مرات
+
+400
+00:30:35,450 --> 00:30:38,830
+بطريقة قياسية و عدة مرات بطريقة جديدة، معناته هذا
+
+401
+00:30:38,830 --> 00:30:43,230
+cool، لكن إذا كان عندك عينات مختلفة فهذا standard
+
+402
+00:30:43,230 --> 00:30:45,150
+deviation of the difference
+
+403
+00:30:47,830 --> 00:30:52,850
+كل عيناق بحلل منها جزء بالقياسي وجزء بالإيه؟ زي
+
+404
+00:30:52,850 --> 00:30:57,730
+ايش مثلا؟ زي مثلا انت بدك تحلل يعني او تطلع نتائج
+
+405
+00:30:57,730 --> 00:31:04,830
+لمثلا جديش في عندك led في دم طفل مثلا مش معجول
+
+406
+00:31:04,830 --> 00:31:11,110
+تاخد منه يعني كوم يعني نصف لتر دم ولا متين ميل دم
+
+407
+00:31:11,110 --> 00:31:14,190
+عشان بدك تحلل عشر مرات بالقياسية وعشر مرات
+
+408
+00:31:14,190 --> 00:31:18,400
+بالجديدةكويس تبتاخد اشي قليل جدا منه بتحله بس مرة
+
+409
+00:31:18,400 --> 00:31:22,760
+واحدة كويس عشان تشوف في النهاية لو أخدت من عشرين
+
+410
+00:31:22,760 --> 00:31:26,940
+طفل او من عشر أطفال صار في عندك عدة نتائج باستخدام
+
+411
+00:31:26,940 --> 00:31:29,900
+الطريقة القياسية و عدة نتائج باستخدام الطريقة
+
+412
+00:31:29,900 --> 00:31:32,620
+الجديدة فبتقدر تختم على الطريقة يعني أنا مابديش
+
+413
+00:31:32,620 --> 00:31:37,460
+أجاوب على السؤال ايش التطبيقات لإنه هيجيلنا جلنا
+
+414
+00:31:37,460 --> 00:31:41,240
+المحاضرة مش الجاية بعد اللي جاية فبس هالجيت الفكرة
+
+415
+00:31:41,240 --> 00:31:44,800
+عندنا كيف نحسبالـ standard deviation of the
+
+416
+00:31:44,800 --> 00:31:47,760
+difference كيف نحسب ال pooled standard deviation
+
+417
+00:31:47,760 --> 00:31:52,140
+وقولنا هنتكلم بالتفصيل عن تطبيقاتهم إذا الله رحب
+
+418
+00:31:52,140 --> 00:31:57,520
+الحصة اللي جاية يعني الحصة بعد اللي جاية يمكن نبدأ
+
+419
+00:31:57,520 --> 00:31:59,280
+الحصة اللي جاية لكن الحصة بعد اللي جاية هيكون
+
+420
+00:31:59,280 --> 00:32:01,560
+تقريبا يعني بشكل أساسي
+
+421
+00:32:05,150 --> 00:32:12,570
+كيف يعني مايتساووش؟ بنفعش
+
+422
+00:32:12,570 --> 00:32:16,510
+مايتساووش لأنه كل عينة انت بتحللها بالجديد و
+
+423
+00:32:16,510 --> 00:32:20,330
+بالقياسي اذا هدا هى سطر خارج سطر العينة التانى كما
+
+424
+00:32:20,330 --> 00:32:24,410
+سطر فمش ممكن لو حللت واحدة بطريقة واحدة فمش قيمة
+
+425
+00:32:24,410 --> 00:32:31,370
+لل data point تبعتك طيب يا شباب نجي نتكلم عن ال
+
+426
+00:32:31,370 --> 00:32:36,180
+significant figures كمان برا احناذاكرنا في
+
+427
+00:32:36,180 --> 00:32:40,200
+الحسابات المتعلقة بال significant figures قلنا إنه
+
+428
+00:32:40,200 --> 00:32:45,540
+في عنا عمليات جامعة و طريح و ضرب و جسمة وللجامعة و
+
+429
+00:32:45,540 --> 00:32:49,140
+الطريح في عنا طرق لحساب عدد ال significant figures
+
+430
+00:32:49,140 --> 00:32:53,420
+في الجواب و أيضا للضرب و القسمة في عنا طرق لحساب
+
+431
+00:32:53,420 --> 00:32:57,210
+عدد ال significant figures اللي في الجوابوأخدنا
+
+432
+00:32:57,210 --> 00:33:01,410
+أمثلة كتير وحتى كمان في الواجب هتلاقي أسئلة كتير
+
+433
+00:33:01,410 --> 00:33:05,370
+على هذا الموضوع وأيضا أخدنا ال logarithmat وكيف
+
+434
+00:33:05,370 --> 00:33:07,930
+نحسب ال significant figures لما نكون في عندى في
+
+435
+00:33:07,930 --> 00:33:12,610
+المسألة logarithmat الآن ..الآن .. في عندنا مشكلة
+
+436
+00:33:12,610 --> 00:33:15,590
+يعني في الحقيقة مهمة جدا يعني الحسابات اللى
+
+437
+00:33:15,590 --> 00:33:21,450
+أخدناها هي حسابات مهمة لا شك و هنستخدمها لكن مش هي
+
+438
+00:33:21,450 --> 00:33:24,230
+الحسابات الوحيدة اللى بتهمنا لأن و أنا في المقتبر
+
+439
+00:33:24,830 --> 00:33:30,650
+أنا في المختبر باجي بأعمل التحليل تلت لخمس مرات،
+
+440
+00:33:30,650 --> 00:33:36,230
+يعني مثلا بدك تعمل معايرة، ابتعمل معايرة من تلت
+
+441
+00:33:36,230 --> 00:33:41,450
+لخمس مرات، يبقى عندك مثلا خمس نتائج، عندك خمس
+
+442
+00:33:41,450 --> 00:33:45,550
+نتائج، من الخمس نتائج إيش بتقوللي؟ انت بتقوللي
+
+443
+00:33:45,550 --> 00:33:49,610
+والله ال average تبعي هلجد؟طيب يبقى حسبة ال
+
+444
+00:33:49,610 --> 00:33:54,090
+average حلو كتير طيب انشوف ازميلكم ازميلكم عملت
+
+445
+00:33:54,090 --> 00:33:59,450
+تجربة خمس مرات تجربة معايرة اول نتيجة عنده عشرين
+
+446
+00:33:59,450 --> 00:34:05,850
+تاني نتيجة عشرة تالت نتيجة عشرة مثلا رابع نتيجة
+
+447
+00:34:05,850 --> 00:34:11,910
+عشرين خمس نتيجة خمستاشر لما نقوله طب انا بسأله
+
+448
+00:34:11,910 --> 00:34:16,030
+سؤال مديش اعرف التفاصيل بقوله جداش المتوسط تبعك؟
+
+449
+00:34:18,240 --> 00:34:22,620
+خمس طعش و خمس طعش و خمس طعش و خمس طعش و خمس طعش و
+
+450
+00:34:22,620 --> 00:34:24,980
+خمس طعش و خمس طعش و خمس طعش و خمس طعش و خمس طعش و
+
+451
+00:34:24,980 --> 00:34:27,940
+خمس طعش و خمس طعش و خمس طعش و خمس طعش و خمس طعش و
+
+452
+00:34:27,940 --> 00:34:29,540
+خمس طعش و خمس طعش و خمس طعش و خمس طعش و خمس طعش و
+
+453
+00:34:29,540 --> 00:34:31,420
+خمس طعش و خمس طعش و خمس طعش و خمس طعش و خمس طعش و
+
+454
+00:34:31,420 --> 00:34:35,640
+خمس طعش و خمس طعش و خمس طعش و خمس طعش و خمس طعش و
+
+455
+00:34:35,640 --> 00:34:41,270
+خمس طعش و خمس طعش وخمس طعش و واحد، اربع طعش و
+
+456
+00:34:41,270 --> 00:34:45,870
+تسعة، كداش نتائجك؟ خمس طعش، طب هل الخمس طعش ..
+
+457
+00:34:45,870 --> 00:34:49,630
+يعني زميل .. لو أنه الفكرة أنه يقولي جواب، إذا بدي
+
+458
+00:34:49,630 --> 00:34:52,650
+أعطي و الجواب فعلا خمس طعش، راح أقول والله أه
+
+459
+00:34:52,650 --> 00:34:56,330
+زميلكم هذا يعني ياخد نفس الدرجة زي زميلكم الأخر،
+
+460
+00:34:56,330 --> 00:35:00,280
+هل هذا كلام منطقي؟لأ، بالعكس يعني هي إن في عنده
+
+461
+00:35:00,280 --> 00:35:03,160
+spread واسع، هذا ال standard deviation اللي عنده
+
+462
+00:35:03,160 --> 00:35:07,260
+إيه شماله كبير، بينما ازميلكم ال spread اللي عنده
+
+463
+00:35:07,260 --> 00:35:11,440
+إيه شماله، يبقى ال average بحد ذاته مش كافي
+
+464
+00:35:11,440 --> 00:35:15,130
+للتعبير على النتيجةالـ Average مش كافلة لنا نتيجة
+
+465
+00:35:15,130 --> 00:35:18,030
+احنا كل نتيجة يجب ان يكون مرتبط معاها error متام
+
+466
+00:35:18,030 --> 00:35:21,290
+ان هي نتيجة عملية بدي يكون مرتبط معاها ايه؟ error
+
+467
+00:35:21,290 --> 00:35:26,230
+طيب ال error هذا يا شباب او ال absolute error
+
+468
+00:35:26,230 --> 00:35:30,990
+المرتبط بالنتيجة هذا هو ال standard deviation يعني
+
+469
+00:35:30,990 --> 00:35:34,910
+لما نقول للأخ اللي وصلت بقى هتقوللي النتيجة اللي
+
+470
+00:35:34,910 --> 00:35:38,470
+بقعته هتقوللي والله خمست عشر زائد او ناقص مثلا
+
+471
+00:35:38,470 --> 00:35:44,360
+اتنينأو تلاتة لما أقول لزميلكم قوللي النتيجة قوللي
+
+472
+00:35:44,360 --> 00:35:50,660
+15.0 زائد أو ناقص point one مثلا فإيش الزائد أو
+
+473
+00:35:50,660 --> 00:35:53,620
+ناقص هذه .. هذه ال uncertainty أو ال absolute
+
+474
+00:35:53,620 --> 00:35:56,840
+uncertainty في ال answer أو يعني ال standard
+
+475
+00:35:56,840 --> 00:35:59,980
+deviation يبجى هذا هو ال standard deviation لما
+
+476
+00:35:59,980 --> 00:36:03,980
+أجي أعمل التجربة أحلل مادة معينة خمس ست مرات
+
+477
+00:36:03,980 --> 00:36:08,900
+حللتها بطلع ال averageمن قيم التحليل والـ Average
+
+478
+00:36:08,900 --> 00:36:11,540
+بطلّق الـ Standard Deviation، هذا الـ Standard
+
+479
+00:36:11,540 --> 00:36:15,360
+Deviation بيكون مضعف لهذه القيمة، plus or minus
+
+480
+00:36:15,360 --> 00:36:18,020
+الـ Standard Deviation، اللي هو الـ Absolute
+
+481
+00:36:18,020 --> 00:36:21,920
+Uncertainty بيكون، اللي منها أنا بدي أفهم جدّيش ال
+
+482
+00:36:21,920 --> 00:36:27,600
+precision اللي الشخص يعني كان محافظ عليها أثناء
+
+483
+00:36:27,600 --> 00:36:32,320
+شغلهجدّاش ال precision فبالتالي بقدر اقول انا ان
+
+484
+00:36:32,320 --> 00:36:37,160
+ال absolute value يعني في الحاجات التجربية صعب
+
+485
+00:36:37,160 --> 00:36:41,780
+انها تكون يعني الها قيمة عادة اي نتيجة يجب ان
+
+486
+00:36:41,780 --> 00:36:47,080
+يرتبط معاها error ما او uncertainity ما فهذا اللي
+
+487
+00:36:47,080 --> 00:36:56,040
+احنا بنعبر عنه عادة بال error الفكرة هي التالي كيف
+
+488
+00:36:56,040 --> 00:37:03,860
+ممكن نعمل حساباتكيف ممكن نعمل حسابات لنتائج
+
+489
+00:37:03,860 --> 00:37:08,060
+موجود فيها uncertainty موجود فيها uncertainty يعني
+
+490
+00:37:08,060 --> 00:37:17,160
+مثلا احنا كنا أخدنا سابقا مثلا لو بد الملي مولز
+
+491
+00:37:17,160 --> 00:37:24,690
+total milli moles بدها تساوي الملي مولزاللي في
+
+492
+00:37:24,690 --> 00:37:29,990
+العينة A زائد الـ millimole اللي في العينة B مثلا
+
+493
+00:37:29,990 --> 00:37:40,830
+لو كان ال millimole هذا مثلا 15.78 وهذا مثلا
+
+494
+00:37:40,830 --> 00:37:51,390
+8.11 ماعندي مشكلة أو 8.1 عاملها بطريقة جديدة بنقول
+
+495
+00:37:51,390 --> 00:37:59,920
+والله النتيجة بتساوي23.89
+
+496
+00:37:59,920 --> 00:38:05,100
+لأنه بينفعش نحط أكتر من الرقم واحد بس لكن يا شباب
+
+497
+00:38:05,100 --> 00:38:09,280
+هذا الكلام اللي حصلت عليه ولا في الأحلام يعني هذا
+
+498
+00:38:09,280 --> 00:38:12,740
+الكلام ماحصلش عليه عمليا ليه؟ لأنه أنا عشان أشوف
+
+499
+00:38:12,740 --> 00:38:18,020
+أكمل المول من إيه بدي أعمل التجربة عدة مرات فكل
+
+500
+00:38:18,020 --> 00:38:23,460
+مرة بدي يكون في عندي value نتيجةطيب النتيجة اللى
+
+501
+00:38:23,460 --> 00:38:28,100
+عندي هيكون مرتبط معها معنى الكلام uncertainty من
+
+502
+00:38:28,100 --> 00:38:31,160
+وين بده يبقى انا عملتها مثلا خمس مرات ال average
+
+503
+00:38:31,160 --> 00:38:36,300
+تباعها صح كان خمستاشر point seven eight لكن ال
+
+504
+00:38:36,300 --> 00:38:40,860
+standard deviation مرتبط معها مثلا point four اربع
+
+505
+00:38:40,860 --> 00:38:48,420
+مثلا طب والنتيجة التانية صحية كانت eight point one
+
+506
+00:38:48,420 --> 00:38:56,890
+لكن مرتبط معهامثلا point two هذا من وين جبنا ال
+
+507
+00:38:56,890 --> 00:39:00,910
+point two هذا ال standard deviation لأن احنا حللنا
+
+508
+00:39:00,910 --> 00:39:06,290
+عدد ال millimoles اكتر من مرة مثلا تمام مرات كل
+
+509
+00:39:06,290 --> 00:39:08,690
+مرة اعطتني نتيجة ال average تمانية واحد من عشرة
+
+510
+00:39:08,690 --> 00:39:13,910
+صحيحطيب ال average 81 من 10 طب ممكن أحسب ال 7
+
+511
+00:39:13,910 --> 00:39:16,610
+deviation اللي هو ال uncertainty ال absolute error
+
+512
+00:39:16,610 --> 00:39:21,830
+فحسبته لجته 2 من 10 لما أجي انا بدي أحسب هدول بقول
+
+513
+00:39:21,830 --> 00:39:26,990
+بالله اه انا في عندي النتيجة هدول absolute numbers
+
+514
+00:39:26,990 --> 00:39:31,750
+بنحسبه على طول 23 و 9 من 10 زاد او ماقص طب ال
+
+515
+00:39:31,750 --> 00:39:39,010
+uncertainties كيف بدي أحسبهم أجمعهم اه بنقول لأال
+
+516
+00:39:39,010 --> 00:39:42,850
+uncertainties لها طريقة حسابيعني ال absolute
+
+517
+00:39:42,850 --> 00:39:47,130
+numbers نعم تجمع وتطرح تضرب وتقسم بالطرق اللي
+
+518
+00:39:47,130 --> 00:39:52,090
+اتعلمناها سابقا لكن ال uncertainties لا يجب ان
+
+519
+00:39:52,090 --> 00:39:56,270
+نطبق القانون ال uncertainty في ال answer تربيع ال
+
+520
+00:39:56,270 --> 00:39:59,870
+uncertainty اللي هي S في ال answer تربيع ايش
+
+521
+00:39:59,870 --> 00:40:03,870
+بتساوي ال uncertainty في الأول تربيع زاد ال
+
+522
+00:40:03,870 --> 00:40:07,110
+uncertainty في التاني تربيع زاد اذا كان عندي كمان
+
+523
+00:40:07,110 --> 00:40:09,890
+اكتر ال uncertainty في التالت تربيع زاد ال
+
+524
+00:40:09,890 --> 00:40:12,920
+uncertainty في الرابع تربيع الاخرييبقى ال
+
+525
+00:40:12,920 --> 00:40:18,140
+uncertainties لا تجمع كما يجمع ال absolute numbers
+
+526
+00:40:18,140 --> 00:40:22,560
+لأ ال uncertainties لازم في الأول نجيب ال
+
+527
+00:40:22,560 --> 00:40:25,320
+uncertain في ال answer تربيع بتساوي أو ال
+
+528
+00:40:25,320 --> 00:40:28,880
+uncertain في ال answer بتساوي الجزر التربيهي لال
+
+529
+00:40:28,880 --> 00:40:32,880
+uncertain في النتيجة الأولى تربيع زاد ال uncertain
+
+530
+00:40:32,880 --> 00:40:35,640
+في النتيجة التانية تربيع زاد ال uncertain في
+
+531
+00:40:35,640 --> 00:40:39,560
+النتيجة التالتة تربيع و هكذا يعني هان يجب أن اقول
+
+532
+00:40:39,560 --> 00:40:45,190
+والله ال S إيه؟بتساوي الجزر التربيعي plus or minus
+
+533
+00:40:45,190 --> 00:40:51,330
+point four point four تربيع
+
+534
+00:40:51,330 --> 00:40:56,430
+زائد plus or minus point two تربيع هاي النتيجة
+
+535
+00:40:56,430 --> 00:41:00,330
+تبعتها هذا اللي بتعطينا ال S A اللي انا بده احطها
+
+536
+00:41:00,330 --> 00:41:07,590
+هنامش أنه بدي أجمع هدول مع بعض مباشرة مثلا لأ بس
+
+537
+00:41:07,590 --> 00:41:09,870
+ال absolute number دي اللي تجمع لكن ال answer
+
+538
+00:41:09,870 --> 00:41:14,150
+تنتظر في إلها طريقة في حالة الجمع والطريق زي ما هو
+
+539
+00:41:14,150 --> 00:41:19,270
+قدامي هي ال S A بهذه الطريقة بنجيبها تضربوا القسم
+
+540
+00:41:19,270 --> 00:41:26,130
+هنشوف إلها طريقة تانية خلينا ناخد بنقول
+
+541
+00:41:26,130 --> 00:41:29,170
+أنه مثلا يعني طلع عندك ال standard deviation
+
+542
+00:41:29,170 --> 00:41:33,700
+للقرائات الأولى هذا ال averageمثلا لو عملنا
+
+543
+00:41:33,700 --> 00:41:37,900
+التجربة الملي مولز من ايه عشان نعرف جديش حللناها
+
+544
+00:41:37,900 --> 00:41:42,800
+خمس مرات كل مرة أعطينا نتيجة ال average إيه لهم لو
+
+545
+00:41:42,800 --> 00:41:45,880
+طلع مثلا خمستاشر تمانية و سبعين هيك ال average طلع
+
+546
+00:41:45,880 --> 00:41:50,460
+طيب مش احنا حللناها خمس مرات بنقدر نحسب ال
+
+547
+00:41:50,460 --> 00:41:55,330
+standard deviation لو حسبناهامثلا اعطاني point 04
+
+548
+00:41:55,330 --> 00:41:59,290
+يبقى ال point 04 هذا عبارة عن ال answer تنتي في ال
+
+549
+00:41:59,290 --> 00:42:02,730
+answer ال absolute answer تنتي في ال answer ال
+
+550
+00:42:02,730 --> 00:42:07,910
+answer عندي 15.78 الآن في الجواب هان نفس الكلام
+
+551
+00:42:07,910 --> 00:42:14,470
+حللت المادة B عشان اشوف اكمل المول فيها فحللتها
+
+552
+00:42:14,470 --> 00:42:19,010
+تمان مرات تمان مرات طبق المتوسط تمانية واحد من
+
+553
+00:42:19,010 --> 00:42:23,470
+عشرةحلالة 8 مرات يعني 8 نتائج حسبت ال standard
+
+554
+00:42:23,470 --> 00:42:29,750
+deviation فاعطاني مثلا 2 من 10 من هنا جدًا طيب يا
+
+555
+00:42:29,750 --> 00:42:36,950
+شباب خلينا ناخد مثال عملية على هذا الكلام و نشوف
+
+556
+00:42:36,950 --> 00:42:43,550
+كيف ممكن نحسب ال uncertainties او عمليات جمع او
+
+557
+00:42:43,550 --> 00:42:48,980
+طرحلأ، نتائج موجود فيها uncertainties اللي هي في
+
+558
+00:42:48,980 --> 00:42:53,880
+الحقيقة يعني شيء واقعي بالنسبة لنا لأن أغلب شغلنا
+
+559
+00:42:53,880 --> 00:42:57,180
+وكل measurement فيها uncertainty، فيها error فمدين
+
+560
+00:42:57,180 --> 00:43:00,220
+أحنا بنعمل measurements إذا فيها إنا errors فنيجي
+
+561
+00:43:00,220 --> 00:43:07,040
+نتطلع على هالمثال التالي المثال إيش بيقول؟ بيقول
+
+562
+00:43:07,040 --> 00:43:11,550
+ال three samples were analyzed for iron contentفي
+
+563
+00:43:11,550 --> 00:43:15,470
+تلت عينات حللناهم لل iron content كل عينة حللناها
+
+564
+00:43:15,470 --> 00:43:18,750
+عدة مرات مثلا نقول حللناها سبعة مرات التانية تمان
+
+565
+00:43:18,750 --> 00:43:23,470
+مرات التالتة تسعة مرات بقول the average percentage
+
+566
+00:43:23,470 --> 00:43:29,250
+of iron in the first sample was 65.06 يعني أول
+
+567
+00:43:29,250 --> 00:43:34,630
+عينة أخدناها حللناها خمس ست مراتفكل مرة اعطتني
+
+568
+00:43:34,630 --> 00:43:40,470
+قيمة نتيجة مرة 66 مرة 65 مرة 64 مرة 67 لما حسبنا
+
+569
+00:43:40,470 --> 00:43:46,290
+المتوسط كده شطلع 65.6% لحظه انه ممكن احسب كمان ايش
+
+570
+00:43:46,290 --> 00:43:49,530
+ال standard deviation هى اللى جت بعد شوية هيعطوه
+
+571
+00:43:49,530 --> 00:43:52,910
+اللى ممكن احسب ال standard بما اندي نتائج واندي ال
+
+572
+00:43:52,910 --> 00:43:56,090
+average بقدر احسب ال standard deviation طب هذه
+
+573
+00:43:56,090 --> 00:44:01,560
+العينة و العينة التانية اعطتنى 56.13العينة التالتة
+
+574
+00:44:01,560 --> 00:44:06,240
+عطبنا 62.68 ايش بيقوللي؟ بيقوللي the estimated
+
+575
+00:44:06,240 --> 00:44:09,880
+standard deviation of each of the three samples
+
+576
+00:44:09,880 --> 00:44:12,840
+where ال estimated يعني ال sample standard
+
+577
+00:44:12,840 --> 00:44:17,960
+deviation جداش جال الأولى 0.07 للتانية 0.01
+
+578
+00:44:17,960 --> 00:44:23,640
+للتالتة 0.02 طالب what's the average iron content
+
+579
+00:44:23,640 --> 00:44:28,020
+of the samples عارفين هذا بالظبط زي ايش؟ زي ما انك
+
+580
+00:44:28,020 --> 00:44:33,260
+تكون بتشتغل في مصنعحديد و صلب و عمال بيجيلك شحنات
+
+581
+00:44:33,260 --> 00:44:36,640
+من الحديد و الصلب و هاد الشحنات بدك تدفع حاجها انت
+
+582
+00:44:36,640 --> 00:44:43,240
+فإجالك أول truck و تاني truck و تالت truck أول
+
+583
+00:44:43,240 --> 00:44:46,820
+truck أخدت عينة ممثلة حلتها لجيت ال average تبعها
+
+584
+00:44:46,820 --> 00:44:55,260
+65.06 حلالك عدة مرات طلعت ل 7 deviation طلع عندك 0
+
+585
+00:44:55,260 --> 00:45:03,370
+.07أذن التحليل الأول 65.06 زاد أو ناقص 0.07 لتراك
+
+586
+00:45:03,370 --> 00:45:09,570
+التاني أخدت عينة ومثلها وحللتها عدة مرات فطلع عندك
+
+587
+00:45:09,570 --> 00:45:16,750
+56.13 طلعت ال standard deviation طلع عندك 0.01 أذن
+
+588
+00:45:16,750 --> 00:45:22,690
+التحليل التاني لتراك التاني 56.13 زاد أو ناقص 0.01
+
+589
+00:45:22,690 --> 00:45:30,330
+لتراك التالتأخدت عينة ومثلة وحللتها 7-8 مرات برضه
+
+590
+00:45:30,330 --> 00:45:39,350
+فطلع عندك النتيجة 62.68-0
+
+591
+00:45:39,350 --> 00:45:44,890
+.02
+
+592
+00:45:45,860 --> 00:45:49,660
+انت لو عارف وزنة الأول ووزنة التانى ووزنة التالت
+
+593
+00:45:49,660 --> 00:45:56,540
+كل الأوزان اللى عندك بتقدر تطلع جداش بدك تدفع
+
+594
+00:45:56,540 --> 00:46:01,340
+الفلوس اذا كان عارفت جداش ال average percentage
+
+595
+00:46:01,340 --> 00:46:05,620
+انت ماتكش تقول للمدير المقتبر او المصدر او المؤسسة
+
+596
+00:46:05,620 --> 00:46:07,880
+انه بضل ال truck الأول فيها الجدوة التانى فيها
+
+597
+00:46:07,880 --> 00:46:11,020
+اللي مظبطش بجيك 100 truck في اليوم ده تحكيله قصة
+
+598
+00:46:11,020 --> 00:46:17,490
+لأ انت بتطلع ال percentage لكل واحدبتجمعهم وبتطلع
+
+599
+00:46:17,490 --> 00:46:20,010
+ال average percentage وبتضرب في الوزن الكل اللي
+
+600
+00:46:20,010 --> 00:46:23,990
+عندك بتفعلها كأنك جدش لازم تدفع الفلوس جدش الوزن
+
+601
+00:46:23,990 --> 00:46:28,620
+اللي بدك تحاسب عليهفكيف بدنا نطلع ال average
+
+602
+00:46:28,620 --> 00:46:31,760
+what's the average iron content of the samples
+
+603
+00:46:31,760 --> 00:46:34,800
+depending on these results معناه كده أننا بدنا
+
+604
+00:46:34,800 --> 00:46:38,460
+نجمعهم و نجسمهم على تلاتة بدنا نجمع هدول و نجسمهم
+
+605
+00:46:38,460 --> 00:46:44,280
+على تلاتة النتيجة الأولى 65.06 زائد أو نقص 0.07
+
+606
+00:46:44,280 --> 00:46:52,390
+النتيجة التانية 6556.13 plus or minus 0.01النتيجة
+
+607
+00:46:52,390 --> 00:46:57,910
+التالتة 62.68 ± 0.02 على تلاتة أنا كاتبلك التلاتة
+
+608
+00:46:57,910 --> 00:47:01,570
+بالإيه؟ بالازرق عشان أقولك إن هذه التلاتة مالهاش
+
+609
+00:47:01,570 --> 00:47:05,050
+دعوة في تحديد عدد ال figures هي عبارة عن exact
+
+610
+00:47:05,050 --> 00:47:12,780
+numbers و بدك تنفيه شوية ال 65.06 هذا exactالـ 56
+
+611
+00:47:12,780 --> 00:47:18,360
+.13 هذا برضه exact، الـ 62.68 برضه exact، هدول
+
+612
+00:47:18,360 --> 00:47:21,760
+بتجمعهم و بتطرحهم و بتدروبهم و بتجسمهم عادي من غير
+
+613
+00:47:21,760 --> 00:47:25,140
+أي مشاكل، مالهو مش دعوة، اللي فيه المشكلة بس إيه؟
+
+614
+00:47:25,750 --> 00:47:32,810
+الـ uncertainty هي الفئة المشكلة طيب بنجمع 65.06
+
+615
+00:47:32,810 --> 00:47:41,890
+زائد 56.13 زائد 62.68 على 3 بيطلع 61.29 طبعا two
+
+616
+00:47:41,890 --> 00:47:46,270
+significant figures على يمين العلامة العشريةبيطلع
+
+617
+00:47:46,270 --> 00:47:50,390
+عنا ايش الجواب 60 هذا هو ال average ال average من
+
+618
+00:47:50,390 --> 00:47:54,690
+وين جبته مجموع ال absolute numbers التلاتة على
+
+619
+00:47:54,690 --> 00:48:01,270
+تلاتة بيطلع عنا 61.29 ماشي يا شباب زائد المشكلة
+
+620
+00:48:01,270 --> 00:48:04,610
+اللي احنا بنواجهها الآن هي ال S A ال relative
+
+621
+00:48:04,610 --> 00:48:08,150
+answer ال absolute answer تنتهي في ال answer بقول
+
+622
+00:48:08,150 --> 00:48:12,610
+اه ال S A بتساوي ال answer تنتهي في الأول تربيع
+
+623
+00:48:13,610 --> 00:48:17,370
+زائد ال uncertainty .. عفوا ال uncertainty في
+
+624
+00:48:17,370 --> 00:48:20,570
+الأول تربية زائد ال uncertainty اللي في النتيجة
+
+625
+00:48:20,570 --> 00:48:23,370
+التانية تربية زائد ال uncertainty في النتيجة
+
+626
+00:48:23,370 --> 00:48:29,090
+التالتة تربية كل واحدة تحت الجزير بلاقي انه عندي
+
+627
+00:48:29,090 --> 00:48:33,930
+ال uncertainty 7.3 في عشرة أساليب اتنين باجي بقول
+
+628
+00:48:33,930 --> 00:48:38,130
+والله يبقى الجواب percent iron بيساوي 61.29 plus
+
+629
+00:48:38,130 --> 00:48:44,370
+or minus 0.073لكن يا شباب انا بقول هذه هي ال
+
+630
+00:48:44,370 --> 00:48:50,090
+uncertainty الان في عندي uncertainty في الجزء من
+
+631
+00:48:50,090 --> 00:48:55,470
+100 اذا الجزء من الف بكون certain ولا very
+
+632
+00:48:55,470 --> 00:48:59,810
+uncertain اذا كان عندي ال uncertainty موجودة في
+
+633
+00:48:59,810 --> 00:49:04,130
+الجزء من 100 فانا بركب في الجزء من الف مافيش اي
+
+634
+00:49:04,130 --> 00:49:09,190
+قيمة للتلاتةفيش أي قيمة لأنه عندي ال uncertainty
+
+635
+00:49:09,190 --> 00:49:15,010
+موجودة في الواحد من مية إذا الواحد من الف أصلا
+
+636
+00:49:15,010 --> 00:49:20,110
+very uncertain علشان هيك و دائما بنقول أنه حدد
+
+637
+00:49:20,110 --> 00:49:25,300
+الأرقام هان بده يكون بساويبنفعش هل تكون معروفة
+
+638
+00:49:25,300 --> 00:49:28,020
+لأقرب واحد من مية؟ و هل تكون معروفة لأقرب واحد من
+
+639
+00:49:28,020 --> 00:49:35,620
+الف؟ بنفع؟ بنفعش فالتنتين يكونوا زي بعض سألني او
+
+640
+00:49:35,620 --> 00:49:41,380
+سألت احد زميلاتكم تقول طب لو كانت 61.291 مثلا plus
+
+641
+00:49:41,380 --> 00:49:48,660
+or minus 0.073 بنفعبنفع أخلي التلاتة؟ أنا قلت لأ،
+
+642
+00:49:48,660 --> 00:49:51,740
+بنفعش، لأنه كمان مرة، where is the uncertainty
+
+643
+00:49:51,740 --> 00:49:56,040
+اللي عندها أنا؟ في الملمية، التلاتة، بلغي هذه و
+
+644
+00:49:56,040 --> 00:50:00,460
+بلغي هذا كمانهنشوف تفاصيل هذا كلام الحصة الجاية،
+
+645
+00:50:00,460 --> 00:50:04,900
+بس الآن بقول إيش؟ بقول إنه الـuncertainty line دي
+
+646
+00:50:04,900 --> 00:50:10,100
+وين في الواحد من مية، إذا الواحد من ألف، الواحد من
+
+647
+00:50:10,100 --> 00:50:13,260
+ألف، مافيش إله أي قيمة، very uncertain، ماينفعش
+
+648
+00:50:13,260 --> 00:50:17,160
+نكتبه، لإن ال uncertainity line دي وين موجودة في
+
+649
+00:50:17,160 --> 00:50:20,200
+الواحد من مية، إذا بفهم هذه واحد من مية، يبقى هذه
+
+650
+00:50:20,200 --> 00:50:23,580
+برضه واحد من مية زيها، هان رقمين، هان رقمين، يبقى
+
+651
+00:50:23,580 --> 00:50:32,490
+الجوابهو عبارة عن 61.29 ± 0.07% هذا يا شباب في
+
+652
+00:50:32,490 --> 00:50:37,610
+حالة الجامع والطرح إذا قال رد الحصة الجاية هنتكلم
+
+653
+00:50:37,610 --> 00:50:44,930
+عن الدرب والجسمة و هنثبتلكم أو هنحاول نستنتج أن ال
+
+654
+00:50:44,930 --> 00:50:48,590
+uncertainty هذه اللي احنا الآن بنتعلمها هي التي
+
+655
+00:50:48,590 --> 00:50:52,770
+تحدد عدد ال significant figures في الجواب مش ال
+
+656
+00:50:52,770 --> 00:50:57,690
+key number ولاأكم digit على يمين العلامة العشرية
+
+657
+00:50:57,690 --> 00:51:03,350
+اللي بيحدد ال answer تنتهي في الجواب او عدد ال
+
+658
+00:51:03,350 --> 00:51:05,950
+significant figures اللي في الجواب هي ال answer
+
+659
+00:51:05,950 --> 00:51:10,270
+تنتهي المصاحبة للجواب وليس اي شيء اخر هذا اذا كان
+
+660
+00:51:10,270 --> 00:51:13,750
+في في الجواب answer تنتهي معلومة هنشوف هذا الكلام
+
+661
+00:51:13,750 --> 00:51:17,170
+اذا الله راد الحصة الجاية في اي سؤال يا شباب
+
diff --git a/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/gmLW3MRwlGM_postprocess.srt b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/gmLW3MRwlGM_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..f58a1fe18ebb46c3592b1ad2fb188d4c2e6d5151
--- /dev/null
+++ b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/gmLW3MRwlGM_postprocess.srt
@@ -0,0 +1,2224 @@
+1
+00:00:20,670 --> 00:00:22,950
+ان شاء الله اليوم بنكمل في ال tests of
+
+2
+00:00:22,950 --> 00:00:26,750
+significance اللي هي اختبارات ذات المغزاة او ذات
+
+3
+00:00:26,750 --> 00:00:31,390
+الدلالة و احنا بنقول ان الحصة الماضية اتكلمنا عن
+
+4
+00:00:31,390 --> 00:00:36,590
+اختبار من الاختبارات قولنا ال if test و ال if test
+
+5
+00:00:36,590 --> 00:00:43,630
+بعطيني فكرة عن هل هناك فرق احصائي جوهري بين ال
+
+6
+00:00:43,630 --> 00:00:47,930
+precision او ال variances او ال standard
+
+7
+00:00:47,930 --> 00:00:52,300
+deviationsلتو procedures او two methods ولا لأ
+
+8
+00:00:52,300 --> 00:00:59,760
+فقلنا اذا كان ال F Calc اقل من ال F Tab معناته ليس
+
+9
+00:00:59,760 --> 00:01:04,960
+هناك فرق احصائي جوهري ما بين ال precision لل two
+
+10
+00:01:04,960 --> 00:01:09,040
+methods او ال variances لل two methods او ايضا ال
+
+11
+00:01:09,040 --> 00:01:13,060
+standard deviations لل two methods اما لو كان
+
+12
+00:01:13,060 --> 00:01:18,470
+العكس فطبعا بيكون هناك فرق احصائي جوهريلكن السؤال
+
+13
+00:01:18,470 --> 00:01:26,830
+الآخر اللي يجب الإجابة عنه يتمثل في هل هناك بالفعل
+
+14
+00:01:26,830 --> 00:01:32,050
+فرق في النتائج ما بين طريقتين مختلفتين أو two
+
+15
+00:01:32,050 --> 00:01:36,230
+procedures مختلفين وقولنا ان اللي بيجاوب على هذا
+
+16
+00:01:36,230 --> 00:01:42,090
+السؤال هو عبارة عن ال T-test ال T-test يا شباب فيه
+
+17
+00:01:42,090 --> 00:01:48,700
+له تلت أحوالالـ T-test فيه له تلت أحوال يعني بيطبق
+
+18
+00:01:48,700 --> 00:01:54,500
+في تلت أحوال مختلفة أول حالة من هذه الحالات هو
+
+19
+00:01:54,500 --> 00:02:00,760
+تطبيق الـ T-test إذا كان في عندي accepted value أو
+
+20
+00:02:00,760 --> 00:02:07,500
+true value knownيعني في عندى نتيجة التحليل معروفة
+
+21
+00:02:07,500 --> 00:02:12,240
+سلفا معروفة مسبقا زى مثلا ما اكون بدى احل المادة
+
+22
+00:02:12,240 --> 00:02:16,840
+فجبت عينة من هذه المادة من معهد القياسات الدولية
+
+23
+00:02:16,840 --> 00:02:21,720
+ومكتوب على هذه المادة انه والله نتيجة التحليل مثلا
+
+24
+00:02:21,720 --> 00:02:28,340
+سبعة وخمسة وخمسين في المية PPMمعروفة نتيجة سلافا
+
+25
+00:02:28,340 --> 00:02:32,160
+قبل ما احلل فانا بدي احلل باستخدام الطريقة الجديدة
+
+26
+00:02:32,160 --> 00:02:37,180
+و بدي اقارن نتيجتي مع النتيجة الحقيقية فهذه أول
+
+27
+00:02:37,180 --> 00:02:41,460
+حالة من حالات التيتس بطبقها إذا كان في عندي
+
+28
+00:02:41,460 --> 00:02:47,260
+accepted أو true value is known الحالة التانية إذا
+
+29
+00:02:47,260 --> 00:02:51,470
+كان فيش عندي accepted أو true value knownمش .. مش
+
+30
+00:02:51,470 --> 00:02:55,190
+معروفة طيب في هذه الحالة يعني إيش بقتر أعمل؟ جال
+
+31
+00:02:55,190 --> 00:03:00,470
+بقتر أحلل replicate samples باستخدام طريقة قياسية
+
+32
+00:03:00,470 --> 00:03:04,850
+و بعتبر إنه هذه صارت والله يعني أه مقبولة و
+
+33
+00:03:04,850 --> 00:03:09,130
+replicate samplesباستخدام الطريقة الجديدة وبعدين
+
+34
+00:03:09,130 --> 00:03:13,450
+بقارن between ال two means المتوسط للأول والمتوسط
+
+35
+00:03:13,450 --> 00:03:16,870
+للتانية وبشوف هل هناك فرق أحصائي جوهري بين
+
+36
+00:03:16,870 --> 00:03:21,050
+المتوسطين ولا لأ يبقى الحالة التانية لل T test
+
+37
+00:03:21,050 --> 00:03:26,810
+ممكن أسميها comparison between two means ال mean
+
+38
+00:03:26,810 --> 00:03:29,310
+اللي بحصل عليه من ال standard و ال mean اللي بحصل
+
+39
+00:03:29,310 --> 00:03:34,950
+عليه من ال new method الحالة التالتة يا شباب اللي
+
+40
+00:03:34,950 --> 00:03:41,590
+بطبق فيها ال T testبقول ال test with multiple
+
+41
+00:03:41,590 --> 00:03:44,950
+samples في بعض الأحيان أنا ماعندي replicate
+
+42
+00:03:44,950 --> 00:03:48,910
+samples ماعندي عينة بحللها عدة مرات بالقياسية و
+
+43
+00:03:48,910 --> 00:03:53,630
+عدة مرات بالطريقة الجديدة لأ أنا في عندي عينات
+
+44
+00:03:53,630 --> 00:03:57,750
+مختلفة multiple samples فبحلل العينة الأولى
+
+45
+00:03:57,750 --> 00:04:02,160
+باستخدام ال standardو بحلل نفس العينة باستخدام
+
+46
+00:04:02,160 --> 00:04:06,260
+الطريقة الجديدة و انتهى الموضوع باخد عينة جديدة
+
+47
+00:04:06,260 --> 00:04:10,000
+عينة أخرى بحللها بال standard و بالجديدة عينة
+
+48
+00:04:10,000 --> 00:04:13,400
+ثالثة بال standard و بالجديدة و هكذا ففي عندي
+
+49
+00:04:13,400 --> 00:04:16,560
+multiple samples إذا كان عندي multiple samples
+
+50
+00:04:16,560 --> 00:04:22,860
+فهناك طريقة لحساب ال T value فيبقى في عندي تلت طرق
+
+51
+00:04:23,080 --> 00:04:25,720
+when an accepted or a true value is known
+
+52
+00:04:25,720 --> 00:04:31,540
+comparison between two means والحالة الأخيرة بنقول
+
+53
+00:04:31,540 --> 00:04:38,400
+comparison
+
+54
+00:04:38,400 --> 00:04:43,000
+between two means والحالة الأخيرة إيش ذكرناها؟قلنا
+
+55
+00:04:43,000 --> 00:04:48,000
+T-test with multiple samples طيب نيجي نتطلع على
+
+56
+00:04:48,000 --> 00:04:51,460
+القانون اللي راح نستخدمه في الحل و أنا أحاول
+
+57
+00:04:51,460 --> 00:04:56,920
+أبسطلك الموضوع بدي أقول أنه كل التلت قوانين اللي
+
+58
+00:04:56,920 --> 00:05:00,920
+هنتكلم عنهم في التلت أحوال لل T-test هيكونوا
+
+59
+00:05:00,920 --> 00:05:05,060
+مشتقين من حاجة احنا درسناها كويس و فاهمينها كويس
+
+60
+00:05:05,060 --> 00:05:09,750
+كتير اللي هي ال confidence limitالـ confidence
+
+61
+00:05:09,750 --> 00:05:12,610
+limit كان فيه قانون بيقول الـ confidence limit
+
+62
+00:05:12,610 --> 00:05:18,310
+بيسوى x bar زادة ونقص الTS على جزر ال N صح؟ الحصة
+
+63
+00:05:18,310 --> 00:05:21,720
+الماضية كنا أخدنا هذا الكلامالـ confidence limit
+
+64
+00:05:21,720 --> 00:05:24,820
+اللي احنا قلنا هي الـ true value in fact الـ true
+
+65
+00:05:24,820 --> 00:05:28,020
+value يعضر عن .. بترجع في range x bar زادة و نقص
+
+66
+00:05:28,020 --> 00:05:32,300
+ال T S على جزر ال N طب لو اجينا .. قعدنا ترتيب هذه
+
+67
+00:05:32,300 --> 00:05:37,020
+المعادلة لو قعدنا ترتيب هذه المعادلة إيش بنقول؟
+
+68
+00:05:37,020 --> 00:05:43,320
+بلس أو ماينس T بتساوي X bar minus M U جزر ال N على
+
+69
+00:05:43,320 --> 00:05:48,200
+S عادي الترتيب فانا في هذه الحالة إيش بأحسب؟بأحسب
+
+70
+00:05:48,200 --> 00:05:53,800
+ال T طب حسبت ال T بقى أقارنها بال T tabulated اللي
+
+71
+00:05:53,800 --> 00:05:58,740
+في الجدول هذا T بتكون calculated فبنفس الطريقة إذا
+
+72
+00:05:58,740 --> 00:06:03,280
+كان ال T calculated أقل إذا ليس هناك فرق إحصائي
+
+73
+00:06:03,280 --> 00:06:10,380
+جوهري بين نتائج الطريقتين والعكس أيضا صحيح طيب هذه
+
+74
+00:06:10,380 --> 00:06:14,080
+الحالة الأولى اللي بتكلم عنها طيب نيجي الآن ناخد
+
+75
+00:06:14,080 --> 00:06:19,410
+مثال كتير بسيطبنقول في a new procedure for
+
+76
+00:06:19,410 --> 00:06:22,570
+determining copper what was used for the
+
+77
+00:06:22,570 --> 00:06:26,490
+determination of copper in a sample بدنا نعين
+
+78
+00:06:26,490 --> 00:06:32,590
+الكبر في عينة ما فاستخدمنا طريقة جديدة لتعين الكبر
+
+79
+00:06:32,590 --> 00:06:37,000
+في هذه العينةالتجارة تم تجاربها خمس مرات
+
+80
+00:07:04,480 --> 00:07:08,380
+مش بس هيك و كمان بقدر احسب ال 7 deviation من الخمس
+
+81
+00:07:08,380 --> 00:07:11,820
+نتائج لكن هو ان معطيني ايضا يقول اندي a standard
+
+82
+00:07:11,820 --> 00:07:17,440
+deviation of plus or minus point seven امنى هيك
+
+83
+00:07:19,050 --> 00:07:24,170
+يعني أعطاني ال X bar و أعطاني ال S بيقول if the
+
+84
+00:07:24,170 --> 00:07:28,530
+true value وهذا اللي بفهمني أي حالة من حالات ال T
+
+85
+00:07:28,530 --> 00:07:32,650
+test بدي أستخدم if the true value for this
+
+86
+00:07:32,650 --> 00:07:37,830
+analysis was 11.7 PPM يبقى العينة هذه التحليل
+
+87
+00:07:37,830 --> 00:07:42,730
+الحقيقي إلها أو الصحيح إلها هو الله 11 سنة و 10
+
+88
+00:07:42,730 --> 00:07:44,170
+فبيسأل السؤال
+
+89
+00:07:53,230 --> 00:07:59,450
+هل التريقة الجديدة بتعطي نتائج إحصائية صحيحة عند
+
+90
+00:07:59,450 --> 00:08:07,250
+مستوى ثقة 95% علما بإن الـ T tabulated 2.776 طبعا
+
+91
+00:08:07,250 --> 00:08:09,910
+لما أقول T tabulated هيك بتطلع على 4 degrees of
+
+92
+00:08:09,910 --> 00:08:15,030
+freedom عند 95% بلاجة 2.776
+
+93
+00:08:16,780 --> 00:08:21,220
+هذه السؤال او بمعنى اخر ممكن انا يعني احاول افهم
+
+94
+00:08:21,220 --> 00:08:24,800
+السؤال بمعنى اخر ممكن اقول هل النتيجة اللي انا
+
+95
+00:08:24,800 --> 00:08:28,950
+حصلت عليها عشرة او تمانية من عشرةبتفرج فرق جوهر
+
+96
+00:08:28,950 --> 00:08:33,510
+يعني 11 7 من 10 بمعنى انه هل السبب في هذا الاختلاف
+
+97
+00:08:33,510 --> 00:08:37,730
+هو سبب عجز في الطريقة او خطأ في الطريقة ولا هو
+
+98
+00:08:37,730 --> 00:08:42,210
+يعني random error ولا هو random error احنا بدنا
+
+99
+00:08:42,210 --> 00:08:47,350
+نثبت اذا كان random error المفروض ان يطلع عندنا ال
+
+100
+00:08:47,350 --> 00:08:51,700
+T Calc اقل من ال T Tabيعني تطلع الطريقة ال
+
+101
+00:08:51,700 --> 00:08:54,420
+character مُتكامف بقتين، بيكون أولا random error،
+
+102
+00:08:54,420 --> 00:08:57,840
+لكن لو ماكانش random error، المفروض T Calc بيطلع
+
+103
+00:08:57,840 --> 00:09:01,420
+أكبر من ال T Tab، بمعنى لا يمكن استخدام الطريقة
+
+104
+00:09:01,420 --> 00:09:04,620
+الجديدة، يعني الفرق مش ناشع عن random error، هذا
+
+105
+00:09:04,620 --> 00:09:09,280
+معنى آخر لفهم المسألة، كويس، بقول أنا اللي بيهمني،
+
+106
+00:09:09,280 --> 00:09:13,800
+بطبق القانونالقانون بيقول plus or minus T بيساوي X
+
+107
+00:09:13,800 --> 00:09:16,640
+bar minus Mu جزر ال N على S إذا plus or minus T
+
+108
+00:09:16,640 --> 00:09:20,720
+بيساوي عشر أو تمانية نخس أحداشر وسبعة جزر الخمسة
+
+109
+00:09:20,720 --> 00:09:25,220
+على سبعة من عشرة اللي هي standard deviation بتطلع
+
+110
+00:09:25,220 --> 00:09:32,740
+عند ال T عبارة عن 2.9 ماهي ال Mu؟ ال Mu هي ال true
+
+111
+00:09:32,740 --> 00:09:39,360
+average ال true average او ال true mean يعني او ال
+
+112
+00:09:39,360 --> 00:09:43,160
+true value ال correct valueالقيمة الصحيحة اللي ..
+
+113
+00:09:43,160 --> 00:09:46,820
+بالظبط يعني اللي في التحليل الموجودة فال T بتطلع
+
+114
+00:09:46,820 --> 00:09:52,560
+92 من 10 طبعا 92 من 10 اللي هي T Calc أكبر من ال T
+
+115
+00:09:52,560 --> 00:09:58,420
+Tab اللي هي 2.776 إذا النتيجة بتقوللي والله إنه
+
+116
+00:09:58,420 --> 00:10:03,520
+هناك فرق إحصائي جوهري بين الطريقتين بمعنى إنه
+
+117
+00:10:03,520 --> 00:10:07,850
+النتيجة 10 أو 8 نتيجة خاطئةالفرق بينها و بين الـ
+
+118
+00:10:07,850 --> 00:10:11,090
+11 و 7 ماعنى مش ناشئ عن Random Error، لأ، في أسباب
+
+119
+00:10:11,090 --> 00:10:15,330
+حقيقية لهذا الحيوان، إن والله الطريقة نفسها خاطئة،
+
+120
+00:10:15,330 --> 00:10:20,450
+الطريقة غير صالحة، بتعطي نتائج أقل من الحقيقة،
+
+121
+00:10:20,450 --> 00:10:24,810
+يعني منخفضة عن الحقيقة، فهذه أول حالة من حالات الـ
+
+122
+00:10:24,810 --> 00:10:30,390
+T-test ابني جي بتطلع عن الحالة التانية للـ T-test
+
+123
+00:10:30,990 --> 00:10:35,710
+بنطلع على comparison between two means وفي هذه
+
+124
+00:10:35,710 --> 00:10:42,390
+الحالة زي ما ذكرت بستخدم طريقة قياسية لتقدير
+
+125
+00:10:42,390 --> 00:10:45,750
+المادة
+
+126
+00:10:45,750 --> 00:10:50,210
+أو الانالايت وبستخدم أيضا طريقة جديدة لتقدير
+
+127
+00:10:50,210 --> 00:10:53,470
+الانالايت وبقارن between two means لو طلعنا على
+
+128
+00:10:53,470 --> 00:10:57,230
+القانون في البداية بدي احاول انه نقتنع مع بعض ان
+
+129
+00:10:57,230 --> 00:11:01,080
+هو نفس القانون اللي استخدمناها سابقاهي ال X bar
+
+130
+00:11:01,080 --> 00:11:03,740
+واحد اللي هي بالطريقة اللي احنا .. الجديدة اللي
+
+131
+00:11:03,740 --> 00:11:08,560
+احنا عملناها كان هنا ميو صح ولا لأ اللي هو ل true
+
+132
+00:11:08,560 --> 00:11:11,400
+بينما ل true ماعندي حاجة true انا .. انا حلتها
+
+133
+00:11:11,400 --> 00:11:15,320
+بطريقة قياسية فبقول X bar لطريقة قياسية بدل ل true
+
+134
+00:11:15,320 --> 00:11:19,220
+صح ولا لأ؟ اذا هذا بدل ل ميو لكن بما ان .. بما ان
+
+135
+00:11:19,220 --> 00:11:23,200
+في عندي two sets of dataففي عندى ال pooled
+
+136
+00:11:23,200 --> 00:11:25,000
+standard deviation، بتجيب ال standard deviation طب
+
+137
+00:11:25,000 --> 00:11:27,740
+لأنه z، للأول ولا للتانى، مادام replicate
+
+138
+00:11:27,740 --> 00:11:31,540
+measurements عملتها بال standard و بال new method،
+
+139
+00:11:31,540 --> 00:11:35,420
+اذا ال S هي عبارة عن ال S P، ال S هي عبارة عن ال
+
+140
+00:11:35,420 --> 00:11:38,960
+pooled standard deviationمول ال N مدام عنده N واحد
+
+141
+00:11:38,960 --> 00:11:42,760
+و N اتنين اذا المحصلة N واحد N اتنين على N واحد
+
+142
+00:11:42,760 --> 00:11:46,580
+زائد N اتنين كله تحت الجزر فيبجى هذا القانون هو
+
+143
+00:11:46,580 --> 00:11:49,720
+نفس القانون اللى احنا استخدمناه سابقا نفس القانون
+
+144
+00:11:49,720 --> 00:11:54,300
+اللى مار معناه في ال confidence limit هو هو تعالوا
+
+145
+00:11:54,300 --> 00:12:02,580
+نطلع على المثال التالفوكمان مرة هذا مثال موجز كان
+
+146
+00:12:02,580 --> 00:12:06,400
+ممكن يعطينا البيانات في جدول و احنا منها نشتق
+
+147
+00:12:06,400 --> 00:12:09,080
+الكلام اللي موجود قدامي نحاول نفهم المثال في
+
+148
+00:12:09,080 --> 00:12:13,920
+البداية بنقول في المثال nickel in a sample was
+
+149
+00:12:13,920 --> 00:12:18,770
+determined using a new procedure wheresix
+
+150
+00:12:18,770 --> 00:12:24,030
+replicate samples resulted in a mean of 19.65%
+
+151
+00:12:24,030 --> 00:12:28,010
+يعني أنا حللت ال nickel في عينة باستخدام طريقة
+
+152
+00:12:28,010 --> 00:12:34,110
+جديدة فأعطتني متوسط 19.65% لما أقول لمتوسط 6 جاروب
+
+153
+00:12:34,110 --> 00:12:37,610
+معناته ممكن أنا أقول والله اه X بقى عارف واحد ممكن
+
+154
+00:12:37,610 --> 00:12:41,350
+أقول والله 6 جاروب هذه يعطيني القيم تبقى 19.45 19
+
+155
+00:12:41,350 --> 00:12:45,200
+.55 19.65تسعة عشر و خمسة و سبعية تسعة عشر و خمسة و
+
+156
+00:12:45,200 --> 00:12:48,880
+تمانية مثلا يعني و أنا أجمعهم و أطلع ال average بس
+
+157
+00:12:48,880 --> 00:12:52,560
+هو now ماعطيني ال average already و من ال average
+
+158
+00:12:52,560 --> 00:12:55,400
+كان بإمكاني .. من ال average و من القيم كان
+
+159
+00:12:55,400 --> 00:12:57,960
+بإمكاني أحسب ال standard deviation و أربق .. و
+
+160
+00:12:57,960 --> 00:13:01,280
+أجيب ال variance لكن هو now برضه ماعطيني قيمة ال
+
+161
+00:13:01,280 --> 00:13:04,560
+variance بيقول لي and a variance يعني مربع ال
+
+162
+00:13:04,560 --> 00:13:08,460
+standard deviation هو عبارة عن point four five two
+
+163
+00:13:08,460 --> 00:13:14,170
+fourبقول five replicate analyses were conducted
+
+164
+00:13:14,170 --> 00:13:19,130
+using a standard procedure طيب عملنا نفس التحليل
+
+165
+00:13:19,130 --> 00:13:27,270
+خمس مرات متتالية باستخدام طريقة قياسية resulting
+
+166
+00:13:27,270 --> 00:13:31,590
+in a mean of 19.24 يبجل ال mean باستخدام الطريقة
+
+167
+00:13:31,590 --> 00:13:36,550
+القياسية كان 19.24% وال variance باستخدام الطريقة
+
+168
+00:13:36,550 --> 00:13:41,700
+القياسية كان 0.105كان نفس الكلام ممكن يقول الحلقة
+
+169
+00:13:41,700 --> 00:13:45,060
+خمس مرات اول مرة تسعة عاشر واحد تاني مرة تسعة عاشر
+
+170
+00:13:45,060 --> 00:13:47,240
+اتنين تالت مرة تسعة عاشر تلاتة تالت مرة تسعة عاشر
+
+171
+00:13:47,240 --> 00:13:50,800
+اربعة مثلا يعني و انا اخد ال average و طلع تسعة
+
+172
+00:13:50,800 --> 00:13:53,880
+عاشر اربعة عشرين و من القيم و ال average ممكن اطلع
+
+173
+00:13:53,880 --> 00:13:56,140
+ال standard deviation و بربعه و بيعطيني ال
+
+174
+00:13:56,140 --> 00:13:59,280
+variance لكن هو معطيني كل هذا الكلام مش بس ايه
+
+175
+00:13:59,280 --> 00:14:04,570
+بيقول if they pull the standard deviationwas point
+
+176
+00:14:04,570 --> 00:14:09,110
+five four six كمان معقين ال S P بتساوي point five
+
+177
+00:14:09,110 --> 00:14:12,870
+four six تعالى بالسؤال if there a significant
+
+178
+00:14:12,870 --> 00:14:16,590
+difference between the two methods هل هناك فرق
+
+179
+00:14:16,590 --> 00:14:21,030
+جوهري بين الطريقتين لاحظوا ما جليش between the
+
+180
+00:14:21,030 --> 00:14:24,390
+precision of the two methods ولا جلي between the
+
+181
+00:14:24,390 --> 00:14:27,210
+variances of the two methods ولا جلي between the
+
+182
+00:14:27,210 --> 00:14:29,470
+results of the two methods جلي between the two
+
+183
+00:14:29,470 --> 00:14:35,120
+methods معناته يجب تطبيق الاختبارينيجب تطبيق
+
+184
+00:14:35,120 --> 00:14:37,860
+الإختبارين، يعني مدين بدي أقول فيه فرق بين
+
+185
+00:14:37,860 --> 00:14:40,380
+الطريقتين أو لأ، بدي أقول في ال precision و أيضا
+
+186
+00:14:40,380 --> 00:14:46,060
+في النتائج، فيجب تطبيق الإختبارين، الآن يا شباب،
+
+187
+00:14:46,060 --> 00:14:48,780
+اللي بدي أطبق الآن هو أطبق في الأول، ال T-test ولا
+
+188
+00:14:48,780 --> 00:14:54,550
+ال F-testبنقول عادة عادة ال if test بمجرد نظر
+
+189
+00:14:54,550 --> 00:14:58,590
+النتائج ال if test أسهل تطبيقه من أي ناحية أسهل
+
+190
+00:14:58,590 --> 00:15:01,470
+لأنه يعني الوصول النتيجة فيه يعني مباشر على طول
+
+191
+00:15:01,470 --> 00:15:05,050
+هذه حاجة الحاجة التانية في احتمال أن ال if test
+
+192
+00:15:05,050 --> 00:15:10,340
+يرسملو رسب ال F-test معناته بنقول اه بحتاجش نعمل
+
+193
+00:15:10,340 --> 00:15:13,520
+ال T بنقول بالله اذا اه هناك فرق بين الطريقتين
+
+194
+00:15:13,520 --> 00:15:16,900
+وانتهى الموضوع او يعني تضيع للوقت ان احسب ال T
+
+195
+00:15:16,900 --> 00:15:20,860
+ممكن ال T ينجح لكن بهمنيش ينجح ولا يرسب مدام رسب
+
+196
+00:15:20,860 --> 00:15:24,960
+واحد فيهم انتهى الموضوع اذا لا يمكن استخدام
+
+197
+00:15:24,960 --> 00:15:28,240
+الطريقة الجديدة او ان هناك فرق جوهري بين الطريقتين
+
+198
+00:15:28,240 --> 00:15:33,000
+فانا بطبق في البداية ال F-test ومن القيم تبعتي
+
+199
+00:15:33,000 --> 00:15:37,750
+بقدر اقول ان ال F-testالـ F بتساوي 0.4524 على 0
+
+200
+00:15:37,750 --> 00:15:44,150
+.105 و لاحظ أنه حطيت الكبير فوق و النتيجة 4.31 لو
+
+201
+00:15:44,150 --> 00:15:47,850
+إجيت أطلعت على ال tabulated if value عند 95%
+
+202
+00:15:47,850 --> 00:15:52,050
+confidence level و 9 degrees of freedom لأنه عندي
+
+203
+00:15:52,050 --> 00:15:58,890
+.. إذا كان بتلاحظ N1 ب6 N2 ب5 هي 11نقص اتنين اللي
+
+204
+00:15:58,890 --> 00:16:03,670
+هو المقام في ال SP ان واحد زاد ان اتنين نقص اتنين
+
+205
+00:16:03,670 --> 00:16:07,070
+هي ال degrees of freedom فبتم عيندي تسعة عيندي نين
+
+206
+00:16:07,070 --> 00:16:11,150
+degrees of freedom لو جيت طلعت تحت عمود ال 95%
+
+207
+00:16:11,150 --> 00:16:16,610
+confidence level بلاحظ ان ال T value 6.26 يبقى ال
+
+208
+00:16:16,610 --> 00:16:24,060
+calculated F value4.31، الـ tabulated 6.26، إذا
+
+209
+00:16:24,060 --> 00:16:27,280
+الـ calculated أقل من الـ tabulated، إذا ليس هناك
+
+210
+00:16:27,280 --> 00:16:32,140
+فرق جوهري، إحصائي جوهري، بين الـ precision أو الـ
+
+211
+00:16:32,140 --> 00:16:34,800
+variances أو الـ standard deviations للـ two
+
+212
+00:16:34,800 --> 00:16:39,240
+methods، بمعنى إن الـ precision comparable، الـ
+
+213
+00:16:39,240 --> 00:16:41,680
+precision، مافيش فرق بينهم من ناحية الـ precision،
+
+214
+00:16:41,680 --> 00:16:46,110
+بتم عند الآن، إذا لازم أطبق الـ T-testلازم اتكلم
+
+215
+00:16:46,110 --> 00:16:49,670
+عن ال T-test و احسب ال T value و اشوف لحظة ان ال T
+
+216
+00:16:49,670 --> 00:16:52,770
+-test يفشل بقدرش اقول انه مافيش فارق بين الطريقتين
+
+217
+00:16:52,770 --> 00:16:57,550
+بدي احسب ال T-test انا عندي لان two sets of data ل
+
+218
+00:16:57,550 --> 00:17:01,330
+replicate measurements اذا معروف انه بدي في الأول
+
+219
+00:17:01,330 --> 00:17:03,810
+احصل على ال mean الأول و احصل على ال mean التاني
+
+220
+00:17:03,810 --> 00:17:08,350
+من ال standard و من ال new اذا لازم اطبق ال T-test
+
+221
+00:17:08,350 --> 00:17:13,420
+لما يكون في عندي comparison between two meansفبقى
+
+222
+00:17:13,420 --> 00:17:16,380
+اطبق القانون القانون بيقول plus or minus T بتساوي
+
+223
+00:17:16,380 --> 00:17:21,480
+ال X bar ال average للأول تسعة عاش خمسة و ستين ال
+
+224
+00:17:21,480 --> 00:17:26,660
+average لل standard تسعة عاش أربعة و عشرين على ال
+
+225
+00:17:26,660 --> 00:17:32,100
+S P point five four six ان واحد بستة ان S ال
+
+226
+00:17:32,100 --> 00:17:36,140
+standard بخمسة يبقى ستة في خمسة على ستة زائد خمسة
+
+227
+00:17:36,140 --> 00:17:40,880
+كله تحت الجزر بتطلع ال T one point two three ال T
+
+228
+00:17:40,880 --> 00:17:47,460
+one point two threeطبعا ال tabulated T value طبعا
+
+229
+00:17:47,460 --> 00:17:51,660
+nine degrees of freedom في الأولى زى ما حكيت هان
+
+230
+00:17:51,660 --> 00:17:57,520
+انا هاد ال F value طبعا اللى هم نعرف ال degrees of
+
+231
+00:17:57,520 --> 00:18:02,020
+freedom اللى هان اللى هى عضارة عن كانت ستة يعنى
+
+232
+00:18:02,020 --> 00:18:05,940
+خمسة بدي اطلع في ال horizon طلعت خمسة هذا كان خمسة
+
+233
+00:18:05,940 --> 00:18:10,800
+بدي اطلع على أربعةفمعنى الكلام بحصل على 6.26 لكن
+
+234
+00:18:10,800 --> 00:18:14,280
+بالنسبة لل T في 9 degrees of freedom يعني هان في
+
+235
+00:18:14,280 --> 00:18:19,160
+البداية ال F بتطلع على New 1 و New 2 متذكرين كيف
+
+236
+00:18:19,160 --> 00:18:23,100
+كنا بنحسب ال F؟ خليني
+
+237
+00:18:29,920 --> 00:18:35,700
+هي ال .. هي ال F احنا عندنا كان عدد ال degrees of
+
+238
+00:18:35,700 --> 00:18:41,800
+freedom عندي خمسة كويس و كان عندي هنا .. هنا كان
+
+239
+00:18:41,800 --> 00:18:48,900
+أربعة لأنه عندي خمسة experiments فهي أربعة وهي
+
+240
+00:18:48,900 --> 00:18:53,200
+مشيت هنا وهي الخمسة هي بيجي 6.26 هذه ال F value
+
+241
+00:18:53,200 --> 00:19:00,720
+كويس بالنسبة لل Tالـ T عندي انا 9 degrees of
+
+242
+00:19:00,720 --> 00:19:10,240
+freedom هيها عندي 95% لأ دي ال F برضه لأ بدي اروح
+
+243
+00:19:10,240 --> 00:19:17,220
+على اليمين اه ممكن هان 9 degrees of freedom فبدأ
+
+244
+00:19:17,220 --> 00:19:23,880
+مش عندي 95 بطلع عندي 2.262 ماشي يا شباب فلازم نعرف
+
+245
+00:19:23,880 --> 00:19:28,810
+نطلع قيمة ال F و قيمة ال T من الجداولفالمهم ال T
+
+246
+00:19:28,810 --> 00:19:36,630
+بيطلع عندى 1.23 أقل من ال 2.26 two معناته كمان ليس
+
+247
+00:19:36,630 --> 00:19:40,550
+هناك فرق أحصائي جوهري بين النتائج اللي بحصل عليها
+
+248
+00:19:40,550 --> 00:19:44,330
+من الطريقتين مدان مافيش فرق أحصائي جوهري بين ال
+
+249
+00:19:44,330 --> 00:19:49,070
+precision و أيضا بين النتائج إذا الجواب النهائي
+
+250
+00:19:49,070 --> 00:19:55,380
+ليس هناك فرقإحصائي جوهري بين الطريقتين بمعنى أخر
+
+251
+00:19:55,380 --> 00:19:58,920
+يمكن استخدام الطريقة الجديدة عوضا عن أو بدلا عن
+
+252
+00:19:58,920 --> 00:20:04,980
+الطريقة القياسية بدون أخطأ كل عشان ال F أبارعا
+
+253
+00:20:04,980 --> 00:20:08,860
+يعني لو طلعت عليه قانون صغير أه لكن لو فشل بيكون
+
+254
+00:20:08,860 --> 00:20:15,040
+من نصيبك تطرش تطبق ال T أه بدام هذا نجح إذا لازم
+
+255
+00:20:15,040 --> 00:20:19,710
+أطبق اللي بعدهو ممكن تبرده هو نقطة الشيء؟ لأ واحد
+
+256
+00:20:19,710 --> 00:20:23,450
+ال F بيعطي هل هناك فرق أحصائي جوهري بين ال
+
+257
+00:20:23,450 --> 00:20:27,210
+precision و التاني بيعطي .. بتكلم عن النتائج
+
+258
+00:20:27,210 --> 00:20:32,790
+بالظبط .. بالظبط .. بالظبط .. بالظبط أستاذ ممكن
+
+259
+00:20:32,790 --> 00:20:37,530
+أنا طالع أقول ال summer debate بالمدينة الصينية؟
+
+260
+00:20:37,530 --> 00:20:43,150
+هو أنت بتقدر يعني .. بتقدر بشكل أو بآخر بتقدر يعني
+
+261
+00:20:44,530 --> 00:20:49,390
+لأ هو مش هيك يعني هو يعني غالبا إذا كان أعطاك ال
+
+262
+00:20:49,390 --> 00:20:53,170
+data points كلها بتقدر تعمل ال SP بس غالبا بتضطرش
+
+263
+00:20:53,170 --> 00:20:56,670
+أنت تطلع ال SP من ال variances لكن in principle
+
+264
+00:20:56,670 --> 00:21:03,110
+يعني ممكن .. ممكن أعطونا ال F tabulated بس
+
+265
+00:21:03,110 --> 00:21:09,310
+احنا بقدر نطلعه طلعناه فارجيتك كيف تطلعه هى يا
+
+266
+00:21:09,310 --> 00:21:09,770
+حبيبي
+
+267
+00:21:13,570 --> 00:21:21,190
+هو إيش جلنا؟ جلنا إنه اعملنا .. اعملنا التجربة ست
+
+268
+00:21:21,190 --> 00:21:25,070
+مرات .. هاد اللي فوق اللي كانت ال S1 تربيك .. ست
+
+269
+00:21:25,070 --> 00:21:29,450
+مرات فمعناته خمسة degrees of freedom إذا هاي خمسة
+
+270
+00:21:29,450 --> 00:21:34,930
+degrees of freedom وعملنا هذه جال أربع مرات يعني
+
+271
+00:21:34,930 --> 00:21:38,050
+.. خمس مرات جال هو يعني أربع .. أربع degrees of
+
+272
+00:21:38,050 --> 00:21:40,850
+freedom فمشينا هاي الخمسة و هاي الأربع هان بال ..
+
+273
+00:21:40,850 --> 00:21:41,650
+بالتيجيو
+
+274
+00:21:44,270 --> 00:21:50,030
+6.26 بالظبط فهيو زي هيك بنطلعه زي ما اتعلمنا الحص
+
+275
+00:21:50,030 --> 00:21:55,710
+الماضي برضه نعم هذا ال degree of freedom من فوق و
+
+276
+00:21:55,710 --> 00:22:01,750
+من الجانب برضه نفس الكلام طيب يا شباب نتكلم عن آخر
+
+277
+00:22:01,750 --> 00:22:06,170
+نوع من أنواع ال stand اللي عفوا ال T test اللي هو
+
+278
+00:22:06,170 --> 00:22:10,060
+ال T test with multiple samplesفبنقول with
+
+279
+00:22:10,060 --> 00:22:13,340
+multiple samples شوفنا القانون تبعه plus or minus
+
+280
+00:22:13,340 --> 00:22:17,080
+T بتسوي ال D bar جزر ال N على S دي او لسان
+
+281
+00:22:17,080 --> 00:22:21,840
+deviation of the difference خلينا نتطلع على مثال
+
+282
+00:22:21,840 --> 00:22:25,780
+مر معنى قبل هيك مثال مر معنى قبل هيك لما نكون عندى
+
+283
+00:22:25,780 --> 00:22:28,780
+multiple samples زى الحالة اللى قدامى بنقول
+
+284
+00:22:28,780 --> 00:22:32,840
+mercury in multiple samples was determined using a
+
+285
+00:22:32,840 --> 00:22:36,950
+standard method and a new suggested methodتم
+
+286
+00:22:36,950 --> 00:22:42,910
+تحليله باستخدام طريقة قياسية وطريقة جديدة مقترحة
+
+287
+00:22:42,910 --> 00:22:47,430
+فبقول six different samples عينات إشمالة مش
+
+288
+00:22:47,430 --> 00:22:52,450
+replicate different samples were analyzed using
+
+289
+00:22:52,450 --> 00:22:55,270
+the two procedures giving the following results in
+
+290
+00:22:55,270 --> 00:22:58,730
+PPM فنتطلع على هذه الأشكال مرمى عن هذا المثال
+
+291
+00:22:58,730 --> 00:23:02,890
+بالظبط هو هوفالعينة الأولى كانت عشرة و تلاتة
+
+292
+00:23:02,890 --> 00:23:06,890
+بالجديدة عشرة و نص بالقياسية العينة التانية اتناشر
+
+293
+00:23:06,890 --> 00:23:09,970
+سبعة بالجديدة اتناشر ستة بالقياسية الى اخرية بسأل
+
+294
+00:23:09,970 --> 00:23:14,070
+سؤال بيقول find the standard deviation of the
+
+295
+00:23:14,070 --> 00:23:17,810
+difference بده ال SD حلو احنا حلناها قبل هيك و
+
+296
+00:23:17,810 --> 00:23:21,590
+طلعنا قيمة ال SD لكن بنعمله كمان مرة بيقول if the
+
+297
+00:23:21,590 --> 00:23:25,250
+two methods have comparable precision إذا كانت two
+
+298
+00:23:25,250 --> 00:23:29,210
+methods ال precision تبعتهم يعني متكافئة متقاربة
+
+299
+00:23:30,460 --> 00:23:33,520
+فبسأل find whether there is any significant
+
+300
+00:23:33,520 --> 00:23:36,040
+difference between the results of the two methods
+
+301
+00:23:36,040 --> 00:23:41,420
+at the 95% confidence level فهل هناك فرق في نتائج
+
+302
+00:23:41,420 --> 00:23:47,390
+الطريقتين عند مستوى الثقة 95%؟بنعطيك ال tabulated
+
+303
+00:23:47,390 --> 00:23:52,130
+T جالب تساوية عند 95% confidence level جالب تساوية
+
+304
+00:23:52,130 --> 00:23:57,450
+2.571 بدنا نحسب في البداية ال S D شوفنا كيف نحسبها
+
+305
+00:23:57,450 --> 00:24:01,450
+بنقول بنطلع ال D I للأولى D I للتانية التالتة
+
+306
+00:24:01,450 --> 00:24:05,010
+الرابعة الخمسة السادسة بنجمعهم summation D I و
+
+307
+00:24:05,010 --> 00:24:10,310
+بنجسبهم على 6 بيطلع ال D bar تلاتة من عشرة، كويس؟
+
+308
+00:24:10,790 --> 00:24:15,210
+هي الـ D bar طبعا بنجيب ال D I minus ال D bar
+
+309
+00:24:15,210 --> 00:24:19,810
+squared ال summation لإلهم بتعطيلنا point seven
+
+310
+00:24:19,810 --> 00:24:24,650
+six بنطلع ال S D point seven six على ستة ناقص واحد
+
+311
+00:24:24,650 --> 00:24:29,390
+ستة جارب ناقص واحد يعني خمسة تحت الجزر بيعطينا
+
+312
+00:24:29,390 --> 00:24:33,270
+point three nine طيب بنيجي بنطبق القانون عشان أجيب
+
+313
+00:24:33,270 --> 00:24:36,450
+ال T ال T إيش بتساوي plus or minus D بتساوي ال D
+
+314
+00:24:36,450 --> 00:24:41,610
+bar اللي هي تلاتة من عشرة في جزر ال Nعلى ال SD 0
+
+315
+00:24:41,610 --> 00:24:48,370
+.39 فطلع ال T 1.88 لو جينا نقارنها ال 2.571 اللي
+
+316
+00:24:48,370 --> 00:24:54,050
+ماعطيها الليه بلاحظ أنه ال T calculated أقل من ال
+
+317
+00:24:54,050 --> 00:25:00,890
+T tabulated بمعنى أخر لا يوجد فرق جوهر بين النتائج
+
+318
+00:25:00,890 --> 00:25:04,370
+اللي بحصل عليها من الطريقتين يعني الطريقة الجديدة
+
+319
+00:25:04,370 --> 00:25:09,510
+يمكن استخدامها عيوظا عن الطريقة القياسية
+
+320
+00:25:15,930 --> 00:25:19,890
+الـ true mean يعني مالوش دعوة لـ true mean أو للـ
+
+321
+00:25:19,890 --> 00:25:21,910
+standard method في هذا الكلام، هذا مالوش دعوة
+
+322
+00:25:21,910 --> 00:25:28,230
+نهائيا، هذا بيعطيك يعني لـ true mean بيعطيك أن
+
+323
+00:25:28,230 --> 00:25:31,870
+عندك replicate measurements أنت عاملها، لكن عندك
+
+324
+00:25:31,870 --> 00:25:34,330
+القراءة الحقيقية معروفة أو النتيجة الحقيقية
+
+325
+00:25:34,330 --> 00:25:39,730
+معروفة، لا ينطبق على هذا الكلام، ال SP بتستخدم نفس
+
+326
+00:25:39,730 --> 00:25:43,020
+النوع من العين، نفس العينةأكتر من مرة بالقياسية
+
+327
+00:25:43,020 --> 00:25:45,860
+أكتر من مرة بالجديدة فالملوش دعوة بهذا الكلام
+
+328
+00:25:45,860 --> 00:25:49,180
+اتكلم عن multiple samples عينات كل عينة مختلفة عن
+
+329
+00:25:49,180 --> 00:25:51,980
+الأخرى عشان هيك لو طلعت على النتائج كمان بتلاحظ
+
+330
+00:25:51,980 --> 00:25:55,700
+النتائج متفاوت فيها نوع من التفاوت لكن زي ما ذكرت
+
+331
+00:25:55,700 --> 00:26:00,220
+سابقا يجب ان عد النتائج في القياسية تكون مساوي لعد
+
+332
+00:26:00,220 --> 00:26:04,380
+النتائج في الجديدة لأنك انت بتعمل التجربة نفسها
+
+333
+00:26:04,380 --> 00:26:07,980
+بالقياسية بعدين بالجديدة وبالتالي لازم يكون عد
+
+334
+00:26:07,980 --> 00:26:16,400
+النتائج متساوي طيب يا شباب نطلع علىاختبار جديد انت
+
+335
+00:26:16,400 --> 00:26:23,800
+يعني بتعمل تحليل ل ال mercury في عيناه فلاجته
+
+336
+00:26:23,800 --> 00:26:35,600
+بيساوي 11.1 PPM 11.2 PPM 11.1 PPM 11.3 PPM 16.5
+
+337
+00:26:35,600 --> 00:26:42,340
+PPMبتقول طب أنا كل نتائجي كانت 11 11 11 11 ايش
+
+338
+00:26:42,340 --> 00:26:47,780
+معنى هذه النتيجة 16؟ هل النتيجة 16 نتيجة مقبولة
+
+339
+00:26:47,780 --> 00:26:51,240
+ولا يجب استبعادها؟
+
+340
+00:26:51,240 --> 00:26:56,020
+يجب استبعادها طب لو كانت 15 طب لو كانت 13
+
+341
+00:26:56,020 --> 00:27:01,320
+نستبعيدها ولا نخليها؟ طب لو كانت 12
+
+342
+00:27:04,740 --> 00:27:08,280
+يعني بعدين هنقول ممكن هو الواحد يعني أنا بجاوب عنك
+
+343
+00:27:08,280 --> 00:27:13,920
+بقول أنه أنت استخدمت شعورك يعني الشخصي في الحكم
+
+344
+00:27:13,920 --> 00:27:19,200
+على يعني قضية علمية قضية الاستباعد أستبعد أو لأ
+
+345
+00:27:19,200 --> 00:27:23,600
+لها قوانينبنقدرش احنا نستخدم شعورنا الشخصي في
+
+346
+00:27:23,600 --> 00:27:27,240
+الحكم على أشياء بتحكمها قوانين شعورك الشخصي
+
+347
+00:27:27,240 --> 00:27:31,420
+بتستخدمهم يعني .. يعني لو واحد جالك والله يعني
+
+348
+00:27:31,420 --> 00:27:34,980
+كافل جو اليوم تقوله والله حر كتير واحد تاني بيقولك
+
+349
+00:27:34,980 --> 00:27:38,420
+لا والله حلو مثلا هذا شعور شخصي يعنيممكن تفوت فيه،
+
+350
+00:27:38,420 --> 00:27:41,180
+وممكن زميل برضه زميلك يقولك والله لأ أنا بدي
+
+351
+00:27:41,180 --> 00:27:44,740
+أخليها، حسب شعوبه الشخص هو يعني، زي ما كنا بنقول
+
+352
+00:27:44,740 --> 00:27:46,780
+في الـSignificant Figure في البداية اللي ما نتعلم،
+
+353
+00:27:46,780 --> 00:27:49,700
+كنا بنقول نسيب رقم عشر، واحد، ولا اتنين، ولا
+
+354
+00:27:49,700 --> 00:27:52,620
+تلاتة، ولا اربعة، ولا خمسة، ولا نسيب الكل اللي
+
+355
+00:27:52,620 --> 00:27:56,060
+بيطلع في الآية الحاسبةيعني كل واحد لو بدأ نتركه
+
+356
+00:27:56,060 --> 00:27:59,960
+حسب شعوره كان اللي جيناه يعني فيه عندنا تمايز بين
+
+357
+00:27:59,960 --> 00:28:06,200
+الطلاب أو بين الناس وكله غلط لأنه احنا فيه عندنا
+
+358
+00:28:06,200 --> 00:28:12,360
+قوانين بنحكم فيها على أكم عدد نخلي مثلا على يمين
+
+359
+00:28:12,360 --> 00:28:15,260
+العلامة العشرية على سن مثال لأن هذا له دعوة بالدقة
+
+360
+00:28:15,260 --> 00:28:18,320
+له دعوة بإدارة القياس له دعوة بعدد السجن والفجرز
+
+361
+00:28:18,320 --> 00:28:22,020
+اللي حسب القوان اللي اتعلمناهافنفس الكلام لنتيجة
+
+362
+00:28:22,020 --> 00:28:27,020
+تطلع انت نتائج ويطلع منهم نتائج او نتيجة تبدو شاذة
+
+363
+00:28:27,020 --> 00:28:33,520
+فهل نستبعد النتيجة اللي تبدو شاذة ولا نحتفظ فيها
+
+364
+00:28:33,520 --> 00:28:38,620
+بنقول بدنا نطبق ال Q rejection test بدنا نطبق ال Q
+
+365
+00:28:38,620 --> 00:28:40,900
+rejection test ايش هو ال Q rejection test ده اللي
+
+366
+00:28:40,900 --> 00:28:48,690
+والله ال Q بتساوي A على W حيث ايههو الفرق بين
+
+367
+00:28:48,690 --> 00:28:53,550
+النتيجة الشاذة حسب وجهة نظرات وأقرب نتيجة إلها
+
+368
+00:28:56,270 --> 00:29:01,590
+و ال W جال النتيجة الشاذة و أبعد نتيجة عنها عشان
+
+369
+00:29:01,590 --> 00:29:06,410
+هيك بالضرورة دائما ال Q كثر لأنه دائما ال نتيجة A
+
+370
+00:29:06,410 --> 00:29:10,370
+اللي هي في البصد النتيجة الشاذة الفرق ما بينها و
+
+371
+00:29:10,370 --> 00:29:14,850
+ما بين أقرب نتيجة إلها قليل بينما المقام النتيجة
+
+372
+00:29:14,850 --> 00:29:19,430
+الشاذة و أبعد نتيجة عنها كبير فبالضرورة ال Q دائما
+
+373
+00:29:19,430 --> 00:29:24,090
+لازم تكون أقل من واحد عكس ال Fالـ Q لازم يكون ..
+
+374
+00:29:24,090 --> 00:29:27,850
+اعملت أكتر من واحد ما سألت غلط انتهى خلاص يعني كل
+
+375
+00:29:27,850 --> 00:29:31,050
+إجابة غلط ماحدش يقول اللي والله هين كاتب القانون
+
+376
+00:29:31,050 --> 00:29:36,130
+صح هين مثلا .. لا ماصبتش احنا
+
+377
+00:29:36,130 --> 00:29:42,410
+يا شباب عادة إيش بنسوي؟ بنجيب قيمة الـ Q المحسوبة
+
+378
+00:29:42,410 --> 00:29:48,250
+حسابا يعني وبنقارنها بـ Q المجدولة في عندنا جداول
+
+379
+00:29:48,250 --> 00:29:52,660
+الـ Q نعم زي ال F و زي ال T في عندنا Q tablesالـ Q
+
+380
+00:29:52,660 --> 00:30:03,520
+-table عند 90% و95% و99% و99.9% و99.9% و99.9% و99
+
+381
+00:30:03,520 --> 00:30:05,300
+.9% و99.9% و99.9% و99.9% و99.9% و99.9% و99.9% و99
+
+382
+00:30:05,300 --> 00:30:05,900
+.9% و99.9% و99.9% و99.9% و99.9% و99.9% و99.9% و99
+
+383
+00:30:05,900 --> 00:30:06,100
+.9% و99.9% و99.9% و99.9% و99.9% و99.9% و99.9% و99
+
+384
+00:30:06,100 --> 00:30:06,440
+.9% و99.9% و99.9% و99.9% و99.9% و99.9% و99.9% و99
+
+385
+00:30:06,440 --> 00:30:10,360
+.9% و99.9% و99.9% و99.9%
+
+386
+00:30:17,710 --> 00:30:22,390
+على نقيب ال F تابل وال T تابل اللي شفناها سابقا
+
+387
+00:30:22,390 --> 00:30:29,290
+هان بنتكلم عن number of observations عدد النتائج
+
+388
+00:30:29,290 --> 00:30:32,550
+مش ال degrees of freedom في ال F و ال T إيش كنا
+
+389
+00:30:32,550 --> 00:30:35,950
+بنقول degrees of freedom لكن في ال Q إيش بنقول
+
+390
+00:30:35,950 --> 00:30:40,590
+number of observations أو number of results كويس
+
+391
+00:30:40,590 --> 00:30:44,730
+number of data points كلهامش ال degrees of freedom
+
+392
+00:30:44,730 --> 00:30:49,270
+فانا بده اشتغل عند ال 95% عادة فبشوف الله كم تجربة
+
+393
+00:30:49,270 --> 00:30:53,030
+عملت اذا بقرا ال Q على طول مثلا عملت تمام تجارب
+
+394
+00:30:53,030 --> 00:31:00,270
+اذا ال Q 0.526 مفهومة تمام تجارب يبقى 0.526 عملت
+
+395
+00:31:00,270 --> 00:31:06,900
+تلاتين تجربة اذا عند 95% 0.298 و هكذاطيب نحاول
+
+396
+00:31:06,900 --> 00:31:12,660
+نشوف مثال نتعلم فيه كيف نحكم على value معينة إذا
+
+397
+00:31:12,660 --> 00:31:17,680
+ما كان يجب استبعادها أو الاحتفاظ فيهافخليني أطلع
+
+398
+00:31:17,680 --> 00:31:21,200
+على التجربة التالية بيقول in the replicate
+
+399
+00:31:21,200 --> 00:31:26,900
+determination of gold في عندي تجربة بقدر فيها
+
+400
+00:31:26,900 --> 00:31:35,760
+الدهب في عيناه فلجأته 96% 99% 97% 94% 100% 95% و
+
+401
+00:31:35,760 --> 00:31:41,000
+72% بنيجي نطلع على 72% و نقول يا ربي هذا القراية
+
+402
+00:31:41,000 --> 00:31:47,790
+إيش مالها قد تبدو يعني شاذة طب نخليها ولا ..هو
+
+403
+00:31:47,790 --> 00:31:51,390
+بيقول اتشيك whether any point should be excluded
+
+404
+00:31:51,390 --> 00:31:54,990
+at the 95% confidence level ولا لأ يعني اذا كنت
+
+405
+00:31:54,990 --> 00:32:01,270
+تشتغل على مستوى ثقة 95% فهل يمكن استبعاد اي نتيجة
+
+406
+00:32:01,270 --> 00:32:06,950
+من نتائج المذكورةإذا كان الـ tabulated Q 95%
+
+407
+00:32:06,950 --> 00:32:11,670
+confidence level بالساعة 0.568 for 7 observations
+
+408
+00:32:11,670 --> 00:32:15,330
+المفروض أن هي لـ 7 observations اللي شفناها غير في
+
+409
+00:32:15,330 --> 00:32:18,810
+الجدول ما علينا، بس على أساس أن هذا القيمة اللي
+
+410
+00:32:18,810 --> 00:32:24,950
+معطق معانا يعنيفإيش بنقول؟ بدنا نجرب على هذا
+
+411
+00:32:24,950 --> 00:32:28,430
+السؤال، إيش بنعمل يا شباب، يا طيبين، يا محترمين؟
+
+412
+00:32:28,430 --> 00:32:33,110
+بنقول أول شغل بنعملها، بنرتب النتائج تبعتنا ترتيب،
+
+413
+00:32:33,110 --> 00:32:37,650
+تصعدي أو تنازلي، ممنوع إنك تشتغل على نتائج زي ما
+
+414
+00:32:37,650 --> 00:32:42,650
+هو بعطيها لك، لأ، بدك ترتبها يا تصعدي، يا تنازلي،
+
+415
+00:32:42,650 --> 00:32:46,720
+فبتصفي نتيجة الشاشة، يا في الأول، يا في الآخرمعايا
+
+416
+00:32:46,720 --> 00:32:51,100
+مش في النص، يا في الأول يا في الآخر طيب، الان
+
+417
+00:32:51,100 --> 00:32:57,440
+رطبناهم 72, 94, 95, 96, 97, 99 و100 بقول بدي أجيب
+
+418
+00:32:57,440 --> 00:33:03,260
+ال A، ال A قال و الله هيهم، الفرق 94 ناقص 72 طب ال
+
+419
+00:33:03,260 --> 00:33:10,780
+W 100 ناقص 72، لو عملناها بيطلع عندي 0.79الـ A هين
+
+420
+00:33:10,780 --> 00:33:13,960
+عمال بقولك الـ A الفرق بين نتيجة الشاذة و أقرب
+
+421
+00:33:13,960 --> 00:33:19,020
+نتيجة إلها و ال W هي الفرق بين نتيجة الشاذة و أبعد
+
+422
+00:33:19,020 --> 00:33:23,680
+نتيجة عنها تفضل فكانت نتيجة الشاذة أكبر من نتيجة
+
+423
+00:33:23,680 --> 00:33:28,720
+الشاذة هي هي نفس الكلام أقرب
+
+424
+00:33:28,720 --> 00:33:31,240
+إلها هي نفس الكلام أقرب نتيجة إلها و أبعد نتيجة
+
+425
+00:33:31,240 --> 00:33:38,940
+عنها في المهم في النهاية موجبة يعنيأكبر من Q tab
+
+426
+00:33:38,940 --> 00:33:45,580
+إذا النتيجة 72% يجب استبعدها لأنها مش ناشئة بمعنى
+
+427
+00:33:45,580 --> 00:33:49,300
+آخر مش ناشئة عن random error لأ في عندك مشكلة
+
+428
+00:33:49,300 --> 00:33:52,720
+أساسية في التجربة اللي انت عملتها يعني التجربة
+
+429
+00:33:52,720 --> 00:33:55,180
+ماعطتك هذه النتيجة نتيجة random error يعني خطأ
+
+430
+00:33:55,180 --> 00:34:03,060
+طبيعي لأ والله في عندك خطأ يعني أساسي طب نيجي نغير
+
+431
+00:34:03,060 --> 00:34:13,540
+تغيير بسيط كتيربدل الـ 72 في عندى 88% برده بنرتب
+
+432
+00:34:13,540 --> 00:34:22,060
+ترتيب ايه تصعدي او تنازلي فبنقول 88,94,95,96,97,99
+
+433
+00:34:22,060 --> 00:34:31,900
+,100 بنجي بنقول a 94-88 على w 100-88 فبتطلع عندى
+
+434
+00:34:31,900 --> 00:34:37,470
+ال Q Calc 0.5طبعا الـ Q Calculate الـ 0.5 أقل من
+
+435
+00:34:37,470 --> 00:34:43,570
+الـ Q Tab معناه الكلام النقطة أو ال data point أو
+
+436
+00:34:43,570 --> 00:34:50,210
+النتيجة 88% لا يمكن استبعدها أنا بأنصح .. أنا
+
+437
+00:34:50,210 --> 00:34:54,270
+بأنصح .. يعني أنا مانعش أطلع على 88 أنا شخصيا يعني
+
+438
+00:34:54,270 --> 00:34:57,690
+لو بستخدم شعور البشر يعني بقول والله أنا بدي
+
+439
+00:34:57,690 --> 00:35:01,350
+أستبعدها لكن مستبعدهاش هيك لما يكون في عندي عدد
+
+440
+00:35:01,350 --> 00:35:08,460
+نتائج قليلأنا بفضل أنه أعمل تجارب أخرى، أعملي كمان
+
+441
+00:35:08,460 --> 00:35:17,620
+تربع تجارب علشان بس أكون أنا متأكد أكتر يعنى ما
+
+442
+00:35:17,620 --> 00:35:22,420
+هي ال Q كانت أصغر هذه عشان هيك خليتها
+
+443
+00:35:31,170 --> 00:35:40,090
+طيب يا شباب خليني أتكلم عن يعني موضوع أخر بتتكلم
+
+444
+00:35:40,090 --> 00:35:44,850
+عن ال linear least squares الآن احنا و احنا في
+
+445
+00:35:44,850 --> 00:35:52,850
+المختبر بنعمل قياسات بنعمل قياساتالقياسات هذه عادة
+
+446
+00:35:52,850 --> 00:35:58,650
+يعني ممكن نرسمها على اي graph خط مستقيم معادلة خط
+
+447
+00:35:58,650 --> 00:36:03,310
+مستقيم او خط مستقيم فالخط المستقيم بنحاول انه يمر
+
+448
+00:36:03,310 --> 00:36:08,020
+بالنقاط اللي انا حصلت عليهالو كانت النقاط
+
+449
+00:36:08,020 --> 00:36:10,740
+scattered يعني منتشرة شوية مش على الخط بالظبط
+
+450
+00:36:10,740 --> 00:36:17,740
+فبحاول ان ارسم الخط بحيث انه يمرأ بمعظم النقاط او
+
+451
+00:36:17,740 --> 00:36:21,920
+انه يعني عدد النقاط اللي اعلى تكون عدد النقاط اللي
+
+452
+00:36:21,920 --> 00:36:27,040
+اقل و انه يمر تقريبا بينهم في النص يعني لكن يا
+
+453
+00:36:27,040 --> 00:36:31,000
+شباب من ناحية عملية لو قلنالكم والله اه هي النقاط
+
+454
+00:36:31,000 --> 00:36:34,640
+و ارسم الخط هذا تأكدوا ان مافيش واحد فيكم راح يرضع
+
+455
+00:36:34,640 --> 00:36:38,910
+عن رسمة زميلهيقولوا بس لو انك شديته هذا لفوق شوية
+
+456
+00:36:38,910 --> 00:36:43,530
+من هنا، مش جاي في النص بزوله شدته لتحت شوية، لو
+
+457
+00:36:43,530 --> 00:36:47,550
+يعني نجلته كله لفوق، لو غيرت ال slope تبعه ..
+
+458
+00:36:47,550 --> 00:36:51,970
+المهم فيش حد هيرضى بعمل غيره، ليش؟ لأنه برضه هذا
+
+459
+00:36:51,970 --> 00:36:55,770
+شعور شخصي أنه والله خط يمر بين النقاط، أنا والله
+
+460
+00:36:55,770 --> 00:37:00,010
+شايفه هذا الخط كويس، غيري مش شايفه خط كويس، بنقدرش
+
+461
+00:37:00,010 --> 00:37:01,510
+نحكم على الأمور بشكل 100%
+
+462
+00:37:04,380 --> 00:37:07,860
+هنا في الحقيقة بتحصل عندي مشكلة لأن لو قلتلكم
+
+463
+00:37:07,860 --> 00:37:14,520
+بالله لو سمحتوا كل واحد يجيبلي نتيجة قياس مثلا لو
+
+464
+00:37:14,520 --> 00:37:17,440
+اعطيتكم انا نقطة على ال y axis و نقطة على ال x
+
+465
+00:37:17,440 --> 00:37:21,300
+شوفوني هيجي اداش كل واحد فيكم هيعطيني نتيجة مختلفة
+
+466
+00:37:21,300 --> 00:37:23,340
+عشان ايك احنا في الكيمة التحليلية في الحقيقة
+
+467
+00:37:23,340 --> 00:37:28,440
+بنهتمش كتير برسم الخط المستقيم بهمليش ان الخط يرسم
+
+468
+00:37:28,440 --> 00:37:32,140
+و اشوف والله بالظبط شكله منيح ولا لأهو ايش اللي
+
+469
+00:37:32,140 --> 00:37:37,720
+بهمني اللي بهمني ان اوجد معادلة الخط المستقيم اوجد
+
+470
+00:37:37,720 --> 00:37:41,680
+معادلة الخط المستقيم لانه لو انا عرفت معادلة الخط
+
+471
+00:37:41,680 --> 00:37:46,280
+المستقيم و اعطيتك النقطة Y و قلتلك هاتلي X كلكم
+
+472
+00:37:46,280 --> 00:37:50,640
+هتطلعوا نفس النتيجة صح ولا لأ فاحنا بدنا نتعلم كيف
+
+473
+00:37:51,640 --> 00:37:56,840
+نوجد معادلة الخط المستقيم كيف نوجد معادلة الخط
+
+474
+00:37:56,840 --> 00:38:00,140
+المستقيم لأنه إذا أوجدنا معادلة الخط المستقيم
+
+475
+00:38:00,140 --> 00:38:06,840
+انتهى صار في عنا قدرة على عمل
+
+476
+00:38:06,840 --> 00:38:11,840
+report للنتائج بشكل دقيق جدا و الكل متفق عليه
+
+477
+00:38:11,840 --> 00:38:17,030
+مافيش حاجة بيقول لأطيب كيف ممكن نوجد معادلة الخط
+
+478
+00:38:17,030 --> 00:38:20,710
+المستقيم؟ في طريقة في الحقيقة بنقولها linear least
+
+479
+00:38:20,710 --> 00:38:24,170
+squares انا ممكن يعني افهمها لكم يعني ببساطة
+
+480
+00:38:24,170 --> 00:38:30,550
+كالتالي في عندي نقطة هيكم شايفينها المركز تبعها
+
+481
+00:38:30,550 --> 00:38:35,690
+فوق مركز الخط بشوية في عندي نقطة تانية واضح انه
+
+482
+00:38:35,690 --> 00:38:43,710
+بعيد اعلى من الخط صحيح؟ طيب هذه النقطةتحت الخط و
+
+483
+00:38:43,710 --> 00:38:48,090
+في مسافة واسعة و النقطة اللى فوق تحت الخط من مركز
+
+484
+00:38:48,090 --> 00:38:51,150
+الخط في مسافة تعالوا في ال linear least squares
+
+485
+00:38:51,150 --> 00:38:56,850
+method ايش بنسوي مربع المسافة من مركز النقطة لمركز
+
+486
+00:38:56,850 --> 00:39:01,530
+الخط كويس و مربع المسافة خلينا ناخد النقاط اللى
+
+487
+00:39:01,530 --> 00:39:07,630
+تحت و مربع المسافة النقطة اللى بقي ده فوقمن مركز
+
+488
+00:39:07,630 --> 00:39:12,530
+النقطة لمركز الخط لو بده اخلي مربعات المسافة هذه
+
+489
+00:39:12,530 --> 00:39:18,990
+اقل ما يمكن ايش الخط بده يحصله؟ هينزلت هينشد لتحت
+
+490
+00:39:18,990 --> 00:39:25,350
+مظبوط لحظة شوية المهم روح ينزل لوين لتحت طيب بنفس
+
+491
+00:39:25,350 --> 00:39:30,570
+الطريقة لو انا قلت بده اخلي مربع المسافة بين
+
+492
+00:39:30,570 --> 00:39:35,220
+النقطة هذه ومركز الخط و النقطة هذه ومركز الخطأقل
+
+493
+00:39:35,220 --> 00:39:40,580
+ما يمكن، بدي يرتفع لفوق، طب لو أنا خليت الآن مربع
+
+494
+00:39:40,580 --> 00:39:43,680
+المسافات هذه اللي فوق و اللي تحت أقل ما يمكن، من
+
+495
+00:39:43,680 --> 00:39:47,800
+وين الخط بدي يمشي؟ بدي يمشي بينهم بالـ .. يعني
+
+496
+00:39:47,800 --> 00:39:52,000
+عشان بيمشي الطريقة بحيث انه يخلي مربعات المسافات
+
+497
+00:39:52,000 --> 00:39:56,180
+هذه أشمالها أقل ما يمكن، وبالتالي بيمشي صح 100%
+
+498
+00:39:56,180 --> 00:40:02,680
+علشان هيك، هذا بيعطيني يعني معادلة أكيد صح، بشكل
+
+499
+00:40:02,680 --> 00:40:08,980
+100%كيف أنا بستفيد من هذا الكلام؟اللي هي ال
+
+500
+00:40:08,980 --> 00:40:12,040
+squares بتقولي والله هو عندي انا اصلا ال y بتساوي
+
+501
+00:40:12,040 --> 00:40:15,460
+mx زائد b هذه معادلة خط المستقيم حيث ال y هي
+
+502
+00:40:15,460 --> 00:40:20,440
+النقطة على ال y axis و ال m هي ال slope و ال x هي
+
+503
+00:40:20,440 --> 00:40:25,040
+عادة ال concentration او ال x axis ال x axis عادة
+
+504
+00:40:25,040 --> 00:40:28,580
+عندي انا ال concentration الترقيز و ال b هي ال
+
+505
+00:40:28,580 --> 00:40:31,720
+intercept اللي هي لو اجهنا لوراها ده هو هذه
+
+506
+00:40:31,720 --> 00:40:37,100
+المسافة يعني التقاطع التقاطع ال y axis مع ال
+
+507
+00:40:37,100 --> 00:40:42,340
+straight lineبنقول عشان نحصل على هذه المعادلة لأي
+
+508
+00:40:42,340 --> 00:40:47,000
+خط مستقيم عشان أحصل على معادلة الخط المستقيم باجي
+
+509
+00:40:47,000 --> 00:40:51,500
+بجيب ال slope في البداية ال slope اول خطوة ان اجيب
+
+510
+00:40:51,500 --> 00:40:56,300
+ايه ال slope ال slope اللي هي ال M بيساوي نفتح جوس
+
+511
+00:40:56,300 --> 00:41:03,430
+summation X1 في Y1 زاد X2 في Y2زاد X تلاتة في Y
+
+512
+00:41:03,430 --> 00:41:08,390
+تلاتة زاد X أربعة في Y أربعة أنا عندي Y وعندي X
+
+513
+00:41:08,390 --> 00:41:13,170
+عددهم متساوى كل لقطة XY فيها كويس يعني كل تركيز
+
+514
+00:41:13,170 --> 00:41:16,250
+فيه إله signal كل تركيز بجيسه إله signal كل تركيز
+
+515
+00:41:16,250 --> 00:41:19,570
+إله signal فعدد ال X بيساوى عدد ال Y فال X واحد Y
+
+516
+00:41:19,570 --> 00:41:23,150
+واحد يعني ال X واحد في ال Y واحد X اتنين في ال Y
+
+517
+00:41:23,150 --> 00:41:25,850
+اتنين X تلاتة في ال Y اتنين بجمعهم head summation
+
+518
+00:41:25,850 --> 00:41:30,190
+X I Y I minusفتح جثة كبيرة بس فارجيكم إيش هدول
+
+519
+00:41:30,190 --> 00:41:35,770
+summation xi and ال x1 x2 x3 x4 مجموعة هو عبارة عن
+
+520
+00:41:35,770 --> 00:41:39,830
+summation xi summation yi هي عبارة عن y1 زائد y2
+
+521
+00:41:39,830 --> 00:41:45,470
+زائد y3 زائد y4 summation yi طيب على n اللي هو
+
+522
+00:41:45,470 --> 00:41:52,070
+عددهم عرض النقاطSummation X I تربية يعني X واحد
+
+523
+00:41:52,070 --> 00:41:55,910
+تربية زايد X اتنين تربية زايد X تلاتة تربية زايد X
+
+524
+00:41:55,910 --> 00:41:59,370
+أربعة تربية إلى آخره فهذه معناته summation X I
+
+525
+00:41:59,370 --> 00:42:06,010
+تربية minus نفتح جوز summation X I كله تربية يعني
+
+526
+00:42:06,010 --> 00:42:08,790
+بدي أجمع X واحد زايد X اتنين زايد X تلاتة زايد X
+
+527
+00:42:08,790 --> 00:42:13,470
+أربعة وكله إيش أسوي في الآخر أربع المجموع على إن
+
+528
+00:42:13,470 --> 00:42:20,150
+اللي هو عددهم هيك إيش بكون عملت بكون طلعت ال Mطب
+
+529
+00:42:20,150 --> 00:42:26,310
+انا عندي نقاط X1 X2 X3 الاخره وانا نقاط Y1 Y2 Y3
+
+530
+00:42:26,310 --> 00:42:31,090
+الاخره جال ايش بقدر اجيب؟ بقدر اجيب ال average ل Y
+
+531
+00:42:31,090 --> 00:42:35,670
+و ال average ل X إذا كان ال Y بتسوى MX زائد B إذا
+
+532
+00:42:35,670 --> 00:42:42,650
+ال Y bar أو ال average بتسوى MX bar زائد B مدام
+
+533
+00:42:42,650 --> 00:42:46,550
+هذا ال Y بتسوى MX زائد B لو حطيت hand bar بحط hand
+
+534
+00:42:46,550 --> 00:42:52,700
+bar سهل الموضوعماشي اذا ان اجيب ال y bar هذا سهل
+
+535
+00:42:52,700 --> 00:42:55,420
+كتير بدي اجمع ال y واحد و ال y اتنين واحد باقطين
+
+536
+00:42:55,420 --> 00:42:59,600
+ال summation yi باقسم على عددهم باقطين ال y bar طب
+
+537
+00:42:59,600 --> 00:43:04,660
+و ال x bar برضه نفس الكلام مجموهم على عددهم بقدر
+
+538
+00:43:04,660 --> 00:43:10,180
+انا ا go اذا ال b بتساوي ال y bar minus ال mx bar
+
+539
+00:43:10,180 --> 00:43:14,960
+اذا هيك بكون جبت ال bمدام جبت ال M إجهبت ال B سهل
+
+540
+00:43:14,960 --> 00:43:19,720
+جدا بس ال M هي المهمة بس ال M هي اللي ممكن نقول
+
+541
+00:43:19,720 --> 00:43:25,320
+نتغلب في حسابها شوية نقسم على X bar نقسمش على X
+
+542
+00:43:25,320 --> 00:43:29,970
+barبنقسمش على X bar بنقول انه ال Y bar بتساوي MX
+
+543
+00:43:29,970 --> 00:43:35,210
+bar زائد B طب ال M معانا ال M معانا و ال X bar
+
+544
+00:43:35,210 --> 00:43:40,070
+معانا و ال Y bar معانا ايش بطلع منها ال B اذا طلعت
+
+545
+00:43:40,070 --> 00:43:44,950
+ال B و ال M اذا صارت المعادلة A كلها معايا عند اي
+
+546
+00:43:44,950 --> 00:43:48,470
+نقطة من ال Y بقدر احسب ال X هي المعادلة اذا كان
+
+547
+00:43:48,470 --> 00:43:54,120
+انا اعطيتك Signal بقدر احسب منها ال Aال X مدام
+
+548
+00:43:54,120 --> 00:43:57,880
+اعطيتك قيمة ال signal اذا بقدر احسب التركيز وهذا
+
+549
+00:43:57,880 --> 00:44:01,580
+هو المهم و مافيش حد فينا بيغلط فيه مدام حسبنا ال M
+
+550
+00:44:01,580 --> 00:44:06,220
+صح و من النقاط بحسب ال B صح اذا المعادلة هذه صارت
+
+551
+00:44:06,220 --> 00:44:11,640
+سليمة لو اعطيتك اي Y ايش بتجيب تعطيني انت ال X
+
+552
+00:44:11,640 --> 00:44:15,720
+تبعها اللي هو ال X axis اللي انا بدوراني اللي هو
+
+553
+00:44:15,720 --> 00:44:16,380
+التركيز
+
+554
+00:44:19,060 --> 00:44:24,300
+لو حبينا طيب احنا عموما خلينا نوجه في اليوم and
+
+555
+00:44:24,300 --> 00:44:27,860
+هذا النقطة والحصة الجاية اذا الله راضي بنتكلم عن
+
+556
+00:44:27,860 --> 00:44:29,120
+المثال
+
diff --git a/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/gmLW3MRwlGM_raw.srt b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/gmLW3MRwlGM_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..9b2a43cc6a764a8226c377cce74b982644cfad66
--- /dev/null
+++ b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/gmLW3MRwlGM_raw.srt
@@ -0,0 +1,2228 @@
+1
+00:00:20,670 --> 00:00:22,950
+ان شاء الله اليوم بنكمل في ال tests of
+
+2
+00:00:22,950 --> 00:00:26,750
+significance اللي هي اختبارات ذات المغزاة او ذات
+
+3
+00:00:26,750 --> 00:00:31,390
+الدلالة و احنا بنقول ان الحصة الماضية اتكلمنا عن
+
+4
+00:00:31,390 --> 00:00:36,590
+اختبار من الاختبارات قولنا ال if test و ال if test
+
+5
+00:00:36,590 --> 00:00:43,630
+بعطيني فكرة عن هل هناك فرق احصائي جوهري بين ال
+
+6
+00:00:43,630 --> 00:00:47,930
+precision او ال variances او ال standard
+
+7
+00:00:47,930 --> 00:00:52,300
+deviationsلتو procedures او two methods ولا لأ
+
+8
+00:00:52,300 --> 00:00:59,760
+فقلنا اذا كان ال F Calc اقل من ال F Tab معناته ليس
+
+9
+00:00:59,760 --> 00:01:04,960
+هناك فرق احصائي جوهري ما بين ال precision لل two
+
+10
+00:01:04,960 --> 00:01:09,040
+methods او ال variances لل two methods او ايضا ال
+
+11
+00:01:09,040 --> 00:01:13,060
+standard deviations لل two methods اما لو كان
+
+12
+00:01:13,060 --> 00:01:18,470
+العكس فطبعا بيكون هناك فرق احصائي جوهريلكن السؤال
+
+13
+00:01:18,470 --> 00:01:26,830
+الآخر اللي يجب الإجابة عنه يتمثل في هل هناك بالفعل
+
+14
+00:01:26,830 --> 00:01:32,050
+فرق في النتائج ما بين طريقتين مختلفتين أو two
+
+15
+00:01:32,050 --> 00:01:36,230
+procedures مختلفين وقولنا ان اللي بيجاوب على هذا
+
+16
+00:01:36,230 --> 00:01:42,090
+السؤال هو عبارة عن ال T-test ال T-test يا شباب فيه
+
+17
+00:01:42,090 --> 00:01:48,700
+له تلت أحوالالـ T-test فيه له تلت أحوال يعني بيطبق
+
+18
+00:01:48,700 --> 00:01:54,500
+في تلت أحوال مختلفة أول حالة من هذه الحالات هو
+
+19
+00:01:54,500 --> 00:02:00,760
+تطبيق الـ T-test إذا كان في عندي accepted value أو
+
+20
+00:02:00,760 --> 00:02:07,500
+true value knownيعني في عندى نتيجة التحليل معروفة
+
+21
+00:02:07,500 --> 00:02:12,240
+سلفا معروفة مسبقا زى مثلا ما اكون بدى احل المادة
+
+22
+00:02:12,240 --> 00:02:16,840
+فجبت عينة من هذه المادة من معهد القياسات الدولية
+
+23
+00:02:16,840 --> 00:02:21,720
+ومكتوب على هذه المادة انه والله نتيجة التحليل مثلا
+
+24
+00:02:21,720 --> 00:02:28,340
+سبعة وخمسة وخمسين في المية PPMمعروفة نتيجة سلافا
+
+25
+00:02:28,340 --> 00:02:32,160
+قبل ما احلل فانا بدي احلل باستخدام الطريقة الجديدة
+
+26
+00:02:32,160 --> 00:02:37,180
+و بدي اقارن نتيجتي مع النتيجة الحقيقية فهذه أول
+
+27
+00:02:37,180 --> 00:02:41,460
+حالة من حالات التيتس بطبقها إذا كان في عندي
+
+28
+00:02:41,460 --> 00:02:47,260
+accepted أو true value is known الحالة التانية إذا
+
+29
+00:02:47,260 --> 00:02:51,470
+كان فيش عندي accepted أو true value knownمش .. مش
+
+30
+00:02:51,470 --> 00:02:55,190
+معروفة طيب في هذه الحالة يعني إيش بقتر أعمل؟ جال
+
+31
+00:02:55,190 --> 00:03:00,470
+بقتر أحلل replicate samples باستخدام طريقة قياسية
+
+32
+00:03:00,470 --> 00:03:04,850
+و بعتبر إنه هذه صارت والله يعني أه مقبولة و
+
+33
+00:03:04,850 --> 00:03:09,130
+replicate samplesباستخدام الطريقة الجديدة وبعدين
+
+34
+00:03:09,130 --> 00:03:13,450
+بقارن between ال two means المتوسط للأول والمتوسط
+
+35
+00:03:13,450 --> 00:03:16,870
+للتانية وبشوف هل هناك فرق أحصائي جوهري بين
+
+36
+00:03:16,870 --> 00:03:21,050
+المتوسطين ولا لأ يبقى الحالة التانية لل T test
+
+37
+00:03:21,050 --> 00:03:26,810
+ممكن أسميها comparison between two means ال mean
+
+38
+00:03:26,810 --> 00:03:29,310
+اللي بحصل عليه من ال standard و ال mean اللي بحصل
+
+39
+00:03:29,310 --> 00:03:34,950
+عليه من ال new method الحالة التالتة يا شباب اللي
+
+40
+00:03:34,950 --> 00:03:41,590
+بطبق فيها ال T testبقول ال test with multiple
+
+41
+00:03:41,590 --> 00:03:44,950
+samples في بعض الأحيان أنا ماعندي replicate
+
+42
+00:03:44,950 --> 00:03:48,910
+samples ماعندي عينة بحللها عدة مرات بالقياسية و
+
+43
+00:03:48,910 --> 00:03:53,630
+عدة مرات بالطريقة الجديدة لأ أنا في عندي عينات
+
+44
+00:03:53,630 --> 00:03:57,750
+مختلفة multiple samples فبحلل العينة الأولى
+
+45
+00:03:57,750 --> 00:04:02,160
+باستخدام ال standardو بحلل نفس العينة باستخدام
+
+46
+00:04:02,160 --> 00:04:06,260
+الطريقة الجديدة و انتهى الموضوع باخد عينة جديدة
+
+47
+00:04:06,260 --> 00:04:10,000
+عينة أخرى بحللها بال standard و بالجديدة عينة
+
+48
+00:04:10,000 --> 00:04:13,400
+ثالثة بال standard و بالجديدة و هكذا ففي عندي
+
+49
+00:04:13,400 --> 00:04:16,560
+multiple samples إذا كان عندي multiple samples
+
+50
+00:04:16,560 --> 00:04:22,860
+فهناك طريقة لحساب ال T value فيبقى في عندي تلت طرق
+
+51
+00:04:23,080 --> 00:04:25,720
+when an accepted or a true value is known
+
+52
+00:04:25,720 --> 00:04:31,540
+comparison between two means والحالة الأخيرة بنقول
+
+53
+00:04:31,540 --> 00:04:38,400
+comparison
+
+54
+00:04:38,400 --> 00:04:43,000
+between two means والحالة الأخيرة إيش ذكرناها؟قلنا
+
+55
+00:04:43,000 --> 00:04:48,000
+T-test with multiple samples طيب نيجي نتطلع على
+
+56
+00:04:48,000 --> 00:04:51,460
+القانون اللي راح نستخدمه في الحل و أنا أحاول
+
+57
+00:04:51,460 --> 00:04:56,920
+أبسطلك الموضوع بدي أقول أنه كل التلت قوانين اللي
+
+58
+00:04:56,920 --> 00:05:00,920
+هنتكلم عنهم في التلت أحوال لل T-test هيكونوا
+
+59
+00:05:00,920 --> 00:05:05,060
+مشتقين من حاجة احنا درسناها كويس و فاهمينها كويس
+
+60
+00:05:05,060 --> 00:05:09,750
+كتير اللي هي ال confidence limitالـ confidence
+
+61
+00:05:09,750 --> 00:05:12,610
+limit كان فيه قانون بيقول الـ confidence limit
+
+62
+00:05:12,610 --> 00:05:18,310
+بيسوى x bar زادة ونقص الTS على جزر ال N صح؟ الحصة
+
+63
+00:05:18,310 --> 00:05:21,720
+الماضية كنا أخدنا هذا الكلامالـ confidence limit
+
+64
+00:05:21,720 --> 00:05:24,820
+اللي احنا قلنا هي الـ true value in fact الـ true
+
+65
+00:05:24,820 --> 00:05:28,020
+value يعضر عن .. بترجع في range x bar زادة و نقص
+
+66
+00:05:28,020 --> 00:05:32,300
+ال T S على جزر ال N طب لو اجينا .. قعدنا ترتيب هذه
+
+67
+00:05:32,300 --> 00:05:37,020
+المعادلة لو قعدنا ترتيب هذه المعادلة إيش بنقول؟
+
+68
+00:05:37,020 --> 00:05:43,320
+بلس أو ماينس T بتساوي X bar minus M U جزر ال N على
+
+69
+00:05:43,320 --> 00:05:48,200
+S عادي الترتيب فانا في هذه الحالة إيش بأحسب؟بأحسب
+
+70
+00:05:48,200 --> 00:05:53,800
+ال T طب حسبت ال T بقى أقارنها بال T tabulated اللي
+
+71
+00:05:53,800 --> 00:05:58,740
+في الجدول هذا T بتكون calculated فبنفس الطريقة إذا
+
+72
+00:05:58,740 --> 00:06:03,280
+كان ال T calculated أقل إذا ليس هناك فرق إحصائي
+
+73
+00:06:03,280 --> 00:06:10,380
+جوهري بين نتائج الطريقتين والعكس أيضا صحيح طيب هذه
+
+74
+00:06:10,380 --> 00:06:14,080
+الحالة الأولى اللي بتكلم عنها طيب نيجي الآن ناخد
+
+75
+00:06:14,080 --> 00:06:19,410
+مثال كتير بسيطبنقول في a new procedure for
+
+76
+00:06:19,410 --> 00:06:22,570
+determining copper what was used for the
+
+77
+00:06:22,570 --> 00:06:26,490
+determination of copper in a sample بدنا نعين
+
+78
+00:06:26,490 --> 00:06:32,590
+الكبر في عينة ما فاستخدمنا طريقة جديدة لتعين الكبر
+
+79
+00:06:32,590 --> 00:06:37,000
+في هذه العينةالتجارة تم تجاربها خمس مرات
+
+80
+00:07:04,480 --> 00:07:08,380
+مش بس هيك و كمان بقدر احسب ال 7 deviation من الخمس
+
+81
+00:07:08,380 --> 00:07:11,820
+نتائج لكن هو ان معطيني ايضا يقول اندي a standard
+
+82
+00:07:11,820 --> 00:07:17,440
+deviation of plus or minus point seven امنى هيك
+
+83
+00:07:19,050 --> 00:07:24,170
+يعني أعطاني ال X bar و أعطاني ال S بيقول if the
+
+84
+00:07:24,170 --> 00:07:28,530
+true value وهذا اللي بفهمني أي حالة من حالات ال T
+
+85
+00:07:28,530 --> 00:07:32,650
+test بدي أستخدم if the true value for this
+
+86
+00:07:32,650 --> 00:07:37,830
+analysis was 11.7 PPM يبقى العينة هذه التحليل
+
+87
+00:07:37,830 --> 00:07:42,730
+الحقيقي إلها أو الصحيح إلها هو الله 11 سنة و 10
+
+88
+00:07:42,730 --> 00:07:44,170
+فبيسأل السؤال
+
+89
+00:07:53,230 --> 00:07:59,450
+هل التريقة الجديدة بتعطي نتائج إحصائية صحيحة عند
+
+90
+00:07:59,450 --> 00:08:07,250
+مستوى ثقة 95% علما بإن الـ T tabulated 2.776 طبعا
+
+91
+00:08:07,250 --> 00:08:09,910
+لما أقول T tabulated هيك بتطلع على 4 degrees of
+
+92
+00:08:09,910 --> 00:08:15,030
+freedom عند 95% بلاجة 2.776
+
+93
+00:08:16,780 --> 00:08:21,220
+هذه السؤال او بمعنى اخر ممكن انا يعني احاول افهم
+
+94
+00:08:21,220 --> 00:08:24,800
+السؤال بمعنى اخر ممكن اقول هل النتيجة اللي انا
+
+95
+00:08:24,800 --> 00:08:28,950
+حصلت عليها عشرة او تمانية من عشرةبتفرج فرق جوهر
+
+96
+00:08:28,950 --> 00:08:33,510
+يعني 11 7 من 10 بمعنى انه هل السبب في هذا الاختلاف
+
+97
+00:08:33,510 --> 00:08:37,730
+هو سبب عجز في الطريقة او خطأ في الطريقة ولا هو
+
+98
+00:08:37,730 --> 00:08:42,210
+يعني random error ولا هو random error احنا بدنا
+
+99
+00:08:42,210 --> 00:08:47,350
+نثبت اذا كان random error المفروض ان يطلع عندنا ال
+
+100
+00:08:47,350 --> 00:08:51,700
+T Calc اقل من ال T Tabيعني تطلع الطريقة ال
+
+101
+00:08:51,700 --> 00:08:54,420
+character مُتكامف بقتين، بيكون أولا random error،
+
+102
+00:08:54,420 --> 00:08:57,840
+لكن لو ماكانش random error، المفروض T Calc بيطلع
+
+103
+00:08:57,840 --> 00:09:01,420
+أكبر من ال T Tab، بمعنى لا يمكن استخدام الطريقة
+
+104
+00:09:01,420 --> 00:09:04,620
+الجديدة، يعني الفرق مش ناشع عن random error، هذا
+
+105
+00:09:04,620 --> 00:09:09,280
+معنى آخر لفهم المسألة، كويس، بقول أنا اللي بيهمني،
+
+106
+00:09:09,280 --> 00:09:13,800
+بطبق القانونالقانون بيقول plus or minus T بيساوي X
+
+107
+00:09:13,800 --> 00:09:16,640
+bar minus Mu جزر ال N على S إذا plus or minus T
+
+108
+00:09:16,640 --> 00:09:20,720
+بيساوي عشر أو تمانية نخس أحداشر وسبعة جزر الخمسة
+
+109
+00:09:20,720 --> 00:09:25,220
+على سبعة من عشرة اللي هي standard deviation بتطلع
+
+110
+00:09:25,220 --> 00:09:32,740
+عند ال T عبارة عن 2.9 ماهي ال Mu؟ ال Mu هي ال true
+
+111
+00:09:32,740 --> 00:09:39,360
+average ال true average او ال true mean يعني او ال
+
+112
+00:09:39,360 --> 00:09:43,160
+true value ال correct valueالقيمة الصحيحة اللي ..
+
+113
+00:09:43,160 --> 00:09:46,820
+بالظبط يعني اللي في التحليل الموجودة فال T بتطلع
+
+114
+00:09:46,820 --> 00:09:52,560
+92 من 10 طبعا 92 من 10 اللي هي T Calc أكبر من ال T
+
+115
+00:09:52,560 --> 00:09:58,420
+Tab اللي هي 2.776 إذا النتيجة بتقوللي والله إنه
+
+116
+00:09:58,420 --> 00:10:03,520
+هناك فرق إحصائي جوهري بين الطريقتين بمعنى إنه
+
+117
+00:10:03,520 --> 00:10:07,850
+النتيجة 10 أو 8 نتيجة خاطئةالفرق بينها و بين الـ
+
+118
+00:10:07,850 --> 00:10:11,090
+11 و 7 ماعنى مش ناشئ عن Random Error، لأ، في أسباب
+
+119
+00:10:11,090 --> 00:10:15,330
+حقيقية لهذا الحيوان، إن والله الطريقة نفسها خاطئة،
+
+120
+00:10:15,330 --> 00:10:20,450
+الطريقة غير صالحة، بتعطي نتائج أقل من الحقيقة،
+
+121
+00:10:20,450 --> 00:10:24,810
+يعني منخفضة عن الحقيقة، فهذه أول حالة من حالات الـ
+
+122
+00:10:24,810 --> 00:10:30,390
+T-test ابني جي بتطلع عن الحالة التانية للـ T-test
+
+123
+00:10:30,990 --> 00:10:35,710
+بنطلع على comparison between two means وفي هذه
+
+124
+00:10:35,710 --> 00:10:42,390
+الحالة زي ما ذكرت بستخدم طريقة قياسية لتقدير
+
+125
+00:10:42,390 --> 00:10:45,750
+المادة
+
+126
+00:10:45,750 --> 00:10:50,210
+أو الانالايت وبستخدم أيضا طريقة جديدة لتقدير
+
+127
+00:10:50,210 --> 00:10:53,470
+الانالايت وبقارن between two means لو طلعنا على
+
+128
+00:10:53,470 --> 00:10:57,230
+القانون في البداية بدي احاول انه نقتنع مع بعض ان
+
+129
+00:10:57,230 --> 00:11:01,080
+هو نفس القانون اللي استخدمناها سابقاهي ال X bar
+
+130
+00:11:01,080 --> 00:11:03,740
+واحد اللي هي بالطريقة اللي احنا .. الجديدة اللي
+
+131
+00:11:03,740 --> 00:11:08,560
+احنا عملناها كان هنا ميو صح ولا لأ اللي هو ل true
+
+132
+00:11:08,560 --> 00:11:11,400
+بينما ل true ماعندي حاجة true انا .. انا حلتها
+
+133
+00:11:11,400 --> 00:11:15,320
+بطريقة قياسية فبقول X bar لطريقة قياسية بدل ل true
+
+134
+00:11:15,320 --> 00:11:19,220
+صح ولا لأ؟ اذا هذا بدل ل ميو لكن بما ان .. بما ان
+
+135
+00:11:19,220 --> 00:11:23,200
+في عندي two sets of dataففي عندى ال pooled
+
+136
+00:11:23,200 --> 00:11:25,000
+standard deviation، بتجيب ال standard deviation طب
+
+137
+00:11:25,000 --> 00:11:27,740
+لأنه z، للأول ولا للتانى، مادام replicate
+
+138
+00:11:27,740 --> 00:11:31,540
+measurements عملتها بال standard و بال new method،
+
+139
+00:11:31,540 --> 00:11:35,420
+اذا ال S هي عبارة عن ال S P، ال S هي عبارة عن ال
+
+140
+00:11:35,420 --> 00:11:38,960
+pooled standard deviationمول ال N مدام عنده N واحد
+
+141
+00:11:38,960 --> 00:11:42,760
+و N اتنين اذا المحصلة N واحد N اتنين على N واحد
+
+142
+00:11:42,760 --> 00:11:46,580
+زائد N اتنين كله تحت الجزر فيبجى هذا القانون هو
+
+143
+00:11:46,580 --> 00:11:49,720
+نفس القانون اللى احنا استخدمناه سابقا نفس القانون
+
+144
+00:11:49,720 --> 00:11:54,300
+اللى مار معناه في ال confidence limit هو هو تعالوا
+
+145
+00:11:54,300 --> 00:12:02,580
+نطلع على المثال التالفوكمان مرة هذا مثال موجز كان
+
+146
+00:12:02,580 --> 00:12:06,400
+ممكن يعطينا البيانات في جدول و احنا منها نشتق
+
+147
+00:12:06,400 --> 00:12:09,080
+الكلام اللي موجود قدامي نحاول نفهم المثال في
+
+148
+00:12:09,080 --> 00:12:13,920
+البداية بنقول في المثال nickel in a sample was
+
+149
+00:12:13,920 --> 00:12:18,770
+determined using a new procedure wheresix
+
+150
+00:12:18,770 --> 00:12:24,030
+replicate samples resulted in a mean of 19.65%
+
+151
+00:12:24,030 --> 00:12:28,010
+يعني أنا حللت ال nickel في عينة باستخدام طريقة
+
+152
+00:12:28,010 --> 00:12:34,110
+جديدة فأعطتني متوسط 19.65% لما أقول لمتوسط 6 جاروب
+
+153
+00:12:34,110 --> 00:12:37,610
+معناته ممكن أنا أقول والله اه X بقى عارف واحد ممكن
+
+154
+00:12:37,610 --> 00:12:41,350
+أقول والله 6 جاروب هذه يعطيني القيم تبقى 19.45 19
+
+155
+00:12:41,350 --> 00:12:45,200
+.55 19.65تسعة عشر و خمسة و سبعية تسعة عشر و خمسة و
+
+156
+00:12:45,200 --> 00:12:48,880
+تمانية مثلا يعني و أنا أجمعهم و أطلع ال average بس
+
+157
+00:12:48,880 --> 00:12:52,560
+هو now ماعطيني ال average already و من ال average
+
+158
+00:12:52,560 --> 00:12:55,400
+كان بإمكاني .. من ال average و من القيم كان
+
+159
+00:12:55,400 --> 00:12:57,960
+بإمكاني أحسب ال standard deviation و أربق .. و
+
+160
+00:12:57,960 --> 00:13:01,280
+أجيب ال variance لكن هو now برضه ماعطيني قيمة ال
+
+161
+00:13:01,280 --> 00:13:04,560
+variance بيقول لي and a variance يعني مربع ال
+
+162
+00:13:04,560 --> 00:13:08,460
+standard deviation هو عبارة عن point four five two
+
+163
+00:13:08,460 --> 00:13:14,170
+fourبقول five replicate analyses were conducted
+
+164
+00:13:14,170 --> 00:13:19,130
+using a standard procedure طيب عملنا نفس التحليل
+
+165
+00:13:19,130 --> 00:13:27,270
+خمس مرات متتالية باستخدام طريقة قياسية resulting
+
+166
+00:13:27,270 --> 00:13:31,590
+in a mean of 19.24 يبجل ال mean باستخدام الطريقة
+
+167
+00:13:31,590 --> 00:13:36,550
+القياسية كان 19.24% وال variance باستخدام الطريقة
+
+168
+00:13:36,550 --> 00:13:41,700
+القياسية كان 0.105كان نفس الكلام ممكن يقول الحلقة
+
+169
+00:13:41,700 --> 00:13:45,060
+خمس مرات اول مرة تسعة عاشر واحد تاني مرة تسعة عاشر
+
+170
+00:13:45,060 --> 00:13:47,240
+اتنين تالت مرة تسعة عاشر تلاتة تالت مرة تسعة عاشر
+
+171
+00:13:47,240 --> 00:13:50,800
+اربعة مثلا يعني و انا اخد ال average و طلع تسعة
+
+172
+00:13:50,800 --> 00:13:53,880
+عاشر اربعة عشرين و من القيم و ال average ممكن اطلع
+
+173
+00:13:53,880 --> 00:13:56,140
+ال standard deviation و بربعه و بيعطيني ال
+
+174
+00:13:56,140 --> 00:13:59,280
+variance لكن هو معطيني كل هذا الكلام مش بس ايه
+
+175
+00:13:59,280 --> 00:14:04,570
+بيقول if they pull the standard deviationwas point
+
+176
+00:14:04,570 --> 00:14:09,110
+five four six كمان معقين ال S P بتساوي point five
+
+177
+00:14:09,110 --> 00:14:12,870
+four six تعالى بالسؤال if there a significant
+
+178
+00:14:12,870 --> 00:14:16,590
+difference between the two methods هل هناك فرق
+
+179
+00:14:16,590 --> 00:14:21,030
+جوهري بين الطريقتين لاحظوا ما جليش between the
+
+180
+00:14:21,030 --> 00:14:24,390
+precision of the two methods ولا جلي between the
+
+181
+00:14:24,390 --> 00:14:27,210
+variances of the two methods ولا جلي between the
+
+182
+00:14:27,210 --> 00:14:29,470
+results of the two methods جلي between the two
+
+183
+00:14:29,470 --> 00:14:35,120
+methods معناته يجب تطبيق الاختبارينيجب تطبيق
+
+184
+00:14:35,120 --> 00:14:37,860
+الإختبارين، يعني مدين بدي أقول فيه فرق بين
+
+185
+00:14:37,860 --> 00:14:40,380
+الطريقتين أو لأ، بدي أقول في ال precision و أيضا
+
+186
+00:14:40,380 --> 00:14:46,060
+في النتائج، فيجب تطبيق الإختبارين، الآن يا شباب،
+
+187
+00:14:46,060 --> 00:14:48,780
+اللي بدي أطبق الآن هو أطبق في الأول، ال T-test ولا
+
+188
+00:14:48,780 --> 00:14:54,550
+ال F-testبنقول عادة عادة ال if test بمجرد نظر
+
+189
+00:14:54,550 --> 00:14:58,590
+النتائج ال if test أسهل تطبيقه من أي ناحية أسهل
+
+190
+00:14:58,590 --> 00:15:01,470
+لأنه يعني الوصول النتيجة فيه يعني مباشر على طول
+
+191
+00:15:01,470 --> 00:15:05,050
+هذه حاجة الحاجة التانية في احتمال أن ال if test
+
+192
+00:15:05,050 --> 00:15:10,340
+يرسملو رسب ال F-test معناته بنقول اه بحتاجش نعمل
+
+193
+00:15:10,340 --> 00:15:13,520
+ال T بنقول بالله اذا اه هناك فرق بين الطريقتين
+
+194
+00:15:13,520 --> 00:15:16,900
+وانتهى الموضوع او يعني تضيع للوقت ان احسب ال T
+
+195
+00:15:16,900 --> 00:15:20,860
+ممكن ال T ينجح لكن بهمنيش ينجح ولا يرسب مدام رسب
+
+196
+00:15:20,860 --> 00:15:24,960
+واحد فيهم انتهى الموضوع اذا لا يمكن استخدام
+
+197
+00:15:24,960 --> 00:15:28,240
+الطريقة الجديدة او ان هناك فرق جوهري بين الطريقتين
+
+198
+00:15:28,240 --> 00:15:33,000
+فانا بطبق في البداية ال F-test ومن القيم تبعتي
+
+199
+00:15:33,000 --> 00:15:37,750
+بقدر اقول ان ال F-testالـ F بتساوي 0.4524 على 0
+
+200
+00:15:37,750 --> 00:15:44,150
+.105 و لاحظ أنه حطيت الكبير فوق و النتيجة 4.31 لو
+
+201
+00:15:44,150 --> 00:15:47,850
+إجيت أطلعت على ال tabulated if value عند 95%
+
+202
+00:15:47,850 --> 00:15:52,050
+confidence level و 9 degrees of freedom لأنه عندي
+
+203
+00:15:52,050 --> 00:15:58,890
+.. إذا كان بتلاحظ N1 ب6 N2 ب5 هي 11نقص اتنين اللي
+
+204
+00:15:58,890 --> 00:16:03,670
+هو المقام في ال SP ان واحد زاد ان اتنين نقص اتنين
+
+205
+00:16:03,670 --> 00:16:07,070
+هي ال degrees of freedom فبتم عيندي تسعة عيندي نين
+
+206
+00:16:07,070 --> 00:16:11,150
+degrees of freedom لو جيت طلعت تحت عمود ال 95%
+
+207
+00:16:11,150 --> 00:16:16,610
+confidence level بلاحظ ان ال T value 6.26 يبقى ال
+
+208
+00:16:16,610 --> 00:16:24,060
+calculated F value4.31، الـ tabulated 6.26، إذا
+
+209
+00:16:24,060 --> 00:16:27,280
+الـ calculated أقل من الـ tabulated، إذا ليس هناك
+
+210
+00:16:27,280 --> 00:16:32,140
+فرق جوهري، إحصائي جوهري، بين الـ precision أو الـ
+
+211
+00:16:32,140 --> 00:16:34,800
+variances أو الـ standard deviations للـ two
+
+212
+00:16:34,800 --> 00:16:39,240
+methods، بمعنى إن الـ precision comparable، الـ
+
+213
+00:16:39,240 --> 00:16:41,680
+precision، مافيش فرق بينهم من ناحية الـ precision،
+
+214
+00:16:41,680 --> 00:16:46,110
+بتم عند الآن، إذا لازم أطبق الـ T-testلازم اتكلم
+
+215
+00:16:46,110 --> 00:16:49,670
+عن ال T-test و احسب ال T value و اشوف لحظة ان ال T
+
+216
+00:16:49,670 --> 00:16:52,770
+-test يفشل بقدرش اقول انه مافيش فارق بين الطريقتين
+
+217
+00:16:52,770 --> 00:16:57,550
+بدي احسب ال T-test انا عندي لان two sets of data ل
+
+218
+00:16:57,550 --> 00:17:01,330
+replicate measurements اذا معروف انه بدي في الأول
+
+219
+00:17:01,330 --> 00:17:03,810
+احصل على ال mean الأول و احصل على ال mean التاني
+
+220
+00:17:03,810 --> 00:17:08,350
+من ال standard و من ال new اذا لازم اطبق ال T-test
+
+221
+00:17:08,350 --> 00:17:13,420
+لما يكون في عندي comparison between two meansفبقى
+
+222
+00:17:13,420 --> 00:17:16,380
+اطبق القانون القانون بيقول plus or minus T بتساوي
+
+223
+00:17:16,380 --> 00:17:21,480
+ال X bar ال average للأول تسعة عاش خمسة و ستين ال
+
+224
+00:17:21,480 --> 00:17:26,660
+average لل standard تسعة عاش أربعة و عشرين على ال
+
+225
+00:17:26,660 --> 00:17:32,100
+S P point five four six ان واحد بستة ان S ال
+
+226
+00:17:32,100 --> 00:17:36,140
+standard بخمسة يبقى ستة في خمسة على ستة زائد خمسة
+
+227
+00:17:36,140 --> 00:17:40,880
+كله تحت الجزر بتطلع ال T one point two three ال T
+
+228
+00:17:40,880 --> 00:17:47,460
+one point two threeطبعا ال tabulated T value طبعا
+
+229
+00:17:47,460 --> 00:17:51,660
+nine degrees of freedom في الأولى زى ما حكيت هان
+
+230
+00:17:51,660 --> 00:17:57,520
+انا هاد ال F value طبعا اللى هم نعرف ال degrees of
+
+231
+00:17:57,520 --> 00:18:02,020
+freedom اللى هان اللى هى عضارة عن كانت ستة يعنى
+
+232
+00:18:02,020 --> 00:18:05,940
+خمسة بدي اطلع في ال horizon طلعت خمسة هذا كان خمسة
+
+233
+00:18:05,940 --> 00:18:10,800
+بدي اطلع على أربعةفمعنى الكلام بحصل على 6.26 لكن
+
+234
+00:18:10,800 --> 00:18:14,280
+بالنسبة لل T في 9 degrees of freedom يعني هان في
+
+235
+00:18:14,280 --> 00:18:19,160
+البداية ال F بتطلع على New 1 و New 2 متذكرين كيف
+
+236
+00:18:19,160 --> 00:18:23,100
+كنا بنحسب ال F؟ خليني
+
+237
+00:18:29,920 --> 00:18:35,700
+هي ال .. هي ال F احنا عندنا كان عدد ال degrees of
+
+238
+00:18:35,700 --> 00:18:41,800
+freedom عندي خمسة كويس و كان عندي هنا .. هنا كان
+
+239
+00:18:41,800 --> 00:18:48,900
+أربعة لأنه عندي خمسة experiments فهي أربعة وهي
+
+240
+00:18:48,900 --> 00:18:53,200
+مشيت هنا وهي الخمسة هي بيجي 6.26 هذه ال F value
+
+241
+00:18:53,200 --> 00:19:00,720
+كويس بالنسبة لل Tالـ T عندي انا 9 degrees of
+
+242
+00:19:00,720 --> 00:19:10,240
+freedom هيها عندي 95% لأ دي ال F برضه لأ بدي اروح
+
+243
+00:19:10,240 --> 00:19:17,220
+على اليمين اه ممكن هان 9 degrees of freedom فبدأ
+
+244
+00:19:17,220 --> 00:19:23,880
+مش عندي 95 بطلع عندي 2.262 ماشي يا شباب فلازم نعرف
+
+245
+00:19:23,880 --> 00:19:28,810
+نطلع قيمة ال F و قيمة ال T من الجداولفالمهم ال T
+
+246
+00:19:28,810 --> 00:19:36,630
+بيطلع عندى 1.23 أقل من ال 2.26 two معناته كمان ليس
+
+247
+00:19:36,630 --> 00:19:40,550
+هناك فرق أحصائي جوهري بين النتائج اللي بحصل عليها
+
+248
+00:19:40,550 --> 00:19:44,330
+من الطريقتين مدان مافيش فرق أحصائي جوهري بين ال
+
+249
+00:19:44,330 --> 00:19:49,070
+precision و أيضا بين النتائج إذا الجواب النهائي
+
+250
+00:19:49,070 --> 00:19:55,380
+ليس هناك فرقإحصائي جوهري بين الطريقتين بمعنى أخر
+
+251
+00:19:55,380 --> 00:19:58,920
+يمكن استخدام الطريقة الجديدة عوضا عن أو بدلا عن
+
+252
+00:19:58,920 --> 00:20:04,980
+الطريقة القياسية بدون أخطأ كل عشان ال F أبارعا
+
+253
+00:20:04,980 --> 00:20:08,860
+يعني لو طلعت عليه قانون صغير أه لكن لو فشل بيكون
+
+254
+00:20:08,860 --> 00:20:15,040
+من نصيبك تطرش تطبق ال T أه بدام هذا نجح إذا لازم
+
+255
+00:20:15,040 --> 00:20:19,710
+أطبق اللي بعدهو ممكن تبرده هو نقطة الشيء؟ لأ واحد
+
+256
+00:20:19,710 --> 00:20:23,450
+ال F بيعطي هل هناك فرق أحصائي جوهري بين ال
+
+257
+00:20:23,450 --> 00:20:27,210
+precision و التاني بيعطي .. بتكلم عن النتائج
+
+258
+00:20:27,210 --> 00:20:32,790
+بالظبط .. بالظبط .. بالظبط .. بالظبط أستاذ ممكن
+
+259
+00:20:32,790 --> 00:20:37,530
+أنا طالع أقول ال summer debate بالمدينة الصينية؟
+
+260
+00:20:37,530 --> 00:20:43,150
+هو أنت بتقدر يعني .. بتقدر بشكل أو بآخر بتقدر يعني
+
+261
+00:20:44,530 --> 00:20:49,390
+لأ هو مش هيك يعني هو يعني غالبا إذا كان أعطاك ال
+
+262
+00:20:49,390 --> 00:20:53,170
+data points كلها بتقدر تعمل ال SP بس غالبا بتضطرش
+
+263
+00:20:53,170 --> 00:20:56,670
+أنت تطلع ال SP من ال variances لكن in principle
+
+264
+00:20:56,670 --> 00:21:03,110
+يعني ممكن .. ممكن أعطونا ال F tabulated بس
+
+265
+00:21:03,110 --> 00:21:09,310
+احنا بقدر نطلعه طلعناه فارجيتك كيف تطلعه هى يا
+
+266
+00:21:09,310 --> 00:21:09,770
+حبيبي
+
+267
+00:21:13,570 --> 00:21:21,190
+هو إيش جلنا؟ جلنا إنه اعملنا .. اعملنا التجربة ست
+
+268
+00:21:21,190 --> 00:21:25,070
+مرات .. هاد اللي فوق اللي كانت ال S1 تربيك .. ست
+
+269
+00:21:25,070 --> 00:21:29,450
+مرات فمعناته خمسة degrees of freedom إذا هاي خمسة
+
+270
+00:21:29,450 --> 00:21:34,930
+degrees of freedom وعملنا هذه جال أربع مرات يعني
+
+271
+00:21:34,930 --> 00:21:38,050
+.. خمس مرات جال هو يعني أربع .. أربع degrees of
+
+272
+00:21:38,050 --> 00:21:40,850
+freedom فمشينا هاي الخمسة و هاي الأربع هان بال ..
+
+273
+00:21:40,850 --> 00:21:41,650
+بالتيجيو
+
+274
+00:21:44,270 --> 00:21:50,030
+6.26 بالظبط فهيو زي هيك بنطلعه زي ما اتعلمنا الحص
+
+275
+00:21:50,030 --> 00:21:55,710
+الماضي برضه نعم هذا ال degree of freedom من فوق و
+
+276
+00:21:55,710 --> 00:22:01,750
+من الجانب برضه نفس الكلام طيب يا شباب نتكلم عن آخر
+
+277
+00:22:01,750 --> 00:22:06,170
+نوع من أنواع ال stand اللي عفوا ال T test اللي هو
+
+278
+00:22:06,170 --> 00:22:10,060
+ال T test with multiple samplesفبنقول with
+
+279
+00:22:10,060 --> 00:22:13,340
+multiple samples شوفنا القانون تبعه plus or minus
+
+280
+00:22:13,340 --> 00:22:17,080
+T بتسوي ال D bar جزر ال N على S دي او لسان
+
+281
+00:22:17,080 --> 00:22:21,840
+deviation of the difference خلينا نتطلع على مثال
+
+282
+00:22:21,840 --> 00:22:25,780
+مر معنى قبل هيك مثال مر معنى قبل هيك لما نكون عندى
+
+283
+00:22:25,780 --> 00:22:28,780
+multiple samples زى الحالة اللى قدامى بنقول
+
+284
+00:22:28,780 --> 00:22:32,840
+mercury in multiple samples was determined using a
+
+285
+00:22:32,840 --> 00:22:36,950
+standard method and a new suggested methodتم
+
+286
+00:22:36,950 --> 00:22:42,910
+تحليله باستخدام طريقة قياسية وطريقة جديدة مقترحة
+
+287
+00:22:42,910 --> 00:22:47,430
+فبقول six different samples عينات إشمالة مش
+
+288
+00:22:47,430 --> 00:22:52,450
+replicate different samples were analyzed using
+
+289
+00:22:52,450 --> 00:22:55,270
+the two procedures giving the following results in
+
+290
+00:22:55,270 --> 00:22:58,730
+PPM فنتطلع على هذه الأشكال مرمى عن هذا المثال
+
+291
+00:22:58,730 --> 00:23:02,890
+بالظبط هو هوفالعينة الأولى كانت عشرة و تلاتة
+
+292
+00:23:02,890 --> 00:23:06,890
+بالجديدة عشرة و نص بالقياسية العينة التانية اتناشر
+
+293
+00:23:06,890 --> 00:23:09,970
+سبعة بالجديدة اتناشر ستة بالقياسية الى اخرية بسأل
+
+294
+00:23:09,970 --> 00:23:14,070
+سؤال بيقول find the standard deviation of the
+
+295
+00:23:14,070 --> 00:23:17,810
+difference بده ال SD حلو احنا حلناها قبل هيك و
+
+296
+00:23:17,810 --> 00:23:21,590
+طلعنا قيمة ال SD لكن بنعمله كمان مرة بيقول if the
+
+297
+00:23:21,590 --> 00:23:25,250
+two methods have comparable precision إذا كانت two
+
+298
+00:23:25,250 --> 00:23:29,210
+methods ال precision تبعتهم يعني متكافئة متقاربة
+
+299
+00:23:30,460 --> 00:23:33,520
+فبسأل find whether there is any significant
+
+300
+00:23:33,520 --> 00:23:36,040
+difference between the results of the two methods
+
+301
+00:23:36,040 --> 00:23:41,420
+at the 95% confidence level فهل هناك فرق في نتائج
+
+302
+00:23:41,420 --> 00:23:47,390
+الطريقتين عند مستوى الثقة 95%؟بنعطيك ال tabulated
+
+303
+00:23:47,390 --> 00:23:52,130
+T جالب تساوية عند 95% confidence level جالب تساوية
+
+304
+00:23:52,130 --> 00:23:57,450
+2.571 بدنا نحسب في البداية ال S D شوفنا كيف نحسبها
+
+305
+00:23:57,450 --> 00:24:01,450
+بنقول بنطلع ال D I للأولى D I للتانية التالتة
+
+306
+00:24:01,450 --> 00:24:05,010
+الرابعة الخمسة السادسة بنجمعهم summation D I و
+
+307
+00:24:05,010 --> 00:24:10,310
+بنجسبهم على 6 بيطلع ال D bar تلاتة من عشرة، كويس؟
+
+308
+00:24:10,790 --> 00:24:15,210
+هي الـ D bar طبعا بنجيب ال D I minus ال D bar
+
+309
+00:24:15,210 --> 00:24:19,810
+squared ال summation لإلهم بتعطيلنا point seven
+
+310
+00:24:19,810 --> 00:24:24,650
+six بنطلع ال S D point seven six على ستة ناقص واحد
+
+311
+00:24:24,650 --> 00:24:29,390
+ستة جارب ناقص واحد يعني خمسة تحت الجزر بيعطينا
+
+312
+00:24:29,390 --> 00:24:33,270
+point three nine طيب بنيجي بنطبق القانون عشان أجيب
+
+313
+00:24:33,270 --> 00:24:36,450
+ال T ال T إيش بتساوي plus or minus D بتساوي ال D
+
+314
+00:24:36,450 --> 00:24:41,610
+bar اللي هي تلاتة من عشرة في جزر ال Nعلى ال SD 0
+
+315
+00:24:41,610 --> 00:24:48,370
+.39 فطلع ال T 1.88 لو جينا نقارنها ال 2.571 اللي
+
+316
+00:24:48,370 --> 00:24:54,050
+ماعطيها الليه بلاحظ أنه ال T calculated أقل من ال
+
+317
+00:24:54,050 --> 00:25:00,890
+T tabulated بمعنى أخر لا يوجد فرق جوهر بين النتائج
+
+318
+00:25:00,890 --> 00:25:04,370
+اللي بحصل عليها من الطريقتين يعني الطريقة الجديدة
+
+319
+00:25:04,370 --> 00:25:09,510
+يمكن استخدامها عيوظا عن الطريقة القياسية
+
+320
+00:25:15,930 --> 00:25:19,890
+الـ true mean يعني مالوش دعوة لـ true mean أو للـ
+
+321
+00:25:19,890 --> 00:25:21,910
+standard method في هذا الكلام، هذا مالوش دعوة
+
+322
+00:25:21,910 --> 00:25:28,230
+نهائيا، هذا بيعطيك يعني لـ true mean بيعطيك أن
+
+323
+00:25:28,230 --> 00:25:31,870
+عندك replicate measurements أنت عاملها، لكن عندك
+
+324
+00:25:31,870 --> 00:25:34,330
+القراءة الحقيقية معروفة أو النتيجة الحقيقية
+
+325
+00:25:34,330 --> 00:25:39,730
+معروفة، لا ينطبق على هذا الكلام، ال SP بتستخدم نفس
+
+326
+00:25:39,730 --> 00:25:43,020
+النوع من العين، نفس العينةأكتر من مرة بالقياسية
+
+327
+00:25:43,020 --> 00:25:45,860
+أكتر من مرة بالجديدة فالملوش دعوة بهذا الكلام
+
+328
+00:25:45,860 --> 00:25:49,180
+اتكلم عن multiple samples عينات كل عينة مختلفة عن
+
+329
+00:25:49,180 --> 00:25:51,980
+الأخرى عشان هيك لو طلعت على النتائج كمان بتلاحظ
+
+330
+00:25:51,980 --> 00:25:55,700
+النتائج متفاوت فيها نوع من التفاوت لكن زي ما ذكرت
+
+331
+00:25:55,700 --> 00:26:00,220
+سابقا يجب ان عد النتائج في القياسية تكون مساوي لعد
+
+332
+00:26:00,220 --> 00:26:04,380
+النتائج في الجديدة لأنك انت بتعمل التجربة نفسها
+
+333
+00:26:04,380 --> 00:26:07,980
+بالقياسية بعدين بالجديدة وبالتالي لازم يكون عد
+
+334
+00:26:07,980 --> 00:26:16,400
+النتائج متساوي طيب يا شباب نطلع علىاختبار جديد انت
+
+335
+00:26:16,400 --> 00:26:23,800
+يعني بتعمل تحليل ل ال mercury في عيناه فلاجته
+
+336
+00:26:23,800 --> 00:26:35,600
+بيساوي 11.1 PPM 11.2 PPM 11.1 PPM 11.3 PPM 16.5
+
+337
+00:26:35,600 --> 00:26:42,340
+PPMبتقول طب أنا كل نتائجي كانت 11 11 11 11 ايش
+
+338
+00:26:42,340 --> 00:26:47,780
+معنى هذه النتيجة 16؟ هل النتيجة 16 نتيجة مقبولة
+
+339
+00:26:47,780 --> 00:26:51,240
+ولا يجب استبعادها؟
+
+340
+00:26:51,240 --> 00:26:56,020
+يجب استبعادها طب لو كانت 15 طب لو كانت 13
+
+341
+00:26:56,020 --> 00:27:01,320
+نستبعيدها ولا نخليها؟ طب لو كانت 12
+
+342
+00:27:04,740 --> 00:27:08,280
+يعني بعدين هنقول ممكن هو الواحد يعني أنا بجاوب عنك
+
+343
+00:27:08,280 --> 00:27:13,920
+بقول أنه أنت استخدمت شعورك يعني الشخصي في الحكم
+
+344
+00:27:13,920 --> 00:27:19,200
+على يعني قضية علمية قضية الاستباعد أستبعد أو لأ
+
+345
+00:27:19,200 --> 00:27:23,600
+لها قوانينبنقدرش احنا نستخدم شعورنا الشخصي في
+
+346
+00:27:23,600 --> 00:27:27,240
+الحكم على أشياء بتحكمها قوانين شعورك الشخصي
+
+347
+00:27:27,240 --> 00:27:31,420
+بتستخدمهم يعني .. يعني لو واحد جالك والله يعني
+
+348
+00:27:31,420 --> 00:27:34,980
+كافل جو اليوم تقوله والله حر كتير واحد تاني بيقولك
+
+349
+00:27:34,980 --> 00:27:38,420
+لا والله حلو مثلا هذا شعور شخصي يعنيممكن تفوت فيه،
+
+350
+00:27:38,420 --> 00:27:41,180
+وممكن زميل برضه زميلك يقولك والله لأ أنا بدي
+
+351
+00:27:41,180 --> 00:27:44,740
+أخليها، حسب شعوبه الشخص هو يعني، زي ما كنا بنقول
+
+352
+00:27:44,740 --> 00:27:46,780
+في الـSignificant Figure في البداية اللي ما نتعلم،
+
+353
+00:27:46,780 --> 00:27:49,700
+كنا بنقول نسيب رقم عشر، واحد، ولا اتنين، ولا
+
+354
+00:27:49,700 --> 00:27:52,620
+تلاتة، ولا اربعة، ولا خمسة، ولا نسيب الكل اللي
+
+355
+00:27:52,620 --> 00:27:56,060
+بيطلع في الآية الحاسبةيعني كل واحد لو بدأ نتركه
+
+356
+00:27:56,060 --> 00:27:59,960
+حسب شعوره كان اللي جيناه يعني فيه عندنا تمايز بين
+
+357
+00:27:59,960 --> 00:28:06,200
+الطلاب أو بين الناس وكله غلط لأنه احنا فيه عندنا
+
+358
+00:28:06,200 --> 00:28:12,360
+قوانين بنحكم فيها على أكم عدد نخلي مثلا على يمين
+
+359
+00:28:12,360 --> 00:28:15,260
+العلامة العشرية على سن مثال لأن هذا له دعوة بالدقة
+
+360
+00:28:15,260 --> 00:28:18,320
+له دعوة بإدارة القياس له دعوة بعدد السجن والفجرز
+
+361
+00:28:18,320 --> 00:28:22,020
+اللي حسب القوان اللي اتعلمناهافنفس الكلام لنتيجة
+
+362
+00:28:22,020 --> 00:28:27,020
+تطلع انت نتائج ويطلع منهم نتائج او نتيجة تبدو شاذة
+
+363
+00:28:27,020 --> 00:28:33,520
+فهل نستبعد النتيجة اللي تبدو شاذة ولا نحتفظ فيها
+
+364
+00:28:33,520 --> 00:28:38,620
+بنقول بدنا نطبق ال Q rejection test بدنا نطبق ال Q
+
+365
+00:28:38,620 --> 00:28:40,900
+rejection test ايش هو ال Q rejection test ده اللي
+
+366
+00:28:40,900 --> 00:28:48,690
+والله ال Q بتساوي A على W حيث ايههو الفرق بين
+
+367
+00:28:48,690 --> 00:28:53,550
+النتيجة الشاذة حسب وجهة نظرات وأقرب نتيجة إلها
+
+368
+00:28:56,270 --> 00:29:01,590
+و ال W جال النتيجة الشاذة و أبعد نتيجة عنها عشان
+
+369
+00:29:01,590 --> 00:29:06,410
+هيك بالضرورة دائما ال Q كثر لأنه دائما ال نتيجة A
+
+370
+00:29:06,410 --> 00:29:10,370
+اللي هي في البصد النتيجة الشاذة الفرق ما بينها و
+
+371
+00:29:10,370 --> 00:29:14,850
+ما بين أقرب نتيجة إلها قليل بينما المقام النتيجة
+
+372
+00:29:14,850 --> 00:29:19,430
+الشاذة و أبعد نتيجة عنها كبير فبالضرورة ال Q دائما
+
+373
+00:29:19,430 --> 00:29:24,090
+لازم تكون أقل من واحد عكس ال Fالـ Q لازم يكون ..
+
+374
+00:29:24,090 --> 00:29:27,850
+اعملت أكتر من واحد ما سألت غلط انتهى خلاص يعني كل
+
+375
+00:29:27,850 --> 00:29:31,050
+إجابة غلط ماحدش يقول اللي والله هين كاتب القانون
+
+376
+00:29:31,050 --> 00:29:36,130
+صح هين مثلا .. لا ماصبتش احنا
+
+377
+00:29:36,130 --> 00:29:42,410
+يا شباب عادة إيش بنسوي؟ بنجيب قيمة الـ Q المحسوبة
+
+378
+00:29:42,410 --> 00:29:48,250
+حسابا يعني وبنقارنها بـ Q المجدولة في عندنا جداول
+
+379
+00:29:48,250 --> 00:29:52,660
+الـ Q نعم زي ال F و زي ال T في عندنا Q tablesالـ Q
+
+380
+00:29:52,660 --> 00:30:03,520
+-table عند 90% و95% و99% و99.9% و99.9% و99.9% و99
+
+381
+00:30:03,520 --> 00:30:05,300
+.9% و99.9% و99.9% و99.9% و99.9% و99.9% و99.9% و99
+
+382
+00:30:05,300 --> 00:30:05,900
+.9% و99.9% و99.9% و99.9% و99.9% و99.9% و99.9% و99
+
+383
+00:30:05,900 --> 00:30:05,900
+.9% و99.9% و99.9% و99.9% و99.9% و99.9% و99.9% و99
+
+384
+00:30:05,900 --> 00:30:06,100
+.9% و99.9% و99.9% و99.9% و99.9% و99.9% و99.9% و99
+
+385
+00:30:06,100 --> 00:30:06,440
+.9% و99.9% و99.9% و99.9% و99.9% و99.9% و99.9% و99
+
+386
+00:30:06,440 --> 00:30:10,360
+.9% و99.9% و99.9% و99.9%
+
+387
+00:30:17,710 --> 00:30:22,390
+على نقيب ال F تابل وال T تابل اللي شفناها سابقا
+
+388
+00:30:22,390 --> 00:30:29,290
+هان بنتكلم عن number of observations عدد النتائج
+
+389
+00:30:29,290 --> 00:30:32,550
+مش ال degrees of freedom في ال F و ال T إيش كنا
+
+390
+00:30:32,550 --> 00:30:35,950
+بنقول degrees of freedom لكن في ال Q إيش بنقول
+
+391
+00:30:35,950 --> 00:30:40,590
+number of observations أو number of results كويس
+
+392
+00:30:40,590 --> 00:30:44,730
+number of data points كلهامش ال degrees of freedom
+
+393
+00:30:44,730 --> 00:30:49,270
+فانا بده اشتغل عند ال 95% عادة فبشوف الله كم تجربة
+
+394
+00:30:49,270 --> 00:30:53,030
+عملت اذا بقرا ال Q على طول مثلا عملت تمام تجارب
+
+395
+00:30:53,030 --> 00:31:00,270
+اذا ال Q 0.526 مفهومة تمام تجارب يبقى 0.526 عملت
+
+396
+00:31:00,270 --> 00:31:06,900
+تلاتين تجربة اذا عند 95% 0.298 و هكذاطيب نحاول
+
+397
+00:31:06,900 --> 00:31:12,660
+نشوف مثال نتعلم فيه كيف نحكم على value معينة إذا
+
+398
+00:31:12,660 --> 00:31:17,680
+ما كان يجب استبعادها أو الاحتفاظ فيهافخليني أطلع
+
+399
+00:31:17,680 --> 00:31:21,200
+على التجربة التالية بيقول in the replicate
+
+400
+00:31:21,200 --> 00:31:26,900
+determination of gold في عندي تجربة بقدر فيها
+
+401
+00:31:26,900 --> 00:31:35,760
+الدهب في عيناه فلجأته 96% 99% 97% 94% 100% 95% و
+
+402
+00:31:35,760 --> 00:31:41,000
+72% بنيجي نطلع على 72% و نقول يا ربي هذا القراية
+
+403
+00:31:41,000 --> 00:31:47,790
+إيش مالها قد تبدو يعني شاذة طب نخليها ولا ..هو
+
+404
+00:31:47,790 --> 00:31:51,390
+بيقول اتشيك whether any point should be excluded
+
+405
+00:31:51,390 --> 00:31:54,990
+at the 95% confidence level ولا لأ يعني اذا كنت
+
+406
+00:31:54,990 --> 00:32:01,270
+تشتغل على مستوى ثقة 95% فهل يمكن استبعاد اي نتيجة
+
+407
+00:32:01,270 --> 00:32:06,950
+من نتائج المذكورةإذا كان الـ tabulated Q 95%
+
+408
+00:32:06,950 --> 00:32:11,670
+confidence level بالساعة 0.568 for 7 observations
+
+409
+00:32:11,670 --> 00:32:15,330
+المفروض أن هي لـ 7 observations اللي شفناها غير في
+
+410
+00:32:15,330 --> 00:32:18,810
+الجدول ما علينا، بس على أساس أن هذا القيمة اللي
+
+411
+00:32:18,810 --> 00:32:24,950
+معطق معانا يعنيفإيش بنقول؟ بدنا نجرب على هذا
+
+412
+00:32:24,950 --> 00:32:28,430
+السؤال، إيش بنعمل يا شباب، يا طيبين، يا محترمين؟
+
+413
+00:32:28,430 --> 00:32:33,110
+بنقول أول شغل بنعملها، بنرتب النتائج تبعتنا ترتيب،
+
+414
+00:32:33,110 --> 00:32:37,650
+تصعدي أو تنازلي، ممنوع إنك تشتغل على نتائج زي ما
+
+415
+00:32:37,650 --> 00:32:42,650
+هو بعطيها لك، لأ، بدك ترتبها يا تصعدي، يا تنازلي،
+
+416
+00:32:42,650 --> 00:32:46,720
+فبتصفي نتيجة الشاشة، يا في الأول، يا في الآخرمعايا
+
+417
+00:32:46,720 --> 00:32:51,100
+مش في النص، يا في الأول يا في الآخر طيب، الان
+
+418
+00:32:51,100 --> 00:32:57,440
+رطبناهم 72, 94, 95, 96, 97, 99 و100 بقول بدي أجيب
+
+419
+00:32:57,440 --> 00:33:03,260
+ال A، ال A قال و الله هيهم، الفرق 94 ناقص 72 طب ال
+
+420
+00:33:03,260 --> 00:33:10,780
+W 100 ناقص 72، لو عملناها بيطلع عندي 0.79الـ A هين
+
+421
+00:33:10,780 --> 00:33:13,960
+عمال بقولك الـ A الفرق بين نتيجة الشاذة و أقرب
+
+422
+00:33:13,960 --> 00:33:19,020
+نتيجة إلها و ال W هي الفرق بين نتيجة الشاذة و أبعد
+
+423
+00:33:19,020 --> 00:33:23,680
+نتيجة عنها تفضل فكانت نتيجة الشاذة أكبر من نتيجة
+
+424
+00:33:23,680 --> 00:33:28,720
+الشاذة هي هي نفس الكلام أقرب
+
+425
+00:33:28,720 --> 00:33:31,240
+إلها هي نفس الكلام أقرب نتيجة إلها و أبعد نتيجة
+
+426
+00:33:31,240 --> 00:33:38,940
+عنها في المهم في النهاية موجبة يعنيأكبر من Q tab
+
+427
+00:33:38,940 --> 00:33:45,580
+إذا النتيجة 72% يجب استبعدها لأنها مش ناشئة بمعنى
+
+428
+00:33:45,580 --> 00:33:49,300
+آخر مش ناشئة عن random error لأ في عندك مشكلة
+
+429
+00:33:49,300 --> 00:33:52,720
+أساسية في التجربة اللي انت عملتها يعني التجربة
+
+430
+00:33:52,720 --> 00:33:55,180
+ماعطتك هذه النتيجة نتيجة random error يعني خطأ
+
+431
+00:33:55,180 --> 00:34:03,060
+طبيعي لأ والله في عندك خطأ يعني أساسي طب نيجي نغير
+
+432
+00:34:03,060 --> 00:34:13,540
+تغيير بسيط كتيربدل الـ 72 في عندى 88% برده بنرتب
+
+433
+00:34:13,540 --> 00:34:22,060
+ترتيب ايه تصعدي او تنازلي فبنقول 88,94,95,96,97,99
+
+434
+00:34:22,060 --> 00:34:31,900
+,100 بنجي بنقول a 94-88 على w 100-88 فبتطلع عندى
+
+435
+00:34:31,900 --> 00:34:37,470
+ال Q Calc 0.5طبعا الـ Q Calculate الـ 0.5 أقل من
+
+436
+00:34:37,470 --> 00:34:43,570
+الـ Q Tab معناه الكلام النقطة أو ال data point أو
+
+437
+00:34:43,570 --> 00:34:50,210
+النتيجة 88% لا يمكن استبعدها أنا بأنصح .. أنا
+
+438
+00:34:50,210 --> 00:34:54,270
+بأنصح .. يعني أنا مانعش أطلع على 88 أنا شخصيا يعني
+
+439
+00:34:54,270 --> 00:34:57,690
+لو بستخدم شعور البشر يعني بقول والله أنا بدي
+
+440
+00:34:57,690 --> 00:35:01,350
+أستبعدها لكن مستبعدهاش هيك لما يكون في عندي عدد
+
+441
+00:35:01,350 --> 00:35:08,460
+نتائج قليلأنا بفضل أنه أعمل تجارب أخرى، أعملي كمان
+
+442
+00:35:08,460 --> 00:35:17,620
+تربع تجارب علشان بس أكون أنا متأكد أكتر يعنى ما
+
+443
+00:35:17,620 --> 00:35:22,420
+هي ال Q كانت أصغر هذه عشان هيك خليتها
+
+444
+00:35:31,170 --> 00:35:40,090
+طيب يا شباب خليني أتكلم عن يعني موضوع أخر بتتكلم
+
+445
+00:35:40,090 --> 00:35:44,850
+عن ال linear least squares الآن احنا و احنا في
+
+446
+00:35:44,850 --> 00:35:52,850
+المختبر بنعمل قياسات بنعمل قياساتالقياسات هذه عادة
+
+447
+00:35:52,850 --> 00:35:58,650
+يعني ممكن نرسمها على اي graph خط مستقيم معادلة خط
+
+448
+00:35:58,650 --> 00:36:03,310
+مستقيم او خط مستقيم فالخط المستقيم بنحاول انه يمر
+
+449
+00:36:03,310 --> 00:36:08,020
+بالنقاط اللي انا حصلت عليهالو كانت النقاط
+
+450
+00:36:08,020 --> 00:36:10,740
+scattered يعني منتشرة شوية مش على الخط بالظبط
+
+451
+00:36:10,740 --> 00:36:17,740
+فبحاول ان ارسم الخط بحيث انه يمرأ بمعظم النقاط او
+
+452
+00:36:17,740 --> 00:36:21,920
+انه يعني عدد النقاط اللي اعلى تكون عدد النقاط اللي
+
+453
+00:36:21,920 --> 00:36:27,040
+اقل و انه يمر تقريبا بينهم في النص يعني لكن يا
+
+454
+00:36:27,040 --> 00:36:31,000
+شباب من ناحية عملية لو قلنالكم والله اه هي النقاط
+
+455
+00:36:31,000 --> 00:36:34,640
+و ارسم الخط هذا تأكدوا ان مافيش واحد فيكم راح يرضع
+
+456
+00:36:34,640 --> 00:36:38,910
+عن رسمة زميلهيقولوا بس لو انك شديته هذا لفوق شوية
+
+457
+00:36:38,910 --> 00:36:43,530
+من هنا، مش جاي في النص بزوله شدته لتحت شوية، لو
+
+458
+00:36:43,530 --> 00:36:47,550
+يعني نجلته كله لفوق، لو غيرت ال slope تبعه ..
+
+459
+00:36:47,550 --> 00:36:51,970
+المهم فيش حد هيرضى بعمل غيره، ليش؟ لأنه برضه هذا
+
+460
+00:36:51,970 --> 00:36:55,770
+شعور شخصي أنه والله خط يمر بين النقاط، أنا والله
+
+461
+00:36:55,770 --> 00:37:00,010
+شايفه هذا الخط كويس، غيري مش شايفه خط كويس، بنقدرش
+
+462
+00:37:00,010 --> 00:37:01,510
+نحكم على الأمور بشكل 100%
+
+463
+00:37:04,380 --> 00:37:07,860
+هنا في الحقيقة بتحصل عندي مشكلة لأن لو قلتلكم
+
+464
+00:37:07,860 --> 00:37:14,520
+بالله لو سمحتوا كل واحد يجيبلي نتيجة قياس مثلا لو
+
+465
+00:37:14,520 --> 00:37:17,440
+اعطيتكم انا نقطة على ال y axis و نقطة على ال x
+
+466
+00:37:17,440 --> 00:37:21,300
+شوفوني هيجي اداش كل واحد فيكم هيعطيني نتيجة مختلفة
+
+467
+00:37:21,300 --> 00:37:23,340
+عشان ايك احنا في الكيمة التحليلية في الحقيقة
+
+468
+00:37:23,340 --> 00:37:28,440
+بنهتمش كتير برسم الخط المستقيم بهمليش ان الخط يرسم
+
+469
+00:37:28,440 --> 00:37:32,140
+و اشوف والله بالظبط شكله منيح ولا لأهو ايش اللي
+
+470
+00:37:32,140 --> 00:37:37,720
+بهمني اللي بهمني ان اوجد معادلة الخط المستقيم اوجد
+
+471
+00:37:37,720 --> 00:37:41,680
+معادلة الخط المستقيم لانه لو انا عرفت معادلة الخط
+
+472
+00:37:41,680 --> 00:37:46,280
+المستقيم و اعطيتك النقطة Y و قلتلك هاتلي X كلكم
+
+473
+00:37:46,280 --> 00:37:50,640
+هتطلعوا نفس النتيجة صح ولا لأ فاحنا بدنا نتعلم كيف
+
+474
+00:37:51,640 --> 00:37:56,840
+نوجد معادلة الخط المستقيم كيف نوجد معادلة الخط
+
+475
+00:37:56,840 --> 00:38:00,140
+المستقيم لأنه إذا أوجدنا معادلة الخط المستقيم
+
+476
+00:38:00,140 --> 00:38:06,840
+انتهى صار في عنا قدرة على عمل
+
+477
+00:38:06,840 --> 00:38:11,840
+report للنتائج بشكل دقيق جدا و الكل متفق عليه
+
+478
+00:38:11,840 --> 00:38:17,030
+مافيش حاجة بيقول لأطيب كيف ممكن نوجد معادلة الخط
+
+479
+00:38:17,030 --> 00:38:20,710
+المستقيم؟ في طريقة في الحقيقة بنقولها linear least
+
+480
+00:38:20,710 --> 00:38:24,170
+squares انا ممكن يعني افهمها لكم يعني ببساطة
+
+481
+00:38:24,170 --> 00:38:30,550
+كالتالي في عندي نقطة هيكم شايفينها المركز تبعها
+
+482
+00:38:30,550 --> 00:38:35,690
+فوق مركز الخط بشوية في عندي نقطة تانية واضح انه
+
+483
+00:38:35,690 --> 00:38:43,710
+بعيد اعلى من الخط صحيح؟ طيب هذه النقطةتحت الخط و
+
+484
+00:38:43,710 --> 00:38:48,090
+في مسافة واسعة و النقطة اللى فوق تحت الخط من مركز
+
+485
+00:38:48,090 --> 00:38:51,150
+الخط في مسافة تعالوا في ال linear least squares
+
+486
+00:38:51,150 --> 00:38:56,850
+method ايش بنسوي مربع المسافة من مركز النقطة لمركز
+
+487
+00:38:56,850 --> 00:39:01,530
+الخط كويس و مربع المسافة خلينا ناخد النقاط اللى
+
+488
+00:39:01,530 --> 00:39:07,630
+تحت و مربع المسافة النقطة اللى بقي ده فوقمن مركز
+
+489
+00:39:07,630 --> 00:39:12,530
+النقطة لمركز الخط لو بده اخلي مربعات المسافة هذه
+
+490
+00:39:12,530 --> 00:39:18,990
+اقل ما يمكن ايش الخط بده يحصله؟ هينزلت هينشد لتحت
+
+491
+00:39:18,990 --> 00:39:25,350
+مظبوط لحظة شوية المهم روح ينزل لوين لتحت طيب بنفس
+
+492
+00:39:25,350 --> 00:39:30,570
+الطريقة لو انا قلت بده اخلي مربع المسافة بين
+
+493
+00:39:30,570 --> 00:39:35,220
+النقطة هذه ومركز الخط و النقطة هذه ومركز الخطأقل
+
+494
+00:39:35,220 --> 00:39:40,580
+ما يمكن، بدي يرتفع لفوق، طب لو أنا خليت الآن مربع
+
+495
+00:39:40,580 --> 00:39:43,680
+المسافات هذه اللي فوق و اللي تحت أقل ما يمكن، من
+
+496
+00:39:43,680 --> 00:39:47,800
+وين الخط بدي يمشي؟ بدي يمشي بينهم بالـ .. يعني
+
+497
+00:39:47,800 --> 00:39:52,000
+عشان بيمشي الطريقة بحيث انه يخلي مربعات المسافات
+
+498
+00:39:52,000 --> 00:39:56,180
+هذه أشمالها أقل ما يمكن، وبالتالي بيمشي صح 100%
+
+499
+00:39:56,180 --> 00:40:02,680
+علشان هيك، هذا بيعطيني يعني معادلة أكيد صح، بشكل
+
+500
+00:40:02,680 --> 00:40:08,980
+100%كيف أنا بستفيد من هذا الكلام؟اللي هي ال
+
+501
+00:40:08,980 --> 00:40:12,040
+squares بتقولي والله هو عندي انا اصلا ال y بتساوي
+
+502
+00:40:12,040 --> 00:40:15,460
+mx زائد b هذه معادلة خط المستقيم حيث ال y هي
+
+503
+00:40:15,460 --> 00:40:20,440
+النقطة على ال y axis و ال m هي ال slope و ال x هي
+
+504
+00:40:20,440 --> 00:40:25,040
+عادة ال concentration او ال x axis ال x axis عادة
+
+505
+00:40:25,040 --> 00:40:28,580
+عندي انا ال concentration الترقيز و ال b هي ال
+
+506
+00:40:28,580 --> 00:40:31,720
+intercept اللي هي لو اجهنا لوراها ده هو هذه
+
+507
+00:40:31,720 --> 00:40:37,100
+المسافة يعني التقاطع التقاطع ال y axis مع ال
+
+508
+00:40:37,100 --> 00:40:42,340
+straight lineبنقول عشان نحصل على هذه المعادلة لأي
+
+509
+00:40:42,340 --> 00:40:47,000
+خط مستقيم عشان أحصل على معادلة الخط المستقيم باجي
+
+510
+00:40:47,000 --> 00:40:51,500
+بجيب ال slope في البداية ال slope اول خطوة ان اجيب
+
+511
+00:40:51,500 --> 00:40:56,300
+ايه ال slope ال slope اللي هي ال M بيساوي نفتح جوس
+
+512
+00:40:56,300 --> 00:41:03,430
+summation X1 في Y1 زاد X2 في Y2زاد X تلاتة في Y
+
+513
+00:41:03,430 --> 00:41:08,390
+تلاتة زاد X أربعة في Y أربعة أنا عندي Y وعندي X
+
+514
+00:41:08,390 --> 00:41:13,170
+عددهم متساوى كل لقطة XY فيها كويس يعني كل تركيز
+
+515
+00:41:13,170 --> 00:41:16,250
+فيه إله signal كل تركيز بجيسه إله signal كل تركيز
+
+516
+00:41:16,250 --> 00:41:19,570
+إله signal فعدد ال X بيساوى عدد ال Y فال X واحد Y
+
+517
+00:41:19,570 --> 00:41:23,150
+واحد يعني ال X واحد في ال Y واحد X اتنين في ال Y
+
+518
+00:41:23,150 --> 00:41:25,850
+اتنين X تلاتة في ال Y اتنين بجمعهم head summation
+
+519
+00:41:25,850 --> 00:41:30,190
+X I Y I minusفتح جثة كبيرة بس فارجيكم إيش هدول
+
+520
+00:41:30,190 --> 00:41:35,770
+summation xi and ال x1 x2 x3 x4 مجموعة هو عبارة عن
+
+521
+00:41:35,770 --> 00:41:39,830
+summation xi summation yi هي عبارة عن y1 زائد y2
+
+522
+00:41:39,830 --> 00:41:45,470
+زائد y3 زائد y4 summation yi طيب على n اللي هو
+
+523
+00:41:45,470 --> 00:41:52,070
+عددهم عرض النقاطSummation X I تربية يعني X واحد
+
+524
+00:41:52,070 --> 00:41:55,910
+تربية زايد X اتنين تربية زايد X تلاتة تربية زايد X
+
+525
+00:41:55,910 --> 00:41:59,370
+أربعة تربية إلى آخره فهذه معناته summation X I
+
+526
+00:41:59,370 --> 00:42:06,010
+تربية minus نفتح جوز summation X I كله تربية يعني
+
+527
+00:42:06,010 --> 00:42:08,790
+بدي أجمع X واحد زايد X اتنين زايد X تلاتة زايد X
+
+528
+00:42:08,790 --> 00:42:13,470
+أربعة وكله إيش أسوي في الآخر أربع المجموع على إن
+
+529
+00:42:13,470 --> 00:42:20,150
+اللي هو عددهم هيك إيش بكون عملت بكون طلعت ال Mطب
+
+530
+00:42:20,150 --> 00:42:26,310
+انا عندي نقاط X1 X2 X3 الاخره وانا نقاط Y1 Y2 Y3
+
+531
+00:42:26,310 --> 00:42:31,090
+الاخره جال ايش بقدر اجيب؟ بقدر اجيب ال average ل Y
+
+532
+00:42:31,090 --> 00:42:35,670
+و ال average ل X إذا كان ال Y بتسوى MX زائد B إذا
+
+533
+00:42:35,670 --> 00:42:42,650
+ال Y bar أو ال average بتسوى MX bar زائد B مدام
+
+534
+00:42:42,650 --> 00:42:46,550
+هذا ال Y بتسوى MX زائد B لو حطيت hand bar بحط hand
+
+535
+00:42:46,550 --> 00:42:52,700
+bar سهل الموضوعماشي اذا ان اجيب ال y bar هذا سهل
+
+536
+00:42:52,700 --> 00:42:55,420
+كتير بدي اجمع ال y واحد و ال y اتنين واحد باقطين
+
+537
+00:42:55,420 --> 00:42:59,600
+ال summation yi باقسم على عددهم باقطين ال y bar طب
+
+538
+00:42:59,600 --> 00:43:04,660
+و ال x bar برضه نفس الكلام مجموهم على عددهم بقدر
+
+539
+00:43:04,660 --> 00:43:10,180
+انا ا go اذا ال b بتساوي ال y bar minus ال mx bar
+
+540
+00:43:10,180 --> 00:43:14,960
+اذا هيك بكون جبت ال bمدام جبت ال M إجهبت ال B سهل
+
+541
+00:43:14,960 --> 00:43:19,720
+جدا بس ال M هي المهمة بس ال M هي اللي ممكن نقول
+
+542
+00:43:19,720 --> 00:43:25,320
+نتغلب في حسابها شوية نقسم على X bar نقسمش على X
+
+543
+00:43:25,320 --> 00:43:29,970
+barبنقسمش على X bar بنقول انه ال Y bar بتساوي MX
+
+544
+00:43:29,970 --> 00:43:35,210
+bar زائد B طب ال M معانا ال M معانا و ال X bar
+
+545
+00:43:35,210 --> 00:43:40,070
+معانا و ال Y bar معانا ايش بطلع منها ال B اذا طلعت
+
+546
+00:43:40,070 --> 00:43:44,950
+ال B و ال M اذا صارت المعادلة A كلها معايا عند اي
+
+547
+00:43:44,950 --> 00:43:48,470
+نقطة من ال Y بقدر احسب ال X هي المعادلة اذا كان
+
+548
+00:43:48,470 --> 00:43:54,120
+انا اعطيتك Signal بقدر احسب منها ال Aال X مدام
+
+549
+00:43:54,120 --> 00:43:57,880
+اعطيتك قيمة ال signal اذا بقدر احسب التركيز وهذا
+
+550
+00:43:57,880 --> 00:44:01,580
+هو المهم و مافيش حد فينا بيغلط فيه مدام حسبنا ال M
+
+551
+00:44:01,580 --> 00:44:06,220
+صح و من النقاط بحسب ال B صح اذا المعادلة هذه صارت
+
+552
+00:44:06,220 --> 00:44:11,640
+سليمة لو اعطيتك اي Y ايش بتجيب تعطيني انت ال X
+
+553
+00:44:11,640 --> 00:44:15,720
+تبعها اللي هو ال X axis اللي انا بدوراني اللي هو
+
+554
+00:44:15,720 --> 00:44:16,380
+التركيز
+
+555
+00:44:19,060 --> 00:44:24,300
+لو حبينا طيب احنا عموما خلينا نوجه في اليوم and
+
+556
+00:44:24,300 --> 00:44:27,860
+هذا النقطة والحصة الجاية اذا الله راضي بنتكلم عن
+
+557
+00:44:27,860 --> 00:44:29,120
+المثال
+
diff --git a/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/iFDrwq-eXd0_postprocess.srt b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/iFDrwq-eXd0_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..db44b1bdf7d0f6a716c7f338d7f749850e6284cf
--- /dev/null
+++ b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/iFDrwq-eXd0_postprocess.srt
@@ -0,0 +1,2156 @@
+1
+00:00:21,400 --> 00:00:25,760
+بسم الله الرحمن الرحيم الحصة الماضية يا شباب كنا
+
+2
+00:00:25,760 --> 00:00:30,960
+اتكلمنا عن ال polyprotic acids وشوفنا كيف بنحسب ال
+
+3
+00:00:30,960 --> 00:00:34,900
+pH لل polyprotic acids بشكل أساسي كنا بنطلع على
+
+4
+00:00:34,900 --> 00:00:39,540
+قيمة ال equilibrium constants للتفككات التفكك
+
+5
+00:00:39,540 --> 00:00:43,580
+الأول والتفكك التاني تحديدا و بنقسم KA1 على KA2
+
+6
+00:00:43,580 --> 00:00:49,010
+إذا كان لجناه أكتر من 100 فمعناته التفكك التانيلا
+
+7
+00:00:49,010 --> 00:00:56,210
+يشارك بكمية يعني معقولة من ال H بلس أو بكمية مهمة
+
+8
+00:00:56,210 --> 00:00:59,590
+من ال H بلس وبالتالي يمكن إلغاءه وبنعتبر فقط
+
+9
+00:00:59,590 --> 00:01:04,910
+التفكك الأول اليوم قبل ما ننتقل لل source of
+
+10
+00:01:04,910 --> 00:01:11,830
+polypotic acids بس بدنا نتكلم عن حاجة بنقولها
+
+11
+00:01:11,830 --> 00:01:19,280
+fractions of dissociating species at given pHلو
+
+12
+00:01:19,280 --> 00:01:22,260
+كان في عنا حاجة زي الـ Phosphoric Acid على سبيل
+
+13
+00:01:22,260 --> 00:01:27,340
+المثال ال Phosphoric Acid كلنا بنعرف أنه في
+
+14
+00:01:27,340 --> 00:01:34,000
+المحلول بيتجزأ يعني لو حطينا مثلا واحد مول من ال
+
+15
+00:01:34,000 --> 00:01:38,540
+Phosphoric Acid في واحد لتر فبنقول أن ال
+
+16
+00:01:38,540 --> 00:01:43,970
+Phosphoric Acid اللي حطيناه في المحلول بيتجزأبحيث
+
+17
+00:01:43,970 --> 00:01:49,770
+انه جزء منه بيبقى على حالته كphosphoric acid H3PO4
+
+18
+00:01:49,770 --> 00:01:58,090
+جزء منه بتحول ال H2PO4 سالب جزء منه بتحول ال HPO4
+
+19
+00:01:58,090 --> 00:02:04,410
+2 سالب وجزء منه بتحول ال PO4 3 سالب مجموعة الأجزاء
+
+20
+00:02:04,410 --> 00:02:09,600
+هذههو عبارة عن التركيز الكلي للفسفوريك أسد، مجموع
+
+21
+00:02:09,600 --> 00:02:13,700
+الأجزاء هو عبارة عن التركيز الكلي للفسفوريك أسد
+
+22
+00:02:19,890 --> 00:02:25,990
+أضفنا H بلس أو هيدروكسيد للمحلول هذا لو أضفنا H
+
+23
+00:02:25,990 --> 00:02:30,210
+بلس أو هيدروكسيد مثلا نتكلم عن ضعف ال H بلس طبعا
+
+24
+00:02:30,210 --> 00:02:35,710
+ال H بلس راح يتفاعل مع ال negatively charged ions
+
+25
+00:02:35,710 --> 00:02:40,670
+ويحولها ل less negatively charged ionsفهيتفاعل مع
+
+26
+00:02:40,670 --> 00:02:47,850
+ال H2PO4 سالب و يحول جزء منها لH3PO4 هيتفاعل مع ال
+
+27
+00:02:47,850 --> 00:02:53,370
+HPO42 سالب يحولها لH2PO4 سالب هيحول جزء من
+
+28
+00:02:53,370 --> 00:02:59,670
+الفوسفات لمثلا الهيدروجين فوسفاتعكس هذا الكلام لو
+
+29
+00:02:59,670 --> 00:03:04,370
+أضافنا Hydroxide الـ Hydroxide راح يقلل لـ Protons
+
+30
+00:03:04,370 --> 00:03:08,990
+اللي في المحلول وبالتالي مثلا الـ H3PO4 في وجود
+
+31
+00:03:08,990 --> 00:03:13,570
+الـ Hydroxide راح يتفاعل جزء منه ويتحول للـ H2PO4
+
+32
+00:03:13,570 --> 00:03:19,870
+سالب الـ H2PO4 ممكن جزء منه يتحول للـ HPO4 و هكذا
+
+33
+00:03:19,870 --> 00:03:25,970
+و هكذا معنى الكلام أنا عند إضافة H Plus أو
+
+34
+00:03:25,970 --> 00:03:26,830
+Hydroxide
+
+35
+00:03:29,790 --> 00:03:35,710
+الأجزاء أو ال fractions من هذه ال species بتتغير
+
+36
+00:03:35,710 --> 00:03:37,030
+بتغير ال pH
+
+37
+00:03:43,530 --> 00:03:48,590
+أحسب جداش موجود على صورة مثلا phosphoric acid عند
+
+38
+00:03:48,590 --> 00:03:54,250
+pH معينة جداش موجود على صورة HPO42 سالب عند نفس ال
+
+39
+00:03:54,250 --> 00:03:58,070
+pH جداش موجود على هيئة phosphate عند نفس ال pH
+
+40
+00:03:58,070 --> 00:04:02,210
+جداش موجود على هيئة H2PO4 سالب عند نفس ال pH
+
+41
+00:04:02,210 --> 00:04:08,330
+فمهمتي أني أعرف الأجزاء المختلفة من كل ال species
+
+42
+00:04:08,330 --> 00:04:12,510
+من ال species اللي عنديعشان اعرف هذه الكلام لابد
+
+43
+00:04:12,510 --> 00:04:17,970
+من تعريف ال alpha values او ال fractions فبقول
+
+44
+00:04:17,970 --> 00:04:23,130
+عندي حاجة بقولها alpha zero zero يعني zero charge
+
+45
+00:04:23,130 --> 00:04:26,570
+يعني مافيش عندى اي شحنة في ال phosphoric acid ايش
+
+46
+00:04:26,570 --> 00:04:29,570
+اللي مافيش فيه اي شحنة هو نفس ال phosphoric acid
+
+47
+00:04:29,570 --> 00:04:36,150
+H3PO4 يعني الجزء اللي لم يتفكك بقي على حاله لم
+
+48
+00:04:36,150 --> 00:04:40,140
+يتفككطيب ال alpha zero تساوي التركيز اللي هو at
+
+49
+00:04:40,140 --> 00:04:44,880
+equilibrium الفوسفوريك أسد at equilibrium على ال C
+
+50
+00:04:44,880 --> 00:04:51,080
+لل H3PO4 هذا عبارة عن التركيز الكلي لل H3PO4 كل ال
+
+51
+00:04:51,080 --> 00:04:57,340
+H3PO4 ال alpha one الواحد هذي بتعبر عن أيضا الشحنة
+
+52
+00:04:57,340 --> 00:05:02,300
+يعني ال species اللي عليه شحنة واحدة على التركيز
+
+53
+00:05:02,300 --> 00:05:07,930
+الكلي ايش اللي عليه شحنة واحدة جال ال H2PO4الـ
+
+54
+00:05:07,930 --> 00:05:14,470
+Alpha 2 اللي عليه شحنتين يعني HPO4 اتنين سالب على
+
+55
+00:05:14,470 --> 00:05:20,760
+التركيز الكلي ال Alpha 3 تلت شحناتPO4 ثلاثة سالب
+
+56
+00:05:20,760 --> 00:05:24,540
+على التركيز الكلية لاحظ انه مافيش عندي اربع شحنات
+
+57
+00:05:24,540 --> 00:05:27,200
+خلاص مافيش عندي اكتر من الف تلاتة من الفسوريكاسين
+
+58
+00:05:27,200 --> 00:05:30,880
+مافيش خلصه البروتونز مافيش عندي اكتر من الف تلاتة
+
+59
+00:05:30,880 --> 00:05:34,840
+الان لو ايه لو اجينا جمعنا Alpha Zero مع Alpha One
+
+60
+00:05:34,840 --> 00:05:38,340
+مع Alpha Two مع Alpha Three بنلاحظ انه بتساوي واحد
+
+61
+00:05:38,340 --> 00:05:44,920
+ليه؟ لأن البسط هيكون H3PO4 زائد H2PO4 سالب زائد
+
+62
+00:05:44,920 --> 00:05:50,080
+HPO4 اتنين سالب زائدPO4 تلاتة سارب هدول مجموعهم ما
+
+63
+00:05:50,080 --> 00:05:56,620
+هو الـC للـH3PO4 مجموع الأجزاء يساوي الكل معنى
+
+64
+00:05:56,620 --> 00:06:00,960
+الكلام مجموع ال fractions دائما تساوي واحد صحيح
+
+65
+00:06:00,960 --> 00:06:05,980
+فلو عرفت انت مثلا تلاتة مش ضرور تحسب الرابعة كل
+
+66
+00:06:05,980 --> 00:06:09,780
+واحد ماقص مجموعة التلاتة بيعطيك الرابعة الان
+
+67
+00:06:09,780 --> 00:06:14,100
+الفكرة يا شباب انه انا عايز اعرف عند pH معينة مثلا
+
+68
+00:06:14,100 --> 00:06:17,520
+جديش عندي phosphoric acidإذا كنت بتعرف كده
+
+69
+00:06:17,520 --> 00:06:21,080
+فوسفوريك أسد يبقى لازم أجيب ال alpha 0 إذا جبتها و
+
+70
+00:06:21,080 --> 00:06:26,340
+أنا عارف تركيز الفوسفوريك أسد الكل يبقى بعرف تركيز
+
+71
+00:06:26,340 --> 00:06:30,800
+الفوسفوريك أسد at equilibrium معايا؟ لو أنا عايز
+
+72
+00:06:30,800 --> 00:06:35,640
+أعرف تركيز الفوسفات at equilibrium عن pH معينة
+
+73
+00:06:35,640 --> 00:06:39,660
+بقول لازم أحسب ال alpha 3 إذا كنت عارف قيمة ال
+
+74
+00:06:39,660 --> 00:06:43,540
+alpha 3 و أنا عارفالتركيز الكوني للفوسفوريك أسد
+
+75
+00:06:43,540 --> 00:06:48,640
+اللي حطيته بقدر أحسب تركيز الفوسفير وهكذا، اذا
+
+76
+00:06:48,640 --> 00:06:56,560
+مهمتي الآن أنه اوجد equations أو علاقاتمن خلالها
+
+77
+00:06:56,560 --> 00:07:00,320
+أقدر أحسب الـAlpha 0 والـAlpha 1 والـAlpha 2
+
+78
+00:07:00,320 --> 00:07:05,740
+والـAlpha 3 كمثال احنا هناخد طريقة حساب أو طريقة
+
+79
+00:07:05,740 --> 00:07:10,380
+اشتقاق معادلة للـAlpha 0 وبنفس الطريقة للـAlpha 1
+
+80
+00:07:10,380 --> 00:07:16,360
+والـAlpha 2 والـAlpha 3 فبنقول
+
+81
+00:07:16,360 --> 00:07:20,930
+في البداية خالص اذا كان انا بدي الـAlpha 0الألف
+
+82
+00:07:20,930 --> 00:07:24,010
+زيرو هي اللى بتتكلم عن ال zero charge يعني بتتكلم
+
+83
+00:07:24,010 --> 00:07:29,010
+عن الفوسفوريك أسد لوحده طبعا عند المجموعة الكلة لل
+
+84
+00:07:29,010 --> 00:07:34,390
+species بيساوى ال C للفوسفوريك أسدإذاً بدي أخلّي
+
+85
+00:07:34,390 --> 00:07:39,130
+كل الطرف الأيمن دالة في الفوسفوريك أسد، لماذا؟ لأن
+
+86
+00:07:39,130 --> 00:07:42,550
+الـAlpha Zero بتساوي الفوسفوريك أسد على التركيز
+
+87
+00:07:42,550 --> 00:07:45,790
+الكلي، فإذا كان أنا بدي أجيب الـAlpha Zero، بدي
+
+88
+00:07:45,790 --> 00:07:50,550
+أخلّي كل الطرف الأيمن دالة في إيه؟ في الفوسفوريك
+
+89
+00:07:50,550 --> 00:07:53,970
+أسد، لماذا؟ لأنه ممكن ساعتها أخد الفوسفوريك أسد
+
+90
+00:07:53,970 --> 00:07:58,200
+عامل مشترك، والفوسفوريك أسد والـC للـH3بأو 4
+
+91
+00:07:58,200 --> 00:08:02,100
+لتركيز الكولير الفاسفريكاسيد هدول حاصل قسمته عبارة
+
+92
+00:08:02,100 --> 00:08:07,850
+عن ال alpha 0أذا بدي أعوض عن الـH3PO4 بدلالة
+
+93
+00:08:07,850 --> 00:08:12,810
+الـH3PO4 يعني هذه حسيبها زي ما هي الـH2PO4 بدعوض
+
+94
+00:08:12,810 --> 00:08:18,070
+عنها بدلالة الـH3PO4 الـHPO42 سالب بدعوض عنها
+
+95
+00:08:18,070 --> 00:08:22,910
+بدلالة الـH3PO4 وأيضا الفوسفات بدعوض عنها بدلالة
+
+96
+00:08:22,910 --> 00:08:27,350
+الـH3PO4 كيف بعمل هذا الكلام؟ لو جينا نطلعه على
+
+97
+00:08:27,350 --> 00:08:32,710
+الـH2PO4 من الـKa1بقول K A1 بيساوي ال H2 P O4 ثالث
+
+98
+00:08:32,710 --> 00:08:38,530
+في ال H Plus على ال H3 P O4 انا بد ال H2 P O4 هدا
+
+99
+00:08:38,530 --> 00:08:43,110
+هي اذا ايش بتساوي؟ بتساوي ال K A1 في ال H3 P O4
+
+100
+00:08:43,110 --> 00:08:48,310
+على ال H Plus هيها ال H2 P O4 ساوي ال K A1 H3 P O4
+
+101
+00:08:48,310 --> 00:08:51,930
+على ال H Plus من وين جيبناها؟ من ال K A1
+
+102
+00:08:51,930 --> 00:08:57,820
+expression من ال K A1نفس الكلام لو اجيت انا ضربت
+
+103
+00:08:57,820 --> 00:09:02,800
+KA1 في KA2 راح ألاحظ ان ال HPO4 اللي هو هذا ال
+
+104
+00:09:02,800 --> 00:09:08,440
+term راح يسوى KA1 و KA2 في ال phosphoric acid على
+
+105
+00:09:08,440 --> 00:09:14,880
+ال H plus squared طب لو ضربت KA1 في KA2 في KA3 راح
+
+106
+00:09:14,880 --> 00:09:18,700
+ألاحظ انه اخر term اللي هو ال phosphate راح يسوى
+
+107
+00:09:18,700 --> 00:09:23,460
+KA1, KA2, KA3 في ال phosphoric acid على ال H plus
+
+108
+00:09:23,460 --> 00:09:25,440
+cubed
+
+109
+00:09:27,450 --> 00:09:33,650
+ماشي يا شباب طب لو عوضت عن هدول إيش بحصل؟ بحصل على
+
+110
+00:09:33,650 --> 00:09:39,370
+معادلة كبيرة كلها دالة في إيه؟في الفوسفوريك أسد طب
+
+111
+00:09:39,370 --> 00:09:44,290
+ناخد الفوسفوريك عامل مشترك و بعدين نقسم الفوسفوريك
+
+112
+00:09:44,290 --> 00:09:50,010
+أسد على c لل H3PO4 بلاحظ أن هذه هي ال alpha 0
+
+113
+00:09:50,010 --> 00:09:55,050
+بتساوي ال H plus تكعيب على H plus تكعيب زائد KA1 H
+
+114
+00:09:55,050 --> 00:10:00,610
+plus تربيع زائد KA1 KA2 H plus زائد KA1 KA2 KA3
+
+115
+00:10:01,810 --> 00:10:07,290
+كويس هذا او هذه طريقة اشتقاق ال alpha 0 بقول انا
+
+116
+00:10:07,290 --> 00:10:10,870
+اشتقاق ال alpha 1 وال alpha 2 وال alpha 3 بيتم
+
+117
+00:10:10,870 --> 00:10:16,270
+بنفس الطريقة بدي اشتق ال alpha 1 بدي اخلي ال c لل
+
+118
+00:10:16,270 --> 00:10:22,470
+H3PO4 كله يكون دالة في ال H2PO4 سالب لأن ال alpha
+
+119
+00:10:22,470 --> 00:10:30,380
+1 هي H2PO4 سالب على ال c لل H3PO4لكن لو اجينا احنا
+
+120
+00:10:30,380 --> 00:10:34,920
+اتطلعنا من ناحية عملية اكتر بقول انه لما .. لما
+
+121
+00:10:34,920 --> 00:10:40,160
+انا اجي اشتق ال alpha one هلاحظ انه يتساوي K A one
+
+122
+00:10:40,160 --> 00:10:46,030
+في ال H plus تربية على نفس المقامنفس المقام بيطلع
+
+123
+00:10:46,030 --> 00:10:50,210
+واحد هو هو طب لو جيت اشتق الألف اتنين بيلاقي K1 K2
+
+124
+00:10:50,210 --> 00:10:54,490
+في ال H plus على نفس المقام اذا المقام دائما هو هو
+
+125
+00:10:54,490 --> 00:11:00,430
+لما بدأت اشتق ال alpha 3 حدد K1 K2 K3 على المقام
+
+126
+00:11:00,430 --> 00:11:07,810
+نفسه اذا المقام ثابت في كل ال alpha values نفس
+
+127
+00:11:07,810 --> 00:11:13,230
+المقام لنفس المركب نفس المقاممش بس هيك لو جيت اطلع
+
+128
+00:11:13,230 --> 00:11:16,850
+تاني على هذا المقام بلاجئ ان هو عبارة عن قد
+
+129
+00:11:16,850 --> 00:11:23,230
+التيرمز اول term فيه هو لو انحط في ال bus بيعطيني
+
+130
+00:11:23,230 --> 00:11:27,230
+ال alpha zero تاني term فيه لو انحط في ال bus
+
+131
+00:11:27,230 --> 00:11:31,090
+بيعطيني ال alpha one تالت term فيه لو كان في ال
+
+132
+00:11:31,090 --> 00:11:36,110
+bus بيعطيني ال alpha two رابع term فيه لو كان في
+
+133
+00:11:36,110 --> 00:11:40,410
+ال bus بيعطينيالألف تلاتة وانت تطلع بالفئة اللي
+
+134
+00:11:40,410 --> 00:11:45,230
+هدا كلها صح ولا لأ هي h plus ال cube على المقام
+
+135
+00:11:45,230 --> 00:11:50,000
+لاحظ h plus هي ال term الأول اعطتك الف زيروفبال
+
+136
+00:11:50,000 --> 00:11:53,600
+term التاني k a one h plus squared هي ال alpha one
+
+137
+00:11:53,600 --> 00:11:58,040
+k a one h plus squared نفس المقام معايا يا شباب
+
+138
+00:11:58,040 --> 00:12:02,840
+فال alpha two هطلعها ك a one k a two في ال h plus
+
+139
+00:12:02,840 --> 00:12:06,380
+ك a one k a two في ال h plus يبقى نفس الحاجة اذا
+
+140
+00:12:06,380 --> 00:12:14,020
+سهل كتير انه اناأوصل لل alpha values سهل كتير عشان
+
+141
+00:12:14,020 --> 00:12:18,580
+نبسط المسألة أكتر بنقول طيب خلينا نتصور ان ال
+
+142
+00:12:18,580 --> 00:12:23,520
+phosphoric acid اللي عندي أكمل روتن فيه ثلاثة مش
+
+143
+00:12:23,520 --> 00:12:28,960
+هيك اذا بقول مادام فيه ثلاثة خليني أعمل المقام هاي
+
+144
+00:12:28,960 --> 00:12:34,580
+alpha مثلا zero ماذا تساوي هاي المقام تحدث عن
+
+145
+00:12:34,580 --> 00:12:40,060
+المقام مادام عندي phosphoric acidإذا تلاتة protons
+
+146
+00:12:40,060 --> 00:12:49,460
+is an H plus ده كيب ماشي بشوف المادة بدون أي شحنة
+
+147
+00:12:49,460 --> 00:12:54,620
+عليها أكم البروتون فيها جالي H3PO4 مافيش عليه ولا
+
+148
+00:12:54,620 --> 00:12:59,260
+شحنة يبقى تلاتة protons بدة بال H plus ايه ال cube
+
+149
+00:12:59,260 --> 00:13:04,860
+زائد خلاص ال R انتهى بقول KA1 تفكك تفكك بقال two
+
+150
+00:13:04,860 --> 00:13:05,500
+protons
+
+151
+00:13:08,160 --> 00:13:14,320
+و K1 و K2 بقى لبروتون اتفكك كمان تفكك راح لبروتون
+
+152
+00:13:17,240 --> 00:13:21,000
+الان يا شباب على طول هذه لو نحطت فوق بتعطينا ال
+
+153
+00:13:21,000 --> 00:13:24,060
+alpha 0 هذه لو نحطت فوق بتعطينا ال alpha 1 هذه لو
+
+154
+00:13:24,060 --> 00:13:26,400
+نحطت فوق بتعطينا ال alpha 2 هذه لو نحطت فوق
+
+155
+00:13:26,400 --> 00:13:30,800
+بتعطينا ال alpha 3 بده ال alpha 0 بحط ال H plus
+
+156
+00:13:30,800 --> 00:13:36,240
+تكريم اذا مجرد انا ماجيب المقام اقدرت على طول اجيب
+
+157
+00:13:36,240 --> 00:13:42,640
+ال alpha values مثلا لو عندي H2CO3 هذا carbonic
+
+158
+00:13:42,640 --> 00:13:50,680
+acid وانا عايز اجيب ال alpha 2 لهانتبهي شوية بقول
+
+159
+00:13:50,680 --> 00:13:56,580
+دائما ببدأ في ايه؟ في المقام بعمل المقام وبناء
+
+160
+00:13:56,580 --> 00:14:00,140
+عليه المسألة بتنحل اكمل بروتون عندي لأول نتشارج ال
+
+161
+00:14:00,140 --> 00:14:06,380
+species اتنين اذا اتش بلس تربيع زاد حصل تفكك يبقى
+
+162
+00:14:06,380 --> 00:14:12,220
+K A1 راح بروتون اتش بلس حصل كمان تفكك K A1 K A2
+
+163
+00:14:12,220 --> 00:14:16,100
+انا بدي Alpha 2 هذه تبعت ال Alpha 0 هذه تبعت ال
+
+164
+00:14:16,100 --> 00:14:20,220
+Alpha 1 هذه تبعت ال Alpha 2مش هيك؟ إذا إيش بده أحط
+
+165
+00:14:20,220 --> 00:14:27,840
+فوق؟ K A1 K A2 ماشي يا شباب إذا في مثل هذه الأحوال
+
+166
+00:14:27,840 --> 00:14:30,400
+كل ال assets ده بتجيبلي fractions تبعتها ال alpha
+
+167
+00:14:30,400 --> 00:14:36,840
+values أول شيء ببني المقام ببني المقام مدان بنيت
+
+168
+00:14:36,840 --> 00:14:41,700
+المقام انتهى جبت ال alpha value مباشرة احنا
+
+169
+00:14:41,700 --> 00:14:51,100
+هنتعامل بشكل أساسيمع .. يعني
+
+170
+00:14:51,100 --> 00:14:57,500
+assets زي هيك بالإضافة لحاجة بقولها H4Y اللي هي ال
+
+171
+00:14:57,500 --> 00:15:03,940
+EDTA برموزها بالرمز H4Y هان بجيبلها ال alpha 4
+
+172
+00:15:03,940 --> 00:15:07,180
+حاجة اللي هعوز ال alpha 4 في المستقبل هيمر معنا
+
+173
+00:15:07,180 --> 00:15:12,480
+هذا الكلام ال alpha 4 ايش هقول ايش بيساوي بقول H
+
+174
+00:15:12,480 --> 00:15:19,660
+plusقص أربعة زائد k a one h plus تلاتة زائد k a
+
+175
+00:15:19,660 --> 00:15:26,260
+one k a two h plus squared زائد k a one k a two k
+
+176
+00:15:26,260 --> 00:15:33,580
+a three h plus زائد k a one k a two k a three k a
+
+177
+00:15:33,580 --> 00:15:39,990
+four طب إيش نحط فوق؟اربعه راحوا كل البروتونات اذا
+
+178
+00:15:39,990 --> 00:15:44,350
+كنت ماخد بالك لكن برضه ممكن تقول هذه alpha 0 alpha
+
+179
+00:15:44,350 --> 00:15:51,630
+1 alpha 2 alpha 3 هاي ال alpha 4 اذا ke1 ke2 ke3
+
+180
+00:15:51,630 --> 00:15:59,510
+ke4 اخلت بالك كيف بدي اشتغل لو اعطاك مثلا حاجة زي
+
+181
+00:15:59,510 --> 00:16:03,150
+لو
+
+182
+00:16:03,150 --> 00:16:10,530
+اعطاك حاجة زيجالك Sodium Oxalate وبدّوا الـ Alpha
+
+183
+00:16:10,530 --> 00:16:17,350
+2 إلها، اعمل المقام في الأولهذه طبعا ال sodium
+
+184
+00:16:17,350 --> 00:16:23,470
+بتروح بحل محلها اتنين protons يعني بنعتبرها لأنه
+
+185
+00:16:23,470 --> 00:16:28,570
+انا بدي هد سبع اجزاليات C2O42 سالب انا مابتش هتكون
+
+186
+00:16:28,570 --> 00:16:32,910
+سالب كبدي هتكون uncharged بتكون هدي H2 اذا اكتر من
+
+187
+00:16:32,910 --> 00:16:37,550
+ال proton بدي يكون مع الاجزاليات اه H plus تربيع
+
+188
+00:16:37,550 --> 00:16:40,550
+زائد KA1 H plus
+
+189
+00:16:49,090 --> 00:16:52,950
+ماخدين باكم يا شاب اذا احنا مش بحاجة للاشتقاق عشان
+
+190
+00:16:52,950 --> 00:16:57,210
+هيك انا في الامتحان بعطيك يعني مدة مقدارها نص
+
+191
+00:16:57,210 --> 00:17:00,310
+دقيقة مثلا تكتب المعادلة بعطيكاش خمس دقايق
+
+192
+00:17:00,310 --> 00:17:04,690
+للاشتقاق لأنه خلاص اتعلمت كيف بدبر اشتق المعادلة
+
+193
+00:17:04,690 --> 00:17:09,800
+بمجرد النظرمش هيك؟ فأرجو أن هذا كلام يكون واضح
+
+194
+00:17:09,800 --> 00:17:16,820
+بالنسبة لنا ناخد مثال على هذا الكلام و بعدين نستمر
+
+195
+00:17:16,820 --> 00:17:21,760
+في الشغل طبعا الموضوع هذا هو موضوع تلميحي أكتر منه
+
+196
+00:17:21,760 --> 00:17:26,000
+موضوع تفصيلي الآن لكن تطبيقاته هتمر معانا في
+
+197
+00:17:26,000 --> 00:17:30,740
+المستقبل إذا الله رد شبترين كاملين تطبيقات على هذا
+
+198
+00:17:30,740 --> 00:17:37,720
+الكلام نطلع على المثال التاليالمثال بيقول كلام
+
+199
+00:17:37,720 --> 00:17:39,760
+بسيط كتير بيقول calculate the equilibrium
+
+200
+00:17:39,760 --> 00:17:44,200
+concentrations of the different species in a 0.1
+
+201
+00:17:44,200 --> 00:17:50,380
+molar phosphoric acid at pH 3 يعني جبت ال
+
+202
+00:17:50,380 --> 00:17:58,560
+phosphoric acid 0.1 molar وحطيت عليه H plus او
+
+203
+00:17:58,560 --> 00:18:03,620
+هيدروكسيد لغاية ما ال pH صارتالان بدى يحسب جداش
+
+204
+00:18:03,620 --> 00:18:08,700
+تركيز الفوسفوريك أسد اللى ماتفككش جداش تركيز ال
+
+205
+00:18:08,700 --> 00:18:13,460
+H2PO4 سالب جداش تركيز ال HPO4 اتنين سالب جداش
+
+206
+00:18:13,460 --> 00:18:15,360
+تركيز الفوسفيات تلاتة سالب
+
+207
+00:18:20,400 --> 00:18:25,360
+و ال alpha 3 كويس فبقول انا في البداية ال H plus
+
+208
+00:18:25,360 --> 00:18:29,740
+عشرة أُس ثالث تلاتة يعني واحد في عشرة أُس ثالث
+
+209
+00:18:29,740 --> 00:18:33,850
+تلاتة molar فانا تركيز ال H plusو هاي اللي لازمني
+
+210
+00:18:33,850 --> 00:18:36,750
+بس انا لازمني ال H بلس و ال K's ال K's معايا لل
+
+211
+00:18:36,750 --> 00:18:39,870
+Phosphoric Acid فيقول والله ال Alpha Zero بيجي
+
+212
+00:18:39,870 --> 00:18:43,110
+بكتب المقام في الأول مدام Phosphoric Acid تلاتة
+
+213
+00:18:43,110 --> 00:18:46,570
+بروتون اذا ال H بلس تكيب زائد K واي وان H بلس
+
+214
+00:18:46,570 --> 00:18:50,030
+تربية زائد K وان K اتو H بلس زائد K وان K اتو K
+
+215
+00:18:50,030 --> 00:18:53,330
+اثري بد ال Alpha Zero اذا ال H بلس هي اللي فوق
+
+216
+00:18:53,330 --> 00:18:58,010
+كاملة ماتتككش مراحش منهم ولا بروتون Alpha Zero
+
+217
+00:18:58,010 --> 00:19:03,160
+يعني كملين التلاتة H بلس تكيببحسبها تطلع عندى 8
+
+218
+00:19:03,160 --> 00:19:09,280
+.2×10² لكن الـ α0 بتساوي الفوسفوريك أسد at
+
+219
+00:19:09,280 --> 00:19:13,140
+equilibrium على ال total concentration للفوسفوريك
+
+220
+00:19:13,140 --> 00:19:16,820
+أسد اللى هو point one اللى أنا أضفته ال point one
+
+221
+00:19:16,820 --> 00:19:20,540
+اتجزأت جزء منه ضل على هيئة الفوسفوريك أسدجداش
+
+222
+00:19:20,540 --> 00:19:23,680
+Phosphoric Acid جال والله هاي ال α 0 8 و 2 ف 10
+
+223
+00:19:23,680 --> 00:19:26,740
+أقصى سلب 2 بدها تساوي ال Phosphoric Acid على ال
+
+224
+00:19:26,740 --> 00:19:30,240
+point 1 يعني ال Phosphoric Acid 8 و 2 ف 10 أقصى
+
+225
+00:19:30,240 --> 00:19:36,320
+سلب 3 مولاربنفس الطريقة لو حسبنا الـ α1 يعني غيرنا
+
+226
+00:19:36,320 --> 00:19:43,300
+بس الـ bust المقام نفسه بلاجة الـ α1.92 طب ما هو
+
+227
+00:19:43,300 --> 00:19:48,580
+كل الـ α values عبارة عن واحد لما تكون الـ α1.92
+
+228
+00:19:48,580 --> 00:19:55,240
+معناته أغلب الفوسفوريك أسد عن pH 3 أيش بيكون؟ آه
+
+229
+00:19:55,240 --> 00:20:00,880
+H2PO4 سالم أغلبه كمية قليلة ضايلة على هيئة H3PO4
+
+230
+00:20:01,820 --> 00:20:06,500
+لكن أغلبه بيكون على هيئة H2PO4 سالب طبعا بيطلع
+
+231
+00:20:06,500 --> 00:20:10,040
+تركيزها تسعة و اتنين فعشرة أس سالب اتنين مولارد
+
+232
+00:20:10,040 --> 00:20:15,100
+بنفس الطريقة ممكن نحسب ال alpha اتنين وال alpha
+
+233
+00:20:15,100 --> 00:20:21,480
+تلاتة ماشي يا شباب حيمور
+
+234
+00:20:21,480 --> 00:20:25,760
+معنى هذا الموضوع بشكل بوسع لكن في المستقبل الآن
+
+235
+00:20:25,760 --> 00:20:32,670
+ننتقل لموضوع غاية في الأهميةالموضوع حساب ال pH لل
+
+236
+00:20:32,670 --> 00:20:35,210
+salts of polyprotic acids يعني احنا خدنا حساب ال
+
+237
+00:20:35,210 --> 00:20:38,950
+pH لل polyprotic acids لكن ما اتكلمناش عن ال salts
+
+238
+00:20:38,950 --> 00:20:42,230
+تبعتها فالان متكلم عن ال salts of polyprotic acids
+
+239
+00:20:42,230 --> 00:20:48,190
+بقول ال salts لل polyprotic acids نوعين يعني طريقة
+
+240
+00:20:48,190 --> 00:20:57,150
+الحساب راح تختلف جذريا حسب نوع ال saltفعندي salts
+
+241
+00:20:57,150 --> 00:21:01,930
+بتكون protonated او salts بتكون unprotonated فمثلا
+
+242
+00:21:01,930 --> 00:21:06,150
+ال phosphoric acid لو أخدنا ال sodium salts تبعته
+
+243
+00:21:06,150 --> 00:21:11,210
+فبنقول في عندي NaH2PO4
+
+244
+00:21:11,210 --> 00:21:18,430
+او Na2HPO4 او Na3PO4
+
+245
+00:21:18,430 --> 00:21:21,330
+هاي التلاتة salts مافيش اي salt اخر هاي ال salts
+
+246
+00:21:21,330 --> 00:21:24,350
+تبعته طب مثلا ال carbonic acid
+
+247
+00:21:27,390 --> 00:21:31,810
+جال والله NaHCO3
+
+248
+00:21:31,810 --> 00:21:39,310
+و Na2CO3 فى salts تانية لو جينا نطلعنا دائما بناجى
+
+249
+00:21:39,310 --> 00:21:46,710
+salts protonated وهذا
+
+250
+00:21:46,710 --> 00:21:54,030
+unprotonated هان هذا protonated
+
+251
+00:22:00,990 --> 00:22:06,410
+والتاني unprotonated إذا دائما في ال polyprotic
+
+252
+00:22:06,410 --> 00:22:10,870
+acids ال salt فتبعتها أحد حاجتين يا إما a
+
+253
+00:22:10,870 --> 00:22:14,650
+protonated salt يا إما unprotonated salt في
+
+254
+00:22:14,650 --> 00:22:19,810
+الحقيقةكل نوع من هدول النوعين فيه طريقة حساب
+
+255
+00:22:19,810 --> 00:22:26,250
+وبتختلف جذريا عن الآخر وإذا ما كنتش أحدد ايش طبيعة
+
+256
+00:22:26,250 --> 00:22:31,370
+الصوت هذا واتجه الاتجاه الصحيح في الحل معناته
+
+257
+00:22:31,370 --> 00:22:39,640
+مسألة غلط 100% انتهتطيب كيف الحل؟ كيف بنحل أو
+
+258
+00:22:39,640 --> 00:22:44,220
+بنوجد ال pH لل salts of polyprotic acids؟ نتكلم في
+
+259
+00:22:44,220 --> 00:22:49,580
+البداية عن الأسهل ال unprotonated salts الأسهل
+
+260
+00:22:49,580 --> 00:22:52,520
+اللي هي ال unprotonated salts إذا كان ال salt
+
+261
+00:22:52,520 --> 00:22:56,820
+unprotonated زي مثلا الفوسفات أو الكربونات، Sodium
+
+262
+00:22:56,820 --> 00:23:01,750
+phosphate، Sodium carbonateفبنقول هذا بيعامل
+
+263
+00:23:01,750 --> 00:23:05,470
+معاملة الـ monoprotic acid اللي احنا شوفناه سابقا
+
+264
+00:23:05,470 --> 00:23:09,510
+بمعنى انه مثلا لو عندى ال sodium phosphate ال
+
+265
+00:23:09,510 --> 00:23:12,930
+sodium phosphate راح فى الميه هيتحول لل hydrogen
+
+266
+00:23:12,930 --> 00:23:16,890
+phosphate و hydroxide و هذا Kb لإنه طالع عندى
+
+267
+00:23:16,890 --> 00:23:21,990
+hydroxide فبدى احسب ال Kb بقول اه Kb بتساوي Kw على
+
+268
+00:23:21,990 --> 00:23:28,490
+Ka طب ال .. مع ال sodium phosphate بيعطينى 3 KsKa1
+
+269
+00:23:28,490 --> 00:23:33,370
+وKa2 وKa3 طبعا ضعطنيش ال Kbs لأن هذا conjugate
+
+270
+00:23:33,370 --> 00:23:37,150
+فضعطيني بس ال KAs ده ال phosphoric acid عبارة عن
+
+271
+00:23:37,150 --> 00:23:43,750
+تلاتة طب أنه Ka أستخدم أنه Ka أستخدم خد بالك بقول
+
+272
+00:23:43,750 --> 00:23:49,470
+بتطلع على المعادلة و بشوف أعلى شحنة إيش أعلى شحنة
+
+273
+00:23:49,470 --> 00:23:58,300
+تلاتة تلاتة إذا هيطلع معايا Ka تلاتةطبعا بإمكانك
+
+274
+00:23:58,300 --> 00:24:01,580
+تتطلع على هيك و دائما تختار أعلى شحناء تحصل على
+
+275
+00:24:01,580 --> 00:24:06,580
+الإجابة الصحيحة دائما لكن بإمكانك أيضا انك تقول
+
+276
+00:24:06,580 --> 00:24:14,340
+ايش اللي بربط من ال HPO42 سالب والـ P O 4 جالب
+
+277
+00:24:14,340 --> 00:24:22,260
+الله هي الـ H P O 4 2 سالب بتتفكك وبتعطيلنا P O 4
+
+278
+00:24:22,260 --> 00:24:28,700
+3 سالب زائد H Plus هذه إلها K A 3 ممكن تعمل زي هيك
+
+279
+00:24:28,700 --> 00:24:33,400
+لكن بقول أنت في غنى أنت في غنى عن ذلك بإمكانك
+
+280
+00:24:33,400 --> 00:24:37,300
+مباشرة تتطلع على أعلى شحنة وتقول والله إذا الـ K A
+
+281
+00:24:37,300 --> 00:24:42,500
+هو عبارة عن أعلى شحنةهن التلاتة هي أعلى شحنة زن KA
+
+282
+00:24:42,500 --> 00:24:49,380
+تلاتة يبقى KB بيساوي KW على KA تلاتة بنحسب قيمته
+
+283
+00:24:49,380 --> 00:24:56,310
+يطلع لنا ال KA point 02 ال KB point 02فابنشتغل
+
+284
+00:24:56,310 --> 00:24:59,810
+عادي بنقول والله الفوسفات بتعطينا hydrogen فوسفات
+
+285
+00:24:59,810 --> 00:25:06,190
+طبعا اتنين سالب هان زائد hydroxide point one صفر
+
+286
+00:25:06,190 --> 00:25:12,720
+صفر point one minus x x x ابني ايجي بنقولالـ Kb
+
+287
+00:25:12,720 --> 00:25:16,580
+اللي حسبناه سوى X تربيع الـ 0.1 minus X وبنعمل
+
+288
+00:25:16,580 --> 00:25:20,740
+الفرضية تبعتنا زي العادة 0.1 أكبر كتير من ال X
+
+289
+00:25:20,740 --> 00:25:25,480
+بنحسب قيمة ال X بتطلع 45 من الف ال relative error
+
+290
+00:25:25,480 --> 00:25:31,060
+45% هل هذا relative error معقول؟ يعني ممكن تتجاوز
+
+291
+00:25:31,060 --> 00:25:35,760
+عنه؟ لأ طبعا، إذا the assumption is invalid and we
+
+292
+00:25:35,760 --> 00:25:40,480
+have to use the quadratic equationلو حسبناها بالـ
+
+293
+00:25:40,480 --> 00:25:44,540
+quadratic equation بتطلع ال X 0.036 ال X يعني
+
+294
+00:25:44,540 --> 00:25:48,140
+عبارة عن الهيدروكسيد يبقى الهيدروكسيد بتطلع 0.036
+
+295
+00:25:48,140 --> 00:25:56,180
+مولار و ال POH 1.44 و ال pH 14 ناقص 1.44 يعني 12
+
+296
+00:25:56,180 --> 00:26:02,700
+.56 ماشي يا شباب اذا اذا كان الصوت un protonated
+
+297
+00:26:02,700 --> 00:26:10,180
+مافيش عندي اي مشكلة فورابحل باستخدام الطريقة اللي
+
+298
+00:26:10,180 --> 00:26:13,820
+احنا متعودين عليها للـ monoprotic acids بجيب ال Kb
+
+299
+00:26:13,820 --> 00:26:18,380
+بس هان في عندي حاجة جوهرية انه Kb بدل سوى Kw على
+
+300
+00:26:18,380 --> 00:26:23,640
+Ka كذا طب عنهي Ka بتطلع على أعلى شحنة نفس الكلام
+
+301
+00:26:23,640 --> 00:26:32,900
+لو جالك مثلا find the pH of a 0.1 molar sodium
+
+302
+00:26:32,900 --> 00:26:40,010
+carbonate بيجي بعطيك Ka1بيدها تساوي أربعة و تلاتة
+
+303
+00:26:40,010 --> 00:26:46,050
+في عشرة أسالب سبعة وال K A2 بتساوي أربعة و تمانية
+
+304
+00:26:46,050 --> 00:26:50,450
+في عشرة أسالب إحداشر فانت على طول بتطلع عليه
+
+305
+00:26:50,450 --> 00:26:56,210
+unprotonated يبدأ الكربونيت في الميه بده يعطينا
+
+306
+00:26:56,210 --> 00:27:02,850
+HCO3 minus زائد hydroxide هذا Kb Kb إيش بده يساوي
+
+307
+00:27:02,850 --> 00:27:09,490
+طبعا Kbبنسبة عشرة أقل سالب اربعة عشرة أقل سالب
+
+308
+00:27:09,490 --> 00:27:13,490
+اربعة على ال K a بجب اطلع اتنين اذا K a اتنين
+
+309
+00:27:13,490 --> 00:27:21,260
+بيطلع عندى اتنين و واحد في عشرة أقل سالب اربعةخلاص
+
+310
+00:27:21,260 --> 00:27:25,680
+هي عندى point one minus X هي X هي X اتنين و واحد
+
+311
+00:27:25,680 --> 00:27:29,340
+فى عشر أقل سالب أربعة واساوي ال X تربيع point one
+
+312
+00:27:29,340 --> 00:27:33,840
+minus X نعمل فرضية ال X بتطلع أربعة و نص فى عشر
+
+313
+00:27:33,840 --> 00:27:38,120
+أقل سالب تلاتة و ال relative error بتطلع أربعة و
+
+314
+00:27:38,120 --> 00:27:42,400
+نص في المية معناه الكلام صحيح اذا ال hydroxide
+
+315
+00:27:44,160 --> 00:27:49,220
+أربعة و نص في عشر أقل سالب تلاتة مولار مباشرة فيش
+
+316
+00:27:49,220 --> 00:27:53,720
+زي ال monoproteic acids ال salts تبعتها طبعا ماشي
+
+317
+00:27:53,720 --> 00:27:59,360
+يا شباب إذا مافيش عندي أي مشكلة في حساب ال ال pH
+
+318
+00:27:59,360 --> 00:28:02,660
+لل unprotonated salts طب على وين المشكلة يعني
+
+319
+00:28:02,660 --> 00:28:06,340
+والله المشكلة في الحقيقة بتيجي لما نتكلم عن ال
+
+320
+00:28:06,340 --> 00:28:10,520
+protonated salts و بدنا نشوف ليش ال protonated
+
+321
+00:28:10,520 --> 00:28:15,560
+salts بتعمل مشكلةايش معنى ال protonated salts يعني
+
+322
+00:28:15,560 --> 00:28:20,620
+مش مباشرة زي ال un protonated salts تعالوا نتطلع
+
+323
+00:28:20,620 --> 00:28:25,640
+على حاجة زي ال dihydrogen phosphate dihydrogen
+
+324
+00:28:25,640 --> 00:28:28,980
+phosphate يعني زي Sodium dihydrogen phosphate لما
+
+325
+00:28:28,980 --> 00:28:32,820
+نحطها في الميه نقول والله ال dihydrogen phosphate
+
+326
+00:28:32,820 --> 00:28:37,220
+ممكن تعطيني H plus و HPO4 اتنين سالم التفكك التاني
+
+327
+00:28:37,220 --> 00:28:41,160
+لل Phosphoric acid هذا كإتنين صح ولا لأ التفكك
+
+328
+00:28:41,160 --> 00:28:46,010
+التاني لل Phosphoric acidفي هذه خطوة معروفة إلها K
+
+329
+00:28:46,010 --> 00:28:52,230
+.A محترم يعني ماشي يا شباب في نفس الوقت قال والله
+
+330
+00:28:52,230 --> 00:28:56,670
+هذه عبارة عن strong conjugate base يعني بتتفعل مع
+
+331
+00:28:56,670 --> 00:28:59,990
+الميه بتاخد ال proton من الميه و ممكن تتحولها ل
+
+332
+00:28:59,990 --> 00:29:04,130
+hydroxide و يطلع اندي فوسفوريك أسد طب هان اتفعلت ك
+
+333
+00:29:04,130 --> 00:29:07,390
+acid أعطتني H plus هان اتفعلت ك base أعطتني
+
+334
+00:29:07,390 --> 00:29:12,710
+hydroxide أخدت H plusيبقى ممكن تتفاعل ك acid
+
+335
+00:29:12,710 --> 00:29:17,050
+لبروتونيتد salt بشكل عام ممكن يتفاعل ك acid يعطيني
+
+336
+00:29:17,050 --> 00:29:22,230
+البروتون و ممكن يتفاعل ك base ياخد البروتون يعني و
+
+337
+00:29:22,230 --> 00:29:27,270
+كأنه ايه و كأنه متردد يعني يتفاعل يعني ك acid او ك
+
+338
+00:29:27,270 --> 00:29:30,750
+base والحاجتين بيحصلوا في الحقيقة يعني الحاجتين
+
+339
+00:29:30,750 --> 00:29:37,000
+بيحصلوا لهذا السبب بقول من الحكمةاعتبار تفكك
+
+340
+00:29:37,000 --> 00:29:41,020
+الميّه من الحكمة لأنه مادام المادة مش معروفة انها
+
+341
+00:29:41,020 --> 00:29:47,060
+acid اكيد بس او base اكيد فالافضل لنا انه نستخدم
+
+342
+00:29:47,060 --> 00:29:51,720
+او يعني ناخد بالاعتبار تفكك الميّه يعني ال H plus
+
+343
+00:29:51,720 --> 00:29:56,320
+اللي جاء من الميّه الآن هدول التلاتة ال
+
+344
+00:29:56,320 --> 00:30:00,080
+equilibrium اللي موجودين عندي في المحلولبقول ال H
+
+345
+00:30:00,080 --> 00:30:10,000
+بلس للمحلول بتساوي ال H بلس اللى جاى من ال H2PO4
+
+346
+00:30:10,000 --> 00:30:17,660
+صحيح هى هذا جاى من تفكك ال H2PO4 ثالث زاد ال H بلس
+
+347
+00:30:17,660 --> 00:30:23,940
+هذا H بلس اللى جاى من تفكك الميهأه الخطوة التانية
+
+348
+00:30:23,940 --> 00:30:28,360
+مش معطيانة H بل عكس هي معطار هيدروكسيد بتاكل ال H
+
+349
+00:30:28,360 --> 00:30:33,860
+بل عكس اذا سالب الهيدروكسيد اللي جاي من تفكك ال
+
+350
+00:30:33,860 --> 00:30:41,320
+H2PO4 سالب يبقى هاي ال H بلس اللي في المحلول هذا
+
+351
+00:30:41,320 --> 00:30:47,400
+ال H بلس زائد هذا ناقص الهيدروكسيدمش هيك؟ الآن
+
+352
+00:30:47,400 --> 00:30:51,800
+بقول طيب ال H plus اللي جاي من تفكك ال H2PO4 طب ما
+
+353
+00:30:51,800 --> 00:30:55,760
+ال H2PO4 سالب لما تتفكك بتعطينا H plus زائد جدها
+
+354
+00:30:55,760 --> 00:31:00,900
+بالظبط HPO4 اتنين سالب، اذا بقول زائد ال HPO4
+
+355
+00:31:00,900 --> 00:31:07,650
+اتنين سالبهان بقول HPO4 2 سالب بدل ال H بلس اللى
+
+356
+00:31:07,650 --> 00:31:12,550
+جاى من تفكك ال H2PO4 لأنه بتسويها طيب ال H بلس
+
+357
+00:31:12,550 --> 00:31:14,770
+اللى جاى من الميادات والله بيساوي ال hydroxide
+
+358
+00:31:14,770 --> 00:31:19,830
+لأنه انا عندي انا عندي الكيبة باليوم هتساوي ال
+
+359
+00:31:19,830 --> 00:31:23,770
+hydroxide في ال H بلس فانا عندي يبقى ال H بلس
+
+360
+00:31:23,770 --> 00:31:24,410
+بتساوي
+
+361
+00:31:27,860 --> 00:31:32,660
+الـ H بلس هي عبارة عن الهيدروكسيد اللى طالع عندى
+
+362
+00:31:32,660 --> 00:31:37,160
+في المحلول الـ H بلس هي عبارة عن الهيدروكسيد لأن
+
+363
+00:31:37,160 --> 00:31:40,960
+الميه لما تتفكك تعطيني H بلس وهيدروكسيد فالـ H بلس
+
+364
+00:31:40,960 --> 00:31:45,100
+اللى جاى من الميه بيساوي الهيدروكسيد الخطوة
+
+365
+00:31:45,100 --> 00:31:50,790
+التالتة هان الهيدروكسيد اللى جاى من الـ H2PO4هو
+
+366
+00:31:50,790 --> 00:31:53,810
+عبارة عن الفوسفوريك أسد يبدو عوضت عنه بالفوسفوريك
+
+367
+00:31:53,810 --> 00:31:58,490
+أسد لأنه لما ال H2PO4 سالب تتفكك في الميطينة
+
+368
+00:31:58,490 --> 00:32:04,930
+هيدروكسيد زائد جدها بالظبط H3PO4 الآن مهمتي إذا
+
+369
+00:32:04,930 --> 00:32:10,270
+كان بدي أوجد ال H بلس في المحلول مهمتي أني أعوض عن
+
+370
+00:32:10,270 --> 00:32:15,310
+هذه الحاجات بالسولت اللي عندى السولت الأصلي اللي
+
+371
+00:32:15,310 --> 00:32:23,590
+هو H2PO4 سالبأو H2PO4 سلب مع H Plus لأن الـ H Plus
+
+372
+00:32:23,590 --> 00:32:27,290
+برضه أنا بدي إياها يعني لا تعتبر بالنسبة لي شيء
+
+373
+00:32:27,290 --> 00:32:31,610
+غريب في المعادلة و طبعا ال Ks ما ال Ks عبارة عن
+
+374
+00:32:31,610 --> 00:32:34,610
+ثوبة ممكن تكون موجودة فكيف بدي أسوي ده اللي بدي
+
+375
+00:32:34,610 --> 00:32:41,430
+أعوض عن هدول التلاتة؟ بحث أو بدلالة الـ H2PO4 سلب
+
+376
+00:32:41,430 --> 00:32:46,010
+ليه؟ لأن الـ H2PO4 سلب هي السلطة اللي عندي فبقول
+
+377
+00:32:46,010 --> 00:32:55,390
+واللهمن ال K A2 بقول ال H P O 4 اتنين سالب راح
+
+378
+00:32:55,390 --> 00:33:00,470
+تساوي ال K A2 في ال H 2 P O 4 سالب على ال H Plus
+
+379
+00:33:00,470 --> 00:33:04,830
+من وين جيبناها؟ جيبناها من ال K A2 هاي K A2،
+
+380
+00:33:04,830 --> 00:33:08,510
+هايها، هادي إلها K A2، إيش بيساوي؟ H Plus في ال H
+
+381
+00:33:08,510 --> 00:33:12,630
+P O 4 اتنين سالب على ال H 2 P O 4 بتتعود عن ال H P
+
+382
+00:33:12,630 --> 00:33:16,710
+O 4 اتنين سالب، بتعطيني القيمة اللي عندى باللون
+
+383
+00:33:16,710 --> 00:33:21,690
+البنيالهيدروكسايد هي عبارة عن ال KW على ال H بلس
+
+384
+00:33:21,690 --> 00:33:25,170
+فش خلاف على هذا الكلام لأن ال KW بتساوي ال H بلس
+
+385
+00:33:25,170 --> 00:33:28,830
+في الهيدروكسايد فبعوض عن الهيدروكسايد بال KW على
+
+386
+00:33:28,830 --> 00:33:33,530
+ال H بلس بالنسبة للفوسفوريك أسيد بجيب أن ال KA1
+
+387
+00:33:36,630 --> 00:33:41,090
+هي عبارة عن H2PO4 ثالث في الـ H بلس على الفوسفوريك
+
+388
+00:33:41,090 --> 00:33:45,430
+أسد فانا بدّي الفوسفوريك أسد إذا بتسوى H2PO4 ثالث
+
+389
+00:33:45,430 --> 00:33:49,950
+في الـ H بلس على الـ KA1 لو جي اترتبت المعادلة هذه
+
+390
+00:33:49,950 --> 00:33:56,810
+بحصل على المعادلة التالية الـ H بلس بتسوى الجزر
+
+391
+00:33:56,810 --> 00:34:11,930
+التربيهي لـ KA1KW زائد KA1KA2في الـ H2PO4 على KA1
+
+392
+00:34:11,930 --> 00:34:18,190
+زائد الـ H2PO4 كتبت هذه بالشكل اللي قدامكم لأن
+
+393
+00:34:18,190 --> 00:34:21,910
+بعضكم في الامتحان حتى في ال standard deviations
+
+394
+00:34:21,910 --> 00:34:25,690
+كان بحط اللي مثلا على ال bus جزر وعلى المقام بحطش
+
+395
+00:34:25,690 --> 00:34:30,670
+جزر لأ هذا الجزر كله تحت الجزر التربيعي كله تحت
+
+396
+00:34:30,670 --> 00:34:35,380
+الجزر التربيعي هذا مجرد ترتيب للمعادلةبفهم من
+
+397
+00:34:35,380 --> 00:34:39,980
+المعادلة ايش؟ بفهم من المعادلة انه والله حساب ال H
+
+398
+00:34:39,980 --> 00:34:44,340
+plus لما نكون عندى protonated salt مش مباشر على
+
+399
+00:34:44,340 --> 00:34:47,740
+طول عمل معادل لأ من القانون بدنا نحسبه لإن فى تلت
+
+400
+00:34:47,740 --> 00:34:51,080
+معادلات يجب ناخدها باين الاعتبار عشان أقدر أحسب ال
+
+401
+00:34:51,080 --> 00:34:55,380
+H plus اللى فى المحلول وهذا القانون بيمثل حل التلت
+
+402
+00:34:55,380 --> 00:35:00,900
+معادلات مع بعض ماشي القانون فى بس تركيز ال salt
+
+403
+00:35:00,900 --> 00:35:07,420
+ومجرد KAsأو KW يعني case equilibrium constants
+
+404
+00:35:07,420 --> 00:35:12,880
+بقول في عندي شروط قد تتحقق وفي كثير من الأحيان
+
+405
+00:35:12,880 --> 00:35:23,320
+بتتحقق ممكن والله ال H2PO4 تكون أكبر كتير من ال
+
+406
+00:35:23,320 --> 00:35:34,680
+KA1 وممكن ال KA1 KA2 في ال H2PO4 تكون أكبر كتيرمن
+
+407
+00:35:34,680 --> 00:35:41,220
+الـ K A1 K W إذا كان هدول الشرطين تحققوا معناته
+
+408
+00:35:41,220 --> 00:35:48,540
+الـ H plus يساوي الجزر التربيهي لـ K A1 K A2 فقط
+
+409
+00:35:48,540 --> 00:35:53,720
+كتير معادلة بسيطة لكن ودتيش بتكون بسيطة فقط إذا
+
+410
+00:35:53,720 --> 00:35:55,640
+كان الشرطين هدول اتحققوا
+
+411
+00:35:58,070 --> 00:36:04,470
+يعني بعض ال .. الكتب أو المواقع تستخدم هذا القانون
+
+412
+00:36:04,470 --> 00:36:09,830
+لحل المسائل الخاصة بال polyprotic .. بال souls of
+
+413
+00:36:09,830 --> 00:36:15,030
+polyprotic acids بقول هذا الكلام مش صحيح إلا إذا
+
+414
+00:36:15,030 --> 00:36:19,530
+كان إيه؟ الشروط تحققت فإحنا هذا هو القانون اللي
+
+415
+00:36:19,530 --> 00:36:23,140
+اشتقناه هو اللي بنستخدمهلكن إذا كانت تحققت الشروط
+
+416
+00:36:23,140 --> 00:36:27,080
+فيمكن استخدام القانون المختصر، لو استخدمت هذا
+
+417
+00:36:27,080 --> 00:36:30,540
+القانون في الامتحان لوحده بدون ما تحقق الشروط، حتى
+
+418
+00:36:30,540 --> 00:36:34,500
+لو إجابتك صحيحة، بتاخد السؤال غلط، ممنوع، لازم
+
+419
+00:36:34,500 --> 00:36:39,180
+تقولي إن الشروط بتتحقق، لأن اشتقاق المعادلة يعتقن
+
+420
+00:36:39,180 --> 00:36:42,720
+هذا القانون، ما بتستخدم هذا القانون إلا إذا كانت
+
+421
+00:36:42,720 --> 00:36:46,940
+تحققت الشروط عندكفي الواقع كمان يعني هذا القانون
+
+422
+00:36:46,940 --> 00:36:51,740
+بيقوللي إيش؟ بيقوللي إشي عجيب بيقوللي إن ال PH لا
+
+423
+00:36:51,740 --> 00:36:55,640
+تعتمد على تركيز الصوت فقط تعتمد على نوع الصوت مش
+
+424
+00:36:55,640 --> 00:36:59,930
+على تركيزهليه؟ لأنه مافيش عندي هذا التركيز بس KA1
+
+425
+00:36:59,930 --> 00:37:07,690
+و KA2 وهذا أيش برضه يعتبر يعني .. شيء يعني عجيب
+
+426
+00:37:07,690 --> 00:37:12,910
+شوية ليه؟ لأن عادة ال PH تتوقف على التركيز عادة
+
+427
+00:37:12,910 --> 00:37:17,630
+لكن هان بنلاحظ أن ال PH لا تتوقف على التركيز وكمان
+
+428
+00:37:17,630 --> 00:37:22,870
+مرة هذا في حالة ما أن الشرطين اللي عندي يتحققوا
+
+429
+00:37:22,870 --> 00:37:25,690
+طيب
+
+430
+00:37:28,910 --> 00:37:35,170
+بدي ألفت انتباهك لنقطة هان لو لاحظت أكم شحنه في
+
+431
+00:37:35,170 --> 00:37:38,910
+عين دي واحدة
+
+432
+00:37:38,910 --> 00:37:44,650
+عشان هيك بدأت في إيش ك
+
+433
+00:37:44,650 --> 00:37:52,530
+إي واحد طيب إيش بيحصل إيش بيحصل لو كان في عيننا
+
+434
+00:37:54,950 --> 00:38:01,290
+صوت مثلا na2hpo4
+
+435
+00:38:01,290 --> 00:38:06,430
+هان لو قلنا هاد راحت بيصير هان عند اتنين سالم
+
+436
+00:38:06,430 --> 00:38:13,530
+شحنتين لو جيت اشتقيت المعادلة راح
+
+437
+00:38:13,530 --> 00:38:22,770
+تلاحظ ان ال h plus اللي عندك راح تساوي ka2kw
+
+438
+00:38:22,770 --> 00:38:32,930
+زائدكأتنين كأتلاتة HPO4 اتنين سالب على الكأتنين
+
+439
+00:38:32,930 --> 00:38:41,290
+زائد ال HPO4 اتنين سالب اذا هاد اتنين يبجى هاي هاد
+
+440
+00:38:41,290 --> 00:38:46,730
+اتنين وهاي هاد اتنين
+
+441
+00:38:47,380 --> 00:38:50,920
+ماشي يا شباب هذا بنقوله a protonated salt with
+
+442
+00:38:50,920 --> 00:38:56,140
+multiple charges ناخد بالنا مش القانون هذا لأي
+
+443
+00:38:56,140 --> 00:39:00,800
+كمان يعني اللي بزيد التعقيد أكتر شوية هذا قانون لا
+
+444
+00:39:00,800 --> 00:39:06,620
+ينطبق على كلLeprotonated Soles لأ هذا بس
+
+445
+00:39:06,620 --> 00:39:08,940
+لـProtonated Soles اللي عليه شحنة واحدة اللي عليه
+
+446
+00:39:08,940 --> 00:39:14,740
+شحنتين حلوة من نفس القانون لكن بدأ بـKa اتنين لو
+
+447
+00:39:14,740 --> 00:39:21,140
+كان عندنا حاجة زي هيك Hy تلاتة سالب فالـH plus له
+
+448
+00:39:21,140 --> 00:39:29,300
+بدها تساوي الجزر التربيهي Ka تلاتة Kw زائد Ka
+
+449
+00:39:29,300 --> 00:39:31,440
+تلاتة Ka أربعة
+
+450
+00:39:42,480 --> 00:39:52,280
+يكويس هيك يا شباب طيب مين يقول ليه
+
+451
+00:39:52,280 --> 00:40:01,520
+صوت زي هذا ايش
+
+452
+00:40:01,520 --> 00:40:02,160
+نكتبله
+
+453
+00:40:05,700 --> 00:40:13,580
+منفعش تستخدم القانون هذا هيه Y 4 سالب في الميه H Y
+
+454
+00:40:13,580 --> 00:40:15,120
+3 سالب زائد
+
+455
+00:40:24,110 --> 00:40:28,590
+محدش يستخدم القانون لحاجة ما مافيش فيها بروتون
+
+456
+00:40:28,590 --> 00:40:33,930
+اوعك اوعك القانون لا يستخدم لشيء ما مافيش فيه
+
+457
+00:40:33,930 --> 00:40:38,750
+بروتون عشان تستخدم القانون ال salt ايش بده يكون ال
+
+458
+00:40:38,750 --> 00:40:42,930
+protonated اذا بقدر اقول انا ان ال salts of
+
+459
+00:40:42,930 --> 00:40:47,810
+monopotic acids معينيا بيكون unprotonated وهذا
+
+460
+00:40:47,810 --> 00:40:52,570
+بعامله معاملة ال sources of monoprotic acids زيها
+
+461
+00:40:52,570 --> 00:40:57,810
+بالظبط لكن ماخد أو لازم ناخد بعينه الاعتبار انه ال
+
+462
+00:40:57,810 --> 00:41:02,670
+Kb في هذه الحالة بتساوي Kw على Ka بيبقى أقل على
+
+463
+00:41:02,670 --> 00:41:08,310
+أعلى شحنة في ال equilibrium كويس أما ال
+
+464
+00:41:08,310 --> 00:41:13,670
+unprotonated salts فبرضه بدي أعرف كيف تنحل بقول
+
+465
+00:41:13,670 --> 00:41:17,770
+باستخدام القانونلا خلاف لـ protonated salts
+
+466
+00:41:17,770 --> 00:41:22,450
+باستخدام القانون الـ H plus بيه تساوي حاجة تحت
+
+467
+00:41:22,450 --> 00:41:26,290
+الجزير طيب إيش اللي تحت الجزير قال والله بيتوقف
+
+468
+00:41:26,290 --> 00:41:33,130
+على إيش الشحنة اللي على ال salt إذا كان شحنة واحدة
+
+469
+00:41:33,130 --> 00:41:43,810
+زي مثلا ال بي كربونيتالـ Oxalate الـ Bioxalate
+
+470
+00:41:43,810 --> 00:41:54,330
+كويس الـ H2PO4 شحنة واحدة بقول اه KA1 KA2 او في
+
+471
+00:41:54,330 --> 00:41:59,250
+الاول الجزر التربيه على ال KA1 KW زائد KA1 KA2
+
+472
+00:41:59,250 --> 00:42:04,010
+تركيز الصوت على KA1 زائد تركيز الصوت اما لو كان
+
+473
+00:42:04,010 --> 00:42:12,390
+شحنتينزي ال .. بي .. زي ال .. بي سوديا مهيدروجين
+
+474
+00:42:12,390 --> 00:42:19,310
+فوسفيت HPO4 اتنين
+
+475
+00:42:19,310 --> 00:42:23,830
+سالف شحن تان فبقول ال H بلس بتساوي الجزر التربيعى
+
+476
+00:42:23,830 --> 00:42:30,290
+لكي اتنين KW زائد كي اتنين كي اتلاتة تركيز الصوت
+
+477
+00:42:30,290 --> 00:42:40,080
+على كي اتنين زائد تركيز الصوتطيب بنفس الطريقة يعني
+
+478
+00:42:40,080 --> 00:42:46,820
+هان في عندى شحنتين قولنا بنبدأ ب K A2 لو كان .. لو
+
+479
+00:42:46,820 --> 00:42:51,060
+اتحققت الشروط انه هذا ال term أكبر كتير من ال K A2
+
+480
+00:42:51,060 --> 00:42:55,520
+KW و هذا ال term أكبر كتير من ال K A2 نصفر أنه K
+
+481
+00:42:55,520 --> 00:43:00,530
+A2 K A3 تحت الجزيرةمثلا زي ما صفت عنا قبل شوية
+
+482
+00:43:00,530 --> 00:43:05,330
+الـKa وKa2 تحت الجزر لكن هذا كان ضمن أو تحت شروط
+
+483
+00:43:05,330 --> 00:43:18,830
+معينة خلينا ناخد مثال you
+
+484
+00:43:18,830 --> 00:43:24,650
+will find the pH of a 0.1 molar sodium bicarbonate
+
+485
+00:43:27,170 --> 00:43:35,490
+Ka1 4 3 10 7 K2 4 8 10 11
+
+486
+00:43:38,750 --> 00:43:44,250
+بقول عادة لو حبيت ممكن انه نكتب المعادلات ال
+
+487
+00:43:44,250 --> 00:43:48,230
+بيكربونيت تتصرف ك acid و بتعطيني H plus و
+
+488
+00:43:48,230 --> 00:43:54,010
+Carbonate ال بيكربونيت برضه تتصرف ك base بتاخد H
+
+489
+00:43:54,010 --> 00:43:57,410
+plus من الميه بتعطي hydroxide و carbonic acid و
+
+490
+00:43:57,410 --> 00:43:59,750
+الميه طبعا تتفاكك على ال H plus و ال hydroxide لو
+
+491
+00:43:59,750 --> 00:44:04,230
+اشتقلنا المعادلة بتكون ال H plus بتساوي ال KA1 KW
+
+492
+00:44:04,230 --> 00:44:09,580
+لأن لو لاحظت انت ال بيكربونيت عليها شحنة واحدةكأو
+
+493
+00:44:09,580 --> 00:44:11,180
+وكأو وكأو وكأو وكأو وكأو وكأو وكأو وكأو وكأو وكأو
+
+494
+00:44:11,180 --> 00:44:14,860
+وكأو وكأو وكأو وكأو وكأو وكأو وكأو وكأو وكأو وكأو
+
+495
+00:44:14,860 --> 00:44:17,520
+وكأو وكأو وكأو وكأو وكأو وكأو وكأو وكأو وكأو وكأو
+
+496
+00:44:17,520 --> 00:44:19,180
+وكأو وكأو وكأو وكأو وكأو وكأو وكأو وكأو وكأو وكأو
+
+497
+00:44:19,180 --> 00:44:21,990
+وكأو وكأو وكأو وكأو وكأو وكأو وكأو وكأو وكأولكن
+
+498
+00:44:21,990 --> 00:44:26,470
+احنا لو أخدنا بالنا لو أخدنا بالنا يعني han أربعة
+
+499
+00:44:26,470 --> 00:44:29,430
+و تلاتة في عشرة أسالة سبعة اللي هي ال K a one ال K
+
+500
+00:44:29,430 --> 00:44:32,510
+w اللي كان عشرة أسالة باربعتاش يعني هدول عشرة
+
+501
+00:44:32,510 --> 00:44:36,810
+أسالة بواحد و أشرين لو طلعت منيها han هذا عشرة
+
+502
+00:44:36,810 --> 00:44:42,620
+أسالة تمانتاش عشرة أسالة تسعتاشللـ 21 ميت مرة ممكن
+
+503
+00:44:42,620 --> 00:44:47,220
+نلغي يعني ممكن ال term ال term هذا أكبر كتير من ال
+
+504
+00:44:47,220 --> 00:44:50,920
+K A1TW برضه نفس الكلمة من ال B كاربونية واحد من
+
+505
+00:44:50,920 --> 00:44:55,020
+عشرة وال K A1 عشرة أقل سالف سبعة واحد من عشرة و
+
+506
+00:44:55,020 --> 00:44:57,540
+هذا عشرة أقل سالف سبعة واضح ان ال واحد من عشرة
+
+507
+00:44:57,540 --> 00:45:01,200
+أكبر كتير من ال Aمن العشرة أقل سالة بسبعة، إذا
+
+508
+00:45:01,200 --> 00:45:06,620
+الفربية عندي هتتحقق، يعني لو استخدمت على طول H بلس
+
+509
+00:45:06,620 --> 00:45:11,320
+بتساوي KA1, KA2، تحت الجزر طبعا، الـH بلس هتطلع
+
+510
+00:45:11,320 --> 00:45:13,400
+عندي برضه أربعة و نصف و عشرة أقل سالة بتسعة، لكن
+
+511
+00:45:13,400 --> 00:45:18,060
+ليش هذا الكلام؟ لأن الفربية عندي تحققت، لكن لو
+
+512
+00:45:18,060 --> 00:45:26,690
+اطلعنا على المثال التاليبقول find the pH of a 0.1
+
+513
+00:45:26,690 --> 00:45:29,550
+millimolar sodium bicarbonate solution نعطينا
+
+514
+00:45:29,550 --> 00:45:35,390
+الـKa1 وKa2 بقول والله لو أنا طبقت القانون تطلع
+
+515
+00:45:35,390 --> 00:45:39,510
+عندى الـH plus سبعة وسبعة وتسعين فعشرة أسالت تسعة
+
+516
+00:45:39,510 --> 00:45:47,030
+وال pH تمانية واحد من عشرة طيب لو إجيتاستخدمت ال
+
+517
+00:45:47,030 --> 00:45:51,810
+shortcut الجزر التربية على ال K1 K2 بدون ما احقق
+
+518
+00:45:51,810 --> 00:45:58,830
+فرضياتي بقول والله بطلع عندى 4.5×109 هنجدش 97 في
+
+519
+00:45:58,830 --> 00:46:05,250
+109 هن 4.5×109 طب هذا طبعا اكيد نتيجة خاطئة ليه؟
+
+520
+00:46:05,250 --> 00:46:10,570
+لأن والله يعني لما نيجي احنا لما نيجي نطلع هن هذا
+
+521
+00:46:10,570 --> 00:46:17,760
+10 أقصى سلب 21 صحيح؟ طب هذا سلب 18واربعة سالب
+
+522
+00:46:17,760 --> 00:46:21,940
+اتنين و عشرين هل السلب اتنين و عشرين اكبر من مثلا
+
+523
+00:46:21,940 --> 00:46:26,400
+السلب واحد و عشرين او متقاربة يعني متقاربة نقدرش ن
+
+524
+00:46:26,400 --> 00:46:30,060
+.. لازم نجمع الاتنين مع بعض هان تحت اه والله ممكن
+
+525
+00:46:30,060 --> 00:46:33,440
+اقول السلب اربعة هان سلب سبعة هذا اكبر كتير من هذا
+
+526
+00:46:33,440 --> 00:46:37,560
+مافيش مشكلة لكن اللي فوق لأعشان هيك مانفعش اقول
+
+527
+00:46:37,560 --> 00:46:41,880
+الجزر التربيعي الـKa1Kw فلازم ااخد بالي من هذه
+
+528
+00:46:41,880 --> 00:46:46,120
+الأمور كمان مرة بقول unprotonated salts مش مشكلة
+
+529
+00:46:46,120 --> 00:46:51,120
+تعامل معاملة salts of monoproteic acids كويس لكن
+
+530
+00:46:51,120 --> 00:46:54,960
+بناخد بالي اعتبار كيف نحسب ال Kbالـ Protonated
+
+531
+00:46:54,960 --> 00:46:59,980
+Salts بدأجي أطلّع على الـ charge اللي عليها دائما
+
+532
+00:46:59,980 --> 00:47:04,560
+ل Protonated القانون ل Protonated مستمرار القانون
+
+533
+00:47:04,560 --> 00:47:07,760
+مموحة في كل المعادلة فتكت ل Protonated Salt
+
+534
+00:47:07,760 --> 00:47:14,400
+المعادلة معناته خلاص مسألة غلط فعنا ل Protonated
+
+535
+00:47:14,400 --> 00:47:21,850
+بدنا نروح للقانون كيف بدي أبدأ؟على الشحنة، شحنة
+
+536
+00:47:21,850 --> 00:47:26,550
+واحدة بدأ بـK A1، شحنتين K A1، راحت، خلاص مش
+
+537
+00:47:26,550 --> 00:47:30,230
+موجودة، صارت K A2 بداية، و هكذا، الاختصار أو ال
+
+538
+00:47:30,230 --> 00:47:38,130
+shortcut معناته بده .. اه بده حقق فرضياتي طيب يا
+
+539
+00:47:38,130 --> 00:47:40,470
+شباب إذا الله راد الحصة اللي جاية بنكمل
+
diff --git a/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/iFDrwq-eXd0_raw.json b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/iFDrwq-eXd0_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..fafa9465c976a944b9d851d421898c6350e6cc95
--- /dev/null
+++ b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/iFDrwq-eXd0_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 4814, "start": 21.4, "end": 48.14, "text": "بسم الله الرحمن الرحيم الحصة الماضية يا شباب كنا اتكلمنا عن ال polyprotic acids وشوفنا كيف بنحسب ال pH لل polyprotic acids بشكل أساسي كنا بنطلع على قيمة ال equilibrium constants للتفككات التفكك الأول والتفكك التاني تحديدا و بنقسم KA1 على KA2 إذا كان لجناه أكتر من 100 فمعناته التفكك التاني", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640, 21542, 9381, 3660, 9673, 46958, 10632, 35186, 13412, 3555, 16758, 9122, 8315, 1975, 2655, 4117, 19528, 8315, 18871, 2423, 6754, 1424, 9411, 21667, 4032, 8592, 38688, 8315, 9122, 33911, 44945, 5016, 35457, 2423, 21677, 24976, 6754, 1424, 9411, 21667, 4724, 8592, 28820, 5551, 3794, 32277, 1829, 9122, 8315, 44945, 9566, 1211, 3615, 15844, 12174, 32640, 3660, 2423, 15625, 35870, 24976, 2655, 5172, 4117, 4117, 9307, 16712, 5172, 4117, 4117, 16247, 12610, 16070, 2655, 5172, 4117, 4117, 16712, 7649, 1829, 6055, 5016, 16254, 28259, 4032, 44945, 4587, 38251, 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"probability": 0.750244140625}, {"start": 25.76, "end": 26.6, "word": " اتكلمنا", "probability": 0.91552734375}, {"start": 26.6, "end": 26.82, "word": " عن", "probability": 0.9892578125}, {"start": 26.82, "end": 27.04, "word": " ال", "probability": 0.83984375}, {"start": 27.04, "end": 27.74, "word": " polyprotic", "probability": 0.7833658854166666}, {"start": 27.74, "end": 28.26, "word": " acids", "probability": 0.78271484375}, {"start": 28.26, "end": 29.48, "word": " وشوفنا", "probability": 0.869873046875}, {"start": 29.48, "end": 29.72, "word": " كيف", "probability": 0.969482421875}, {"start": 29.72, "end": 30.42, "word": " بنحسب", "probability": 0.9503580729166666}, {"start": 30.42, "end": 30.96, "word": " ال", "probability": 0.96533203125}, {"start": 30.96, "end": 31.62, "word": " pH", "probability": 0.5478515625}, {"start": 31.62, "end": 31.9, "word": " لل", "probability": 0.73095703125}, {"start": 31.9, "end": 32.56, "word": " polyprotic", "probability": 0.93603515625}, {"start": 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"probability": 0.84912109375}, {"start": 181.51, "end": 182.17, "word": " راح", "probability": 0.7666015625}, {"start": 182.17, "end": 183.01, "word": " يقلل", "probability": 0.98291015625}, {"start": 183.01, "end": 183.67, "word": " لـ", "probability": 0.57373046875}, {"start": 183.67, "end": 184.37, "word": " Protons", "probability": 0.6378173828125}, {"start": 184.37, "end": 184.93, "word": " اللي", "probability": 0.93212890625}, {"start": 184.93, "end": 185.05, "word": " في", "probability": 0.90966796875}, {"start": 185.05, "end": 185.51, "word": " المحلول", "probability": 0.995849609375}, {"start": 185.51, "end": 186.27, "word": " وبالتالي", "probability": 0.91396484375}, {"start": 186.27, "end": 186.89, "word": " مثلا", "probability": 0.97607421875}, {"start": 186.89, "end": 187.17, "word": " الـ", "probability": 0.94091796875}, {"start": 187.17, "end": 188.39, "word": " H3PO4", "probability": 0.851806640625}, {"start": 188.39, "end": 188.73, "word": " في", "probability": 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"end": 202.09, "word": " الكلام", "probability": 0.9586588541666666}, {"start": 202.09, "end": 203.19, "word": " أنا", "probability": 0.480712890625}, {"start": 203.19, "end": 204.09, "word": " عند", "probability": 0.95458984375}, {"start": 204.09, "end": 204.57, "word": " إضافة", "probability": 0.8983154296875}, {"start": 204.57, "end": 204.83, "word": " H", "probability": 0.939453125}, {"start": 204.83, "end": 205.33, "word": " Plus", "probability": 0.1390380859375}, {"start": 205.33, "end": 205.97, "word": " أو", "probability": 0.86376953125}, {"start": 205.97, "end": 206.83, "word": " Hydroxide", "probability": 0.9153645833333334}], "temperature": 1.0}, {"id": 9, "seek": 21703, "start": 209.79, "end": 217.03, "text": "الأجزاء أو ال fractions من هذه ال species بتتغير بتغير ال pH", "tokens": [6027, 10721, 7435, 11622, 16606, 34051, 2423, 36058, 9154, 29538, 2423, 6172, 39894, 2655, 17082, 13546, 39894, 17082, 13546, 2423, 21677], "avg_logprob": -0.22940341586416418, "compression_ratio": 1.0833333333333333, "no_speech_prob": 3.5762786865234375e-07, "words": [{"start": 209.79, "end": 210.71, "word": "الأجزاء", "probability": 0.83544921875}, {"start": 210.71, "end": 210.89, "word": " أو", "probability": 0.6884765625}, {"start": 210.89, "end": 211.01, "word": " ال", "probability": 0.77587890625}, {"start": 211.01, "end": 211.51, "word": " fractions", "probability": 0.361328125}, {"start": 211.51, "end": 212.11, "word": " من", "probability": 0.9794921875}, {"start": 212.11, "end": 213.05, "word": " هذه", "probability": 0.8916015625}, {"start": 213.05, "end": 213.23, "word": " ال", "probability": 0.900390625}, {"start": 213.23, "end": 214.03, "word": " species", "probability": 0.79541015625}, {"start": 214.03, "end": 215.71, "word": " بتتغير", "probability": 0.952880859375}, {"start": 215.71, "end": 216.33, "word": " بتغير", "probability": 0.9482421875}, {"start": 216.33, "end": 216.49, "word": " ال", "probability": 0.9775390625}, {"start": 216.49, "end": 217.03, "word": " pH", "probability": 0.74951171875}], "temperature": 1.0}, {"id": 10, "seek": 24995, "start": 223.53, "end": 249.95, "text": "أحسب جداش موجود على صورة مثلا phosphoric acid عند pH معينة جداش موجود على صورة HPO42 سالب عند نفس ال pH جداش موجود على هيئة phosphate عند نفس ال pH جداش موجود على هيئة H2PO4 سالب عند نفس ال pH فمهمتي أني أعرف الأجزاء المختلفة من كل ال species من ال species اللي عندي", "tokens": [10721, 5016, 35457, 10874, 3215, 33599, 3714, 29245, 23328, 15844, 20328, 13063, 3660, 50113, 15040, 19775, 16345, 8258, 43242, 21677, 20449, 9957, 3660, 10874, 3215, 33599, 3714, 29245, 23328, 15844, 20328, 13063, 3660, 12557, 46, 15628, 8608, 6027, 3555, 43242, 8717, 36178, 2423, 21677, 10874, 3215, 33599, 3714, 29245, 23328, 15844, 39896, 19986, 3660, 46542, 43242, 8717, 36178, 2423, 21677, 10874, 3215, 33599, 3714, 29245, 23328, 15844, 39896, 19986, 3660, 389, 17, 34885, 19, 8608, 6027, 3555, 43242, 8717, 36178, 2423, 21677, 6156, 2304, 16095, 31371, 14739, 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"start": 401.62, "end": 414.0, "text": "التركيز الكوني للفوسفوريك أسد اللي حطيته بقدر أحسب تركيز الفوسفير وهكذا، اذا مهمتي الآن أنه اوجد equations أو علاقات", "tokens": [6027, 2655, 31747, 1829, 11622, 33251, 11536, 1829, 24976, 5172, 41779, 5172, 13063, 1829, 4117, 5551, 3794, 3215, 13672, 1829, 11331, 9566, 36081, 3224, 4724, 28543, 2288, 5551, 5016, 35457, 6055, 31747, 1829, 11622, 27188, 41779, 5172, 13546, 37037, 4117, 15730, 12399, 1975, 15730, 3714, 16095, 31371, 6024, 48506, 14739, 3224, 1975, 29245, 3215, 11787, 34051, 11203, 995, 4587, 9307], "avg_logprob": -0.32402664911551554, "compression_ratio": 1.4137931034482758, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 401.62, "end": 402.34, "word": "التركيز", "probability": 0.791357421875}, {"start": 402.34, "end": 402.78, "word": " الكوني", "probability": 0.469970703125}, {"start": 402.78, "end": 403.36, "word": " للفوسفوريك", "probability": 0.7007882254464286}, {"start": 403.36, "end": 403.54, "word": " أسد", 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المجموعة الكلة لل species بيساوى ال C للفوسفوريك أسد", "tokens": [6027, 10721, 46538, 30767, 13546, 2407, 39896, 13672, 7578, 39894, 2655, 4117, 19528, 18871, 2423, 4018, 4602, 37495, 22653, 39894, 2655, 4117, 19528, 18871, 27188, 41779, 5172, 13063, 1829, 4117, 5551, 3794, 3215, 45164, 24401, 3224, 23032, 3555, 3615, 995, 43242, 9673, 7435, 2304, 2407, 27884, 2423, 28820, 3660, 24976, 6172, 4724, 1829, 3794, 995, 2407, 7578, 2423, 383, 24976, 5172, 41779, 5172, 13063, 1829, 4117, 5551, 3794, 3215], "avg_logprob": -0.23772322003330504, "compression_ratio": 1.5620915032679739, "no_speech_prob": 0.0, "words": [{"start": 440.25, "end": 440.93, "word": "الألف", "probability": 0.5575358072916666}, {"start": 440.93, "end": 441.43, "word": " زيرو", "probability": 0.718994140625}, {"start": 441.43, "end": 441.77, "word": " هي", "probability": 0.59619140625}, {"start": 441.77, "end": 442.11, "word": " اللى", "probability": 0.732421875}, {"start": 442.11, "end": 442.59, "word": " بتتكلم", 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"probability": 0.78466796875}, {"start": 446.71, "end": 447.27, "word": " المجموعة", "probability": 0.84560546875}, {"start": 447.27, "end": 448.83, "word": " الكلة", "probability": 0.6158854166666666}, {"start": 448.83, "end": 449.01, "word": " لل", "probability": 0.67431640625}, {"start": 449.01, "end": 449.63, "word": " species", "probability": 0.59375}, {"start": 449.63, "end": 450.37, "word": " بيساوى", "probability": 0.790283203125}, {"start": 450.37, "end": 450.49, "word": " ال", "probability": 0.603515625}, {"start": 450.49, "end": 450.81, "word": " C", "probability": 0.6103515625}, {"start": 450.81, "end": 451.59, "word": " للفوسفوريك", "probability": 0.8452497209821429}, {"start": 451.59, "end": 451.95, "word": " أسد", "probability": 0.9830729166666666}], "temperature": 1.0}, {"id": 20, "seek": 47737, "start": 452.79, "end": 477.37, "text": "إذاً بدي أخلّي كل الطرف الأيمن دالة في الفوسفوريك أسد، لماذا؟ لأن الـAlpha Zero بتساوي الفوسفوريك أسد على التركيز الكلي، فإذا كان أنا 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"probability": 0.65869140625}, {"start": 1041.76, "end": 1042.0, "word": " موضوع", "probability": 0.961181640625}, {"start": 1042.0, "end": 1042.52, "word": " تفصيلي", "probability": 0.82578125}, {"start": 1042.52, "end": 1042.94, "word": " الآن", "probability": 0.7166748046875}, {"start": 1042.94, "end": 1044.02, "word": " لكن", "probability": 0.8515625}, {"start": 1044.02, "end": 1044.72, "word": " تطبيقاته", "probability": 0.9778645833333334}, {"start": 1044.72, "end": 1045.12, "word": " هتمر", "probability": 0.8162434895833334}, {"start": 1045.12, "end": 1045.68, "word": " معانا", "probability": 0.9373372395833334}, {"start": 1045.68, "end": 1046.0, "word": " في", "probability": 0.9619140625}, {"start": 1046.0, "end": 1046.58, "word": " المستقبل", "probability": 0.9935302734375}, {"start": 1046.58, "end": 1046.82, "word": " إذا", "probability": 0.896728515625}, {"start": 1046.82, "end": 1047.0, "word": " الله", "probability": 0.935546875}, {"start": 1047.0, "end": 1047.24, "word": " رد", "probability": 0.864013671875}, {"start": 1047.24, "end": 1047.8, "word": " شبترين", "probability": 0.71357421875}, {"start": 1047.8, "end": 1048.34, "word": " كاملين", "probability": 0.8162841796875}, {"start": 1048.34, "end": 1049.3, "word": " تطبيقات", "probability": 0.960546875}, {"start": 1049.3, "end": 1049.56, "word": " على", "probability": 0.93212890625}, {"start": 1049.56, "end": 1050.74, "word": " هذا", "probability": 0.97314453125}, {"start": 1050.74, "end": 1051.22, "word": " الكلام", "probability": 0.9588216145833334}, {"start": 1051.22, "end": 1053.36, "word": " نطلع", "probability": 0.79443359375}, {"start": 1053.36, "end": 1053.48, "word": " على", "probability": 0.73876953125}, {"start": 1053.48, "end": 1053.86, "word": " المثال", "probability": 0.98583984375}, {"start": 1053.86, "end": 1054.38, "word": " التالي", "probability": 0.9441731770833334}], "temperature": 1.0}, {"id": 46, "seek": 108078, "start": 1056.36, "end": 1080.78, "text": "المثال بيقول كلام بسيط كتير بيقول calculate the equilibrium concentrations of the different species in a 0.1 molar phosphoric acid at pH 3 يعني جبت ال phosphoric acid 0.1 molar وحطيت عليه H plus او هيدروكسيد لغاية ما ال pH صارت", "tokens": [45340, 12984, 6027, 4724, 1829, 39648, 28242, 10943, 4724, 3794, 1829, 9566, 9122, 2655, 13546, 4724, 1829, 39648, 8873, 264, 15625, 33512, 295, 264, 819, 6172, 294, 257, 1958, 13, 16, 45712, 19775, 16345, 8258, 412, 21677, 805, 37495, 22653, 10874, 3555, 2655, 2423, 19775, 16345, 8258, 1958, 13, 16, 45712, 4032, 5016, 9566, 36081, 47356, 389, 1804, 1975, 2407, 8032, 25708, 32887, 4117, 3794, 25708, 5296, 17082, 995, 10632, 19446, 2423, 21677, 20328, 9640, 2655], "avg_logprob": -0.1450892911328898, "compression_ratio": 1.3878504672897196, "no_speech_prob": 0.0, "words": [{"start": 1056.36, "end": 1056.98, "word": "المثال", "probability": 0.935546875}, {"start": 1056.98, "end": 1057.34, "word": " بيقول", "probability": 0.90869140625}, {"start": 1057.34, "end": 1057.72, 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"word": " ال", "probability": 0.83740234375}, {"start": 1070.38, "end": 1070.82, "word": " phosphoric", "probability": 0.795166015625}, {"start": 1070.82, "end": 1071.14, "word": " acid", "probability": 0.9580078125}, {"start": 1071.14, "end": 1071.34, "word": " 0", "probability": 0.75927734375}, {"start": 1071.34, "end": 1071.7, "word": ".1", "probability": 0.99658203125}, {"start": 1071.7, "end": 1072.06, "word": " molar", "probability": 0.6875}, {"start": 1072.06, "end": 1073.18, "word": " وحطيت", "probability": 0.9039306640625}, {"start": 1073.18, "end": 1073.64, "word": " عليه", "probability": 0.9833984375}, {"start": 1073.64, "end": 1075.68, "word": " H", "probability": 0.8505859375}, {"start": 1075.68, "end": 1076.36, "word": " plus", "probability": 0.2919921875}, {"start": 1076.36, "end": 1078.56, "word": " او", "probability": 0.77294921875}, {"start": 1078.56, "end": 1079.18, "word": " هيدروكسيد", "probability": 0.7916666666666666}, {"start": 1079.18, "end": 1079.58, "word": " لغاية", "probability": 0.989501953125}, {"start": 1079.58, "end": 1079.7, "word": " ما", "probability": 0.91064453125}, {"start": 1079.7, "end": 1079.82, "word": " ال", "probability": 0.9599609375}, {"start": 1079.82, "end": 1080.14, "word": " pH", "probability": 0.87890625}, {"start": 1080.14, "end": 1080.78, "word": " صارت", "probability": 0.9739583333333334}], "temperature": 1.0}, {"id": 47, "seek": 109535, "start": 1081.8, "end": 1095.36, "text": "الان بدى يحسب جداش تركيز الفوسفوريك أسد اللى ماتفككش جداش تركيز ال H2PO4 سالب جداش تركيز ال HPO4 اتنين سالب جداش تركيز الفوسفيات تلاتة سالب", "tokens": [6027, 7649, 47525, 7578, 7251, 5016, 35457, 10874, 3215, 33599, 6055, 31747, 1829, 11622, 27188, 41779, 5172, 13063, 1829, 4117, 5551, 3794, 3215, 13672, 7578, 3714, 9307, 5172, 4117, 4117, 8592, 10874, 3215, 33599, 6055, 31747, 1829, 11622, 2423, 389, 17, 34885, 19, 8608, 6027, 3555, 10874, 3215, 33599, 6055, 31747, 1829, 11622, 2423, 389, 34885, 19, 1975, 2655, 1863, 9957, 8608, 6027, 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0.8653157552083334}, {"start": 1085.62, "end": 1086.28, "word": " جداش", "probability": 0.8587239583333334}, {"start": 1086.28, "end": 1088.34, "word": " تركيز", "probability": 0.9915771484375}, {"start": 1088.34, "end": 1088.7, "word": " ال", "probability": 0.9169921875}, {"start": 1088.7, "end": 1089.84, "word": " H2PO4", "probability": 0.8426513671875}, {"start": 1089.84, "end": 1090.2, "word": " سالب", "probability": 0.6505533854166666}, {"start": 1090.2, "end": 1090.78, "word": " جداش", "probability": 0.8525390625}, {"start": 1090.78, "end": 1091.2, "word": " تركيز", "probability": 0.995849609375}, {"start": 1091.2, "end": 1091.34, "word": " ال", "probability": 0.9423828125}, {"start": 1091.34, "end": 1092.26, "word": " HPO4", "probability": 0.70751953125}, {"start": 1092.26, "end": 1092.56, "word": " اتنين", "probability": 0.7999267578125}, {"start": 1092.56, "end": 1092.92, "word": " سالب", "probability": 0.9645182291666666}, {"start": 1092.92, "end": 1093.46, "word": " جداش", "probability": 0.9680989583333334}, {"start": 1093.46, "end": 1093.82, "word": " تركيز", "probability": 0.9967041015625}, {"start": 1093.82, "end": 1094.54, "word": " الفوسفيات", "probability": 0.75909423828125}, {"start": 1094.54, "end": 1094.96, "word": " تلاتة", "probability": 0.8868408203125}, {"start": 1094.96, "end": 1095.36, "word": " سالب", "probability": 0.9708658854166666}], "temperature": 1.0}, {"id": 48, "seek": 111196, "start": 1100.4, "end": 1111.96, "text": "و ال alpha 3 كويس فبقول انا في البداية ال H plus عشرة أُس ثالث تلاتة يعني واحد في عشرة أُس ثالث تلاتة molar فانا تركيز ال H plus", "tokens": [2407, 2423, 8961, 805, 9122, 45865, 3794, 6156, 3555, 39648, 1975, 8315, 8978, 29739, 28259, 10632, 2423, 389, 1804, 6225, 8592, 25720, 5551, 10859, 3794, 38637, 6027, 12984, 6055, 1211, 9307, 3660, 37495, 22653, 36764, 24401, 8978, 6225, 8592, 25720, 5551, 10859, 3794, 38637, 6027, 12984, 6055, 1211, 9307, 3660, 45712, 6156, 7649, 995, 6055, 31747, 1829, 11622, 2423, 389, 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" H", "probability": 0.64599609375}, {"start": 1104.82, "end": 1105.36, "word": " plus", "probability": 0.279541015625}, {"start": 1105.36, "end": 1107.2, "word": " عشرة", "probability": 0.8597005208333334}, {"start": 1107.2, "end": 1107.48, "word": " أُس", "probability": 0.6101888020833334}, {"start": 1107.48, "end": 1107.76, "word": " ثالث", "probability": 0.6134440104166666}, {"start": 1107.76, "end": 1108.26, "word": " تلاتة", "probability": 0.8970947265625}, {"start": 1108.26, "end": 1108.58, "word": " يعني", "probability": 0.86279296875}, {"start": 1108.58, "end": 1108.94, "word": " واحد", "probability": 0.94873046875}, {"start": 1108.94, "end": 1109.08, "word": " في", "probability": 0.89599609375}, {"start": 1109.08, "end": 1109.38, "word": " عشرة", "probability": 0.8499348958333334}, {"start": 1109.38, "end": 1109.56, "word": " أُس", "probability": 0.8766276041666666}, {"start": 1109.56, "end": 1109.74, "word": " ثالث", "probability": 0.95751953125}, {"start": 1109.74, "end": 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" فتبعتها", "probability": 0.640185546875}, {"start": 1328.03, "end": 1328.57, "word": " أحد", "probability": 0.8525390625}, {"start": 1328.57, "end": 1329.19, "word": " حاجتين", "probability": 0.98046875}, {"start": 1329.19, "end": 1329.79, "word": " يا", "probability": 0.55322265625}, {"start": 1329.79, "end": 1330.21, "word": " إما", "probability": 0.924072265625}, {"start": 1330.21, "end": 1330.87, "word": " a", "probability": 0.293701171875}, {"start": 1330.87, "end": 1331.63, "word": " protonated", "probability": 0.93359375}, {"start": 1331.63, "end": 1332.17, "word": " salt", "probability": 0.9541015625}, {"start": 1332.17, "end": 1332.69, "word": " يا", "probability": 0.85888671875}, {"start": 1332.69, "end": 1332.95, "word": " إما", "probability": 0.968505859375}, {"start": 1332.95, "end": 1334.15, "word": " unprotonated", "probability": 0.8477783203125}, {"start": 1334.15, "end": 1334.53, "word": " salt", "probability": 0.94775390625}, {"start": 1334.53, "end": 1334.65, 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"word": " الآخر", "probability": 0.97216796875}, {"start": 1343.03, "end": 1344.17, "word": " وإذا", "probability": 0.7762044270833334}, {"start": 1344.17, "end": 1344.45, "word": " ما", "probability": 0.6953125}, {"start": 1344.45, "end": 1344.87, "word": " كنتش", "probability": 0.6193033854166666}, {"start": 1344.87, "end": 1345.45, "word": " أحدد", "probability": 0.8515625}, {"start": 1345.45, "end": 1345.73, "word": " ايش", "probability": 0.7159016927083334}, {"start": 1345.73, "end": 1346.25, "word": " طبيعة", "probability": 0.9658203125}, {"start": 1346.25, "end": 1346.67, "word": " الصوت", "probability": 0.920654296875}, {"start": 1346.67, "end": 1346.89, "word": " هذا", "probability": 0.493408203125}, {"start": 1346.89, "end": 1347.87, "word": " واتجه", "probability": 0.7696533203125}, {"start": 1347.87, "end": 1348.75, "word": " الاتجاه", "probability": 0.961181640625}, {"start": 1348.75, "end": 1349.45, "word": " الصحيح", "probability": 0.990966796875}, {"start": 1349.45, 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"text": "في الواقع كمان يعني هذا القانون بيقوللي إيش؟ بيقوللي إشي عجيب بيقوللي إن ال PH لا تعتمد على تركيز الصوت فقط تعتمد على نوع الصوت مش على تركيزه", "tokens": [41185, 2423, 14407, 4587, 3615, 9122, 2304, 7649, 37495, 22653, 23758, 25062, 7649, 11536, 4724, 1829, 39648, 20292, 11933, 1829, 8592, 22807, 4724, 1829, 39648, 20292, 11933, 8592, 1829, 6225, 7435, 1829, 3555, 4724, 1829, 39648, 20292, 36145, 2423, 16530, 20193, 6055, 34268, 2304, 3215, 15844, 6055, 31747, 1829, 11622, 31767, 35473, 6156, 47432, 6055, 34268, 2304, 3215, 15844, 8717, 45367, 31767, 35473, 37893, 15844, 6055, 31747, 1829, 11622, 3224], "avg_logprob": -0.1321522870533903, "compression_ratio": 1.8333333333333333, "no_speech_prob": 1.7881393432617188e-06, "words": [{"start": 2204.84, "end": 2205.04, "word": "في", "probability": 0.7275390625}, {"start": 2205.04, "end": 2205.52, "word": " الواقع", "probability": 0.98291015625}, {"start": 2205.52, "end": 2205.92, "word": " كمان", "probability": 0.8194986979166666}, 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0.9833984375}, {"start": 2575.88, "end": 2576.12, "word": " K", "probability": 0.49169921875}, {"start": 2576.12, "end": 2576.5, "word": " A3", "probability": 0.98046875}, {"start": 2576.5, "end": 2576.76, "word": " تحت", "probability": 0.9912109375}, {"start": 2576.76, "end": 2577.26, "word": " الجزيرة", "probability": 0.8712565104166666}], "temperature": 1.0}, {"id": 108, "seek": 260465, "start": 2577.77, "end": 2604.65, "text": "مثلا زي ما صفت عنا قبل شوية الـKa وKa2 تحت الجزر لكن هذا كان ضمن أو تحت شروط معينة خلينا ناخد مثال you will find the pH of a 0.1 molar sodium bicarbonate", "tokens": [2304, 12984, 15040, 30767, 1829, 19446, 20328, 5172, 2655, 6225, 8315, 12174, 36150, 13412, 2407, 10632, 2423, 39184, 42, 64, 4032, 42, 64, 17, 6055, 33753, 25724, 11622, 2288, 44381, 23758, 25961, 48812, 27842, 34051, 6055, 33753, 13412, 32887, 9566, 20449, 9957, 3660, 16490, 1211, 9957, 995, 8717, 47283, 3215, 50113, 6027, 291, 486, 915, 264, 21677, 295, 257, 1958, 13, 16, 45712, 20265, 272, 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"seek": 261548, "start": 2607.17, "end": 2615.49, "text": "Ka1 4 3 10 7 K2 4 8 10 11", "tokens": [42, 64, 16, 1017, 805, 1266, 1614, 591, 17, 1017, 1649, 1266, 2975], "avg_logprob": -0.6004464498588017, "compression_ratio": 0.8620689655172413, "no_speech_prob": 7.748603820800781e-07, "words": [{"start": 2607.1699999999996, "end": 2608.45, "word": "Ka1", "probability": 0.44049072265625}, {"start": 2608.45, "end": 2609.73, "word": " 4", "probability": 0.0811767578125}, {"start": 2609.73, "end": 2610.11, "word": " 3", "probability": 0.274658203125}, {"start": 2610.11, "end": 2610.49, "word": " 10", "probability": 0.634765625}, {"start": 2610.49, "end": 2611.19, "word": " 7", "probability": 0.52197265625}, {"start": 2611.19, "end": 2612.71, "word": " K2", "probability": 0.56103515625}, {"start": 2612.71, "end": 2613.09, "word": " 4", "probability": 0.59033203125}, {"start": 2613.09, "end": 2613.61, "word": " 8", "probability": 0.990234375}, {"start": 2613.61, "end": 2614.19, "word": " 10", 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صارت K A2 بداية، و هكذا، الاختصار أو ال shortcut معناته بده .. اه بده حقق فرضياتي طيب يا شباب إذا الله راد الحصة اللي جاية بنكمل", "tokens": [3615, 23942, 25124, 5016, 1863, 3660, 12399, 13412, 5016, 1863, 3660, 36764, 24401, 3660, 47525, 10721, 4724, 39184, 42, 316, 16, 12399, 13412, 5016, 29399, 9957, 591, 316, 16, 12399, 12602, 39319, 2655, 12399, 16490, 1211, 33546, 37893, 3714, 29245, 23328, 3660, 12399, 20328, 9640, 2655, 591, 316, 17, 4724, 28259, 10632, 12399, 4032, 8032, 4117, 15730, 12399, 2423, 47283, 2655, 9381, 9640, 34051, 2423, 24822, 20449, 8315, 47395, 47525, 3224, 4386, 1975, 3224, 47525, 3224, 11331, 4587, 4587, 6156, 43042, 1829, 9307, 1829, 23032, 1829, 3555, 35186, 13412, 3555, 16758, 11933, 15730, 21984, 12602, 18513, 21542, 9381, 3660, 13672, 1829, 10874, 995, 10632, 44945, 24793, 1211], "avg_logprob": -0.2540509239942939, "compression_ratio": 1.6201923076923077, "no_speech_prob": 1.0371208190917969e-05, "words": [{"start": 2838.07, "end": 2839.07, "word": "على", "probability": 0.79345703125}, {"start": 2839.07, "end": 2841.43, "word": " الشحنة،", "probability": 0.7869873046875}, {"start": 2841.43, "end": 2841.85, "word": " شحنة", "probability": 0.9027099609375}, {"start": 2841.85, "end": 2842.39, "word": " واحدة", "probability": 0.9788411458333334}, {"start": 2842.39, "end": 2842.85, "word": " بدأ", "probability": 0.61767578125}, {"start": 2842.85, "end": 2843.07, "word": " بـK", "probability": 0.4761555989583333}, {"start": 2843.07, "end": 2843.47, "word": " A1،", "probability": 0.4601643880208333}, {"start": 2843.47, "end": 2844.05, "word": " شحنتين", "probability": 0.9752197265625}, {"start": 2844.05, "end": 2844.27, "word": " K", "probability": 0.6162109375}, {"start": 2844.27, "end": 2845.31, "word": " A1،", "probability": 0.7815755208333334}, {"start": 2845.31, "end": 2846.11, "word": " راحت،", "probability": 0.805908203125}, {"start": 2846.11, "end": 2846.41, "word": " خلاص", "probability": 0.9894205729166666}, {"start": 2846.41, "end": 2846.55, "word": " مش", "probability": 0.919921875}, {"start": 2846.55, "end": 2846.91, "word": " موجودة،", "probability": 0.7584228515625}, {"start": 2846.91, "end": 2847.23, "word": " صارت", "probability": 0.9783528645833334}, {"start": 2847.23, "end": 2847.41, "word": " K", "probability": 0.955078125}, {"start": 2847.41, "end": 2847.73, "word": " A2", "probability": 0.966552734375}, {"start": 2847.73, "end": 2848.59, "word": " بداية،", "probability": 0.854736328125}, {"start": 2848.59, "end": 2848.77, "word": " و", "probability": 0.73974609375}, {"start": 2848.77, "end": 2849.29, "word": " هكذا،", "probability": 0.7960205078125}, {"start": 2849.29, "end": 2849.95, "word": " الاختصار", "probability": 0.90693359375}, {"start": 2849.95, "end": 2850.11, "word": " أو", "probability": 0.60693359375}, {"start": 2850.11, "end": 2850.23, "word": " ال", "probability": 0.77490234375}, {"start": 2850.23, "end": 2850.63, "word": " shortcut", "probability": 0.673828125}, {"start": 2850.63, "end": 2851.89, "word": " معناته", "probability": 0.9368489583333334}, {"start": 2851.89, "end": 2853.71, "word": " بده", "probability": 0.46240234375}, {"start": 2853.71, "end": 2854.31, "word": " ..", "probability": 0.54736328125}, {"start": 2854.31, "end": 2856.09, "word": " اه", "probability": 0.59796142578125}, {"start": 2856.09, "end": 2856.37, "word": " بده", "probability": 0.85986328125}, {"start": 2856.37, "end": 2856.63, "word": " حقق", "probability": 0.8948567708333334}, {"start": 2856.63, "end": 2857.37, "word": " فرضياتي", "probability": 0.8515625}, {"start": 2857.37, "end": 2857.99, "word": " طيب", "probability": 0.8158365885416666}, {"start": 2857.99, "end": 2858.13, "word": " يا", "probability": 0.974609375}, {"start": 2858.13, "end": 2858.37, "word": " شباب", "probability": 0.9918619791666666}, {"start": 2858.37, "end": 2858.59, "word": " إذا", "probability": 0.7529296875}, {"start": 2858.59, "end": 2858.77, "word": " الله", "probability": 0.79052734375}, {"start": 2858.77, "end": 2859.13, "word": " راد", "probability": 0.69677734375}, {"start": 2859.13, "end": 2859.59, "word": " الحصة", "probability": 0.9208984375}, {"start": 2859.59, "end": 2859.71, "word": " اللي", "probability": 0.7265625}, {"start": 2859.71, "end": 2859.93, "word": " جاية", "probability": 0.91650390625}, {"start": 2859.93, "end": 2860.47, "word": " بنكمل", "probability": 0.8717447916666666}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2861.3485, "duration_after_vad": 2747.928124999993}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/iyej-ZK7KYU.srt b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/iyej-ZK7KYU.srt
new file mode 100644
index 0000000000000000000000000000000000000000..482bd8abfc164e2053b523b317ee9b787a2d5e1a
--- /dev/null
+++ b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/iyej-ZK7KYU.srt
@@ -0,0 +1,2002 @@
+1
+00:00:20,970 --> 00:00:26,130
+بسم الله الرحمن الرحيم اليوم يا شباب نكمل في ال
+
+2
+00:00:26,130 --> 00:00:29,270
+acid-base equilibria في الحصة الماضية كنا نتكلم
+
+3
+00:00:29,270 --> 00:00:34,340
+عن حسابات الـ pH الخاصة بالـ strong acids و الـ strong
+
+4
+00:00:34,340 --> 00:00:38,800
+bases و أيضا الـ salts للـ strong acids و الـ strong
+
+5
+00:00:38,800 --> 00:00:43,640
+bases. شفنا أن الـ strong acid هو الـ acid الذي
+
+6
+00:00:43,640 --> 00:00:50,180
+يتفكك بنسبة 100%. و أيضا الـ strong base هو الـ base
+
+7
+00:00:50,180 --> 00:00:55,240
+الذي يتفكك بنسبة 100%. اليوم إن شاء الله نتكلم عن
+
+8
+00:00:55,240 --> 00:01:00,560
+حسابات الـ pH للـ weak acids و الـ weak bases و أيضا
+
+9
+00:01:00,560 --> 00:01:04,580
+الـ salts المشتقة من الـ weak acids و الـ weak bases.
+
+10
+00:01:04,580 --> 00:01:09,440
+بنقول إذا كان تعريفنا للـ strong acid و الـ strong
+
+11
+00:01:09,440 --> 00:01:14,040
+base أنهما هما المادتان اللتان تتفككان بنسبة 100%، فتعريفنا
+
+12
+00:01:14,040 --> 00:01:18,860
+للـ weak acids و الـ weak bases هو أنهما هما المادتان اللتان
+
+13
+00:01:18,860 --> 00:01:24,700
+لا تتفككان بنسبة 100%. طبعا مثلا الـ strong acids
+
+14
+00:01:24,700 --> 00:01:29,450
+عرفناها بالاسم، فما عداها يعتبر weak. الـ Strong
+
+15
+00:01:29,450 --> 00:01:33,870
+Acids عرفناها بالاسم، فما عداها يعتبر weak. أيضا ما
+
+16
+00:01:33,870 --> 00:01:38,730
+يميز الـ weak acids هو أننا نكتب له equilibrium
+
+17
+00:01:38,730 --> 00:01:43,070
+constant لأنه يتفكك جزئيا، لا يتفكك بنسبة 100%.
+
+18
+00:01:43,070 --> 00:01:45,970
+فدائما الـ weak acid موجود معه equilibrium
+
+19
+00:01:45,970 --> 00:01:49,930
+constant. كلما كبر هذا equilibrium constant كلما
+
+20
+00:01:49,930 --> 00:01:53,890
+الـ acid كان أقوى، طبعا هو weak لكنه أقوى من غيره.
+
+21
+00:01:55,190 --> 00:02:00,410
+كلما زادت قيمة الـ equilibrium constant كلما اعتبرنا أن
+
+22
+00:02:00,410 --> 00:02:03,590
+الـ acid أقوى، و كلما قلت قيمة الـ equilibrium
+
+23
+00:02:03,590 --> 00:02:12,250
+constant أيضا نقول أن كلما قلت قيمة الـ
+
+24
+00:02:12,250 --> 00:02:16,660
+equilibrium constant الـ acid يكون أضعف. نفس الكلام
+
+25
+00:02:16,660 --> 00:02:20,600
+بالنسبة للـ bases، كل base مرتبط معه equilibrium
+
+26
+00:02:20,600 --> 00:02:24,940
+constant لأنه weak base. فلمّا نزيد قيمة الـ
+
+27
+00:02:24,940 --> 00:02:29,040
+equilibrium constant معناته الـ weak base هذا أقوى
+
+28
+00:02:29,040 --> 00:02:31,820
+من غيره، بينما لما تقل قيمة الـ equilibrium
+
+29
+00:02:31,820 --> 00:02:38,060
+constant فمعناته الـ base أضعف. على أي حال، نستطيع
+
+30
+00:02:38,060 --> 00:02:40,740
+أن نقول هذا كشيء عام.
+
+31
+00:02:43,500 --> 00:02:47,700
+الـ strong acids تتفكك في الماء و تعطي H+. لكن
+
+32
+00:02:47,700 --> 00:02:52,360
+ليس  لازم أن ننسى أن الماء أيضا يتفكك و يعطي H+. فهل
+
+33
+00:02:52,360 --> 00:02:54,220
+يجب علينا أن
+
+34
+00:02:57,050 --> 00:03:00,650
+نأخذ بعين الاعتبار الـ H+  الذي يأتي من الماء أم
+
+35
+00:03:00,650 --> 00:03:05,090
+لا؟ في الحقيقة هذا سؤال مهم و قد يكون له أهمية
+
+36
+00:03:05,090 --> 00:03:10,330
+كبيرة جدا كما شفنا في الحصة الماضية، بالذات لو
+
+37
+00:03:10,330 --> 00:03:16,030
+كان تركيز الحمض ضعيفا نسبيا، تركيز
+
+38
+00:03:16,030 --> 00:03:20,070
+قليل، عندها تركيز الـ H+ الذي يأتي من الماء قد
+
+39
+00:03:20,070 --> 00:03:24,210
+يكون قيمته مهمة، و في بعض الأحيان قد يكون أهم من
+
+40
+00:03:24,210 --> 00:03:27,650
+كمية الـ H+ التي تأتي من الحمض. لكن لو كان
+
+41
+00:03:27,650 --> 00:03:32,850
+تركيز الحمض أو القاعدة معقول، فنلاحظ طبيعيا أن
+
+42
+00:03:32,850 --> 00:03:36,110
+كمية الـ H+ أو الـ Hydroxide التي تأتي من الماء
+
+43
+00:03:36,110 --> 00:03:43,400
+تكون قليلة للغاية. فمثلا نأخذ بعض الأمثلة، و من خلال
+
+44
+00:03:43,400 --> 00:03:49,700
+هذه الأمثلة نعلق على منهجية التفكير في: هل يعني الـ
+
+45
+00:03:49,700 --> 00:03:53,340
+H+ الذي يأتي من الماء هذا مهم أم لا؟ و كيف
+
+46
+00:03:53,340 --> 00:03:57,260
+نحسب الـ H+ للمحلول؟ فنطلع على هذا المثال الذي
+
+47
+00:03:57,260 --> 00:04:03,810
+أمامي: بقول calculate the pH and pOH for a 0.1 molar
+
+48
+00:04:03,810 --> 00:04:08,310
+acetic acid solution. طبعا لم يعطيني الـ Ka لأن
+
+49
+00:04:08,310 --> 00:04:11,950
+الـ acetic acid يعتبر weak acid، فالـ Ka له 1.
+
+50
+00:04:11,950 --> 00:04:15,030
+75 × 10⁻⁵
+
+51
+00:04:17,070 --> 00:04:21,670
+بقول ببساطة تامة، أستطيع أن أقول أن الـ H+
+
+52
+00:04:21,670 --> 00:04:26,670
+للمحلول تساوي الـ H+ الذي يأتي من الـ acetic
+
+53
+00:04:26,670 --> 00:04:31,810
+acid زائد الـ H+ الذي يأتي من الماء. لكن يا شباب،
+
+54
+00:04:31,810 --> 00:04:35,150
+أصلا الـ H+ الذي يأتي من الماء في الأحوال
+
+55
+00:04:35,150 --> 00:04:39,670
+العادية، عندما يكون الماء بمفرده، 10⁻⁷.
+
+56
+00:04:39,670 --> 00:04:44,010
+ليه؟ لأن  Kw = [H+][OH⁻] في
+
+57
+00:04:44,010 --> 00:04:47,720
+الماء، إذا لم يكن لدي إلا الماء.  فالأصل أن الـ H+
+
+58
+00:04:47,720 --> 00:04:51,220
+10⁻⁷، الذي يأتي من الماء، لكن في
+
+59
+00:04:51,220 --> 00:04:55,300
+وجود acetic acid معناته أني أضيف H+ إلى
+
+60
+00:04:55,300 --> 00:04:59,660
+equilibrium الماء، ماذا يحصل للماء؟  راح حسب
+
+61
+00:04:59,660 --> 00:05:04,760
+لشاتلييه، يعني تفككه راح يقل بشكل كبير جدا في
+
+62
+00:05:04,760 --> 00:05:08,600
+وجود H+ الذي يأتي من الـ acetic acid. يبقى تفكك الماء
+
+63
+00:05:08,600 --> 00:05:12,940
+في وجود الـ acetic acid لا يكاد يذكر، تفككه أصلا
+
+64
+00:05:12,940 --> 00:05:17,880
+الماء ضعيف. لكن أيضا في وجود الأسيتيك أسيد، نظرا لوجود
+
+65
+00:05:17,880 --> 00:05:23,520
+common ion مهم، فتفكك الماء يقل بشكل كبير، فوق ضعفه،
+
+66
+00:05:23,520 --> 00:05:27,280
+يقل بشكل كبير جدا، معناه هذا الكلام مبرر ليه أنني
+
+67
+00:05:27,280 --> 00:05:32,540
+أقول تفكك الماء لا يكاد يذكر، يعني وكأنه الـ H+
+
+68
+00:05:32,540 --> 00:05:36,040
+للمحلول هو عبارة عن الـ H+ الذي يأتي من
+
+69
+00:05:36,040 --> 00:05:38,180
+الأسيتيك أسيد فقط.
+
+70
+00:05:40,670 --> 00:05:44,470
+كمان ملاحظة، الحصة الماضية كنا نقول: والله، عندنا
+
+71
+00:05:44,470 --> 00:05:47,470
+حمض، إذا الـ H+ للمحلول تساوي الـ H+ للـ
+
+72
+00:05:47,470 --> 00:05:50,590
+حمض زائد الماء، عندما يكون هذا strong كنت على طول
+
+73
+00:05:50,590 --> 00:05:56,170
+أعوض عن قيمة الـ H+ بتركيز الحمض، صح؟ وبعدين
+
+74
+00:05:56,170 --> 00:06:00,580
+أقارن، أقول: طيب، كم الـ hydroxide؟ معي أنتم؟ مباشرة.
+
+75
+00:06:00,580 --> 00:06:04,140
+لكن هنا لن أستطيع أن أفعل هذا الكلام، ليه؟ لأن الـ
+
+76
+00:06:04,140 --> 00:06:08,080
+H+ الذي يأتي من الحمض الضعيف ليس هو تركيز الحمض
+
+77
+00:06:08,080 --> 00:06:12,700
+الضعيف، يجب حسابه في البداية، يجب حسابه، بعدين ممكن
+
+78
+00:06:12,700 --> 00:06:17,420
+نقارنه بالـ H+ الذي يأتي من الماء، الذي هو قيمة
+
+79
+00:06:17,420 --> 00:06:23,790
+الـ hydroxide. فنرى كيف نفكر في حل المسألة. بقول: نحن
+
+80
+00:06:23,790 --> 00:06:26,790
+نفرض أن الـ H+ للمحلول تساوي الـ H+
+
+81
+00:06:26,790 --> 00:06:30,670
+الذي يأتي من الـ acetic acid، على فرض أن الماء أصلا تفككه
+
+82
+00:06:30,670 --> 00:06:34,790
+ضعيف جدا، وفي وجود الـ common ion، تفككه يكاد يكون
+
+83
+00:06:34,790 --> 00:06:39,610
+شبه معدوم، كويس؟ فالـ acetic acid يعطينا H+ و
+
+84
+00:06:39,610 --> 00:06:44,270
+Acetate. يبقى الـ  CH₃COO⁻ أو الـ acetic acid كان 0.1
+
+85
+00:06:44,270 --> 00:06:49,830
+قبل الـ equilibrium، 0.1 - x. يبقى الآن
+
+86
+00:06:49,830 --> 00:06:53,410
+أستطيع أن أقول أن الـ equilibrium constant،  Ka يساوي
+
+87
+00:06:53,410 --> 00:06:58,210
+[CH₃COO⁻][H⁺]/[CH₃COOH].  طبعا الـ H⁺ و الـ acetate x، يعني x²،
+
+88
+00:06:58,210 --> 00:07:02,730
+الـ 0.1 - x.  نفترض أن الـ 0.1 كالعادة أكبر بكثير من x،  لأن
+
+89
+00:07:02,730 --> 00:07:07,790
+أبسط حل المسألة، الـ x بتطلع 1.3 × 10⁻³
+
+90
+00:07:07,790 --> 00:07:12,170
+هل بالفعل الـ x كمية مهملة؟ نعم. نجيب الـ relative
+
+91
+00:07:13,180 --> 00:07:17,120
+error، الذي يطلع عندي 1.3%.
+
+92
+00:07:17,120 --> 00:07:19,800
+نعرف نجيب الـ relative error. إذا
+
+93
+00:07:19,800 --> 00:07:22,200
+الـ assumption valid، و الـ H⁺ للمحلول الذي طلع عندي
+
+94
+00:07:22,200 --> 00:07:26,320
+1.3 × 10⁻³. كويس؟ الآن لأن
+
+95
+00:07:26,320 --> 00:07:32,920
+الـ x هي الـ H⁺، طلع عندي 1.3 × 10⁻³، الآن أستطيع أن أقول كلام بسيط جدا،
+
+96
+00:07:32,920 --> 00:07:35,700
+أقول: طيب، كم قيمة الـ hydroxide في المحلول؟
+
+97
+00:07:49,780 --> 00:07:56,590
+الهيدروكسيد يطلع عندنا 7.6 × 10⁻¹². طيب،
+
+98
+00:07:56,590 --> 00:07:59,910
+إيش هو الـ hydroxide؟ قال هو الـ H⁺ الذي جاء من
+
+99
+00:07:59,910 --> 00:08:03,330
+الماء، لأنه مصدر الـ hydroxide الوحيد هو الماء، و
+
+100
+00:08:03,330 --> 00:08:08,410
+الماء عندما يتفكك يعطيني بالضبط H⁺ و بالضبط
+
+101
+00:08:08,410 --> 00:08:12,170
+hydroxide. إذا كان الـ hydroxide 7.6 × 10⁻¹²، إذا الـ H⁺ الذي جاء من الماء 7.6 × 10⁻¹²
+
+102
+00:08:12,170 --> 00:08:15,670
+كمية مهملة بالنسبة للـ 1.3 × 10⁻³
+
+103
+00:08:15,670 --> 00:08:20,960
+كمية مهملة.  لأن هذا ممكن أيضا أن
+
+104
+00:08:20,960 --> 00:08:25,660
+أجيب، والله لو حبيت نسبة الخطأ في إهمال الـ H⁺
+
+105
+00:08:25,660 --> 00:08:31,760
+الذي يأتي من الماء، يعني هذا هو الـ H⁺ الذي يأتي
+
+106
+00:08:31,760 --> 00:08:36,240
+من الماء. لو قسمته على قيمة الـ H⁺ للمحلول × 100
+
+107
+00:08:36,240 --> 00:08:41,080
+من 100 يعطيني نسبة الخطأ، يعطيني نسبة خطأ
+
+108
+00:08:41,080 --> 00:08:44,340
+متدنية للغاية، وكأنه ما في عندي أي نسبة خطأ لإهمال
+
+109
+00:08:44,340 --> 00:08:48,700
+الـ H⁺ الذي يأتي من الماء. طيب، لو حبينا نشتغل عند
+
+110
+00:08:48,700 --> 00:08:54,580
+تركيز أقل من الـ acetic acid، مثلا، نطلع على المثال
+
+111
+00:08:54,580 --> 00:09:00,540
+الذي يقول: احسب الـ pH و pOH لـ 1 millimolar
+
+112
+00:09:00,540 --> 00:09:03,800
+acetic acid. بقول بنفس الطريقة: بقول هو حمض، أصلا الـ
+
+113
+00:09:03,800 --> 00:09:10,090
+H⁺ للمحلول يساوي الـ H⁺ للحمض زائد الـ H⁺ الذي
+
+114
+00:09:10,090 --> 00:09:13,370
+يأتي من الماء، لكن الـ H⁺ الذي يأتي من الماء لازم
+
+115
+00:09:13,370 --> 00:09:16,730
+تكون مهملة هنا، تعتبر أصلا قليلة جدا، فبالتالي
+
+116
+00:09:16,730 --> 00:09:21,670
+أنه في وجود acetic acid، تفكك الماء أيضا سيقل،
+
+117
+00:09:21,670 --> 00:09:25,030
+يبقى هيصبح قليلا جدا جدا جدا، إذا يمكن إهماله،
+
+118
+00:09:25,030 --> 00:09:29,270
+وبالتالي الـ H⁺ في المحلول هي عبارة عن الـ H⁺
+
+119
+00:09:29,270 --> 00:09:33,330
+الذي يأتي من الـ acetic acid. طيب، الـ acetic acid
+
+120
+00:09:33,330 --> 00:09:36,740
+يتفكك، يعطي H⁺ و Acetate. 10⁻³
+
+121
+00:09:36,740 --> 00:09:40,980
+0.001، 10⁻³ - x، x، x. معنى
+
+122
+00:09:40,980 --> 00:09:44,360
+الكلام: الـ equilibrium constant، Ka يساوي x²
+
+123
+00:09:44,360 --> 00:09:48,680
+على 10⁻³ - x. و نفترض، لكي
+
+124
+00:09:48,680 --> 00:09:52,820
+نبسط المسألة، أن الـ 10⁻³ أكبر بكثير
+
+125
+00:09:52,820 --> 00:09:56,580
+من الـ x. الـ x تطلع عندنا 1.23 × 10⁻⁴. هل بالفعل يمكن إهمال الـ x بجانب
+
+126
+00:09:56,580 --> 00:10:00,790
+الـ 10⁻³؟ نحسب الـ relative، إذا يطلع
+
+127
+00:10:00,790 --> 00:10:05,410
+30%. إذا، نعم لا يمكن إهمال الـ x. الـ
+
+128
+00:10:05,410 --> 00:10:09,250
+assumption invalid، و يجب استخدام الـ quadratic
+
+129
+00:10:09,250 --> 00:10:14,050
+equation لمعرفة قيمة الـ x أو الـ hydrogen ion
+
+130
+00:10:14,050 --> 00:10:16,810
+concentration بشكل جيد. هل معنى الكلام هذا أن الـ H⁺
+
+131
+00:10:16,810 --> 00:10:24,720
+الذي يأتي من الماء قليل أم لا؟ نقول
+
+132
+00:10:24,720 --> 00:10:29,420
+هذا ليس له علاقة بالـ H⁺ الذي يأتي من الماء، لسه
+
+133
+00:10:29,420 --> 00:10:34,020
+بعدما نستخدم الـ quadratic equation لحساب الـ H⁺
+
+134
+00:10:34,020 --> 00:10:36,880
+الحقيقي، نجيب الـ hydroxide، الذي يساوي الـ
+
+135
+00:10:36,880 --> 00:10:41,340
+H⁺ الذي يأتي من الماء. وبعدين نقارن بين
+
+136
+00:10:41,340 --> 00:10:45,160
+الاثنين. طبعا سيطلع أيضا قليلا، لا يكاد يذكر، لأنه لا
+
+137
+00:10:45,160 --> 00:10:48,020
+يُعقل يا شباب أن يكون عندي محلول acetic acid تركيزه
+
+138
+00:10:48,020 --> 00:10:51,800
+معقول، 1 millimolar يعتبر كبيرا نسبيا، و يكون فيه
+
+139
+00:10:51,800 --> 00:10:57,220
+تركيز الهيدروكسيد عاليا، له قيمة كبيرة، لا يمكن،
+
+140
+00:10:57,220 --> 00:11:01,550
+ليه؟ لأن هذا محلول ماذا؟ حمض، حمض معناته يعني
+
+141
+00:11:01,550 --> 00:11:04,950
+حامض، لا يمكن أن يكون الهيدروكسيد قيمته كبيرة، وإلا
+
+142
+00:11:04,950 --> 00:11:09,950
+كان محلول ماذا؟ قاعدي، وهذا كلام طبعا غير صحيح. طيب،
+
+143
+00:11:09,950 --> 00:11:12,950
+هذا بالنسبة للحموض، ماذا لو كان اسم الحمض، لو جاء
+
+144
+00:11:12,950 --> 00:11:18,250
+nitrous acid، لو جاء hypochlorous acid، لو جاء
+
+145
+00:11:18,250 --> 00:11:21,810
+chlorous acid، لو جاء hydrocyanic acid، لو جاء
+
+146
+00:11:21,810 --> 00:11:26,090
+benzoic acid. كله نفس الكلام، كله نفس الكلام، نحن
+
+147
+00:11:26,090 --> 00:11:30,010
+بنتعامل بنفس الصيغة، نفس الشيء. يعني نحن أخذنا مثال
+
+148
+00:11:30,010 --> 00:11:33,890
+جاء فيه acetic acid. ممكن أن تسمي الحمض أي اسم
+
+149
+00:11:33,890 --> 00:11:37,530
+آخر، الذي سيختلف هو الـ Ka الخاص به.  ممكن الحمض
+
+150
+00:11:37,530 --> 00:11:40,530
+نسميه، لكي لا نتغلب، HA. جاءك أي weak acid اكتبوا
+
+151
+00:11:40,530 --> 00:11:44,760
+HA. ما دام monoprotic، ما دام monoprotic يعني فيه فقط
+
+152
+00:11:44,760 --> 00:11:49,320
+one proton. جاءك hydrocyanic acid اكتبوا HA، ماشي؟
+
+153
+00:11:49,320 --> 00:11:54,400
+كله نفس الكلام. فأخذنا مثال الـ acetic acid هذا
+
+154
+00:11:54,400 --> 00:12:03,940
+كله الكلام ينطبق على كل الـ monoprotic weak acids.
+
+155
+00:12:03,940 --> 00:12:08,580
+الآن نطلع على الـ bases. و بما أننا نتكلم عن قواعد
+
+156
+00:12:08,580 --> 00:12:13,830
+فنقول: الـ bases التي سنتعامل معها، تقريبا يعني
+
+157
+00:12:13,830 --> 00:12:18,270
+معظمها مشتقة من الـ ammonia، يعني هذه ammonia: NH₃.
+
+158
+00:12:18,270 --> 00:12:22,290
+بدل الـ H ممكن تكون R1، بدل الـ H
+
+159
+00:12:22,290 --> 00:12:27,810
+الثانية R2، صارت NHR1R2، بدل الـ H
+
+160
+00:12:27,810 --> 00:12:33,810
+الثالثة ممكن تكون R3،  إيش الـ R؟ ممكن تكون
+
+161
+00:12:33,810 --> 00:12:37,410
+ميثيل، ممكن تكون إيثيل، ممكن تكون بنزيل، حلقة بنزيل
+
+162
+00:12:37,410 --> 00:12:41,570
+فينيل، يعني لو كانت حلقة بنزيل، ممكن تكون أنيلين. لو
+
+163
+00:12:41,570 --> 00:12:48,010
+كان مثلا إيثيل يكون إيثيل أمين. ميثيل ميثيل أمين. لو كان
+
+164
+00:12:48,010 --> 00:12:54,810
+حلقتين بنزيل ثنائي بنزيل أمين، كويس؟ يعني ممكن الأمين يكون
+
+165
+00:12:54,810 --> 00:12:59,590
+secondary، primary، secondary، tertiary، ممكن أي حاجة،
+
+166
+00:12:59,590 --> 00:13:04,610
+كله بيتعامل معاملة الأمونيا. ما في أمامه خيار إلا
+
+167
+00:13:04,610 --> 00:13:08,690
+أنه يأخذ
+
+168
+00:13:08,690 --> 00:13:12,770
+بروتون من الماء، لأنه قاعدة، فيصبح هو موجب، و الماء
+
+169
+00:13:12,770 --> 00:13:18,850
+
+223
+00:16:53,400 --> 00:16:57,780
+أساليب أتبعها  لأن هذه القيمة اللي هي الـ H⁺ تساوي الـ
+
+224
+00:16:57,780 --> 00:17:02,040
+Hydroxide اللي جاي من الميه ليه؟ لأن مصدر الـ H⁺
+
+225
+00:17:02,040 --> 00:17:05,980
+الوحيد هو الميه. الأمونيا ما بتعطيني ميه، ما بتعطيني
+
+226
+00:17:05,980 --> 00:17:11,700
+H⁺. الميه بس هي اللي بتعطي H⁺. إذا المصدر
+
+227
+00:17:11,700 --> 00:17:17,550
+الوحيد للـ H⁺ هو الميه. طبعا الميه لما تتفكك
+
+228
+00:17:17,550 --> 00:17:21,610
+بتعطي H⁺ وبتعطي  Hydroxide. إذا كمية
+
+229
+00:17:21,610 --> 00:17:24,910
+الـ Hydroxide اللي جاية من الميه أيضا تساوي خمسة وثلاثة فعشرة أس سالب اثني عشر. لو بدنا نقارنها بالواحد
+
+230
+00:17:24,910 --> 00:17:28,570
+وتسعة فعشرة أس سالب ثلاثة، لا تكاد تذكر. يعني ألف مليون
+
+231
+00:17:28,570 --> 00:17:32,430
+مرة تقريبا أكبر منها. إذا كان ممكن بسهولة، أو يعني
+
+232
+00:17:32,430 --> 00:17:38,710
+مبررٌ لنا بسهولة أن نلغي كمية الـ hydroxide اللي
+
+233
+00:17:38,710 --> 00:17:42,610
+جاية من الميّه. لو حاببنا نحسب نسبة الخطأ، إنه
+
+234
+00:17:42,610 --> 00:17:46,510
+والله لغينا الـ hydroxide اللي جاية من الميّه،
+
+235
+00:17:46,510 --> 00:17:48,910
+بنجد أن لغينا الـ hydroxide اللي جاية من الميّه،
+
+236
+00:17:48,910 --> 00:17:51,750
+بُجْسِم هذه، اللي هو الـ hydroxide اللي جاية من الميّه
+
+237
+00:17:51,750 --> 00:17:55,250
+على الـ hydroxide اللي في المحلول في 100 من 100،
+
+238
+00:17:55,250 --> 00:18:00,470
+بيعطيني كمية قليلة للغاية، كمية قليلة للغاية طبعا
+
+239
+00:18:00,470 --> 00:18:04,670
+أنا عندي من الـ hydroxide بحسب الـ pOH وأسهل
+
+240
+00:18:04,670 --> 00:18:11,790
+طريقة  إيجادها من 14 بتعطيني الـ pH. ماشي هذا الكلام
+
+241
+00:18:11,790 --> 00:18:18,030
+يا شباب، إذا لو كان عندي weak base أو weak acid،
+
+242
+00:18:18,030 --> 00:18:23,810
+الشغل يعني بنقدر نقول إنه بسيط كثير، لكن ممنوع منعا
+
+243
+00:18:23,810 --> 00:18:28,070
+باتا أنك والله تحط لي قيمة الـ H⁺ هي عبارة عن
+
+244
+00:18:28,070 --> 00:18:31,490
+تركيز الـ weak acid أو الـ hydroxide هي عبارة عن
+
+245
+00:18:31,490 --> 00:18:35,870
+تركيز الـ weak base. لأ، ما ضبطش هذا إلا للـ strong acids
+
+246
+00:18:35,870 --> 00:18:38,830
+و strong bases. هدول الـ weak acids والـ weak bases،
+
+247
+00:18:38,830 --> 00:18:43,710
+لازم نحسب  جدّاش قيمة الـ H⁺ و جدّاش قيمة الـ
+
+248
+00:18:43,710 --> 00:18:49,450
+Hydroxide. سبق الآن ننتقل يا شباب إلى الـ salts of
+
+249
+00:18:49,450 --> 00:18:55,410
+weak acids والـ salts of weak bases. وبقول في هذه
+
+250
+00:18:55,410 --> 00:18:59,630
+الحالة، أنا عندي نوعين من أنواع الـ salts. عندي
+
+251
+00:18:59,630 --> 00:19:04,830
+نوع بيكون أحد مكوناته جاي من strong acid أو strong
+
+252
+00:19:04,830 --> 00:19:10,580
+base. هو الـ salt شقين، شق من الحمض، و شق من
+
+253
+00:19:10,580 --> 00:19:14,300
+القاعدة هي اللي بيعطيك الـ salt. وبقول أحد هدول
+
+254
+00:19:14,300 --> 00:19:19,040
+الشقين هذا، أول نوع بده يكون جاي من حاجة strong، يا
+
+255
+00:19:19,040 --> 00:19:25,000
+strong acid يا strong base. زي إيش مثلا؟ مثلا
+
+256
+00:19:25,000 --> 00:19:32,100
+عندي لو أخدنا sodium
+
+257
+00:19:32,100 --> 00:19:38,220
+acetate. هذا جاي from acetic acid
+
+258
+00:19:40,020 --> 00:19:52,740
+وهذا from strong base. كل الـ ...
+
+259
+00:19:52,740 --> 00:19:57,780
+هذا كنوع يعني من أنواع الأملاح جاي طبعا من weak
+
+260
+00:19:57,780 --> 00:20:03,280
+acid زي ما احنا شايفين جزء، ومن strong base جزء آخر.
+
+261
+00:20:04,550 --> 00:20:10,550
+طيب، أنا بسأل سؤال: هو هذه... لما نقول weak acid، هو
+
+262
+00:20:10,550 --> 00:20:17,410
+إيش اللي خلاه weak؟ ليش هو weak؟ المرافق
+
+263
+00:20:17,410 --> 00:20:20,710
+... المرافق ضعيف. المرافق...
+
+264
+00:20:20,710 --> 00:20:21,350
+... المرافق...
+
+265
+00:20:21,350 --> 00:20:21,730
+... المرافق...
+
+266
+00:20:21,730 --> 00:20:21,930
+... المرافق...
+
+267
+00:20:21,930 --> 00:20:23,350
+... المرافق...
+
+268
+00:20:23,350 --> 00:20:26,290
+... المرافق...
+
+269
+00:20:26,290 --> 00:20:29,520
+... المرافق...  الأسيتات
+
+270
+00:20:29,520 --> 00:20:34,780
+الأسيتيك أسد هو الحمض ضعيف. ليش الأسيتيك أسد ضعيف ده؟
+
+271
+00:20:34,780 --> 00:20:39,020
+لأنه المرافق، الـ conjugate base تبعته إيش مالها؟ إيش
+
+272
+00:20:39,020 --> 00:20:43,860
+معنى إنها قوية؟ أحسنته، تتفاعل مع الماء. هيها هي
+
+273
+00:20:43,860 --> 00:20:50,960
+الأسيتات + H₂O ⇌ HOAc + Hydroxide. هل هذا تفاعل
+
+274
+00:20:50,960 --> 00:20:54,560
+بيتم ولا لأ؟ ليش بيتم؟
+
+275
+00:20:58,820 --> 00:21:02,260
+ماشي، احنا بدنا نشوف، ادعم هذا strong conjugate base.
+
+276
+00:21:02,260 --> 00:21:06,300
+ليش هو strong؟ لأنّه بيتفاعل مع الماء. طب مش
+
+277
+00:21:06,300 --> 00:21:09,960
+بنعرف أنه هيتفاعل، بيتم. بنطلع على النواتج. آسف،
+
+278
+00:21:09,960 --> 00:21:14,580
+النواتج راسب أو غاز أو weak electrolyte، إذا بيتم.
+
+279
+00:21:14,580 --> 00:21:17,640
+فهي طبعا weak electrolyte. الأسيتيك أسد weak ولا مش weak؟
+
+280
+00:21:17,640 --> 00:21:21,760
+الأسيتيك أسد، بما أنه فيه عندي في النواتج أسيتيك أسد، إذا
+
+281
+00:21:21,760 --> 00:21:27,210
+نعم التفاعل بيتم. أي، أش بتفاعل مع الميّه، معناتها يا
+
+282
+00:21:27,210 --> 00:21:29,890
+بده يعطينا H⁺ يا بده يعطينا Hydroxide. إذا بيغيّر
+
+283
+00:21:29,890 --> 00:21:35,070
+الـ pH. إذا إله تأثير على الـ pH. بينما الصادم إيش
+
+284
+00:21:35,070 --> 00:21:37,490
+قلنا عنه المرة الماضية؟
+
+285
+00:21:43,930 --> 00:21:48,530
+هل هذا التفاعل بيتم؟ بقى هذا لا يتم، لأنه طالع عندي
+
+286
+00:21:48,530 --> 00:21:52,730
+Sodium Hydroxide، و Sodium Hydroxide لا هو غاز ولا
+
+287
+00:21:52,730 --> 00:21:56,890
+هو راسب ولا هو weak. هذا strong electrolyte، بتكونش
+
+288
+00:21:56,890 --> 00:22:04,860
+فما بيتكون. إذا أنا عندي شقّ بيتفاعلش نهائيا مع الميه،
+
+289
+00:22:04,860 --> 00:22:07,980
+وبالتالي هذا ما لي دعوة فيه بالـ pH، ما بيغيّر الـ pH،
+
+290
+00:22:07,980 --> 00:22:12,600
+وشق ثاني آه بيتفاعل مع الميه وبيغيّر الـ pH، يبقى هذا
+
+291
+00:22:12,600 --> 00:22:16,340
+أول نوع من أنواع الـ salts. نفس الكلام لو كان في عندنا
+
+292
+00:22:16,340 --> 00:22:22,720
+مثلا ammonium chloride.
+
+293
+00:22:22,720 --> 00:22:30,500
+بقول هذا جاي من weak base، from weak base لأنه
+
+294
+00:22:30,500 --> 00:22:33,980
+strong conjugate acid from weak base، وهذا جاي من
+
+295
+00:22:33,980 --> 00:22:44,100
+إيه؟ from strong acid. طب هذا from weak base. طب ليش
+
+296
+00:22:44,100 --> 00:22:51,380
+الـ ammonia weak؟ لأنه مرافقه قوي. صحيح الـ ammonia weak،
+
+297
+00:22:51,380 --> 00:22:54,100
+لأنه مرافقه قوي. إيش مرافقه؟
+
+298
+00:22:56,630 --> 00:23:06,830
+الأمونيوم + الميه ⇌ NH₃ + H₃O⁺. بما أن هذا
+
+299
+00:23:06,830 --> 00:23:10,810
+weak electrolyte، إذا كان هيتفاعل بيتم. كويس، لكن الـ
+
+300
+00:23:10,810 --> 00:23:14,670
+chloride جاي من strong acid. طب ليش هو strong acid؟
+
+301
+00:23:14,670 --> 00:23:18,490
+لأن مرافقه ضعيف، ما بيتفاعلش مع الميه. إذا هذا ولا عدّ
+
+302
+00:23:18,490 --> 00:23:23,230
+إنه موجود. إذا الـ salts احنا بنجيب نُجْسِمها، نُجْسِم الـ
+
+303
+00:23:23,230 --> 00:23:28,260
+salts نفسه، نُجْسِم. بنلغي نهائيا اللي بيتفاعلش مع المياه،
+
+304
+00:23:28,260 --> 00:23:31,880
+و نجسّم اللي بيتفاعل... اللي بيتفاعل بس هو المهم، لأن اللي
+
+305
+00:23:31,880 --> 00:23:35,180
+بيتفعلش مع المياه لا يؤثر على الـ pH، وجوده وعدمه
+
+306
+00:23:35,180 --> 00:23:41,220
+واحد من spectator ions. ماشي يا شباب... إذا هذا أول
+
+307
+00:23:41,220 --> 00:23:45,040
+نوع من أنواع الـ salts، الـ salts المكوّنة من weak
+
+308
+00:23:45,040 --> 00:23:50,580
+acid أو weak base مع جزء آخر جاي من strong acid أو
+
+309
+00:23:50,580 --> 00:23:52,820
+strong base. هذا أول نوع من أنواع الـ salts.
+
+310
+00:23:56,360 --> 00:24:00,940
+نفس الكلام بس الإثنين بيتفاعلوش مع الميه، خدت بالك؟ طيب
+
+311
+00:24:00,940 --> 00:24:06,220
+نيجي نتطلع على... يعني
+
+312
+00:24:06,220 --> 00:24:10,580
+لو طلعنا على التفاعل هذا، بلاحظ إيش طلع عندي يا
+
+313
+00:24:10,580 --> 00:24:15,580
+شباب؟ طلع عندي Hydroxide. إذا هذي أكتب لها Kₐ ولا K
+
+314
+00:24:15,580 --> 00:24:24,520
+b؟ K b. طيب، في الكتب كلها وفي المسائل بيعطيني إيش هو
+
+315
+00:24:24,520 --> 00:24:28,680
+الـ equilibrium constant للـ conjugate لحاجة عليها
+
+316
+00:24:28,680 --> 00:24:32,400
+شحنة. لأ، بيعطيني بس للـ uncharged species. الـ case
+
+317
+00:24:32,400 --> 00:24:35,160
+تبعها، يعني هان لو بده يعطيني الأسيتات ما بيعطينيش
+
+318
+00:24:35,160 --> 00:24:38,180
+الأسيتات، بيعطيني الـ acetic acid. فهو إيش بيعطيني؟
+
+319
+00:24:38,180 --> 00:24:42,100
+بيعطيني الـ Kₐ. لكن هذا الـ equilibrium Kₐ ولا K b؟
+
+320
+00:24:42,100 --> 00:24:47,020
+K b. إذا لازم أعرف أحول من الـ Kₐ اللي بيعطيها للـ K b.
+
+321
+00:24:47,020 --> 00:24:51,160
+نفس الكلام هان، هان هيعطيني بس للـ ammonia، K b
+
+322
+00:24:51,160 --> 00:24:56,140
+للأمونيا. لكن هذا إيش طالع عندي؟ H⁺. إذا هذا K
+
+323
+00:24:56,140 --> 00:24:59,880
+ايه؟ المعروف. حول من K b ل K a،
+
+324
+00:24:59,880 --> 00:25:07,000
+لازم في هذه... طبعا بنقعد نستخدم الـ K w. فكيف بدنا
+
+325
+00:25:07,000 --> 00:25:12,160
+نحوّل من Kₐ ل K b ومن K b ل Kₐ؟ ناخد مثال، مثلا الـ
+
+326
+00:25:12,160 --> 00:25:15,320
+Acetic Acid والـ Acetate. فالـ Acetic Acid بتفكك
+
+327
+00:25:15,320 --> 00:25:20,240
+بعطينا H⁺ و Acetate. الـ Kₐ بده يعطينا H⁺ في
+
+328
+00:25:20,240 --> 00:25:23,400
+الـ Acetate على الـ Acetic Acid. طيب تفكك الـ Acetate،
+
+329
+00:25:23,400 --> 00:25:25,560
+الـ Acetate في الميه بعطينا Acetic Acid و
+
+330
+00:25:25,560 --> 00:25:29,080
+Hydroxide. الـ K b بعطينا Acetic Acid في الـ Hydroxide
+
+331
+00:25:29,080 --> 00:25:30,900
+على الـ Acetate.
+
+332
+00:25:33,360 --> 00:25:39,080
+ماشي يا شباب؟ طيب، الآن لو ضربنا Kₐ في K b بلاحظ
+
+333
+00:25:39,080 --> 00:25:42,460
+بيعطينا H⁺ في الـ hydroxide. طبعا هذا الكلام
+
+334
+00:25:42,460 --> 00:25:46,900
+يعني بيساوي K w، بيساوي عشرة أس سالب أربعة عشر. يبقى
+
+335
+00:25:46,900 --> 00:25:50,220
+الـ Kₐ في الـ K b بتساوي عشرة أس سالب أربعة عشر. يبقى
+
+336
+00:25:50,220 --> 00:25:53,600
+لو عندي أنا الـ Kₐ بقدر أجيب الـ K b، ولو عندي الـ K
+
+337
+00:25:53,600 --> 00:25:57,440
+b بقدر أجيب الـ Kₐ. طبعا هذا الكلام صحيح فقط للـ acid
+
+338
+00:25:57,440 --> 00:26:02,120
+base conjugates، للـ acid والمرافق تبعه الـ base، والمرافق تبعه.
+
+339
+00:26:02,120 --> 00:26:07,260
+ماشي يا شباب؟ الآن يعني احنا مؤهلّين أنّه
+
+340
+00:26:07,260 --> 00:26:16,400
+نحاول ندرس كيف نحسب الـ pH لـ الـ salts، وناخد طبعا
+
+341
+00:26:16,400 --> 00:26:20,720
+احنا بنتكلم لسه عن النوع الأول، اللي هو واحد منهم
+
+342
+00:26:20,720 --> 00:26:25,640
+جاي من weak acid أو weak base الشق، والشق الثاني
+
+343
+00:26:25,640 --> 00:26:29,870
+جاي من الـ strong. طيب، نتطلع على المثال التالي، بيقول
+
+344
+00:26:29,870 --> 00:26:34,290
+find the pH of a 0.1 molar solution of sodium
+
+345
+00:26:34,290 --> 00:26:38,470
+acetate. الـ Kₐ لاحظ، هو sodium acetate، لكن إيش
+
+346
+00:26:38,470 --> 00:26:44,390
+يعطيك الـ Kₐ مش الـ K b. بيعطيك إيش الـ K b؟ ليش؟ لأن الـ K b
+
+347
+00:26:44,390 --> 00:26:47,370
+هدول الـ conjugate، ما بيعطيك الـ conjugate، هو بيعطيك
+
+348
+00:26:47,370 --> 00:26:52,470
+لأصل الملح، أصله، أصله جاي من acetic acid، بيعطيك الـ
+
+349
+00:26:52,470 --> 00:26:56,630
+Kₐ للـ acetic acid. فالـ Kₐ واحد و خمسة وسبعين فعشرة
+
+350
+00:26:56,630 --> 00:27:02,070
+أس سالب خمسة. بنيجي بنقول والله في البداية لو إجيت
+
+351
+00:27:02,070 --> 00:27:08,090
+قلت Sodium Acetate هي Na⁺ OAc⁻، بقول هذا
+
+352
+00:27:08,090 --> 00:27:14,730
+جاي من strong base، إذا هو weak conjugate acid، يبقى
+
+353
+00:27:14,730 --> 00:27:19,150
+إيه؟ ما لوش دعوة في حاجة. يبقى عندي بس acetate. الـ
+
+354
+00:27:19,150 --> 00:27:25,140
+acetate في المياه بتعطينا الـ HOAc +
+
+355
+00:27:25,140 --> 00:27:34,920
+الهيدروكسايد. الـ HOAc
+
+356
+00:27:34,920 --> 00:27:41,560
++ الهيدروكسايد.
+
+357
+00:27:42,730 --> 00:27:47,150
+بتفكّر بتعطي H⁺ + Hydroxide. لكن بنفس المنهجية،
+
+358
+00:27:47,150 --> 00:27:51,590
+بنقول الـ acetate إيش بتعطيني؟ Hydroxide. إذا هو
+
+359
+00:27:51,590 --> 00:27:56,090
+محلول قاعدي. اتبع مدار بتعطيني Hydroxide. إذا
+
+360
+00:27:56,090 --> 00:28:01,550
+محلولها إيه؟ قاعدي. محلول قاعدي. طيب، لا يمكن يكون
+
+361
+00:28:01,550 --> 00:28:05,590
+فيه H⁺ كتير، لأن المحلول القاعدي لا يمكن يكون
+
+362
+00:28:05,590 --> 00:28:08,370
+فيه H⁺ كتير. هذه حاجة، الحاجة الثانية المحلول
+
+363
+00:28:08,370 --> 00:28:13,210
+القاعدي، طالع إنّه OH⁻. إيش بده يخلي الميه تسوي
+
+364
+00:28:13,210 --> 00:28:17,150
+تفككها؟ راح يرجع لوراء. معناه كلاهما أصلا كمية الـ
+
+365
+00:28:17,150 --> 00:28:20,530
+hydroxide اللي جاي منها قليلة، لا تكاد تذكر. فما
+
+366
+00:28:20,530 --> 00:28:23,690
+بالكم بعد ما أحط محلول الـ acetate، والـ acetate
+
+367
+00:28:23,690 --> 00:28:26,630
+بيعطيني Hydroxide، يعني عندي common ion، يبقى التفكك
+
+368
+00:28:26,630 --> 00:28:30,830
+راح يرجع لوراء. معناه الكلام كمية الـ hydroxide اللي
+
+369
+00:28:30,830 --> 00:28:35,370
+جاية من الميه... لأ، ما بتتكلم سواء الـ H⁺ وهذا
+
+370
+00:28:35,370 --> 00:28:40,150
+محلول قاعدي، مش محلول حمضي. إذا بقدر أقول أن الـ
+
+371
+00:28:40,150 --> 00:28:43,670
+hydroxide للمحلول هو عبارة عن الـ hydroxide اللي
+
+372
+00:28:43,670 --> 00:28:48,870
+جاي من الـ acetate. بجهز أول خطوة، أنا لغيت الـ Na⁺
+
+373
+00:28:48,870 --> 00:28:53,510
+هذه ولا عدّها موجودة. ليه؟ لأنها weak conjugate
+
+374
+00:28:53,510 --> 00:28:57,670
+acid، لأنها جاية من الـ strong base، فهي ما بتتفعلش مع
+
+375
+00:28:57,670 --> 00:29:02,430
+الميه. إذا لا تؤثر على الـ pH. يبقى بس اللي بيؤثر على
+
+376
+00:29:02,430 --> 00:29:06,330
+الـ pH الـ Acetate. أخدت الـ Acetate وقلت طيب، المصدر
+
+377
+00:29:06,330 --> 00:29:11,170
+الـ hydroxide الـ Acetate وأيضا الميه. فأثبتت أن الـ
+
+378
+00:29:11,170 --> 00:29:15,110
+hydroxide اللي جاي من الميه لا يكاد يُفْجَر، قليل جدا، و
+
+379
+00:29:15,110 --> 00:29:20,250
+أثبتُه يعني مرحليا، لأنه لازم أبرهن على أن إثباتي
+
+380
+00:29:20,250 --> 00:29:26,040
+كان، أو فرضيتي كانت صحيحة. لكن في المستقبل... بقول
+
+381
+00:29:26,040 --> 00:29:28,720
+بيبقى عندي بس أسيتات. إذا اللي أسيتات في الميه
+
+382
+00:29:28,720 --> 00:29:32,560
+بتعطينا Hydroxide و acetic acid. يبقى 0.1، 0.0،
+
+383
+00:29:32,560 --> 00:29:36,420
+0.1 - x، x، x. الـ equilibrium constant
+
+384
+00:29:36,420 --> 00:29:40,720
+بدي أحسبه، هذا K b، لازم أحسبه. K w على الـ Kₐ
+
+385
+00:29:40,720 --> 00:29:46,400
+بيعطيني خمسة وسبعة فعشرة أس سالب عشرة. فبقول
+
+386
+00:29:46,400 --> 00:29:50,120
+والله الـ K b اللي بيساوي x² على 0.1
+
+387
+00:29:50,120 --> 00:29:54,070
+- x. بفترض الـ 0.1 أكبر كتير من الـ x علشان
+
+388
+00:29:54,070 --> 00:29:57,970
+أبسط المسألة، فتطلع عندي الـ
+
+445
+00:34:28,000 --> 00:34:32,640
+الـ Kb بيعطيني الـ Ka برضه خمسة و سبعة فعشرة أس سالب عشرة
+
+446
+00:34:32,640 --> 00:34:36,540
+سالم عشرة، إذا الـ Ka بتساوي الـ H plus في الـ
+
+447
+00:34:36,540 --> 00:34:39,280
+ammonia على الـ ammonium، يعني الـ Ka بتساوي x تنبيه
+
+448
+00:34:39,280 --> 00:34:43,200
+على الـ point two five ناقص x، وعشان أبسط المسألة
+
+449
+00:34:43,200 --> 00:34:48,450
+بقول أن الـ point two five أكبر كثير من الـ x، إذا
+
+450
+00:34:48,450 --> 00:34:54,560
+ممكن إلغاء الـ x جانب الـ point 25، وهذا فرضية بأجيب
+
+451
+00:34:54,560 --> 00:34:57,840
+والله قيمة الـ x بتطلع واحد و اثنين في عشرة أس سالب
+
+452
+00:34:57,840 --> 00:35:01,400
+خمسة، بقول هل بالفعل الواحد و اثنين في عشرة أس سالب
+
+453
+00:35:01,400 --> 00:35:04,920
+خمسة أقل كتير من الـ point two five، بنجيب الـ
+
+454
+00:35:04,920 --> 00:35:08,160
+relative error و بيطلع حاجة جزء من الألف في المئة
+
+455
+00:35:08,160 --> 00:35:12,660
+جزء من الألف في المئة، معناه كلام نعم، الـ assumption
+
+456
+00:35:12,660 --> 00:35:18,930
+عندي valid، الـ assumption عندي valid، معنى الكلام الـ
+
+457
+00:35:18,930 --> 00:35:22,030
+H plus بتساوي واحد و اثنين في عشرة أس سالب خمسة
+
+458
+00:35:22,030 --> 00:35:27,770
+وهذا الـ H plus في المحلول اللي هو جاي طبعاً من الـ ammonium
+
+459
+00:35:27,770 --> 00:35:32,920
+طب هنا بقدر أجيب قيمة الـ hydroxide، على طول Kw بتساوي
+
+460
+00:35:32,920 --> 00:35:36,400
+الهيدروكسيد في الـ H بلس، يبقى الهيدروكسيد بتساوي
+
+461
+00:35:36,400 --> 00:35:42,100
+ثمانية و ثلاثة في عشرة أس سالب عشرة، هذا عبارة عن الـ
+
+462
+00:35:42,100 --> 00:35:46,780
+H بلس اللي جاي من الميّه، لإنه مصدر الهيدروكسيد
+
+463
+00:35:46,780 --> 00:35:50,600
+الوحيد هو الميّه، والميّه لما تتفكك بتعطيني
+
+464
+00:35:52,630 --> 00:35:57,010
+هيدروكسايد و protons يعني H بلس، فطبيعي أن الـ H
+
+465
+00:35:57,010 --> 00:35:59,950
+بلس اللي جاي من الميّه بتساوي الهيدروكسيد، معنى
+
+466
+00:35:59,950 --> 00:36:02,590
+الكلام الـ H بلس اللي جاي من الميّه عبارة عن ثمانية
+
+467
+00:36:02,590 --> 00:36:05,830
+و ثلاثة في عشرة أس سالب عشرة، هل يمكن إلغاء
+
+468
+00:36:05,830 --> 00:36:10,010
+الثمانية و ثلاثة في عشرة أس سالب عشرة بالمقارنة مع
+
+469
+00:36:10,010 --> 00:36:14,190
+الواحد و اثنين في عشرة أس سالب خمسة؟ ممكن إلغاها
+
+470
+00:36:14,190 --> 00:36:16,150
+ولا لأ؟ والله بنجيب الـ relative error ولا ولا
+
+471
+00:36:16,150 --> 00:36:20,700
+نجيب الـ relative error، لو لغيناها، فعندي
+
+472
+00:36:20,700 --> 00:36:24,460
+ثمانية و ثلاثة في عشرة أس سالب عشرة على واحد و
+
+473
+00:36:24,460 --> 00:36:27,480
+اثنين في عشرة أس سالب خمسة في مئة من المئة، بيطلع
+
+474
+00:36:27,480 --> 00:36:32,020
+الرقم يعني قليل جداً، جزء من الألف في المئة، نسبة الخطأ يعني
+
+475
+00:36:32,020 --> 00:36:39,570
+لا شك أنّه إلغاء أو عدم الاهتمام أو إهمال الـ H plus
+
+476
+00:36:39,570 --> 00:36:43,210
+اللي جاية من الميّه هذا شيء طبيعي جداً، ليه؟ لأنّه في
+
+477
+00:36:43,210 --> 00:36:50,010
+عندي كمية من الـ H plus كبيرة جاية من الـ ammonium
+
+478
+00:36:50,010 --> 00:36:54,250
+طبعاً أنا ممكن برضه يعني ألفت انتباهكم لنقطة
+
+479
+00:36:56,730 --> 00:37:01,290
+لو قلنا الـ Ka،  حسبناها هنا بتساوي خمسة و سبعة
+
+480
+00:37:01,290 --> 00:37:07,790
+في عشرة أس سالب عشرة، وهذا الـ Kw تفكك بيساوي عشرة
+
+481
+00:37:07,790 --> 00:37:13,390
+أس سالب أربعة عشر، لو إجينا احنا قلنا أن هذا التفكك
+
+482
+00:37:13,390 --> 00:37:18,170
+بيعطيني H plus، وهذا التفكك أيضاً بيعطيني H plus مثلاً
+
+483
+00:37:18,170 --> 00:37:24,250
+برضه هذا بيدلك يعني أو بيعطيك فكرة هل شغلك يعني
+
+484
+00:37:24,250 --> 00:37:28,780
+منطقي أو فرضيتك منطقية ولا لأ، هذا عشرة أس سالب عشرة
+
+485
+00:37:28,780 --> 00:37:32,000
+الـ Ka، وهذا عشرة أس سالب أربعة عشر، يعني الأول لو
+
+486
+00:37:32,000 --> 00:37:39,380
+طلعناه ماشي بدرجة أكبر من الثاني بحوالي سبعة
+
+487
+00:37:39,380 --> 00:37:43,490
+وخمسين ألف مرة، لأ دي خمسة مش واحد، هذي خمسة وسبعة (57)
+
+488
+00:37:43,490 --> 00:37:47,870
+ألف مرة، إيش معناه هذا الكلام؟ يعني لما يعطيني
+
+489
+00:37:47,870 --> 00:37:52,630
+الأول 57 ألف بروتون، الثاني بيعطيني بروتون واحد، كل
+
+490
+00:37:52,630 --> 00:37:56,550
+57 ألف بروتون، الثاني إيش بيعطيني؟ بروتون واحد، إذا
+
+491
+00:37:56,550 --> 00:38:00,370
+هذا البروتون يعني لا يكاد يذكر، يعني كميته قليلة
+
+492
+00:38:00,370 --> 00:38:07,530
+جداً، كميته قليلة للغاية، طيب، نفس الكلام يمكن
+
+493
+00:38:07,530 --> 00:38:12,810
+برضه أقوله في حكاية القواعد
+
+494
+00:38:18,580 --> 00:38:22,600
+برضه الـ Kb كان بيساوي خمسة و سبعة في عشرة أس سالب
+
+495
+00:38:22,600 --> 00:38:28,820
+عشرة، وهنا الـ H2O H plus زائد هيدروكسيد، والـ Kw
+
+496
+00:38:28,820 --> 00:38:33,780
+بده يساوي عشرة أس سالب أربعة عشر، نفس الكلام يعني
+
+497
+00:38:33,780 --> 00:38:37,580
+بشوف الهيدروكسيد اللي جاية من هنا، كل خمسة وسبعين
+
+498
+00:38:37,580 --> 00:38:42,560
+ألف هيدروكسيد جاية من الأول، لأنها الـ equilibrium
+
+499
+00:38:42,560 --> 00:38:44,800
+constant، هذا rate
+
+500
+00:38:46,840 --> 00:38:50,480
+التفكك الثاني، مستمر، بقول كل 57 ألف هيدروكسيد
+
+501
+00:38:50,480 --> 00:38:53,900
+بحصلها في التفكك الأول، بحصل مقابلها على واحدة بس
+
+502
+00:38:53,900 --> 00:38:56,940
+من التفكك الثاني، إذا التفكك الثاني هذا لا يكاد
+
+503
+00:38:56,940 --> 00:38:59,760
+يذكر، التفكك الثاني هذا لا يكاد يذكر، وكأنه مش
+
+504
+00:38:59,760 --> 00:39:04,880
+موجود، واخدين بالنا يا شباب؟ طبعاً بعد هيك سهل أنّه
+
+505
+00:39:04,880 --> 00:39:10,640
+نحسب الـ pH على طول من واحد و اثنين في 10 أس سالب خمسة، minus log
+
+506
+00:39:10,640 --> 00:39:15,880
+بتعطينا 4.92، ولاحظ أن الـ pH حامضية، ليه؟ لأن هذا
+
+507
+00:39:15,880 --> 00:39:19,620
+salt مشتق من weak base، الـ salt اللي ممكن مشتق من
+
+508
+00:39:19,620 --> 00:39:24,020
+weak base، الـ pH تبعه حامضية، بعكس الـ salt المشتق من
+
+509
+00:39:24,020 --> 00:39:28,200
+weak acid، الـ pH تبعه قاعدي، وطبعاً الـ pOH بنجيبها
+
+510
+00:39:28,200 --> 00:39:31,260
+14 ناقص الـ pH
+
+511
+00:39:35,250 --> 00:39:39,070
+خلّينا يا شباب برضه بما أنّه فتحنا هذا الموضوع، ناخد
+
+512
+00:39:39,070 --> 00:39:42,770
+النوع الثاني من الـ salts، النوع الثاني من الـ salts
+
+513
+00:39:42,770 --> 00:39:45,750
+طبعاً احنا لما نيجي نتطلع على الـ salts بنقول الـ salts
+
+514
+00:39:45,750 --> 00:39:51,370
+شقين، ممكن شق منه يكون جاي من strong acid، و شق جاي
+
+515
+00:39:51,370 --> 00:39:54,570
+من strong base، هذا ما درسناه الحصة الماضية، الآن
+
+516
+00:39:54,570 --> 00:40:01,390
+درسنا شق جاي من weak acid مثلاً أو weak base، و شق
+
+517
+00:40:01,390 --> 00:40:07,200
+جاي من strong، اللي جاي من الـ strong لا يحسب، لأنه
+
+518
+00:40:07,200 --> 00:40:12,040
+very weak conjugate، طبعاً لا يتفاعل مع الميّه، طيب
+
+519
+00:40:12,040 --> 00:40:16,200
+ممكن النوع الثالث من أنواع الـ salts اللي احنا راح
+
+520
+00:40:16,200 --> 00:40:22,060
+نذكرها، الـ salt مشتق من اثنين weak، weak acid و weak
+
+521
+00:40:22,060 --> 00:40:26,180
+base، أو weak base و weak acid، معايا يعني ما فيش
+
+522
+00:40:26,180 --> 00:40:30,740
+حاجة strong، زي إيش مثلاً؟ زي مثلاً الـ ammonium
+
+523
+00:40:30,740 --> 00:40:31,380
+cyanide
+
+524
+00:40:34,380 --> 00:40:48,060
+NH4CN، هذا from weak acid اللي هو HCN، وهذا from
+
+525
+00:40:48,060 --> 00:40:51,480
+weak
+
+526
+00:40:51,480 --> 00:41:01,000
+base اللي هو NH3، صح ولا لأ؟ إذا هذا strong
+
+527
+00:41:03,200 --> 00:41:08,440
+conjugate base،  من weak acid، ليش هو weak acid؟
+
+528
+00:41:08,440 --> 00:41:13,500
+لأن الـ conjugate base تبعه strong، طب وهذا ليش هو
+
+529
+00:41:13,500 --> 00:41:21,440
+weak base؟ إذا خلينا نعمل السهم هذا هنا، وناخد
+
+530
+00:41:21,440 --> 00:41:26,940
+السهم هذا هيك، ونقول والله هذا عبارة عن strong
+
+531
+00:41:26,940 --> 00:41:29,160
+conjugate
+
+532
+00:41:30,390 --> 00:41:34,990
+أسيد، إيش يعني strong conjugate base؟ يعني بيتفاعل
+
+533
+00:41:34,990 --> 00:41:39,090
+مع الميّه، وإيش يعني strong conjugate acid؟ بيتفاعل
+
+534
+00:41:39,090 --> 00:41:42,230
+مع الميّه، إذا الاثنين تفاعلوا مع الميّه، دي مشكلة،
+
+535
+00:41:42,230 --> 00:41:45,810
+الاثنين لازم يعدوا في الحسابات، ومش بس هيك كمان،
+
+536
+00:41:45,810 --> 00:41:49,830
+والميّه كمان بتعدي في الحسابات، إذا كان يعني كان في
+
+537
+00:41:49,830 --> 00:41:54,850
+ضرورة لها، طب بشوف المثال اللي قدامنا بيقول for
+
+538
+00:41:54,850 --> 00:41:59,330
+example، look at the calculation of pH for a 0.1
+
+539
+00:41:59,330 --> 00:42:06,190
+molar ammonium cyanide، معطيك الـ Kb للأمونيا واحد و
+
+540
+00:42:06,190 --> 00:42:10,410
+ثمانية في عشرة أس سالب خمسة، ومعطيك الـ Ka للـ HCN
+
+541
+00:42:10,410 --> 00:42:14,010
+طبعاً لأنه بيعطيك  Ka للـ conjugate، بيعطيك للأصل زي ما
+
+542
+00:42:14,010 --> 00:42:19,170
+أنت فاهم، ستة في عشرة أس سالب عشرة، طيب بنقول
+
+543
+00:42:19,170 --> 00:42:24,990
+التالي، إذا الأمونيا في الميّه بتعطينا بروتون
+
+544
+00:42:24,990 --> 00:42:31,070
+وأمونيا، الـ Ka لها خمسة وسبعة في عشرة أس سالب عشرة
+
+545
+00:42:31,070 --> 00:42:35,150
+والسينيد في الميّه بتعطينا HCN زائد هيدروكسيد
+
+546
+00:42:35,150 --> 00:42:39,850
+وهذا Kb، لأنه طالع عندي هيدروكسيد، لما نحسبها Kw على
+
+547
+00:42:39,850 --> 00:42:45,650
+Ka بتطلع عندي واحد وسبعة في عشرة أس سالب خمسة، طيب كيف
+
+548
+00:42:45,650 --> 00:42:49,800
+الآن بدي أفكر أنا؟ بقول لما الكونستنت ده أكثر، وكمان
+
+549
+00:42:49,800 --> 00:42:55,860
+هي الميّه، يعني إذا كان في اتنين، هي الـ H2O H بلس زائد
+
+550
+00:42:55,860 --> 00:43:01,980
+هيدروكسيد، تعالوا الـ Kw هي عشرة أس سالب أربعة عشر
+
+551
+00:43:01,980 --> 00:43:09,520
+تعالوا في الأول نقارن الـ two equilibria، هيك الشغل
+
+552
+00:43:09,520 --> 00:43:12,440
+بنقارن، ما هو لما الكونستنت ده أكثر من الـ
+
+553
+00:43:12,440 --> 00:43:16,110
+equilibrium مشكلة، فإبداً أحاول أنا اختصر هالـ
+
+554
+00:43:16,110 --> 00:43:20,670
+equilibrium هذه لـ one single equilibrium، بحاول
+
+555
+00:43:20,670 --> 00:43:25,540
+أعمل هذا الكلام، طبعاً يمكن حل الأكثر من إيكوليبريا
+
+556
+00:43:25,540 --> 00:43:29,020
+لكن احنا بنحاول نبسط الموضوع، ومش هنا  كن حل أكثر من
+
+557
+00:43:29,020 --> 00:43:34,120
+إيكوليبريا، بنحل بس بالتبسيط لأقل أو لأقرب لـ
+
+558
+00:43:34,120 --> 00:43:39,580
+إيكوليبريا واحد فقط إن أمكن، ما أمكنش بنقول والله آه
+
+559
+00:43:39,580 --> 00:43:42,680
+هذه مسألة تحتاج إلى أنّه نحل بالـ two equilibrium
+
+560
+00:43:42,680 --> 00:43:46,460
+يعني يمكن أعطيكم هذا الكلام، أتكلم عن الـ polyprotic
+
+561
+00:43:46,460 --> 00:43:50,320
+acids، ففي البداية نطلع على الاثنين ونحاول نفهم من
+
+562
+00:43:50,320 --> 00:43:52,420
+الـ equilibrium constant، هذا الـ equilibrium
+
+563
+00:43:52,420 --> 00:43:56,840
+constant عشرة أس سالب عشرة، هذا الـ equilibrium
+
+564
+00:43:56,840 --> 00:44:01,180
+constant عشرة أس سالب خمسة، إذا أنّه بيتم بدرجة
+
+565
+00:44:01,180 --> 00:44:07,420
+كبيرة، الثاني، الثاني بيتم، آه الـ Kb بيتم أكبر يعني
+
+566
+00:44:07,420 --> 00:44:15,480
+تقريباً مئة ألف مرة أكثر من الأول، يعني كل ما هذا
+
+567
+00:44:15,480 --> 00:44:20,620
+يعطيني 100 ألف Hydroxide، هذا بيعطيني واحدة Proton،
+
+568
+00:44:20,620 --> 00:44:23,700
+Proton واحد، كل 100 ألف Hydroxide، إيش بيعطيني
+
+569
+00:44:23,700 --> 00:44:28,540
+جمالها الأول؟ Proton واحد، يعني معناه الكلام وكأنه
+
+570
+00:44:28,540 --> 00:44:34,300
+هذا الأول ما إله قيمة، ما إله قيمة بالمقارنة مع
+
+571
+00:44:34,300 --> 00:44:40,200
+الثاني، إذا المحلول في البداية بنقول، من كلامي
+
+572
+00:44:40,200 --> 00:44:42,820
+بمقارنة الاثنين، الـ first equilibrium can be
+
+573
+00:44:42,820 --> 00:44:47,560
+neglected، يهمل معايا ولا لأ؟ يمكن إهماله في
+
+574
+00:44:47,560 --> 00:44:51,720
+الحقيقة، الحاجة الثانية، مدام أهملنا، طب تعال نتطلع
+
+575
+00:44:51,720 --> 00:44:54,540
+على الـ equilibrium الثالث اللي هو الميّه، أنا عندي
+
+576
+00:44:54,540 --> 00:44:58,940
+هذه عشرة أس سالب خمسة، وهنا عشرة أس سالب أربعة عشر،
+
+577
+00:44:58,940 --> 00:45:02,280
+يعني كل ما الأول يعطينا Hydroxide، الثاني كم Hydroxide بيعطيني،
+
+578
+00:45:02,280 --> 00:45:05,780
+Hydroxide، بيعطيني كمية قليلة كتير، طب لما من الأول
+
+579
+00:45:05,780 --> 00:45:08,820
+يعطيني... لو قسمنا عشرة أس سالب خمسة على عشرة
+
+580
+00:45:08,820 --> 00:45:13,340
+أس سالب أربعة عشر، تقريباً بتطلع عشرة أس تسعة، يعني
+
+581
+00:45:13,340 --> 00:45:17,540
+كل ألف مليون Hydroxide بحصلها من الأول، بحصلها
+
+582
+00:45:17,540 --> 00:45:23,460
+Hydroxide واحدة من الميّه، معايا ولا لأ؟ كل ألف
+
+583
+00:45:23,460 --> 00:45:27,400
+مليون، عشرة أس تسعة Hydroxide بحصلها من الأول
+
+584
+00:45:27,400 --> 00:45:32,140
+الثاني بيعطيني إيه؟ one single...  لا، إذا
+
+585
+00:45:32,140 --> 00:45:39,730
+هذا الثاني راح، طبعاً واحد من الألف مليون ولا شيء، إذا
+
+586
+00:45:39,730 --> 00:45:43,650
+يا شباب اختصرت هذه الـ equilibrium لإيه؟ لـ one
+
+587
+00:45:43,650 --> 00:45:46,110
+single equilibrium، هذا هو الـ equilibrium المهم
+
+588
+00:45:46,110 --> 00:45:49,830
+عندي، هذا هو اللي هيأثر على الـ pH، إذا الـ pH تبعتي
+
+589
+00:45:49,830 --> 00:45:53,890
+إيش حتكون؟ قاعدية
+
+590
+00:45:53,890 --> 00:45:57,850
+معليش أنا فجأة استفدت، حتى لو ما عرفتش أحسبها، عرفت
+
+591
+00:45:57,850 --> 00:46:02,310
+أن الـ pH تبعتي حتكون إيش؟ قاعدية، بنبني الآن لعملية
+
+592
+00:46:02,310 --> 00:46:06,970
+الحساب، يبدأ الحساب بس one equilibrium، cyanide زائد
+
+593
+00:46:06,970 --> 00:46:11,950
+H2O بيعطينا HCN زائد hydroxide، هالمعنى لكلام، هذه
+
+594
+00:46:11,950 --> 00:46:15,190
+الـ equilibrium مش موجودة، لا موجودة، لكن تأثيرها على
+
+595
+00:46:15,190 --> 00:46:19,640
+الـ pH لا يكاد يذكر، قليل للغاية، طب الآن يا شباب هي
+
+596
+00:46:19,640 --> 00:46:24,280
+الـ cyanide والميّه بيعطينا HCN و Hydroxide، هذا
+
+597
+00:46:24,280 --> 00:46:31,160
+عندي 0.100، 0.1-x، معنى الكلام الـ Kb بده يساوي
+
+598
+00:46:31,160 --> 00:46:35,180
+الـ HCN في الهيدروكسيد على الـ CN في الـ CN minus
+
+599
+00:46:35,180 --> 00:46:40,720
+فبقول، معنى الكلام راح نلاقي أنّه الـ equilibrium
+
+600
+00:46:40,720 --> 00:46:45,340
+constant الـ Kb بده يساوي x تربيع على الـ point one
+
+601
+00:46:45,340 --> 00:46:49,240
+ناقص x، بفترض أن الـ point one أكبر كتير من الـ x، الـ
+
+602
+00:46:49,240 --> 00:46:52,660
+x بتطلع عندي واحد و ثلاثة في عشرة أس سالب ثلاثة
+
+603
+00:46:52,660 --> 00:46:57,340
+معنى الكلام الـ relative error قليل، إذا الـ
+
+604
+00:46:57,340 --> 00:47:00,840
+assumption valid، يبدأ على طول الـ hydroxide واحد و
+
+605
+00:47:00,840 --> 00:47:04,400
+ثلاثة في عشرة أس سالب ثلاثة، ومنها الـ pOH اثنين و
+
+606
+00:47:04,400 --> 00:47:10,300
+ثمانية وتسعون، والـ pH أربعة عشر ناقص الـ pOH، ماشي
+
+607
+00:47:10,300 --> 00:47:21,160
+يا جماعة، طيب هيك بنكون أخذنا أو أكملنا دراسة كيفية
+
+608
+00:47:21,160 --> 00:47:26,020
+حساب الـ pH لـ weak acids والـ weak bases والـ
+
+609
+00:47:26,020 --> 00:47:29,580
+salts لـ weak acids والـ weak bases بنوعها
+
+610
+00:47:29,580 --> 00:47:35,220
+المكونة من weak acid أو weak base مع
\ No newline at end of file
diff --git a/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/iyej-ZK7KYU_raw.json b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/iyej-ZK7KYU_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..aa4063bf79bd8c261ce96e74c16deee6b0ad4079
--- /dev/null
+++ b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/iyej-ZK7KYU_raw.json
@@ -0,0 +1 @@
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ال H plus اللي جاي من الميه هذا مهم ولا مش مهم وكيف نحسب ال H plus للمحلول فنتطلع على هذا المثال اللي جدامي بقول calculate the pH and pOH", "tokens": [5172, 2304, 12984, 15040, 8717, 47283, 3215, 45030, 11242, 16247, 2304, 12984, 37977, 4032, 27842, 16490, 1211, 6027, 29538, 16247, 2304, 12984, 37977, 8717, 30241, 4587, 15844, 9154, 3224, 7435, 10632, 16712, 5172, 4117, 13546, 8978, 8032, 1211, 37495, 22653, 2423, 389, 1804, 13672, 1829, 10874, 47302, 9154, 9673, 1829, 3224, 23758, 3714, 16095, 49429, 37893, 3714, 16095, 4032, 4117, 33911, 8717, 5016, 35457, 2423, 389, 1804, 5296, 19528, 5016, 1211, 12610, 6156, 29399, 9566, 1211, 3615, 15844, 23758, 9673, 12984, 6027, 13672, 1829, 10874, 3215, 10943, 1829, 4724, 39648, 8873, 264, 21677, 293, 280, 31187], "avg_logprob": -0.14900129357564082, "compression_ratio": 1.6886792452830188, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 220.12, "end": 220.96, "word": "فمثلا", "probability": 0.8233642578125}, {"start": 220.96, 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"seek": 73042, "start": 703.92, "end": 730.42, "text": "و ممكن ال acid نسميه عشان ما نتغلبش HA جالك منزل weak acid اكتبوا HA مادامه monoprotic مادامه monoprotic يعني فيه بس one proton جالك hydrocyanic acid اكتبوا HA ماشي كله نفس الكلام فاحنا أخدنا مثال ال acetic acid ده كده الكلام المنطبق على كل ال monoprotic weak acids الآن نطلع على ال bases", "tokens": [2407, 3714, 43020, 2423, 8258, 8717, 38251, 1829, 3224, 6225, 8592, 7649, 19446, 8717, 2655, 17082, 46152, 8592, 11979, 10874, 6027, 4117, 9154, 11622, 1211, 5336, 8258, 1975, 4117, 2655, 3555, 14407, 11979, 3714, 18513, 10943, 3224, 1108, 404, 81, 9411, 3714, 18513, 10943, 3224, 1108, 404, 81, 9411, 37495, 22653, 8978, 3224, 4724, 3794, 472, 31728, 10874, 6027, 4117, 15435, 1344, 30732, 8258, 1975, 4117, 2655, 3555, 14407, 11979, 3714, 33599, 1829, 28242, 3224, 8717, 36178, 2423, 28820, 10943, 6156, 39319, 8315, 5551, 9778, 3215, 8315, 50113, 6027, 2423, 696, 3532, 8258, 11778, 3224, 9122, 3215, 3224, 2423, 28820, 10943, 9673, 1863, 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"text": "نفس العالم بس التنين بتفعلوش مع الميه خدت بالك طيب نيجي نتطلع على يعني لو طلعنا على التفاعل هذا بلاحظ ايش طلع عندي يا شباب طلع عندي hydroxide اذا هذي اكتبلها K A ولا K B K B طيب", "tokens": [1863, 36178, 18863, 45340, 4724, 3794, 16712, 1863, 9957, 39894, 5172, 30241, 2407, 8592, 20449, 9673, 1829, 3224, 16490, 3215, 2655, 20666, 4117, 23032, 1829, 3555, 8717, 1829, 7435, 1829, 8717, 2655, 9566, 1211, 3615, 15844, 37495, 22653, 45164, 23032, 1211, 3615, 8315, 15844, 16712, 5172, 995, 30241, 23758, 4724, 15040, 5016, 19913, 1975, 1829, 8592, 23032, 1211, 3615, 18871, 16254, 35186, 13412, 3555, 16758, 23032, 1211, 3615, 18871, 16254, 15435, 34454, 1975, 15730, 8032, 8848, 1829, 1975, 4117, 2655, 3555, 1211, 11296, 591, 316, 49429, 591, 363, 591, 363, 23032, 1829, 3555], "avg_logprob": -0.2729388348599698, "compression_ratio": 1.6910112359550562, "no_speech_prob": 2.980232238769531e-07, "words": [{"start": 1436.36, "end": 1436.7, "word": "نفس", "probability": 0.712646484375}, 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Acid طيب تفكك ال Acetate .. ال Acetate في الميه بعطينا Acetic Acid و Hydroxide ال KB بعطينا Acetic Acid في ال Hydroxide على ال Acetate", "tokens": [41185, 29538, 4386, 23032, 3555, 3615, 995, 4724, 4587, 22488, 8717, 14851, 9778, 40448, 2423, 591, 54, 6156, 4117, 33911, 47525, 8315, 8717, 5016, 12610, 9154, 31233, 5296, 42, 33, 4032, 9154, 591, 33, 5296, 16135, 8717, 47283, 3215, 50113, 6027, 50113, 15040, 2423, 5097, 3532, 5097, 327, 4032, 2423, 5097, 302, 473, 6156, 6027, 5097, 3532, 5097, 327, 39894, 5172, 4117, 4117, 45030, 9566, 1829, 8315, 389, 7721, 4032, 5097, 302, 473, 2423, 31233, 47525, 3224, 37495, 9566, 1829, 8315, 389, 7721, 8978, 2423, 5097, 302, 473, 15844, 2423, 5097, 3532, 5097, 327, 23032, 1829, 3555, 6055, 5172, 4117, 4117, 2423, 5097, 302, 473, 4386, 2423, 5097, 302, 473, 8978, 9673, 1829, 3224, 45030, 9566, 1829, 8315, 5097, 3532, 5097, 327, 4032, 24231, 340, 34454, 2423, 591, 33, 45030, 9566, 1829, 8315, 5097, 3532, 5097, 327, 8978, 2423, 24231, 340, 34454, 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الهيدروكسايد", "tokens": [6027, 39184, 23097, 4378, 30767, 16373, 3215, 2423, 3224, 25708, 2288, 2407, 4117, 3794, 995, 25708, 2423, 39184, 23097, 4378, 30767, 16373, 3215, 2423, 3224, 25708, 32887, 4117, 3794, 995, 25708], "avg_logprob": -0.5136718470603228, "compression_ratio": 1.6851851851851851, "no_speech_prob": 5.364418029785156e-07, "words": [{"start": 1642.78, "end": 1643.36, "word": "الـ", "probability": 0.3116455078125}, {"start": 1643.36, "end": 1644.16, "word": " HOAC", "probability": 0.33734130859375}, {"start": 1644.16, "end": 1645.14, "word": " زائد", "probability": 0.564697265625}, {"start": 1645.14, "end": 1646.38, "word": " الهيدروكسايد", "probability": 0.7933213975694444}, {"start": 1646.38, "end": 1648.5, "word": " الـ", "probability": 0.4288330078125}, {"start": 1648.5, "end": 1654.92, "word": " HOAC", "probability": 0.414581298828125}, {"start": 1654.92, "end": 1656.28, "word": " زائد", "probability": 0.7275390625}, {"start": 1656.28, "end": 1661.56, "word": " 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"text": "بقول لما الكورفين ده أكتر و كمان هى الميه يعنى إذا كان حبين هى ال H2O H بلس زائد هيدروفسايد تعالوا ال KWLH عشرة أس سالب أربعة عشر تعالوا في الأول نقارن ال two equilibria هيك الشغل بنقارن ما هو لما الكورفين ده أكتر من ال equilibrium مشكلة", "tokens": [3555, 39648, 5296, 15042, 33251, 13063, 5172, 9957, 11778, 3224, 5551, 4117, 2655, 2288, 4032, 9122, 2304, 7649, 8032, 7578, 9673, 1829, 3224, 37495, 1863, 7578, 11933, 15730, 25961, 11331, 21292, 1863, 8032, 7578, 2423, 389, 17, 46, 389, 4724, 1211, 3794, 30767, 16373, 3215, 8032, 25708, 32887, 5172, 3794, 995, 25708, 37279, 6027, 14407, 2423, 591, 54, 43, 39, 6225, 8592, 25720, 5551, 3794, 8608, 6027, 3555, 5551, 25513, 27884, 6225, 46309, 37279, 6027, 14407, 8978, 16247, 12610, 8717, 4587, 9640, 1863, 2423, 732, 14204, 4668, 39896, 4117, 25124, 17082, 1211, 44945, 4587, 9640, 1863, 19446, 31439, 5296, 15042, 33251, 13063, 5172, 9957, 11778, 3224, 5551, 4117, 2655, 2288, 9154, 2423, 15625, 37893, 28820, 3660], "avg_logprob": -0.28258546193440753, "compression_ratio": 1.747787610619469, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 2567.66, "end": 2568.24, "word": "بقول", "probability": 0.73095703125}, {"start": 2568.24, "end": 2568.62, "word": " لما", "probability": 0.80908203125}, {"start": 2568.62, "end": 2569.04, "word": " الكورفين", "probability": 0.464080810546875}, {"start": 2569.04, "end": 2569.26, "word": " ده", "probability": 0.6029052734375}, {"start": 2569.26, "end": 2569.44, "word": " أكتر", "probability": 0.8885498046875}, {"start": 2569.44, "end": 2569.52, "word": " و", "probability": 0.6123046875}, {"start": 2569.52, "end": 2569.8, "word": " كمان", "probability": 0.7539876302083334}, {"start": 2569.8, "end": 2570.02, "word": " هى", "probability": 0.4388427734375}, {"start": 2570.02, "end": 2570.46, "word": " الميه", "probability": 0.8743489583333334}, {"start": 2570.46, "end": 2570.66, "word": " يعنى", "probability": 0.7111002604166666}, {"start": 2570.66, "end": 2570.82, 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2579.3, "word": " KWLH", "probability": 0.63818359375}, {"start": 2579.3, "end": 2580.44, "word": " عشرة", "probability": 0.806640625}, {"start": 2580.44, "end": 2580.7, "word": " أس", "probability": 0.682861328125}, {"start": 2580.7, "end": 2581.14, "word": " سالب", "probability": 0.5745442708333334}, {"start": 2581.14, "end": 2581.56, "word": " أربعة", "probability": 0.7771809895833334}, {"start": 2581.56, "end": 2581.98, "word": " عشر", "probability": 0.662109375}, {"start": 2581.98, "end": 2584.72, "word": " تعالوا", "probability": 0.9630533854166666}, {"start": 2584.72, "end": 2584.82, "word": " في", "probability": 0.65478515625}, {"start": 2584.82, "end": 2585.1, "word": " الأول", "probability": 0.985595703125}, {"start": 2585.1, "end": 2585.8, "word": " نقارن", "probability": 0.9439697265625}, {"start": 2585.8, "end": 2586.1, "word": " ال", "probability": 0.9658203125}, {"start": 2586.1, "end": 2586.26, "word": " two", "probability": 0.7080078125}, {"start": 2586.26, "end": 2587.4, "word": " equilibria", "probability": 0.794677734375}, {"start": 2587.4, "end": 2589.08, "word": " هيك", "probability": 0.947021484375}, {"start": 2589.08, "end": 2589.52, "word": " الشغل", "probability": 0.98681640625}, {"start": 2589.52, "end": 2590.32, "word": " بنقارن", "probability": 0.9005126953125}, {"start": 2590.32, "end": 2590.86, "word": " ما", "probability": 0.6171875}, {"start": 2590.86, "end": 2591.12, "word": " هو", "probability": 0.55712890625}, {"start": 2591.12, "end": 2591.64, "word": " لما", "probability": 0.893310546875}, {"start": 2591.64, "end": 2591.94, "word": " الكورفين", "probability": 0.9224853515625}, {"start": 2591.94, "end": 2592.08, "word": " ده", "probability": 0.97607421875}, {"start": 2592.08, "end": 2592.28, "word": " أكتر", "probability": 0.96142578125}, {"start": 2592.28, "end": 2592.38, "word": " من", "probability": 0.984375}, {"start": 2592.38, "end": 2592.44, "word": " ال", "probability": 0.52490234375}, {"start": 2592.44, "end": 2592.78, "word": " equilibrium", "probability": 0.71533203125}, {"start": 2592.78, "end": 2593.48, "word": " مشكلة", "probability": 0.8870442708333334}], "temperature": 1.0}, {"id": 113, "seek": 260155, "start": 2594.21, "end": 2601.55, "text": "فابد احاول انا اختصر هال equilibrium هذه ل one single equilibrium بحاول اعمل هذا الكلام", "tokens": [5172, 16758, 3215, 1975, 5016, 995, 12610, 1975, 8315, 1975, 46456, 9381, 2288, 8032, 6027, 15625, 29538, 5296, 472, 2167, 15625, 4724, 5016, 995, 12610, 1975, 25957, 1211, 23758, 2423, 28820, 10943], "avg_logprob": -0.3390151515151515, "compression_ratio": 1.2647058823529411, "no_speech_prob": 0.0, "words": [{"start": 2594.21, "end": 2594.63, "word": "فابد", "probability": 0.5670979817708334}, {"start": 2594.63, "end": 2595.05, "word": " احاول", "probability": 0.80279541015625}, {"start": 2595.05, "end": 2595.27, "word": " انا", "probability": 0.6962890625}, {"start": 2595.27, "end": 2595.95, "word": " اختصر", "probability": 0.97119140625}, {"start": 2595.95, "end": 2596.11, "word": " هال", "probability": 0.5855712890625}, {"start": 2596.11, "end": 2596.57, "word": " equilibrium", "probability": 0.69873046875}, {"start": 2596.57, "end": 2597.01, "word": " هذه", "probability": 0.56201171875}, {"start": 2597.01, "end": 2597.15, "word": " ل", "probability": 0.837890625}, {"start": 2597.15, "end": 2598.81, "word": " one", "probability": 0.39404296875}, {"start": 2598.81, "end": 2599.29, "word": " single", "probability": 0.8828125}, {"start": 2599.29, "end": 2600.07, "word": " equilibrium", "probability": 0.896484375}, {"start": 2600.07, "end": 2600.67, "word": " بحاول", "probability": 0.705047607421875}, {"start": 2600.67, "end": 2600.93, "word": " اعمل", "probability": 0.9397786458333334}, {"start": 2600.93, "end": 2601.09, "word": " هذا", "probability": 0.9423828125}, {"start": 2601.09, "end": 2601.55, "word": " الكلام", "probability": 0.9435221354166666}], "temperature": 1.0}, {"id": 114, "seek": 262686, "start": 2602.46, "end": 2626.86, "text": "طبعا يمكن حل الاكتر من اكوليبريا لكن احنا بنحاول نبسط الموضوع و مش هناكن حل اكتر من اكوليبريا بنحل بس بالتبسيط لأقل او لا اقرب لا اكوليبريا واحد فقط ان امكن ماامكنش بنقول والله اه هذه مسألة تحتاج الى انه نحل بال two equilibrium يعني يمكن اعطيكم هذا الكلام اتكلم عن ال polyprotic acids", "tokens": [9566, 3555, 3615, 995, 7251, 43020, 11331, 1211, 42963, 4117, 2655, 2288, 9154, 1975, 4117, 2407, 20292, 3555, 16572, 995, 44381, 1975, 5016, 8315, 44945, 5016, 995, 12610, 8717, 3555, 3794, 9566, 9673, 2407, 11242, 45367, 4032, 37893, 8032, 1863, 995, 19452, 11331, 1211, 1975, 4117, 2655, 2288, 9154, 1975, 4117, 12610, 1829, 3555, 16572, 995, 44945, 5016, 1211, 4724, 3794, 20666, 2655, 3555, 3794, 1829, 9566, 5296, 10721, 4587, 1211, 1975, 2407, 20193, 1975, 4587, 25513, 20193, 1975, 4117, 12610, 1829, 3555, 16572, 995, 36764, 24401, 6156, 47432, 16472, 1975, 43020, 19446, 10943, 19452, 8592, 44945, 39648, 16070, 43761, 1975, 3224, 29538, 47524, 10721, 37977, 6055, 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33911, 10632, 11331, 3794, 16758, 2423, 21677, 5296, 16095, 1975, 15730, 21984, 12602, 18513, 21542, 9381, 3660, 25724, 995, 10632, 44945, 44510, 10721, 8717, 2655, 4117, 19528, 18871, 2423, 5517, 6547], "avg_logprob": -0.16702586926262955, "compression_ratio": 1.4110429447852761, "no_speech_prob": 2.205371856689453e-06, "words": [{"start": 2857.24, "end": 2857.9, "word": "الاتنين", "probability": 0.732666015625}, {"start": 2857.9, "end": 2858.48, "word": " او", "probability": 0.80859375}, {"start": 2858.48, "end": 2859.0, "word": " weak", "probability": 0.9375}, {"start": 2859.0, "end": 2859.36, "word": " acid", "probability": 0.953125}, {"start": 2859.36, "end": 2859.62, "word": " weak", "probability": 0.7890625}, {"start": 2859.62, "end": 2859.94, "word": " base", "probability": 0.90380859375}, {"start": 2859.94, "end": 2860.12, "word": " مع", "probability": 0.88525390625}, {"start": 2860.12, "end": 2860.38, "word": " weak", "probability": 0.9921875}, {"start": 2860.38, "end": 2860.68, "word": " base", "probability": 0.91162109375}, {"start": 2860.68, "end": 2860.92, "word": " weak", "probability": 0.98876953125}, {"start": 2860.92, "end": 2861.34, "word": " acid", "probability": 0.97412109375}, {"start": 2861.34, "end": 2861.96, "word": " هدول", "probability": 0.9012044270833334}, {"start": 2861.96, "end": 2862.3, "word": " النوعين", "probability": 0.9283854166666666}, {"start": 2862.3, "end": 2862.84, "word": " اخدنا", "probability": 0.8216552734375}, {"start": 2862.84, "end": 2863.46, "word": " كيفية", "probability": 0.98193359375}, {"start": 2863.46, "end": 2863.82, "word": " حساب", "probability": 0.978515625}, {"start": 2863.82, "end": 2863.92, "word": " ال", "probability": 0.982421875}, {"start": 2863.92, "end": 2864.4, "word": " pH", "probability": 0.35498046875}, {"start": 2864.4, "end": 2865.16, "word": " لهم", "probability": 0.6685791015625}, {"start": 2865.16, "end": 2865.44, "word": " اذا", "probability": 0.81591796875}, {"start": 2865.44, "end": 2865.66, "word": " الله", "probability": 0.89111328125}, {"start": 2865.66, "end": 2866.0, "word": " راد", "probability": 0.67529296875}, {"start": 2866.0, "end": 2866.72, "word": " الحصة", "probability": 0.9874674479166666}, {"start": 2866.72, "end": 2867.02, "word": " الجاية", "probability": 0.8907877604166666}, {"start": 2867.02, "end": 2867.28, "word": " بنبدأ", "probability": 0.8894856770833334}, {"start": 2867.28, "end": 2867.66, "word": " نتكلم", "probability": 0.9892578125}, {"start": 2867.66, "end": 2867.86, "word": " عن", "probability": 0.99169921875}, {"start": 2867.86, "end": 2867.98, "word": " ال", "probability": 0.8447265625}, {"start": 2867.98, "end": 2868.26, "word": " butter", "probability": 0.5400390625}, {"start": 2868.26, "end": 2868.96, "word": " solutions", "probability": 0.91943359375}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2869.75425, "duration_after_vad": 2759.6243749999876}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/iyej-ZK7KYU_raw.srt b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/iyej-ZK7KYU_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..eaf26a0db8cfd2aeb891b260782d82d9c97c0b79
--- /dev/null
+++ b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/iyej-ZK7KYU_raw.srt
@@ -0,0 +1,2456 @@
+1
+00:00:20,970 --> 00:00:26,130
+بسم الله الرحمن الرحيم اليوم يا شباب بنكمل في ال
+
+2
+00:00:26,130 --> 00:00:29,270
+acid base equilibria في الحصة الماضية كنا اتكلمنا
+
+3
+00:00:29,270 --> 00:00:34,340
+عنحسابات ال pH الخاصة بال strong acids و ال strong
+
+4
+00:00:34,340 --> 00:00:38,800
+bases وايضا ال salts لل strong acids و ال strong
+
+5
+00:00:38,800 --> 00:00:43,640
+bases شوفنا ان ال strong acid هو ال acid اللى
+
+6
+00:00:43,640 --> 00:00:50,180
+بيتفكك بنسبة 100% وايضا ال strong base هو ال base
+
+7
+00:00:50,180 --> 00:00:55,240
+اللى بتفكك بنسبة 100%اليوم ان شاء الله بنتكلم عن
+
+8
+00:00:55,240 --> 00:01:00,560
+حسابات ال pH لل weak acids و ال weak bases و أيضا
+
+9
+00:01:00,560 --> 00:01:04,580
+ال salts المشتقة من ال weak acids و ال weak bases
+
+10
+00:01:04,580 --> 00:01:09,440
+بنقول إذا كان تعريفنا لل strong acid و ال strong
+
+11
+00:01:09,440 --> 00:01:14,040
+base أنه هي المواد اللي بتتفكك بنسبة 100% فتعريفنا
+
+12
+00:01:14,040 --> 00:01:18,860
+لل weak acids و ال weak basesبإنها هي المواد اللي
+
+13
+00:01:18,860 --> 00:01:24,700
+لا تتفكك بنسبة 100% طبعا مثلا ال strong acids
+
+14
+00:01:24,700 --> 00:01:29,450
+عرفناها بالاسم فما عداها يعتبر weakالـ Strong
+
+15
+00:01:29,450 --> 00:01:33,870
+Acids عرفناها بالاسم فما عداها يعتبر weak أيضا ما
+
+16
+00:01:33,870 --> 00:01:38,730
+يميز ال weak acids انه بنقدر نكتبله equilibrium
+
+17
+00:01:38,730 --> 00:01:43,070
+constant لأنه بتفكك جزئيا لا يتفكك بالنسبة 100%
+
+18
+00:01:43,070 --> 00:01:45,970
+فدائما ال weak acid موجود معاه equilibrium
+
+19
+00:01:45,970 --> 00:01:49,930
+constant كل ما كبر هال equilibrium constant كل ما
+
+20
+00:01:49,930 --> 00:01:53,890
+ال acid كان أقوى، طبعا هو weak لكنه أقوى من غيره
+
+21
+00:01:55,190 --> 00:02:00,410
+زادت قيمة ال equilibrium constant كل ما اعتبرنا ان
+
+22
+00:02:00,410 --> 00:02:03,590
+ال acid أقوى و كل ما قلت قيمة ال equilibrium
+
+23
+00:02:03,590 --> 00:02:12,250
+constant أيضا بنقول انه كل ما قلت قيمة ال
+
+24
+00:02:12,250 --> 00:02:16,660
+equilibrium constant ال acid بيكون أبعثنفس الكلاب
+
+25
+00:02:16,660 --> 00:02:20,600
+بالنسبة لل bases كل base مرتبط معاه equilibrium
+
+26
+00:02:20,600 --> 00:02:24,940
+constant لأنه weak base فلمّا نزيد قيمة ال
+
+27
+00:02:24,940 --> 00:02:29,040
+equilibrium constant معناته ال weak base هذا أقوى
+
+28
+00:02:29,040 --> 00:02:31,820
+من غيره بينما لما نتقل قيمة ال equilibrium
+
+29
+00:02:31,820 --> 00:02:38,060
+constant فمعناته ال base أضعف على أي حال بنقدر
+
+30
+00:02:38,060 --> 00:02:40,740
+نقول احنا انه كشي عام
+
+31
+00:02:43,500 --> 00:02:47,700
+الـ strong acids تتفكك في الميّه وتعطيني H+. لكن
+
+32
+00:02:47,700 --> 00:02:52,360
+مش لازم ننسى ان الميّه ايضا بتتفكك وتعطي H+. فهل
+
+33
+00:02:52,360 --> 00:02:54,220
+يجب علينا انه
+
+34
+00:02:57,050 --> 00:03:00,650
+ناخد بعين الاعتبار الـ H بلف الجام من الميه ولا
+
+35
+00:03:00,650 --> 00:03:05,090
+لأ؟ في الحقيقة هذا سؤال مهم و قد يكون فيه أهمية
+
+36
+00:03:05,090 --> 00:03:10,330
+كبيرة جدا زي ما شفنا في الحصة الماضية بالذات لو
+
+37
+00:03:10,330 --> 00:03:16,030
+كان تركيز الاسد المضاعف تركيزقليل نسبيا، تركيز
+
+38
+00:03:16,030 --> 00:03:20,070
+قليل، عندها تركيز الـH بلس اللي جاية من الميه قد
+
+39
+00:03:20,070 --> 00:03:24,210
+يكون قيمته مهمة وفي بعض الأحيان ممكن تكون أهم من
+
+40
+00:03:24,210 --> 00:03:27,650
+كمية الـH بلس اللي جاية من الـAcid لكن لو كان
+
+41
+00:03:27,650 --> 00:03:32,850
+تركيز الـAcid أو الـBase معقول فبنلاحظ طبيعي أن
+
+42
+00:03:32,850 --> 00:03:36,110
+كمية الـH بلس أو الـHydroxide اللي جاية من الميه
+
+43
+00:03:36,110 --> 00:03:43,400
+تكون قليلة للغايةفمثلا ناخد بعض الأمثلة ومن خلال
+
+44
+00:03:43,400 --> 00:03:49,700
+هذه الأمثلة نعلق على منهجية التفكير في هل يعني ال
+
+45
+00:03:49,700 --> 00:03:53,340
+H plus اللي جاي من الميه هذا مهم ولا مش مهم وكيف
+
+46
+00:03:53,340 --> 00:03:57,260
+نحسب ال H plus للمحلول فنتطلع على هذا المثال اللي
+
+47
+00:03:57,260 --> 00:04:03,810
+جدامي بقول calculate the pH and pOHFor a 0.1 molar
+
+48
+00:04:03,810 --> 00:04:08,310
+acetic acid solution، طبعاً ماعطيني الـKa لأن
+
+49
+00:04:08,310 --> 00:04:11,950
+الـacetic acid يعتبر weak acid، فالـKa له 1
+
+50
+00:04:11,950 --> 00:04:15,030
+.75×10−5
+
+51
+00:04:17,070 --> 00:04:21,670
+بقول ببساطة خالص بقدر يعني اقول ان ال H plus
+
+52
+00:04:21,670 --> 00:04:26,670
+للمحلول تساوي ال H plus اللي جاية من ال acetic
+
+53
+00:04:26,670 --> 00:04:31,810
+acid زائد ال H plus اللي جاية من الميه لكن يا شباب
+
+54
+00:04:31,810 --> 00:04:35,150
+اصلا ال H plus اللي جاية من الميه في الأحوال
+
+55
+00:04:35,150 --> 00:04:39,670
+العادية لما نكون الميه مجبرة لحالها عشرة أس سالب
+
+56
+00:04:39,670 --> 00:04:44,010
+سبعة ليه؟ لأن الكيبة بليوم دي ساوي H plus في ال
+
+57
+00:04:44,010 --> 00:04:47,720
+hydroxide اذا كان فش عندى غير الميهفالأصل إن الـ H
+
+58
+00:04:47,720 --> 00:04:51,220
+بلس عشرة أقصى ثالث سبعة اللي جاي من الميّه لكن في
+
+59
+00:04:51,220 --> 00:04:55,300
+وجود Acetic Acid معناته أنا بضيف H بلس على ال
+
+60
+00:04:55,300 --> 00:04:59,660
+equilibrium للميّه إيش بيحصل للميّه؟ راح أه حسب
+
+61
+00:04:59,660 --> 00:05:04,760
+الاتشاتليت يعني تفككها راح يقل بشكل كبير جدا في
+
+62
+00:05:04,760 --> 00:05:08,600
+وجود H بلس جاية من ال Acetic Acid يبقى تفكك الميّه
+
+63
+00:05:08,600 --> 00:05:12,940
+في وجود ال Acetic Acid لا يكاد يذكر تفككها أصلا
+
+64
+00:05:12,940 --> 00:05:17,880
+الميّه ضعيفلكن أيضا في وجود الاسيتك أسد نظرا لوجود
+
+65
+00:05:17,880 --> 00:05:23,520
+common ion مهم فتفكك الميه بيقل بشكل كبير فوق ضعفه
+
+66
+00:05:23,520 --> 00:05:27,280
+بيقل بشكل كبير خالص معناه الكلام هذا مبرر ليه انه
+
+67
+00:05:27,280 --> 00:05:32,540
+والله اقول تفكك الميه لا يكاد يذكر يعني وكأنه ال H
+
+68
+00:05:32,540 --> 00:05:36,040
+plus للمحلول هو عبارة عن ال H plus اللي جاي من
+
+69
+00:05:36,040 --> 00:05:38,180
+الاسيتك أسد فقط
+
+70
+00:05:40,670 --> 00:05:44,470
+كمان ملاحظة الحصة الماضية كنا بنقول والله اه عندنا
+
+71
+00:05:44,470 --> 00:05:47,470
+acid اذا ال H plus ده المحلول تساوي ال H plus ده
+
+72
+00:05:47,470 --> 00:05:50,590
+ال acid زائد الميه لما نكون هذا strong كنت على طول
+
+73
+00:05:50,590 --> 00:05:56,170
+بعوض عن قيمة ال H plus بتركيز ال acid صح؟ وبعدين
+
+74
+00:05:56,170 --> 00:06:00,580
+بقارن بقول طب جدش ال hydroxide؟معايا انتوا؟ مباشرة
+
+75
+00:06:00,580 --> 00:06:04,140
+لكن هالجيت مش راح أقدر أعمل هذا الكلام ليه؟ لأن ال
+
+76
+00:06:04,140 --> 00:06:08,080
+H plus اللي جاية من الحمض الضعيف مش هي تركيز الحمض
+
+77
+00:06:08,080 --> 00:06:12,700
+الضعيف يجب حسابها في البداية يجب حسابها بعدين ممكن
+
+78
+00:06:12,700 --> 00:06:17,420
+نقارنها بال H plus اللي جاية من الميه اللي هي قيمة
+
+79
+00:06:17,420 --> 00:06:23,790
+ال hydroxide فنشوف كيف بنفكر بحل المسألةبقول احنا
+
+80
+00:06:23,790 --> 00:06:26,790
+اتفاجنى على ان ال H بلس للمحلول بتساوي ال H بلس
+
+81
+00:06:26,790 --> 00:06:30,670
+لجرم ال Acetic Acid على فرض ان الميه اصلا تفككها
+
+82
+00:06:30,670 --> 00:06:34,790
+ضعيف جدا وفي وجود ال common ion تفككها يكاد يكون
+
+83
+00:06:34,790 --> 00:06:39,610
+شبه معدوم كويس فال Acetic Acid بيعطينا H بلس و
+
+84
+00:06:39,610 --> 00:06:44,270
+Acetate يبقى ال H OAC او ال Acetic Acid كان واحد
+
+85
+00:06:44,270 --> 00:06:49,830
+من عشرة قبل ال equilibrium 000.1-XXX يبقى الان
+
+86
+00:06:49,830 --> 00:06:53,410
+مقدر اقول ان ال equilibrium constant بدي يساوي ال
+
+87
+00:06:53,410 --> 00:06:58,210
+acetate في ال H بلس على ال point على ال acetic
+
+88
+00:06:58,210 --> 00:07:02,730
+acid طبعا ال H بلس و ال acetate XX يعني X تربيع ال
+
+89
+00:07:02,730 --> 00:07:07,790
+0.1-X بفترض ان ال 0.1 كالعادة أكبر كتير من X عشان
+
+90
+00:07:07,790 --> 00:07:12,170
+ابسط حل المسألة ال X بتطلع 1 و 3 في 10 أقل سالم 3
+
+91
+00:07:13,180 --> 00:07:17,120
+هل بالفعل ال X كمية مهملة؟ نعم بنجيب ال relative
+
+92
+00:07:17,120 --> 00:07:19,800
+error اللي بيطلع عندى واحد و تلاتة من عشرة في
+
+93
+00:07:19,800 --> 00:07:22,200
+المية بنعرف نجيب ال relative error إذا ال
+
+94
+00:07:22,200 --> 00:07:26,320
+assumption valid و ال H plus للمحلول اللي طلع عندى
+
+95
+00:07:26,320 --> 00:07:32,920
+واحد و تلاتة في عشر أقل سالب تلاتة، كويس؟ الآن لأن
+
+96
+00:07:32,920 --> 00:07:35,700
+ال X هي ال H plus طلعت عندى واحد و تلاتة في عشر
+
+97
+00:07:35,700 --> 00:07:39,020
+أقل سالب تلاتة، الآن بقدر أقول كلام بسيط كتير،
+
+98
+00:07:39,020 --> 00:07:41,240
+بقول طب قداش قيمة ال hydroxide في المحلول؟
+
+99
+00:07:49,780 --> 00:07:56,590
+الهيدروكسايد بيطلع عندنا7 و 6 ف 10 أقصالب 12 طب
+
+100
+00:07:56,590 --> 00:07:59,910
+إيش هو ال hydroxide قال هو ال H بلس اللي جاه من
+
+101
+00:07:59,910 --> 00:08:03,330
+الميه لإنه مصدر ال hydroxide اللي وحيد هو الميه و
+
+102
+00:08:03,330 --> 00:08:08,410
+الميه لما تتفكك بتعطيني بالظبط H بلس و جده بالظبط
+
+103
+00:08:08,410 --> 00:08:12,170
+hydroxide فإذا كان ال hydroxide 7 و 6 ف 10 أقصالب
+
+104
+00:08:12,170 --> 00:08:15,670
+12 إذا ال H بلس اللي جاه من الميه 7 و 6 ف 10
+
+105
+00:08:15,670 --> 00:08:20,960
+أقصالب 12كمية مهملة بالنسبة للواحد و تلاتة في عشر
+
+106
+00:08:20,960 --> 00:08:25,660
+أقل ثالث تلاتة كمية مهملة علشان هيك ممكن كمان انا
+
+107
+00:08:25,660 --> 00:08:31,760
+اجيب والله لو حبيت نسبة الخطأ في ان لغية ال H plus
+
+108
+00:08:31,760 --> 00:08:36,240
+اللي جاي من الميه يعني هذا هو ال H plus اللي جاي
+
+109
+00:08:36,240 --> 00:08:41,080
+من الميه لو جسمته على قيمة ال H plus للمحلولفي 100
+
+110
+00:08:41,080 --> 00:08:44,340
+من 100 بيعطيني نسبة الخطأ بيعطيني نسبة خطأ يعني
+
+111
+00:08:44,340 --> 00:08:48,700
+متدنية للغاية وكأنه مافيش عندى اي نسبة خطأ لإلغاء
+
+112
+00:08:48,700 --> 00:08:54,580
+ال H plus اللى جاى من الميه طيب لو حبينا نشتغل عند
+
+113
+00:08:54,580 --> 00:09:00,540
+تركيز اقل من الacetic acid مثلا نتطلع على المثال
+
+114
+00:09:00,540 --> 00:09:03,800
+اللى بيقول يحسب ال pH و POH لواحد millimolar
+
+115
+00:09:03,800 --> 00:09:10,090
+acetic acid بقول بنفس الطريقة بقول هو acidأصلا ال
+
+116
+00:09:10,090 --> 00:09:13,370
+H++ للمحلول بيساوي ال H++ للacid زاد ال H++ اللي
+
+117
+00:09:13,370 --> 00:09:16,730
+جاية من الميه لكن ال H++ اللي جاية من الميه لازم
+
+118
+00:09:16,730 --> 00:09:21,670
+تكون زاد محفوظة هنا تعتبر أصلا قليلة جدا فمبالنا
+
+119
+00:09:21,670 --> 00:09:25,030
+أنه في وجود acetic acid التفاكر في الميه كمان هيقل
+
+120
+00:09:25,030 --> 00:09:29,270
+يبقى هتصير قليلة جدا جدا جدا إذا يمكن إهمالها
+
+121
+00:09:29,270 --> 00:09:33,330
+وبالتالي ال H++ اللي في المحلول هي عبارة عن ال H++
+
+122
+00:09:33,330 --> 00:09:36,740
+اللي جاية من الacetic acidطيب الـ acetic acid
+
+123
+00:09:36,740 --> 00:09:40,980
+بتفتت بيعطي H plus و Acetate عشرة أقل سالب تلاتة
+
+124
+00:09:40,980 --> 00:09:44,360
+صفر صفر عشرة أقل سالب تلاتة minus X X X معنى
+
+125
+00:09:44,360 --> 00:09:48,680
+الكلام ال equilibrium constant بده يساوي X تربيه
+
+126
+00:09:48,680 --> 00:09:52,820
+على واحد فعشرة أقل سالب تلاتة minus X وبنفترض عشان
+
+127
+00:09:52,820 --> 00:09:56,580
+نبسط المسألة الواحد فعشرة أقل سالب تلاتة أكبر كتير
+
+128
+00:09:56,580 --> 00:10:00,790
+من ال Xال X بتطلع عندنا واحد واتنين وتلاتين فعشرة
+
+129
+00:10:00,790 --> 00:10:05,410
+أقصى سالب أربعة هل بالفعل يمكن إلغاء ال X جنب
+
+130
+00:10:05,410 --> 00:10:09,250
+العشرة أقصى سالب تلاتة نحسب ال relative إذا بطلع
+
+131
+00:10:09,250 --> 00:10:14,050
+تلات عاشر فالمية إذا نعم لا يمكن إلغاء ال X ال
+
+132
+00:10:14,050 --> 00:10:16,810
+assumption invalid واجب استخدام ال quadratic
+
+133
+00:10:16,810 --> 00:10:24,720
+equation علشان نعرفقيمة ال X أو ال hydrogen ion
+
+134
+00:10:24,720 --> 00:10:29,420
+concentration بشكل جيد هل معنى الكلام هذا ان ال H
+
+135
+00:10:29,420 --> 00:10:34,020
+plus اللي جاية من الميه قليلة ولا مش قليلة؟ بنقول
+
+136
+00:10:34,020 --> 00:10:36,880
+هذه مافيش علاقة بال H plus اللي جاية من الميه لسه
+
+137
+00:10:36,880 --> 00:10:41,340
+بعد ما استخدم ال quadratic equation لحسابالـ H
+
+138
+00:10:41,340 --> 00:10:45,160
+Plus الحقيقية بجيب الـ Hydroxide اللي هو يساوي الـ
+
+139
+00:10:45,160 --> 00:10:48,020
+H Plus اللي جاي من الميه و بعدين بقارن ما بين
+
+140
+00:10:48,020 --> 00:10:51,800
+الاتنين طبعا هيطلع برضه قليل لا يكد يذكر لأنه لا
+
+141
+00:10:51,800 --> 00:10:57,220
+يوقل يا شباب ان يكون عندى محلول Acetic Acid تركيز
+
+142
+00:10:57,220 --> 00:11:01,550
+معقول واحد ملي مولار يعتبر كبير نسبياو يكون فيه
+
+143
+00:11:01,550 --> 00:11:04,950
+تركيز الهيدروكسايد عالي له قيمة كبيرة، لا يمكن،
+
+144
+00:11:04,950 --> 00:11:09,950
+ليه؟ لأن هذا محلول ايه؟ acid، acid معناته يعني
+
+145
+00:11:09,950 --> 00:11:12,950
+حامض، لا يمكن الهيدروكسايد يكون قيمته كبيرة و الا
+
+146
+00:11:12,950 --> 00:11:18,250
+كان محلول ايه؟ قاعد، و هذا كلام طبعا مش صحيحطيب
+
+147
+00:11:18,250 --> 00:11:21,810
+هذا بالنسبة لل acids ايش مكان اسم ال acid لو جالنا
+
+148
+00:11:21,810 --> 00:11:26,090
+nitrous acid لو جالنا hypochloric acid لو جالنا
+
+149
+00:11:26,090 --> 00:11:30,010
+chlorous acid لو جالنا hydrocyanic acid لو جالنا
+
+150
+00:11:30,010 --> 00:11:33,890
+benzoyic acid كله نفس الكلام كله نفس الكلام احنا
+
+151
+00:11:33,890 --> 00:11:37,530
+بضعيفة نفس الصيغة نفس الشيء يعني احنا خدنا مثال
+
+152
+00:11:37,530 --> 00:11:40,530
+جلنا فيه acetic acid ممكن انت تسمي ال acid اي اسم
+
+153
+00:11:40,530 --> 00:11:44,760
+تاني اللي هيخلف فقط هو ال ke تبعهو ممكن ال acid
+
+154
+00:11:44,760 --> 00:11:49,320
+نسميه عشان ما نتغلبش HA جالك منزل weak acid اكتبوا
+
+155
+00:11:49,320 --> 00:11:54,400
+HA مادامه monoprotic مادامه monoprotic يعني فيه بس
+
+156
+00:11:54,400 --> 00:11:59,440
+one proton جالك hydrocyanic acid اكتبوا HA ماشي
+
+157
+00:11:59,440 --> 00:12:03,940
+كله نفس الكلام فاحنا أخدنا مثال ال acetic acid ده
+
+158
+00:12:03,940 --> 00:12:08,580
+كده الكلام المنطبق على كل ال monoprotic weak acids
+
+159
+00:12:08,580 --> 00:12:13,830
+الآن نطلع على ال basesوبما أنه بنتكلم عن شيعة
+
+160
+00:12:13,830 --> 00:12:18,270
+فبنقول ال basis اللي احنا هنتعامل معها تقريبا يعني
+
+161
+00:12:18,270 --> 00:12:22,290
+معظمها مشتاق من ال ammonia يعني هذه ammonia in
+
+162
+00:12:22,290 --> 00:12:27,810
+each تلاتةبدل ال H ممكن تكون R واحد، بدل ال H
+
+163
+00:12:27,810 --> 00:12:33,810
+تانية R اتنين، صارت N H R واحد R اتنين، بدل ال H
+
+164
+00:12:33,810 --> 00:12:37,410
+التالتة ممكن تكون R تلاتة، إيش ال R؟ ممكن تكون
+
+165
+00:12:37,410 --> 00:12:41,570
+مثل، ممكن تكون إثل، ممكن تكون بنزين، حلقة بنزين
+
+166
+00:12:41,570 --> 00:12:48,010
+فنل، يعني لو كانت حلقة بنزين ممكن تكون أنيلينلو
+
+167
+00:12:48,010 --> 00:12:54,810
+كان مثلا اثل يكون اثلامين مثل مثلامين لو كان
+
+168
+00:12:54,810 --> 00:12:59,590
+حلقتين بنزين بايفلامين كويسة يعني ممكن الامين يكون
+
+169
+00:12:59,590 --> 00:13:04,610
+secondary primary secondary tertiary ممكن اي حاجة
+
+170
+00:13:04,610 --> 00:13:08,690
+كله بيتعامل معاملة الامونيا مافيش قدامه خيار الا
+
+171
+00:13:08,690 --> 00:13:12,770
+انه ياخد
+
+172
+00:13:12,770 --> 00:13:18,850
+بروتون من الميه لأنه بيزفبيصير هو موجب و الماء
+
+173
+00:13:18,850 --> 00:13:24,490
+يتحول لهيدروكسايد زي مثلا ال ammonia هنشوف هذه ال
+
+174
+00:13:24,490 --> 00:13:30,990
+ammonia هذه الموجب هذه ال H ممكن تكون اي حاجةممكن
+
+175
+00:13:30,990 --> 00:13:36,990
+تكون R1 R2 R3 مش مشكلة او R1 بس مش مشكلة لكن دائما
+
+176
+00:13:36,990 --> 00:13:42,430
+ايش اللي بيحصل بتاخد ال proton و بتصير H موجبة NHA
+
+177
+00:13:42,430 --> 00:13:45,870
+موجبة بغض النظر عن ايش اللي معاها و بعدين ال
+
+178
+00:13:45,870 --> 00:13:49,870
+hydroxide كل ال bases اللي هنتعامل معاها زي ايه
+
+179
+00:13:49,870 --> 00:13:54,330
+ماشي يا جماعة يبدأ كل ال bases اللي هنتعامل معاها
+
+180
+00:13:54,330 --> 00:14:00,990
+بنفس الطريقة طيب الآن يا شباب نفس المنهجيةبنقول
+
+181
+00:14:00,990 --> 00:14:08,200
+والله في عنده baseإذا الـ H بلس اللي في المحلول
+
+182
+00:14:08,200 --> 00:14:11,560
+الهيدروكسيد اللي في المحلول عفوا هو عبارة عن
+
+183
+00:14:11,560 --> 00:14:14,540
+الهيدروكسيد اللي جاي من ال base اللي هو الأمونيا
+
+184
+00:14:14,540 --> 00:14:18,360
+في هذه الحالة زائد الهيدروكسيد اللي جاية من الميه
+
+185
+00:14:18,360 --> 00:14:22,680
+لكن هذا محلول ال base محلول الأمونيا هل يُعقل أن
+
+186
+00:14:22,680 --> 00:14:26,240
+يكون فيه H بلس كتير لأن الهيدروكسيد اللي جاية من
+
+187
+00:14:26,240 --> 00:14:29,400
+الميه بيساوي ال H بلس هل يُعقل أن يكون فيه H بلس
+
+188
+00:14:29,400 --> 00:14:32,700
+كتير في محلول الأمونيا من وين بده ييجي لا يُعقل
+
+189
+00:14:32,700 --> 00:14:36,650
+وإلا بيصير acidicفطبعا كمية الـ H بلس في المحلول
+
+190
+00:14:36,650 --> 00:14:40,750
+تكاد تكون معدومة قليلة جدا جدا إذا الـ hydroxide
+
+191
+00:14:40,750 --> 00:14:44,950
+اللي جاي من الميه اللي هو بيساوي الـ H بلس تركيزه
+
+192
+00:14:44,950 --> 00:14:49,670
+لا يكاد يدكر قليل جدا وبالتالي يمكن إلغاءهيمكن
+
+193
+00:14:49,670 --> 00:14:52,950
+إلغاءه وهذه حاجة منهجية في التفكير كمان منهجية
+
+194
+00:14:52,950 --> 00:14:56,770
+تانية بتقول إنه أنا عندي الميه بتعطي H بلس و
+
+195
+00:14:56,770 --> 00:14:59,990
+Hydroxide وفي أحسن الأحوال لما نكون ميه مجترة
+
+196
+00:14:59,990 --> 00:15:03,670
+بتعطي 10 أو سالف سبعة Hydroxide طب فما بالك إنه
+
+197
+00:15:03,670 --> 00:15:07,410
+نحط عليها أمونيا والأمونيا بتطلع Hydroxide يمكنليش
+
+198
+00:15:07,410 --> 00:15:11,550
+تحصل ال equilibrium؟بدي يرجع لورا خالص معنا كلام
+
+199
+00:15:11,550 --> 00:15:15,330
+كمية ال hydroxide اللى جاى من الميّه، أيضا لا تكاد
+
+200
+00:15:15,330 --> 00:15:19,450
+تذكر يبقى ممكن بسهولة إلغاء الميّه، إذا في أكتر من
+
+201
+00:15:19,450 --> 00:15:23,030
+منهجية للتفكير، كلها تقود إلى إن والله كمية ال
+
+202
+00:15:23,030 --> 00:15:28,380
+hydroxide اللى جاى من الميّه كمية لا تكاد تذكر،الـ
+
+203
+00:15:28,380 --> 00:15:33,360
+OH للمحلول هو عبارة عن الـ OH للأمونيا، إذا ما فى
+
+204
+00:15:33,360 --> 00:15:36,560
+عندى بس أمونيا بتتفكك، الأمونيا بتعطى أمونيام
+
+205
+00:15:36,560 --> 00:15:41,220
+وهيدروكساي طبعا مع الميه، فالأمونيا كانت point two
+
+206
+00:15:41,220 --> 00:15:45,580
+صفر صفر point two minus x x x، الآن ال equilibrium
+
+207
+00:15:45,580 --> 00:15:53,980
+constantبقول KB هان هاد ال B معناته اه اسمه base
+
+208
+00:15:53,980 --> 00:15:57,640
+dissociation constant و لما كنا بنتكلم عن ال acid
+
+209
+00:15:57,640 --> 00:16:02,480
+كانت KA يعني acid dissociation constant على اي حال
+
+210
+00:16:02,480 --> 00:16:06,380
+عشان نحل المسألة بنفترض ان ال point 2 اكبر كتير من
+
+211
+00:16:06,380 --> 00:16:10,440
+ال X اذا ال X بتطلع انها واحد وتسعة في عشر اقل
+
+212
+00:16:10,440 --> 00:16:14,760
+ثالث تلاتة هل بالفعل ال واحد وتسعة في عشر اقل ثالث
+
+213
+00:16:14,760 --> 00:16:19,450
+تلاتة اكبر كتير من ال Xعفوًا ال point two أكبر
+
+214
+00:16:19,450 --> 00:16:21,830
+كتير من ال X يعني أكبر كتير من ال واحد وتسعة فعشرة
+
+215
+00:16:21,830 --> 00:16:24,550
+أو سالب تلاتة بنقول والله بنجيب relative error
+
+216
+00:16:24,550 --> 00:16:30,170
+بيطلع أن حوالي واحد في المية إذا الفرضية صحيحة لكن
+
+217
+00:16:30,170 --> 00:16:34,130
+هذا بدلنيش على جداش كمية ال H plus أو ال hydroxide
+
+218
+00:16:34,130 --> 00:16:37,550
+اللي جاي من الميه هذا بس بيقول إنه أه إذا كان
+
+219
+00:16:37,550 --> 00:16:41,770
+أخدنا في الاعتبار الأمونيا إذا والله أه شغل صح هيك
+
+220
+00:16:41,770 --> 00:16:45,490
+وكمية ال hydroxide اللي جاي من الأمونيا هو عبارة
+
+221
+00:16:45,490 --> 00:16:49,300
+عن واحد وتسعة فعشرة أو سالب تلاتةممكن منه يا شباب
+
+222
+00:16:49,300 --> 00:16:53,400
+احسب ال H بلس ده المحلول بعطيني خمسة و تلاتة فعشرة
+
+223
+00:16:53,400 --> 00:16:57,780
+أساليب أتبعاش هذه القيمة اللي هي ال H بلس تساوي ال
+
+224
+00:16:57,780 --> 00:17:02,040
+hydroxide اللي جاي من الميه ليه؟ لأن مصدر ال H بلس
+
+225
+00:17:02,040 --> 00:17:05,980
+الوحيد هو الميه الأمونيا ما بتعطيني ميه ما بتعطيني
+
+226
+00:17:05,980 --> 00:17:11,700
+H بلس الميه بس هي اللي بتعطي H بلس اذا المصدر
+
+227
+00:17:11,700 --> 00:17:17,550
+الوحيد ده ال H بلسهو الميه طبعا الميه لما تتفكك
+
+228
+00:17:17,550 --> 00:17:21,610
+بتعطي H بلس وبتعطي جده بالظبط Hydroxide إذا كمية
+
+229
+00:17:21,610 --> 00:17:24,910
+ال Hydroxide اللي جاية من الميه أيضا تساوي خمسة و
+
+230
+00:17:24,910 --> 00:17:28,570
+تلاتة فعشرة أسالب اتناشر لو بدنا نقارنها بالواحد
+
+231
+00:17:28,570 --> 00:17:32,430
+وتسعة فعشرة أسالب تلاتة لاتكاد تذكر يعني ألف مليون
+
+232
+00:17:32,430 --> 00:17:38,710
+مرة تقريبا أكبر منهاإذا كان ممكن بسهولة أو يعني
+
+233
+00:17:38,710 --> 00:17:42,610
+مبرر إلينا بسهولة إنه نلغي كمية ال hydroxide اللي
+
+234
+00:17:42,610 --> 00:17:46,510
+جاية من الميّه، لو حاببنا نحسب نسبة الخطأ إنه
+
+235
+00:17:46,510 --> 00:17:48,910
+والله لغينا ال hydroxide اللي جاية من الميّه،
+
+236
+00:17:48,910 --> 00:17:51,750
+بنجسم هذه اللي هو ال hydroxide اللي جاية من الميّه
+
+237
+00:17:51,750 --> 00:17:55,250
+على ال hydroxide اللي في المحلول في 100 من 100،
+
+238
+00:17:55,250 --> 00:18:00,470
+بيعطيني كمية قليلة للغايةكمية قايلة للغاية طبعا
+
+239
+00:18:00,470 --> 00:18:04,670
+انا في عندى من ال hydroxide بحسب ال POH وأسهل
+
+240
+00:18:04,670 --> 00:18:11,790
+طريقة اتراحها من 14 بتعطيني ال pH ماشي هذا الكلام
+
+241
+00:18:11,790 --> 00:18:18,030
+يا شبابإذا لو كان عندي weak base او weak acid
+
+242
+00:18:18,030 --> 00:18:23,810
+الشغل يعني بنقدر نقول انه بسيط كتير لكن ممنوع منعا
+
+243
+00:18:23,810 --> 00:18:28,070
+بثا انك والله تحطيلي قيمة ال H plus هي عبارة عن
+
+244
+00:18:28,070 --> 00:18:31,490
+تركيز ال weak acid او ال hydroxide هي عبارة عن
+
+245
+00:18:31,490 --> 00:18:35,870
+تركيز ال weak base لأ مظبطش هذا بس لل strong acids
+
+246
+00:18:35,870 --> 00:18:38,830
+و strong bases هدول ال weak acids و ال weak bases
+
+247
+00:18:38,830 --> 00:18:43,710
+لازم نحسبجدّاش قيمة الـ H Plus وجدّاش قيمة الـ
+
+248
+00:18:43,710 --> 00:18:49,450
+Hydroxide فسبن الان ننتقل يا شباب الى ال salts of
+
+249
+00:18:49,450 --> 00:18:55,410
+weak acids و ال salts of weak bases و بقول في هذه
+
+250
+00:18:55,410 --> 00:18:59,630
+الحالة انا في عندى نوعين من انواع ال salts في عندى
+
+251
+00:18:59,630 --> 00:19:04,830
+نوع بيكون احد مكوناته جاي من strong acid او strong
+
+252
+00:19:04,830 --> 00:19:10,580
+base هو ال salt شقين شقينشق من الحمض وشق من
+
+253
+00:19:10,580 --> 00:19:14,300
+القاعدة هي اللي بيعطيك ال salt فبقول أحد هدول
+
+254
+00:19:14,300 --> 00:19:19,040
+الشقين هذا أول نوع بدي يكون جاي من حاجة strong يا
+
+255
+00:19:19,040 --> 00:19:25,000
+strong acid يا strong base زي ايش مثلا مثلا
+
+256
+00:19:25,000 --> 00:19:32,100
+في عندي لو أخدنا sodium
+
+257
+00:19:32,100 --> 00:19:38,220
+acetate هذا جاي from acidic
+
+258
+00:19:40,020 --> 00:19:52,740
+acid وهذا from ايش وهذا from strong base كل ال ..
+
+259
+00:19:52,740 --> 00:19:57,780
+هذا كنوع يعني من أنواع الأملح جاي طبعا من weak
+
+260
+00:19:57,780 --> 00:20:03,280
+acid زي ما احنا شايفين جزء ومن strong base جزء اخر
+
+261
+00:20:04,550 --> 00:20:10,550
+طيب انا بسأل سؤال هو هذه .. لما نقول weak acid هو
+
+262
+00:20:10,550 --> 00:20:17,410
+إيش اللي خلاه weak؟ ليش هو weak؟ المرافق
+
+263
+00:20:17,410 --> 00:20:20,710
+.. المرافق ضعيف المرافق تبقى جوي .. المرافق تبقى
+
+264
+00:20:20,710 --> 00:20:21,350
+جوي .. المرافق تبقى جوي .. المرافق تبقى جوي ..
+
+265
+00:20:21,350 --> 00:20:21,730
+المرافق تبقى جوي .. المرافق تبقى جوي .. المرافق
+
+266
+00:20:21,730 --> 00:20:21,930
+تبقى جوي .. المرافق تبقى جوي .. المرافق تبقى جوي
+
+267
+00:20:21,930 --> 00:20:23,350
+.. المرافق تبقى جوي .. المرافق تبقى جوي .. المرافق
+
+268
+00:20:23,350 --> 00:20:26,290
+تبقى جوي .. المرافق تبقى جوي .. المرافق تبقى جوي
+
+269
+00:20:26,290 --> 00:20:29,520
+.. المرافق تبقى جوي .. المرافق تبقى جويالاسيتات
+
+270
+00:20:29,520 --> 00:20:34,780
+الاستك أسد هو الحمض ضعيف ليش الاستك أسد ضعيف ده
+
+271
+00:20:34,780 --> 00:20:39,020
+لأنه المرافق ال conjugate base تبعته إيش مالها إيش
+
+272
+00:20:39,020 --> 00:20:43,860
+معنى إنها قوية أحسنته تتفاعل مع الماء هيها هي
+
+273
+00:20:43,860 --> 00:20:50,960
+الاسيتات زائد H2O HOAC زائد Hydroxide هل هذا تفاعل
+
+274
+00:20:50,960 --> 00:20:54,560
+بيتم ولا لأ ليش بيتم
+
+275
+00:20:58,820 --> 00:21:02,260
+ماشي احنا بدنا نشوف ادعم هذا strong conjugate base
+
+276
+00:21:02,260 --> 00:21:06,300
+ليش هو strong؟ جال انه بتفاعل مع الماء طب مش
+
+277
+00:21:06,300 --> 00:21:09,960
+بعرفنا انه هيتفاعل بيتم بنتطلع على النواتج اسكان
+
+278
+00:21:09,960 --> 00:21:14,580
+النواتج راسب او غاز او weak electrolyte اذا بيتم
+
+279
+00:21:14,580 --> 00:21:17,640
+فهي طبعا weak electrolyte استكاسد weak ولا مش weak
+
+280
+00:21:17,640 --> 00:21:21,760
+الاستكاسد بما انه في عنده في النواتج استكاسد اذا
+
+281
+00:21:21,760 --> 00:21:27,210
+نعم التفاعل بيتم اي اش بتفاعل مع الميهمعناته يا
+
+282
+00:21:27,210 --> 00:21:29,890
+بدى يعطينا H بلس يا بدى يعطينا Hydroxide إذا بيغير
+
+283
+00:21:29,890 --> 00:21:35,070
+ال pH إذا إله تأثير على ال pH بينما الصادم إيش
+
+284
+00:21:35,070 --> 00:21:37,490
+قلنا عنه المرة الماضية؟
+
+285
+00:21:43,930 --> 00:21:48,530
+هل هذا التفاعل بيتم؟ بقى هذا لا يتم لأنه طالع عندي
+
+286
+00:21:48,530 --> 00:21:52,730
+Sodium Hydroxide و Sodium Hydroxide لا هو غاز ولا
+
+287
+00:21:52,730 --> 00:21:56,890
+هو راسب ولا هو weak هذا strong electrolyte بتكونش
+
+288
+00:21:56,890 --> 00:22:04,860
+فما بيتكون اذا انا عندي شق بتفعلش نهائيامع الميه
+
+289
+00:22:04,860 --> 00:22:07,980
+وبالتالي هذا ماليش دعوة في ال pH ما بيغير ال pH
+
+290
+00:22:07,980 --> 00:22:12,600
+وشيق تاني اه بتفعل مع الميه وبيغير ال pH يبقى هذا
+
+291
+00:22:12,600 --> 00:22:16,340
+أول نوع من أنواع ال salts نفس الكلام لو كان في عنا
+
+292
+00:22:16,340 --> 00:22:22,720
+مثلا ammonium chloride
+
+293
+00:22:22,720 --> 00:22:30,500
+بقول هذا جاي من weak basefrom weak base لأنه
+
+294
+00:22:30,500 --> 00:22:33,980
+strong conjugate acid from weak base وهذا جاي من
+
+295
+00:22:33,980 --> 00:22:44,100
+ايه؟ from strong acid طب هذا from weak base طب ليش
+
+296
+00:22:44,100 --> 00:22:51,380
+ال ammonia weak؟ لأنه مرافقها صحيح ال ammonia weak
+
+297
+00:22:51,380 --> 00:22:54,100
+لأنه مرافقها قوي ايش مرافقها؟
+
+298
+00:22:56,630 --> 00:23:06,830
+الأمونيام مع الميه بيعطينا NH3 زائد H3O بما أن هذا
+
+299
+00:23:06,830 --> 00:23:10,810
+weak إلكتروبات إذا كانت تتفاعل بيتم كويس لكن ال
+
+300
+00:23:10,810 --> 00:23:14,670
+chloride جاي من strong acid طب ليش هو strong acid؟
+
+301
+00:23:14,670 --> 00:23:18,490
+لأن مراقبه ضعيف متفاعلش مع الميه إذا هذا ولا عد
+
+302
+00:23:18,490 --> 00:23:23,230
+إنه موجود إذا ال salts إحنا بنجيب نجسمها نجسم ال
+
+303
+00:23:23,230 --> 00:23:28,260
+salts نفسه لجسمينجسم بنلغى نهائيا بتفعلش مع المياه
+
+304
+00:23:28,260 --> 00:23:31,880
+و جسم بتفعل .. اللى بتفعل بس هو المهم لأن اللى
+
+305
+00:23:31,880 --> 00:23:35,180
+بتفعلش مع المياه لا يؤثر على ال pitch وجوده و عدمه
+
+306
+00:23:35,180 --> 00:23:41,220
+واحد ال spectator ion ماشي يا شباب .. اذا هذا اول
+
+307
+00:23:41,220 --> 00:23:45,040
+نوع من انواع ال salts ال salts المكونة من weak
+
+308
+00:23:45,040 --> 00:23:50,580
+acid او weak base مع جزء اخر جاي من strong acid او
+
+309
+00:23:50,580 --> 00:23:52,820
+strong base هذا اول نوع من انواع ال salts
+
+310
+00:23:56,360 --> 00:24:00,940
+نفس العالم بس التنين بتفعلوش مع الميه خدت بالك طيب
+
+311
+00:24:00,940 --> 00:24:06,220
+نيجي نتطلع على يعني
+
+312
+00:24:06,220 --> 00:24:10,580
+لو طلعنا على التفاعل هذا بلاحظ ايش طلع عندي يا
+
+313
+00:24:10,580 --> 00:24:15,580
+شباب طلع عندي hydroxide اذا هذي اكتبلها K A ولا K
+
+314
+00:24:15,580 --> 00:24:24,520
+B K B طيبفي الكتب كلها وفي المسائل بيعطيني إيش هو
+
+315
+00:24:24,520 --> 00:24:28,680
+ال equilibrium constant لل conjugate لحاجة عليها
+
+316
+00:24:28,680 --> 00:24:32,400
+شحنة لأ بعطيني بس لل uncharged species ال case
+
+317
+00:24:32,400 --> 00:24:35,160
+تبعتها يعني هان لو بدى يعطيني الأستيت ماعطينيش
+
+318
+00:24:35,160 --> 00:24:38,180
+الأستيت بيعطيني ال acetic acid فهو إيش بيعطيني
+
+319
+00:24:38,180 --> 00:24:42,100
+بيعطيني ال K a لكن هذا ال equilibrium K a ولا Kb
+
+320
+00:24:42,100 --> 00:24:47,020
+Kb إذا لازم أعرف أحول من ال K a اللي بيعطيها لل Kb
+
+321
+00:24:47,020 --> 00:24:51,160
+نفس الكلام هان هان هيعطيني بس لل ammoniaكي بي
+
+322
+00:24:51,160 --> 00:24:56,140
+للأمونيا لكن هذا ايش طالع عند اتش بلس اذا هذا كي
+
+323
+00:24:56,140 --> 00:24:59,880
+ايه الجهاز المعروف حول من كي بي من كي بي لكي اي
+
+324
+00:24:59,880 --> 00:25:07,000
+لازمفي هذه .. طبعا بقعد نستخدم ال KW فكيف بدنا
+
+325
+00:25:07,000 --> 00:25:12,160
+نحول من KA لKB و من KB لKA ناخد مثال مثلا ال
+
+326
+00:25:12,160 --> 00:25:15,320
+Acetic Acid و ال Acetate فال Acetic Acid بتفكك
+
+327
+00:25:15,320 --> 00:25:20,240
+بعطينا H Plus و Acetate ال KA بده يعطينا H Plus في
+
+328
+00:25:20,240 --> 00:25:23,400
+ال Acetate على ال Acetic Acid طيب تفكك ال Acetate
+
+329
+00:25:23,400 --> 00:25:25,560
+.. ال Acetate في الميه بعطينا Acetic Acid و
+
+330
+00:25:25,560 --> 00:25:29,080
+Hydroxide ال KB بعطينا Acetic Acid في ال Hydroxide
+
+331
+00:25:29,080 --> 00:25:30,900
+على ال Acetate
+
+332
+00:25:33,360 --> 00:25:39,080
+ماشي يا شبابطيب الان لو ضربنا K A في K B بلاحظ
+
+333
+00:25:39,080 --> 00:25:42,460
+بيعطينا H Plus في ال hydroxide طبعا هذا الكلام
+
+334
+00:25:42,460 --> 00:25:46,900
+يعني بيساوي K W بيساوي عشر أقص سالم أربعتاش يبقى
+
+335
+00:25:46,900 --> 00:25:50,220
+ال K A في ال K B بتساوي عشر أقص سالم أربعتاش يبقى
+
+336
+00:25:50,220 --> 00:25:53,600
+لو عندى أنا ال K A بقدر أجيب ال K B و لو عندى ال K
+
+337
+00:25:53,600 --> 00:25:57,440
+B بقدر أجيب ال K E طبعا هذا كلام صحيح فقط لل acid
+
+338
+00:25:57,440 --> 00:26:02,120
+base conjugates لل acid و المرافق تبعه ال base و
+
+339
+00:26:02,120 --> 00:26:07,260
+المرافق تبعه ماشي يا شبابالان يعني احنا مؤهلين انه
+
+340
+00:26:07,260 --> 00:26:16,400
+نحاول ندرس كيف نحسب ال pH ل ال salts و ناخد طبعا
+
+341
+00:26:16,400 --> 00:26:20,720
+احنا بنتكلم لسه عن النوع الاول اللي هو واحد منهم
+
+342
+00:26:20,720 --> 00:26:25,640
+جاي من weak acid او weak base الشق والشق التاني
+
+343
+00:26:25,640 --> 00:26:29,870
+جاي من ال strongطيب نتطلع على المثال التالي بيقول
+
+344
+00:26:29,870 --> 00:26:34,290
+find the pH of a 0.1 molar solution of sodium
+
+345
+00:26:34,290 --> 00:26:38,470
+acetate ال K A لاحظ هو sodium acetate لكن ايش
+
+346
+00:26:38,470 --> 00:26:44,390
+يعطيك ال K A مش ال KB بيعطيكاش ال KB ليش لأن ال KB
+
+347
+00:26:44,390 --> 00:26:47,370
+هدل ال conjugate ما بيعطيك ال conjugate هو بيعطيك
+
+348
+00:26:47,370 --> 00:26:52,470
+لأصل الملح أصله أصله جاي من acetic acid بيعطيك ال
+
+349
+00:26:52,470 --> 00:26:56,630
+K A للacetic acidفالـ KA واحد وخمسة وسبعين فعشرة
+
+350
+00:26:56,630 --> 00:27:02,070
+أقل سالب خمسة بنيجي بنقول والله في البداية لو إجيت
+
+351
+00:27:02,070 --> 00:27:08,090
+قولت Sodium Acetate هي NA plus OAC minus بقول هذا
+
+352
+00:27:08,090 --> 00:27:14,730
+جاي من strong base إذا هو weak conjugate acid يبقى
+
+353
+00:27:14,730 --> 00:27:19,150
+أيه؟ مالوش دعوة في حاجة يبقى عندي بس acetate ال
+
+354
+00:27:19,150 --> 00:27:25,140
+acetate في المياه بتعطيناالـ HOAC زائد
+
+355
+00:27:25,140 --> 00:27:34,920
+الهيدروكسايد الـ HOAC
+
+356
+00:27:34,920 --> 00:27:41,560
+زائد الهيدروكسايد
+
+357
+00:27:42,730 --> 00:27:47,150
+بتفكر بتعطي H بلس زائد Hydroxide لكن بنفس المدهجية
+
+358
+00:27:47,150 --> 00:27:51,590
+بنقول ال acetate إيش بتعطيني؟ Hydroxide إذا هو
+
+359
+00:27:51,590 --> 00:27:56,090
+محلول قاعدى، اتبع مدار بتعطيني Hydroxide إذا
+
+360
+00:27:56,090 --> 00:28:01,550
+محلولها إيه؟ قاعدى، محلول قاعدى، طيب لا يمكن يكون
+
+361
+00:28:01,550 --> 00:28:05,590
+فيها H بلس كتيرلأن المحلول القاعدى لا يمكن يكون
+
+362
+00:28:05,590 --> 00:28:08,370
+فيه H بلس كتير هذه حاجة الحاجة التانية المحلول
+
+363
+00:28:08,370 --> 00:28:13,210
+القاعدى طالع انها OH ايش بده يخلي الميه تسوي
+
+364
+00:28:13,210 --> 00:28:17,150
+تفككها راح يرجع لورا معناه كلاه اصلا كمية ال
+
+365
+00:28:17,150 --> 00:28:20,530
+hydroxide اللى جاى منها قليلة لا تكاد تذكر فما
+
+366
+00:28:20,530 --> 00:28:23,690
+بالكم بعد ما احط محلول ال acetate و ال acetate
+
+367
+00:28:23,690 --> 00:28:26,630
+يعطيني hydroxide يعني اندي common ion يبقى التفكك
+
+368
+00:28:26,630 --> 00:28:30,830
+راح يرجع لورا معناه الكلام كمية ال hydroxide اللى
+
+369
+00:28:30,830 --> 00:28:35,370
+جاية من الميهلأ تكتب تتكلم سواء ال H بلس وهذا
+
+370
+00:28:35,370 --> 00:28:40,150
+محلول قاعدي مش محلول حمضي اذا بقدر اقول ان ال
+
+371
+00:28:40,150 --> 00:28:43,670
+hydroxide للمحلول هو عبارة عن ال hydroxide اللي
+
+372
+00:28:43,670 --> 00:28:48,870
+جاي من ال acetate بجه اول خطوة انا لغيت ال NA بلس
+
+373
+00:28:48,870 --> 00:28:53,510
+هذه ولا عدنها موجودة ليه؟ لانها weak conjugate
+
+374
+00:28:53,510 --> 00:28:57,670
+acid لانها جاي من ال strong base فهي ماتتفعلش مع
+
+375
+00:28:57,670 --> 00:29:02,430
+الميهإذا لا تؤثر على ال pH يبقى بس اللي بيؤثر على
+
+376
+00:29:02,430 --> 00:29:06,330
+ال pH ال Acetate أخدت ال Acetate و قلت طيب المصدر
+
+377
+00:29:06,330 --> 00:29:11,170
+ال hydroxide ال Acetate و أيضا الميه فأثبتت أن ال
+
+378
+00:29:11,170 --> 00:29:15,110
+hydroxide اللي جاي من الميه لا يكد يفجر قليل جدا و
+
+379
+00:29:15,110 --> 00:29:20,250
+أثبته يعني مرحليا لأنه لازم أبرهن على أن إثباتي
+
+380
+00:29:20,250 --> 00:29:26,040
+كان أو فرضيتي كانت صحيحة لكن في المستقبلفبقول
+
+381
+00:29:26,040 --> 00:29:28,720
+بيبقى عندي بس أسيتات إذا اللي أسيتات في الميه
+
+382
+00:29:28,720 --> 00:29:32,560
+بتعطينا hydroxide وacetic acid يبقى point one صفر
+
+383
+00:29:32,560 --> 00:29:36,420
+صفر point one minus x x x ال equilibrium constant
+
+384
+00:29:36,420 --> 00:29:40,720
+بدي أحسبه هذا كي بي لازم أحسبه كي و على الكي ا
+
+385
+00:29:40,720 --> 00:29:46,400
+بيعطيني خمسة و سبعة فعشرة أقل سالب عشرة فبقول
+
+386
+00:29:46,400 --> 00:29:50,120
+والله الكي بي اللي بيسوى x تربيع ال point one
+
+387
+00:29:50,120 --> 00:29:54,070
+minus xبفترض ال point one أكبر كتير من ال X علشان
+
+388
+00:29:54,070 --> 00:29:57,970
+أبسط المسألة فتطلع عند ال X سبعة و ستة في عشر عقل
+
+389
+00:29:57,970 --> 00:30:04,830
+سالب ستةهل فرضيتي صحيحة؟ والله سبعة و ستة في عشرة
+
+390
+00:30:04,830 --> 00:30:08,750
+أقل سالسة على point one فيه مية من مية بتطلع كمية
+
+391
+00:30:08,750 --> 00:30:13,670
+قليلة جدا جدا جدا لا تكتر تكتر إذا ال assumption
+
+392
+00:30:13,670 --> 00:30:17,690
+تبعي valid مش مشكلة فيه وال hydroxide بيساوي سبعة
+
+393
+00:30:17,690 --> 00:30:23,050
+و ستة في عشرة أقل سالب ستة الآن بقدر من هذه القيمة
+
+394
+00:30:23,050 --> 00:30:28,050
+أحسب قيمة ال hydroxide اللي من وين جايةمن الميه
+
+395
+00:30:28,050 --> 00:30:31,750
+بحسب عن قيمة الـ H plus وهى اللى بتساوي
+
+396
+00:30:31,750 --> 00:30:34,510
+الهيدروكسيد اللى جاى من الميه فالهيدروكسيد اللى
+
+397
+00:30:34,510 --> 00:30:38,090
+جاى من الميه بتطلع واحد و تلاتة فعشرة أقصى تسعة هل
+
+398
+00:30:38,090 --> 00:30:42,770
+هذه القيمة بالفعل يمكن إلغاها جانب الهيدروكسيد
+
+399
+00:30:42,770 --> 00:30:47,600
+اللى جاى من الاسيتيت طب خلنا نشوف نسبة الخطألأن
+
+400
+00:30:47,600 --> 00:30:50,880
+بعض الناس بيقولك عشرة او سالب ستة لعشرة او سالب
+
+401
+00:30:50,880 --> 00:30:54,780
+تسعة يمكن مش كتير فتعالوا نشوفها بيطلع عندنا point
+
+402
+00:30:54,780 --> 00:30:59,000
+01% يعني ان نلغي ال hydroxide اللي جاء من الميه
+
+403
+00:30:59,000 --> 00:31:02,920
+يعني هذا اشي لا يؤثر مطلقا على النتيجة وبيقديش
+
+404
+00:31:02,920 --> 00:31:09,200
+لخطأ نهائيا او خطأ محسوس نهائيا طبعا انا طلعت ال
+
+405
+00:31:09,200 --> 00:31:14,060
+hydroxide فبجيب منها ال POHو بعدين 14 نقص ال POH
+
+406
+00:31:14,060 --> 00:31:19,420
+بيعطينا ال pH و لاحظوا معايا ان ال pH طلعت عندى
+
+407
+00:31:19,420 --> 00:31:28,500
+حوالى 8.9 قاعدية يعني و هذا ايش بدك تلاحظه ال salt
+
+408
+00:31:28,500 --> 00:31:33,460
+اللى جاى من weak acid ال pH تبعته قاعدية و ال salt
+
+409
+00:31:33,460 --> 00:31:37,680
+اللى جاى من weak base ال pH تبعته حرضية اه بدك
+
+410
+00:31:37,680 --> 00:31:43,370
+تاخد بالك من هذا الكلامهان لأن الاسيتيتا اعطتني
+
+411
+00:31:43,370 --> 00:31:47,910
+hydroxide فلازم تعطيني اشي قاعدى لكن ممكن نتطلع
+
+412
+00:31:47,910 --> 00:31:54,210
+على مثلا ال ammonium chloride هذا ملح ammonium
+
+413
+00:31:54,210 --> 00:31:56,830
+chloride طبعا ال ammonium chloride نصين برضه نفس
+
+414
+00:31:56,830 --> 00:32:02,770
+الكلام ممكن اقول والله ال ammonium chloride هذا هو
+
+415
+00:32:02,770 --> 00:32:04,590
+NH4
+
+416
+00:32:06,640 --> 00:32:13,700
+هذا جاي من HCl يعني هذا weak conjugate base اذا
+
+417
+00:32:13,700 --> 00:32:17,240
+ماتدخلش في الميه وهذا جاي من weak base اذا هذا
+
+418
+00:32:17,240 --> 00:32:23,460
+strong conjugate acid يعني متفاعل مع الميه ممكن
+
+419
+00:32:23,460 --> 00:32:29,290
+تكتب الميه تكتب H3O بلس لكن ممكن نكتبه برضهكالتالي
+
+420
+00:32:29,290 --> 00:32:34,650
+سيئة طبعا اذا انا مافيش عندى و كأنه مافيش عندى
+
+421
+00:32:34,650 --> 00:32:37,430
+chloride لأنه بيأثرش على ال pH يبقى اللي عندى بس
+
+422
+00:32:37,430 --> 00:32:43,730
+ammonium طيب هذا إله Ka لكن المسألة إيش معطيانة؟
+
+423
+00:32:43,730 --> 00:32:49,550
+Kb فلازم أحول من Ka من Kb لKa لكن في البداية بنقول
+
+424
+00:32:49,550 --> 00:32:53,150
+بنفس الصيغة ال H plus اللي في المحلول يعبر عن ال H
+
+425
+00:32:53,150 --> 00:32:56,490
+plus اللي جاية من ال ammonium زاد ال H plus اللي
+
+426
+00:32:56,490 --> 00:32:58,010
+جاية من الميه هي الميه
+
+427
+00:33:02,070 --> 00:33:06,170
+لكن الـ H Plus اللي جاي من الميّه أصلا قليلة، مش
+
+428
+00:33:06,170 --> 00:33:11,050
+هيك؟ فما بقاكم لما نضيف عليها H Plus جاي من
+
+429
+00:33:11,050 --> 00:33:15,750
+الأموديام، إيش بحصل؟ تفكك الميّه تقريبا بينعدم
+
+430
+00:33:15,750 --> 00:33:21,430
+بقلب درجة كبيرة جدا وبالتالي لا يكاد يذكر تركيز
+
+431
+00:33:21,430 --> 00:33:26,540
+الـ H Plus اللي جاي من الميّهالان أتش ثلاثة قاعدة
+
+432
+00:33:26,540 --> 00:33:31,380
+ضعيفة، إذا الان أتش فوري بلس، strong conjugate
+
+433
+00:33:31,380 --> 00:33:37,520
+acid، acid، strong conjugate acid، هيوطاني H بلس،
+
+434
+00:33:37,520 --> 00:33:41,140
+فعند المي عصم تفككها ضعيف، في وجود ال H بلس اللي
+
+435
+00:33:41,140 --> 00:33:44,940
+جاي من الأمونيام، بيرجع لورة طبعا، لأنه common ion
+
+436
+00:33:44,940 --> 00:33:49,380
+فتفككها بيصير أضعف كتير جدا، وممكن نثبت هذا الكلام
+
+437
+00:33:49,640 --> 00:33:53,020
+إذا الـ H بلس اللى جاى من الميه لا تكاد تفجر يبقى
+
+438
+00:33:53,020 --> 00:33:56,140
+الـ H بلس المحلول هي عبارة عن الـ H بلس للأمونيام
+
+439
+00:33:56,140 --> 00:33:59,100
+يبقى ان في عندي بس أمونيام كيف بدي أجيب الـ H بلس
+
+440
+00:33:59,100 --> 00:34:04,300
+للأمونيام؟ بدي أحطه في الميه و أفككه فالأمونيام
+
+441
+00:34:04,300 --> 00:34:09,180
+بيعطيني H بلس و أمونياه تركيزه point two five صفر
+
+442
+00:34:09,180 --> 00:34:17,340
+صفر point two five minus X X Xالان يا شباب بقول
+
+443
+00:34:17,340 --> 00:34:21,780
+انا عندى h plus تعالى عزى انها دى k a لكن السؤال
+
+444
+00:34:21,780 --> 00:34:28,000
+بيعطينى kb بدي احسب ال k a فبقول k a بساوي k w على
+
+445
+00:34:28,000 --> 00:34:32,640
+ال kb بيعطينى ال k a برضه خمسة و سبعة فعشرة اقل
+
+446
+00:34:32,640 --> 00:34:36,540
+سالم عشرة اذا ال k a بتساوي ال h plus في ال
+
+447
+00:34:36,540 --> 00:34:39,280
+ammonia على ال ammonium يعني ال k a بساوي x تنبيه
+
+448
+00:34:39,280 --> 00:34:43,200
+على ال point two five minus x وعشان ابسط المسألة
+
+449
+00:34:43,200 --> 00:34:48,450
+بقول ان ال point two fiveأكبر كثير من ال X إذا
+
+450
+00:34:48,450 --> 00:34:54,560
+ممكن إلغاء ال X جانب ال point 25 وهذا فرضيةبأجيب
+
+451
+00:34:54,560 --> 00:34:57,840
+والله قيمة ال X بتطلع واحد و اتنين فى عشرة أس سالب
+
+452
+00:34:57,840 --> 00:35:01,400
+خمسة بقول هل بالفعل الواحد و اتنين فى عشرة أس سالب
+
+453
+00:35:01,400 --> 00:35:04,920
+خمسة أقل كتير من ال point two five بنجيب ال
+
+454
+00:35:04,920 --> 00:35:08,160
+relative error و بيطلع حاجة جزء من الف في المية
+
+455
+00:35:08,160 --> 00:35:12,660
+جزء من الف في المية معناه كلام نعم ال assumption
+
+456
+00:35:12,660 --> 00:35:18,930
+عندى valid ال assumption عندى validمعنى الكلام الـ
+
+457
+00:35:18,930 --> 00:35:22,030
+H plus بدل ساعة واحد و اتنين فعشرة أس سالب خمسة
+
+458
+00:35:22,030 --> 00:35:27,770
+وهان هادرال محلول اللي هو جاي طبعا من ال ammonium
+
+459
+00:35:27,770 --> 00:35:32,920
+طب هان بقدر اجيب قيمة ال hydroxideعلى طول KW بساوي
+
+460
+00:35:32,920 --> 00:35:36,400
+الهيدروكسيد في ال H بلس يبقى الهيدروكسيد بيساوي
+
+461
+00:35:36,400 --> 00:35:42,100
+تمانية و تلاتة فعشرة أس سالم عشرة هذا عبارة عن ال
+
+462
+00:35:42,100 --> 00:35:46,780
+H بلس اللي جاي من الميه لإنه مصدر الهيدروكسيد
+
+463
+00:35:46,780 --> 00:35:50,600
+الوحيد هو الميه و الميه لما تتفكك بتعطيني
+
+464
+00:35:52,630 --> 00:35:57,010
+هيدروكسايد هو protons يعني H بلس فطبيعي ان ال H
+
+465
+00:35:57,010 --> 00:35:59,950
+بلس اللي جاه من الميه بتساوي الهيدروكسايد معنى
+
+466
+00:35:59,950 --> 00:36:02,590
+الكلام ال H بلس اللي جاه من الميه عبارة عن تمانية
+
+467
+00:36:02,590 --> 00:36:05,830
+و تلاتة في عشرة أس سالب عشرة هل يمكن إلغاء
+
+468
+00:36:05,830 --> 00:36:10,010
+التمانية و تلاتة في عشرة أس سالب عشرة بالمقارنة مع
+
+469
+00:36:10,010 --> 00:36:14,190
+الواحد و اتنين في عشرة أس سالب خمسة ممكن إلغاها
+
+470
+00:36:14,190 --> 00:36:16,150
+ولا لأ و الله بنجيب ال relative error ولا و لا
+
+471
+00:36:16,150 --> 00:36:20,700
+جناهابنجيب ال relative error لو لغيناها فعندي
+
+472
+00:36:20,700 --> 00:36:24,460
+تمانية و تلاتة في عشرة أس سالب عشرة على واحد و
+
+473
+00:36:24,460 --> 00:36:27,480
+اتنين في عشرة أس سالب خمسة في مية من المية بيطلع
+
+474
+00:36:27,480 --> 00:36:32,020
+الرقم يعني قليل جدا جزء من الف مية نسبة الخطأ يعني
+
+475
+00:36:32,020 --> 00:36:39,570
+لا شك انه الغاء او عدم الاهتمام او اهمالالـ H plus
+
+476
+00:36:39,570 --> 00:36:43,210
+اللي جاية من الميه هذا شئ طبيعي جدا ليه؟ لأنه في
+
+477
+00:36:43,210 --> 00:36:50,010
+عندي كمية من الـ H plus كبيرة جاية من ال ammonium
+
+478
+00:36:50,010 --> 00:36:54,250
+طبعا انا ممكن برضه يعني ألفت انتباهكم لنقطة
+
+479
+00:36:56,730 --> 00:37:01,290
+لو قلنا ال K A تو حسبناها هان بتساوي خمسة و سبعة
+
+480
+00:37:01,290 --> 00:37:07,790
+فعشرة أس سالب عشرة و هاد ال K W تفكك بيساوي عشرة
+
+481
+00:37:07,790 --> 00:37:13,390
+أس سالب أربعة عشرلو اجينا احنا قلنا ان هذا التفكك
+
+482
+00:37:13,390 --> 00:37:18,170
+بعطيني H plus وهذا التفكك ايضا بعطيني H plus مثلا
+
+483
+00:37:18,170 --> 00:37:24,250
+برضه هذا بيدلك يعني او بيعطيك فكرة هل شغلك يعني
+
+484
+00:37:24,250 --> 00:37:28,780
+منطقة او فرضيتك منطقية ولا لأهذا عشرة أساليب عشرة
+
+485
+00:37:28,780 --> 00:37:32,000
+ال K.E. وهذا عشرة أساليب أربعة عاشر يعني الأول لو
+
+486
+00:37:32,000 --> 00:37:39,380
+طلعت عليه ماشي بدرجة أكبر من التاني بحوالي سبعة
+
+487
+00:37:39,380 --> 00:37:43,490
+وخمسين ألف مرة لأ دي خمسة مش واحد هذي خمسة وسبعة57
+
+488
+00:37:43,490 --> 00:37:47,870
+ألف برة، إيش معناه هذا الكلام؟ يعني لما يعطيني
+
+489
+00:37:47,870 --> 00:37:52,630
+الأول 57 ألف بروتون، التاني بعطيني بروتون واحد، كل
+
+490
+00:37:52,630 --> 00:37:56,550
+57 ألف بروتون، التاني إيش بعطيني؟ بروتون واحد، إذا
+
+491
+00:37:56,550 --> 00:38:00,370
+هذا البروتون يعني لا يكاد يذكر، يعني كميته قليلة
+
+492
+00:38:00,370 --> 00:38:07,530
+جدا، كميته قليلة للغاية، اكويس، نفس الكلام يمكن
+
+493
+00:38:07,530 --> 00:38:12,810
+برضه قوله في حكاية الأستات
+
+494
+00:38:18,580 --> 00:38:22,600
+برضه ال Kb كان بيساوي خمسة و سبعة في عشرة أقل سالب
+
+495
+00:38:22,600 --> 00:38:28,820
+عشرة و هان ال H2O H plus زائد هيدروكسيد و ال KW
+
+496
+00:38:28,820 --> 00:38:33,780
+بده يساوي عشرة أقل سالب أربعة عشر نفس الكلام يعني
+
+497
+00:38:33,780 --> 00:38:37,580
+بشوف الهيدروكسيد اللي جاية من هان كل خمسة و سبعين
+
+498
+00:38:37,580 --> 00:38:42,560
+ألف هيدروكسيدة جاية من الأول لإن هى ال equilibrium
+
+499
+00:38:42,560 --> 00:38:44,800
+constant هذا rate
+
+500
+00:38:46,840 --> 00:38:50,480
+التفكك التاني مستمر، بقول كل 57 ألف هيدروكسيدة
+
+501
+00:38:50,480 --> 00:38:53,900
+بحصلها في التفكك الأول بحصل مقابلها على واحدة بس
+
+502
+00:38:53,900 --> 00:38:56,940
+من التفكك التاني، اذا التفكك التاني هذا لا يكاد
+
+503
+00:38:56,940 --> 00:38:59,760
+يذكر، التفكك التاني هذا لا يكاد يذكر، وكأنه مش
+
+504
+00:38:59,760 --> 00:39:04,880
+موجودماخدين بالنا يا شباب؟ طبعا بعد هيك سهل انه
+
+505
+00:39:04,880 --> 00:39:10,640
+نحسب ال pH على طول من 1 و 2 في 10 او 5 minus log
+
+506
+00:39:10,640 --> 00:39:15,880
+تعطينا 94 و 92 و لاحظ ان ال pH حامضية ليه؟ لأن هذا
+
+507
+00:39:15,880 --> 00:39:19,620
+salt مشتق من weak base ال salt اللي ممكن مشتق من
+
+508
+00:39:19,620 --> 00:39:24,020
+weak base ال pH تبعته حامضيةبعكس الصوت المشتق من
+
+509
+00:39:24,020 --> 00:39:28,200
+weak acid ال pH تبعته قاعدية و طبعا ال POH بنجيبها
+
+510
+00:39:28,200 --> 00:39:31,260
+14 ناقص ال pH
+
+511
+00:39:35,250 --> 00:39:39,070
+خلّينا يا شباب برضه بما أنه فتحنا هذا الموضوع ناخد
+
+512
+00:39:39,070 --> 00:39:42,770
+النوع التاني من ال salts النوع التاني من ال salts
+
+513
+00:39:42,770 --> 00:39:45,750
+طبعا احنا مانش نطلع على ال salts بنقول ال salts
+
+514
+00:39:45,750 --> 00:39:51,370
+شقين ممكن شق منه يكون جاي من strong acid و شق جاي
+
+515
+00:39:51,370 --> 00:39:54,570
+من strong base هذا ما درسناه الحصة الماضية الآن
+
+516
+00:39:54,570 --> 00:40:01,390
+درسنا شق جاي من weak acid مثلا او weak base و شق
+
+517
+00:40:01,390 --> 00:40:07,200
+جاي من strongاللي جاي من الـ strong لا يحسب لأنه
+
+518
+00:40:07,200 --> 00:40:12,040
+very weak conjugate طبعا لا يتفعل مع الميه طيب
+
+519
+00:40:12,040 --> 00:40:16,200
+ممكن النوع التالت من أنواع ال salts اللي احنا راح
+
+520
+00:40:16,200 --> 00:40:22,060
+نذكرها ال salt مشتق من اتنين weak weak acid و weak
+
+521
+00:40:22,060 --> 00:40:26,180
+base او weak base و weak acid معايا يعني مافيش
+
+522
+00:40:26,180 --> 00:40:30,740
+حاجة strong زي ايش مثلا زي مثلا ال ammonium
+
+523
+00:40:30,740 --> 00:40:31,380
+cyanide
+
+524
+00:40:34,380 --> 00:40:48,060
+NH4CN هدا from weak acid اللي هو HCN وهدا from
+
+525
+00:40:48,060 --> 00:40:51,480
+weak
+
+526
+00:40:51,480 --> 00:41:01,000
+base اللي هو NH3 صح ولا لأ؟ اذا هذا strong
+
+527
+00:41:03,200 --> 00:41:08,440
+conjugate base مدمن weak acid ليش هو weak acid؟
+
+528
+00:41:08,440 --> 00:41:13,500
+لأن ال conjugate base تبعه strong طب و هذا ليش هو
+
+529
+00:41:13,500 --> 00:41:21,440
+weak base؟ اذا خلينا نعمل السهم هذا هان و ناخد
+
+530
+00:41:21,440 --> 00:41:26,940
+السهم هذا هيك و نقول والله هذا عبارة عن strong
+
+531
+00:41:26,940 --> 00:41:29,160
+conjugate
+
+532
+00:41:30,390 --> 00:41:34,990
+أسد، إيش يعني strong conjugate base؟ يعني بيتفاعل
+
+533
+00:41:34,990 --> 00:41:39,090
+مع الميه، وإيش يعني strong conjugate acid؟ بتتفاعل
+
+534
+00:41:39,090 --> 00:41:42,230
+مع الميه، إذا الإتنين اتفاعلوا مع الميه، دي مشكلة،
+
+535
+00:41:42,230 --> 00:41:45,810
+الإتنين لازم يعدوا في الحسابات، ومش بس هيك كمان،
+
+536
+00:41:45,810 --> 00:41:49,830
+والميه كمان بتعدي في الحسابات إذا كان يعني كان في
+
+537
+00:41:49,830 --> 00:41:54,850
+ضرورة إلهاطب بمشوف المثال اللي قدامنا بيقول for
+
+538
+00:41:54,850 --> 00:41:59,330
+example look at the calculation of pH for a 0.1
+
+539
+00:41:59,330 --> 00:42:06,190
+molar ammonium cyanide معطيك ال Kb للأمونيا واحد و
+
+540
+00:42:06,190 --> 00:42:10,410
+تمانية في عشر أقل سالب خمسة ومعطيك ال Ka لل HCN
+
+541
+00:42:10,410 --> 00:42:14,010
+طبعا لأنه بيعطيكاش لل conjugate بيعطيك للأصل زي ما
+
+542
+00:42:14,010 --> 00:42:19,170
+انت فاهمان ستة في عشرة أقل سالب عشرة طيب بنقول
+
+543
+00:42:19,170 --> 00:42:24,990
+التاليإذا الأمونيا في الميّه بتعطينا بروتون
+
+544
+00:42:24,990 --> 00:42:31,070
+وأمونيا الـKa لها خمسة سبعة عشرة أس سالم عشرة
+
+545
+00:42:31,070 --> 00:42:35,150
+والسينايد في الميّه بتعطينا HCN زائد هيدروكسيد
+
+546
+00:42:35,150 --> 00:42:39,850
+وهذا KP لأنه طالع عندي هيدروكسيد لما نحسبها كW على
+
+547
+00:42:39,850 --> 00:42:45,650
+Ka بتطلع عندي واحد سبعة عشرة أس سالم خمسة طيب كيف
+
+548
+00:42:45,650 --> 00:42:49,800
+الأن بدي أفكر أنا؟بقول لما الكورفين ده أكتر و كمان
+
+549
+00:42:49,800 --> 00:42:55,860
+هى الميه يعنى إذا كان حبين هى ال H2O H بلس زائد
+
+550
+00:42:55,860 --> 00:43:01,980
+هيدروفسايد تعالوا ال KWLH عشرة أس سالب أربعة عشر
+
+551
+00:43:01,980 --> 00:43:09,520
+تعالوا في الأول نقارن ال two equilibria هيك الشغل
+
+552
+00:43:09,520 --> 00:43:12,440
+بنقارن ما هو لما الكورفين ده أكتر من ال
+
+553
+00:43:12,440 --> 00:43:16,110
+equilibrium مشكلةفابد احاول انا اختصر هال
+
+554
+00:43:16,110 --> 00:43:20,670
+equilibrium هذه ل one single equilibrium بحاول
+
+555
+00:43:20,670 --> 00:43:25,540
+اعمل هذا الكلامطبعا يمكن حل الاكتر من اكوليبريا
+
+556
+00:43:25,540 --> 00:43:29,020
+لكن احنا بنحاول نبسط الموضوع و مش هناكن حل اكتر من
+
+557
+00:43:29,020 --> 00:43:34,120
+اكوليبريا بنحل بس بالتبسيط لأقل او لا اقرب لا
+
+558
+00:43:34,120 --> 00:43:39,580
+اكوليبريا واحد فقط ان امكن ماامكنش بنقول والله اه
+
+559
+00:43:39,580 --> 00:43:42,680
+هذه مسألة تحتاج الى انه نحل بال two equilibrium
+
+560
+00:43:42,680 --> 00:43:46,460
+يعني يمكن اعطيكم هذا الكلام اتكلم عن ال polyprotic
+
+561
+00:43:46,460 --> 00:43:50,320
+acidsففي البداية نطلع على الاتنين و نحاول نفهم من
+
+562
+00:43:50,320 --> 00:43:52,420
+ال equilibrium constant هذا ال equilibrium
+
+563
+00:43:52,420 --> 00:43:56,840
+constant عشرة أس سالب عشرة هذا ال equilibrium
+
+564
+00:43:56,840 --> 00:44:01,180
+constant عشرة أس سالب خمسة اذا انه بيتم بدرجة
+
+565
+00:44:01,180 --> 00:44:07,420
+كبيرة التاني التاني بيتم اه ال Kb بيتم اكبر يعني
+
+566
+00:44:07,420 --> 00:44:15,480
+تقريبا مائة الف مرة اكتر من الاوليعني كل ما هذا
+
+567
+00:44:15,480 --> 00:44:20,620
+يعطيني 100 ألف Hydroxide هذا بيعطيني واحدة Proton،
+
+568
+00:44:20,620 --> 00:44:23,700
+Proton واحد كل 100 ألف Hydroxide، إيش بيعطيني
+
+569
+00:44:23,700 --> 00:44:28,540
+جمالها الأول؟ Proton واحد يعني معناه الكلام و كأنه
+
+570
+00:44:28,540 --> 00:44:34,300
+هذا الأول فيش إله قيمة، فيش إله قيمة بالمقارنة مع
+
+571
+00:44:34,300 --> 00:44:40,200
+التاني، إذا المحلول في البداية بنقولمن كلامي
+
+572
+00:44:40,200 --> 00:44:42,820
+مقارنة الاتنين ال first equilibrium can be
+
+573
+00:44:42,820 --> 00:44:47,560
+neglected يهمل معايا ولا لأ؟ يمكن اهماله في
+
+574
+00:44:47,560 --> 00:44:51,720
+الحقيقة الحاجة التانية مدام أهملنا طب تعالى نتطلع
+
+575
+00:44:51,720 --> 00:44:54,540
+على ال equilibrium التالت اللى هو الميه أنا عندي
+
+576
+00:44:54,540 --> 00:44:58,940
+هذه عشرة أس سالب خمسة وهنا عشرة أس سالب اربعتاش
+
+577
+00:44:58,940 --> 00:45:02,280
+يعني كل ما الأول يعطينا hydroxide التاني أكمه
+
+578
+00:45:02,280 --> 00:45:05,780
+hydroxide بعطينيكمية قليلة كتير طب لما من الأول
+
+579
+00:45:05,780 --> 00:45:08,820
+يعطيني .. لو جسدنا خمسة عشر أقص سالب خمسة على عشر
+
+580
+00:45:08,820 --> 00:45:13,340
+أقص سالب أربعة عاش تقريبا بتطلع عشر أقص تسعة يعني
+
+581
+00:45:13,340 --> 00:45:17,540
+كل ألف مليون hydroxide بحصلها من الأول بحصلها
+
+582
+00:45:17,540 --> 00:45:23,460
+hydroxide واحدة من الميه، معايا ولا لأ؟ كل ألف
+
+583
+00:45:23,460 --> 00:45:27,400
+مليون عشر أقص تسعة hydroxide بحصلها من الأول
+
+584
+00:45:27,400 --> 00:45:32,140
+التاني بيعطيني ايه؟ one single .. حرزان؟ لأ، اذا
+
+585
+00:45:32,140 --> 00:45:39,730
+هذا التاني راحطبعا واحد من الف مليون ولا إشي إذا
+
+586
+00:45:39,730 --> 00:45:43,650
+يا شباب اختصرت هذه ال equilibrium لإيه ل one
+
+587
+00:45:43,650 --> 00:45:46,110
+single equilibrium هذا هو ال equilibrium المهم
+
+588
+00:45:46,110 --> 00:45:49,830
+عندي هذا هو اللي هيأثر على ال pH إذا ال pH تبعتي
+
+589
+00:45:49,830 --> 00:45:53,890
+إيش هتكون قاعدية
+
+590
+00:45:53,890 --> 00:45:57,850
+ماعلي أنا فجأة استفدت حتى لو ماعرفتش أحسبها عرفت
+
+591
+00:45:57,850 --> 00:46:02,310
+إن ال pH تبعتي هتكون إيهقاعدية تبنيج الآن لعملية
+
+592
+00:46:02,310 --> 00:46:06,970
+الحساب يبدأ الحساب بس one equilibrium cyanide زائد
+
+593
+00:46:06,970 --> 00:46:11,950
+H2و بيعطينا HCN زائد hydroxide هالمعنى لكلام هذه
+
+594
+00:46:11,950 --> 00:46:15,190
+ال equilibrium مش موجودة لا موجودة لكن تأثيرها على
+
+595
+00:46:15,190 --> 00:46:19,640
+ال pH لا يكاد يذكر قليل للغايةطب الآن يا شباب هي
+
+596
+00:46:19,640 --> 00:46:24,280
+الـ cyanide والميّه بيعطينا HCN وHydroxide هذا
+
+597
+00:46:24,280 --> 00:46:31,160
+عندي 0.100 0.1-XXX معناه الكلام الـKb بده يساوي
+
+598
+00:46:31,160 --> 00:46:35,180
+الـHCN في الهيدروكسيد على الـCN في الـCN minus
+
+599
+00:46:35,180 --> 00:46:40,720
+فبقول معناه الكلام راح نلاقي انه ال equilibrium
+
+600
+00:46:40,720 --> 00:46:45,340
+constant الـKbبيده يساوي X تربيع ال point one
+
+601
+00:46:45,340 --> 00:46:49,240
+minus X بفترض ان ال point one أكبر كتير من ال X ال
+
+602
+00:46:49,240 --> 00:46:52,660
+X بتطلع عندي واحد و تلاتة في عشر أقل سالم تلاتة
+
+603
+00:46:52,660 --> 00:46:57,340
+معنى الكلام ال relative error قليل اذا ال
+
+604
+00:46:57,340 --> 00:47:00,840
+assumption valid يبدأ على طول ال hydroxide واحد و
+
+605
+00:47:00,840 --> 00:47:04,400
+تلاتة في عشر أقل سالم تلاتة ومنها ال POH اتنين و
+
+606
+00:47:04,400 --> 00:47:10,300
+تسعة و تمانين و ال pH اربعة عشر ناقص ال POH ماشي
+
+607
+00:47:10,300 --> 00:47:21,160
+يا جماعةطيب هيك بنكون أخدنا أو أكملنا دراسة كيفية
+
+608
+00:47:21,160 --> 00:47:26,020
+حساب ال PH ل ال weak acids و ال weak bases و ال
+
+609
+00:47:26,020 --> 00:47:29,580
+salts ل ال weak acids و ال weak bases بنوعها
+
+610
+00:47:29,580 --> 00:47:35,220
+المكونة من weak acid او weak base مع strong base
+
+611
+00:47:35,220 --> 00:47:40,120
+او strong acidالاتنين او weak acid weak base مع
+
+612
+00:47:40,120 --> 00:47:43,820
+weak base weak acid هدول النوعين اخدنا كيفية حساب
+
+613
+00:47:43,820 --> 00:47:47,860
+ال pH لهم اذا الله راد الحصة الجاية بنبدأ نتكلم عن
+
+614
+00:47:47,860 --> 00:47:48,960
+ال butter solutions
+
diff --git a/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/j-9i1UBw5Do.srt b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/j-9i1UBw5Do.srt
new file mode 100644
index 0000000000000000000000000000000000000000..da4d16e3576a911d4f41120f5a74022d73beccf4
--- /dev/null
+++ b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/j-9i1UBw5Do.srt
@@ -0,0 +1,1779 @@
+1
+00:00:21,680 --> 00:00:26,040
+بسم الله الرحمن الرحيم. طيب يا شباب، نكمل في الـ
+
+2
+00:00:26,040 --> 00:00:31,160
+chapter الخاص بالـ equilibrium concepts، فنتكلم
+
+3
+00:00:31,160 --> 00:00:35,480
+اليوم عن... بشكل أساسي نتكلم عن الـ equilibrium
+
+4
+00:00:35,480 --> 00:00:38,560
+calculations. لكن قبل ما نروح للـ calculations،
+
+5
+00:00:38,560 --> 00:00:42,860
+تعالوا نتطلع شوية على Le Chatelier principle. طبعًا،
+
+6
+00:00:42,860 --> 00:00:48,220
+هذا مفهوم مر معنا في سنة أولى كيمياء عامة. مفهوم Le
+
+7
+00:00:48,220 --> 00:00:53,880
+Chatelier  كثير بسيط، كثير، بيصير بنقول إنه إذا كان...
+
+8
+00:00:53,880 --> 00:00:56,600
+كان في عندنا equilibrium ما، وأثرنا عليه بمؤثر
+
+9
+00:00:56,600 --> 00:01:01,300
+خارجي، فبنلاحظ إن الـ equilibrium بيمشي في اتجاه
+
+10
+00:01:01,300 --> 00:01:07,540
+بيحاول فيه تقليل تأثير المؤثر الخارجي. فعلى سبيل
+
+11
+00:01:07,540 --> 00:01:17,170
+المثال، لو كان في عندنا تفاعل ما في اتزان، وأضفنا
+
+12
+00:01:17,170 --> 00:01:22,050
+كمية من المتفاعلات، بنلاحظ إن التفاعل بيمشي للأمام.
+
+13
+00:01:22,050 --> 00:01:26,350
+لو سحبنا كمية من النواتج، برضه التفاعل بيمشي للأمام.
+
+14
+00:01:26,350 --> 00:01:31,630
+لو أضفنا كمية من النواتج، التفاعل بيمشي للخلف، و
+
+15
+00:01:31,630 --> 00:01:38,250
+هكذا. فيه تقريبًا، يعني أربعة عوامل ممكن ندرسها، و
+
+16
+00:01:38,250 --> 00:01:41,830
+ندرس تأثيرها على الـ equilibrium. أول حاجة، أو أول
+
+17
+00:01:41,830 --> 00:01:47,220
+عامل مهم بالنسبة لنا اللي هو التركيز. بالطبع، كما
+
+18
+00:01:47,220 --> 00:01:52,380
+ذكرت، إذا كان زدنا من تركيز المتفاعلات، بنلاحظ
+
+19
+00:01:52,380 --> 00:01:56,600
+التفاعل بيمشي للأمام. إذا كان أخدنا جزء، أو تخلصنا
+
+20
+00:01:56,600 --> 00:02:00,520
+من جزء من النواتج، التفاعل برضه بيمشي للأمام. إذا
+
+21
+00:02:00,520 --> 00:02:04,510
+كان زدنا تركيز النواتج، التفاعل بيمشي للخلف. هذا ما
+
+22
+00:02:04,510 --> 00:02:10,990
+يتعلق بالتركيز، وحنشوف تطبيقاته خلال الفصل. إذا
+
+23
+00:02:10,990 --> 00:02:15,010
+الله راد، العامل الثاني اللي ممكن نتكلم عنه هو
+
+24
+00:02:15,010 --> 00:02:19,920
+الحرارة. مثلًا، الحرارة. نلاحظ أن بعض التفاعلات بتكون
+
+25
+00:02:19,920 --> 00:02:25,100
+exothermic، أو طاردة للحرارة، بمعنى أنها تولد كمية من
+
+26
+00:02:25,100 --> 00:02:29,580
+الحرارة. هذا النوع من التفاعلات، لو سخناها، يعني لو
+
+27
+00:02:29,580 --> 00:02:33,140
+زدنا الحرارة، الأصل أنه التفاعل بيرجع للخلف، لأن
+
+28
+00:02:33,140 --> 00:02:37,760
+الحرارة يمكن النظر إليها من النواتج، إذا كانت طاردة
+
+29
+00:02:37,760 --> 00:02:42,160
+للحرارة. فالنتيجة عندنا أحد النواتج حرارة، فمعناه الكلام
+
+30
+00:02:42,160 --> 00:02:46,080
+إذا كان زدنا من النواتج، اللي هي الحرارة، بنلاحظ أن
+
+31
+00:02:46,080 --> 00:02:50,520
+التفاعل بيمشي للخلف. عكس هذا الكلام، لو كان التفاعل
+
+32
+00:02:50,520 --> 00:02:54,320
+ماص للحرارة، وزيدنا درجة الحرارة، التفاعل بده حرارة،
+
+33
+00:02:54,320 --> 00:03:00,580
+فالتفاعل بيمشي للأمام. العامل الثالث، عادة احنا
+
+34
+00:03:00,580 --> 00:03:05,420
+ما بنحكيش فيه بالنسبة للكيمياء التحليلية، لأنه بيتعلق
+
+35
+00:03:05,420 --> 00:03:13,200
+بالضغط. بنقول إن تأثير الضغط على السوائل، عادة يعني
+
+36
+00:03:13,200 --> 00:03:16,880
+شبه معدوم، لا يؤثر على السوائل أو على الصلب. الضغط
+
+37
+00:03:16,880 --> 00:03:20,880
+مهم بس في حالة الغازات، واحنا خلال الفصل هذا، أو الـ
+
+38
+00:03:20,880 --> 00:03:26,420
+course هذا، بندرس المحاليل والـ solids، لا ندرس يعني
+
+39
+00:03:26,420 --> 00:03:30,480
+الصلب، لا ندرس الصلب. وبالتالي، الضغط يعني عامل من
+
+40
+00:03:30,480 --> 00:03:33,940
+العوامل اللي عادة احنا ما بندرسهاش، وبالتالي تأثيرها
+
+41
+00:03:33,940 --> 00:03:39,080
+very marginal، أو غير مهم، فيما يتعلق بنوعية
+
+42
+00:03:39,080 --> 00:03:43,420
+المحاليل اللي احنا بندرسها. العامل الرابع اللي ممكن
+
+43
+00:03:43,420 --> 00:03:46,340
+نتكلم عنه، اللي هو وجود catalyst، أو استخدام
+
+44
+00:03:46,340 --> 00:03:52,660
+catalyst، أو عامل مساعد، أو عامل حفاز. عادة، وجود أو
+
+45
+00:03:52,660 --> 00:04:00,700
+استخدام عامل حفاز يسرّع التفاعل، بمعنى أنه يقلل الزمن
+
+46
+00:04:00,700 --> 00:04:05,280
+اللازم للوصول إلى نقطة الاتزان، لكنه لا يؤثر فيها.
+
+47
+00:04:05,280 --> 00:04:12,160
+كيف؟ يعني مثلًا عندي equilibrium يستغرق مثلًا ساعة
+
+48
+00:04:13,650 --> 00:04:18,810
+عشان يصل لحالة الاتزان. بقول ماشي، لو استخدمنا عامل
+
+49
+00:04:18,810 --> 00:04:22,950
+حفاز، ممكن مثلًا ياخد دقيقة عشان يوصل لحالة الاتزان،
+
+50
+00:04:22,950 --> 00:04:26,730
+لكن لو شوفنا قيمة الـ equilibrium constant، بنلاحظ
+
+51
+00:04:26,730 --> 00:04:30,830
+أنها هي هي. لو شوفنا جدّاش عندنا متفاعلات، جدّاش عندنا نواتج،
+
+52
+00:04:30,830 --> 00:04:35,860
+نفسها في الحالتين. لكن الزمن اللازم للوصول إلى نقطة
+
+53
+00:04:35,860 --> 00:04:40,360
+الاتزان بيكون قل بشكل كبير في وجود الـ catalyst. هذا
+
+54
+00:04:40,360 --> 00:04:46,060
+يعني مفهوم الـ catalyst. فالـ catalyst لا يؤثر في
+
+55
+00:04:46,060 --> 00:04:51,320
+الحقيقة على نقطة الاتزان، ولكن يقلل الزمن اللازم
+
+56
+00:04:51,320 --> 00:04:56,140
+للوصول إليها. هذا ما يتعلق بـ Le Chatelier. طبعًا الموضوع
+
+57
+00:04:56,140 --> 00:05:04,790
+مر معنا سابقًا. الآن خلينا نتكلم عن مفهوم، المفهوم
+
+58
+00:05:04,790 --> 00:05:08,530
+هذا هنتعرض له برضه خلال الفصل، ويكون له تطبيقات
+
+59
+00:05:08,530 --> 00:05:13,330
+مهمة عندنا، اللي هو stepwise equilibrium constant.
+
+60
+00:05:15,410 --> 00:05:20,130
+في الحقيقة، بعض الـ equilibria، بعض الاتزانات، تتم
+
+61
+00:05:20,130 --> 00:05:24,550
+ بخطوة واحدة، زي مثلًا اتزان الـ acetic acid. آه والله،
+
+62
+00:05:24,550 --> 00:05:30,490
+بيتفكك لـ acetate جزئيًا، يعني، و H plus. مثلًا، هذا
+
+63
+00:05:30,490 --> 00:05:36,490
+اتزان خطوة واحدة. لكن في اتزانات أخرى تتم على عدة
+
+64
+00:05:36,490 --> 00:05:42,580
+خطوات. زي مثلًا الفوسفوريك أسيد. أول خطوة بيفقد بروتون،
+
+65
+00:05:42,580 --> 00:05:47,300
+وبيتحول لـ H2PO4 سالب. ثاني خطوة بيفقد كمان بروتون،
+
+66
+00:05:47,300 --> 00:05:53,560
+بيتحول لـ HPO42 سالب. ثالث خطوة بيفقد تلاتة بروتون،
+
+67
+00:05:53,560 --> 00:05:59,980
+أو بروتون إضافي، يعني بيتحول لـ PO43 سالب. مثلًا، فيه
+
+68
+00:05:59,980 --> 00:06:04,850
+هنا equilibria تتم بخطوة واحدة، وفيه equilibria
+
+69
+00:06:04,850 --> 00:06:09,390
+تتم بأكثر من خطوة. هنا بنتكلم عن الـ
+
+70
+00:06:09,390 --> 00:06:12,810
+equilibria اللي بتتم بأكثر من خطوة، وناخد مثال عام.
+
+71
+00:06:12,810 --> 00:06:20,560
+لو عندي equilibrium A to B، بيعطينا A زائد AB. بقول
+
+72
+00:06:20,560 --> 00:06:27,600
+تفكك الـ A to B تفكك أولي، فاعطانا A زائد AB. لهذا
+
+73
+00:06:27,600 --> 00:06:34,080
+التفكك بقدر أكتب equilibrium constant، يعني ثابت
+
+74
+00:06:34,080 --> 00:06:41,120
+اتزان. سواء A في الـ AB تركيزات على الـ A to B. طيب، الـ
+
+75
+00:06:41,120 --> 00:06:44,980
+AB هذا اللي طلع عندي في الخطوة الأولى، ممكن يتفكك
+
+76
+00:06:44,980 --> 00:06:51,480
+فيعطينا A زائد B. برضه هذا له ثابت اتزان. عبارة عن A
+
+77
+00:06:51,480 --> 00:06:56,820
+في B على الـ AB. تركيزات. طب، لو ضربنا K واحد في K
+
+78
+00:06:56,820 --> 00:07:01,600
+اتنين، هذه القيمة في هذه القيمة، بلاَحِظ بيطلع عندنا A
+
+79
+00:07:01,600 --> 00:07:10,020
+squared times B over A to B. كويس. طيب، إيش بيحصل لو
+
+80
+00:07:10,020 --> 00:07:14,400
+إن هذا الـ equilibrium اللي فوق، اتفكك بخطوة واحدة،
+
+81
+00:07:14,400 --> 00:07:17,160
+مش بخطوتين. خلينا نشوفه.
+
+82
+00:07:21,920 --> 00:07:27,280
+A to B أعطانا اتنين A، وأعطانا B. هي تفكك كامل. الآن
+
+83
+00:07:27,280 --> 00:07:36,220
+الـ K، A squared times B over A to B. هو نفس الشكل
+
+84
+00:07:36,220 --> 00:07:41,420
+اللي جبناه سابقًا. نفس هذا. معنى الكلام، التفكك اللي
+
+85
+00:07:41,420 --> 00:07:41,940
+عندي
+
+86
+00:07:45,140 --> 00:07:50,800
+K راح تساوي K واحد في K اتنين. وكأنه إذا كان عندي
+
+87
+00:07:50,800 --> 00:07:56,000
+multistep equilibria، أو stepwise equilibria، فحاصل
+
+88
+00:07:56,000 --> 00:07:59,720
+ضرب الـ equilibrium constants للخطوات المختلفة،
+
+89
+00:07:59,720 --> 00:08:04,740
+يساوي الـ equilibrium constant للخطوة المحصلة. فلو
+
+90
+00:08:04,740 --> 00:08:08,600
+كان عندي حاجة مثلًا زي الـ phosphoric acid، شفناها.
+
+91
+00:08:08,600 --> 00:08:13,590
+إيه؟ K واحد، و K اتنين، و K تلاتة. لو إن الفوسفوريك أسيد
+
+92
+00:08:13,590 --> 00:08:19,710
+اتفكك مرة واحدة لـ 3H plus زائد فوسفيت، هلاحظ إن الـ
+
+93
+00:08:19,710 --> 00:08:25,990
+K لهذه الخطوة بتساوي K1 K2 K3. هنشوف في الحقيقة
+
+94
+00:08:25,990 --> 00:08:30,030
+تفاصيل هذا الكلام لكن في المستقبل. الآن مجرد
+
+95
+00:08:30,030 --> 00:08:34,350
+إشارة، هتيجي تطبيقاتها في المستقبل.
+
+96
+00:08:36,280 --> 00:08:41,300
+الآن، بشكل أساسي، محاضرة اليوم عايزين نطلع على الـ
+
+97
+00:08:41,300 --> 00:08:47,880
+calculations باستخدام الـ equilibrium constants.
+
+98
+00:08:47,880 --> 00:08:53,440
+يعني الـ equilibrium calculations. وبقول في هذه الـ...
+
+99
+00:08:53,440 --> 00:08:56,920
+...أو في هذا الموضوع تحديدًا، إحنا اتكلمنا الحصة
+
+100
+00:08:56,920 --> 00:09:02,210
+الماضية عن تقسيم الـ equilibrium constants لقسمين:
+
+101
+00:09:02,210 --> 00:09:06,790
+إما equilibrium constant كبير، أو equilibrium
+
+102
+00:09:06,790 --> 00:09:12,490
+constant مش كبير. مش كبير. فعملناهم بس حاجتين: يا
+
+103
+00:09:12,490 --> 00:09:16,550
+كبير، يا مش كبير. كبير يعني أكبر من 10 أس -2.
+
+104
+00:09:16,550 --> 00:09:21,250
+مش كبير، أقل من 10 أس -2. بغض النظر هل هو very
+
+105
+00:09:21,250 --> 00:09:25,800
+small، أو متوسط. الآن، بس بدي أطلع أنا على المنهجية في
+
+106
+00:09:25,800 --> 00:09:29,440
+الحل، منهجية الحل. بقول: مفتاح حل أي مسألة
+
+107
+00:09:29,440 --> 00:09:34,940
+equilibrium، أي مسألة اتزان، مفتاح الحل يكمن في قيمة
+
+108
+00:09:34,940 --> 00:09:38,200
+الـ equilibrium constant. يعني أنا عشان أحل أي مسألة
+
+109
+00:09:38,200 --> 00:09:42,340
+اتزان، بتطلع على قيمة الـ equilibrium constant. إذا
+
+110
+00:09:42,340 --> 00:09:46,980
+كان الـ equilibrium constant very small، كويس،
+
+111
+00:09:46,980 --> 00:09:53,800
+معناته تقريبًا المتفاعلات باقية على ما هي عليه، لم
+
+112
+00:09:53,800 --> 00:10:00,300
+تتحول إلى نواتج إلا بكميات مهملة، مقدارها X. يعني
+
+113
+00:10:00,300 --> 00:10:06,110
+كمية المتفاعلات التي تحولت إلى نواتج هي كمية قليلة
+
+114
+00:10:06,110 --> 00:10:10,870
+جدًا، مقدارها X، وهي مهملة إذا ما قورنت بكمية
+
+115
+00:10:10,870 --> 00:10:14,990
+المتفاعلات المتبقية. يعني كل المتفاعلات ضايْلة
+
+116
+00:10:14,990 --> 00:10:18,830
+تقريبًا زي ما هي. إيش اللي اتحول منها؟ X، وهي كمية
+
+117
+00:10:18,830 --> 00:10:26,610
+مهملة بالنسبة لإيه؟ للمتفاعلات. هذا الكلام لو
+
+118
+00:10:26,610 --> 00:10:31,330
+كان الـ equilibrium constant very large، معناته إيه؟
+
+119
+00:10:31,330 --> 00:10:36,920
+معناته أنه تقريبًا كل المتفاعلات تحولت إلى نواتج،
+
+120
+00:10:36,920 --> 00:10:44,980
+وتبقى من المتفاعلات كمية قليلة، مقدارها X، لا تقارن
+
+121
+00:10:44,980 --> 00:10:48,580
+بالنواتج. هي كمية مهملة، إذا ما قارناها بالنسبة
+
+122
+00:10:48,580 --> 00:10:50,260
+ لإيش؟ للنواتج.
+
+123
+00:10:52,590 --> 00:10:56,030
+الحالة الثالثة، إذا كان الـ equilibrium constant
+
+124
+00:10:56,030 --> 00:11:02,490
+متوسط. في هذه الحالة بنقول في عندي كمية appreciable،
+
+125
+00:11:02,490 --> 00:11:10,170
+يعني كمية محسوسة من المتفاعلات، وأيضًا عندي كمية
+
+126
+00:11:10,170 --> 00:11:14,910
+محسوسة من النواتج. عشان هيك، يعني في الحقيقة ما بقدرش
+
+127
+00:11:14,910 --> 00:11:18,580
+أقول واحدة أكثر من الثانية بشكل كبير خالص، أو واحدة
+
+128
+00:11:18,580 --> 00:11:23,860
+يعني اتكولت بشكل مهمل. ما بقدرش. لكن كطريقة حل، بدي أحط
+
+129
+00:11:23,860 --> 00:11:28,120
+هذا النوع من المسائل مع الحالة الأولى، اللي هي
+
+130
+00:11:28,120 --> 00:11:35,640
+وكأنه، وكأنه كمية المتفاعلات التي تحولت إلى نواتج
+
+131
+00:11:36,380 --> 00:11:40,300
+كمية مهملة، X، لا تكاد تذكر. يعني نفس الحالة الأولى
+
+132
+00:11:40,300 --> 00:11:47,260
+تمامًا في الحل. لكن كناحية عملية، لأ، مش صحيح الكلام
+
+133
+00:11:47,260 --> 00:11:51,320
+هذا. وإن كان في الحل أبسط طريقة لحلها هو أنه نـ
+
+134
+00:11:51,320 --> 00:11:56,760
+ نعتبر أنه يعني كمية المتفاعلات اللي اتحولت لنواتج
+
+135
+00:11:56,760 --> 00:12:01,640
+مهملة، كمية قليلة، X، لا تكاد تذكر. لما أقول هيك يعني
+
+136
+00:12:01,640 --> 00:12:05,890
+والله أنا بعتبر هذا الكلام. ولما أقول بدي أفترض أن
+
+137
+00:12:05,890 --> 00:12:09,110
+كمية النواتج أكبر كتير من المتفاعلات، أو كمية
+
+138
+00:12:09,110 --> 00:12:12,670
+المتفاعلات أكبر كتير من النواتج، بقول: هذه فرضيات،
+
+139
+00:12:12,670 --> 00:12:15,590
+هذه فرضيات. أي واحد ممكن يقول والله أنا بفترض كذا،
+
+140
+00:12:15,590 --> 00:12:19,690
+لكن المشكلة مش في الفرضية، المشكلة أن الفرضية
+
+141
+00:12:19,690 --> 00:12:23,210
+يجب أن تقترن بتحقيق الفرضية. يعني أنت افترضت أي
+
+142
+00:12:23,210 --> 00:12:27,670
+شيء، لازم في الحل أتحققه. إذا كان ما قدرت تثبت أن
+
+143
+00:12:27,670 --> 00:12:30,950
+والله بالفعل مثلًا النواتج أكبر كتير من المتفاعلات،
+
+144
+00:12:30,950 --> 00:12:34,440
+أو المتفاعلات أكبر كتير من النواتج، إذا كان ما قدرتش
+
+145
+00:12:34,440 --> 00:12:37,540
+تثبت هذا الكلام، أو طلع معاك عكسه، لازم تقول: آه،
+
+146
+00:12:37,540 --> 00:12:41,620
+والله فرضيتي غلط، وترجع للحل من الأول خالص. هنشوف
+
+147
+00:12:41,620 --> 00:12:49,260
+أمثلة على هذا الكلام. طيب، تعالوا نطلع على بعض
+
+148
+00:12:49,260 --> 00:12:51,040
+الأمثلة العملية.
+
+149
+00:12:53,590 --> 00:12:58,170
+الآن في عندنا مثال كثير بسيط، بيقول: Calculate the
+
+150
+00:12:58,170 --> 00:13:02,950
+equilibrium concentration of A and B in a 0.1
+
+151
+00:13:02,950 --> 00:13:06,290
+molar solution of weak electrolyte AB. يعني عندي AB
+
+152
+00:13:06,290 --> 00:13:10,990
+هذا weak electrolyte بيتفكك، بيعطيني A و B. فعايز يحسب
+
+153
+00:13:10,990 --> 00:13:17,740
+تركيزات A و B في 0.1 molar AB. بقول: إيش if the
+
+154
+00:13:17,740 --> 00:13:21,040
+equilibrium constant of the reaction is 3 في 10
+
+155
+00:13:21,040 --> 00:13:25,640
+أس سالب 6. إيش رأيكم في الـ equilibrium constant هذا؟
+
+156
+00:13:25,640 --> 00:13:30,400
+مفتاح الحل: صغير. معنى الكلام إيش؟ يعني صغير، معناته
+
+157
+00:13:30,400 --> 00:13:33,560
+أنه، معناته ببساطة أنه
+
+158
+00:13:35,860 --> 00:13:38,700
+تقريبًا المتفاعلات، حتى الـ AB اللي هي راح تتفكك،
+
+159
+00:13:38,700 --> 00:13:43,400
+بمقدار ضئيل جدًا، مقداره X. والـ X هذه كمية مهملة إذا
+
+160
+00:13:43,400 --> 00:13:47,400
+ما قورنت بالـ 0.1، بكمية المتفاعلات الأصلية. ليه؟ لأن
+
+161
+00:13:47,400 --> 00:13:50,560
+الـ equilibrium constant صغير. فبالتالي، المتفاعلات
+
+162
+00:13:50,560 --> 00:13:54,120
+آه، هيتحول جزء منها لنواتج، لكن هذا الجزء إيش
+
+163
+00:13:54,120 --> 00:13:58,640
+مقداره؟ X، وهو كمية صغيرة جدًا، مهملة إذا ما قورنت بالـ
+
+164
+00:13:58,640 --> 00:14:02,980
+0.1 اللي هو تركيز المتفاعلات. إحنا كيف بنحل المسائل
+
+165
+00:14:02,980 --> 00:14:07,660
+هذه عشان نكون عمليين؟ بنقول: في البداية بنعمل جدول
+
+166
+00:14:07,660 --> 00:14:12,160
+زي اللي قدامكم في النص. الـ equation، أو معادلة
+
+167
+00:14:12,160 --> 00:14:20,800
+التفاعل. AB بتعطينا A و B. في السطر اللي فوق بنحط
+
+168
+00:14:20,800 --> 00:14:28,100
+التركيزات قبل الاتزان. قبل الاتزان: AB واحد من عشرة،
+
+169
+00:14:28,100 --> 00:14:33,300
+A صفر، B صفر. ما فيش عندك كمية من A، أو كم
+
+223
+00:18:30,030 --> 00:18:41,640
+تقريبا 6 من 10%، طيب هل هذا الخطأ النسبي معتبر، أم يمكن اهماله ونعتبر شغلنا صحيح؟
+
+224
+00:18:41,640 --> 00:18:46,340
+بنقول هذا يعتمد على
+
+225
+00:18:46,340 --> 00:18:50,180
+أيّ معيار لدينا؟ المعيار
+
+226
+00:18:50,180 --> 00:18:54,680
+الذي لدينا هو 5%، أي خطأ أقل من
+
+227
+00:18:54,680 --> 00:18:57,720
+5% نعتبره خطأً محتملًا، يعني
+
+228
+00:18:57,720 --> 00:19:02,730
+خطأ، لكنه خطأ محتمل. طبعاً الـ 5%
+
+229
+00:19:02,730 --> 00:19:08,550
+هذا ليس شيئاً مُنَزَّلاً، ليس شيئاً ثابتاً، ليس شيئاً يعني منصوصاً عليه
+
+230
+00:19:08,550 --> 00:19:14,330
+وخلاص في أي نظام علمي أو في أي مختبر أو في أي شركة.
+
+231
+00:19:14,330 --> 00:19:17,950
+لا، هذا الـ 5% نحن نعتبره في معظم كتب
+
+232
+00:19:17,950 --> 00:19:20,850
+الكيمياء التحليلية، في معظم مساقات الكيمياء التحليلية.
+
+233
+00:19:20,850 --> 00:19:26,800
+لكن ممكن تشتغل في شركة تعتمد 5% مثلاً، يعني لو
+
+234
+00:19:26,800 --> 00:19:31,320
+اشتغلت في شركة Samsung أو Nokia أو ما شابه، التي
+
+235
+00:19:31,320 --> 00:19:35,440
+تعمل جوالات،  لا تعتمد نسبة خطأ 5%، يعني كل 100 جوال
+
+236
+00:19:35,440 --> 00:19:39,560
+يريدون أن يُخرجوا خمسة خربانة، هذه مشكلة كبيرة، غير مضبوط.
+
+237
+00:19:39,560 --> 00:19:45,200
+فممكن يعتمدوا على مثلاً جزء من المليون مثلاً.
+
+238
+00:19:45,200 --> 00:19:48,480
+فإنّ حتى في الكيمياء التحليلية حسب الشركة، ممكن
+
+239
+00:19:48,480 --> 00:19:50,780
+الشركة تقول أقصى نسبة خطأ عندي 1%.
+
+240
+00:19:50,780 --> 00:19:55,500
+نسبة خطأ غير ذلك، لا، أشتغل بحل المسألة حل عادي
+
+241
+00:19:55,500 --> 00:20:00,720
+بدون أي فرضيات، اعتبر فرضيتك خاطئة، وهذا الكلام تتأكد
+
+242
+00:20:00,720 --> 00:20:05,060
+من الشركة أو المكان الذي تشتغل فيه، إذا ما هي نسبة
+
+243
+00:20:05,060 --> 00:20:07,580
+الخطأ المسموح بها، لكن نحن عادةً في الكيمياء
+
+244
+00:20:07,580 --> 00:20:11,220
+التحليلية نشتغل على أساس نسبة خطأ 5%.
+
+245
+00:20:12,820 --> 00:20:16,820
+أكثر من 5% يعني هذا شيء يُعتَبر غير صحيح.
+
+246
+00:20:16,820 --> 00:20:21,020
+أقل من 5% يُعتَبر خطأً محتملًا. طيب، بما أن
+
+247
+00:20:21,020 --> 00:20:24,260
+طلع أن الخطأ جيد، ليس لدينا مشكلة فيه، يعني
+
+248
+00:20:24,260 --> 00:20:29,200
+فنقول إنّ A تساوي 5.5 × 10<sup>−4</sup>
+
+249
+00:20:29,200 --> 00:20:33,620
+وB لأنها X،  B أيضاً تساوي X، يعني 5.5 × 10<sup>−4</sup>
+
+250
+00:20:33,620 --> 00:20:39,600
+و AB = 10<sup>−1</sup> − X، لكن لا أحد
+
+251
+00:20:39,600 --> 00:20:44,180
+يهتمّ بـ X لأنّه صغير جداً، نحن حققنا الفرضية وقلنا
+
+252
+00:20:44,180 --> 00:20:47,960
+أنّ X أقل بكثير من 10<sup>−1</sup>، فهي تُعتَبَر
+
+253
+00:20:47,960 --> 00:20:51,600
+10<sup>−1</sup> أيضاً. إذا كنتَ تريد التأكد والاستفادة و
+
+254
+00:20:51,600 --> 00:20:55,140
+الاستمتاع بالمعلومات التي أخذتها سابقاً، حاول الاعتماد على
+
+255
+00:20:55,140 --> 00:20:59,260
+الآلة الحاسبة، لكن إشتغل significant figures، و اجعل
+
+256
+00:20:59,260 --> 00:21:02,780
+هدفك رقمين فقط، فتُصبح عندك أيضاً 10<sup>−1</sup>
+
+257
+00:21:02,780 --> 00:21:06,250
+إذا كنتَ إستخدمت significant figures، سيُصبح معك
+
+258
+00:21:06,250 --> 00:21:11,970
+مرة أخرى 10<sup>−1</sup>. طيب، نأتي لننظر في المثال التالي.
+
+259
+00:21:11,970 --> 00:21:18,590
+المثال يقول: In the reaction A + B يعطينا C
+
+260
+00:21:18,590 --> 00:21:27,150
++ D, if 0.2 moles of A.  أنتَ تقول مول، وليس
+
+261
+00:21:27,150 --> 00:21:32,670
+مولاري، أنا يهمني التركيز، لا يهمني عدد المولات. طيب، of A is
+
+262
+00:21:32,670 --> 00:21:38,990
+mixed with 0.5 mol of B in one liter. طيب، بما أن
+
+263
+00:21:38,990 --> 00:21:41,650
+خلاص،  يبقى هذا مولارية، لأن عدد المولات في اللتر
+
+264
+00:21:41,650 --> 00:21:45,250
+خلاص، الحمد لله تخلصنا من الحسابات، لكن لو أعطاني أي
+
+265
+00:21:45,250 --> 00:21:49,030
+حجم آخر، سأقسم على الحجم باللتر لأحصل على الـ
+
+266
+00:21:49,030 --> 00:21:52,650
+مولارية التي سأستخدمها بعد قليل في بناء الجدول.
+
+267
+00:21:53,140 --> 00:21:56,500
+يقول: Find the equilibrium concentrations of A, B,
+
+268
+00:21:56,680 --> 00:22:04,120
+C and D.  يُريد تركيزات جميع المواد عند الاتزان،  يُعطينا
+
+269
+00:22:04,120 --> 00:22:08,080
+ثابت الاتزان K لهذا التفاعل = 4 × 10<sup>−9</sup>
+
+270
+00:22:08,080 --> 00:22:12,920
+مفتاح الحل أعطاني المفتاح 4 × 10<sup>−9</sup>.
+
+271
+00:22:12,920 --> 00:22:18,060
+ماذا ترون؟ طبعاً صغير جداً، صغير جداً، معنى
+
+272
+00:22:18,060 --> 00:22:23,400
+الكلام، المتفاعلات ستبقى على حالها، كمية قليلة جداً
+
+273
+00:22:23,400 --> 00:22:28,380
+مقدارها X هي التي ستتحول إلى نواتج. طيب،  لِعَلى
+
+274
+00:22:28,380 --> 00:22:35,220
+هذا السبب نبني الجدول، المعادلة A + B ← C + D، 2 من 10 مولاري
+
+275
+00:22:35,220 --> 00:22:40,360
+B 5 من 10 مولاري، C 0، D 0. هذا قبل الاتزان، بعد
+
+276
+00:22:40,360 --> 00:22:45,860
+الاتزان، A سينقص مقداراً قليلاً مقداره X، B
+
+277
+00:22:45,860 --> 00:22:50,320
+سينقص مقداراً قليلاً مقداره X، C سيتكون منه X
+
+278
+00:22:50,320 --> 00:22:56,000
+و D أيضاً سيتكون منه X. الآن نعمل تعبير
+
+279
+00:22:56,000 --> 00:23:00,490
+ثابت الاتزان،  K = C ×
+
+280
+00:23:00,490 --> 00:23:05,110
+D / A × B، مع كلام X × X / 0.2 −
+
+281
+00:23:05,110 --> 00:23:11,450
+X × 0.5 − X. والآن سأفترض افتراضاً، سأقول سأهمل
+
+282
+00:23:11,450 --> 00:23:14,650
+X، سأفترض أن 0.2 أكبر بكثير من X، و أن
+
+283
+00:23:14,650 --> 00:23:20,690
+0.5 أكبر بكثير من X. الأقل نفترض أنّ 0.2
+
+284
+00:23:20,690 --> 00:23:25,210
+أكبر بكثير من X. دائماً الأقل، لماذا؟ من أجل البساطة.
+
+285
+00:23:25,210 --> 00:23:28,250
+إذا كان 0.2 أكبر بكثير من X التي هي
+
+286
+00:23:28,250 --> 00:23:31,670
+القيمة الصغيرة، فمن الطبيعي أن 0.5 ستكون
+
+287
+00:23:31,670 --> 00:23:36,790
+أكبر بكثير من X، فغالباً نختار ماذا؟ الأقل. نفترض
+
+288
+00:23:36,790 --> 00:23:40,730
+أنّه نفترض 0.2 أكبر بكثير من X، إذن راحت
+
+289
+00:23:40,730 --> 00:23:45,240
+الـ X هذه و راحت الـ X هذه. الآن التعبير ثابت
+
+290
+00:23:45,240 --> 00:23:47,300
+الاتزان يساوي X<sup>2</sup> / 0.
+
+291
+00:23:47,300 --> 00:23:50,540
+2 × 0.5، ومنها X = 2 × 10<sup>−5</sup>
+
+292
+00:23:50,540 --> 00:23:56,780
+لسه ما عملت شيء، لازماً فوراً أتحقق من
+
+293
+00:23:56,780 --> 00:24:02,520
+الفرضية، لازماً أتحقق من الفرضية، فأقسِم X على ماذا؟
+
+294
+00:24:02,520 --> 00:24:05,720
+على 0.2 × 100% لأحصل على
+
+295
+00:24:05,720 --> 00:24:10,550
+الخطأ النسبي، يطلع 1%، يُعتَبَر خطأً
+
+296
+00:24:10,550 --> 00:24:15,870
+قليل جداً. إذاً A تساوي 0.2 − X، وطبعاً
+
+297
+00:24:15,870 --> 00:24:20,390
+رأينا أنّ X هذا نهمله، 0.2، الـ B
+
+298
+00:24:20,390 --> 00:24:25,110
+0.5 − X نهمل الـ X، يعني 0.5، الـ C و
+
+299
+00:24:25,110 --> 00:24:30,290
+الـ D كل واحدة فيهم X، يعني 2 × 10<sup>−5</sup>. هذه
+
+300
+00:24:30,290 --> 00:24:34,790
+طريقة حل المسائل عندما يكون لدينا ثابت الاتزان
+
+301
+00:24:34,790 --> 00:24:41,410
+صغير، ليس كبيراً، قليل، معظم عملنا على أو
+
+302
+00:24:41,410 --> 00:24:45,670
+باستخدام هذا المفهوم، معظم عملنا. لكن لدينا
+
+303
+00:24:45,670 --> 00:24:51,630
+فصل يُعطينا ثابت اتزان كبير جداً،
+
+304
+00:24:51,630 --> 00:24:56,210
+سنرى بعض الأمثلة كيف نحلّ المسائل إذا كان
+
+305
+00:24:56,210 --> 00:25:04,380
+ثابت الاتزان كبيراً جداً، very large، سنأخذ
+
+306
+00:25:04,380 --> 00:25:06,720
+نفس المثال الذي درسناه قبل قليل، نقول: In the
+
+307
+00:25:06,720 --> 00:25:12,760
+reaction A + B يعطينا C + D. نقول: If 0.2 mol
+
+308
+00:25:12,760 --> 00:25:16,580
+of A is mixed with 0.5 mol of B in one liter. نفس
+
+309
+00:25:16,580 --> 00:25:20,100
+المثال، Find the equilibrium concentrations of A, B,
+
+310
+00:25:20,100 --> 00:25:23,400
+C and D. The equilibrium constant of the reaction
+
+311
+00:25:23,400 --> 00:25:30,240
+is 4 × 10<sup>8</sup>.  يعني ماذا؟ يعني كبير جداً.
+
+312
+00:25:30,240 --> 00:25:34,500
+ماذا يعني كبير جداً؟  معناه أنّ جميع المتفاعلات
+
+313
+00:25:34,500 --> 00:25:39,840
+ستتحول إلى نواتج إلا جزء يسير مقداره X يمكن إهماله
+
+314
+00:25:39,840 --> 00:25:44,060
+إذا ما قورن بالنواتج. طيب، نرى كيف نُترجِم هذا الكلام.
+
+315
+00:25:44,060 --> 00:25:50,130
+نذهب إلى جدولنا، المعادلة في الأعلى، التركيزات قبل
+
+316
+00:25:50,130 --> 00:25:54,490
+الاتزان فوق، التركيزات بعد الاتزان تحت، لدينا
+
+317
+00:25:54,490 --> 00:25:59,430
+المعادلة A + B يعطينا C + D، A كانت 0.2 مولاري، B
+
+318
+00:25:59,430 --> 00:26:06,750
+كانت 0.5 مولاري، C صفر، D صفر.  واضحٌ لي أنّ
+
+319
+00:26:06,750 --> 00:26:12,070
+المول الواحد من A يتفاعل مع مول واحد من B، إذن الـ 0.2 مول
+
+320
+00:26:12,070 --> 00:26:13,750
+من A، كم سيتفاعل من B؟
+
+321
+00:26:16,910 --> 00:26:20,290
+الواحد يتفاعل مع واحد، الـ 0.2 مع كم؟
+
+322
+00:26:20,290 --> 00:26:24,330
+سيتفاعل مع 0.2، طبعاً ليس مع 0.5.
+
+323
+00:26:24,330 --> 00:26:28,390
+لنفترض أنّ ليس لدينا 0.5، لدينا 100 مول، 100
+
+324
+00:26:28,390 --> 00:26:32,950
+مولاري من B،  الـ 0.2 مول من A سيتفاعل مع
+
+325
+00:26:32,950 --> 00:26:37,470
+ماذا؟ سيتفاعل مع 0.2. واضحٌ، واحد لواحد، التفاعل واحد
+
+326
+00:26:37,470 --> 00:26:41,170
+لواحد، فـ 0.2 سيتفاعل مع 0.2،
+
+327
+00:26:41,170 --> 00:26:46,290
+وماذا سيزيد من 0.5؟ 0.3. يعني
+
+328
+00:26:46,290 --> 00:26:51,290
+وكأنه هذه كتبتها أنا: 0.2 + 0.3 = 0.5،  الـ 0.2 هذه
+
+329
+00:26:51,290 --> 00:26:56,270
+سيتفاعل مع 0.2 هذه، ويعطينا النواتج، ماذا سيزيد
+
+330
+00:26:56,270 --> 00:27:03,630
+من B؟ B موجودة بزيادة، B موجود 0.5،
+
+331
+00:27:03,630 --> 00:27:07,770
+منها تفاعل 0.2، بقي 0.3. الـ A
+
+332
+00:27:07,770 --> 00:27:12,800
+سينقص منها X،  الـ B 0.3 هذه زائدة، زائدة
+
+333
+00:27:12,800 --> 00:27:17,360
+و X التي زادت من التفاعل. من التفاعل، الـ 0.2
+
+334
+00:27:17,360 --> 00:27:21,840
+مع 0.2 تفاعلت، وزاد من هذه X، ومن
+
+335
+00:27:25,400 --> 00:27:30,880
+هذه X،  الـ B 0.2. جميع المتفاعلات 0.2
+
+336
+00:27:30,880 --> 00:27:35,000
+ستعطينا 0.2 لأنّ المول الواحد من A يعطي
+
+337
+00:27:35,000 --> 00:27:39,020
+مول واحد من C، يعطي مول واحد من D، إذن الـ 0.2
+
+338
+00:27:39,020 --> 00:27:43,960
+ستعطينا 0.2 و 0.2.  يبقى 0.2 − X، جميع
+
+339
+00:27:43,960 --> 00:27:47,500
+المتفاعلات تحوّلت إلى نواتج ما عدا كمية قليلة
+
+340
+00:27:47,500 --> 00:27:55,220
+مقدارها X. يبقى 0.2 − X، 0.2 − X. يبقى
+
+341
+00:27:55,220 --> 00:27:59,950
+نأتي لننظر في ثابت الاتزان، C × D
+
+342
+00:27:59,950 --> 00:28:04,190
+/ A × B، الـ K أو ثابت الاتزان يريد
+
+343
+00:28:04,190 --> 00:28:09,630
+أن يساوي 0.2 − X × 0.2 − X التي هي C و D
+
+344
+00:28:09,630 --> 00:28:15,070
+الـ A التي هي X، الـ B التي هي 0.3 + X.  بناءً على
+
+345
+00:28:15,070 --> 00:28:20,800
+الفرضية، لأبسط المعادلة سأهمل كل شيء
+
+346
+00:28:20,800 --> 00:28:24,840
+أو الـ X المُضافة أو المطروحة، فأقول على أصغر شيء
+
+347
+00:28:24,840 --> 00:28:30,000
+موجود لديّ 0.2، إذن مُفترَض أنّ الـ 0.2 أكبر
+
+348
+00:28:30,000 --> 00:28:35,340
+بكثير من X، إذن هذه الـ X راحت، وهذه الـ X راحت، و
+
+349
+00:28:35,340 --> 00:28:39,820
+هذه الـ X لديّ أيضاً راحت. يبقى 4 × 10<sup>−9</sup> يساوي
+
+350
+00:28:39,820 --> 00:28:46,530
+0.04 / 0.3، X = 3.3 × 10<sup>−10</sup>
+
+351
+00:28:46,530 --> 00:28:50,410
+يبقى قيمة X = 3.3 × 10<sup>−10</sup>. فهل لأن
+
+352
+00:28:50,410 --> 00:28:59,030
+ثابت الاتزان صغير؟ لا، هو، لاحظ، لأنّ ثابت
+
+353
+00:28:59,030 --> 00:29:02,790
+الاتزان صغير، فهو سيتفاعل، X سيتفاعل مع X. معي؟ أنتَ
+
+354
+00:29:02,790 --> 00:29:09,070
+معي 0.3،  كما هي، X سيتفاعل مع X، ويعطينا X و X.  الـ
+
+355
+00:29:09,070 --> 00:29:17,130
+ثابت الاتزان هنا كان صغيراً، هنا كبيراً، يعني
+
+356
+00:29:17,130 --> 00:29:21,650
+هنا مثلاً، سؤالي، سؤالي، ماذا يقول؟  يقول: لماذا
+
+357
+00:29:21,650 --> 00:29:29,930
+قلنا في المثال هذا أنّ 0.2 تفاعلت مع
+
+358
+00:29:29,930 --> 00:29:38,070
+الـ ... مع الـ ... هنا، وكأنه نحن نقول: ماذا هنا؟ X
+
+359
+00:29:38,070 --> 00:29:41,990
+تفاعل مع X، أعطانا X و أعطانا X، صحيح؟ مثلاً، يعني هي
+
+360
+00:29:41,990 --> 00:29:49,150
+لدينا 0.2 كمية ضئيلة جداً من ستتفاعل.
+
+361
+00:29:49,150 --> 00:29:52,490
+ماذا يُكَبِّرُ كمية المتفاعلات؟ X،  الـ B كمية ضئيلة من
+
+362
+00:29:52,490 --> 00:29:57,470
+ستتفاعل، ماذا يقابلُ الكمية المتفاعلات؟ X،  أيضاً، هذا لأنّ
+
+363
+00:29:57,470 --> 00:30:01,130
+ثابت الاتزان ماذا به؟ ثابت
+
+364
+00:30:01,130 --> 00:30:04,890
+الاتزان صغير، لكن هنا ثابت الاتزان كبير
+
+365
+00:30:04,890 --> 00:30:07,970
+فـ X = 3.3 × 10<sup>−10</sup>
+
+366
+00:30:09,540 --> 00:30:12,260
+الآن يمكنني أن أقول أن نحسب الخطأ النسبي، لكن واضح
+
+367
+00:30:12,260 --> 00:30:17,100
+أنّ الخطأ النسبي ماذا سيكون؟ سيكون كمية، يعني
+
+368
+00:30:17,100 --> 00:30:19,800
+قليلة جداً،  الخطأ النسبي X / 0.2 × 100%
+
+369
+00:30:19,800 --> 00:30:23,880
+يطلع تقريباً 0.005%، معنى الكلام الافتراض صحيح، ليس لدينا
+
+370
+00:30:23,880 --> 00:30:30,580
+مشكلة فيه. A تساوي 3.3 × 10<sup>−10</sup>, B تساوي
+
+371
+00:30:30,580 --> 00:30:34,770
+0.3 ،  C و D 0.2.
+
+372
+00:30:34,770 --> 00:30:42,190
+أريد أن آخذ مثالاً عندما يكون ثابت الاتزان كبيراً،
+
+373
+00:30:42,190 --> 00:30:54,930
+وأحاول أن آخذ النسبة التكافؤية ليست واحد لواحد.
+
+374
+00:30:54,930 --> 00:31:04,100
+أن ننظر في نسب تكافؤية ليست واحد لواحد، فننظر
+
+375
+00:31:04,100 --> 00:31:10,520
+في المثال التالي، أقول: A و B يتفاعلان كالتالي، A
+
+376
+00:31:10,520 --> 00:31:18,180
++ 2B يعطينا 2C، أقول: Assume 0.1 mole of
+
+377
+00:31:18,180 --> 00:31:24,310
+A reacts with 0.2 mole of B in one liter، جيد.
+
+378
+00:31:24,310 --> 00:31:27,150
+جيد، أعطاني مولات لكن أعطاني الحجم لتر، يبقى خلصني
+
+379
+00:31:27,150 --> 00:31:30,950
+من حساب المولارية، لأن عدد المولات في
+
+380
+00:31:30,950 --> 00:31:35,310
+اللتر هي المولارية. خلاص أعطاني وكأنه مولارية،  فـ K
+
+381
+00:31:35,310 --> 00:31:39,150
+تساوي 1 × 10<sup>10</sup>،  ماذا ترون فيه؟ ضخم
+
+382
+00:31:39,150 --> 00:31:42,970
+جداً. Find the equilibrium concentrations of A, B and
+
+383
+00:31:42,970 --> 00:31:51,430
+C.  يُريد A يتفاعل مع 2B ويعطينا 2C، فيُريد أن يحسب في
+
+384
+00:31:51,430 --> 00:31:54,750
+النهاية عند الاتزان، كم تركيز A، كم
+
+445
+00:36:41,240 --> 00:36:45,820
+هي أنت طالع عايش فيها عندي هنا، point two minus الـ
+
+446
+00:36:45,820 --> 00:36:51,940
+2x أنا بأفترض إنه هدول الجلال صحيح ولا لأ؟ عشان أخلص
+
+447
+00:36:51,940 --> 00:36:55,400
+منهم لو فرضت أن الـ X point أكبر من X واحدة كان
+
+448
+00:36:55,400 --> 00:36:58,040
+يمكن إنه مش أكبر من الـ 2X لكن أنا ببدأ أفترض إنه
+
+449
+00:36:58,040 --> 00:37:03,560
+أكبر من الـ 2X صحيح ولا لأ؟ صحيح ولا لأ؟ فهي اللي حصل
+
+450
+00:37:03,560 --> 00:37:10,480
+طيب
+
+451
+00:37:10,480 --> 00:37:11,060
+يا شباب
+
+452
+00:37:14,570 --> 00:37:17,270
+بدل ما أعطيك مثال على نظرية خاطئة، بدي أعطيك برضه
+
+453
+00:37:17,270 --> 00:37:22,090
+خليني أقف عند هذه الـ slide، بدي أقول مثلاً لو كان
+
+454
+00:37:22,090 --> 00:37:29,390
+عندك هذه point six مش point two، بقول والله الآن
+
+455
+00:37:29,390 --> 00:37:33,670
+واضح أن الواحد من عشرة بتفعل بعد كده؟ 2 من 10، إذن
+
+456
+00:37:33,670 --> 00:37:37,090
+إيش بزيد؟ 4 من 10، يعني ممكن أكتب هذا 2 من 10 زائد
+
+457
+00:37:37,090 --> 00:37:45,240
+4 من 10، يبقى هذه بس هي اللي عاملة بتعملها، طيب لو
+
+458
+00:37:45,240 --> 00:37:49,240
+إيه؟
+
+459
+00:37:49,240 --> 00:37:53,600
+هو عايز يقول زائد، لأ، ما فعش، لأن كل اللي موجود
+
+460
+00:37:53,600 --> 00:37:58,080
+اتنين من عشرة منها، ما فعش يكون زائد، سالب، اه،
+
+461
+00:37:58,080 --> 00:37:58,500
+طيب
+
+462
+00:38:04,560 --> 00:38:08,440
+لأ، مش واحد من عشرة، لأن الواحد من عشرة بتفعل مع
+
+463
+00:38:08,440 --> 00:38:12,160
+اتنين من عشرة، الواحد من عشرة بتفعل مع اتنين من
+
+464
+00:38:12,160 --> 00:38:16,400
+عشرة، اتفهمت؟ عشان هي مكتوب اتنين من عشرة زائد أربعة
+
+465
+00:38:16,400 --> 00:38:18,860
+من عشرة، الاتنين من عشرة بتفعل مع الواحد من عشرة
+
+466
+00:38:18,860 --> 00:38:25,030
+والأربعة من عشرة بتنزل، ماشي يا شباب؟ بنيجي نطلع
+
+467
+00:38:25,030 --> 00:38:29,750
+الآن على فرض إنه في عندنا .. على فرض إنه في عندنا مثلاً
+
+468
+00:38:29,750 --> 00:38:35,850
+خمسة من عشرة و .. و اتنين من عشرة، إيش بده يكون في
+
+469
+00:38:35,850 --> 00:38:42,770
+عندي؟ كيف؟ مع عشرة بتطلع .. هي المعادلة اللي
+
+470
+00:38:42,770 --> 00:38:45,390
+عندك موجودة .. هذه مش خمسة .. مش واحد من عشرة ..
+
+471
+00:38:45,390 --> 00:38:49,470
+هذه خمسة من عشرة مولار و اتنين من عشرة .. انتبه
+
+472
+00:38:49,470 --> 00:38:50,810
+عليها شوية ..
+
+473
+00:38:53,340 --> 00:38:59,440
+كيف؟ أين هو؟ الاتنين من عشرة اجل ثلاثة من عشرة
+
+474
+00:38:59,440 --> 00:39:05,360
+زائد X و 2X، ثلاثة من عشرة زائد X، ليش ثلاثة من
+
+475
+00:39:05,360 --> 00:39:11,450
+عشرة؟ 4 من 10، ليش؟ لأن هذه الخمسة من عشرة أضارع عن
+
+476
+00:39:11,450 --> 00:39:15,910
+4 من 10 زائد 1 من 10، الواحد من عشرة بتفعل مع
+
+477
+00:39:15,910 --> 00:39:20,470
+الاتنين من عشرة، لأن الواحد بتفعل مع اتنين، إذن إيش
+
+478
+00:39:20,470 --> 00:39:27,470
+بده يكون موجود هنا؟ 4 من 10 زائد X، دخلت بالك؟ بدك
+
+479
+00:39:27,470 --> 00:39:32,570
+تعرف تدبر حالك في هذه التحويلات، هي شغل سهل مش صعب
+
+480
+00:39:32,570 --> 00:39:34,170
+يعني كيف؟
+
+481
+00:39:36,200 --> 00:39:39,580
+طيب يا سيد، إذا كان فيه تركيز، إنت يا سيد، مين يركز؟
+
+482
+00:39:39,580 --> 00:39:44,980
+لغة السؤال يكون
+
+483
+00:39:44,980 --> 00:39:49,660
+واضح، زي اللغة الموجودة قدامك واضحة جداً، يعني طيب
+
+484
+00:39:49,660 --> 00:39:52,600
+نيجي نطلع على آخر مثال يا شباب، و نعطيكم المثال اللي
+
+485
+00:39:52,600 --> 00:39:57,160
+بده يهمكم لما يكون الـ equilibrium constant يعني
+
+486
+00:39:57,160 --> 00:40:02,900
+متوسط، بنقول in the reaction، نحاول نختصر شوية، طيب
+
+487
+00:40:03,980 --> 00:40:08,320
+بنقول in the reaction A plus B بيعطينا C زائد D
+
+488
+00:40:08,320 --> 00:40:12,900
+وناخد نفس المتغيرات اللي أخذناها سابقاً، فبقول if 0.2
+
+489
+00:40:12,900 --> 00:40:18,380
+mole of A is mixed with 0.5 mole of B in one liter
+
+490
+00:40:18,380 --> 00:40:23,800
+بيقول find the concentration of A, B, C and D at
+
+491
+00:40:23,800 --> 00:40:26,020
+equilibrium، الـ equilibrium constant of the
+
+492
+00:40:26,020 --> 00:40:30,820
+reaction is ثلاثة من عشرة، بقول والله ثلاثة من عشرة
+
+493
+00:40:30,820 --> 00:40:34,260
+يعني هيكون appreciable amount من الـ reactants و
+
+494
+00:40:34,260 --> 00:40:38,820
+appreciable amount من الـ products، لكن في طريقة
+
+495
+00:40:38,820 --> 00:40:42,640
+الحل، إيش قلنا؟ بدنا نعتبر وكأنه
+
+496
+00:40:47,710 --> 00:40:53,890
+المتفاعلات بتبقى كما هي، وتتحول جزء يسير جداً منها
+
+497
+00:40:53,890 --> 00:40:54,810
+إلى نواتج
+
+498
+00:40:58,120 --> 00:41:00,740
+بتفترضش العكس، بقول لك طريقة الحل بالشكل اللي بقول لك
+
+499
+00:41:00,740 --> 00:41:05,460
+إياه، بتفترض إنه تنحل على الحالة الأولى، اللي هي
+
+500
+00:41:05,460 --> 00:41:08,700
+بتفترض إنه وكأنه الـ equilibrium constant، بتفترض إنه
+
+501
+00:41:08,700 --> 00:41:12,720
+مش كبير، يعني صغير جداً، مش كبير، يعني صغير جداً، نفس
+
+502
+00:41:12,720 --> 00:41:16,410
+الكلام اللي ذكرناه في الحالة الأولى، طيب نيجي نطلع
+
+503
+00:41:16,410 --> 00:41:22,030
+على الجدول، بنقول A و B بتعطينا C و D، point two
+
+504
+00:41:22,030 --> 00:41:25,350
+point five، قبل الـ equilibrium، بعد الـ equilibrium
+
+505
+00:41:25,350 --> 00:41:28,630
+بما إنه احنا في تربة، احنا في تربة أن الحل على
+
+506
+00:41:28,630 --> 00:41:31,890
+الحالة الأولى، يعني point two minus x، point five
+
+507
+00:41:31,890 --> 00:41:36,650
+minus x، يعني كأن المتفاعلات باقية زي ما هي، ولكن
+
+508
+00:41:36,650 --> 00:41:40,730
+اتحول جزء يسير جداً منها لنواتج، فبنقول بيعطينا X و
+
+509
+00:41:40,730 --> 00:41:43,590
+X، من هذا الكلام طبعاً شفنا المثال السابق كان كيف
+
+510
+00:41:43,590 --> 00:41:49,090
+بنحل، هو نفس الطريقة، K بتساوي C في الـ D على الـ A في
+
+511
+00:41:49,090 --> 00:41:54,410
+الـ B، X في X على 0.2 minus X، 0.5 minus X، نيجي نعمل
+
+512
+00:41:54,410 --> 00:41:59,830
+فرضية، بنختار الأصغر، 0.2 minus X، بدنا .. بنقول يعني
+
+513
+00:41:59,830 --> 00:42:05,040
+الـ 0.2 أكبر كتير من الـ X، إذن الـ 0.3 اللي هو الـ
+
+514
+00:42:05,040 --> 00:42:09,820
+equilibrium constant يساوي X تربيع على 0.2 times 0.5
+
+515
+00:42:09,820 --> 00:42:15,600
+الـ X بتطلع 0.17، الـ
+
+516
+00:42:15,600 --> 00:42:20,900
+X 0.17، احنا بدنا نجيب الـ relative error، فبنقول الـ
+
+517
+00:42:20,900 --> 00:42:26,920
+relative error 0.17 على 0.2 في 100 من 100 بتطلع 87
+
+518
+00:42:26,920 --> 00:42:33,320
+%، طبعاً 87% نسبة خطأ يعني هذا إيش لا يُغتفر، يعني خطأ
+
+519
+00:42:33,320 --> 00:42:38,680
+مش ممكن أي حد يرضى بنسبة خطأ 87%، فإيش بتقول على
+
+520
+00:42:38,680 --> 00:42:44,770
+طول، the assumption is invalid or unacceptable، غير
+
+521
+00:42:44,770 --> 00:42:50,450
+مقبول، غير صحيح، and we must not neglect X، وطبيعي
+
+522
+00:42:50,450 --> 00:42:54,010
+أنه لا يمكن أنه نلغي الـ X جانب الـ 2 من 10، in
+
+523
+00:42:54,010 --> 00:42:57,510
+comparison with 0.2، therefore the equilibrium
+
+524
+00:42:57,510 --> 00:43:02,090
+should be as follows، رجعناها زي أول و حلينا
+
+525
+00:43:02,090 --> 00:43:04,970
+المعادلة، يعني جمعناها و طلعنا الـ quadratic
+
+526
+00:43:04,970 --> 00:43:10,780
+equation، المعادلة التربيعية، وروحنا للقانون العام
+
+527
+00:43:10,780 --> 00:43:14,100
+اللي هي الـ X بتساوي ناقص B، الجذر التربيعي على B
+
+528
+00:43:14,100 --> 00:43:20,820
+squared ناقص 4AC على 2A، لما نحلها باستخدام
+
+529
+00:43:20,820 --> 00:43:24,880
+القانون، بيطلع عندي الـ X بقد ايش؟ واحد من عشرة، point one
+
+530
+00:43:24,880 --> 00:43:29,880
+one molar، طبعاً ما هي ما .. ما حنا قلنا ما بنعملهاش
+
+531
+00:43:29,880 --> 00:43:37,230
+ما بنعملهاش، لأ، كيف تعمل بنسبة لـ 0.2؟ زيها يعني
+
+532
+00:43:37,230 --> 00:43:43,410
+تقريباً نصها، فالـ A بتطلع 0.2 minus 0.11، بتطلع 0.09
+
+533
+00:43:43,410 --> 00:43:50,650
+الـ B بتطلع 0.5 minus 0.11، بتساوي 0.39، الـ C و الـ D
+
+534
+00:43:50,650 --> 00:43:56,790
+بتساوي 0.11 مولار، كل واحدة فيهم X، هذه هي
+
+535
+00:43:56,790 --> 00:44:00,150
+طريقة الحل يا شباب، لكن أنا بدي ألفت انتباهكم لنقطة
+
+536
+00:44:01,090 --> 00:44:06,470
+دائماً إذا كان الـ equilibrium constant مش كبير و مش
+
+537
+00:44:06,470 --> 00:44:12,290
+صغير، دائماً هتطلع الـ relative error عالية، وضع
+
+538
+00:44:12,290 --> 00:44:17,500
+طبيعي، وضع طبيعي، لأن كيف؟ نسبة الخطأ هتطلع أكثر من
+
+539
+00:44:17,500 --> 00:44:21,780
+5%، دائماً إذا كان إيه؟ إذا كان الـ equilibrium
+
+540
+00:44:21,780 --> 00:44:24,800
+constant لا هو كبير ولا هو صغير، فنسبة الخطأ دائماً
+
+541
+00:44:24,800 --> 00:44:29,960
+هتكون عالية، هتكون دائماً فيها مشكلة، يعني مش هتطلع
+
+542
+00:44:29,960 --> 00:44:34,460
+أقل من 5%، لأ، هتكون أكبر من 5%، وبالتالي يجب أن
+
+543
+00:44:34,460 --> 00:44:37,920
+الحل باستخدام الـ quadratic equation، لكن إحنا في
+
+544
+00:44:37,920 --> 00:44:41,900
+الحل إيش هنسوي؟ بمجرد ما يطلع عندنا الـ relative
+
+545
+00:44:41,900 --> 00:44:47,800
+error أكبر من 5% حسبناها، هنيجي إيش نقول؟ هنقول the
+
+546
+00:44:47,800 --> 00:44:52,220
+assumption is إيش؟ invalid or unacceptable
+
+547
+00:44:52,220 --> 00:44:58,390
+therefore، لهذا السبب، we should use the quadratic
+
+548
+00:44:58,390 --> 00:45:03,150
+equation، نقطة، نقطة، مش هنحل هذا الكلام، مش
+
+549
+00:45:03,150 --> 00:45:08,190
+هنطلع، مش هنطلع، يعني إيش بيسموها الـ quadratic
+
+550
+00:45:08,190 --> 00:45:11,970
+equation، يعني بنقف بس لهنا، مش هنطلع الـ X بهذه
+
+551
+00:45:11,970 --> 00:45:15,680
+الطريقة، مش هنحل الـ quadratic equation نفسها، لأ
+
+552
+00:45:15,680 --> 00:45:19,720
+إحنا بس هنوصل لهنا، طلعنا الـ relative error أكثر من
+
+553
+00:45:19,720 --> 00:45:23,680
+خمسة في المئة، إيش هنقول؟ هنقول the assumption is
+
+554
+00:45:23,680 --> 00:45:29,480
+invalid or unacceptable، therefore we should use
+
+555
+00:45:29,480 --> 00:45:34,100
+the quadratic equation، ونقطة، مش هنكمل حل المسألة
+
+556
+00:45:34,100 --> 00:45:37,900
+اه، مش هنكمل، بس هنيجي لهنا، إيه كويس؟ سواء كان في
+
+557
+00:45:37,900 --> 00:45:43,910
+إمتحان أو كان في واجب، يبقى مادام أكثر من 5%، انتهينا
+
+558
+00:45:43,910 --> 00:45:50,050
+طيب يا شباب، في حد عنده سؤال؟ هيك من الكلام خلصنا
diff --git a/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/j-9i1UBw5Do_raw.srt b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/j-9i1UBw5Do_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..c80e4a1460226b19dcff89b8099dbe02042cc558
--- /dev/null
+++ b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/j-9i1UBw5Do_raw.srt
@@ -0,0 +1,2232 @@
+1
+00:00:21,680 --> 00:00:26,040
+بسم الله الرحمن الرحيم طيب يا شباب بنكمل في ال
+
+2
+00:00:26,040 --> 00:00:31,160
+chapter الخاص بال equilibrium concepts فبنتكلم
+
+3
+00:00:31,160 --> 00:00:35,480
+اليوم عن .. بشكل أساسي بنتكلم عن ال equilibrium
+
+4
+00:00:35,480 --> 00:00:38,560
+calculations لكن قبل ما نروح لل calculations
+
+5
+00:00:38,560 --> 00:00:42,860
+تعالوا نتطلع شوية على Le Chatelier principle طبعا
+
+6
+00:00:42,860 --> 00:00:48,220
+هذه مفهوم مر معنا في سنة أولى كيميا عامة مفهوم Le
+
+7
+00:00:48,220 --> 00:00:53,880
+Chatelier كتير بسيطكتير بصير بنقول إنه إذا كان ..
+
+8
+00:00:53,880 --> 00:00:56,600
+كان في عندنا equilibrium ما و أثرنا عليه بمؤثر
+
+9
+00:00:56,600 --> 00:01:01,300
+خارجي فبنلاحظ إنه ال equilibrium بيمشي في اتجاه
+
+10
+00:01:01,300 --> 00:01:07,540
+بيحاول فيه تقليل تأثير المؤثر الخارجي فعلى سبيل
+
+11
+00:01:07,540 --> 00:01:17,170
+المثال لو كان في عندنا تفاعل ما في اتزانو أضفنا
+
+12
+00:01:17,170 --> 00:01:22,050
+كمية من المتفاعلات بنلاحظ إن التفاعل بيمشي للأمام
+
+13
+00:01:22,050 --> 00:01:26,350
+لو سحبنا كمية من النواتج برضه التفاعل بيمشي للأمام
+
+14
+00:01:26,350 --> 00:01:31,630
+لو أضفنا كمية من النواتج التفاعل بيمشي للخلف و
+
+15
+00:01:31,630 --> 00:01:38,250
+هكذا ففيه إنه تقريبا يعني أربع عوامل ممكن ندرسها و
+
+16
+00:01:38,250 --> 00:01:41,830
+ندرس تأثيرها على ال equilibrium أول حاجة أو أول
+
+17
+00:01:41,830 --> 00:01:47,220
+عامل مهم بالنسبة لنا اللي هو التركيزفبالطبع كما
+
+18
+00:01:47,220 --> 00:01:52,380
+ذكرت إذا كان زدنا من تركيز المتفاعلات بنلاحظ
+
+19
+00:01:52,380 --> 00:01:56,600
+التفاعل بيمشي للأمام إذا كان أخدنا جزء أو تخلصنا
+
+20
+00:01:56,600 --> 00:02:00,520
+من جزء من النواتج التفاعل برضه بيمشي للأمام إذا
+
+21
+00:02:00,520 --> 00:02:04,510
+كانزدنا تركيز النواتج التفاعل بيمشي للخلف هذا ما
+
+22
+00:02:04,510 --> 00:02:10,990
+يتعلق بالتركيز وحنشوف تطبيقات إله خلال الفصل إذا
+
+23
+00:02:10,990 --> 00:02:15,010
+الله راد العامل التاني اللي ممكن نتكلم عنه هو
+
+24
+00:02:15,010 --> 00:02:19,920
+حرارة مثلاالحرارة نلاحظ أن بعض التفاعلات بتكون
+
+25
+00:02:19,920 --> 00:02:25,100
+exothermic أو طاردة للحرارة بصاحبها تولد كمية من
+
+26
+00:02:25,100 --> 00:02:29,580
+الحرارة هذا النوع من التفاعلات لو سخناها يعني لو
+
+27
+00:02:29,580 --> 00:02:33,140
+زدنا الحرارة الأصل أنه التفاعل برجع للخلف لأن
+
+28
+00:02:33,140 --> 00:02:37,760
+الحرارة يمكن النظر إليها من النواتج إذا كانوا طارد
+
+29
+00:02:37,760 --> 00:02:42,160
+للحرارة فالنتج عنا أحد النواتج حرارة فمعناه كلام
+
+30
+00:02:42,160 --> 00:02:46,080
+إذا كان زدنا من النواتج لي الحرارة بنلاحظ أن
+
+31
+00:02:46,080 --> 00:02:50,520
+التفاعلبيمشي للخلف عكس هذا الكلام لو كان التفاعل
+
+32
+00:02:50,520 --> 00:02:54,320
+معصد الحرارة وزيدنا درجة الحرارة التفاعل بده حرارة
+
+33
+00:02:54,320 --> 00:03:00,580
+فالتفاعل بيمشي للأمام العامل التالت عادة احنا
+
+34
+00:03:00,580 --> 00:03:05,420
+مابنحكيش فيه بالنسبة للكيمة التحليلية لأنه بيتعلق
+
+35
+00:03:05,420 --> 00:03:13,200
+بالضغطبنقول إنه تأثير الضغوط على السوائل عادة يعني
+
+36
+00:03:13,200 --> 00:03:16,880
+شبه معدوم، لا يؤثر على السوائل أو على الصلب، الضغط
+
+37
+00:03:16,880 --> 00:03:20,880
+مهم بس في حالة الغازات، واحنا خلال الفصل هذا أو ال
+
+38
+00:03:20,880 --> 00:03:26,420
+course هذا بندرس المحاليل وال solids، لا ندرس يعني
+
+39
+00:03:26,420 --> 00:03:30,480
+الصلب، لا ندرس الصلب وبالتالي الضغطيعني عامل من
+
+40
+00:03:30,480 --> 00:03:33,940
+العوامل اللي عادة إحنا بندرسهاش وبتالي تأثيرها
+
+41
+00:03:33,940 --> 00:03:39,080
+very marginal أو غير مهم فيما يتعلق بنوعية
+
+42
+00:03:39,080 --> 00:03:43,420
+المحاليل اللي إحنا بندرسها العامل الرابع اللي ممكن
+
+43
+00:03:43,420 --> 00:03:46,340
+نتكلم عنه اللي هو وجود catalyst أو استخدام
+
+44
+00:03:46,340 --> 00:03:52,660
+catalyst أو عامل مساعد أو عامل حفازعادة وجود أو
+
+45
+00:03:52,660 --> 00:04:00,700
+استخدام عامل حفاز يسرع التفاعل بمعنى هو يقلل الزمن
+
+46
+00:04:00,700 --> 00:04:05,280
+اللازم للوصول إلى نقطة الإتزان لكنه لا يؤثر فيها
+
+47
+00:04:05,280 --> 00:04:12,160
+كيف؟ يعني مثلا عندي equilibrium يستغرق مثلا ساعة
+
+48
+00:04:13,650 --> 00:04:18,810
+عشان يصل لحالة الإتزان بقول ماشي لو استخدمنا عامل
+
+49
+00:04:18,810 --> 00:04:22,950
+حفاظ ممكن مثلا ياخد دقيقة عشان يوصل لحالة الإتزان
+
+50
+00:04:22,950 --> 00:04:26,730
+لكن لو شوفنا قيمة ال equilibrium constant بنلاحظ
+
+51
+00:04:26,730 --> 00:04:30,830
+ان هي هي لو شوفنا جداش عنا متفاعلات جداش عنا نواتج
+
+52
+00:04:30,830 --> 00:04:35,860
+نفسها في الحالتين لكنالزمن اللازم للوصول إلى نقطة
+
+53
+00:04:35,860 --> 00:04:40,360
+الإتزان بيكون قل بشكل كبير في وجود ال catalyst هذا
+
+54
+00:04:40,360 --> 00:04:46,060
+يعني مفهوم ال catalyst فال catalyst لا يؤثر في
+
+55
+00:04:46,060 --> 00:04:51,320
+الحقيقة على نقطة الإتزان ولكن يقلل الزمن اللازم
+
+56
+00:04:51,320 --> 00:04:56,140
+للوصول إليها هذا ما يتعلق Blitzschlag طبعا الموضوع
+
+57
+00:04:56,140 --> 00:05:04,790
+مر معنا سابقاالان خلينا نتكلم عن مفهوم، المفهوم
+
+58
+00:05:04,790 --> 00:05:08,530
+هذا هنتعرضله برضه خلال الفصل و هيكون له تطبيقات
+
+59
+00:05:08,530 --> 00:05:13,330
+مهمة عندنا اللي هو stepwise equilibrium constant
+
+60
+00:05:15,410 --> 00:05:20,130
+في الحقيقة بعض ال equilibrium بعض الاتزانات تتم
+
+61
+00:05:20,130 --> 00:05:24,550
+بخطوة واحدة زي مثلا اتزان ال acetic acid اه والله
+
+62
+00:05:24,550 --> 00:05:30,490
+بيتفكك ل acetate جزئيا يعني و H plus مثلا هذا
+
+63
+00:05:30,490 --> 00:05:36,490
+اتزان خطوة واحدة لكن في اتزانات اخرى تتم على عدة
+
+64
+00:05:36,490 --> 00:05:42,580
+خطواتزي مثلا الفوسفوريك أسد أول خطوة بيفقد بروتون
+
+65
+00:05:42,580 --> 00:05:47,300
+وبتحول ال H2PO4 سالب تاني خطوة بيفقد كمان بروتون
+
+66
+00:05:47,300 --> 00:05:53,560
+بتحول ال HPO42 سالب تالت خطوة بيفقد تلاتة بروتون
+
+67
+00:05:53,560 --> 00:05:59,980
+او بروتون إضافي يعني بتحول لل PO43 سالب مثلا ففيه
+
+68
+00:05:59,980 --> 00:06:04,850
+هنا equilibriumتتم بخطوة واحدة وفيها انها
+
+69
+00:06:04,850 --> 00:06:09,390
+Equilibria تتم بأكثر من خطوة هان بنتكلم عن ال
+
+70
+00:06:09,390 --> 00:06:12,810
+Equilibria اللي بتتم بأكثر من خطوة وناخد مثال عام
+
+71
+00:06:12,810 --> 00:06:20,560
+لو عندي Equilibria A to B بيعطينا A زائد ABبقول
+
+72
+00:06:20,560 --> 00:06:27,600
+اتفكك ال A to B تفكك أولي فاعطانا A زائد AB لهذا
+
+73
+00:06:27,600 --> 00:06:34,080
+التفكك بقدر اكتب equilibrium constant يعني ثابت
+
+74
+00:06:34,080 --> 00:06:41,120
+اتزان سوى A في ال A B تركيزات على ال A to B طيب ال
+
+75
+00:06:41,120 --> 00:06:44,980
+A B هذا اللي طلع عندي في الخطوة الأولى ممكن يتفكك
+
+76
+00:06:44,980 --> 00:06:51,480
+فيعطينا A زائد B برضه هذا له ثابت اتزانعبارة عن a
+
+77
+00:06:51,480 --> 00:06:56,820
+في b على ال a بي تركيزات طب لو ضربنا k واحد في k
+
+78
+00:06:56,820 --> 00:07:01,600
+اتنين هذه القيمة في هذه القيمة بلاحظ بيطلع عندنا a
+
+79
+00:07:01,600 --> 00:07:10,020
+squared times b over a to b كويس طيب إيش بيحصل لو
+
+80
+00:07:10,020 --> 00:07:14,400
+إن هذا ال equilibrium اللي فوق اتفكك بخطوة واحدة
+
+81
+00:07:14,400 --> 00:07:17,160
+مش بخطوطين خلينا نشوفه
+
+82
+00:07:21,920 --> 00:07:27,280
+A to B اعطانا اتنين A و اعطانا B هي تفكك كامل الان
+
+83
+00:07:27,280 --> 00:07:36,220
+ال K A squared times B over A to B هو نفس الشكل
+
+84
+00:07:36,220 --> 00:07:41,420
+اللى جفناه سابق النفس هذا معنى الكلام التفكك اللى
+
+85
+00:07:41,420 --> 00:07:41,940
+عندى
+
+86
+00:07:45,140 --> 00:07:50,800
+ك راح تساوي كواحد كاتنين وكأنه إذا كان عندي
+
+87
+00:07:50,800 --> 00:07:56,000
+multistep equilibria أو stepwise equilibria فحاصل
+
+88
+00:07:56,000 --> 00:07:59,720
+ضرب ال equilibrium constants للخطوات المختلفة
+
+89
+00:07:59,720 --> 00:08:04,740
+يساوي ال equilibrium constant للخطوة المحصلة فلو
+
+90
+00:08:04,740 --> 00:08:08,600
+كان عندي حاجة مثلا زي ال phosphoric acid شفناها
+
+91
+00:08:08,600 --> 00:08:13,590
+إيه كواحد و كاتنين و كتلاتةلو ان الفوسفوريك أسن
+
+92
+00:08:13,590 --> 00:08:19,710
+اتفكك مرة واحدة ل 3H plus زائد فوسفيت هلاحظ ان ال
+
+93
+00:08:19,710 --> 00:08:25,990
+K لهذه الخطوة بتساوي K1 K2 K3 هنشوف في الحقيقة
+
+94
+00:08:25,990 --> 00:08:30,030
+تفاصيل هذا الكلام لكن في المستقبل، الآن بس مجرد
+
+95
+00:08:30,030 --> 00:08:34,350
+إشارة هتيجي تطبيقاتها في المستقبل
+
+96
+00:08:36,280 --> 00:08:41,300
+الان بشكل أساسي محاضرة اليوم عايزين نطلع على ال
+
+97
+00:08:41,300 --> 00:08:47,880
+calculations باستخدام ال equilibrium constants
+
+98
+00:08:47,880 --> 00:08:53,440
+يعني ال equilibrium calculations وبقول في هذه ال
+
+99
+00:08:53,440 --> 00:08:56,920
+.. او في هذا الموضوع تحديدا احنا اتكلمنا الحصة
+
+100
+00:08:56,920 --> 00:09:02,210
+الماضية عن تقسيمال equilibrium constants لقسمين
+
+101
+00:09:02,210 --> 00:09:06,790
+إما equilibrium constant كبير أو equilibrium
+
+102
+00:09:06,790 --> 00:09:12,490
+constant مش كبير مش كبير فعملناهم بس حاجتين يا
+
+103
+00:09:12,490 --> 00:09:16,550
+كبير يا مش كبير كبير يعني أكبر من عشر أقصى اتنين
+
+104
+00:09:16,550 --> 00:09:21,250
+مش كبير أقل من عشر أقصى اتنين بغض النظر هل هو very
+
+105
+00:09:21,250 --> 00:09:25,800
+small أو متوسطالان بس بدى أطلع أنا على المنهجية في
+
+106
+00:09:25,800 --> 00:09:29,440
+الحل، منهجية الحل بقول مفتاح حل أي مسألة
+
+107
+00:09:29,440 --> 00:09:34,940
+equilibrium أي مسألة اتزان مفتاح الحل يكمن في قيمة
+
+108
+00:09:34,940 --> 00:09:38,200
+ال equilibrium constant يعني أنا عشان أحل أي مسألة
+
+109
+00:09:38,200 --> 00:09:42,340
+اتزان بتطلع على قيمة ال equilibrium constant إذا
+
+110
+00:09:42,340 --> 00:09:46,980
+كان ال equilibrium constant very small، كويس،
+
+111
+00:09:46,980 --> 00:09:53,800
+معناتهقريبا المتفاعلات باقية على ما هي عليه لم
+
+112
+00:09:53,800 --> 00:10:00,300
+تتحول إلى نواتج إلا بكميات مهملة مقدارها X يعني
+
+113
+00:10:00,300 --> 00:10:06,110
+كمية المتفاعلات التي تحولت إلى نواتجهي كمية قليلة
+
+114
+00:10:06,110 --> 00:10:10,870
+جدا مقدارها X وهي مهملة إذا ما قورنت بكمية
+
+115
+00:10:10,870 --> 00:10:14,990
+المتفاعلات المتبقية يعني كل المتفاعلات ضايلة
+
+116
+00:10:14,990 --> 00:10:18,830
+تقريبا زي ما هي إيش اللي اتحول منها X وهي كمية
+
+117
+00:10:18,830 --> 00:10:26,610
+مهملة بالنسبة لإيه؟ للمتفاعلات أكس هذا الكلام لو
+
+118
+00:10:26,610 --> 00:10:31,330
+كان ال equilibrium constant very large معناته إيه؟
+
+119
+00:10:31,330 --> 00:10:36,920
+معناته أنهتقريبا كل المتفاعلات تحولت إلى نواتج
+
+120
+00:10:36,920 --> 00:10:44,980
+وتبقى من المتفاعلات كمية قليلة مقدارها X لا تقارن
+
+121
+00:10:44,980 --> 00:10:48,580
+بالنواتج هي كمية مهمة لا إذا ما قارنها بالنسبة
+
+122
+00:10:48,580 --> 00:10:50,260
+لإيش لنواتج
+
+123
+00:10:52,590 --> 00:10:56,030
+الحالة التالتة إذا كان ال equilibrium constant
+
+124
+00:10:56,030 --> 00:11:02,490
+متوسط في هذه الحالة بنقول في عندي كمية appreciable
+
+125
+00:11:02,490 --> 00:11:10,170
+يعني كمية محسوسة من المتفاعلات وأيضا عندي كمية
+
+126
+00:11:10,170 --> 00:11:14,910
+محسوسة من النواتج عشان هيك يعني في الحقيقة بقدرش
+
+127
+00:11:14,910 --> 00:11:18,580
+أقول واحدة أكتر من التانية بشكل كبير خالصأو واحدة
+
+128
+00:11:18,580 --> 00:11:23,860
+يعني اتكولت بشكل مهمل بقدرش لكن كطريقة حل بدي أحط
+
+129
+00:11:23,860 --> 00:11:28,120
+هذا النوع من المسائل مع الحالة الأولى اللي هي
+
+130
+00:11:28,120 --> 00:11:35,640
+وكأنه وكأنه كمية المتفاعلات التي تحولت إلى نواتج
+
+131
+00:11:36,380 --> 00:11:40,300
+كمية مهملة X لا تكاد تذكر يعني نفس الحالة الأولى
+
+132
+00:11:40,300 --> 00:11:47,260
+تماما في الحل لكن ك ناحية عملية لأ مش صحيح الكلام
+
+133
+00:11:47,260 --> 00:11:51,320
+هذا وإن كان في الحل أبسط طريقة لحلها هو أنه أن
+
+134
+00:11:51,320 --> 00:11:56,760
+نعتبر أنه يعني كمية المتفاعلات اللي اتحولت لنباتج
+
+135
+00:11:56,760 --> 00:12:01,640
+مهملة كمية قليلة X لا تكاد تذكر لما أقول هيك يعني
+
+136
+00:12:01,640 --> 00:12:05,890
+والله أنا بتعتبر هذا الكلامولما أقول بدي أفترض أن
+
+137
+00:12:05,890 --> 00:12:09,110
+كمية النواتج أكبر كتير من المتفاعلات أو كمية
+
+138
+00:12:09,110 --> 00:12:12,670
+المتفاعلات أكبر كتير من النواتج، بقول هذه فرضيات،
+
+139
+00:12:12,670 --> 00:12:15,590
+هذه فرضيات، أي واحد ممكن يقول والله أنا بفترض،
+
+140
+00:12:15,590 --> 00:12:19,690
+كذا، لكن المشكلة مش في الفرضية، المشكلة أن الفرضية
+
+141
+00:12:19,690 --> 00:12:23,210
+يجب أن تقترن بتحقيق الفرضية، يعني انت افترضت أي
+
+142
+00:12:23,210 --> 00:12:27,670
+شيء، لازم في الحل اتحققه، إذا كان ماقدرت تثبت أن
+
+143
+00:12:27,670 --> 00:12:30,950
+والله بالفعل مثلا النواتج أكبر كتير من المتفاعلات
+
+144
+00:12:30,950 --> 00:12:34,440
+أو المتفاعلات أكبر كتير من النواتج،إذا كان مقدر
+
+145
+00:12:34,440 --> 00:12:37,540
+تثبت هذا الكلام أو طلع معاك عكسه لازم تقول أه
+
+146
+00:12:37,540 --> 00:12:41,620
+والله فرضيت غلط وترجع للحل من الأول خالص هنشوف
+
+147
+00:12:41,620 --> 00:12:49,260
+أمثلة على هذا الكلام طيب تعالوا نطلع على بعض
+
+148
+00:12:49,260 --> 00:12:51,040
+الأمثلة العملية
+
+149
+00:12:53,590 --> 00:12:58,170
+الان في عنا مثال كتير بسيط بيقول calculate the
+
+150
+00:12:58,170 --> 00:13:02,950
+equilibrium concentration of A and B in a 0.1
+
+151
+00:13:02,950 --> 00:13:06,290
+molar solution of weak electrolyte AB يعني عندي AB
+
+152
+00:13:06,290 --> 00:13:10,990
+هذا weak electrolyte بتفكك بتعطيني A وB فعايز يحسب
+
+153
+00:13:10,990 --> 00:13:17,740
+تركيزات A وB في 0.1 molar ABبقول إيش if the
+
+154
+00:13:17,740 --> 00:13:21,040
+equilibrium constant of the reaction is 3 في 10
+
+155
+00:13:21,040 --> 00:13:25,640
+أسالب 6 إيش رأيكم في ال equilibrium constant هذا
+
+156
+00:13:25,640 --> 00:13:30,400
+مفتاح الحل صغير معنى الكلام إيش يعني صغير معناته
+
+157
+00:13:30,400 --> 00:13:33,560
+أنه معناته ببساطة أنه
+
+158
+00:13:35,860 --> 00:13:38,700
+تقريبا المتفاعلات حتى الهزام اللي هي راح تجل
+
+159
+00:13:38,700 --> 00:13:43,400
+بمقدار ضئيل جدا مقداره X وال X هذه كمية مهملة إذا
+
+160
+00:13:43,400 --> 00:13:47,400
+ما قُرنت بال 0.1 بكمية المتفاعلات الأصلية ليه؟ لأن
+
+161
+00:13:47,400 --> 00:13:50,560
+ال equilibrium constant صغير فبالتالي المتفاعلات
+
+162
+00:13:50,560 --> 00:13:54,120
+أه هيتحول جزء منها لنواتج لكن هذا الجزء إيش
+
+163
+00:13:54,120 --> 00:13:58,640
+مقداره؟ X وهو كمية صغيرة جدا مهملة إذا ما قرنت بال
+
+164
+00:13:58,640 --> 00:14:02,980
+0.1اللي هو تركيز المتفاعلات احنا كيف بنحل المسائل
+
+165
+00:14:02,980 --> 00:14:07,660
+هذه عشان نكون عمليين؟ بنقول في البداية بنعمل جدول
+
+166
+00:14:07,660 --> 00:14:12,160
+زي اللي قدامكم في النص ال equation أو معادلة
+
+167
+00:14:12,160 --> 00:14:20,800
+التفاعل a,b بتعطينا a وb في السطر اللي فوق بنحط
+
+168
+00:14:20,800 --> 00:14:28,100
+التركيزات قبل الإتزانقبل الاتزان a b واحد من عشرة
+
+169
+00:14:28,100 --> 00:14:33,300
+a صفر b صفر مجليش في عندك كمية من a او كمية من b
+
+170
+00:14:33,300 --> 00:14:37,660
+لأ بس عندنا a b بعد الاتزان اه من ال equilibrium
+
+171
+00:14:37,660 --> 00:14:40,040
+constant ايش ال equilibrium constant بيقول ليه
+
+172
+00:14:40,040 --> 00:14:42,620
+بيقول ليه ان equilibrium constant very small
+
+173
+00:14:42,620 --> 00:14:48,020
+معناتهالمتفاعلات اللي هي واحد من عشرة راح تقل
+
+174
+00:14:48,020 --> 00:14:53,400
+المقدار ضقيل جدا كمية صغيرة مقدارها X طبعا النواتج
+
+175
+00:14:53,400 --> 00:14:59,180
+عندنا واحد يعني X واحد يعني X هيطلع منها X من A و
+
+176
+00:14:59,180 --> 00:15:04,260
+X من B هذا بناء الجدول في البداية بعدين بعد ما
+
+177
+00:15:04,260 --> 00:15:09,340
+أبني الجدول بقى أروح لإيه بقى أروح ل ال
+
+178
+00:15:09,340 --> 00:15:10,640
+equilibrium constant
+
+179
+00:15:14,000 --> 00:15:16,320
+بروح لل equilibrium constant بقول ال equilibrium
+
+180
+00:15:16,320 --> 00:15:20,540
+constant بيستوي K بيستوي A في B على ال A B معنى
+
+181
+00:15:20,540 --> 00:15:25,560
+الكلام X اللي هي تركيز A X اللي هي تركيز B من
+
+182
+00:15:25,560 --> 00:15:30,940
+الجدولعلى ال a b point one minus x الان انا لو جيت
+
+183
+00:15:30,940 --> 00:15:33,280
+طلعت على المعادلة يصير هذه x تربيع على point one
+
+184
+00:15:33,280 --> 00:15:35,800
+minus x بيبقى تساوية تلاتة في عشر أقصى لبسية تلاتة
+
+185
+00:15:35,800 --> 00:15:40,420
+لو بدي احلها بيصير معادلة تربيعية صعبة الحل لكن ..
+
+186
+00:15:40,420 --> 00:15:43,920
+لكن انا من قيمة ال equilibrium constant بقدر اعمل
+
+187
+00:15:43,920 --> 00:15:48,940
+فرضي انا عامل بقول انه كمية ال .. يعني المتفاعلات
+
+188
+00:15:48,940 --> 00:15:52,020
+اللي تحولت لوقت جديد ليها xكمية لا تكاد تذكر
+
+189
+00:15:52,020 --> 00:15:56,560
+بالنسبة للـ 0.1 عشانك بإمكاني أعمل فرضية أقول فيها
+
+190
+00:15:56,560 --> 00:16:01,420
+أن ال X أقل كتير من ال 0.1 أو أن ال 0.1 أكبر كتير
+
+191
+00:16:01,420 --> 00:16:05,240
+من ال X، منطقي؟ فرضيتي ولا لأ؟ فرضية منطقية، ليش
+
+192
+00:16:05,240 --> 00:16:08,200
+منطقية؟ لأن ال equilibrium constant very small،
+
+193
+00:16:08,200 --> 00:16:14,320
+يعني ال X is expected to be very smallفباجي بقول
+
+194
+00:16:14,320 --> 00:16:19,260
+ماشي نفترض أسيوم سطر كامل point one أكبر كتير من
+
+195
+00:16:19,260 --> 00:16:24,760
+ال X إذا بألغي ال X و دائما لما تلغي بتلغي فقط
+
+196
+00:16:24,760 --> 00:16:31,680
+الشيء المطروح أو المجموعة لكميةما بتلغي ال X هذه
+
+197
+00:16:31,680 --> 00:16:35,180
+او ال X هذه اوعى ليه لو ال X مضروبة او اذا كان
+
+198
+00:16:35,180 --> 00:16:39,800
+عندك X مقصومة ممنوعة فسمة او ضرب لا اللي بتقدر
+
+199
+00:16:39,800 --> 00:16:44,060
+تلغيه الجمع والطرح بسألك جداش معاك تقولي مثلا
+
+200
+00:16:44,060 --> 00:16:49,080
+مليون شكلمليون شكل زاد او ناقص X جداش ال X عندك
+
+201
+00:16:49,080 --> 00:16:53,600
+قولش شكل اذا اه تسعمية او تسعة و تسعين او تسعة و
+
+202
+00:16:53,600 --> 00:16:55,180
+تسعين او تسعين او تسعين لأ والله مليون معاك مش
+
+203
+00:16:55,180 --> 00:16:58,760
+مشكلة لكن لو قلتلي جداش بقول بس لجداش معاك و تقولي
+
+204
+00:16:58,760 --> 00:17:02,520
+والله مليون شكل مضروبة في X بس بقول لجداش ال X
+
+205
+00:17:02,520 --> 00:17:06,700
+تبعتك و تقولي عشر أقل سالب ستة اه اذا جداش معاك
+
+206
+00:17:06,700 --> 00:17:11,260
+شكل اه بتفرج كتير عملية الضرب عملية يعني بتختلف
+
+207
+00:17:11,260 --> 00:17:16,190
+جدا عن عملية الجمع والطرح فانتبتقدر تلغي اشي مجموع
+
+208
+00:17:16,190 --> 00:17:20,550
+الى او مطروح من لكن مابتقدر تلغي اشي مضروب او
+
+209
+00:17:20,550 --> 00:17:24,970
+مقصوم على الكويس هذا الكلام اتذكر بس اتذكر ان اللي
+
+210
+00:17:24,970 --> 00:17:30,330
+مسموح اليك تلغيه او تفترض انه ممكن تلغيه هو الشئ
+
+211
+00:17:30,330 --> 00:17:37,130
+المجموع او المطروح طيب بنقول لما نيجي نحل المعادلة
+
+212
+00:17:37,130 --> 00:17:40,030
+اترى ان X بتساوي خمسة و نص في عشر اقل سالب اربعة
+
+213
+00:17:41,370 --> 00:17:45,850
+الان هذه قيمة ال X لكن ال X بناء على ايه؟ بناء على
+
+214
+00:17:45,850 --> 00:17:49,810
+الفرضية قبل ما أروح لأي مكان مدام طلعت قيمة ال X
+
+215
+00:17:49,810 --> 00:17:55,370
+بدي أحقق فرضيتي كيف يتم تحقيق الفرضية؟ اتطلع عليها
+
+216
+00:17:55,370 --> 00:17:59,110
+هاي الفرضية تبعتي point one أكبر كتير من ال X مش
+
+217
+00:17:59,110 --> 00:18:07,050
+هيك باجي بحط سهم هيكفي مية، أيش بتفهم منه؟ ال X
+
+218
+00:18:07,050 --> 00:18:12,370
+على واحد من عشرة في مية من مية، أيش بتعطيك؟ بتعطيك
+
+219
+00:18:12,370 --> 00:18:17,970
+حاجة اسمها relative error الخطأ النسبي، هيها ال X
+
+220
+00:18:17,970 --> 00:18:21,550
+على ال point one في مية من مية، بس تتطلع دايما،
+
+221
+00:18:21,550 --> 00:18:24,630
+الشي اللي أنت بدك تلغيه على ال value في مية من
+
+222
+00:18:24,630 --> 00:18:30,030
+مية، هي ال relative error، أيش أعطتك قيمة؟أعطتك
+
+223
+00:18:30,030 --> 00:18:41,640
+تقريبا 6 من 10% طيب هل هذه الخطأ النسبي؟معتبر ولا
+
+224
+00:18:41,640 --> 00:18:46,340
+يمكن اهماله ونعتبر شغلنا صح؟ بنقول هذا بيعتمد على
+
+225
+00:18:46,340 --> 00:18:50,180
+ايش ال criteria او المعيار اللي عندنا احنا المعيار
+
+226
+00:18:50,180 --> 00:18:54,680
+اللي عندنا هو خمسة في المية اي اشي اي خطأ اقل من
+
+227
+00:18:54,680 --> 00:18:57,720
+خمسة في المية نعتبره كأنه مش خطأ خطأ محتمل يعني
+
+228
+00:18:57,720 --> 00:19:02,730
+خطأ لكنه خطأ اي محتمل ممكنطبعاً الخمسة في المية
+
+229
+00:19:02,730 --> 00:19:08,550
+هذه مش اشي منزل مش اشي ثابت مش اشي يعني منصوص عليه
+
+230
+00:19:08,550 --> 00:19:14,330
+وخلاص في اي نظام علمى او في اي مختبر او في اي شركة
+
+231
+00:19:14,330 --> 00:19:17,950
+لأ هذا الخمسة في المية احنا بنعتبرها في معظم كتب
+
+232
+00:19:17,950 --> 00:19:20,850
+الكيميا التحليلية في معظم مساقات الكيميا التحليلية
+
+233
+00:19:20,850 --> 00:19:26,800
+لكن ممكن تشتغل في شركةبتعتمدش 5% مثلا يعني لو
+
+234
+00:19:26,800 --> 00:19:31,320
+اشتغلت في شركة Samsung ولا Nokia ولا ما شابه اللي
+
+235
+00:19:31,320 --> 00:19:35,440
+بتعمل جوالات بتعتمد نسبة خاطرة 5% يعني كل 100 جوال
+
+236
+00:19:35,440 --> 00:19:39,560
+بدهم يطلعوا خمسة خربانين دي مشكلة كبيرة، مظبطش،
+
+237
+00:19:39,560 --> 00:19:45,200
+فممكن يطلعوا على مثلا جزء من مليونبالمليون مثلا
+
+238
+00:19:45,200 --> 00:19:48,480
+فانت حتى في الكيمة التحليلية حسب الشركة ممكن
+
+239
+00:19:48,480 --> 00:19:50,780
+الشركة تقول الله أحد أقصى عندي انا واحد في المية
+
+240
+00:19:50,780 --> 00:19:55,500
+نسبة خاطر غير هيك لأ اشتغل بحل المسألة حل عادي
+
+241
+00:19:55,500 --> 00:20:00,720
+بدون اي فرضيات اعتبر فرضيتك غلط فهذا الكلام تتأكد
+
+242
+00:20:00,720 --> 00:20:05,060
+من الشركة او المحل اللي تشتغل فيه اذا كان ايش نسبة
+
+243
+00:20:05,060 --> 00:20:07,580
+الخطأ المسموح فيها بس احنا عادة في الكيمة
+
+244
+00:20:07,580 --> 00:20:11,220
+التحليلية بنشتغل على اساس نسبة خطأ خمسة في المية
+
+245
+00:20:12,820 --> 00:20:16,820
+أكتر من خمسة في المية يعني هذا شيء يعتبر مش صحيح
+
+246
+00:20:16,820 --> 00:20:21,020
+أقل من خمسة في المية يعتبر خطأ محتمل طيب مدام هيك
+
+247
+00:20:21,020 --> 00:20:24,260
+طلعنا أن الخطأ جيد مافيش عندنا مشكلة فيه يعني
+
+248
+00:20:24,260 --> 00:20:29,200
+فبنقول ال A بدأ تسوي خمسة و نصف عشر أقل سالب أربعة
+
+249
+00:20:29,200 --> 00:20:33,620
+ال B لأنها X ال B برضه بتسوي X يعني خمسة و نصف عشر
+
+250
+00:20:33,620 --> 00:20:39,600
+أقل سالب أربعة ال ABواحد من عشرة ناقص X لكن ماحدش
+
+251
+00:20:39,600 --> 00:20:44,180
+يتراحى ال X لأنه طوي احنا يعني حققنا الفرضية وقلنا
+
+252
+00:20:44,180 --> 00:20:47,960
+ان ال X أقل كتير من واحد من عشرة فهي لازم تقول
+
+253
+00:20:47,960 --> 00:20:51,600
+واحد من عشرة كمان اذا كان حابب تتأكد و تستفيد و
+
+254
+00:20:51,600 --> 00:20:55,140
+تنبسط من الكلام اللي أخدته سابقا حاول تتراحى على
+
+255
+00:20:55,140 --> 00:20:59,260
+الآية الحاسبة لكن اشتغل significant figures وخلي
+
+256
+00:20:59,260 --> 00:21:02,780
+طبعا هدفك خلي بس رقمين فتطلع عندك كمان واحد من
+
+257
+00:21:02,780 --> 00:21:06,250
+عشرةإذا كانت اشتغلت significant figures هيطلع معاك
+
+258
+00:21:06,250 --> 00:21:11,970
+ورد واحد من عشرة طيب نيجي نتطلع على المثال التالي
+
+259
+00:21:11,970 --> 00:21:18,590
+المثال بيقول in the reaction a plus b تعطينا c
+
+260
+00:21:18,590 --> 00:21:27,150
+plus d if 0.2 moles of a اه انت باهل اللفظ مول مش
+
+261
+00:21:27,150 --> 00:21:32,670
+مولر انا بهمني التركيز بهمليش ال molesطيب of a is
+
+262
+00:21:32,670 --> 00:21:38,990
+mixed with 0.5 mol of b in one liter اه مدام هيك
+
+263
+00:21:38,990 --> 00:21:41,650
+خلاص يبقى سارة molarity لأن ال mol في ال liter
+
+264
+00:21:41,650 --> 00:21:45,250
+خلاص الحمد لله ريحنا من الحسابات لكن لو أعطاني أي
+
+265
+00:21:45,250 --> 00:21:49,030
+حجم آخر بدي أقسم على الحجم بال liter عشان أطلع ال
+
+266
+00:21:49,030 --> 00:21:52,650
+molarity اللي بدي استخدمها بعد شوية في بناء الجدول
+
+267
+00:21:53,140 --> 00:21:56,500
+بقول find the equilibrium concentrations of A, B,
+
+268
+00:21:56,680 --> 00:22:04,120
+C and D بده تركيزات كل المواد عند الاتزان نعطينا
+
+269
+00:22:04,120 --> 00:22:08,080
+ال equilibrium constant لل reaction أربعة فعشرة
+
+270
+00:22:08,080 --> 00:22:12,920
+أسالب تسعةمفتاح الحل اعطاني المفتاح اربعة فى عشران
+
+271
+00:22:12,920 --> 00:22:18,060
+سنة تسعة ايش رأيكم طبعا صغير للغاية صغير جدا معنى
+
+272
+00:22:18,060 --> 00:22:23,400
+الكلام المتفاعلات هتبقى على حالها اللى تمية قليلة
+
+273
+00:22:23,400 --> 00:22:28,380
+جدا مقدارها X هي اللى هتتحول لا نواتج طيب علشان
+
+274
+00:22:28,380 --> 00:22:35,220
+هيك اطول بنبنى الجدول المعادلة ABCDA 2 من 10 مولار
+
+275
+00:22:35,220 --> 00:22:40,360
+B 5 من 10 مولار C 0 دي 0 هذا قبل الإبتزان بعد
+
+276
+00:22:40,360 --> 00:22:45,860
+الإبتزان A راح تقلب مقدار بقيل لغاية مقداره X B
+
+277
+00:22:45,860 --> 00:22:50,320
+راح تقلب مقدار بقيل لغاية مقداره X C هيتكون منها X
+
+278
+00:22:50,320 --> 00:22:56,000
+و D أيضا هيتكون منها X الآن بدنا نعمل ال
+
+279
+00:22:56,000 --> 00:23:00,490
+equilibrium constant expressionالـ K بتسوي ال C في
+
+280
+00:23:00,490 --> 00:23:05,110
+ال D على ال A في ال B مع كلام X في X على 0.2 minus
+
+281
+00:23:05,110 --> 00:23:11,450
+X 0.5 minus X والآن بدي أفرض فرضيا بدي أقول بدي
+
+282
+00:23:11,450 --> 00:23:14,650
+ألغي ال X فأفرض أن ال 0.2 أكبر كتير من ال X ولا ال
+
+283
+00:23:14,650 --> 00:23:20,690
+0.5 أكبر كتير من ال Xالأقل بتفرض أن ال point 2
+
+284
+00:23:20,690 --> 00:23:25,210
+أكبر كتير من ال X دائما الأقل ليه؟ ده لأجل البساطة
+
+285
+00:23:25,210 --> 00:23:28,250
+إذا كان ال point 2 أكبر كتير من ال X اللي هي
+
+286
+00:23:28,250 --> 00:23:31,670
+القليلة فبالضرورة عايشة طبيعي أن ال point 5 هتكون
+
+287
+00:23:31,670 --> 00:23:36,790
+أكبر كتير من ال X فدائما بختار إيه؟ الأقل فبفترض
+
+288
+00:23:36,790 --> 00:23:40,730
+أنه assume ال point 2 أكبر كتير من ال X إذا راحت
+
+289
+00:23:40,730 --> 00:23:45,240
+ال X هذه وراحت ال X هذهالان ال expression ال
+
+290
+00:23:45,240 --> 00:23:47,300
+equilibrium constant ساوي ال X تربيع على ال point
+
+291
+00:23:47,300 --> 00:23:50,540
+two في ال point five و منها ال X تطلع اتنين في
+
+292
+00:23:50,540 --> 00:23:56,780
+عشرة أسالب خمسة لسه ماعملتش حاجة لازم فورا أحقق
+
+293
+00:23:56,780 --> 00:24:02,520
+الفرضية لازم أحقق الفرضية فبد أجسم ال X على ايه
+
+294
+00:24:02,520 --> 00:24:05,720
+على ال اتنين من عشرة في مية من مية عشان أجيب ال
+
+295
+00:24:05,720 --> 00:24:10,550
+relative error بطلع واحد من مية في الميةيعتبر قطاء
+
+296
+00:24:10,550 --> 00:24:15,870
+قليل للغاية إذا ال A بتساوي 2 من 10 ناقص X و طبعا
+
+297
+00:24:15,870 --> 00:24:20,390
+احنا اتثوى شوفنا ان ال X ده بنكتب هاش 2 من 10 ال B
+
+298
+00:24:20,390 --> 00:24:25,110
+5 من 10 ناقص X بنكتب هاش ال X يعني 5 من 10 ال C و
+
+299
+00:24:25,110 --> 00:24:30,290
+ال D كل واحدة فيهم X يعني 2 في 10 السالب خمسة هذه
+
+300
+00:24:30,290 --> 00:24:34,790
+يعني طريقة حل المسائل لما يكون عندي ال equilibrium
+
+301
+00:24:34,790 --> 00:24:41,410
+constant A شماله مش كبيرقليل، معظم شغلنا على أو
+
+302
+00:24:41,410 --> 00:24:45,670
+باستخدام هذا المفهوم، معظم شغلنا، لكن في عنا
+
+303
+00:24:45,670 --> 00:24:51,630
+chapter بجيلنا ال equilibrium constant حلّجي كبير،
+
+304
+00:24:51,630 --> 00:24:56,210
+فحنشوف بعض الأمثلة كيف بنحل المسائل إذا كان ال
+
+305
+00:24:56,210 --> 00:25:04,380
+equilibrium constant عندي كبير، very largeفناخد
+
+306
+00:25:04,380 --> 00:25:06,720
+نفس المثال اللي درسناه قبل شوية نقول in the
+
+307
+00:25:06,720 --> 00:25:12,760
+reaction a plus b بتعطينا c plus d نقول if 0.2 mol
+
+308
+00:25:12,760 --> 00:25:16,580
+of a is mixed with 0.5 mol of b in one liter نفس
+
+309
+00:25:16,580 --> 00:25:20,100
+المثالة find the equilibrium concentrations of a,b
+
+310
+00:25:20,100 --> 00:25:23,400
+,c and d the equilibrium constant of the reaction
+
+311
+00:25:23,400 --> 00:25:30,240
+isأربعة عشرة أس تمانية يعني أيه يعني كبير للغاية
+
+312
+00:25:30,240 --> 00:25:34,500
+إيش معنى كبير للغاية معناته أن كل المتفاعلات
+
+313
+00:25:34,500 --> 00:25:39,840
+هيتحول إلى نواتج إلا جزء يسير مقداره X يمكن إهماله
+
+314
+00:25:39,840 --> 00:25:44,060
+إذا ما قُرن بالنواتج طيب نشوف كيف نترجم هذا الكلام
+
+315
+00:25:44,060 --> 00:25:50,130
+بنروح لجدول تبعنا المعادلة في النصالتركيزات قبل
+
+316
+00:25:50,130 --> 00:25:54,490
+الاتزان فوق التركيزات بعد الاتزان تحت عندي
+
+317
+00:25:54,490 --> 00:25:59,430
+المعادلة A وB بتعطينا C وD A كانت 2 من 10 مولر B
+
+318
+00:25:59,430 --> 00:26:06,750
+كانت 5 من 10 مولر C صفر وD صفر انا عندي واضح ان ال
+
+319
+00:26:06,750 --> 00:26:12,070
+1 مول من A بتفعل مع 1 مول من B اذا ال 2 من 10 مول
+
+320
+00:26:12,070 --> 00:26:13,750
+من A ماعددش هتفعل من B
+
+321
+00:26:16,910 --> 00:26:20,290
+الواحد بتفاعل مع واحد الاتنين من عشرة مع جداش
+
+322
+00:26:20,290 --> 00:26:24,330
+هتتفاعل مع اتنين من عشرة طبعا مش مع خمسة من عشرة
+
+323
+00:26:24,330 --> 00:26:28,390
+افرض ان انا عندي مش خمسة من عشرة عندي ميت مول ميت
+
+324
+00:26:28,390 --> 00:26:32,950
+مولر من بي الاتنين من عشرة مول من ايه هتتفاعل مع
+
+325
+00:26:32,950 --> 00:26:37,470
+المين؟ هتتفاعل مع جدة واضح واحد لواحد التفاعل واحد
+
+326
+00:26:37,470 --> 00:26:41,170
+لواحد فالاتنين من عشرة هتتفاعل مع اتنين من عشرة
+
+327
+00:26:41,170 --> 00:26:46,290
+وإيش هيزيد من الخمسة من عشرة تلاتة من عشرةيعني
+
+328
+00:26:46,290 --> 00:26:51,290
+وكأنه هذه كتبتها انا اتنين من عشرة زائد تلاتة من
+
+329
+00:26:51,290 --> 00:26:56,270
+عشرة هي التلاتة من عشرة اللي زادت الاتنين هذه
+
+330
+00:26:56,270 --> 00:27:03,630
+هتتفاعل مع الاتنين هذه وتعطيلنا النواتج ايش هيزيد
+
+331
+00:27:03,630 --> 00:27:07,770
+من بيه بيه موجودة ب excess بيه موجود خمسة من عشرة
+
+332
+00:27:07,770 --> 00:27:12,800
+منها اتفاعل اتنين من عشرة دلت تلاتة من عشرةالـ A
+
+333
+00:27:12,800 --> 00:27:17,360
+بزيد منها X الـ B ثلاثة من عشرة هذه زايدة زايدة
+
+334
+00:27:17,360 --> 00:27:21,840
+والـ X اللي زادت من التفاعل من التفاعل الاتنين من
+
+335
+00:27:21,840 --> 00:27:25,400
+عشرة مع الاتنين من عشرة اتفاعله وزاد من هذه X ومن
+
+336
+00:27:25,400 --> 00:27:30,880
+هذه X الـ B اتنين من عشرة كل المتفاعلات اتنين من
+
+337
+00:27:30,880 --> 00:27:35,000
+عشرة بتعطي اتنين من عشرة لأن الواحد مول من A بعطي
+
+338
+00:27:35,000 --> 00:27:39,020
+واحد مول من C بعطي واحد مول من D إذا الاتنين من
+
+339
+00:27:39,020 --> 00:27:43,960
+عشرةبتعطى 2 من 10 و 2 من 10 يبجى 2 من 10 ناقص x كل
+
+340
+00:27:43,960 --> 00:27:47,500
+المتفاعلات تحولت الى نواتج ماعدى كمية قليلة
+
+341
+00:27:47,500 --> 00:27:55,220
+مقدارها x يبجى 2 من 10 ناقص x 2 من 10 ناقص x يبجى
+
+342
+00:27:55,220 --> 00:27:59,950
+بنجى نطلع على ال equilibrium constantالـ C في D
+
+343
+00:27:59,950 --> 00:28:04,190
+على A في B الـ K أو ال equilibrium constant بده
+
+344
+00:28:04,190 --> 00:28:09,630
+يساوي 2 من 10 minus X 2 من 10 minus X اللي هي C وD
+
+345
+00:28:09,630 --> 00:28:15,070
+الـ A اللي هي X الـ B اللي هي 3 من 10 زائد X القدر
+
+346
+00:28:15,070 --> 00:28:20,800
+بالدعم الفرضيةعشان أبسط المعادلة بدي ألغي كل الشيء
+
+347
+00:28:20,800 --> 00:28:24,840
+أو ال Xات المضافة أو المطروحة فبقل على أصغر شيء
+
+348
+00:28:24,840 --> 00:28:30,000
+موجود عندى 2 من 10 اذا مفترض انه ال 2 من 10 أكبر
+
+349
+00:28:30,000 --> 00:28:35,340
+كتير من ال X يبقى هاد ال X راحت و هاد ال X راحت و
+
+350
+00:28:35,340 --> 00:28:39,820
+هاد ال X عندى كمان راحت يبقى 4 فعشرة أستمرة سوى ال
+
+351
+00:28:39,820 --> 00:28:46,530
+point 04 على point 3 من ال Xيعني ال X بالساعة
+
+352
+00:28:46,530 --> 00:28:50,410
+تلاتة و تلاتة في عشرة أقل سالب عشرة يبقى قيمة ال X
+
+353
+00:28:50,410 --> 00:28:59,030
+تلاتة و تلاتة في عشرة أقل سالب عشرة فضل هل عشان
+
+354
+00:28:59,030 --> 00:29:02,790
+الكون سانتجليه؟ لأ هو خد بالك عشان طبعا الكون
+
+355
+00:29:02,790 --> 00:29:09,070
+سانتجليه قليل فهو هيتفاعل X هيتفاعل مع Xمعايا انت
+
+356
+00:29:09,070 --> 00:29:17,130
+30 درجة زي ما هي X هيتفاعل مع X و هيعطينا X و X ال
+
+357
+00:29:17,130 --> 00:29:21,650
+equilibrium constant هنا كان صغير هنا كبير يعني
+
+358
+00:29:21,650 --> 00:29:29,930
+هنا مثلا ازميلكم اه ازميلكم ايش بيقول بيقول ليش ما
+
+359
+00:29:29,930 --> 00:29:38,070
+حكينا في المثالهذا انه الاتنين من عشرة اتفعلت مع
+
+360
+00:29:38,070 --> 00:29:41,990
+ال .. مع ال .. هنا و كأنه احنا بنقول ايش هنا X
+
+361
+00:29:41,990 --> 00:29:49,150
+اتفعل مع X اعطانا X واعطانا Xكويس؟ مثلا يعني فهي
+
+362
+00:29:49,150 --> 00:29:52,490
+عندنا اتنين من عشرة كمية ضائلة جدا من هالاتفاعل
+
+363
+00:29:52,490 --> 00:29:57,470
+ايش مكبر الكمية الاتفاعلات؟ X ال B كمية ضائلة من
+
+364
+00:29:57,470 --> 00:30:01,130
+هالاتفاعلات لازم كمية مناظرة تكون X برضه هذا لأن
+
+365
+00:30:01,130 --> 00:30:04,890
+ال equilibrium constant ايش ماله؟ ال equilibrium
+
+366
+00:30:04,890 --> 00:30:07,970
+constant صغير لكن هنا ال equilibrium constant كبير
+
+367
+00:30:09,540 --> 00:30:12,260
+فال X بتطلع تلاتة و تلاتة في عشرة أقل سالب عشرة
+
+368
+00:30:12,260 --> 00:30:17,100
+الآن بقدر أقول أنه نحسب ال relative error بس واضح
+
+369
+00:30:17,100 --> 00:30:19,800
+أنه relative error إيش هيكون؟ هيكون كمية يعني
+
+370
+00:30:19,800 --> 00:30:23,880
+قليلة للغاية ال relative error ال X على اتنين من
+
+371
+00:30:23,880 --> 00:30:27,440
+عشرة في مية من مية بتطلع تقريبا خمسة من الف في
+
+372
+00:30:27,440 --> 00:30:30,580
+المية معناه الكلام ال assumption valid مش عادي
+
+373
+00:30:30,580 --> 00:30:34,770
+مشكلة فيه ال A هي عبارة عن Xتلاتة و تلاتة في عشرة
+
+374
+00:30:34,770 --> 00:30:38,590
+أسالب عشرة ال b عبارة عن تلاتة من عشرة زايد x طبعا
+
+375
+00:30:38,590 --> 00:30:42,190
+بتنكتمش تبجى تلاتة من عشرة ال c و ال d اتنين من
+
+376
+00:30:42,190 --> 00:30:49,470
+عشرة ناقص x برضه بتنكتمش يعني اتنين من عشرة طيب
+
+377
+00:30:49,470 --> 00:30:54,930
+بدي اخد مثال لما نكون ال equilibrium constant كبير
+
+378
+00:30:54,930 --> 00:30:58,950
+و بدي احاول انه اخد ال stoichiometry مش واحد لواحد
+
+379
+00:31:00,180 --> 00:31:04,100
+ان نتطلع على Stoichiometries مش واحد لواحد فنتطلع
+
+380
+00:31:04,100 --> 00:31:10,520
+على المثال التالي بقول a و b react as follows a
+
+381
+00:31:10,520 --> 00:31:18,180
+plus 2b بيعطينا 2c بقولك assume point one mole of
+
+382
+00:31:18,180 --> 00:31:24,310
+a reacts with point two mole of bن one liter حلو
+
+383
+00:31:24,310 --> 00:31:27,150
+كتير أعطاني مول لكن أعطاني الحجم liter يبقى ريحني
+
+384
+00:31:27,150 --> 00:31:30,950
+من حساب ال molarity لأنه مدام العدد المولات في ال
+
+385
+00:31:30,950 --> 00:31:35,310
+liter هي ال molarity خلاص أعطاني و كأنه molar فك
+
+386
+00:31:35,310 --> 00:31:39,150
+بتساوي واحد في عشرة أقص عشرة أيش رايكوا فيه ضخم
+
+387
+00:31:39,150 --> 00:31:42,970
+جدا find the equilibrium concentrations of a,b and
+
+388
+00:31:42,970 --> 00:31:51,430
+cبدو يسيب A يتفعل مع 2B ويعطينا 2C فعايز يحسب في
+
+389
+00:31:51,430 --> 00:31:54,750
+النهاية عند ال equilibrium جداش تركيز ال A جداش
+
+390
+00:31:54,750 --> 00:31:58,110
+تركيز ال B وجداش تركيز ال C بقول بما ان ال
+
+391
+00:31:58,110 --> 00:32:02,090
+equilibrium constant كبير معناه الكلام المتفاعلات
+
+392
+00:32:02,090 --> 00:32:06,990
+تقريبا كلها راح تتحول إلى نواتج إلا كمية قليلة جدا
+
+393
+00:32:06,990 --> 00:32:15,170
+مقدارها X فحنشوف الجدولعند المعادلة a plus 2b
+
+394
+00:32:15,170 --> 00:32:19,830
+بتعطينا 2c التركيزات قبل الإتزان 1 من 10 2 من 10
+
+395
+00:32:19,830 --> 00:32:25,750
+ال b بعد الإتزان خدوا بالكم لو لاحظنا بس أن ال 1
+
+396
+00:32:25,750 --> 00:32:32,480
+moleبتفاعل مع اتنين مول، اذا الواحد من عشرة بتفاعل
+
+397
+00:32:32,480 --> 00:32:35,560
+مع اتنين ضعفه، الواحد بتفاعل مع ضعفه، يبجي هذا ..
+
+398
+00:32:35,560 --> 00:32:38,440
+يبجي .. فاش اشهر هيزيد من ايه ولا بيه في الحقيقة
+
+399
+00:32:38,440 --> 00:32:42,280
+الا الكميات ال stoichiometric القليلة جدا ال
+
+400
+00:32:42,280 --> 00:32:47,500
+equilibrium concentrations علشان هيك هان بيزيد X و
+
+401
+00:32:47,500 --> 00:32:52,690
+هان بيزيد اتنين X، ده انه هاد اتنين مولطب ايش راح
+
+402
+00:32:52,690 --> 00:32:56,250
+يتكون؟ خد بالك لو اعتبرت ان ال a لو بدك تحسب اللي
+
+403
+00:32:56,250 --> 00:33:01,030
+اتكون من ال aفبتقول هذه واحد مول ايش بيعطينا من ال
+
+404
+00:33:01,030 --> 00:33:06,190
+c اتنين اذا الواحد من عشرة ايش بيعطي اتنين من عشرة
+
+405
+00:33:06,190 --> 00:33:11,370
+لو استخدم ال b بتقول هان اتنين بتعطي اتنين يبقى
+
+406
+00:33:11,370 --> 00:33:14,710
+اتنين من عشرة ايش بتعطي زي هاتنين من عشرة فسواء
+
+407
+00:33:14,710 --> 00:33:18,930
+استخدمت a او b للمصول الى الناتج نفس النتيجة
+
+408
+00:33:18,930 --> 00:33:24,070
+فدائما هتلاحظ انه النتيجة point two minus اتنين x
+
+409
+00:33:24,660 --> 00:33:30,420
+ليش الـ2X هذه؟ لأن هو عنده هنا 2C في 2C ف2C معناته
+
+410
+00:33:30,420 --> 00:33:36,360
+عنده بيكون 2X يبقى الـC عبارة عن 0.2-2X الـB عبارة
+
+411
+00:33:36,360 --> 00:33:42,840
+عن 2X، 2B يعني 2X، A عبارة عن X باجي إيش بقول؟
+
+412
+00:33:47,800 --> 00:33:53,820
+في المثال اللى فات ايش عملت؟ كام
+
+413
+00:33:53,820 --> 00:34:02,120
+زايد من هذا؟ اللى زايد منه صفر هدول
+
+414
+00:34:02,120 --> 00:34:05,800
+الاتنين بتفعلوا مع بعض وهي الصفر هذا بينزل مافيش
+
+415
+00:34:05,800 --> 00:34:10,360
+اشي زادبتفعل مع اتنين من عشرة طبعا لإن الواحد
+
+416
+00:34:10,360 --> 00:34:14,900
+بتفعل مع اتنين صح ولا لأ؟ هيو اه الواحد بتفعل مع
+
+417
+00:34:14,900 --> 00:34:18,280
+اتنين إذا الواحد من عشرة بتفعل مع الاتنين من عشرة
+
+418
+00:34:18,280 --> 00:34:24,140
+صح ولا لأ؟ طبيعي طيب يا شباب الآن لو طلعنا على ال
+
+419
+00:34:24,140 --> 00:34:28,600
+equilibrium constant و لاحظ معايا C squared لإن في
+
+420
+00:34:28,600 --> 00:34:35,110
+اتنين جابل ال CA هي هي B² لأنه في اتنين قبل ال B
+
+421
+00:34:35,110 --> 00:34:40,010
+باشي بتطلع C ايش تركيز ال C هي point two minus
+
+422
+00:34:40,010 --> 00:34:45,230
+اتنين X اذا point two minus اتنين X الكل تربيه على
+
+423
+00:34:45,230 --> 00:34:52,680
+A اللي هي X مش مشكلةب هي تركيز بـ2X تربيع، إذا
+
+424
+00:34:52,680 --> 00:35:00,260
+بنعوض عن ال X value و بنقول point 2 أكبر كتير من
+
+425
+00:35:00,260 --> 00:35:06,170
+2Xالـ Point 2 أكبر كتير من الـ 2X كفرضية معناه
+
+426
+00:35:06,170 --> 00:35:12,030
+الكلام بنحسب الـ X بتساوي 1 في 10 أقص سالب 4
+
+427
+00:35:12,030 --> 00:35:16,350
+وبنوجه فان بنقول هذا فا بس يعني أعطانا قيمة الـ X
+
+428
+00:35:16,350 --> 00:35:20,990
+لكن هذا الكلام بدنا نثبت إذا كان الفرضية تبعتنا
+
+429
+00:35:20,990 --> 00:35:25,790
+كانت صحيحة ولا مش صحيحة فبنرجع إيش بنقول؟ بنقول ال
+
+430
+00:35:25,790 --> 00:35:30,190
+.. اه خدوا بالكم 2 احنا فرضنا الـ Point 2 أكبر
+
+431
+00:35:30,190 --> 00:35:39,660
+كتير من إيه؟من الـ 2x إذا باجي بقول 2x على 2 من 10
+
+432
+00:35:39,660 --> 00:35:43,580
+في 100 من 100 لأن أنا لغيت ال 2x بالنسبة لل 2 من
+
+433
+00:35:43,580 --> 00:35:47,440
+10 فبتقول 2 في x على ال point 2 في 100 من 100
+
+434
+00:35:47,440 --> 00:35:52,380
+بيطلع 1 من 10 في المية ال assumption طبعا valid مش
+
+435
+00:35:52,380 --> 00:35:57,000
+عندى مشكلة فيه ال a بتساوي ال x 1 في 10 أقل سالب 4
+
+436
+00:35:57,000 --> 00:36:02,830
+ال b 2x يعني 2 في 10 أقل سالب 4point two minus
+
+437
+00:36:02,830 --> 00:36:06,870
+اتنين X على الفاضي ليه؟ لأن طوا يقول إنها قليلة
+
+438
+00:36:06,870 --> 00:36:09,430
+جدًا بالنسبالي point two ولو اشتغلت significant
+
+439
+00:36:09,430 --> 00:36:12,970
+figures أيضًا هيطلع معاك إنه مافيش قيمة لعملية
+
+440
+00:36:12,970 --> 00:36:19,170
+الطرح وبالتالي point two molar لأنه
+
+441
+00:36:19,170 --> 00:36:24,910
+انا فربط اذا كان انت ملاحظ معايا فربط إن ال point
+
+442
+00:36:24,910 --> 00:36:29,370
+two أكبر كتير من ال اتنين X فهي ال اتنين X على ال
+
+443
+00:36:29,370 --> 00:36:36,960
+point twoفى مية من مية ايش
+
+444
+00:36:36,960 --> 00:36:41,240
+مالها ال 2x لأن
+
+445
+00:36:41,240 --> 00:36:45,820
+هي انت طالع عايش فيها عندى هنا point two minus ال
+
+446
+00:36:45,820 --> 00:36:51,940
+2x انا بتفترض انه هدول الجلالصح ولا لأ؟ عشان اتخلص
+
+447
+00:36:51,940 --> 00:36:55,400
+منهم لو فرضت ان ال X point أكبر من X واحدة كان
+
+448
+00:36:55,400 --> 00:36:58,040
+يمكن انه مش أكبر من ال 2X لكن انا بدأ افترض ان هو
+
+449
+00:36:58,040 --> 00:37:03,560
+أكبر من ال 2X صح ولا لأ؟ صح ولا لأ؟ فهي اللي حصل
+
+450
+00:37:03,560 --> 00:37:10,480
+طيب
+
+451
+00:37:10,480 --> 00:37:11,060
+يا شباب
+
+452
+00:37:14,570 --> 00:37:17,270
+دبل ما اعطيك مثال على نظرية خاطرة بدي اعطيك برضه
+
+453
+00:37:17,270 --> 00:37:22,090
+خليني اقفل عند هذه ال slide بدي اقول مثلا لو كان
+
+454
+00:37:22,090 --> 00:37:29,390
+عندك هذه point six مش point two بقول والله الآن
+
+455
+00:37:29,390 --> 00:37:33,670
+واضح ان الواحد من عشرة بتفعل بعد كده؟ 2 من 10 اذا
+
+456
+00:37:33,670 --> 00:37:37,090
+ايش بزيد؟ 4 من 10 يعني ممكن اكتب هذا 2 من 10 زائد
+
+457
+00:37:37,090 --> 00:37:45,240
+4 من 10 يبقى هذهبس هي اللي عاملة بتعملها، طيب لو
+
+458
+00:37:45,240 --> 00:37:49,240
+ايه؟
+
+459
+00:37:49,240 --> 00:37:53,600
+هو عارف يقول زائد، لأ، مالفعش، لإن كل اللي موجود
+
+460
+00:37:53,600 --> 00:37:58,080
+اتنين من عشرة منها، مالفعش يكون زائد، سالب، اه،
+
+461
+00:37:58,080 --> 00:37:58,500
+طيب
+
+462
+00:38:04,560 --> 00:38:08,440
+لأ مش واحد من عشرة لأن الواحد من عشرة بتفعل مع
+
+463
+00:38:08,440 --> 00:38:12,160
+اتنين من عشرة الواحد من عشرة بتفعل مع اتنين من
+
+464
+00:38:12,160 --> 00:38:16,400
+عشرة اتفهمت؟ عشان هي كتبت اتنين من عشرة زائد اربعة
+
+465
+00:38:16,400 --> 00:38:18,860
+من عشرة الاتنين من عشرة بتفعل مع الواحد من عشرة
+
+466
+00:38:18,860 --> 00:38:25,030
+والاربعة من عشرة بتنزل ماشي يا شبابابن يجيب نتطلع
+
+467
+00:38:25,030 --> 00:38:29,750
+الآن على فرض انه في عنا .. على فرض انه في عنا مثلا
+
+468
+00:38:29,750 --> 00:38:35,850
+خمسة من عشرة و .. و اتنين من عشرة ايش بده يكون في
+
+469
+00:38:35,850 --> 00:38:42,770
+عين دي؟ كيف؟ مع عشرة بتتطلع .. هي المعادلة اللي
+
+470
+00:38:42,770 --> 00:38:45,390
+عندك موجودة .. هذه مش خمسة .. مش واحد من عشرة ..
+
+471
+00:38:45,390 --> 00:38:49,470
+هذه خمسة من عشرة مولار و اتنين من عشرة .. انتبه
+
+472
+00:38:49,470 --> 00:38:50,810
+عليها شوية ..
+
+473
+00:38:53,340 --> 00:38:59,440
+كيف؟ اين هو اجل؟ الاتنين من عشرة اجل تلاتة من عشرة
+
+474
+00:38:59,440 --> 00:39:05,360
+زائد X و اتنين X تلاتة من عشرة زائد X ليش تلاتة من
+
+475
+00:39:05,360 --> 00:39:11,450
+عشرة؟4 من 10 ليش؟ لأن هذه الخمسة من عشرة أضارع عن
+
+476
+00:39:11,450 --> 00:39:15,910
+4 من 10 زائد 1 من 10 الواحد من عشرة بتفعل مع
+
+477
+00:39:15,910 --> 00:39:20,470
+التنين من عشرة لأن الواحد بتفعل مع اتنين اذا ايش
+
+478
+00:39:20,470 --> 00:39:27,470
+بدي يكون موجود هان؟ 4 من 10 سائد X دخلت بالك؟ بدك
+
+479
+00:39:27,470 --> 00:39:32,570
+تعرف تدبر حالك في هذه التحولات هي شغل سهل مش صعب
+
+480
+00:39:32,570 --> 00:39:34,170
+يعني كيف؟
+
+481
+00:39:36,200 --> 00:39:39,580
+طيب يا سيد إذا كان بيه تركيز إنت يا سيد مين يركز؟
+
+482
+00:39:39,580 --> 00:39:44,980
+لغة السؤال يكون
+
+483
+00:39:44,980 --> 00:39:49,660
+واضح زي اللغة الموجودة قدامك واضحة جدا يعني طيب
+
+484
+00:39:49,660 --> 00:39:52,600
+نجي نطلع على آخر مثال يا شباب و نعطيكم المثال اللي
+
+485
+00:39:52,600 --> 00:39:57,160
+بده يازميلكم لما يكون ال equilibrium constant يعني
+
+486
+00:39:57,160 --> 00:40:02,900
+متوسط بنقول in the reaction حاول نختصر شوية طيب
+
+487
+00:40:03,980 --> 00:40:08,320
+بنقول in the reaction A plus B بيعطينا C زائد D
+
+488
+00:40:08,320 --> 00:40:12,900
+وناخد نفس المتاريج اللي أخدناها سابقا فبقول if 0.2
+
+489
+00:40:12,900 --> 00:40:18,380
+mole of A is mixed with 0.5 mole of B in one liter
+
+490
+00:40:18,380 --> 00:40:23,800
+بيقول find the concentration of A, B, C and Dأت
+
+491
+00:40:23,800 --> 00:40:26,020
+ايكوليبريام ال ايكوليبريام constant of the
+
+492
+00:40:26,020 --> 00:40:30,820
+reaction is تلاتة من عشرة بقول والله تلاتة من عشرة
+
+493
+00:40:30,820 --> 00:40:34,260
+يعني هيكون appreciable amount من ال reactants و
+
+494
+00:40:34,260 --> 00:40:38,820
+appreciable amount من ال products لكن في طريقة
+
+495
+00:40:38,820 --> 00:40:42,640
+الحل ايش قلنا بدنا نعتبر وكأنه
+
+496
+00:40:47,710 --> 00:40:53,890
+المتفاعلات بتبقى كما هي وتتحول جزء يسير جدا منها
+
+497
+00:40:53,890 --> 00:40:54,810
+إلى نواتج
+
+498
+00:40:58,120 --> 00:41:00,740
+بتفرضش العكس، بقولك طريقة الحل بالشكل اللي بقولك
+
+499
+00:41:00,740 --> 00:41:05,460
+إياه، تفترض إنه تنحل على الحالة الأولى، اللي هي
+
+500
+00:41:05,460 --> 00:41:08,700
+تفترض إنه وكأنه ال equilibrium constant، تفرض إنه
+
+501
+00:41:08,700 --> 00:41:12,720
+مش كبير يعني صغير جدا، مش كبير يعني صغير جدا، نفس
+
+502
+00:41:12,720 --> 00:41:16,410
+الكلام اللي جفناه في الحالة الأولىطيب نيجي نطلع
+
+503
+00:41:16,410 --> 00:41:22,030
+على الجدول بنقول a و b بتعطينا c و d point to
+
+504
+00:41:22,030 --> 00:41:25,350
+point five قبل ال equilibrium بعد ال equilibrium
+
+505
+00:41:25,350 --> 00:41:28,630
+مما انه احنا في ترابعة احنا في ترابعة ان الحل على
+
+506
+00:41:28,630 --> 00:41:31,890
+الحالة الأولى يعني point two minus x point five
+
+507
+00:41:31,890 --> 00:41:36,650
+minus x يعني كأن المتفاعلاتبعيلة زي ما هي ولكن
+
+508
+00:41:36,650 --> 00:41:40,730
+اتحول جزء ياسير جدا منها لنواتج فبنقول بيعطينا X و
+
+509
+00:41:40,730 --> 00:41:43,590
+X من هذا الكلام طبعا شوفنا المثال السابق كان كيف
+
+510
+00:41:43,590 --> 00:41:49,090
+بنحل هو نفس الطريقة K بتساوي C في ال D على ال A في
+
+511
+00:41:49,090 --> 00:41:54,410
+ال B X في X على 0.2 minus X 0.5 minus X نجي نعمل
+
+512
+00:41:54,410 --> 00:41:59,830
+فرضية بنختار الأصغر 0.2 minus X بدنا .. بنقول يعني
+
+513
+00:41:59,830 --> 00:42:05,040
+ال 0.2 أكبر كتير من ال X إذاالـ 0.3 اللي هو ال
+
+514
+00:42:05,040 --> 00:42:09,820
+equilibrium constant سوى X تربيع على 0.2 times 0.5
+
+515
+00:42:09,820 --> 00:42:15,600
+ال X بتطلع 0.17 ال
+
+516
+00:42:15,600 --> 00:42:20,900
+X 0.17 احنا بدنا نجيب ال relative error فبنقول ال
+
+517
+00:42:20,900 --> 00:42:26,920
+relative error 0.17 على 0.2 في 100 من 100 بتطلع 87
+
+518
+00:42:26,920 --> 00:42:33,320
+%طبعا 87% نسبة خطأ يعني هذا ايش لا يغتفر يعني خطأ
+
+519
+00:42:33,320 --> 00:42:38,680
+مش ممكن اي حد يرضعلك بالنسبة خطأ 87% فاش بتقول على
+
+520
+00:42:38,680 --> 00:42:44,770
+طول the assumption isinvalid or unacceptable غير
+
+521
+00:42:44,770 --> 00:42:50,450
+مقبول غير صحيح and we must not neglect X وضبيعي
+
+522
+00:42:50,450 --> 00:42:54,010
+أنه لا يمكن أنه نلغي ال X جانب ال 2 من 10 in
+
+523
+00:42:54,010 --> 00:42:57,510
+comparison with 0.2 therefore the equilibrium
+
+524
+00:42:57,510 --> 00:43:02,090
+should be as follows رجعناها زي أول و حلينا
+
+525
+00:43:02,090 --> 00:43:04,970
+المعادلة يعني جمعناها و طلعنا ال quadratic
+
+526
+00:43:04,970 --> 00:43:10,780
+equation المعادلة التربيعية و روحناللقانون العام
+
+527
+00:43:10,780 --> 00:43:14,100
+اللى هى ال X بتسوى minus B الجزر التربيه على B
+
+528
+00:43:14,100 --> 00:43:20,820
+squared minus 4AC على 2A لما ينحلوا باستخدام
+
+529
+00:43:20,820 --> 00:43:24,880
+القانون بطلع عندى ال X بقداش واحد من عشر point one
+
+530
+00:43:24,880 --> 00:43:29,880
+one molar طبعا ماهي ما .. ماحنا جولنا مابنعملهاش
+
+531
+00:43:29,880 --> 00:43:37,230
+مابنعملهاشلأ كيف تعمل بالنسبة لـ 0.2؟ زيها يعني
+
+532
+00:43:37,230 --> 00:43:43,410
+تقريبا نصها فالـ A تطلع 0.2 minus 0.11 تطلع 0.09
+
+533
+00:43:43,410 --> 00:43:50,650
+ال B تطلع 0.5 minus 0.11 بتسوء 0.39 ال C و ال D
+
+534
+00:43:50,650 --> 00:43:56,790
+بتسوء 0.11 مدار المستوين كل واحدة فيهم X هذه هي
+
+535
+00:43:56,790 --> 00:44:00,150
+طريقة الحل يا شباب لكن أنا بدي ألفة انتباهكم لنقطة
+
+536
+00:44:01,090 --> 00:44:06,470
+دائما إذا كان ال equilibrium constant مش كبير و مش
+
+537
+00:44:06,470 --> 00:44:12,290
+صغير، دائما هتطلع ال relative error عالية، وضع
+
+538
+00:44:12,290 --> 00:44:17,500
+طبيعي، وضع طبيعي لأن كيف؟نسبة الخطأ هتطلع اكتر من
+
+539
+00:44:17,500 --> 00:44:21,780
+5% دائما اذا كان ايه؟ اذا كان ال equilibrium
+
+540
+00:44:21,780 --> 00:44:24,800
+constant لهو كبير ولا هو صغير فنسبة الخطأ دائما
+
+541
+00:44:24,800 --> 00:44:29,960
+هتكون شمالها هتكون دائما فيها مشكلة يعني مش هتطلع
+
+542
+00:44:29,960 --> 00:44:34,460
+اقل من 5% لأ هتكون اكبر من 5% وبالتالي يجب انه
+
+543
+00:44:34,460 --> 00:44:37,920
+الحل باستخدام ال quadratic equationلكن إحنا في
+
+544
+00:44:37,920 --> 00:44:41,900
+الحل إيش هنسوي؟ بمجرد ما يطلع عنا ال relative
+
+545
+00:44:41,900 --> 00:44:47,800
+error أكبر من 5% حسبنا، هنيجي إيش نقول؟ هنقول the
+
+546
+00:44:47,800 --> 00:44:52,220
+assumption is إيش؟ invalid or unacceptable
+
+547
+00:44:52,220 --> 00:44:58,390
+therefore لهذا السبب we should useThe quadratic
+
+548
+00:44:58,390 --> 00:45:03,150
+equation، نقطة، نقطة، مش هنحل هذا الكلام، مش
+
+549
+00:45:03,150 --> 00:45:08,190
+هنطلع، مش هنطلع يعني إيش بيسموها ال quadratic
+
+550
+00:45:08,190 --> 00:45:11,970
+equation، يعني بحنقعد بس لهان، مش هنطلع ال X بهذه
+
+551
+00:45:11,970 --> 00:45:15,680
+الطريقةمش هنقلع ال quadratic equation نفسها لأ
+
+552
+00:45:15,680 --> 00:45:19,720
+احنا بس هنوصل لهان طلعنا ال relative error اكتر من
+
+553
+00:45:19,720 --> 00:45:23,680
+خمسة في المية ايش هنقول؟ هنقول the assumption is
+
+554
+00:45:23,680 --> 00:45:29,480
+invalid or unacceptable therefore we should use
+
+555
+00:45:29,480 --> 00:45:34,100
+the quadratic equation ونقطة مش هنكمل حل المسألة
+
+556
+00:45:34,100 --> 00:45:37,900
+اه مش هنكمل بس هنجفلهان ايه كويس؟ سواء كان في
+
+557
+00:45:37,900 --> 00:45:43,910
+امتحان او كان في واجبيبقى مادام اكتر من 5% انتهينا
+
+558
+00:45:43,910 --> 00:45:50,050
+طيب يا شباب في حد عنده سؤال هيك من الكون خلصنا
+
diff --git a/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/qoNm4V0vKyQ.srt b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/qoNm4V0vKyQ.srt
new file mode 100644
index 0000000000000000000000000000000000000000..7fed0373df25cfa60b37f78b48ac2ca1cc46a2f0
--- /dev/null
+++ b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/qoNm4V0vKyQ.srt
@@ -0,0 +1,1366 @@
+1
+00:00:22,250 --> 00:00:25,630
+اليوم إن شاء الله بنكمل في الـ Redox equilibria و
+
+2
+00:00:25,630 --> 00:00:30,340
+titrations، بنتكلم بشكل أساسي عن الـ cell potential
+
+3
+00:00:30,340 --> 00:00:33,660
+لكن قبل ما نبدأ نتكلم عن الـ cell potential، بحب بس
+
+4
+00:00:33,660 --> 00:00:39,680
+أذكركم أنه في الحصة الماضية كنا تعرّفنا على الـ
+
+5
+00:00:39,680 --> 00:00:43,980
+Redox reactions وكيف بنستخدم الـ oxidation numbers
+
+6
+00:00:43,980 --> 00:00:47,460
+عشان نعرف إذا كان عندنا Redox reaction أو لا، نعرف
+
+7
+00:00:47,460 --> 00:00:52,400
+الـ oxidation process والـ reduction process، وكمان
+
+8
+00:00:52,400 --> 00:00:58,980
+تعلمنا أو راجعنا كيف نوزّن المعادلات الـ electro-
+
+9
+00:00:58,980 --> 00:01:00,680
+chemical equations
+
+10
+00:01:02,710 --> 00:01:10,190
+بعدين تعرّفنا على إيش يعني half cell، إيش يعني half-
+
+11
+00:01:10,190 --> 00:01:13,910
+cell potential، وكيف ممكن نجيبها، وقلنا أنه عشان
+
+12
+00:01:13,910 --> 00:01:17,310
+نقدر نجيب الـ half cell potential، لابد من وجود
+
+13
+00:01:17,310 --> 00:01:24,250
+electrode قياسي أو standard half cell، فقدمنا لكم
+
+14
+00:01:25,150 --> 00:01:27,830
+الـ Standard Hydrogen Electrode أو الـ Normal
+
+15
+00:01:27,830 --> 00:01:31,670
+Hydrogen Electrode، اللي قلنا أنه الـ potential
+
+16
+00:01:31,670 --> 00:01:35,870
+تبعه صفر، طبعًا at standard state، وهذا الصفر
+
+17
+00:01:35,870 --> 00:01:40,310
+arbitrarily chosen، يعني إحنا اخترناه بشكل اختياري
+
+18
+00:01:40,740 --> 00:01:47,980
+وعلى أساس استخدام الـ SHE، استطعنا تكوين جداول،
+
+19
+00:01:47,980 --> 00:01:53,300
+الجداول هذه فيها كم كبير جدًا من الـ standard
+
+20
+00:01:53,300 --> 00:01:56,540
+reduction potential أو الـ standard electrode
+
+21
+00:01:56,540 --> 00:02:03,420
+potential، اللي يعني بتعالج تقريبًا معظم الـ half-
+
+22
+00:02:03,420 --> 00:02:06,840
+cells المعروفة أو الـ half reactions المعروفة
+
+23
+00:02:06,840 --> 00:02:14,690
+بالنسبة لنا على أنها Redox half cells، فقلنا إنه إذا
+
+24
+00:02:14,690 --> 00:02:19,370
+كان بنكون خلية، الخلية دي مكوّنة من two electrodes،
+
+25
+00:02:19,370 --> 00:02:24,070
+واحد منهم الـ SHE، فبالضرورة القراءة لـ الـ potential
+
+26
+00:02:24,070 --> 00:02:28,070
+للخلية هي القراءة الخاصة بالـ other electrode، لأنه
+
+27
+00:02:28,070 --> 00:02:34,580
+حسب التعريف، الـ SHE كان الـ potential تبعه صفر أيضًا
+
+28
+00:02:34,580 --> 00:02:38,840
+شفنا في الحصة الماضية كيف ممكن نعرف إذا كان تفاعل
+
+29
+00:02:38,840 --> 00:02:42,760
+ماشي بيمشي ولا لأ، قلنا إنه بنجيب التفاعل لنصين، و
+
+30
+00:02:42,760 --> 00:02:47,320
+بنرتّب النص اللي له E note أعلى فوق، والنص اللي له
+
+31
+00:02:47,320 --> 00:02:50,980
+E note أقل تحت، وبعدين بنعمل بيضونال من أقصى
+
+32
+00:02:50,980 --> 00:02:55,730
+اليسار لأقصى اليمين، هذا هو التفاعل اللي بيحصل، هذا
+
+33
+00:02:55,730 --> 00:02:58,350
+هو التفاعل، إيش يعني بيحصل؟ يعني بيحصل
+
+34
+00:02:58,350 --> 00:03:03,250
+spontaneously، تلقائيًا، وبالتالي بيعطيني جهود،
+
+35
+00:03:03,250 --> 00:03:07,150
+يعني هذا بيكون… هذا بيكون في… بهذا الطريقة
+
+36
+00:03:07,150 --> 00:03:11,630
+بيكون Galvanic Cell، الكاثود positive، والأنود
+
+37
+00:03:11,630 --> 00:03:19,190
+negative، اليوم بنكمل بنقول والله يعني إحنا لو بدنا
+
+38
+00:03:19,190 --> 00:03:24,310
+نعالج الموضوع بحيادية تامة، بنقول إن الـ SHE هذا
+
+39
+00:03:24,310 --> 00:03:28,950
+يعني standard electrode صحيح وممتاز جدًا، لكن للأسف
+
+40
+00:03:28,950 --> 00:03:34,310
+التعامل معه صعب ليه؟ لأنه أنا بدي أحاول إني دائمًا
+
+41
+00:03:34,310 --> 00:03:39,170
+أثبت الـ hydrogen hydrogen gas flow عند واحد
+
+42
+00:03:39,170 --> 00:03:43,510
+atmosphere، طبعًا hydrogen gas flow في جو مختبر الـ
+
+43
+00:03:43,510 --> 00:03:48,270
+hydrogen نفسه، يعني بيشتعل، يعني لو أحد ولّع عود
+
+44
+00:03:48,270 --> 00:03:53,770
+كبريت، لو أحد ولّع flame بنزين، flame أو غيره، لو أحد
+
+45
+00:03:53,770 --> 00:03:57,650
+استخدم جداحة لأي سبب، ممكن إنه يحصل عندنا نوع من
+
+46
+00:03:57,650 --> 00:04:01,580
+الانفجار، هذه حاجة… أيضًا التفاعل ليس كثير سريع،
+
+47
+00:04:01,580 --> 00:04:06,000
+التفاعل الـ H2 يتحول لـ 2H بلس و2H… مش سريع
+
+48
+00:04:06,000 --> 00:04:10,540
+كثير، وبالتالي بنستخدم طبعًا Platinized Platinum
+
+49
+00:04:10,540 --> 00:04:18,020
+فاستخدام الـ SHE مقلق، يعني مش سهل، عشان هيك معظم
+
+50
+00:04:18,020 --> 00:04:22,370
+جامعات العالم ما فيش فيها SHE، طبعًا عندنا في الجامعة
+
+51
+00:04:22,370 --> 00:04:26,450
+الثانوية أكيد ما فيش SHE، ولا عمره كان عندنا SHE، لكن
+
+52
+00:04:26,450 --> 00:04:30,030
+أيضًا في الجامعات العريقة، ممكن نلاقي… من أفضل
+
+53
+00:04:30,030 --> 00:04:33,310
+الجامعات في العالم ما فيش فيها SHE، طب ها كيف هذه
+
+54
+00:04:33,310 --> 00:04:38,810
+الجامعات، وكيف هدول العلماء الكبار، كيف بيجيبوا الـ
+
+55
+00:04:38,810 --> 00:04:45,410
+potential إذا كان ما فيش عندهم SHE؟ فبنقول
+
+56
+00:04:45,410 --> 00:04:50,290
+في حاجة بنسميها reference electrodes، reference يعني
+
+57
+00:04:50,290 --> 00:04:55,750
+إلكترودات مرجعية، فيها نوعين من أنواع الـ reference
+
+58
+00:04:55,750 --> 00:04:59,670
+electrodes المستخدمة بكثرة في المختبرات والجامعات
+
+59
+00:04:59,670 --> 00:05:05,330
+ومراكز الأبحاث وغيره، هدول الـ two electrodes،
+
+60
+00:05:05,330 --> 00:05:09,790
+واحد منهم اسمه saturated calomel electrode،
+
+61
+00:05:13,490 --> 00:05:17,730
+اللي شايفينه قدامنا هو عبارة عن انتفاخ من الزجاج،
+
+62
+00:05:17,730 --> 00:05:22,610
+موجود فيه مكونات تفاعل Mercury Chloride،
+
+63
+00:05:25,740 --> 00:05:33,000
+مركوري وكلوريد، هذا الـ reaction،
+
+64
+00:05:33,000 --> 00:05:41,820
+محاط بـ saturated KCl solution، وبينه وبين المحلول
+
+65
+00:05:41,820 --> 00:05:47,760
+عشان يكون فيه نوع من الانتقال الأيوني، فيه فَرِيط أو
+
+66
+00:05:47,760 --> 00:05:53,190
+asbestos fiber، ممكن في أغلب الأحيان نلاقي فِرايكِر،
+
+67
+00:05:53,190 --> 00:05:58,910
+مادة مسامية بحيث أنه تسمح بانتقال الأيونات، لكن
+
+68
+00:05:58,910 --> 00:06:02,490
+المحلول ما بينتقلش خلالها مش على طول، والمحلول بينزل
+
+69
+00:06:02,490 --> 00:06:09,050
+لـ… الأيونات هنا ممكن تتحرّك يعني بدرجة كافية اللي
+
+70
+00:06:09,050 --> 00:06:14,440
+تعمل توصيل، هذا الفَرِيط أو الـ Asbestos Fiber أو
+
+71
+00:06:14,440 --> 00:06:20,100
+الفَرِيط الفِيكوري عمومًا يمكن
+
+72
+00:06:20,100 --> 00:06:24,100
+استبدال الـ Salt Bridge فيه، يعني بدل الـ Salt
+
+73
+00:06:24,100 --> 00:06:27,500
+Bridge، هذا كافي لأنه يعمل فصل بين المحلولين،
+
+74
+00:06:27,500 --> 00:06:30,720
+المحلولين اللي داخل الإلكترود والمحلول اللي أريد
+
+75
+00:06:30,720 --> 00:06:35,080
+أن أجيب الـ potential، فبستغنى على الـ Salt Bridge
+
+76
+00:06:35,080 --> 00:06:38,780
+أو بستغنى على الـ Semi-permeable membrane، فهذا هو
+
+77
+00:06:38,780 --> 00:06:42,920
+أحد أنواع الـ Reference Electrodes المستخدم بكثرة،
+
+78
+00:06:42,920 --> 00:06:46,700
+بنقوله Saturated Calomel electrode، وهذا…
+
+79
+00:06:46,700 --> 00:06:49,760
+الأشياء اللي بنتذكرها المهمة بالنسبة لنا، لو جبنا
+
+80
+00:06:49,760 --> 00:06:54,300
+Saturated Calomel electrode وحطّيناه مع الـ SHE في
+
+81
+00:06:54,300 --> 00:07:00,420
+خلية، راح ألاحظ أنه الـ potential لـ Saturated
+
+82
+00:07:00,420 --> 00:07:04,550
+Calomel electrode موجب، 0.242 ملي فولت،
+
+83
+00:07:04,550 --> 00:07:08,330
+0.242 ملي فولت موجب، 0.242
+
+84
+00:07:08,330 --> 00:07:13,030
+ملي فولت، يعني في هذه الحالة بيكون الـ
+
+85
+00:07:13,030 --> 00:07:18,030
+standard Calomel electrode هو الكاثود، والـ SHE
+
+86
+00:07:18,030 --> 00:07:21,570
+هو الأنود، لكن المهم الفرق بينهم جداش 0.242
+
+87
+00:07:21,570 --> 00:07:25,870
+ملي فولت، فيه إنّه electrode تاني برضه مهم
+
+88
+00:07:25,870 --> 00:07:32,390
+جدا اسمه Ag/AgCl reference electrode،
+
+89
+00:07:33,940 --> 00:07:39,180
+هذا لو حطّيناه بنفس الطريقة، تكوين ونفس الطريقة لكن
+
+90
+00:07:39,180 --> 00:07:42,420
+عبارة عن silver wire، الـ silver wire هذا بيكون فيه
+
+91
+00:07:42,420 --> 00:07:49,620
+عليه طبقة من الـ AgCl، فهذا Ag/AgCl، وهي عندنا…
+
+92
+00:07:49,620 --> 00:07:56,640
+مثلاً بدي بس أعكسه شوية، بدي أخلي هنا الـ SHE
+
+93
+00:07:56,640 --> 00:08:05,420
+وهنا الـ Ag/AgCl، لو حطّينا voltmeter بينهم بنلاحظ
+
+94
+00:08:05,420 --> 00:08:11,400
+إن الـ potential هنا 0.199 millivolt، يعني 0.199
+
+95
+00:08:11,400 --> 00:08:17,120
+volt، إذا تلقائيًا الـ Ag/AgCl electrode هذا
+
+96
+00:08:17,120 --> 00:08:20,180
+عبارة عن reference electrode، دائمًا الـ potential
+
+97
+00:08:20,180 --> 00:08:23,220
+تبعته ثابتة، وعشان هيك هو reference، في أي محلول
+
+98
+00:08:23,220 --> 00:08:28,180
+بنحطه، الـ potential تبعته ثابتة، 0.199 من level، وأيضًا
+
+99
+00:08:28,180 --> 00:08:31,700
+الـ saturated calomel electrode، الـ potential تبعته
+
+100
+00:08:31,700 --> 00:08:35,680
+ثابت، عشان هيك هو reference، جداش الـ potential تبعته
+
+101
+00:08:35,680 --> 00:08:41,740
+دائمًا 0.242، يعني الاثنين أكثر من الـ SHE، الـ SHE صفر،
+
+102
+00:08:41,740 --> 00:08:47,390
+هو… 0.199 لـ Ag/AgCl، 0.242
+
+103
+00:08:47,390 --> 00:08:53,350
+لـ saturated calomel electrode، لو
+
+104
+00:08:53,350 --> 00:09:02,630
+جينا مثلاً، أنا بقول والله ما فيش عندي SHE، ما فيش عندي
+
+105
+00:09:02,630 --> 00:09:07,770
+SHE في المختبرات، طيب كيف ممكن أوجد الـ standard
+
+106
+00:09:07,770 --> 00:09:13,130
+electrode potential؟ يعني مثلاً الـ zinc، تو إلكترود
+
+107
+00:09:13,130 --> 00:09:15,930
+بعطيني zinc solid، كيف بدي أوجد الـ electrode
+
+108
+00:09:15,930 --> 00:09:21,050
+potential؟ هذا مش معروف، على فرض مش معروف عنا، كيف
+
+109
+00:09:21,050 --> 00:09:25,410
+بدي أوجده؟ أنا عندي مثلاً standard calomel electrode،
+
+110
+00:09:25,410 --> 00:09:31,810
+كويس، عندي standard calomel electrode، لو إجيت وصلته
+
+111
+00:09:33,140 --> 00:09:36,760
+نتكلم في البداية عن الـ Ag/AgCl، لأنه معايا هي،
+
+112
+00:09:36,760 --> 00:09:41,260
+وعندي هي المرسومة، بقول على فرض أنه عندي Ag/AgCl،
+
+113
+00:09:41,260 --> 00:09:47,900
+electrode، روحت حطّيت الـ Ag/AgCl electrode مع my
+
+114
+00:09:47,900 --> 00:09:52,800
+electrode اللي هو الـ zinc solid، وهي الـ zinc
+
+115
+00:09:52,800 --> 00:10:00,580
+المحلول، لو حطّيناهم مع بعض، بلاقي إن القراءة سالب
+
+116
+00:10:00,580 --> 00:10:06,780
+0.961، لاحظ أنت في البداية إن الـ Ag/
+
+117
+00:10:06,780 --> 00:10:16,740
+AgCl عن الـ SHE 0.199 volts، كويس،
+
+118
+00:10:16,740 --> 00:10:23,360
+بالنسبة لـ 0.199 volts، طيب إيش لما
+
+119
+00:10:23,360 --> 00:10:23,980
+نجي؟
+
+120
+00:10:27,010 --> 00:10:31,410
+لما أنا آجي أوجد
+
+121
+00:10:31,410 --> 00:10:37,210
+أو يعني أجيب جداش الـ potential ما بين الـ Ag/AgCl
+
+122
+00:10:37,210 --> 00:10:42,410
+والـ zinc، راح أحصل على هذه القيمة كلها 0.96
+
+123
+00:10:42,410 --> 00:10:48,970
+1، 0.961، لكن أنا الـ E note إيش
+
+124
+00:10:48,970 --> 00:10:52,850
+بنجيبها؟ هذه هي الـ E note اللي هي بين الـ SHE و your
+
+125
+00:10:52,850 --> 00:10:58,730
+electrode، هذه هي الـ E note، أنا بدي الـ E note، فأنا
+
+126
+00:10:58,730 --> 00:11:02,950
+استخدمت الـ Ag/AgCl مع الـ zinc، أعطتني هذه القيمة،
+
+127
+00:11:02,950 --> 00:11:07,770
+لكن هذه القيمة عبارة عن مجموعتين، تان المسافة من
+
+128
+00:11:07,770 --> 00:11:12,430
+هنا لهنا، زائد المسافة من هنا لهنا، المسافة هذه هي
+
+129
+00:11:12,430 --> 00:11:18,100
+الـ E note، إذا هذه القراءة ناقص اللي هي 0.1
+
+130
+00:11:18,100 --> 00:11:22,620
+99 volts، بتعطينا الـ E note، عشان هيك الـ E
+
+131
+00:11:22,620 --> 00:11:27,460
+note راح تجي 0.762، يعني هي هذه هنا،
+
+132
+00:11:27,460 --> 00:11:32,510
+هذه بتكون 0.762 بالسالب، هذه الأصل
+
+133
+00:11:32,510 --> 00:11:39,130
+تكون 0.199، بالمجموع
+
+134
+00:11:39,130 --> 00:11:43,310
+0.9 أو الـ E note، الـ E هي عبارة عن E للـ
+
+135
+00:11:43,310 --> 00:11:47,730
+cathode ناقص E للـ anode، فبقول بده يطلع 0.
+
+136
+00:11:47,730 --> 00:11:52,070
+961، 0.961، الـ 0.96
+
+137
+00:11:52,070 --> 00:11:55,170
+1 هذا عبارة عن حاجتين، عبارة عن هذه المسافة، هذا
+
+138
+00:11:55,170 --> 00:11:58,410
+الـ volt، وعبارة عن هذه المسافة، فأنا عارف إن هذا
+
+139
+00:11:58,410 --> 00:12:04,250
+0.199، إذا بتطرح، بتطلع الـ SHE
+
+140
+00:12:04,250 --> 00:12:09,030
+للإلكترود تبعي، بتطلع عندي -0.762
+
+141
+00:12:09,030 --> 00:12:13,870
+volts، نعم هي
+
+142
+00:12:13,870 --> 00:12:19,410
+بالسالب، إيش معنى السالب؟ معناته إن الـ Ag/AgCl هو
+
+143
+00:12:19,410 --> 00:12:23,110
+الكاثود فقط، يعني هذا الـ schematic بفرجيك أنت
+
+144
+00:12:23,110 --> 00:12:27,510
+كيف تحسب الإشارة، بتعرفك بس إيش هو الكاثود وإيش
+
+145
+00:12:27,510 --> 00:12:32,250
+هو الأنود، لكن كيف بدك تحسب؟ بقول المسافة هذه كلها 0.
+
+146
+00:12:32,250 --> 00:12:38,830
+961، أنا بدي هذه المسافة، إذا الـ 0.961 ناقص الـ 0.
+
+147
+00:12:38,830 --> 00:12:43,550
+199، هذا بيعطيك المسافة من your electrode للـ SHE، و
+
+148
+00:12:43,550 --> 00:12:50,210
+بما إن your electrode هنا على يسار الـ SHE، هيك أنا
+
+149
+00:12:50,210 --> 00:12:56,960
+بأخذ الـ Ag/AgCl هيك سالب، هيك موجب، بمعنى إيه؟ بمعنى إنه
+
+150
+00:12:56,960 --> 00:13:00,240
+إذا كان الـ electrode اللي أنا بجيبُه على يسار الـ Ag/
+
+151
+00:13:00,240 --> 00:13:05,860
+AgCl فهو سالب، إذا كان على يمينه فهو موجب، بأخذ
+
+152
+00:13:05,860 --> 00:13:12,940
+بالنسبة نفس الكلام الـ SHE هيك سالب، هيك موجب، فالمهم
+
+153
+00:13:12,940 --> 00:13:15,580
+ببساطة خالص، إحنا خلّينا نقول إنه
+
+154
+00:13:18,640 --> 00:13:23,060
+عملية القياس سهلة جدًا، عملية القياس سهلة جدًا، بجيب
+
+155
+00:13:23,060 --> 00:13:28,180
+الـ Ag/AgCl مع my electrode، بيعطيني قيمة كويسة، لكن
+
+156
+00:13:28,180 --> 00:13:31,680
+أنا ما بدي هذه القيمة، أنا بدي بس من الـ SHE، إذا بدي
+
+157
+00:13:31,680 --> 00:13:36,080
+أقرأ هذه القيمة منه، خلاص، طيب أعطيكم كمان مثال،
+
+158
+00:13:36,080 --> 00:13:46,300
+أعطيكم كمان مثال، لو إجيت… خلّينا نستخدم الـ مثلاً،
+
+159
+00:13:47,530 --> 00:13:53,970
+هي الـ SCE، وهي your electrode، بدي وليكن الـ iron،
+
+160
+00:13:53,970 --> 00:13:57,550
+يبقى فيه عندي iron تلاتة، وفيه عندي iron اتنين،
+
+161
+00:13:57,550 --> 00:14:00,750
+plus، كل واحد فيهم واحد molar، وأنا بدي أجيب الـ E
+
+162
+00:14:00,750 --> 00:14:06,600
+note، هي الـ SCE، وهذا بيكون platinum، لأنه ما فيش عندي
+
+163
+00:14:06,600 --> 00:14:12,300
+iron solid في الـ equation، فمش عندي iron solid،
+
+164
+00:14:12,300 --> 00:14:14,960
+وبالتالي بيكون platinum indicator electrode أو
+
+165
+00:14:14,960 --> 00:14:20,440
+working electrode، ماشي، بقول… بقول نيجي نتطلع، بقول
+
+166
+00:14:20,440 --> 00:14:23,680
+the potential of the following half-cell reaction،
+
+167
+00:14:23,680 --> 00:14:27,400
+at standard state، اللي هي هيها، was measured versus
+
+168
+00:14:27,400 --> 00:14:32,610
+SCE، versus saturated calomel electrode، giving a
+
+169
+00:14:32,610 --> 00:14:36,730
+value of 0.529 موجب، يعني لما أنا استخدم الـ SCE
+
+170
+00:14:36,730 --> 00:14:42,230
+وأعطتني قراءة موجبة، معناته هي على إيه؟ على يمين
+
+171
+00:14:42,230 --> 00:14:49,650
+يعني الـ SHE هو الأنود، والـ SCE
+
+172
+00:14:49,650 --> 00:14:53,150
+هو الأنود، والـ other electrode هو الكاثود، ليه؟ لأن
+
+173
+00:14:53,150 --> 00
+
+223
+00:19:11,490 --> 00:19:16,870
+reference electrodes تم قياسهم against اللي هو ال
+
+224
+00:19:16,870 --> 00:19:20,510
+SHE ومعروف جدًّا ال potential تبعهم، هذا ألف بقى
+
+225
+00:19:20,510 --> 00:19:25,530
+يعني ماشي، إذا انجد هذه المسافة هذه معروفة، وهذه
+
+226
+00:19:25,530 --> 00:19:29,070
+معروفة، بس بنجيب هذه، مالفرق، هذه ناقص هذه، فبيقول ال
+
+227
+00:19:29,070 --> 00:19:36,070
+point 242 minus point 103 بيعطيني point 139 volts
+
+228
+00:19:36,070 --> 00:19:43,130
+أو 139 millivolts، إذا بنقدر بسهولة نحول من
+
+229
+00:20:02,510 --> 00:20:06,230
+الخلية اللي عندي الآن صارت أبسط كثير في وجود ال
+
+230
+00:20:06,230 --> 00:20:11,750
+reference electrodes لأن
+
+231
+00:20:11,750 --> 00:20:17,370
+كل اللي لازم نعمل إلكترود في بيكر، واحد منهم هو ال
+
+232
+00:20:17,370 --> 00:20:21,110
+reference electrode، لازم أجيب خلية فيها semi
+
+233
+00:20:21,110 --> 00:20:24,290
+permeable membrane، ولازم أجيب خلية فيها salt
+
+234
+00:20:24,290 --> 00:20:29,490
+bridge لأن ال salt bridge هي موجودة هنا في ال
+
+235
+00:20:29,490 --> 00:20:32,950
+reference electrode، في آخره في عندي جولنة زي Fret
+
+236
+00:20:32,950 --> 00:20:39,010
+Vicar Fret أو Asbestos Fiber، هي اللي بتخلي أو
+
+237
+00:20:39,010 --> 00:20:43,210
+بتسمح للأيونات أنه تنتقل من المحلول للقطب، أو من
+
+238
+00:20:43,210 --> 00:20:45,230
+القطب للمحلول
+
+239
+00:21:01,300 --> 00:21:05,520
+والـ reference electrode وبجيب على طول جدًّا فرق
+
+240
+00:21:05,520 --> 00:21:09,560
+الجهد ما بين الـ two electrodes، يعني هذا بالنسبة للـ
+
+241
+00:21:09,560 --> 00:21:13,400
+reference electrode، ولو حبيت أن أعمل relation ما
+
+242
+00:21:13,400 --> 00:21:19,220
+بينه وما بين الـ SHE بقى على الـ voltage line scale
+
+243
+00:21:19,220 --> 00:21:23,060
+اللي شفناه، الـ schematic اللي شفناه، بقدر أن أوجد الـ
+
+244
+00:21:23,060 --> 00:21:27,000
+potential versus saturated versus standard
+
+245
+00:21:27,000 --> 00:21:28,860
+hydrogen electrode
+
+246
+00:21:32,030 --> 00:21:38,530
+طيب، الآن لو سألنا حالنا سؤال، قلنا أن الـ
+
+247
+00:21:38,530 --> 00:21:44,010
+potential للخلية هي عبارة عن إيه؟ بنقول، معناه أن
+
+248
+00:21:44,010 --> 00:21:47,330
+الـ potential للخلية هي عبارة عن الـ E للـ cathode
+
+249
+00:21:47,330 --> 00:21:51,470
+ناقص الـ E للأنود، أو الـ E right ناقص الـ E left
+
+250
+00:21:51,470 --> 00:21:56,130
+وقلنا أن دائمًا الـ cathode على اليمين، والأنود على
+
+251
+00:21:56,130 --> 00:22:01,290
+اليسار، عشان هيك الـ E right ناقص E left بتصدرلكن،
+
+252
+00:22:01,290 --> 00:22:06,110
+لكن، بنقول إنه مش دائمًا أنا لازم أرسم الخلية علشان
+
+253
+00:22:06,110 --> 00:22:09,030
+أشوف إيش اللي على اليمين، وإيش اللي على اليسار، ولا
+
+254
+00:22:09,030 --> 00:22:13,350
+لازم أني أقعد أكتب يعني كلام طويل جدًّا يعبر لي عن
+
+255
+00:22:13,350 --> 00:22:17,010
+الخلية، إيش هي الخلية، يوصفها، اللي يعني ممكن نعمل
+
+256
+00:22:17,010 --> 00:22:21,490
+حاجة بنقولها cell representation، يعني تمثيل الخلية
+
+257
+00:22:21,490 --> 00:22:27,370
+بخط، سطر واحد بس، بيمثل إيه الخلية، وبيعبر عنها تعبير
+
+258
+00:22:27,370 --> 00:22:31,560
+كامل، الـ cell representation، مثلًا الخلية اللي قدامي
+
+259
+00:22:31,560 --> 00:22:36,360
+إذا كان تركيز الزنك كلوريد point two molar، أو
+
+260
+00:22:36,360 --> 00:22:40,480
+تركيز النحاس كبريتات point one molar، نيجي نطلع إيش
+
+261
+00:22:40,480 --> 00:22:45,700
+نشوف كيف بتمثل هذه الخلية المرسومة قدامي على هيئة
+
+262
+00:22:45,700 --> 00:22:51,360
+يعني سطر واحد بس، بيعبر عنها تعبير كامل، بقول ببدأ
+
+263
+00:22:51,360 --> 00:22:55,320
+دائمًا بالأنود، أو باليسار، لأنه بكتب بالإنجليزي أنا
+
+264
+00:22:55,320 --> 00:22:59,760
+فمن اليسار لليمين، فبقول، بدأت هذه الخلية عند الـ zinc
+
+265
+00:22:59,760 --> 00:23:04,120
+الـ solid، فهنا بدأت zinc solid، تمام، الآن بدي
+
+266
+00:23:04,120 --> 00:23:07,400
+أتكلّم في إيه؟ في المحلول، بدي أخلص الخلية هذه هيك
+
+267
+00:23:07,400 --> 00:23:11,180
+بدي أمشي، أنا لما أنا أخلص الخلية، صح ولا لأ؟ هذه
+
+268
+00:23:11,180 --> 00:23:14,300
+هذه الـ zinc، هيك بدي أعدي من الـ salt bridge، أعدي
+
+269
+00:23:14,300 --> 00:23:18,270
+هنا، هذه الخلية تبعتي، تعالوا وناخد ونمشي هذا
+
+270
+00:23:18,270 --> 00:23:22,610
+المسار خطوة خطوة، الـ zinc solid هذا هو، خلّصناه، إجينا
+
+271
+00:23:22,610 --> 00:23:26,390
+بدنا نروح على المحلول، انتقلنا من صلب إلى
+
+272
+00:23:26,390 --> 00:23:31,790
+phase آخر، اللي هو solution، من صلب، من phase صلب لـ
+
+273
+00:23:31,790 --> 00:23:40,310
+phase solution، هنا بحط خط عمودي، هذا اسمه phase
+
+274
+00:23:40,310 --> 00:23:42,850
+boundary، هذا بيقول لي أنك تنتقل من phase لـ
+
+275
+00:23:42,850 --> 00:23:46,650
+phase، أنت انتقلت من phase لـ phase، هذا الخط معناته
+
+276
+00:23:46,650 --> 00:23:49,930
+هنا انتقلت من الـ solid، عديت على المحلول، بدي أحط خط
+
+277
+00:23:49,930 --> 00:23:54,570
+أنه إيه، انتقلت أنا من الـ solid لإيه؟ للمحلول، طب
+
+278
+00:23:54,570 --> 00:23:58,870
+عديت على المحلول، انتقلت فيه، بدي أجي أنتقل، بدي أكمل
+
+279
+00:23:58,870 --> 00:24:01,450
+بدي أروح على الـ salt bridge، الـ salt bridge هي
+
+280
+00:24:01,450 --> 00:24:05,550
+عبارة عن التمثيل تبعها، الخطين هدول اللي قدامي، هذه
+
+281
+00:24:05,550 --> 00:24:11,630
+هي الـ salt bridge، فش خط مائل عندنا، فش خط مقلوب فيه،
+
+282
+00:24:11,630 --> 00:24:15,690
+خط عمودي هيو، هذا phase boundary، اسمه أنه انتقلت من
+
+283
+00:24:15,690 --> 00:24:20,690
+solid لـ solution، من solution لـ solid، هذا الـ phase
+
+284
+00:24:20,690 --> 00:24:25,730
+boundary، بمشي في المحلول، بلّغ الـ salt bridge هنا
+
+285
+00:24:25,730 --> 00:24:29,530
+عديت في الـ salt bridge، خلّصت المحلول، ماشي، هي
+
+286
+00:24:29,530 --> 00:24:36,440
+المحلول، المحلول إيش هذا؟ هذا copper sulfate، فالزنك
+
+287
+00:24:36,440 --> 00:24:40,220
+وصلت كمان مرة، بنعدي في المحلول، إيش المحلول فيه؟ فيه
+
+288
+00:24:40,220 --> 00:24:45,220
+زنك كلوريد، جدًّا تركيزه point two molar، طب ماشي
+
+289
+00:24:45,220 --> 00:24:48,840
+عديت، وصلت الـ salt bridge، هذه خطين، إيش الـ gate هنا؟
+
+290
+00:24:48,840 --> 00:24:53,180
+فيه copper sulfate، جدًّا تركيزه واحد من عشرة molar، طب
+
+291
+00:24:53,180 --> 00:24:57,080
+هنا عديت، وصلت هذا الـ gate، الـ phase
+
+292
+00:24:57,080 --> 00:25:01,960
+boundary، في عندي خط هذا، هوبعدين copper solid، بتكون
+
+293
+00:25:01,960 --> 00:25:07,780
+الخلية هيك خلصت، الخلية هيك خلصت، فإيش معناتها؟
+
+294
+00:25:07,780 --> 00:25:13,380
+معناته إنه والله solid zinc electrode immersed in
+
+295
+00:25:13,380 --> 00:25:18,860
+zinc chloride solution، concentration تبعه point
+
+296
+00:25:18,860 --> 00:25:23,640
+two molar، هذا الأنود لأنه على اليسار، وفي عندي salt
+
+297
+00:25:23,640 --> 00:25:30,600
+bridge، وفي عندي copper wire immersed in point one
+
+298
+00:25:30,600 --> 00:25:33,480
+molar copper sulfate solution، وهذا الإيه؟ هذا الـ
+
+299
+00:25:33,480 --> 00:25:37,160
+cathode؟ لو بدي أجي أجيب... هذه هي خلية تبعتي
+
+300
+00:25:37,160 --> 00:25:40,060
+المرسومة، أنا لو بدي أجي أجيب أنا الـ potential لهذه
+
+301
+00:25:40,060 --> 00:25:44,400
+الخلية، بدي أقول والله E للـ cathode اللي هو اليمين،
+
+302
+00:25:44,400 --> 00:25:50,470
+E right ناقص E left، E للـ copper solution ناقص E
+
+303
+00:25:50,470 --> 00:25:56,070
+للـ zinc، ماشي يا شباب، إذا أنا لو أجيت كتبتها
+
+304
+00:25:56,070 --> 00:26:00,250
+بشكل معكوس، copper solid، copper sulfate، بعدين zinc
+
+305
+00:26:00,250 --> 00:26:04,790
+chloride، zinc، بتكون الخلية معكوسة، يبقى هتعطيني
+
+306
+00:26:04,790 --> 00:26:09,130
+إشارة مخالفة للخلية الأولى، يتجه زي ما بتنكتب
+
+307
+00:26:09,130 --> 00:26:13,450
+الخلية، زي ما بطلع الـ E، الـ potential تبعها دائمًا E
+
+308
+00:26:13,450 --> 00:26:17,990
+right ناقص E left، يمكن أول مرة يمر معنا أن
+
+309
+00:26:17,990 --> 00:26:22,890
+التركيزات اللي أخذناها، ما كتبناش واحد molar، يعني
+
+310
+00:26:22,890 --> 00:26:30,370
+تركيزات مش قياسية، والسؤال اللي بنسأله، مدام
+
+311
+00:26:30,370 --> 00:26:36,480
+عند التركيزات مش قياسية، تعالوا نسأل سؤال، تغيير
+
+312
+00:26:36,480 --> 00:26:41,580
+التركيز يؤثر على الـ potential، يعني أنا كنت بستخدم
+
+313
+00:26:41,580 --> 00:26:47,340
+standard concentrations، يعني دائمًا واحد molar، أو
+
+314
+00:26:47,340 --> 00:26:52,980
+pressures واحد أتموسفير، فهل تغيير التركيز يؤثر على
+
+315
+00:26:52,980 --> 00:26:59,530
+الـ potential ولا لأ؟ بنقول، تغيير التركيز بالطبع
+
+316
+00:26:59,530 --> 00:27:03,810
+بيأثر على الـ potential، ويعني هذا المفتاح قدامنا
+
+317
+00:27:03,810 --> 00:27:11,750
+يعني آفاق كثير كثير ممتازة، الشخص
+
+318
+00:27:11,750 --> 00:27:16,550
+أو العالم اللي تحدّث عن كيفية تغير الـ potential مع
+
+319
+00:27:16,550 --> 00:27:23,250
+التغيير في الـ concentration هو نيرنست، نيرنست، نيرنست
+
+320
+00:27:23,250 --> 00:27:28,370
+عمل معادلة، أنا بعتبرها من أفضل، يعني من يعني أهم
+
+321
+00:27:28,370 --> 00:27:33,130
+المعادلات في الـ electro analytical chemistry، ليه؟
+
+322
+00:27:33,130 --> 00:27:37,750
+لأنه بتعطيني علاقة بين الـ concentration والـ
+
+323
+00:27:37,750 --> 00:27:44,470
+potential، وإحنا ممكن نعرف هذا الكلام، ممكن نعرف
+
+324
+00:27:44,470 --> 00:27:47,850
+يعني
+
+325
+00:27:47,850 --> 00:27:54,770
+هذا الكلام عن طريق أنه لو أخذنا تفاعل ما... لو
+
+326
+00:27:54,770 --> 00:27:58,230
+أخذنا تفاعل ما، التفاعل هذا بيقول لي a من A وb من
+
+327
+00:27:58,230 --> 00:28:03,520
+B زائد n electrons بتعطينا c من C وd من D، لو أخذنا
+
+328
+00:28:03,520 --> 00:28:08,700
+هذا التفاعل، وقلنا بدنا نجيب الـ E له، نيرنست
+
+329
+00:28:08,700 --> 00:28:12,560
+equation، إيش بتقول؟ بتقول إن الـ E، الـ potential لهذا
+
+330
+00:28:12,560 --> 00:28:16,260
+التفاعل بتساوي الـ E°، standard equilibrium
+
+331
+00:28:16,260 --> 00:28:19,500
+potential، إيش يعني الـ standard equilibrium
+
+332
+00:28:19,500 --> 00:28:23,320
+potential؟ هذا الـ potential لما A وB وC وD كل
+
+333
+00:28:23,320 --> 00:28:26,700
+تركيزاتهم إيش تكون؟ كل واحد فيهم واحد molar، واحد
+
+334
+00:28:26,700 --> 00:28:28,980
+molar، واحد molar، كويس؟
+
+335
+00:28:31,210 --> 00:28:34,670
+فهذه E بتساوي الـ E°، standard equilibrium
+
+336
+00:28:34,670 --> 00:28:39,510
+Potential ناقص RT على NF لن الـ reaction quotient، يعني C أس C، D أس D على A أس A، B أس B
+
+337
+00:28:39,510 --> 00:28:44,210
+reaction quotient، اللي هو عبارة عن
+
+338
+00:28:44,210 --> 00:28:51,220
+نوع من حاصل ضرب المتفاعلات، كل واحد مرفوع لأس اللي بيناسب
+
+339
+00:28:51,220 --> 00:28:54,980
+عدد المولات تبعته، الـ K، الـ equilibrium constant هو
+
+340
+00:28:54,980 --> 00:28:59,900
+الـ reaction quotient، لأن إحنا يعني ما نعرفش إذا كان
+
+341
+00:28:59,900 --> 00:29:03,020
+التفاعل وصل equilibrium ولا لأ، يعني بنتكلم عن الـ
+
+342
+00:29:03,020 --> 00:29:06,720
+reaction quotient بشكل عام، بنقول إيش هي الـ R؟ الـ R
+
+343
+00:29:06,720 --> 00:29:12,160
+هي عبارة عن الـ molar gas constant، اللي هي 8.314
+
+344
+00:29:12,160 --> 00:29:18,800
+8.314، الـ T اللي هي الـ temperature بالـ Kelvin، يعني
+
+345
+00:29:18,800 --> 00:29:24,940
+الـ degree C زائد 273، الـ F اللي هي ثابت فاراداي
+
+346
+00:29:24,940 --> 00:29:30,980
+ثابت فاراداي، اللي هو 96485 coulomb per equivalent، الـ N
+
+347
+00:29:30,980 --> 00:29:38,060
+هي عدد الإلكترونات per mole، عدد الإلكترونات per
+
+348
+00:29:38,060 --> 00:29:42,340
+mole، إحنا لما نيجي نعوض عن الـ R بقيمتها، لما نعوض
+
+349
+00:29:50,060 --> 00:29:55,720
+عن الـ T عند 25 degree C، يعني 298 Kelvin، لما نعوض
+
+350
+00:29:55,720 --> 00:29:58,880
+عن الـ F بـ 96485
+
+351
+00:30:00,800 --> 00:30:04,200
+بيعطينا... ونعوض كمان عن اللي... نغيرها... نحولها
+
+352
+00:30:04,200 --> 00:30:08,080
+لـ log، لما نحول اللي اللي لـ log بدي أضرب في 2.303
+
+353
+00:30:08,080 --> 00:30:13,800
+لما نعمل هذا الكلام، بلاحظ أنه هذه القيمة بتصير 0
+
+354
+00:30:13,800 --> 00:30:19,360
+.0592 على N log
+
+355
+00:30:19,360 --> 00:30:26,400
+الـ reaction quotient اللي إحنا حكينا عنه، هذه معادلة
+
+356
+00:30:26,400 --> 00:30:27,560
+السيد نيرنست
+
+357
+00:30:39,250 --> 00:30:43,730
+الـ C أس C، D أس D، A أس A، B أس B، انتبهوا شوية،
+
+358
+00:30:43,730 --> 00:30:48,370
+الآن يا شباب، على فرض أن A وB وC وD واحد مولار كل
+
+359
+00:30:48,370 --> 00:30:53,830
+واحدة فيهم، يبقى log الواحد بيساوي صفر، يبقى راح كل
+
+360
+00:30:53,830 --> 00:30:57,250
+هذا الكلام، إذا الـ E صارت بتساوي الـ E°، يبقى
+
+361
+00:30:57,250 --> 00:31:00,710
+آه صح هذا الكلام، لأن الـ E بتساوي الـ E° لما
+
+362
+00:31:00,710 --> 00:31:05,430
+يكون عندي standard conditions، مش هيك؟ آه، لكن لو
+
+363
+00:31:05,430 --> 00:31:12,890
+اتغيرت التركيزات، بلاحظ أنه الـ E هتتغير، طيب نيجي
+
+364
+00:31:12,890 --> 00:31:18,130
+نشوف تطبيق على هذا الكلام، نيجي نطلع على تطبيق على
+
+365
+00:31:18,130 --> 00:31:23,510
+هذا الكلام، نشوف إيش بيقول لي؟ بيقول لي calculate the
+
+366
+00:31:23,510 --> 00:31:27,450
+electrode potential for the half cell below
+
+367
+00:31:30,830 --> 00:31:39,770
+إذا كانت المحاليل تحتوي على 0.1 مولار
+
+368
+00:31:39,770 --> 00:31:44,970
+نحاس 2 بلس، فبقول والله half cell reaction هي نحاس 2
+
+369
+00:31:44,970 --> 00:31:48,090
+بلس زائد 2 إلكترون بيعطينا نحاس، هذا الكلام بجيبه على
+
+370
+00:31:48,090 --> 00:31:53,930
+طول، يعني، أو هو معطى في السؤال، E° تبعته 0.342
+
+371
+00:31:54,520 --> 00:31:59,560
+أنا بدّي الـ E، E° معي، أنا بدي الـ E، يعني
+
+372
+00:31:59,560 --> 00:32:04,720
+لما أنا أجي أستخدم تركيز من النحاس 0.1 molar بدل
+
+373
+00:32:04,720 --> 00:32:09,040
+1 molar، كيف الـ potential بدها تتغير؟ بقول والله الـ
+
+374
+00:32:09,040 --> 00:32:13,820
+E بتساوي الـ E° ناقص 0.0592 على N log النحاس
+
+375
+00:32:13,820 --> 00:32:16,280
+solid، اللي هي النواتج على المتفاعلات، طبعًا النحاس
+
+376
+00:32:16,280 --> 00:32:20,880
+solid لا يكتب ضمن الـ equilibrium لأنه تركيزه ثابت
+
+377
+00:32:20,880 --> 00:32:26,920
+لا يتغير، يعني، فعادة بنحط واحد، طب ما أجي أعوض، أنا بقول
+
+378
+00:32:26,920 --> 00:32:30,340
+E بتساوي الـ E°، هذه الـ E° at standard state
+
+379
+00:32:30,340 --> 00:32:33,420
+أو standard conditions، point three four two ناقص
+
+380
+00:32:33,420 --> 00:32:36,760
+point oh five nine two على N، N هيها والله اثنين
+
+381
+00:32:36,760 --> 00:32:42,800
+إلكترون، log واحد على النحاس 2 بلس، واحد من عشرة،
+
+382
+00:32:42,800 --> 00:32:47,320
+بلاحظ أنه بيطلع عندي الـ E بتساوي point three one
+
+383
+00:32:47,320 --> 00:32:52,180
+two، إذا اتغيرت
+
+384
+00:32:52,180 --> 00:32:56,880
+الـ potential في وجود point one molar نحاس، عامة
+
+385
+00:32:56,880 --> 00:32:59,720
+كانت عليه لما كانت one molar نحاس، لما كانت one
+
+386
+00:32:59,720 --> 00:33:03,600
+molar نحاس، كان log واحد على واحد بيساوي صفر، يبقى كل هذا
+
+387
+00:33:03,600 --> 00:33:11,090
+راح، لما كانت واحد مولار نحاس، كان log الواحد على واحد
+
+388
+00:33:11,090 --> 00:33:15,530
+مولار، معناته log الواحد بصفر، واحد على واحد بواحد،
+
+389
+00:33:15,530 --> 00:33:19,590
+log الواحد بصفر، إذا الـ E بدها تساوي الـ E°،
+
+390
+00:33:19,590 --> 00:33:22,970
+وهذا طبعًا وضع طبيعي، ليه؟ لأن الـ E بتساوي الـ E°
+
+391
+00:33:22,970 --> 00:33:27,290
+at standard
\ No newline at end of file
diff --git a/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/tK31Pig9Ny8.srt b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/tK31Pig9Ny8.srt
new file mode 100644
index 0000000000000000000000000000000000000000..3180ef0f8c71850597b1107e2017fbd9bd775192
--- /dev/null
+++ b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/tK31Pig9Ny8.srt
@@ -0,0 +1,2017 @@
+1
+00:00:20,910 --> 00:00:24,810
+بقى شوية بالحصة الماضية كنا بدأنا نتكلم عن ال
+
+2
+00:00:24,810 --> 00:00:29,690
+stoichiometric calculations ووصلنا لطرق التعبير عن
+
+3
+00:00:29,690 --> 00:00:33,410
+ال concentration فاتكلمنا عن ال molarity وشوفنا أن
+
+4
+00:00:33,410 --> 00:00:37,510
+ال molarity هي عبارة عن number of moles of solute
+
+5
+00:00:37,510 --> 00:00:42,870
+dissolved in one liter of solution وقلنا من هذا
+
+6
+00:00:42,870 --> 00:00:49,750
+الكلام قلنا أنه ممكن نقول ال millimoles تساوي ال
+
+7
+00:00:49,750 --> 00:00:52,990
+molarity في ال volume بالمل وهذه كانت علاقة مهمة
+
+8
+00:00:52,990 --> 00:00:56,950
+جدا. أكملت العلاقة السابقة اللي كنا بنقول ال
+
+9
+00:00:56,950 --> 00:01:01,110
+millimole بتساوي milligram من ال substance على ال
+
+10
+00:01:01,110 --> 00:01:04,510
+formula weight. اليوم بنكمل في نفس السياق، نتكلم
+
+11
+00:01:04,510 --> 00:01:09,810
+عن normality calculations لكن اليوم فقط هنتكلم
+
+12
+00:01:09,810 --> 00:01:13,810
+عن مقدمة في ال normality وسنعود لنفس الموضوع في
+
+13
+00:01:13,810 --> 00:01:18,210
+المستقبل بعد محاضرات قليلة إن شاء الله. إيش
+
+14
+00:01:18,210 --> 00:01:20,830
+المقصود بال normality؟ ال normality زي ال molarity
+
+15
+00:01:20,830 --> 00:01:27,550
+هي عبارة عن وحدة أو مصطلح يُراد به التعبير عن
+
+16
+00:01:27,550 --> 00:01:32,330
+التركيز، تعبير عن التركيز. كيف يمكن أن نعرف ال
+
+17
+00:01:32,330 --> 00:01:35,810
+normality؟ يمكن تعريف ال normality على أنها number
+
+18
+00:01:35,810 --> 00:01:40,730
+of equivalents of solute dissolved in one liter of
+
+19
+00:01:40,730 --> 00:01:44,080
+solution. لكن لما نتكلم نقول والله number of
+
+20
+00:01:44,080 --> 00:01:49,240
+equivalents، فإيش هو ال equivalent؟ هذا يعني لازم
+
+21
+00:01:49,240 --> 00:01:52,200
+نعرفه؛ لأن احنا بيقول number of moles، بنعرف ال mole
+
+22
+00:01:52,200 --> 00:01:57,340
+لكن number of equivalents، لسة احنا ما درسناش إيش
+
+23
+00:01:57,340 --> 00:02:03,020
+يعني equivalent. فممكن تعريف ال equivalent على أنه
+
+24
+00:02:03,020 --> 00:02:08,540
+ال equivalent بيساوي ال
+
+25
+00:02:08,540 --> 00:02:14,510
+number of grams على ال equivalent weight. number of
+
+26
+00:02:14,510 --> 00:02:18,330
+grams of solute طبعا على ال equivalent weight، فهذا
+
+27
+00:02:18,330 --> 00:02:21,170
+يُعطينا number of equivalents. طيب number of grams
+
+28
+00:02:21,170 --> 00:02:23,930
+of solute، هذه مفهومة، لكن إيش هو ال equivalent
+
+29
+00:02:23,930 --> 00:02:27,490
+weight؟ برضه ما حلينا مشكلة. جاء ال equivalent
+
+30
+00:02:27,490 --> 00:02:33,970
+weight هو عبارة عن ال formula weight على n، حيث أن
+
+31
+00:02:33,970 --> 00:02:40,040
+هذه عبارة عن number of reacting units. number of
+
+32
+00:02:40,040 --> 00:02:46,320
+reacting units، عدد الوحدات المتفاعلة. برضه يعني
+
+33
+00:02:46,320 --> 00:02:49,700
+الموضوع مش واضح بالنسبة لنا؛ لأن عدد الوحدات
+
+34
+00:02:49,700 --> 00:02:52,560
+المتفاعلة، زي إيش؟ يعني ممكن نقول والله إذا كان عندي
+
+35
+00:02:52,560 --> 00:02:56,180
+تفاعل acid base، فعدد الوحدات المتفاعلة ممكن تكون
+
+36
+00:02:56,180 --> 00:03:01,360
+والله protons (H+)، أو hydroxides. لو كان عندي
+
+37
+00:03:01,360 --> 00:03:04,560
+تفاعل أكسدة أو اختزال، فعدد الوحدات المتفاعلة
+
+38
+00:03:04,560 --> 00:03:11,120
+electrons. فبرضه هذا يتوقف على التفاعل. عشان هيك لما
+
+39
+00:03:11,120 --> 00:03:15,980
+نقول احنا ال normality هي عدد ال equivalence من ال
+
+40
+00:03:15,980 --> 00:03:19,220
+solute المذابة في ال liter، وال equivalent هو عبارة
+
+41
+00:03:19,220 --> 00:03:22,140
+عن جرامات solute على ال equivalent weight، وال
+
+42
+00:03:22,140 --> 00:03:25,320
+equivalent weight هو عبارة عن formula weight على N،
+
+43
+00:03:25,320 --> 00:03:31,170
+عدد من ال reacting units. هذه جِدّة، يعني الحسابات
+
+44
+00:03:31,170 --> 00:03:37,730
+تبعنا ليست حسابات مباشرة، وتتوقف بشكل أساسي على نوع
+
+45
+00:03:37,730 --> 00:03:41,570
+التفاعل اللي ال solute أو المادة اللي عندي بدها
+
+46
+00:03:41,570 --> 00:03:45,780
+تُعدِيه. عشان هيك يا شباب، يمكن كان هذا من الدوافع
+
+47
+00:03:45,780 --> 00:03:53,600
+المهمة خلف يعني التقليل من استخدام ال normality
+
+48
+00:03:53,600 --> 00:03:57,040
+لدرجة أننا الآن في الكيمياء التحليلية ما نستخدمش
+
+49
+00:03:57,040 --> 00:03:59,780
+ال normality في الحسابات تبعاتنا، عادة لا نستخدمها
+
+50
+00:03:59,780 --> 00:04:05,610
+في الحسابات تبعاتنا. الآن نستخدم فقط ال molarity، مش
+
+51
+00:04:05,610 --> 00:04:09,170
+ال normality. طيب مدام بنستخدم احنا ال molarity، مش
+
+52
+00:04:09,170 --> 00:04:12,590
+ال normality، واستخدام ال normality
+
+53
+00:04:12,590 --> 00:04:16,830
+يمكن في الـ... يعني أصبح ضئيل جدا ومحدود للغاية في
+
+54
+00:04:16,830 --> 00:04:20,290
+الأربعين سنة اللي فاتوا تقريبا، أو في الثلاثين سنة
+
+55
+00:04:20,290 --> 00:04:24,270
+أو أكثر اللي فاتوا. فليش إحنا بندرسها؟ ليش ندرس ال
+
+56
+00:04:24,270 --> 00:04:28,420
+normality إذًا؟ مدام توقفنا عن استخدامها تقريبا، فليش
+
+57
+00:04:28,420 --> 00:04:32,660
+ندرسها؟ نقول دراستها مهمة جدا؛ لأن كل ال
+
+58
+00:04:32,660 --> 00:04:38,360
+literature السابق في عشرات السنوات الماضية، و
+
+59
+00:04:38,360 --> 00:04:43,660
+القرون الماضية، يعني آخر قرنين تقريبا، كل الدراسات
+
+60
+00:04:43,660 --> 00:04:47,040
+اللي كانت بتتم كانت بتتم باستخدام ال normality. فهل
+
+61
+00:04:47,040 --> 00:04:52,350
+يعقل أن... يعني لا نلقي بالا للنتائج اللي العلماء من
+
+62
+00:04:52,350 --> 00:04:56,290
+قديم الزمان حصلوا عليها، وأصبحت لنا يعني مكتبة
+
+63
+00:04:56,290 --> 00:05:00,210
+قيمة جدا من النتائج المختلفة. فلا يجوز إلا أن طبعا
+
+64
+00:05:00,210 --> 00:05:03,930
+نهمل هذه النتائج. عشان هيك لازم نفهم إيش يعني
+
+65
+00:05:03,930 --> 00:05:07,390
+normality، وكيف نستخدمها، وإيش معنى النتائج اللي
+
+66
+00:05:07,390 --> 00:05:12,490
+علماؤنا السابقين حصلوا عليها. هذا جانب من الجوانب
+
+67
+00:05:12,490 --> 00:05:17,580
+والجانب الآخر صحيح، إحنا في الكيمياء نفضل عدم
+
+68
+00:05:17,580 --> 00:05:21,120
+استخدام ال normality ولا نوصي باستخدامها، لكن
+
+69
+00:05:21,120 --> 00:05:27,060
+للأسف بعض الأنظمة الأخرى، كمثلا الطب، أو جزء مهم من
+
+70
+00:05:27,060 --> 00:05:32,680
+ال biochemistry والتحاليل الطبية، البيئة في بعض
+
+71
+00:05:32,680 --> 00:05:36,560
+الأحيان، نجد أن هناك علماء يستخدموا، لازالوا
+
+72
+00:05:36,560 --> 00:05:40,800
+يستخدموا بشكل أساسي ال normality. فطبعا أيضا لا
+
+73
+00:05:40,800 --> 00:05:46,140
+يُعقل أن نُغفل النتائج تبعتهم. لأ، علشان هيك
+
+74
+00:05:46,140 --> 00:05:49,720
+إحنا لازم نفهم ال normality بشكل واضح وجيد جدا
+
+75
+00:05:50,270 --> 00:05:53,530
+وفي نفس الوقت لا ندعو لاستخدامها، بالعكس ندعو
+
+76
+00:05:53,530 --> 00:05:57,050
+الجميع للاقتصار على استخدام ال molarity، خاصة في العصر
+
+77
+00:05:57,050 --> 00:06:02,050
+الحديث اللي أصبح يعني فيه نوع من العالمية في
+
+78
+00:06:02,050 --> 00:06:07,710
+العلوم، وهناك مؤسسات عالمية بتوصي باستخدام يعني
+
+79
+00:06:07,710 --> 00:06:11,550
+أساليب معينة للتعبير عن التركيز، واحنا في الأوساط
+
+80
+00:06:11,550 --> 00:06:15,530
+العلمية الكيميائية، نوصي باستخدام ال molarity، مش
+
+81
+00:06:15,530 --> 00:06:22,910
+ال normality. ماشي يا شباب؟ طيب نتكلم أكثر عن إيش
+
+82
+00:06:22,910 --> 00:06:26,590
+يعني reacting unit؟ reacting unit إحنا بنقول والله
+
+83
+00:06:26,590 --> 00:06:32,270
+عدد الوحدات المتفاعلة. لما نكون عندي مثلا acid زي
+
+84
+00:06:32,270 --> 00:06:37,370
+ال HCl، إيش فيه ممكن يتفاعل؟ ما فيش إلا البروتون
+
+85
+00:06:37,370 --> 00:06:41,110
+الپروتون. في acid base بيتفاعل البروتون. كم البروتون
+
+86
+00:06:41,110 --> 00:06:45,290
+فيه عندي؟ واحد. لما نكون فيه عندي واحد، ما فيش قدامه
+
+87
+00:06:45,290 --> 00:06:48,890
+خيار إلا إنه بس الواحد ده يتفاعل. عشان هيك عادة ال
+
+88
+00:06:48,890 --> 00:06:53,850
+HCl معروف تفاعله، بده يتفاعل مثلا أي حاجة لو بفقد
+
+89
+00:06:53,850 --> 00:06:57,590
+البروتون واحد. وبالتالي لما نقول ال equivalent
+
+90
+00:06:57,590 --> 00:07:02,450
+weight بيساوي formula weight على N، N بالنسبة لل HCl
+
+91
+00:07:02,450 --> 00:07:05,850
+دائما واحد. ليه؟ لأنه ما فيش عنده غير بروتون، مش
+
+92
+00:07:05,850 --> 00:07:08,630
+معقول يتفاعلوا إثنين بروتون، لأنه ما فيش عنده إلا
+
+93
+00:07:08,630 --> 00:07:12,150
+بروتون واحد. فمثلا ال HCl دائما ال formula weight
+
+94
+00:07:12,150 --> 00:07:16,470
+بتساوي ال equivalent weight. لو جئنا لل nitric
+
+95
+00:07:16,470 --> 00:07:19,170
+acid، لل perchloric acid، نفس الكلام، في ال acid
+
+96
+00:07:19,170 --> 00:07:22,950
+base reaction تبعهم، ال equivalent weight هو ال
+
+97
+00:07:22,950 --> 00:07:28,040
+formula weight. كبُدّاز، لما نقول والله عندي ال sodium
+
+98
+00:07:28,040 --> 00:07:31,460
+hydroxide، كم hydroxide في ال sodium hydroxide؟ إذًا
+
+99
+00:07:31,460 --> 00:07:33,560
+برضه نفس الكلام، ال equivalent weight هو ال formula
+
+100
+00:07:33,560 --> 00:07:37,060
+weight على واحد، يعني هو ال formula weight. نفس
+
+101
+00:07:37,060 --> 00:07:40,480
+الكلام، ال ammonia مثلا، ال ammonia معروفة عبارة عن
+
+102
+00:07:40,480 --> 00:07:46,320
+قاعدة. مع كم H+ بتتفاعل؟ مع كم H+ بتتفاعل؟
+
+103
+00:07:46,320 --> 00:07:49,980
+بتتفاعل مع واحد، بيعطي NH4+، NH4، واحد موجب فوقها يعني، فبتتفاعل بس مع واحد
+
+104
+00:07:49,980 --> 00:07:53,440
+عشان هيك، برضه الأمونيا هي عبارة عن مادة، base، ال
+
+105
+00:07:53,440 --> 00:07:59,720
+equivalent weight لها دائما بيساوي ال formula
+
+106
+00:07:59,720 --> 00:08:01,820
+weight، لأنه لا تتفاعل إلا فقط مع بروتون واحد. لكن
+
+107
+00:08:07,770 --> 00:08:14,910
+مثلا لو كان في عندنا، خلينا نقول sulfuric acid، H2SO4
+
+109
+00:08:14,910 --> 00:08:19,390
+قال والله ممكن يتفاعل مع sodium hydroxide واحد
+
+110
+00:08:19,390 --> 00:08:24,150
+وبالتالي يعطينا sodium hydrogen sulfate. وفي هذه
+
+111
+00:08:24,150 --> 00:08:27,170
+الحالة إذا كان تفاعل بس مع واحد sodium hydroxide
+
+112
+00:08:27,170 --> 00:08:31,990
+معناته بده يفقد بروتون واحد، صح؟ معناته ال
+
+113
+00:08:31,990 --> 00:08:33,770
+equivalent weight بيساوي ال formula weight على
+
+114
+00:08:33,770 --> 00:08:37,770
+واحد. مش هيك، لأن number of reacting units، ال
+
+115
+00:08:37,770 --> 00:08:40,470
+reacting units يا إما بروتونات يا إما هيدروكسيد
+
+116
+00:08:40,470 --> 00:08:43,350
+اللي دخل في التفاعل. فدخل بس بروتون واحد، إذًا
+
+117
+00:08:43,350 --> 00:08:47,730
+formula weight على واحد. طيب
+
+118
+00:08:47,730 --> 00:08:50,650
+ال sulfuric acid لو تفاعل مع excess sodium
+
+119
+00:08:50,650 --> 00:08:56,890
+hydroxide، يعني sodium hydroxide كثير بزيادة، كم
+
+120
+00:08:56,890 --> 00:09:01,830
+بروتون منه هيتفاعل؟ إذا عدد ال reacting units من
+
+121
+00:09:01,830 --> 00:09:05,730
+المفروض يكون إثنين. يبقى ال equivalent weight يساوي في
+
+122
+00:09:05,730 --> 00:09:10,430
+هذه الحالة formula weight على إثنين. نفس الكلام لو
+
+123
+00:09:10,430 --> 00:09:14,490
+حكينا عن الفوسفوريك أسيد. ممكن الفوسفوريك أسيد يتفاعل
+
+124
+00:09:14,490 --> 00:09:21,290
+مع واحد sodium hydroxide ويعطي NaH2PO4. تفاعل بس مع
+
+125
+00:09:21,290 --> 00:09:24,230
+واحد sodium hydroxide، يعني بروتون واحد فقط اللي
+
+126
+00:09:24,230 --> 00:09:28,630
+تفاعل. معناته في هذه الحالة، الفوسفوريك أسيد ال
+
+127
+00:09:28,630 --> 00:09:30,890
+equivalent weight له بيساوي ال formula weight على
+
+128
+00:09:30,890 --> 00:09:34,930
+واحد. ممكن الفوسفوريك أسيد يتفاعل مع إثنين sodium
+
+129
+00:09:34,930 --> 00:09:40,670
+hydroxide، وفي هذه الحالة بحصل على Na2HPO4.
+
+130
+00:09:40,670 --> 00:09:44,170
+في هذه الحالة ال equivalent weight للفوسفوريك أسيد
+
+131
+00:09:44,170 --> 00:09:49,090
+بيساوي ال formula weight على إثنين. وفي الحالة يعني
+
+132
+00:09:49,090 --> 00:09:52,970
+الأخيرة ممكن نقول أنه خلينا الفوسفوريك أسيد يتفاعل مع
+
+133
+00:09:52,970 --> 00:09:57,350
+ثلاثة مولز من إيش؟ من ال sodium hydroxide، ساعتها
+
+134
+00:09:57,350 --> 00:10:02,270
+هيعطينا Na3PO4، sodium phosphate. في هذه
+
+135
+00:10:02,270 --> 00:10:06,310
+الحالة ال equivalent weight للفوسفوريك أسيد هيكون
+
+136
+00:10:06,310 --> 00:10:10,750
+formula weight على ثلاثة. إذًا يا شباب، معنى الكلام
+
+137
+00:10:10,750 --> 00:10:15,110
+ال equivalent weight يتوقف على نوع التفاعل اللي
+
+138
+00:10:15,110 --> 00:10:18,670
+بتتعدى المادة، على نوع التفاعل. طبعا ال reacting
+
+139
+00:10:18,670 --> 00:10:21,190
+units، وال reacting units تتوقف على نوع التفاعل اللي
+
+140
+00:10:21,190 --> 00:10:26,650
+بتتعدى المادة. عشان هيك ما أقدرش أقول لك مثلا حضر لي واحد
+
+141
+00:10:26,650 --> 00:10:31,250
+normal phosphoric acid. ممكن أقول لك حضر لي واحد مولار
+
+142
+00:10:31,250 --> 00:10:33,970
+فوسفوريك أسيد، بيقول لي سهل، باخذ واحد مول، بحطه
+
+143
+00:10:33,970 --> 00:10:37,990
+في لتر solution، واحد مولار، سهل كثير، باخذ واحد
+
+144
+00:10:37,990 --> 00:10:40,730
+مول، بحطه في لتر solution، بيعطينا واحد مولار
+
+145
+00:10:40,730 --> 00:10:44,430
+فوسفوريك أسيد، ما فيش مشكلة، لكن لما أنا أقول لك حضر لي
+
+146
+00:10:44,430 --> 00:10:50,650
+واحد normal phosphoric acid، ما ينفعش، لأنك بيبقى
+
+147
+00:10:50,650 --> 00:10:54,260
+بتوزنه وزنها، الوزن هو اللي بيبقى بتوزنه، بتعتمد على
+
+148
+00:10:54,260 --> 00:10:56,640
+عدد ال reacting units، وال reacting units بتعتمد
+
+149
+00:10:56,640 --> 00:10:59,920
+على التفاعل من غير ما أقول لك إيش التفاعل اللي بده
+
+150
+00:10:59,920 --> 00:11:02,980
+يتعدى الفوسفوريك أسيد، بتقدرش تقول لي والله آه ممكن
+
+151
+00:11:02,980 --> 00:11:06,240
+أحضر لك واحد normal فوسفوريك أسيد. بدي أقول لك حضر
+
+152
+00:11:06,240 --> 00:11:10,560
+واحد normal فوسفوريك أسيد عشان أستخدمه في تفاعله مع
+
+153
+00:11:10,560 --> 00:11:14,860
+إثنين sodium hydroxide مثلا، أو ثلاثة moles من ال
+
+154
+00:11:14,860 --> 00:11:18,280
+sodium hydroxide، هتعرفي اللي توزنه؟ لأنك عرفت ال
+
+155
+00:11:18,280 --> 00:11:23,100
+reacting units، بمعنى أنك حددت ال equivalent weight
+
+156
+00:11:23,100 --> 00:11:26,620
+تبعك، ومنها حسبت عدد ال equivalence، وبعدين حسبت
+
+157
+00:11:26,620 --> 00:11:30,000
+ال normality. لكن غير هيك لأ. عشان هيك في حسابات ال
+
+158
+00:11:30,000 --> 00:11:34,180
+normality يا شباب، لابد أن نعرف إيش هو التفاعل
+
+159
+00:11:34,180 --> 00:11:37,700
+اللي المادة بدها تتعدى فيه. مش زي ال molarity، على طول
+
+160
+00:11:37,700 --> 00:11:39,800
+ال molarity، والله عدد المولات في ال liter، مش
+
+161
+00:11:39,800 --> 00:11:44,450
+مشكلة. لكن normality لأ. وهذا سبب أننا يمكن ما بنحبش
+
+162
+00:11:44,450 --> 00:11:48,190
+كثير أن نتعامل مع ال normality؛ لأنه لو بده
+
+163
+00:11:48,190 --> 00:11:52,150
+يُحضّر محلول، بدك تقول والله هذا كذا normal عندما
+
+164
+00:11:52,150 --> 00:11:55,710
+يتفاعل مع المادة الفلانية بالـ
+
+165
+00:11:55,710 --> 00:12:01,620
+stoichiometry الفلانية. فهذا كلام مش سهل يعني. طيب
+
+166
+00:12:01,620 --> 00:12:06,100
+ممكن بنفس الطريقة، يعني ممكن نقول أنه إذا كان
+
+167
+00:12:06,100 --> 00:12:09,740
+التفاعل تفاعل أكسدة واختزال، فبنحاول نقسمه لنصين،
+
+168
+00:12:09,740 --> 00:12:15,700
+نشوف والله كم إلكترون في كل نصف. يعني فمثلا ال
+
+169
+00:12:15,700 --> 00:12:21,020
+permanganate، المنجنيز فيها سبعة، ممكن يتحول
+
+170
+00:12:21,020 --> 00:12:24,980
+لمنجنيز إثنين. في هذه الحالة، في عندي من سبعة
+
+171
+00:12:24,980 --> 00:12:28,700
+إلى إثنين، في عندي خمسة إلكترونز. ممكن يتحول لمجنيز
+
+172
+00:12:28,700 --> 00:12:32,970
+ثلاثة حسب الوسط. في هذه الحالة في عندي ٧ على ٣، في
+
+173
+00:12:32,970 --> 00:12:36,810
+عندي ٤، وكده حوالي منجنيز ٤ من ٧ على ٤، في عندي ٣
+
+174
+00:12:36,810 --> 00:12:39,910
+برضه حسب التفاعل، حسب الوسط اللي بيكون موجود فيه
+
+175
+00:12:39,910 --> 00:12:45,030
+لكن عدد الإلكترونات هي اللي بيسميها reacting units.
+
+176
+00:12:47,030 --> 00:12:51,250
+ف ال normality زي ما عرفناها، قلنا هي عدد ال
+
+177
+00:1
+
+223
+00:15:51,580 --> 00:15:55,040
+على N equivalent يعني كل واحد مول فيه N equivalent
+
+224
+00:15:55,040 --> 00:15:58,460
+أو نقول والله N equivalent موجودة في كل واحد مول
+
+225
+00:15:58,460 --> 00:16:01,880
+هذا نفس الكلام فهذا هو اعتبر conversion factor
+
+226
+00:16:01,880 --> 00:16:06,980
+هنستخدمه في الحلول الآن نيجي ناخد تطبيقات بس عشان
+
+227
+00:16:06,980 --> 00:16:11,440
+الأمور تكون واضحة، هنحاول ناخد تطبيقات نشوف إيش
+
+228
+00:16:11,440 --> 00:16:14,680
+معنى الكلام اللي أخدناه، كيف ممكن نستخدمه في الحل؟
+
+229
+00:16:14,680 --> 00:16:20,500
+فبنقول المثال أو الـ example، المثال بيقول find the
+
+230
+00:16:20,500 --> 00:16:24,580
+equivalent weights of الأمونيا، وميعطيك الـ formula
+
+231
+00:16:24,580 --> 00:16:31,940
+ويتقله الـ oxalic acid H2C2O4، هذا oxalic acid
+
+232
+00:16:31,940 --> 00:16:37,940
+ميعطيك الـ formula ويتقله، بس إيش جالك؟ جالك الـ
+
+233
+00:16:37,940 --> 00:16:40,760
+oxalic acid in the reaction with excess sodium
+
+234
+00:16:40,760 --> 00:16:43,460
+hydroxide، إيش معناه إنه يقول لك excess sodium
+
+235
+00:16:43,460 --> 00:16:46,760
+hydroxide؟ معناته هدول الـ two protons إيش بده
+
+236
+00:16:46,760 --> 00:16:50,400
+يجري لهم؟ بدهم يتفاعلوا كلهم، عشان هيك الـ number of
+
+237
+00:16:50,400 --> 00:16:54,260
+reacting units، أنت لازم تفهم هذا الكلام لما نقول لك
+
+238
+00:16:54,260 --> 00:16:57,700
+excess sodium hydroxide، معناته كل البروتونات إيش
+
+239
+00:16:57,700 --> 00:17:03,190
+مالها؟ اتفاعلت، لأن هذا acid، فمعنى الكلام إنّه بجد
+
+240
+00:17:03,190 --> 00:17:08,990
+باتنين، عشان هيك بيقول لك and potassium permanganate
+
+241
+00:17:08,990 --> 00:17:14,710
+KMnO4 when، ماسبقش هيك جالك، when مانجانيز سبعة
+
+242
+00:17:14,710 --> 00:17:17,410
+اللي هو في الـ potassium permanganate، المانجانيز
+
+243
+00:17:17,410 --> 00:17:20,730
+سبعة، لإن الـ oxygen أربعة، أربعة في اتنين سالب هي
+
+244
+00:17:20,730 --> 00:17:24,350
+ثمانية سالب، البوتاسيوم واحد موجب، بقال سبعة سالب
+
+245
+00:17:24,350 --> 00:17:27,470
+إذًا المانجانيز سبعة موجب، هذه الـ oxidation number
+
+246
+00:17:27,470 --> 00:17:32,670
+إله بيتحول لمانجانيز اتنين، من سبعة موجب لاتنين موجب، في
+
+247
+00:17:32,670 --> 00:17:36,210
+الفرق كم إلكترون؟ خمسة، بس هاد المعلومة، الآن
+
+248
+00:17:36,210 --> 00:17:39,350
+نيجي نحل نطلع الـ equivalent weight، فبنقول
+
+249
+00:17:39,350 --> 00:17:42,090
+الأمونيا، الأمونيا بتفاعل مع إيش؟ لأنها
+
+250
+00:17:42,090 --> 00:17:46,410
+معروفة زي الـ HCl، بتفعل بس مع واحد Hydroxide، زي الـ
+
+251
+00:17:46,410 --> 00:17:50,150
+sodium hydroxide، بتفاعل بس مع واحد HCl، الأمونيا
+
+252
+00:17:50,150 --> 00:17:57,500
+بتفاعل بس مع واحد H+، مفهومة؟ لو... لو كان عندك مية
+
+253
+00:17:57,500 --> 00:18:01,900
+طن HCl، اللي هو عندك، ملكي الواحدة أمونيا هياخد H plus
+
+254
+00:18:01,900 --> 00:18:07,880
+واحدة ويسيب الباقي، هيش... بتحملش أكتر، لو جالك excess
+
+255
+00:18:07,880 --> 00:18:14,700
+نفس الكلام، لأنه ما فيش عندك تفاعل إلا واحد فقط،
+
+256
+00:18:14,700 --> 00:18:17,880
+ما بتفاعلش مع أكتر من واحد، فالـ equivalent weight
+
+257
+00:18:17,880 --> 00:18:21,080
+بتساوي الـ formula weight بالنسبة للأمونيا على واحد،
+
+258
+00:18:21,080 --> 00:18:25,820
+إذًا بيساوي 17 gram per equivalent، نيجي نطلع على الـ
+
+259
+00:18:25,820 --> 00:18:29,820
+equivalent weight للـ H2C2O4، جالك Xs، معناته Xs
+
+260
+00:18:29,820 --> 00:18:32,460
+sodium hydroxide، معناته الـ two protons هيتفاعلوا، جالك
+
+261
+00:18:32,460 --> 00:18:36,200
+الـ N بجد... بجد، قلنا الـ N باتنين، إذًا نطلع
+
+262
+00:18:36,200 --> 00:18:38,460
+بنلاقي الـ equivalent weight بيساوي 90 على 2
+
+263
+00:18:38,460 --> 00:18:41,900
+90 على 2، 45 جرام per equivalent
+
+264
+00:18:41,900 --> 00:18:46,140
+بالنسبة للبرمنجنات، جالك المنجنيز سبعة اتحول
+
+265
+00:18:46,140 --> 00:18:49,340
+لمنجنيز اتنين، معناته خمسة electrons، يبقى الـ
+
+266
+00:18:49,340 --> 00:18:52,490
+equivalent weight للبرمنجنات بده يساوي formula
+
+267
+00:18:52,490 --> 00:18:58,010
+weight على خمسة، يبقى بده يساوي 158 على خمسة، واحد
+
+268
+00:18:58,010 --> 00:19:01,350
+وتلاتين، أقل ستة من عشرة، يبقى حساب الـ equivalent
+
+269
+00:19:01,350 --> 00:19:06,490
+weight يا شباب، شغلة مش صعبة، مجرد بس إنّه نعرف عدد
+
+270
+00:19:06,490 --> 00:19:11,550
+الـ reacting units، بنيجي لحسابات جوهرية في الحقيقة
+
+271
+00:19:11,550 --> 00:19:16,150
+مهمة جدًا، لأنها يعني من خلالها بنعرف تركيزات
+
+272
+00:19:16,150 --> 00:19:21,140
+المحلول، وهذا مهم كتير بالنسبة لنا، فمثلاً نتطلع على
+
+273
+00:19:21,140 --> 00:19:25,320
+المثال اللي قدامي، بيقول find the normality of the
+
+274
+00:19:25,320 --> 00:19:29,480
+solution containing خمسة وتلاتة من عشر جرام على لتر
+
+275
+00:19:29,480 --> 00:19:34,730
+of sodium carbonate، بقول لك إيه؟ عشان بده يحسب هو
+
+276
+00:19:34,730 --> 00:19:38,970
+normality، لازم يقول لك إيش هو التفاعل اللي بتعدي
+
+277
+00:19:38,970 --> 00:19:43,910
+المادة فيه، فجالك إنّه الـ carbonate reacts with، إيه إيش
+
+278
+00:19:43,910 --> 00:19:47,930
+معنى الكلام الـ N بتساوي اتنين، هي قصدها الـ N بتساوي
+
+279
+00:19:47,930 --> 00:19:52,010
+اتنين، فبقول أنا علشان يعني أقدر أحل المثال، أحله لك
+
+280
+00:19:52,010 --> 00:19:57,270
+بتلات طرق، تلات طرق، يعني آخر طريقة أنا بدي أقول لك إنها
+
+281
+00:19:57,270 --> 00:20:00,850
+يمكن تكون أسهل طريقة، لكن بدي أمشي معاك خطوة خطوة
+
+282
+00:20:02,200 --> 00:20:07,320
+الحل بهذه الطرق، الطريقة الأولى أمتع، لكن الحل بأخر
+
+283
+00:20:07,320 --> 00:20:13,180
+طريقة أسهل، فهنشوف، عشان أنا أجيب الـ normality، أول
+
+284
+00:20:13,180 --> 00:20:16,580
+ما أجيب، أجيب الـ equivalent weight، لازم خطوة أساسية
+
+285
+00:20:16,580 --> 00:20:19,440
+لأن الـ equivalent weight بدو يوصل لعدد الـ
+
+286
+00:20:19,440 --> 00:20:22,320
+equivalence، عدد الـ equivalence على الـ volume بدو
+
+287
+00:20:22,320 --> 00:20:24,680
+يُوصلنا للـ normality، مفهوم؟ فالخطوات المنطقية
+
+288
+00:20:24,680 --> 00:20:27,720
+equivalent weight، equivalence، بعدين بده يقسم الـ
+
+289
+00:20:27,720 --> 00:20:31,920
+equivalence على الـ volume، فبقول equivalent weight
+
+290
+00:20:31,920 --> 00:20:36,840
+بدّه يساوي الـ formula weight على اتنين، ليش اتنين؟
+
+291
+00:20:36,840 --> 00:20:40,680
+لأنه عاجل لك reacts with two protons، فبتطلع الـ
+
+292
+00:20:40,680 --> 00:20:44,200
+equivalent weight 53، طيب عدد الـ
+
+293
+00:20:44,200 --> 00:20:47,960
+equivalence ده؟ قال والله الجرام من المادة على الـ
+
+294
+00:20:47,960 --> 00:20:50,680
+equivalent weight، فالـ gram عندي خمسة وتلاتة، الـ
+
+295
+00:20:50,680 --> 00:20:53,920
+weight خمسة وتلاتة gram على الـ equivalent weight
+
+296
+00:20:53,920 --> 00:20:57,240
+تلاتة وخمسة، وطلع واحد من عشرة، بدنا إيش؟ هذا عدد
+
+297
+00:20:57,240 --> 00:20:59,980
+الـ equivalence، بدنا نقسمها على الحجم، الحجم liter ما هو؟
+
+298
+00:20:59,980 --> 00:21:03,700
+يبقى واحد liter، الحجم المعطيني هو liter، إذًا الـ
+
+299
+00:21:03,700 --> 00:21:09,060
+normality واحد من عشرة normal، ماشي يا شباب؟ ببساطة
+
+300
+00:21:09,060 --> 00:21:13,100
+بجيب الـ equivalent weight، ومنها بجيب عدد الـ
+
+301
+00:21:13,100 --> 00:21:16,180
+equivalence، بقسم الـ grams على الـ equivalent weight
+
+302
+00:21:16,180 --> 00:21:19,060
+وبعدين بقسمها على الحجم، ها، ومعطيني إياه في liter، إذًا
+
+303
+00:21:19,060 --> 00:21:21,340
+هذا هو... هذه الـ normality اللي طلعت معي، عدد الـ
+
+304
+00:21:21,340 --> 00:21:23,440
+equivalence والـ normality، لأن الـ equivalence
+
+305
+00:21:23,440 --> 00:21:28,640
+موجودة في liter، طيب نيجي نتطلع على حل المسألة
+
+306
+00:21:28,640 --> 00:21:32,680
+بالـ dimensional analysis أو الـ factor label method
+
+307
+00:21:34,510 --> 00:21:37,970
+بقول بده الـ normality، يعني إيه؟ إيش بده؟ يعني بده
+
+308
+00:21:37,970 --> 00:21:41,350
+عدد الـ equivalence من الـ sodium carbonate في الـ
+
+309
+00:21:41,350 --> 00:21:44,610
+liter، هاي معناها الـ normality، هذا على اليسار، هاي
+
+310
+00:21:44,610 --> 00:21:48,530
+معناها الـ normality، فأنا بقول إيش في عندي معطيات،
+
+311
+00:21:48,530 --> 00:21:51,590
+عندي خمسة وتلاتة من عشر جرام sodium carbonate على
+
+312
+00:21:51,590 --> 00:21:55,470
+الـ liter، لما أجي أشتغل dimensional analysis،
+
+313
+00:21:55,470 --> 00:21:58,770
+دائماً بحط في اعتباري إني أنا ما بفهمش في الجرامات،
+
+314
+00:21:58,770 --> 00:22:00,950
+أنا ما بعرفش في الجرامات، أنا بفهم في الـ moles والـ
+
+315
+00:22:00,950 --> 00:22:04,960
+millimoles، ما بفهمش في الـ grams أو الـ milligrams
+
+316
+00:22:04,960 --> 00:22:07,420
+بفهم في الـ moles أو الـ millimoles، عشان كده لما
+
+317
+00:22:07,420 --> 00:22:12,000
+يعطيني gram، ما فيش قدام خيار، طريق واحد فقط لا يتغير
+
+318
+00:22:12,000 --> 00:22:15,880
+بدي أحولها لـ mole، أعطاني gram، بدي أحولها لـ mole
+
+319
+00:22:15,880 --> 00:22:21,790
+مباشرة، فكيف بدي أحول الـ gram لـ mole؟ طبعاً الكتلة
+
+320
+00:22:21,790 --> 00:22:25,750
+المولية، فبنقول الـ factor، كل مول من الـ sodium
+
+321
+00:22:25,750 --> 00:22:28,870
+carbonate هو عبارة عن 106 gram من الـ sodium
+
+322
+00:22:28,870 --> 00:22:32,610
+carbonate، المول عبارة عن gram formula weight 106
+
+323
+00:22:32,610 --> 00:22:36,730
+gram، ابني، حولناها لمول، الآن المول يمكن تحويله لـ
+
+324
+00:22:36,730 --> 00:22:41,010
+equivalent، لأني قلت لك قبل شوية كل مول يحتوي على
+
+325
+00:22:41,010 --> 00:22:44,710
+عدد من الـ equivalence، فبالنسبة للصوديوم كربونيت قال
+
+326
+00:22:44,710 --> 00:22:48,010
+لي بتفاعل معه؟ اتنين بروتون، لذا كل مول اتنين
+
+327
+00:22:48,010 --> 00:22:51,650
+equivalent، أو كل اتنين equivalent صوديوم كربونيت
+
+328
+00:22:51,650 --> 00:22:56,290
+موجودة في واحد مول صوديوم كربونيت، معناته النتيجة
+
+329
+00:22:56,290 --> 00:23:01,250
+point one normal، ماشي يا شباب؟ فهذه أو هذا هو الحل
+
+330
+00:23:01,250 --> 00:23:05,030
+باستخدام الـ factor labeled method، نتطلع على الحل
+
+331
+00:23:05,760 --> 00:23:09,280
+اللي أنا بقول لك كتير كتير كتير ممكن يكون بسيط و
+
+332
+00:23:09,280 --> 00:23:15,000
+إحنا بقول لك مباشرة هذا إيش؟ جرام على الـ liter، طيب
+
+333
+00:23:15,000 --> 00:23:19,060
+أنا يعني بقدر أحوله لـ mole على الـ liter، صح ولا لأ؟
+
+334
+00:23:19,060 --> 00:23:22,170
+إيش بدي أعمل؟ بدي أقسم على الـ formula weight، صار mole
+
+335
+00:23:22,170 --> 00:23:24,630
+على الـ liter، مظبوط؟ طب أنا عندي الـ normality، الـ
+
+336
+00:23:24,630 --> 00:23:27,550
+molarity يعني، طب أنا عندي الـ normality بتساوي N في
+
+337
+00:23:27,550 --> 00:23:31,230
+الـ molarity، خلاص انتهى الموضوع، معايا؟ كمان مرة،
+
+338
+00:23:31,230 --> 00:23:33,990
+بقول هذا gram على الـ liter، أنا بحاول أجيب الـ
+
+339
+00:23:33,990 --> 00:23:37,610
+molarity، بعرف، molarity، خبير molarity أنا،
+
+340
+00:23:37,610 --> 00:23:40,110
+فبحاول على طول، كيف؟ بقسم على الـ formula weight،
+
+341
+00:23:40,110 --> 00:23:43,110
+اتحول على الـ molarity، طب أنا بعرف إن الـ normality
+
+342
+00:23:43,110 --> 00:23:47,140
+بتساوي N في الـ molarity، طب الآن ما هي بـ اتنين
+
+343
+00:23:47,140 --> 00:23:52,080
+اتنين في الـ molarity، بيطلع معايا على طول إن اللي هو
+
+344
+00:23:52,080 --> 00:23:54,340
+عدد الـ reacting units اللي هي هنا للبروتونات
+
+345
+00:23:54,340 --> 00:23:58,580
+المتفاعلة، فضل السؤال بيوضح لي إن البروتون لازم
+
+346
+00:23:58,580 --> 00:24:02,560
+أعرف إنه إيش؟ السؤال بيحدد لك إن البروتون فعلاً لازم
+
+347
+00:24:02,560 --> 00:24:06,780
+أعرفه؟ لأ، لأ هو بيقول لك أو بيعطيك المعادلة، فأنت
+
+348
+00:24:06,780 --> 00:24:10,360
+بتعرف، فهنا عندي نفس الطريقة، بيقول لك أنا بأعتمد في
+
+349
+00:24:10,360 --> 00:24:14,910
+الحل على N بتساوي N في M، الـ molarity، الـ number of
+
+350
+00:24:14,910 --> 00:24:18,090
+moles، خمسة وتلاتة maximum يعني على الـ formula weight
+
+351
+00:24:18,090 --> 00:24:22,210
+إذًا الـ molarity طلعناها، فش مشكلة، بضربها في اتنين
+
+352
+00:24:22,210 --> 00:24:24,830
+يبقى أنت ما عليك إنك تطلع الـ molarity بس، والـ molarity
+
+353
+00:24:24,830 --> 00:24:28,930
+بتعرف تطلعها، بده شطارة، وبعد ما تطلعها اضرب في الـ
+
+354
+00:24:28,930 --> 00:24:32,810
+N، خلاص حصلت على الـ normality، طب نتطلع على المثال
+
+355
+00:24:32,810 --> 00:24:36,630
+التالي، نفس الكلام بالظبط، لكن الـ reacting units
+
+356
+00:24:36,630 --> 00:24:40,400
+مختلفة شوية، وفي طبعاً فكرة أنا بحب إنك تعرفها، بيقول
+
+357
+00:24:40,400 --> 00:24:44,820
+find the normality of the solution containing 5
+
+358
+00:24:44,820 --> 00:24:51,060
+.2670 gram per liter potassium dichromate، وبيعطيك
+
+359
+00:24:51,060 --> 00:24:55,660
+الـ formula weight، وإيه؟ 294، بيقول لك if
+
+360
+00:24:55,660 --> 00:25:00,280
+chromium 6 is reduced to chromium 3، إيش معنى كلام
+
+361
+00:25:00,280 --> 00:25:05,890
+هذا؟ جداش الـ in؟ بنقول هي في الحقيقة مش تلاتة، هي
+
+362
+00:25:05,890 --> 00:25:12,830
+ستة، ليش؟ لأن المول كم كروم فيه؟ فيه اتنين، كل
+
+363
+00:25:12,830 --> 00:25:16,850
+واحدة فيهم تلت إلكترونات، لأن أنا بهمني المول، أنا
+
+364
+00:25:16,850 --> 00:25:21,450
+بهمني المادة، يا دي، كم إلكترون فيها؟ آه، فبتعطيني
+
+365
+00:25:21,450 --> 00:25:24,110
+تلاتة للكروم الأولى وتلاتة للكروم التانية،
+
+366
+00:25:24,110 --> 00:25:28,290
+معناته في عندي ستة electrons، معنى الكلام number
+
+367
+00:25:28,290 --> 00:25:31,510
+of reacting units، ستة، برضه بقدر أعرف هذا الكلام
+
+368
+00:25:31,510 --> 00:25:36,250
+مباشرة، بقول أكسجين سبعة، مش هيك؟ في اتنين سالب
+
+369
+00:25:36,250 --> 00:25:39,710
+يبقى سالب أربعة عشر، البوتاسيوم واحد موجب، واحد في
+
+370
+00:25:39,710 --> 00:25:43,170
+اتنين يعني اتنين موجب، إذًا بيبقى سالب اتناشر، يبقى
+
+371
+00:25:43,170 --> 00:25:48,070
+لكروم اتنين موجب اتناشر، لكروم اتنين موجب
+
+372
+00:25:48,070 --> 00:25:52,250
+اتناشر إيش؟ بتعطى اتنين كروم تلاتة، يعني اتنين في
+
+373
+00:25:52,250 --> 00:25:57,910
+تلاتة بستة، كيف بدك تساوي؟ 6 × 2، بدك 6 إلكترونات،
+
+374
+00:25:57,910 --> 00:26:01,590
+فبصير يعني بنفسك... يعني أي طريقة استخدمتها للحصول على
+
+375
+00:26:01,590 --> 00:26:05,290
+عدد الإلكترونات حاجة مباشرة، بس هو هنا ميعطيك إنه
+
+376
+00:26:05,290 --> 00:26:08,330
+الـ Chromium 6 اللي موجود هنا بيتحول لـ Chromium 3
+
+377
+00:26:08,330 --> 00:26:12,570
+وأنت عندك في المول الواحد، أنت هتلاقي لـ Chromium 2 × 3،
+
+378
+00:26:12,570 --> 00:26:17,500
+عندك 6 إلكترونات، إذًا الـ N عندك 6، نفس الكلام يا
+
+379
+00:26:17,500 --> 00:26:20,740
+شباب، أنا فيه أجيب في البداية الـ equivalent weight
+
+380
+00:26:20,740 --> 00:26:23,980
+خلينا نشتغلها بطريقة... هذه الـ equivalent weight بدها
+
+381
+00:26:23,980 --> 00:26:27,540
+تساوي الـ formula weight على 6، الـ equivalent weight
+
+382
+00:26:27,540 --> 00:26:31,820
+بدها تساوي الـ formula weight على 6، طيب الـ number
+
+383
+00:26:31,820 --> 00:26:35,140
+of equivalents لـ gram بالضبط، الـ weight على الـ
+
+384
+00:26:35,140 --> 00:26:37,060
+equivalent weight، طلع إن الـ number of equivalents
+
+385
+00:26:37,060 --> 00:26:41,230
+طب هي مدورة في لتر، إذًا هذه هي الـ normality، هذه هي
+
+386
+00:26:41,230 --> 00:26:44,450
+الـ normality، ممكن نحل نفس المسألة باستخدام الـ
+
+387
+00:26:44,450 --> 00:26:48,330
+dimensional analysis، بقول إيش يعني normality؟ جالك
+
+388
+00:26:48,330 --> 00:26:52,850
+عدد الـ equivalence من الـ dichromate في الـ liter، طب
+
+389
+00:26:52,850 --> 00:26:58,420
+إيش عندي معلومات؟ جالك 5.267 جرام من الـ dichromate
+
+390
+00:26:58,4
+
+445
+00:31:36,890 --> 00:31:40,870
+في البداية، إيش بتلاقي على البطول؟ على الـ label
+
+446
+00:31:40,870 --> 00:31:48,130
+اللي موجود على البطول؟ بتلاقي الـ density للمحلول و
+
+447
+00:31:48,130 --> 00:31:51,850
+بتلاقي أيضا الـ percentage للـ analyte، يعني إذا كان
+
+448
+00:31:51,850 --> 00:31:55,960
+جزاية HCl، قدّيش الـ percentage للـ HCl؟ اسكتكزازيت
+
+449
+00:31:55,960 --> 00:32:01,440
+فوسفوريك أسد، قدّيش الـ percentage فوسفوريك أسد؟ معايا
+
+450
+00:32:01,440 --> 00:32:06,040
+بيعطيك الـ percentage مثلا 10%، ولا 20%، ولا 50%؟ طب
+
+451
+00:32:06,040 --> 00:32:12,020
+والباقي مية، ولا 90%، ولا 99%؟ طب الباقي مية، ماشي
+
+452
+00:32:12,020 --> 00:32:16,920
+فهو بيعطيك الـ density وبيعطيك الـ percentage، الـ
+
+453
+00:32:16,920 --> 00:32:21,860
+density للمحلول وبيعطيك الـ percentage، ماشي؟ أنتَ
+
+454
+00:32:21,860 --> 00:32:24,820
+المفروض تستخدم الـ density والـ percentage، وأيضا
+
+455
+00:32:24,820 --> 00:32:27,700
+طبعا إن أنتَ عارف إيش هي المادة، فمعاكِ الفورمولوات
+
+456
+00:32:27,700 --> 00:32:35,090
+بتطلع الـ molarity. كيف بنعمل هذا الكلام؟ تعالوا
+
+457
+00:32:35,090 --> 00:32:40,270
+نطلع، كيف ممكن أحصل على الـ modularity من أي بطل
+
+458
+00:32:40,270 --> 00:32:46,090
+فيها محلول مركز معروف الـ density والـ percentage؟
+
+459
+00:32:47,540 --> 00:32:52,020
+نتقل على المثال التالي: What volume of concentrated
+
+460
+00:32:52,020 --> 00:32:56,100
+HCl؟ الـ formula weight هذه بتلاقيها على الـ label
+
+461
+00:32:56,100 --> 00:33:01,280
+formula weight ستة وثلاثين ونصف، معروفة H وCl، الـ
+
+462
+00:33:01,280 --> 00:33:05,280
+percentage اثنين وثلاثين في المئة، يعني ثمانية و
+
+463
+00:33:05,280 --> 00:33:08,440
+ستون في المئة ماء، واثنين وثلاثين في المئة بس HCl
+
+464
+00:33:08,440 --> 00:33:12,500
+مش كله HCl، لأ، ثمانية وستين في المئة ماء، واثنين و
+
+465
+00:33:12,500 --> 00:33:16,370
+ثلاثين في المئة بس HCl. فالـ density 1.1 من
+
+466
+00:33:16,370 --> 00:33:19,910
+عشرة جرام على المل، يعني لو أخذت عشرة مل من هذا
+
+467
+00:33:19,910 --> 00:33:24,030
+المحلول بوزنه  إلى عشرة جرام. العشرة مل الواحد بوزن
+
+468
+00:33:24,030 --> 00:33:27,410
+واحد فاصلة واحد من عشرة.  إيه الـ
+
+469
+00:33:27,410 --> 00:33:33,070
+density؟ إيه كويس؟ فهذا المركز بيقول، قدّيش أكمل
+
+470
+00:33:33,070 --> 00:33:37,210
+لازمين عشان أحضر خمسمئة مل من two molar solution
+
+471
+00:33:37,960 --> 00:33:42,260
+عايز أعرف قدّيش آخذ من المركز عشان أحضر 500 مل من
+
+472
+00:33:42,260 --> 00:33:46,260
+two molar solution. بدّي أذكّركم، مفتاح الحل هو الـ
+
+473
+00:33:46,260 --> 00:33:50,240
+density. مفتاح الحل هو الـ density. الـ density هذه هي
+
+474
+00:33:50,240 --> 00:33:56,320
+عبارة عن، الكل ينتبه، جرام solution لكل مل، كم
+
+475
+00:33:56,320 --> 00:34:00,460
+جرام solution لكل، يعني كل مل قدّيش كتلته كم جرام؟
+
+476
+00:34:00,460 --> 00:34:05,750
+طب أنا بدّي جرام solution، أنا بدّي gram solution،
+
+477
+00:34:05,750 --> 00:34:09,950
+أنا بدّي gram ولا مول solution، وإيش الفائدة؟ أنا بدّي
+
+478
+00:34:09,950 --> 00:34:16,770
+gram HCl، بدّي مول HCl، مش هيك؟ مش solution، عشان هيك
+
+479
+00:34:16,770 --> 00:34:22,060
+بدّك تنتبه شوية، تنتبه شوية. أنا لو ضربت جرام solution
+
+480
+00:34:22,060 --> 00:34:27,080
+في الـ percentage، هذا solution هل كله HCl؟ لأ، 32%
+
+481
+00:34:27,080 --> 00:34:31,980
+منه HCl. إذًا لو ضربت في 32%، إيش بتحوّل؟ HCl بس، مش
+
+482
+00:34:31,980 --> 00:34:36,420
+محلول، ببطّل محلول، بيصير بس HCl. يعني هذا جرام
+
+483
+00:34:36,420 --> 00:34:40,860
+solution ضربناه في الـ percentage، بتحوّل لإيش؟ لـ
+
+484
+00:34:40,860 --> 00:34:46,740
+gram HCl. ليش؟ لأن الـ HCl هو فقط 32% منه، فلو
+
+485
+00:34:46,740 --> 00:34:50,680
+ضربناها في 32%، الثلث تقريبا، فبكون هذا عبارة عن
+
+486
+00:34:50,680 --> 00:34:57,240
+الـ HCl، آه ساعتها بقدر أتعامل معاه، فبقول 1.1 هي
+
+487
+00:34:57,240 --> 00:35:02,240
+الـ density في الـ percentage، ولاحظوا إنها من 100،
+
+488
+00:35:02,240 --> 00:35:06,850
+حولته لـ milligram، ضربته في 10 أس 3. إذًا صار عندي
+
+489
+00:35:06,850 --> 00:35:11,710
+milligram HCl على المل. ماشي؟ إحنا بنعرف الـ density
+
+490
+00:35:11,710 --> 00:35:17,150
+في الـ percentage، صارت gram HCl، ضربت في 10 أس 3
+
+491
+00:35:17,150 --> 00:35:23,430
+صارت milligram HCl، ماشي؟ في إيه لكل واحد مل. طب أنا
+
+492
+00:35:23,430 --> 00:35:26,930
+مدّيش milligram HCl، أنا مدّيش millimole HCl، لما نكون
+
+493
+00:35:26,930 --> 00:35:30,070
+millimole على الـ milliliter، يعني إيش؟ ملي مول على
+
+494
+00:35:30,070 --> 00:35:34,410
+ملي لتر، إيش يعني؟ مولارتي هي اللي بدّي إياها، فإيش عشان
+
+495
+00:35:34,410 --> 00:35:38,990
+أحصل على ملي مول؟ إيش بدّي؟ بدّي أقسم، بدّي هيني زي ما
+
+496
+00:35:38,990 --> 00:35:43,410
+إنتوا شايفين، بأقسّم على الـ formula weight، هذا هي
+
+497
+00:35:43,410 --> 00:35:47,230
+خلاص، طلعت الـ molarity. كمان مرة بقول، عندي الـ
+
+498
+00:35:47,230 --> 00:35:50,950
+density، جرام solution، أنا مش مهتم بالـ solution، الـ
+
+499
+00:35:50,950 --> 00:35:53,830
+solution فيه ماء وفي مادة أخرى، ما فيش فايدة منه،
+
+500
+00:35:54,280 --> 00:35:57,360
+ما بعرف أعمل عليه أي Stoichiometric Calculation، بدّي
+
+501
+00:35:57,360 --> 00:36:01,280
+أحوّل للـ analyte، بدّي أحوّل للـ HCl، قدّيش منه HCl
+
+502
+00:36:01,280 --> 00:36:07,280
+قال 32%، 32 من مئة، ما أحد يكتب 32 من غير.. من غير
+
+503
+00:36:07,280 --> 00:36:15,740
+..مش كسر، يعني مش 32 ضعف، لأ، 32 من مئة، ثلث HCl، تمام؟
+
+504
+00:36:15,740 --> 00:36:18,960
+فَضربناها في point three two، حولناها لـ milligram، أنا
+
+505
+00:36:18,960 --> 00:36:22,200
+ضربناها في عشرة أس تلاتة، صار milligram HCl على
+
+506
+00:36:22,200 --> 00:36:25,680
+الـ milli، أنا بدّي millimole على الـ milli، إذًا بس بدّي أقسم
+
+507
+00:36:25,680 --> 00:36:30,620
+على الـ formula weight، بتعطيني molarity. هاي المنطق
+
+508
+00:36:30,620 --> 00:36:35,920
+تبعنا، فجسمنا، طلع عندي تسعة وأربعة من عشرة، الكتافة؟
+
+509
+00:36:35,920 --> 00:36:36,840
+آه، كنت على الحجم
+
+510
+00:36:41,920 --> 00:36:46,680
+هي أنا بأتكلم عن الـ milli، أنا أخذت واحد ملي، واحد ملي من
+
+511
+00:36:46,680 --> 00:36:50,620
+المحلول، أنتَ بترجع عليّ، أنتَ بترجع عليّ، واحد ملي من إيش؟
+
+512
+00:36:50,620 --> 00:36:57,160
+من المحلول، هذا الواحد ملي قدّيش فيه من الـ HCl؟ 32%
+
+513
+00:36:57,160 --> 00:37:04,440
+ضربت فيه 32%، صارت الـ value هذه من الـ HCl في الـ milli
+
+514
+00:37:04,440 --> 00:37:10,620
+مش هيك؟ مش الـ 32% من الـ 1.1 من 10 هي اللي في الـ milli
+
+515
+00:37:10,620 --> 00:37:13,680
+موجودة، أنا ما عندي غيرها الـ milli، اعتبر ما عندي غيرها
+
+516
+00:37:13,680 --> 00:37:20,680
+الـ milli، تمام؟ كان وزنه 1.1 من 10 gram solution، أنا
+
+517
+00:37:20,680 --> 00:37:24,700
+ما بدّيش gram solution، ما بدّيش gram HCl، فضربته في
+
+518
+00:37:24,700 --> 00:37:28,820
+point three two، صار gram HCl، ضربته في عشرة أس
+
+519
+00:37:28,820 --> 00:37:33,160
+تلاتة، صار اللي قدامي. وين هذا الكلام موجود؟ في
+
+520
+00:37:33,160 --> 00:37:38,640
+الـ milli، فيه الحجم. ما لَقدّيش الحجم يا عمّ؟ هو هو الحجم، هي
+
+521
+00:37:38,640 --> 00:37:43,500
+وَجاعد في الـ milli، هادي الكتلة في الـ milli، الكتلة هادي
+
+522
+00:37:43,500 --> 00:37:47,840
+موجودة في واحد milli، بس فايلة زي ما هي، لكن بقول أنا
+
+523
+00:37:47,840 --> 00:37:51,920
+ما بدّيش كتلة، أنا بدّي milli mole، كيف بدّه يحوّل الكتلة
+
+524
+00:37:51,920 --> 00:37:55,020
+هادي لـ milli mole؟ على الكتلة المولية، اتحوّل لـ
+
+525
+00:37:55,020 --> 00:37:57,120
+milli mole. إذًا الـ milli mole على الـ milliliter
+
+526
+00:37:57,120 --> 00:38:00,180
+معناته إيش صارت؟ molarity، الـ molarity تسعة و
+
+527
+00:38:00,180 --> 00:38:05,410
+أربعة وستين. الآن سهل جداً أقول الـ molarity في الـ
+
+528
+00:38:05,410 --> 00:38:08,350
+volume، يعني الـ millimoles قبل التخفيف تساوي
+
+529
+00:38:08,350 --> 00:38:11,030
+المولارتي في الـ volume، يعني الـ millimoles بعد
+
+530
+00:38:11,030 --> 00:38:16,230
+التخفيف. فـ 9.64 في الـ volume بالمل بتساوي 2 في 500
+
+531
+00:38:16,230 --> 00:38:19,170
+بعد التخفيف، بطلع الـ volume بالمل من المركز اللي
+
+532
+00:38:19,170 --> 00:38:24,780
+لازم آخذه، 10.4 من 10 مل. بقول هدول العشرة وأربعة من
+
+533
+00:38:24,780 --> 00:38:28,380
+عشرة milli باخدهم وبحطهم على كمية من الماء، يعني و
+
+534
+00:38:28,380 --> 00:38:32,420
+لتكن مثلا مئتين milli، بحطهم شوية شوية، دائما بضيف
+
+535
+00:38:32,420 --> 00:38:36,960
+المركز على الماء، مش الماء على المركز. المركز على
+
+536
+00:38:36,960 --> 00:38:42,200
+الماء، بالذات في حالة الـ H2SO4، بس بشكل عام خلينا
+
+537
+00:38:42,200 --> 00:38:47,350
+نقول، general practice procedure، أو general
+
+538
+00:38:47,350 --> 00:38:51,290
+practice عندنا، إنّه دائماً نضيف المركز على الماء، مش
+
+539
+00:38:51,290 --> 00:38:56,010
+الماء على المركز، بنضيفه شوية شوية، ضفناه، بنكمل
+
+540
+00:38:56,010 --> 00:39:02,430
+الحجم لـ 500 مل، بكون عندنا 500 مل من 2 molar HCl
+
+541
+00:39:02,430 --> 00:39:06,950
+solution. الاثنين هي الاثنين لتر، ما أعطيه لنا يا
+
+542
+00:39:06,950 --> 00:39:14,620
+حبيبي، هيها، بدّه يحضّر 500 مل من 2 molar. طيب نأخذ اللي
+
+543
+00:39:14,620 --> 00:39:18,400
+فاته أي شيء، بدّي آخذ مثال وبدّي أفرجك كيف هو بسيط
+
+544
+00:39:18,400 --> 00:39:22,880
+كثير، نفس المنطق تماماً. ففي عندنا bottle من الـ
+
+545
+00:39:22,880 --> 00:39:28,020
+concentrated H2SO4، وإحنا حابين نحسب قدّيش الـ
+
+546
+00:39:28,020 --> 00:39:31,560
+molarity إليه، علشان نحضّر لتر من point one
+
+547
+00:39:31,560 --> 00:39:34,990
+molar solution. فالمثال بيقول: How many ml of
+
+548
+00:39:34,990 --> 00:39:45,490
+concentrated H2SO4؟ معطيك على البطول 98
+
+549
+00:39:45,490 --> 00:39:59,260
+.1%،  94%، 6% ماء. الـ density 1.83. كويس؟ قدّيش بدنا من
+
+550
+00:39:59,260 --> 00:40:02,280
+الحمض المركز، علشان نحضّر واحد لتر من point one
+
+551
+00:40:02,280 --> 00:40:07,360
+molar solution؟ بقول أبسط شيء خالص، بقول أنا عند الـ
+
+552
+00:40:07,360 --> 00:40:13,800
+density، مفتاح الحل هذا، جرام solution عليه على
+
+553
+00:40:13,800 --> 00:40:17,500
+الـ milli، بدّي جرام solution على الـ milli، أنا ما بدّيش جرام
+
+554
+00:40:17,500 --> 00:40:22,140
+solution، بدّي جرام H2SO4، إيش بعمل؟ بضرب في الـ
+
+555
+00:40:22,140 --> 00:40:26,060
+percentage. ما بدّيش جرام، بدّي ملي جرام، بضرب في إيش؟ في
+
+556
+00:40:26,060 --> 00:40:30,080
+10 أس 3. إذًا صارت هذه الوزنة موجودة في الـ milli، أنا ما بدّيش
+
+557
+00:40:30,080 --> 00:40:34,020
+ملي جرام على المل، أنا بدّي ملي مول على المل، بأقسّم
+
+558
+00:40:34,020 --> 00:40:37,820
+على الـ formula weight، صارت مولارتها. الموضوع هي بهذه
+
+559
+00:40:37,820 --> 00:40:43,530
+البساطة خالص، يعني بساطة شديدة جداً. في البداية بجيب
+
+560
+00:40:43,530 --> 00:40:47,450
+milligram على المل، وبعدين بأقسّم على الفورمولا
+
+561
+00:40:47,450 --> 00:40:51,490
+بتعطيني millimol على المل، يعني molarity، كويس، بتطلع
+
+562
+00:40:51,490 --> 00:40:55,510
+عندي الـ molarity 17.5. الآن بنفس الطريقة اللي
+
+563
+00:40:55,510 --> 00:41:01,900
+ذكرناها سابقاً، بنقول إنّه MIVI، أو الـ milli مولز قبل
+
+564
+00:41:01,900 --> 00:41:05,400
+التخفيف تساوي الـ milli مولز بعد التخفيف، معناته الكلام
+
+565
+00:41:05,400 --> 00:41:10,660
+17.5 في الـ volume بالمل تساوي 0.1 في ألف. لازم هذه
+
+566
+00:41:10,660 --> 00:41:14,200
+..مدام هذه بالمل لازم هذه تكون بالمل، نفس الحاجة،
+
+567
+00:41:14,200 --> 00:41:17,930
+عشان ملي مول تساوي ملي مول. بتطلع الـ volume 5.71
+
+568
+00:41:17,930 --> 00:41:22,250
+بناخذه وبنضيفه على شوية ماء، على 200 مل ماء مثلاً،
+
+569
+00:41:22,250 --> 00:41:27,690
+شوية شوية، على الجدار بينزل، لأن الـ H2SO4 شرّه جداً
+
+570
+00:41:27,690 --> 00:41:32,710
+للماء، لو.. لو حطيت الماء عليه، ممكن هو ينط، بدّه
+
+571
+00:41:32,710 --> 00:41:35,830
+يحاول يوصل، لكن لما نضيفه هو على الماء بتخفف أول
+
+572
+00:41:35,830 --> 00:41:39,390
+بأول، وطبعاً يعني أثناء الإضافة على الماء الماء
+
+573
+00:41:39,390 --> 00:41:43,770
+بتسخّن، بتصير زي النار، يعني حرارة عالية، فلازم تنتبه
+
+574
+00:41:43,880 --> 00:41:48,380
+بعد ما نضيفه، بنكمل الحجم لواحد لتر، بنكون حصلنا على
+
+575
+00:41:48,380 --> 00:41:53,100
+واحد لتر من point one molar solution. أنا عندي easy
+
+576
+00:41:53,100 --> 00:41:56,880
+shortcut ممكن أنتَ تحفظها، أو يعني تطلع عليها. الـ
+
+577
+00:41:56,880 --> 00:42:00,960
+molarity بتساوي الـ density اللي هي جرام solution
+
+578
+00:42:00,960 --> 00:42:05,160
+على المل، بتروح من الـ percentage، تحوّل لإيش؟ لـ gram
+
+579
+00:42:05,160 --> 00:42:09,320
+solute على المل، بحوّل في عشرة أس تلاتة، حولت ملي gram ع
+
+580
+00:42:09,320 --> 00:42:14,740
+الـ milli على الـ formula weight، من اللي مل على اللي، يعني
+
+581
+00:42:14,740 --> 00:42:20,500
+مولارتي، يعني فيك تحفظ هذا القانون وتحِل عليه، يعني
+
+582
+00:42:20,500 --> 00:42:24,580
+المسائل متعلقة بالـ density calculations، بس لازم
+
+583
+00:42:24,580 --> 00:42:29,500
+تتذكر إنّ الـ percentage، مثلاً 35%، معناته تهيئة
+
+584
+00:42:29,500 --> 00:42:35,080
+كتابتها مش 35 ضعف، لأ، كسر، الـ percentage، قدر عن
+
+585
+00:42:35,080 --> 00:42:42,630
+إيش؟ عن كسر، بالظبط، خلاص، من مئة على مئة. طيب في شباب
+
+586
+00:42:42,630 --> 00:42:49,850
+يعني مصطلحين بحب أنه نفرّج بينهم، هيمروا معنا في
+
+587
+00:42:49,850 --> 00:42:53,110
+المستقبل بشكل واسع كثير، لكن هلّا جيت نأخذ يعني إيش
+
+588
+00:42:53,110 --> 00:42:59,530
+المفهوم العام لهم، لو إحنا قلنا لك حضّر واحد من
+
+589
+00:42:59,530 --> 00:43:05,680
+عشرة مولر acetic acid، قال والله بنأخذ واحد من عشرة
+
+590
+00:43:05,680 --> 00:43:10,380
+مول من الـ Acetic Acid وبنحطه في شوية ماء وبنكمل
+
+591
+00:43:10,380 --> 00:43:15,940
+للتر، صار عندنا واحد من عشرة مولار Acetic Acid. طب
+
+592
+00:43:15,940 --> 00:43:20,460
+الواحد من عشرة مول هو عبارة عن قدّيش الـ.. لو قلنا
+
+593
+00:43:20,460 --> 00:43:23,100
+قدّيش المول من الـ Acetic Acid؟ بقول ستين جرام مثلاً
+
+594
+00:43:23,100 --> 00:43:28,840
+ستين جرام، ستين جرام، طيب..
+
+595
+00:43:31,940 --> 00:43:35,880
+يعني الواحد من عشرة مول، ستة جرام، ستة جرام، بدنا
+
+596
+00:43:35,880 --> 00:43:38,960
+نحطها في لتر، بعطيني واحد من عشرة molar acetic
+
+597
+00:43:38,960 --> 00:43:42,620
+acid. طيب يا شباب، الـ acetic acid أنا بعرف أنه
+
+598
+00:43:42,620 --> 00:43:47,780
+electrolyte ضعيف، electrolyte إيش ماله؟ ضعيف،
+
+599
+00:43:47,780 --> 00:43:52,420
+فمعنى الكلام، لما أنا أحطه في الماء، إيش بده يصير له؟
+
+600
+00:43:52,420 --> 00:43:58,280
+جزء منه بده يتفكّك. الآن صح، أنا وزنت واحد من عشرة مول في
+
+601
+00:43:58,280 --> 00:44:01,820
+اللتر، بسمّي هذا التركيز اللي هو واحد من عشرة مولار
+
+602
+00:44:01,820 --> 00:44:08,340
+بسمّيه analytical concentration، وبرمزه بالرمز C، للـ
+
+603
+00:44:08,340 --> 00:44:13,700
+H O A C. ما آخذ بالك؟ قدّيش التركيز واحد من.. طب كيف
+
+604
+00:44:13,700 --> 00:44:17,660
+عرفته؟ أنا وزنت واحد من عشرة مول وحطيته في اللتر،
+
+605
+00:44:17,660 --> 00:44:21,600
+ف
\ No newline at end of file
diff --git a/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/tK31Pig9Ny8_postprocess.srt b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/tK31Pig9Ny8_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..8ddf8792a81451304923ca0dfb0e332e84a68048
--- /dev/null
+++ b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/tK31Pig9Ny8_postprocess.srt
@@ -0,0 +1,2504 @@
+1
+00:00:20,910 --> 00:00:24,810
+بقى شوية بالحصة الماضية كنا بدأنا نتكلم عن ال
+
+2
+00:00:24,810 --> 00:00:29,690
+stoichiometric calculations ووصلنا لطرق التعبير عن
+
+3
+00:00:29,690 --> 00:00:33,410
+ال concentration فاتكلمنا عن ال molarity وشوفنا ان
+
+4
+00:00:33,410 --> 00:00:37,510
+ال molarity هي عبارة عن number of moles of solute
+
+5
+00:00:37,510 --> 00:00:42,870
+dissolved in one liter of solutionو قلنا من هذا
+
+6
+00:00:42,870 --> 00:00:49,750
+الكلام قلنا انه ممكن نقول ال millimoles تساوي ال
+
+7
+00:00:49,750 --> 00:00:52,990
+modality في ال volume بالمل وهذه كانت علاقة مهمة
+
+8
+00:00:52,990 --> 00:00:56,950
+جدا أكملت العلاقة السابقة اللي كنا بنقول ال
+
+9
+00:00:56,950 --> 00:01:01,110
+millimole بتساوي milligram من ال substance على ال
+
+10
+00:01:01,110 --> 00:01:04,510
+formula weight اليوم بنكمل في نفس السياقة بنتكلم
+
+11
+00:01:04,510 --> 00:01:09,810
+عن ال normalitycalculations لكن اليوم فقط هنتكلم
+
+12
+00:01:09,810 --> 00:01:13,810
+عن مقدمة في ال normality و هنرجع لنفس الموضوع في
+
+13
+00:01:13,810 --> 00:01:18,210
+المستقبل بعد محاضرات قليلة إذا الله راد إيش
+
+14
+00:01:18,210 --> 00:01:20,830
+المقصود بال normality؟ ال normality زي ال molarity
+
+15
+00:01:20,830 --> 00:01:27,550
+هي عبارة عن وحدة أو مصطلح يراد به التعبير عن
+
+16
+00:01:27,550 --> 00:01:32,330
+التركيز تعبير عن التركيز كيف يمكن نعرف ال
+
+17
+00:01:32,330 --> 00:01:35,810
+normality؟يمكن تعريف الـ normality علي إنها number
+
+18
+00:01:35,810 --> 00:01:40,730
+of equivalents of solute dissolved in one liter of
+
+19
+00:01:40,730 --> 00:01:44,080
+solutionلكن لما نتكلم نقول والله number of
+
+20
+00:01:44,080 --> 00:01:49,240
+equivalents فإيش هو ال equivalent هذا يعني لازم
+
+21
+00:01:49,240 --> 00:01:52,200
+نعرفه لأن احنا بيقول number of moles بنعرف ال mole
+
+22
+00:01:52,200 --> 00:01:57,340
+لكن number of equivalents لسه احنا مادرسناش إيش
+
+23
+00:01:57,340 --> 00:02:03,020
+يعني equivalent فممكن تعريف ال equivalent على إنه
+
+24
+00:02:03,020 --> 00:02:08,540
+ال equivalent بيساوي ال
+
+25
+00:02:08,540 --> 00:02:14,510
+number of gramsعلى ال equivalent weight number of
+
+26
+00:02:14,510 --> 00:02:18,330
+grams of solute طبعا على ال equivalent weight فهذا
+
+27
+00:02:18,330 --> 00:02:21,170
+بيعطينا number of equivalents طيب number of grams
+
+28
+00:02:21,170 --> 00:02:23,930
+of solute هذه مفهومة لكن ايش هو ال equivalent
+
+29
+00:02:23,930 --> 00:02:27,490
+weight برضه بحلناش المشكلة جال ال equivalent
+
+30
+00:02:27,490 --> 00:02:33,970
+weight هو عبارة عن ال formula weight على n حيث ان
+
+31
+00:02:33,970 --> 00:02:40,040
+هذه عبارة عن number of reacting unitsnumber of
+
+32
+00:02:40,040 --> 00:02:46,320
+reacting units عدد الوحدات المتفاعلة برضه يعني
+
+33
+00:02:46,320 --> 00:02:49,700
+الموضوع مش واضح بالنسبالنا لأن عدد الوحدات
+
+34
+00:02:49,700 --> 00:02:52,560
+المتفاعلة زي إيش يعني ممكن نقول والله إذا كان عندي
+
+35
+00:02:52,560 --> 00:02:56,180
+تفاعل acid base فعدد الوحدات المتفاعلة ممكن هتكون
+
+36
+00:02:56,180 --> 00:03:01,360
+والله protons H plus أو hydroxides لو كان عندي
+
+37
+00:03:01,360 --> 00:03:04,560
+تفاعل أكسد أو اختزال فعدد الوحدات المتفاعلة
+
+38
+00:03:04,560 --> 00:03:11,120
+electrons فبرضه هذا بتوقف على التفاعلعشان هيك لما
+
+39
+00:03:11,120 --> 00:03:15,980
+نقول احنا ال normality هي عدد ال equivalence من ال
+
+40
+00:03:15,980 --> 00:03:19,220
+solute المذابة في ال liter وال equivalent هو عبارة
+
+41
+00:03:19,220 --> 00:03:22,140
+عن اجرام solute على ال equivalent weight وال
+
+42
+00:03:22,140 --> 00:03:25,320
+equivalent weight هو عبارة عن formula weight على N
+
+43
+00:03:25,320 --> 00:03:31,170
+عدد من ال reacting unitsهذه جثة يعني الحسابات
+
+44
+00:03:31,170 --> 00:03:37,730
+تبعتنا مش حسابات مباشرة و تتوقف بشكل أساسي على نوع
+
+45
+00:03:37,730 --> 00:03:41,570
+التفاعل اللي ال solute أو المادة اللي عندى بدها
+
+46
+00:03:41,570 --> 00:03:45,780
+تعديهعلشان هيك يا شباب يمكن كان هذا من الدوافع
+
+47
+00:03:45,780 --> 00:03:53,600
+المهمة خلف يعني التقليل من استخدام ال normality
+
+48
+00:03:53,600 --> 00:03:57,040
+لدرجة ان احنا الآن في الكيمة التحليلية مانستخدمش
+
+49
+00:03:57,040 --> 00:03:59,780
+ال normality في الحسابات تبعاتنا عادة لا نستخدمها
+
+50
+00:03:59,780 --> 00:04:05,610
+في الحسابات تبعاتناالان بنستخدم فقط ال molarity مش
+
+51
+00:04:05,610 --> 00:04:09,170
+ال normality طيب مدام بنستخدم احنا ال normality ..
+
+52
+00:04:09,170 --> 00:04:12,590
+ال molarity مش ال normality و استخدام ال normality
+
+53
+00:04:12,590 --> 00:04:16,830
+يمكن في ال .. يعني أصبح ضئيل جدا و محدود للغاية في
+
+54
+00:04:16,830 --> 00:04:20,290
+الأربعين سنة اللي فاتوا تقريبا او في التلاتين سنة
+
+55
+00:04:20,290 --> 00:04:24,270
+او اكتر اللي فاتوا فليش احنا بندرسها؟ ليش ندرس ال
+
+56
+00:04:24,270 --> 00:04:28,420
+normality اذا؟ مدام توقفنا عن استخدامها تقريبافليش
+
+57
+00:04:28,420 --> 00:04:32,660
+ندرسها؟ بنقول دراستها مهمة جدا لأن كل ال
+
+58
+00:04:32,660 --> 00:04:38,360
+literature السابق في عشرات السنوات الماضية و
+
+59
+00:04:38,360 --> 00:04:43,660
+القرون الماضية يعني آخر قرنين تقريبا كل الدراسات
+
+60
+00:04:43,660 --> 00:04:47,040
+اللي كانت بتتم كانت بتتم باستخدام ال normality فهل
+
+61
+00:04:47,040 --> 00:04:52,350
+يعقل انهيعني لا نلقي بالا للنتائج اللي العلماء من
+
+62
+00:04:52,350 --> 00:04:56,290
+قديم الزمان حصلوا عليها و أصبحت لنا يعني مكتبة
+
+63
+00:04:56,290 --> 00:05:00,210
+قيمة جدا من النتائج المختلفة فلا يجوز إلا أن طبعا
+
+64
+00:05:00,210 --> 00:05:03,930
+نهمل هذه النتائج عشان هيك لازم نفهم إيش يعني
+
+65
+00:05:03,930 --> 00:05:07,390
+normality وكيف نستخدمها وإيش معنى النتائج اللي
+
+66
+00:05:07,390 --> 00:05:12,490
+علماءنا السابقين حصلوا عليها هذا جانب من الجوانب
+
+67
+00:05:12,490 --> 00:05:17,580
+والجانب الآخر صحيح احنا في الكيميابنفضّل عدم
+
+68
+00:05:17,580 --> 00:05:21,120
+استخدام الـ normality و لا نوصي باستخدامها، لكن
+
+69
+00:05:21,120 --> 00:05:27,060
+للأسف بعض الأنظمة الأخرى كمثلا الطب أو جزء مهم من
+
+70
+00:05:27,060 --> 00:05:32,680
+ال biochemistry والتحاليل الطبيةالبيئة في بعض
+
+71
+00:05:32,680 --> 00:05:36,560
+الأحيان نجد انه هناك علماء يستخدموا لازالوا
+
+72
+00:05:36,560 --> 00:05:40,800
+يستخدموا بشكل أساسي ال normality فطبعا ايضا لا
+
+73
+00:05:40,800 --> 00:05:46,140
+يُعقل انه لانوا القيبالا للنتائج تباعتهم لأ علشانك
+
+74
+00:05:46,140 --> 00:05:49,720
+احنا لازم نفهم ال normality بشكل واضح و جيد كتير
+
+75
+00:05:50,270 --> 00:05:53,530
+وفي نفس الوقت لا ندعو الاستخدامها، بالعكس ندعو
+
+76
+00:05:53,530 --> 00:05:57,050
+الجميع للاقتزام باستخدام الـMolarity خاصة في العصر
+
+77
+00:05:57,050 --> 00:06:02,050
+الحديث اللي أصبح يعني فيه نوع من العالمية في
+
+78
+00:06:02,050 --> 00:06:07,710
+العلوم وهناك مؤسسات عالمية بتوصي باستخدام يعني
+
+79
+00:06:07,710 --> 00:06:11,550
+أساليب معينة للتعبير عن التركيز واحنا الأوساط
+
+80
+00:06:11,550 --> 00:06:15,530
+العلمية الكيميائية توصي باستخدام الـMolarity مش
+
+81
+00:06:15,530 --> 00:06:22,910
+الـNormality، ماشي يا شبابطيب نتكلم اكتر عن ايش
+
+82
+00:06:22,910 --> 00:06:26,590
+يعني reacting unit؟ reacting unit احنا بنقول والله
+
+83
+00:06:26,590 --> 00:06:32,270
+عدد الوحدات المتفاعلة لما نكون عندى مثلا acid زى
+
+84
+00:06:32,270 --> 00:06:37,370
+ال HClأيش فيه ممكن يتفاعل؟ فش اللي غيرها البروتون
+
+85
+00:06:37,370 --> 00:06:41,110
+البروتون asset base بتفعل البروتون أكم البروتون
+
+86
+00:06:41,110 --> 00:06:45,290
+فيه عندى؟ واحد لما نكون فيه عندى واحد فش قدامه
+
+87
+00:06:45,290 --> 00:06:48,890
+خيار إلا إنه بس الواحد دول يتفاعل عشان هيك عادة ال
+
+88
+00:06:48,890 --> 00:06:53,850
+HCL معروف تفاعله بده يتفاعل مثلا أي حاجة لو بفقد
+
+89
+00:06:53,850 --> 00:06:57,590
+البروتون واحد وبالتالي لما نقول ال equivalent
+
+90
+00:06:57,590 --> 00:07:02,450
+weight بساوي formula weight على N N بالنسبة للHCL
+
+91
+00:07:02,450 --> 00:07:05,850
+دائما واحدليه؟ لأنه مافيش عنده وره إلا بروتون، مش
+
+92
+00:07:05,850 --> 00:07:08,630
+معقول يتفعلوا إتنين بروتون، لأنه مافيش عنده إلا
+
+93
+00:07:08,630 --> 00:07:12,150
+بروتون واحد، فمثلا ال HCl دائما ال formula weight
+
+94
+00:07:12,150 --> 00:07:16,470
+بتساوي ال equivalent weight، لو إجينا لل nitric
+
+95
+00:07:16,470 --> 00:07:19,170
+acid، لل pericloric acid، نفس الكلام في ال acid
+
+96
+00:07:19,170 --> 00:07:22,950
+base reaction تبعهم، ال equivalent weight هو ال
+
+97
+00:07:22,950 --> 00:07:28,040
+formula weightكبازز لما نقول والله عندى ال sodium
+
+98
+00:07:28,040 --> 00:07:31,460
+hydroxide أكم hydroxide فى ال sodium hydroxide اذا
+
+99
+00:07:31,460 --> 00:07:33,560
+برضه نفس الكلام ال equivalent weight هو ال formula
+
+100
+00:07:33,560 --> 00:07:37,060
+weight على واحد يعنى فهو ال formula weight نفس
+
+101
+00:07:37,060 --> 00:07:40,480
+الكلام ال ammonia مثلا ال ammonia معروفة عبارة عن
+
+102
+00:07:40,480 --> 00:07:46,320
+باز مع أكم H plus بيتفاعلمع أكم H بلس بيتفاعل،
+
+103
+00:07:46,320 --> 00:07:49,980
+بتفاعلش اللي مع واحد، بيعطي N H أربعة موجب، N H
+
+104
+00:07:49,980 --> 00:07:53,440
+أربعة، واحد موجب فوقها يعني، فبتفاعل بس مع واحد
+
+105
+00:07:53,440 --> 00:07:59,720
+عشان هيك، برضه الأمونيا هو عبارة عن مادة، base، ال
+
+106
+00:07:59,720 --> 00:08:01,820
+equivalent weight إليها دائما بساوي ال formula
+
+107
+00:08:01,820 --> 00:08:07,770
+weight، لأنه لا تتفاعل إلا فقط مع بروتون، واحدلكن
+
+108
+00:08:07,770 --> 00:08:14,910
+مثلا لو كان في عنا خلينا نقول sulfuric acid H2SO4
+
+109
+00:08:14,910 --> 00:08:19,390
+قال والله ممكن يتفاعل مع Sodium Hydroxide واحد
+
+110
+00:08:19,390 --> 00:08:24,150
+وبالتالي يعطينا Sodium Hydrogen Sulfate وفي هذه
+
+111
+00:08:24,150 --> 00:08:27,170
+الحالة إذا كان اتفاعل بس مع واحد Sodium Hydroxide
+
+112
+00:08:27,170 --> 00:08:31,990
+معناته بدي يفقد واحد بروتون صح؟ معناته ال
+
+113
+00:08:31,990 --> 00:08:33,770
+equivalent weight بيساوي ال formula weight على
+
+114
+00:08:33,770 --> 00:08:37,770
+واحدمش هيك لأن number of reacting units ال
+
+115
+00:08:37,770 --> 00:08:40,470
+reacting units يا إما بروتونات يا إما هيدروكسيد
+
+116
+00:08:40,470 --> 00:08:43,350
+اللي دخل في التفاعل فدخل بس بروتون واحد إذا
+
+117
+00:08:43,350 --> 00:08:47,730
+فورمولة وقت على واحد طيب
+
+118
+00:08:47,730 --> 00:08:50,650
+ال sulfuric acid لو اتفاعل مع excess sodium
+
+119
+00:08:50,650 --> 00:08:56,890
+hydroxide يعني sodium hydroxide كتير بزيادة أكم
+
+120
+00:08:56,890 --> 00:09:01,830
+بروتون منه هيتفاعلهأذا عاد ال reacting units من
+
+121
+00:09:01,830 --> 00:09:05,730
+مقدش يكون اتنين يبقى ال equivalent weight يساوي في
+
+122
+00:09:05,730 --> 00:09:10,430
+هذه الحالة formula weight على اتنين نفس الكلام لو
+
+123
+00:09:10,430 --> 00:09:14,490
+حكينا عن الفوسفوريك أسد ممكن الفوسفوريك أسد يتفاعل
+
+124
+00:09:14,490 --> 00:09:21,290
+مع واحد صوديوم هيدروكسيد ويعطي NaH2PO4 فعل بس مع
+
+125
+00:09:21,290 --> 00:09:24,230
+واحد صوديوم هيدروكسيد يعني واحد proton فقط اللي
+
+126
+00:09:24,230 --> 00:09:28,630
+اتفعلمعنى كلام في هذه الحالة الفوسفوريك أسيد ال
+
+127
+00:09:28,630 --> 00:09:30,890
+equivalent weight له بيساوي ال formula weight على
+
+128
+00:09:30,890 --> 00:09:34,930
+واحد ممكن الفوسفوريك أسيد يتفاعل مع اتنين sodium
+
+129
+00:09:34,930 --> 00:09:40,670
+hydroxide وفي هذه الحالة بحصل على NA2HPO4
+
+130
+00:09:40,670 --> 00:09:44,170
+في هذه الحالة ال equivalent weight للفوسفوريك أسيد
+
+131
+00:09:44,170 --> 00:09:49,090
+بيساوي ال formula weight على اتنين وفي الحالة يعني
+
+132
+00:09:49,090 --> 00:09:52,970
+الأخيرة ممكن نقول انهخلّي الفوسفوريك أسيد يتفعل مع
+
+133
+00:09:52,970 --> 00:09:57,350
+تلاتة مولز من أيه؟ من الـ Sodium Hydroxide سايتها
+
+134
+00:09:57,350 --> 00:10:02,270
+هيعطينا NA تلاتة PO4 Sodium Phosphate في هذه
+
+135
+00:10:02,270 --> 00:10:06,310
+الحالة ال equivalent weight للفوسفوريك أسيد هيكون
+
+136
+00:10:06,310 --> 00:10:10,750
+formula weight على تلاتة، إذا يا شبابمعنى الكلام
+
+137
+00:10:10,750 --> 00:10:15,110
+ال equivalent weight يتوقف على نوع التفاعل اللي
+
+138
+00:10:15,110 --> 00:10:18,670
+بتعدي المادة على نوع التفاعل طبعا ال reacting
+
+139
+00:10:18,670 --> 00:10:21,190
+units وال reacting units توقف على نوع التفاعل اللي
+
+140
+00:10:21,190 --> 00:10:26,650
+بتعدي المادة عشان هيك مقدرش اقولك مثلا حضرلي واحد
+
+141
+00:10:26,650 --> 00:10:31,250
+normal phosphoric acidممكن اقولك حضرلي واحد مولار
+
+142
+00:10:31,250 --> 00:10:33,970
+فوسفوريك أسد، بيقوللي سهل، باخد واحد مولار، بحطه
+
+143
+00:10:33,970 --> 00:10:37,990
+في لتر solution، واحد مولار، سهل كتير، باخد واحد
+
+144
+00:10:37,990 --> 00:10:40,730
+مولار، بحطه في لتر solution، بيعطينا واحد مولار
+
+145
+00:10:40,730 --> 00:10:44,430
+فوسفوريك أسد، مافي مشكلة، لكن لما انا أقولك حضرلي
+
+146
+00:10:44,430 --> 00:10:50,650
+واحد normal in فوسفوريك أسد، مانفعش، لأنك بيبقى
+
+147
+00:10:50,650 --> 00:10:54,260
+بتوزن وزنها، الوزن هي اللي بيبقى بتوزنهابتعتمد على
+
+148
+00:10:54,260 --> 00:10:56,640
+عدد ال reacting units وال reacting units بتعتمد
+
+149
+00:10:56,640 --> 00:10:59,920
+على التفاعل من غير ما يقولك إيش التفاعل اللي بده
+
+150
+00:10:59,920 --> 00:11:02,980
+يعدي الفوسفوريك أسد، بتقدرش تقولي والله أه ممكن
+
+151
+00:11:02,980 --> 00:11:06,240
+أحضر لك واحد normal فوسفوريك أسد، بدي أقولك حضر
+
+152
+00:11:06,240 --> 00:11:10,560
+واحد normal فوسفوريك أسد عشان أستخدمه في تفاعله مع
+
+153
+00:11:10,560 --> 00:11:14,860
+اتنين sodium hydroxide مثلا، أو تلاتة moles من ال
+
+154
+00:11:14,860 --> 00:11:18,280
+sodium hydroxide، هتعرفيش اللي توزنه؟لأنك عرفت ال
+
+155
+00:11:18,280 --> 00:11:23,100
+reacting units بمعنى انك حددت ال equivalent weight
+
+156
+00:11:23,100 --> 00:11:26,620
+تبعك و منها حسبت عدد ال equivalence و بعدين حسبت
+
+157
+00:11:26,620 --> 00:11:30,000
+ال normality لكن غير هيك لأ عشان هيك في حسابات ال
+
+158
+00:11:30,000 --> 00:11:34,180
+normality يا شباب لابد اننا نعرف ايش هو التفاعل
+
+159
+00:11:34,180 --> 00:11:37,700
+اللي المادة بدها تعديه مش زي ال molarity على طول
+
+160
+00:11:37,700 --> 00:11:39,800
+ال molarity و الله عرض الملات في ال letter مش
+
+161
+00:11:39,800 --> 00:11:44,450
+مشكلة لكن normality لأ وهذا سببتالت يمكن بيخلّينا
+
+162
+00:11:44,450 --> 00:11:48,190
+مش كتير نحب أنه نتعامل مع ال normality لأنه لو بده
+
+163
+00:11:48,190 --> 00:11:52,150
+حدر محلول بدك تبقى اه والله هذا كذا normal حينما
+
+164
+00:11:52,150 --> 00:11:55,710
+او عندما يتفاعل مع المادة الفلانية بال
+
+165
+00:11:55,710 --> 00:12:01,620
+stoichiometer الفلانية فهذا كلام مش سهل يعنيطيب
+
+166
+00:12:01,620 --> 00:12:06,100
+ممكن في نفس الطريقة يعني ممكن نقول إنه إذا كان
+
+167
+00:12:06,100 --> 00:12:09,740
+التفاعل تفاعل أكسدة واختزال فبنحاول نقسمه لنصين
+
+168
+00:12:09,740 --> 00:12:15,700
+نشوف والله أكم إلكترون في كل نص يعني فمثلا ال
+
+169
+00:12:15,700 --> 00:12:21,020
+permanganate المنجانيز فيها سبعة ممكن يتحول
+
+170
+00:12:21,020 --> 00:12:24,980
+لمنجانيز اتنين في هذه الحالة في عندي من سبعة
+
+171
+00:12:24,980 --> 00:12:28,700
+لاتنين في عندي خمسة إلكترونز ممكن يتحول لمنجانيز
+
+172
+00:12:28,700 --> 00:12:32,970
+تلاتة حسب الوسطفى هذه الحالة فى عندى 7 على 3 فى
+
+173
+00:12:32,970 --> 00:12:36,810
+عندى 4 وكده حوالى مانجانيز 4 من 7 على 4 فى عندى 3
+
+174
+00:12:36,810 --> 00:12:39,910
+بورضه حسب التفاعل حسب الوسط اللى بيكون موجود فيه
+
+175
+00:12:39,910 --> 00:12:45,030
+لكن عدد الإلكترونات هي اللى بيسميها reacting units
+
+176
+00:12:47,030 --> 00:12:51,250
+ف ال normality زي ما عرفناها قلنا هي عدد ال
+
+177
+00:12:51,250 --> 00:12:55,210
+equivalence على ال letter او انه ال normality
+
+178
+00:12:55,210 --> 00:12:58,990
+عبارة عن milliequivalence على ال milliliter حطينا
+
+179
+00:12:58,990 --> 00:13:02,950
+millie فوق و millie تحت بإمكاني معنى الكلام ال
+
+180
+00:13:02,950 --> 00:13:06,550
+milliequivalent بدي ساوي ال normality في ال volume
+
+181
+00:13:06,550 --> 00:13:10,290
+بالmill زي ما كانت ال millimole بتساوي ال molarity
+
+182
+00:13:10,290 --> 00:13:12,680
+في ال volume بالmillالـ Milliequivalent أيش
+
+183
+00:13:12,680 --> 00:13:16,660
+بتساوي؟ الـ Normalty في الـ Volume بالمل هذي شغلة
+
+184
+00:13:16,660 --> 00:13:20,380
+مربط معناها سابقا يبقى أول Milliequivalent حسبناه
+
+185
+00:13:20,380 --> 00:13:23,900
+بقولنا Normalty في الـ Volume بالمل برضه ممكن أعرف
+
+186
+00:13:23,900 --> 00:13:26,880
+الـ Milliequivalent على إنه milligram على ال
+
+187
+00:13:26,880 --> 00:13:30,700
+equivalent weight فهذا تعريف تاني لإيه؟ لـ
+
+188
+00:13:30,700 --> 00:13:33,960
+Milliequivalent زي ما كنا بيقول الملي مول بيساوي
+
+189
+00:13:33,960 --> 00:13:37,520
+milligram على ال formula weight ال equivalent
+
+190
+00:13:37,520 --> 00:13:42,300
+weight مشكلة ال formula weight لأ ماشيهذه
+
+191
+00:13:42,300 --> 00:13:46,060
+العلاقتين بنحسب من خلالهم الـ milliequivalent يبقى
+
+192
+00:13:46,060 --> 00:13:48,580
+milliequivalent إما بنقول normality ال volume
+
+193
+00:13:48,580 --> 00:13:52,040
+بالمل أو بنقول milligram على ال equivalent weight
+
+194
+00:13:52,040 --> 00:13:56,220
+إيش ال equivalent what بيساوي؟ شفناه formula
+
+195
+00:13:56,220 --> 00:14:01,980
+weight على Nطيب يا شباب لو قلنا طيب ماشي ال
+
+196
+00:14:01,980 --> 00:14:05,320
+milliequivalent هو عبارة عن milligram على ال
+
+197
+00:14:05,320 --> 00:14:08,060
+equivalent weight طب وال equivalent weight formula
+
+198
+00:14:08,060 --> 00:14:10,940
+weight على N خلينا نعوض عن ال equivalent weight
+
+199
+00:14:10,940 --> 00:14:12,740
+هنا ب formula weight على N
+
+200
+00:14:16,250 --> 00:14:20,010
+طيب عوضنا بيصير milligram على الفورمولوات، طب إيش
+
+201
+00:14:20,010 --> 00:14:23,250
+ال milligram على الفورمولوات؟ ما هي ال millimoles،
+
+202
+00:14:23,250 --> 00:14:27,130
+إذا .. إذا ال N هذا بتطلع فوق، إذا ال
+
+203
+00:14:27,130 --> 00:14:29,810
+milliequivalent N في ال millimole، وهذا علاقة كتير
+
+204
+00:14:29,810 --> 00:14:33,270
+كتير كتير ممتازة، هنستخدمها في حلول كتير من
+
+205
+00:14:33,270 --> 00:14:36,830
+المسائل، و هتكون يعني علاقة تبسيطية للحل، علاقة
+
+206
+00:14:36,830 --> 00:14:40,970
+تبسيطية جدا للحل، يبقى رجعنا تاني لمفهوم إيه؟ ال
+
+207
+00:14:40,970 --> 00:14:42,590
+millimole حتى في وجود
+
+208
+00:14:46,240 --> 00:14:51,000
+لو جسمنا الطرفين على ملي لتر، ملي equivalent على
+
+209
+00:14:51,000 --> 00:14:56,180
+الملي لتر، إيش يعني؟ملي اكوفلانت على الملي لتر
+
+210
+00:14:56,180 --> 00:14:58,940
+مايعرفها normality طب ملي مول على الملي لتر ايش
+
+211
+00:14:58,940 --> 00:15:03,400
+يعني اه حد حلوة كتير يبقى ان normality بتساوي in
+
+212
+00:15:03,400 --> 00:15:06,520
+في ال molarity اذا انا بقدر احول من ملي مول ل ملي
+
+213
+00:15:06,520 --> 00:15:11,560
+اكوفلانت بسهولة و بقدر احول ايضا من normality ل
+
+214
+00:15:11,560 --> 00:15:14,380
+molarity او من molarity ل normality برضه بسهولة
+
+215
+00:15:14,380 --> 00:15:18,120
+باستخدام العلاقتين هدوه العلاقات جوهرية جدا في حل
+
+216
+00:15:18,120 --> 00:15:21,720
+المسائل لازم ناخد بالنا منهم
+
+217
+00:15:23,790 --> 00:15:27,810
+بدي أذكرك بحاجة في بعض الأحيان نستخدم ال
+
+218
+00:15:27,810 --> 00:15:32,290
+dimensional analysis أو ال factor labelled method
+
+219
+00:15:32,290 --> 00:15:37,110
+فبنستخدم factors conversion factors فبنقول في حالة
+
+220
+00:15:37,110 --> 00:15:42,390
+ال equivalence و ال milliequivalence عادة بنقول كل
+
+221
+00:15:42,390 --> 00:15:48,500
+moleيحتوي على عدد من الملي إكويفلانت كل مول يحتوي
+
+222
+00:15:48,500 --> 00:15:51,580
+على عدد من الملي إكويفلانت ونقول والله واحد مول
+
+223
+00:15:51,580 --> 00:15:55,040
+على N equivalent يعني كل واحد مول في N equivalent
+
+224
+00:15:55,040 --> 00:15:58,460
+أو نقول والله N equivalent موجودة في كل واحد مول
+
+225
+00:15:58,460 --> 00:16:01,880
+هذا نفس الكلام فهذا هو اعتبر conversion factor
+
+226
+00:16:01,880 --> 00:16:06,980
+هنستخدمه في الحلول الآن نيجي ناخد تطبيقات بس عشان
+
+227
+00:16:06,980 --> 00:16:11,440
+الأمور تكون واضحة عنانحاول ناخد تطبيقات نشوف إيش
+
+228
+00:16:11,440 --> 00:16:14,680
+معنى الكلام اللي أخدناه كيف ممكن نستخدمه في الحل
+
+229
+00:16:14,680 --> 00:16:20,500
+فبنقول المثال او ال example المثال بيقول find the
+
+230
+00:16:20,500 --> 00:16:24,580
+equivalent weights of أمونيا وميعطيك ال formula
+
+231
+00:16:24,580 --> 00:16:31,940
+ويتقلها ال oxalic acid H2C2O4 هذا oxalic acid
+
+232
+00:16:31,940 --> 00:16:37,940
+ميعطيك ال formula ويتقلهأه بس ايش جالك؟ جالك ال
+
+233
+00:16:37,940 --> 00:16:40,760
+Oxalic acid in the reaction with excess sodium
+
+234
+00:16:40,760 --> 00:16:43,460
+hydroxide ايش معناه انه يقولك excess sodium
+
+235
+00:16:43,460 --> 00:16:46,760
+hydroxide؟ معناته هدول ال two protons ايش بده
+
+236
+00:16:46,760 --> 00:16:50,400
+يجرعلهم؟ بدهم يتفاعلوا كلهم عشان هيك ال number of
+
+237
+00:16:50,400 --> 00:16:54,260
+reacting units انت لازم تفهم هذا الكلام لما نقولك
+
+238
+00:16:54,260 --> 00:16:57,700
+excess sodium hydroxide معناته كل البروتونات ايش
+
+239
+00:16:57,700 --> 00:17:03,190
+مالها؟ اتفاعلت لان هذا acidفمعنى الكلام ان بجدش
+
+240
+00:17:03,190 --> 00:17:08,990
+باتنين عشان هيك بيقولك and potassium permanganate
+
+241
+00:17:08,990 --> 00:17:14,710
+KMNO4 when ماسبكاش هيك جالك when مانجانيز سبعة
+
+242
+00:17:14,710 --> 00:17:17,410
+اللي هو في ال potassium permanganate المانجانيز
+
+243
+00:17:17,410 --> 00:17:20,730
+سبعة لإن ال oxygen أربعة أربعة في اتنين سالب هي
+
+244
+00:17:20,730 --> 00:17:24,350
+تمانية سالب البوتاسيوم واحد موجب بقال سبعة سالب
+
+245
+00:17:24,350 --> 00:17:27,470
+إذا المانجانيز سبعة موجب هذه ال oxidation number
+
+246
+00:17:27,470 --> 00:17:32,670
+إلهبتحول لمجاريز اتنين من سبعة موجب لاتنين موجب في
+
+247
+00:17:32,670 --> 00:17:36,210
+اندئة كام إلكترون، خمسة، بس هاد المعلومة، الآن
+
+248
+00:17:36,210 --> 00:17:39,350
+نيجي انحل نطلع ال equivalent weight فبنقول
+
+249
+00:17:39,350 --> 00:17:42,090
+الأمونيا، الأمونيا مجالكاش بتفعل مع إيش، لإنها
+
+250
+00:17:42,090 --> 00:17:46,410
+معروفة زي الـHCl بتفعلش بس مع واحد Hydroxide زي ال
+
+251
+00:17:46,410 --> 00:17:50,150
+Sodium Hydroxide بتفعل بس مع واحد HCl، الأمونيا
+
+252
+00:17:50,150 --> 00:17:57,500
+بتفعل بس مع واحد H+, مفهومةلو .. لو كان عندك مية
+
+253
+00:17:57,500 --> 00:18:01,900
+طن HC اللي هو عندك ملكي الواحد أمونيا هياخد H plus
+
+254
+00:18:01,900 --> 00:18:07,880
+واحدة ويسيب الباقي هيش .. بتحملش أكترلو جال excess
+
+255
+00:18:07,880 --> 00:18:14,700
+نفس الكلام لأنه مافيش عندك اتفاعل الا واحد فقط،
+
+256
+00:18:14,700 --> 00:18:17,880
+مابتفعلش مع اكتر من واحد فال equivalent weight
+
+257
+00:18:17,880 --> 00:18:21,080
+بتسوى ال formula weight بالنسبة للأمونيا على واحد،
+
+258
+00:18:21,080 --> 00:18:25,820
+اذا بيسوى 17 gram per equivalentبنجي نطلع على ال
+
+259
+00:18:25,820 --> 00:18:29,820
+equivalent weight للـ H2C2O4 جالك Xs معناته Xs
+
+260
+00:18:29,820 --> 00:18:32,460
+Sodium Hydroxide معناته ال two protons هيتفاجب جال
+
+261
+00:18:32,460 --> 00:18:36,200
+ال N بجد .. بجداش جولنا ال N بتنين اذا بنتطلع
+
+262
+00:18:36,200 --> 00:18:38,460
+بنلاك ال equivalent weight بساوة 4 نوات على 2
+
+263
+00:18:38,460 --> 00:18:41,900
+تسعين على 2 خمسة و أربعين جرام per equivalent
+
+264
+00:18:41,900 --> 00:18:46,140
+بالنسبة للبرمجانات جالك المنجانيز سبعة اتحول
+
+265
+00:18:46,140 --> 00:18:49,340
+لمنجانيز اتنين معناته خمسة electrons يبقى ال
+
+266
+00:18:49,340 --> 00:18:52,490
+equivalent weight للبرمجانات بده ساويفورمولا
+
+267
+00:18:52,490 --> 00:18:58,010
+weight على خمسة يبقى بده يساوي 158 على خمسة واحة
+
+268
+00:18:58,010 --> 00:19:01,350
+وتلاتين اقل ستة من عشرة يبقى حساب ال equivalent
+
+269
+00:19:01,350 --> 00:19:06,490
+weight يا شباب شغلة مش صعبة مجرد بس انه نعرف عدد
+
+270
+00:19:06,490 --> 00:19:11,550
+ال reacting units بنيجي لحسابات جوهرية في الحقيقة
+
+271
+00:19:11,550 --> 00:19:16,150
+مهمة جدا لأنها يعني من خلالها بنعرف تركيزات
+
+272
+00:19:16,150 --> 00:19:21,140
+المحليل وهذا مهم كتير بالنسبة لنافمثلا نتطلع على
+
+273
+00:19:21,140 --> 00:19:25,320
+المثال اللي جدامي بيقول find the normality of the
+
+274
+00:19:25,320 --> 00:19:29,480
+solution containing خمسة و تلاتة من عشر جرام ع لتر
+
+275
+00:19:29,480 --> 00:19:34,730
+of sodium carbonateبقولك ايه عشان بده يحسب هو
+
+276
+00:19:34,730 --> 00:19:38,970
+normality لازم يقولك ايش هو التفاعل اللي بتعدي
+
+277
+00:19:38,970 --> 00:19:43,910
+المادة فجالك انه ال carbonate reacts with ايه ايش
+
+278
+00:19:43,910 --> 00:19:47,930
+معنى الكلام ال N بتساوي اتنين هي جصده ال N بتساوي
+
+279
+00:19:47,930 --> 00:19:52,010
+اتنين فبقول انا علشان يعني اقدر احل المثال احلهلك
+
+280
+00:19:52,010 --> 00:19:57,270
+بتلت طرق تلت طرق يعني اخر طريقة انا بدي اقولك انها
+
+281
+00:19:57,270 --> 00:20:00,850
+يمكن تكون اسهل طريقة لكن بدي امشي معاك خطوة خطوة
+
+282
+00:20:02,200 --> 00:20:07,320
+الحل بهذه الطرق بطريقة أولى أمتع لكن الحل بأخر
+
+283
+00:20:07,320 --> 00:20:13,180
+طريقة أسهل فحنشوف عشان أنا أجيب ال normality أول
+
+284
+00:20:13,180 --> 00:20:16,580
+ما أجيب أجيب ال equivalent weight لازم خطوة أساسية
+
+285
+00:20:16,580 --> 00:20:19,440
+لأن ال equivalent weight بدو يوصل لعدد ال
+
+286
+00:20:19,440 --> 00:20:22,320
+equivalence عدد ال equivalence على ال volume بدو
+
+287
+00:20:22,320 --> 00:20:24,680
+يوصلنا ل normality مفهوم فالخطوات المنطقية
+
+288
+00:20:24,680 --> 00:20:27,720
+equivalent weight equivalence بعدين بده يجسم ال
+
+289
+00:20:27,720 --> 00:20:31,920
+equivalence على ال volumeفبقول equivalent weight
+
+290
+00:20:31,920 --> 00:20:36,840
+بده يساوي ال formula weight على اتنين، ليش اتنين؟
+
+291
+00:20:36,840 --> 00:20:40,680
+لأنه عاجل لك reacts with two protons فبتطلع ال
+
+292
+00:20:40,680 --> 00:20:44,200
+equivalent weight تلاتة و خمسينطيب عدد ال
+
+293
+00:20:44,200 --> 00:20:47,960
+equivalence دي قال والله ال gram من المادة على ال
+
+294
+00:20:47,960 --> 00:20:50,680
+equivalent weight فال gram عندي خمسة و تلاتة ال
+
+295
+00:20:50,680 --> 00:20:53,920
+weight خمسة و تلاتة gram على ال equivalent weight
+
+296
+00:20:53,920 --> 00:20:57,240
+تلاتة و خمسة و طلع واحد من عشرة بدنا إيش هذا عدد
+
+297
+00:20:57,240 --> 00:20:59,980
+ال equivalence بدنا نقسمها الحجم الحجم liter ما هو
+
+298
+00:20:59,980 --> 00:21:03,700
+يبقى واحد liter الحجم المعطيني هي liter إذا ال
+
+299
+00:21:03,700 --> 00:21:09,060
+normality واحد من عشرة normal ماشي يا شباب ببساطة
+
+300
+00:21:09,060 --> 00:21:13,100
+بجيب ال equivalent weightو منها بجيب عدد ال
+
+301
+00:21:13,100 --> 00:21:16,180
+equivalence بجسم ال grams على ال equivalent weight
+
+302
+00:21:16,180 --> 00:21:19,060
+و بعدين بجسمها الحجم ها و اعطينيها في liter اذا
+
+303
+00:21:19,060 --> 00:21:21,340
+هذا هو .. هذه ال normality اللي طلعت معي عدد ال
+
+304
+00:21:21,340 --> 00:21:23,440
+equivalence و ال normality لأن ال equivalence
+
+305
+00:21:23,440 --> 00:21:28,640
+موجودة في liter طيب نيجي نتقلع على حل المسألة
+
+306
+00:21:28,640 --> 00:21:32,680
+بالdimensional analysis او ال factor label method
+
+307
+00:21:34,510 --> 00:21:37,970
+بقول بده ال normality يعني إيه إيش بده؟ يعني بده
+
+308
+00:21:37,970 --> 00:21:41,350
+عدد ال equivalence من ال sodium carbonate في ال
+
+309
+00:21:41,350 --> 00:21:44,610
+liter، هاي معناه ال normality، هذا على اليسار، هاي
+
+310
+00:21:44,610 --> 00:21:48,530
+معناه ال normality، فأنا بقول إيش في عندي معطيات،
+
+311
+00:21:48,530 --> 00:21:51,590
+عندي خمسة و تلاتة من عشر جرام sodium carbonate على
+
+312
+00:21:51,590 --> 00:21:55,470
+ال liter، لما أجي أشتغل dimensional analysis،
+
+313
+00:21:55,470 --> 00:21:58,770
+دائما بحط في اعتباري أنه أنا بفهمش في الإجرامات،
+
+314
+00:21:58,770 --> 00:22:00,950
+أنا بعرفش في الإجرامات، أنا بفهم في ال moles و ال
+
+315
+00:22:00,950 --> 00:22:04,960
+millimoles،بفهمش في ال gramات او ال milligramات
+
+316
+00:22:04,960 --> 00:22:07,420
+بفهم في ال moles او ال millimoles عشانكي لما
+
+317
+00:22:07,420 --> 00:22:12,000
+يعطيني gram مافيش قدام خيار طريق واحد فقط لا يتغير
+
+318
+00:22:12,000 --> 00:22:15,880
+بده احولها لمole اعطاني gram بده احولها لمole
+
+319
+00:22:15,880 --> 00:22:21,790
+مباشرة فكيف بده احول ال gram لمole؟طبعا الكتلة
+
+320
+00:22:21,790 --> 00:22:25,750
+المولية فبنقول ال factor كل مول من ال sodium
+
+321
+00:22:25,750 --> 00:22:28,870
+carbonate هو عبارة عن 106 gram من ال sodium
+
+322
+00:22:28,870 --> 00:22:32,610
+carbonate المول عبارة عن gram formula weight 106
+
+323
+00:22:32,610 --> 00:22:36,730
+gram ابناجي حولناها لمول الآن المول يمكن تحويله لا
+
+324
+00:22:36,730 --> 00:22:41,010
+equivalent لأنه قلتلك قبل شوية كل مول يحتوي على
+
+325
+00:22:41,010 --> 00:22:44,710
+عدد من ال equivalenceفبالنسبة للصوديم كربونيت قال
+
+326
+00:22:44,710 --> 00:22:48,010
+لي بتفعل معه اتنين بروتون لذا كل مول اتنين
+
+327
+00:22:48,010 --> 00:22:51,650
+equivalent او كل اتنين equivalent صوديم كربونيت
+
+328
+00:22:51,650 --> 00:22:56,290
+موجودة في واحد مول صوديم كربونيت معناته النتيجة
+
+329
+00:22:56,290 --> 00:23:01,250
+point one normal ماشي يا شباب فهذه او هذا هو الحل
+
+330
+00:23:01,250 --> 00:23:05,030
+باستخدام ال factor labeled method نتطلع على الحل
+
+331
+00:23:05,760 --> 00:23:09,280
+اللي انا بقولك كتير كتير كتير ممكن يكون بسيط و
+
+332
+00:23:09,280 --> 00:23:15,000
+احنا بقولك مباشرة هذا ايش اجرام ع ال letter طيب
+
+333
+00:23:15,000 --> 00:23:19,060
+انا يعني بقدر احوله لمول ع ال letter صح ولا لأ؟
+
+334
+00:23:19,060 --> 00:23:22,170
+ايش بدي اعمل؟بدي اكسب على ال formula which صار مول
+
+335
+00:23:22,170 --> 00:23:24,630
+على ال letter، مظبوط؟ طب أنا عند ال normality، ال
+
+336
+00:23:24,630 --> 00:23:27,550
+molarity يعني، طب أنا عند ال normality بتساوي N في
+
+337
+00:23:27,550 --> 00:23:31,230
+ال molarity، خلاص انتهى الموضوع، معايا؟ كمان مرة،
+
+338
+00:23:31,230 --> 00:23:33,990
+بقول هذا ground على ال letter، انا بحاول ال
+
+339
+00:23:33,990 --> 00:23:37,610
+molarity، بعرف، molarity، خبير molarity انا،
+
+340
+00:23:37,610 --> 00:23:40,110
+فبحاول على طول، كيف؟ بكسب على ال formula which،
+
+341
+00:23:40,110 --> 00:23:43,110
+اتحول على ال molarity، طب انا بعرف ان ال normality
+
+342
+00:23:43,110 --> 00:23:47,140
+بتساويان في الـ molarity طب الان ما هي ب اتنين
+
+343
+00:23:47,140 --> 00:23:52,080
+اتنين في ال molarity بطلع معايا على طول ان اللي هو
+
+344
+00:23:52,080 --> 00:23:54,340
+عدد ال reacting units اللي هي هنا لبروتناتي
+
+345
+00:23:54,340 --> 00:23:58,580
+المتفائلة فضل السؤال بيوضح لي ان البروتون لازم
+
+346
+00:23:58,580 --> 00:24:02,560
+اعرف انه ايش السؤال بيحددلك ان البروتون فعلا لازم
+
+347
+00:24:02,560 --> 00:24:06,780
+اعرفه لا لا هو بيقولك او بيعطيك المعادلة فانت
+
+348
+00:24:06,780 --> 00:24:10,360
+بتعرف فهنا عندي نفس الطريقة بيقولك انا باعتمد في
+
+349
+00:24:10,360 --> 00:24:14,910
+الحال على N بتساوي N في MالـMolarity الـ number of
+
+350
+00:24:14,910 --> 00:24:18,090
+moles خمسة و تلاتة maximum يعني على الفورمولويت
+
+351
+00:24:18,090 --> 00:24:22,210
+إذا المولاريتي طلعناها فش مشكلة بضربها في اتنين
+
+352
+00:24:22,210 --> 00:24:24,830
+يبقى انت ماعليك انك طلع المولاريتي بس و المولاريتي
+
+353
+00:24:24,830 --> 00:24:28,930
+بتعرف تطلعها بدها شطارة و بعد ما تطلعها اضرب في ال
+
+354
+00:24:28,930 --> 00:24:32,810
+in خلاص حصلت على ال normality طب نتطلع على المثال
+
+355
+00:24:32,810 --> 00:24:36,630
+التالي نفس الكلام بالظبط لكن ال reacting units
+
+356
+00:24:36,630 --> 00:24:40,400
+مختلفة شوية و في طبعا فكرة انا بحب انك تعرفهابيقول
+
+357
+00:24:40,400 --> 00:24:44,820
+find the normality of the solution containing 5
+
+358
+00:24:44,820 --> 00:24:51,060
+.2670 gram per liter potassium dichromate وبيعطيك
+
+359
+00:24:51,060 --> 00:24:55,660
+ال formula وية ايه؟ همتين اربعة أو تسعين بيقولك if
+
+360
+00:24:55,660 --> 00:25:00,280
+acromion 6 is reduced to acromion 3 ايش معنى كلام
+
+361
+00:25:00,280 --> 00:25:05,890
+هذا؟ جداش ال in؟ بنقول هي في الحقيقة مش تلاتةهي
+
+362
+00:25:05,890 --> 00:25:12,830
+ستة، ليش؟ لأن المول أكم إكروميوم فيه؟ في اتنين، كل
+
+363
+00:25:12,830 --> 00:25:16,850
+واحدة فيهم تلت إلكترونات، لأن أنا بهمن المول، أنا
+
+364
+00:25:16,850 --> 00:25:21,450
+بهمن المادة يا دي، أكم إلكترون فيها؟ أه فبتعطيني
+
+365
+00:25:21,450 --> 00:25:24,110
+تلاتة للإكرومة الأولى و تلاتة للإكرومة التانية،
+
+366
+00:25:24,110 --> 00:25:28,290
+معناته في عندي ستة electrons، معنى الكلام number
+
+367
+00:25:28,290 --> 00:25:31,510
+of reacting units، ستة، برضه بقدر أعرف هذا الكلام
+
+368
+00:25:31,510 --> 00:25:36,250
+مباشرة، بقول أكسجين سبعة، مش هيك؟فى اتنين سالب
+
+369
+00:25:36,250 --> 00:25:39,710
+يبقى سالب اربعتاشر البوتاسيوم واحد موجب واحد فى
+
+370
+00:25:39,710 --> 00:25:43,170
+اتنين يعنى اتنين موجب اذا بيبقى سالب اتناشر يبقى
+
+371
+00:25:43,170 --> 00:25:48,070
+لكروميام اتنين موجب اتناشر لكروميام اتنين موجب
+
+372
+00:25:48,070 --> 00:25:52,250
+اتناشر ايش بتعطى اتنين كروميام تلاتة يعنى اتنين فى
+
+373
+00:25:52,250 --> 00:25:57,910
+تلاتة بستةبكيف بدك تساوي 6×12، بدك 6 إلكترونات،
+
+374
+00:25:57,910 --> 00:26:01,590
+فسي يعني بنفسك .. يعني أي طريقة استخدمت للحصول على
+
+375
+00:26:01,590 --> 00:26:05,290
+عدد الإلكترونات حاجة مباشرة، بس هان هو ميعطيك إنه
+
+376
+00:26:05,290 --> 00:26:08,330
+الـChromium 6 اللي موجود هان بتحول لChromium 3
+
+377
+00:26:08,330 --> 00:26:12,570
+وإنت عندك في المول الواقع تنتهي لـChromium 2×3،
+
+378
+00:26:12,570 --> 00:26:17,500
+عندك 6 إلكتروناتإذا ال N عندك F6 نفس الكلام يا
+
+379
+00:26:17,500 --> 00:26:20,740
+شباب أنا فيه أجيب في البداية ال equivalent weight
+
+380
+00:26:20,740 --> 00:26:23,980
+خلينا نشتغلها بطريقة هذه ال equivalent weight بدها
+
+381
+00:26:23,980 --> 00:26:27,540
+تساوي ال formula weight على 6 ال equivalent weight
+
+382
+00:26:27,540 --> 00:26:31,820
+بدها تساوي ال formula weight على 6 طيب ال number
+
+383
+00:26:31,820 --> 00:26:35,140
+of equivalents ل gram بالظبط ال weight على ال
+
+384
+00:26:35,140 --> 00:26:37,060
+equivalent weight طلع أن ال number of equivalents
+
+385
+00:26:37,060 --> 00:26:41,230
+طب هي مدورة في لتر إذا هذه هي ال normalityهذه هي
+
+386
+00:26:41,230 --> 00:26:44,450
+ال normality ممكن نحل نفس المسألة باستخدام ال
+
+387
+00:26:44,450 --> 00:26:48,330
+dimensional analysis بقول إيش يعني normality؟ جال
+
+388
+00:26:48,330 --> 00:26:52,850
+عدد ال equivalence من ال dichromate في ال liter طب
+
+389
+00:26:52,850 --> 00:26:58,420
+إيش عندي معلومات؟جال 5.267 إجرام من الـDichromate
+
+390
+00:26:58,420 --> 00:27:02,540
+على لتر، هذه المعلومات، أنا جرامات؟ مافهمش جرامات،
+
+391
+00:27:02,540 --> 00:27:06,060
+أنا كيميائي، بفهم بالـmoles، فبده يحول لمول، بده
+
+392
+00:27:06,060 --> 00:27:10,260
+conversion factor، بيقول كل مول يحتوي على هو عبارة
+
+393
+00:27:10,260 --> 00:27:17,040
+عن 294 إجرام بوتاسيوم Dichromateحولت ل مول، الآن
+
+394
+00:27:17,040 --> 00:27:19,720
+عملية التحويل من مول ل equivalent سهلة كثير، كل
+
+395
+00:27:19,720 --> 00:27:22,940
+مول عدد من ال equivalence، كل مول موجود فيه عدد من
+
+396
+00:27:22,940 --> 00:27:26,080
+ال equivalence، اذا ات بده اقول ستة equivalence من
+
+397
+00:27:26,080 --> 00:27:29,160
+ال potassium diachromate موجودة في كل مول من ال
+
+398
+00:27:29,160 --> 00:27:32,180
+potassium diachromate، كيف عرفت هذا؟ هي ال N، هي
+
+399
+00:27:32,180 --> 00:27:34,940
+ال N، ستة equivalence من ال potassium diachromate
+
+400
+00:27:34,940 --> 00:27:39,560
+موجودة في كل مول من ال potassium diachromateأو انك
+
+401
+00:27:39,560 --> 00:27:43,460
+يعني تشتغل بالطريقة السهلة جدا اقول هذه gram ع
+
+402
+00:27:43,460 --> 00:27:46,520
+الliter مش هيك بقسم الفروق لصار مول ع الliter
+
+403
+00:27:46,520 --> 00:27:51,220
+molarity بضرب في ستة خلاص صارت normality اه يا
+
+404
+00:27:51,220 --> 00:27:56,500
+شباب كيف بدك تحل حل المهم في النهاية يعني اعتمد
+
+405
+00:27:56,500 --> 00:28:00,500
+طريقة في الحل اللي توصلك للنتيجة الصحيحة بيعني
+
+406
+00:28:00,500 --> 00:28:06,060
+اسرع طريق وبأبصر طريق وبأضمن طريق كويس؟
+
+407
+00:28:14,410 --> 00:28:18,410
+هو بتحدث عن الكروم ويقول لك الكروم ستة بتحول لكروم
+
+408
+00:28:18,410 --> 00:28:22,290
+تلاتة أكم الكروم اللي فيه عندك كان في المركب تنتين
+
+409
+00:28:22,290 --> 00:28:27,690
+إذا اتنين في ستة وهذا اتنين في تلاتة تنتين عندك كل
+
+410
+00:28:27,690 --> 00:28:31,670
+واحدة فيهم تلت إلكترونات إذا التنتين أكم الكروم
+
+411
+00:28:31,670 --> 00:28:37,710
+اللي بيعطوك؟ ستة قيمة الان هي اللي في التفاعل
+
+412
+00:28:42,880 --> 00:28:46,340
+لأ هو التفاعل اللي عندنا هاد تفاعلات تامة أصلا
+
+413
+00:28:46,340 --> 00:28:55,140
+يعني أنت عندك التفاعل كامل أكم إلكترون فيه في إيش؟
+
+414
+00:28:55,140 --> 00:29:02,160
+بالظبط يعني يعني هي هذه ممكن احنا لحظة شوية يعني
+
+415
+00:29:02,160 --> 00:29:05,580
+احنا لو أنت متذكر إيش أخرت في سنة أولى كان ممكن
+
+416
+00:29:05,580 --> 00:29:13,050
+تقولني أنهالـ Dichromate رفعت الزائد 14 H Plus
+
+417
+00:29:13,050 --> 00:29:20,170
+زائد 6 إلكترون بتعطيلنا 2 كروميام 3 زائد 7 مية فهي
+
+418
+00:29:20,170 --> 00:29:24,310
+التفاعل اللي هو بيقولك عنه يعني أو اللي بتكلملك
+
+419
+00:29:24,310 --> 00:29:29,650
+عنه فالـ Dichromate تحول لكروميام 3 طب أكم إلكترون
+
+420
+00:29:29,650 --> 00:29:35,970
+لكل واحد مول 6كويسة عشان هيك جسمنا على او قولنا
+
+421
+00:29:35,970 --> 00:29:42,810
+انه بيساوي ستة طيب خلينا نطلع على موضوع تاني يا
+
+422
+00:29:42,810 --> 00:29:48,910
+شباب موضوع كتير كتير مهم في الحقيقة الحل
+
+423
+00:29:48,910 --> 00:29:52,890
+بطريقة اللي قلناها قبل شوية بنتكلم عن ال density
+
+424
+00:29:52,890 --> 00:29:56,630
+calculations يعني ال calculations اللي بنستخدم
+
+425
+00:29:56,630 --> 00:30:03,740
+فيها ال densityوهي في الحقيقة يعني مفهوم لشيء مهم
+
+426
+00:30:03,740 --> 00:30:07,920
+جدا في الكيميا، مفهوم لشيء مهم جدا في الكيميا،
+
+427
+00:30:07,920 --> 00:30:13,660
+يعني مثلا لو قلتلك لو سمحت حضرلي خمسمائة مل من
+
+428
+00:30:13,660 --> 00:30:23,050
+واحد molar HCl وهي exhaust ال HCl المركزةأعطيتك
+
+429
+00:30:23,050 --> 00:30:28,110
+اجزاز ال HCl المركزة فبتقول بسيطة يعني أنا باخد
+
+430
+00:30:28,110 --> 00:30:32,810
+حجم معين من المركز وبقى أخففه بعطيني واحد molar
+
+431
+00:30:32,810 --> 00:30:37,510
+خمسمية مل من ال HCl فبتيجي تطلع على الاجزازة تشوف
+
+432
+00:30:37,510 --> 00:30:41,030
+جداش التركيز عشان تقول ال molarity في ال volume
+
+433
+00:30:41,030 --> 00:30:43,870
+قبل التركيز تساوي ال molarity في ال volume بعد
+
+434
+00:30:43,870 --> 00:30:50,570
+التركيز هي قانون التخفيفقانون التخفيف الملي مولز
+
+435
+00:30:50,570 --> 00:30:55,610
+قبل التخفيف بتساوي الملي مولز بعد التخفيف فبتاخد
+
+436
+00:30:55,610 --> 00:30:59,950
+حجم معين من المركز لكن عشان تاخد حجم معين بتعرف
+
+437
+00:30:59,950 --> 00:31:05,570
+جديشالتركيز فبتيجي تطلع في البطل على ال label
+
+438
+00:31:05,570 --> 00:31:09,190
+تبعها بتلوفها بتلاقي مش مكتوب التركيز مكتموش
+
+439
+00:31:09,190 --> 00:31:13,850
+التركيز لا ال HCl ولا ال sulphuric acid ولا ال
+
+440
+00:31:13,850 --> 00:31:19,670
+nitric acid ولا ال .. ولا ال .. ال acetic acid ولا
+
+441
+00:31:19,670 --> 00:31:23,910
+ال ammonia ولا ال H2O2 ولا حتى ال organics زي
+
+442
+00:31:23,910 --> 00:31:27,550
+الميثانول والإيثانول لو هزت ال molarity بتلاقيش
+
+443
+00:31:27,550 --> 00:31:34,250
+molarityطب ها كيف بدك تحضر مادة إلها تركيز معين و
+
+444
+00:31:34,250 --> 00:31:36,890
+أنت مش عارف ال modality؟ إذا لازم تحسب ال modality
+
+445
+00:31:36,890 --> 00:31:40,870
+في البداية، إيش بتلاقي على البطول؟ على ال label
+
+446
+00:31:40,870 --> 00:31:48,130
+اللي موجود على البطول؟ بتلاقي ال density للمحلول و
+
+447
+00:31:48,130 --> 00:31:51,850
+بتلاقي أيضا ال percentage لل analyte، يعني إذا كان
+
+448
+00:31:51,850 --> 00:31:55,960
+جزاية HCl، جدّيش ال percentage للHClاسكتكزازيت
+
+449
+00:31:55,960 --> 00:32:01,440
+فوسفوريك أسد جداش ال percentage فوسفوريك أسدمعايا
+
+450
+00:32:01,440 --> 00:32:06,040
+بيعطيك ال percentage مثلا 10% و لا 20% و لا 50% طب
+
+451
+00:32:06,040 --> 00:32:12,020
+و الباقي مية و لا 90% و لا 99% طب الباقي مية ماشي
+
+452
+00:32:12,020 --> 00:32:16,920
+فهو بيعطيك ال density و بيعطيك ال percentage ال
+
+453
+00:32:16,920 --> 00:32:21,860
+density للمحلول و بيعطيك ال percentage ماشي انت
+
+454
+00:32:21,860 --> 00:32:24,820
+المفروض تستخدم ال density و ال percentage و ايضا
+
+455
+00:32:24,820 --> 00:32:27,700
+طبعا ان انت عارف ايش هي المادة فمعاكي الفورمولوات
+
+456
+00:32:27,700 --> 00:32:35,090
+بتطلع ال molarityكيف بنعمل هذا الكلام؟ تعالوا
+
+457
+00:32:35,090 --> 00:32:40,270
+نطلع، كيف ممكن أحصل على ال modularity من أي بطل
+
+458
+00:32:40,270 --> 00:32:46,090
+فيها محلول مركز معروف ال density وال percentage؟
+
+459
+00:32:47,540 --> 00:32:52,020
+نتقل على المثال التالي what volume of concentrated
+
+460
+00:32:52,020 --> 00:32:56,100
+HCL ال formula weight هذه بتلاقيها على ال label
+
+461
+00:32:56,100 --> 00:33:01,280
+formula weight ستة و تلاتين و نص معروفة H و CL ال
+
+462
+00:33:01,280 --> 00:33:05,280
+percentage اتنين و تلاتين في المية يعني تمانية و
+
+463
+00:33:05,280 --> 00:33:08,440
+ستين في المية ميه و اتنين و تلاتين في المية بس HCL
+
+464
+00:33:08,440 --> 00:33:12,500
+مش كله HCL لأ تمانية و ستين في المية ميه و اتنين و
+
+465
+00:33:12,500 --> 00:33:16,370
+تلاتين في المية بس HCLفبال density واحد واحد من
+
+466
+00:33:16,370 --> 00:33:19,910
+عشرة جرام على المل يعني لو أخلت عشرة مل من هذا
+
+467
+00:33:19,910 --> 00:33:24,030
+المحلول بوزنه لحد عشر جرام العشرة مل الواحد بوزن
+
+468
+00:33:24,030 --> 00:33:27,410
+واحد واحد من عشرة العشرة بوزن واحد عاشر أيه ال
+
+469
+00:33:27,410 --> 00:33:33,070
+density؟ ايه كويس؟ فهذا المركز بيقول جداش أكمل
+
+470
+00:33:33,070 --> 00:33:37,210
+لزمين عشان أحضر خمسمية مل من two molar solution
+
+471
+00:33:37,960 --> 00:33:42,260
+عايز اعرف جداش اخد من المركز عشان احضر 500 مل من
+
+472
+00:33:42,260 --> 00:33:46,260
+two molar solution بدي اذكركم مفتاح الحل هو ال
+
+473
+00:33:46,260 --> 00:33:50,240
+density مفتاح الحل هو ال density ال density هذه هي
+
+474
+00:33:50,240 --> 00:33:56,320
+عبارة عن الكل ينتبه اجرام solution لكل مل اكم
+
+475
+00:33:56,320 --> 00:34:00,460
+اجرام solution لكل يعني كل مل جداش كتلته اكم اجرام
+
+476
+00:34:00,460 --> 00:34:05,750
+طب انا بديش اجرام solutionانا بديش gram solution
+
+477
+00:34:05,750 --> 00:34:09,950
+انا بدي gram و لا مول solution وش الفايدة؟ انا بدي
+
+478
+00:34:09,950 --> 00:34:16,770
+gram hcl بدي مول hcl مش هيك مش solution عشان هيك
+
+479
+00:34:16,770 --> 00:34:22,060
+بدك تتبه شوية تتبه شوية انا لو ضربتإجرام solution
+
+480
+00:34:22,060 --> 00:34:27,080
+في ال percentage هذا solution هل كله HCl؟ لأ 32%
+
+481
+00:34:27,080 --> 00:34:31,980
+منه HCl إذا لو ضربت في 32% إيش بتحول؟ HCl بس مش
+
+482
+00:34:31,980 --> 00:34:36,420
+محلول بيبطل محلول بيصير بس HCl يعني هذا إجرام
+
+483
+00:34:36,420 --> 00:34:40,860
+solution ضربناه في ال percentage بتحول لإيش؟ ل
+
+484
+00:34:40,860 --> 00:34:46,740
+gram HClليش؟ لأن الـHCl هو فقط 32% منه، فلو
+
+485
+00:34:46,740 --> 00:34:50,680
+ضربناها في 32%، التلت تقريبا، فبكون هذا عبارة عن
+
+486
+00:34:50,680 --> 00:34:57,240
+الـHCl، أه ساعتها بقدر أتعامل معاه، فبقول 1 و 1 هي
+
+487
+00:34:57,240 --> 00:35:02,240
+ال density في ال percentage، و لاحظوا إنها من 100،
+
+488
+00:35:02,240 --> 00:35:06,850
+حولته لmilligram، ضربته في 10 أقصى 3اذا صار عندى
+
+489
+00:35:06,850 --> 00:35:11,710
+milligram hcl على المل اشي احنا بنعرفه ال density
+
+490
+00:35:11,710 --> 00:35:17,150
+فى ال percentage صارت gram hcl دورت فى 10 عقل 3
+
+491
+00:35:17,150 --> 00:35:23,430
+صارت milligram hcl ماشي فى ايه لكل واحد mil طب انا
+
+492
+00:35:23,430 --> 00:35:26,930
+مديش milligram hcl انا مدي millimole hcl لما نكون
+
+493
+00:35:26,930 --> 00:35:30,070
+millimole على ال milliliter يعني ايش؟ملي مول على
+
+494
+00:35:30,070 --> 00:35:34,410
+ملي لتر ايش يعني مولارتي هي اللي بديها فإيش عشان
+
+495
+00:35:34,410 --> 00:35:38,990
+احصل على ملي مول ايش بدي بدي اقبع بدي هيني زي ما
+
+496
+00:35:38,990 --> 00:35:43,410
+انتوا شايفين بأجسم على ال formula weight هدا هي
+
+497
+00:35:43,410 --> 00:35:47,230
+خلاص طلعت ال molarity كمان مرة بقول عندي ال
+
+498
+00:35:47,230 --> 00:35:50,950
+density اجرام solution انا مش مهتم بال solution ال
+
+499
+00:35:50,950 --> 00:35:53,830
+solution فيه مية و فيه مادة أخرى مافيش فايدة منه
+
+500
+00:35:54,280 --> 00:35:57,360
+ماعرفش أعمل عليه أي Stoichiometric Calculation بدي
+
+501
+00:35:57,360 --> 00:36:01,280
+أحوّل لل Analyte بدي أحوّل لل HCl جدّاش منه HCl
+
+502
+00:36:01,280 --> 00:36:07,280
+جال 32% 32 عالمية ماحدش يكتب 32 من غير .. من غير
+
+503
+00:36:07,280 --> 00:36:15,740
+.. مش كثر يعني مش 32 ضعف لأ 32 مئة تلت HClتمام؟
+
+504
+00:36:15,740 --> 00:36:18,960
+فضربناها في point three two حولناها لميلي جرام انا
+
+505
+00:36:18,960 --> 00:36:22,200
+ضربناها في عشرة اقص تلاتة صار ميلي جرام hcl على
+
+506
+00:36:22,200 --> 00:36:25,680
+الميلي انا بدي ميلي مول على الميلي اذا بس بدي اقسم
+
+507
+00:36:25,680 --> 00:36:30,620
+عليا الفورمولويات بتعطيني molarity هاي المنطق
+
+508
+00:36:30,620 --> 00:36:35,920
+تبعنا فجسمنا طلع عندى تسعة واربعة اقصتين الكتافة؟
+
+509
+00:36:35,920 --> 00:36:36,840
+اه كنت على الحجم
+
+510
+00:36:41,920 --> 00:36:46,680
+هي انا بتكلم عن الملي انا خدت واحد ملي واحد ملي من
+
+511
+00:36:46,680 --> 00:36:50,620
+المحلول انت بيه عليا انت بيه عليا واحد ملي من ايش؟
+
+512
+00:36:50,620 --> 00:36:57,160
+من المحلول هذا الواحد ملي جديش فيه من ال HCl 32%
+
+513
+00:36:57,160 --> 00:37:04,440
+ضربت فيه 32% صارت ال value هذه من ال HCl في الملي
+
+514
+00:37:04,440 --> 00:37:10,620
+مش هيك؟مش ال 32% من ال 1 1 من 10 هي اللي في الملي
+
+515
+00:37:10,620 --> 00:37:13,680
+موجودة انا مش عندى غيرها الملي اعتبر مش عندى غيرها
+
+516
+00:37:13,680 --> 00:37:20,680
+الملي تمام كان وزنه 1 1 من 10 gram solution انا
+
+517
+00:37:20,680 --> 00:37:24,700
+مابديش gram solution مابدي gram hcl فضربته في
+
+518
+00:37:24,700 --> 00:37:28,820
+point three two صار gram hcl ضربته في عشر أقصى
+
+519
+00:37:28,820 --> 00:37:33,160
+تلاتة صار اللي جدامى وين هذا الكلام موجود؟ في
+
+520
+00:37:33,160 --> 00:37:38,640
+الملي فيه الحجمما لاجدش الحجم يا عم هو هو الحجم هي
+
+521
+00:37:38,640 --> 00:37:43,500
+و جاعد في الملي هادى الكتلة في الملي الكتلة هادى
+
+522
+00:37:43,500 --> 00:37:47,840
+موجودة في واحد mill بس فايلة زي ما هي لكن بقول انا
+
+523
+00:37:47,840 --> 00:37:51,920
+بديش كتلة انا بدي milli mole كيه بده احول الكتلة
+
+524
+00:37:51,920 --> 00:37:55,020
+هادى ل milli mole؟ على الكتلة المولية اتحول ل
+
+525
+00:37:55,020 --> 00:37:57,120
+milli mole اذا ال milli mole على ال milliliter
+
+526
+00:37:57,120 --> 00:38:00,180
+معناته ايش صارت? molarity ال molarity تتسعة و
+
+527
+00:38:00,180 --> 00:38:05,410
+اربعة و ستينالان سهل جدا اقول المولاريتي في ال
+
+528
+00:38:05,410 --> 00:38:08,350
+volume يعني ال millimoles قبل التخفيف تسوى
+
+529
+00:38:08,350 --> 00:38:11,030
+المولاريتي في ال volume يعني ال millimoles بعد
+
+530
+00:38:11,030 --> 00:38:16,230
+التخفيف ف9.64 في ال volume بالمل بتسوى 2 في 500
+
+531
+00:38:16,230 --> 00:38:19,170
+بعد التخفيف بطلع ال volume بالمل من المركز اللي
+
+532
+00:38:19,170 --> 00:38:24,780
+لازم اخده 10.4 من 10 ملبقول هدول العشرة وأربعة من
+
+533
+00:38:24,780 --> 00:38:28,380
+عشرة mil باخدهم و بحطهم على كمية من الميه يعني و
+
+534
+00:38:28,380 --> 00:38:32,420
+لتاكن مثلا متين mil بحطهم شوية شوية دائما بضيف
+
+535
+00:38:32,420 --> 00:38:36,960
+المركز على الميه مش الميه على المركز المركز على
+
+536
+00:38:36,960 --> 00:38:42,200
+الميه بالذات في حالة ال H2SO4 بس بشكل عام خلينا
+
+537
+00:38:42,200 --> 00:38:47,350
+نقولهيقول general practice procedure او general
+
+538
+00:38:47,350 --> 00:38:51,290
+practice عندنا انه دائما نضيف المركز على الميه مش
+
+539
+00:38:51,290 --> 00:38:56,010
+الميه على المركز بنضيفه شوية شوية اضفناه بنكمل
+
+540
+00:38:56,010 --> 00:39:02,430
+الحجم ل 500ml بكون عندنا 500ml من 2 molar HCl
+
+541
+00:39:02,430 --> 00:39:06,950
+solution الاتنين هي الاتنين لتر ما اعطيه لنا يا
+
+542
+00:39:06,950 --> 00:39:14,620
+حبيبي هيها بده يحضر 500ml من 2 molarطيب ناخد اللي
+
+543
+00:39:14,620 --> 00:39:18,400
+فاته أي إشي بدي أخد مثال و بدي أفرجك كيف هو بسيط
+
+544
+00:39:18,400 --> 00:39:22,880
+كتير نفس المنطق تماما ففي عندنا bottle من ال
+
+545
+00:39:22,880 --> 00:39:28,020
+concentrated H2SO4 و أحنا حابين نحسب جدش ال
+
+546
+00:39:28,020 --> 00:39:31,560
+molarity إليها علشان نحبر letter من point one
+
+547
+00:39:31,560 --> 00:39:34,990
+molar solutionفالمثال بيقول how many ml of
+
+548
+00:39:34,990 --> 00:39:45,490
+concentrated H2SO4 معطيك على البطول 98
+
+549
+00:39:45,490 --> 00:39:59,260
+.1% 94% 6% ميه ال density 1.83كويس جديش بدنا من
+
+550
+00:39:59,260 --> 00:40:02,280
+الحمض المركز علشان حضر واحد determined point one
+
+551
+00:40:02,280 --> 00:40:07,360
+molar solution بقول اببساطة خالص بقول انا عند ال
+
+552
+00:40:07,360 --> 00:40:13,800
+density مفتاح الحل هاد اجرام solutionعليته على
+
+553
+00:40:13,800 --> 00:40:17,500
+الملي بدي جرام solution على الملي انا بديش جرام
+
+554
+00:40:17,500 --> 00:40:22,140
+solution بدي جرام H2SO4 ايش بعمل؟ بضرب في ال
+
+555
+00:40:22,140 --> 00:40:26,060
+percentage بديش جرام بدي ملي جرام بضرب في ايش؟ في
+
+556
+00:40:26,060 --> 00:40:30,080
+10 أقصر اذا صار هذه الوزنة موجودة في المل انا بديش
+
+557
+00:40:30,080 --> 00:40:34,020
+ملي جرام على المل انا بدي ملي مول على المل بجسم
+
+558
+00:40:34,020 --> 00:40:37,820
+على ال formula weight صارت مولارتها الموضوع هي بها
+
+559
+00:40:37,820 --> 00:40:43,530
+البساطة خالص يعني بساطة شديدة جدافي البداية بجيب
+
+560
+00:40:43,530 --> 00:40:47,450
+milligram ع المل و بعدين بجسم على الفورمولات
+
+561
+00:40:47,450 --> 00:40:51,490
+بعطيني millimol ع المل يعني molarity، كويس، بتطلع
+
+562
+00:40:51,490 --> 00:40:55,510
+عندى ال molarity 17.5، الآن بنفس الطريقة اللى
+
+563
+00:40:55,510 --> 00:41:01,900
+ذكرناها سابقا بنقول انهMIVI أو الملي مولز قبل
+
+564
+00:41:01,900 --> 00:41:05,400
+التخفيف تساوي الملي مولز بعد التخفيف، معناه الكلام
+
+565
+00:41:05,400 --> 00:41:10,660
+17.5 في ال volume بالمل تساوي 0.1 في الف لازم هذه
+
+566
+00:41:10,660 --> 00:41:14,200
+.. مدام هذه بالمل لازم هذه تكون بالمل، نفس الحاجة،
+
+567
+00:41:14,200 --> 00:41:17,930
+عشان ملي مول تساوي ملي مولبتطلع ال volume 5.71
+
+568
+00:41:17,930 --> 00:41:22,250
+بناخده و بنضيفه على شوية ميه على 200 مل ميه مثلا
+
+569
+00:41:22,250 --> 00:41:27,690
+شوية شوية على الجدار بينزل لأن ال H2SO4 شره جدا
+
+570
+00:41:27,690 --> 00:41:32,710
+للميه لو .. لو حطيت الميه عليه ممكن هو ينط بده
+
+571
+00:41:32,710 --> 00:41:35,830
+يحاول يوصل لكن لما نضيفه هو على الميه بتخفف أول
+
+572
+00:41:35,830 --> 00:41:39,390
+بأول و طبعا يعني أثناء الإضافة على الميه الميه
+
+573
+00:41:39,390 --> 00:41:43,770
+بتسخن بتصير زي النعر يعني حرارة عالية فلازم تنتبه
+
+574
+00:41:43,880 --> 00:41:48,380
+بعد ما نضيفه بنكمل الحجم لواحد لتر بنكون حصلنا على
+
+575
+00:41:48,380 --> 00:41:53,100
+واحد لتر من point one molar solution انا عندى easy
+
+576
+00:41:53,100 --> 00:41:56,880
+shortcut ممكن انت تحفظها او يعني تطلع عليها ال
+
+577
+00:41:56,880 --> 00:42:00,960
+molarity بتساوي ال density اللى هى a gram solution
+
+578
+00:42:00,960 --> 00:42:05,160
+ع المل بتروح من ال percentage تحول لإيه؟ ل gram
+
+579
+00:42:05,160 --> 00:42:09,320
+solute على المل بحول فى عشرة قصيرة حول ملي gram ع
+
+580
+00:42:09,320 --> 00:42:14,740
+الملعلى الفورمولوات من اللي مُل على اللي يعني
+
+581
+00:42:14,740 --> 00:42:20,500
+مُلارتي يعني فيك تحفظ هذا القانون و تحل عليه يعني
+
+582
+00:42:20,500 --> 00:42:24,580
+المسائل متعلقة بال density calculations بس لازم
+
+583
+00:42:24,580 --> 00:42:29,500
+تتذكر انه ال percentage مثلا 35% معناه تهيأت
+
+584
+00:42:29,500 --> 00:42:35,080
+كتابتها مش 35 ضعيف لأ كسر ال percentage قدر عن
+
+585
+00:42:35,080 --> 00:42:42,630
+ايه؟ عن كسربالظبط خلاص من مية على مية طيب في شباب
+
+586
+00:42:42,630 --> 00:42:49,850
+يعني مصطلحين بحب أنه نفرج بينهم هيمروا معنا في
+
+587
+00:42:49,850 --> 00:42:53,110
+المستقبل بشكل واسع كتير لكن هل جيت ناخد يعني إيش
+
+588
+00:42:53,110 --> 00:42:59,530
+المفهوم العام اللي لهم لو إحنا قلنالك حضر واحد من
+
+589
+00:42:59,530 --> 00:43:05,680
+عشرة مولر acidic acidقال و الله بناخد واحد من عشرة
+
+590
+00:43:05,680 --> 00:43:10,380
+مول من ال Acetic Acid و بنحطه فيه شوية ميه و بنكمل
+
+591
+00:43:10,380 --> 00:43:15,940
+ل لتر صار عندنا واحد من عشرة مولار Acetic Acid طب
+
+592
+00:43:15,940 --> 00:43:20,460
+الواحد من عشرة مول هو عبارة عن جداش ال .. لو قلنا
+
+593
+00:43:20,460 --> 00:43:23,100
+جداش المول من ال Acetic Acid بقول ستين اجرام مثلا
+
+594
+00:43:23,100 --> 00:43:28,840
+ستين اجرام ستين اجرام طيب ..
+
+595
+00:43:31,940 --> 00:43:35,880
+يعني الواحد من عشرة مول ستة gram ستة gram بدنا
+
+596
+00:43:35,880 --> 00:43:38,960
+نحطها في liter بعطيني واحد من عشرة molar acetic
+
+597
+00:43:38,960 --> 00:43:42,620
+acid طيب يا شباب ال acetic acid أنا بعرف أنه
+
+598
+00:43:42,620 --> 00:43:47,780
+electrolyte بعيف، electrolyte إيش ماله؟ بعيف،
+
+599
+00:43:47,780 --> 00:43:52,420
+فمعنى الكلام لما أنا أحطه في الميه إيش بده يجراله؟
+
+600
+00:43:52,420 --> 00:43:58,280
+جزء منه بده يتفككالان صح انا وزنت 1 من 10 مول في
+
+601
+00:43:58,280 --> 00:44:01,820
+ال letter بسمي هذا التركيز اللي هو 1 من 10 مولار
+
+602
+00:44:01,820 --> 00:44:08,340
+بسميه analytical concentration C برمزه بالرمز C لل
+
+603
+00:44:08,340 --> 00:44:13,700
+H O A Cمااخد بالك؟ جداش التركيز واحد من .. طب كيف
+
+604
+00:44:13,700 --> 00:44:17,660
+عرفته؟ أنا وزنت واحد من عشرة مول وحطته في ال liter
+
+605
+00:44:17,660 --> 00:44:21,600
+فجداش التركيز واحد من عشرة مولار لكن أنا ماليش
+
+606
+00:44:21,600 --> 00:44:25,520
+دعوة اتفكك ولا لا التركيز الكلي هو عبارة عن واحد
+
+607
+00:44:25,520 --> 00:44:29,460
+من عشرة مولار هذا التركيز اسمه ايه؟ analytical
+
+608
+00:44:29,460 --> 00:44:33,760
+concentration لكن لما ينحط في الميه جزء منه مضله
+
+609
+00:44:33,760 --> 00:44:38,990
+زي ما هو أغلبه لكن جزء منه اشمالهبيتفكك فالتركيز
+
+610
+00:44:38,990 --> 00:44:41,830
+الكلي اللي هو analytical concentration بساوي
+
+611
+00:44:41,830 --> 00:44:46,090
+التركيز اللي ما اتفككش اللي ضايل زي ما هو زائد
+
+612
+00:44:46,090 --> 00:44:50,410
+التركيز اللي اتفكك بسمي هذا analytical
+
+613
+00:44:50,410 --> 00:44:53,890
+concentration اللي ما اتفككش هو equilibrium
+
+614
+00:44:53,890 --> 00:44:58,310
+concentrationEquilibrium اللى موجود فى المحلول
+
+615
+00:44:58,310 --> 00:45:02,530
+فعليا كويس ففى فرق بين ال analytical concentration
+
+616
+00:45:02,530 --> 00:45:05,910
+او فى فرق بين ال equilibrium concentration ال
+
+617
+00:45:05,910 --> 00:45:09,550
+analytical بالنسبة لـ C وهذا عبارة عن الكمية اللى
+
+618
+00:45:09,550 --> 00:45:11,910
+انا بوزنها او الكمية اللى انا عارف انا اخدتها و
+
+619
+00:45:11,910 --> 00:45:15,490
+حطيتها لكن فى المحلول ايش حصل جزء منها اتفكك جزء
+
+620
+00:45:15,490 --> 00:45:18,210
+منها راح جزء منها مش موجود جزء منها حصل و
+
+621
+00:45:18,210 --> 00:45:23,030
+dimerizationلكن جداش dial زي ما هو هذا ايش اسمه
+
+622
+00:45:23,030 --> 00:45:27,250
+equilibrium concentration و دائما بنحطه بجثين
+
+623
+00:45:27,250 --> 00:45:33,030
+مربعين ماشي هذه بس مجرد يعني ملاحظة هتستخدمها إذا
+
+624
+00:45:33,030 --> 00:45:37,850
+الله راد في المستقبل الحصة الجاية هنتقل لل
+
+625
+00:45:37,850 --> 00:45:41,170
+dilution problems و نكمل برضه في ال stoichiometric
+
+626
+00:45:41,170 --> 00:45:41,910
+titrations
+
diff --git a/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/tK31Pig9Ny8_raw.srt b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/tK31Pig9Ny8_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..8ddf8792a81451304923ca0dfb0e332e84a68048
--- /dev/null
+++ b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/tK31Pig9Ny8_raw.srt
@@ -0,0 +1,2504 @@
+1
+00:00:20,910 --> 00:00:24,810
+بقى شوية بالحصة الماضية كنا بدأنا نتكلم عن ال
+
+2
+00:00:24,810 --> 00:00:29,690
+stoichiometric calculations ووصلنا لطرق التعبير عن
+
+3
+00:00:29,690 --> 00:00:33,410
+ال concentration فاتكلمنا عن ال molarity وشوفنا ان
+
+4
+00:00:33,410 --> 00:00:37,510
+ال molarity هي عبارة عن number of moles of solute
+
+5
+00:00:37,510 --> 00:00:42,870
+dissolved in one liter of solutionو قلنا من هذا
+
+6
+00:00:42,870 --> 00:00:49,750
+الكلام قلنا انه ممكن نقول ال millimoles تساوي ال
+
+7
+00:00:49,750 --> 00:00:52,990
+modality في ال volume بالمل وهذه كانت علاقة مهمة
+
+8
+00:00:52,990 --> 00:00:56,950
+جدا أكملت العلاقة السابقة اللي كنا بنقول ال
+
+9
+00:00:56,950 --> 00:01:01,110
+millimole بتساوي milligram من ال substance على ال
+
+10
+00:01:01,110 --> 00:01:04,510
+formula weight اليوم بنكمل في نفس السياقة بنتكلم
+
+11
+00:01:04,510 --> 00:01:09,810
+عن ال normalitycalculations لكن اليوم فقط هنتكلم
+
+12
+00:01:09,810 --> 00:01:13,810
+عن مقدمة في ال normality و هنرجع لنفس الموضوع في
+
+13
+00:01:13,810 --> 00:01:18,210
+المستقبل بعد محاضرات قليلة إذا الله راد إيش
+
+14
+00:01:18,210 --> 00:01:20,830
+المقصود بال normality؟ ال normality زي ال molarity
+
+15
+00:01:20,830 --> 00:01:27,550
+هي عبارة عن وحدة أو مصطلح يراد به التعبير عن
+
+16
+00:01:27,550 --> 00:01:32,330
+التركيز تعبير عن التركيز كيف يمكن نعرف ال
+
+17
+00:01:32,330 --> 00:01:35,810
+normality؟يمكن تعريف الـ normality علي إنها number
+
+18
+00:01:35,810 --> 00:01:40,730
+of equivalents of solute dissolved in one liter of
+
+19
+00:01:40,730 --> 00:01:44,080
+solutionلكن لما نتكلم نقول والله number of
+
+20
+00:01:44,080 --> 00:01:49,240
+equivalents فإيش هو ال equivalent هذا يعني لازم
+
+21
+00:01:49,240 --> 00:01:52,200
+نعرفه لأن احنا بيقول number of moles بنعرف ال mole
+
+22
+00:01:52,200 --> 00:01:57,340
+لكن number of equivalents لسه احنا مادرسناش إيش
+
+23
+00:01:57,340 --> 00:02:03,020
+يعني equivalent فممكن تعريف ال equivalent على إنه
+
+24
+00:02:03,020 --> 00:02:08,540
+ال equivalent بيساوي ال
+
+25
+00:02:08,540 --> 00:02:14,510
+number of gramsعلى ال equivalent weight number of
+
+26
+00:02:14,510 --> 00:02:18,330
+grams of solute طبعا على ال equivalent weight فهذا
+
+27
+00:02:18,330 --> 00:02:21,170
+بيعطينا number of equivalents طيب number of grams
+
+28
+00:02:21,170 --> 00:02:23,930
+of solute هذه مفهومة لكن ايش هو ال equivalent
+
+29
+00:02:23,930 --> 00:02:27,490
+weight برضه بحلناش المشكلة جال ال equivalent
+
+30
+00:02:27,490 --> 00:02:33,970
+weight هو عبارة عن ال formula weight على n حيث ان
+
+31
+00:02:33,970 --> 00:02:40,040
+هذه عبارة عن number of reacting unitsnumber of
+
+32
+00:02:40,040 --> 00:02:46,320
+reacting units عدد الوحدات المتفاعلة برضه يعني
+
+33
+00:02:46,320 --> 00:02:49,700
+الموضوع مش واضح بالنسبالنا لأن عدد الوحدات
+
+34
+00:02:49,700 --> 00:02:52,560
+المتفاعلة زي إيش يعني ممكن نقول والله إذا كان عندي
+
+35
+00:02:52,560 --> 00:02:56,180
+تفاعل acid base فعدد الوحدات المتفاعلة ممكن هتكون
+
+36
+00:02:56,180 --> 00:03:01,360
+والله protons H plus أو hydroxides لو كان عندي
+
+37
+00:03:01,360 --> 00:03:04,560
+تفاعل أكسد أو اختزال فعدد الوحدات المتفاعلة
+
+38
+00:03:04,560 --> 00:03:11,120
+electrons فبرضه هذا بتوقف على التفاعلعشان هيك لما
+
+39
+00:03:11,120 --> 00:03:15,980
+نقول احنا ال normality هي عدد ال equivalence من ال
+
+40
+00:03:15,980 --> 00:03:19,220
+solute المذابة في ال liter وال equivalent هو عبارة
+
+41
+00:03:19,220 --> 00:03:22,140
+عن اجرام solute على ال equivalent weight وال
+
+42
+00:03:22,140 --> 00:03:25,320
+equivalent weight هو عبارة عن formula weight على N
+
+43
+00:03:25,320 --> 00:03:31,170
+عدد من ال reacting unitsهذه جثة يعني الحسابات
+
+44
+00:03:31,170 --> 00:03:37,730
+تبعتنا مش حسابات مباشرة و تتوقف بشكل أساسي على نوع
+
+45
+00:03:37,730 --> 00:03:41,570
+التفاعل اللي ال solute أو المادة اللي عندى بدها
+
+46
+00:03:41,570 --> 00:03:45,780
+تعديهعلشان هيك يا شباب يمكن كان هذا من الدوافع
+
+47
+00:03:45,780 --> 00:03:53,600
+المهمة خلف يعني التقليل من استخدام ال normality
+
+48
+00:03:53,600 --> 00:03:57,040
+لدرجة ان احنا الآن في الكيمة التحليلية مانستخدمش
+
+49
+00:03:57,040 --> 00:03:59,780
+ال normality في الحسابات تبعاتنا عادة لا نستخدمها
+
+50
+00:03:59,780 --> 00:04:05,610
+في الحسابات تبعاتناالان بنستخدم فقط ال molarity مش
+
+51
+00:04:05,610 --> 00:04:09,170
+ال normality طيب مدام بنستخدم احنا ال normality ..
+
+52
+00:04:09,170 --> 00:04:12,590
+ال molarity مش ال normality و استخدام ال normality
+
+53
+00:04:12,590 --> 00:04:16,830
+يمكن في ال .. يعني أصبح ضئيل جدا و محدود للغاية في
+
+54
+00:04:16,830 --> 00:04:20,290
+الأربعين سنة اللي فاتوا تقريبا او في التلاتين سنة
+
+55
+00:04:20,290 --> 00:04:24,270
+او اكتر اللي فاتوا فليش احنا بندرسها؟ ليش ندرس ال
+
+56
+00:04:24,270 --> 00:04:28,420
+normality اذا؟ مدام توقفنا عن استخدامها تقريبافليش
+
+57
+00:04:28,420 --> 00:04:32,660
+ندرسها؟ بنقول دراستها مهمة جدا لأن كل ال
+
+58
+00:04:32,660 --> 00:04:38,360
+literature السابق في عشرات السنوات الماضية و
+
+59
+00:04:38,360 --> 00:04:43,660
+القرون الماضية يعني آخر قرنين تقريبا كل الدراسات
+
+60
+00:04:43,660 --> 00:04:47,040
+اللي كانت بتتم كانت بتتم باستخدام ال normality فهل
+
+61
+00:04:47,040 --> 00:04:52,350
+يعقل انهيعني لا نلقي بالا للنتائج اللي العلماء من
+
+62
+00:04:52,350 --> 00:04:56,290
+قديم الزمان حصلوا عليها و أصبحت لنا يعني مكتبة
+
+63
+00:04:56,290 --> 00:05:00,210
+قيمة جدا من النتائج المختلفة فلا يجوز إلا أن طبعا
+
+64
+00:05:00,210 --> 00:05:03,930
+نهمل هذه النتائج عشان هيك لازم نفهم إيش يعني
+
+65
+00:05:03,930 --> 00:05:07,390
+normality وكيف نستخدمها وإيش معنى النتائج اللي
+
+66
+00:05:07,390 --> 00:05:12,490
+علماءنا السابقين حصلوا عليها هذا جانب من الجوانب
+
+67
+00:05:12,490 --> 00:05:17,580
+والجانب الآخر صحيح احنا في الكيميابنفضّل عدم
+
+68
+00:05:17,580 --> 00:05:21,120
+استخدام الـ normality و لا نوصي باستخدامها، لكن
+
+69
+00:05:21,120 --> 00:05:27,060
+للأسف بعض الأنظمة الأخرى كمثلا الطب أو جزء مهم من
+
+70
+00:05:27,060 --> 00:05:32,680
+ال biochemistry والتحاليل الطبيةالبيئة في بعض
+
+71
+00:05:32,680 --> 00:05:36,560
+الأحيان نجد انه هناك علماء يستخدموا لازالوا
+
+72
+00:05:36,560 --> 00:05:40,800
+يستخدموا بشكل أساسي ال normality فطبعا ايضا لا
+
+73
+00:05:40,800 --> 00:05:46,140
+يُعقل انه لانوا القيبالا للنتائج تباعتهم لأ علشانك
+
+74
+00:05:46,140 --> 00:05:49,720
+احنا لازم نفهم ال normality بشكل واضح و جيد كتير
+
+75
+00:05:50,270 --> 00:05:53,530
+وفي نفس الوقت لا ندعو الاستخدامها، بالعكس ندعو
+
+76
+00:05:53,530 --> 00:05:57,050
+الجميع للاقتزام باستخدام الـMolarity خاصة في العصر
+
+77
+00:05:57,050 --> 00:06:02,050
+الحديث اللي أصبح يعني فيه نوع من العالمية في
+
+78
+00:06:02,050 --> 00:06:07,710
+العلوم وهناك مؤسسات عالمية بتوصي باستخدام يعني
+
+79
+00:06:07,710 --> 00:06:11,550
+أساليب معينة للتعبير عن التركيز واحنا الأوساط
+
+80
+00:06:11,550 --> 00:06:15,530
+العلمية الكيميائية توصي باستخدام الـMolarity مش
+
+81
+00:06:15,530 --> 00:06:22,910
+الـNormality، ماشي يا شبابطيب نتكلم اكتر عن ايش
+
+82
+00:06:22,910 --> 00:06:26,590
+يعني reacting unit؟ reacting unit احنا بنقول والله
+
+83
+00:06:26,590 --> 00:06:32,270
+عدد الوحدات المتفاعلة لما نكون عندى مثلا acid زى
+
+84
+00:06:32,270 --> 00:06:37,370
+ال HClأيش فيه ممكن يتفاعل؟ فش اللي غيرها البروتون
+
+85
+00:06:37,370 --> 00:06:41,110
+البروتون asset base بتفعل البروتون أكم البروتون
+
+86
+00:06:41,110 --> 00:06:45,290
+فيه عندى؟ واحد لما نكون فيه عندى واحد فش قدامه
+
+87
+00:06:45,290 --> 00:06:48,890
+خيار إلا إنه بس الواحد دول يتفاعل عشان هيك عادة ال
+
+88
+00:06:48,890 --> 00:06:53,850
+HCL معروف تفاعله بده يتفاعل مثلا أي حاجة لو بفقد
+
+89
+00:06:53,850 --> 00:06:57,590
+البروتون واحد وبالتالي لما نقول ال equivalent
+
+90
+00:06:57,590 --> 00:07:02,450
+weight بساوي formula weight على N N بالنسبة للHCL
+
+91
+00:07:02,450 --> 00:07:05,850
+دائما واحدليه؟ لأنه مافيش عنده وره إلا بروتون، مش
+
+92
+00:07:05,850 --> 00:07:08,630
+معقول يتفعلوا إتنين بروتون، لأنه مافيش عنده إلا
+
+93
+00:07:08,630 --> 00:07:12,150
+بروتون واحد، فمثلا ال HCl دائما ال formula weight
+
+94
+00:07:12,150 --> 00:07:16,470
+بتساوي ال equivalent weight، لو إجينا لل nitric
+
+95
+00:07:16,470 --> 00:07:19,170
+acid، لل pericloric acid، نفس الكلام في ال acid
+
+96
+00:07:19,170 --> 00:07:22,950
+base reaction تبعهم، ال equivalent weight هو ال
+
+97
+00:07:22,950 --> 00:07:28,040
+formula weightكبازز لما نقول والله عندى ال sodium
+
+98
+00:07:28,040 --> 00:07:31,460
+hydroxide أكم hydroxide فى ال sodium hydroxide اذا
+
+99
+00:07:31,460 --> 00:07:33,560
+برضه نفس الكلام ال equivalent weight هو ال formula
+
+100
+00:07:33,560 --> 00:07:37,060
+weight على واحد يعنى فهو ال formula weight نفس
+
+101
+00:07:37,060 --> 00:07:40,480
+الكلام ال ammonia مثلا ال ammonia معروفة عبارة عن
+
+102
+00:07:40,480 --> 00:07:46,320
+باز مع أكم H plus بيتفاعلمع أكم H بلس بيتفاعل،
+
+103
+00:07:46,320 --> 00:07:49,980
+بتفاعلش اللي مع واحد، بيعطي N H أربعة موجب، N H
+
+104
+00:07:49,980 --> 00:07:53,440
+أربعة، واحد موجب فوقها يعني، فبتفاعل بس مع واحد
+
+105
+00:07:53,440 --> 00:07:59,720
+عشان هيك، برضه الأمونيا هو عبارة عن مادة، base، ال
+
+106
+00:07:59,720 --> 00:08:01,820
+equivalent weight إليها دائما بساوي ال formula
+
+107
+00:08:01,820 --> 00:08:07,770
+weight، لأنه لا تتفاعل إلا فقط مع بروتون، واحدلكن
+
+108
+00:08:07,770 --> 00:08:14,910
+مثلا لو كان في عنا خلينا نقول sulfuric acid H2SO4
+
+109
+00:08:14,910 --> 00:08:19,390
+قال والله ممكن يتفاعل مع Sodium Hydroxide واحد
+
+110
+00:08:19,390 --> 00:08:24,150
+وبالتالي يعطينا Sodium Hydrogen Sulfate وفي هذه
+
+111
+00:08:24,150 --> 00:08:27,170
+الحالة إذا كان اتفاعل بس مع واحد Sodium Hydroxide
+
+112
+00:08:27,170 --> 00:08:31,990
+معناته بدي يفقد واحد بروتون صح؟ معناته ال
+
+113
+00:08:31,990 --> 00:08:33,770
+equivalent weight بيساوي ال formula weight على
+
+114
+00:08:33,770 --> 00:08:37,770
+واحدمش هيك لأن number of reacting units ال
+
+115
+00:08:37,770 --> 00:08:40,470
+reacting units يا إما بروتونات يا إما هيدروكسيد
+
+116
+00:08:40,470 --> 00:08:43,350
+اللي دخل في التفاعل فدخل بس بروتون واحد إذا
+
+117
+00:08:43,350 --> 00:08:47,730
+فورمولة وقت على واحد طيب
+
+118
+00:08:47,730 --> 00:08:50,650
+ال sulfuric acid لو اتفاعل مع excess sodium
+
+119
+00:08:50,650 --> 00:08:56,890
+hydroxide يعني sodium hydroxide كتير بزيادة أكم
+
+120
+00:08:56,890 --> 00:09:01,830
+بروتون منه هيتفاعلهأذا عاد ال reacting units من
+
+121
+00:09:01,830 --> 00:09:05,730
+مقدش يكون اتنين يبقى ال equivalent weight يساوي في
+
+122
+00:09:05,730 --> 00:09:10,430
+هذه الحالة formula weight على اتنين نفس الكلام لو
+
+123
+00:09:10,430 --> 00:09:14,490
+حكينا عن الفوسفوريك أسد ممكن الفوسفوريك أسد يتفاعل
+
+124
+00:09:14,490 --> 00:09:21,290
+مع واحد صوديوم هيدروكسيد ويعطي NaH2PO4 فعل بس مع
+
+125
+00:09:21,290 --> 00:09:24,230
+واحد صوديوم هيدروكسيد يعني واحد proton فقط اللي
+
+126
+00:09:24,230 --> 00:09:28,630
+اتفعلمعنى كلام في هذه الحالة الفوسفوريك أسيد ال
+
+127
+00:09:28,630 --> 00:09:30,890
+equivalent weight له بيساوي ال formula weight على
+
+128
+00:09:30,890 --> 00:09:34,930
+واحد ممكن الفوسفوريك أسيد يتفاعل مع اتنين sodium
+
+129
+00:09:34,930 --> 00:09:40,670
+hydroxide وفي هذه الحالة بحصل على NA2HPO4
+
+130
+00:09:40,670 --> 00:09:44,170
+في هذه الحالة ال equivalent weight للفوسفوريك أسيد
+
+131
+00:09:44,170 --> 00:09:49,090
+بيساوي ال formula weight على اتنين وفي الحالة يعني
+
+132
+00:09:49,090 --> 00:09:52,970
+الأخيرة ممكن نقول انهخلّي الفوسفوريك أسيد يتفعل مع
+
+133
+00:09:52,970 --> 00:09:57,350
+تلاتة مولز من أيه؟ من الـ Sodium Hydroxide سايتها
+
+134
+00:09:57,350 --> 00:10:02,270
+هيعطينا NA تلاتة PO4 Sodium Phosphate في هذه
+
+135
+00:10:02,270 --> 00:10:06,310
+الحالة ال equivalent weight للفوسفوريك أسيد هيكون
+
+136
+00:10:06,310 --> 00:10:10,750
+formula weight على تلاتة، إذا يا شبابمعنى الكلام
+
+137
+00:10:10,750 --> 00:10:15,110
+ال equivalent weight يتوقف على نوع التفاعل اللي
+
+138
+00:10:15,110 --> 00:10:18,670
+بتعدي المادة على نوع التفاعل طبعا ال reacting
+
+139
+00:10:18,670 --> 00:10:21,190
+units وال reacting units توقف على نوع التفاعل اللي
+
+140
+00:10:21,190 --> 00:10:26,650
+بتعدي المادة عشان هيك مقدرش اقولك مثلا حضرلي واحد
+
+141
+00:10:26,650 --> 00:10:31,250
+normal phosphoric acidممكن اقولك حضرلي واحد مولار
+
+142
+00:10:31,250 --> 00:10:33,970
+فوسفوريك أسد، بيقوللي سهل، باخد واحد مولار، بحطه
+
+143
+00:10:33,970 --> 00:10:37,990
+في لتر solution، واحد مولار، سهل كتير، باخد واحد
+
+144
+00:10:37,990 --> 00:10:40,730
+مولار، بحطه في لتر solution، بيعطينا واحد مولار
+
+145
+00:10:40,730 --> 00:10:44,430
+فوسفوريك أسد، مافي مشكلة، لكن لما انا أقولك حضرلي
+
+146
+00:10:44,430 --> 00:10:50,650
+واحد normal in فوسفوريك أسد، مانفعش، لأنك بيبقى
+
+147
+00:10:50,650 --> 00:10:54,260
+بتوزن وزنها، الوزن هي اللي بيبقى بتوزنهابتعتمد على
+
+148
+00:10:54,260 --> 00:10:56,640
+عدد ال reacting units وال reacting units بتعتمد
+
+149
+00:10:56,640 --> 00:10:59,920
+على التفاعل من غير ما يقولك إيش التفاعل اللي بده
+
+150
+00:10:59,920 --> 00:11:02,980
+يعدي الفوسفوريك أسد، بتقدرش تقولي والله أه ممكن
+
+151
+00:11:02,980 --> 00:11:06,240
+أحضر لك واحد normal فوسفوريك أسد، بدي أقولك حضر
+
+152
+00:11:06,240 --> 00:11:10,560
+واحد normal فوسفوريك أسد عشان أستخدمه في تفاعله مع
+
+153
+00:11:10,560 --> 00:11:14,860
+اتنين sodium hydroxide مثلا، أو تلاتة moles من ال
+
+154
+00:11:14,860 --> 00:11:18,280
+sodium hydroxide، هتعرفيش اللي توزنه؟لأنك عرفت ال
+
+155
+00:11:18,280 --> 00:11:23,100
+reacting units بمعنى انك حددت ال equivalent weight
+
+156
+00:11:23,100 --> 00:11:26,620
+تبعك و منها حسبت عدد ال equivalence و بعدين حسبت
+
+157
+00:11:26,620 --> 00:11:30,000
+ال normality لكن غير هيك لأ عشان هيك في حسابات ال
+
+158
+00:11:30,000 --> 00:11:34,180
+normality يا شباب لابد اننا نعرف ايش هو التفاعل
+
+159
+00:11:34,180 --> 00:11:37,700
+اللي المادة بدها تعديه مش زي ال molarity على طول
+
+160
+00:11:37,700 --> 00:11:39,800
+ال molarity و الله عرض الملات في ال letter مش
+
+161
+00:11:39,800 --> 00:11:44,450
+مشكلة لكن normality لأ وهذا سببتالت يمكن بيخلّينا
+
+162
+00:11:44,450 --> 00:11:48,190
+مش كتير نحب أنه نتعامل مع ال normality لأنه لو بده
+
+163
+00:11:48,190 --> 00:11:52,150
+حدر محلول بدك تبقى اه والله هذا كذا normal حينما
+
+164
+00:11:52,150 --> 00:11:55,710
+او عندما يتفاعل مع المادة الفلانية بال
+
+165
+00:11:55,710 --> 00:12:01,620
+stoichiometer الفلانية فهذا كلام مش سهل يعنيطيب
+
+166
+00:12:01,620 --> 00:12:06,100
+ممكن في نفس الطريقة يعني ممكن نقول إنه إذا كان
+
+167
+00:12:06,100 --> 00:12:09,740
+التفاعل تفاعل أكسدة واختزال فبنحاول نقسمه لنصين
+
+168
+00:12:09,740 --> 00:12:15,700
+نشوف والله أكم إلكترون في كل نص يعني فمثلا ال
+
+169
+00:12:15,700 --> 00:12:21,020
+permanganate المنجانيز فيها سبعة ممكن يتحول
+
+170
+00:12:21,020 --> 00:12:24,980
+لمنجانيز اتنين في هذه الحالة في عندي من سبعة
+
+171
+00:12:24,980 --> 00:12:28,700
+لاتنين في عندي خمسة إلكترونز ممكن يتحول لمنجانيز
+
+172
+00:12:28,700 --> 00:12:32,970
+تلاتة حسب الوسطفى هذه الحالة فى عندى 7 على 3 فى
+
+173
+00:12:32,970 --> 00:12:36,810
+عندى 4 وكده حوالى مانجانيز 4 من 7 على 4 فى عندى 3
+
+174
+00:12:36,810 --> 00:12:39,910
+بورضه حسب التفاعل حسب الوسط اللى بيكون موجود فيه
+
+175
+00:12:39,910 --> 00:12:45,030
+لكن عدد الإلكترونات هي اللى بيسميها reacting units
+
+176
+00:12:47,030 --> 00:12:51,250
+ف ال normality زي ما عرفناها قلنا هي عدد ال
+
+177
+00:12:51,250 --> 00:12:55,210
+equivalence على ال letter او انه ال normality
+
+178
+00:12:55,210 --> 00:12:58,990
+عبارة عن milliequivalence على ال milliliter حطينا
+
+179
+00:12:58,990 --> 00:13:02,950
+millie فوق و millie تحت بإمكاني معنى الكلام ال
+
+180
+00:13:02,950 --> 00:13:06,550
+milliequivalent بدي ساوي ال normality في ال volume
+
+181
+00:13:06,550 --> 00:13:10,290
+بالmill زي ما كانت ال millimole بتساوي ال molarity
+
+182
+00:13:10,290 --> 00:13:12,680
+في ال volume بالmillالـ Milliequivalent أيش
+
+183
+00:13:12,680 --> 00:13:16,660
+بتساوي؟ الـ Normalty في الـ Volume بالمل هذي شغلة
+
+184
+00:13:16,660 --> 00:13:20,380
+مربط معناها سابقا يبقى أول Milliequivalent حسبناه
+
+185
+00:13:20,380 --> 00:13:23,900
+بقولنا Normalty في الـ Volume بالمل برضه ممكن أعرف
+
+186
+00:13:23,900 --> 00:13:26,880
+الـ Milliequivalent على إنه milligram على ال
+
+187
+00:13:26,880 --> 00:13:30,700
+equivalent weight فهذا تعريف تاني لإيه؟ لـ
+
+188
+00:13:30,700 --> 00:13:33,960
+Milliequivalent زي ما كنا بيقول الملي مول بيساوي
+
+189
+00:13:33,960 --> 00:13:37,520
+milligram على ال formula weight ال equivalent
+
+190
+00:13:37,520 --> 00:13:42,300
+weight مشكلة ال formula weight لأ ماشيهذه
+
+191
+00:13:42,300 --> 00:13:46,060
+العلاقتين بنحسب من خلالهم الـ milliequivalent يبقى
+
+192
+00:13:46,060 --> 00:13:48,580
+milliequivalent إما بنقول normality ال volume
+
+193
+00:13:48,580 --> 00:13:52,040
+بالمل أو بنقول milligram على ال equivalent weight
+
+194
+00:13:52,040 --> 00:13:56,220
+إيش ال equivalent what بيساوي؟ شفناه formula
+
+195
+00:13:56,220 --> 00:14:01,980
+weight على Nطيب يا شباب لو قلنا طيب ماشي ال
+
+196
+00:14:01,980 --> 00:14:05,320
+milliequivalent هو عبارة عن milligram على ال
+
+197
+00:14:05,320 --> 00:14:08,060
+equivalent weight طب وال equivalent weight formula
+
+198
+00:14:08,060 --> 00:14:10,940
+weight على N خلينا نعوض عن ال equivalent weight
+
+199
+00:14:10,940 --> 00:14:12,740
+هنا ب formula weight على N
+
+200
+00:14:16,250 --> 00:14:20,010
+طيب عوضنا بيصير milligram على الفورمولوات، طب إيش
+
+201
+00:14:20,010 --> 00:14:23,250
+ال milligram على الفورمولوات؟ ما هي ال millimoles،
+
+202
+00:14:23,250 --> 00:14:27,130
+إذا .. إذا ال N هذا بتطلع فوق، إذا ال
+
+203
+00:14:27,130 --> 00:14:29,810
+milliequivalent N في ال millimole، وهذا علاقة كتير
+
+204
+00:14:29,810 --> 00:14:33,270
+كتير كتير ممتازة، هنستخدمها في حلول كتير من
+
+205
+00:14:33,270 --> 00:14:36,830
+المسائل، و هتكون يعني علاقة تبسيطية للحل، علاقة
+
+206
+00:14:36,830 --> 00:14:40,970
+تبسيطية جدا للحل، يبقى رجعنا تاني لمفهوم إيه؟ ال
+
+207
+00:14:40,970 --> 00:14:42,590
+millimole حتى في وجود
+
+208
+00:14:46,240 --> 00:14:51,000
+لو جسمنا الطرفين على ملي لتر، ملي equivalent على
+
+209
+00:14:51,000 --> 00:14:56,180
+الملي لتر، إيش يعني؟ملي اكوفلانت على الملي لتر
+
+210
+00:14:56,180 --> 00:14:58,940
+مايعرفها normality طب ملي مول على الملي لتر ايش
+
+211
+00:14:58,940 --> 00:15:03,400
+يعني اه حد حلوة كتير يبقى ان normality بتساوي in
+
+212
+00:15:03,400 --> 00:15:06,520
+في ال molarity اذا انا بقدر احول من ملي مول ل ملي
+
+213
+00:15:06,520 --> 00:15:11,560
+اكوفلانت بسهولة و بقدر احول ايضا من normality ل
+
+214
+00:15:11,560 --> 00:15:14,380
+molarity او من molarity ل normality برضه بسهولة
+
+215
+00:15:14,380 --> 00:15:18,120
+باستخدام العلاقتين هدوه العلاقات جوهرية جدا في حل
+
+216
+00:15:18,120 --> 00:15:21,720
+المسائل لازم ناخد بالنا منهم
+
+217
+00:15:23,790 --> 00:15:27,810
+بدي أذكرك بحاجة في بعض الأحيان نستخدم ال
+
+218
+00:15:27,810 --> 00:15:32,290
+dimensional analysis أو ال factor labelled method
+
+219
+00:15:32,290 --> 00:15:37,110
+فبنستخدم factors conversion factors فبنقول في حالة
+
+220
+00:15:37,110 --> 00:15:42,390
+ال equivalence و ال milliequivalence عادة بنقول كل
+
+221
+00:15:42,390 --> 00:15:48,500
+moleيحتوي على عدد من الملي إكويفلانت كل مول يحتوي
+
+222
+00:15:48,500 --> 00:15:51,580
+على عدد من الملي إكويفلانت ونقول والله واحد مول
+
+223
+00:15:51,580 --> 00:15:55,040
+على N equivalent يعني كل واحد مول في N equivalent
+
+224
+00:15:55,040 --> 00:15:58,460
+أو نقول والله N equivalent موجودة في كل واحد مول
+
+225
+00:15:58,460 --> 00:16:01,880
+هذا نفس الكلام فهذا هو اعتبر conversion factor
+
+226
+00:16:01,880 --> 00:16:06,980
+هنستخدمه في الحلول الآن نيجي ناخد تطبيقات بس عشان
+
+227
+00:16:06,980 --> 00:16:11,440
+الأمور تكون واضحة عنانحاول ناخد تطبيقات نشوف إيش
+
+228
+00:16:11,440 --> 00:16:14,680
+معنى الكلام اللي أخدناه كيف ممكن نستخدمه في الحل
+
+229
+00:16:14,680 --> 00:16:20,500
+فبنقول المثال او ال example المثال بيقول find the
+
+230
+00:16:20,500 --> 00:16:24,580
+equivalent weights of أمونيا وميعطيك ال formula
+
+231
+00:16:24,580 --> 00:16:31,940
+ويتقلها ال oxalic acid H2C2O4 هذا oxalic acid
+
+232
+00:16:31,940 --> 00:16:37,940
+ميعطيك ال formula ويتقلهأه بس ايش جالك؟ جالك ال
+
+233
+00:16:37,940 --> 00:16:40,760
+Oxalic acid in the reaction with excess sodium
+
+234
+00:16:40,760 --> 00:16:43,460
+hydroxide ايش معناه انه يقولك excess sodium
+
+235
+00:16:43,460 --> 00:16:46,760
+hydroxide؟ معناته هدول ال two protons ايش بده
+
+236
+00:16:46,760 --> 00:16:50,400
+يجرعلهم؟ بدهم يتفاعلوا كلهم عشان هيك ال number of
+
+237
+00:16:50,400 --> 00:16:54,260
+reacting units انت لازم تفهم هذا الكلام لما نقولك
+
+238
+00:16:54,260 --> 00:16:57,700
+excess sodium hydroxide معناته كل البروتونات ايش
+
+239
+00:16:57,700 --> 00:17:03,190
+مالها؟ اتفاعلت لان هذا acidفمعنى الكلام ان بجدش
+
+240
+00:17:03,190 --> 00:17:08,990
+باتنين عشان هيك بيقولك and potassium permanganate
+
+241
+00:17:08,990 --> 00:17:14,710
+KMNO4 when ماسبكاش هيك جالك when مانجانيز سبعة
+
+242
+00:17:14,710 --> 00:17:17,410
+اللي هو في ال potassium permanganate المانجانيز
+
+243
+00:17:17,410 --> 00:17:20,730
+سبعة لإن ال oxygen أربعة أربعة في اتنين سالب هي
+
+244
+00:17:20,730 --> 00:17:24,350
+تمانية سالب البوتاسيوم واحد موجب بقال سبعة سالب
+
+245
+00:17:24,350 --> 00:17:27,470
+إذا المانجانيز سبعة موجب هذه ال oxidation number
+
+246
+00:17:27,470 --> 00:17:32,670
+إلهبتحول لمجاريز اتنين من سبعة موجب لاتنين موجب في
+
+247
+00:17:32,670 --> 00:17:36,210
+اندئة كام إلكترون، خمسة، بس هاد المعلومة، الآن
+
+248
+00:17:36,210 --> 00:17:39,350
+نيجي انحل نطلع ال equivalent weight فبنقول
+
+249
+00:17:39,350 --> 00:17:42,090
+الأمونيا، الأمونيا مجالكاش بتفعل مع إيش، لإنها
+
+250
+00:17:42,090 --> 00:17:46,410
+معروفة زي الـHCl بتفعلش بس مع واحد Hydroxide زي ال
+
+251
+00:17:46,410 --> 00:17:50,150
+Sodium Hydroxide بتفعل بس مع واحد HCl، الأمونيا
+
+252
+00:17:50,150 --> 00:17:57,500
+بتفعل بس مع واحد H+, مفهومةلو .. لو كان عندك مية
+
+253
+00:17:57,500 --> 00:18:01,900
+طن HC اللي هو عندك ملكي الواحد أمونيا هياخد H plus
+
+254
+00:18:01,900 --> 00:18:07,880
+واحدة ويسيب الباقي هيش .. بتحملش أكترلو جال excess
+
+255
+00:18:07,880 --> 00:18:14,700
+نفس الكلام لأنه مافيش عندك اتفاعل الا واحد فقط،
+
+256
+00:18:14,700 --> 00:18:17,880
+مابتفعلش مع اكتر من واحد فال equivalent weight
+
+257
+00:18:17,880 --> 00:18:21,080
+بتسوى ال formula weight بالنسبة للأمونيا على واحد،
+
+258
+00:18:21,080 --> 00:18:25,820
+اذا بيسوى 17 gram per equivalentبنجي نطلع على ال
+
+259
+00:18:25,820 --> 00:18:29,820
+equivalent weight للـ H2C2O4 جالك Xs معناته Xs
+
+260
+00:18:29,820 --> 00:18:32,460
+Sodium Hydroxide معناته ال two protons هيتفاجب جال
+
+261
+00:18:32,460 --> 00:18:36,200
+ال N بجد .. بجداش جولنا ال N بتنين اذا بنتطلع
+
+262
+00:18:36,200 --> 00:18:38,460
+بنلاك ال equivalent weight بساوة 4 نوات على 2
+
+263
+00:18:38,460 --> 00:18:41,900
+تسعين على 2 خمسة و أربعين جرام per equivalent
+
+264
+00:18:41,900 --> 00:18:46,140
+بالنسبة للبرمجانات جالك المنجانيز سبعة اتحول
+
+265
+00:18:46,140 --> 00:18:49,340
+لمنجانيز اتنين معناته خمسة electrons يبقى ال
+
+266
+00:18:49,340 --> 00:18:52,490
+equivalent weight للبرمجانات بده ساويفورمولا
+
+267
+00:18:52,490 --> 00:18:58,010
+weight على خمسة يبقى بده يساوي 158 على خمسة واحة
+
+268
+00:18:58,010 --> 00:19:01,350
+وتلاتين اقل ستة من عشرة يبقى حساب ال equivalent
+
+269
+00:19:01,350 --> 00:19:06,490
+weight يا شباب شغلة مش صعبة مجرد بس انه نعرف عدد
+
+270
+00:19:06,490 --> 00:19:11,550
+ال reacting units بنيجي لحسابات جوهرية في الحقيقة
+
+271
+00:19:11,550 --> 00:19:16,150
+مهمة جدا لأنها يعني من خلالها بنعرف تركيزات
+
+272
+00:19:16,150 --> 00:19:21,140
+المحليل وهذا مهم كتير بالنسبة لنافمثلا نتطلع على
+
+273
+00:19:21,140 --> 00:19:25,320
+المثال اللي جدامي بيقول find the normality of the
+
+274
+00:19:25,320 --> 00:19:29,480
+solution containing خمسة و تلاتة من عشر جرام ع لتر
+
+275
+00:19:29,480 --> 00:19:34,730
+of sodium carbonateبقولك ايه عشان بده يحسب هو
+
+276
+00:19:34,730 --> 00:19:38,970
+normality لازم يقولك ايش هو التفاعل اللي بتعدي
+
+277
+00:19:38,970 --> 00:19:43,910
+المادة فجالك انه ال carbonate reacts with ايه ايش
+
+278
+00:19:43,910 --> 00:19:47,930
+معنى الكلام ال N بتساوي اتنين هي جصده ال N بتساوي
+
+279
+00:19:47,930 --> 00:19:52,010
+اتنين فبقول انا علشان يعني اقدر احل المثال احلهلك
+
+280
+00:19:52,010 --> 00:19:57,270
+بتلت طرق تلت طرق يعني اخر طريقة انا بدي اقولك انها
+
+281
+00:19:57,270 --> 00:20:00,850
+يمكن تكون اسهل طريقة لكن بدي امشي معاك خطوة خطوة
+
+282
+00:20:02,200 --> 00:20:07,320
+الحل بهذه الطرق بطريقة أولى أمتع لكن الحل بأخر
+
+283
+00:20:07,320 --> 00:20:13,180
+طريقة أسهل فحنشوف عشان أنا أجيب ال normality أول
+
+284
+00:20:13,180 --> 00:20:16,580
+ما أجيب أجيب ال equivalent weight لازم خطوة أساسية
+
+285
+00:20:16,580 --> 00:20:19,440
+لأن ال equivalent weight بدو يوصل لعدد ال
+
+286
+00:20:19,440 --> 00:20:22,320
+equivalence عدد ال equivalence على ال volume بدو
+
+287
+00:20:22,320 --> 00:20:24,680
+يوصلنا ل normality مفهوم فالخطوات المنطقية
+
+288
+00:20:24,680 --> 00:20:27,720
+equivalent weight equivalence بعدين بده يجسم ال
+
+289
+00:20:27,720 --> 00:20:31,920
+equivalence على ال volumeفبقول equivalent weight
+
+290
+00:20:31,920 --> 00:20:36,840
+بده يساوي ال formula weight على اتنين، ليش اتنين؟
+
+291
+00:20:36,840 --> 00:20:40,680
+لأنه عاجل لك reacts with two protons فبتطلع ال
+
+292
+00:20:40,680 --> 00:20:44,200
+equivalent weight تلاتة و خمسينطيب عدد ال
+
+293
+00:20:44,200 --> 00:20:47,960
+equivalence دي قال والله ال gram من المادة على ال
+
+294
+00:20:47,960 --> 00:20:50,680
+equivalent weight فال gram عندي خمسة و تلاتة ال
+
+295
+00:20:50,680 --> 00:20:53,920
+weight خمسة و تلاتة gram على ال equivalent weight
+
+296
+00:20:53,920 --> 00:20:57,240
+تلاتة و خمسة و طلع واحد من عشرة بدنا إيش هذا عدد
+
+297
+00:20:57,240 --> 00:20:59,980
+ال equivalence بدنا نقسمها الحجم الحجم liter ما هو
+
+298
+00:20:59,980 --> 00:21:03,700
+يبقى واحد liter الحجم المعطيني هي liter إذا ال
+
+299
+00:21:03,700 --> 00:21:09,060
+normality واحد من عشرة normal ماشي يا شباب ببساطة
+
+300
+00:21:09,060 --> 00:21:13,100
+بجيب ال equivalent weightو منها بجيب عدد ال
+
+301
+00:21:13,100 --> 00:21:16,180
+equivalence بجسم ال grams على ال equivalent weight
+
+302
+00:21:16,180 --> 00:21:19,060
+و بعدين بجسمها الحجم ها و اعطينيها في liter اذا
+
+303
+00:21:19,060 --> 00:21:21,340
+هذا هو .. هذه ال normality اللي طلعت معي عدد ال
+
+304
+00:21:21,340 --> 00:21:23,440
+equivalence و ال normality لأن ال equivalence
+
+305
+00:21:23,440 --> 00:21:28,640
+موجودة في liter طيب نيجي نتقلع على حل المسألة
+
+306
+00:21:28,640 --> 00:21:32,680
+بالdimensional analysis او ال factor label method
+
+307
+00:21:34,510 --> 00:21:37,970
+بقول بده ال normality يعني إيه إيش بده؟ يعني بده
+
+308
+00:21:37,970 --> 00:21:41,350
+عدد ال equivalence من ال sodium carbonate في ال
+
+309
+00:21:41,350 --> 00:21:44,610
+liter، هاي معناه ال normality، هذا على اليسار، هاي
+
+310
+00:21:44,610 --> 00:21:48,530
+معناه ال normality، فأنا بقول إيش في عندي معطيات،
+
+311
+00:21:48,530 --> 00:21:51,590
+عندي خمسة و تلاتة من عشر جرام sodium carbonate على
+
+312
+00:21:51,590 --> 00:21:55,470
+ال liter، لما أجي أشتغل dimensional analysis،
+
+313
+00:21:55,470 --> 00:21:58,770
+دائما بحط في اعتباري أنه أنا بفهمش في الإجرامات،
+
+314
+00:21:58,770 --> 00:22:00,950
+أنا بعرفش في الإجرامات، أنا بفهم في ال moles و ال
+
+315
+00:22:00,950 --> 00:22:04,960
+millimoles،بفهمش في ال gramات او ال milligramات
+
+316
+00:22:04,960 --> 00:22:07,420
+بفهم في ال moles او ال millimoles عشانكي لما
+
+317
+00:22:07,420 --> 00:22:12,000
+يعطيني gram مافيش قدام خيار طريق واحد فقط لا يتغير
+
+318
+00:22:12,000 --> 00:22:15,880
+بده احولها لمole اعطاني gram بده احولها لمole
+
+319
+00:22:15,880 --> 00:22:21,790
+مباشرة فكيف بده احول ال gram لمole؟طبعا الكتلة
+
+320
+00:22:21,790 --> 00:22:25,750
+المولية فبنقول ال factor كل مول من ال sodium
+
+321
+00:22:25,750 --> 00:22:28,870
+carbonate هو عبارة عن 106 gram من ال sodium
+
+322
+00:22:28,870 --> 00:22:32,610
+carbonate المول عبارة عن gram formula weight 106
+
+323
+00:22:32,610 --> 00:22:36,730
+gram ابناجي حولناها لمول الآن المول يمكن تحويله لا
+
+324
+00:22:36,730 --> 00:22:41,010
+equivalent لأنه قلتلك قبل شوية كل مول يحتوي على
+
+325
+00:22:41,010 --> 00:22:44,710
+عدد من ال equivalenceفبالنسبة للصوديم كربونيت قال
+
+326
+00:22:44,710 --> 00:22:48,010
+لي بتفعل معه اتنين بروتون لذا كل مول اتنين
+
+327
+00:22:48,010 --> 00:22:51,650
+equivalent او كل اتنين equivalent صوديم كربونيت
+
+328
+00:22:51,650 --> 00:22:56,290
+موجودة في واحد مول صوديم كربونيت معناته النتيجة
+
+329
+00:22:56,290 --> 00:23:01,250
+point one normal ماشي يا شباب فهذه او هذا هو الحل
+
+330
+00:23:01,250 --> 00:23:05,030
+باستخدام ال factor labeled method نتطلع على الحل
+
+331
+00:23:05,760 --> 00:23:09,280
+اللي انا بقولك كتير كتير كتير ممكن يكون بسيط و
+
+332
+00:23:09,280 --> 00:23:15,000
+احنا بقولك مباشرة هذا ايش اجرام ع ال letter طيب
+
+333
+00:23:15,000 --> 00:23:19,060
+انا يعني بقدر احوله لمول ع ال letter صح ولا لأ؟
+
+334
+00:23:19,060 --> 00:23:22,170
+ايش بدي اعمل؟بدي اكسب على ال formula which صار مول
+
+335
+00:23:22,170 --> 00:23:24,630
+على ال letter، مظبوط؟ طب أنا عند ال normality، ال
+
+336
+00:23:24,630 --> 00:23:27,550
+molarity يعني، طب أنا عند ال normality بتساوي N في
+
+337
+00:23:27,550 --> 00:23:31,230
+ال molarity، خلاص انتهى الموضوع، معايا؟ كمان مرة،
+
+338
+00:23:31,230 --> 00:23:33,990
+بقول هذا ground على ال letter، انا بحاول ال
+
+339
+00:23:33,990 --> 00:23:37,610
+molarity، بعرف، molarity، خبير molarity انا،
+
+340
+00:23:37,610 --> 00:23:40,110
+فبحاول على طول، كيف؟ بكسب على ال formula which،
+
+341
+00:23:40,110 --> 00:23:43,110
+اتحول على ال molarity، طب انا بعرف ان ال normality
+
+342
+00:23:43,110 --> 00:23:47,140
+بتساويان في الـ molarity طب الان ما هي ب اتنين
+
+343
+00:23:47,140 --> 00:23:52,080
+اتنين في ال molarity بطلع معايا على طول ان اللي هو
+
+344
+00:23:52,080 --> 00:23:54,340
+عدد ال reacting units اللي هي هنا لبروتناتي
+
+345
+00:23:54,340 --> 00:23:58,580
+المتفائلة فضل السؤال بيوضح لي ان البروتون لازم
+
+346
+00:23:58,580 --> 00:24:02,560
+اعرف انه ايش السؤال بيحددلك ان البروتون فعلا لازم
+
+347
+00:24:02,560 --> 00:24:06,780
+اعرفه لا لا هو بيقولك او بيعطيك المعادلة فانت
+
+348
+00:24:06,780 --> 00:24:10,360
+بتعرف فهنا عندي نفس الطريقة بيقولك انا باعتمد في
+
+349
+00:24:10,360 --> 00:24:14,910
+الحال على N بتساوي N في MالـMolarity الـ number of
+
+350
+00:24:14,910 --> 00:24:18,090
+moles خمسة و تلاتة maximum يعني على الفورمولويت
+
+351
+00:24:18,090 --> 00:24:22,210
+إذا المولاريتي طلعناها فش مشكلة بضربها في اتنين
+
+352
+00:24:22,210 --> 00:24:24,830
+يبقى انت ماعليك انك طلع المولاريتي بس و المولاريتي
+
+353
+00:24:24,830 --> 00:24:28,930
+بتعرف تطلعها بدها شطارة و بعد ما تطلعها اضرب في ال
+
+354
+00:24:28,930 --> 00:24:32,810
+in خلاص حصلت على ال normality طب نتطلع على المثال
+
+355
+00:24:32,810 --> 00:24:36,630
+التالي نفس الكلام بالظبط لكن ال reacting units
+
+356
+00:24:36,630 --> 00:24:40,400
+مختلفة شوية و في طبعا فكرة انا بحب انك تعرفهابيقول
+
+357
+00:24:40,400 --> 00:24:44,820
+find the normality of the solution containing 5
+
+358
+00:24:44,820 --> 00:24:51,060
+.2670 gram per liter potassium dichromate وبيعطيك
+
+359
+00:24:51,060 --> 00:24:55,660
+ال formula وية ايه؟ همتين اربعة أو تسعين بيقولك if
+
+360
+00:24:55,660 --> 00:25:00,280
+acromion 6 is reduced to acromion 3 ايش معنى كلام
+
+361
+00:25:00,280 --> 00:25:05,890
+هذا؟ جداش ال in؟ بنقول هي في الحقيقة مش تلاتةهي
+
+362
+00:25:05,890 --> 00:25:12,830
+ستة، ليش؟ لأن المول أكم إكروميوم فيه؟ في اتنين، كل
+
+363
+00:25:12,830 --> 00:25:16,850
+واحدة فيهم تلت إلكترونات، لأن أنا بهمن المول، أنا
+
+364
+00:25:16,850 --> 00:25:21,450
+بهمن المادة يا دي، أكم إلكترون فيها؟ أه فبتعطيني
+
+365
+00:25:21,450 --> 00:25:24,110
+تلاتة للإكرومة الأولى و تلاتة للإكرومة التانية،
+
+366
+00:25:24,110 --> 00:25:28,290
+معناته في عندي ستة electrons، معنى الكلام number
+
+367
+00:25:28,290 --> 00:25:31,510
+of reacting units، ستة، برضه بقدر أعرف هذا الكلام
+
+368
+00:25:31,510 --> 00:25:36,250
+مباشرة، بقول أكسجين سبعة، مش هيك؟فى اتنين سالب
+
+369
+00:25:36,250 --> 00:25:39,710
+يبقى سالب اربعتاشر البوتاسيوم واحد موجب واحد فى
+
+370
+00:25:39,710 --> 00:25:43,170
+اتنين يعنى اتنين موجب اذا بيبقى سالب اتناشر يبقى
+
+371
+00:25:43,170 --> 00:25:48,070
+لكروميام اتنين موجب اتناشر لكروميام اتنين موجب
+
+372
+00:25:48,070 --> 00:25:52,250
+اتناشر ايش بتعطى اتنين كروميام تلاتة يعنى اتنين فى
+
+373
+00:25:52,250 --> 00:25:57,910
+تلاتة بستةبكيف بدك تساوي 6×12، بدك 6 إلكترونات،
+
+374
+00:25:57,910 --> 00:26:01,590
+فسي يعني بنفسك .. يعني أي طريقة استخدمت للحصول على
+
+375
+00:26:01,590 --> 00:26:05,290
+عدد الإلكترونات حاجة مباشرة، بس هان هو ميعطيك إنه
+
+376
+00:26:05,290 --> 00:26:08,330
+الـChromium 6 اللي موجود هان بتحول لChromium 3
+
+377
+00:26:08,330 --> 00:26:12,570
+وإنت عندك في المول الواقع تنتهي لـChromium 2×3،
+
+378
+00:26:12,570 --> 00:26:17,500
+عندك 6 إلكتروناتإذا ال N عندك F6 نفس الكلام يا
+
+379
+00:26:17,500 --> 00:26:20,740
+شباب أنا فيه أجيب في البداية ال equivalent weight
+
+380
+00:26:20,740 --> 00:26:23,980
+خلينا نشتغلها بطريقة هذه ال equivalent weight بدها
+
+381
+00:26:23,980 --> 00:26:27,540
+تساوي ال formula weight على 6 ال equivalent weight
+
+382
+00:26:27,540 --> 00:26:31,820
+بدها تساوي ال formula weight على 6 طيب ال number
+
+383
+00:26:31,820 --> 00:26:35,140
+of equivalents ل gram بالظبط ال weight على ال
+
+384
+00:26:35,140 --> 00:26:37,060
+equivalent weight طلع أن ال number of equivalents
+
+385
+00:26:37,060 --> 00:26:41,230
+طب هي مدورة في لتر إذا هذه هي ال normalityهذه هي
+
+386
+00:26:41,230 --> 00:26:44,450
+ال normality ممكن نحل نفس المسألة باستخدام ال
+
+387
+00:26:44,450 --> 00:26:48,330
+dimensional analysis بقول إيش يعني normality؟ جال
+
+388
+00:26:48,330 --> 00:26:52,850
+عدد ال equivalence من ال dichromate في ال liter طب
+
+389
+00:26:52,850 --> 00:26:58,420
+إيش عندي معلومات؟جال 5.267 إجرام من الـDichromate
+
+390
+00:26:58,420 --> 00:27:02,540
+على لتر، هذه المعلومات، أنا جرامات؟ مافهمش جرامات،
+
+391
+00:27:02,540 --> 00:27:06,060
+أنا كيميائي، بفهم بالـmoles، فبده يحول لمول، بده
+
+392
+00:27:06,060 --> 00:27:10,260
+conversion factor، بيقول كل مول يحتوي على هو عبارة
+
+393
+00:27:10,260 --> 00:27:17,040
+عن 294 إجرام بوتاسيوم Dichromateحولت ل مول، الآن
+
+394
+00:27:17,040 --> 00:27:19,720
+عملية التحويل من مول ل equivalent سهلة كثير، كل
+
+395
+00:27:19,720 --> 00:27:22,940
+مول عدد من ال equivalence، كل مول موجود فيه عدد من
+
+396
+00:27:22,940 --> 00:27:26,080
+ال equivalence، اذا ات بده اقول ستة equivalence من
+
+397
+00:27:26,080 --> 00:27:29,160
+ال potassium diachromate موجودة في كل مول من ال
+
+398
+00:27:29,160 --> 00:27:32,180
+potassium diachromate، كيف عرفت هذا؟ هي ال N، هي
+
+399
+00:27:32,180 --> 00:27:34,940
+ال N، ستة equivalence من ال potassium diachromate
+
+400
+00:27:34,940 --> 00:27:39,560
+موجودة في كل مول من ال potassium diachromateأو انك
+
+401
+00:27:39,560 --> 00:27:43,460
+يعني تشتغل بالطريقة السهلة جدا اقول هذه gram ع
+
+402
+00:27:43,460 --> 00:27:46,520
+الliter مش هيك بقسم الفروق لصار مول ع الliter
+
+403
+00:27:46,520 --> 00:27:51,220
+molarity بضرب في ستة خلاص صارت normality اه يا
+
+404
+00:27:51,220 --> 00:27:56,500
+شباب كيف بدك تحل حل المهم في النهاية يعني اعتمد
+
+405
+00:27:56,500 --> 00:28:00,500
+طريقة في الحل اللي توصلك للنتيجة الصحيحة بيعني
+
+406
+00:28:00,500 --> 00:28:06,060
+اسرع طريق وبأبصر طريق وبأضمن طريق كويس؟
+
+407
+00:28:14,410 --> 00:28:18,410
+هو بتحدث عن الكروم ويقول لك الكروم ستة بتحول لكروم
+
+408
+00:28:18,410 --> 00:28:22,290
+تلاتة أكم الكروم اللي فيه عندك كان في المركب تنتين
+
+409
+00:28:22,290 --> 00:28:27,690
+إذا اتنين في ستة وهذا اتنين في تلاتة تنتين عندك كل
+
+410
+00:28:27,690 --> 00:28:31,670
+واحدة فيهم تلت إلكترونات إذا التنتين أكم الكروم
+
+411
+00:28:31,670 --> 00:28:37,710
+اللي بيعطوك؟ ستة قيمة الان هي اللي في التفاعل
+
+412
+00:28:42,880 --> 00:28:46,340
+لأ هو التفاعل اللي عندنا هاد تفاعلات تامة أصلا
+
+413
+00:28:46,340 --> 00:28:55,140
+يعني أنت عندك التفاعل كامل أكم إلكترون فيه في إيش؟
+
+414
+00:28:55,140 --> 00:29:02,160
+بالظبط يعني يعني هي هذه ممكن احنا لحظة شوية يعني
+
+415
+00:29:02,160 --> 00:29:05,580
+احنا لو أنت متذكر إيش أخرت في سنة أولى كان ممكن
+
+416
+00:29:05,580 --> 00:29:13,050
+تقولني أنهالـ Dichromate رفعت الزائد 14 H Plus
+
+417
+00:29:13,050 --> 00:29:20,170
+زائد 6 إلكترون بتعطيلنا 2 كروميام 3 زائد 7 مية فهي
+
+418
+00:29:20,170 --> 00:29:24,310
+التفاعل اللي هو بيقولك عنه يعني أو اللي بتكلملك
+
+419
+00:29:24,310 --> 00:29:29,650
+عنه فالـ Dichromate تحول لكروميام 3 طب أكم إلكترون
+
+420
+00:29:29,650 --> 00:29:35,970
+لكل واحد مول 6كويسة عشان هيك جسمنا على او قولنا
+
+421
+00:29:35,970 --> 00:29:42,810
+انه بيساوي ستة طيب خلينا نطلع على موضوع تاني يا
+
+422
+00:29:42,810 --> 00:29:48,910
+شباب موضوع كتير كتير مهم في الحقيقة الحل
+
+423
+00:29:48,910 --> 00:29:52,890
+بطريقة اللي قلناها قبل شوية بنتكلم عن ال density
+
+424
+00:29:52,890 --> 00:29:56,630
+calculations يعني ال calculations اللي بنستخدم
+
+425
+00:29:56,630 --> 00:30:03,740
+فيها ال densityوهي في الحقيقة يعني مفهوم لشيء مهم
+
+426
+00:30:03,740 --> 00:30:07,920
+جدا في الكيميا، مفهوم لشيء مهم جدا في الكيميا،
+
+427
+00:30:07,920 --> 00:30:13,660
+يعني مثلا لو قلتلك لو سمحت حضرلي خمسمائة مل من
+
+428
+00:30:13,660 --> 00:30:23,050
+واحد molar HCl وهي exhaust ال HCl المركزةأعطيتك
+
+429
+00:30:23,050 --> 00:30:28,110
+اجزاز ال HCl المركزة فبتقول بسيطة يعني أنا باخد
+
+430
+00:30:28,110 --> 00:30:32,810
+حجم معين من المركز وبقى أخففه بعطيني واحد molar
+
+431
+00:30:32,810 --> 00:30:37,510
+خمسمية مل من ال HCl فبتيجي تطلع على الاجزازة تشوف
+
+432
+00:30:37,510 --> 00:30:41,030
+جداش التركيز عشان تقول ال molarity في ال volume
+
+433
+00:30:41,030 --> 00:30:43,870
+قبل التركيز تساوي ال molarity في ال volume بعد
+
+434
+00:30:43,870 --> 00:30:50,570
+التركيز هي قانون التخفيفقانون التخفيف الملي مولز
+
+435
+00:30:50,570 --> 00:30:55,610
+قبل التخفيف بتساوي الملي مولز بعد التخفيف فبتاخد
+
+436
+00:30:55,610 --> 00:30:59,950
+حجم معين من المركز لكن عشان تاخد حجم معين بتعرف
+
+437
+00:30:59,950 --> 00:31:05,570
+جديشالتركيز فبتيجي تطلع في البطل على ال label
+
+438
+00:31:05,570 --> 00:31:09,190
+تبعها بتلوفها بتلاقي مش مكتوب التركيز مكتموش
+
+439
+00:31:09,190 --> 00:31:13,850
+التركيز لا ال HCl ولا ال sulphuric acid ولا ال
+
+440
+00:31:13,850 --> 00:31:19,670
+nitric acid ولا ال .. ولا ال .. ال acetic acid ولا
+
+441
+00:31:19,670 --> 00:31:23,910
+ال ammonia ولا ال H2O2 ولا حتى ال organics زي
+
+442
+00:31:23,910 --> 00:31:27,550
+الميثانول والإيثانول لو هزت ال molarity بتلاقيش
+
+443
+00:31:27,550 --> 00:31:34,250
+molarityطب ها كيف بدك تحضر مادة إلها تركيز معين و
+
+444
+00:31:34,250 --> 00:31:36,890
+أنت مش عارف ال modality؟ إذا لازم تحسب ال modality
+
+445
+00:31:36,890 --> 00:31:40,870
+في البداية، إيش بتلاقي على البطول؟ على ال label
+
+446
+00:31:40,870 --> 00:31:48,130
+اللي موجود على البطول؟ بتلاقي ال density للمحلول و
+
+447
+00:31:48,130 --> 00:31:51,850
+بتلاقي أيضا ال percentage لل analyte، يعني إذا كان
+
+448
+00:31:51,850 --> 00:31:55,960
+جزاية HCl، جدّيش ال percentage للHClاسكتكزازيت
+
+449
+00:31:55,960 --> 00:32:01,440
+فوسفوريك أسد جداش ال percentage فوسفوريك أسدمعايا
+
+450
+00:32:01,440 --> 00:32:06,040
+بيعطيك ال percentage مثلا 10% و لا 20% و لا 50% طب
+
+451
+00:32:06,040 --> 00:32:12,020
+و الباقي مية و لا 90% و لا 99% طب الباقي مية ماشي
+
+452
+00:32:12,020 --> 00:32:16,920
+فهو بيعطيك ال density و بيعطيك ال percentage ال
+
+453
+00:32:16,920 --> 00:32:21,860
+density للمحلول و بيعطيك ال percentage ماشي انت
+
+454
+00:32:21,860 --> 00:32:24,820
+المفروض تستخدم ال density و ال percentage و ايضا
+
+455
+00:32:24,820 --> 00:32:27,700
+طبعا ان انت عارف ايش هي المادة فمعاكي الفورمولوات
+
+456
+00:32:27,700 --> 00:32:35,090
+بتطلع ال molarityكيف بنعمل هذا الكلام؟ تعالوا
+
+457
+00:32:35,090 --> 00:32:40,270
+نطلع، كيف ممكن أحصل على ال modularity من أي بطل
+
+458
+00:32:40,270 --> 00:32:46,090
+فيها محلول مركز معروف ال density وال percentage؟
+
+459
+00:32:47,540 --> 00:32:52,020
+نتقل على المثال التالي what volume of concentrated
+
+460
+00:32:52,020 --> 00:32:56,100
+HCL ال formula weight هذه بتلاقيها على ال label
+
+461
+00:32:56,100 --> 00:33:01,280
+formula weight ستة و تلاتين و نص معروفة H و CL ال
+
+462
+00:33:01,280 --> 00:33:05,280
+percentage اتنين و تلاتين في المية يعني تمانية و
+
+463
+00:33:05,280 --> 00:33:08,440
+ستين في المية ميه و اتنين و تلاتين في المية بس HCL
+
+464
+00:33:08,440 --> 00:33:12,500
+مش كله HCL لأ تمانية و ستين في المية ميه و اتنين و
+
+465
+00:33:12,500 --> 00:33:16,370
+تلاتين في المية بس HCLفبال density واحد واحد من
+
+466
+00:33:16,370 --> 00:33:19,910
+عشرة جرام على المل يعني لو أخلت عشرة مل من هذا
+
+467
+00:33:19,910 --> 00:33:24,030
+المحلول بوزنه لحد عشر جرام العشرة مل الواحد بوزن
+
+468
+00:33:24,030 --> 00:33:27,410
+واحد واحد من عشرة العشرة بوزن واحد عاشر أيه ال
+
+469
+00:33:27,410 --> 00:33:33,070
+density؟ ايه كويس؟ فهذا المركز بيقول جداش أكمل
+
+470
+00:33:33,070 --> 00:33:37,210
+لزمين عشان أحضر خمسمية مل من two molar solution
+
+471
+00:33:37,960 --> 00:33:42,260
+عايز اعرف جداش اخد من المركز عشان احضر 500 مل من
+
+472
+00:33:42,260 --> 00:33:46,260
+two molar solution بدي اذكركم مفتاح الحل هو ال
+
+473
+00:33:46,260 --> 00:33:50,240
+density مفتاح الحل هو ال density ال density هذه هي
+
+474
+00:33:50,240 --> 00:33:56,320
+عبارة عن الكل ينتبه اجرام solution لكل مل اكم
+
+475
+00:33:56,320 --> 00:34:00,460
+اجرام solution لكل يعني كل مل جداش كتلته اكم اجرام
+
+476
+00:34:00,460 --> 00:34:05,750
+طب انا بديش اجرام solutionانا بديش gram solution
+
+477
+00:34:05,750 --> 00:34:09,950
+انا بدي gram و لا مول solution وش الفايدة؟ انا بدي
+
+478
+00:34:09,950 --> 00:34:16,770
+gram hcl بدي مول hcl مش هيك مش solution عشان هيك
+
+479
+00:34:16,770 --> 00:34:22,060
+بدك تتبه شوية تتبه شوية انا لو ضربتإجرام solution
+
+480
+00:34:22,060 --> 00:34:27,080
+في ال percentage هذا solution هل كله HCl؟ لأ 32%
+
+481
+00:34:27,080 --> 00:34:31,980
+منه HCl إذا لو ضربت في 32% إيش بتحول؟ HCl بس مش
+
+482
+00:34:31,980 --> 00:34:36,420
+محلول بيبطل محلول بيصير بس HCl يعني هذا إجرام
+
+483
+00:34:36,420 --> 00:34:40,860
+solution ضربناه في ال percentage بتحول لإيش؟ ل
+
+484
+00:34:40,860 --> 00:34:46,740
+gram HClليش؟ لأن الـHCl هو فقط 32% منه، فلو
+
+485
+00:34:46,740 --> 00:34:50,680
+ضربناها في 32%، التلت تقريبا، فبكون هذا عبارة عن
+
+486
+00:34:50,680 --> 00:34:57,240
+الـHCl، أه ساعتها بقدر أتعامل معاه، فبقول 1 و 1 هي
+
+487
+00:34:57,240 --> 00:35:02,240
+ال density في ال percentage، و لاحظوا إنها من 100،
+
+488
+00:35:02,240 --> 00:35:06,850
+حولته لmilligram، ضربته في 10 أقصى 3اذا صار عندى
+
+489
+00:35:06,850 --> 00:35:11,710
+milligram hcl على المل اشي احنا بنعرفه ال density
+
+490
+00:35:11,710 --> 00:35:17,150
+فى ال percentage صارت gram hcl دورت فى 10 عقل 3
+
+491
+00:35:17,150 --> 00:35:23,430
+صارت milligram hcl ماشي فى ايه لكل واحد mil طب انا
+
+492
+00:35:23,430 --> 00:35:26,930
+مديش milligram hcl انا مدي millimole hcl لما نكون
+
+493
+00:35:26,930 --> 00:35:30,070
+millimole على ال milliliter يعني ايش؟ملي مول على
+
+494
+00:35:30,070 --> 00:35:34,410
+ملي لتر ايش يعني مولارتي هي اللي بديها فإيش عشان
+
+495
+00:35:34,410 --> 00:35:38,990
+احصل على ملي مول ايش بدي بدي اقبع بدي هيني زي ما
+
+496
+00:35:38,990 --> 00:35:43,410
+انتوا شايفين بأجسم على ال formula weight هدا هي
+
+497
+00:35:43,410 --> 00:35:47,230
+خلاص طلعت ال molarity كمان مرة بقول عندي ال
+
+498
+00:35:47,230 --> 00:35:50,950
+density اجرام solution انا مش مهتم بال solution ال
+
+499
+00:35:50,950 --> 00:35:53,830
+solution فيه مية و فيه مادة أخرى مافيش فايدة منه
+
+500
+00:35:54,280 --> 00:35:57,360
+ماعرفش أعمل عليه أي Stoichiometric Calculation بدي
+
+501
+00:35:57,360 --> 00:36:01,280
+أحوّل لل Analyte بدي أحوّل لل HCl جدّاش منه HCl
+
+502
+00:36:01,280 --> 00:36:07,280
+جال 32% 32 عالمية ماحدش يكتب 32 من غير .. من غير
+
+503
+00:36:07,280 --> 00:36:15,740
+.. مش كثر يعني مش 32 ضعف لأ 32 مئة تلت HClتمام؟
+
+504
+00:36:15,740 --> 00:36:18,960
+فضربناها في point three two حولناها لميلي جرام انا
+
+505
+00:36:18,960 --> 00:36:22,200
+ضربناها في عشرة اقص تلاتة صار ميلي جرام hcl على
+
+506
+00:36:22,200 --> 00:36:25,680
+الميلي انا بدي ميلي مول على الميلي اذا بس بدي اقسم
+
+507
+00:36:25,680 --> 00:36:30,620
+عليا الفورمولويات بتعطيني molarity هاي المنطق
+
+508
+00:36:30,620 --> 00:36:35,920
+تبعنا فجسمنا طلع عندى تسعة واربعة اقصتين الكتافة؟
+
+509
+00:36:35,920 --> 00:36:36,840
+اه كنت على الحجم
+
+510
+00:36:41,920 --> 00:36:46,680
+هي انا بتكلم عن الملي انا خدت واحد ملي واحد ملي من
+
+511
+00:36:46,680 --> 00:36:50,620
+المحلول انت بيه عليا انت بيه عليا واحد ملي من ايش؟
+
+512
+00:36:50,620 --> 00:36:57,160
+من المحلول هذا الواحد ملي جديش فيه من ال HCl 32%
+
+513
+00:36:57,160 --> 00:37:04,440
+ضربت فيه 32% صارت ال value هذه من ال HCl في الملي
+
+514
+00:37:04,440 --> 00:37:10,620
+مش هيك؟مش ال 32% من ال 1 1 من 10 هي اللي في الملي
+
+515
+00:37:10,620 --> 00:37:13,680
+موجودة انا مش عندى غيرها الملي اعتبر مش عندى غيرها
+
+516
+00:37:13,680 --> 00:37:20,680
+الملي تمام كان وزنه 1 1 من 10 gram solution انا
+
+517
+00:37:20,680 --> 00:37:24,700
+مابديش gram solution مابدي gram hcl فضربته في
+
+518
+00:37:24,700 --> 00:37:28,820
+point three two صار gram hcl ضربته في عشر أقصى
+
+519
+00:37:28,820 --> 00:37:33,160
+تلاتة صار اللي جدامى وين هذا الكلام موجود؟ في
+
+520
+00:37:33,160 --> 00:37:38,640
+الملي فيه الحجمما لاجدش الحجم يا عم هو هو الحجم هي
+
+521
+00:37:38,640 --> 00:37:43,500
+و جاعد في الملي هادى الكتلة في الملي الكتلة هادى
+
+522
+00:37:43,500 --> 00:37:47,840
+موجودة في واحد mill بس فايلة زي ما هي لكن بقول انا
+
+523
+00:37:47,840 --> 00:37:51,920
+بديش كتلة انا بدي milli mole كيه بده احول الكتلة
+
+524
+00:37:51,920 --> 00:37:55,020
+هادى ل milli mole؟ على الكتلة المولية اتحول ل
+
+525
+00:37:55,020 --> 00:37:57,120
+milli mole اذا ال milli mole على ال milliliter
+
+526
+00:37:57,120 --> 00:38:00,180
+معناته ايش صارت? molarity ال molarity تتسعة و
+
+527
+00:38:00,180 --> 00:38:05,410
+اربعة و ستينالان سهل جدا اقول المولاريتي في ال
+
+528
+00:38:05,410 --> 00:38:08,350
+volume يعني ال millimoles قبل التخفيف تسوى
+
+529
+00:38:08,350 --> 00:38:11,030
+المولاريتي في ال volume يعني ال millimoles بعد
+
+530
+00:38:11,030 --> 00:38:16,230
+التخفيف ف9.64 في ال volume بالمل بتسوى 2 في 500
+
+531
+00:38:16,230 --> 00:38:19,170
+بعد التخفيف بطلع ال volume بالمل من المركز اللي
+
+532
+00:38:19,170 --> 00:38:24,780
+لازم اخده 10.4 من 10 ملبقول هدول العشرة وأربعة من
+
+533
+00:38:24,780 --> 00:38:28,380
+عشرة mil باخدهم و بحطهم على كمية من الميه يعني و
+
+534
+00:38:28,380 --> 00:38:32,420
+لتاكن مثلا متين mil بحطهم شوية شوية دائما بضيف
+
+535
+00:38:32,420 --> 00:38:36,960
+المركز على الميه مش الميه على المركز المركز على
+
+536
+00:38:36,960 --> 00:38:42,200
+الميه بالذات في حالة ال H2SO4 بس بشكل عام خلينا
+
+537
+00:38:42,200 --> 00:38:47,350
+نقولهيقول general practice procedure او general
+
+538
+00:38:47,350 --> 00:38:51,290
+practice عندنا انه دائما نضيف المركز على الميه مش
+
+539
+00:38:51,290 --> 00:38:56,010
+الميه على المركز بنضيفه شوية شوية اضفناه بنكمل
+
+540
+00:38:56,010 --> 00:39:02,430
+الحجم ل 500ml بكون عندنا 500ml من 2 molar HCl
+
+541
+00:39:02,430 --> 00:39:06,950
+solution الاتنين هي الاتنين لتر ما اعطيه لنا يا
+
+542
+00:39:06,950 --> 00:39:14,620
+حبيبي هيها بده يحضر 500ml من 2 molarطيب ناخد اللي
+
+543
+00:39:14,620 --> 00:39:18,400
+فاته أي إشي بدي أخد مثال و بدي أفرجك كيف هو بسيط
+
+544
+00:39:18,400 --> 00:39:22,880
+كتير نفس المنطق تماما ففي عندنا bottle من ال
+
+545
+00:39:22,880 --> 00:39:28,020
+concentrated H2SO4 و أحنا حابين نحسب جدش ال
+
+546
+00:39:28,020 --> 00:39:31,560
+molarity إليها علشان نحبر letter من point one
+
+547
+00:39:31,560 --> 00:39:34,990
+molar solutionفالمثال بيقول how many ml of
+
+548
+00:39:34,990 --> 00:39:45,490
+concentrated H2SO4 معطيك على البطول 98
+
+549
+00:39:45,490 --> 00:39:59,260
+.1% 94% 6% ميه ال density 1.83كويس جديش بدنا من
+
+550
+00:39:59,260 --> 00:40:02,280
+الحمض المركز علشان حضر واحد determined point one
+
+551
+00:40:02,280 --> 00:40:07,360
+molar solution بقول اببساطة خالص بقول انا عند ال
+
+552
+00:40:07,360 --> 00:40:13,800
+density مفتاح الحل هاد اجرام solutionعليته على
+
+553
+00:40:13,800 --> 00:40:17,500
+الملي بدي جرام solution على الملي انا بديش جرام
+
+554
+00:40:17,500 --> 00:40:22,140
+solution بدي جرام H2SO4 ايش بعمل؟ بضرب في ال
+
+555
+00:40:22,140 --> 00:40:26,060
+percentage بديش جرام بدي ملي جرام بضرب في ايش؟ في
+
+556
+00:40:26,060 --> 00:40:30,080
+10 أقصر اذا صار هذه الوزنة موجودة في المل انا بديش
+
+557
+00:40:30,080 --> 00:40:34,020
+ملي جرام على المل انا بدي ملي مول على المل بجسم
+
+558
+00:40:34,020 --> 00:40:37,820
+على ال formula weight صارت مولارتها الموضوع هي بها
+
+559
+00:40:37,820 --> 00:40:43,530
+البساطة خالص يعني بساطة شديدة جدافي البداية بجيب
+
+560
+00:40:43,530 --> 00:40:47,450
+milligram ع المل و بعدين بجسم على الفورمولات
+
+561
+00:40:47,450 --> 00:40:51,490
+بعطيني millimol ع المل يعني molarity، كويس، بتطلع
+
+562
+00:40:51,490 --> 00:40:55,510
+عندى ال molarity 17.5، الآن بنفس الطريقة اللى
+
+563
+00:40:55,510 --> 00:41:01,900
+ذكرناها سابقا بنقول انهMIVI أو الملي مولز قبل
+
+564
+00:41:01,900 --> 00:41:05,400
+التخفيف تساوي الملي مولز بعد التخفيف، معناه الكلام
+
+565
+00:41:05,400 --> 00:41:10,660
+17.5 في ال volume بالمل تساوي 0.1 في الف لازم هذه
+
+566
+00:41:10,660 --> 00:41:14,200
+.. مدام هذه بالمل لازم هذه تكون بالمل، نفس الحاجة،
+
+567
+00:41:14,200 --> 00:41:17,930
+عشان ملي مول تساوي ملي مولبتطلع ال volume 5.71
+
+568
+00:41:17,930 --> 00:41:22,250
+بناخده و بنضيفه على شوية ميه على 200 مل ميه مثلا
+
+569
+00:41:22,250 --> 00:41:27,690
+شوية شوية على الجدار بينزل لأن ال H2SO4 شره جدا
+
+570
+00:41:27,690 --> 00:41:32,710
+للميه لو .. لو حطيت الميه عليه ممكن هو ينط بده
+
+571
+00:41:32,710 --> 00:41:35,830
+يحاول يوصل لكن لما نضيفه هو على الميه بتخفف أول
+
+572
+00:41:35,830 --> 00:41:39,390
+بأول و طبعا يعني أثناء الإضافة على الميه الميه
+
+573
+00:41:39,390 --> 00:41:43,770
+بتسخن بتصير زي النعر يعني حرارة عالية فلازم تنتبه
+
+574
+00:41:43,880 --> 00:41:48,380
+بعد ما نضيفه بنكمل الحجم لواحد لتر بنكون حصلنا على
+
+575
+00:41:48,380 --> 00:41:53,100
+واحد لتر من point one molar solution انا عندى easy
+
+576
+00:41:53,100 --> 00:41:56,880
+shortcut ممكن انت تحفظها او يعني تطلع عليها ال
+
+577
+00:41:56,880 --> 00:42:00,960
+molarity بتساوي ال density اللى هى a gram solution
+
+578
+00:42:00,960 --> 00:42:05,160
+ع المل بتروح من ال percentage تحول لإيه؟ ل gram
+
+579
+00:42:05,160 --> 00:42:09,320
+solute على المل بحول فى عشرة قصيرة حول ملي gram ع
+
+580
+00:42:09,320 --> 00:42:14,740
+الملعلى الفورمولوات من اللي مُل على اللي يعني
+
+581
+00:42:14,740 --> 00:42:20,500
+مُلارتي يعني فيك تحفظ هذا القانون و تحل عليه يعني
+
+582
+00:42:20,500 --> 00:42:24,580
+المسائل متعلقة بال density calculations بس لازم
+
+583
+00:42:24,580 --> 00:42:29,500
+تتذكر انه ال percentage مثلا 35% معناه تهيأت
+
+584
+00:42:29,500 --> 00:42:35,080
+كتابتها مش 35 ضعيف لأ كسر ال percentage قدر عن
+
+585
+00:42:35,080 --> 00:42:42,630
+ايه؟ عن كسربالظبط خلاص من مية على مية طيب في شباب
+
+586
+00:42:42,630 --> 00:42:49,850
+يعني مصطلحين بحب أنه نفرج بينهم هيمروا معنا في
+
+587
+00:42:49,850 --> 00:42:53,110
+المستقبل بشكل واسع كتير لكن هل جيت ناخد يعني إيش
+
+588
+00:42:53,110 --> 00:42:59,530
+المفهوم العام اللي لهم لو إحنا قلنالك حضر واحد من
+
+589
+00:42:59,530 --> 00:43:05,680
+عشرة مولر acidic acidقال و الله بناخد واحد من عشرة
+
+590
+00:43:05,680 --> 00:43:10,380
+مول من ال Acetic Acid و بنحطه فيه شوية ميه و بنكمل
+
+591
+00:43:10,380 --> 00:43:15,940
+ل لتر صار عندنا واحد من عشرة مولار Acetic Acid طب
+
+592
+00:43:15,940 --> 00:43:20,460
+الواحد من عشرة مول هو عبارة عن جداش ال .. لو قلنا
+
+593
+00:43:20,460 --> 00:43:23,100
+جداش المول من ال Acetic Acid بقول ستين اجرام مثلا
+
+594
+00:43:23,100 --> 00:43:28,840
+ستين اجرام ستين اجرام طيب ..
+
+595
+00:43:31,940 --> 00:43:35,880
+يعني الواحد من عشرة مول ستة gram ستة gram بدنا
+
+596
+00:43:35,880 --> 00:43:38,960
+نحطها في liter بعطيني واحد من عشرة molar acetic
+
+597
+00:43:38,960 --> 00:43:42,620
+acid طيب يا شباب ال acetic acid أنا بعرف أنه
+
+598
+00:43:42,620 --> 00:43:47,780
+electrolyte بعيف، electrolyte إيش ماله؟ بعيف،
+
+599
+00:43:47,780 --> 00:43:52,420
+فمعنى الكلام لما أنا أحطه في الميه إيش بده يجراله؟
+
+600
+00:43:52,420 --> 00:43:58,280
+جزء منه بده يتفككالان صح انا وزنت 1 من 10 مول في
+
+601
+00:43:58,280 --> 00:44:01,820
+ال letter بسمي هذا التركيز اللي هو 1 من 10 مولار
+
+602
+00:44:01,820 --> 00:44:08,340
+بسميه analytical concentration C برمزه بالرمز C لل
+
+603
+00:44:08,340 --> 00:44:13,700
+H O A Cمااخد بالك؟ جداش التركيز واحد من .. طب كيف
+
+604
+00:44:13,700 --> 00:44:17,660
+عرفته؟ أنا وزنت واحد من عشرة مول وحطته في ال liter
+
+605
+00:44:17,660 --> 00:44:21,600
+فجداش التركيز واحد من عشرة مولار لكن أنا ماليش
+
+606
+00:44:21,600 --> 00:44:25,520
+دعوة اتفكك ولا لا التركيز الكلي هو عبارة عن واحد
+
+607
+00:44:25,520 --> 00:44:29,460
+من عشرة مولار هذا التركيز اسمه ايه؟ analytical
+
+608
+00:44:29,460 --> 00:44:33,760
+concentration لكن لما ينحط في الميه جزء منه مضله
+
+609
+00:44:33,760 --> 00:44:38,990
+زي ما هو أغلبه لكن جزء منه اشمالهبيتفكك فالتركيز
+
+610
+00:44:38,990 --> 00:44:41,830
+الكلي اللي هو analytical concentration بساوي
+
+611
+00:44:41,830 --> 00:44:46,090
+التركيز اللي ما اتفككش اللي ضايل زي ما هو زائد
+
+612
+00:44:46,090 --> 00:44:50,410
+التركيز اللي اتفكك بسمي هذا analytical
+
+613
+00:44:50,410 --> 00:44:53,890
+concentration اللي ما اتفككش هو equilibrium
+
+614
+00:44:53,890 --> 00:44:58,310
+concentrationEquilibrium اللى موجود فى المحلول
+
+615
+00:44:58,310 --> 00:45:02,530
+فعليا كويس ففى فرق بين ال analytical concentration
+
+616
+00:45:02,530 --> 00:45:05,910
+او فى فرق بين ال equilibrium concentration ال
+
+617
+00:45:05,910 --> 00:45:09,550
+analytical بالنسبة لـ C وهذا عبارة عن الكمية اللى
+
+618
+00:45:09,550 --> 00:45:11,910
+انا بوزنها او الكمية اللى انا عارف انا اخدتها و
+
+619
+00:45:11,910 --> 00:45:15,490
+حطيتها لكن فى المحلول ايش حصل جزء منها اتفكك جزء
+
+620
+00:45:15,490 --> 00:45:18,210
+منها راح جزء منها مش موجود جزء منها حصل و
+
+621
+00:45:18,210 --> 00:45:23,030
+dimerizationلكن جداش dial زي ما هو هذا ايش اسمه
+
+622
+00:45:23,030 --> 00:45:27,250
+equilibrium concentration و دائما بنحطه بجثين
+
+623
+00:45:27,250 --> 00:45:33,030
+مربعين ماشي هذه بس مجرد يعني ملاحظة هتستخدمها إذا
+
+624
+00:45:33,030 --> 00:45:37,850
+الله راد في المستقبل الحصة الجاية هنتقل لل
+
+625
+00:45:37,850 --> 00:45:41,170
+dilution problems و نكمل برضه في ال stoichiometric
+
+626
+00:45:41,170 --> 00:45:41,910
+titrations
+
diff --git a/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/vZ-UTtn_jnQ_raw.json b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/vZ-UTtn_jnQ_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..29caaed5b976d6e3a0f9fc05833ea81941e3793e
--- /dev/null
+++ b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/vZ-UTtn_jnQ_raw.json
@@ -0,0 +1 @@
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charge balance حاجة كتير بسيطة، بدي أقول والله تركيز الشحنات الموجبة يساوي تركيز الشحنات السالبة، الشحنات الموجبة مافيش عندي غير ال H plus، تركيز الشحنات الموجبة على ال H plus تساوي تركيز ال H plus", "tokens": [3555, 1863, 39648, 9122, 33911, 8717, 29245, 3215, 50113, 15040, 2423, 4602, 4772, 12399, 2423, 4602, 4772, 11331, 26108, 3660, 9122, 2655, 13546, 4724, 3794, 1829, 9566, 3660, 12399, 4724, 16254, 5551, 39648, 16070, 43761, 6055, 31747, 1829, 11622, 25124, 5016, 8315, 2655, 9673, 29245, 49401, 7251, 3794, 995, 45865, 6055, 31747, 1829, 11622, 25124, 5016, 8315, 2655, 21136, 6027, 49401, 12399, 25124, 5016, 8315, 2655, 9673, 29245, 49401, 19446, 41185, 8592, 18871, 16254, 32771, 13546, 2423, 389, 1804, 12399, 6055, 31747, 1829, 11622, 25124, 5016, 8315, 2655, 9673, 29245, 49401, 15844, 2423, 389, 1804, 6055, 3794, 995, 45865, 6055, 31747, 1829, 11622, 2423, 389, 1804], "avg_logprob": -0.13938376001108474, "compression_ratio": 2.101063829787234, "no_speech_prob": 0.0, "words": 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constant صغير كتير علشان هيك بتكون ال b minus اللى من ال strong اللى أكبر كتير من ال a plus إذا هى بتساوي ال cb minus يعني ال b minus بدها تساوي point to molar", "tokens": [2407, 24793, 10632, 2423, 257, 1804, 13672, 7578, 10874, 995, 10632, 9154, 2423, 257, 272, 9122, 2304, 10632, 5296, 9307, 25961, 2655, 6055, 2655, 7435, 2288, 5296, 33456, 3224, 2423, 15625, 5754, 20328, 17082, 13546, 9122, 2655, 13546, 11203, 8592, 7649, 39896, 4117, 39894, 30544, 2423, 272, 3175, 13672, 7578, 9154, 2423, 2068, 13672, 7578, 5551, 4117, 26890, 9122, 2655, 13546, 9154, 2423, 257, 1804, 11933, 15730, 8032, 7578, 39894, 3794, 995, 45865, 2423, 269, 65, 3175, 37495, 22653, 2423, 272, 3175, 47525, 11296, 6055, 3794, 995, 45865, 935, 281, 45712], "avg_logprob": -0.21127717974393265, "compression_ratio": 1.7897435897435898, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 2322.83, "end": 2323.41, "word": "وكمية", "probability": 0.7721354166666666}, {"start": 2323.41, "end": 2323.65, "word": " 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"probability": 0.8494466145833334}, {"start": 2589.44, "end": 2590.12, "word": " بنستخدم", "probability": 0.982421875}, {"start": 2590.12, "end": 2590.32, "word": " ال", "probability": 0.97802734375}, {"start": 2590.32, "end": 2590.78, "word": " systematic", "probability": 0.7890625}, {"start": 2590.78, "end": 2591.46, "word": " approach", "probability": 0.9677734375}, {"start": 2591.46, "end": 2591.82, "word": " لكن", "probability": 0.806640625}, {"start": 2591.82, "end": 2592.46, "word": " تقريبا", "probability": 0.9931640625}, {"start": 2592.46, "end": 2592.7, "word": " يعني", "probability": 0.922119140625}, {"start": 2592.7, "end": 2592.98, "word": " يمكن", "probability": 0.755859375}, {"start": 2592.98, "end": 2593.26, "word": " بعد", "probability": 0.96435546875}, {"start": 2593.26, "end": 2593.4, "word": " ال", "probability": 0.4482421875}, {"start": 2593.4, "end": 2593.88, "word": " 95", "probability": 0.7685546875}, {"start": 2593.88, "end": 2595.22, "word": " بدأنا", "probability": 0.9861653645833334}, {"start": 2595.22, "end": 2596.08, "word": " باستخدام", "probability": 0.987060546875}, {"start": 2596.08, "end": 2598.64, "word": " الكتاب", "probability": 0.9827473958333334}, {"start": 2598.64, "end": 2599.38, "word": " الجديد", "probability": 0.9830729166666666}, {"start": 2599.38, "end": 2599.74, "word": " تبعنا", "probability": 0.894775390625}, {"start": 2599.74, "end": 2599.88, "word": " اللي", "probability": 0.933349609375}, {"start": 2599.88, "end": 2600.5, "word": " مستخدمش", "probability": 0.8927734375}, {"start": 2600.5, "end": 2601.04, "word": " ال", "probability": 0.88720703125}, {"start": 2601.04, "end": 2601.34, "word": " systematic", "probability": 0.76220703125}, {"start": 2601.34, "end": 2601.86, "word": " approach", "probability": 0.9677734375}, {"start": 2601.86, "end": 2602.0, "word": " و", "probability": 0.85693359375}, {"start": 2602.0, "end": 2602.12, "word": " انا", "probability": 0.80712890625}, {"start": 2602.12, "end": 2602.48, "word": " لجيته", "probability": 0.8856201171875}, {"start": 2602.48, "end": 2602.56, "word": " و", "probability": 0.68115234375}, {"start": 2602.56, "end": 2602.94, "word": " الطلاب", "probability": 0.9638671875}, {"start": 2602.94, "end": 2603.2, "word": " ايضا", "probability": 0.8939208984375}, {"start": 2603.2, "end": 2604.1, "word": " لجوه", "probability": 0.95166015625}, {"start": 2604.1, "end": 2604.78, "word": " اسهل", "probability": 0.84375}, {"start": 2604.78, "end": 2605.1, "word": " كتير", "probability": 0.9755859375}, {"start": 2605.1, "end": 2605.9, "word": " بالنسبة", "probability": 0.9967041015625}, {"start": 2605.9, "end": 2607.86, "word": " للاستيعاب", "probability": 0.86484375}, {"start": 2607.86, "end": 2608.3, "word": " و", "probability": 0.99560546875}, {"start": 2608.3, "end": 2608.58, "word": " انه", "probability": 0.78173828125}, {"start": 2608.58, "end": 2609.06, "word": " نحصل", "probability": 0.97802734375}, {"start": 2609.06, "end": 2610.22, "word": " درجات", "probability": 0.98974609375}, {"start": 2610.22, "end": 2611.66, "word": " بنوجف", "probability": 0.7224934895833334}, {"start": 2611.66, "end": 2611.8, "word": " ان", "probability": 0.92431640625}, {"start": 2611.8, "end": 2612.06, "word": " شاء", "probability": 0.894775390625}, {"start": 2612.06, "end": 2612.16, "word": " الله", "probability": 0.96435546875}, {"start": 2612.16, "end": 2612.56, "word": " هان", "probability": 0.662841796875}, {"start": 2612.56, "end": 2612.86, "word": " اليوم", "probability": 0.8896484375}, {"start": 2612.86, "end": 2613.0, "word": " اذا", "probability": 0.6890869140625}, {"start": 2613.0, "end": 2613.18, "word": " كان", "probability": 0.97998046875}, {"start": 2613.18, "end": 2613.32, "word": " في", "probability": 0.90625}, {"start": 2613.32, "end": 2613.54, "word": " اي", "probability": 0.8154296875}, {"start": 2613.54, "end": 2613.82, "word": " سؤال", "probability": 0.99658203125}, {"start": 2613.82, "end": 2614.22, "word": " ممكن", "probability": 0.96875}, {"start": 2614.22, "end": 2615.84, "word": " نجاوب", "probability": 0.956787109375}, {"start": 2615.84, "end": 2616.18, "word": " عليه", "probability": 0.99072265625}], "temperature": 1.0}, {"id": 114, "seek": 262134, "start": 2618.14, "end": 2621.34, "text": "طيب معنا الكلام إذا الله راضي الحصة الجاية بتشوفكم", "tokens": [9566, 1829, 3555, 20449, 8315, 2423, 28820, 10943, 11933, 15730, 21984, 12602, 46958, 1829, 21542, 9381, 3660, 25724, 995, 10632, 39894, 8592, 38688, 24793], "avg_logprob": -0.2146875, "compression_ratio": 1.1794871794871795, "no_speech_prob": 0.0, "words": [{"start": 2618.14, "end": 2618.5, "word": "طيب", "probability": 0.8492838541666666}, {"start": 2618.5, "end": 2618.74, "word": " معنا", "probability": 0.843994140625}, {"start": 2618.74, "end": 2619.1, "word": " الكلام", "probability": 0.7827962239583334}, {"start": 2619.1, "end": 2619.28, "word": " إذا", "probability": 0.68505859375}, {"start": 2619.28, "end": 2619.48, "word": " الله", "probability": 0.765625}, {"start": 2619.48, "end": 2619.84, "word": " راضي", "probability": 0.64501953125}, {"start": 2619.84, "end": 2620.24, "word": " الحصة", "probability": 0.9705403645833334}, {"start": 2620.24, "end": 2620.66, "word": " الجاية", "probability": 0.9259440104166666}, {"start": 2620.66, "end": 2621.34, "word": " بتشوفكم", "probability": 0.93212890625}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2621.95075, "duration_after_vad": 2523.716874999994}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/vZ-UTtn_jnQ_raw.srt b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/vZ-UTtn_jnQ_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..03ec14b6eae691a619c89620c3e28d24d37105fe
--- /dev/null
+++ b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/vZ-UTtn_jnQ_raw.srt
@@ -0,0 +1,2152 @@
+1
+00:00:21,260 --> 00:00:24,940
+بسم الله الرحمن الرحيم طيب يا شباب بنكمل ان شاء
+
+2
+00:00:24,940 --> 00:00:28,560
+الله في ال chapter الخاص بال general equilibrium
+
+3
+00:00:28,560 --> 00:00:34,760
+concepts and calculations في الحصة الماضية أخدنا
+
+4
+00:00:34,760 --> 00:00:41,320
+أمثلة متعددة على كيف نحل مسائل equilibrium إذا كان
+
+5
+00:00:41,320 --> 00:00:47,120
+ال equilibrium constant كان كبير أو مش كبير فشوفنا
+
+6
+00:00:47,120 --> 00:00:54,050
+انه في الحالتينبنطلّع علىالـ equilibrium constant
+
+7
+00:00:54,050 --> 00:00:59,770
+و بنقرر هل قيمة ال X مهملة بالنسبة للنواتج أو
+
+8
+00:00:59,770 --> 00:01:04,630
+مهملة بالنسبة للمتفاعلات اليوم بنكمل في نفس
+
+9
+00:01:04,630 --> 00:01:12,050
+الموضوع لكن في البداية هناخد مثال يتعلق بال common
+
+10
+00:01:12,050 --> 00:01:16,510
+ion effect أو وجود ايون مشترك و ايش تأثير هذا
+
+11
+00:01:16,510 --> 00:01:23,920
+الايون المشترك بمعنى انه بدي اتطلع علىالمعادلة
+
+12
+00:01:23,920 --> 00:01:27,560
+الكيميائية او ال chemical equilibrium equation و
+
+13
+00:01:27,560 --> 00:01:31,140
+بدى اقول ايش هو ال common ion المقصود في ال common
+
+14
+00:01:31,140 --> 00:01:36,660
+ion هو عبارة عن المادة المضافة لا ال equilibrium
+
+15
+00:01:36,660 --> 00:01:40,320
+هذا او المادة الموجودة في ال equilibrium وتشكل جزء
+
+16
+00:01:40,320 --> 00:01:44,950
+من النواتجتشكل جزء من النواتج فال equilibrium او
+
+17
+00:01:44,950 --> 00:01:51,290
+الاتزان بده يتم في وجود كمية من النواتج بالطبع حسب
+
+18
+00:01:51,290 --> 00:01:56,630
+قاعدة او مبدأ لتشاتليه مدام في عنده نواتج ازيادة
+
+19
+00:01:56,630 --> 00:02:00,870
+كويس فالاصل انه ال equilibrium بده يرجع للخلف فده
+
+20
+00:02:00,870 --> 00:02:04,290
+كلام صحيح احنا هنحاول ناخد مثال على هذا الكلام
+
+21
+00:02:04,290 --> 00:02:09,670
+ونشوف هل بالفعل التفكك بيقل في وجود ال common ion
+
+22
+00:02:09,670 --> 00:02:16,200
+او لأالمثال بيقول calculate the equilibrium
+
+23
+00:02:16,200 --> 00:02:22,820
+concentrations of A, B and ABin a 0.1 molar AB
+
+24
+00:02:22,820 --> 00:02:29,020
+يعني عندي 0.1 molar AB لهذه الجهة يمكن المثال مر
+
+25
+00:02:29,020 --> 00:02:33,220
+معنى هو هو أول مثال أخدناه ال AB هو عبارة عن weak
+
+26
+00:02:33,220 --> 00:02:36,640
+electrolyte لكن في إضافة صغيرة بيقول in a presence
+
+27
+00:02:36,640 --> 00:02:43,280
+of 0.2 molar B يعني في عندي 0.2 molar من النواتج
+
+28
+00:02:43,280 --> 00:02:48,460
+فالتفكك بده يحصل لكن في وجود 0.2 molar من النواتج
+
+29
+00:02:50,330 --> 00:02:54,290
+The equilibrium constant is 3 في 10 أُس سالب 6
+
+30
+00:02:54,290 --> 00:02:58,730
+بقول ببساطة خالص في الحقيقة أنا بالطريقة اللي
+
+31
+00:02:58,730 --> 00:03:02,370
+بأتبعها بالحال مابيهمنيش إذا كان عندي common ion
+
+32
+00:03:02,370 --> 00:03:06,930
+أو عندي common ion أو يعني أي شيء آخر أنا اللي
+
+33
+00:03:06,930 --> 00:03:11,730
+بيهمني أني أكتب المعادلةأحط التركيزات قبل ال
+
+34
+00:03:11,730 --> 00:03:14,550
+equilibrium فوق وعند ال equilibrium أو بعد ال
+
+35
+00:03:14,550 --> 00:03:18,190
+equilibrium تحت و بعدين من ال equilibrium constant
+
+36
+00:03:18,190 --> 00:03:23,770
+بقدر أحل المسألة فلو طلعنا على المعادلة المعادلة
+
+37
+00:03:23,770 --> 00:03:30,730
+تقولي والله a b بتعطينا a plus b طب التركيزات قبل
+
+38
+00:03:30,730 --> 00:03:35,870
+الاتزان a b واحد من عشرة في المسألةA قال لي هو فيه
+
+39
+00:03:35,870 --> 00:03:40,490
+أي إشي من A، لأ، B قال لي بيه اتنين من عشرة عندك،
+
+40
+00:03:40,490 --> 00:03:44,390
+يبقى AB واحد من عشرة و B اتنين من عشرة، بسيطة، هذا
+
+41
+00:03:44,390 --> 00:03:48,770
+جاب الإتزان، باجي لبعد الإتزان، AB مادة ضعيفة،
+
+42
+00:03:48,770 --> 00:03:54,220
+weak electrolyte، electrolyte ضعيف،راح يتفكك اقول
+
+43
+00:03:54,220 --> 00:03:58,100
+equilibrium constant صغير اصلا فراح يتفكك بمقدار
+
+44
+00:03:58,100 --> 00:04:03,000
+يعني ضئيل جدا مقداره x زي ما اتعودنا هيعطيني x من
+
+45
+00:04:03,000 --> 00:04:08,940
+a و هيعطيني x من b مش هيك لكن عند بي 2 من 10 اذا 2
+
+46
+00:04:08,940 --> 00:04:15,450
+من 10 زائد x بتساوي تركيز bعند بعض الإتزان الـAB
+
+47
+00:04:15,450 --> 00:04:20,810
+بده يجيل المقدار X A بدها تصير X B بدها تصير 2 من
+
+48
+00:04:20,810 --> 00:04:23,910
+10 اللي أصلا هي موجودة زائد الـX اللي إجتها من
+
+49
+00:04:23,910 --> 00:04:29,710
+الـAB من تفكك الـAB إذا هتكون 0.2 plus X الآن من
+
+50
+00:04:29,710 --> 00:04:36,510
+ال equilibrium constant النواتج اللي هو AX بـ0.2
+
+51
+00:04:36,510 --> 00:04:43,840
+plus X على الـAB 0.1 minus Xطبعا عشان أحل المسألة
+
+52
+00:04:43,840 --> 00:04:47,400
+بد أفرض الفرضية تبعتي ممكن أقول ال point two أكبر
+
+53
+00:04:47,400 --> 00:04:50,680
+كتير من ال X أو ال point one أكبر كتير من ال X لكن
+
+54
+00:04:50,680 --> 00:04:54,640
+طبعا أنا بختار الأقل point one أكبر كتير من ال X
+
+55
+00:04:54,640 --> 00:04:57,920
+لأنه إذا كانت ال point one أكبر كتير من ال X
+
+56
+00:04:57,920 --> 00:05:02,130
+فبالضرورة ال point two أكبر كتير من ال Xإذا ال
+
+57
+00:05:02,130 --> 00:05:06,850
+equilibrium constant 3 في 10 أقص سالب 6 بيكون 0.2
+
+58
+00:05:06,850 --> 00:05:13,610
+في X على 0.1 وال X بتطلع 1.5 في 10 أقص سالب 6 لو
+
+59
+00:05:13,610 --> 00:05:17,890
+أجيت أنا قارنت ال X هذه مع ال X اللي حصلت عليها في
+
+60
+00:05:17,890 --> 00:05:23,350
+غياب في عدم وجود ال B أول مثال حالينا كانت ال X
+
+61
+00:05:23,350 --> 00:05:28,630
+بيكون 5.5 في 10 أقص سالب 4لو أقارنها بالواحد و نصف
+
+62
+00:05:28,630 --> 00:05:33,250
+عشرة أس سالب ستة، معناته قلت بشكل ملحوظ، يبقى وجود
+
+63
+00:05:33,250 --> 00:05:39,530
+common ion بخل التفكك يرجع للخلف أو بمعنى أخر بيقل
+
+64
+00:05:39,530 --> 00:05:44,220
+التفكك في وجود ال common ionطبعاً لما نطلع قيمة ال
+
+65
+00:05:44,220 --> 00:05:47,840
+X هذا مش كافي لازم أطلع ال relative error فبتدجم
+
+66
+00:05:47,840 --> 00:05:51,860
+ال X على point one في مية من مية بيطلع عنا واحد و
+
+67
+00:05:51,860 --> 00:05:55,340
+نصف عشرة أسالب تلاتة في المية خطأ نسبة لا يكاد
+
+68
+00:05:55,340 --> 00:06:02,100
+يذكر إذا ال assumption عناOkay valid ال A هي عبارة
+
+69
+00:06:02,100 --> 00:06:05,340
+عن X واحد و نصف عشر أقل سالب ستة molar ال B عبارة
+
+70
+00:06:05,340 --> 00:06:09,160
+عن point two بجمعش إلها ال X وال A عبارة عن point
+
+71
+00:06:09,160 --> 00:06:12,860
+one مش ضروري أترح منها ال X لأن أحنا قلنا أن ال X
+
+72
+00:06:12,860 --> 00:06:21,100
+أقل منها بكتير يبقى هذا مثال على إيش بيحصل لو كان
+
+73
+00:06:21,100 --> 00:06:25,720
+في عنا common ion واستنتجنا منه أن التفكك بيقل في
+
+74
+00:06:25,720 --> 00:06:32,660
+وجود ال common ionالآن بننتقل لموضوعنا الرئيسي هذه
+
+75
+00:06:32,660 --> 00:06:39,160
+الحصة اللي هو الـ Systemic Approach ال chemical
+
+76
+00:06:39,160 --> 00:06:43,860
+equilibrium calculations في الحقيقة في يعني two
+
+77
+00:06:43,860 --> 00:06:51,620
+approachesلحلها او في طريقتين يعني لحل ال chemical
+
+78
+00:06:51,620 --> 00:06:55,560
+equilibrium calculations الطريقة اللي احنا اتعودنا
+
+79
+00:06:55,560 --> 00:06:58,980
+عليها في الحل وشوفناها الحصة الماضية بالتفصيل و
+
+80
+00:06:58,980 --> 00:07:05,320
+اللي بتعتمد اساسا على انه في عندى والله مقدار ضئيل
+
+81
+00:07:05,320 --> 00:07:11,280
+مقداره Xلا يكاد يذكر بالنسبة للمتفاعلات أو لا يكاد
+
+82
+00:07:11,280 --> 00:07:14,720
+يذكر بالنسبة للنواتج بحسب قيمة equilibrium
+
+83
+00:07:14,720 --> 00:07:18,340
+constant هدول المفهومين هم أو هذا المفهوم البسيط
+
+84
+00:07:18,340 --> 00:07:23,150
+هو اللي بستخدمه في الحل فقطأي مسألة بتنحل بناء على
+
+85
+00:07:23,150 --> 00:07:27,950
+هذا المفهوم بدي أشوف والله هل ألغي ال X بالنسبة
+
+86
+00:07:27,950 --> 00:07:31,970
+للنواتج أو المتفاعلات وهذا الكلام بتوقف على قيمة
+
+87
+00:07:31,970 --> 00:07:35,670
+ال equilibrium constant هذا منهجنا في الحل خلال
+
+88
+00:07:35,670 --> 00:07:39,090
+الفصل هذا كله احنا بتبين هذا الأسلوب في الحل لكن
+
+89
+00:07:39,090 --> 00:07:43,970
+يا شبابفي طريقة أخرى للحل اسمها الطريقة المنهجية
+
+90
+00:07:43,970 --> 00:07:49,950
+في يعني ناس كتير بيفضلوا استخدامها أو بيحبوا
+
+91
+00:07:49,950 --> 00:07:55,550
+يستخدموها وفي كتب ممتازة جدا في الكيمة التحليلية
+
+92
+00:07:55,550 --> 00:08:00,910
+تعتمد ال systematic approach وبالتالي يعني أنا
+
+93
+00:08:00,910 --> 00:08:04,790
+وجدت أنه من المفيد و الكاتب طبعا كاتب ال textbook
+
+94
+00:08:04,790 --> 00:08:08,530
+تبعنا وجد من المفيد أنه على الأقل نعطيك فكرة بسيطة
+
+95
+00:08:08,530 --> 00:08:14,490
+عنهاونقول لك ايش أساسيات الطريقة المنهجية في حال
+
+96
+00:08:14,490 --> 00:08:18,930
+مسائل ال equilibrium بنقول ببساطة خالص الطريقة
+
+97
+00:08:18,930 --> 00:08:23,850
+المنهجية او ال systematic approach تعتمد على تكوين
+
+98
+00:08:23,850 --> 00:08:30,390
+معادلات يساوي عدد المجاهيل على الأقل اللي موجودة
+
+99
+00:08:30,390 --> 00:08:36,320
+عند في المثلة يعني مثلا لو عندي اي اتزانمعناته في
+
+100
+00:08:36,320 --> 00:08:40,940
+IND عدة species موجودة في المحلول هذه ال species
+
+101
+00:08:40,940 --> 00:08:45,360
+مجهولة لأنه قبل ما أحسب ما بقدرش أعرف تركيز كل
+
+102
+00:08:45,360 --> 00:08:48,860
+species منها أو كل مادة أو كل ايون منها ما بقدر
+
+103
+00:08:48,860 --> 00:08:54,180
+اعرف هذا الكلام طيب من ال equilibriumequations
+
+104
+00:08:54,180 --> 00:08:59,900
+بقدر أجيب معادلات اسمها equilibrium equations اللي
+
+105
+00:08:59,900 --> 00:09:02,940
+هي ال equilibrium constants بقدر أجيب معادلات
+
+106
+00:09:02,940 --> 00:09:09,880
+equilibrium constants لكن عشان أحل و أوجد مجموعة
+
+107
+00:09:09,880 --> 00:09:15,060
+من المجاهيل يجب أن يكون لدي مجموعة من المعادلات
+
+108
+00:09:15,060 --> 00:09:20,650
+تساوي عدد المجاهيلفي معظم الأحيان بلاقيش عندى عدد
+
+109
+00:09:20,650 --> 00:09:25,550
+معادلات تساوي عدد المجاهيل طب إيش بدى أعمل؟ مافيش
+
+110
+00:09:25,550 --> 00:09:29,810
+عندى عدد معادلات يساوي عدد المجاهيل قال باطلع على
+
+111
+00:09:29,810 --> 00:09:35,190
+إيجاد معادلات جديدة المعادلات الجديدة هذه مبنية
+
+112
+00:09:35,190 --> 00:09:39,250
+على أساس حاجتين أول حاجة في هدول الحاجتين ان في
+
+113
+00:09:39,250 --> 00:09:43,930
+عندى mass conservationفي عندى قانون بقاء المادة
+
+114
+00:09:43,930 --> 00:09:49,650
+يعنى او الكتلة ومعنى هذا الكلام انه ابساطة خالص لو
+
+115
+00:09:49,650 --> 00:09:55,810
+في عندى مادة معينة حطيت تركيز معين منها في المحلول
+
+116
+00:09:55,810 --> 00:10:03,830
+فهذه المادة اتجزأت فتقول التركيز الكلييساوي مجموع
+
+117
+00:10:03,830 --> 00:10:06,630
+تركيزات الأجزاء المختلفة هذا وضع طبيعي هذا mass
+
+118
+00:10:06,630 --> 00:10:11,270
+conservation ولا وين بده يروح لما يتجزق بده يطير
+
+119
+00:10:11,270 --> 00:10:15,850
+بده يختفي لأ والله التركيز الكلي بده يساوي مجموع
+
+120
+00:10:15,850 --> 00:10:19,950
+تركيزات الأجزاء المختلفة هذا وضع طبيعي هنشوفهتفصيل
+
+121
+00:10:19,950 --> 00:10:25,770
+بعد شوية هذا أول مفهوم المفهوم التاني قال المحاليل
+
+122
+00:10:25,770 --> 00:10:30,370
+electro neutral متعادلة كهربيا بلاجيش محلول سالب
+
+123
+00:10:30,370 --> 00:10:35,230
+كهربيا او محلول موجب كهربيا ما بلاجي هذا الكلام
+
+124
+00:10:35,230 --> 00:10:40,590
+المحاليل متعادلة اذا تركيز الشحنات الموجبة يساوي
+
+125
+00:10:40,590 --> 00:10:44,970
+تركيز الشحنات السالبة وضع طبيعي ليه لأن المحاليل
+
+126
+00:10:44,970 --> 00:10:49,670
+متعادلة فيجب ان تكون تركيزات المحاليلتركيزات
+
+127
+00:10:49,670 --> 00:10:53,350
+الشحنات السالية بتساوي تركيزات الشحنات الموجة بقى
+
+128
+00:10:53,350 --> 00:10:59,050
+خلينا نتطلع على هذا المثال و نحاول نترجم المفاهيم
+
+129
+00:10:59,050 --> 00:11:03,030
+اللي ذكرناها على هذا المثال فبيقول write mass and
+
+130
+00:11:03,030 --> 00:11:06,370
+charge balance equations for 0.1 molar acetic acid
+
+131
+00:11:06,370 --> 00:11:12,910
+in waterفي البداية الـ systematic approach تعتمد
+
+132
+00:11:12,910 --> 00:11:17,550
+اعتماد يعني كبير جدا على انه يجب علينا ان نكتب
+
+133
+00:11:17,550 --> 00:11:20,690
+جميع الاتزانات اللي موجودة في المحلول فعشان انا
+
+134
+00:11:20,690 --> 00:11:24,250
+اكتب اتزان واسيب الباقي، لأ، بدك تكتب كل الاتزانات
+
+135
+00:11:24,250 --> 00:11:29,510
+المحتملة في المحلولطيب الان لو اجينا شوفنا ال
+
+136
+00:11:29,510 --> 00:11:32,290
+acidic acid ايش بيحصلله في الميه جال ورا ال acidic
+
+137
+00:11:32,290 --> 00:11:38,010
+acid بتفكك جزئيا في الميه بيعطينا acetate و الميه
+
+138
+00:11:38,010 --> 00:11:41,750
+اصلا برضه يعني بتتفكك جزئيا بتعطي H plus و
+
+139
+00:11:41,750 --> 00:11:45,650
+hydroxide مش هيك فهي ال equilibrium الموجودة طيب
+
+140
+00:11:45,650 --> 00:11:49,230
+انا لو بدى احل المسألة هذه و اعرف تركيزات الايونات
+
+141
+00:11:49,230 --> 00:11:52,490
+المختلفة يعني بدى اعرف تركيز ال acidic acid اللي
+
+142
+00:11:52,490 --> 00:11:58,410
+ماتفككشبدي اعرف جداش تركيز ال H بلس، بدي اعرف جداش
+
+143
+00:11:58,410 --> 00:12:02,530
+تركيز الاسيتات، بدي اعرف جداش تركيز الهيدروكسيد،
+
+144
+00:12:02,530 --> 00:12:07,350
+يبقى في عندي أربع مجاهيل، طيب أنا فش عندي إلا يمكن
+
+145
+00:12:07,350 --> 00:12:13,190
+معادلتين ال equilibrium constant ل الacetic acid و
+
+146
+00:12:13,190 --> 00:12:19,340
+ال KW للميه، هاي اللي موجودين عنديطب كيف بدى أحل
+
+147
+00:12:19,340 --> 00:12:23,960
+معادلتين وما عندى اللي غير؟ يعني كيف بدى أحل
+
+148
+00:12:23,960 --> 00:12:27,660
+معادلتين بمجهولين باربع مجاهيل وما عندى اللي غير
+
+149
+00:12:27,660 --> 00:12:32,620
+بس معادلتين؟ مالفعش، بدى أجيب معادلتين أخرينعشان
+
+150
+00:12:32,620 --> 00:12:35,520
+يكون عندي أربع معادلات و أربع مجاهيل أه ساعتها
+
+151
+00:12:35,520 --> 00:12:39,440
+بقدر أحلهم، أنا هالجيت مش هذا موضوعي، أنا موضوعي
+
+152
+00:12:39,440 --> 00:12:44,740
+بس أنه بدي أكتب معادلات mass balance و charge
+
+153
+00:12:44,740 --> 00:12:48,720
+balance، لكن أفرجيك ليش، يعني بحكيلك ليش، لأنه أنا
+
+154
+00:12:48,720 --> 00:12:53,560
+في الأصل لو بدي أجيب تركيزاتالاستك أسد وال إتش بلس
+
+155
+00:12:53,560 --> 00:12:57,500
+والأستيت والهيدروكسيد لازم يكون عندي أربع معادلات
+
+156
+00:12:57,500 --> 00:13:00,820
+لأن في عندي أربع مجاهيل فهنا في عندي معادلتين من
+
+157
+00:13:00,820 --> 00:13:03,880
+ال equilibrium constants إذا أنا بدي أجيب معادلتين
+
+158
+00:13:03,880 --> 00:13:11,420
+تانية الآن احنا خلينا نفهم الموضوعبنقول كيف نوجد
+
+159
+00:13:11,420 --> 00:13:14,320
+مثلا ال charge balance، ال charge balance حاجة
+
+160
+00:13:14,320 --> 00:13:17,880
+كتير بسيطة، بدي أقول والله تركيز الشحنات الموجبة
+
+161
+00:13:17,880 --> 00:13:21,740
+يساوي تركيز الشحنات السالبة، الشحنات الموجبة مافيش
+
+162
+00:13:21,740 --> 00:13:26,820
+عندي غير ال H plus، تركيز الشحنات الموجبة على ال H
+
+163
+00:13:26,820 --> 00:13:32,550
+plus تساوي تركيز ال H plusهذا كلام بيساوي تركيز
+
+164
+00:13:32,550 --> 00:13:36,050
+شحنة السالبة السالب عندي هيدروكسيد سالب تركيز
+
+165
+00:13:36,050 --> 00:13:38,030
+الشحنة السالبة على الهيدروكسيد تساوي تركيز
+
+166
+00:13:38,030 --> 00:13:41,510
+الهيدروكسيد تركيز الشحنة السالبة على الأستيت تساوي
+
+167
+00:13:41,510 --> 00:13:45,830
+تركيز الأستيتأذا عند ال H بلس بيساوي هيدروكسيد
+
+168
+00:13:45,830 --> 00:13:49,770
+زائد أسيتيت هذا عبارة عن charge balance equation
+
+169
+00:13:49,770 --> 00:13:54,990
+معادلة بسميها charge balance equation يعني تركيزات
+
+170
+00:13:54,990 --> 00:14:01,790
+الشحنات الموجبة تساوي تركيزات الشحنات السالبة لأنه
+
+171
+00:14:01,790 --> 00:14:03,250
+المحلي ال electro neutral
+
+172
+00:14:05,870 --> 00:14:09,230
+الـ Mass Balance Equations أنا عندي 0.1 مولار
+
+173
+00:14:09,230 --> 00:14:12,930
+أساتيك أسد، ده التركيز الكلي اللي بسميه إيش؟ C
+
+174
+00:14:12,930 --> 00:14:16,970
+للأساتيك أسد، Analytical Concentration للأساتيك
+
+175
+00:14:16,970 --> 00:14:21,930
+أسدبقول والله انا بدي اجيب ال mass balance بقول
+
+176
+00:14:21,930 --> 00:14:25,810
+التركيز الكلي اللى هو ال point one يساوي ال acetic
+
+177
+00:14:25,810 --> 00:14:30,010
+acid اللى ماتفككش زائد ال acetic acid اللى اتفكك
+
+178
+00:14:30,010 --> 00:14:33,930
+اللى اتفكك يساوي ايش تركيز ال acetate لأن ال
+
+179
+00:14:33,930 --> 00:14:38,110
+acetic acid لما يتفكك ايش بعطينى؟أسيتيت اذا ال
+
+180
+00:14:38,110 --> 00:14:42,590
+point one تساوي تركيز ال acetic acid اللي ماتفككش
+
+181
+00:14:42,590 --> 00:14:45,750
+اللي ضايل في ال equilibrium زائد تركيز ال acetate
+
+182
+00:14:45,750 --> 00:14:50,810
+هذه معادلة بقولها mass balance mass balance
+
+183
+00:14:50,810 --> 00:14:59,290
+equation ماشي نعم واحد من عشرة
+
+184
+00:14:59,290 --> 00:15:05,310
+مولاند هو كان واحد من عشرةكيف صرت لك ان تقول mass
+
+185
+00:15:05,310 --> 00:15:09,370
+balance؟ لأ، mass balance مش هو ماكنت لأ، mass
+
+186
+00:15:09,370 --> 00:15:15,570
+balance معناته انه التركيز .. التركيز الكلي اللي
+
+187
+00:15:15,570 --> 00:15:22,310
+هو هيو يساويمجموع تركيزات الأجزاء المختلفة، فهو
+
+188
+00:15:22,310 --> 00:15:26,650
+جزء من التركيز الكلي، ضال زي ما هو، أيه؟ وجزء منه
+
+189
+00:15:26,650 --> 00:15:31,150
+اتحول للاستات، مجموع الأجزاء يساوي التركيز الكلي،
+
+190
+00:15:31,150 --> 00:15:34,950
+هاي معناه mass balance، مش معناته يعني كتلة، كويس؟
+
+191
+00:15:34,950 --> 00:15:41,050
+mass balance، مفهومه يعني التركيزات المختلفة
+
+192
+00:15:41,050 --> 00:15:48,820
+الجزئية تساوي التركيز الكلينجي نتطلع على المثال
+
+193
+00:15:48,820 --> 00:15:53,160
+التالي وفيه شوية مفاهيم اكويس انه نتبهلها بقول
+
+194
+00:15:53,160 --> 00:15:59,760
+write a mass and charge balance equations for 0.1
+
+195
+00:15:59,760 --> 00:16:04,460
+molar silver diamonium chloride او diamonia
+
+196
+00:16:04,460 --> 00:16:09,750
+chlorideأنا في عندي silver diamonia chloride واحد
+
+197
+00:16:09,750 --> 00:16:14,250
+من عشر مولار هذا مُركّب أيوني بيتفكك تفكك كامل
+
+198
+00:16:14,250 --> 00:16:19,410
+بعطيني chloride زائد silver diamonia complex لو
+
+199
+00:16:19,410 --> 00:16:22,650
+مافيش عندي غير هذا التفكك كيقولت والله ال chloride
+
+200
+00:16:22,650 --> 00:16:29,090
+بساوي هذا مش هيك ال chloride بساوي وانا ممكن اقول
+
+201
+00:16:29,090 --> 00:16:33,650
+يعني هالجيت من هذه المعادلة ان ال chloride
+
+202
+00:16:36,420 --> 00:16:42,940
+بدو يساوي الـC للـSilver Diammonium
+
+203
+00:16:42,940 --> 00:16:45,680
+Complex
+
+204
+00:16:46,470 --> 00:16:49,810
+الـ C تركيزي الكلي للـ Silver لإيه؟ لأنه أنا في
+
+205
+00:16:49,810 --> 00:16:54,090
+عيندي Equilibria تانية الـ Silver بي أمونيا هذا
+
+206
+00:16:54,090 --> 00:16:58,030
+اللي طلع عيندي بتفكك جزئيا بيحطيني Silver أمونيا و
+
+207
+00:16:58,030 --> 00:17:01,310
+أمونيا و الـ Silver أمونيا كمان بتفكك بيحطيني
+
+208
+00:17:01,310 --> 00:17:04,610
+Silver و أمونيا و الأمونيا بتلاقى على في الميه
+
+209
+00:17:04,610 --> 00:17:10,550
+فتحطيني أمونيام و Hydroxideو الميه كمان تتفكك لا H
+
+210
+00:17:10,550 --> 00:17:14,130
+بلصه Hydroxide ففيه عندي مجموعة من ايه؟ من
+
+211
+00:17:14,130 --> 00:17:17,430
+التفككات و مجموعة من ال species لاحظوا معادلات
+
+212
+00:17:17,430 --> 00:17:22,090
+كتيرة و مجاهير كتيرة ايضا فكيف انا بدى اوجد
+
+213
+00:17:22,090 --> 00:17:26,090
+المجاهيل هذه بقول نعم ال equilibrium constant
+
+214
+00:17:26,090 --> 00:17:30,950
+equations هذه معلومة لكن بتففيش فبدى mass with
+
+215
+00:17:30,950 --> 00:17:34,150
+charge balance equations علشان يكون عندي عدد
+
+216
+00:17:34,150 --> 00:17:40,700
+المجاهيلبساوى عدد المعادلات على الأقل عدد
+
+217
+00:17:40,700 --> 00:17:44,160
+المعادلات لازم يساوى عدد المجاهل ما علينا احنا
+
+218
+00:17:44,160 --> 00:17:49,160
+مهمتنا مش الحل المهمتنا بس انه نكتب ال mass
+
+219
+00:17:49,160 --> 00:17:52,260
+balance و ال charge balance equations فنيجي نطلع
+
+220
+00:17:52,260 --> 00:17:56,750
+على في البداية ال charge balance equationبقول
+
+221
+00:17:56,750 --> 00:17:59,830
+والله في ال charge balance equation عندي الموجب
+
+222
+00:17:59,830 --> 00:18:05,150
+تركيزات الشحنات الموجبة وطلع ايش بقول انا تركيزات
+
+223
+00:18:05,150 --> 00:18:08,910
+مش الايونات الموجبة تركيزات الشحنات الموجبة يساوي
+
+224
+00:18:08,910 --> 00:18:13,810
+تركيزات الشحنات السالبة فبقول الموجب هي تركيز
+
+225
+00:18:13,810 --> 00:18:17,870
+الشحن الموجبة على ال H plus تساوي تركيز ال H plus
+
+226
+00:18:17,870 --> 00:18:21,270
+تركيز الشحن الموجبة على ال silverتساوي تركيز
+
+227
+00:18:21,270 --> 00:18:25,210
+السلفر، تركيز الشحن الموجب على الأمونيام يساوي
+
+228
+00:18:25,210 --> 00:18:29,010
+تركيز الأمونيام، تركيز الشحن الموجب على السلفر by
+
+229
+00:18:29,010 --> 00:18:33,170
+أمونيا يساوي تركيز السلفر by أمونيا، تركيز الشحن
+
+230
+00:18:33,170 --> 00:18:36,250
+الموجب على السلفر أمونيا يساوي تركيز السلفر
+
+231
+00:18:36,250 --> 00:18:40,070
+أمونيا، هذا كلام كله، هذا الموجب السالب تركيز
+
+232
+00:18:40,070 --> 00:18:43,490
+الشحن السالب على الهيدروكسيد يساوي تركيز
+
+233
+00:18:43,490 --> 00:18:46,890
+الهيدروكسيدتركيز الشحنة السالبة على الكلورايد
+
+234
+00:18:46,890 --> 00:18:50,050
+يساوي تركيز الكلورايد يبقى السالب على الشجة
+
+235
+00:18:50,050 --> 00:18:53,850
+والموجب على الشجة صار عندي معادلة المعادلة هذه
+
+236
+00:18:53,850 --> 00:19:01,370
+بقولها charge balance equation ماشي يا شباب الآن
+
+237
+00:19:01,370 --> 00:19:06,190
+خلينا نوجد mass balance equations mass balance
+
+238
+00:19:06,190 --> 00:19:10,710
+equationsو تعالوا في البداية يعني قبل ما اوجد انا
+
+239
+00:19:10,710 --> 00:19:16,170
+ال math plus equations تعالوا اقولكم هالشغلة خليني
+
+240
+00:19:16,170 --> 00:19:23,430
+اقول هي عندي ال complex انا مين
+
+241
+00:19:23,430 --> 00:19:28,070
+يقوللي جداش هذا point one molar؟ مين يقوللي جداش
+
+242
+00:19:28,070 --> 00:19:32,020
+ال C للاج؟جدش التركيز الكلي للفضة بدي يكون في
+
+243
+00:19:32,020 --> 00:19:35,520
+المحلول اذا كان انا اللي حطيته point one molar A G
+
+244
+00:19:35,520 --> 00:19:41,960
+N H اتنين CL جدش التركيز الكلي للفضة واحد من عشرة
+
+245
+00:19:41,960 --> 00:19:45,520
+نفسه هذا واحد واحد من عشرة لأنه كل mole من هذا
+
+246
+00:19:45,520 --> 00:19:49,080
+المركب في واحد mole من ال silver اذا بما انه هذا
+
+247
+00:19:49,080 --> 00:19:52,040
+التركيز واحد من عشرة يبقى ال silver واحد من عشرة
+
+248
+00:19:52,040 --> 00:19:58,200
+molar طب ايش ال C لل أمونيا اتنين من عشرة molar ال
+
+249
+00:19:58,200 --> 00:20:03,940
+C للكلورايد1 من 10 امونيا حلو كتير اذا انا بقدر
+
+250
+00:20:03,940 --> 00:20:08,780
+اوجد mass balance equation لل silver ايش بتساوي
+
+251
+00:20:08,780 --> 00:20:11,300
+قال والله ال 1 من 10 هو التركيز الكل لل silver
+
+252
+00:20:11,300 --> 00:20:15,700
+يساوي كل اش فيه silver التركيزات الجزئية لل silver
+
+253
+00:20:15,700 --> 00:20:19,900
+كلها بقدر اجيب mass balance equation لل امونيا
+
+254
+00:20:19,900 --> 00:20:26,740
+تركيز الامونيا الكل يساوي مجموع التركيزات الجزئية
+
+255
+00:20:26,740 --> 00:20:32,630
+للامونيا كلهاالتركيز الكلي للأمونيا يسمى مجموعة
+
+256
+00:20:32,630 --> 00:20:38,810
+التركيزات الكلية الجزئية للأمونيا طيب، الآن بنتطلع
+
+257
+00:20:38,810 --> 00:20:42,370
+للأمونيا مثلا، بنتطلع للمعدن التحتانية في الأول
+
+258
+00:20:42,370 --> 00:20:51,330
+الـC للـAG الـAG بتساوي 1 من 10 وهي نفسها
+
+259
+00:20:51,330 --> 00:20:55,890
+الchloride برضه 1 من 10 كويس، لكن إيش بتساوي؟ كل
+
+260
+00:20:55,890 --> 00:21:04,790
+إيش فيه silver، بقول الـAG plusأي جي اي
+
+261
+00:21:04,790 --> 00:21:10,630
+جي اي جي
+
+262
+00:21:10,630 --> 00:21:14,610
+اي جي اي جي اي جي اي جي اي جي اي جي اي جي اي جي اي
+
+263
+00:21:14,610 --> 00:21:21,150
+جي اي جي اي جي اي جي اي جي
+
+264
+00:21:21,150 --> 00:21:31,580
+اي جي اي جي اي جي اي جيجداش point two اذا point
+
+265
+00:21:31,580 --> 00:21:35,740
+two بتساوي كل اشي فيها أمونيا مش هيك كل التركيزات
+
+266
+00:21:35,740 --> 00:21:41,580
+الجزية للأمونيا فبقول silver by ammonia بقول تركيز
+
+267
+00:21:41,580 --> 00:21:46,360
+الأمونيا في ال silver by ammonia ضعف تركيز ال
+
+268
+00:21:46,360 --> 00:21:50,860
+silver by ammonia تركيز ال .. تركيز الأمونيا في ال
+
+269
+00:21:50,860 --> 00:21:55,160
+silver by ammonia ضعف تركيز ال silver by ammonia
+
+270
+00:21:55,160 --> 00:22:00,180
+اذا بدي احط هنا اتنينلأن تركيز الأمونيا جداش ضعفه
+
+271
+00:22:00,180 --> 00:22:05,960
+في اتنين مش هيك طيب تركيز ال silver في تركيز
+
+272
+00:22:05,960 --> 00:22:09,360
+الأمونيا في ال silver أمونيا واحد لواحد يعني تركيز
+
+273
+00:22:09,360 --> 00:22:12,920
+ال silver أمونيا زائد تركيز الأمونيا زائد تركيز
+
+274
+00:22:12,920 --> 00:22:16,360
+الأمونيا هذه التركيزات كلها هي التركيزات الجزئية
+
+275
+00:22:16,360 --> 00:22:19,740
+اللي فيها أمونيا كل الأمونيا مجموعة كل الأمونيا
+
+276
+00:22:19,740 --> 00:22:23,700
+تركيزات الأمونيا اتنين من عشرة مولار يبقى هذه
+
+277
+00:22:23,700 --> 00:22:28,680
+عبارة عن mass balance equationفى ما يتعلق بالإيه
+
+278
+00:22:28,680 --> 00:22:33,460
+بالأمونيا يبقى جبت charge balance equation جبت two
+
+279
+00:22:33,460 --> 00:22:40,860
+mass balance equations ماشي يا شباب طيب نطلع على
+
+280
+00:22:40,860 --> 00:22:47,860
+مثال آخر المثال إيش بيقول كلام كتير بسيط بيقول
+
+281
+00:22:47,860 --> 00:22:54,340
+write mass and charge balance equations for a
+
+282
+00:22:54,340 --> 00:23:02,140
+solution of H2Sبقول فش أبسط من هيك أنا ال H2S له
+
+283
+00:23:02,140 --> 00:23:07,620
+تركيز كله لكن بعد ما حط ال H2S في الميه بتفكك
+
+284
+00:23:07,620 --> 00:23:11,580
+جزئيا و الميه كمان بتتفكك وضع الطبيعة جزئيا برضه
+
+285
+00:23:11,580 --> 00:23:20,820
+فبقول ال C لل H2S لو حبيتي ال C لل H2S تركيز كله
+
+286
+00:23:20,820 --> 00:23:25,620
+لل H2S بساوي كل إش فيه سلفر لأن أي إش فيه سلفر جاي
+
+287
+00:23:25,620 --> 00:23:32,350
+من ال H2Sفهي ال H2S زائد ال HS- زائد ال S2- من وين
+
+288
+00:23:32,350 --> 00:23:40,830
+جبناهم؟ من المعادلات هي H2S HS- S2- كل إش فيه S
+
+289
+00:23:40,830 --> 00:23:46,510
+فيه سلفر جاي من ال H2S إذا التركيز الكل لل H2S بده
+
+290
+00:23:46,510 --> 00:23:50,390
+يساوي مجموعة التركيزات المختلفة اللي فيها سلفر
+
+291
+00:23:53,010 --> 00:23:57,650
+نعم تفككتش مرتين انا قلت ال H2S بتفكك بيعطيني HS
+
+292
+00:23:57,650 --> 00:24:03,330
+minus زي .. هذا equilibrium ال HS minus هذا كمان
+
+293
+00:24:03,330 --> 00:24:06,850
+جزء منه بي .. مش كله جزء منه بيتفكك بيعطيني H plus
+
+294
+00:24:06,850 --> 00:24:11,790
+و S2 minus كويس بعدين ال H2 او بتفكك بتعطيكي H
+
+295
+00:24:11,790 --> 00:24:15,910
+plus و hydroxide هيك بتتم عملية التفكك يعني هذا
+
+296
+00:24:15,910 --> 00:24:22,300
+stepwise dissociation equilibriumطب نيجي نطلع و
+
+297
+00:24:22,300 --> 00:24:26,660
+الكل ينتبه نطلع على ال charge balance equation
+
+298
+00:24:26,660 --> 00:24:30,820
+بقول الموجب على شجة والسالب على شجة انا عندي
+
+299
+00:24:30,820 --> 00:24:35,700
+الموجب مش غير ال H plus اذا تركيز الشحنات الموجبة
+
+300
+00:24:35,700 --> 00:24:40,860
+علىالبروتون او ال H بلس تساوي تركيز ال H بلس فاش
+
+301
+00:24:40,860 --> 00:24:45,940
+مشكلة تركيز الشحنات السالبة على الهيدروكسيد تساوي
+
+302
+00:24:45,940 --> 00:24:48,860
+تركيز الهيدروكسيد لأنه الهيدروكسيد واحد الشحنات
+
+303
+00:24:48,860 --> 00:24:52,520
+السالبة واحد تركيز الشحنات السالبة على ال HS
+
+304
+00:24:52,520 --> 00:24:58,580
+بتساوي تركيز ال HS طيب الآن نيجي تركيز الشحنات
+
+305
+00:24:58,580 --> 00:25:05,320
+السالبة على السلفر بعف تركيز السلفر السلفر واحد
+
+306
+00:25:06,110 --> 00:25:09,070
+الشحنات السلب اللي عليه قد إيش؟ اتنين، فإذا كان
+
+307
+00:25:09,070 --> 00:25:13,190
+عندي مول من السلفر، إذا عندي مول من السلفر، أكمل
+
+308
+00:25:13,190 --> 00:25:17,790
+شحنات فيه؟ اتنين، إذا تركيز الشحنات اللي على
+
+309
+00:25:17,790 --> 00:25:22,730
+السلفر تساوي ضعف تركيز السلفر، يبقى فيه عندي هنا
+
+310
+00:25:22,730 --> 00:25:27,830
+اتنين، ناخد بالنا من هذا الكلام كويس كتير، كمان
+
+311
+00:25:27,830 --> 00:25:32,340
+مثال، برضه نوضح فيه هذا المفهوم أكتر من هيكالمثال
+
+312
+00:25:32,340 --> 00:25:36,920
+بيقول write mass and charge balance equations for
+
+313
+00:25:36,920 --> 00:25:40,240
+cadmium sulphide in solution ال cadmium sulphide
+
+314
+00:25:40,240 --> 00:25:44,660
+يا شباب هاد عبارة عن مادة شححت الذوبان في الميه
+
+315
+00:25:44,660 --> 00:25:50,580
+فتتفكك جزئيا بشكل ضئيل للغاية في الميه بتعطينا
+
+316
+00:25:50,580 --> 00:25:56,820
+cadmium و sulphur او sulphideموضوع طبيعي انه الكدم
+
+317
+00:25:56,820 --> 00:26:00,800
+لو مافيش عندى اي تفكك غير هذا يبقى الكدم يبقى
+
+318
+00:26:00,800 --> 00:26:03,760
+بساوى السلفر يقول ها جاءت الكدم يبقى بساوى كل
+
+319
+00:26:03,760 --> 00:26:09,360
+السلفر لكن السلفر ايش حصل له اتجزأ نتيجة ال
+
+320
+00:26:09,360 --> 00:26:12,740
+equilibrium جزء منه اتحول .. جزء منه ضال زي ما هو
+
+321
+00:26:12,740 --> 00:26:20,380
+S2- جزء منه اتحول لـHS- جزء منه اتحول لـH2S فالكدم
+
+322
+00:26:20,380 --> 00:26:26,110
+صحيح بساوى السلفر لكن بساوى كل السلفرفممكن نقول
+
+323
+00:26:26,110 --> 00:26:28,590
+والله الآن خلينا نكتب math with charge balance
+
+324
+00:26:28,590 --> 00:26:33,290
+equations نتطلع على ال charge balance equation
+
+325
+00:26:33,290 --> 00:26:37,510
+بقول الموجب على شجة والسالب على شجة تركيز الشحنات
+
+326
+00:26:37,510 --> 00:26:41,390
+الموجبة على ال H بيساوي تركيز ال H plus تركيز
+
+327
+00:26:41,390 --> 00:26:45,050
+الشحنات الموجبة على الكدميوم يساوي ضعف تركيز
+
+328
+00:26:45,050 --> 00:26:48,950
+الكدميومتركيز الشحنات السالبة على ال OH يساوي
+
+329
+00:26:48,950 --> 00:26:52,530
+تركيز ال OH تركيز الشحنات السالبة على ال HS يساوي
+
+330
+00:26:52,530 --> 00:26:57,670
+تركيز ال HS تركيز الشحنات السالبة على ال sulphide
+
+331
+00:26:57,670 --> 00:27:02,470
+يساوي ضعيف تركيز ال sulphide ده انه كل مول عليه
+
+332
+00:27:02,470 --> 00:27:07,930
+اتنين مول شحنات طيب هذه بتعبر عن ال charge balance
+
+333
+00:27:07,930 --> 00:27:11,810
+الآن ال mass balance equation بقول ال cadmium
+
+334
+00:27:11,810 --> 00:27:16,990
+بساوي كل الصلفرصح ولا لأ؟ لأن ال cadmium sulfide
+
+335
+00:27:16,990 --> 00:27:21,610
+بيتفكك ل cadmium و لا sulfur، إذا ال cadmium
+
+336
+00:27:21,610 --> 00:27:25,710
+بيساوي كل ال sulfur، هذا اتجزأ، ماشي ال cadmium
+
+337
+00:27:25,710 --> 00:27:29,350
+بيساوي مجموع الأجزاء، فمجموع الأجزاء هي عبارة عن
+
+338
+00:27:29,350 --> 00:27:33,410
+إيه؟ عبارة عن كل إش فيه sulfur، يبقى بيساوي ال H2S
+
+339
+00:27:33,410 --> 00:27:39,650
+زائد ال HS-, زائد ال S2-, هذه بنقولها mass balance
+
+340
+00:27:39,650 --> 00:27:40,350
+equation
+
+341
+00:27:43,600 --> 00:27:51,660
+لكن الـH2S هو مجموعة من التلفزيون ماشي
+
+342
+00:27:51,660 --> 00:27:55,260
+ممكن تقول كمان يعني ان الـC يعني ازميلكم بيقول
+
+343
+00:27:55,260 --> 00:27:59,460
+بقول الـC للـH2S .. للـC للسلفر مش ال .. مافيش عن
+
+344
+00:27:59,460 --> 00:28:06,580
+الـH2S يعني الـC للسلفر بتساوي الـH2S زاد الـHS-
+
+345
+00:28:06,580 --> 00:28:10,160
+زاد الـS صحيح هذا الكلام لكن هذه
+
+346
+00:28:13,660 --> 00:28:17,620
+كل السلفر، هذا كل السلفر، إيش كل السلفر بيساوي؟ ال
+
+347
+00:28:17,620 --> 00:28:22,800
+cadmium لإنه لما ال cadmium يتفكك، يتفكك لإيش؟ ال
+
+348
+00:28:22,800 --> 00:28:26,940
+cadmium of sulfide بتفكك لإيه؟ ل cadmium ولا سلفر،
+
+349
+00:28:26,940 --> 00:28:31,160
+فالسلفر كله اللي هو مجموعه هو عبارة عن ال cadmium،
+
+350
+00:28:31,160 --> 00:28:33,700
+هاي مجموعه صحيه؟ كلامك صحيه؟ بيساوي؟
+
+351
+00:28:37,540 --> 00:28:41,220
+طبعا، اه لكن المشكلة يعني هي الفكرة وين؟ الفكرة
+
+352
+00:28:41,220 --> 00:28:45,420
+انه هذا بساوي هذا، لكن هذا ايش ماله؟ اتجزة، اذا
+
+353
+00:28:45,420 --> 00:28:52,100
+هذا بساوي مجموع الأجزاء كلها، بس طيب يا شباب ناخد
+
+354
+00:28:52,100 --> 00:28:54,320
+كمان مثال يعني بسيط
+
+355
+00:29:04,010 --> 00:29:07,810
+هلأ على المثال ناخد بس ال charge balance equation
+
+356
+00:29:07,810 --> 00:29:16,010
+لهالاتزان اللى عندى ال ki بتفكر بنسبة 100% لكي بلس
+
+357
+00:29:16,010 --> 00:29:19,870
+وال I سالب ال aluminum iodide برضه بتفكك بنسبة 100
+
+358
+00:29:19,870 --> 00:29:25,390
+% لل aluminum تلاتة موجب و تلاتة I سالب ال H2O
+
+359
+00:29:25,390 --> 00:29:28,170
+بتفكك ل H بلس و Hydroxyl بقول بدي ال charge
+
+360
+00:29:28,170 --> 00:29:31,830
+balance فبقول فى شرسط من هيك الموجب على شجةوالسالب
+
+361
+00:29:31,830 --> 00:29:36,530
+على شجة فبقول السالب ال iodide تركيز الشحن السالب
+
+362
+00:29:36,530 --> 00:29:40,070
+على ال I تساوي تركيز ال I تركيز الشحن السالب على
+
+363
+00:29:40,070 --> 00:29:43,350
+ال hydroxide تساوي تركيز ال hydroxide لأن واحد لا
+
+364
+00:29:43,350 --> 00:29:46,890
+واحد تركيز الشحن الموجب على ال H تساوي تركيز ال H
+
+365
+00:29:46,890 --> 00:29:50,510
+تركيز الشحن الموجب على ال potassium تساوي تركيز ال
+
+366
+00:29:50,510 --> 00:29:56,490
+potassium تركيز الشحن الموجب على ال aluminum تلت
+
+367
+00:29:56,490 --> 00:30:02,540
+أمثال تركيز ال aluminum ماشي يا شبابماشي هذا
+
+368
+00:30:02,540 --> 00:30:06,700
+الكلام يبقى هاي معنى او هيك بنجيب ال charge
+
+369
+00:30:06,700 --> 00:30:12,860
+والmass balance equations
+
+370
+00:30:12,860 --> 00:30:19,960
+الان بدي اخد مثالين صغار بصفات كتير بيعبروا عن
+
+371
+00:30:19,960 --> 00:30:24,620
+يعني طريقة استخدام ال mass و ال charge balance
+
+372
+00:30:24,620 --> 00:30:28,100
+equations او ال systematic approach in general فحل
+
+373
+00:30:28,100 --> 00:30:32,210
+المسائلطريقة استخدامها كيف بدنا نحل مسائل باستخدام
+
+374
+00:30:32,210 --> 00:30:35,890
+ال systematic approach الغرب من هذا الكلام انه لو
+
+375
+00:30:35,890 --> 00:30:39,630
+اتصفحت اي كتاب كيمة حللية باستخدام ال systematic
+
+376
+00:30:39,630 --> 00:30:49,800
+approach لازم تعرف كيف يعني تقرأه كيف تفهمهتقدر
+
+377
+00:30:49,800 --> 00:30:54,880
+يعني وسائل الحل اللي بيستخدمها لكن احنا زي ما قلت
+
+378
+00:30:54,880 --> 00:30:58,600
+مش هنستخدم هذه الطريقة في حل المسائل تبعتنا حل
+
+379
+00:30:58,600 --> 00:31:02,140
+المسائل تبعتنا هتعتمد على الأمثلة اللي ذكرناها
+
+380
+00:31:02,140 --> 00:31:07,900
+الحصة الماضية و بداية الحصة الحالية فطبعا مطلوب
+
+381
+00:31:07,900 --> 00:31:11,120
+مننا نعرف لو قلتلك زي المثال التالي لو قلتلك use
+
+382
+00:31:11,120 --> 00:31:16,530
+the systematic approach to calculateThe
+
+383
+00:31:16,530 --> 00:31:21,010
+equilibrium concentrations of A and B in a 0.1
+
+384
+00:31:21,010 --> 00:31:22,490
+molar A-B solution
+
+385
+00:31:27,030 --> 00:31:30,690
+أما إحنا عادة في المسائل تبعتنا لأ مش في أثناء ال
+
+386
+00:31:30,690 --> 00:31:35,250
+course مش هنستخدم هذا النوع من أنواع الحل على أي
+
+387
+00:31:35,250 --> 00:31:40,050
+حال المثال اللي قدامي إيش بتقول طبعا مسألة مرت
+
+388
+00:31:40,050 --> 00:31:46,170
+معناها حلناها بالمفاهيم اللي احنا اتحدثنا عنها
+
+389
+00:31:46,170 --> 00:31:51,550
+سابقا ونشوف هل ال X قليلة جدا بالنسبة للنواتج أو
+
+390
+00:31:51,550 --> 00:31:54,670
+قليلة جدا بالنسبة للمتفاعلاتهذا كلام شفناه وحلينا
+
+391
+00:31:54,670 --> 00:31:57,830
+المثال هذا تحديدا، لكن الآن بدنا نحله باستخدام
+
+392
+00:31:57,830 --> 00:32:02,590
+systematic approach بس علشان يعني نستوعب كيف في ال
+
+393
+00:32:02,590 --> 00:32:07,130
+systematic approach بيفكروا فالمثال بيقول use the
+
+394
+00:32:07,130 --> 00:32:09,250
+systematic approach to calculate the equilibrium
+
+395
+00:32:09,250 --> 00:32:13,390
+concentrations of A وB and AB in a 0.1 molar AB
+
+396
+00:32:13,390 --> 00:32:18,830
+solution The equilibrium constant is 3 في 10 أسالب
+
+397
+00:32:18,830 --> 00:32:25,750
+6تلاتة في عشر أقل سالب ستة طبعا مافيش عندى مشكلة
+
+398
+00:32:25,750 --> 00:32:29,110
+ال equilibrium هيه اللى بيعطيه اللى هدا هو A وB
+
+399
+00:32:29,110 --> 00:32:34,190
+بيعطينا تفكك جزء A وA وB بقول أنا علشان أحلي
+
+400
+00:32:34,190 --> 00:32:38,370
+المسألة هدى و أجيب قيمة A وB وA وB أنا بحاجة لأ
+
+401
+00:32:38,370 --> 00:32:41,430
+يعني تلت مجهيل هي مجهول هي اتنين هي تلتة بحاجة لأ
+
+402
+00:32:41,430 --> 00:32:44,790
+كام معادلة أنا من ال equilibrium constant عندى
+
+403
+00:32:44,790 --> 00:32:49,940
+معادلةالـ Equilibrium constant يقول أنك معادلة كي
+
+404
+00:32:49,940 --> 00:32:55,000
+بتساوي a في b على ab تركيزات مش هيك؟ طيب معادلة
+
+405
+00:32:55,000 --> 00:32:59,220
+بتحلش المسألة أنا بدي تلت معادلات ال charge
+
+406
+00:32:59,220 --> 00:33:02,120
+balance equation بقدرش أجيب لإن مافيش عندي charges
+
+407
+00:33:03,670 --> 00:33:06,430
+فبدي أجيب mass balance equations بدي تنتين mass
+
+408
+00:33:06,430 --> 00:33:11,330
+balance equations قايل أشوف كيف بنجيبهم أول شيء
+
+409
+00:33:11,330 --> 00:33:17,970
+بنعمله بنقول والله يعني لو بدينا من ال a b بقول
+
+410
+00:33:17,970 --> 00:33:21,490
+والله يعني عندي في البداية كيف أساوي a في b على ال
+
+411
+00:33:21,490 --> 00:33:28,110
+a bكما يسمى تركيز الكل لـAB بيساوي الـAB اللى ما
+
+412
+00:33:28,110 --> 00:33:32,710
+اتفككش زي الـAB اللى اتفكك اللى اتفكك بيساوي يا A
+
+413
+00:33:32,710 --> 00:33:33,950
+يا B زي ما بدك تكتبها
+
+414
+00:33:42,610 --> 00:33:50,150
+بما ان ال equilibrium constant صغير فالتفكك يكون
+
+415
+00:33:50,150 --> 00:33:54,590
+قليل جدا يبقى a قليلة جدا يبقى aB أكبر كتير من a
+
+416
+00:33:56,340 --> 00:34:00,220
+الـ A و B يتساوى 0.1 هذه أول .. هذه mass balance
+
+417
+00:34:00,220 --> 00:34:03,940
+equation لكن استفدت منها لغاية الـ A فصار عند الـ
+
+418
+00:34:03,940 --> 00:34:08,200
+A و B بتساوى 0.1 يبقى الـ A و B ايش بتساوي 0.1 هذه
+
+419
+00:34:08,200 --> 00:34:11,760
+معادلة خلصت منها باشي بقول طب ال equilibrium اللي
+
+420
+00:34:11,760 --> 00:34:16,200
+عندي انا لو لاحظنا A و B لما اتفكك بتفكك لإيش؟
+
+421
+00:34:16,200 --> 00:34:20,560
+بنفعل A ماتسويش ال B .. اذا ال A تساوي ال B هذه
+
+422
+00:34:20,560 --> 00:34:24,260
+mass balance equation برضهلأنه لما ال a بيتفكك
+
+423
+00:34:24,260 --> 00:34:28,600
+بيعطينا a و b لازم شرط ال a تساوي ال b لأن ال a
+
+424
+00:34:28,600 --> 00:34:35,060
+بيتفكك ل a و لb فلازم ال a تساوي ال b فهذه برضه
+
+425
+00:34:35,060 --> 00:34:39,980
+mass balance equation تانية a بتساوي ال b فيعني
+
+426
+00:34:39,980 --> 00:34:42,880
+بتساوي ال a مثلا فتصير a تربيع على ال point one
+
+427
+00:34:42,880 --> 00:34:46,060
+بتساوي ال equilibrium constant إذا ال a بتساوي
+
+428
+00:34:46,060 --> 00:34:50,580
+خمسة و نصف عشرة أساليب أربعةطبعا هذا لا يعفينا انه
+
+429
+00:34:50,580 --> 00:34:54,040
+لازم نجيب relative error لانه انا لغيت ال a
+
+430
+00:34:54,040 --> 00:34:58,860
+بالنسبة لل a b فبتنقسم تركيز ال a على ال a b في
+
+431
+00:34:58,860 --> 00:35:01,380
+100 من 100 نفس الكلام بتطلع انه point five five
+
+432
+00:35:01,380 --> 00:35:05,960
+percent نفس الرقم اللى طلع انه سابقا اذا ال a
+
+433
+00:35:05,960 --> 00:35:09,180
+بتساوي ال b بتساوي خمسة و نصف عشرة اقصى لباربعة
+
+434
+00:35:09,180 --> 00:35:12,860
+لان هي ال a خمسة و نصف عشرة اقصى لباربعة و ال a ب
+
+435
+00:35:12,860 --> 00:35:17,880
+point one ناقص خمسة و نصف عشرة اقصى لباربعة معناته
+
+436
+00:35:19,650 --> 00:35:23,750
+point one لأنه بتنترحش الخمسة و نصف عشر أو سالب
+
+437
+00:35:23,750 --> 00:35:31,570
+أربعة من ال point one فهذه طريقة الحل باستخدام ال
+
+438
+00:35:31,570 --> 00:35:39,830
+systematic approach ارجع حاضر هاي ده رجعته بالفعل
+
+439
+00:35:39,830 --> 00:35:46,770
+مشانة مشكلة زي ما بدك زي ما بدك مثلا برضه بتقول أن
+
+440
+00:35:46,770 --> 00:35:51,520
+ال A B أكبر كتير من ال Bهي هي لأنه بتفكك ل A و ل B
+
+441
+00:35:51,520 --> 00:35:58,380
+طيب ناخد هالمثال هذا برضه طوح علناه لكن بدنا نحاول
+
+442
+00:35:58,380 --> 00:36:02,060
+نحله باستخدام ال systematic approach ونقول كيف
+
+443
+00:36:02,060 --> 00:36:05,960
+بنحله ما استخدماش ال Xات زي ما انتوا شايفين بقول
+
+444
+00:36:05,960 --> 00:36:09,920
+using the systematic approach calculate the
+
+445
+00:36:09,920 --> 00:36:16,320
+equilibrium concentrations of A وB and AB in a 0.1
+
+446
+00:36:16,320 --> 00:36:21,340
+molar ABالـ Equilibrium constant تلاتة في عشرة أقل
+
+447
+00:36:21,340 --> 00:36:26,560
+سالب ستة بيقول in the presence of point two molar
+
+448
+00:36:26,560 --> 00:36:33,720
+Mb متل يعني بي Mb strong electrolyte ال Mb strong
+
+449
+00:36:33,720 --> 00:36:37,820
+electrolyte where the equilibrium below takes
+
+450
+00:36:37,820 --> 00:36:41,180
+place هذه ال equilibrium اللي عندك ال A بيتفكر
+
+451
+00:36:41,180 --> 00:36:46,380
+جزءيا ل A plus و B minus ال
+
+452
+00:36:46,380 --> 00:36:55,210
+Mbبتتفكك كليا ل M plus و B minus ايش بدي اعمل؟ لو
+
+453
+00:36:55,210 --> 00:37:00,390
+لاحظته معايا برضه، انا في عند هاي مجهول، مجهولين،
+
+454
+00:37:00,390 --> 00:37:07,410
+تلاتة، يمكن لو حبينا نقول أربعة، ال M plus، كويس،
+
+455
+00:37:07,410 --> 00:37:12,050
+فاندي أربعة معادلات تقريبا يعني، مفتاح الحل دائما
+
+456
+00:37:12,050 --> 00:37:15,350
+هو equilibrium constant، بشوف منه إيش اللي بده،
+
+457
+00:37:15,350 --> 00:37:16,830
+إيش المعادلة اللي لازماني
+
+458
+00:37:21,980 --> 00:37:26,340
+تركيز الكل لـ B بي لها مصدرين
+
+459
+00:37:29,200 --> 00:37:33,940
+اللي هي 2 من 10 اللي جاي من تفكك ال MB ال MB 2 من
+
+460
+00:37:33,940 --> 00:37:37,800
+10 هذا بيعطينا على طول 2 من 10 B لأنه بتفكك بنسبة
+
+461
+00:37:37,800 --> 00:37:43,780
+100% زائد ال B اللي جاي من تفكك ال AB يبقى هيها C
+
+462
+00:37:43,780 --> 00:37:47,460
+لل B minus يعبر عن ال B minus from the strong
+
+463
+00:37:47,460 --> 00:37:52,900
+electrolyte زائد ال B minus اللي جاي من تفكك ال AB
+
+464
+00:37:52,900 --> 00:37:57,140
+هذه كمية قليلة ال B minus اللي جاي من تفكك ال AB
+
+465
+00:37:57,140 --> 00:38:01,350
+مظبوط ولا لأ؟طيب بقول ال b اللي جاية من تفكك ال a
+
+466
+00:38:01,350 --> 00:38:04,870
+b بتساوي ال a plus بديش كل مرة أقول b اللي جاية من
+
+467
+00:38:04,870 --> 00:38:09,030
+تفكك ال a b لأنه في فرق من .. في عند التنتين b
+
+468
+00:38:09,030 --> 00:38:11,190
+واحدة جاية من ال a b و واحدة من ال strong
+
+469
+00:38:11,190 --> 00:38:14,850
+electrolyte بختلفوا عن بعض فأنا مش كل مرة بدي أقول
+
+470
+00:38:14,850 --> 00:38:19,050
+b سالب اللي جاية من تفكك ال a b فقولت والله ال b
+
+471
+00:38:19,050 --> 00:38:21,930
+سالب اللي جاية من تفكك ال a b هي عبارة عن ال a
+
+472
+00:38:21,930 --> 00:38:28,080
+plusإذا الـ C للـ B- بتساوي الـ B- من الـ Strong
+
+473
+00:38:28,080 --> 00:38:34,980
+Electrolyte زائد الـ A+, اللي أعوضنا فيها عن الـ B
+
+474
+00:38:34,980 --> 00:38:39,740
+- اللي جاء من تفكك الـ AB طبعا كمان مرة بنقول كمية
+
+475
+00:38:39,740 --> 00:38:42,220
+الـ B- اللي جاء من الـ Strong Electrolyte اتنين من
+
+476
+00:38:42,220 --> 00:38:45,710
+عشرةوكمية ال a plus اللى جاية من ال a b كمية لات
+
+477
+00:38:45,710 --> 00:38:49,190
+كانت تتجر لأنه ال equilibrium constant صغير كتير
+
+478
+00:38:49,190 --> 00:38:54,590
+علشان هيك بتكون ال b minus اللى من ال strong اللى
+
+479
+00:38:54,590 --> 00:38:58,130
+أكبر كتير من ال a plus إذا هى بتساوي ال cb minus
+
+480
+00:38:58,130 --> 00:39:03,530
+يعني ال b minus بدها تساوي point to molarيبقى الـP
+
+481
+00:39:03,530 --> 00:39:07,830
+- بتساوي 0.2 مولار هذا بداية بنفس الطريقة اللي
+
+482
+00:39:07,830 --> 00:39:10,690
+عملناها المرة الماضية بنقول الـC للـAB التركيز
+
+483
+00:39:10,690 --> 00:39:16,810
+الكل للـAB بدي ساوي الـAB زائد الـA+, الـAB زائد
+
+484
+00:39:16,810 --> 00:39:20,950
+الـA+, لكن ال equilibrium constant كمان صغير كتير
+
+485
+00:39:20,950 --> 00:39:26,890
+فالـAB أكبر كتير من الـA+, إذا الـC للـAB اللي هي
+
+486
+00:39:26,890 --> 00:39:31,360
+واحد من عشرة تساوي الـA الـABالتركيز ال
+
+487
+00:39:31,360 --> 00:39:38,020
+equilibrium هيك بنكون احنا قادرين الآنعلى انه
+
+488
+00:39:38,020 --> 00:39:42,860
+انعوض بنقول k بتساوي a plus في ال b minus على ال a
+
+489
+00:39:42,860 --> 00:39:46,420
+b ال a plus ايه ان دي مجهولة ال b minus طلعناها
+
+490
+00:39:46,420 --> 00:39:51,160
+قبل شوية بتساوي point two ال a b بتساوي point one
+
+491
+00:39:51,160 --> 00:39:54,540
+برضه طلعناها قبل شوية اذا ال a plus بتساوي واحد و
+
+492
+00:39:54,540 --> 00:39:58,680
+نص في عشرة قص سالب ستة طبعا نفس الرقم اللي كنا
+
+493
+00:39:58,680 --> 00:40:07,180
+طلعنا سابقالازم أحقق فرضيتي أتأكد أنه شغلي سليم
+
+494
+00:40:07,180 --> 00:40:17,840
+فبدى أجسم قيمة ال A plus بدي أقسمها على واحد من
+
+495
+00:40:17,840 --> 00:40:21,600
+عشرةفي مية من مية فبيطلع عند واحد و نص في عشر أقل
+
+496
+00:40:21,600 --> 00:40:25,700
+سالب تلاتة في المية طبعا كمية قليلة جدا لا تكاد
+
+497
+00:40:25,700 --> 00:40:29,280
+تذكر يبجر relative error قليل كتير مع أن الكلام ال
+
+498
+00:40:29,280 --> 00:40:32,820
+assumption valid وال a plus بتساوي واحد و نص في
+
+499
+00:40:32,820 --> 00:40:38,780
+عشر أقل سالب ستة ال b point two plusبنكتب الـ 1
+
+500
+00:40:38,780 --> 00:40:44,480
+.5×10⁻6 لأنها كمية قليلة جدا تعتبر و نفس الكلام
+
+501
+00:40:44,480 --> 00:40:50,520
+بنتبهش ال 1.5×10⁻7.1 يعني ال a بيكون point one ال
+
+502
+00:40:50,520 --> 00:40:56,900
+b point two وال a plus 1.5×10⁻6
+
+503
+00:40:57,320 --> 00:41:01,400
+هذه هي الطريقة اللى بنستخدمها في حل المسائل في
+
+504
+00:41:01,400 --> 00:41:06,980
+حالة الاستخدام لل systemic approach لكن للأمانة
+
+505
+00:41:06,980 --> 00:41:11,240
+الطريقة تبدو يعني سهلة كتير و مباشرة برضه يعني
+
+506
+00:41:11,240 --> 00:41:18,110
+مجهود لكن المشكلة إذا كان في عنا معادلات كتيريعني
+
+507
+00:41:18,110 --> 00:41:21,650
+مثلا لو طلعنا على معادلات الأمونيا قبل شوية كانوا
+
+508
+00:41:21,650 --> 00:41:24,910
+تقريبا أربع معادلات أو خمسة مثلا يعني و كلهم
+
+509
+00:41:24,910 --> 00:41:29,390
+مليانين مجاهيل ال equilibrium مرات بيكون فيها كمية
+
+510
+00:41:29,390 --> 00:41:34,310
+كبيرة مثلا خمس ست سبعة معادلاتوكل معادلة فيها
+
+511
+00:41:34,310 --> 00:41:38,570
+مجموعة من المجاهيل، معنى الكلام، إذا ماكانش فيه
+
+512
+00:41:38,570 --> 00:41:41,930
+عندنا فكرة كويسة عن الكيميا أو فكرة كويسة عن ال
+
+513
+00:41:41,930 --> 00:41:48,110
+equilibrium constants وخطوة خطوة يعني نقدر نفهم
+
+514
+00:41:48,110 --> 00:41:51,130
+إيش اللي نلغي وإيش اللي مانلغيهوش، يعني مثلا لو
+
+515
+00:41:51,130 --> 00:41:54,850
+طلعنا على ال charge balanceوهذه معادلة ال charge
+
+516
+00:41:54,850 --> 00:41:58,550
+balance في حالة ال ammonia ال silver by ammonia
+
+517
+00:41:58,550 --> 00:42:04,590
+complex اللي أخدناه لجينا كوم حاجات ال H plus و ال
+
+518
+00:42:04,590 --> 00:42:08,330
+silver by ammonia و ال silver ammonia و ال ammonia
+
+519
+00:42:08,330 --> 00:42:14,650
+كل هدول مع بعض كانوا بيساووا السالم طب أنا في
+
+520
+00:42:14,650 --> 00:42:20,010
+النهاية بدي أحاول أنه أتخلص من من مجموعة منهم بحيث
+
+521
+00:42:20,010 --> 00:42:24,360
+أنه أخلي أيون معين بيساوي أيون أخرما بديش يكون
+
+522
+00:42:24,360 --> 00:42:27,340
+اندهان أربعة خمسة على طرف المعادل الأيمن و أربعة
+
+523
+00:42:27,340 --> 00:42:30,780
+خمسة على طرف المعادل الأيصر معنى الكلام أنه في
+
+524
+00:42:30,780 --> 00:42:36,420
+الحقيقة الشغل باستخدام ال systematic approach قد
+
+525
+00:42:36,420 --> 00:42:40,580
+يكون مزعج لبعض الناس إلا إذا كان في عندك معلومات
+
+526
+00:42:40,580 --> 00:42:44,160
+جيدة في الكيميا ساعتها راح تستمتع و أنت بتشتغل
+
+527
+00:42:44,160 --> 00:42:48,360
+systematic approach مش بس راح تحل مسائل يعني لمجرد
+
+528
+00:42:48,360 --> 00:42:53,040
+الحل لأنك راح تستمتع و أنت بتحل المسائللكن أنا
+
+529
+00:42:53,040 --> 00:42:58,840
+وجدت أنه الأفضل لنا أن نحل بالطريقة اللي ذكرناها
+
+530
+00:42:58,840 --> 00:43:04,120
+سابقا مع أنه احنا في الجامعة كنا في .. من بداية
+
+531
+00:43:04,120 --> 00:43:10,120
+الجامعة تقريبا لغاية الخمسة وتسعينو احنا بنستخدم
+
+532
+00:43:10,120 --> 00:43:13,400
+ال systematic approach لكن تقريبا يعني يمكن بعد ال
+
+533
+00:43:13,400 --> 00:43:20,500
+95 بدأنا باستخدام الكتاب الجديد تبعنا اللي مستخدمش
+
+534
+00:43:20,500 --> 00:43:23,200
+ال systematic approach و انا لجيته و الطلاب ايضا
+
+535
+00:43:23,200 --> 00:43:30,220
+لجوه اسهل كتير بالنسبة للاستيعاب و انه نحصل درجات
+
+536
+00:43:30,220 --> 00:43:33,820
+بنوجف ان شاء الله هان اليوم اذا كان في اي سؤال
+
+537
+00:43:33,820 --> 00:43:40,240
+ممكن نجاوب عليهطيب معنا الكلام إذا الله راضي الحصة
+
+538
+00:43:40,240 --> 00:43:41,340
+الجاية بتشوفكم
+
diff --git a/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/zAo8HpYFglk.srt b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/zAo8HpYFglk.srt
new file mode 100644
index 0000000000000000000000000000000000000000..fa62b06d19bc0aecc727634875416b1dcb93626e
--- /dev/null
+++ b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/zAo8HpYFglk.srt
@@ -0,0 +1,1791 @@
+1
+00:00:21,900 --> 00:00:25,720
+بسم الله الرحمن الرحيم الحصة الماضية يا شباب بدنا
+
+2
+00:00:25,720 --> 00:00:30,960
+نتكلم عن الـ acid-base titrations واتحدثنا
+
+3
+00:00:30,960 --> 00:00:34,160
+باستفادة عن الـ indicators وشوفنا أنه ليس أي
+
+4
+00:00:34,160 --> 00:00:38,700
+indicator يمكن استخدامه لأي acid-base titration
+
+5
+00:00:38,700 --> 00:00:42,280
+لأ، في عندنا شروط لاختيار الـ indicator، من أهم هذه
+
+6
+00:00:42,280 --> 00:00:48,100
+الشروط أن قيمة pK للإنديكاتور لازم تكون بين و
+
+7
+00:00:48,100 --> 00:00:51,740
+بين قيمة pH at equivalence point، نوع من الموائمة
+
+8
+00:00:51,740 --> 00:00:58,000
+أو الموائمة، لازم تكون قيمة pH at equivalence point
+
+9
+00:00:58,000 --> 00:01:02,600
+تقريباً بتساوي قيمة pK للإنديكاتور، لا تختلف عنه كثيراً
+
+10
+00:01:03,040 --> 00:01:06,980
+اليوم نحاول نتحدث أكثر عن الـ acid-base titrations
+
+11
+00:01:06,980 --> 00:01:15,020
+فبنبدأ بشكل أساسي بالحديث عن كيف تتم عملية titration
+
+12
+00:01:15,020 --> 00:01:20,760
+بالرجوع لمعلومات كنا درسناها سابقاً في بداية ما
+
+13
+00:01:20,760 --> 00:01:28,650
+اتحدثنا عن ماذا تعني volumetric titrations أو ما هي
+
+14
+00:01:28,650 --> 00:01:32,430
+مواصفات التفاعل الذي يمكن اعتباره titration
+
+15
+00:01:32,430 --> 00:01:36,170
+reaction؟ فإحنا كنا نقول أن التفاعل يجب أن يكون
+
+16
+00:01:36,170 --> 00:01:39,850
+كمّياً، أحد شروطه أنه يكون كمياً، معناه
+
+17
+00:01:39,850 --> 00:01:44,390
+أنه يتم بنسبة 100%، هذا الكلام أو هذه الجملة مهمة جداً
+
+18
+00:01:44,390 --> 00:01:46,510
+لِكي نقدر نتخيل معاً
+
+19
+00:01:49,800 --> 00:01:54,820
+كيف يمكن حل مسائل الـ titrations، فبقول على سبيل
+
+20
+00:01:54,820 --> 00:01:59,400
+المثال: لو في عندي حمض يتفاعل مع قاعدة، طبعاً سيعطينا
+
+21
+00:01:59,400 --> 00:02:03,300
+الـ conjugate، ممكن نسميه ملح، وماء، سيعطي الـ
+
+22
+00:02:03,300 --> 00:02:09,640
+conjugate وماء، فعلى سبيل المثال لما يكون الحمض
+
+23
+00:02:09,640 --> 00:02:13,900
+عندي كميته أكبر من القاعدة، التفاعل كما نعرف
+
+24
+00:02:13,900 --> 00:02:18,460
+يحدث كمّياً، سهم في اتجاه واحد، فبقول
+
+25
+00:02:18,460 --> 00:02:23,700
+على سبيل المثال: لو عندي x millimole من الحمض و y
+
+26
+00:02:23,700 --> 00:02:29,780
+millimole من القاعدة، فبقول أنه إذا كان الحمض
+
+27
+00:02:29,780 --> 00:02:33,260
+أكثر من القاعدة، فـ millimole من الحمض المتبقي
+
+28
+00:02:33,260 --> 00:02:40,380
+ستكون x - y، القاعدة ستختفي تماماً لأنها تفاعلت
+
+29
+00:02:40,380 --> 00:02:44,680
+كلياً مع الحمض، والحمض أكثر من القاعدة، سيُنتج
+
+30
+00:02:44,680 --> 00:02:50,830
+كمية من الملح مقدارها y، أو كمية من الـ conjugate
+
+31
+00:02:50,830 --> 00:02:57,030
+مقدارها y millimole، من الطبيعي أنني بما أنني أتعامل
+
+32
+00:02:57,030 --> 00:03:01,430
+مع أحجام، فبقول أضفت حجماً معيناً من القاعدة على حجم
+
+33
+00:03:01,430 --> 00:03:05,710
+معين من الحمض، إذا تركيز الحمض المتبقي x
+
+34
+00:03:05,710 --> 00:03:10,190
+- y على الحجم الكلي، وأيضاً تركيز الـ
+
+35
+00:03:10,190 --> 00:03:15,430
+conjugate y على الحجم الكلي، هذا الكلام يحدث في
+
+36
+00:03:15,430 --> 00:03:18,030
+الـ titration، ويحدث أيضاً شيء آخر في مرحلة
+
+37
+00:03:18,030 --> 00:03:22,370
+أخرى، بقول: when millimole base is larger than
+
+38
+00:03:22,370 --> 00:03:28,410
+millimole acid، مثلاً بعد نقطة التكافؤ، فبقول على
+
+39
+00:03:28,410 --> 00:03:33,730
+سبيل المثال: الـ y أكبر من الـ x، فعندما يتفاعل، أضيف
+
+40
+00:03:33,730 --> 00:03:38,850
+كمية كبيرة من القاعدة على الحمض، فالحمض يختفي،
+
+41
+00:03:39,910 --> 00:03:44,130
+القاعدة بدلاً من أن تكون y، ستكون y - x millimole من الـ
+
+42
+00:03:44,130 --> 00:03:49,070
+base، الـ conjugate هو عبارة عن x، لأن الحمض كله
+
+43
+00:03:49,070 --> 00:03:55,390
+تحول إلى الـ conjugate، فهو عبارة عن x، الحالتين في كل
+
+44
+00:03:55,390 --> 00:03:59,710
+Titration، في بناء أي Titration curve، لازماً يكونوا
+
+45
+00:03:59,710 --> 00:04:03,730
+موجودين، الحالتين في بناء أي Titration curve لازماً
+
+46
+00:04:03,730 --> 00:04:07,510
+يكونوا موجودين، الآن أريد أن أطلع على بعض
+
+47
+00:04:07,510 --> 00:04:13,460
+الأمثلة وأرى كيف نشتغل أو كيف نبني الـ
+
+48
+00:04:13,460 --> 00:04:18,280
+titration curve، أو بمعنى آخر: كيف أستطيع عمل حسابات
+
+49
+00:04:18,280 --> 00:04:25,680
+لقيمة pH بعد إضافة كميات معلومة من حمض على قاعدة أو
+
+50
+00:04:25,680 --> 00:04:30,300
+من قاعدة على حمض، وأريد أن أبدأ بحمض قوي وقاعدة
+
+51
+00:04:30,300 --> 00:04:35,750
+قوية، فلو اطلعنا على المثال التالي، المثال يقول
+
+52
+00:04:35,750 --> 00:04:41,570
+calculate the pH of a 50 ml solution of 0.1 molar
+
+53
+00:04:41,570 --> 00:04:51,430
+HCl، يبقى في عندي 50 ml solution من HCl، هذه 50 ml
+
+54
+00:04:51,430 --> 00:05:00,730
+HCl تركيزه 0.1 molar، بقول: after addition of 0, 20,
+
+55
+00:05:00,910 --> 00:05:05,310
+40, 50, 80 و 100 ml of 0.1 molar sodium
+
+56
+00:05:05,310 --> 00:05:13,490
+hydroxide، يعني في بيوريت فيها هيدروكسيد الصوديوم
+
+57
+00:05:13,490 --> 00:05:17,790
+وأنا أضيف شيئاً فشيئاً من هذه البيوريت أو من هذا
+
+58
+00:05:17,790 --> 00:05:21,470
+المحلول هيدروكسيد الصوديوم على محلول HCl
+
+59
+00:05:21,470 --> 00:05:28,870
+ومطلوب مني أن أحسب قيمة pH في الفلاسك الذي عندي
+
+60
+00:05:28,870 --> 00:05:36,870
+بقول: جيد جداً أن أستطيع بناء الـ curve أو الـ
+
+61
+00:05:36,870 --> 00:05:42,930
+titration curve، هو عبارة عن علاقة بين حجم المادة
+
+62
+00:05:42,930 --> 00:05:47,030
+المعايرة (الـ titrant) الذي هو في هذه الحالة هيدروكسيد الصوديوم و
+
+63
+00:05:47,030 --> 00:05:53,910
+قيمة pH، فبقول في البداية، أي titration curve الذي
+
+64
+00:05:53,910 --> 00:06:02,820
+أبنيه، يجب أن أكون قادراً على حساب قيمة pH في أربع مواضع
+
+65
+00:06:02,820 --> 00:06:09,520
+أريد حساب قيمة pH قبل إضافة أي شيء من الـ titrant، يعني
+
+66
+00:06:09,520 --> 00:06:14,020
+after addition of zero ml من الـ titrant، بعدين أريد
+
+67
+00:06:14,020 --> 00:06:21,760
+أن أعرف أحسب قيمة pH قبل نقطة النهاية أو التكافؤ، هي
+
+68
+00:06:21,760 --> 00:06:24,900
+مرحلة ثانية، المرحلة الثالثة أو النوع الثالث من
+
+69
+00:06:24,900 --> 00:06:29,760
+الحسابات، أريد أن أحسب قيمة pH بالضبط عند نقطة التكافؤ
+
+70
+00:06:31,450 --> 00:06:36,910
+المرحلة الأخيرة، أحسب قيمة pH بعد نقطة التكافؤ، عند
+
+71
+00:06:36,910 --> 00:06:41,590
+إضافة titrant زائد، كمية من الـ titrant أكثر من
+
+72
+00:06:41,590 --> 00:06:46,980
+كمية المادة محلّلة (analyte)، فلو اطلعنا على المثال الذي عندي،
+
+73
+00:06:46,980 --> 00:06:51,120
+بقول عندي خمسون مل HCl تركيزه point one molar، أريد
+
+74
+00:06:51,120 --> 00:06:55,380
+أن أضع عليه هيدروكسيد الصوديوم، ماشي، فأريد أن أحسب قيمة pH
+
+75
+00:06:55,380 --> 00:06:59,140
+after addition of، في البداية zero ml، فبقول والله
+
+76
+00:06:59,140 --> 00:07:02,840
+after addition of zero ml Sodium Hydroxide، كيف
+
+77
+00:07:02,840 --> 00:07:07,470
+أريد أن أحسب قيمة pH؟ بقول ليس عندي إلا HCl، لم أضف
+
+78
+00:07:07,470 --> 00:07:11,090
+عليه بعد أي هيدروكسيد الصوديوم، يبقى ما هي قيمة H+
+
+79
+00:07:11,090 --> 00:07:17,170
+لهذا المحلول؟ هي نفس تركيز HCl، لأنه HCl حمض
+
+80
+00:07:17,170 --> 00:07:23,430
+قوي، يتفكك كلياً، إذا قيمة H+ تساوي point one، الذي
+
+81
+00:07:23,430 --> 00:07:27,870
+هو تركيز الحمض، معناه أن قيمة pH تساوي واحد، سهل
+
+82
+00:07:27,870 --> 00:07:34,840
+جداً، قيمة pH تساوي واحد، سهل جداً، طيب يبقى ممكن أضع
+
+83
+00:07:34,840 --> 00:07:41,000
+هنا هذه الـ zero ml وهنا قيمة pH تساوي واحد، بعد
+
+84
+00:07:41,000 --> 00:07:44,140
+ما أضفت zero ml من هيدروكسيد الصوديوم، أو بمعنى
+
+85
+00:07:44,140 --> 00:07:49,100
+آخر: لم أضف أي هيدروكسيد صوديوم، طيب الآن نأتي
+
+86
+00:07:49,100 --> 00:07:52,480
+نضيف كمية من هيدروكسيد الصوديوم، وليكن مثلاً
+
+87
+00:07:52,480 --> 00:07:58,220
+عشرون مل من هيدروكسيد الصوديوم، بقول: millimole H+
+
+88
+00:07:58,220 --> 00:08:01,420
+المتبقية، إذا أضفت هيدروكسيد الصوديوم عشرين millimole،
+
+89
+00:08:01,420 --> 00:08:06,100
+فـ millimole هيدروكسيد الصوديوم المتبقية تساوي millimole
+
+90
+00:08:06,100 --> 00:08:10,440
+من HCl ناقص millimole من هيدروكسيد الصوديوم
+
+91
+00:08:10,440 --> 00:08:15,480
+الذي أضفته، عندي خمسون مل من point one
+
+92
+00:08:15,480 --> 00:08:19,300
+molar HCl، أضفت عليه عشرون مل من point one molar
+
+93
+00:08:19,300 --> 00:08:23,660
+هيدروكسيد الصوديوم، إذا خمسة ناقص اثنين يساوي ثلاثة
+
+94
+00:08:23,660 --> 00:08:30,080
+يعني باختصار، عندي ثلاثة millimole HCl، الآن قيمة H+
+
+95
+00:08:30,080 --> 00:08:34,100
+ستساوي ثلاثة على الحجم الكلي، تساوي point oh
+
+96
+00:08:34,100 --> 00:08:38,120
+four three molar، يعني قيمة pH one point three four
+
+97
+00:08:38,120 --> 00:08:43,400
+معناه كلام: عند إضافة عشرين مل كانت قيمة pH one point
+
+98
+00:08:43,400 --> 00:08:48,730
+three four، طبعاً يمكنني عمل هذا الكلام مباشرة
+
+99
+00:08:48,730 --> 00:08:53,150
+أقول: والله هي HCl + هيدروكسيد الصوديوم
+
+100
+00:08:53,150 --> 00:08:59,750
+تعطينا NaCl + H2O، عندي خمسة، عندي اثنين، إذا بضلّ ثلاثة،
+
+101
+00:08:59,750 --> 00:09:04,800
+أصبح اثنين، أصبح صفر، مباشرةً عندي
+
+102
+00:09:04,800 --> 00:09:08,340
+خمسة millimole HCl، point one في خمسين، أضفت اثنين
+
+103
+00:09:08,340 --> 00:09:12,180
+millimole هيدروكسيد الصوديوم، طبعاً هذان الاثنان يتفاعلان مع
+
+104
+00:09:12,180 --> 00:09:17,460
+اثنين، يتبقى ثلاثة، إذاً HCl ثلاثة على سبعين، انتهى
+
+105
+00:09:17,460 --> 00:09:23,600
+يبقى قيمة H+ ثلاثة على سبعين، نحسبها
+
+106
+00:09:23,600 --> 00:09:25,500
+نحسبها، لكن عادةً أنتَ
+
+107
+00:09:29,600 --> 00:09:34,380
+هي الأحماض والقواعد، التفاعلات التي تتم فيها
+
+108
+00:09:34,380 --> 00:09:39,420
+بنسبة واحد لواحد، أجل، لماذا؟ لأنه عندنا دائماً واحد منهم
+
+109
+00:09:39,420 --> 00:09:44,580
+قوي، ويتفاعل H+ واحد أو OH- واحد، فعندك
+
+110
+00:09:44,580 --> 00:09:48,260
+التفاعل دائماً واحد لواحد، لماذا؟ لأن التفاعل يتم
+
+111
+00:09:48,260 --> 00:09:52,500
+خطوة بخطوة (stepwise)، يتم مرة واحدة، يعني مثلاً لو عندنا
+
+112
+00:09:52,500 --> 00:10:00,020
+كربونات وأريد أن أضع عليها HCl، طبعاً اثنان HCl مع
+
+113
+00:10:00,020 --> 00:10:03,040
+الكربونات يعطينا حمض كربونيك، لكن هذا يتم
+
+114
+00:10:03,040 --> 00:10:07,300
+في خطوتين، الأول، نقول: H+ +
+
+115
+00:10:07,300 --> 00:10:09,880
+carbonate يعطينا bicarbonate
+
+116
+00:10:16,900 --> 00:10:21,440
+بعدين bicarbonate تتحول لحمض كربونيك أيضاً بإضافة H+
+
+117
+00:10:21,440 --> 00:10:24,800
+واحدة، لكن في تفاعلات، النسبة ليست واحد لو
+
+118
+00:10:24,800 --> 00:10:29,260
+واحد صحيح، لكن هذا الكلام يتم عادةً في الـ
+
+119
+00:10:29,260 --> 00:10:33,380
+electrochemical reactions، لأن هذا الكلام يعتمد على
+
+120
+00:10:33,380 --> 00:10:38,060
+عدد الإلكترونات بشكل أساسي، فنراه في... لما نتكلم
+
+121
+00:10:38,060 --> 00:10:43,340
+عن آخر جزء سنأخذه، الـ electrochemistry، يعني أو الـ
+
+122
+00:10:43,340 --> 00:10:46,640
+redox titrations، فنراه في المستقبل، ونرى كيف
+
+123
+00:10:46,640 --> 00:10:49,760
+نتعامل معه، لكن هذه الحسابات بسيطة جداً جداً
+
+124
+00:10:49,760 --> 00:10:54,140
+طيب لو أتينا أضفنا أربعين مل من هيدروكسيد الصوديوم،
+
+125
+00:10:54,140 --> 00:10:59,410
+بقول: أسهل من هكذا، لو أردت عملها مباشرةً،
+
+126
+00:10:59,410 --> 00:11:06,910
+بقول والله عندي خمسة، أضفت عليه أربعة، لأنه
+
+127
+00:11:06,910 --> 00:11:10,770
+أربعين مل، يعني أربعين في واحد من عشرة يعني أربعة
+
+128
+00:11:10,770 --> 00:11:15,030
+إذاً يتبقى هنا واحد، هنا صفر، يبقى HCl واحد على
+
+129
+00:11:15,030 --> 00:11:20,310
+تسعين، ليس ثمانين، تسعين يا شباب، قيمة pH تُحسب على طول
+
+130
+00:11:21,670 --> 00:11:25,710
+تعطينا واحد وتسعة من عشرة، هي عند أربعين مل واحد
+
+131
+00:11:25,710 --> 00:11:32,370
+وتسعة من عشرة، ماشي وهكذا، نفس طريقة الحسابات قبل
+
+132
+00:11:32,370 --> 00:11:37,490
+نقطة النهاية، لو أردت إضافة مثلاً خمسة، عشرة، خمسة وعشرين،
+
+133
+00:11:37,490 --> 00:11:41,530
+ثلاثين، خمسة وثلاثين، أربعين، خمسة وأربعين، نفس طريقة الحسابات، طيب نأتي
+
+134
+00:11:41,530 --> 00:11:45,380
+الآن نضيف خمسين مل من هيدروكسيد الصوديوم، بقول
+
+135
+00:11:45,380 --> 00:11:49,980
+والله لو عملت بنفس الطريقة، أقول: هذا خمسة
+
+136
+00:11:49,980 --> 00:11:54,210
+millimole، وأضفت عليه خمسة، إذاً هذا صفر، وهذا صفر، أصبح
+
+137
+00:11:54,210 --> 00:11:58,350
+ماذا أريد أن أحسب؟ لا شيء، فأنا أقول: this is
+
+138
+00:11:58,350 --> 00:12:01,770
+the equivalence point، هذه هي نقطة التكافؤ، نفس
+
+139
+00:12:06,390 --> 00:12:09,170
+الكلام، بقول: millimole H+ المتبقية point one في خمسين
+
+140
+00:12:09,170 --> 00:12:12,990
+ناقص point one في خمسين تساوي صفر، معناه: this
+
+141
+00:12:12,990 --> 00:12:15,250
+is the equivalence point، طيب كيف أحسب قيمة H+؟
+
+142
+00:12:15,250 --> 00:12:19,580
+ليس لدينا إلا كلوريد الصوديوم
+
+143
+00:12:19,580 --> 00:12:23,180
+وهذا ليس له علاقة طبعاً، خمسة millimole لكن ليس له علاقة
+
+144
+00:12:23,180 --> 00:12:28,960
+لأنه ملح حمض قوي وقاعدة قوية (salt of strong acid and strong base)
+
+145
+00:12:28,960 --> 00:12:32,280
+جاء من حمض قوي وقاعدة قوية، لا يتفاعلان مع الماء
+
+146
+00:12:32,280 --> 00:12:35,780
+لا Na+ يتفاعل مع الماء، ولا Cl-
+
+147
+00:12:35,780 --> 00:12:39,420
+يتفاعل مع الماء، إذاً من أين أحسب قيمة H+؟ من
+
+148
+00:12:39,420 --> 00:12:45,720
+تفكك الماء، يبقى قيمة Kw ستساوي
+
+149
+00:12:45,720 --> 00:12:49,520
+x²، أو يعني قيمة H+ ستساوي قيمة hydroxide
+
+150
+00:12:49,520 --> 00:12:53,260
+بـ 10⁻⁷، يعني قيمة pH ستساوي
+
+151
+00:12:53,260 --> 00:12:57,620
+سبعة، إذاً at equivalence point لما يكون عندي حمض قوي
+
+152
+00:12:57,620 --> 00:13:00,880
+وقاعدة قوية، معايرة، at equivalence point
+
+153
+00:13:00,880 --> 00:13:05,000
+أحسب قيمة H+ من تفكك الماء، لأنه ليس لديه غيره
+
+154
+00:13:05,000 --> 00:13:09,440
+انتهى HCl، انتهى هيدروكسيد الصوديوم
+
+155
+00:13:09,440 --> 00:13:13,020
+NaCl الذي تكون لا يتفاعل مع الماء، طيب كيف
+
+156
+00:13:13,020 --> 00:13:15,880
+نحسب قيمة H+؟ المصدر الوحيد لـ H+ هو
+
+157
+00:13:15,880 --> 00:13:20,640
+الماء، إذاً الماء عندما يتفكك يعطيني H+ و hydroxide
+
+158
+00:13:20,640 --> 00:13:25,360
+قيمة Kw تساوي x²، أو hydroxide في H+، يبقى
+
+159
+00:13:25,360 --> 00:13:27,520
+معنى الكلام: قيمة H+ ستساوي قيمة hydroxide
+
+160
+00:13:27,520 --> 00:13:32,760
+تساوي 10⁻⁷، وقيمة pH تساوي 7، معنى الكلام: قيمة
+
+161
+00:13:32,760 --> 00:13:39,250
+pH الناتجة عن معايرة حمض قوي وقاعدة قوية سبعة
+
+162
+00:13:39,250 --> 00:13:45,590
+متعادلة، جيد هذا الكلام، نأتي لخطوة ثانية، لو أردنا
+
+163
+00:13:45,590 --> 00:13:49,890
+أن نضيف كمية أكبر من هيدروكسيد الصوديوم، بقول: الآن
+
+164
+00:13:49,890 --> 00:13:53,850
+الوضع سيتغير قليلاً، يعني عندنا هنا كما قلنا هي
+
+165
+00:13:53,850 --> 00:13:57,700
+عند pH سبعة كانت نقطة التكافؤ، أنا أشتغل
+
+166
+00:13:57,700 --> 00:14:02,720
+بنفس الطريقة، أقول: والله عندي خمسة millimoles HCl،
+
+167
+00:14:02,720 --> 00:14:05,920
+عندي ثمانية millimoles هيدروكسيد الصوديوم، الآن هذا
+
+168
+00:14:05,920 --> 00:14:11,220
+صار صفر، هذا صار ثلاثة، ثلاثة يعني ثلاثة
+
+169
+00:14:11,220 --> 00:14:17,870
+على ثمانين وخمسين، مئة وثلاثين، هذا تركيز ماذا؟
+
+170
+00:14:17,870 --> 00:14:22,390
+الهيدروكسيد، سأقوله بال
+
+223
+00:18:41,420 --> 00:18:46,380
+والاسيتيت برضه بعرف احسب الـ PH لها hydroxide
+
+224
+00:18:46,380 --> 00:18:51,500
+هأورجيكم إياه بعد شوية يبقى هاي اللي حصل عندي هان
+
+225
+00:18:51,500 --> 00:18:57,980
+يبقى في عندي أربع نقاط لازم أعرف أحسب الـ PH عندها
+
+226
+00:18:57,980 --> 00:19:04,610
+خلينا ناخد مثال حسابي، بنقول find the pH of a 50 ml
+
+227
+00:19:04,610 --> 00:19:09,610
+solution of 0.1 molar acetic acid، هيه after
+
+228
+00:19:09,610 --> 00:19:15,310
+addition of 0, 10, 25, 50, 60 and 100 ml of 0.1
+
+229
+00:19:15,310 --> 00:19:19,090
+molar sodium hydroxide، وبدون تأخير تعالوا نقول
+
+230
+00:19:19,090 --> 00:19:21,730
+والله آه after addition of 0 ml sodium hydroxide
+
+231
+00:19:21,730 --> 00:19:24,970
+إيش اللي بيحصل؟ فش عندي إلاّ acetic acid، مين
+
+232
+00:19:24,970 --> 00:19:26,910
+يقول يجدّش الـ H plus عندي؟
+
+233
+00:19:32,660 --> 00:19:36,860
+طبعاً زميلكم ممتاز قال إنّه بنقدرش نقول واحد من عشرة
+
+234
+00:19:36,860 --> 00:19:40,720
+طبعاً واحد من عشرة إذا كان الحمض قوي، بس هذا
+
+235
+00:19:40,720 --> 00:19:46,660
+حمض ضعيف، طيب كيف بحسب الـ PH للحمض الضعيف؟ قال هاي
+
+236
+00:19:46,660 --> 00:19:53,820
+الـ equation: HOEC H plus زائد acetate، point one صفر
+
+237
+00:19:53,820 --> 00:20:01,670
+صفر point one minus X، X، X، إذا بدي أقول k a بتساوي x
+
+238
+00:20:01,670 --> 00:20:05,030
+تربيع على الـ point one minus x، هذا كان مثال أخدناه
+
+239
+00:20:05,030 --> 00:20:10,250
+سابقا لوحده، هالجُزء جاي جزء من إيه؟ من الحل، فبقول
+
+240
+00:20:10,250 --> 00:20:13,130
+k a بتساوي الـ x تربيع على الـ point one minus x، بنفرض
+
+241
+00:20:13,130 --> 00:20:16,210
+أنّ الـ point one أكبر كتير من الـ x، الـ k a بتساوي x
+
+242
+00:20:16,210 --> 00:20:18,450
+تربيع على الـ point one، والـ x بتساوي واحد و تلاتة في عشر
+
+243
+00:20:18,450 --> 00:20:21,370
+أُقصى سالم، تلاتة، بنجيب الـ relative error، بيطلع
+
+244
+00:20:21,370 --> 00:20:24,870
+واحد و تلاتة من عشر في المية، قليل، معناته الـ
+
+245
+00:20:24,870 --> 00:20:27,970
+assumption valid، والـ H plus واحد و تلاتة فعشرة
+
+246
+00:20:27,970 --> 00:20:32,430
+سالب تلاتة، يعني الـ PH اتنين و تمانية و تمانين، يبقى
+
+247
+00:20:32,430 --> 00:20:39,870
+هنا الـ PH اتنين و تمانية و تمانين، ماشي يا شباب؟ هذه
+
+248
+00:20:39,870 --> 00:20:44,410
+أول نقطة مش عليها خلاف، لكن شفنا كيف في عند فرق
+
+249
+00:20:44,410 --> 00:20:48,370
+واضح بين هذا الحساب و الحساب في حالة الـ strong
+
+250
+00:20:48,370 --> 00:20:55,150
+acid مع الـ strong base، نيجي الآن نبدأ نضيف  OH
+
+251
+00:20:55,150 --> 00:20:58,930
+ماشي، فبقول after addition of عشرة مل Sodium
+
+252
+00:20:58,930 --> 00:21:03,470
+Hydroxide، عشرة مل Sodium Hydroxide، بقول هذا عندي
+
+253
+00:21:03,470 --> 00:21:07,130
+خمسة ملي مول، عشرة مل يبقى واحد ملي مول، يبقى هذا
+
+254
+00:21:07,130 --> 00:21:12,690
+صار أربعة، صفر، واحد، دائماً مجموع هذا وهذا
+
+255
+00:21:14,080 --> 00:21:18,220
+بيتهم يساووا خمسة، ليه؟ لأنّ عندي خمسة millimole
+
+256
+00:21:18,220 --> 00:21:22,500
+استك أسد، صار أربعة، وين راح الـ millimole؟ طبعاً
+
+257
+00:21:22,500 --> 00:21:26,460
+اتحول لأستيت، فدائماً مجموعة الأستيت و الاستك أسد
+
+258
+00:21:26,460 --> 00:21:29,360
+بتساوي الاستك أسد الـ إيه؟ الأصل، لو عندي في العصر
+
+259
+00:21:29,360 --> 00:21:35,100
+خمسة millimole استك أسد طول المعايرة، ولا عمره
+
+260
+00:21:35,100 --> 00:21:37,900
+بيتغير، بيبقوا دائماً خمسة millimole، بس ممكن تجزّأ،
+
+261
+00:21:37,900 --> 00:21:40,720
+آه جزء منه صار استك أسد، جزء منه صار أستيت،
+
+262
+00:21:40,720 --> 00:21:45,670
+مجموعهم دائماً إيه؟ خمسة، فبدي أجيب التركيز، قال والله
+
+263
+00:21:45,670 --> 00:21:50,910
+أربعة على ستين، وهذا تركيزه واحد على ستين، مفهوم؟
+
+264
+00:21:50,910 --> 00:21:55,650
+ناخد هذا الكلام يعني بالتفصيل، بنقول والله الـ
+
+265
+00:21:55,650 --> 00:21:58,310
+initial millimole of acetic acid، واحد من عشرة في
+
+266
+00:21:58,310 --> 00:22:00,770
+خمسين، خمسة millimole، millimole of sodium
+
+267
+00:22:00,770 --> 00:22:03,970
+hydroxide، point one في عشرة يعني واحد، إذا
+
+268
+00:22:03,970 --> 00:22:08,220
+millimole of acetic acid left، خمسة نقص واحد، أربعة
+
+269
+00:22:08,220 --> 00:22:12,000
+تركيز الاستيك أسد أربعة على ستين مولار، طيب
+
+270
+00:22:12,000 --> 00:22:16,360
+الملي مول الاسيتات formed، المتكونة، وشوفنا إحنا قلنا
+
+271
+00:22:16,360 --> 00:22:20,100
+سابقا، لما اتنين حاجتين محلولين يتفاعلوا مع بعض
+
+272
+00:22:20,100 --> 00:22:25,800
+بجيب المتبقى والمتكون، بتذكرين؟ إذا كانت بتتفاعل؟
+
+273
+00:22:25,800 --> 00:22:29,200
+بتتفاعل، هالي تخفيف، لكن إذا كانت بتتفاعل طبعاً بجيب
+
+274
+00:22:29,200 --> 00:22:35,730
+المتبقى والـ إيه؟ والمتكون، طب ليش ما جبناش المتكون في
+
+275
+00:22:35,730 --> 00:22:38,950
+حالة الـ strong acid مع الـ strong base؟ لأنّ المتكون
+
+276
+00:22:38,950 --> 00:22:43,670
+هو عبارة عن ملح لا strong acid و strong base، لا
+
+277
+00:22:43,670 --> 00:22:48,710
+يتفاعل مع الماء ولا يؤثر في الـ PH، لكن هان لأ بيؤثر
+
+278
+00:22:48,710 --> 00:22:51,830
+في الـ PH، ليه؟ لأنّ الـ acetate هادي strong
+
+279
+00:22:51,830 --> 00:22:56,880
+conjugate base، تتفاعل مع الميه، المهم، فإيش صار عندي؟
+
+280
+00:22:56,880 --> 00:23:03,020
+لو اتطلعنا منيح، هي Acetic Acid وهي Acetate، معنى
+
+281
+00:23:03,020 --> 00:23:06,140
+الكلام هي فيه عندي hand buffer، ولو لاحظت الـ
+
+282
+00:23:06,140 --> 00:23:09,700
+titration curve، الخط هذا، أنا عمال أضيف Hydroxide،
+
+283
+00:23:09,700 --> 00:23:14,150
+لكن الـ PH أُشماله تقريباً ثابتة، مابتتغيرش، أنا عامل
+
+284
+00:23:14,150 --> 00:23:18,270
+بضيف sodium hydroxide لكن الـ PH أُشماله ثابتة
+
+285
+00:23:18,270 --> 00:23:22,130
+لأنّه buffer، أو يعني مابتتغيرش كتير، لأنّه buffer
+
+286
+00:23:22,130 --> 00:23:25,230
+معنى الكلام هذا عبارة عن buffer، طب كيف بدي أحصل الـ
+
+287
+00:23:25,230 --> 00:23:30,670
+PH للـ buffer؟ طبعاً أنا بحب أني أستخدم الـ X، لكن أنتَ
+
+288
+00:23:30,670 --> 00:23:34,150
+مش ضروري تستخدمها، لأنّ معروف أنّ هذا buffer، فممكن
+
+289
+00:23:34,150 --> 00:23:38,370
+تنزل أربعة على ستين، محلها أربعة على ستين و واحد على ستين من غير الـ
+
+290
+00:23:38,370 --> 00:23:43,340
+X، لأنّ الـ X دائماً هتطلع قيمتها قيمة مهمة لأ، فنقول k
+
+291
+00:23:43,340 --> 00:23:46,720
+a بتساوي الـ x، الـ واحد على ستين minus x، كان بإمكاننا نحط
+
+292
+00:23:46,720 --> 00:23:50,940
+بس واحد على ستين وأربعة على ستين من غير الـ x، لكن لو حلّيناها
+
+293
+00:23:50,940 --> 00:23:55,760
+بالشكل هذا بتطلع الـ x، sin دي سبعة في عشرة أُقل سالب خمسة
+
+294
+00:23:55,760 --> 00:24:00,590
+و relative error 0.42، يعني لو لجأت للـ x، يعني لو
+
+295
+00:24:00,590 --> 00:24:04,050
+مالجتش الـ X عندي نسبة خطأ أربعة من عشرة في المية
+
+296
+00:24:04,050 --> 00:24:07,170
+يعني ولا حاجة، إنّ معايا لغاية خمسة في المية مش
+
+297
+00:24:07,170 --> 00:24:10,770
+أعشار، لأ خمسة صحيح في المية، معنى الكلام الـ
+
+298
+00:24:10,770 --> 00:24:15,170
+assumption valid، الـ H plus بيساوي هيّه X، يعني سبعة
+
+299
+00:24:15,170 --> 00:24:18,530
+في عشرة أُقل سالب خمسة، ومنها الـ PH بتساوي أربعة
+
+300
+00:24:18,530 --> 00:24:25,860
+و خمسة و سبعين، جاينده عشرة، الـ PH أربعة و خمسة و سبعين، بنفس الشكل
+
+301
+00:24:25,860 --> 00:24:29,260
+بشتغل كل النقاط قبل نقطة النهاية، بتبقى آخد كمان
+
+302
+00:24:29,260 --> 00:24:33,680
+نقطة، بقول after addition of 25 ml sodium
+
+303
+00:24:33,680 --> 00:24:42,540
+hydroxide، لو أنا حبيت ممكن أقول فوراً والله هان 25
+
+304
+00:24:42,540 --> 00:24:49,280
+يبقى هاد 2 و نص، هاد 2 و نص، هاد صفر، هاد 2 و نص، يبقى
+
+305
+00:24:49,280 --> 00:24:56,310
+2 و نص على 75، هاد 2 و نص على خمسة، أثناء المثالة
+
+306
+00:24:56,310 --> 00:24:59,990
+برضه بإمكاني أني أقول نفس الكلام، الـ initial
+
+307
+00:24:59,990 --> 00:25:03,390
+millimole acetic acid خمسة، الـ millimole sodium
+
+308
+00:25:03,390 --> 00:25:06,510
+hydroxide added، اتنين و نص، إذا الـ millimole acetic
+
+309
+00:25:06,510 --> 00:25:10,210
+acid left، اتنين و نص، تركيز الـ acetic acid اتنين و
+
+310
+00:25:10,210 --> 00:25:13,030
+نص على خمسة و سبعين، الـ millimole acetate formed
+
+311
+00:25:13,030 --> 00:25:16,570
+اتنين و نص، تركيز الـ acetate اتنين و نص على خمسة و
+
+312
+00:25:16,570 --> 00:25:19,490
+سبعين، عندي acetate و acetic acid، إذا هذا buffer
+
+313
+00:25:19,490 --> 00:25:24,210
+دائماً قبل نقطة النهاية، هلاّ جي هذا الكلام صحيح، هنا
+
+314
+00:25:24,210 --> 00:25:28,550
+الاستيك أسد، H بلاس، أستيت، 2.5 على 45، صفر، 2.5 على
+
+315
+00:25:28,550 --> 00:25:33,070
+45، بإمكاني أنزل هذا على طول من غير الـ X و أحل، بقول
+
+316
+00:25:33,070 --> 00:25:38,990
+ك أيه بدها تساوي الاتنين و نص على خمسة و سبعين في x
+
+317
+00:25:38,990 --> 00:25:43,590
+على اتنين و نص على خمسة و سبعين، لو
+
+318
+00:25:43,590 --> 00:25:46,410
+حطينا الـ x، ممكن أنّه نلغيها، ونحن نلغي، أنّه ألغاها
+
+319
+00:25:46,410 --> 00:25:49,590
+فش مشكلة في الـ x، واحد و خمسة و سبعين في عشرة أُقل
+
+320
+00:25:49,590 --> 00:25:52,950
+سالب خمسة، الـ relative error حتى خمسة من مية في
+
+321
+00:25:52,950 --> 00:25:59,110
+المية، ولا إشي، يعني فالـ assumption valid، فالـ .. الـ
+
+322
+00:25:59,110 --> 00:26:03,170
+.. الـ H plus بتطلع واحد و خمسة و سبعين في عشرة أُقل
+
+323
+00:26:03,170 --> 00:26:07,610
+سالم خمسة، يعني الـ PH أربعة و ستة و سبعين، يعني عند
+
+324
+00:26:07,610 --> 00:26:19,270
+خمسة و عشرين الـ PH كانت أربعة و ستة و سبعين، لو جيت
+
+325
+00:26:19,270 --> 00:26:24,950
+اطلعت أنا والـ X إيش بتساوي؟ هي الـ K A، لو لاحظت
+
+326
+00:26:24,950 --> 00:26:30,230
+معايا الـ X هيّه إيه؟ الـ K A، إيش معنى هذا الكلام؟
+
+327
+00:26:30,230 --> 00:26:37,810
+معناته إنّه عند نص الحجم اللازم
+
+328
+00:26:37,810 --> 00:26:43,490
+لنقطة النهاية، عند نصّه بالظبط، يعني عند نص الحجم
+
+329
+00:26:43,490 --> 00:26:49,310
+اللازم لنقطة النهاية، الـ X بتساوي الـ K A، أو الـ PH
+
+330
+00:26:49,310 --> 00:26:54,630
+بتساوي الـ PKA، بمعنى آخر، بمعنى آخر، halfway to the
+
+331
+00:26:54,630 --> 00:26:59,710
+equivalence point، عندنا الـ H plus بتساوي الـ K A، و
+
+332
+00:26:59,710 --> 00:27:03,150
+الـ PH بتساوي الـ PKA، يعني لو كان في عندي أسد مجهول
+
+333
+00:27:03,150 --> 00:27:08,310
+الـ K A، ماعلينا، أعمل معايرة، عملت معايرة
+
+334
+00:27:10,820 --> 00:27:14,800
+فعرفت جدّاش الحجم اللازم للوصول لنقطة النهاية، لأنّه
+
+335
+00:27:14,800 --> 00:27:18,980
+بقصر عليه الكاشف بيتغير لونه، فعرفت جدّاش الحجم
+
+336
+00:27:18,980 --> 00:27:22,520
+اللازم للوصول لنقطة النهاية، لو أخدت نص هذا الحجم
+
+337
+00:27:22,520 --> 00:27:28,200
+عند نص الحجم، الـ K A بتساوي الـ H Plus، أو الـ P K A
+
+338
+00:27:28,200 --> 00:27:33,230
+بتساوي الـ PH، معنى الكلام لو عندي acid مجهول الـ Ka
+
+339
+00:27:33,230 --> 00:27:38,490
+بسهولة بهذه الطريقة بقدر أعين الـ Ka له بمجرد
+
+340
+00:27:38,490 --> 00:27:44,050
+معرفته لنقطة النهاية وتحديد يعني الحجم اللازم
+
+341
+00:27:44,050 --> 00:27:49,290
+لنقطة النهاية، أي نص بالظبط، الـ H plus بتساوي الـ Ka
+
+342
+00:27:49,290 --> 00:27:55,550
+طب تعالوا نشتغل عند إضافة خمسين مل من الـ sodium
+
+343
+00:27:55,550 --> 00:27:56,250
+hydroxide
+
+344
+00:28:01,730 --> 00:28:08,030
+لما يكون تركيز الصودم هيدروكسايد 50، لما
+
+345
+00:28:08,030 --> 00:28:11,110
+يكون تركيز الصودم هيدروكسايد واحد من عشرة في 50 مل، يعني
+
+346
+00:28:11,110 --> 00:28:15,790
+عندي خمسة ملي مول، خمسة اتفعل مع خمسة، يكون هذا صار منه صفر،
+
+347
+00:28:15,790 --> 00:28:19,750
+هذا صار منه صفر، هذا اتكون خمسة، لأنّ مجموع الاتنين
+
+348
+00:28:19,750 --> 00:28:25,280
+هدول بدو يكون خمسة، خمسة زائد صفر بتساوي خمسة، فليس عندي
+
+349
+00:28:25,280 --> 00:28:30,500
+لا استاتيك أسد ولا هيدروكسايد، فقط استاتيات، خمسة على
+
+350
+00:28:30,500 --> 00:28:32,500
+خمسين، وخمسين مية
+
+351
+00:28:36,290 --> 00:28:40,530
+بقدر أقول ملي مول أستك أسد خمسة، ملي مول صودم
+
+352
+00:28:40,530 --> 00:28:44,870
+هيدروكسايت خمسة، ملي مول أستك أسد lift صفر، خمسة
+
+353
+00:28:44,870 --> 00:28:49,250
+ناقص خمسة، معناته this is the equivalence point
+
+354
+00:28:49,250 --> 00:28:53,490
+الملي مول أستات form، طبعاً خمسة، تركيز الأستات خمسة
+
+355
+00:28:53,490 --> 00:28:56,550
+على الـ total volume، خمسين وخمسين يعني مية، خمسة من
+
+356
+00:28:56,550 --> 00:29:00,670
+مية، طب كيف الآن المحلول يحتوي فقط على الأستات
+
+357
+00:29:00,670 --> 00:29:04,960
+الاستك أسد خلص، صودم هيدروكسايت خلص، فش عندي إلاّ
+
+358
+00:29:04,960 --> 00:29:07,220
+بير بس اسيتات، طب كيف بدي أحسب الـ H plus من
+
+359
+00:29:07,220 --> 00:29:11,200
+الاسيتات؟ بقول آه، الاسيتات في المياه بتعطينا
+
+360
+00:29:11,200 --> 00:29:14,640
+هيدروكسيد و استك أسد، الاسيتات خمسة من مائة،
+
+361
+00:29:14,640 --> 00:29:19,400
+الهيدروكسيد صفر، والـ استك أسد صفر، بعد الـ
+
+362
+00:29:19,400 --> 00:29:23,860
+equilibrium، الاسيتات point oh five minus x، x
+
+363
+00:29:23,860 --> 00:29:30,640
+اتحول لهيدروكسايد X، استيك أسيد X، يبقى بدي أجيب الـ
+
+364
+00:29:30,640 --> 00:29:36,060
+X اللي هي الهيدروكسايد، وقاعدين نحولها للـ H بلس
+
+365
+00:29:36,060 --> 00:29:39,300
+نعم
+
+366
+00:29:39,300 --> 00:29:43,400
+كيف كيف استهلاك نفسك في اتفاعل عشرة volleyball
+
+367
+00:29:43,400 --> 00:29:48,000
+عشرة volleyball من إيش؟ من الـ H خمسة، ونفس الشيء لأ
+
+368
+00:29:48,000 --> 00:29:54,050
+الواحد بيعطيك واحد، الواحد بيعطيك واحد، فحسب
+
+369
+00:29:54,050 --> 00:29:57,170
+المتفاعلات هان خمسة ملي مول أستيك أسد اتفاعلت
+
+370
+00:29:57,170 --> 00:30:00,870
+تعطيك خمسة ملي مول أستيت، يعني معجوز خمسة ملي مول
+
+371
+00:30:00,870 --> 00:30:03,930
+أستيك أسد تعطيك عشرة ملي مول أستيت، من أين هم ييجوا؟
+
+372
+00:30:03,930 --> 00:30:09,750
+كل أستيت هي عمارة عن أستيك أسد، بس بنزولي بوتون فلأ
+
+373
+00:30:09,750 --> 00:30:12,710
+عدد ملي مولات الاستيك أسد هي نفس عدد ملي مولات
+
+374
+00:30:12,710 --> 00:30:20,140
+الأستيت، لما نخلص طبعاً خمسة ملي مول H2O لأنّ الواحد
+
+375
+00:30:20,140 --> 00:30:25,240
+بتعطي واحد، مدام اتفعل خمسة ملي مول، واحد ملي مول،
+
+376
+00:30:25,240 --> 00:30:28,580
+بتفعل مع واحد ملي مول، بعطي واحد ملي مول وواحد
+
+377
+00:30:28,580 --> 00:30:32,720
+ملي مول، خمسة ملي مول، بتفعل مع خمسة ملي مول، لاحظ
+
+378
+00:30:32,720 --> 00:30:36,560
+هدول أصفار صاروا، بيعطي خمسة وخمسة، ماشي
+
+379
+00:30:36,560 --> 00:30:40,540
+استوكيومتري، يعني أخدناها بالتفصيل في الـ chapter
+
+380
+00:30:40,540 --> 00:30:45,150
+ماضي، طيب المشكلة هي أنّ الاسيتات إيش طالع عندي؟
+
+381
+00:30:45,150 --> 00:30:52,450
+هيدروكسيد، إذا بتجيب الـ KB، الـ KB بيساوي KW على KA، KB
+
+382
+00:30:52,450 --> 00:30:56,310
+بيساوي عشرة أُقل سالب 14 على KA، بيطلع خمسة و سبعة في عشرة أُقل
+
+383
+00:30:56,310 --> 00:31:00,680
+سالب 10، إذا الـ Kb بيتساوي X تربيع على الـ point O5
+
+384
+00:31:00,680 --> 00:31:04
+
+445
+00:36:11,810 --> 00:36:15,330
+صحيح؟ بنقول لأ، في الحقيقة، في بعض
+
+446
+00:36:15,330 --> 00:36:19,600
+الأحيان إذا كان الـ Kb كبير، بصير فيه قيمة مهمة
+
+447
+00:36:19,600 --> 00:36:22,760
+للهيدروكسيد اللي جاي من الـ conjugate، لكن هل لاحظت
+
+448
+00:36:22,760 --> 00:36:27,640
+الحظ؟ لأ، لأن الـ Kb عشرة أس سالب عشرة، يعني كمية
+
+449
+00:36:27,640 --> 00:36:30,320
+الهيدروكسيد اللي جاية منه، واضِح أنها قليلة
+
+450
+00:36:30,320 --> 00:36:34,940
+وبالإضافة لها، الـ common ion effect بتقل بشكل كبير
+
+451
+00:36:34,940 --> 00:36:39,300
+جدا أيضا. علشان هيك بنقول أنه احنا الصح أن نعرف
+
+452
+00:36:39,300 --> 00:36:44,460
+نحسب الهيدروكسيد اللي جاية من الـ conjugate في وجود
+
+453
+00:36:44,460 --> 00:36:48,720
+الـ hydroxide الزيادة. الصح أننا راح نحسبها. حاول
+
+454
+00:36:48,720 --> 00:36:55,500
+نحسبها ونتأكد أنها كمية مهملة، مش كمية يعني محسوسة.
+
+455
+00:36:56,120 --> 00:37:00,880
+بقول: لو أضفنا أي كمية أخرى، مثلا 100 مل من الـ
+
+456
+00:37:00,880 --> 00:37:05,600
+sodium hydroxide، نفس الكلام، 100 مل، يعني عند الـ
+
+457
+00:37:05,600 --> 00:37:08,820
+millimole hydroxide excess عشرة، اللي هو المضاف
+
+458
+00:37:08,820 --> 00:37:12,540
+hydroxide ناقص الخمسة اللي هو الـ acid صرف عند خمسة
+
+459
+00:37:12,540 --> 00:37:16,060
+acid، hydroxide الزيادة خمسة، عالمية وخمسين molar
+
+460
+00:37:16,640 --> 00:37:19,980
+معناه كان الـ pOH واحد وثمانية وأربعين، والـ pH
+
+461
+00:37:19,980 --> 00:37:22,840
+أربعة عشر ناقص واحد وثمانية وأربعين، يعني اثنا عشر و
+
+462
+00:37:22,840 --> 00:37:27,380
+اثنين وخمسين. في النهاية بقدر أبني يعني tight
+
+463
+00:37:27,380 --> 00:37:34,500
+ratio curve. ممتاز. طيب يا شباب، الآن، إيه خاطر أنه
+
+464
+00:37:34,500 --> 00:37:40,290
+ناخد عكس هذا الكلام تماما. احنا شفنا معايرة weak
+
+465
+00:37:40,290 --> 00:37:46,310
+acid مع strong base، فهل ممكن ندرس معايرة weak base
+
+466
+00:37:46,310 --> 00:37:53,350
+مع strong acid؟ بنقول نعم، ممكن ندرس معايرة weak
+
+467
+00:37:53,350 --> 00:37:58,330
+base مع strong acid، weak base زي الأمونيا مثلا
+
+468
+00:37:58,330 --> 00:38:02,590
+بتفاعل مع strong acid زي الـ HCl
+
+469
+00:38:07,150 --> 00:38:15,210
+in NH4 plus في البداية لو حبينا بيقول
+
+470
+00:38:15,210 --> 00:38:20,570
+هي من الـ HCl اللي هو الـ titrate، وهي الـ pH. لاحظوا
+
+471
+00:38:20,570 --> 00:38:29,550
+أنه أنا عندي في المحلول، في عندي أمونيا بعيرها بالـ
+
+472
+00:38:29,550 --> 00:38:30,510
+HCl
+
+473
+00:38:32,950 --> 00:38:36,450
+مش هيك؟ إذا المحلول لو بده يجيب الـ pH، قلنا بدي
+
+474
+00:38:36,450 --> 00:38:39,390
+أربع مواضع لازم أعرفها علشان أقدر أبني الـ
+
+475
+00:38:39,390 --> 00:38:45,910
+titration curve بشكل كويس. فبقول: أول موضع عند صفر،
+
+476
+00:38:45,910 --> 00:38:51,450
+إيش في عندي عند صفر؟ أمونيا، الـ ammonia base ولا الـ
+
+477
+00:38:51,450 --> 00:38:55,530
+acid؟ الـ base، يعني الـ pH هيكون عالية. يبقى عند صفر
+
+478
+00:38:55,530 --> 00:38:59,550
+هيكون عالي. دي بس أمونيا. طب كيف بدي أحسب الـ pH
+
+479
+00:38:59,550 --> 00:39:02,970
+للأمونيا؟ في طريقة إحنا عارفينها، أخذناها قبل كده؟
+
+480
+00:39:02,970 --> 00:39:08,610
+وأخذنا مثال. إيش Kw؟
+
+481
+00:39:08,610 --> 00:39:15,070
+لأ لأ لأ لأ لأ. الـ NH3 زائد مية بتعطينا NH4 plus
+
+482
+00:39:15,070 --> 00:39:20,960
+زائد هيدروكسيد. والـ NH3 لها Kb معروف، واحد و
+
+483
+00:39:20,960 --> 00:39:24,980
+ثمانية في عشر أس سالب خمسة بالظبط. يعني أخذنا مثال
+
+484
+00:39:24,980 --> 00:39:29,480
+كامل عليها. جبل هيك نفس الأمونيا. يبقى طريقة حسابها
+
+485
+00:39:29,480 --> 00:39:35,680
+أول حاجة تحسب الأمونيا. بعدين باجي بقول: لما نضيف
+
+486
+00:39:35,680 --> 00:39:43,720
+في HCl، الأمونيا عمال بتقل، والأمونيوم
+
+487
+00:39:43,720 --> 00:39:55,430
+بيتكون. إذا هذا بيفرق، هذا بيفرق لغاية ما كل الأمونيا
+
+488
+00:39:55,430 --> 00:40:03,770
+تخلص، تتحول لإيه؟ لأمونيوم. هذا عبارة عن الـ
+
+489
+00:40:03,770 --> 00:40:08,670
+equivalence point. بعدين، والله، هذه الأمونيوم اللي
+
+490
+00:40:08,670 --> 00:40:13,250
+اتكونت، بتبقى زي ما هي. لما أضيف عليها H plus، الاتنين
+
+491
+00:40:13,250 --> 00:40:21,070
+acids مابتتفاعلوا مع بعض. يبقى عكس الـ acetic acid مع
+
+492
+00:40:21,070 --> 00:40:24,430
+الـ sodium hydroxide تماما. الـ curve كان طالع من
+
+493
+00:40:24,430 --> 00:40:29,070
+تحت ورايح لفوق، فجأة جاي من فوق ونازل لتحت. طريقة
+
+494
+00:40:29,070 --> 00:40:33,390
+الحساب، طريقة مباشرة. فهنا، عشان أقدر أحسب أنا الـ
+
+495
+00:40:33,390 --> 00:40:37,550
+titration curve وأحسب الـ pH بعد كل إضافة من الـ H
+
+496
+00:40:37,550 --> 00:40:41,990
+بلس، بقول: لازم أعرف أحسب الـ H plus للأمونيا، الـ H plus
+
+497
+00:40:41,990 --> 00:40:47,570
+للفرد، الـ H plus للأمونيوم، الـ H plus لخلطة من
+
+498
+00:40:47,570 --> 00:40:49,410
+الأمونيوم والـ H plus
+
+499
+00:40:52,110 --> 00:40:56,150
+ماشي بسرعة، يعني إحنا مش هنحل المسألة، لكن في معناه
+
+500
+00:40:56,150 --> 00:41:00,870
+شوية واجد نمشي عليها بسرعة. بقول: في البداية، خلاص
+
+501
+00:41:00,870 --> 00:41:03,470
+after addition of 0 ml، إيش اللي عندي؟ أمونيا
+
+502
+00:41:03,470 --> 00:41:07,630
+الأمونيا في المية بتتفكك لأمونيوم و hydroxide
+
+503
+00:41:07,630 --> 00:41:11,330
+الأمونيا تركيزها واحد من عشرة، اللي معطى في السؤال، لأن
+
+504
+00:41:11,330 --> 00:41:16,920
+هوا بيقول لي 50 ml solution من 0.1 molar ammonia، بعد
+
+505
+00:41:16,920 --> 00:41:21,780
+إضافة 0، 10، 25، 50، 60 و100 مل من الـ 0.1 مولر
+
+506
+00:41:21,780 --> 00:41:26,600
+HCl. فتركيز الأمونيا، الابتدائي هو واحد من عشرة
+
+507
+00:41:26,600 --> 00:41:32,440
+ناقص x. x تربيع على واحد من عشرة ناقص x. الـ Kb بيساوي الـ x تربيع على واحد
+
+508
+00:41:32,440 --> 00:41:38,240
+من عشرة ناقص x. وبنفرض طبعا أن الـ x كمية مهملة. فالـ x
+
+509
+00:41:38,240 --> 00:41:41,880
+بتطلع واحد وثلاثة في عشرة أس سالب ثلاثة. بنطلع relative error
+
+510
+00:41:41,880 --> 00:41:47,030
+بتطلع واحد وثلاثة في المئة. بنقول: إذا الـ assumption valid.
+
+511
+00:41:47,030 --> 00:41:51,410
+الـ x اللي هي الـ hydroxide تساوي واحد وثلاثة في عشرة أس سالب ثلاثة.
+
+512
+00:41:51,410 --> 00:41:57,650
+يبقى الـ pOH 2.8، ومنها الـ pH يبقى، هنا الـ pH 11
+
+513
+00:41:57,650 --> 00:42:02,930
+و12 من المئة. باجي بعد أي إضافة، مثلا عشرة مل HCl،
+
+514
+00:42:02,930 --> 00:42:08,550
+بقول: والله، عند عشرة مل HCl، الـ ... هاي لو حبينا
+
+515
+00:42:08,550 --> 00:42:13,290
+نعملها على طول. فهذا خمسة، هذا واحد، وده أربعة، هنا
+
+516
+00:42:13,290 --> 00:42:19,760
+صفر، هنا واحد، ولو حبيت، هذه واحد على ستين، وهذه أربعة
+
+517
+00:42:19,760 --> 00:42:24,020
+على ستين. وهذا buffer، لأنه صار عندنا أمونيوم و
+
+518
+00:42:24,020 --> 00:42:30,320
+أمونيا. معناه، كلها بنحلها على أنها buffer. الـ Kb بيده
+
+519
+00:42:30,320 --> 00:42:34,380
+يساوي الأمونيوم في الهيدروكسيد على الأمونيا.
+
+520
+00:42:34,380 --> 00:42:38,380
+فبيطلع قيمة الهيدروكسيد، بيطلع سبعة في عشرة أس سالب
+
+521
+00:42:38,380 --> 00:42:44,180
+خمسة، ومنه بيطلع الـ pOH، ومنه بيطلع الـ pH أربعة عشر
+
+522
+00:42:44,180 --> 00:42:48,960
+ناقص الـ pOH. لو اشتغلنا عند خمسة وعشرين مل، اللي
+
+523
+00:42:48,960 --> 00:42:53,980
+هو الحجم، نص الحجم اللازم للوصول لنقطة النهاية، هنا
+
+524
+00:42:53,980 --> 00:42:59,050
+يعني هذه هي نقطة النهاية، نص الحجم، and هذه النقطة
+
+525
+00:42:59,050 --> 00:43:03,530
+بالظبط لما الأمونيوم يساوي الأمونيا، يعني هذا اثنين
+
+526
+00:43:03,530 --> 00:43:10,270
+ونص. بيطلع إن هنا اثنين ونص، وهنا بيطلع إن اثنين
+
+527
+00:43:10,270 --> 00:43:13,790
+ونص. يبقى اثنين ونص على خمسة وسبعين، واثنين ونص
+
+528
+00:43:13,790 --> 00:43:17,550
+على خمسة وسبعين، يعني متساوي، يعني كويس. and نص
+
+529
+00:43:17,550 --> 00:43:24,070
+الحجم اللازم لنقطة النهاية. بلاحظ أنه الـ x اللي هي
+
+530
+00:43:24,070 --> 00:43:35,300
+الهيدروكسيد، بتساوي الـ Kb، أو الـ pH بتساوي الـ الـ الـ
+
+531
+00:43:35,300 --> 00:43:42,940
+... لحظة شوية، الـ P... الـ pOH ماشي، بتساوي الـ pKb، أو
+
+532
+00:43:42,940 --> 00:43:52,200
+يعني أربعة عشر ناقص الـ pH بدها تساوي الـ pKb، كويس؟
+
+533
+00:43:56,480 --> 00:44:00,860
+طيب، وموضح، الـ buffer بيقدر نحسبه، واتعلمنا كيف
+
+534
+00:44:00,860 --> 00:44:05,400
+نحسبه قبل كده. عند نقطة النهاية بالظبط، after 50 ml،
+
+535
+00:44:05,400 --> 00:44:12,380
+عند إضافة 50 ml، الوضع طبعا مباشر. بقول: عند 50 ml،
+
+536
+00:44:12,380 --> 00:44:16,610
+في عندي خمسة من المئة، وهنا خمسة من المئة، وهنا صفر،
+
+537
+00:44:16,610 --> 00:44:20,890
+وهنا صفر، وهنا صفر، وهنا خمسة. إذا هذا بيعطيني خمسة
+
+538
+00:44:20,890 --> 00:44:25,750
+على مية، اللي هو تركيز الأمونيوم. كيف بدي أوجد الـ
+
+539
+00:44:25,750 --> 00:44:28,670
+H plus للأمونيوم؟ قال: والله، الأمونيوم بتتفكك
+
+540
+00:44:28,670 --> 00:44:33,230
+بيعطيني H plus وأمونيا. الأمونيوم خمسة من مئة
+
+541
+00:44:33,230 --> 00:44:37,550
+خمسة من مئة ناقص x، x، x. لكن هذه إيه؟ H plus، يعني Ka
+
+542
+00:44:37,550 --> 00:44:42,820
+إيه؟ فبدي أجيب الـ Ka، بتساوي Kw على الـ Kb. بتجيب
+
+543
+00:44:42,820 --> 00:44:50,520
+الـ Ka بتساوي Kw على الـ Kb. معناه الكلام، الـ Ka خمسة و
+
+544
+00:44:50,520 --> 00:44:55,880
+سبعة في عشرة أس سالب عشرة. بتطلع. ومنها بحسب الـ x اللي
+
+545
+00:44:55,880 --> 00:45:00,580
+هي الـ H plus. لو طلعت على الـ H plus، بتطلع خمسة و
+
+546
+00:45:00,580 --> 00:45:03,800
+سبعة... الـ H plus خمسة وثلاثة وثلاثة، وعشرة وستة و
+
+547
+00:45:03,800 --> 00:45:06,740
+ستة. يعني الـ pH خمسة وسبعة وعشرين. وهذا بيقول ليه
+
+548
+00:45:06,740 --> 00:45:12,320
+أنه الـ pH at equivalence point لمعايرة الـ weak base
+
+549
+00:45:12,320 --> 00:45:17,810
+acidic. كويس؟ بنشوف هذا الكلام. آخر نقطة، لو أضفنا
+
+550
+00:45:17,810 --> 00:45:22,650
+زيادة من الـ HCl. بقول: لما نضيف زيادة من الـ HCl،
+
+551
+00:45:22,650 --> 00:45:28,490
+معناه الكلام في عندي HCl excess. يبقى بحسب الـ H plus
+
+552
+00:45:28,490 --> 00:45:35,350
+مباشرة. طيب، ما هو الأمونيوم بيعطيني H plus؟ هل الـ H
+
+553
+00:45:35,350 --> 00:45:38,770
+plus اللي جاي من الأمونيوم مهمل؟ بقول: والله، الـ Ka
+
+554
+00:45:38,770 --> 00:45:42,370
+للأمونيوم عشرة أس سالب عشرة، فكميته قليلة جدا
+
+555
+00:45:42,370 --> 00:45:45,130
+بالإضافة لإنه لما يكون في عندي H plus جاي من الـ
+
+556
+00:45:45,130 --> 00:45:48,930
+acid، معناته الـ equilibrium كمان هيرجع لإيه؟ لورا
+
+557
+00:45:48,930 --> 00:45:53,820
+يبقى مهمل بشكل كبير خالص. أنا برجع أقول لكم تطلعوا على
+
+558
+00:45:53,820 --> 00:45:58,280
+المثال بالتفصيل، لأن الحصة الجاية، إن شاء الله،
+
+559
+00:45:58,280 --> 00:46:02,780
+عنها، هنبدأ في معايرة polyprotic acids. فبنشوفكم
+
+560
+00:46:02,780 --> 00:46:04,100
+إن شاء الله الحصة الجاية.
+
diff --git a/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/zweVAmxBXOg_raw.srt b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/zweVAmxBXOg_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..b53b5dff9128fec1a4014a17733e81d26ebabf2d
--- /dev/null
+++ b/PL9fwy3NUQKwbICh15S1cAUCJm1SxVhq19/zweVAmxBXOg_raw.srt
@@ -0,0 +1,2348 @@
+1
+00:00:22,120 --> 00:00:26,940
+بسم الله الرحمن الرحيم طيب يا شباب الحصة الماضية
+
+2
+00:00:26,940 --> 00:00:31,340
+كنا برضه نقشنا موضوع ال significant figures وشوفنا
+
+3
+00:00:31,340 --> 00:00:37,740
+كيف ممكن نعمل عمليات الجمع والطرح والقسمة والضرب
+
+4
+00:00:37,740 --> 00:00:43,560
+وشوفنا انه .. يعني كان في ان عملية ضرب وكان في ان
+
+5
+00:00:43,560 --> 00:00:51,550
+اكثر من عملية متضمنة عملية حسابية متضمنةفبنترك
+
+6
+00:00:51,550 --> 00:00:55,510
+دائما على الأقل one additional significant figure
+
+7
+00:00:55,510 --> 00:01:00,070
+مش significant one additional figure زيادة على
+
+8
+00:01:00,070 --> 00:01:05,270
+أساس أنه مانعملش عملية تقريب في كل خطوة من الخطوات
+
+9
+00:01:05,270 --> 00:01:08,630
+اللازمة للحل لأن كل ما عملنا عمليات تقريب أكتر كل
+
+10
+00:01:08,630 --> 00:01:12,910
+ما زاد الخطأ بالظبط اليوم بنتحدث عن
+
+11
+00:01:18,400 --> 00:01:25,340
+بتحدث عن ال logarithms كيف نعمل حسابات
+
+12
+00:01:25,340 --> 00:01:30,180
+إذا كان في عندنا عملية تتضمن logarithms بنقول
+
+13
+00:01:30,180 --> 00:01:35,920
+ببساطة خلاص بنطلع على ال logarithm و لازم نفس
+
+14
+00:01:35,920 --> 00:01:40,240
+القوانين اللي اتعلمناها سابقافي تعداد عدد ال
+
+15
+00:01:40,240 --> 00:01:43,060
+significant figures نطبقها على اللغة ريتمات فمثلا
+
+16
+00:01:43,060 --> 00:01:49,840
+في عندى حاجة بنقولها log 2.0 في 10 اقص 3 انا
+
+17
+00:01:49,840 --> 00:01:54,460
+كاتبلك ال 10 اقص 3 بخط أزراج علشان نعرف ان هذا
+
+18
+00:01:54,460 --> 00:01:58,100
+الجزء مالهوش تعوى بال significant figures ماهي له
+
+19
+00:01:58,100 --> 00:02:04,450
+دخل بال significant figuresمعنى الكلام log 2.0 في
+
+20
+00:02:04,450 --> 00:02:07,250
+عشرة أقصى ثلاثة، هذه قيمة أكم significant figure
+
+21
+00:02:07,250 --> 00:02:10,790
+في هذا العدد، فيه اتنين، إذا الجواب يجب أن يحتوي
+
+22
+00:02:10,790 --> 00:02:14,970
+على اتنين، الجواب يجب أن يحتوي على اتنين، مش ممكن
+
+23
+00:02:14,970 --> 00:02:19,330
+يحتوي على أكثر أو أقل، ليه؟ لأن هذه عملية تحويل من
+
+24
+00:02:19,330 --> 00:02:24,440
+natural number ل logوبالتالي مش عملية قياس يعني
+
+25
+00:02:24,440 --> 00:02:28,160
+بمعنى اخر مافيش عندى زيادة او نقص فى عدد ال
+
+26
+00:02:28,160 --> 00:02:31,420
+significant figures لأن الزيادة او النقص فى عدد ال
+
+27
+00:02:31,420 --> 00:02:34,600
+significant figures يستدعى ان احنا عملنا تجربة
+
+28
+00:02:34,600 --> 00:02:39,080
+اخرى باستخدام اداء اما اكثر دقة او اقل دقة واحنا
+
+29
+00:02:39,080 --> 00:02:43,540
+لا احنا بس مجرد بنحول نتيجة لشكل اخر مش ان احنا
+
+30
+00:02:43,540 --> 00:02:47,120
+يعني اجرينا قياس جديد فانا عندى هان two
+
+31
+00:02:47,120 --> 00:02:52,290
+significant figures فى ال natural numberأيضا ال
+
+32
+00:02:52,290 --> 00:02:54,870
+logarithm بدى يحتوي على two significant figures
+
+33
+00:02:54,870 --> 00:03:00,310
+بطلع على الإجابة اللى حصلت عليها بلاقي 3.30 أكتر
+
+34
+00:03:00,310 --> 00:03:03,470
+significant figure في عندى في الجواب 3 بنقول في
+
+35
+00:03:03,470 --> 00:03:08,910
+الحقيقة لأ مش تلاتة بس اتنين لأنه التلاتةاللي احنا
+
+36
+00:03:08,910 --> 00:03:13,410
+شايفينه اللي مكتوب بالازرق هذا عبارة عن log العشرة
+
+37
+00:03:13,410 --> 00:03:18,710
+اقص تلاتة عندها log 2.0 في عشرة اقص تلاتة العشرة
+
+38
+00:03:18,710 --> 00:03:23,110
+اقص تلاتة ايش بتعطيني اللوج تبعها تلاتة فاللي على
+
+39
+00:03:23,110 --> 00:03:27,670
+يسار العلامة العشرية هذا في ال logarithms لا يحسب
+
+40
+00:03:27,670 --> 00:03:30,350
+ضمن ال significant figures ده انه مش significant
+
+41
+00:03:30,350 --> 00:03:34,780
+figures هذا فقط بيقول ليهبيقولي ال scientific
+
+42
+00:03:34,780 --> 00:03:39,220
+notation ايش بتعطيني يعني مثلا لو كانت بس log 10
+
+43
+00:03:39,220 --> 00:03:42,800
+أقص 5 ال 5 بيساوي الخمسة هذه العاشر أقص خمسة مش
+
+44
+00:03:42,800 --> 00:03:47,020
+قياس هذه اي عدد مالوش دعوة بال significant figures
+
+45
+00:03:47,020 --> 00:03:53,260
+log العاشر أقص 200 بتعطيني 200 مش هيك؟log العشرة
+
+46
+00:03:53,260 --> 00:03:57,040
+أُس كذا مائلها دخل في حساب عدد ال significant
+
+47
+00:03:57,040 --> 00:04:02,380
+figures علشان هيك اللي على يسار العلامة العشرية لا
+
+48
+00:04:02,380 --> 00:04:06,200
+يحسب ضمن عدد ال significant figures يعني مبدأ أعد
+
+49
+00:04:06,200 --> 00:04:14,080
+هي واحد هي اتنين أما التلاتة فهي ايه؟ non
+
+50
+00:04:14,080 --> 00:04:19,660
+-significant التلاتة تعتبر non-significant ماشي يا
+
+51
+00:04:19,660 --> 00:04:25,640
+شبابأذا كما ذكرت اللي على يسار العلامة العشرية لا
+
+52
+00:04:25,640 --> 00:04:29,560
+يحسب نهائيا اللي على يمين العلامة العشرية يحسب
+
+53
+00:04:29,560 --> 00:04:34,740
+نبدأ نعد من العلامة العشرية و نمشي لليمين بما في
+
+54
+00:04:34,740 --> 00:04:42,200
+ذلك زي ما هنشوف المثال التالي بما في ذلك الأصفر
+
+55
+00:04:42,200 --> 00:04:50,070
+يعني مثلا انا بدأ أجيب log 1.18 لو سألتأكم
+
+56
+00:04:50,070 --> 00:04:54,730
+significant figure موجود في هذا ال .. تلاتة ..
+
+57
+00:04:54,730 --> 00:04:57,790
+تلاتة .. إذا الجواب على أكم significant figure بده
+
+58
+00:04:57,790 --> 00:05:02,130
+يحتوي على تلاتة باجي بقول لهذا الحاسبة على طول
+
+59
+00:05:02,130 --> 00:05:07,810
+بتساوي point o seven two لاحظوا معايا أن ال o أو
+
+60
+00:05:07,810 --> 00:05:11,810
+الصفر يعني اللي مكتوب باللون الأزرق هذه أيضا
+
+61
+00:05:11,810 --> 00:05:16,030
+significantيبقى في ال logarithms إذا كان العدد
+
+62
+00:05:16,030 --> 00:05:19,870
+logarithmic فكل اللي على يمين الفاصلة significant
+
+63
+00:05:19,870 --> 00:05:26,610
+بما في ذلك الأصفر يبقى 0.072 هذا يشمله تلاتة
+
+64
+00:05:26,610 --> 00:05:29,910
+significant figures تلاتة بمعنى أخر لو كان عندي
+
+65
+00:05:29,910 --> 00:05:37,690
+مثلا log 11.8 هلاحظ أنها 1.072 هذا الواحدnon
+
+66
+00:05:37,690 --> 00:05:42,890
+significant لأن هي نفسها log 1.18 في عشر عقل واحد
+
+67
+00:05:42,890 --> 00:05:51,870
+بتسوي 1.072 فالواحد هذه هي الواحد هذه مش هيك؟ اذا
+
+68
+00:05:51,870 --> 00:05:56,990
+ببدأ اعيد من وين؟ من الفاصلة بما في ذلك الأصفار
+
+69
+00:05:56,990 --> 00:06:00,870
+هذا الفرق الوحيد اللي بدنا نتعلمه مدان بده احولها
+
+70
+00:06:00,870 --> 00:06:06,320
+logإذا بدي أقول اللي على اليسار لا يحسب لأنه له
+
+71
+00:06:06,320 --> 00:06:08,920
+دعوة بالصيانة الـ thick notation اللي على يمين
+
+72
+00:06:08,920 --> 00:06:15,000
+العلامة العشرية كله يحسب بما في ذلك أيه؟ الأصفر،
+
+73
+00:06:15,000 --> 00:06:21,020
+جيس هذا الكلام؟ كل الأصفر تحسب، نبدأ من العلامة
+
+74
+00:06:21,020 --> 00:06:25,980
+العشرية وكل الأصفر على يمين العلامة العشرية تحسب،
+
+75
+00:06:25,980 --> 00:06:31,720
+وين ما كانتمش زي العادة بنعيد من أول عدد صحيح لأ
+
+76
+00:06:31,720 --> 00:06:36,220
+اللي ع اليسار لا يحسب نهائيا ليه؟ لأنه إله دعوة
+
+77
+00:06:36,220 --> 00:06:45,310
+فقط بال scientific notation طيب خلينا نتطلع علىمش
+
+78
+00:06:45,310 --> 00:06:48,730
+log انت log لما ناجي اقول انت log point o eighty
+
+79
+00:06:48,730 --> 00:06:51,890
+three معناته ال point o eighty three هذا عبارة عن
+
+80
+00:06:51,890 --> 00:06:54,710
+log number مدام انا جيبها انت log او ال inverse
+
+81
+00:06:54,710 --> 00:06:59,450
+log اذا ال point o eighty three ايش مالها؟ هي
+
+82
+00:06:59,450 --> 00:07:04,410
+عبارة عن log number اذا ببدأ اعد كل اللي على يمين
+
+83
+00:07:04,410 --> 00:07:10,270
+العلامة العشرية واحد اتنين تلاتة ماخدين بالنا؟ اذا
+
+84
+00:07:10,270 --> 00:07:15,040
+لما تجيب ال ant logبأطلع أنا هذا عبارة عن log
+
+85
+00:07:15,040 --> 00:07:18,980
+number مدام log number إذا اللي على اليسار لا يحسب
+
+86
+00:07:18,980 --> 00:07:22,800
+اللي على اليمين كله يحسب معنى الكلام ال point o
+
+87
+00:07:22,800 --> 00:07:25,860
+eighty three هذا فيه تلاتة significant figures مش
+
+88
+00:07:25,860 --> 00:07:29,880
+اتنين على طول القالة بتقول one point two one تلاتة
+
+89
+00:07:29,880 --> 00:07:32,340
+significant figures ال one point two one هذا
+
+90
+00:07:32,340 --> 00:07:36,040
+natural number عدد طبيعي مش log number تلاتة أه
+
+91
+00:07:36,040 --> 00:07:46,780
+تلاتة ممكن أطلع أنا برضه علىلو جيت انت قلت antilog
+
+92
+00:07:46,780 --> 00:07:49,880
+100
+
+93
+00:07:49,880 --> 00:07:55,060
+antilog عفوان 2
+
+94
+00:07:55,060 --> 00:08:03,060
+.083 بدنا نجيب ال antilog ل 2.083 اكم significant
+
+95
+00:08:03,060 --> 00:08:07,890
+figure فيها عندهمتلاتة هذا الاتنين ايش ماله؟ مالوش
+
+96
+00:08:07,890 --> 00:08:13,750
+دعوة اه اذاك بده يكون one point two one في عشرة أس
+
+97
+00:08:13,750 --> 00:08:20,110
+اتنين هذا هو inverse log يا حبيبي shift يعني shift
+
+98
+00:08:20,110 --> 00:08:24,530
+log ماشي طيب يا شباب نفس الكلام إنهان لو حاولنا
+
+99
+00:08:24,530 --> 00:08:29,930
+نتطلع على twelve point one هذا عبارة عن natural
+
+100
+00:08:29,930 --> 00:08:32,850
+number لإنه بتجيبله ال log عامل is an account
+
+101
+00:08:32,850 --> 00:08:33,910
+significant figure فيه
+
+102
+00:08:36,660 --> 00:08:40,180
+أكم significant figure for you and her تلاتة ماشي
+
+103
+00:08:40,180 --> 00:08:45,460
+على أي حسبة تلعب 1.083 اللي على اليسار يحسب لا
+
+104
+00:08:45,460 --> 00:08:50,120
+يحسب اللي على اليمين كله يحسب اذا point 083 هي
+
+105
+00:08:50,120 --> 00:08:54,120
+عبارة عن تلت أرقام الواحد اللي على اليسار لا يحسب
+
+106
+00:08:54,120 --> 00:08:59,700
+اذا الجواب يكون 1.083 هذا ما يتعلق بال logarithms
+
+107
+00:09:00,130 --> 00:09:04,570
+Logarithms كتير كتير الموضوع بسيط بقول بتطلع
+
+108
+00:09:04,570 --> 00:09:07,250
+natural number بعد عدد ال significant figures اللي
+
+109
+00:09:07,250 --> 00:09:11,590
+فيه نفس العدد بده يكون في الجواب لكن بدي أخد بعين
+
+110
+00:09:11,590 --> 00:09:15,950
+الاعتبار بعدش أي شي على يسار العلامة العشرية مش
+
+111
+00:09:15,950 --> 00:09:20,090
+شغلي اللي على يمين العلامة العشرية بعده كله بس هاي
+
+112
+00:09:20,090 --> 00:09:25,370
+القانون الوحيد اللي بدك تاخد بالك منه طيب الآن
+
+113
+00:09:25,370 --> 00:09:31,800
+ننتقل لموضوع تانيبنتكلم فيه عن ال errors احنا
+
+114
+00:09:31,800 --> 00:09:35,940
+هنرجع يا شباب ل stick diff configures كمان مرة لكن
+
+115
+00:09:35,940 --> 00:09:41,900
+بعد ما نحط أرضية جديدةلشغلنا في المستقبل تتعلق بال
+
+116
+00:09:41,900 --> 00:09:46,240
+uncertainty اللي هي هنشتاقها من ال errors هنشتاقها
+
+117
+00:09:46,240 --> 00:09:49,280
+من ال standard deviation زي ما هنشوف بعد شوية
+
+118
+00:09:49,280 --> 00:09:55,060
+فهنرجع تاني لل significant figures راجعة خلينا
+
+119
+00:09:55,060 --> 00:09:57,420
+نقول نهائية يعني هنخلص موضوع ال significant
+
+120
+00:09:57,420 --> 00:10:02,720
+figures لما نرجع كمان مرة يمكن يعني المحاضرة مش
+
+121
+00:10:02,720 --> 00:10:07,000
+الجاية يمكن بعد اللي جايةعلى أي حال، لما نتكلم عن
+
+122
+00:10:07,000 --> 00:10:09,920
+ال errors يا شباب، بتكلم عن شيء منطقي جدا في
+
+123
+00:10:09,920 --> 00:10:12,580
+الكيمة التحليلية، ليه؟ لأنه احنا في الكيمة
+
+124
+00:10:12,580 --> 00:10:17,040
+التحليلية بنعمل تجارب، والتجارب نتائجها دائما
+
+125
+00:10:17,040 --> 00:10:25,500
+نتائج رقمية، عددية، كمية، التجارب هذه تحتمل الخطأ
+
+126
+00:10:26,160 --> 00:10:30,760
+تحتمل أن يكون فيها أخطاء فالخطأ شيء طبيعي في أي
+
+127
+00:10:30,760 --> 00:10:35,820
+شيء تجريبي مدام اللي بده يقوم بالتجربة هو إنسان أو
+
+128
+00:10:35,820 --> 00:10:40,480
+اللي بده يقوم بالتجربة هو جهاز صنعه إنسان فيجب أن
+
+129
+00:10:40,480 --> 00:10:44,340
+يكون هناك نوع من الخطأ فالخطأ موجود لكن لو قلنا
+
+130
+00:10:44,340 --> 00:10:50,640
+تعالوا نصنف الأخطاء تعالوا نصنف الأخطاءوالله أحدكم
+
+131
+00:10:50,640 --> 00:10:55,500
+ممكن يقول يعني في عنا أخطاء ناشئة عن الوزن نعم عنا
+
+132
+00:10:55,500 --> 00:11:00,700
+أخطاء ناشئة عن الوزن في موازين حساسة وفي موازين
+
+133
+00:11:00,700 --> 00:11:04,920
+غير حساسة في موازين بتجيس لأقرب واحد جرام في بتجيس
+
+134
+00:11:04,920 --> 00:11:07,800
+لأقرب واحد من عشر جرام في بتجيس لأقرب واحد من مية
+
+135
+00:11:07,800 --> 00:11:10,740
+جرام في بتجيس لأقرب واحد من ألف واحد لعشرة ألف
+
+136
+00:11:10,740 --> 00:11:16,420
+واحد لمائة ألف من الجرام في موازين يعني تتفاوت في
+
+137
+00:11:16,420 --> 00:11:20,850
+دقتها صحيحممكن خطأ يكون ناشي عن انه والله ميزان
+
+138
+00:11:20,850 --> 00:11:25,450
+بيعطينيش الدقة المطلوبة مثلا ممكن يكون خطأ في
+
+139
+00:11:25,450 --> 00:11:31,730
+ميزان لأنه يعني الميزان دائما بيقيس اكثر من اللازم
+
+140
+00:11:31,730 --> 00:11:35,950
+يعني مثلا في عند ميزان انا ب .. احط عليه gram
+
+141
+00:11:35,950 --> 00:11:40,070
+بيجرى اجرامه اتنين من عشرة او اجرامه واحد من عشرة
+
+142
+00:11:40,070 --> 00:11:44,090
+حطيت عليه اتنين gram بيجرى اتنين ونص مثلا يعني
+
+143
+00:11:44,090 --> 00:11:49,250
+دائما بيعطي قراءة بزيادةأو بالنقص فى عندى ميزان
+
+144
+00:11:49,250 --> 00:11:53,250
+يعني فى مشكلة ميزان يحتاج الى calibration معايرة
+
+145
+00:11:53,250 --> 00:11:58,070
+فى عندى ميزان زى هيك وبالتالي هذا بيأد إلى أخطاء
+
+146
+00:11:58,070 --> 00:12:04,650
+ناتج عن عملية الوزنأو أيضًا في عندى أخطاء ناتجة عن
+
+147
+00:12:04,650 --> 00:12:10,490
+الحجم فمثلًا أنا والله بدى أخد حجم معين بستخدم
+
+148
+00:12:10,490 --> 00:12:14,850
+pipet معينة والله هو مكتوب عليها الحجم تبعها اللى
+
+149
+00:12:14,850 --> 00:12:18,850
+بتاخده لكن يعني ماقدرانى أن هذا الحجم صحيح يمكن
+
+150
+00:12:18,850 --> 00:12:22,250
+لما تاخد هذا الحجم تكون ماخدة اكتر ب mil او اتنين
+
+151
+00:12:22,250 --> 00:12:27,100
+او تلاتة او خمسة مثلًا او اقلفممكن أخطاء تكون
+
+152
+00:12:27,100 --> 00:12:31,640
+ناشئة أيضا عن الحجم، ممكن أخطاء تكون ناشئة عن
+
+153
+00:12:31,640 --> 00:12:35,500
+الطريقة نفسها، الطريقة دائما بتعطي نتائج أعلى من
+
+154
+00:12:35,500 --> 00:12:40,140
+اللازم أو الطريقة دائما بتعطي نتائج أقل من اللازم،
+
+155
+00:12:40,140 --> 00:12:43,640
+في طرق زيكي؟ نعم، هناك طرق تحليلية معروفة بتعطي
+
+156
+00:12:43,640 --> 00:12:49,680
+نتائج أعلى أو نتائج أدنى، أقل، ممكن الجهاز أيضا
+
+157
+00:12:49,680 --> 00:12:54,910
+يكون في مجال للخطأالجهاز أيضًا بيكون مجال الخطأ،
+
+158
+00:12:54,910 --> 00:13:00,090
+ممكن يعني ما هواش معايير بشكل سليم، في مشكلة في
+
+159
+00:13:00,090 --> 00:13:04,970
+مصدر إضاءة، في مشكلة في الـ detector، في مشكلة في
+
+160
+00:13:04,970 --> 00:13:10,130
+الضوء الـ monochromator، الضوء المفروض يكون مثلًا
+
+161
+00:13:10,130 --> 00:13:13,770
+أحادي الموجة، ضوء أصفر، ضوء أحمر، ضوء أخضر، أحادي
+
+162
+00:13:13,770 --> 00:13:18,470
+الموجة، مابتطلعش عند ضوء يعني خلّيني أقول نقي، ع
+
+163
+00:13:18,470 --> 00:13:21,090
+سبيل المثال، يعني قد يكون الجهاز نفسه بيدّي
+
+164
+00:13:21,090 --> 00:13:26,320
+الأخطاءوأسباب الأخطاء يعني قد تكون متعددة للغاية
+
+165
+00:13:26,320 --> 00:13:33,250
+كتيرة خالصأنا مقدرش أحصرها في محاضرة مثلا وإحنا لو
+
+166
+00:13:33,250 --> 00:13:37,570
+فكرنا كل ما فكرنا في أشياء مختلفة هنلاقي في عنا
+
+167
+00:13:37,570 --> 00:13:41,370
+مجال أكبر لإن يكون في عنا أنواع مختلفة من الأخطاء
+
+168
+00:13:41,370 --> 00:13:45,130
+لكن أنا في الكيميا التحليية بحب دائما المواضيع أن
+
+169
+00:13:45,130 --> 00:13:50,970
+تكون محددة فأنا بدي أصنف الأخطاء لصنفين فقط كل
+
+170
+00:13:50,970 --> 00:13:54,690
+الأخطاء اللي ذكرتها و اللي ممكن تفكر فيها تندرج
+
+171
+00:13:54,690 --> 00:14:00,240
+بمن هدول التصنيفينأو هدول القسمين أول قسم من
+
+172
+00:14:00,240 --> 00:14:07,220
+الأخطاء بدي أسميه determined error خطأ يعني خليني
+
+173
+00:14:07,220 --> 00:14:13,860
+أقول معناه يعني يمكن تقديره determined يمكن تقديره
+
+174
+00:14:13,860 --> 00:14:21,900
+ومعرفة مصدره تتبعه معرفة مصدره وفي أغلب الأحيان
+
+175
+00:14:21,900 --> 00:14:27,610
+تصحيحهوفي أغلب الأحيان إيش؟ تصحيحه لأنه يعتبر خطأ
+
+176
+00:14:27,610 --> 00:14:33,310
+منهجي برضه يسمى systematic error يسمى systematic
+
+177
+00:14:33,310 --> 00:14:39,190
+error خطأ منهجي ما يميزه عن الأخطاء الأخرى أن خطأ
+
+178
+00:14:39,190 --> 00:14:45,430
+له اتجاه unidirectional دائما في اتجاه واحد يعني
+
+179
+00:14:45,430 --> 00:14:53,920
+بمعنى إيه؟ بمعنى أنهدائما النتائج تبعتي بتكون اعلى
+
+180
+00:14:53,920 --> 00:14:58,880
+من النتيجة المقبولة او الحقيقية او انها دائما
+
+181
+00:14:58,880 --> 00:15:03,820
+النتائج بتكون اقل يبقى دائما يا اما اعلى يا اما
+
+182
+00:15:03,820 --> 00:15:08,000
+اقل فش fluctuation حوالين النتيجة الحقيقية فش
+
+183
+00:15:08,000 --> 00:15:10,920
+تذبذب حوالين النتيجة الحقيقية يعني مرة اعلى مرة
+
+184
+00:15:10,920 --> 00:15:17,250
+اقل مرة اقل مرة اعلى و هكذا لأ فشكله إما أعلى أو
+
+185
+00:15:17,250 --> 00:15:21,290
+كله إما إيه أقل، فيش تذبذب، عشان هيك بنقول ال
+
+186
+00:15:21,290 --> 00:15:24,470
+systematic error أو ال determinant error، هذا
+
+187
+00:15:24,470 --> 00:15:33,650
+unidirectional error، error له اتجاه معين،
+
+188
+00:15:33,650 --> 00:15:40,370
+دائما، دائما، يا أعلى يا أقل، فيش تذبذب؟طيب يا
+
+189
+00:15:40,370 --> 00:15:49,050
+شباب زي إيش مثلا، زي إيش؟ أنا والله وصلتني عينة من
+
+190
+00:15:49,050 --> 00:15:54,550
+معهد القياسات العالمية بتقول إنه تحليل ال zinc في
+
+191
+00:15:54,550 --> 00:16:01,440
+هذه العينة هو عبارة عن خمسة PPM، خمسة PPMمعروف،
+
+192
+00:16:01,440 --> 00:16:05,120
+هذه العينة اللي وصلتني تحليل الزنك فيها جديه، خمسة
+
+193
+00:16:05,120 --> 00:16:09,220
+PPM، أجيت أنا عملت التجربة بالطريقة اللي احنا
+
+194
+00:16:09,220 --> 00:16:14,000
+بنشتغل فيها في المختبر، فلجيته اتناش، احداش،
+
+195
+00:16:14,000 --> 00:16:18,360
+اتناش، احداش، اتناش، تلتاش، احداش، اتناش، يبقى
+
+196
+00:16:18,360 --> 00:16:24,070
+دائما ايه؟ دائما اعلى، مش خمسةايش بشك انا؟ بشك
+
+197
+00:16:24,070 --> 00:16:27,670
+بقول طيب ايش السبب؟ من وين جاي الخطأ هذا؟ هذا واضح
+
+198
+00:16:27,670 --> 00:16:32,270
+ان الأخطاء كلها عالية بقول والله في احتمال في
+
+199
+00:16:32,270 --> 00:16:36,810
+احتمال انه يعني الوزن اللي انا باخدها اكبر فتعالوا
+
+200
+00:16:36,810 --> 00:16:41,610
+نختبر الميزان بقول انا باخد وزن مقدارها واحد gram
+
+201
+00:16:41,610 --> 00:16:49,700
+طب تعالوا نحط واحد gram قياسيوكتلة قياسية مقدارها
+
+202
+00:16:49,700 --> 00:16:54,200
+واحد gram اجيت أخدتها وحطيتها على الميزان والله
+
+203
+00:16:54,200 --> 00:17:00,300
+الميزان قرأها مثلا ستة من عشر gram معناته لما انا
+
+204
+00:17:00,300 --> 00:17:05,640
+اوزن على الميزان gram هيكون الموزن اكتر من gram اه
+
+205
+00:17:05,640 --> 00:17:10,010
+الميزان فيه مشكلةلكن لو الميزان قرأها واحد دي gram
+
+206
+00:17:10,010 --> 00:17:14,290
+بالظبط، معناته الميزان فيه مشكلة؟ لأ، باشر بقول طب
+
+207
+00:17:14,290 --> 00:17:17,650
+أنا إيش بعمل بعد هيك؟ بقول أنا آه باخد بال pipet
+
+208
+00:17:17,650 --> 00:17:23,030
+20 mil عشان عاير، فأنا بدور بالعينة و باخد
+
+209
+00:17:23,030 --> 00:17:27,270
+بالpipet 20 mil، طب أخدت 20 mil، طب يمكن ال pipet
+
+210
+00:17:27,270 --> 00:17:31,210
+مابتعطينيش 20 mil، يمكن بتعطيني أكتر من 20 mil،
+
+211
+00:17:31,210 --> 00:17:35,390
+عشان هيك انتي بتطلع اندي أعلى دائمافليش بسوي ممكن
+
+212
+00:17:35,390 --> 00:17:39,690
+اخد .. انظف البيت كويس كتير و اخد عشرين مل ميه
+
+213
+00:17:39,690 --> 00:17:43,170
+مجترة و بعدين أحط العشرين مل هدول اللي أخدتهم على
+
+214
+00:17:43,170 --> 00:17:47,850
+الميزان، المفروض يعطوني عشرين جرام لأن كثافة الميه
+
+215
+00:17:47,850 --> 00:17:54,620
+واحد جرام للمل او لالصد مثل المكعببلاحظ أنه ممكن
+
+216
+00:17:54,620 --> 00:18:00,160
+ألاحظ أنه بدل عشرين بتعطيني تلاتين مثلا أو أربعين
+
+217
+00:18:00,160 --> 00:18:05,460
+مثلا بعرف أنه ال bibet إيش فيها مشكلة لكن لو
+
+218
+00:18:05,460 --> 00:18:09,360
+أعطتنا عشرين بالظبط يبقى ال bibet مظبوطة صح ولا لأ
+
+219
+00:18:09,360 --> 00:18:13,100
+طيب ال bibet مظبوطة بتظل إيش؟ بتظل عملية والله
+
+220
+00:18:13,100 --> 00:18:16,280
+يعني ال buret ممكن تكون بتعطي خطأ بنفس الطريقة
+
+221
+00:18:16,280 --> 00:18:20,140
+بشوف ال buretإذا أعطتني خطأ، بقول الخطأ منها،
+
+222
+00:18:20,140 --> 00:18:23,720
+ماعطتنيش خطأ، بدي أفكر بحاجة تانية، بقول طب من وين
+
+223
+00:18:23,720 --> 00:18:27,800
+ممكن يجي الخطأ؟ أه بقول أنا والله بدوّب العين بعد
+
+224
+00:18:27,800 --> 00:18:32,700
+ما أوزنهاطيب يمكن يكون ال solvent اللي أنا بدوّب
+
+225
+00:18:32,700 --> 00:18:36,820
+فيه موجود فيه شوية زنك معايا؟ ال solvent اللي أنا
+
+226
+00:18:36,820 --> 00:18:41,160
+بدوّب فيه يمكن يكون فيه زنك أنا بدور على زنك فبروح
+
+227
+00:18:41,160 --> 00:18:46,280
+بعمل مثلا ال solvent لحاله من غير العينة بلاجي
+
+228
+00:18:46,280 --> 00:18:50,160
+الفرق او بلاجي انه اه والله موجود فيه زنك بعرف ان
+
+229
+00:18:50,160 --> 00:18:54,040
+ال solvent اللي انا كنت بدوّب فيه مش نظيف مجمل
+
+230
+00:18:54,040 --> 00:18:58,470
+الكلاماللي ذكرناه بيقول إيش؟ بيقول إن ال
+
+231
+00:18:58,470 --> 00:19:03,670
+determinant error أه هو unidirectional لكن يمكن
+
+232
+00:19:03,670 --> 00:19:10,370
+تتبعوه وماعرفت مصدره وإذا عرفت مصدره بصححه إذا
+
+233
+00:19:10,370 --> 00:19:15,670
+وبستطيع في أغلب الأحيان أني أصححه النوع الآخر من
+
+234
+00:19:15,670 --> 00:19:22,650
+الخطأ حاجة بنقولها indeterminate error خطأ لا يمكن
+
+235
+00:19:24,490 --> 00:19:30,130
+تتبعه ولا معرفة مصدره وبالتالي لا يمكن تصحيحه هو
+
+236
+00:19:30,130 --> 00:19:33,970
+ال indeterminate error هذا خطأ بنسميه random
+
+237
+00:19:33,970 --> 00:19:38,690
+عشوائي بمعنى ايه؟ بمعنى انه بعمل التجربة اعلى من
+
+238
+00:19:38,690 --> 00:19:42,290
+الحقيقية بعملها مرة تانية اقل مرة تالتة اعلى مرة
+
+239
+00:19:42,290 --> 00:19:45,930
+رابعة اقل مرتين اعلى مرة اقل مرتين اقل مرة اعلى و
+
+240
+00:19:45,930 --> 00:19:52,150
+هكذا المهم ان النتيجة تتذبذب حول النتيجة الصحيحة
+
+241
+00:19:52,150 --> 00:19:57,950
+هذا اسمه random errorلأ ال determinant دائما
+
+242
+00:19:57,950 --> 00:20:02,630
+النتائج اعلى او دائما كلها يعني اعلى او كلها اقل
+
+243
+00:20:02,630 --> 00:20:08,370
+هذا بيتذبذب مرة اعلى مرة اقل مرة اعلى مرة اقل كويس
+
+244
+00:20:08,370 --> 00:20:14,230
+بنقول هو عشان هي random عشوائي مرة اعلى مرة اعلى
+
+245
+00:20:14,230 --> 00:20:20,370
+عشوائي بنقول ايش يا شباب؟ بنقول انه عادة كل
+
+246
+00:20:21,950 --> 00:20:24,890
+قراءاتنا خاضة على الـ Random Error، كلها خاضة على
+
+247
+00:20:24,890 --> 00:20:28,090
+الـ Random Error، مش ممكن نعمل التجربة بنفس الشكل،
+
+248
+00:20:28,090 --> 00:20:33,710
+بنفس الكيفية، بنفس الدقة، بنفس الطريقة،
+
+249
+00:20:33,710 --> 00:20:36,750
+مرات متعددة، مش ممكن، لازم يكون فيه اختلاف، ولو
+
+250
+00:20:36,750 --> 00:20:41,160
+بسيطعشان هيك ال random error لا يمكن إلغاءه
+
+251
+00:20:41,160 --> 00:20:45,940
+نهائيًا، يجب إنه يكون موجود، لكن غير مقبول إنه
+
+252
+00:20:45,940 --> 00:20:49,800
+تكون قيمته كبيرة، كيف يعني؟ يعني مثلا إنت روحت على
+
+253
+00:20:49,800 --> 00:20:55,260
+المختبر و بدك تعمل عملية معايرة، فبدك تغسل فلوسك
+
+254
+00:20:55,260 --> 00:20:59,520
+أول شغلة عشان تنجل عليه العينة، فإنت شفت فلوسك يا
+
+255
+00:20:59,520 --> 00:21:03,840
+الله ما أحلى، جميل جدا، شكله نظيف خالص، فقولت ليش
+
+256
+00:21:03,840 --> 00:21:08,650
+أغسله؟ مابيديش هيه نظيففروحت على طول حطيت العينة
+
+257
+00:21:08,650 --> 00:21:16,270
+مثلا acid او base على فرض انه كان ال beaker هذا
+
+258
+00:21:16,270 --> 00:21:19,730
+قبل شوية او قبل ساعة او اليوم اللي جابله محطوت فيه
+
+259
+00:21:19,730 --> 00:21:26,550
+acid مركز مثلا او base مركز و مكبوب مش مغسول اذا
+
+260
+00:21:26,550 --> 00:21:32,100
+ايش اتر هو؟ acid او base معنى الكلاموإذا بدك تعيير
+
+261
+00:21:32,100 --> 00:21:34,700
+acid أو base، فإن أكيد حيطلع عندك خطأ، قراعتك
+
+262
+00:21:34,700 --> 00:21:38,280
+الأولى خطأ، إما بالزيادة أو بالنقص، ليه؟ لأنه أصلا
+
+263
+00:21:38,280 --> 00:21:42,980
+كان موجود في ال flask acid أو base وحتاج تركيزه
+
+264
+00:21:42,980 --> 00:21:46,580
+عليه لأنه كان مثلا تركيزه اللي كان في الأصل كان
+
+265
+00:21:46,580 --> 00:21:52,540
+تركيز مركزهيطلع عندك خطأ، لو قلتلك كرر التجربة و
+
+266
+00:21:52,540 --> 00:21:56,020
+أحصل على نفس الخطأ، بتقدرش، لأنك أصلا مش عارف
+
+267
+00:21:56,020 --> 00:21:59,960
+مصدره، مش عارف أنه كان في ال flask زمان اليوم اللي
+
+268
+00:21:59,960 --> 00:22:04,620
+جابله مثلا أسد مركز و ضايل أثاره موجودة في ال
+
+269
+00:22:04,620 --> 00:22:08,920
+flask، تعرفش هذا الكلام أنت؟نفس الكلام اللى بنشوفه
+
+270
+00:22:08,920 --> 00:22:12,820
+عادة فى المختبرات و الله انت بتكون مستعجل بدك تروح
+
+271
+00:22:12,820 --> 00:22:17,320
+يا فلان دوّلني بالله ال buffer من جانبك يعني هو
+
+272
+00:22:17,320 --> 00:22:20,720
+خلاص بالمجرد انك أشرتله على جنية بفكر ان هذه هي ال
+
+273
+00:22:20,720 --> 00:22:24,820
+buffer فبروح بيعطيها لك هي مش buffer حطيت انت
+
+274
+00:22:24,820 --> 00:22:28,200
+الكمية على انها buffer على اساس ان هو يعني اعطاهلك
+
+275
+00:22:28,200 --> 00:22:32,900
+انها buffer و خلاص رجعتها فتطلع معاك نتيجة مختلفة
+
+276
+00:22:32,900 --> 00:22:38,650
+ممكن تحط indicator بزيادة شويةأو بنقص شوية برضه
+
+277
+00:22:38,650 --> 00:22:44,090
+النتيجة هتتذبذب ممكن تيجي تتغلب في قراءة ال end
+
+278
+00:22:44,090 --> 00:22:47,790
+point فتقول يا فلان شوف للون بالله إيجا اللون ولا
+
+279
+00:22:47,790 --> 00:22:52,650
+لأ مثلا يعني فطبعا فلان ممكن يكون خبير وممكن يكون
+
+280
+00:22:52,650 --> 00:22:56,250
+مش خبير ومش كل مرة هشوفلك اللون يعني هو شافولك مرة
+
+281
+00:22:56,250 --> 00:22:59,610
+أزميله هيشوفه مرة كل واحد هيشوفه مرة وهيحصل عندك
+
+282
+00:22:59,610 --> 00:23:03,770
+نوع من الخطأ في بعض الأحيان بعض الطلاب بيكون فيه
+
+283
+00:23:03,770 --> 00:23:08,120
+في إيده أكل مختبر تلت ساعاتوالله مش مفطر فراح يعني
+
+284
+00:23:08,120 --> 00:23:12,800
+جايب sandwich على المختبر فضل في إيده أثار من مادة
+
+285
+00:23:12,800 --> 00:23:18,100
+قلوية أو مادة حمضية مثلا يعني أو مادة من المواد
+
+286
+00:23:18,100 --> 00:23:20,840
+اللي أنت بتحللها فوجعه شوية في ال flask ومش مااخد
+
+287
+00:23:20,840 --> 00:23:23,900
+باله، لو أخد باله لكبه وعاد التجربة، لكن هو مش
+
+288
+00:23:23,900 --> 00:23:30,890
+مااخد باله، المهم نتيجة أخطاءأو تصرفات غير محسوبة
+
+289
+00:23:30,890 --> 00:23:35,730
+وغير يعني محددة معروفة سلفان ممكن أحصل على نتائج
+
+290
+00:23:35,730 --> 00:23:40,050
+مختلفة هان بنقول إيه؟ بنقول نتائج المختلفة هذه
+
+291
+00:23:40,050 --> 00:23:45,230
+طبيعية لكن ال analyst الجيد اللي بيشتغل في التحليل
+
+292
+00:23:45,230 --> 00:23:51,110
+هو جيد بيعمل نتيجة الانتباه الشديد والخبرة
+
+293
+00:23:51,110 --> 00:23:56,770
+والدراية والاهتمام بالعمل بيعمل على تقليل الخطأ
+
+294
+00:23:57,710 --> 00:24:01,610
+العشوائي ال random error اللي هو ال indeterminate
+
+295
+00:24:01,610 --> 00:24:06,610
+error بيعمل على تقليله بشكل كبير جدا لا يستطيع ان
+
+296
+00:24:06,610 --> 00:24:12,590
+ينهي لكن بيعمل على تقليله بشكل كبير للغاية فمهمتنا
+
+297
+00:24:12,590 --> 00:24:18,190
+انه نشتغل بدقة نشتغل باهتمام نشتغل بانتباه علشان
+
+298
+00:24:18,190 --> 00:24:22,170
+الخطأ ال indeterminate ال random اللي لازم يكون
+
+299
+00:24:22,170 --> 00:24:28,710
+موجود يكون اقل ما يمكن ماشي يا شبابممكن احنا برضه
+
+300
+00:24:28,710 --> 00:24:34,310
+نتطلع على الأخطاء حسابيا ك absolute error او
+
+301
+00:24:34,310 --> 00:24:38,470
+relative error ال
+
+302
+00:24:38,470 --> 00:24:42,850
+absolute error هو عبارة عن الخطأ المطلق يعني مثلا
+
+303
+00:24:42,850 --> 00:24:47,950
+انت بتعمل تجربة بتطلع نتيجة النتيجة الحقيقية او
+
+304
+00:24:47,950 --> 00:24:55,250
+المقبولة معروفة فنتيجتك ناقص مطروح منهاالنتيجة
+
+305
+00:24:55,250 --> 00:24:58,430
+الحقيقية أو المقبولة هذا بعطيك حاجة بنقولها
+
+306
+00:24:58,430 --> 00:25:04,090
+absolute error فمثلا اعمل التحليل لجات النتيجة 11
+
+307
+00:25:04,090 --> 00:25:11,130
+.1% بينما انت عارف مأهد القياسات الدولية مثلا
+
+308
+00:25:11,130 --> 00:25:17,430
+بيقولك انه نتيجة 12.1%انت بتقدر تحسب هان ال
+
+309
+00:25:17,430 --> 00:25:22,250
+absolute error ال absolute error مش النسبة بيقولك
+
+310
+00:25:22,250 --> 00:25:27,970
+نتيجتك التجربية ناقص النتيجة الحقيقية هان 11 و 1
+
+311
+00:25:27,970 --> 00:25:35,060
+من 10 ناقص 12 و 1 من 10 بيعطيك سالب 1 يعنيبيقولك
+
+312
+00:25:35,060 --> 00:25:38,540
+إن نتيجتك أقل السالب يعني نتيجتك أقل من الحقيقية
+
+313
+00:25:38,540 --> 00:25:41,940
+يعني ال absolute error ممكن يكون موجب نتيجتك أعلى
+
+314
+00:25:41,940 --> 00:25:47,320
+أو أقل يعني نتيجتك أقل فإله اتجاه إله اتجاه هذا
+
+315
+00:25:47,320 --> 00:25:51,140
+بيقول ال absolute error لكن للأمانة و بديك تستوعب
+
+316
+00:25:51,140 --> 00:25:54,160
+هذا كلام كويس كتير مافيش معنى لل absolute error
+
+317
+00:25:54,160 --> 00:26:04,320
+مافيش معنى مافيش معنى لأنه مثلاانت جبت قطعة مثلا
+
+318
+00:26:04,320 --> 00:26:12,400
+قطعة ذهب وزنتها اجرام معروفة انها gram وزنتها على
+
+319
+00:26:12,400 --> 00:26:20,360
+ميزان كويس فطلعت وزنتها تمادية من عشرة gram بقول
+
+320
+00:26:20,360 --> 00:26:26,180
+ان ال absolute error سالب اتنين من عشرة سالب اتنين
+
+321
+00:26:26,180 --> 00:26:26,640
+من عشرة
+
+322
+00:26:30,050 --> 00:26:34,710
+لو كان عندك ألف جرام كيلو جرام مختوم كيلو جرام مية
+
+323
+00:26:34,710 --> 00:26:40,990
+في المية دهب وزنته على ميزان آخر فأعطاك تسعمية
+
+324
+00:26:40,990 --> 00:26:46,590
+وتسعة وتسعين وتمانية من عشرةإذا إيش ال absolute
+
+325
+00:26:46,590 --> 00:26:51,010
+error؟ برضه سالب اتنين من عشرة جرام لكن لما تقولي
+
+326
+00:26:51,010 --> 00:26:54,990
+والله عندك عملت وزنة أولى أو العينة الأولى اللى هي
+
+327
+00:26:54,990 --> 00:26:59,150
+واحد جرام بتقولي سالب اتنين من عشرة جرام و الوزنة
+
+328
+00:26:59,150 --> 00:27:01,350
+الكبيرة برضه سالب اتنين من عشرة جرام نفس ال
+
+329
+00:27:01,350 --> 00:27:06,350
+absolute error لكن معناهم مختلف تماما الأولى سالب
+
+330
+00:27:06,350 --> 00:27:10,850
+اتنين من عشرة على واحد في مية من مية هذه عشرين في
+
+331
+00:27:10,850 --> 00:27:19,590
+المية خطأبينما التانية اتنين من عشرة في .. في ..
+
+332
+00:27:19,590 --> 00:27:25,470
+قولنا من الألف اتنين من عشرة على الألف في مية من
+
+333
+00:27:25,470 --> 00:27:29,370
+مية بيعطيك اتنين من مية في المية نسبة خطأ الأولى
+
+334
+00:27:29,370 --> 00:27:33,370
+عشرين في المية والتانية اتنين من مية في الميةمعنى
+
+335
+00:27:33,370 --> 00:27:38,290
+الكلام الخطأ ك absolute value مافيش إله معنى، لازم
+
+336
+00:27:38,290 --> 00:27:42,950
+تقولجانبه إيش حجم العينة، وإلا مافيش فايدة منه ك
+
+337
+00:27:42,950 --> 00:27:45,830
+absolute value، ليه؟ لأنه من غير ما نعرف حجم
+
+338
+00:27:45,830 --> 00:27:50,230
+العينة، حتى لو كان نفس ال absolute error مافيش إله
+
+339
+00:27:50,230 --> 00:27:53,950
+قيمة، مافيش إله معنى، لازم نجيب حاجة بنقولها
+
+340
+00:27:54,640 --> 00:27:59,040
+relative error الخطأ النسبي هذا بيعطيني دلالة هذا
+
+341
+00:27:59,040 --> 00:28:02,820
+بيعطيني دلالة فمثلا انا طلعت ال absolute error قبل
+
+342
+00:28:02,820 --> 00:28:09,960
+شوية سالب واحد لكن العينة الحقيقية جداش كانت
+
+343
+00:28:09,960 --> 00:28:15,020
+اطمعاش واحد جال ممكن اجيب ال relative error بتساوي
+
+344
+00:28:15,020 --> 00:28:19,410
+ايش بتساوي ال absolute errorعلى ال accepted او ال
+
+345
+00:28:19,410 --> 00:28:24,530
+true value في 100 من 100 فلو طبقت الكلام هذا بقول
+
+346
+00:28:24,530 --> 00:28:27,510
+سالب واحد على اتناشر واحد من عشرة في 100 من 100
+
+347
+00:28:27,510 --> 00:28:30,610
+بيعطيني سالب تمانية و تلاتة من عشرة في المية يعني
+
+348
+00:28:30,610 --> 00:28:35,050
+بيقول لي انه نسبة الخطأ اللي عندك نسبة الخطأ مش
+
+349
+00:28:35,050 --> 00:28:39,230
+قيمته المطلقة نسبته تمانية و تلاتة من عشرة بالسالب
+
+350
+00:28:39,230 --> 00:28:42,610
+اه بفهم انه اه والله نسبة خطأ تمانية و تلاتة من
+
+351
+00:28:42,610 --> 00:28:47,210
+عشرة يعني نسبة دقة واحد و تسعين وسبعة من عشرة في
+
+352
+00:28:47,210 --> 00:28:50,880
+الميةإذا كان نسبة الخطأ هالجد إذا نسبة الديقة يعني
+
+353
+00:28:50,880 --> 00:28:55,580
+دقتي واحد وتسعين وسبعة من عشرة في المية فال
+
+354
+00:28:55,580 --> 00:28:59,300
+relative error هنستخدمه كتير خلال الفصل هذا يعتبر
+
+355
+00:28:59,300 --> 00:29:07,040
+طبعا أفضل كتير من ال absolute error برضه يا شباب
+
+356
+00:29:07,040 --> 00:29:10,700
+في مصطلح مش كتير بنستخدمه للأمانة يعني اسمه
+
+357
+00:29:10,700 --> 00:29:15,510
+relative accuracy relative accuracyهو استكمال للـ
+
+358
+00:29:15,510 --> 00:29:17,330
+Relative Error، إذا كان الـ Relative Error الجد
+
+359
+00:29:17,330 --> 00:29:19,690
+الباجر Relative Accuracy، إذا كان الـ Relative
+
+360
+00:29:19,690 --> 00:29:23,350
+Error إله قيمة، فبقية القيمة للـ 100 هي عبارة عن
+
+361
+00:29:23,350 --> 00:29:28,170
+Relative Accuracy بتساوي Your Value أو Your Result
+
+362
+00:29:28,920 --> 00:29:33,200
+الـ Experimental Result على الـ True Value في 100
+
+363
+00:29:33,200 --> 00:29:37,800
+من 100 فالـ Experimental Result كانت عن 11 و 1 من
+
+364
+00:29:37,800 --> 00:29:43,480
+10 على الـ True Value كانت 12 و 1 من 10 في 100 من
+
+365
+00:29:43,480 --> 00:29:48,120
+100 بيطلع استكمال الـ 8 و 3 من 10 السابقة بتكون
+
+366
+00:29:48,120 --> 00:29:54,100
+عبارة عن 91.7% مجموعة الـ Relative Error و
+
+367
+00:29:54,100 --> 00:29:59,500
+Relative Accuracyالمفروض انه 100% بيجمعوا الاتنين
+
+368
+00:29:59,500 --> 00:30:10,300
+ل 100% احنا حاليا هنحاول انه يعني نركز على مفهوم
+
+369
+00:30:10,300 --> 00:30:14,290
+ال errorنحاول أن نركز على مفهوم الـError وراحين
+
+370
+00:30:14,290 --> 00:30:20,270
+نعبر عنه بما يعرف بـStandard Deviation أو الانحراف
+
+371
+00:30:20,270 --> 00:30:24,270
+المياري بدنا نحاول نركز على مفهوم الـError لأن
+
+372
+00:30:24,270 --> 00:30:29,030
+الـError يعتبر جزء مهم جدا من دراستنا لأنه بتعلق
+
+373
+00:30:29,030 --> 00:30:33,450
+بمعظم نتائجنا، فيها Error فبدنا نعرف كيف نعبر عن
+
+374
+00:30:33,450 --> 00:30:36,530
+الـError احنا بدنا نعبر عن الـError أو
+
+375
+00:30:36,530 --> 00:30:42,500
+الـUncertainty بالإيه؟ بالـStandard Deviationأيش
+
+376
+00:30:42,500 --> 00:30:46,060
+هو ال standard deviation ال standard deviation يا
+
+377
+00:30:46,060 --> 00:30:50,460
+شباب المقصود فيه طبعا باللغة العربية بتقوله انحراف
+
+378
+00:30:50,460 --> 00:30:56,540
+معياري انحراف معياري ايش المقصود فيه مثلا انا بدي
+
+379
+00:30:56,540 --> 00:31:02,020
+اخد أطوال الشباب الموجودين في الغرفة أخدت أطوال
+
+380
+00:31:02,020 --> 00:31:06,680
+الشباب شاب شاب just أطوالهم لو بدي اجيب المتوسط
+
+381
+00:31:07,550 --> 00:31:13,050
+بجمع الأطوال كلها و بجسمها على عدد الشباب بياطين
+
+382
+00:31:13,050 --> 00:31:18,730
+المتوسط ايش يعني المتوسط؟ يعني قيمة في النص يعني
+
+383
+00:31:18,730 --> 00:31:24,230
+في قيم أعلى منها و في قيم أقل منها و هي وين جاية
+
+384
+00:31:24,230 --> 00:31:28,490
+في النص ال standard deviation بعبر عن ال spread
+
+385
+00:31:28,490 --> 00:31:35,070
+انتشار النتائج انتشار الحوالينالـ mean أو المتوسط
+
+386
+00:31:35,070 --> 00:31:38,610
+الـ average يبقى الاستخدام دي فيه عشان ايش بده
+
+387
+00:31:38,610 --> 00:31:42,410
+اطلع عليه انا؟ اطلع عليه كأنه ال spread انتشار
+
+388
+00:31:42,410 --> 00:31:47,330
+النتائج حوالين المتوسط هذا بيقول عنه الانحراف
+
+389
+00:31:47,330 --> 00:31:52,970
+المعياري طبعا لما نقاجي اخد شباب زيكمفي صف واحد
+
+390
+00:31:52,970 --> 00:31:59,450
+تقريبا نفس السن من نفس البلد بلاحظ انه يعني
+
+391
+00:31:59,450 --> 00:32:04,150
+الأطوال هتكون متقاربة إلى حد كبير عشان هيك ال
+
+392
+00:32:04,150 --> 00:32:09,770
+spread إيش هيكون؟قليل عشان هيك بنقول انه يعني
+
+393
+00:32:09,770 --> 00:32:14,510
+الانحراف المعياري هيكون قليل هنا في عندي مثلا
+
+394
+00:32:14,510 --> 00:32:18,610
+الشكل
+
+395
+00:32:18,610 --> 00:32:23,590
+اللي عامل زي الجرس اللي هو هذا الشكل اللي بيعبر عن
+
+396
+00:32:23,590 --> 00:32:27,430
+الانحراف المعياري .. الانحراف المعياري عامل زي
+
+397
+00:32:27,430 --> 00:32:32,890
+الجرس بال shape بنقوله بال shapeشكل الجرس وبيكون
+
+398
+00:32:32,890 --> 00:32:37,570
+في الرياضيات اسمه Gaussian curve يعني هو متناثل
+
+399
+00:32:37,570 --> 00:32:42,890
+حوالين الوساط يعني لو حطيت مرقاه بالظبط عند الخط
+
+400
+00:32:42,890 --> 00:32:47,850
+الأخضر اللي مبين بتلاحظ انه بيكمل الجزء الآخر فهو
+
+401
+00:32:47,850 --> 00:32:51,730
+Gaussian curve وهذا بنحصل عليه لو كان عدد النتائج
+
+402
+00:32:51,730 --> 00:32:55,690
+اللي عندنا كبير جدا بنحصل على هذا الشكل فلاحظوا
+
+403
+00:32:55,690 --> 00:33:02,660
+انه ال spreadلأ ال curve الأزرق قليل أقل من ال
+
+404
+00:33:02,660 --> 00:33:06,080
+spread لل curve الأحمر، صح؟ عشان هيك ال standard
+
+405
+00:33:06,080 --> 00:33:12,360
+deviation الناشرة عن القياسات اللي حصلنا منها على
+
+406
+00:33:12,360 --> 00:33:17,240
+ال curve الأزرق بيكون أقل من ال standard deviation
+
+407
+00:33:17,240 --> 00:33:22,460
+للقياسات اللي حصلنا عليها أو اعتطني ال curve
+
+408
+00:33:22,460 --> 00:33:29,380
+الأحمرفقلنا لو أخدنا متوسط أطوال الشباب هان هيكون
+
+409
+00:33:29,380 --> 00:33:33,800
+متوسط معين طب لو أخدنا ال spread هيكون spread ضيق
+
+410
+00:33:33,800 --> 00:33:40,180
+لأن الشباب كلهم في زي ما ذكرت يعني متقاربين في
+
+411
+00:33:40,180 --> 00:33:48,060
+السن والبيئة والبلد والعمر يعني نفس الحاجة تقريبا
+
+412
+00:33:48,060 --> 00:33:52,880
+بينما لو قلنا والله احناعدادكم مية مثلا لو قلنا
+
+413
+00:33:52,880 --> 00:33:58,920
+والله بدنا ناخد أول ميت نفر بدهم يمشوا في شارع
+
+414
+00:33:58,920 --> 00:34:04,180
+السوق مثلا والله من الأنفار اللي هيمشوا مثلا واحدة
+
+415
+00:34:04,180 --> 00:34:10,620
+ست معها تلت اربع ولاد راجل وصاحبه مثلا مجموعة بنات
+
+416
+00:34:10,620 --> 00:34:15,120
+عادة ثانوية او جامعة مجموعة شباب اعدادية او
+
+417
+00:34:15,120 --> 00:34:21,370
+ابتدائية مثلا يعني بنلاحظ ان في ايه؟في فروقات مهمة
+
+418
+00:34:21,370 --> 00:34:24,370
+في الأطوال مثلا أو اذا كانت بتاخد الأوزان نفس
+
+419
+00:34:24,370 --> 00:34:28,330
+الشيء ففي فروقات مهمة فحتاج ال spread ايش ماله؟
+
+420
+00:34:28,330 --> 00:34:33,350
+واسع مش هتلاقيه ضيق لكن لو أخدت مثلا الأطفال في
+
+421
+00:34:33,350 --> 00:34:39,890
+الروضةسنة تمهيدي أو سنة أول أبستان أو أول مدرسة
+
+422
+00:34:39,890 --> 00:34:44,970
+يعني مثلا أول ابتدائي هتلاحظ إنه في كل فئة هيكون
+
+423
+00:34:44,970 --> 00:34:50,050
+فيه نوع من التقارب فال spread هذا هو المقصود في
+
+424
+00:34:50,050 --> 00:34:56,180
+إيش يعني standard deviationاحنا بالنسبة لنا عشان
+
+425
+00:34:56,180 --> 00:34:59,800
+تستوعب معايا كويس، احنا بنعمل نفس التجربة عدة
+
+426
+00:34:59,800 --> 00:35:04,600
+مرات، فالاصل ايهاش ال spread يكون؟ ضيق للغاية،
+
+427
+00:35:04,600 --> 00:35:07,300
+الاصل يعني انه يكون ال spread عندنا ضيق، يعني
+
+428
+00:35:07,300 --> 00:35:13,100
+بنقدر نحكم على جودة العمليات تبعتنا او شغلنا من ال
+
+429
+00:35:13,100 --> 00:35:17,100
+spread اللي احنا بنفصل عليه، ليه؟ لأن احنا بنكرر
+
+430
+00:35:17,100 --> 00:35:22,580
+نفس التجربةأكتر من مرة يعني زي ما أجيو أجيس والله
+
+431
+00:35:22,580 --> 00:35:27,040
+وزن بني آدم أكتر من مرة وهو هيتغير الأصل أنه يكون
+
+432
+00:35:27,040 --> 00:35:31,280
+متقارب جدا جدا جدا أو طوله متقارب مالحاجش يتغير
+
+433
+00:35:31,280 --> 00:35:35,660
+فنفس الكلام التجربة احنا يعني بنعملها التجربة طبعا
+
+434
+00:35:35,660 --> 00:35:39,120
+لأن فيها experimental error وممكن ما تكونش العينة
+
+435
+00:35:39,120 --> 00:35:43,120
+يعني مية هي ممثلة لكن مش مية في المية ممثلة مايمكن
+
+436
+00:35:43,120 --> 00:35:46,860
+يكون فيه فروقات ويكون في عندنا standard deviation
+
+437
+00:35:46,860 --> 00:35:56,580
+يعني مختلف شويةطيب يا شباب من الناحية الإحصائية
+
+438
+00:35:56,580 --> 00:36:00,940
+احنا قلنا شكل ال standard deviation curve هو عبارة
+
+439
+00:36:00,940 --> 00:36:05,500
+عن bell shape Gaussian curve ال Gaussian curve هذا
+
+440
+00:36:05,500 --> 00:36:10,360
+يعني يلو معادلات رياضية بتحكمه يلو معادلات رياضية
+
+441
+00:36:10,360 --> 00:36:14,720
+بتحكمه طبعا ضمن مفهوم ال statistics أو الإحصاء
+
+442
+00:36:14,720 --> 00:36:21,250
+فإيش اللي بنقوله احنا احنا بنقول انه عادةإذا كان
+
+443
+00:36:21,250 --> 00:36:27,090
+في عندنا عينة العينة هذه جيبنا لها المتوسط فهيكون
+
+444
+00:36:27,090 --> 00:36:33,030
+في عندنا قيمة متوسطة هيكون في أقل منها أو أكتر
+
+445
+00:36:33,030 --> 00:36:36,470
+منها ال spread بيحكم ال standard deviation طب لو
+
+446
+00:36:36,470 --> 00:36:40,910
+أجينا أخدنا مثال قولنا أن عدد طلابنا في هذه القاعة
+
+447
+00:36:40,910 --> 00:36:49,530
+100 طالب و أجينا أخدنا المتوسط فوجدنا مثلا المتوسط
+
+448
+00:36:50,470 --> 00:36:54,810
+متوسط الأطوال مية و سبعين مية و خمسة و سبعين
+
+449
+00:36:54,810 --> 00:37:00,710
+centimeter مثلا بنقول طيب خلينا نجيس ال standard
+
+450
+00:37:00,710 --> 00:37:04,530
+deviation ال spread كيف بدنا نجيسه بعد شوية هنجيسه
+
+451
+00:37:04,530 --> 00:37:08,050
+بعد شوية هنتعلم كيف نعمله لكن ال standard
+
+452
+00:37:08,050 --> 00:37:11,310
+deviation طلع مثلا خمسة centimeter
+
+453
+00:37:17,930 --> 00:37:22,350
+الجداول الأخصار بتقول ان ال X bar زائد او ناقص S
+
+454
+00:37:22,350 --> 00:37:29,820
+68% من النتائجبتوجع ما بين ال X bar زائد او ناقص
+
+455
+00:37:29,820 --> 00:37:35,380
+بمعنى ان جدش المتوسط ان ال X bar 175 ناقص خمسة
+
+456
+00:37:35,380 --> 00:37:39,520
+يعني مية و سبعين زائد خمسة يعني مية و تمانين يعني
+
+457
+00:37:39,520 --> 00:37:44,200
+من مية و سبعين ل مية و تمانين لو عددكم مية طالب و
+
+458
+00:37:44,200 --> 00:37:46,960
+متوسطكم كان مية و خمسة و سبعين و ال standard
+
+459
+00:37:46,960 --> 00:37:51,440
+deviation كان خمسة صنطي و عدد ده جولنا جداش مية
+
+460
+00:37:51,440 --> 00:37:57,760
+اذا هلاجي تمانية و ستين طالب فيكمطولهم بين الـ 170
+
+461
+00:37:57,760 --> 00:38:02,960
+و الـ 180 طيب و الـ 32 اللي ضايقين؟ لأ طوالهم خارج
+
+462
+00:38:02,960 --> 00:38:09,740
+ال range هذا طب لو أخدت X bar زادة و نقص 2S قال 95
+
+463
+00:38:09,740 --> 00:38:15,940
+% من ال 100 هيكون .. هيكون بيوجعوا في هذا ال range
+
+464
+00:38:15,940 --> 00:38:21,480
+يعني لو أجيتوا و عملتم X bar 175 ناقص 2S يعني عشرة
+
+465
+00:38:22,540 --> 00:38:29,060
+إذا مية و خمسة و ستين إلى مية و خمسة و تمانين
+
+466
+00:38:29,060 --> 00:38:35,980
+هنلاحظ أنه 95% من الطلاب بيوجع طولهم في هذا ال
+
+467
+00:38:35,980 --> 00:38:39,860
+range هذه فوائد مهمة جدا .. فوائد مهمة جدا من وين
+
+468
+00:38:39,860 --> 00:38:42,940
+جيبنا هذا كلب من جامعة؟ أحصائيا هذا كلب معروف ليه؟
+
+469
+00:38:42,940 --> 00:38:50,790
+هذا كان ناتج يعني آلاف و عشرات آلاف التجارباللي
+
+470
+00:38:50,790 --> 00:38:55,410
+عملناها سابقة وحصلنا منها دائما على هذه النتائج
+
+471
+00:38:55,410 --> 00:39:00,390
+طبعا لو وسعنا ال range شوية هنضم عدد أكبر من
+
+472
+00:39:00,390 --> 00:39:03,490
+الطلاب يعني لو قلنا مثلا اتنين و نص S هنلاقي تسعة
+
+473
+00:39:03,490 --> 00:39:07,450
+و تسعين في المية من الطلاب بيندرجوا في X bar زادة
+
+474
+00:39:07,450 --> 00:39:14,570
+او ناقص اتنين S ال X bar المتوسط قلناها ال S هي ال
+
+475
+00:39:14,570 --> 00:39:18,010
+standard deviation اللي قلنا هناخده كيف نحسبه الجد
+
+476
+00:39:19,820 --> 00:39:24,960
+ما هو زائد S يعني زائد خمسة ناقص S يعني ناقص خمسة
+
+477
+00:39:24,960 --> 00:39:28,960
+مية خمسة وسبعين ناقص خمسة مية وسبعين طب زائد خمسة
+
+478
+00:39:28,960 --> 00:39:35,360
+ما هي زائد أو ناقص عشان تعملها range اتنين S نفسه
+
+479
+00:39:35,360 --> 00:39:38,920
+خمسة اتنين في خمسة عشرة يبقى مية وخمسة وسبعين ناقص
+
+480
+00:39:38,920 --> 00:39:43,640
+عشرة مية وخمسين زائد عشرة مية وخمسين من احصائيا
+
+481
+00:39:43,640 --> 00:39:47,620
+وجدنا ان هذا كلام دائما موجود احصائيا السؤال هل
+
+482
+00:39:47,620 --> 00:39:54,010
+السؤال اسم القيم هذا؟إيش إلها اسم يعني؟
+
+483
+00:39:54,010 --> 00:40:01,930
+يعني هذه عدد من أفراد العينة بيكون مشمول إذا كان X
+
+484
+00:40:01,930 --> 00:40:05,510
+bar زائد أو نقص S أو X bar زائد أو نقص 2S إلى آخر
+
+485
+00:40:05,510 --> 00:40:10,590
+على أي حال يا شباب في عنا أربع أنواع من أنواع ال
+
+486
+00:40:10,590 --> 00:40:15,170
+standard deviation اللي هندرسها أول نوع بنقوله
+
+487
+00:40:15,170 --> 00:40:20,970
+population standard deviationpopulation بتعني كل
+
+488
+00:40:20,970 --> 00:40:27,470
+العينة يعني مثلا انا بدي اشوف متوسط اطوال طلاب في
+
+489
+00:40:27,470 --> 00:40:34,190
+شعبة 101 كيميا تحليلية اللي هم انتوا ايش بعمل بجيس
+
+490
+00:40:34,190 --> 00:40:39,550
+اطوال كل الشباب كلهم population كل ال population و
+
+491
+00:40:39,550 --> 00:40:43,870
+بجيب المتوسط بجسم على عددهم بجيب المتوسط المتوسط
+
+492
+00:40:43,870 --> 00:40:50,030
+في هذه الحالة اسمه MUاسمه ال true mean ال true
+
+493
+00:40:50,030 --> 00:40:56,790
+mean المتوسط ال إيه؟ الحقيقي لأنه مش تقديري مش
+
+494
+00:40:56,790 --> 00:41:02,110
+تجريبي يعني هذا true mean مش يعني estimated مش
+
+495
+00:41:02,110 --> 00:41:07,630
+مقدر لأ والله أنا إجيت جست كل أفراد العينات و
+
+496
+00:41:07,630 --> 00:41:11,050
+بعدين جسمت على عددهم فال mean اللي حصلت عليه إيه
+
+497
+00:41:11,050 --> 00:41:19,520
+شماله؟حقيقي ال true mean كويس فهذا اسمه MU XI هي
+
+498
+00:41:19,520 --> 00:41:23,780
+عبارة عن طول الشاب الأول يكون اسمه X1 الشاب التاني
+
+499
+00:41:23,780 --> 00:41:27,880
+X2 الشاب التالت X3 الشاب الرابع طوله X4 الشاب
+
+500
+00:41:27,880 --> 00:41:34,780
+الخامس X5 و هكذا يبقى summation مجموعة XI اللي هو
+
+501
+00:41:34,780 --> 00:41:40,290
+طول الأول نقص المتوسط تربيع زائدطول التاني نقص
+
+502
+00:41:40,290 --> 00:41:42,930
+المتوسط التربية زائد طول التالت نقص المتوسط
+
+503
+00:41:42,930 --> 00:41:43,490
+التربية زائد طول التالت نقص المتوسط التربية زائد
+
+504
+00:41:43,490 --> 00:41:43,530
+طول التالت نقص المتوسط التربية زائد طول التالت نقص
+
+505
+00:41:43,530 --> 00:41:43,890
+المتوسط التربية زائد طول التالت نقص المتوسط
+
+506
+00:41:43,890 --> 00:41:43,890
+التربية زائد طول التالت نقص المتوسط التربية زائد
+
+507
+00:41:43,890 --> 00:41:43,890
+طول التالت نقص المتوسط التربية زائد طول التالت نقص
+
+508
+00:41:43,890 --> 00:41:43,890
+المتوسط التربية زائد طول التالت نقص المتوسط
+
+509
+00:41:43,890 --> 00:41:45,590
+التربية زائد طول التالت نقص المتوسط التربية زائد
+
+510
+00:41:45,590 --> 00:41:55,150
+طول التالت نقص المتوسط التربية زائد طول
+
+511
+00:41:55,150 --> 00:41:57,230
+التالت نقص
+
+512
+00:41:59,910 --> 00:42:02,870
+أه يبقى ال population standard deviation بتحدث عن
+
+513
+00:42:02,870 --> 00:42:07,370
+عدد data points كبير بتحدث عن عدد من ال
+
+514
+00:42:07,370 --> 00:42:11,470
+experiments ايش مالها كبير خالص احنا في الكيما
+
+515
+00:42:11,470 --> 00:42:14,210
+بنعمل يعني اكتر من اشرين تجربة اشرين تلاتين تجربة
+
+516
+00:42:14,210 --> 00:42:17,970
+احنا في الكيما بنقدرش نحلل المادة مثلا اشرين
+
+517
+00:42:17,970 --> 00:42:22,930
+تلاتين مرة احنا بنحللها تلت لخمس مرات علشان هيك
+
+518
+00:42:22,930 --> 00:42:26,610
+احنا في الكيما بنتعاملش مع حاجة اسمها population
+
+519
+00:42:26,610 --> 00:42:30,730
+standard deviationأنا لو بدي أخد أطوال الشباب مثلا
+
+520
+00:42:30,730 --> 00:42:35,090
+كتجربة باخد مثلا أول سطرين لإنه أول سطرين مثلا
+
+521
+00:42:35,090 --> 00:42:38,730
+بقولهم بالمثل الكلية لإنه والله ماجعدوش انا
+
+522
+00:42:38,730 --> 00:42:45,430
+ماجعدتهمش جانب بعض لإنهم مثلا اجسارولا لأنهم مثلا
+
+523
+00:42:45,430 --> 00:42:50,150
+يعني من بلد واحدة او من .. لأ عشوائيا جاعد وانا
+
+524
+00:42:50,150 --> 00:42:54,490
+اختارت هذه العينة لكن هل بالضرورة لو أخدت أطوال
+
+525
+00:42:54,490 --> 00:42:57,350
+العينة اللي هم ال تمام تنفار اللي قدامها الأول
+
+526
+00:42:57,350 --> 00:43:02,410
+سطرين هل بالضرورة المتوسط تبعهم يساوي المتوسط
+
+527
+00:43:02,410 --> 00:43:08,230
+الحقيقي للكل؟ لأ هذا اسمه إيش experimental mean او
+
+528
+00:43:08,230 --> 00:43:13,120
+average experimental average تجريبيestimated
+
+529
+00:43:13,120 --> 00:43:18,440
+تقديري يعني بيعبر عن الكل إلى حد ما علشان هيك احنا
+
+530
+00:43:18,440 --> 00:43:23,620
+بنقول انه احنا مابنتعامل مع ال population standard
+
+531
+00:43:23,620 --> 00:43:27,100
+deviation population غلبة كتير يعني مثلا لو بدي
+
+532
+00:43:27,100 --> 00:43:31,440
+انا اجيب متوسط أطواء الشباب قطاع غزة في الجامعات
+
+533
+00:43:31,440 --> 00:43:34,600
+بدروح لف على كل الجامعات واخدوا أطواء كل شخص هذه
+
+534
+00:43:34,600 --> 00:43:39,510
+مشكلة عويصةقصة طويلة جدا مانقدرش نعملها فعادة ال
+
+535
+00:43:39,510 --> 00:43:42,210
+population standard deviation احنا في الكيميا
+
+536
+00:43:42,210 --> 00:43:46,630
+تحديدا مابنستخدمهاش هايش اللي بنستخدمه جانب نستخدم
+
+537
+00:43:46,630 --> 00:43:52,870
+حاجة بنقولها sample standard deviation عينة فقط
+
+538
+00:43:52,870 --> 00:43:57,250
+عينة او estimated standard deviation بدل ما يكون
+
+539
+00:43:57,250 --> 00:44:03,910
+اسمه sigma ايش سمناه S صغيرة S صغيرة ايش بتساوي؟
+
+540
+00:44:04,800 --> 00:44:09,260
+نفس الكلام زي هدا بالظبط summation xi اللي هي
+
+541
+00:44:09,260 --> 00:44:13,000
+الأول مثلا يعني احنا بقوله ناخد التمانية هدول هيك
+
+542
+00:44:13,000 --> 00:44:17,960
+بظبط معناه تمانية x طول الأول ناقص ال average تبع
+
+543
+00:44:17,960 --> 00:44:23,120
+التمانية ال experimental mean ال average أو ال
+
+544
+00:44:23,120 --> 00:44:28,100
+mean ل data points الطبع التربيع الطول التاني ناقص
+
+545
+00:44:28,100 --> 00:44:32,790
+الالـ X bar اللى هو المتوسط التربيع طول التالت
+
+546
+00:44:32,790 --> 00:44:37,730
+ناقص المتوسط التربيع إلى لما نخلص التمانية على إن
+
+547
+00:44:37,730 --> 00:44:42,230
+ناقص واحد هدى عدد التجارب اللى هي عدد أفراد العينة
+
+548
+00:44:42,230 --> 00:44:46,780
+ناقص واحد عدد التجارب ناقص واحد إيه الاسم؟بنقولها
+
+549
+00:44:46,780 --> 00:44:49,880
+عادة degrees of freedom يعني هذه الكلمة .. هذه
+
+550
+00:44:49,880 --> 00:44:54,160
+البصطلح ان ناقص واحد عادة تجارب ناقص واحد بنقوله
+
+551
+00:44:54,160 --> 00:44:57,780
+number of degrees of freedom في الرياضيات number
+
+552
+00:44:57,780 --> 00:45:03,040
+of degrees of freedom فهذا الناتج تبعنا بنقوله ايه
+
+553
+00:45:03,040 --> 00:45:07,480
+estimated standard deviation او sample standard
+
+554
+00:45:07,480 --> 00:45:10,640
+deviation هذا هو اللي بنستخدمه ما بنستخدم ال
+
+555
+00:45:10,640 --> 00:45:17,060
+population standard deviationكمثال يعني على هذا
+
+556
+00:45:17,060 --> 00:45:24,120
+الكلام لو جينا و طلعنا على ال replicate weights
+
+557
+00:45:24,120 --> 00:45:32,520
+عملنا عدة يعني في عندي وزنة حطيتها عدة مرات على
+
+558
+00:45:32,520 --> 00:45:35,580
+ميزان فعطتني twenty nine point ايه التلاتين و
+
+559
+00:45:35,580 --> 00:45:38,680
+اتنين و عشرة two eight point six two nine point
+
+560
+00:45:38,680 --> 00:45:44,570
+seven milligram فبدوا يحسب ال Sوبدي احسب حاجات
+
+561
+00:45:44,570 --> 00:45:48,990
+اخرى هوضحها الحصة الجاية بس هالجيت بدنا نقول كيف
+
+562
+00:45:48,990 --> 00:45:54,050
+نحسب ال S ففي انتهاء النتائج اربع نتائج بقول والله
+
+563
+00:45:54,050 --> 00:45:58,270
+علشان احسب ال S او ال estimated بدي اجيب في الاول
+
+564
+00:45:58,270 --> 00:46:02,310
+ال average ال experimental mean فبقول بجمعهم
+
+565
+00:46:03,200 --> 00:46:07,520
+وبقسمهم على أربعة الأربعة هذه عدد exact number
+
+566
+00:46:07,520 --> 00:46:09,160
+ماحدش يقولها دعوة من ال significant figures لا
+
+567
+00:46:09,160 --> 00:46:12,400
+مالاش دعوة انا بقول هنا ك significant figures
+
+568
+00:46:12,400 --> 00:46:18,020
+الجواب بيحتوي على عدد واحد لا مش تلاتة عدد واحد
+
+569
+00:46:18,020 --> 00:46:20,640
+بعد العلامة العشرية عدد واحد بعد العلامة العشرية
+
+570
+00:46:20,640 --> 00:46:20,840
+عدد واحد بعد العلامة العشرية عدد واحد بعد العلامة
+
+571
+00:46:20,840 --> 00:46:22,940
+العشرية عدد واحد بعد العلامة العشرية عدد واحد بعد
+
+572
+00:46:22,940 --> 00:46:25,800
+العلامة العشرية عدد واحد بعد العلامة العشرية عدد
+
+573
+00:46:25,800 --> 00:46:25,960
+واحد بعد العلامة العشرية عدد واحد بعد العلامة
+
+574
+00:46:25,960 --> 00:46:26,620
+العشرية عدد واحد بعد العلامة العشرية عدد واحد بعد
+
+575
+00:46:26,620 --> 00:46:28,180
+العلامة العشرية عدد واحد بعد العلامة العشرية عدد
+
+576
+00:46:28,180 --> 00:46:32,530
+واحد بعد العلامة العشرية عدأربعة فبنقول ال X واحد
+
+577
+00:46:32,530 --> 00:46:39,570
+أول نتيجة ناقص ال X bar كويس اتنين من عشرة ال X
+
+578
+00:46:39,570 --> 00:46:43,370
+اتنين ناقص ال X bar ال X تلاتة ناقص ال X bar ال X
+
+579
+00:46:43,370 --> 00:46:48,280
+أربعة ناقص ال X bar بحصل على هذه القيمتمام؟ باجي
+
+580
+00:46:48,280 --> 00:46:53,320
+بربع هدول لإنه بدي x i minus x bar تربيع بربعهم
+
+581
+00:46:53,320 --> 00:46:57,960
+بيطلع عنده قيم بجمعها بيطلع عنده مجموعهم اللي هو
+
+582
+00:46:57,960 --> 00:47:03,620
+summation x i minus x bar تربيع summation بيطلع
+
+583
+00:47:03,620 --> 00:47:07,120
+عنده one point four one لو جسمت على ال n minus one
+
+584
+00:47:07,120 --> 00:47:11,900
+تحت الجزر كله بيعطيني ال standard deviation ال
+
+585
+00:47:11,900 --> 00:47:14,340
+standard deviation بيطلع عنده point six nine
+
+586
+00:47:14,340 --> 00:47:19,080
+milligramsماشي يا شباب الحصة الجاية هنبدأ من هذا
+
+587
+00:47:19,080 --> 00:47:19,580
+المثال
+